National Library of Energy BETA

Sample records for tis ti cal

  1. CriTi-CAL: A computer program for Critical Coiled Tubing Calculations

    SciTech Connect (OSTI)

    He, X.

    1995-12-31

    A computer software package for simulating coiled tubing operations has been developed at Rogaland Research. The software is named CriTiCAL, for Critical Coiled Tubing Calculations. It is a PC program running under Microsoft Windows. CriTi-CAL is designed for predicting force, stress, torque, lockup, circulation pressure losses and along-hole-depth corrections for coiled tubing workover and drilling operations. CriTi-CAL features an user-friendly interface, integrated work string and survey editors, flexible input units and output format, on-line documentation and extensive error trapping. CriTi-CAL was developed by using a combination of Visual Basic and C. Such an approach is an effective way to quickly develop high quality small to medium size software for the oil industry. The software is based on the results of intensive experimental and theoretical studies on buckling and post-buckling of coiled tubing at Rogaland Research. The software has been validated by full-scale test results and field data.

  2. CAL/AAEM Legislative Report

    E-Print Network [OSTI]

    Buchele, Michael J

    2005-01-01

    CAL/AAEM is working with CAL/ACEP and particularly the GAC (interests of CAL/AAEM and CAL/ ACEP have been aligned, andwheel. In addition, CAL/ACEP legislative initiatives have

  3. TIS (Technology Information System): The Intelligent Gateway Processor (IGP)

    SciTech Connect (OSTI)

    Hampel, V.E.; Barker, R.; Berch, M.; Kawin, R.; Lann, N.; McGrogan, S.; Sharpe, N.; Winiger, G.

    1984-10-01

    The Technology Information System (TIS) is an Intelligent Gateway Processor (IGP) capable of interconnecting heterogeneous information resources at geographically distributed locations in an automated, unified, and controlled manner. It augments the capabilities of personal computers and workstations of scientists and engineers by providing a shared directory to worldwide bibliographic and numeric resources and a library of self-guided procedures by which test, data, and graphs can be downloaded, reformatted, aggregated, analyzed, and shared among users and different host machines. The TIS link capability is used routinely for transcontinental tutorials and as a proactical means for the audiovisual linking of TIS users with experts at their respective locations. The IGP universal user interface permits changes and additions of available resources while running non-stop. The TIS/IGP at th Lawrence Livermore National Laboratory (LLNL) serves as the host system for several different communities of users who develop integrated information systems for personal and shared programmatic resources. The TIS local area network utilizes a 10 Mbps Ethernet which serves as a testbed for high-technology hardware and software.

  4. Sustainability Cal State Fullerton

    E-Print Network [OSTI]

    de Lijser, Peter

    Sustainability at Cal State Fullerton A Report from the Sustainability Initiative Study Group October 28, 2008 #12;Sustainability at Cal State Fullerton A Report from the Sustainability Initiative Safety Sally Yassine Contracts & Procurement #12;Sustainability at Cal State Fullerton A Report from

  5. Toponome Imaging System (TIS): imaging the proteome with functional resolution

    E-Print Network [OSTI]

    Cai, Long

    established as an automated imaging technology capable of high- performance, high-content applications at continuous intensity levels for the first time.TIS directly addresses protein-network architecture. A breakthrough in fluorescence imaging has been reported using multi-epitope-ligand cartography (MELC) technology

  6. CalAAEM Legislative Report- Summer 2006

    E-Print Network [OSTI]

    Buchele, Michael J

    2006-01-01

    3, Summer 2006 Page 63 CAL/ACEP Monitored Legislation: 1.emergency medicine, but CAL/ACEP is in support of conformitycontinues to work with Cal/ACEP, and particularly the GAC (

  7. CAL/ACEP Joins CAL/AAEM and UC Irvine in Sponsoring the Western Journal of Emergency Medicine

    E-Print Network [OSTI]

    Mallon, William K.; Swadron, Stuart P

    2009-01-01

    P erspectives CAL/ACEP Joins CAL/AAEM and UC Irvine inof AAEM (CAL/AAEM) and the California Chapter of ACEP (CAL/ACEP). Based on an agreement forged this year, CAL/ACEP

  8. Case study of CalSTRS headquarters

    E-Print Network [OSTI]

    Goins, John; Moezzi, Mithra

    2011-01-01

    peers % satisfied CalSTRS LEED CBE office UFAD temperaturelevel CalSTRS visual comfort LEED noise level CBE officebuilding to three peer groups: LEED-rated buildings 7 , all

  9. President's Message: What's Happening at CAL/AAEM?

    E-Print Network [OSTI]

    Vogler, Francine

    2005-01-01

    Conference) along with CAL/ACEP and CAL/ENA. The LLC, heldto join forces with CAL/ ACEP in a political alliance forhas been approached by CAL/ ACEP to join forces on those

  10. CAL/AAEM President's Message: Proposition 67—Serving a Vital Need in California Emergency Care

    E-Print Network [OSTI]

    Lotfipour, Shahram

    2004-01-01

    and Leadership Forum with Cal/ACEP and Cal/ENA. Cal/AAEMBusiness Forum at every Cal/ACEP Assembly. We have continuedAdvocacy through Cal/ACEP. Cal/AAEM has a representative on

  11. SoCal Edge: Accelerating Investments in Innovative Building Technologi...

    Office of Environmental Management (EM)

    SoCal Edge: Accelerating Investments in Innovative Building Technologies SoCal Edge: Accelerating Investments in Innovative Building Technologies October 26, 2015 - 2:53pm Addthis...

  12. ${\\cal D}$-deformed harmonic oscillators

    E-Print Network [OSTI]

    F. Bagarello; F. Gargano; D. Volpe

    2014-12-30

    We analyze systematically several deformations arising from two-dimensional harmonic oscillators which can be described in terms of $\\cal{D}$-pseudo bosons. They all give rise to exactly solvable models, described by non self-adjoint hamiltonians whose eigenvalues and eigenvectors can be found adopting the quite general framework of the so-called $\\cal{D}$-pseudo bosons. In particular, we show that several models previously introduced in the literature perfectly fit into this scheme.

  13. The New York arTisT doesN'T jusT paiNT The

    E-Print Network [OSTI]

    Snider, Barry B.

    154 The New York arTisT doesN'T jusT paiNT The female bodY; she charTs all of The faNTasies, a Yuskavage's work: its seriousness and its play. No question, the New York­based painter has spent a lifetime: A painter hits on an idea that seems relatively new or interesting and soon endless iterations

  14. CATCH BY LEADI G COU TIS 1960 70 U.N. USES NEARLY 100 FISHING VESSELS

    E-Print Network [OSTI]

    , test sea w a t e r , and to analyze samples of the aquat ic life fish eat . FAO Aims T he aims and marine engineers d sign th flshm sels and arrange constructton and d h The department head IS Jan-) TI-bottom quality, and presence of heavy metals (like mercury and cadmium) were che cked. Many Below Safety Levels

  15. President’s Message: Keeping Informed – The CAL/AAEM News Service

    E-Print Network [OSTI]

    Swadron, Stuart P

    2008-01-01

    have a strong beacon in CAL/ACEP, CAL/AAEM and OCMA. My hopeour colleagues in the CAL/ACEP leadership, with your help,

  16. Challenging the Cost Effectiveness of Medi-Cal Managed Care

    E-Print Network [OSTI]

    Riner, R. Myles

    2009-01-01

    American College of Emergency Physicians (CAL/ACEP), and amember of the ACEP Reimbursement Committee. There were no

  17. Project Charter CALS External Relations Advancement Planning: Alumni

    E-Print Network [OSTI]

    Herrman WALSAA Board Tara Talbot CALS BOV Kara Luedtke External Relations Megan O'Rourke UP&S, Career

  18. LumiCal alignment system - Status report

    E-Print Network [OSTI]

    Daniluk, W.; Lesiak, T.; Moszczy?ski, A.; Pawlik, B.; Wojto?, T.; Zawiejski, L.

    2015-01-01

    The paper describes the status of the laser-based alignment-system for the luminosity detector, LumiCal, taking into considerations the conditions of the International Large Detector in the International Linear Collider project. The design of the system comprises two parts: the first one containing semi-transparent silicon sensors used to deliver simultaneous position measurements in the X,Y directions of the monitored object, and the second one in which the interferometric technique, i.e. the Frequency Scanning Interferometry (FSI), is proposed. Two laboratory prototypes for both components of the system were built and the preliminary measurements of the DUT displacements demonstrated their utility in the design of the final alignment system. The alignment of the LumiCal detector will allow us to monitor the detector displacements and possible deformations in its internal structure. Lack of information of the displacements will introduce a systematic effect which will have an impact on the accuracy of the fi...

  19. CalStar Products | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County, California: Energy ResourcesCRED: A New Model(Redirected fromCalStar

  20. Absolute orientation-dependent TiN(001) step energies from two-dimensional equilibrium island shape and

    E-Print Network [OSTI]

    Khare, Sanjay V.

    ; Adatoms B1 NaCl-structure TiN is widely used for de- positing hard wear-resistant coatings on cutting tools, diffusion-barrier layers in microelectronic devices, corrosion-resistant coatings on mechani- cal

  1. President's Message- The Future of CalAAEM, Part II

    E-Print Network [OSTI]

    Gabaeff, Steven C

    2006-01-01

    a more even footing with Cal/ACEP financially. These effortsmedicine and fee splitting The ACEP leadership expends thephysician income. 5. Mandatory ACEP membership… is it legal?

  2. SoCalGas- New Construction Advanced Homes Incentives

    Broader source: Energy.gov [DOE]

    SoCalGas offers an incentive for home builders to build homes which exceed 2008 Title 24 standards by 15%. The program is open to all single-family and multi-family new construction projects. A...

  3. Challenging the Cost Effectiveness of Medi-Cal Managed Care

    E-Print Network [OSTI]

    Riner, R. Myles

    2009-01-01

    on the average per capita cost of the eligibility cohort orCal population. The per capita cost method of calculatingwith the adjusted average per capita costs (AAPCC), and with

  4. SoCalGas- Residential Energy Efficiency Loan Program

    Broader source: Energy.gov [DOE]

    The Southern California Gas Company (SoCalGas) offers The Home Energy Upgrade Financing (HEUF) program to its residential customers interested in making energy efficient improvements to their homes...

  5. Testimonials- Partnerships in Battery Technologies- CalBattery

    Broader source: Energy.gov [DOE]

    Phil Roberts, CEO and Founder of California Lithium Battery (CalBattery), describes the new growth and development that was possible through partnering with the U.S. Department of Energy.

  6. CALS Office of Student Services--Career Development Cornell University 140 Roberts Hall Ithaca, NY 14853 www.cals.cornell.edu P: 607/255CALS (2257) F: 607/2544613 calsstudentservices@cornell.edu

    E-Print Network [OSTI]

    Angenent, Lars T.

    2257-01-01

    or view them online at: www.cals.cornell.edu/cals/current/career/. Job Pos ngs: An extensive number than five years ago, you can search for Cornell alumni job pos ngs by establishing an experience

  7. CALS APC Self Study 2013-14 CALS Academic Planning Council (APC) Self-Study Review 2013-14

    E-Print Network [OSTI]

    to remove apparent conflict of interest. · improve the utility of the APC website and College of Engineering APCs were reviewed. An online survey was sent to all CALS faculty and academic staff (designated "Survey A") and a separate survey

  8. The structure of supersymmetry in ${\\cal PT}$ symmetric quantum mechanics

    E-Print Network [OSTI]

    D. Bazeia; Ashok Das; L. Greenwood; L. Losano

    2009-03-17

    The structure of supersymmetry is analyzed systematically in ${\\cal PT}$ symmetric quantum mechanical theories. We give a detailed description of supersymmetric systems associated with one dimensional ${\\cal PT}$ symmetric quantum mechanical theories. We show that there is a richer structure present in these theories compared to the conventional theories associated with Hermitian Hamiltonians. We bring out various properties associated with these supersymmetric systems and generalize such quantum mechanical theories to higher dimensions as well as to the case of one dimensional shape invariant potentials.

  9. UCLA CalTeach-Math Junior Year Program Description

    E-Print Network [OSTI]

    Ferguson, Thomas S.

    8 UCLA CalTeach-Math Junior Year Program Description: o Pedagogical Content Preparation: The Math 103ABC Seminar Students in the junior year program take Math 103ABC, Observation and Participation: Mathematics Instruction. Each quarter of the Math 103 sequence is a 2 unit seminar course designed to expose

  10. UCLA CalTeach-Math Sophomore Year Program Description

    E-Print Network [OSTI]

    Ferguson, Thomas S.

    7 UCLA CalTeach-Math Sophomore Year Program Description: o Pedagogical Content Preparation: The Math 72SL Seminar Students in the sophomore program take Math 72SL, Classroom Practices in Middle School Mathematics. Math 72SL is a 2 unit seminar course designed to expose students to current issues

  11. UCLA CalTeach-Math Freshman Year Program Description

    E-Print Network [OSTI]

    Ferguson, Thomas S.

    6 UCLA CalTeach-Math Freshman Year Program Description: o Pedagogical Content Preparation: The Math 71SL Seminar Students in the freshman program take Math 71SL, Classroom Practices in Elementary: Observations in an Elementary School Students in Math 71SL observe mathematics teaching in a local elementary

  12. Cal. PRC Section 6909 - Oil and Gas and Mineral Leases: Geothermal...

    Open Energy Info (EERE)

    Cal. PRC Section 6909 - Oil and Gas and Mineral Leases: Geothermal Resources Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Cal....

  13. Californians Newly Eligible for Medi-Cal under Health Care Reform

    E-Print Network [OSTI]

    Pourat, Nadereh; Martinez, Ana E.; Kominski, Gerald F.

    2011-01-01

    for Medi-Cal under Health Care Reform Nadereh Pourat, Ana E.implementation of health care reform by incorporating manyCal under Health Care Reform. Los Angeles, CA: UCLA Center

  14. CAMPARE and Cal-Bridge: Promo5ng Astronomy & Physics for

    E-Print Network [OSTI]

    Rudolph, Alexander L.

    CAMPARE and Cal-Bridge: Promo5ng Astronomy & Physics for Underrepresented Colloquium UC Berkeley October 16, 2014 #12;Why CAMPARE and Cal-Bridge? · "Li% United States Hispanic 17% 31% #12;Why CAMPARE and Cal-Bridge? · "LiQle progress has been

  15. ${\\cal N} = 1$ Euler Anomaly Flow from Dilaton Effective Action

    E-Print Network [OSTI]

    Prochazka, Vladimir

    2015-01-01

    We consider ${\\cal N} =1$ supersymmetric gauge theories in the conformal window. The running of the gauge coupling is absorbed into the metric by applying a suitable matter superfield- and Weyl-transformation. The computation becomes equivalent to one of a free theory in a curved background carrying the information of the renormalisation group flow. We use the techniques of conformal anomaly matching and dilaton effective action, by Komargodski and Schwimmer, to rederive the difference of the Euler anomaly coefficient $\\Delta a \\equiv a_{\\rm UV} - a_{\\rm IR} $ for the ${\\cal N} =1$ theory. The structure of $\\Delta a $ is therefore in one-to-one correspondence with the Wess-Zumino dilaton action.

  16. NC_MAJOR ACAD_PLAN SUBPLAN PLANDESCR SUBPLANDESCR DEGREE ACAD_PROG 11A 11AGSCI Agriculture Undeclared CALS

    E-Print Network [OSTI]

    PSSPAE Plant and Soil Sciences-BS Agroecology Concentration BS CALS 11PB 11PBBS Plant Biology-BS BS CALS

  17. CliniCal anesthesia ConferenCe 2015

    E-Print Network [OSTI]

    Thompson, Michael

    Can-am CliniCal anesthesia ConferenCe 2015 T H I r T Y - T H I r D a n n u a l Conference 2015 Please FaX, Mail or e-Mail: CMe aDMinistRatOR Continuing Health Sciences education mcmaster conferences: yes no www.twitter.com/mcmaster_chse http://ca.linkedin.com/pub/mcmaster-continuing- health

  18. Giant resonances in Ti-46,Ti-48 

    E-Print Network [OSTI]

    Tokimoto, Y.; Lui, Y. -W; Clark, H. L.; John, B.; Chen, X.; Youngblood, David H.

    2006-01-01

    The giant resonance region from 9 MeV < E-x < 55 MeV in Ti-46 and Ti-48 has been studied with inelastic scattering of 240 MeV alpha particles at small angles including 0(degrees). Isoscalar monopole strength in Ti-46 (Ti-48) was found corresponding...

  19. Cal-Bridge: A CSU-UC PhD Bridge Program to Increase Diversity in Astronomy and Physics

    E-Print Network [OSTI]

    Rudolph, Alexander L.

    Cal-Bridge: A CSU-UC PhD Bridge Program to Increase Diversity in Astronomy Cal Poly Pomona October 23, 2014 #12;Why Cal-Bridge (and CAMPARE)? · "Li States Hispanic 17% 31% #12;Why Cal-Bridge (and CAMPARE)? Percent of doctorates awarded

  20. 15 Cal. Veh. Code § 35780 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand Dalton Jump to:Wylie, Texas:V.S.A. Chapter 5 CommonOpen5414Cal. Veh.

  1. 15 Cal. Veh. Code § 35781 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand Dalton Jump to:Wylie, Texas:V.S.A. Chapter 5 CommonOpen5414Cal. Veh.1

  2. Cal. Pub. Res. Code § 6370 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine:Kansas: Energy ResourcesParish, Louisiana:Pub. Res. Code4136009Cal.

  3. CalRENEW-1 Solar Power Plant | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy Electricals Ltd BHEL JumpCMNA Power Jump to:OffshoreCalRENEW-1

  4. CALS Office of Student Services--Career Development Cornell University 140 Roberts Hall Ithaca, NY 14853 www.cals.cornell.edu P: 607/255CALS (2257) F: 607/2544613 calsstudentservices@cornell.edu

    E-Print Network [OSTI]

    Angenent, Lars T.

    2257-01-01

    , salaries, job and in ternship search techniques, and graduate school infor ma on. Materials are searchable what majors, salary informa on, and much more. Alumni Career Link ­ This network of 900+ CALS alum

  5. M i n u t e s CALS Curriculum Committee Meeting

    E-Print Network [OSTI]

    330. The motion was approved. NEW BUSINESS Brewing Certificate Proposal ­ The proposal rationale was held a motion was made by Grummer and seconded by Bonhoff to support the creation of a Brewing of support to the APC for the Brewing Certificate Proposal on behalf of the CALS Curriculum Committee. CALS

  6. The M8 Power Calibration Experiment (M8CAL)

    SciTech Connect (OSTI)

    Robinson, W. R.; Bauer, T. H.

    1994-05-01

    The M8 calibration experiment was a series of 23 irradiations in TREAT performed to determine the relationship between the fission power generated in the TREAT core and the fission power generated in experiment fuel located in an in-core experiment vehicle and irradiated by core neutrons. The experiment was planned to provide the essential calibration information specifically needed for planning and analysis of the M8 test (and subsequent tests similar in geometry to M8) to be performed in the post-upgrade TREAT core. Irradiations were performed in TREAT cores loaded with a full-slotted (to optimize hodoscope performance) and with a half-slotted (to maximize energy deposition). Tests included a few selected low-power irradiations of fresh IFR-type U-Zr and U-Pu-Zr fuel pins supplemented by multiple irradiations of uranium-zirconium monitor wires ranging from low steady-state power to high-power maximal transients. This report describes the M8CAL test hardware, measurements, analysis assumptions, and methods used to deduce power coupling between the reactor and experiment fuel--including both absolute magnitudes and axial distributions. Power coupling results are reported for fresh IF fuel pins under high-power transient test conditions appropriate to the planned M8 transient test. In line with previous calibration data, measured dependence of power coupling on the specifics of each irradiation is also shown to correlate well with the in-core axial locations of the TREAT control rods. Estimates are made for maximal test fuel energy deposition capabilty in controlled transients.

  7. Marine mammal monitoring and habitat investigations during CalCOFI surveys

    E-Print Network [OSTI]

    Soldevilla, M S; Wiggins, S M; Calambokidis, J; Douglas, A; Oleson, E M; Hildebrand, John A

    2006-01-01

    Lowry. 2005. U.S. Pacific Marine Mammal Stock Assessments:Ecol. Model. 193:645–662. MARINE MAMMAL MONITORING CalCOFIW. D. 1997. Role of marine mammals in aquatic ecosystems.

  8. Data regression using the TI's calculators TI 82 and TI 83

    E-Print Network [OSTI]

    Torres, Rodolfo

    Data regression using the TI's calculators TI 82 and TI 83 TI 85 TI 86 Doing data regression in the TI-82 or TI-83 Entering the data Press to get the statistics menu. Select and press .Edit Enter the x-data in L1 and the y-data in L2. Doing the regression Press to get the statistics menu. Select and select

  9. Complete set of elastic, dielectric, and piezoelectric coefficents of 0.93Pb,,Zn1/3Nb2/3...O30.07PbTiO3 single crystal poled along 011

    E-Print Network [OSTI]

    Cao, Wenwu

    ­0.07PbTiO3 single crystal poled along 011 Rui Zhang Department of Physics, Harbin Institute of Technology, and piezoelectric coefficients of rhomboheral phase 0.93Pb Zn1/3Nb2/3 O3­0.07PbTiO3 single crystal poled along 011 boundary MPB exhibit superior electromechani- cal properties at room temperature when being poled along

  10. Qiu Ti’s Contributions to Juelanshe and the Intersection of Modernist Ideology, Public Receptivity, and Personal Identity for a Woman Oil Painter in Early Twentieth-Century China

    E-Print Network [OSTI]

    Wright, Amanda Sue

    2011-12-31

    : Modern Chinese Oil Painting,” In Julia Frances Andrews, Kuiyi Shen, and Jonathan D. Spence, eds. A Century in Crisis : Modernity and Tradition in the Art of Twentieth- Century China (New York: Guggenheim Museum: Harry N. Abrams, 1998): 175. 1.1 A...'s Series of Contemporary Paintings by Chinese Artists Section II [O]CCIDENTAL: NO.8” Liangyou 93 (1934). 1.4 “Exposition of Storm Society Paintings,” Shidai huabao (Nov 1933). 1.5 “Juelanshe jiang????” Shidai huabao 5.4 (Nov 1933). 1...

  11. The Blackbody Radiation Laws in the $ \\textrm{AdS}_5 \\times {\\cal S}^5 $ Spacetime

    E-Print Network [OSTI]

    Ramaton Ramos; Henrique Boschi-Filho

    2015-04-25

    In the footsteps of our previous work \\cite{RamatonBoschi} we generalize the Stefan-Boltzmann and Wien's displacement laws for the $ \\textrm{AdS}_5 \\times {\\cal S}^5 $ spacetime, the background of the AdS/CFT correspondence foremost realization. Our results take into account the $ \\textrm{AdS}_5 \\times {\\cal S}^5 $ full dimensionality in the electromagnetic field $A^{\\mu}$ wave equation, which yields the higher-dimensional blackbody characteristic features suggested in literature. In particular, the total radiated power and the spectral radiancy match the original Stefan-Boltzmann and Wien's displacement laws in the low-energy regime up to available experimental data.

  12. http://dnr.cals.cornell.edu/undergraduate/ntres-4300-environmental-and-natural-resources-policy-COURSE APPLICATION

    E-Print Network [OSTI]

    Walter, M.Todd

    http://dnr.cals.cornell.edu/undergraduate/ntres-4300-environmental-and-natural-resources-policy- processes COURSE APPLICATION Environmental Policy Processes (NTRES 4300) Sessions: Fall, 2014; January 2015://dnr.cals.cornell.edu/undergraduate/ntres-4300-environmental-and-natural-resources-policy- processes ). This recommendation is due to Catherine

  13. Earth System Modeling Facility: Linking Climate to Cal-(IT)2 and OptIPuter

    E-Print Network [OSTI]

    Rose, Michael R.

    Earth System Modeling Facility: Linking Climate to Cal-(IT)2 and OptIPuter Charlie Zender in quantitatively-based environmental planning. #12;1. Overview Present: 1. Earth System Modeling Facility (ESMF) 2 and Planning #12;2. Earth System Modeling Facility (ESMF) Background: In 2003, NSF, UCI, & IGPP awarded $1.3M

  14. SCHROEDER AND LOVE.: RECREATIONAL FISHING AND MARINE FISH POPULATIONS CalCOFI Rep., Vol. 43, 2002

    E-Print Network [OSTI]

    Love, Milton

    SCHROEDER AND LOVE.: RECREATIONAL FISHING AND MARINE FISH POPULATIONS CalCOFI Rep., Vol. 43, 2002 RECREATIONAL FISHING AND MARINE FISH POPULATIONS IN CALIFORNIA DONNA M. SCHROEDER AND MILTON S. LOVE Marine@lifesci.ucsb.edu ABSTRACT We present and review information regarding recre- ational angling and exploited marine fish

  15. After-School energizerS Classroom-based PhysiCal aCtivities

    E-Print Network [OSTI]

    Gopalakrishnan, K.

    After-School energizerS Classroom-based PhysiCal aCtivities Integrating physical activity with academic concepts energizerS were DevelopeD by in pArtnerShip with Activity Promotion Laboratory SchoolSchool Energizers is the third edition of classroom energizers, and the developed specifically for the 21st Century

  16. 46 CAMP 2012 Proceedings and Profiles UCla ChemiCal engineer regan

    E-Print Network [OSTI]

    California at Los Angles, University of

    46 CAMP 2012 Proceedings and Profiles UCLA UCla ChemiCal engineer regan PatterSon takeS the international Stage in geneva R egan Patterson is a UCLA junior majoring in Chemical Engineering project integrates her engineering foundation with her environmental interest. Patterson simulates

  17. The Biosta s cs Consul ng Service provides comprehensive sta s cal consul ng and

    E-Print Network [OSTI]

    ABOUT US The Biosta s cs Consul ng Service provides comprehensive sta s cal consul ng and data. DropIn is free, try it today. ByAppointment Service: These consul ng services include: Sample size for any of the above services, please fill out a consul ng applica on here: www

  18. Accepted to WTS 2008, Cal Poly Pomona, Pomona, California, April 24-26, 2008 Service Organization and Discovery for Facilitating RFID Network

    E-Print Network [OSTI]

    California at Los Angeles, University of

    Accepted to WTS 2008, Cal Poly Pomona, Pomona, California, April 24-26, 2008 Service Organization to WTS 2008, Cal Poly Pomona, Pomona, California, April 24-26, 2008 It is general knowledge

  19. Aerosol impacts on California winter clouds and precipitation during CalWater 2011: local pollution versus long-range transported dust

    E-Print Network [OSTI]

    2014-01-01

    California winter clouds and precipitation during CalWater 2011 mountain barrier. Together with the weak vertical transport,

  20. New Fuzzy Extra Dimensions from $SU({\\cal N})$ Gauge Theories

    E-Print Network [OSTI]

    Seckin Kurkcuoglu

    2015-05-18

    We start with an $SU(\\cal {N})$ Yang-Mills theory on a manifold ${\\cal M}$, suitably coupled to two distinct set of scalar fields in the adjoint representation of $SU({\\cal N})$, which are forming a doublet and a triplet, respectively under a global $SU(2)$ symmetry. We show that a direct sum of fuzzy spheres $S_F^{2 \\, Int} := S_F^2(\\ell) \\oplus S_F^2 (\\ell) \\oplus S_F^2 \\left ( \\ell + \\frac{1}{2} \\right ) \\oplus S_F^2 \\left ( \\ell - \\frac{1}{2} \\right )$ emerges as the vacuum solution after the spontaneous breaking of the gauge symmetry and lay the way for us to interpret the spontaneously broken model as a $U(n)$ gauge theory over ${\\cal M} \\times S_F^{2 \\, Int}$. Focusing on a $U(2)$ gauge theory we present complete parameterizations of the $SU(2)$-equivariant, scalar, spinor and vector fields characterizing the effective low energy features of this model. Next, we direct our attention to the monopole bundles $S_F^{2 \\, \\pm} := S_F^2 (\\ell) \\oplus S_F^2 \\left ( \\ell \\pm \\frac{1}{2} \\right )$ over $S_F^2 (\\ell)$ with winding numbers $\\pm 1$, which naturally come forth through certain projections of $S_F^{2 \\, Int}$, and discuss the low energy behaviour of the $U(2)$ gauge theory over ${\\cal M} \\times S_F^{2 \\, \\pm}$. We study models with $k$-component multiplet of the global $SU(2)$, give their vacuum solutions and obtain a class of winding number $\\pm (k-1)$ monopole bundles $S_F^{2 \\,, \\pm (k-1)}$ as certain projections of these vacuum solutions. We make the observation that $S_F^{2 \\, Int}$ is indeed the bosonic part of the $N=2$ fuzzy supersphere with $OSP(2,2)$ supersymmetry and construct the generators of the $osp(2,2)$ Lie superalgebra in two of its irreducible representations using the matrix content of the vacuum solution $S_F^{2 \\, Int}$. Finally, we show that our vacuum solutions are stable by demonstrating that they form mixed states with non-zero von Neumann entropy.

  1. An ${\\cal N}=3$ Solution in Dyonic ISO(7) Gauged Maximal Supergravity and Its Uplift to Massive Type IIA

    E-Print Network [OSTI]

    Yi Pang; Junchen Rong

    2015-10-16

    We consider a certain ${\\cal N}=1$ supersymmetric, SO(3)$\\times$SO(3) invariant, subsector of the dyonic ISO(7)-gauged maximal supergravity in four-dimensions. The theory contains two scalar fields and two pseudoscalar fields. We look for stationary points of the scalar potential, especially the one preserving ${\\cal N}=3$ supersymmetry of the original ISO(7) gauged theory. The ${\\cal N}=3$ stationary point corresponding to the $AdS$ vacuum in the $D=4$ theory is lifted to a warped $AdS_4\\times X_6$ type solution in massive type IIA supergravity. This $D=10$ background should be the dual of a certain ${\\cal N}=3$ Chern-Simons matter theory in three dimensions.

  2. An ${\\cal N}=3$ Solution in Dyonic ISO(7) Gauged Maximal Supergravity and Its Uplift to Massive Type IIA

    E-Print Network [OSTI]

    Pang, Yi

    2015-01-01

    We consider a certain ${\\cal N}=1$ supersymmetric, SO(3)$\\times$SO(3) invariant, subsector of the dyonic ISO(7)-gauged maximal supergravity in four-dimensions. The theory contains two scalar fields and two pseudoscalar fields. We look for stationary points of the scalar potential, especially the one preserving ${\\cal N}=3$ supersymmetry of the original ISO(7) gauged theory. The ${\\cal N}=3$ stationary point corresponding to the $AdS$ vacuum in the $D=4$ theory is lifted to a warped $AdS_4\\times X_6$ type solution in massive type IIA supergravity. This $D=10$ background should be the dual of a certain ${\\cal N}=3$ Chern-Simons matter theory in three dimensions.

  3. Crystallization and Preliminary Diffraction Analysis of the CAL PDZ Domain in Complex with a Selective Peptide Inhibitor

    SciTech Connect (OSTI)

    J Amacher; P Cushing; J Weiner; D Madden

    2011-12-31

    Cystic fibrosis (CF) is associated with loss-of-function mutations in the CF transmembrane conductance regulator (CFTR), which regulates epithelial fluid and ion homeostasis. The CFTR cytoplasmic C-terminus interacts with a number of PDZ (PSD-95/Dlg/ZO-1) proteins that modulate its intracellular trafficking and chloride-channel activity. Among these, the CFTR-associated ligand (CAL) has a negative effect on apical-membrane expression levels of the most common disease-associated mutant {Delta}F508-CFTR, making CAL a candidate target for the treatment of CF. A selective peptide inhibitor of the CAL PDZ domain (iCAL36) has recently been developed and shown to stabilize apical expression of {Delta}F508-CFTR, enhancing net chloride-channel activity, both alone and in combination with the folding corrector corr-4a. As a basis for structural studies of the CAL-iCAL36 interaction, a purification protocol has been developed that increases the oligomeric homogeneity of the protein. Here, the cocrystallization of the complex in space group P2{sub 1}2{sub 1}2{sub 1}, with unit-cell parameters a = 35.9, b = 47.7, c = 97.3 {angstrom}, is reported. The crystals diffracted to 1.4 {angstrom} resolution. Based on the calculated Matthews coefficient (1.96 {angstrom}{sup 3} Da{sup -1}), it appears that the asymmetric unit contains two complexes.

  4. A note on ${\\cal N}\\ge 6$ Superconformal Quantum Field Theories in three dimensions

    E-Print Network [OSTI]

    Denis Bashkirov

    2011-08-20

    Based on the structure of the three-dimensional superconformal algebra we show that every irreducible ${\\mathcal N}=6$ three-dimensional superconformal theory containes exactly one conserved U(1)-symmetry current in the stress tensor supermultiplet and that superconformal symmetry of every ${\\mathcal N}=7$ superconformal theory is in fact enhanced to ${\\mathcal N}=8$. Moreover, an irreducible ${\\cal N}=8$ superconformal theory does not have any global symmetries. The first observation explains why all known examples of ${\\mathcal N}=6$ superconformal theories have a global abelian symmetry.

  5. Angular Momentum and Gravimagnetization of the ${\\cal N}=2$ SYM vacuum

    E-Print Network [OSTI]

    A. Gorsky

    2011-02-09

    In this note we discuss the gravimagnetization of the ${\\cal N}=2$ SYM vacuum in the $\\Omega$-background. It is argued that the Seiberg-Witten prepotential is related to the vacuum density of the angular momentum in the Euclidean $R^4$ space. The possible role of the dyonic instantons as the microscopic angular momentum carriers which could yield the spontaneous vacuum gravimagnetization is conjectured. We interpret the dyonic instanton as a kind of the Euclidean bounce in $R^4$ similar to one responsible for the Schwinger pair creation. The induced angular momentum in $R^4$ is also briefly considered in the dual Liouville formulation of $SU(2)$ theory via AGT relation.

  6. Optical photometry of the eclipsing Large Magellanic Cloud supersoft source CAL 87

    E-Print Network [OSTI]

    C. Alcock

    1997-02-13

    We present optical photometry of the eclipsing supersoft source, CAL87. These observations comprise long term data accumulated as a by-product of the MACHO Project, and high speed white light photometry of a single eclipse. We (i) derive an improved ephemeris of To = HJD 2450111.5144(3) + 0.44267714(6)E for the time of minimum light, (ii) find the eclipse structure to be stable over a period of 4 years, and (iii) investigate the colour variation as a function of orbital phase. The resolution afforded by the high speed nature of the white light observations enables us to see new structure in the light curve morphology.

  7. Stress Tensor of Static Dipoles in strongly coupled $\\cal{N}$=4 Gauge Theory

    E-Print Network [OSTI]

    Shu Lin; Edward Shuryak

    2007-08-16

    In the context of the AdS/CFT correspondence we calculate the induced stress tensor of static dipoles (electric-electric and electric-magnetic) in a strongly coupled ${\\cal N}=4$ SYM gauge theory, by solving the linearized Einstein equation with Maldecena string as a source. Analytic expressions are given for the far-field and a near-field close to one charge, and compared to what one has in weak coupling. The result can be compared to lattice results for QCD-like theories in a deconfined but strongly coupled regime.

  8. Effective actions in ${\\cal N}$=1, D5 supersymmetric gauge theories: harmonic superspace approach

    E-Print Network [OSTI]

    I. L. Buchbinder; N. G. Pletnev

    2015-11-04

    We consider the off-shell formulation of the 5D, $ {\\cal N}$=1 super Yang-Mills and super Chern-Simons theories in harmonic superspace. Using such a formulation we develop a manifestly supersymmetric and gauge invariant approach to constructing the one-loop effective action both in super Yang-Mills and super Chern-Simons models. On the base of this approach we compute the leading low-energy quantum contribution to the effective action on the Abelian vector multiplet background. This contribution corresponds to $F^4$ invariant which is given in 5D superfield form.

  9. Effective actions in ${\\cal N}$=1, D5 supersymmetric gauge theories: harmonic superspace approach

    E-Print Network [OSTI]

    Buchbinder, I L

    2015-01-01

    We consider the off-shell formulation of the 5D, $ {\\cal N}$=1 super Yang-Mills and super Chern-Simons theories in harmonic superspace. Using such a formulation we develop a manifestly supersymmetric and gauge invariant approach to constructing the one-loop effective action both in super Yang-Mills and super Chern-Simons models. On the base of this approach we compute the leading low-energy quantum contribution to the effective action on the Abelian vector multiplet background. This contribution corresponds to $F^4$ invariant which is given in 5D superfield form.

  10. Secretary Chu Named Cal Alumnus of the Year | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-ThroughputUpcomingmagnetoresistance |Komlov,SearchFederalNamed Cal Alumnus of the

  11. Transfer of Air Force technical procurement bid set data to small businesses, using CALS and EDI: Test report

    SciTech Connect (OSTI)

    NONE

    1994-08-15

    This report documents a test transfer of three Air Force technical procurement bid sets to one large and twelve small businesses, using the Department of Defense (DoD) Continuous Acquisition and Life-cycle Support (CALS) and ANSI ASC X12 Electronic Data Interchange (EDI) standards. The main goal of the test was to evaluate the effectiveness of using CALS technical data within the context of the DoD`s EDI-based standard approach to electronic commerce in procurement, with particular emphasis on receipt and use of the data by small contractors. Air Force procurement data was provided by the Sacramento Air Logistics Center at McClellan Air Force Base; the manufacturing participants were selected from among McClellan`s ``Blue Ribbon`` contractors, located throughout the US. The test was sponsored by the Air Force CALS Test Network, headquartered at Wright-Patterson Air Force Base. The test successfully demonstrated the technical feasibility of including CALS MIL-R-28002 (Raster) engineering data in an EDI Specification/Technical Information transaction set (ANSI ASC X12 841) when issuing electronic requests for quotation to small businesses. In many cases, the data was complete enough for the contractor participant to feel comfortable generating a quote. Lessons learned from the test are being fed back to the CALS and EDI standards organizations, and to future implementors of CALS-EDI based acquisition or contracting systems, which require the transfer of technical information, such as engineering data, manufacturing process data, quality test data, and other product or process data, in the form of a CALS or other digital datafile.

  12. The TileCal Energy Reconstruction for LHC Run2 and Future Perspectives

    E-Print Network [OSTI]

    Seixas, Jose; The ATLAS collaboration

    2015-01-01

    The Tile Calorimeter (TileCal) is the main hadronic calorimeter of ATLAS and it covers the central part of the detector (|eta|energy deposited by the particles in TileCal is read out by approximately 10,000 channels. The signal provided by the readout electronics for each channel is digitized at 40 MHz and its amplitude is estimated by an optimal filtering algorithm. The increase of LHC luminosity leads to signal pile-up that deforms the signal of interest and compromises the amplitude estimation performance. This work presents the proposed algorithm for energy estimation during LHC Run 2. The method is based on the same approach used during LHC Run 1, namely the Optimal Filter (OF). The only difference is that the signal baseline (pedestal) will be subtracted from the received digitized samples, while in Run 1 this quantity was estimated on an event-by-event basis. The pedestal value is estimated through special calibration runs and it is stored in a data base for online and offline usage. Addi...

