National Library of Energy BETA

Sample records for tion releases sulfur

  1. CUSSSFIC4TION CMUXLLq

    Office of Legacy Management (LM)

    CUSSSFIC4TION CMUXLLq RITE AUG 1 7 1962 Fcx the Atomic. Energy Commisaion~ Chief. Declaseifle@tlon Brar\qh F-mm A. B. Grsaingsr (Other ends tifmtioel) The die wae foutq3 to workvery satiafactorilywiti thlanew Qpeof incert, andncm,of tbepmvLouedsfeotaofeoo+tH&' iOitYwaslmd. D&e& ._: . . ..YG ~Kl.3. i>ro;rid3 -&I:: clcsuro on bct.k.mds of the .plece m & Die #l, is also to be tried outoo 4zgust22. Barr~l~or~~~Die~~hadalaobeenawlLfiedta' plwidesd~do~-

  2. CLASSIFICdTION CAWXL~ DAm

    Office of Legacy Management (LM)

    CLASSIFICdTION CAWXL~ DAm NAR 6 1969 For the Atomic EhergY hDh=+= ,' ROBERT L JACKSON /(\' t' for the Chief, Declassification B~Jx~

  3. Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

  4. Sulfur mustard primes human neutrophils for increased degranulation and stimulates cytokine release via TRPM2/p38 MAPK signaling

    SciTech Connect (OSTI)

    Ham, Hwa-Yong; Hong, Chang-Won; Lee, Si-Nae; Kwon, Min-Soo; Kim, Yeon-Ja; Song, Dong-Keun

    2012-01-01

    Sulfur mustard (2,2′-bis-chloroethyl-sulfide; SM) has been a military threat since the World War I. The emerging threat of bioterrorism makes SM a major threat not only to military but also to civilian world. SM injury elicits an inflammatory response characterized by infiltration of neutrophils. Although SM was reported to prime neutrophils, the mechanism has not been identified yet. In the present study, we investigated the mechanism of SM-induced priming in human neutrophils. SM increased [Ca{sup 2+}]{sub i} in human neutrophils in a concentration-dependent fashion. Transient receptor potential melastatin (TRPM) 2 inhibitors (clotrimazole, econazole and flufenamic acid) and silencing of TRPM2 by shRNA attenuated SM-induced [Ca{sup 2+}]{sub i} increase. SM primed degranulation of azurophil and specific granules in response to activation by fMLP as previously reported. SB203580, an inhibitor of p38 MAPK, inhibited SM-induced priming. Neither PD98057, an ERK inhibitor, nor SP600215, a JNK inhibitor, inhibited SM-induced priming. In addition, SM enhanced phosphorylation of NF-kB p65 and release of TNF-α, interleukin (IL)-6 and IL-8. SB203580 inhibited SM-induced NF-kB phosphorylation and cytokine release. These results suggest the involvement of TRPM2/p38 MAPK pathway in SM-induced priming and cytokines release in neutrophils. -- Highlights: ► SM increased [Ca{sup 2+}]{sub i} in human neutrophils through TPRM2-mediated calcium influx. ► SM primed degranulation of azurophil and specific granules. ► SM enhanced p38 MAPK and NF-κB p65 phosphorylation in human neutrophils. ► SM enhanced release of TNF-α, interleukin (IL)-6 and IL-8 from human neutrophils. ► SB203580 inhibited SM-induced priming, NF-κB p65 phosphorylation and cytokine release.

  5. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H.

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  6. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur...

    Office of Scientific and Technical Information (OSTI)

    Title: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur ...

  7. Releases from the Heating Oil Reserve | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Releases from the Heating Oil Reserve Releases from the Heating Oil Reserve The Northeast Home Heating Oil Reserve (NEHHOR), a one million barrel supply of ultra low sulfur ...

  8. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  9. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  10. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  11. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  12. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Hu, Zhicheng

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  13. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  14. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  15. Bacterial Sulfur Storage Globules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for...

  16. Separation of sulfur isotopes

    DOE Patents [OSTI]

    DeWitt, Robert; Jepson, Bernhart E.; Schwind, Roger A.

    1976-06-22

    Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

  17. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, Nand K.; Ruether, John A.; Smith, Dennis N.

    1988-01-01

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

  18. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, N.K.; Ruether, J.A.; Smith, D.N.

    1987-10-07

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

  19. News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases News Releases We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. News Releases - 2016» News Releases - 2015» News Releases - 2014» News Releases - 2013» News Releases - 2012» News Releases - 2011» News Releases - 2010» News Releases - 2009» News Releases - 2008» The thermal traits of a leaf, critical for photosynthesis, may be under strong evolutionary selection

  20. Sodium-sulfur thermal battery

    SciTech Connect (OSTI)

    Ludwig, F.A.

    1990-12-11

    This paper discusses a sodium-sulfur thermal battery for generating electrical energy at temperatures above the melting point of sodium metal and sulfur. It comprises a sodium electrode comprising sodium metal; a sulfur electrode comprising sulfur; and a separator located between the sodium and sulfur electrodes. The separator having sufficient porosity to allow preliminary migration of fluid sodium metal and fluid sulfur and fluid sodium polysulfides therethrough during operation of the thermal battery to form a mixed polysulfides electrolyte gradient within the separator.

  1. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Mikkor, Mati

    1981-01-01

    This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

  2. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun; Yu, Qiquan; Chang, Shih-Ger

    1996-01-01

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

  3. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Topouzian, Armenag

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  4. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P.

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  5. SULFUR POLYMER ENCAPSULATION.

    SciTech Connect (OSTI)

    KALB, P.

    2001-08-22

    Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not

  6. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  7. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  8. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  9. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  10. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T.; Jozewicz, Wojciech

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  11. Volume efficient sodium sulfur battery

    DOE Patents [OSTI]

    Mikkor, Mati

    1980-01-01

    In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

  12. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    globally distributed sulfur-oxidizing bacteria in the deep sea carry bacterial genes for the oxidation of elemental sulfur. Although such observations are common in...

  13. News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Releases News Releases Accessible by Topic, Keywords (See "Search Releases") or Chronologically (See "ALL") News Releases Science Briefs Photos Picture of the Week Publications Social Media Videos Fact Sheets The thermal traits of a leaf, critical for photosynthesis, may be under strong evolutionary selection that occurs in response to environmental temperatures. Here a thermal leaf image details temperature variation, which greatly affects plant functions since

  14. Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    SciTech Connect (OSTI)

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

    2015-04-07

    A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

  15. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    DOE Patents [OSTI]

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

    2014-06-17

    Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

  16. Alkali metal/sulfur battery

    DOE Patents [OSTI]

    Anand, Joginder N.

    1978-01-01

    Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

  17. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur ...

  18. Martinez Sulfuric Acid Regeneration Plt Biomass Facility | Open...

    Open Energy Info (EERE)

    Martinez Sulfuric Acid Regeneration Plt Biomass Facility Jump to: navigation, search Name Martinez Sulfuric Acid Regeneration Plt Biomass Facility Facility Martinez Sulfuric Acid...

  19. Identification of Martian Regolith Sulfur Components In Shergottites...

    Office of Scientific and Technical Information (OSTI)

    Sulfur Components In Shergottites Using Sulfur K XANES and FeS Ratios. Citation Details In-Document Search Title: Identification of Martian Regolith Sulfur Components In ...

  20. FINAL RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE AWARDEE: ____________________________________________________ The work under Award No. DE-__________________________, dated ______________, between the United States of America (represented by the Department of Energy, National Energy Technology Laboratory, and the undersigned awardee, having been completed and finally accepted , and in consideration of Final Payment thereunder, the United States of America, its officers, agents and employees are hereby released from all liabilities,

  1. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","6/2016","1/15/1985" ,"Release Date:","8/31/2016" ,"Next Release

  2. The SpallaTion

    Office of Environmental Management (EM)

    The Science Behind Cheaper Biofuels The Science Behind Cheaper Biofuels August 15, 2011 - 11:50am Addthis Brookhaven National Laboratory is modeling the metabolic processes in rapeseed plants to optimize production of plant oils for biofuels. Shown above are developing embryos extracted from a growing rapeseed plant. The embryos accumulate seed oils which represent the most energy-dense form of biologically stored sunlight, and have great potential as renewable resources for fuel and industrial

  3. Seal for sodium sulfur battery

    DOE Patents [OSTI]

    Topouzian, Armenag; Minck, Robert W.; Williams, William J.