  13. The string origin of dyonic ${\\cal N}=8$ supergravity and its simple Chern-Simons duals

    E-Print Network [OSTI]

    Adolfo Guarino; Daniel L. Jafferis; Oscar Varela

    2015-11-09

    We clarify the higher-dimensional origin of a class of dyonic gaugings of $D=4$ ${\\cal N}=8$ supergravity recently discovered, when the gauge group is chosen to be ISO(7). This dyonically-gauged maximal supergravity arises from consistent truncation of massive IIA supergravity on $S^6$, and its magnetic coupling constant descends directly from the Romans mass. The critical points of the supergravity uplift to new AdS$_4$ massive type IIA vacua. We identify the corresponding CFT$_3$ duals as super-Chern-Simons-matter theories with simple gauge group SU$(N)$, with level $k$ given by the Romans mass. In particular, we find a critical point that uplifts to the first explicit ${\\cal N}=2$ AdS$_4$ massive IIA background. We compute its free energy and that of the candidate dual Chern-Simons theory by localisation to a solvable matrix model, and find perfect agreement. This provides the first AdS$_4$/CFT$_3$ precision match in massive type IIA string theory.

  14. The TileCal Energy Reconstruction for LHC Run2 and Future Perspectives

    E-Print Network [OSTI]

    Peralva, Bernardo Sotto-Maior

    2015-01-01

    The TileCal is the main hadronic calorimeter of ATLAS and it covers the central part of the detector ($|\\eta|$ energy deposited by the particles in TileCal is read out by approximately 10,000 channels. The signal provided by the readout electronics for each channel is digitized at 40 MHz and its amplitude is estimated by an optimal filtering algorithm. The increase of LHC luminosity leads to signal pile-up that deforms the signal of interest and compromises the amplitude estimation performance. This work presents the proposed algorithm for energy estimation during LHC Run 2. The method is based on the same approach used during LHC Run 1, namely the Optimal Filter. The only difference is that the signal baseline (pedestal) will be subtracted from the received digitized samples, while in Run 1 this quantity was estimated on an event-by-event basis. The pedestal value is estimated through special calibration runs and it is stored in a data base for online and offline usage. Additionally, the backg...

  15. Exact results for ${\\cal N}=2$ supersymmetric gauge theories on compact toric manifolds and equivariant Donaldson invariants

    E-Print Network [OSTI]

    Bershtein, Mikhail; Ronzani, Massimiliano; Tanzini, Alessandro

    2015-01-01

    We provide a contour integral formula for the exact partition function of ${\\cal N}=2$ super-symmetric $U(N)$ gauge theories on compact toric four-manifolds by means of supersymmetric localisation. We perform the explicit evaluation of the contour integral for $U(2)$ ${\\cal N}=2$ theory on $\\mathbb{P}^2$ for all instanton numbers. In the zero mass case, corresponding to the ${\\cal N}=4$ supersymmetric gauge theory, we obtain the generating function of the Euler characteristics of instanton moduli spaces in terms of quasi-modular forms. In the decoupling limit of infinite mass we find that the generating function of local and surface observables computes equivariant Donaldson invariants, thus proving in this case a long-standing conjecture by N. Nekrasov. In the case of vanishing first Chern class the resulting equivariant Donaldson polynomials are new.

  16. CAL 87 - an evolved wind-driven supersoft X-ray binary

    E-Print Network [OSTI]

    A. S. Oliveira; J. E. Steiner

    2007-07-23

    Compact binary supersoft X-ray sources (CBSS) are explained as being associated with hydrostatic nuclear burning on the surface of a white dwarf with high accretion rate. This high mass transfer rate has been suggested to be caused by dynamical instability, expected when the donor star is more massive than the accreting object. When the orbital period is smaller than ~6 hours, this mechanism does not work and the CBSS with such periods are believed to be fed by a distinct mechanism: the wind-driven accretion. Such a mechanism has been proposed to explain the properties of objects like SMC 13, T Pyx and V617 Sgr. One observational property that offers a critical test for discriminating between the above two possibilities is the orbital period change. As systems with wind-driven accretion evolve with increasing periods, some of them may reach quite long orbital periods. The above critical test may, therefore, also be applied to orbital periods longer than 6 hours. CAL 87 is an eclipsing system in the LMC with an orbital period of 10.6 hours that could provide the opportunity for testing the hypothesis of the system being powered by wind-driven accretion. We obtained eclipse timings for this system and show that its orbital period increases with a rate of P/Pdot = +7.2(+/-1.3) X 10^{6} years. Contrary to the common belief, we conclude that CAL 87 is the first confirmed case of a wind-driven CBSS with an orbital period longer than 6 hours. The system is probably an evolved object that had an initial secondary mass of M2i=0.63 solar masses but is currently reduced to about M2=0.34 solar masses. We discuss evidence that other CBSS, like CAL 83 and V Sge stars, like WX Cen, are probably also wind-driven systems. This may in fact be the rule, and systems with inverted mass ratio, the exception.

  17. Three-point functions in ${\\cal N}=4$ SYM: the hexagon proposal at three loops

    E-Print Network [OSTI]

    Eden, Burkhard

    2015-01-01

    Basso, Komatsu and Vieira recently proposed an all-loop framework for the computation of three-point functions of single-trace operators of ${\\cal N}=4$ super-Yang-Mills, the "hexagon program". This proposal results in several remarkable predictions, including the three-point function of two protected operators with an unprotected one in the $SU(2)$ and $SL(2)$ sectors. Such predictions consist of an "asymptotic" part---similar in spirit to the asymptotic Bethe Ansatz of Beisert and Staudacher for two-point functions---as well as additional finite-size "wrapping" L\\"uscher-like corrections. The focus of this paper is on such wrapping corrections, which we compute at three-loops in the $SL(2)$ sector. The resulting structure constants perfectly match the ones obtained in the literature from four-point correlators of protected operators.

  18. AlTiN layer effect on mechanical properties of Ti-doped diamond-like carbon composite coatings

    E-Print Network [OSTI]

    Volinsky, Alex A.

    AlTiN layer effect on mechanical properties of Ti-doped diamond-like carbon composite coatings Adhesion Ti/Ti-doped diamond-like carbon (DLC) and Ti/AlTiN/Ti-DLC composite coatings were deposited on the properties of these composite coatings was investigated through microstructure and mechanical properties

  19. Fabrication of functionally graded TiC/Ti composites by Laser Engineered Net Shaping

    E-Print Network [OSTI]

    DuPont, John N.

    engineered net shaping (LENS), with compositions changing from pure Ti to approximately 95 vol% TiC; Microstructure; TiC carbide 1. Introduction Functionally graded materials (FGMs) are a class of advanced

  20. Cosmology based on $f(R)$ gravity with ${\\cal O}(1)$ eV sterile neutrino

    E-Print Network [OSTI]

    A. S. Chudaykin; D. S. Gorbunov; A. A. Starobinsky; R. A. Burenin

    2015-05-13

    We address the cosmological role of an additional ${\\cal O}(1)$ eV sterile neutrino in modified gravity models. We confront the present cosmological data with predictions of the FLRW cosmological model based on a variant of $f(R)$ modified gravity proposed by one of the authors previously. This viable cosmological model which deviation from general relativity with a cosmological constant $\\Lambda$ decreases as $R^{-2n}$ for large, but not too large values of the Ricci scalar $R$ provides an alternative explanation of present dark energy and the accelerated expansion of the Universe. Various up-to-date cosmological data sets exploited include Planck CMB anisotropy, CMB lensing potential, BAO, cluster mass function and Hubble constant measurements. We find that the CMB+BAO constraints strongly the sum of neutrino masses from above. This excludes values $\\lambda\\sim 1$ for which distinctive cosmological features of the model are mostly pronounced as compared to the $\\Lambda$CDM model, since then free streaming damping of perturbations due to neutrino rest masses is not sufficient to compensate their extra growth occurring in $f(R)$ gravity. Thus, we obtain $\\lambda>8.2$ ($2\\sigma$) with cluster systematics and $\\lambda>9.4$ ($2\\sigma$) without that. In the latter case we find for the sterile neutrino mass $0.47\\,\\,\\rm{eV}$$\\,<\\,$$m_{\

  1. Probing Wilson loops in ${\\cal N}=4$ Chern-Simons-matter theories at weak coupling

    E-Print Network [OSTI]

    Griguolo, Luca; Mauri, Andrea; Penati, Silvia; Seminara, Domenico

    2015-01-01

    For three-dimensional ${\\cal N}=4$ super Chern-Simons-matter theories associated to necklace quivers $U(N_0) \\times U(N_1) \\times \\cdots U(N_{2r-1}) $, we study at quantum level the two kinds of 1/2 BPS Wilson loop operators recently introduced in arXiv:1506.07614. We perform a two-loop evaluation and find the same result for the two kinds of operators, so moving to higher loops a possible quantum uplift of the classical degeneracy. We also compute the 1/4 BPS bosonic Wilson loop and discuss the quantum version of the cohomological equivalence between fermionic and bosonic Wilson loops. We compare the perturbative result with the Matrix Model prediction and find perfect matching, after identification and remotion of a suitable framing factor. Finally, we discuss the potential appearance of three-loop contributions that might break the classical degeneracy and briefly analyse possible implications on the BPS nature of these operators.

  2. Understanding sources of organic aerosol during CalNex-2010 using the CMAQ-VBS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Woody, M. C.; Baker, K. R.; Hayes, P. L.; Jimenez, J. L.; Koo, B.; Pye, H. O. T.

    2015-10-05

    Community Multiscale Air Quality (CMAQ) model simulations utilizing the volatility basis set (VBS) treatment for organic aerosols (CMAQ-VBS) were evaluated against measurements collected at routine monitoring networks (Chemical Speciation Network (CSN) and Interagency Monitoring of Protected Visual Environments (IMPROVE)) and those collected during the 2010 California at the Nexus of Air Quality and Climate Change (CalNex) field campaign to examine important sources of organic aerosol (OA) in southern California. CMAQ-VBS (OA lumped by volatility, semivolatile POA) underpredicted total organic carbon (OC) at CSN (?25.5 % Normalized Median Bias (NMdnB)) and IMPROVE (?63.9 % NMdnB) locations and total OC wasmore »underpredicted to a greater degree compared to the CMAQ-AE6 (9.9 and ?55.7 % NMdnB, respectively; semi-explicit OA treatment, SOA lumped by parent hydrocarbon, nonvolatile POA). However, comparisons to aerosol mass spectrometer (AMS) measurements collected at Pasadena, CA indicated that CMAQ-VBS better represented the diurnal profile and the primary/secondary split of OA. CMAQ-VBS secondary organic aerosol (SOA) underpredicted the average measured AMS oxygenated organic aerosol (OOA, a surrogate of SOA) concentration by a factor of 5.2 (4.7 ?g m?3 measured vs. 0.9 ?g m?3 modeled), a considerable improvement to CMAQ-AE6 SOA predictions, which were approximately 24× lower than the average AMS OOA concentration. We use two new methods, based on species ratios and on a simplified SOA parameterization from the observations, to apportion the SOA underprediction for CMAQ-VBS to too slow photochemical oxidation (estimated as 1.5× lower than observed at Pasadena using ? log (NOx: NOy)), low intrinsic SOA formation efficiency (low by 1.6 to 2× for Pasadena), and too low emissions or too high dispersion for the Pasadena site (estimated to be 1.6 to 2.3× too low/high). The first and third factors will be similar for CMAQ-AE6, while the intrinsic SOA formation efficiency for that model is estimated to be too low by about 7×. For CMAQ-VBS, 90 % of the anthropogenic SOA mass formed was attributed to aged secondary semivolatile vapors (70 % originating from volatile organic compounds (VOCs) and 20 % from intermediate volatility compounds (IVOCs)). From source-apportioned model results, we found most of the CMAQ-VBS modeled POA at the Pasadena CalNex site was attributable to meat cooking emissions (48 %, and consistent with a substantial fraction of cooking OA in the observations), compared to 18 % from gasoline vehicle emissions, 13 % from biomass burning (in the form of residential wood combustion), and 8 % from diesel vehicle emissions. All "other" inventoried emission sources (e.g. industrial/point sources) comprised the final 13 %. The CMAQ-VBS semivolatile POA treatment underpredicted AMS hydrocarbon-like OA (HOA) + cooking-influenced OA (CIOA) at Pasadena by a factor of 1.8 (1.16 ?g m?3 modeled vs. 2.05 ?g m?3 observed) compared to a factor of 1.4 overprediction of POA in CMAQ-AE6, but did well to capture the AMS diurnal profile of HOA and CIOA, with the exception of the midday peak. We estimated that using the National Emission Inventory (NEI) POA emissions without scaling to represent SVOCs underestimates SVOCs by ~1.7×.« less

  3. Electrostatic carrier doping of GdTiO3/SrTiO3 interfaces

    E-Print Network [OSTI]

    2011-01-01

    of GdTiO 3 /SrTiO 3 interfaces Pouya Moetakef, 1 Tyler A.each GdTiO 3 /SrTiO 3 interface. The sheet carrier densitieselectron gas bound to the interface. These carrier densities

  4. Design of a New Switching Power Supply for the ATLAS TileCAL Front-End Electronics

    E-Print Network [OSTI]

    Drake, G; The ATLAS collaboration

    2012-01-01

    We present the design of an upgraded switching power supply for the front-end electronics of the ATLAS hadron tile calorimeter (TileCAL) at the LHC. The new design features significant improvement in noise, improved fault detection, and improved reliability, while retaining the compact size, water-cooling, output control, and monitoring features in this 300 KHz design. We discuss the steps taken to improve the design. We present the results from extensive radiation testing to qualify the design, including SEU sensitivity. We also present our reliability analysis. Production of 2400 new bricks for the detector is currently in progress, and we present preliminary results from the production checkout.

  5. An Upgraded Front-End Switching Power Supply Design for the ATLAS TileCAL Detector of the LHC

    E-Print Network [OSTI]

    Drake, G; The ATLAS collaboration; De Lurgio, P; Henriques, A; Minashvili, I; Nemecek, S; Price, L; Proudfoot, J; Stanek, R

    2011-01-01

    We present the design of an upgraded switching power supply brick for the front-end electronics of the ATLAS hadron tile calorimeter (TileCAL) at the LHC. The new design features significant improvement in noise, improved fault detection, and generally a more robust design, while retaining the compact size, water-cooling, output control, and monitoring features in this 300 KHz design. We discuss the improvements to the design, and the radiation testing that we have done to qualify the design. We also present our plans for the production of 2400 new bricks for installation on the detector in 2013.

  6. High-Pressure Behavior of Perovskite: FeTiO3 Dissociation into Fe1; TiO and Fe1Ti2O5

    E-Print Network [OSTI]

    Steinle-Neumann, Gerd

    High-Pressure Behavior of Perovskite: FeTiO3 Dissociation into ðFe1À; TiÞO and Fe1þTi2ÀO5 X. Wu,1 G, Australia (Received 22 January 2009; published 7 August 2009) The stability of perovskite structure, we observe in situ the breakdown of FeTiO3 perovskite into a ðFe1À; TiÞO þ Fe1þTi2ÀO5 assemblage

  7. Flipping Photoelectron Spins in Topological Insulators

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and photoelectron spin opens a wide range of possibilities for TIs. Strengthening Spintronics The ability to shine polarized light on a topological insulator (TI) and excite...

  8. r1(t) = (cos t)i + (sin t)i + tk, at

    E-Print Network [OSTI]

    MA 271 EXAM 1 FALL 2002 Name. 1. Find the angle between the curves at the indicated point. r1(t) = (cos t)i + (sin t)i + tk, at (1,0,0). 1-20) = (1 + t)i + tzj + tetk,. 2.

  9. A=17Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07) (See Energy Level93TI07)93TI07)

  10. A=17Ne (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07) (See93TI07)82AJ01) (See93TI07)

  11. Effect of aspect ratios of in situ formed TiB whiskers on the mechanical properties of TiBw/Ti6Al4V composites

    E-Print Network [OSTI]

    Hong, Soon Hyung

    online 27 December 2011 Ti alloy matrix composites reinforced with nanosized TiB whiskers (TiBw/Ti­6Al­4V composites (TMCs) reinforced using disparate ceramics as reinforcing agents have been of great interest­4V composites Min Young Koo,a Jae Sung Park,a Min Kyu Park,b Kyung Tae Kimc and Soon Hyung Honga

  12. Inland EmpIrE mErchandIsE Exports calIfornIa statE UnIvErsIty fUllErton

    E-Print Network [OSTI]

    de Lijser, Peter

    Inland EmpIrE mErchandIsE Exports calIfornIa statE UnIvErsIty fUllErton 20122012 CSUF Mihaylo University, Fullerton An Overview and Analysis of Inland Empire Exports #12;novEmbEr 2011 InstItUtE for EconomIc and EnvIronmEntal stUdIEs33 #12;Inland EmpIrE mErchandIsE Exports calIfornIa statE UnIvErsIty f

  13. Ti Leggett | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr.Theories (Journal Article) | SciTech20Home3Ti

  14. uel cells are attractive alternatives to combustion engines for electri-cal-power generation because of their very high efficiencies and low

    E-Print Network [OSTI]

    Haile, Sossina M.

    with water to yield hydrogen and carbon dioxide), there is inevitably some resid- ual carbon monoxide in the hydrogen supply. Carbon monoxide, in turn, is extremely detrimental to the catalysts in the fuel-cell anodeuel cells are attractive alternatives to combustion engines for electri- cal-power generation

  15. Volume 103. number 4 CHEhIlCAL PHYSICS LETTERS 6 January 1984 INFLUENCE OF ELECTRON AND NUCLEAR SPIN ON PHOTOFRAGMENT ALIGNMENT

    E-Print Network [OSTI]

    Volume 103. number 4 CHEhIlCAL PHYSICS LETTERS 6 January 1984 INFLUENCE OF ELECTRON AND NUCLEAR generally fragment when they are excited with photons of energy higher than their dissociation Limit Companies Foundation, Inc. to be adlusted for the effects of spin angular momen- ta that are not aligned

  16. Moffitt Library Student Leadership Hundreds of Cal students have shaped the vision for the new Moffitt Library through participation in focus

    E-Print Network [OSTI]

    California at Berkeley, University of

    Moffitt Library Student Leadership Hundreds of Cal students have shaped the vision for the new Moffitt Library through participation in focus groups, surveys, service learning projects, committees, and feedback on themed comment boards in the library and on the Moffitt Library Facebook page (facebook

  17. A=17C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not1959AJ76)93TI07) (Not2AJ01)93TI07)

  18. A=17He (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07) (See Energy Level93TI07) (Not

  19. A=17N (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07) (See93TI07) (See Energy Level

  20. A=17Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07) (See93TI07) (See6AJ04)

  1. A=17Si (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07)82AJ01) (SeeSi (1993TI07) (Not

  2. A=18C (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07)82AJ01)83AJ01) (Not95TI07) (See

  3. Combustion synthesis/quasi-isostatic pressing of TiC0.7NiTi cermets: microstructure and transformation characteristics

    E-Print Network [OSTI]

    Meyers, Marc A.

    Combustion synthesis/quasi-isostatic pressing of TiC0.7­NiTi cermets: microstructure Abstract TiC0.7­NiTi cermets were produced by com- bustion synthesis followed by quasi-isostatic consolidation while the reaction products were still hot and ductile. The TiC0.7­NiTi cermets were characterized

  4. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2014-12-20

    Four different parameterizations for the formation and evolution of secondary organic aerosol (SOA) are evaluated using a 0-D box model representing the Los Angeles Metropolitan Region during the CalNex 2010 field campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA formed only from the oxidation of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generationmore »oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model-measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model/measurement agreement for mass concentration. When comparing the three parameterizations, the Grieshop et al. (2009) parameterization more accurately reproduces both the SOA mass concentration and oxygen-to-carbon ratio inside the urban area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the parameterizations over-predict urban SOA formation at long photochemical ages (≈ 3 days) compared to observations from multiple sites, which can lead to problems in regional and global modeling. Among the explicitly modeled VOCs, the precursor compounds that contribute the greatest SOA mass are methylbenzenes. Polycyclic aromatic hydrocarbons (PAHs) are less important precursors and contribute less than 4% of the SOA mass. The amounts of SOA mass from diesel vehicles, gasoline vehicles, and cooking emissions are estimated to be 16–27, 35–61, and 19–35%, respectively, depending on the parameterization used, which is consistent with the observed fossil fraction of urban SOA, 71 (±3) %. In-basin biogenic VOCs are predicted to contribute only a few percent to SOA. A regional SOA background of approximately 2.1 ?g m?3 is also present due to the long distance transport of highly aged OA. The percentage of SOA from diesel vehicle emissions is the same, within the estimated uncertainty, as reported in previous work that analyzed the weekly cycles in OA concentrations (Bahreini et al., 2012; Hayes et al., 2013). However, the modeling work presented here suggests a strong anthropogenic source of modern carbon in SOA, due to cooking emissions, which was not accounted for in those previous studies. Lastly, this work adapts a simple two-parameter model to predict SOA concentration and O/C from urban emissions. This model successfully predicts SOA concentration, and the optimal parameter combination is very similar to that found for Mexico City. This approach provides a computationally inexpensive method for predicting urban SOA in global and climate models. We estimate pollution SOA to account for 26 Tg yr?1 of SOA globally, or 17% of global SOA, 1/3 of which is likely to be non-fossil.« less

  5. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2015-05-26

    Four different literature parameterizations for the formation and evolution of urban secondary organic aerosol (SOA) frequently used in 3-D models are evaluated using a 0-D box model representing the Los Angeles metropolitan region during the California Research at the Nexus of Air Quality and Climate Change (CalNex) 2010 campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle- and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA that formed only from the oxidationmore »of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generation oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model–measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate-volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model–measurement agreement for mass concentration. The results from the three parameterizations show large differences (e.g., a factor of 3 in SOA mass) and are not well constrained, underscoring the current uncertainties in this area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the recent parameterizations overpredict urban SOA formation at long photochemical ages (? 3 days) compared to observations from multiple sites, which can lead to problems in regional and especially global modeling. However, reducing IVOC emissions by one-half in the model to better match recent IVOC measurements improves SOA predictions at these long photochemical ages. Among the explicitly modeled VOCs, the precursor compounds that contribute the greatest SOA mass are methylbenzenes. Measured polycyclic aromatic hydrocarbons (naphthalenes) contribute 0.7% of the modeled SOA mass. The amounts of SOA mass from diesel vehicles, gasoline vehicles, and cooking emissions are estimated to be 16–27, 35–61, and 19–35%, respectively, depending on the parameterization used, which is consistent with the observed fossil fraction of urban SOA, 71(±3) %. The relative contribution of each source is uncertain by almost a factor of 2 depending on the parameterization used. In-basin biogenic VOCs are predicted to contribute only a few percent to SOA. A regional SOA background of approximately 2.1 ?g m?3 is also present due to the long-distance transport of highly aged OA, likely with a substantial contribution from regional biogenic SOA. The percentage of SOA from diesel vehicle emissions is the same, within the estimated uncertainty, as reported in previous work that analyzed the weekly cycles in OA concentrations (Bahreini et al., 2012; Hayes et al., 2013). However, the modeling work presented here suggests a strong anthropogenic source of modern carbon in SOA, due to cooking emissions, which was not accounted for in those previous studies and which is higher on weekends. Lastly, this work adapts a simple two-parameter model to predict SOA concentration and O/C from urban emissions. This model successfully predicts SOA concentration, and the optimal parameter combination is very similar to that found for Mexico City. This approach provides a computationally inexpensive method for predicting urban SOA in global

  6. Cal Poly Report Employee Newsletter October 2, 2013 file:///V:/UA/Marketing and Communications/Web_Sites_Private/calpol... 1 of 7 10/7/2013 3:21 PM

    E-Print Network [OSTI]

    Sze, Lawrence

    Cal Poly Report Employee Newsletter October 2, 2013 file:///V:/UA/Marketing and Communications/Web:///V:/UA/Marketing and Communications/Web_Sites_Private/calpol... 2 of 7 10/7/2013 3:21 PM #12;Cal Poly Report Employee Newsletter October 2, 2013 file:///V:/UA/Marketing and Communications/Web_Sites_Private/calpol... 3 of 7 10/7/2013 3

  7. Morphology, deformation, and defect structures of TiCr{sub 2} in Ti-Cr alloys

    SciTech Connect (OSTI)

    Chen, K.C.; Allen, S.M.; Livingston, J.D.

    1992-12-31

    The morphologies and defect structures of TiCr{sub 2} in several Ti-Cr alloys have been examined by optical metallography, x-ray diffraction, and transmission electron microscopy (TEM), in order to explore the room-temperature deformability of the Laves phase TiCr{sub 2}. The morphology of the Laves phase was found to be dependent upon alloy composition and annealing temperature. Samples deformed by compression have also been studied using TEM. Comparisons of microstructures before and after deformation suggest an increase in twin, stacking fault, and dislocation density within the Laves phase, indicating some but not extensive room-temperature deformability.

  8. Irradiation study of Ti6Al4V and Ti6Al4V1B for FRIB beam dump: Experimental plan

    E-Print Network [OSTI]

    McDonald, Kirk

    Irradiation study of Ti6Al4V and Ti6Al4V1B for FRIB beam dump: Experimental plan Aida Amroussia;Motivation · Study of irradiation damage in Ti-6Al-4V and Ti-6Al-4V-1B · Irradiation with different particles boron addition improves mechanical properties of Ti-6Al-4V after irradiation? Are the changes

  9. SW 55 Ti ROTOR Used In Beckman Coulter

    E-Print Network [OSTI]

    Marchant, Jonathan

    SW 55 Ti ROTOR Used In Beckman Coulter Class H, R, and S Preparative Ultracentrifuges FPO L5-TB-062M August 2006 © 2006 Beckman Coulter, Inc. Printed in the U.S.A. #12;2 SW 55 Ti Rotor SAFETY NOTICE made by other manufacturers may fit in the SW 55 Ti rotor, their safety in this rotor cannot

  10. Carrier-Controlled Ferromagnetism in SrTiO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moetakef, Pouya; Williams, James R.; Ouellette, Daniel G.; Kajdos, Adam P.; Goldhaber-Gordon, David; Allen, S. James; Stemmer, Susanne

    2012-06-01

    Magnetotransport and superconducting properties are investigated for uniformly La-doped SrTiO3 films and GdTiO3/SrTiO3 heterostructures, respectively. GdTiO3/SrTiO3 interfaces exhibit a high-density 2D electron gas on the SrTiO3 side of the interface, while, for the SrTiO3 films, carriers are provided by the dopant atoms. Both types of samples exhibit ferromagnetism at low temperatures, as evidenced by a hysteresis in the magnetoresistance. For the uniformly doped SrTiO3 films, the Curie temperature is found to increase with doping and to coexist with superconductivity for carrier concentrations on the high-density side of the superconducting dome. The Curie temperature of the GdTiO3/SrTiO3 heterostructures scales with themore »thickness of the SrTiO3 quantum well. The results are used to construct a stability diagram for the ferromagnetic and superconducting phases of SrTiO3.« less

  11. A=10Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA2 September 92004TI06)2004TI06) (See

  12. A=16Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not illustrated) This nucleus93TI07)

  13. A=16Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not illustrated)71AJ02) (See93TI07)

  14. A=16Ne (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not illustrated)71AJ02)82AJ01)93TI07)

  15. A=16Si (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not1959AJ76) (See the71AJ02)93TI07)

  16. A=17Al (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not1959AJ76) (See the71AJ02)93TI07)Al

  17. A=17Be (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not1959AJ76)93TI07) (Not illustrated)

  18. A=17F (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07) (See Energy Level Diagrams for

  19. A=17Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07) (See Energy

  20. A=17O (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07)82AJ01) (See Energy

  1. A=17P (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07)82AJ01) (See

  2. A=18B (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07)82AJ01) (SeeSi

  3. A=18Be (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07)93TI07)82AJ01) (SeeSi78AJ03)7AJ02)

  4. A=20Li (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06) (See EnergyLi (1998TI06)

  5. A=20Na (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06)3AJ01) (See Energy98TI06)

  6. A=3n (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See2010PU04)1987TI07) (Not

  7. A=4H (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See2010PU04)1987TI07)4A

  8. A=4HE (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See2010PU04)1987TI07)4AHe

  9. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See2010PU04)1987TI07)4AHeLi

  10. A=5H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)5 - 74AJ01) (See2002TI10) (Not

  11. A=5He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)5 - 74AJ01)4AJ01)2002TI10)

  12. Microstructure and mechanical properties of Ti/AlTiN/Ti-diamondlike carbon composite coatings on steel

    E-Print Network [OSTI]

    Volinsky, Alex A.

    for cutting tools.1­3 Some of these have already been applied in selected cases in modern machining techniquesTiN coating on hardened or austenitic stainless steels has been proven to improve cutting performance in heavy duty machining. These improvements were observed in different cutting operations due to the coat- ing

  13. Giant persistent photoconductivity in BaTiO{sub 3}/TiO{sub 2} heterostructures

    SciTech Connect (OSTI)

    Plodinec, Milivoj; Šanti?, Ana; Gajovi?, Andreja; Zavašnik, Janez; ?eh, Miran

    2014-10-13

    The persistent photoconductivity (PPC) effect in nanotube arrays of barium titanate and TiO{sub 2} (BTO/TiO{sub 2}NT) was studied at room temperature under daylight illumination. The BTO/TiO{sub 2}NT heterostructures exhibited a giant PPC effect that was six orders of magnitude higher than the dark conductivity, followed by a slow relaxation for 3 h. The PPC in this material was explained by the existence of defects at the surfaces and the interfaces of the investigated heterostructures. The sample was prepared using a two-step synthesis: the anodization of a Ti-foil and a subsequent hydrothermal synthesis. The structural and electrical characteristics were studied by micro-Raman spectroscopy, field-emission-gun scanning electron microscopy, and impedance spectroscopy.

  14. Measurement of the $^{44}$Ti($\\alpha$,p)$^{47}$V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed $^{44}$Ti.

    E-Print Network [OSTI]

    Murphy, Alexander

    2015-01-01

    Measurement of the $^{44}$Ti($\\alpha$,p)$^{47}$V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed $^{44}$Ti.

  15. Photometric study of southern SU UMa-type dwarf novae and candidates -- III: NSV 10934, MM Sco, AB Nor, CAL 86

    E-Print Network [OSTI]

    T. Kato; P. Nelson; C. Stockdale; B. Monard; T. Richards; R. Stubbings; H. Yamaoka; B. Heathcote; R. Santallo

    2003-10-01

    We photometrically observed four southern dwarf novae in outburst (NSV 10934, MM Sco, AB Nor and CAL 86). NSV 10934 was confirmed to be an SU UMa-type dwarf nova with a mean superhump period of 0.07478(1) d. This star also showed transient appearance of quasi-periodic oscillations (QPOs) during the final growing stage of the superhumps. Combined with the recent theoretical interpretation and with the rather unusual rapid terminal fading of normal outbursts, NSV 10934 may be a candidate intermediate polar showing SU UMa-type properties. The mean superhump periods of MM Sco and AB Nor were determined to be 0.06136(4) d and 0.08438(2) d, respectively. We suggest that AB Nor belongs to a rather rare class of long-period SU UMa-type dwarf novae with low mass-transfer rates. We also observed an outburst of the suspected SU UMa-type dwarf nova CAL 86. We identified this outburst as a normal outburst and determined the mean decline rate of 1.1 mag/d.

  16. TiNi shape memory alloy thin films for microactuator application

    E-Print Network [OSTI]

    Fu, Yongqing

    TiNi films were prepared by co-sputtering TiNi target and a separate Ti target. Crystalline structure and phase transformation behaviors of TiNi films were investigated. Results showed that TiNi films had fine grain size ...

  17. Structural and Morphological Difference Between Ti/TiN/TiCN Coatings Grown in Multilayer and Graded Form

    SciTech Connect (OSTI)

    Restrepo, E.; Baena, A.; Agudelo, C.; Castillo, H.; Devia, A.; Marino, A.

    2006-12-04

    Thin films can be grown in super-lattice, multilayers and graded form, having each one advantages and disadvantages. The difference between multilayer and graded coatings is the interface. In multilayers the interface is abrupt and in graded coatings it is diffuse. The interface influences many chemical and physical properties of the materials, and its choice depends on the application. Graded coatings have the advantage of having gradual properties such as thermal expansion coefficient and lattice parameter, avoiding adherence problems due to good match between their component materials. In this work the comparison between some properties of coatings grown as multilayer and graded is performed. The materials are produced using the sputtering DC technique because of its facility to control the deposition parameters and generate a slow growth. The target is a disc of titanium and the samples are made of stainless steel 304. The working gases are argon, nitrogen and methane, which are mixed according to the material to be produced, i.e. Ti layer is grown with argon, the TiN film is produced with a mixture of argon and nitrogen, and the TiCN material is obtained mixing argon, nitrogen and methane. These materials are characterized with AFM in order to determine grain size and with XPS studying the chemical composition and performing depth profiles.

  18. A=6H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)58AJ01)79AJ01)4AJ01)2002TI10)

  19. A Review Corrosion of TI Grade 7 and Other TI Alloys in Nuclear Waste Repository Environments

    SciTech Connect (OSTI)

    F. Hua; K. Mon; P. Pasupathi; G. Gordon

    2004-05-11

    Titanium alloy degradation modes are reviewed in relation to their performance in repository environments. General corrosion, localized corrosion, stress corrosion cracking, hydrogen induced cracking, microbially influenced corrosion, and radiation-assisted corrosion of Ti alloys are considered. With respect to the Ti Grade 7 drip shields selected for emplacement in the repository at Yucca Mountain, general corrosion, hydrogen induced cracking, and radiation-assisted corrosion will not lead to failure within the 10,000 year regulatory period; stress corrosion cracking (in the absence of disruptive events) is of no consequence to barrier performance; and localized corrosion and microbially influenced corrosion are not expected to occur. To facilitate the discussion, Ti Grades 2, 5, 7, 9, 11, 12, 16, 17, 18, and 24 are included in this review.

  20. Artificial Photosynthesis on TiO2-Passivated InP Nanopillars

    E-Print Network [OSTI]

    2015-01-01

    of TiO 2 by atomic layer deposition. The role of theseof TiO 2 by atomic layer deposition. Plane wave-densitycontaminants. 8 Atomic layer deposition (ALD) of TiO 2 was

  1. Microstructural Characterization and Shape Memory Response of Ni-Rich NiTiHf and NiTiZr High Temperature Shape Memory Alloys 

    E-Print Network [OSTI]

    Evirgen, Alper

    2014-08-14

    NiTiHf and NiTiZr high temperature shape memory alloys (HTSMAs) have drawn a great deal of attention as cheaper alternatives to Pt, Pd and Au alloyed NiTi-based HTSMAs while NiTiZr alloys also providing at least 20% weight reduction then its Ni...

  2. Thermoelastic Analysis of a Vibrating TiB/Ti Cantilever Beam Using Differential Thermography

    SciTech Connect (OSTI)

    Byrd, Larry; Wyen, Travis; Byrd, Alex

    2008-02-15

    Differential thermography has been used to detect the fluctuating temperatures due the thermoelastic effect for a number of years. This paper examines functionally graded TiB/Ti cantilever beams excited on an electromechanical shaker in fully reversed bending. Finite difference analysis of specimens was used to look at the effect of heat conduction, convection and the fundamental frequency on the surface temperature distribution and compared to experimental data. The thermoelastic effect was also used to detect cracking and the stress field at the tip of the fixture during fatigue.

  3. A New Method of Low Cost Production of Ti Alloys to Reduce Energy...

    Broader source: Energy.gov (indexed) [DOE]

    vehicle Benefits in "use phase" of Krollwrought Ti does not outweigh the energy consumption of manufacturing, but, HSPT Ti breaks even in six years compared with using...

  4. Film Coating Process Research and Characterization of TiN Coated Racetrack-type Ceramic Pipe

    E-Print Network [OSTI]

    Wang, Jie; Zhang, Bo; Wei, Wei; Fan, Le; Pei, Xiangtao; Hong, Yuanzhi; Wang, Yong

    2015-01-01

    TiN film was coated on the internal face of racetrack-type ceramic pipe by three different methods: radio-frequency sputtering, DC sputtering and DC magnetron sputtering. The deposition rates of TiN film under different coating methods were compared. According to the AFM, SEM, XPS test results,these properties were analyzed, such as TiN film roughness and surface morphology. At the same time, the deposition rates were studied under two types' cathode, Ti wires and Ti plate. According to the SEM test results, Ti plate cathode can improve the TiN/Ti film deposition rate obviously.

  5. Equation of State Model Quality Study for Ti and Ti64.

    SciTech Connect (OSTI)

    Wills, Ann Elisabet; Sanchez, Jason James

    2015-02-01

    Titanium and the titanium alloy Ti64 (6% aluminum, 4% vanadium and the balance ti- tanium) are materials used in many technologically important applications. To be able to computationally investigate and design these applications, accurate Equations of State (EOS) are needed and in many cases also additional constitutive relations. This report describes what data is available for constructing EOS for these two materials, and also describes some references giving data for stress-strain constitutive models. We also give some suggestions for projects to achieve improved EOS and constitutive models. In an appendix, we present a study of the 'cloud formation' issue observed in the ALEGRA code. This issue was one of the motivating factors for this literature search of available data for constructing improved EOS for Ti and Ti64. However, the study shows that the cloud formation issue is only marginally connected to the quality of the EOS, and, in fact, is a physical behavior of the system in question. We give some suggestions for settings in, and improvements of, the ALEGRA code to address this computational di culty.