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  4. Recovery of sulfur from native ores

    SciTech Connect (OSTI)

    Womack, J.T.; Wiewiorowski, T.K.; Astley, V.C.; Perez, J.W.; Headington, T.A.

    1992-03-17

    This patent describes a process for removing elemental sulfur from ores containing elemental sulfur. It comprises crushing a sulfur-containing ore to a coarse particle size wherein ore particles produced during crushing enable substantially all of the sulfur to be liberated during a heating step and to produce an ore gangue that is substantially not susceptible to flotation: forming an aqueous ore slurry containing about 50-80% by weight of solids from the crushed ore and adjusting the pH to at least a pH of about 8.0; heating the aqueous ore slurry formed in step (b) under elevated pressure to a temperature of about 240{degrees} - 315{degrees} F. for sufficient time to melt and liberate elemental sulfur contained in the ore to produce liberated molten sulfur and ore gangue, wherein the slurry is heated while agitating the slurry at sufficient velocity to substantially maintain the ore, ore gangue and liberated molten sulfur in suspension; cooling the heated slurry sufficiently to resolidify the liberated molten sulfur; conditioning the aqueous slurry of step (d) with a flotation aid; separating the condition aqueous slurry of ore gangue and resolidified sulfur in a flotation unit to produce a sulfur-rich flotation concentrate overstream; and recovering the sulfur-rich flotation concentrate and separating the sulfur therefrom.

  5. Two stage sorption of sulfur compounds

    DOE Patents [OSTI]

    Moore, William E.

    1992-01-01

    A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

  6. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key partsa positive and negative electrode and an electrolytethat exchange ions to store and release electricity. Using different materials for these components changes a batterys chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  7. Catalytic conversion of sulfur dioxide and trioxide

    SciTech Connect (OSTI)

    Solov'eva, E.L.; Shenfel'd, B.E.; Kuznetsova, S.M.; Khludenev, A.G.

    1987-11-10

    The reclamation and utilization of sulfur-containing wastes from the flue gas of fossil-fuel power plants and the subsequent reduction in sulfur emission is addressed in this paper. The authors approach this problem from the standpoint of the catalytic oxidation of sulfur dioxide on solid poison-resistant catalysts with subsequent sorption of the sulfur trioxide and its incorporation into the manufacture of sulfuric acid. The catalyst they propose is a polymetallic dust-like waste from the copper-smelting industry comprised mainly of iron and copper oxides. Experiments with this catalyst were carried out using multifactorial experiment planning.

  8. Process for reducing sulfur in coal char

    DOE Patents [OSTI]

    Gasior, Stanley J.; Forney, Albert J.; Haynes, William P.; Kenny, Richard F.

    1976-07-20

    Coal is gasified in the presence of a small but effective amount of alkaline earth oxide, hydroxide or carbonate to yield a char fraction depleted in sulfur. Gases produced during the reaction are enriched in sulfur compounds and the alkaline earth compound remains in the char fraction as an alkaline earth oxide. The char is suitable for fuel use, as in a power plant, and during combustion of the char the alkaline earth oxide reacts with at least a portion of the sulfur oxides produced from the residual sulfur contained in the char to further lower the sulfur content of the combustion gases.