  6. A=10B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA2 September 92004TI06) (See Energy Level

  7. A=10F (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA2 September79AJ01)8AJ01) (Not2004TI06)

  8. A=10He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA2 September79AJ01)8AJ01)4AJ01)2004TI06)

  9. A=10N (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA279AJ01) (See the2004TI06) (Not

  10. A=10Ne (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA279AJ01) (See the2004TI06)8AJ01)

  11. A=16Al (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not illustrated)59AJ76) (See the Energy6 -93TI07)

  12. A=16B (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not illustrated)59AJ76) (See the93TI07) (Not

  13. A=16Be (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not illustrated)59AJ76) (See6AJ04) (Not93TI07)

  14. A=16C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not illustrated)59AJ76) (See6AJ04)82AJ01)93TI07)

  15. A=16F (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not illustrated)59AJ76)1959AJ76)93TI07) (See

  16. A=16He (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not illustrated) This nucleus has not

  17. A=16Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not illustrated) This nucleus has

  18. A=16N (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not illustrated)

  19. A=16O (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not1959AJ76) (See the

  20. A=17B (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01) (Not93TI07) (Not1959AJ76) (See2AJ01)

  1. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See Energy Level Diagrams forLi (1995TI07)

  2. A=18Mg, etc. (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See Energy Level Diagrams forLi95TI07)

  3. A=18Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See Energy Level3AJ01) (Not95TI07) (Not

  4. A=18O (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See Energy1959AJ76) (See95TI07) (See

  5. A=19B (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See Energy1959AJ76)7AJ02) (Not95TI07) (Not

  6. A=19F (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See72AJ02) (Not illustrated)95TI07) (See

  7. A=19Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See72AJ02) (Not87AJ02)7AJ02)3AJ01)95TI07)

  8. A=19Ne (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See72AJ02)1959AJ76) (See95TI07) (See

  9. A=19O (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See72AJ02)1959AJ76)83AJ01) (See95TI07)

  10. A=20F (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06) (See Energy Level

  11. A=20He (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06) (See Energy

  12. A=20Mg (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06) (See

  13. A=20N (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06) (See72AJ02)7AJ02)

  14. A=20Ne (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06)3AJ01)

  15. A=20O (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See Energy Level Diagrams

  16. A=20n (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See Energy

  17. A=3H (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See Energy3

  18. A=3He (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See

  19. A=3Li (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See2010PU04) GENERAL:

  20. A=4n (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)

  1. A=5Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)5 - 7

  2. A=5Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)5 -66LA04) (See8AJ01)

  3. A=5n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)5 -66LA04)4AJ01)1988AJ01)

  4. A=6B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)58AJ01) (Not illustrated)

  5. A=6Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)58AJ01) (Not4AJ01)

  6. A=6C (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06)58AJ01)79AJ01)

  7. A=6n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams for 6He)79AJ01) (Not2002TI10) (Not

  8. A=7B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams for 6He)79AJ01)2002TI10) (See the

  9. A=7He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams for59AJ76) (See2002TI10) (See

  10. A=8n (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams8Be (59AJ76)4AJ01) (Not2004TI06)

  11. A=9Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams8Be79AJ01) (See Energy2004TI06) (See

  12. A=9C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams8Be79AJ01) (See74AJ01)2004TI06) (See

  13. A=9He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams8Be79AJ01)74AJ01) (See2004TI06) (See

  14. TiSol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJThin Film Solar Technologies JumpTiSol Jump to: navigation, search

  15. Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers

    E-Print Network [OSTI]

    Volinsky, Alex A.

    . In industry, electroplated Ni, Zn, and Ni/Cu/Ni coatings are generally ap- plied because of their good technology, without liquid waste pollu- tion, opposite to electroplating. It can also produce coatingsCorrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers Yuanyuan Cheng

  16. HIGH-TEMPERATURE FRACTURE AND FATIGUE RESISTANCE OF A DUCTILE b-TiNb REINFORCED g-TiAl

    E-Print Network [OSTI]

    Ritchie, Robert

    are in part aimed at improving their low room-temperature ten- sile ductility and fracture toughness, bothHIGH-TEMPERATURE FRACTURE AND FATIGUE RESISTANCE OF A DUCTILE b-TiNb REINFORCED g the fracture toughness of g-TiAl, even at high temperatures, from about 12 to H40 MPa m1/2 , although

  17. Significantly accelerated osteoblast cell growth on aligned TiO2 nanotubes

    E-Print Network [OSTI]

    Daraio, Chiara

    Significantly accelerated osteoblast cell growth on aligned TiO2 nanotubes Seunghan Oh, Chiara: Vertically aligned yet laterally spaced nanoscale TiO2 nanotubes have been grown on Ti by anodization/propagation of the osteoblast is substantially improved by the topography of the TiO2 nanotubes with the filopodia of growing

  18. Short communication TiO2 nanoparticles-decorated carbon nanotubes for significantly improved

    E-Print Network [OSTI]

    Short communication TiO2 nanoparticles-decorated carbon nanotubes for significantly improved to synthesize nanohybrids of anatase TiO2 nanoparticles-decorating carbon nanotubes (CNTs@TiO2). The nanohybrid a l a b s t r a c t TiO2 nanoparticles-decorated CNTs.

  19. Anisotropic thermal transport in highly ordered TiO2 nanotube arrays Liying Guo,1

    E-Print Network [OSTI]

    Lin, Zhiqun

    Anisotropic thermal transport in highly ordered TiO2 nanotube arrays Liying Guo,1 Jun Wang,2 Zhiqun amorphous and anatase TiO2 nanotube arrays. Strong anisotropic thermal conductivity is observed: 0.617 W K-1 for amorphous TiO2 nanotube arrays. The anatase TiO2 nanotube arrays are found to have a higher and anisotropic

  20. Development of Ti/Ti{sub 3}Sn functionally gradient material produced by eutectic bonding method

    SciTech Connect (OSTI)

    Kirihara, S.; Takeda, M.; Tsujimoto, T. [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering] [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering

    1996-07-15

    Although many materials which have a single function have been developed, future needs are anticipated to include materials which have various functions. A functionally gradient material (FGM) which has characteristics of two different materials is a promising candidate for multi-functional material. The present methods for production of FGM, however, are very complicated and costly. In this study the authors answer the serious problem of high production cost by fabricating the FGM by a eutectic bonding method. This fabrication method includes structural control of FGM by changing the cooling process. They describe Ti/Ti{sub 3}Sn FGM obtained by the eutectic bonding method, and tell how the structure of its composition gradient part is changed by controlling the cooling process.

  1. Measurement of neutron capture on 50Ti at thermonuclear energies

    E-Print Network [OSTI]

    P. V. Sedyshev; P. Mohr; H. Beer; H. Oberhummer; Yu. P. Popov; W. Rochow

    1999-07-28

    At the Karlsruhe and Tuebingen 3.75 MV Van de Graaff accelerators the thermonuclear 50Ti(n,gamma)51Ti(5.8 min) cross section was measured by the fast cyclic activation technique via the 320.852 and 928.65 keV gamma-ray lines of the 51Ti-decay. Metallic Ti samples of natural isotopic composition and samples of TiO2 enriched in 50Ti by 67.53 % were irradiated between two gold foils which served as capture standards. The capture cross-section was measured at the neutron energies 25, 30, 52, and 145 keV, respectively. The direct capture cross section was determined to be 0.387 +/- 0.011 mbarn at 30 keV. We found evidence for a bound state s-wave resonance with an estimated radiative width of 0.34 eV which destructively interfers with direct capture. The strength of a suggested s-wave resonance at 146.8 keV was determined. The present data served to calculate, in addition to the directly measured Maxwellian averaged capture cross sections at 25 and 52 keV, an improved stellar 50Ti(n,gamma)51Ti rate in the thermonuclear energy region from 1 to 250 keV. The new stellar rate leads at low temperatures to much higher values than the previously recommended rate, e.g., at kT=8 keV the increase amounts to about 50 %. The new reaction rate therefore reduces the abundance of 50Ti due to s-processing in AGB stars.

  2. Comparison of Mixed Layer Heights from Airborne High Spectral Resolution Lidar, Ground-based Measurements, and the WRP-Chem Model during CalNex and CARES

    SciTech Connect (OSTI)

    Scarino, Amy Jo; Obland, Michael; Fast, Jerome D.; Burton, S. P.; Ferrare, R. A.; Hostetler, Chris A.; Berg, Larry K.; Lefer, Barry; Haman, C.; Hair, John; Rogers, Ray; Butler, Carolyn; Cook, A. L.; Harper, David

    2014-06-05

    The California Research at the Nexus of Air Quality and Climate Change (CalNex) and Carbonaceous Aerosol and Radiative Effects Study (CARES) field campaigns during May and June 2010 provided a data set appropriate for studying characteristics of the planetary boundary layer (PBL). The NASA Langley Research Center (LaRC) airborne High Spectral Resolution Lidar (HSRL) was deployed to California onboard the NASA LaRC B-200 aircraft to aid incharacterizing aerosol properties during these two field campaigns. Measurements of aerosol extinction (532 nm), backscatter (532 and 1064 nm), and depolarization (532 and 1064 nm) profiles during 31 flights, many in coordination with other research aircraft and ground sites, constitute a diverse data set for use in characterizing the spatial and temporal distribution of aerosols, as well as the depth and variability of the daytime mixed layer (ML), which is a subset within the PBL. This work illustrates the temporal and spatial variability of the ML in the vicinity of Los Angeles and Sacramento, CA. ML heights derived from HSRL measurements are compared to PBL heights derived from radiosonde profiles, ML heights measured from ceilometers, and simulated PBL heights from the Weather Research and Forecasting Chemistry (WRF-Chem) community model. Comparisons between the HSRL ML heights and the radiosonde profiles in Sacramento result in a correlation coefficient value (R) of 0.93 (root7 mean-square (RMS) difference of 157 m and bias difference (HSRL radiosonde) of 5 m). HSRL ML heights compare well with those from the ceilometer in the LA Basin with an R of 0.89 (RMS difference of 108 m and bias difference (HSRL Ceilometer) of -9.7 m) for distances of up to 30 km between the B-200 flight track and the ceilometer site. Simulated PBL heights from WRF-Chem were compared with those obtained from all flights for each campaign, producing an R of 0.58 (RMS difference of 604 m and a bias difference (WRF-Chem HSRL) of -157 m) for CalNex and 0.59 (RMS difference of 689 m and a bias difference (WRF-Chem HSRL) of 220 m) for CARES. Aerosol backscatter simulations are also available from WRF15 Chem and are compared to those from HSRL to examine differences among the methods used to derive ML heights.

  3. The combustion synthesis of Ni-Ti shape memory alloys

    SciTech Connect (OSTI)

    Moore, J.J.; Yi, H.C. (Colorado School of Mines, Golden (USA))

    1990-08-01

    Combustion synthesis of Ni-Ti-series shape-memory alloys yields both time and energy savings over conventional production methods. The solidified combustion synthesis process products have been cold-rolled into plates which exhibit the shape-memory effect, and it was noted that shape-memory transition temperatures may be tailored over a -78 to 460 C temperature range through the substitution of a third element for Ni; this element may be Pd or Fe. Accounts are given of the experimental combustion syntheses of Ni-Ti-Fe and Ti-Ni-Pd. 24 refs.

  4. Superconductivity in amorphous Ti(1-x)V(x) thin films 

    E-Print Network [OSTI]

    Watson, Paul Willard

    1986-01-01

    V si Ti isV ss Ti zsV ri Ti 4s V. si Ti. sz V. ss Ti rpV sp 200 330 3. 125 208. 9 53. 4. 885 178. 4 58. 210 3. 050 197. 9 36. 190 2. 732 198. 1 40. 180 2. 577 182. 4 101. 600 3. 145 193. 1 57. 440 3. 220 195. 0 56. 410 3. 595 208. 5 78...

  5. TI--CR--AL--O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

    2000-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  6. TiNi-based thin films for MEMS applications

    E-Print Network [OSTI]

    Fu, Yongqing

    In this paper, some critical issues and problems in the development of TiNi thin films were discussed, including preparation and characterization considerations, residual stress and adhesion, frequency improvement, fatigue ...

  7. Low thermal expansion behavior and thermal durability of ZrTiO4Al2TiO5Fe2O3 ceramics between 750 and 1400

    E-Print Network [OSTI]

    Cao, Guozhong

    bottoms, and turbochargers.1 However, Al2TiO5 materials have a relatively low mechanical strength because

  8. Shape memory behavior of ultrafine grained NiTi and TiNiPd shape memory alloys 

    E-Print Network [OSTI]

    Kockar, Benat

    2009-05-15

    The cyclic instability in shape memory characteristics of NiTi-based shape memory alloys (SMAs), such as transformation temperatures, transformation and irrecoverable strains and transformation hysteresis upon thermal and ...

  9. Photocatalytic reduction of methylene blue by TiO2 nanotube arrays: effects of TiO2 crystalline phase

    E-Print Network [OSTI]

    Kang, Xiongwu; Chen, Shaowei

    2010-01-01

    arrays: effects of TiO 2 crystalline phase Xiongwu Kang •formation of well- de?ned anatase crystalline phase. Moreat 470 °C, the brookite crystalline phase also started to

  10. A comparative study of precipitation effects in Ti only and Ti-V Ultra Low Carbon (ULC) strip steels

    SciTech Connect (OSTI)

    Ooi, S.W.; Fourlaris, G. . E-mail: g.fourlaris@swansea.ac.uk

    2006-04-15

    Two ULC steel grades were investigated, one based on combined vanadium and titanium additions and the other based on titanium only additions. It has been established that TiC formation during interphase precipitation retards grain growth of the {l_brace}111{r_brace} texture grains during continuous annealing and hence positively affects the r value of the Ti only steel. The formation of newly formed TiC precipitates on dislocations during continuous annealing has been found to result in an increase of the yield strength in both steel grades, as the annealing temperature is increased. It is also confirmed that VC particles formed during the coiling process dissolve during the continuous annealing cycles. Suitable continuous annealing cycles can be adopted to produce high formable steels with a bake hardening potential using the beneficial effects of combined Ti-V additions.

  11. A GIS-based Soil Erosion Risk Map for New Mexico Bulut, G.G.1; Cal, M.P.2; Richardson, C.P.3; Gallegos, J.B.4

    E-Print Network [OSTI]

    Cal, Mark P.

    A GIS-based Soil Erosion Risk Map for New Mexico Bulut, G.G.1; Cal, M.P.2; Richardson, C.P.3; Gallegos, J.B.4 Abstract A soil erosion risk map was developed for the State of New Mexico using the Universal Soil Loss Equation (USLE), a fuzzy logic model (FuzzyCell) and ArcGIS Desktop 9.3 software. Soil

  12. The Influence of Ni-Coated TiC on Laser-Deposited IN625 Metal Matrix Composites

    E-Print Network [OSTI]

    2010-01-01

    The In?uence of Ni-Coated TiC on Laser-Deposited IN625 Metalwith Ni-coated and uncoated TiC reinforcement particles toand spatial distribution of TiC particles in the deposited

  13. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    SciTech Connect (OSTI)

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, Allen B.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-01-03

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for assessing aerosol effects on cold season precipitation in California.

  14. Engineering the Martensitic Transformation Hysteresis of Ni-Rich NiTi Alloys 

    E-Print Network [OSTI]

    Franco, Brian Eelan

    2014-12-18

    The shape memory behavior in NiTi alloys can be exploited for a wide variety of applications that require active materials. The application dictates the transformation temperatures and hysteresis of the alloy. NiTi alloys ...

  15. Synthesis, electrochemistry and First Principles Calculation studies of layered Li-Ni-Ti-O compounds

    E-Print Network [OSTI]

    Kang, Kisuk

    New layered cathode materials, Li?.?Ni?.??Ti?.??O?, were synthesized by means of ion-exchange from Na?.?Ni?.??Ti?.??O?. The degree of cation disordering in the material depends critically on the synthesis conditions. Longer ...

  16. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation...

    Office of Scientific and Technical Information (OSTI)

    reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film supported on Cu(111), CuTiOxCu(111), during CO oxidation was explored using density...

  17. EVALUATION OF VARIOUS FABRICATION TECHNIQUES FOR FABRICATION OF FINE FILAMENT NbTi SUPERCONDUCTORS

    E-Print Network [OSTI]

    Scanlan, R.M.

    2010-01-01

    i c Formation in Fine Filament Nb-Ti Superconductors," lEEK~ of closely spaced fine filaments. Refe ~ences "HanufactureFOR FABRICATION OF FINE FILAMENT NbTi SUPERCONDUCTORS R.M.

  18. Ti(III) Doped Titanium Dioxide: an Effective Strategy to Improve the Visible Light Photocatalytic Activity

    E-Print Network [OSTI]

    Zuo, Fan

    2012-01-01

    1 An Overview of Photocatalysis and TiO 2 Photocatalyst 1.11 An Overview of Photocatalysis and TiO 2 Photocatalystthe heterogeneous photocatalysis for solar energy conversion

  19. BaTiO? based materials for piezoelectric and electro-optic applications

    E-Print Network [OSTI]

    Avrahami, Ytshak, 1969-

    2003-01-01

    Ferroelectric materials are key to many modem technologies, in particular piezoelectric actuators and electro-optic modulators. BaTiO? is one of the most extensively studied ferroelectric materials. The use of BaTiO? for ...

  20. Photoconductivities in anatase TiO{sub 2} nanorods

    SciTech Connect (OSTI)

    Chen, Ruei-San, E-mail: rsc@mail.ntust.edu.tw [Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China); Liu, Yi-Ling; Chan, Ching-Hsiang; Huang, Ying-Sheng [Department of Electronic Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China)

    2014-10-13

    The photoconduction (PC) properties of single-crystalline titanium dioxide (TiO{sub 2}) nanorods (NRs) with anatase phase were investigated and compared. By examining the material's inherent properties, the anatase TiO{sub 2} NRs exhibit superior PC efficiency (quantitatively defined by normalized gain) which is near one order of magnitude higher than that of the rutile ones. The optimal photoconductive gain of the anatase NR device can also reach 1.6?×?10{sup 7} at the light intensity of 0.02?Wm{sup ?2} and a low bias of 0.1?V. The power-dependent and time-resolved PC measurements were performed to investigate the physical mechanisms. The higher quantum efficiency and mobility product was confirmed to be responsible for the higher PC efficiency in the anatase TiO{sub 2} NRs in comparison to the rutile ones.

  1. Compton Profile Study of Intermetallic Ti{sub 3}Al

    SciTech Connect (OSTI)

    Vyas, V.; Sharma, G. [Department of Physics, Banasthali University, Banasthali-304022 (India); Mishra, M. C.; Sharma, B. K. [Department of Physics, University of Rajasthan, Jaipur-302004 (India); Joshi, K. B. [Department of Physics, University College of Science, M.L.Sukhadia University, Udaipur-313 002 (India)

    2011-10-20

    The Compton scattering measurement on intermetallic alloy Ti{sub 3}Al is reported in this work. The measurement is made using 59.54 keV gamma-rays from Am{sup 241} source. Theoretical calculation of Compton profile is also performed employing CRYSTAL code within the framework of density functional theory to compare with the measurement. The theoretical profile of the alloy is also synthesized following the superposition model taking the published Compton profiles of elemental solids from the APW method. The experimental study of charge transfer in the alloys has also been done by performing the experimental Compton profile measurements on Ti and Al following the superposition model and charge transfer from Al to Ti is clearly seen on the alloy formation.

  2. Hydrogen adsorption on Pd/TiFe (110) surface S.E. Kulkovaa

    E-Print Network [OSTI]

    Kim, Jai Sam

    Hydrogen adsorption on Pd/TiFe (110) surface S.E. Kulkovaa , S.V. Eremeeva,b,*, V.E. Egorushkinc February 2003 by E.L. Ivchenko Abstract Adsorption of hydrogen on the TiFe (110) surface covered. Electronic band structure 1. Introduction The TiFe alloy is an excellent material for hydrogen storage [1

  3. Synthesis and characterization of perovskite PbTiO3 nanoparticles with solution processability

    E-Print Network [OSTI]

    Lin, Zhiqun

    Synthesis and characterization of perovskite PbTiO3 nanoparticles with solution processability Jun with perovskite structure (ABO3), for example, lead titanate (PbTiO3), are the most studied ferroelectric oxides polarization direction. Ferroelectrics with perovskite structure (ABO3), such as barium titanate (BaTiO3

  4. Investigation into Photoconductivity in Single CNF/TiO2-Dye Core–Shell Nanowire Devices

    E-Print Network [OSTI]

    Li, Zhuangzhi; Rochford, Caitlin; Baca, Francisco Javier A.

    2010-06-15

    A vertically aligned carbon nanofiber array coated with anatase TiO2 (CNF/TiO2) is an attractive possible replacement for the sintered TiO2 nanoparticle network in the original dye-sensitized solar cell (DSSC) design due to the potential...

  5. Exciton-like trap states limit electron mobility in TiO2 nanotubes

    E-Print Network [OSTI]

    Exciton-like trap states limit electron mobility in TiO2 nanotubes Christiaan Richter and Charles A , that low mobility in polycrystalline TiO2 nanotubes is not due to scattering from grain boundaries (electrons) be transported through an anodic TiO2 electrode, either along the length of nanotubes in the case

  6. Freestanding TiO2 Nanotube Arrays with Ultrahigh Aspect Ratio via Electrochemical Anodization

    E-Print Network [OSTI]

    Lin, Zhiqun

    Articles Freestanding TiO2 Nanotube Arrays with Ultrahigh Aspect Ratio via Electrochemical,5 photocatalytic,6 and solar cells.7­10 In the latter context, each individual TiO2 nanotube is perpendicular acid (HF) aqueous solution was used as electrolyte, the maximum thickness of TiO2 nanotube arrays

  7. Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications

    E-Print Network [OSTI]

    Cao, Guozhong

    Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications-grown and the O2-annealed TNT array electrodes. The improved biosensor properties of the TiO2 nanotube arrays were, particularly TiO2 nanotubes (TNT), which possess large surface areas, have been widely used as chemical sensors

  8. Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials Abdullah Al storage processes. Here we analyze the role of atomic Ti catalysts in the hydrogenation of Al-based hydrogen storage materials. We show that Ti atoms near the Al surface activate gas-phase H2, a key step

  9. Coating power RF components with TiN

    SciTech Connect (OSTI)

    Kuchnir, M.; Hahn, E.

    1995-03-01

    A facility for coating RF power components with thin films of Ti and/or TiN has been in operation for some time at Fermilab supporting the Accelerator Division RF development work and the TESLA program. It has been experimentally verified that such coatings improve the performance of these components as far as withstanding higher electric fields. This is attributed to a reduction in the secondary electron emission coefficient of the surfaces when coated with a thin film containing titanium. The purpose of this Technical Memorandum is to describe the facility and the procedure used.

  10. Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures

    SciTech Connect (OSTI)

    Ngai, J. H.; Kumah, D. P.; Walker, F. J.; Ahn, C. H.

    2014-02-10

    We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

  11. Structural relaxation and nanoindentation response in Zr-Cu-Ti amorphous thin films

    SciTech Connect (OSTI)

    Chou, H. S.; Huang, J. C.; Chang, L. W. [Department of Materials and Optoelectronic Science, Center for Nanoscience and Nanotechnology, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Nieh, T. G. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States)

    2008-11-10

    Ternary Zr-Cu-Ti system, especial with a high Ti content, is normally difficult to be fully vitrified. In this paper, we demonstrate that cosputtering can produce amorphous Zr-Cu-Ti thin films with an excessive Ti content even as high as 19%. Sub-T{sub g} annealing of the film induces the formation of medium-range-ordered clusters and to raise the nanohardness by 35% to 6.6 GPa. The promising mechanical properties of the sub-T{sub g} annealed Zr{sub 52}Cu{sub 29}Ti{sub 19} films offer great potential for microelectromechanical system applications.

  12. The corrosion behavior and hemocompatibility of TiNi alloys coated with DLC by plasma based ion implantation

    E-Print Network [OSTI]

    Zheng, Yufeng

    The corrosion behavior and hemocompatibility of TiNi alloys coated with DLC by plasma based ion successfully deposited on Ti­50.8 at.% Ni alloys using plasma based ion implantation (PBII) technique on the surface modification of TiNi alloys, including ion implan- tation, multi arc ion-plating as well as Ti

  13. Seebeck coefficient of a quantum confined, high-electron-density electron gas in SrTiO3

    E-Print Network [OSTI]

    Cain, Tyler; Lee, SungBin; Moetakef, Pouya; Balents, Leon; Stemmer, Susanne; Allen, S. James

    2012-01-01

    of SrTiO 3 layer thick- ness d. All GdTiO 3 layers were 8 nmof SrTiO 3 layer thick- ness. All GdTiO 3 layers were 4 nmappreciable dependence on thick- ness. We approximate Eq. (

  14. Evolution of Hollow TiO2 Nanostructures via the Kirkendall Effect Driven by Cation Exchange with Enhanced Photoelectrochemical

    E-Print Network [OSTI]

    Wang, Xudong

    . The evolution of TiO2 nanotubes from ZnO NW scaffolds was seamlessly integrated with TiO2 NR branch growthEvolution of Hollow TiO2 Nanostructures via the Kirkendall Effect Driven by Cation Exchange. In this paper, we report a discovery of hollow TiO2 nanostructure evolution in a vapor-solid deposition system

  15. Development and properties of TiIn binary alloys as dental biomaterials Q.Y. Wang a

    E-Print Network [OSTI]

    Zheng, Yufeng

    Development and properties of Ti­In binary alloys as dental biomaterials Q.Y. Wang a , Y.B. Wang b 2012 Available online 23 December 2012 Keywords: Dental alloy Ti­In alloys Electrochemical behavior Ti (CP­Ti) is the strongest unalloyed titanium and employed as dental prostheses material, possessing

  16. A 40 mm BORE Nb-Ti MODEL DIPOLE MAGNET

    E-Print Network [OSTI]

    Taylor, C.

    2010-01-01

    September 9-13, 1984 A 40 mm BORE Nb-Ti MODEL DIPOLE MAGNETNo. DE- AC03- 76SF0009B. A 40 mm BORE Nb- Tl MOOEL OIPOLEMPa) Midplane Shim (mm) ColI Length (mm) Number of Strands

  17. Universidad Simn Bolvar Depto. de Computacin y T.I.

    E-Print Network [OSTI]

    Meza, Oscar J.

    Universidad Simón Bolívar Depto. de Computación y T.I. CI2693 Laboratorio de Algoritmos y) y en amplitud (BFS) usando el Modelo General de Etiquetamiento. Estos algoritmos se deben la clase abstracta Algoritmo, de la cual descenderán todos los algoritmos a ser usados en adelante

  18. C t ti N R t Construction News Report

    E-Print Network [OSTI]

    Cunz Hall C t ti N R t Renovation Construction News Report June 2010 Bid Package 301 Site Work! LEED credits will be obtained by creating a more energy efficient building. According to the U.S. Department of Energy, buildings use 39% of the energy and 74% of the electricity produced each year

  19. Synthesis of hectorite-TiO2 and kaolinite-TiO2 nanocomposites with photocatalytic activity for the degradation of model air pollutants

    SciTech Connect (OSTI)

    Destaillats, Hugo; Kibanova, D.; Trejo, M.; Destaillats, H.; Cervini-Silva, J.

    2008-03-01

    We studied the synthesis and photocatalytic activity of small-sized TiO{sub 2} supported on hectorite and kaolinite. Deposition of TiO{sub 2} on the clay mineral surface was conducted by using a sol-gel method with titanium isopropoxide as precursor. Anatase TiO{sub 2} particles formation was achieved by hydrothermal treatment at 180 C. Material characterization was conducted using XRD, SEM, XPS, ICP-OES, BET and porosimetry analysis. Efficiency in synthesizing clay-TiO{sub 2} composites depended strongly on the clay mineral structure. Incorporation of anatase in hectorite, an expandable clay mineral, was found to be very significant (> 36 wt.% Ti) and to be followed by important structural changes at the clay mineral surface. Instead, no major structural modifications of the clay were observed for kaolinite-TiO{sub 2}, as compared with the untreated material. Photocatalytic performance of clay-TiO{sub 2} composites was evaluated with ATR-FTIR following the oxidation of adsorbed toluene and d-limonene, two model air pollutants. In either case, the photocatalytic removal efficiency of these hydrophobic substrates by the synthesized clay-TiO{sub 2} composites was comparable to that observed using pure commercial TiO{sub 2} (Degussa P25).

  20. Aging of {alpha}{prime}{sub a} martensite in U-0.77Ti

    SciTech Connect (OSTI)

    Speer, J.G. [Colorado School of Mines, Golden, CO (United States). Dept. of Metallurgical and Materials Engineering] [Colorado School of Mines, Golden, CO (United States). Dept. of Metallurgical and Materials Engineering; Edmonds, D.V. [Univ. of Leeds (United Kingdom). Dept. of Materials] [Univ. of Leeds (United Kingdom). Dept. of Materials

    1999-05-28

    A detailed examination of the aging response in a quenched U-077 wt% Ti alloy using transmission electron microscopy is presented. The acicular martensite in this alloy is supersaturated with Ti after quenching, and decomposes via coherent precipitation of U{sub 2}Ti which grows as rods parallel to [100]{sub {alpha}}, followed by coarsening via a cellular discontinuous mechanism. The {alpha}/U{sub 2}Ti orientation relationship for both the continuous and discontinuous precipitates may be described as: (001){sub U{sub 2}Ti}{parallel}(100){sub {alpha}}, (01{bar 1}0){sub U{sub 2}Ti}{parallel}(010){sub {alpha}}, (2{ovr 11}0){sub U{sub 2}Ti}{parallel}(001){sub {alpha}}.

  1. Multiple dielectric transitions in the PbTiO3-Bi(Zn1/2Ti1/2)O3-Bi(Mg1/2Ti1/2)O3 David M. Stein,1

    E-Print Network [OSTI]

    Rappe, Andrew M.

    . The next step toward using these tetragonality enhancing additives in piezoelectric applications boundary (MPB) to improve piezoelectric performance. Results from the (1Àx)[0.75 PbTiO3-0.25Bi(Zn1/2Ti1/2)O investigated as a replace- ment for lead in piezoelectric perovskite systems. The Bi3þ cation possesses the 6

  2. Adhesion evaluation of TiN and (Ti, Al)N coatings on titanium 6Al-4V

    SciTech Connect (OSTI)

    James, R.D.; Gruss, K.A.; Horie, Y.; Davis, R.F.; Paisley, D.L.; Parthasarthi, S.; Tittmann, B.R.

    1996-12-31

    The metallic components of gas turbine engines are continually subjected to hostile atmospheres. Nitride coatings improve the performance of the metallic compressor blades in these engines. To assess the adhesion of nitride coatings on metals, titanium 6% aluminum 4% vanadium substrates were coated with titanium nitride (TiN) using both cathodic arc and electron beam evaporation. Titanium aluminum nitride ((Ti, Al)N) was also deposited using cathodic arc evaporation. The interfaces of the coated samples were loaded in tension using a high speed shock wave which caused spallation either at the interface, in the coating or in the metal. Scanning acoustic microscopy analysis of the spalled samples detected delaminations at the interface in the samples deposited by cathodic arc evaporation. DYNA2D modeling of plate impact spallation experiments revealed the tensile adhesion strength for TiN deposited by both techniques was {approx} 2.0 GPa. The tensile adhesion strength for (Ti, Al)N was less than 1.5 GPa.

  3. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries

    SciTech Connect (OSTI)

    Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

    2014-08-19

    Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12–TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12–TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

  4. Production of {sup 44}Ti in neutrino-driven aspherical supernova explosions

    SciTech Connect (OSTI)

    Fujimoto, Shin-ichiro [Kumamoto National College of Technology, 2659-2 Suya, Goshi 861-1102 (Japan); Ono, Masaomi; Hashimoto, Masa-aki [Department of Physics, School of Sciences, Kyushu University, Fukuoka 810-8560 (Japan); Kotake, Kei [National Astronomical Observatory Japan, 2-21-1, Osawa, Mitaka, Tokyo, 181-8588 (Japan)

    2014-05-02

    We examine the synthesis of {sup 44}Ti in a neutrino-driven aspherical supernova (SN), focusing on reaction rates related to {sup 44}Ti and rotation of a progenitor. We have performed 2D hydrodynamic simulations of SN of a 15M{sub ?} progenitor, whose angular velocity is manually set to be a cylindrical distribution and have followed explosive nucleosynthesis in the ejecta. We find that the faster rates of {sup 40}Ca(?,?){sup 44}Ti and the slower rate of {sup 44}Ti(?,p){sup 47}V lead to more massive ejection of {sup 44}Ti and {sup 56}Ni and larger ratios <{sup 44}Ti/{sup 56}Ni>. Faster rotation also results in more massive ejection of {sup 44}Ti and {sup 56}Ni. Ratios <{sup 44}Ti/{sup 56}Ni> are however independent from rotation. Large masses of {sup 44}Ti and large ratios <Ti/{sup 56}Ni> observed in SN 1987A and Cas A (> 1O{sup ?4}M{sub ?} and 1-2 respectively) are not realized in all the models.

  5. Structural and chemical characterization of BaTiO{sub 3} nanorods

    SciTech Connect (OSTI)

    Zagar, K.; Recnik, A.; Sturm, S.; Gajovic, A.; Ceh, M.

    2011-03-15

    Research highlights: {yields} Polycrystalline BaTiO{sub 3} nanorods were synthesized with EPD into AAO templates. {yields} Nanorods are composed of crystalline, nanosized grains with pseudo-cubic structure. {yields} Integrowth of hexagonal BaTiO{sub 3} polymorph within pseudo-cubic structure was observed. -- Abstract: An electron-microscopy investigation was performed on BaTiO{sub 3} nanorods that were processed by sol-gel electrophoretic deposition (EPD) into anodic aluminium oxide (AAO) membranes. The BaTiO{sub 3} nanorods grown within the template membranes had diameters ranging from 150 to 200 nm, with an average length of 10-50 {mu}m. By using various electron-microscopy techniques we showed that the processed BaTiO{sub 3} nanorods were homogeneous in their chemical composition. The BaTiO{sub 3} nanorods were always polycrystalline and were composed of well-crystallized, defect-free, pseudo-cubic BaTiO{sub 3} grains, ranging from 10 to 30 nm. No intergranular phases were observed between the BaTiO{sub 3} grains. A low-temperature hexagonal polymorph that is coherently intergrown with the BaTiO{sub 3} perovskite matrix was also observed as a minor phase. When annealing the AAO templates containing the BaTiO{sub 3} sol in an oxygen atmosphere the presence of the hexagonal polymorph was diminished.

  6. Ti{sub 5}O{sub 5} superstructures of cubic titanium monoxide

    SciTech Connect (OSTI)

    Gusev, A. I.

    2013-08-15

    A cubic model is proposed for the Ti{sub 5}O{sub 5} (Ti{sub 5} Black-Small-Square O{sub 5}{open_square} {identical_to} Ti{sub 90} Black-Small-Square {sub 18}O{sub 90}{open_square}{sub 18}) superstructure of nonstoichiometric titanium monoxide Ti{sub x}O{sub z} with double imperfection. The unit cell of the cubic Ti{sub 5}O{sub 5} superstructure has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of Ti{sub x}O{sub z} monoxide and belongs to space group Pm 3-bar m . The channel of the disorder-order transition, i.e., Ti{sub x}O{sub z} (space group Fm 3-bar m)-Ti{sub 5}O{sub 5} (space group Pm 3-bar m), includes 75 superstructure vectors of seven stars (k{sub 10}), (k{sub 7}), (k{sub 6(1)}), (k{sub 6(2)}), (k{sub 4(1)}), (k{sub 4(2)}), and (k{sub 1}). The distribution functions of Ti and O atoms over the sites of the cubic Ti{sub 5}O{sub 5} superstructure are calculated. A comparison of the X-ray and electron diffraction data obtained for ordered TiO{sub 1.087} monoxide with the theoretical simulation results supports the existence of the cubic Ti{sub 5}O{sub 5} superstructure. The cubic (space group Pm 3-bar m) Ti{sub 5}O{sub 5} superstructure is shown to be a high-temperature structure relative to the well-known monoclinic (space group C2/m) superstructure of the same type.

  7. Irradiation study of Ti6Al4V and Ti6Al4V1B for FRIB beam dump: Aida Amroussia, PhD Student

    E-Print Network [OSTI]

    McDonald, Kirk

    Irradiation study of Ti6Al4V and Ti6Al4V1B for FRIB beam dump: Aida Amroussia, PhD Student Chemical Engineering and Materials Science Michigan State University May 19, 2014 1 #12;Outline · Irradiation-EBSD · Nano-indentation tests · Vickers Hardness tests · Insitu-tensile tests 2 #12;Irradiation experiments

  8. Irradiation study of Ti6Al4V and Ti6Al4V1B for FRIB beam dump: Preliminary results

    E-Print Network [OSTI]

    McDonald, Kirk

    Irradiation study of Ti6Al4V and Ti6Al4V1B for FRIB beam dump: Preliminary results Aida Amroussia;Outline · Irradiation of samples with high energy heavy ions (NSCL- MSU)(Ca 40 @ 50 MeV/u) and low energy the same areas on the samples before and after irradiation. 2 #12;Observations · Deterioration

  9. The Effect of Ramp Rate on the C49 to C54 Titanium Disilicide Phase Transformation from Ti and Ti(Ta)

    SciTech Connect (OSTI)

    BAILEY, GLENN A.; HU, YAO ZHI; SMITH, PAUL M.; TAY, SING PIN

    1999-09-22

    The C49 to C54 TiSi{sub 2} transformation temperature is shown to be reduced by increasing the ramp rate during rapid thermal processing and this effect is more pronounced for thinner initial Ti and Ti(Ta) films. Experiments were performed on blanket wafers and on wafers that had patterned polycrystalline Si lines with Si{sub 3}N{sub 4} sidewall spacers. Changing the ramp rate caused no change in the transformation temperature for 60 nm blanket Ti films. For blanket Ti films of 25 or 40 nm, however, increasing the ramp rate from 7 to 180 C/s decreased the transformation temperature by 15 C. Studies of patterned lines indicate that sheet resistance of narrow lines is reduced by increased ramp rates for both Ti and Ti(Ta) films, especially as the linewidths decrease below 0.4 {micro}m. This improvement is particularly pronounced for the thinnest Ti(Ta) films, which exhibited almost no linewidth effect after being annealed with a ramp rate of 75 C/s.

  10. Deformation behavior and dislocation mechanisms in TiAl alloys

    SciTech Connect (OSTI)

    Sriram, S.; Vasudevan, V.K. [Univ. of Cincinnati, OH (United States). Dept. of Materials Science and Engineering; Dimiduk, D.M. [Wright Lab., Wright-Patterson AFB, OH (United States)

    1995-08-01

    Polycrystalline Ti-50 and Ti-52Al (in at.%) alloys, with large grain sizes (50Al-300{mu}m, 52Al-500{mu}m) and containing low ({approximately}250 wt.ppm) levels of oxygen were deformed under compression over a wide temperature range (77--1,173 K). The 0.2% proof stress-temperature profiles comprise of three distinct regimes: Regime 1 (between 77--{approximately}600 K), regime 2 (between {approximately}600--1,073 K), and regime 3 (above 1,073 K). Deformation temperature influences the types of dislocations present, the nature of superdislocation dissociations, and the morphological characteristics of both ordinary and super dislocations. Collectively, experiment and theory suggest that the flow properties at low temperatures (regime 1) are controlled by lattice friction, whereas at higher temperatures (regime 2) the properties are dislocation obstacle controlled.

  11. Thermodynamic and mechanical properties of TiC from ab initio calculation

    SciTech Connect (OSTI)

    Dang, D. Y.; Fan, J. L.; Gong, H. R., E-mail: gonghr@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

    2014-07-21

    The temperature-dependent thermodynamic and mechanical properties of TiC are systematically investigated by means of a combination of density-functional theory, quasi-harmonic approximation, and thermal electronic excitation. It is found that the quasi-harmonic Debye model should be pertinent to reflect thermodynamic properties of TiC, and the elastic properties of TiC decease almost linearly with the increase of temperature. Calculations also reveal that TiC possesses a pronounced directional pseudogap across the Fermi level, mainly due to the strong hybridization of Ti 3d and C 2p states. Moreover, the strong covalent bonding of TiC would be enhanced (reduced) with the decrease (increase) of temperature, while the change of volume (temperature) should have negligible effect on density of states at the Fermi level. The calculated results agree well with experimental observations in the literature.

  12. LaTiO?/KTaO? interfaces: A new two-dimensional electron gas system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Nanjing University, Nanjing; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO?, and a band insulator, KTaO?. For LaTiO?/KTaO? interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO?-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO? at room temperature. By using KTaO?, we achieve mobilities in LaTiO?/KTaO? interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO?. By density functional theory, we attribute the higher mobilitymore »in KTaO? 2DEGs to the smaller effective mass for electrons in KTaO?.« less

  13. Photoemission study of the electronic structure and charge density waves of Na?Ti?Sb?O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, S. Y. [Science and Technology on Surface Physics and Chemistry Lab., Mianyang (China); Fundan Univ., Shanghai (China); Jiang, J. [Fundan Univ., Shanghai (China); Nanjing Univ., Nanjing (China); Ye, Z. R. [Fundan Univ., Shanghai (China); Niu, X. H. [Fundan Univ., Shanghai (China); Nanjing Univ., Nanjing (China); Song, Y. [Rice Univ., Houston, TX (United States); Zhang, C. L. [Rice Univ., Houston, TX (United States); Univ. of Tennessee, Knoxville, TN (United States); Dai, P. C. [Rice Univ., Houston, TX (United States); Xie, B. P. [Fundan Univ., Shanghai (China); Nanjing Univ., Nanjing (China); Lai, X. C. [Science and Technology on Surface Physics and Chemistry Lab., Mianyang (China); Feng, D. L. [Fundan Univ., Shanghai (China); Nanjing Univ., Nanjing (China)

    2015-04-30

    The electronic structure of Na?Ti?Sb?O single crystal is studied by photon energy and polarization dependent angle-resolved photoemission spectroscopy (ARPES). The obtained band structure and Fermi surface agree well with the band structure calculation of Na?Ti?Sb?O in the non-magnetic state, which indicates that there is no magnetic order in Na?Ti?Sb?O and the electronic correlation is weak. Polarization dependent ARPES results suggest the multi-band and multi-orbital nature of Na?Ti?Sb?O. Photon energy dependent ARPES results suggest that the electronic structure of Na?Ti?Sb?O is rather two-dimensional. Moreover, we find a density wave energy gap forms below the transition temperature and reaches 65 meV at 7 K, indicating that Na?Ti?Sb?O is likely a weakly correlated CDW material in the strong electron-phonon interaction regime. (author)

  14. Photoemission study of the electronic structure and charge density waves of Na?Ti?Sb?O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, S. Y.; Jiang, J.; Ye, Z. R.; Niu, X. H.; Song, Y.; Zhang, C. L.; Dai, P. C.; Xie, B. P.; Lai, X. C.; Feng, D. L.

    2015-04-30

    The electronic structure of Na?Ti?Sb?O single crystal is studied by photon energy and polarization dependent angle-resolved photoemission spectroscopy (ARPES). The obtained band structure and Fermi surface agree well with the band structure calculation of Na?Ti?Sb?O in the non-magnetic state, which indicates that there is no magnetic order in Na?Ti?Sb?O and the electronic correlation is weak. Polarization dependent ARPES results suggest the multi-band and multi-orbital nature of Na?Ti?Sb?O. Photon energy dependent ARPES results suggest that the electronic structure of Na?Ti?Sb?O is rather two-dimensional. Moreover, we find a density wave energy gap forms below the transition temperature and reaches 65 meV atmore »7 K, indicating that Na?Ti?Sb?O is likely a weakly correlated CDW material in the strong electron-phonon interaction regime. (author)« less

  15. Photocatalytic Inhibition of Algae Growth Using TiO2, WO3, and

    E-Print Network [OSTI]

    Ouellette, Anthony J. A.

    Photocatalytic Inhibition of Algae Growth Using TiO2, WO3, and Cocatalyst Modifications C L O V I Road, Cocoa, Florida 32922-5703 TiO2 and WO3, with and without noble metal cocatalysts, were employed structures. Introduction Wide band gap metal oxides such as TiO2 and WO3 (Eg ) 3.1 and 2.7 eV, respectively

  16. Effect Of The Plasma Deposition Parameters On The Properties Of Ti/TiN Multilayers For Hard Coatings Applications

    SciTech Connect (OSTI)

    Saoula, N.; Henda, K.; Kesri, R.

    2008-09-23

    In this study, we present the effect of the plasma deposition parameters on the mechanical properties of Ti/TiN multilayers. The elaboration of our films has been carried out by RF-Magnetron Sputtering (13.56 MHz) under nitrogen and argon reactive plasma at low pressure. The film depositions have been done on steel substrates. The first step of our study was the optimization of the depositions conditions in order to obtain good quality films. The amount of nitrogen in the sputtering gases being fixed at 10%. The total pressure was set between 2mTorr to 10mTorr. The deposited multilayers were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), atomic force microscopy (AFM) and micro-indentation.

  17. Segregation of Mn2+ Dopants as Interstitials in SrTiO3 Grain Boundaries

    SciTech Connect (OSTI)

    Yang, Hao; Kotula, Paul G.; Sato, Yukio; Chi, Miaofang; Ikuhara, Yuichi; Browning, Nigel D.

    2013-10-03

    Mn doped SrTiO3 shows promising magnetic and electrical properties, but the doping mechanism remains unclear. In this research Mn4+ is found to substitute Ti in bulk SrTiO3, but Mn2+ segregates inside grain boundaries at both Sr and interstitial sites. Mn interstitial doping has never been reported, but is found possible with the formation of Sr vacancies. This finding is significantly different from the amphoteric doping of Mn2+ substituting Sr and Mn4+ substituting Ti sites, therefore leads to different understanding on the defect mediated electrical and magnetic properties of transition metal doped perovskites.

  18. Features of a priori heavy doping of the n-TiNiSn intermetallic semiconductor

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Romaka, V. V.; Hlil, E. K.; Stadnyk, Yu. V.; Budgerak, S. M.

    2011-07-15

    The crystal structure, the distribution of electron density, and the energy, kinetic, and magnetic properties of the n-TiNiSn intermetallic semiconductor are investigated. It is shown that a priori doping of n-TiNiSn with donors originates from partial, up to 0.5 at %, redistribution of Ti and Ni atoms in crystallographic sites of Ti atoms. The correlation is established between the donor concentration, amplitude of modulation of the continuous energy bands, and degree of filling of low-scale fluctuation potential wells with charge carriers. The results obtained are discussed within the Shklovskii-Efros model of a heavily doped and compensated semiconductor.

  19. Ferroelectric and ferromagnetic properties in BaTiO{sub 3} thin films on Si (100)

    SciTech Connect (OSTI)

    Singamaneni, Srinivasa Rao, E-mail: ssingam@ncsu.edu; Prater, John T. [Materials Science Division, Army Research Office, Research Triangle Park, North Carolina 27709 (United States); Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Punugupati, Sandhyarani; Hunte, Frank; Narayan, Jagdish [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2014-09-07

    In this paper, we report on the epitaxial integration of room temperature lead-free ferroelectric BaTiO{sub 3} thin (?1050?nm) films on Si (100) substrates by pulsed laser deposition technique through a domain matching epitaxy paradigm. We employed MgO and TiN as buffer layers to create BaTiO{sub 3}/SrRuO{sub 3}/MgO/TiN/Si (100) heterostructures. C-axis oriented and cube-on-cube epitaxial BaTiO{sub 3} is formed on Si (100) as evidenced by the in-plane and out-of-plane x-ray diffraction, and transmission electron microscopy. X-ray photoemission spectroscopic measurements show that Ti is in 4(+) state. Polarization hysteresis measurements together with Raman spectroscopy and temperature-dependent x-ray diffraction confirm the room temperature ferroelectric nature of BaTiO{sub 3}. Furthermore, laser irradiation of BaTiO{sub 3} thin film is found to induce ferromagnetic-like behavior but affects adversely the ferroelectric characteristics. Laser irradiation induced ferromagnetic properties seem to originate from the creation of oxygen vacancies, whereas the pristine BaTiO{sub 3} shows diamagnetic behavior, as expected. This work has opened up the route for the integration of room temperature lead-free ferroelectric functional oxides on a silicon platform.

  20. Ann bay lodyans 14 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml fcjNlVfcHto" r ' K A N S A S L lBf iAH.r ANN BAY... LODYANS1 4 Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a. A 51* AYITI SE PEP AYISYEN PM 7854 .H39 A56 2000 v. 14 Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 2000 YON TI PYE ZORANJ Se istwa yon ti fi ki...

  1. Large oriented arrays and continuous films of TiO2 based nanotubes.

    SciTech Connect (OSTI)

    Xu, Huifang; Liu, Jun; Voigt, James A.; Tian, Zhengrong Ryan; McKenzie, Bonnie Beth

    2003-08-01

    We report for the first time a one-step, templateless method to directly prepare large arrays of oriented TiO{sub 2}-based nanotubes and continuous films. These titania nanostructures can also be easily prepared as conformal coatings on a substrate. The nanostructured films were formed on a Ti substrate seeded with TiO{sub 2} nanoparticles. SEM and TEM results suggested that a folding mechanism of sheetlike structures was involved in the formation of the nanotubes. The oriented arrays of TiO{sub 2} nanotubes, continuous films, and coatings are expected to have potentials for applications in catalysis, filtration, sensing, photovoltaic cells, and high surface area electrodes.

  2. Synthesis of Highly Ordered TiO2 Nanotubes Using Ionic Liquids for Photovoltaics Applications

    SciTech Connect (OSTI)

    2009-04-01

    This factsheet describes a study that deals with a new, ‘green’ approach of synthesizing highly ordered TiO2 nanotubes using ionic liquids for photovoltaics (PV) applications.

  3. Spin and orbital Ti magnetism at LaMnO3/SrTiO3 interfaces

    SciTech Connect (OSTI)

    Garcial-Barriocanal, J; Cezar, J. C.; Bruno, F. Y.; Thakur, P.; Brookes, N. B.; Utfeld, C.; Riviera-Calzada, A.; Giblin, S. R.; Taylor, J. W.; Duffy, J. A.; Dugdale, S. B.; Nakamura, T.; Kodama, K.; Leon, C.; Okamoto, Satoshi; Santamaria, J.

    2010-01-01

    In systems with strong electron-lattice coupling, such as manganites, orbital degeneracy is lifted, what causes a null expectation value of the orbital moment. Magnetic structure is thus determined by spin-spin superexchange. In titanates, however, with much smaller Jahn-Teller distortions, orbital degeneracy might allow non-zero values of the orbital magnetic moment. Accordingly, novel forms of ferromagnetic superexchange interaction unique to t2g electrons systems have been theoretically predicted, although their experimental observation has remained elusive. Here we report a new kind of Ti3+ ferromagnetism at LaMnO3/SrTiO3 epitaxial interfaces. It results from charge transfer to the empty conduction band of the titanate and has spin and orbital contributions evidencing the role played by orbital degeneracy. The possibility of tuning magnetic alignment (ferromagnetic or antiferromagnetic) of Ti and Mn moments by structural parameters is demonstrated. This result will provide important clues for the understanding of the effects of orbital degeneracy in superexchange coupling.

  4. Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl: A rare example of Ti(IV) in a square pyramidal oxygen coordination

    SciTech Connect (OSTI)

    Batuk, Maria; Batuk, Dmitry; Abakumov, Artem M.; Hadermann, Joke

    2014-07-01

    A new oxychloride Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl has been synthesized using the solid state method. Its crystal and magnetic structure was investigated in the 1.5–550 K temperature range using electron diffraction, high angle annular dark field scanning transmission electron microscopy, atomic resolution energy dispersive X-ray spectroscopy, neutron and X-ray powder diffraction. At room temperature Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl crystallizes in the P4/mmm space group with the unit cell parameters a=3.91803(3) Å and c=19.3345(2) Å. Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl is a new n=4 member of the oxychloride perovskite-based homologous series A{sub n+1}B{sub n}O{sub 3n?1}Cl. The structure is built of truncated Pb{sub 3}Fe{sub 3}TiO{sub 11} quadruple perovskite blocks separated by CsCl-type Pb{sub 2}Cl slabs. The perovskite blocks consist of two layers of (Fe,Ti)O{sub 6} octahedra sandwiched between two layers of (Fe,Ti)O{sub 5} square pyramids. The Ti{sup 4+} cations are preferentially located in the octahedral layers, however, the presence of a noticeable amount of Ti{sup 4+} in a five-fold coordination environment has been undoubtedly proven using neutron powder diffraction and atomic resolution compositional mapping. Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl is antiferromagnetically ordered below 450(10) K. The ordered Fe magnetic moments at 1.5 K are 4.06(4) ?{sub B} and 3.86(5) ?{sub B} on the octahedral and square-pyramidal sites, respectively. - Highlights: • Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl has been synthesized using the solid state method. • The structure has been refined using neutron powder diffraction data at 1.5–550 K. • It is a new n=4 member of the perovskite-related homologous series A{sub n+1}B{sub n}O{sub 3n?1}Cl. • Ti{sup 4+} cations have both octahedral and square-pyramidal coordination environment. • Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl is antiferromagnetically ordered below T{sub N}?450 K.

  5. Measurement of the 44Ti(alpha,p)47V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed 44Ti from radioactive waste

    E-Print Network [OSTI]

    Murphy, A; Davinson, T; Dressler, R; Fallis, J; Kankainen, A; Laird, A; Murphy, C; Seiffert, C; Schumann, D; Stowasser, T; Stora, T; Wang, C; Woods, P

    2014-01-01

    Measurement of the 44Ti(alpha,p)47V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed 44Ti from radioactive waste

  6. Visible light photocatalytic degradation of 4-chlorophenol using vanadium and nitrogen co-doped TiO{sub 2}

    SciTech Connect (OSTI)

    Jaiswal, R.; Kothari, D. C.; Patel, N.; Miotello, A.

    2013-02-05

    Vanadium and Nitrogen were codoped in TiO{sub 2} photocatalyst by Sol-gel method to utilize visible light more efficiently for photocatalytic reactions. A noticeable shift of absorption edge to visible light region was obtained for the singly-doped namely V-TiO{sub 2}, N-TiO{sub 2} and codoped V-N-TiO{sub 2} samples in comparison with undoped TiO{sub 2}, with smallest band gap obtained with codoped-TiO{sub 2}. The photocatalytic activities for all TiO{sub 2} photocatalysts were tested by 4-chlorophenol (organic pollutant) degradation under visible light irradiation. It was found that codoped TiO{sub 2} exhibits the best photocatalytic activity, which could be attributed to the synergistic effect produced by V and N dopants.

  7. Titanium oxide (TiO2), an abundant material with photocatalytic activity and chemical stability is an important candidate for photocatalytic applications. The photocatalytic activity of the TiO2

    E-Print Network [OSTI]

    phase. In the current project, phase and morphology changes in TiO2 nanotubes were studied using ex studies were also performed to understand the phase and morphology of the nanotubes. As prepared TiO2 nanotubes transform to anatase at 450 oC and transformed to rutile when heated to 800 oC. TiO2 nanotubes

  8. Effect of WC/TiC grain size ratio on microstructure and mechanical properties of WCTiCCo cemented carbides

    E-Print Network [OSTI]

    Hong, Soon Hyung

    of TiC powder as 1 lm. The microstructures of sintered WC­TiC­10 wt%Co cemented carbides were than that expected by modified Hall­Petch type equation. Transverse rupture strength of WC­20TiC­10 wt for decades [1]. Generally, cemented carbides are based on the WC­Co and some cubic carbide such as TiC, Ta

  9. dc electric field tunable bulk acoustic wave solidly mounted resonator using SrTiO3

    E-Print Network [OSTI]

    York, Robert A.

    dc electric field tunable bulk acoustic wave solidly mounted resonator using SrTiO3 G. N. SaddikTiO3 solidly mounted bulk acoustic wave resonator has been designed, fabricated, and tested of Physics. DOI: 10.1063/1.2759464 Thin film bulk acoustic wave resonators FBARs have been in use by research

  10. Crystal Plasticity Modeling of Deformation and Creep in Polycrystalline Ti-6242

    E-Print Network [OSTI]

    Ghosh, Somnath

    Crystal Plasticity Modeling of Deformation and Creep in Polycrystalline Ti-6242 DHYANJYOTI DEKA computational model based on crystal plasticity for the analysis of two-phase a/b Ti-6242 polycrystalline alloys. A rate-dependent elastic-crystal plas- ticity model is incorporated in this model to accommodate

  11. Sputtered TiN films for superconducting coplanar waveguide resonators S. Ohya,1, a)

    E-Print Network [OSTI]

    Martinis, John M.

    Sputtered TiN films for superconducting coplanar waveguide resonators S. Ohya,1, a) B. Chiaro,2 A control the energy of these particles to obtain high-quality TiN films. Superconducting coplanar waveguideN in larger circuits. I. INTRODUCTION Superconducting coplanar-waveguide (SCPW) res- onators are used

  12. A protocol to develop crack-free biomimetic coatings on Ti6Al4V substrates

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    A protocol to develop crack-free biomimetic coatings on Ti6Al4V substrates Sahil Jalota,a) Sutapa/Kadikoy, Istanbul 34755, Turkey (Received 22 November 2006; accepted 16 February 2007) Biomimetic coating in implantology. While this paper specifically refers to coating Ti6Al4V, the results are valid with other related

  13. An Experimental and Theoretical Multi-Mbar Study of Ti-6Al-4V

    SciTech Connect (OSTI)

    Tegner, B E; Macleod, S G; CYNN, H; Proctor, J; Evans, W J; McMahon, M I; Ackland, G J

    2011-04-13

    We report results from an experimental and theoretical study of the room temperature (RT) compression of the ternary alloy Ti-6Al-4V. In this work, we have extended knowledge of the equation of state (EOS) from 40 GPa to 221 GPa, and observed a different sequence of phase transitions to that reported previously for pure Ti.

  14. Irradiation-induced disordering and amorphization of Al3Ti-based intermetallic compounds

    E-Print Network [OSTI]

    Motta, Arthur T.

    Irradiation-induced disordering and amorphization of Al3Ti-based intermetallic compounds Jeong October 2015 Accepted 19 October 2015 Available online 21 October 2015 a b s t r a c t An in situ ion-irradiation irradiation-induced disordering and amorphization of Al3Ti-based intermetallic compounds. Thin foil samples

  15. Preparation of BaTiO3 nanoparticles by combustion spray pyrolysis Sangjin Leea

    E-Print Network [OSTI]

    Messing, Gary L.

    Preparation of BaTiO3 nanoparticles by combustion spray pyrolysis Sangjin Leea , Taehwan Sona were synthesized by combustion spray pyrolysis using a 1:1 molar ratio of oxidizer and fuel. To prepare. Keywords: BaTiO3; Nanomaterials; Spray pyrolysis; Combustion; Powder technology 1. Introduction Fine barium

  16. TESLA Report 2004-02 Anti-multipactor TiN coating of RF power

    E-Print Network [OSTI]

    N layers generation on surfaces which were not protected in this way previously. Thin TiN films on ceramicTESLA Report 2004-02 1 Anti-multipactor TiN coating of RF power coupler components for TESLA performance of couplers) J. Lorkiewicz1 , The Andrzej Soltan Institute for Nuclear Studies, Pl 05-400 Otwock

  17. Electrochemical Monitoring of TiO2 Atomic Layer Deposition by Chronoamperometry and Scanning Electrochemical Microscopy

    E-Print Network [OSTI]

    Yu, Edward T.

    Electrochemical Monitoring of TiO2 Atomic Layer Deposition by Chronoamperometry and Scanning) was used to characterize the atomic layer deposition (ALD) of TiO2 on indium-doped tin oxide (ITO). KEYWORDS: atomic layer deposition (ALD), scanning electrochemical microscopy (SECM), nanoporous films

  18. Processing and Mechanical Properties of Ti2AlC Reinforced with Alumina Fibers 

    E-Print Network [OSTI]

    Jeon, Kwonguk

    2012-10-19

    The fabrication and mechanical properties of Ti2AlC composites reinforced with the alumina oxide fibers, such as NextelTM 720 and ALBF1, were described in this thesis. Alumina fibers and Ti2AlC powders were dispersed in the water and slip cast...

  19. TiGa binary alloys developed as potential dental materials , W.J. Lin a

    E-Print Network [OSTI]

    Zheng, Yufeng

    Ti­Ga binary alloys developed as potential dental materials K.J. Qiu a , W.J. Lin a , F.Y. Zhou, Beijing 100083, China d General Dental Department, School of Stomatology, Peking University, Beijing in dental field. The results of OM and XRD showed that the microstructure of all experimental as-cast Ti

  20. Biomaterials 24 (2003) 39313939 Corrosion and wear-corrosion behavior of NiTi modified

    E-Print Network [OSTI]

    Crone, Wendy C.

    2003-01-01

    Biomaterials 24 (2003) 3931­3939 Corrosion and wear-corrosion behavior of NiTi modified by plasma, aerospace, and automotive industries. NiTi alloys are important materials for biomedical and dental devices. The alloy has been used for making orthodontic dental arch wires and medical guide wires for diagnostic

  1. EPR Study of the Surface Characteristics of Nanostructured TiO2 under UV Irradiation

    E-Print Network [OSTI]

    EPR Study of the Surface Characteristics of Nanostructured TiO2 under UV Irradiation Juan M irradiation in a vacuum show some Ti3+ centers. In contrast, under these conditions only weak signals activated by UV irradiation.1,2 However, reduced quantum yields, along with the gen- eration of undesired

  2. Superelastic and cyclic response of NiTi SMA at various strain rates and temperatures

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    in the range of 77­400 K. The influence of the annealing temperature on the fatigue response is also examined of NiTi SMAs depend on the annealing temperature; (2) in cyclic loading, the dissipated energy over loading rates, NiTi SMAs show properties similar to ordinary steels, as has been established by the first

  3. TiN-Coating Effects on Stainless Steel Tribological Behavior Under Dry and Lubricated Conditions

    E-Print Network [OSTI]

    Volinsky, Alex A.

    deposition (PVD) on cutting tools and other material surfaces susceptible to wear help extending the life highlighted their advantages over uncoated tools (Ref 2-4). TiN coatings wear can change dramaticallyTiN-Coating Effects on Stainless Steel Tribological Behavior Under Dry and Lubricated Conditions

  4. Preparation and properties of ce-doped TiO{sub 2} photocatalyst

    SciTech Connect (OSTI)

    Yan, Ningning; Zhu, Zhongqi; Zhang, Jin [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)] [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China); Zhao, Zongyan [School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093 (China)] [School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093 (China); Liu, Qingju, E-mail: qjliu@ynu.edu.cn [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)] [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)

    2012-08-15

    Highlights: ? The cerium ion doped TiO{sub 2} (Ce-TiO{sub 2}) powders were prepared and characterized. ? The spectrum absorption region of Ce-TiO{sub 2} is red-shifted to visible light. ? The recombination of photo-generated electron-hole pairs of Ce-TiO{sub 2} is inhibited. ? The photocatalytic activity was effected by Ce ion content and greatly improved. -- Abstract: TiO{sub 2} nanoparticles doped with different content of Ce ion were prepared by sol–gel method. The samples were characterized by XRD, XPS, TEM, UV–Vis, and PL, the photocatalytic activity was evaluated by photocatalytic degradation of methylene blue (MB) under the irradiation of fluorescent lamp. The results indicate that Ce ion is incorporated into the lattice of TiO{sub 2}, which can restrain the increase of grain size, broaden the absorption region to visible light, and inhibit the recombination of the photo-generated electron and hole pairs. Moreover, the photocatalytic activity of Ce-TiO{sub 2} in MB degradation is evidently enhanced. The MB degradation rate of the sample with Ce:Ti = 0.33% (molar ratio) in 8 h is 90.03%, which is much higher than that of P25 (68.19%).

  5. Nanostructured SrTiO3/WO3 Heterojunction Thin Films for Efficient Photoelectrochemical Water

    E-Print Network [OSTI]

    Ehrman, Sheryl H.

    Nanostructured SrTiO3/WO3 Heterojunction Thin Films for Efficient Photoelectrochemical Water transfer and separation of photogenerated charge carriers. Introduction #12;Why SrTiO3 and WO3 Tungsten Oxide (WO3) [Eg :- ~ 2.7 eV] Advantages: Basically n-type in nature due to presence of oxygen vacancies

  6. Noncollinear second-harmonic generation in sub-micrometer-poled RbTiOPO4

    E-Print Network [OSTI]

    Arie, Ady

    Noncollinear second-harmonic generation in sub-micrometer-poled RbTiOPO4 S. Moscovich, A. Arie, R generated noncollinear quasi-phase-matched second harmonic wave in an RbTiOPO4 crystal that was poled using systematic nonlinear frequency conversion study of samples produced by the HV-AFM method. The short poling

  7. Stable atomic structure of NiTi austenite

    SciTech Connect (OSTI)

    Zarkevich, Nikolai A [Ames Laboratory; Johnson, Duane D [Ames Laboratory

    2014-08-01

    Nitinol (NiTi), the most widely used shape-memory alloy, exhibits an austenite phase that has yet to be identified. The usually assumed austenitic structure is cubic B2, which has imaginary phonon modes, hence it is unstable. We suggest a stable austenitic structure that “on average” has B2 symmetry (observed by x-ray and neutron diffraction), but it exhibits finite atomic displacements from the ideal B2 sites. The proposed structure has a phonon spectrum that agrees with that from neutron scattering, has diffraction spectra in agreement with x-ray diffraction, and has an energy relative to the ground state that agrees with calorimetry data.

  8. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    E-Print Network [OSTI]

    Jaiswal, A.

    2010-01-01

    a LiFePO 4 /Li 4 Ti 5 O 12 full-cell at several different4 /Li 4 Ti 5 O 12 coin full-cell. Figure 1. 0.2 µ m (a) (b)in LiFePO 4 /Li 4 Ti 5 O 12 full cells. Nano-LiFePO 4 showed

  9. A Theoretical Study on the Hydrogen Transport Mechanism in SrTiO3 Perovskite. II. Scandium

    E-Print Network [OSTI]

    Helgaker, Trygve

    A Theoretical Study on the Hydrogen Transport Mechanism in SrTiO3 Perovskite. II. Scandium Doping to clarify the proton-conduction mechanism in Sc-doped SrTiO3 perovskite, from the viewpoint of energetics, Inc. DOI: 10.1002/qua.24086 Introduction As is well known, cubic SrTiO3 perovskite shows high proton

  10. DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural and Surface

    E-Print Network [OSTI]

    Lin, Zhiqun

    DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural and Surface Engineering on TiO2 Nanotubes Jun Wang[a] and Zhiqun Lin*[b] 2754 2012 Wiley-VCH Verlag GmbH & Co-defined structural parameters and enhanced electronic properties, highly ordered TiO2 nanotube arrays have been

  11. Modelling the coarsening behaviour of TiC precipitates in high-strength, low-alloy steels

    E-Print Network [OSTI]

    Cambridge, University of

    Modelling the coarsening behaviour of TiC precipitates in high-strength, low-alloy steels Jae Hoon­sheet steels rely on a dispersion of fine precipitates based on TiC, generated during the major phase changes of the stoichiometry of titanium and carbon. The purpose was to assess the influences of interface energy and Ti/C

  12. Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage the dissociative chemisorption of hydrogen in Ti-doped alanate storage materials. © 2007 American Institute

  13. A numerical method for predicting the bending fatigue life of NiTi and stainless steel root canal

    E-Print Network [OSTI]

    Zheng, Yufeng

    A numerical method for predicting the bending fatigue life of NiTi and stainless steel root canal. A numerical method for predicting the bending fatigue life of NiTi and stainless steel root canal instruments­titanium alloy (NiTi) and stainless steel (SS) endodontic files using finite element analysis. Methodology

  14. 'Tis the Season for Giving the Gift of Energy Savings | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s s i s t a n t S e c r e t1(TRIDEC)

  15. 'Tis the Season for Giving the Gift of Energy Savings | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12 Beta-3 Racetracks Y-12 Beta-3of thePoliciesDuringWays to

  16. nh gi Tn hi Ti nguyn Thin nhin do Trn du Deep Horizon Khi phc loi chim ng bin ti vng b bin Alabama

    E-Print Network [OSTI]

    ánh giá Tn hi Tài nguyên Thiên nhiên do Tràn du Deep Horizon Khôi phc loài chim ng bin ti vùng b Alabama s hình thành 5 nn làm t ca chim ng dc theo vùng b bin Mobile và Baldwin, Alabama tng c hi làm có th c tìm thy quanh nm ti khu vc b bin Alabama. Chim ng bin òi hi nhng khu vc làm t rng rãi vi

  17. Phase transition behavior and high piezoelectric properties in lead-free BaTiO3CaTiO3BaHfO3 ceramics

    E-Print Network [OSTI]

    Cao, Wenwu

    ceramics Dali Wang · Zhaohua Jiang · Bin Yang · Shantao Zhang · Mingfu Zhang · Feifei Guo · Wenwu Cao of lead-free (1-x)Ba(Hf0.16Ti0.84)O3­x (Ba0.70Ca0.30)TiO3 (BCHT) ceramics fabricated by the conventional been proposed based on their dielectric behavior. It is found that BHCT ceramics undergo a complicated

  18. The 40Ca(alpha,gamma)44Ti reaction in the energy regime of supernova nucleosynthesis

    E-Print Network [OSTI]

    H. Nassar; M. Paul; I. Ahmad; Y. Ben-Dov; J. Caggiano; S. Ghelberg; S. Goriely; J. P. Greene; M. Hass; A. Heger; A. Heinz; D. J. Henderson; R. V. F. Janssens; C. L. Jiang; Y. Kashiv; B. S. Nara Singh; A. Ofan; R. C. Pardo; T. Pennington; K. E. Rehm; G. Savard; R. Scott; R. Vondrasek

    2006-01-11

    The 44Ti(t1/2 = 59 y) nuclide, an important signature of supernova nucleosynthesis, has recently been observed as live radioactivity by gamma-ray astronomy from the Cas A remnant. We investigate in the laboratory the major 44Ti production reaction, 40Ca(alpha,gamma)44Ti (E_cm = 0.6-1.2 MeV/u), by direct off- line counting of 44Ti nuclei. The yield, significantly higher than inferred from previous experiments, is analyzed in terms of a statistical model using microscopic nuclear inputs. The associated stellar rate has important astrophysical consequences, increasing the calculated supernova 44Ti yield by a factor ~2 over previous estimates and bringing it closer to Cas A observations.

  19. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore »(Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (« less

  20. TiN/VN composites with core/shell structure for supercapacitors

    SciTech Connect (OSTI)

    Dong, Shanmu; Chen, Xiao; Gu, Lin; Zhou, Xinhong; Wang, Haibo; Liu, Zhihong; Han, Pengxian; Yao, Jianhua; Wang, Li; Cui, Guanglei; Chen, Liquan; Institute of Physics, Chinese Academy of Sciences, Beijing 100080

    2011-06-15

    Research highlights: {yields} Vanadium and titanium nitride nanocomposite with core-shell structure was prepared. {yields} TiN/VN composites with different V:Ti molar ratios were obtained. {yields} TiN/VN composites can provide promising electronic conductivity and favorable capacity storage. -- Abstract: TiN/VN core-shell composites are prepared by a two-step strategy involving coating of commercial TiN nanoparticles with V{sub 2}O{sub 5}.nH{sub 2}O sols followed by ammonia reduction. The highest specific capacitance of 170 F g{sup -1} is obtained when scanned at 2 mV s{sup -1} and a promising rate capacity performance is maintained at higher voltage sweep rates. These results indicate that these composites with good electronic conductivity can deliver a favorable capacity performance.

  1. Reaction rate sensitivity of 44Ti production in massive stars and implications of a thick target yield measurement of 40Ca(alpha,gamma)44Ti

    SciTech Connect (OSTI)

    Hoffman, R D; Sheets, S A; Burke, J T; Scielzo, N D; Rauscher, T; Norman, E B; Tumey, S; Brown, T A; Grant, P G; Hurst, A M; Phair, L; Stoyer, M A; Wooddy, T; Fisker, J L; Bleuel, D

    2010-02-16

    We evaluate two dominant nuclear reaction rates and their uncertainties that affect {sup 44}Ti production in explosive nucleosynthesis. Experimentally we develop thick-target yields for the {sup 40}Ca({alpha},{gamma}){sup 44}Ti reaction at E{sub {alpha}} = 4.13, 4.54, and 5.36 MeV using {gamma}-ray spectroscopy. At the highest beam energy, we also performed an activation measurement which agrees with the thick target result. From the measured yields a stellar reaction rate was developed that is smaller than current statistical-model calculations and recent experimental results, which would suggest lower {sup 44}Ti production in scenarios for the {alpha}-rich freeze out. Special attention has been paid to assessing realistic uncertainties of stellar reaction rates produced from a combination of experimental and theoretical cross sections. With such methods, we also develop a re-evaluation of the {sup 44}Ti({alpha},p){sup 47}V reaction rate. Using these two rates we carry out a sensitivity survey of {sup 44}Ti synthesis in eight expansions representing peak temperature and density conditions drawn from a suite of recent supernova explosion models. Our results suggest that the current uncertainty in these two reaction rates could lead to as large an uncertainty in {sup 44}Ti synthesis as that produced by different treatments of stellar physics.

  2. Active wear and failure mechanisms of TiN-coated high speed steel and TiN-coated cemented carbide tools when machining powder metallurgically made stainless steels

    SciTech Connect (OSTI)

    Jiang, L.; Haenninen, H.; Paro, J.; Kauppinen, V.

    1996-09-01

    In this study, active wear and failure mechanisms of both TiN-coated high speed steel and TiN-coated cemented carbide tools when machining stainless steels made by powder metallurgy in low and high cutting speed ranges, respectively, have been investigated. Abrasive wear mechanisms, fatigue-induced failure, and adhesive and diffusion wear mechanisms mainly affected the tool life of TiN-coated high speed steel tools at cutting speeds below 35 m/min, between 35 and 45 m/min, and over 45 m/min, respectively. Additionally, fatigue-induced failure was active at cutting speeds over 45 m/min in the low cutting speed range when machining powder metallurgically made duplex stainless steel 2205 and austenitic stainless steel 316L. In the high cutting speed range, from 100 to 250 m/min, fatigue-induced failure together with diffusion wear mechanism, affected the tool life of TiN-coated cemented carbide tools when machining both 316L and 2205 stainless steels. It was noticed that the tool life of TiN-coated high speed steel tools used in the low cutting speed range when machining 2205 steel was longer than that when machining 316L steel, whereas the tool life of TiN-coated cemented carbide tools used in the high cutting speed range when machining 316L steel was longer than that when machining 2205 steel.

  3. Preparation and lithium intercalation behavior of TiO{sub 2} in aqueous solutions

    SciTech Connect (OSTI)

    Li, Yunjiao, E-mail: yunjiaoli6601@hotmail.com; Li, Lin; Chen, Lingpeng; Wang, Xuanyu; Xu, Cang

    2014-04-01

    Highlights: • The poor crystalline anatase phase or amorphous TiO{sub 2} was prepared by TiCl{sub 4} hydrolysis under different pH conditions. • Phase transition behavior and lithium intercalation ability of the obtained TiO{sub 2} were found to be related to TiO{sub 2} property. • The results indicate that TiO{sub 2} products obtained from TiCl{sub 4} hydrolysis at lower pH are favorable for lithium intercalation. - Abstract: The low crystalline or amorphous TiO{sub 2} was prepared by TiCl{sub 4} hydrolysis in aqueous solutions under different pH conditions at 45 °C. The products obtained at lower pH (1.23–3.10) appear to be nano-sized particles with poor crystalline anatase structure and an uniform particle size distribution, while the product prepared at pH 4.10 presents in a poor crystalline anatase structure and the regular morphology starts to disappear, and the products obtained at higher pH (>6.00) are amorphous and irregular morphology. The hydrolysis products obtained at pH 2.60 and 8.80 were heat-treated at 300, 400, 600, 700 and 800 °C for 3 h, respectively, to figure out the phase transition. The differences in phase transition process were observed, which verified the properties difference. The lithium intercalation abilities of the obtained TiO{sub 2} were studied. The results indicated that the TiO{sub 2} obtained at lower pH are more favorable for lithium intercalation and are better precursors.

  4. Visible-light active TiO2 for microwave assisted photocatalytic reactions using mercury electrodeless discharge lamps

    E-Print Network [OSTI]

    Cirkva, Vladimir

    of transition metal ions in wt.% was determined by electron microprobe Ag/TiO2: 143 (Eg) 196 (Eg) 395 (B1g) 513 (A1g) 519 (B1g) 638 (Eg) -50 0 50 100 150 200 250 300 350 400 Int 5001000 Raman shift (cm-1) Raman spectroscopy anatase TiO2: A1g+2B1g+3Eg (Eg) (A1g) (B1g) (B1g) (Eg) (Eg) A B C D A-TiO2 B-V/TiO2 C-Zr/TiO2 D

  5. Fabrication and characterization of photovoltaic devices based on perovskite compounds with TiO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Kanayama, Masato Oku, Takeo Suzuki, Atsushi; Yamada, Masahiro; Sakamoto, Hiroki; Fukunishi, Sakiko; Kohno, Kazufumi

    2015-02-27

    Perovskite-type photovoltaic devices were fabricated by a spin-coating method using a mixture solution. The compact and meso-porous TiO{sub 2} of the solar cells were fabricated from TiO{sub 2} nanoparticles and sol, and the photovoltaic properties and microstructures were characterized. The conversion efficiencies were improved by the combination of TiO{sub 2} nanoparticles and sol. Current density was also improved by increasing numbers of spin-coatings of meso-porous TiO{sub 2}. Thick meso-porous TiO2 layers would assist the construction of perovskite layers and block of the leak current.