  9. NONEQUILIBRIUM SULFUR CAPTURE & RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR

    SciTech Connect (OSTI)

    Bert Zauderer

    2003-04-21

    Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. The reacted particles impact and melt in the liquid slag layer on the combustor wall by the centrifugal force of the swirling combustion gases. Due to the low solubility of sulfur in slag, it must be rapidly drained from the combustor to limit sulfur gas re-evolution. Prior analyses and laboratory scale data indicated that for Coal Tech's 20 MMBtu/hour, air-cooled, slagging coal combustor slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to validate this sulfur-in-slag model in a group of combustor tests. A total of 36 days of testing on the combustor were completed during the period of performance of this project. This was more that double the 16 test days that were required in the original work statement. The extra tests were made possible by cost saving innovations that were made in the operation of the combustor test facility and in additional investment of Coal Tech resources in the test effort. The original project plan called for two groups of tests. The first group of tests involved the injection of calcium sulfate particles in the form of gypsum or plaster of Paris with the coal into the 20 MMBtu/hour-combustor. The second group of tests consisted of the entire two-step process, in which lime or limestone is co-injected with coal and reacts with the sulfur gas released during combustion to form calcium sulfate particles that impact and dissolve in the slag layer. Since this sulfur capture process has been validated in numerous prior tests in this combustor, the primary effort in the present project was on achieving the high slag flow rates needed to retain the sulfur in the slag.

  10. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  11. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfurmore » were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.« less

  12. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfur were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.

  13. On the formation of carbonyl sulfide in the reduction of sulfur dioxide by carbon monoxide on lanthanum oxysulfide catalyst: A study by XPS and TPR/MS

    SciTech Connect (OSTI)

    Lau, N.T.; Fang, M. [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center] [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center

    1998-10-25

    Both the X-ray photoelectron spectroscopy (XPS) and temperature-programmed reaction, coupled with mass spectrometry (TPR/MS), are used to study the formation of carbonyl sulfide in the reduction of sulfur dioxide on lanthanum oxysulfide catalyst. It was found that the lattice sulfur of the oxysulfide is released and reacts with carbon monoxide to form carbonyl sulfide when the oxysulfide is heated. The oxysulfide is postulated to form sulfur vacancies at a temperature lower than that for the formation of carbonyl sulfide and atomic sulfur is released in the process. The atomic sulfur can either enter the gas phase and leave the oxysulfide catalyst or react with carbon monoxide to form carbonyl sulfide.

  14. code release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    code release - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  15. Grain Boundary Percolation Modeling of Fission Gas Release in Oxide Fuels

    SciTech Connect (OSTI)

    Paul C. Millett; Michael R. Tonks; S. B. Biner

    2012-05-01

    We present a new approach to fission gas release modeling in oxide fuels based on grain boundary network percolation. The method accounts for variability in the bubble growth and coalescence rates on individual grain boundaries, and the resulting effect on macroscopic fission gas release. Two-dimensional representa- tions of fuel pellet microstructures are considered, and the resulting gas release rates are compared with traditional two-stage Booth models, which do not account for long-range percolation on grain boundary net- works. The results show that the requirement of percolation of saturated grain boundaries can considerably reduce the total gas release rates, particularly when gas resolution is considered.

  16. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  17. Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries

    SciTech Connect (OSTI)

    Liang, Chengdu; Dudney, Nancy J; Howe, Jane Y

    2015-05-05

    The invention is directed in a first aspect to a sulfur-carbon composite material comprising: (i) a bimodal porous carbon component containing therein a first mode of pores which are mesopores, and a second mode of pores which are micropores; and (ii) elemental sulfur contained in at least a portion of said micropores. The invention is also directed to the aforesaid sulfur-carbon composite as a layer on a current collector material; a lithium ion battery containing the sulfur-carbon composite in a cathode therein; as well as a method for preparing the sulfur-composite material.

  18. Northeast Home Heating Oil Reserve (NEHHOR) Releases | Department of Energy

    Energy Savers [EERE]

    Releases Northeast Home Heating Oil Reserve (NEHHOR) Releases The Northeast Home Heating Oil Reserve (NEHHOR), a one million barrel supply of ultra low sulfur distillate (diesel), was created to build a buffer to allow commercial companies to compensate for interruptions in supply during severe winter weather, The first emergency use of NEHHOR was in 2012. Emergency Loans after Hurricane Sandy In late October 2012, Hurricane Sandy made landfall on the northeastern shore of the United States,

  19. Stabilized sulfur binding using activated fillers

    DOE Patents [OSTI]

    Kalb, Paul D.; Vagin, Vyacheslav P.; Vagin, Sergey P.