  6. Brazing ZrO{sub 2} ceramic to Ti–6Al–4V alloy using NiCrSiB amorphous filler foil: Interfacial microstructure and joint properties

    SciTech Connect (OSTI)

    Cao, J., E-mail: cao_jian@hit.edu.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Song, X.G., E-mail: song_xiaoguohit@yahoo.com.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Li, C., E-mail: li_chun1989@yahoo.cn [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Zhao, L.Y., E-mail: Zhao_ly@163.com [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Feng, J.C., E-mail: feng_jicai@163.com [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China)

    2013-07-15

    Reliable brazing of ZrO{sub 2} ceramic and Ti–6Al–4V alloy was achieved using NiCrSiB amorphous filler foil. The interfacial microstructure of ZrO{sub 2}/Ti–6Al–4V joints was characterized by scanning electron microscope, energy dispersive spectrometer and micro-focused X-ray diffractometer. The effects of brazing temperature on the interfacial microstructure and joining properties of brazed joints were investigated in detail. Active Ti of Ti–6Al–4V alloy dissolved into molten filler metal and reacted with ZrO{sub 2} ceramic to form a continuous TiO reaction layer, which played an important role in brazing. Various reaction phases including Ti{sub 2}Ni, Ti{sub 5}Si{sub 3} and ?-Ti were formed in brazed joints. With an increasing of brazing temperature, the TiO layer thickened gradually while the Ti{sub 2}Ni amount reduced. Shear test indicated that brazed joints tend to fracture at the interface between ZrO{sub 2} ceramic and brazing seam or Ti{sub 2}Ni intermetallic layer. The maximum average shear strength reached 284.6 MPa when brazed at 1025 °C for 10 min. - Graphical Abstract: Interfacial microstructure of ZrO{sub 2}/TC4 joint brazed using NiCrSiB amorphous filler foil was: ZrO{sub 2}/TiO/Ti{sub 2}Ni + ?-Ti + Ti{sub 5}Si{sub 3}/?-Ti/Widmanstätten structure/TC4. - Highlights: • Brazing of ZrO{sub 2} ceramic and Ti-6Al-4V alloy was achieved. • Interfacial microstructure was TiO/Ti{sub 2}Ni + ? + Ti{sub 5}Si{sub 3}/?/Widmanstätten structure. • The formation of TiO produced the darkening effect of ZrO{sub 2} ceramic. • The highest joining strength of 284.6MPa was obtained.

  7. High-Resolution Soft X-Ray Spectral Analysis in the CK Region of Titanium Carbide (TiC) using the DV-X alpha Molecular Orbital Method

    E-Print Network [OSTI]

    Shimomura, Kenta

    2010-01-01

    1 XRD pattern of the measured TiC powder sample. Figure 2XAS. Intensity (arb. units) TiC X-ray: Cu K? voltage: 40 kVintensity (arb. units) CK-XES TiC b a c HOPG e f CK-XAS TiC

  8. Nanoscale compositional analysis of NiTi shape memory alloy films deposited by DC magnetron sputtering

    SciTech Connect (OSTI)

    Sharma, S. K.; Mohan, S.; Bysakh, S.; Kumar, A.; Kamat, S. V.

    2013-11-15

    The formation of surface oxide layer as well as compositional changes along the thickness for NiTi shape memory alloy thin films deposited by direct current magnetron sputtering at substrate temperature of 300 °C in the as-deposited condition as well as in the postannealed (at 600 °C) condition have been thoroughly studied by using secondary ion mass spectroscopy, x-ray photoelectron spectroscopy, and scanning transmission electron microscopy-energy dispersive x-ray spectroscopy techniques. Formation of titanium oxide (predominantly titanium dioxide) layer was observed in both as-deposited and postannealed NiTi films, although the oxide layer was much thinner (8 nm) in as-deposited condition. The depletion of Ti and enrichment of Ni below the oxide layer in postannealed films also resulted in the formation of a graded microstructure consisting of titanium oxide, Ni{sub 3}Ti, and B2 NiTi. A uniform composition of B2 NiTi was obtained in the postannealed film only below a depth of 200–250 nm from the surface. Postannealed film also exhibited formation of a ternary silicide (Ni{sub x}Ti{sub y}Si) at the film–substrate interface, whereas no silicide was seen in the as-deposited film. The formation of silicide also caused a depletion of Ni in the film in a region ?250–300 nm just above the film substrate interface.

  9. Photo-oxidative degradation of TiO{sub 2}/polypropylene films

    SciTech Connect (OSTI)

    García-Montelongo, X.L.; Martínez-de la Cruz, A.; Vázquez-Rodríguez, S.; Torres-Martínez, Leticia M.

    2014-03-01

    Graphical abstract: - Highlights: • Photo-oxidative degradation of polypropylene is accelerated by TiO{sub 2} incorporation. • Weight loss, FTIR, SEM and GPC shown high degree of degradation of polypropylene. • A mechanism of the photo-degradation of polypropylene by TiO{sub 2} is proposed. - Abstract: Photo-oxidative degradation of polypropylene films with TiO{sub 2} nanoparticles incorporated was studied in a chamber of weathering with Xenon lamps as irradiation source. TiO{sub 2} powder with crystalline structure of anatase was synthesized by thermal treatments at 400 and 500 °C starting from a precursor material obtained by sol–gel method. Composites of TiO{sub 2}/polypropylene were prepared with 0.1, 0.5 and 1.0 wt% of TiO{sub 2}. The mixture of components was performed using a twin screw extruder, the resulting material was pelletized by mechanical fragmenting and then hot-pressed in order to form polypropylene films with TiO{sub 2} dispersed homogeneously. Photo-oxidative degradation process was followed by visual inspection, weight loss of films, scanning electron microscopy (SEM), infrared spectroscopy with Fourier transformed (FTIR), and gel permeation chromatography (GPC)

  10. Graphene oxide modified TiO2 nanotube arrays?enhanced visible light photoelectrochemical properties

    SciTech Connect (OSTI)

    Song, Peng; Zhang, Xiao-Yan; Sun, Mingxun; Cui, Xiao-Li; Lin, Yuehe

    2012-03-01

    Novel nanocomposite films based on graphene oxide (GO) and TiO{sub 2} nanotube arrays were synthesized by assembling GO on the surface of self-organized TiO{sub 2} nanotube arrays through a simple assembling method. The composite films were characterized with field emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and UV-vis diffuse reflectance spectroscopy. Photoelectrochemical properties of the composite nanotube arrays were investigated under visible light illumination. Remarkably enhanced visible light photoelectrochemical response was observed for the GO decorated TiO{sub 2} nanotube composite electrode compared with pristine TiO{sub 2} nanotube arrays. Sensitizing effect of GO on the photoelectrochemical response of TiO{sub 2} nanotube arrays was demonstrated and about 15 times enhanced maximum photoconversion efficiency was obtained with the presence of GO. Enhanced photocatalytic activity of TiO{sub 2} nanotube arrays towards degradation of methyl blue was also demonstrated after modification of GO. The results presented here demonstrate GO to be efficient for the improvement of utilization of visible light for TiO{sub 2} nanotube arrays.

  11. Location Of Hole And Electron Traps On Nanocrystalline Anatase TiO2

    SciTech Connect (OSTI)

    Mercado, Candy C.; Knorr, Fritz J.; McHale, Jeanne L.; Usmani, Shirin M.; Ichimura, Andrew S.; Saraf, Laxmikant V.

    2012-05-17

    The defect photoluminescence from TiO2 nanoparticles in the anatase phase is reported for nanosheets which expose predominantly (001) surfaces, and compared to that from conventional anatase nanoparticles which expose mostly (101) surfaces. Also reported is the weak defect photoluminescence of TiO2 nanotubes, which we find using electron back-scattered diffraction to consist of walls which expose (110) and (100) facets. The nanotubes exhibit photoluminescence that is blue-shifted and much weaker than that from conventional TiO2 nanoparticles. Despite the preponderance of (001) surfaces in the nanosheet samples, they exhibit photoluminescence similar to that of conventional nanoparticles. We assign the broad visible photoluminescence of anatase nanoparticles to two overlapping distributions: hole trap emission associated with oxygen vacancies on (101) exposed surfaces, which peaks in the green, and a broader emission extending into the red which results from electron traps on under-coordinated titanium atoms, which are prevalent on (001) facets. The results of this study suggest how morphology of TiO2 nanoparticles could be optimized to control the distribution and activity of surface traps. Our results also shed light on the mechanism by which the TiCl4 surface treatment heals traps on anatase and mixed-phase TiO2 films, and reveals distinct differences in the trap-state distributions of TiO2 nanoparticles and nanotubes. The molecular basis for electron and hole traps and their spatial separation on different facets is discussed.

  12. Direct Evidence of Lithium-Induced Atomic Ordering in Amorphous TiO2 Nanotubes

    SciTech Connect (OSTI)

    Gao, Qi; Gu, Meng; Nie, Anmin; Mashayek, Farzad; Wang, Chong M.; Odegard, Gregory M.; Shahbazian-Yassar, Reza

    2014-01-27

    In this paper, we report the first direct chemical and imaging evidence of lithium-induced atomic ordering in amorphous TiO2 nanomaterials and propose new reaction mechanisms that contradict the many works in the published literature on the lithiation behavior of these materials. The lithiation process was conducted in situ inside an atomic resolution transmission electron microscope. Our results indicate that the lithiation started with the valence reduction of Ti4+ to Ti3+ leading to a LixTiO2 intercalation compound. The continued intercalation of Li ions in TiO2 nanotubes triggered an amorphous to crystalline phase transformation. The crystals were formed as nano-islands and identified to be Li2Ti2O4 with cubic structure (a = 8.375 Å). The tendency for the formation of these crystals was verified with density functional theory (DFT) simulations. The size of the crystalline islands provides a characteristic length scale (?5 nm) at which the atomic bonding configuration has been changed within a short time period. This phase transformation is associated with local inhomogeneities in Li distribution. On the basis of these observations, a new reaction mechanism is proposed to explain the first cycle lithiation behavior in amorphous TiO2 nanotubes.

  13. Physical properties and electronic structure of a new barium titanate suboxide Ba1+?Ti13-?O?? (? = 0.11)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, Costel R.; Jiang, Shan; Deng, Xiaoyu; Qian, Yiting; Khan, Saeed; Hawthorn, David G.; Kotliar, Gabriel; Ni, Ni

    2015-04-01

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+?Ti13-?O?? (? = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti²? state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of themore »Ti?? semi-cluster and the TiO? quasi-squares, respectively.« less

  14. Physical properties and electronic structure of a new barium titanate suboxide Ba1+?Ti13-?O?? (? = 0.11)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, Costel R. [Univ. of California Los Angeles, Los Angeles, CA (United States); Jiang, Shan [Univ. of California Los Angeles, Los Angeles, CA (United States); Deng, Xiaoyu [Rutgers Univ., Piscataway, NJ (United States)] (ORCID:0000000178020966); Qian, Yiting [Univ. of Waterloo, Waterloo (Canada)] (ORCID:0000000250175517); Khan, Saeed [Univ. of California Los Angeles, Los Angeles, CA (United States); Hawthorn, David G. [Univ. of Waterloo, Waterloo (Canada)] (ORCID:0000000270020416); Kotliar, Gabriel [Rutgers Univ., Piscataway, NJ (United States); Ni, Ni [Univ. of California Los Angeles, Los Angeles, CA (United States)

    2015-04-01

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+?Ti13-?O?? (? = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti²? state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of the Ti?? semi-cluster and the TiO? quasi-squares, respectively.

  15. Electrochromism in sol-gel deposited TiO(sub 2) films

    SciTech Connect (OSTI)

    Bell, J.M.; Barczynska, J.; Evans, L.A.; MacDonald, K.A.; Wang, J.; Green, D.C.; Smith, G.B.

    1994-12-31

    Electrochromism in sol-gel deposited TiO{sub 2} films and films containing TiO{sub 2} and WO{sub 3} has been observed. The films are deposited by dip-coating from a precursor containing titanium isopropoxide in ethanol or titanium propoxide in ethanol, and after deposition the films are heat treated to between 250 C and 300 C. The films do not show any signs of crystallinity. However substantial coloration is observed using Li{sup +} ions in a non-aqueous electrolyte, both in pure TiO{sub 2} films and in mixed metal oxide films (WO{sub 3}:TiO{sub 2}), although the voltage required to produce coloration is different in the two cases. Results will be presented detailing the optical switching and charge transport properties of the films during cyclic voltammetry. These results will be used to compare the performance of the TiO{sub 2} films with other electrochromics. The TiO{sub 2} and mixed metal films all color cathodically, and the colored state is a neutral greyish color for TiO{sub 2}, while the bleached state is transparent and colorless. Results on coloration efficiency and the stability under repeated electrochemical cycling will also be presented. The neutral color of the TiO{sub 2} films and mixed-metal films means that electrochromic windows based on TiO{sub 2} may have significant advantages over WO{sub 3}-based windows. A detailed analysis of the optical properties of the colored state of the films will be presented. The dynamics of coloration for these films is also under investigation, and preliminary results will be presented.

  16. The thermal stability of TiB[sub 2] in Ni-43 a% Al

    SciTech Connect (OSTI)

    Korinko, P.S. (General Motors, Indianapolis, IN (United States). Allison Gas Turbine Div.); Duquette, D.J. (Rensselaer Polytechnic Inst., Troy, NY (United States))

    1994-02-01

    The intermetallic compound NiAl has been suggested for use as a matrix for high temperature composites. Interest in this compound is derived from its low density compared to conventional superalloys, high melting point, and excellent oxidation resistance. It has been demonstrated that a composite of stoichiometric NiAl and TiB[sub 2] is stable when exposed at elevated temperatures for extended periods of time. However, it has been shown that a composite consisting of Ni[sub 3]Al and TiB[sub 2] is not stable in the same temperature range. In the case of Ni[sub 3]Al, the TiB[sub 2] particles dissolve and the matrix is enriched with Ti and transforms to Ni[sub 3](Al,Ti) and NiTi. If stoichiometric NiAl reinforced with TiB[sub 2] is used in a high temperature oxidizing atmosphere, then there is also a possibility that the Al may be depleted as it is oxidized. If this occurs, the composition of the matrix may shift to nickel-rich NiAl or even to Ni[sub 3]Al. This work was conducted to determine if TiB[sub 2] is used in a high temperature oxidizing atmosphere, then there is also a possibility that the Al may be depleted as it is oxidized. If this occurs, the composition of the matrix may shift to nickel-rich NiAl or even to Ni[sub 3]Al. This work was conducted to determine if TiB[sub 2] is stable in nickel-rich NiAl. The Ni-Al phase diagram is shown, and the composition of NiAl used in this study is indicated.

  17. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K???Bi???TiO?-BaTiO?-Na???Bi???TiO? piezoelectric materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26

    We synthesized grain-oriented lead-free piezoelectric materials in (K???Bi???TiO?-BaTiO?-xNa???Bi???TiO? (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d?? ~ 190pC/N) and high temperature stability (~160°C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180° domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectricmore »materials.« less

  18. Thick target measurement of the 40Ca(alpha,gamma)44Ti reaction rate

    SciTech Connect (OSTI)

    Sheets, S A; Burke, J T; Scielzo, N D; Phair, L; Bleuel, D; Norman, E B; Grant, P G; Hurst, A M; Tumey, S; Brown, T A; Stoyer, M

    2009-02-06

    The thick-target yield for the {sup 40}Ca({alpha},{gamma}){sup 44}Ti reaction has been measured for E{sub beam} = 4.13, 4.54, and 5.36 MeV using both an activation measurement and online {gamma}-ray spectroscopy. The results of the two measurements agree. From the measured yield a reaction rate is deduced that is smaller than statistical model calculations. This implies a smaller {sup 44}Ti production in supernova compared to recently measured {sup 40}Ca({alpha},{gamma}){sup 44}Ti reaction rates.

  19. Photo-induced wettability of TiO{sub 2} film with Au buffer layer

    SciTech Connect (OSTI)

    Purkayastha, Debarun Dhar; Sangani, L. D. Varma; Krishna, M. Ghanashyam; Madhurima, V.

    2014-04-24

    The effect of thickness of Au buffer layer (15-25 nm) between TiO{sub 2} film and substrate on the wettability of TiO{sub 2} films is reported. TiO{sub 2} films grown on Au buffer layer have a higher contact angle of 96-;100° as compared to 47.6o for the film grown without buffer layer. The transition from hydrophobicity to hydrophilicity under UV irradiation occurs within 10 min. for the buffer layered films whereas it is almost 30 min. for the film grown without buffer layer. The enhanced photo induced hydrophilicity is shown to be surface energy driven.

  20. On the origins of hardness of Cu–TiN nanolayered composites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pathak, S.; Li, N.; Maeder, X.; Hoagland, R. G.; Baldwin, J. K.; Michler, J.; Misra, A.; Wang, J.; Mara, N. A.

    2015-07-18

    We investigated the mechanical response of physical vapor deposited Cu–TiN nanolayered composites of varying layer thicknesses from 5 nm to 200 nm. Both the Cu and TiN layers were found to consist of single phase nanometer sized grains. The grain sizes in the Cu and TiN layers, measured using transmission electron microscopy and X-ray diffraction, were found to be comparable to or smaller than their respective layer thicknesses. Indentation hardness testing revealed that the hardness of such nanolayered composites exhibits a weak dependence on the layer thickness but is more correlated to their grain size.

  1. Doping of TiO 2 Polymorphs for Altered Optical and Photocatalytic Properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nie, Xiliang; Zhuo, Shuping; Maeng, Gloria; Sohlberg, Karl

    2009-01-01

    This paper reviews recent investigations of the influence of dopants on the optical properties of TiO 2 polymorphs. The common undoped polymorphs of TiO 2 are discussed and compared. The results of recent doping efforts are tabulated, and discussed in the context of doping by elements of the same chemical group. Dopant effects on the band gap and photocatalytic activity are interpreted with reference to a simple qualitative picture of the TiO 2 electronic structure,more »which is supported with first-principles calculations. « less

  2. Doping ofTiO2Polymorphs for Altered Optical and Photocatalytic Properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nie, Xiliang; Zhuo, Shuping; Maeng, Gloria; Sohlberg, Karl

    2009-01-01

    This paper reviews recent investigations of the influence of dopants on the optical properties ofTiO2polymorphs. The common undoped polymorphs ofTiO2are discussed and compared. The results of recent doping efforts are tabulated, and discussed in the context of doping by elements of the same chemical group. Dopant effects on the band gap and photocatalytic activity are interpreted with reference to a simple qualitative picture of theTiO2electronic structure, which is supported with first-principles calculations.

  3. Thermomechanical behavior of 55Ni45Ti nitinol

    SciTech Connect (OSTI)

    Ford, D.S.; White, S.R. [Univ. of Illinois, Urbana, IL (United States)] [Univ. of Illinois, Urbana, IL (United States)

    1996-06-01

    Extensive and full range mechanical testing of 55Ni45Ti nitinol alloy wire up to failure over a wide range of testing temperatures is reported. Thermomechanical properties are obtained including: initial modulus, secondary modulus, critical martensitic start and finish stresses, plastic flow stress, recovery strain limit, failure stress and plastic modulus. The data is correlated with the Brinson constitutive model modified to account for full range loading. The ratio of austenite to martensite moduli was found to be 5.8 and the secondary modulus (stress-induced martensite) was found to be smaller by a factor of two when compared to the modulus of (stress-free) thermally induced martensite. The influence of the initial temperature treatment of the nitinol was shown to be pronounced within the transformation range. Reasonably accurate correlation is obtained with the modified Brinson constitutive model although there is some discrepancy in critical stress predictions which is partially attributed to experimental scatter.

  4. Ab initio study of irradiation tolerance for different M{sub n+1}AX{sub n} phases: Ti{sub 3}SiC{sub 2} and Ti{sub 3}AlC{sub 2}

    SciTech Connect (OSTI)

    Zhao, Shijun; Xue, Jianming, E-mail: jmxue@pku.edu.cn; Wang, Yugang [State Key Laboratory of Nuclear Physics and Technology, School of Physics, Peking University, Beijing 100871 (China); Center for Applied Physics and Technology, Peking University, Beijing 100871 (China); Huang, Qing [Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang (China)

    2014-01-14

    Layered ternary M{sub n+1}AX{sub n} (MAX) materials are recently proposed to be promising candidates for future fission and fusion programmes because of their unique properties inherited from both ceramics and metals. However, different M{sub n+1}AX{sub n} materials demonstrate different behaviors when exposed to energetic neutron or ion irradiations. Based on first-principles calculations, we have investigated the irradiation tolerance of two typical M{sub n+1}AX{sub n} materials: Ti{sub 3}SiC{sub 2} and Ti{sub 3}AlC{sub 2} from two aspects. First, we make a detailed analysis on the interatomic bonding characters, which are believed to be responsible for the resistance to radiation-induced amorphization. Second, the formation energies of various intrinsic and antisite defects in these two compounds are calculated in order to elucidate their amorphization mechanism. Our results show that the absence of orbitals overlap of Al-C in Ti{sub 3}AlC{sub 2} renders it more resistant to amorphization compared to Ti{sub 3}SiC{sub 2}. In addition, the antisite defects Al{sub Ti(1)} and Al{sub Ti(2)} in Ti{sub 3}AlC{sub 2} have much lower formation energies compared to Si{sub Ti(1)} and Si{sub Ti(2)} in Ti{sub 3}SiC{sub 2}, which implies that the replacement of Ti with Al is easier than Si, thus providing an alternative way to accommodate the defects resulted from irradiation damage cascades. These results indicate that Ti{sub 3}AlC{sub 2} is more irradiation tolerant than Ti{sub 3}SiC{sub 2}, in accordance with experimental observations. Our results have profound implications for the choice of appropriate MAX phase with best performance to be used in next reaction reactors.

  5. | Faire carrire l'UdeM Concepteur en technologies de gestion des services TI

    E-Print Network [OSTI]

    Charette, André

    processus de gestion TI conformément au référentiel ITIL et détermine les priorités d'amélioration relatives'exploitation Windows et Linux; o du référentiel ITIL V3, de ses bonnes pratiques et

  6. Role of polaron hopping in leakage current behavior of a SrTiO3 ...

    E-Print Network [OSTI]

    2014-03-14

    Dec 10, 2013 ... Meyer et al. suggested pinning of compensating electrons by the work function of the electrodes on both sides of. Ba0.3Sr0.7TiO3 thin film but ...

  7. Growth and characterization of superconducting spinel oxide LiTi2O4 thin films

    E-Print Network [OSTI]

    Chopdekar, R.V.

    2009-01-01

    2004). [37] F. Gomory, Superconductor Science and TechnologyHabermeier, Journal of Superconductivity 13, 871 (2000). [SrTiO 3?? and LTO both superconduct and both have mixed-

  8. DNA nanoconjugates Labeling TiO2 Nanoparticles with Dyes for Optical

    E-Print Network [OSTI]

    Brown, Eric

    signal as mapped by XFM. This strongly implies the intracellular integrity of the TiO2­DNA nanoconjugates Indian Institute of Technology Bombay Powai Mumbai 400076 (India) Prof. V. Dravid Department of Material

  9. Macroporous TiO2 Photoanodes for High Efficiency PSI-Based Biohybrid Photovoltaics

    E-Print Network [OSTI]

    Macroporous TiO2 Photoanodes for High Efficiency PSI-Based Biohybrid Photovoltaics and efficiency of PSI-based biohybrid photovoltaics due to the high integraVon of PSI

  10. Lucas-Kanade Optical Flow Estimation on the TI C66x Digital Signal Processor

    E-Print Network [OSTI]

    Bakos, Jason D.

    technology for lightweight mobile platforms. The C66x DSP is based on TI's Keystone architecture and consists, scratchpad, or a mixture of both. Like other VLIW archi- tectures, the compiler must software pipeline each

  11. The development and synthetic applications of Ti- and Pd-catalyzed processes

    E-Print Network [OSTI]

    Hyde, Alan M. (Alan Michael)

    2009-01-01

    Chapter 1. Ti-Catalyzed Asymmetric Reduction of Aromatic Heterocycles A method for the highly selective asymmetric reduction of quinoxalines and quinazolines was developed. This complements technologies developed by others ...

  12. Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110)

    SciTech Connect (OSTI)

    Chen, Long; Li, Zhenjun; Smith, R. Scott; Kay, Bruce D.; Dohnalek, Zdenek

    2014-04-16

    Understanding hydrogen formation on TiO2 surfaces is of great importance as it could provide fundamental insight into water splitting for hydrogen production using solar energy. In this work, hydrogen formation from glycols having different numbers of methyl end-groups have been studied using temperature pro-grammed desorption on reduced, hydroxylated, and oxidized TiO2(110) surfaces. The results from OD-labeled glycols demon-strate that gas-phase molecular hydrogen originates exclusively from glycol hydroxyl groups. The yield is controlled by a combi-nation of glycol coverage, steric hindrance, TiO2(110) order and the amount of subsurface charge. Combined, these results show that proximal pairs of hydroxyl aligned glycol molecules and subsurface charge are required to maximize the yield of this redox reaction. These findings highlight the importance of geometric and electronic effects in hydrogen formation from adsorbates on TiO2(110).

  13. Fabrication and characterization of porous NiTi Shape Memory Alloy by elevated pressure sintering 

    E-Print Network [OSTI]

    Vandygriff, Eric Layton

    2002-01-01

    have not been adequately developed. Currently, three methods are commonly used for producing porous NiTi SMAs from elemental powders. These methods include conventional sintering, Self-propagating High-temperature Synthesis (SHS), and sintering...

  14. Transformation Induced Fatigue of Ni-Rich NiTi Shape Memory Alloy Actuators 

    E-Print Network [OSTI]

    Schick, Justin Ryan

    2011-02-22

    In this work the transformation induced fatigue of Ni-rich NiTi shape memory alloys (SMAs) was investigated. The aerospace industry is currently considering implementing SMA actuators into new applications. However, before ...

  15. The origin of photochemical anisotropy in SrTiO3 Jennifer L. Giocondia,b

    E-Print Network [OSTI]

    Rohrer, Gregory S.

    products on catalytic surfaces have been used to probe the anisotropy of the reactivity of SrTiO3 proximity, then the reverse reaction to reform water is likely. Photochemical anisotropies are studied using

  16. Flat panel display using Ti-Cr-Al-O thin film

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solan Beach, CA)

    2002-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  17. Process for producing Ti-Cr-Al-O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

    2001-01-01

    Thin films of Ti-Cr-Al-O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti-Cr-Al-O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti-Cr-Al-O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti-Cr-Al-O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  18. Shape-Memory Transformations of NiTi: Minimum-Energy Pathways...

    Office of Scientific and Technical Information (OSTI)

    Details In-Document Search This content will become publicly available on December 24, 2015 Title: Shape-Memory Transformations of NiTi: Minimum-Energy Pathways between Austenite,...

  19. Porous TiO2 microspheres with tunable properties for photocatalytic air purification Alberto Naldoni a,

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    2012 Keywords: TiO2 Nanostructured microsphere Silica Photocatalysis NOx a b s t r a c t The synthesis, photonic materials, batteries and membrane fuel cells, and photocatalysis [7­15]. Titanium dioxide

  20. Structural and magnetic phase transitions inEuTi1-xNbxO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Ling; Morris, James R.; Koehler, Michael R.; Dun, Zhiling; Zhou, Haidong; Yan, Jiaqiang; Mandrus, David; Keppens, Veerle

    2015-07-30

    We have investigated the structural and magnetic phase transitions in EuTi1-xNbxO3 (0 ? x ? 0.3) with synchrotron powder x-ray diffraction, resonant ultrasound spectroscopy, and magnetization measurements. Upon Nb doping, the Pm3¯m ? I4/mcm structural transition shifts to higher temperatures and the room temperature lattice parameter increases while the magnitude of the octahedral tilting decreases. In addition, Nb substitution for Ti destabilizes the antiferromagnetic ground state of the parent compound and long-range ferromagnetic order is observed in the samples with x ? 0.1. The structural transition in pure and doped compounds is marked by a dramatic steplike softening of themore »elastic moduli near TS , which resembles that of SrTiO3 and can be adequately modeled using the Landau free energy model employing the same coupling between strain and octahedral tilting order parameter as previously used to model SrTiO3.« less

  1. Low Spring Index NiTi Coil Actuators for Use in Active Compression Garments

    E-Print Network [OSTI]

    Holschuh, Bradley T.

    This paper describes the modeling, development, and testing of low spring index nickel titanium (NiTi) coil actuators designed for use in wearable compression garments, and presents a prototype tourniquet system using these ...

  2. A SUPERCOOLED MAGNETIC LIQUID STATE IN THE FRUSTRATED PYROCHLORE DY2TI2O7

    E-Print Network [OSTI]

    Davis, James C.

    -domain dynamics of toroidal Dy2Ti2O7 samples. We show that the EMF resulting from internal field variations can) project and for Peter Meyers on dark matter detection experiments, Ethan joined the group of Ali Yazdani

  3. Effect of Aging Heat Treatments on Ni52Ti48 Shape Memory Alloy 

    E-Print Network [OSTI]

    Akin, Erhan

    2011-10-21

    Ni-rich NiTi shape memory alloys (SMAs) are capable of attaining a wide range of transformation temperatures depending on the heat treatment conditions and superior thermo-mechanical cycling stability, which are desired for repeated solid...

  4. Microstructure and dielectric properties of textured SrTiO3 thin films

    E-Print Network [OSTI]

    Schmidt, S; Lu, J W; Keane, S P; Bregante, L D; Klenov, D O; Stemmer, Susanne

    2005-01-01

    2003). D. O. Klenov, T. R. Taylor and S. Stemmer, "SrTiO 3Symp. Proc. 401 : T. R. Taylor, P. J. Hansen, B. Acikel, N.2003). B. Acikel, T. R. Taylor, P. J. Hansen, J. S. Speck

  5. Low-Energy Electron Microscopy Studies of Interlayer Mass Transport Kinetics on TiN(111)

    E-Print Network [OSTI]

    Israeli, Navot

    on cutting tools, diffusion-barriers in microelectronic devices, corrosion- resistant layers on mechanicalCl-structure TiN and related transition-metal (TM) nitrides are widely used as hard wear- resistant coatings

  6. Adhesion strength of sputtered TiAlN-coated WC insert tool

    SciTech Connect (OSTI)

    Budi, Esmar; Razali, M. Mohd.; Nizam, A. R. Md.

    2013-09-09

    The adhesion strength of TiAlN coating that deposited by using DC magnetron sputtering on WC insert tool are studied. TiAlN coating are deposited on Tungsten Carbide (WC) insert tool by varying negatively substrate bias from 79 to 221 volt and nitrogen flow rate from 30 to 72 sccm. The adhesion strength are obtained by using Rockwell indentation test method with a Brale diamond at applied load of 60,100 and 150 kgf. The lateral diameter of indentation is plotted on three different applied loads and the adhesion strength of TiAlN coating was obtained from the curved slopes at 100 and 150 kgf. The lower curve slop indicated better adhesion strength. The results shows that the adhesion strength of sputterred TiAlN coating tend to increase as the negatively substrate bias and nitrogen flow rate are increased.

  7. The thermomechanical constitutive experimentation of NiTi shape memory alloy strips and rods 

    E-Print Network [OSTI]

    Howard, Stephen David

    1995-01-01

    The purpose of this thesis was to study the effect of temperature on the thermomechanical constitutive behavior of NiTi shape memory alloy strip and rod specimens. The stress-strain relationship is analyzed for isothermal monotonic tensile testing...

  8. Waterless TiO{sub 2} atomic layer deposition using titanium tetrachloride and titanium tetraisopropoxide

    SciTech Connect (OSTI)

    Anderson, Virginia R.; Cavanagh, Andrew S.; Abdulagatov, Aziz I.; Gibbs, Zachary M.; George, Steven M.

    2014-01-15

    The surface chemistry for TiO{sub 2} atomic layer deposition (ALD) typically utilizes water or other oxidants that can oxidize underlying substrates such as magnetic disks or semiconductors. To avoid this oxidation, waterless or oxidant-free surface chemistry can be used that involves titanium halides and titanium alkoxides. In this study, waterless TiO{sub 2} ALD was accomplished using titanium tetrachloride (TiCl{sub 4}) and titanium tetraisopropoxide (TTIP). In situ transmission Fourier transform infrared (FTIR) studies were employed to study the surface species and the reactions during waterless TiO{sub 2} ALD. At low temperatures between 125 and 225??°C, the FTIR absorbance spectra revealed that the isopropoxide species remained on the surface after TTIP exposures. The TiCl{sub 4} exposures then removed the isopropoxide species and deposited additional titanium species. At high temperatures between 250 and 300??°C, the isopropoxide species were converted to hydroxyl species by ?-hydride elimination. The observation of propene gaseous reaction product by quadrupole mass spectrometry (QMS) confirmed the ?-hydride elimination reaction pathway. The TiCl{sub 4} exposures then easily reacted with the hydroxyl species. QMS studies also observed the 2-chloropropane and HCl gaseous reaction products and monitored the self-limiting nature of the TTIP reaction. Additional studies examined the waterless TiO{sub 2} ALD growth at low and high temperature. Quartz crystal microbalance measurements observed growth rates of ?3?ng/cm{sup 2} at a low temperature of 150??°C. Much higher growth rates of ?15?ng/cm{sup 2} were measured at a higher temperature of 250??°C under similar reaction conditions. X-ray reflectivity analysis measured a growth rate of 0.55 ± 0.05?Å/cycle at 250??°C. X-ray photoelectron depth-profile studies showed that the TiO{sub 2} films contained low Cl concentrations <1 at. %. This waterless TiO{sub 2} ALD process using TiCl{sub 4} and TTIP should be valuable to prevent substrate oxidation during TiO{sub 2} ALD on oxygen-sensitive substrates.

  9. Interfacial dislocations in (111) oriented (Ba0.7Sr0.3)TiO3 films on SrTiO3 single crystal

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, Xuan; Yamada, Tomoaki; Lin, Ruoqian; Kamo, Takafumi; Funakubo, Hiroshi; Wu, Di; Xin, Huolin L.; Su, Dong

    2015-10-08

    In this study, we have investigated the interfacial structure of epitaxial (Ba,Sr)TiO3 films grown on (111)-oriented SrTiO3 single-crystal substrates using transmission electron microscopy (TEM) techniques. Compared with the (100) epitaxial perovskite films, we observe dominant dislocation half-loop with Burgers vectors of a comprised of a misfit dislocation along , and threading dislocations along or . The misfit dislocation with Burgers vector of a can dissociate into two ½ a partial dislocations and one stacking fault. We found the dislocation reactions occur not only between misfit dislocations, but also between threading dislocations. Via three-dimensional electron tomography, we retrievedmore »the configurations of the threading dislocation reactions. The reactions between threading dislocations lead to a more efficient strain relaxation than do the misfit dislocations alone in the near-interface region of the (111)-oriented (Ba0.7Sr0.3)TiO3 films.« less

  10. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-15

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached ?225?kV bias voltage while generating less than 100?pA of field emission (<10?pA) using a 40?mm cathode/anode gap, corresponding to field strength of 13.7?MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ?22.5 MV/m with field emission less than 100?pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  11. Preparation and properties of sliver and nitrogen co-doped TiO{sub 2} photocatalyst

    SciTech Connect (OSTI)

    Zhang, Ying; Zhang, Jin; Zhu, Zhongqi; Yan, Ningning; Liu, Qingju

    2013-11-15

    Graphical abstract: - Highlights: • The silver and nitrogen co-doped TiO{sub 2} photocatalysts were prepared and characterized. • The light absorption threshold wavelength of Ag–N–TiO{sub 2} is red-shifted to visible light. • The recombination of the photo-generated electrons and holes of Ag–N–TiO{sub 2} is inhibited. • The photocatalytic activity of Ag–N–TiO{sub 2} is remarkable improved. - Abstract: TiO{sub 2} photocatalysts co-doped with different content of Ag and N were prepared by sol–gel method combined with microwave chemical method. The samples were analyzed by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope (TEM), ultraviolet–visible diffuse reflectance spectrum (UV–vis) and photo-luminescence emission spectrum (PL). The photocatalytic activity was investigated by photocatalytic degradation of methylene blue (MB) under irradiation of fluorescent lamp. The results indicate that Ag and N co-doping can restrain the increase of grain size, broaden the absorption spectrum to visible light region, and inhibit the recombination of the photo-generated electron–hole pairs. Moreover, the photocatalytic activity of Ag–N–TiO{sub 2} in MB degradation is remarkable improved. The degradation rate of the sample with Ag:TiO{sub 2} = 0.05 at%, N:TiO{sub 2} = 18.50 wt% in 5 h is 93.44%, which is much higher than that of Degussa P25 (39.40%)

  12. Formation of various TiO2 nanostructures from electrochemically anodized titanium

    E-Print Network [OSTI]

    Lin, Zhiqun

    widely exploited for use in the areas of gas sensors,2­4 hydrogen generation,5,6 photo- catalysts,7,8 cell separation,9 dye sensitized solar cells (DSSC),10­19 and quantum dot20­26 sensitized solar cells TiO2 nanotube is perpendicular to the membrane surface.16,29­31 Since the as-prepared anodic TiO2

  13. Observation of Ti{sup 4+} ions in a high power impulse magnetron sputtering plasma

    SciTech Connect (OSTI)

    Andersson, Joakim; Anders, Andre; Ehiasarian, Arutiun P.

    2008-08-18

    Multiply charged titanium ions including Ti{sup 4+} were observed in high power impulse magnetron sputtering discharges. Mass/charge spectrometry was used to identify metal ion species. Quadruply charged titanium ions were identified by isotope-induced broadening at mass/charge 12. Due to their high potential energy, Ti{sup 4+} ions give a high yield of secondary electrons, which in turn are likely to be responsible for the generation of multiply charged states.

  14. [TiII] and [NiII] emission from the strontium filament of eta Carinae

    E-Print Network [OSTI]

    M. A. Bautista; H. Hartman; T. R. Gull; N. Smith; K. Lodders

    2006-06-12

    We study the nature of the [TiII] and [NiII] emission from the so-called strontium filament found in the ejecta of eta Carinae. To this purpose we employ multilevel models of the TiII and NiII systems which are used to investigate the physical condition of the filament and the excitation mechanisms of the observed lines. For the TiII ion, for which no atomic data was previously available, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. It is found that the observed spectrum is consistent with the lines being excited in a mostly neutral region with an electron density of the order of $10^7$ cm$^{-3}$ and a temperature around 6000 K. In analyzing three observations with different slit orientations recorded between March~2000 and November~2001 we find line ratios that change among various observations, in a way consistent with changes of up to an order of magnitude in the strength of the continuum radiation field. These changes result from different samplings of the extended filament, due to the different slit orientations used for each observation, and yield clues on the spatial extent and optical depth of the filament. The observed emission indicates a large Ti/Ni abundance ratio relative to solar abundances. It is suggested that the observed high Ti/Ni ratio in gas is caused by dust-gas fractionation processes and does not reflect the absolute Ti/Ni ratio in the ejecta of \\etacar. We study the condensation chemistry of Ti, Ni and Fe within the filament and suggest that the observed gas phase overabundance of Ti

  15. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, X.; Kattel, S.; Xiong, K.; Mudiyanselage, K.; Rykov, S.; Senanayake, S. D.; Rodriguez, J. A.; Liu, P.; Stacchiola, D. J.; Chen, J. G.

    2015-07-17

    Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.

  16. Phase transition and dielectric properties of nanograin BaTiO3 ceramic under high pressure

    E-Print Network [OSTI]

    Cao, Wenwu

    Phase transition and dielectric properties of nanograin BaTiO3 ceramic under high pressure Jinlong Temperature dependence of the dielectric constant of nanograin BaTiO3 ceramic has been investigated under decreases with at a rate of dTC/d =-40.0 1.1 K/GPa for coarse-grain ceramic and -34.3 1.4 K/GPa for ceramic

  17. Enhancing solar photocatalytic detoxification by adsorption of porphyrins onto TiO sub 2

    SciTech Connect (OSTI)

    Majumder, S.A.; Ondrias, M.R. . Dept. of Chemistry); Prairie, M.R.; Shelnutt, J.A. )

    1991-01-01

    Titanium dioxide (TiO{sub 2}) is a known photocatalyst for solar detoxification of water containing organic contaminants including PCB's and dioxins. Unfortunately, the UV light used by the photocatalyst only comprises about 4% of the strong spectrum. Metalloporphyrins strongly absorb in the visible and near infrared region. Using visible light, we have investigated Ni(II) uroporphyrin (NiUroP), Sn(IV)Cl{sub 2} uroporphyrin (SnUroP) and Sn(IV)Cl{sub 2} tetrakis(p-carboxyphenyl) porphyrin (SnTCPP) as possible enhancers of destruction of a model organic compound, salicylic acid (SA), by means of photosensitization of colloidal TiO{sub 2} particles. All three porphyrins are found to adsorb reversibly onto the colloidal TiO{sub 2} upon variation of pH. Adsorption of porphyrins results in the increased colloidal stability of fine TiO{sub 2} particles in the pH range 5--8. While NiUroP on TiO{sub 2} does not show any enhancement of photodestruction, the adsorption of SnUroP increases the destruction rate compared to that of the bare TiO{sub 2} surface. The effect of ambient oxygen on the observed photolability of the Sn porphyrins and enhancement of photodestruction of SA was also investigated. SnTCPP does not photodecompose upon illumination either in the presence or absence of TiO{sub 2}, but neither does it bind to the photocatalyst at pH 6. At pH 4.5 it adsorbs onto TiO{sub 2} but it also photodecompose at this pH. We are attempting to stabilize the adsorbed porphyrins by adding suitable peripheral substituents onto the porphyrin macrocycle. 27 refs., 6 figs.

  18. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ~22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  19. Multiferroic BaTiO3-CoFe2O4 Nanostructures

    E-Print Network [OSTI]

    Ramesh, R.

    an additional degree of freedom in the design of actuators, transducers, and storage devices. HoweverMultiferroic BaTiO3-CoFe2O4 Nanostructures H. Zheng,1 J. Wang,1 S. E. Lofland,3 Z. Ma,1 L. Mohaddes and magnetic order param- eters in a nanostructured BaTiO3-CoFe2O4 ferroelectromagnet. This facilitates

  20. Production of Ni-Cr-Ti-natural fibres composite and investigation of mechanical properties

    SciTech Connect (OSTI)

    Pesmen, G.; Erol, A.

    2015-03-30

    Intermetallic materials such as Ni{sub 2}Ti, Cr{sub 2}Ti are among advanced technology materials that have outstanding mechanical and physical properties for high temperature applications. Especially creep resistance, low density and high hardness properties stand out in such intermetallics. The microstructure, mechanical properties of (%50Ni-%48Cr-%2Ti)-%10Naturel Fibres and (%64Ni-%32Cr-%4Ti)-%10Naturel Fibres powders were investigated using specimens produced by tube furnace sintering at 1000-1200-1400°C temperature. A composite consisting of ternary additions, a metallic phase, Ti,Cr and Ni have been prepared under Ar shroud and then tube furnace sintered. XRD, SEM (Scanning Electron Microscope), were investigated to characterize the properties of the specimens. Experimental results carried out for composition (%64Ni-%32Cr-%4Ti)-%10Naturel at 1400°C suggest that the best properties as 112.09HV and 5,422g/cm{sup 3} density were obtained at 1400°C.

  1. ALMA observations of TiO$_2$ around VY Canis Majoris

    E-Print Network [OSTI]

    De Beck, E; Muller, S; Black, J H; O'Gorman, E; Richards, A M S; Baudry, A; Maercker, M; Decin, L; Humphreys, E M

    2015-01-01

    Titanium dioxide, TiO$_2$, is a refractory species that could play a crucial role in the dust-condensation sequence around oxygen-rich evolved stars. To date, gas phase TiO$_2$ has been detected only in the complex environment of the red supergiant VY CMa. We aim to constrain the distribution and excitation of TiO$_2$ around VY CMa in order to clarify its role in dust formation. We analyse spectra and channel maps for TiO$_2$ extracted from ALMA science verification data. We detect 15 transitions of TiO$_2$, and spatially resolve the emission for the first time. The maps demonstrate a highly clumpy, anisotropic outflow in which the TiO$_2$ emission likely traces gas exposed to the stellar radiation field. A roughly east-west oriented, accelerating bipolar-like structure is found, of which the blue component runs into and breaks up around a solid continuum component. A distinct tail to the south-west is seen for some transitions, consistent with features seen in the optical and near-infrared. We find that a si...

  2. Composite WO3/TiO2 nanostructures for high electrochromic activity.

    SciTech Connect (OSTI)

    Reyes, Karla Rosa; Stephens, Zachary Dan.; Robinson, David B.

    2013-05-01

    A composite material consisting of TiO2 nanotubes (NTs) with WO3 electrodeposited homogeneously on its surface has been fabricated, detached from its substrate, and attached to a fluorine-doped tin oxide film on glass for application to electrochromic (EC) reactions. A paste of TiO2 made from commercially available TiO2 nanoparticles creates an interface for the TiO2 NT film to attach to the FTO glass, which is conductive and does not cause solution-phase ions in an electrolyte to bind irreversibly with the material. The effect of NT length on the current density and the EC contrast of the material were studied. The EC redox reaction seen in this material is diffusion- limited, having relatively fast reaction rates at the electrode surface. The composite WO3/TiO2 nanostructures showed higher ion storage capacity, better stability, enhanced EC contrast and longer memory time compared with the pure WO3 and TiO2.

  3. WO3/TiO2 nanotube photoanodes for solar water splitting with simultaneous wastewater treatment.

    SciTech Connect (OSTI)

    Reyes, Karla Rosa; Robinson, David B.

    2013-05-01

    Nanostructured WO3/TiO2 nanotubes with properties that enhance solar photoconversion reactions were developed, characterized and tested. The TiO2 nanotubes were prepared by anodization of Ti foil, and WO3 was electrodeposited on top of the nanotubes. SEM images show that these materials have the same ordered structure as TiO2 nanotubes, with an external nanostructured WO3 layer. Diffuse reflectance spectra showed an increase in the visible absorption relative to bare TiO2 nanotubes, and in the UV absorption relative to bare WO3 films. Incident simulated solar photon-to-current efficiency increased from 30% (for bare WO3) to 50% (for WO3/TiO2 composites). With the addition of diverse organic pollutants, the photocurrent densities exhibited more than a 5-fold increase. Chemical oxygen demand measurements showed the simultaneous photodegradation of organic pollutants. The results of this work indicate that the unique structure and composition of these composite materials enhance the charge carrier transport and optical properties compared with the parent materials.

  4. Deposition and characterization of TiZrV-Pd thin films by dc magnetron sputtering

    E-Print Network [OSTI]

    Wang, Jie; Xu, Yan-Hui; Wei, Wei; Fan, Le; Pei, Xiang-Tao; Hong, Yuan-Zhi; Wang, Yong

    2015-01-01

    TiZrV film is mainly applied in the ultra-high vacuum pipe of storage ring. Thin film coatings of palladium which was added onto the TiZrV film to increase the service life of nonevaporable getters and enhance pumping speed for H2, was deposited on the inner face of stainless steel pipes by dc magnetron sputtering using argon gas as the sputtering gas. The TiZrV-Pd film properties were investigated by atomic force microscope (AFM), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and X-Ray Diffraction (XRD). The grain size of TiZrV and Pd film were about 0.42~1.3 nm and 8.5~18.25 nm respectively. It was found that the roughness of TiZrV films was small, about 2~4 nm, for Pd film it is large, about 17~19 nm. PP At. % of Pd in TiZrV/Pd films varied from 86.84 to 87.56 according to the XPS test results.

  5. Enhancement of solar photocatalytic detoxification by adsorption of porphyrins onto TiO sub 2

    SciTech Connect (OSTI)

    Majumder, S.A.; Ondrias, M.R. . Dept. of Chemistry); Prairie, M.R. ); Shelnutt, J.A. . Dept. of Chemistry Sandia National Labs., Albuquerque, NM )

    1991-01-01

    Titanium dioxide (TiO{sub 2}) is a photocatalyst for solar detoxification of water containing organic contaminants such as solvents, PCB's, dioxins, pesticides, and dyes. Unfortunately, the ultraviolet (UV) energy used by TiO{sub 2} ({lambda}<400 nm) only comprises about 4% of the solar spectrum. One way of enhancing the efficiency of solar detoxification technologies is to utilize a larger portion of the solar spectrum to initiate the Tio{sub 2}- catalyzed detoxification chemistry. Metalloporphyrins strongly absorb visible and near infrared radiation. By utilization of a process called photosensitization, adsorption of these dyes onto TiO{sub 2} can enable a much broader portion of the solar spectrum to be used. Photosensitization relies upon the ability of the dye molecule to absorb more of the solar energy than bare TiO{sub 2} and to interact electronically with the TiO{sub 2} surface in such a way as to initiate TiO{sub 2}-based redox photochemistry using the dye-absorbed energy. 16 refs., 7 figs.

  6. A Comparative Study of the Water Gas Shift Reaction Over Platinum Catalysts Supported on CeO2, TiO2 and Ce-Modified TiO2

    SciTech Connect (OSTI)

    Gonzalez, I.; Navarro, R; Wen, W; Marinkovic, N; Rodriguez, J; Rosa, F; Fierro, J

    2010-01-01

    WGS reaction has been investigated on catalysts based on platinum supported over CeO{sub 2}, TiO{sub 2} and Ce-modified TiO{sub 2}. XPS and XANES analyses performed on calcined catalysts revealed a close contact between Pt precursors and cerium species on CeO{sub 2} and Ce-modified TiO{sub 2} supports. TPR results corroborate the intimate contact between Pt and cerium entities in the Pt/Ce-TiO{sub 2} catalyst that facilitates the reducibility of the support at low temperatures while the Ce-O-Ti surface interactions established in the Ce-modified TiO{sub 2} support decreases the reduction of TiO{sub 2} at high temperature. The changes in the support reducibility leads to significant differences in the WGS activity of the studied catalysts. Pt supported on Ce-modified TiO{sub 2} support exhibits better activity than those corresponding to individual CeO{sub 2} and TiO{sub 2}-supported catalysts. Additionally, the Ce-TiO{sub 2}-supported catalyst displays better stability at reaction temperatures higher than 573 K that observed on pure TiO{sub 2}-supported counterpart. Activity measurements, when coupled with the physicochemical characterization of catalysts suggest that the modifications in the surface reducibility of the support play an essential role in the enhancement of activity and stability observed when Pt is supported on the Ce-modified TiO{sub 2} substrate.

  7. In vitro biocompatibility study of nano TiO2 materials , Y.D. Wang2,b

    E-Print Network [OSTI]

    Zheng, Yufeng

    Company, LTD. TiO2 nanotube, with mean diameter 20nm, was provided by Department of Physics, HongkongIn vitro biocompatibility study of nano TiO2 materials W. Han1, a , Y.D. Wang2,b and Y.F. Zheng3,c yfzheng@pku.edu.cn Keywords: nano TiO2, in vitro, biocompatibility, cell proliferation, cell apoptosis

  8. Role of Benzyl Alcohol in Controlling the Growth of TiO2 on Carbon Nanotubes David J. Cooke,*,

    E-Print Network [OSTI]

    Elliott, James

    Role of Benzyl Alcohol in Controlling the Growth of TiO2 on Carbon Nanotubes David J. Cooke) in the morphological control of the growth of TiO2 on carbon nanotubes (CNTs) by the consideration of two model systems of thin-film TiO2.14,15 Kongkanand et al. reported that combining single-wall carbon nanotubes (SWCNTs

  9. nh Gi Thit Hi Ti Nguyn Thin Nhin ca V Trn Du Deepwater Horizon Cc D n Khu Vc

    E-Print Network [OSTI]

    Sinh Vnh St. Joseph thuc Qun Gulf, và có th thêm c khu Bo Tn Thy Sinh Cng Alligator thuc Qun Franklin hi ti ba Khu Bo Tn Thy Sinh (Vnh St. Joseph, Cng Alligator, và St. Andrews). Bc tip theo s bao gm vic bin báo mang tính giáo dc và cp các t ri ti các li h tàu ti Vnh St. Joseph, Cng Alligator, and Vnh St

  10. Comparison of precipitate behaviors in ultra-low carbon, titanium-stabilized interstitial free steel sheets under different annealing processes

    SciTech Connect (OSTI)

    Shi, J.; Wang, X.

    1999-12-01

    Ultra-low carbon, titanium-stabilized interstitial free (ULC Ti-IF) steel sheets are widely used in the automobile industry because of excellent deep drawability. The annealing process is critical to their final property, and there are two different annealing processes used in industrial production of interstitial free (IF) steel sheets, namely batch annealing and continuous annealing. In this study, precipitation behaviors of titanium IF steels, that is, TiN, TiS, Ti{sub 4}(CS){sub 2}, and TiC, the size and dispersion of TiN, TiS, and Ti{sub 4}(CS){sub 2} remained almost unchanged after either annealing process. Conversely, the average size of a TiC particle increased substantially after both annealing processes, while TiC after continuous annealing was larger than that after batch annealing due to the higher heating temperature of continuous annealing. Two new particles, FeTiP and (Ti, Mn)S, were also observed in the batch annealing process but not in continuous annealing. The structure of FeTiP and (Ti, Mn)S were studied, and furthermore the evolution of FeTiP precipitation was found to be closely related to recrystallization in batch annealing. Finally, the interrelation among processing parameters, precipitation behaviors, and final property was studied.

  11. Advancements in Ti Alloy Powder Production by Close-Coupled Gas Atomization

    SciTech Connect (OSTI)

    Heidloff, Andy; Rieken, Joel; Anderson, Iver; Byrd, David

    2011-04-01

    As the technology for titanium metal injection molding (Ti-MIM) becomes more readily available, efficient Ti alloy fine powder production methods are required. An update on a novel close-coupled gas atomization system has been given. Unique features of the melting apparatus are shown to have measurable effects on the efficiency and ability to fully melt within the induction skull melting system (ISM). The means to initiate the melt flow were also found to be dependent on melt apparatus. Starting oxygen contents of atomization feedstock are suggested based on oxygen pick up during the atomization and MIM processes and compared to a new ASTM specification. Forming of titanium by metal injection molding (Ti-MIM) has been extensively studied with regards to binders, particle shape, and size distribution and suitable de-binding methods have been discovered. As a result, the visibility of Ti-MIM has steadily increased as reviews of technology, acceptability, and availability have been released. In addition, new ASTM specification ASTM F2885-11 for Ti-MIM for biomedical implants was released in early 2011. As the general acceptance of Ti-MIM as a viable fabrication route increases, demand for economical production of high quality Ti alloy powder for the preparation of Ti-MIM feedstock correspondingly increases. The production of spherical powders from the liquid state has required extensive pre-processing into different shapes thereby increasing costs. This has prompted examination of Ti-MIM with non-spherical particle shape. These particles are produced by the hydride/de-hydride process and are equi-axed but fragmented and angular which is less than ideal. Current prices for MIM quality titanium powder range from $40-$220/kg. While it is ideal for the MIM process to utilize spherical powders within the size range of 0.5-20 {mu}m, titanium's high affinity for oxygen to date has prohibited the use of this powder size range. In order to meet oxygen requirements the top size cut has traditionally been 45 {mu}m, and in some instances a bottom cut at +5 {mu}m is made to remove ultra-fine particles and reduce oxygen content. Predictably, use of irregular shaped or larger particle feedstock powder can reduce part quality as sintering shrinkage and part detail suffer. Thus, widespread production and technological use of Ti-MIM is limited due in large part to Ti alloy feedstock cost and availability, not MIM processing capability. Lower cost feedstock of fine, spherical Ti alloy powder with sufficient purity must be available in order to fully utilize the advantages of the Ti-MIM processing route allowing expansion of the market to small complex Ti parts in many high volume applications.

  12. Structure of epitaxial (Fe,N) codoped rutile TiO2 thin films by x-ray absorption

    SciTech Connect (OSTI)

    Kaspar, Tiffany C.; Ney, A.; Mangham, Andrew N.; Heald, Steve M.; Joly, Yves; Ney, V.; Wilhelm, F.; Rogalev, A.; Yakou, Flora; Chambers, Scott A.

    2012-07-23

    Homoepitaxial thin films of Fe:TiO2 and (Fe,N):TiO2 were deposited on rutile(110) by molecular beam epitaxy. X-ray absorption near edge spectroscopy (XANES) spectra were collected at the Ti L-edge, Fe L-edge, O K-edge, N K-edge, and Ti K-edge. No evidence of structural disorder associated with a high concentration of oxygen vacancies is observed. Substitution of Fe for Ti could not be confirmed, although secondary phase Fe2O3 and metallic Fe can be ruled out. The similarity of the N K-edge spectra to O, and the presence of a strong x-ray linear dichroism (XLD) signal for the N K-edge, indicates that N is substitutional for O in the rutile lattice, and is not present as a secondary phase such as TiN. Simulations of the XANES spectra qualitatively confirm substitution, although N appears to be present in more than one local environment. Neither Fe:TiO2 nor (Fe,N):TiO2 exhibit intrinsic room temperature ferromagnetism, despite the presence of mixed valence Fe(II)/Fe(III) in the reduced (Fe,N):TiO2 film.

  13. Synthesis and characterization of CdS doped TiO{sub 2} nanocrystalline powder: A spectroscopic study

    SciTech Connect (OSTI)

    Thakur, Priya; Chadha, Ridhima; Biswas, Nandita; Sarkar, Sisir K.; Mukherjee, Tulsi; Joshi, Satyawati S.; Kapoor, Sudhir

    2012-07-15

    Graphical abstract: Raman spectra of TiO{sub 2} sample doped with 50% CdS and annealed at 600 °C. Highlights: ? Transformation from anatase to rutile is prohibited in doped TiO{sub 2}. ? FTIR study indicates that TiO{sub 2} lattice has been modified in the presence of CdS. ? Raman spectroscopy is found to be more sensitive as compared to XRD. -- Abstract: This report aimed to study the effect of CdS doping in TiO{sub 2} on the phase transformation of TiO{sub 2} from anatase to rutile using X-ray diffraction (XRD) and Raman spectroscopy. CdS-doped TiO{sub 2} nanocomposites have been prepared and characterized using Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). We have observed that contrary to bare TiO{sub 2}, phase transformation of TiO{sub 2} from anatase to rutile is hindered when doped with CdS at high temperature. Raman spectroscopy is found to be more sensitive for detection of the surface of TiO{sub 2} as compared to XRD.

  14. Reactivity Screening of Anatase TiO2 Nanotube Arrays and Anatase Thin Films: A Surface Chemistry Point of View

    SciTech Connect (OSTI)

    Funk, S.; Hokkanen, B.; Nurkic, T.; Goering, J.; Kadossov, E.; Burghaus, Uwe; Ghicov, A.; Schmuki, P.; Yu, Zhongqing; Thevuthasan, Suntharampillai; Saraf, Laxmikant V.

    2008-09-19

    As a reactivity screening we collected thermal desorption spectroscopy (TDS) data of iso-butane, O2, CO2, and CO adsorbed on ordered TiO2 nanotube (TiNTs) arrays. As a reference system iso-butane adsorption on an anatase TiO2 thin film has been considered as well. The as-grown TiNTs are vertically aligned and amorphous. Polycrystalline (poly.) anatase or poly. anatase/rutile mixed nanotubes are formed by annealing confirmed by x-ray diffraction (XRD) and scanning electron microscopy (SEM). The anatase thin film was grown on SrTiO3(001) and characterized by XRD and atomic force microscopy (AFM). Surprisingly, oxygen distinctly interacts with the TiNTs whereas this process is not observed on fully oxidized single crystal rutile TiO2(110). Desorption temperatures of 110-150 K and 100-120 K were observed for CO2 and CO, respectively, on the TiNTs. Variations in the binding energies of the alkanes on TiNTs and anatase thin films also were present, i.e., a structure-activity relationship (SAR) is evident.

  15. Efficiency of clay-TiO2 nanocomposites on the photocatalytic elimination of a model hydrophobic air pollutant

    E-Print Network [OSTI]

    Kibanova, Daria

    2010-01-01

    of semiconductor photocatalysis Chem. Rev. 1995, 95, 69-effluents by TiO 2 photocatalysis Catalysis Today 2000, 63,clay on adsorption and photocatalysis of gaseous molecules

  16. Three-dimensional multimodal imaging and analysis of biphasic microstructure in a Ti-Ni-Sn thermoelectric material

    E-Print Network [OSTI]

    Douglas, Jason E; Echlin, McLean P; Lenthe, William C; Seshadri, Ram; Pollock, Tresa M

    2015-01-01

    microstructure in a Ti–Ni–Sn thermoelectric material Jasonsolid-state option. Thermoelectric materials, which convertin biphasic hH- based thermoelectric materials. This work

  17. Fatigue crack growth behavior of Ti-1100 at elevated temperature

    SciTech Connect (OSTI)

    Maxwell, D.C.; Nicholas, T.

    1995-12-31

    Effects of temperature, frequency, and cycles with superimposed hold times are evaluated in Ti-1100 in order to study the complex creep-fatigue-environment interactions in this material. Crack growth rate tests conducted at cyclic loading frequency of 1.0 Hz show that raising the temperature from 593 to 650 C has only a slightly detrimental effect on crack growth rate, although these temperatures produce growth rates significantly higher than at room temperature. From constant {Delta}K tests, the effects of temperature at constant frequency show a minimum crack growth rate at 250 C. From the minimum crack growth rate at 250 C, the crack growth rate increases linearly with temperature. Increases in frequency at constant temperatures of 593 and 650 C produce a continuous decrease in growth rate in going from 0.001 to 1.0 Hz, although the behavior is primarily cycle dependent in this region. Tests at 1.0 Hz with superimposed hold times from 1 to 1,000 s are used to evaluate creep-fatigue-environment interactions. Hold times at maximum load are found to initially decrease and then increase the cyclic crack growth rate with increasing duration. This is attributed to crack-tip blunting during short hold times and environmental degradation at long hold times. Hold times at minimum load show no change in growth rates, indicating that there is no net environmental degradation to the bulk material beyond that experienced during the baseline 1 Hz cycling.

  18. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Peker, Atakan (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1997-01-01

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.c wherein x is from 0.1 to 0.3, y.cndot.c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b.

  19. Adsorption, Desorption, and Dissociation of Benzene on TiO2(110) and Pd/TiO2(110)

    SciTech Connect (OSTI)

    Zhou, Jing; Dag, Sefa; Senanayake, Sanjaya D; Hathorn, Bryan C; Kalinin, Sergei V; Meunier, Vincent; Mullins, David R; Overbury, Steven {Steve} H; Baddorf, Arthur P

    2006-01-01

    Adsorption and reaction of benzene molecules on clean TiO{sub 2}(110) and on TiO{sub 2}(110) with deposited Pd nanoparticles are investigated using a combination of scanning tunneling microscopy (STM), temperature-programmed desorption, and first-principles calculations. Above {approx}50 K, the one-dimensional motion of benzene between bridging oxygen rows is shown to be too fast for STM imaging. At 40 K benzene molecules form chains on top of titanium rows, with calculations indicating every other benzene is rotated 30{sup o}. Both experimental and theoretical studies find no dissociative reactivity of benzene on the clean TiO{sub 2}(110) surface, due to little hybridization between TiO{sub 2} and benzene electronic states. After deposition of Pd nanoparticles, molecular benzene is observed with STM both on the substrate and adjacent to metallic particles. Upon heating to 800 K, benzene fully breaks down into its atomic constituents in a multistep decomposition process.

  20. Formation of single-domain anatase TiO2,,001...-,,14... islands on SrTiO3,,001... after thermal annealing

    E-Print Network [OSTI]

    Castell, Martin

    studied as a promising material for applications in sensors, photocataly- sis, solar energy conversion annealing Fabien Sillya) and Martin R. Castellb) Department of Materials, University of Oxford, Parks Road these materials are strongly dependent on the nature of the TiO2 surfaces and its nano- structures

  1. nh gi Tn tht Ti nguyn Thin nhin Trn du Deepwater Horizon D n phc hi C bin ti B Bin Quc Gia

    E-Print Network [OSTI]

    Horizon. Sau s c tràn du Deepwater Horizon, mt lng áng k du t n bãi bin dc theo Florida Panhandle. Trong vi C rùa( Thallasiumtestudium ) , loài ph bin nht ti thm c bin GUIS 3 ) t các im quan trc o lng và

  2. Heterostructured Ceramic Powders for Photocatalytic Hydrogen Production: Nanostructured TiO2 Shells Surrounding Microcrystalline (Ba,Sr)TiO3 Cores

    E-Print Network [OSTI]

    Rohrer, Gregory S.

    Heterostructured Ceramic Powders for Photocatalytic Hydrogen Production: Nanostructured TiO2 Shells areas, but had the highest rates of photochemical hydrogen production from water/methanol solu- tions coatings. I. Introduction INTEREST in photochemical hydrogen production began sev- eral decades ago upon

  3. Ferroelectric performances and crystal structures of (Pb, La)(Zr, Ti, Nb)O{sub 3}

    SciTech Connect (OSTI)

    Kitamura, Naoto [Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 (Japan); Division of Ecosystem Research, Research Institute for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 (Japan); Mizoguchi, Takuma [Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 (Japan); Itoh, Takanori [AGC Seimi Chemical Co., Ltd., 3-2-10 Chigasaki-City, Kanagawa 253-8585 (Japan); Idemoto, Yasushi, E-mail: idemoto@rs.noda.tus.ac.jp [Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 (Japan); Division of Ecosystem Research, Research Institute for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 (Japan)

    2014-02-15

    In this study, we focused on Nb and La substituted Pb(Zr, Ti)O{sub 3}: i.e., (Pb, La)(Zr, Ti, Nb)O{sub 3}. As for the samples, dependences of ferroelectric properties on La and Nb compositions were examined. In addition, the crystal structures were analyzed by the Rietveld method, and then a relationship between the metal compositions and the crystal structures were discussed. From P–E hysteresis loop measurements, it was found that the remanant polarization of Pb(Zr, Ti)O{sub 3} was increased by both the La and Nb substitutions although the heavy substitution of La had an undesirable effect. It was also indicated that the Curie temperature decreased with increasing La content. The Rietveld analysis using synchrotron X-ray diffraction patterns demonstrated that the structure distortion was relaxed by the La and Nb substitutions. Such a change in the crystals was well consistent with the harmful effects on the Curie temperature and the remanent polarization by the heavy La substitution. - Graphical abstract: Rietveld refinement pattern of 2 mol% PbSiO{sub 3}-added Pb{sub 0.95}La{sub 0.05}Zr{sub 0.50}Ti{sub 0.45}Nb{sub 0.05}O{sub 3} (synchrotron X-ray diffraction). Display Omitted - Highlights: • (Pb,La)(Zr,Ti,Nb)O{sub 3} were successfully synthesized. • Remanant polarization of Pb(Zr,Ti)O{sub 3} was improved by substitutions of La and Nb. • Crystal structures of (Pb,La)(Zr,Ti,Nb)O{sub 3} were refined and the distortions were estimated.

  4. Application for Department CalNet Deputy

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    is to the left of the department name for each employee in the directory. Department Name department codes and Department names, go to http://directory.berkeley.edu, and find and click on the record for the employee you wish to have deputized. Their UID is to the right of their name. The 5 digit Processing unit

  5. Cal/OSHA process safety standard update

    SciTech Connect (OSTI)

    Pourmehraban, I.

    1995-12-31

    Process Safety Management (PSM) regulation applies mainly to chemical and oil companies, plus other industries such as food processing, and paper production. It covers plants that deal with any of about 130 toxic chemicals in quantities above thresholds limits in Appendix A of PSM standard or flammable liquids and gases in quantities greater than 10,000 pounds. The State Consultation PSM teams (North and South) use a detailed audit checklist featuring above elements for audit of facilities requesting PSM assistance. The audit focuses on three generic activities: records, onsite conditions, and interviews. Records include written programs that outline the requirements and documentation of completion. Onsite conditions are implementation of activities specified in written programs. Interviews are for evaluation of transferred information to the workers that are already developed in written programs and training programs.

  6. Case study of CalSTRS headquarters

    E-Print Network [OSTI]

    Goins, John; Moezzi, Mithra

    2011-01-01

    Energy Management System building. Building Energy Management System Commissioning onthe building energy management system was completed during

  7. Case study of CalSTRS headquarters

    E-Print Network [OSTI]

    Goins, John; Moezzi, Mithra

    2011-01-01

    Existing Building Operations and Maintenance) certification.a building operations and maintenance survey administered toCBE's web-based Operations and Maintenance survey. This

  8. December 8, 2011 TO: CALS Department Chairs

    E-Print Network [OSTI]

    or international), teaching assessments, program pamphlets, etc. can be included. Deadline: Please submit six

  9. CalEnergy Generation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine:Kansas: Energy ResourcesParish, Louisiana:Pub. Res.Code11720

  10. CalCars | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County, California: Energy ResourcesCRED: A New Model

  11. CalEnergy Generation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County, California: Energy ResourcesCRED: A New Model(Redirected from

  12. Thermodynamic and kinetic analyses of the CO2 chemisorption mechanism on Na2TiO3: Experimental and theoretical evidences

    SciTech Connect (OSTI)

    Duan, Yuhua [U.S. DOE

    2014-01-01

    ABSTRACT: Sodium metatitanate (Na2TiO3) was successfully synthesized via a solid-state reaction. The Na2TiO3 structure and microstructure were characterized using X-ray diffraction, scanning and transmission electron microscopy, and N2 adsorption. Then, the CO2 chemisorption mechanism on Na2TiO3 was systematically analyzed to determine the influence of temperature. The CO2 chemisorption capacity of Na2TiO3 was evaluated both dynamically and isothermally, and the products were reanalyzed to elucidate the Na2TiO3?CO2 reaction mechanism. Different chemical species (Na2CO3, Na2O, and Na4Ti5O12 or Na16Ti10O28) were identified during the CO2 capture process in Na2TiO3. In addition, some CO2 chemisorption kinetic parameters were determined. The ?H? was found to be 140.9 kJ/mol, to the Na2TiO3?CO2 system, between 600 and 780 °C. Results evidenced that CO2 chemisorption on Na2TiO3 highly depends on the reaction temperature. Furthermore, the experiments were theoretically supported by different thermodynamic calculations. The calculated thermodynamic properties of CO2 capture reactions by (Na2TiO3, Na4Ti5O12, and Na16Ti10O28) sodium titanates were fully investigated.

  13. Microstructure and tribological performance of nanocomposite Ti-Si-C-N coatings deposited using hexamethyldisilazane precursor

    SciTech Connect (OSTI)

    Wei Ronghua; Rincon, Christopher; Langa, Edward; Yang Qi

    2010-09-15

    Thick nanocomposite Ti-Si-C-N coatings (20-30 {mu}m) were deposited on Ti-6Al-4V substrate by magnetron sputtering of Ti in a gas mixture of Ar, N{sub 2}, and hexamethyldisilazane (HMDSN) under various deposition conditions. Microstructure and composition of the coatings were studied using scanning electron microscopy, x-ray diffraction, and energy dispersive x-ray spectroscopy, while the mechanical and tribological properties of these coatings were studied using Rc indentation, and micro- and nanoindentations, solid particle erosion testing, and ball-on-disk wear testing. It has been observed that the Si concentration of these coatings is varied from 0% (TiN) to 15% (Ti-Si-C-N), while the structure of these coatings is similar to the nanocomposite Ti-Si-N coatings and consists of nanocrystalline B1 structured Ti(C,N) in an amorphous matrix of SiC{sub x}N{sub y} with the grain size of 5->100 nm, depending on the coating preparation process. These coatings exhibit excellent adhesion when subjected to Rc indentation tests. The microhardness of these coatings varies from 1200 to 3400 HV25, while the nanohardness varies from 10 to 26 GPa. Both the microhardness and nanohardness are slightly lower than those of similar coatings prepared using trimethylsilane. However, the erosion test using a microsand erosion tester at both 30 deg. and 90 deg. incident angles shows that these coatings have very high erosion resistance and up to a few hundred times of improvement has been observed. These coatings also exhibit very high resistance to sliding wear with a low coefficient of friction of about 0.2 in dry sliding. There are a few advantages of using the HMDSN precursor to prepare the Ti-Si-C-N coatings over conventional magnetron sputtered deposition of Ti-Si-N coatings including composition uniformity, precursor handling safety, and high deposition rate. The coatings can be applied to protect gas turbine compressor blades from solid particle erosion and steam turbine blades from liquid droplet erosion, as well as other mechanical components that experience severe abrasion. These coatings may also be used in areas where both high wear resistance and low friction are required.

  14. Dielectric and photocatalytic properties of sulfur doped TiO{sub 2} nanoparticles prepared by ball milling

    SciTech Connect (OSTI)

    Jalalah, Mohammed [Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box 1988, Najran, 11001 (Saudi Arabia); Electrical Engineering Department, College of Engineering, Najran University, P.O. Box 1988, Najran, 11001 (Saudi Arabia); Faisal, M. [Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box 1988, Najran, 11001 (Saudi Arabia); Bouzid, Houcine [Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box 1988, Najran, 11001 (Saudi Arabia); Department of Physics, Faculty of Sciences and Arts, Najran University, P.O. Box 1988, Najran, 11001 (Saudi Arabia); Ismail, Adel A., E-mail: adelali141@yahoo.com [Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box 1988, Najran, 11001 (Saudi Arabia); Nanostructured and Nanotechnology Materials Division, Central Metallurgical R and D Institute, CMRDI, P.O. Box 87, Helwan, 11421, Cairo (Egypt); Chemistry Department, Science and Art at Sharurah, Najran University (Saudi Arabia); Al-Sayari, Saleh A. [Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box 1988, Najran, 11001 (Saudi Arabia); Chemistry Department, Science and Art at Sharurah, Najran University (Saudi Arabia)

    2013-09-01

    Graphical abstract: - Highlights: • Designing of visible light responsive photocatalyst utilizing ball milling. • Sulphur used as dopant in commercial TiO{sub 2} P25 at different atomic percentage. • S doping resulted in an intense increase in absorption in the visible light region. • Newly design photocatalyst exhibited excellent photocatalytic performance. • 0.11 at.% S-doped TiO{sub 2} shows 3-times higher activity than that of TiO{sub 2} P25. - Abstract: Sulfur (S) doped commercial TiO{sub 2} P-25 has been achieved by changing the amount of thiourea using ball milling technique. The results of XRD clearly reveal biphasial anatase and rutile mixtures for all prepared samples and doping of S does not change the morphology of the TiO{sub 2}. The optical absorption edge of S-doped TiO{sub 2} was red shifted with indirect bandgap energy of 2.8 eV. The dielectric studies confirm that the dielectric constant of TiO{sub 2} increases after doping, however it becomes more conductive. Newly designed S-doped TiO{sub 2} photocatalysts exhibited excellent photocatalytic performance for the degradation of methylene blue (MB) under visible light. The overall photocatalytic activity of 0.11 at.% S-doped TiO{sub 2} was significantly 3-times higher than that of commercial TiO{sub 2} P-25 and complete degradation of MB has taken place after 90 min of irradiation under visible light while only 35% dye degraded when the reaction has been carried out in the presence of undoped TiO{sub 2}.

  15. Study of new states in visible light active W, N co-doped TiO{sub 2} photo catalyst

    SciTech Connect (OSTI)

    Sajjad, Ahmed Khan Leghari; Shamaila, Sajjad; Zhang, Jinlong

    2012-11-15

    Highlights: ? Visible light efficient W, N co-doped TiO{sub 2} photo catalysts are prepared by sol–gel. ? Oxygen vacancies are detected in the form of new linkages as N-Ti-O, N-W-O, Ti-O-N and W-O-N. ? W, N co-doped titania has new energy states which narrows the band gap effectively. ? Oxygen vacancies are proved to be the cause for high photo catalytic activity. ? W and N co-doping plays the major role to make the composite thermally stable. -- Abstract: The visible light efficient W, N co-doped TiO{sub 2} photo catalysts are prepared by sol–gel method. New linkages of N, W and O are formed as N-Ti-O, N-W-O, Ti-O-N and W-O-N. Electron paramagnetic resonance illustrates the presence of oxygen vacancies in W, N co-doped TiO{sub 2} acting as trapping agencies for electrons to produce active species. X-ray photoelectron spectroscopy confirms the presence of new energy states. New linkages and oxygen vacancies are proved to be the main cause for the improved photo catalytic performances. W, N co-doped TiO{sub 2} has new energy states which narrow the band gap effectively. W, N co-doped TiO{sub 2} is thermally stable and retains its anatase phase up to 900 °C. 4.5% W, N co-doped TiO{sub 2} showed superior activity for the degradation of Rhodamine B and 2,4-dichlorophenol as compared to pure titania, Degussa P-25, traditional N-doped TiO{sub 2} and pure WO{sub 3}.

  16. Enhanced photoelectrochemical properties of TiO{sub 2} by codoping with tungsten and silver

    SciTech Connect (OSTI)

    Khan, Matiullah, E-mail: matiullahustb@gmail.com [Department of Inorganic Nonmetallic Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Department of Physics, Kohat University of Science and Technology (KUST), Kohat 26000 (Pakistan); Jiang, Peng; Cao, Wenbin, E-mail: wbcao@ustb.edu.cn [Department of Inorganic Nonmetallic Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Li, Jing [State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083 (China)

    2014-04-21

    The Tungsten (W) and Silver (Ag) codoped TiO{sub 2} samples were successfully synthesized by hydrothermal method without any post calcination. To understand the correlation between electronic structure and photocatalytic properties, the synthesized samples were characterized using X-ray diffraction, Brunauer–Emmett–Teller specific surface area, transmission electron microscopy, ultra-violet–visible absorption spectra, and X-ray photoelectron spectroscopy (XPS), and the photocatalytic properties were evaluated under visible light irradiations. Codoping could not induce any changes in the phase and all the synthesized samples displayed pure anatase phase with spherical morphology. Visible light absorptions of the codoped samples were dramatically improved compared to the corresponding mono-doped samples. XPS analysis indicated that the dopant atoms successfully entered the TiO{sub 2} network. Results from the visible light photodegradation experiments showed that tungsten-silver codoped TiO{sub 2} possessed strong ability in photo-degrading methylene blue compared to tungsten doped TiO{sub 2} and silver doped TiO{sub 2}, which was attributed to the smaller particle size, higher specific surface area, enhanced visible light absorption, and improved separation of photogenerated carriers.

  17. Deformation and fracture behavior of composite structured Ti-Nb-Al-Co(-Ni) alloys

    SciTech Connect (OSTI)

    Okulov, I. V. Marr, T.; Schultz, L.; Eckert, J.; Kühn, U.; Freudenberger, J.; Oertel, C.-G.; Skrotzki, W.

    2014-02-17

    Tensile ductility of the Ti-based composites, which consist of a ?-Ti phase surrounded by ultrafine structured intermetallics, is tunable through the control of intermetallics. The two Ti-based alloys studied exhibit similar compressive yield strength (about 1000?MPa) and strain (about 35%–40%) but show a distinct difference in their tensile plasticity. The alloy Ti{sub 71.8}Nb{sub 14.1}Ni{sub 7.4}Al{sub 6.7} fractures at the yield stress while the alloy Ti{sub 71.8}Nb{sub 14.1}Co{sub 7.4}Al{sub 6.7} exhibits about 4.5% of tensile plastic deformation. To clarify the effect of microstructure on the deformation behavior of these alloys, tensile tests were carried out in the scanning electron microscope. It is shown that the distribution as well as the type of intermetallics affects the tensile ductility of the alloys.

  18. First-principles study on negative thermal expansion of PbTiO{sub 3}

    SciTech Connect (OSTI)

    Wang, Fangfang; Chen, Jun; Xing, Xianran; Xie, Ying; Fu, Honggang

    2013-11-25

    It is well known that perovskite-type PbTiO{sub 3} behaves negative thermal expansion in a wide temperature range from room temperature to Curie temperature (763?K). The present study reports the first-principles study of the anisotropic thermal expansion of PbTiO{sub 3}, in the framework of the density-functional theory and the density-functional perturbation theory. The curve of temperature dependence of the unit cell volume is presented from 20 to 520?K through the calculation of the minimum of total free energy at each temperature point. The negative thermal expansion of PbTiO{sub 3} is calculated without empirical parameters. Furthermore, the distinctive thermodynamic act of PbTiO{sub 3} from expanding to contracting at tetragonal phase is reproduced. The ab-initio calculations reveal that this unique appearance depends on the phonon vibration. The dynamical contributions of various atoms are also calculated to account for the disparate role of Pb-O and Ti-O bond.

  19. Core–shell TiO? microsphere with enhanced photocatalytic activity and improved lithium storage

    SciTech Connect (OSTI)

    Guo, Hong; Tian, Dongxue; Liu, Lixiang; Wang, Yapeng; Guo, Yuan; Yang, Xiangjun

    2013-05-01

    Inorganic hollow core–shell spheres have attracted considerable interest due to their singular properties and wide range of potential applications. Herein a novel facile generic strategy of combining template assisted and solvothermal alcoholysis is employed to prepare core–void–shell anatase TiO? nanoparticle aggregates with an excellent photocatalytic activity, and enhanced lithium storage in large quantities. Amorphous carbon can be loaded on the TiO? nanoparticles uniformly under a suitably formulated ethanol/water system in the solvothermal alcoholysis process, and the subsequent calcination results of the formation of core–shell–shell anatase TiO? nanoparticle aggregates. The intrinsic core–void–shell nature as well as high porosity of the unique nanostructures contributes greatly to the superior photocatalytic activity and improved performance as anode materials for lithium ion batteries. - Graphical abstract: A novel strategy of combining template assisted and solvothermal alcoholysis is employed to prepare unique core–void–shell anatase TiO? nanoparticle aggregates with the superior photocatalytic activity and improved lithium storage. Highlights: • TiO? mesospheres are synthesized by solvothermal alcoholysis. • It is core–void–shell structure and the thickness of shell is estimated to 80 nm. • It exhibits a remarkable photocatalytic activity and improved lithium storage.

  20. Influence of rare earth doping on thermoelectric properties of SrTiO{sub 3} ceramics

    SciTech Connect (OSTI)

    Liu, J. Wang, C. L.; Li, Y.; Su, W. B.; Zhu, Y. H.; Li, J. C.; Mei, L. M.

    2013-12-14

    Thermoelectric properties of SrTiO{sub 3} ceramics, doped with different rare earth elements, were investigated in this work. It's found that the ionic radius of doping elements plays an important role on thermoelectric properties: SrTiO{sub 3} ceramics doped with large rare earth ions (such as La, Nd, and Sm) exhibit large power factors, and those doped with small ions (such as Gd, Dy, Er, and Y) exhibit low thermal conductivities. Therefore, a simple approach for enhancing the thermoelectric performance of SrTiO{sub 3} ceramics is proposed: mainly doped with large ions to obtain a large power factor and, simultaneously, slightly co-doped with small ions to obtain a low thermal conductivity. Based on this rule, Sr{sub 0.8}La{sub 0.18}Yb{sub 0.02}TiO{sub 3} ceramics were prepared, whose ZT value at 1?023?K reaches 0.31, increasing by a factor of 19% compared with the single-doped counterpart Sr{sub 0.8}La{sub 0.2}TiO{sub 3} (ZT?=?0.26)

  1. Significant increase of Curie temperature in nano-scale BaTiO{sub 3}

    SciTech Connect (OSTI)

    Li, Yueliang; Liao, Zhenyu; Fang, Fang; Zhu, Jing; Wang, Xiaohui; Li, Longtu

    2014-11-03

    The low Curie temperature (T{sub c}?=?130?°C) of bulk BaTiO{sub 3} greatly limits its applications. In this work, the phase structures of BaTiO{sub 3} nanoparticles with sizes ranging from 2.5?nm to 10?nm were studied at various temperatures by using aberration-corrected transmission electron microscopy (TEM) equipped with an in-situ heating holder. The results implied that each BaTiO{sub 3} nanoparticle was composed of different phases, and the ferroelectric ones were observed in the shells due to the complicated surface structure. The ferroelectric phases in BaTiO{sub 3} nanoparticles remained at 600?°C, suggesting a significant increase of T{sub c}. Based on the in-situ TEM results and the data reported by others, temperature-size phase diagrams for BaTiO{sub 3} particles and ceramics were proposed, showing that the phase transition became diffused and the T{sub c} obviously increased with decreasing size. The present work sheds light on the design and fabrication of advanced devices for high temperature applications.

  2. Synthesis and Characterization of PhotocatalyticTiO2-ZnFe2O4Nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Srinivasan, Sesha S.; Wade, Jeremy; Stefanakos, Elias K.

    2006-01-01

    A new coprecipitation/hydrolysis synthesis route is used to create aTiO2-ZnFe2O4nanocomposite that is directed towards extending the photoresponse ofTiO2from UV to visible wavelengths (>400?nm). The effect ofTiO2's accelerated anatase-rutile phase transformation due to the presence of the coupledZnFe2O4narrow-bandgap semiconductor is evaluated. The transformation's dependence on pH, calcinations temperature, particle size, andZnFe2O4concentration has been analyzed using XRD, SEM, and UV-visible spectrometry. The requirements for retaining the highly photoactive anatase phase present in aZnFe2O4nanocomposite are outlined. The visible-light-activated photocatalytic activity of theTiO2-ZnFe2O4nanocomposites has been compared to an AldrichTiO2reference catalyst, using a solar-simulated photoreactor formore »the degradation of phenol.« less

  3. Femtosecond laser-induced periodic surface structure on the Ti-based nanolayered thin films

    SciTech Connect (OSTI)

    Petrovi?, Suzana M.; Gakovi?, B.; Peruško, D.; Stratakis, E.; Department of Materials Science and Technology, University of Crete, 710 03 Heraklion, Crete ; Bogdanovi?-Radovi?, I.; ?ekada, M.; Fotakis, C.; Department of Physics, University of Crete, 714 09 Heraklion, Crete ; Jelenkovi?, B.

    2013-12-21

    Laser-induced periodic surface structures (LIPSSs) and chemical composition changes of Ti-based nanolayered thin films (Al/Ti, Ni/Ti) after femtosecond (fs) laser pulses action were studied. Irradiation is performed using linearly polarized Ti:Sapphire fs laser pulses of 40 fs pulse duration and 800 nm wavelength. The low spatial frequency LIPSS (LSFL), oriented perpendicular to the laser polarization with periods slightly lower than the irradiation wavelength, was typically formed at elevated laser fluences. On the contrary, high spatial frequency LIPSS (HSFL) with uniform period of 155 nm, parallel to the laser light polarization, appeared at low laser fluences, as well as in the wings of the Gaussian laser beam distribution for higher used fluence. LSFL formation was associated with the material ablation process and accompanied by the intense formation of nanoparticles, especially in the Ni/Ti system. The composition changes at the surface of both multilayer systems in the LSFL area indicated the intermixing between layers and the substrate. Concentration and distribution of all constitutive elements in the irradiated area with formed HSFLs were almost unchanged.

  4. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, X.; Peker, A.; Johnson, W.L.

    1997-04-08

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3} K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM{sub 1{minus}x}Ti{sub x}){sub a} Cu{sub b} (Ni{sub 1{minus}y}Co{sub y}){sub c} wherein x is from 0.1 to 0.3, y{center_dot}c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b. 2 figs.

  5. A Ni/surface-modified Diamond Composite Electroplating Coating on Superelastic NiTi Alloy as Potential Dental Bur Design

    E-Print Network [OSTI]

    Zheng, Yufeng

    A Ni/surface-modified Diamond Composite Electroplating Coating on Superelastic NiTi Alloy: Composite Electroplating; Surface-modified Diamond Particles; Interfacial Adhesion; NiTi alloy; Dental Bur into nickel coating, and its shank made of stainless steel. There are strong demands from the dentist

  6. 19.2% Efficient InP Heterojunction Solar Cell with Electron-Selective TiO2 Contact

    E-Print Network [OSTI]

    Javey, Ali

    19.2% Efficient InP Heterojunction Solar Cell with Electron-Selective TiO2 Contact Xingtian Yin for solar energy conversion.20 The most efficient InP solar cells use a homojunction configurationP to form a heterojunction solar cell with an efficiency of 17.4%.23,24 Here, by employing a TiO2 electron

  7. PS-wave moveout inversion for tilted TI media: A physical-modeling study Pawan Dewangan1

    E-Print Network [OSTI]

    PS-wave moveout inversion for tilted TI media: A physical-modeling study Pawan Dewangan1 , Ilya Tsvankin2 , Mike Batzle3 , Kasper van Wijk4 , and Matthew Haney5 ABSTRACT Mode-converted PS-waves can- and PS- waves can be inverted for the parameters of a horizontal TI layer with a tilted symmetry axis

  8. MICROSTRUCTURE STUDY AND CRYSTALLINE PHASE FORMATION ON Nb2O5-Ba9Ti2O20 MICROWAVE RESONATORS

    E-Print Network [OSTI]

    MICROSTRUCTURE STUDY AND CRYSTALLINE PHASE FORMATION ON Nb2O5-Ba9Ti2O20 MICROWAVE RESONATORS Maria: dielectric resonators, crystalline phases, microstructures, microwave measurements ABSTRACT We report on the development of barium nanotitanate (Ba2Ti9O20) dielectric resonators (DRs) for microwave applications

  9. TiO2 Polymer Nanocomposites In conjunction with Dr. Ashok Kumar in the Mechanical Engineering Department at

    E-Print Network [OSTI]

    Harmon, Julie P.

    TiO2 Polymer Nanocomposites In conjunction with Dr. Ashok Kumar in the Mechanical Engineering and Engineering, C 23, 737 (2003). 17. "Polymer-TiO2 Nanocomposites: A route Towards Visually Transparent Broadband UV filters and High Refractive Index Materials", Macromolecular Materials Engineering, 288, 44

  10. Face shear piezoelectric properties of relaxor-PbTiO3 single crystals Shujun Zhang,1,a

    E-Print Network [OSTI]

    Cao, Wenwu

    Face shear piezoelectric properties of relaxor-PbTiO3 single crystals Shujun Zhang,1,a Fei Li,1TiO3 crystals, piezoelectric d36 coefficients were determined to be in the range of 2000­2500 p-frequency-transducer applications. © 2011 American Institute of Physics. doi:10.1063/1.3584851 The excellent electromechanical

  11. Mechanism of Electron-Induced Hydrogen Desorption from Hydroxylated Rutile TiO2 (110) D. P. Acharya,

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Mechanism of Electron-Induced Hydrogen Desorption from Hydroxylated Rutile TiO2 (110) D. P. Acharya electrons with controlled energy and flux into single surface hydroxyls (OH) in cryogenic scanning tunneling on the bridging oxygen (Obr) rows on TiO2(110) generates a bridge-bonded hydroxyl (OHbr), has received attention

  12. Ferromagnetism in Topochemically Prepared Layered Perovskite Li0.3Ni0.85La2Ti3O10

    E-Print Network [OSTI]

    Spinu, Leonard

    Ferromagnetism in Topochemically Prepared Layered Perovskite Li0.3Ni0.85La2Ti3O10 Doinita Neiner between the perovskite blocks of triple-layer Ruddlesden-Popper titanate Li2La2Ti3O10 by ion exchange

  13. Chemically grown TiO2 on glass with superior photocatalytic properties G. Kenanakis a,b,

    E-Print Network [OSTI]

    : Titanium dioxide thin films Degussa P25 TiO2 Sol­gel technique Photocatalysis Stearic acid Methylene blue of photocatalysis for various applications such as water treatment, air purification and fuel cells [1­5]. TiO2

  14. Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure

    E-Print Network [OSTI]

    Cao, Guozhong

    Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure Min Intercalation Electrochemistry Capacitance Lithium Ion batteries A B S T R A C T We demonstrate TiO2@graphitic on the electrode surface and enhanced lithium ion intercalation, leading to lower charge transfer resistance

  15. Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation of

    E-Print Network [OSTI]

    Brown, Eric

    Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation that an alizarin red S ~ARS! dye coating on TiO2 nanoparticles enables visible light activation of reactive oxygen species. Successful coating of nanoparti- cles with dye is demonstrated through

  16. Pulsed laser-induced oxygen deficiency at TiO{sub 2} surface: Anomalous structure and electrical transport properties

    SciTech Connect (OSTI)

    Nakajima, Tomohiko; Tsuchiya, Tetsuo; Kumagai, Toshiya

    2009-09-15

    We have studied pulsed laser-induced oxygen deficiencies at rutile TiO{sub 2} surfaces. The crystal surface was successfully reduced by excimer laser irradiation, and an oxygen-deficient TiO{sub 2-{delta}} layer with 160 nm thickness was formed by means of ArF laser irradiation at 140 mJ/cm{sup 2} for 2000 pulses. The TiO{sub 2-{delta}} layer fundamentally maintained a rutile structure, though this structure was distorted by many stacking faults caused by the large oxygen deficiency. The electrical resistivity of the obtained TiO{sub 2-{delta}} layer exhibited unconventional metallic behavior with hysteresis. A metal-insulator transition occurred at 42 K, and the electrical resistivity exceeded 10{sup 4} OMEGA cm below 42 K. This metal-insulator transition could be caused by bipolaronic ordering derived from Ti-Ti pairings that formed along the stacking faults. The constant magnetization behavior observed below 42 K is consistent with the bipolaronic scenario that has been observed previously for Ti{sub 4}O{sub 7}. These peculiar electrical properties are strongly linked to the oxygen-deficient crystal structure, which contains many stacking faults formed by instantaneous heating during excimer laser irradiation. - Graphical abstract: A pulsed laser-irradiated TiO{sub 2-{delta}} substrate showed an unconventional metallic phase, with hysteresis over a wide range of temperatures and a metal-insulator transition at 42 K.

  17. Preparation and characterization of VOx/TiO2 catalytic coatings on stainless steel plates for structured catalytic reactors.

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Preparation and characterization of VOx/TiO2 catalytic coatings on stainless steel plates are used in the mild oxidation of hydrocarbons and NOx abatement are studied. Stainless steel (316 L) was chosen because of its large application in industrial catalytic reactors. TiO2 films on stainless steel

  18. Resistive switching phenomena in TiO{sub x} nanoparticle layers for memory applications

    SciTech Connect (OSTI)

    Goren, Emanuelle; Tsur, Yoed; Ungureanu, Mariana; Zazpe, Raul; Rozenberg, Marcelo; Hueso, Luis E.; Casanova, Fèlix; Stoliar, Pablo

    2014-10-06

    Electrical characteristics of a Co/ TiO{sub x}/Co resistive memory device, fabricated by two different methods, are reported. In addition to crystalline TiO{sub 2} layers fabricated via conventional atomic layer deposition (ALD), an alternative method has been examined, where TiO{sub x} nanoparticle layers were fabricated via sol-gel. The different devices have shown different hysteresis loops with a unique crossing point for the sol-gel devices. A simple qualitative model is introduced to describe the different current-voltage behaviours by suggesting only one active metal-oxide interface for the ALD devices and two active metal-oxide interfaces for the sol-gel devices. Furthermore, we show that the resistive switching behaviour could be easily tuned by proper interface engineering and that despite having a similar active material, different fabrication methods can lead to dissimilar resistive switching properties.

  19. NbTiN Based SIS Multilayer Structures for SRF Applications

    SciTech Connect (OSTI)

    Valente, Anne-marie; Eremeev, Grigory; Phillips, H.; Reece, Charles; Spradlin, Joshua; Yang, Qiguang; Lukaszew, Rosa

    2013-09-01

    For the past three decades, bulk niobium has been the material of choice for SRF cavities applications. RF cavity performance is now approaching the theoretical limit for bulk niobium. For further improvement of RF cavity performance for future accelerator projects, Superconductor ? Insulator - Superconductor (SIS) multilayer structures (as recently proposed by Alex Gurevich) present the theoretical prospect to reach RF performance beyond bulk Nb, using thinly layered higher-Tc superconductors with enhanced Hc1. Jefferson Lab (JLab) is pursuing this approach with the development of NbTiN and AlN based multilayer SIS structures. This paper presents the results on the characteristics of NbTiN films and the first RF measurements on NbTiN-based multilayer structure on thick Nb films.

  20. Surface roughness and interface width scaling of magnetron sputter deposited Ni/Ti multilayers

    SciTech Connect (OSTI)

    Maidul Haque, S.; Biswas, A.; Tokas, R. B.; Bhattacharyya, D.; Sahoo, N. K.; Bhattacharya, Debarati

    2013-09-14

    Using an indigenously built r.f. magnetron sputtering system, several single layer Ti and Ni films have been deposited at varying deposition conditions. All the samples have been characterized by Grazing Incidence X-ray Reflectivity (GIXR) and Atomic Force Microscopy to estimate their thickness, density, and roughness and a power law dependence of the surface roughness on the film thickness has been established. Subsequently, at optimized deposition condition of Ti and Ni, four Ni/Ti multilayers of 11-layer, 21-layer, 31-layer, and 51-layer having different bilayer thickness have been deposited. The multilayer samples have been characterized by GIXR and neutron reflectivity measurements and the experimental data have been fitted assuming an appropriate sample structure. A power law correlation between the interface width and bilayer thickness has been observed for the multilayer samples, which was explained in the light of alternate roughening/smoothening of multilayers and assuming that at the interface the growth “restarts” every time.

  1. Industrial Application of Thin Films (TiAl)N Deposited on Thermo-Wells

    SciTech Connect (OSTI)

    Velez, G.; Jaramillo, S.; Arango, Y. C.; Devia, D.; Quintero, J.; Devia, A.

    2006-12-04

    The thermo-well is formed by two layers, one layer is a ceramic and the other layer is anviloy (comprised tungsten). They are used to coat the thermocouple in the control temperature system during the Aluminum-Silicon alloy melting process. After two weeks of continuous work at 750 deg. C of temperature (the alloy temperature), a high wear in this material is observed, affecting the ceramic. (TiAl)N thin films are deposited directly on the anviloy substrates by the PAPVD (Plasma Assisted Physics Vapor Deposition) in arc pulsed technique, using a TiAl target in a mono-vaporizer system, composed by a reactor and a power controlled system. Two opposite electrodes are placed into the reactor and discharge is produced by a controlled power system. The XRD (X-ray diffraction) patterns show the presence of the (TiAl)N thin film peaks. The morphological characteristics are studied by the scanning probe microscopy (SPM)

  2. Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil

    SciTech Connect (OSTI)

    Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

    1994-06-01

    The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.

  3. Thermoelectricity of Nanocomposites Containing TiO2–CoO Coaxial Nanocables

    SciTech Connect (OSTI)

    Su, L.; Zhang, L.; Gana, Y.X.

    2011-04-01

    TiO{sub 2}-CoO coaxial nanocables were deposited into anodic aluminum oxide (AAO) nanoporous templates to form nanocomposite materials. Electron microscopic analysis was conducted to reveal their structures. Seebeck coefficients of the composites were measured. The highest absolute value of Seebeck coefficient is 393 {micro}V K{sup -1} for the TiO{sub 2} nanotube-filled AAO. The TiO{sub 2}-CoO coaxial nanocable-filled AAO has a lower absolute value of 300 {micro}V K{sup -1}. Both composites showed n-type behavior. The effect of Ag nanoparticles addition on the thermoelectric behavior was also examined.

  4. Thermo-mechanical processing (TMP) of Ti-48Al-2Nb-2Cr based alloys

    SciTech Connect (OSTI)

    Fuchs, G.E.

    1995-02-01

    The effects of heat treatment and deformation processing on the microstructures and properties of {gamma}-TiAl based alloys produced by ingot metallurgy (I/M) and powder metallurgy (P/M) techniques were examined. The alloy selected for this work is the second generation {gamma}-TiAl based alloy -- Ti-48Al-2Nb-2Cr (at %). Homogenization of I/M samples was performed at a variety of temperatures, followed by hot working by isothermal forging. P/M samples were prepared from gas atomized powders, consolidated by both HIP and extrusion and some of the HIPed material was then hot worked by isothermal forging. The effects of processing, heat treatment and hot working on the microstructures and properties will be discussed.

  5. Quadruply Bonded Dimetal Units Supported by 2,4,6-Triisopropylbenzoates MM(TiPB)4 (MM ) Mo2, MoW, and W2)

    E-Print Network [OSTI]

    Turro, Claudia

    Quadruply Bonded Dimetal Units Supported by 2,4,6-Triisopropylbenzoates MM(TiPB)4 (MM ) Mo2, Mo, and cyclic voltammetry) of the new compounds MM(TiPB)4, where MM ) MoW and W2 and TiPB ) 2 in the visible region of the spectrum that are assigned to MM to arylcarboxylate * transitions, 1 MLCT. Each

  6. Growth of Aligned Single-Crystalline Rutile TiO2 Nanowires on Arbitrary Substrates and Their Application in Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Zhou, Chongwu

    the anodization method has been used to grow TiO2 nanotubes,28 an oblique angle deposition method has beenGrowth of Aligned Single-Crystalline Rutile TiO2 Nanowires on Arbitrary Substrates TiO2 is a wide band gap semiconductor with important applications in photovoltaic cells

  7. A novel magnetically separable TiO2/CoFe2O4 nanofiber with high photocatalytic activity under UVvis light

    E-Print Network [OSTI]

    Gong, Jian Ru

    photocatalytic ability, various morphologies of TiO2 including nanoparticles, nanotubes, nanostructured filmsA novel magnetically separable TiO2/CoFe2O4 nanofiber with high photocatalytic activity under UV pollutants [1,2]. Titanium dioxide (TiO2) is considered as an interesting material and has been widely

  8. Inuence of foreign-object damage on crack initiation and early crack growth during high-cycle fatigue of Ti6Al4V

    E-Print Network [OSTI]

    Ritchie, Robert

    ; Ti±6Al±4V 1. Introduction The high-cycle fatigue (HCF) of aircraft gas-turbine engine components has-cycle fatigue of Ti±6Al±4V J.O. Peters, R.O. Ritchie * Department of Materials Science and Mineral Engineering of small surface fatigue cracks in a Ti±6Al±4V alloy, processed for typical turbine blade applications

  9. High Density n-Si/n-TiO2 Core/Shell Nanowire Arrays with Enhanced Photoactivity

    SciTech Connect (OSTI)

    Hwang, Yun Jeong; Boukai, Akram; Yang, Peidong

    2008-11-15

    There are currently great needs to develop low-cost inorganic materials that can efficiently perform solar water splitting as photoelectrolysis of water into hydrogen and oxygen has significant potential to provide clean energy. We investigate the Si/TiO2 nanowire heterostructures to determine their potential for the photooxidation of water. We observed that highly dense Si/TiO2 core/shell nanowire arrays enhanced the photocurrent by 2.5 times compared to planar Si/TiO2 structure due to their low reflectance and high surface area. We also showed that n-Si/n-TiO2 nanowire arrays exhibited a larger photocurrent and open circuit voltage than p-Si/n-TiO2 nanowires due to a barrier at the heterojunction.

  10. Interface control of ferroelectricity in LaNiO{sub 3}-BaTiO{sub 3} superlattices

    SciTech Connect (OSTI)

    Wu, Yin-Zhong, E-mail: yzwu@cslg.edu.cn [Jiangsu Laboratory of Advanced Functional Materials and Physics Department, Changshu Institute of Technology, Changshu 215500 (China); School of Mathematics and Physics, Suzhou University of Science and Technology, Suzhou 215009 (China); Lu, Hai-Shuang; Cai, Tian-Yi; Ju, Sheng, E-mail: jusheng@suda.edu.cn [Department of Physics and Jiangsu Key Laboratory of Thin Films, Soochow University, Suzhou 215006 (China)

    2014-08-15

    LaNiO{sub 3}-BaTiO{sub 3} superlattices with different types of interfaces are studied from first-principles density-functional theory. It is revealed that the ferroelectricity in the superlattice with (NiO{sub 2}){sup ?}/(BaO){sup 0} interfaces is enhanced from that of the superlattice with (LaO){sup +}/(TiO{sub 2}){sup 0} interfaces. The origin lies at the polar discontinuity at the interface, which makes the holes localized within the (NiO{sub 2}){sup ?}/(BaO){sup 0} interface, but drives a penetration of electrons into BaTiO{sub 3} component near (LaO){sup +}/(TiO{sub 2}){sup 0} interface. Our calculations demonstrate an effective avenue to the robust ferroelectricity in BaTiO{sub 3} ultrathin films.

  11. Thermal protection of H13 steel by growth of (TiAl)N films by PAPVD pulsed arc technique

    SciTech Connect (OSTI)

    Jimenez, H.; Devia, D.M.; Benavides, V.; Devia, A. Arango, Y.C.; Arango, P.J.; Velez, J.M.

    2008-08-15

    (TiAl)N Films were grown on H13 steel by a plasma assisted repetitive pulsed arc discharge. To grow the coatings, a TiAl sintered cathode was used, 50% Ti-50% Al. The deposition system consists of a reaction chamber with two electrodes placed face to face. A pulsed power supply, which allows for control of parameters like time active arc, time between arcs, arc energy, and others, is used to generate the discharge. Thermal changes were carried out on H13 steel before and after growing the (TiAl)N films. X-ray diffraction (XRD) was employed to study the coatings, observing the H13 steel and (TiAl)N oxidation temperature. Morphological characteristics were analyzed by means of an Atomic Force Microscopy (AFM). Scanning electron microscopy (SEM) revealed the surface chemical composition of the films and morphological details of the samples.

  12. ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars

    SciTech Connect (OSTI)

    Wang, Dong, E-mail: dong.wang@tu-ilmenau.de; Yan, Yong; Schaaf, Peter [Chair Materials for Electronics, Institute of Materials Engineering and Institute of Micro- and Nanotechnologies MacroNano, TU Ilmenau, Gustav-Kirchhoff-Str. 5, 98693 Ilmenau (Germany); Sharp, Thomas [Oxford Instruments Plasma Technology Ltd., Yatton, Bristol BS49 4AP (United Kingdom); Schönherr, Sven; Ronning, Carsten [Institute for Solid State Physics, Friedrich Schiller University Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Ji, Ran [SUSS MicroTec Lithography GmbH, Schleissheimer Str. 90, 85748 Garching (Germany)

    2015-01-01

    Porous Si nanopillar arrays are used as templates for atomic layer deposition of ZnO and TiO{sub 2}, and thus, ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars are fabricated. The diffusion of the precursor molecules into the inside of the porous structure occurs via Knudsen diffusion and is strongly limited by the small pore size. The luminescence of the ZnO/porous-Si nanocomposite nanopillars is also investigated, and the optical emission can be changed and even quenched after a strong plasma treatment. Such nanocomposite nanopillars are interesting for photocatalysis and sensors.

  13. Single crystal growth and characterization of ilmenite, FeTiO?, for electronic applications 

    E-Print Network [OSTI]

    Gries, Brian Leonard

    1988-01-01

    unit cell (Figure1) with the corundum structure (AI203) and is similar to the perovskite structure represented by ABoa (1, 6). This structure consists of alternating layers of Fe2+ and Ti4+ iona separated by hexagonally stacked layers of oxygen ions... as a source of raw materials and possibly as a source of semiconductor materials for a lunar base. 44 REFERENCES 1. R. K. Pandey and B. A. Baird, Single Crystal Growth and Characterization of Fe-Ti- Oxide Compounds, Proceedings of NASA Symposium...

  14. Prevention of hydrogen embrittlement by a TiO/sub 2/ surface layer

    SciTech Connect (OSTI)

    Nelson, J.G.; Murray, G.T.

    1984-03-01

    This article discusses the problem of hydrogen embrittlement of steels and its prevention, particularly by surface coatings. Preventive methods to date have largely been directed toward microstructure control. Because of the absence of data on prevention of hydrogen embrittlement by TiO/sub 2/ films, and because of the data that indicate that hydrogen diffusion in TiO/sub 2/ films is very low, the authors explore here the effect of a titanium oxide film on hydrogen embrittlement of 15-5 PH (an ARMCO Steel Corp. product) stainless steel.

  15. Ann bay lodyans 10 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 10 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml Tl CHENN LO A Te gen yon nonm ki te...

  16. Ann bay lodyans 12 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 12 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml EPI BONDYE KREYE PREMYE FS A Nan...

  17. Ann bay lodyans 4 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 4 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml Tl CHAT: PI PITI PI RED Vwala se te...

  18. Ann bay lodyans 1 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 1 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 1 Se Bryant Freeman...

  19. Visible Light Photocatalysis via CdS/TiO2Nanocomposite Materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Srinivasan, Sesha S.; Wade, Jeremy; Stefanakos, Elias K.

    2006-01-01

    Nanostructured colloidal semiconductors with heterogeneous photocatalytic behavior have drawn considerable attention over the past few years. This is due to their large surface area, high redox potential of the photogenerated charge carriers, and selective reduction/oxidation of different classes of organic compounds. In the present paper, we have carried out a systematic synthesis of nanostructured CdS-TiO2via reverse micelle process. The structural and microstructural characterizations of the as-prepared CdS-TiO2nanocomposites are determined using XRD and SEM-EDS techniques. The visible light assisted photocatalytic performance is monitored by means of degradation of phenol in water suspension.

  20. Full $fp$-shell study of even-even $^{48-56}$Ti isotopes

    E-Print Network [OSTI]

    F. A. Majeed; A. A. Auda

    2006-02-02

    The level schemes and transition rates {\\em B}({\\em E}2;$\\uparrow$) of eve-even $^{48-56}$Ti isotopes were studied by performing large-scale shell model calculations with FPD6 and GXPF1 effective interactions. Excellent agreement were obtained by comparing the first 2$^{+}$ level for all isotopes with the recently available experimental data, but studying the transition strengths {\\em B}({\\em E}2; 0$^+_{g.s.} \\to2^+_1$) for all Ti isotopes using constant proton-neutron effective charges prove the limitations of the present large-scale calculations to reproduce the experiment in detail.

  1. Ann bay lodyans 11 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 11 Se Bryant Freeman ("Tonton Liben...") ki pare ti liv sa a. AYITI SE PEP AYISYEN PM 7854 .H39 A56 2000 PM Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 1997 YON PWASON KI RELE TEZEN Vwala se yon jennfi yo rele Wozilya ak yon jennjan yo rele Tezen ki...

  2. Ann bay lodyans 15 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS15 Se Bryant Freeman ("Tonton Liben...") ki pare ti liv sa a. H ^ AYITI SE PEP AYISYEN 2 0 0 0 Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 2000 PM 7854 .H39 A56 2000 v. 15 YON KONTRA AK LEDJAB Vwala te gen yon malerez ki te deja gen douz pitit, e...

  3. Ann bay lodyans 5 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 5 Se Bryant Freeman ("Tonton Liben.... Tijo we yon tig ki te tonbe nan yon gwo twou. Li pa t kapab soti paske twou a fon. Kounye a tig la prizonye. Li di Tijo: "Ou se yon bon ti gason, ede m soti, souple." Tijo reponn: "Si mwen retire ou nan twou a, ou ap manje m." Tig la di: "O non...

  4. Ann bay lodyans 3 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 3 Se Bryant Freeman ("Tonton Liben...") ki pare ti liv sa a. AYITI SE PEP AYISYEN Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 2000 PM 7854 • H39 A56 KUAN POU M JWENN KOB? Vwala te gen yon zarenyen ki te raze net. Li di nan tet li: "M bezwen jwenn kob...

  5. Effect of pulse frequency on microstructural, nanomechanical, and wear properties of electrodeposited Ni–TiN composite coatings

    SciTech Connect (OSTI)

    Xia, Fafeng; Tian, Jiyu; Ma, Chunyang Guo, Xue; Potts, Matt

    2014-12-21

    The current paper reports successful syntheses of Ni–TiN composite coatings by pulse electrodeposition. The effect of pulse frequency on the microstructures, nanomechanical, and wear properties of the coatings was investigated using transmission electron microscopy, X–ray diffraction, nanoindenter, scanning electron microscopy, and wear test instrument. The results showed that the Ni–TiN composite coating prepared at the pulse frequency of 100?Hz showed the presence of a less number of TiN particles and some degrees of aggregation in micro-regions. By contrast, in the Ni–TiN coating deposited at the pulse frequency of 500?Hz, the TiN particles were large in number and dispersed homogeneously, thereby, offering the coating a uniform and fine structure. The average grain diameters of Ni and TiN in the coating prepared at 100?Hz were 154.7 and 44.8?nm, respectively, whereas those for the coating prepared at 500?Hz were 67.3 and 25.9?nm, respectively. The maximum TiN content in the Ni-TiN coating deposited at 800?Hz was approximately 10.5?wt.?%. The maximum microhardness and the Young's modulus values for the Ni–TiN composite coatings deposited at 800?Hz were 35.7?GPa and 167.4?GPa, respectively. Furthermore, the Ni–TiN composite coating prepared at 100?Hz had more severe damages, whereas the morphologies of worn surface of the coatings deposited at 500?Hz and 800?Hz were smooth and only a few small pits appeared on the surface.

  6. Preparation, characterization, and photocatalytic studies on anatase nano-TiO{sub 2} at internal air lift circulating photocatalytic reactor

    SciTech Connect (OSTI)

    Xu, Hang, E-mail: xhinbj@126.com; Li, Mei; Jun, Zhang

    2013-09-01

    Graphical abstract: The micro morphological structure of the nano-TiO{sub 2} particles was also observed with TEM, as shown in figure. The TEM images clearly exhibited the homogeneous microstructure of particles with a size of around 10–15 nm. - Highlights: • Nano-TiO{sub 2} was prepared by complex techniques of sol–gel, micro-emulsion and solvent thermal. • The size of TiO{sub 2} was nano level and uniformity. • Nano-TiO{sub 2} exhibited high photo-catalytic activity at internal air lift circulating reactor. • The best nano-TiO{sub 2} dosage was obtained. - Abstract: Anatase nano-titania (TiO{sub 2}) powder was prepared by using a sol–gel process mediated in reverse microemulsion combined with a solvent thermal technique. The structures of the obtained TiO{sub 2} were characterized by TG-DSC, XRD, TEM. The photocatalytic decomposition of methylene blue (MB) on nano-TiO{sub 2} was studied by using an internal air lift circulating photocatalytic reactor. The results show that the anatase structure appears in the calcination temperature range of 400–510 °C, while the transformation of anatase into rutile takes place above 510 °C. The homogeneous microstructure of nano-TiO{sub 2} particles was obtained with a size of around 10–15 nm. In the photocatalytic performance, degradation process follows pseudo first order kinetics with different dosages of photocatalyst and initial MB concentrations and optimal TiO{sub 2} dosage is 0.1 g/L with neutral medium.

  7. Aspects of the SrO-CuO-TiO2 Ternary System Related to the Deposition of SrTiO3 and Copper-Doped SrTiO3 Thin-Film Buffer Layers

    SciTech Connect (OSTI)

    A. Ayala

    2004-12-20

    YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) coated conductors are promising materials for large-scale superconductivity applications. One version of a YBCO coated conductor is based on ion beam assisted deposition (IBAD) of magnesium oxide (MgO) onto polycrystalline metal substrates. SrTiO{sub 3} (STO) is often deposited by physical vapor deposition (PVD) methods as a buffer layer between the YBCO and IBAD MgO due to its chemical stability and lattice mismatch of only {approx}1.5% with YBCO. In this work, some aspects of the stability of STO with respect to copper (Cu) and chemical solution deposition of STO on IBAD MgO templates were examined. Solubility limits of Cu in STO were established by processing Cu-doped STO powders by conventional bulk preparation techniques. The maximum solubility of Cu in STO was {approx}1% as determined by transmission electron microscopy (TEM) and Rietveld refinements of x-ray diffraction (XRD) data. XRD analysis, performed in collaboration with NIST, on powder compositions on the STO/SrCuO{sub 2} tie line did not identify any ternary phases. SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer layers were prepared by pulsed laser deposition (PLD) and CSD on IBAD MgO flexible metallic textured tapes. TEM analysis of a {approx}100 nm thick SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer layer deposited by PLD showed a smooth Cu-doped STO/MgO interface. A {approx}600 nm thick YBCO film, deposited onto the SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer by PLD, exhibited a T{sub c} of 87 K and critical current density (J{sub c}) of {approx}1 MA/cm{sup 2}. STO and Cu-doped STO thin films by CSD were {approx}30 nm thick. The in plane alignment (FWHM) after deposition of the STO improved by {approx}1{sup o} while it degraded by {approx}2{sup o} with the SrCu{sub 0.05}TiO{sub y} buffer. YBCO was deposited by PLD on the STO and SrCu{sub 0.05}TiO{sub y} buffers. The in plane alignment (FWHM) of the YBCO with the STO buffer layer slightly improved while that of the YBCO with the SrCu{sub 0.05}TiO{sub y} buffer layer remained constant. A goal of the CSD approach to fabrication of coated conductors is process simplicity. In this study, single layer textured films were obtained without a nucleating seed layer that has been deemed necessary by several investigators. These results indicate that Cu-doped STO buffer layers deposited by PLD or CSD are compatible with IBAD MgO and YBCO and that CSD is a viable approach to coated conductor fabrication.

  8. Towards Real Time Optimal Auto-tuning of PID Controllers 

    E-Print Network [OSTI]

    Hill, Aaron Jamison

    2013-08-22

    board comes equipped with 512MB of DDR3-1600 RAM. Our design environment was a Microsoft Windows 7 PC with an AMD Phenom 9500 Quad-Core processor at 2.20 GHz with 8 GB of DDR3 RAM hosting Ti’s Code Composer Studio version 5.3 for programming...

  9. Microstructural evolution and characterisation of interfacial phases in Al2O3/Ag-Cu-Ti/Al2O3 braze joints

    E-Print Network [OSTI]

    Ali, M.; Knowles, K. M.; Mallinson, P. M.; Fernie, J. A.

    2015-06-14

    . With the 0.7 at% Ti alloy, wetting was controlled by a titanium oxide layer, resulting in a contact angle of 63°. With the 8.0 at% Ti alloy, a layer containing both Ti3Cu3O and Ti4Cu2O was observed, resulting in a similar contact angle to that obtained... inhomogeneous interfacial structures, with some regions of interface lacking evidence for preserving a chemical bond between the ABA and alumina. Other regions show significant development of the titanium oxide layer along with decomposition of the Ti3Cu3O...

  10. Photoelectrochemical Water Splitting of Nitrogen and Hydrogen Treated P25 TiO2 Films

    E-Print Network [OSTI]

    Zavodivker, Liat Shari

    2014-01-01

    Quantum Dot Solar Cells. Harvesting Light Energy with CdSeSolar Cells by Design: Photoelectrochemistry of TiO 2 Nanorod Arrays Decorated with CdSe.Solar Cells. Tuning Photoresponse through Size and Shape Control of CdSe

  11. Electronic and mechanical properties of Zr{sub 2}TiAl: A first principles study

    SciTech Connect (OSTI)

    Reddy, P. V. Sreenivasa, E-mail: kanchana@iith.ac.in; Kanchana, V., E-mail: kanchana@iith.ac.in [Department of Physics, Indian Institute of Technology Hyderabad, Ordnance Factory Estate, Yeddumailaram-502205, Andhra Pradesh (India)

    2014-04-24

    First principles study of electronic and mechanical properties of ternary phase Zr{sub 2}TiAl intermetallic compound has been carried out by using full potential linear augmented plane wave (FP-LAPW) method. Our calculated lattice parameter is in good agreement with the experiment. We find the magnetic phase of the compound to be stable with a magnetic moment of 1.95 ?{sub B}. The major contribution to the total magnetic moment arises mainly from the Ti atom with the local magnetic moment of 1.22 ?{sub B}. From the density of states plots we find the Ti-d and Zr-d to dominate at the Fermi level (E{sub F}) with enhanced crystal field splitting and exchange splitting found in Ti. The mechanical stability of the compound is confirmed from the calculated elastic constants, and we find the compound to be ductile in nature from the calculated Pugh’s ratio and Cauchy’s pressure.

  12. Surface characteristics and corrosion resistance properties of TiNi shape memory alloy coated with Ta

    E-Print Network [OSTI]

    Zheng, Yufeng

    for electroplated, crimped, or swaged metal bands that can be abrasive, loosen, crack, or fall off. For coatingSurface characteristics and corrosion resistance properties of TiNi shape memory alloy coated coated with tantalum by the arc ion plating method with the aim to improve their radiopacity. Surface

  13. Atomic and electronic structure of the ferroelectric BaTiO{sub 3}/Ge(001) interface

    SciTech Connect (OSTI)

    Fredrickson, Kurt D.; Ponath, Patrick; Posadas, Agham B.; Demkov, Alexander A., E-mail: demkov@physics.utexas.edu [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States); McCartney, Martha R.; Smith, David J. [Department of Physics, Arizona State University, Tempe, Arizona 85287 (United States); Aoki, Toshihiro [LeRoy Eyring Center for Solid State Science, Arizona State University, Tempe, Arizona 85287 (United States)

    2014-06-16

    In this study, we demonstrate the epitaxial growth of BaTiO{sub 3} on Ge(001) by molecular beam epitaxy using a thin Zintl template buffer layer. A combination of density functional theory, atomic-resolution electron microscopy and in situ photoemission spectroscopy is used to investigate the electronic properties and atomic structure of the BaTiO{sub 3}/Ge interface. Aberration-corrected scanning transmission electron micrographs reveal that the Ge(001) 2?×?1 surface reconstruction remains intact during the subsequent BaTiO{sub 3} growth, thereby enabling a choice to be made between several theoretically predicted interface structures. The measured valence band offset of 2.7?eV matches well with the theoretical value of 2.5?eV based on the model structure for an in-plane-polarized interface. The agreement between the calculated and measured band offsets, which are highly sensitive to the detailed atomic arrangement, indicates that the most likely BaTiO{sub 3}/Ge(001) interface structure has been identified.

  14. Enhanced photodegradation of methyl orange with TiO nanoparticles using a triboelectric

    E-Print Network [OSTI]

    Wang, Zhong L.

    creatures. Consequently, a green, energy-saving and low cost method for purifying water sources is desired triboelectric nanogenerator (TENG) whose electric power output can be used for enhancing the photodegradation of MO with the presence of TiO2 nanoparticles, because the TENG generated electric field can effectively

  15. The pore wall structure of porous semi-crystalline anatase TiO2.

    SciTech Connect (OSTI)

    Kim, Dr Man-Ho [National Institute of Standards and Technol/University of Maryland, College Park; Doh, Dr. Jeong-Mann [Harbin Institute of Technology & Korea Institute of Science and Technology; Han, Seong Chul [Harbin Institute of Technology & Korea Institute of Science and Technology; Chae, Keun Hwa [Harbin Institute of Technology & Korea Institute of Science and Technology; Yu, Byung-Yong [Harbin Institute of Technology & Korea Institute of Science and Technology; Hong, Kyung Tea [Harbin Institute of Technology & Korea Institute of Science and Technology; Jackson, Andrew [NIST Center for Neutron Research (NCRN), Gaithersburg, MD; Anovitz, Lawrence {Larry} M [ORNL

    2011-01-01

    The structure of porous TiO2 prepared by electrochemical anodization in a fluoride-containing ethylene glycol electrolyte solution was quantitatively studied using small-angle neutron scattering (SANS) and ultra-small-angle neutron scattering (USANS). The cylindrical pores along the coaxial direction were somewhat irregular in shape, were widely distributed in diameter, and seemed to have a broadly pseudo-hexagonal arrangement. The scattering from the pore wall showed a negative deviation from Porod scattering, indicating that the interface between TiO2 and the pore was not sharp. A density gradient of around 40 60 A at the pore wall (i.e. the interface between the pore and the TiO2 matrix) was estimated using both constant and semi-sigmoidal interface models. This gradient may be due to the presence of fluorine and carbon partially absorbed by the pore wall from the fluoride-containing electrolyte or to sorbed water molecules on the wall. The neutron contrast-matching point between the TiO2 matrix and the pores filled with liquid H2O/D2O mixtures was 51/49%(v/v) H2O/D2O, yielding an estimated mass density of 3.32 g cm3. The specific surface area of the sample derived from the (U)SANS data was around 939 1003 m2 cm3 (283 302 m2 g1).

  16. The pore wall structure of porous semi-crystalline anatase TiO2

    SciTech Connect (OSTI)

    Kim, Dr Man-Ho [National Institute of Standards and Technol/University of Maryland, College Park; Doh, Dr. Jeong-Mann [Harbin Institute of Technology & Korea Institute of Science and Technology; Han, Seong Chul [Harbin Institute of Technology & Korea Institute of Science and Technology; Chae, Keun Hwa [Harbin Institute of Technology & Korea Institute of Science and Technology; Yu, Byung-Yong [Harbin Institute of Technology & Korea Institute of Science and Technology; Hong, Kyung Tea [Harbin Institute of Technology & Korea Institute of Science and Technology; Jackson, Andrew [NIST Center for Neutron Research (NCRN), Gaithersburg, MD; Anovitz, Lawrence {Larry} M [ORNL

    2011-01-01

    The structure of porous TiO2 prepared by electrochemical anodization in a fluoride-containing ethylene glycol electrolyte solution was quantitatively studied using small angle neutron scattering (SANS) and ultra small angle neutron scattering (USANS). The cylindrical pores along the coaxial direction were somewhat irregular shape, were broadly distributed in diameter, and seemed to have a broadly pseudo-hexagonal arrangement. The scattering from the pore wall showed a negative deviation from Porod scattering, indicating the interface between TiO2 and the pore was not sharp. A density gradient of around 40 ~ 60 at the pore wall (i.e. interface between the pore and the TiO2 matrix) was estimated using both constant and semi-sigmoidal interface models. This may be due to the presence of fluorine and carbon partially absorbed by the pore wall from the fluoride-containing electrolyte and sorbed water molecules on the wall. The neutron contrast-matching point between the TiO2 matrix and the pores filled with liquid H2O/D2O mixtures was 51/49 vol/vol H2O/D2O, yielding an estimated mass density of 3.32 g/cm3. The specific surface area of the sample derived from the (U)SANS data, S/V, was around 939 ~ 1003 m2/cm3 (283~ 302m2/g).

  17. Fabrication of NiTi shape memory alloy from elemental powders by hot isostatic pressing 

    E-Print Network [OSTI]

    McNeese, Matthew Doyle

    1997-01-01

    .0 and 50.6at.% Ni, packed and sealed into stainless steel containers, hot isostatically pressed (HIPed) at 20OMPa and 900-1050 'C, and machined to expose a gauge section of consolidated NiTi material for thennomechanical testing. Some samples of material...

  18. Optical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry

    E-Print Network [OSTI]

    the absorption of the solar spectrum by through utilizing their plasmon resonances. One challengeOptical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry Fei WangV range, a much better match to the solar spectrum than the 3.8 eV Ag plasmon. AFM measurements indicate

  19. Surface Structure of TiO2011-2 1 T. J. Beck,1

    E-Print Network [OSTI]

    Diebold, Ulrike

    the efficiency with which photo- generated carriers are trapped at the surface or the rate at which on an early low-energy electron diffraction (LEED) study [11], it was concluded that TiO2001 forms 011-2 1-states scanning tunneling mi- croscopy (STM) images were acquired with positive sample bias voltages. During STM

  20. Migration velocity analysis for TI media in the presence of quadratic lateral velocity variation

    E-Print Network [OSTI]

    Tsvankin, Ilya

    of lateral heteroge- neity on image gathers obtained after prestack depth migration and found that quadratic that application of prestack depth migration (PSDM) with anisotropic MVA yields sig- nificantly improved imagesMigration velocity analysis for TI media in the presence of quadratic lateral velocity variation

  1. Structure of the photo-catalytically active surface of SrTiO3

    E-Print Network [OSTI]

    Plaza, Manuel; Ko, J Y Peter; Brock, Joel D; Shen, Mei; Simpson, Burton H; Rodríguez-López, Joaquín; Ritzert, Nicole L; Abruña, Héctor D; Letchworth-Weaver, Kendra; Gunceler, Deniz; Arias, T A; Schlom, Darrell G

    2015-01-01

    A major goal of energy research is to use visible light to cleave water directly, without an applied voltage, into hydrogen and oxygen. Since the initial reports of the ultraviolet (UV) activity of TiO2 and SrTiO3 in the 1970s, researchers have pursued a fundamental understanding of the mechanistic and molecular-level phenomena involved in photo-catalysis. Although it requires UV light, after four decades SrTiO3 is still the gold standard for splitting water. It is chemically stable and catalyzes both the hydrogen and the oxygen reactions without applied bias. While ultrahigh vacuum (UHV) surface science techniques have provided useful insights, we still know relatively little about the structure of electrodes in contact with electrolytes under operating conditions. Here, we report the surface structure evolution of a SrTiO3 electrode during water splitting, before and after training with a positive bias. Operando high-energy X-ray reflectivity measurements demonstrate that training the electrode irreversibly...

  2. Grain size dependence of fracture toughness and crack-growth resistance of superelastic NiTi

    E-Print Network [OSTI]

    Sun, Qing-Ping

    Available online xxxx Keywords: Shape memory alloys Martensitic phase transformation Microstructure to a reversible martensitic phase transformation (PT), superelastic (SE) NiTi shape memory alloys (SMAs with thickness of 1.7 mm were sandwiched in stainless steel sheets and were cold-rolled to 42% of thickness

  3. Process Modeling of Ti-6Al-4V Linear Friction Welding (LFW)

    E-Print Network [OSTI]

    Grujicic, Mica

    Process Modeling of Ti-6Al-4V Linear Friction Welding (LFW) Mica Grujicic, G. Arakere, B finite-element analysis of the linear friction welding (LFW) process is combined with the basic physical in the open literature revealed that the weld region consists of a thermo- mechanically affected zone (TMAZ

  4. Interface and Size Effects on TiN-based Nanostructured Thin Films 

    E-Print Network [OSTI]

    Kim, Ickchan

    2012-07-16

    dependent and the layer thickness leading to the highest radiation tolerance was around 10 nm. In addition, the embedded epitaxial cubic AlN with cladding TiN nanolayers showed higher effective thermal conductivity than that of AlN single layer as well...

  5. Injection seeding of a Ti: sapphire laser using a Ramp-Hold-Fire technique 

    E-Print Network [OSTI]

    Larsen, Matthew P

    1997-01-01

    An injection seeded Ti:sapphire laser, pumped by the second harmonic of a Q-switched Nd:YAG laser, has been constructed for use in an experiment that will explore the validity of the Bell-Clauser-Horne inequalities.[] A new technique, Ramp...

  6. W deposition and titanium fluoride formation during WF6 reduction by Ti: Reaction path and mechanisms

    E-Print Network [OSTI]

    Allen, Leslie H.

    W deposition and titanium fluoride formation during WF6 reduction by Ti: Reaction path, Materials Research Laboratory, and Department of Materials Science, University of Illinois, 1304 West Green Street, Urbana, Illinois 61801 V. C. Hornback and D. J. Allman Symbios Logic Incorporated, 1635 Aeroplaza

  7. St h ti d i l i fStochastic dynamic analysis of offshore wind turbines

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    1 St h ti d i l i fStochastic dynamic analysis of offshore wind turbines ­ with emphasis on fatigue Co te ts · Overview of offshore wind technology · Modelling of environmental conditions · Dynamic analysis of offshore bottom-fixed wind turbines · Modelling and dynamic analysis of floating wind turbines

  8. FTIR Analysis of Apatite Formation on Bioactive Glass Coatings on Ti Alloys

    E-Print Network [OSTI]

    FTIR Analysis of Apatite Formation on Bioactive Glass Coatings on Ti Alloys E. Saiz, M. Goldman and orthopedic applications. To do this, we have been coating these metals with glasses whose compositions®, however, will not coat (it cracks) the implant alloys due to large differences in coefficient of thermal

  9. On perfectly plastic flow in porous material T.I. Zohdi*,a

    E-Print Network [OSTI]

    Sevostianov, Igor

    On perfectly plastic flow in porous material T.I. Zohdi*,a , M. Kachanovb , I. Sevostianovc in final revised form 15 December 2001 Abstract Experimental observations suggest that for perfectly-plastic of the pores and their orientation. The underlying microscale mechanism is that local plastic ``pockets'' near

  10. Supporting Online Materials Electron Microscopy Observation of TiO2 Nanocrystal Evolution in High-

    E-Print Network [OSTI]

    Wang, Xudong

    was allowed to cool down naturally without changing the system pressure and carrier gas flow. (3) Growth of Si of gaseous TiCl4 and H2O vapors were controlled by solenoid valves and adjusted by fine tuning the precursor as the carrier gas, which provided a background pressure of 2.7 Torr. The chamber temperature was maintained

  11. Tantalum coated NiTi alloy by PIIID for biomedical application Y. Zhou a,b

    E-Print Network [OSTI]

    Zheng, Yufeng

    by electrodeposition [14], magnetron sputtering [15], plasma immersion ion implantation (PIII) [16,17] and multi-arc November 2012 Keywords: PIIID Ta coating Corrosion resistance NiTi Plasma immersion ion implantation technique combines the advantages of plasma immer- sion ion implantation (PIII) and magnetron deposition

  12. Calculation of TiO2 Surface and Subsurface Oxygen Vacancy by the Screened Exchange Functional

    E-Print Network [OSTI]

    Li, Hongfei; Guo, Yuzheng; Robertson, John

    2015-07-20

    . M.; Lu, G. Q., Anatase TiO2 Single Crystals with a Large Percentage of Reactive Facets. Nature 2008, 453, 638-641. 14 Thomas, A. G.; Flavell, W. R.; Mallick, A. K.; Kumarasinghe, A. R.; Tsoutsou, D.; Khan, N.; Chatwin, C.; Rayner, S.; Smith, G. C...

  13. Metastable bcc phase formation in the Nb-Cr-Ti system

    SciTech Connect (OSTI)

    Thoma, D.J.; Perepezko, J.H.

    1994-08-01

    Metastable disordered bcc phases have been formed from the melt in the Nb-Cr-Ti system where primary Laves phases would develop under equilibrium solidification conditions. Three vertical temperature-composition sections in the ternary system incorporating NbCr, were evaluated: the Nb-Cr binary, the TiCr{sub 2}-NbCr{sub 2} isoplethal section, and the NbCr{sub 2}-Ti plethal section. In the rapid solidification of NbCr{sub 2}, metastable bcc phase formation was not observed, but deviations from NbCr{sub 2} stoichiometry or alloying with Ti was found to promote bcc phase formation by decreasing the required liquid undercooling to reach the metastable bcc liquidus and solidus. The metastable phases were characterized through x-ray diffraction (XRD), and systematic deviations from Vegard`s Rule have been defined in the three plethal sections. The metastable bcc phases decompose at temperatures >800{degrees}C to uniformly refined microstructures. As a result, novel microstructural tailoring schemes are possible through the metastable precursor microstructures.

  14. VNIvw..TI~orSi1lAR BACHELOR OF SCIENCE IN BIOCHEMISTRY

    E-Print Network [OSTI]

    Virginia Tech

    A"imn~''ED VNIvw..TI~orSi1lAR BACHELOR OF SCIENCE IN BIOCHEMISTRY COLLEGE OF SCIENCE GRADUATION: Scientific Reasoning and Discovery (Natural Sciences): BCRM 1014 Introduction to Biochemistry General Biochemistry Lab. Prob. Biochemistry (1)_ (4)_ (3)_ (6)_ #BCHM 4115 4116 #BCHM 4124 #12;BlOC 2013 BIOL 1105

  15. Passive film-induced stress and mechanical properties of a-Ti in methanol solution

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Passive film-induced stress and mechanical properties of a-Ti in methanol solution Zhi Qin 2013 Accepted 7 October 2013 Available online 14 October 2013 Keywords: A. Titanium C. Passive films C. Stress corrosion C. Effects of strain C. Interfaces a b s t r a c t Passive films play an important role

  16. Zircons from kimberlite: New insights from oxygen isotopes, trace elements, and Ti in zircon thermometry

    E-Print Network [OSTI]

    Meyers, Stephen R.

    Africa, Siberia, Brazil, and the United States have been analyzed for their Ti concentration and selected of Sa~o Paulo, 05508-080 Sa~o Paulo, SP, Brazil Received 8 May 2006; accepted in revised form 23 April, precise and accurate laser-fluorination oxygen isotope data were obtained for zircons from Brazil (5.1 ± 0

  17. Solar Energy Materials & Solar Cells 71 (2002) 261271 Photoelectric behavior of nanocrystalline TiO2

    E-Print Network [OSTI]

    Huang, Yanyi

    2002-01-01

    Solar Energy Materials & Solar Cells 71 (2002) 261­271 Photoelectric behavior of nanocrystalline Ti , Feng-Qin Liue a State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking Earth Materials and Bioinorganic Chemistry, Peking University, Beijing 100871, People's Republic

  18. Preparation of Size-Controlled TiO2 Nanoparticles and Derivation of Optically Transparent Photocatalytic

    E-Print Network [OSTI]

    Kim, Sang Kyu

    for controlling the size of individual particles and for obtaining the stabilized colloidal suspensions. TiO2, and the long-term stability of the suspension without ag- glomeration or precipitation is prerequisite alkoxide stabilized in acidic ethanol/water solution. The sizes of particles have been controlled

  19. Carbon Nitride-TiO2 Hybrid Modified with Hydrogenase for Visible Light Driven Hydrogen Production

    E-Print Network [OSTI]

    Caputo, Christine A.; Wang, Lidong; Beranek, Radim; Reisner, Erwin

    2015-06-29

    5.8 × 105 mol H2 (mol H2ase)–1 after 72 h in a sacrificial electron donor solution at pH 6 during solar AM 1.5G irradiation. An external quantum efficiency up to 4.8 % for photon to hydrogen conversion was achieved. The CNx-TiO2-H2ase construct...

  20. Structural and electrical characterization of CoTiN metal gates

    SciTech Connect (OSTI)

    Wongpiya, Ranida; Ouyang, Jiaomin; Chung, Chia-Jung; Duong, Duc T.; Clemens, Bruce; Deal, Michael; Nishi, Yoshio

    2015-02-21

    As the gate size continues to decrease in nanoscale transistors, having metal gates with amorphous or near amorphous structures can potentially reduce grain-induced work function variation. Furthermore, amorphous materials are known to have superior diffusion barrier properties, which can help prevent work function change due to the diffusion of metals in contact with the gate. In this work we show that with the addition of cobalt, thin films of polycrystalline TiN become more amorphous with a smaller grain size. Co{sub x}(TiN){sub 1-x} films, where x?=?60–80%, appear to consist of nanocrystals embedded in an amorphous matrix, and are thermally stable with no significant crystallization up to an annealing temperature of at least 600?°C. Reducing the nitrogen gas flow ratio during sputter deposition from 9% to 2.5% further decreases the films' crystallinity, which is apparent by more sparse and even smaller nanocrystals. In addition to being partially amorphous, these CoTiN films also exhibit good thermal stability, low resistivity, low roughness, and have the potential for atomic layer deposition compatibility. Even though these materials are not completely amorphous, their small crystal size and amorphous matrix can potentially reduce work function variation and improve their diffusion barrier property. These properties make CoTiN a good candidate as a gate material for future nanoelectronic devices and technology.

  1. Room temperature alcohol sensing by oxygen vacancy controlled TiO{sub 2} nanotube array

    SciTech Connect (OSTI)

    Hazra, A.; Dutta, K.; Bhowmik, B.; Bhattacharyya, P.; Chattopadhyay, P. P.

    2014-08-25

    Oxygen vacancy (OV) controlled TiO{sub 2} nanotubes, having diameters of 50–70?nm and lengths of 200–250?nm, were synthesized by electrochemical anodization in the mixed electrolyte comprising NH{sub 4}F and ethylene glycol with selective H{sub 2}O content. The structural evolution of TiO{sub 2} nanoforms has been studied by field emission scanning electron microscopy. Variation in the formation of OVs with the variation of the structure of TiO{sub 2} nanoforms has been evaluated by photoluminescence and X-ray photoelectron spectroscopy. The sensor characteristics were correlated to the variation of the amount of induced OVs in the nanotubes. The efficient room temperature sensing achieved by the control of OVs of TiO{sub 2} nanotube array has paved the way for developing fast responding alcohol sensor with corresponding response magnitude of 60.2%, 45.3%, and 36.5% towards methanol, ethanol, and 2-propanol, respectively.

  2. Inorganic-modified semiconductor TiO2 nanotube arrays for photocatalysis

    E-Print Network [OSTI]

    Lin, Zhiqun

    Inorganic-modified semiconductor TiO2 nanotube arrays for photocatalysis Mengye Wang,ab James Ioccozia,b Lan Sun,*a Changjian Lin*a and Zhiqun Lin*b Semiconductor photocatalysis is a promising resistance, and nontoxicity. This Review briefly introduces the key mechanisms of photocatalysis, highlights

  3. SrTiO3 Nanocuboids from a Lamellar Microemulsion Linhua Hu,*,,

    E-Print Network [OSTI]

    Marks, Laurence D.

    -angle annular dark field (HAADF) imaging, the as-prepared SrTiO3 nanocuboids grow between three layers of water structures in a mixture of water, oil, and surfactant: normal micelle, reverse micelle, and the lamellar E. Winans,§ Laurence D. Marks,*, and Kenneth R. Poeppelmeier*,, Department of Chemistry

  4. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Hyun You; Liu, Ping

    2015-09-21

    Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film supported on Cu(111), CuTiOx/Cu(111), during CO oxidation was explored using density functional theory (DFT). The unique structural frame of CuTiOx is able to stabilize and isolate a single Cu+ site on the terrace, which is previously proposed active for CO oxidation. Furthermore, it is not the case, where the reaction via both the Langmuir–Hinshelwood (LH) and the Mars-van Krevelen (M-vK) mechanisms are hindered on such single Cu+ site. Upon the formation ofmore »step-edges, the synergy among Cu?+ sites, TiOx matrix, and Cu(111) is able to catalyze the reaction well. Depending on temperatures and partial pressure of CO and O2, the surface structure varies, which determines the dominant mechanism. In accordance with our results, the Cu?+ ion alone does not work well for CO oxidation in the form of single sites, while the synergy among multiple active sites is necessary to facilitate the reaction.« less

  5. Pseudocapacitive Lithium-Ion Storage in Oriented Anatase TiO2 Nanotube Arrays

    SciTech Connect (OSTI)

    Zhu, K.; Wang, Q.; Kim, J. H.; Pesaran, A. A.; Frank, A. J.

    2012-06-07

    We report on the synthesis and electrochemical properties of oriented anatase TiO{sub 2} nanotube (NT) arrays as electrodes for Li-ion batteries. The TiO{sub 2} NT electrodes displayed both pseudocapacitive Li{sup +} storage associated with the NT surface and the Li{sup +} storage within the bulk material. The relative contribution of the pseudocapacitive and bulk storages depends strongly on the scan rate. While the charges are stored primarily in the bulk at low scan rates (<< 1 mV/s), the surface storage dominates the total storage capacity at higher scan rates (>1 mV/s). The storage capacity of the NT electrodes as a function of charge/discharge rates showed no dependence on the NT film thickness, suggesting that the Li{sup +} insertion/extraction processes occur homogeneously across the entire length of NT arrays. These results indicated that the electron conduction along the NT walls and the ion conduction within the electrolyte do not cause significant hindering of the charge/discharge kinetics for NT electrode architectures. As a result of the surface pseudocapacitive storage, the reversible Li{sup +} storage capacities for TiO{sub 2} NT electrodes were higher than the theoretical storage capacity for bulk anatase TiO{sub 2} materials.

  6. Glass-Blown Pyrex Resonator with Compensating Ti Coating for Reduction of TCF

    E-Print Network [OSTI]

    Chen, Zhongping

    of metallic glasses to achieve spherical structures has been explored by using a blow-molding technique [6]; processing of these materials requires temperatures in excess of 1,600 C. A highly parallel glass-blowingGlass-Blown Pyrex Resonator with Compensating Ti Coating for Reduction of TCF Joan Giner1

  7. Finite Element Based Micromechanical Analysis of Precipitated NiTi Shape Memory Alloys 

    E-Print Network [OSTI]

    Cox, Austin Edward

    2015-07-22

    into the material and its thermomechanical response than ever before. The most widely modeled and produced SMA class in industry today is one which hosts Ni as a core component of its composition, and usually takes the form of NiTi. When these SMA materials are heat...

  8. The Effects of the TI-Navigator System on Student Achievement (Algebra I)

    E-Print Network [OSTI]

    Wurtele, Eve Syrkin

    The Effects of the TI-Navigator System on Student Achievement (Algebra I) Demographics of Sample (n in student understanding and attitudes when technology was used in Algebra I. 2. Used two types of technology and warranted. Other technologies could also be compared and developed to contribute to algebra students

  9. Investigation of surface endothelialization on biomedical nitinol (NiTi) alloy: Effects of surface micropatterning combined

    E-Print Network [OSTI]

    Lee, James

    Investigation of surface endothelialization on biomedical nitinol (NiTi) alloy: Effects of surface outstanding biocompatibility in our previous studies. In this study, endothelialization on biomedical nitinol- trolled thickness between 40 and 50 nm were deposited onto micropatterned nitinol surface in a direct

  10. Enhanced low-temperature impact toughness of nanostructured Ti V. V. Stolyarov and R. Z. Valiev

    E-Print Network [OSTI]

    Zhu, Yuntian T.

    and ductility of nanostructured Ti as well as smaller fracture dimples at lower temperatures. This result not result in high impact toughness if they have low ductility. Recently, some nanostructured materials is whether such an increase in strength and ductility leads to an increase in the impact toughness

  11. Rapid construction of TiO2 aggregates using microwave assisted synthesis and its application for

    E-Print Network [OSTI]

    Cao, Guozhong

    Rapid construction of TiO2 aggregates using microwave assisted synthesis and its application for dye-sensitized solar cells Xuyang Wang,a Jianjun Tian,*a Chengbin Fei,b Lili Lv,a Yajie Wangb, with a size of $500 nm have been synthesized by a microwave assisted method at 150 C in a short time ($10

  12. Enhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2 Nanotubes

    E-Print Network [OSTI]

    Cao, Guozhong

    -called third generation of solar cells including dye-sensitized solar cells, DSCs2,3 and organic phoEnhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2- tovoltaics, OPVs.4-6 OPVs or polymer-based photovoltaic devices can be processed from solution and have

  13. Isothermal oxidation behavior and microstructure of plasma surface Ta coating on ?-TiAl

    SciTech Connect (OSTI)

    Song, Jian; Zhang, Ping-Ze Wei, Dong-Bo; Wei, Xiang-Fei; Wang, Ya

    2014-12-15

    The oxidation behavior of ?-TiAl with Ta surface coating fabricated by double glow plasma surface alloying technology was investigated by thermogravimetric method. Oxidation experiments were carried out at 750 °C and 850 °C in air for 100 h. The modification layer was comprised of deposition layer and diffusion layer, which metallurgically adhered to the substrate. Tantalum element decreased with the case depth. The oxidation morphology was studied by a scanning electron microscope and X-ray diffraction. The results highlighted that in the oxidizing process of the oxidation, the phase containing Ta-richer may restrain diffusing outward of the element Al in the matrix. Ti diffused outward, and formed the TiO{sub 2} scales, while the middle layer was rich in Al, and formed the continuous Al{sub 2}O{sub 3} scales after oxidation, which was effective to prevent further infiltration of oxygen atoms, and as a result the oxidation resistance increased immensely. - Highlights: • A Ta modified coating was prepared on ?-TiAl using DGP surface alloying technology. • The modification layer metallurgically adhered to the substrate. • The bonding force is about 60 N, satisfying the demands of practical use. • The oxidation resistance increased immensely at 750 °C and 850 °C.

  14. Hierarchically structured TiO2 for Ba-filled skutterudite with enhanced thermoelectric

    E-Print Network [OSTI]

    Cao, Guozhong

    Hierarchically structured TiO2 for Ba-filled skutterudite with enhanced thermoelectric performance be considered. Thermoelectric (TE) materials are a very good candidate to achieve a more efficient usage performance of a thermoelectric material is governed by its power factor P ¼ S2 s. The challenge to develop

  15. Photoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2 nanocomposite

    E-Print Network [OSTI]

    coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resources are low cost, environmentally friendly, high efficiency and stability. TiO2 is a strong candidate due

  16. Quasi-zero lattice mismatch and band alignment of BaTiO{sub 3} on epitaxial (110)Ge

    SciTech Connect (OSTI)

    Hudait, M. K.; Zhu, Y.; Jain, N. [Bradley Department of Electrical and Computer Engineering, Virginia Tech, Blacksburg, Virginia 24061 (United States); Maurya, D.; Zhou, Y.; Priya, S [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2013-07-14

    Growth, structural, and band alignment properties of pulsed laser deposited amorphous BaTiO{sub 3} on epitaxial molecular beam epitaxy grown (110)Ge layer, as well as their utilization in low power transistor are reported. High-resolution x-ray diffraction demonstrated quasi-zero lattice mismatch of BaTiO{sub 3} on (110)Ge. Cross-sectional transmission electron microscopy micrograph confirms the amorphous nature of BaTiO{sub 3} layer as well as shows a sharp heterointerface between BaTiO{sub 3} and Ge with no traceable interfacial layer. The valence band offset, {Delta}E{sub v}, of 1.99 {+-} 0.05 eV at the BaTiO{sub 3}/(110)Ge heterointerface is measured using x-ray photoelectron spectroscopy. The conduction band offset, {Delta}E{sub c}, of 1.14 {+-} 0.1 eV is calculated using the bandgap energies of BaTiO{sub 3} of 3.8 eV and Ge of 0.67 eV. These band offset parameters for carrier confinement and the interface chemical properties of the BaTiO{sub 3}/(110)Ge system are significant advancement towards designing Ge-based p-and n-channel metal-oxide semiconductor field-effect transistors for low-power application.

  17. Effect of silicon on ultra-low temperature toughness of Nb–Ti microalloyed cryogenic pressure vessel steels

    SciTech Connect (OSTI)

    Qiu, J.A. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Wu, K.M., E-mail: wukaiming2000@yahoo.com [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Li, J.H. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Research and Development Center of WISCO, Wuhan 430080 (China); Hodgson, P.D. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Institute for Frontier Materials, Deakin University, Geelong, Victoria 3220 (Australia); Hou, T.P. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Ding, Q.F. [Research and Development Center of WISCO, Wuhan 430080 (China)

    2013-09-15

    The effect of Si on the ultra-low temperature toughness of Nb–Ti microalloyed cryogenic pressure vessel steels was investigated by electron back-scattered diffraction and transmission electron microscope with energy dispersive spectroscopy. Equiaxed ferrite and bainite were obtained in the tempered steels with small Si additions. Nanosized Nb–Ti carbides (< 10 nm) were formed in the steel containing 0.05% Si, whereas much coarser carbides (> 30 nm) were found in the steel containing 0.47% Si. The ultra-low temperature toughness of the Nb–Ti microalloyed cryogenic pressure vessel steel was remarkably enhanced by the reduction in the Si content, which was attributed to the pre-existing iron carbide formation before the precipitation of nanosized Nb–Ti carbides during tempering. - Highlights: • Nanosized Nb-Ti carbides formed in the tempered steel with smaller Si addition. • Coarser Nb-Ti carbides formed in the tempered steel with more Si addition. • Pre-existing cememtites provide nucleation sites for Nb-Ti carbide precipitation. • Ultra-low temperature toughness was remarkably enhanced by Si content reduction.

  18. Atomic structures and electronic properties of 2H-NbSe{sub 2}: The impact of Ti doping

    SciTech Connect (OSTI)

    Li, Hongping, E-mail: hpli@mail.ujs.edu.cn, E-mail: zcwang@wpi-aimr.tohoku.ac.jp; Chen, Lin; Zhang, Kun; Liang, Jiaqing; Tang, Hua; Li, Changsheng [Institute for Advanced Materials, School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013 (China); Liu, Xiaojuan; Meng, Jian [State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Wang, Zhongchang, E-mail: hpli@mail.ujs.edu.cn, E-mail: zcwang@wpi-aimr.tohoku.ac.jp [Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-09-14

    Layered transition metal dichalcogenides have aroused renewed interest as electronic materials, yet their electronic performances could be modified by chemical doping. Here, we perform a systematic first-principles calculation to investigate the effect of Ti doping on atomic structure and electronic properties of the 2H-NbSe{sub 2}. We consider a total of three possible Ti-doping models and find that both the substitution and intercalated models are chemically preferred with the intercalation model being more favorable than the substitution one. Structural analyses reveal a slight lattice distortion triggered by Ti doping, but the original structure of 2H-NbSe{sub 2} is maintained. We also observe an expansion of c axis in the substituted model, which is attributed to the reduced van der Waals interaction arising from the increased Se-Se bond length. Our calculations also predict that the electron transport properties can be enhanced by the Ti doping, especially for the Ti-intercalated 2H-NbSe{sub 2}, which should be beneficial for the realization of superconductivity. Furthermore, the covalence element is found in the Ti-Se bonds, which is ascribed to the hybridization of Ti 3d and Se 4p orbitals. The findings indicate that doping of transition metals can be regarded as a useful way to tailor electronic states so as to improve electron transport properties of 2H-NbSe{sub 2}.

  19. Study of structure of the TiO{sub 2}–MoO{sub 3} bilayer films by Raman spectroscopy

    SciTech Connect (OSTI)

    Santos, Elias de Barros; Sigoli, Fernando Aparecido; Mazali, Italo Odone

    2014-12-15

    Highlights: • TiO{sub 2}–MoO{sub 3} bilayer thin films were easily prepared by dip-coating technique. • Ti and Mo metallo-organic compounds were used as source of its respective oxide. • TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3} were identified. • The bilayer structure was investigated by Raman spectroscopy. - Abstract: In this work, TiO{sub 2}–MoO{sub 3} films were easily prepared by dip-coating technique and metallo-organic decomposition process (MOD). Raman analyses indicate the formation of TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3}. It was observed that the Raman bands intensities attributed to TiO{sub 2} and MoO{sub 3} oxides were dependent on the number of decomposition–deposition cycles (DDC). The different number of DDC generates films with different thicknesses and the Raman signal was sensitive to this variation. Raman analyses provided qualitative information about the bilayer structure of the bi-component TiO{sub 2}–MoO{sub 3} films, which was confirmed by scanning electron microscopy. In this direction, the dip-coating technique and MOD process can be an efficient strategy to facile preparation of many samples to be used in applications.

  20. Physical properties and electronic structure of a new barium titanate suboxide Ba1+?Ti13-?O?? (? = 0.11)

    SciTech Connect (OSTI)

    Rotundu, Costel R.; Jiang, Shan; Deng, Xiaoyu; Qian, Yiting; Khan, Saeed; Hawthorn, David G.; Kotliar, Gabriel; Ni, Ni

    2015-04-01

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+?Ti13-?O?? (? = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti²? state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of the Ti?? semi-cluster and the TiO? quasi-squares, respectively.