    2015-07-21

    A method of making a stable, sulfur binding composite comprising impregnating a solid aggregate with an organic modifier comprising unsaturated hydrocarbons with at least one double or triple covalent bond between adjacent carbon atoms to create a modifier-impregnated aggregate; heating and drying the modifier-impregnated aggregate to activate the surface of the modifier-impregnated aggregate for reaction with sulfur.

  20. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu; King, David L.

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  1. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G.; Mohan, Thyagarajan; Angelici, Robert J.

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  2. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 ...

  3. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  4. Scientists Probe Lithium-Sulfur Batteries in Real Time - Joint...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7, 2012, Videos Scientists Probe Lithium-Sulfur Batteries in Real Time Lithium-sulfur batteries are a promising technology that could some day power electric vehicles. Scientists ...

  5. Understanding Lithium-Sulfur Batteries at the Molecular Level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 17, 2015, Accomplishments Understanding Lithium-Sulfur Batteries at the Molecular Level Conceived some 40 years ago, the lithium-sulfur battery can store, in theory, ...

  6. Sulfur Poisoning of Metal Membranes for Hydrogen Separation ...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Sulfur Poisoning of Metal Membranes for Hydrogen Separation Citation Details In-Document Search Title: Sulfur Poisoning of Metal Membranes for Hydrogen Separation ...

  7. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Newsroom Press Releases Newsroom Press Releases Media Contacts Photo Gallery The Hanford Story Hanford Blog Hanford YouTube Channel

  8. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  9. A new, safer method of sulfur degassing

    SciTech Connect (OSTI)

    Schico, C.M.; Clem, K.R.; Hartley, D.; Watson, E.A.

    1985-10-01

    The Exxon system for degassing liquid sulfur is presented, and it can reduce total H2S in liquid sulfur to levels as low as 10-15 wppm under the commercial conditions tested. Because Exxon found commercially available mechanical degassing systems to be inadequate, the Claus plant initiated an RandD program to develop the new degassing process. Hydrogen sulfide and hydrogen polysulfide are inherent to the Claus process. The major concerns associated with this H2S in the Claus liquid sulfur include: toxic levels of H2S are possible while loading/unloading liquid sulfur; the H2S lower explosive limit in air can be exceeded in unvented pit/tank vapor space; nuisance odors/environmental concerns; and potential government regulations/ customer restrictions. Results are presented in this article of successful commercial tests using the process at five sites.

  10. Definition of Non-Conventional Sulfur Utilization in Western Kazakhstan for Sulfur Concrete (Phase 1)

    SciTech Connect (OSTI)

    Kalb, Paul

    2007-05-31

    Battelle received a contract from Agip-KCO, on behalf a consortium of international oil and gas companies with exploration rights in the North Caspian Sea, Kazakhstan. The objective of the work was to identify and help develop new techniques for sulfur concrete products from waste, by-product sulfur that will be generated in large quantitites as drilling operations begin in the near future. BNL has significant expertise in the development and use of sulfur concrete products and has direct experience collaborating with the Russian and Kazakh partners that participated. Feasibility testing was successfully conducted for a new process to produce cost-effective sulfur polymer cement that has broad commerical applications.

  11. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    DOE Patents [OSTI]

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  12. Copper mercaptides as sulfur dioxide indicators

    DOE Patents [OSTI]

    Eller, Phillip G.; Kubas, Gregory J.

    1979-01-01

    Organophosphine copper(I) mercaptide complexes are useful as convenient and semiquantitative visual sulfur dioxide gas indicators. The air-stable complexes form 1:1 adducts in the presence of low concentrations of sulfur dioxide gas, with an associated color change from nearly colorless to yellow-orange. The mercaptides are made by mixing stoichiometric amounts of the appropriate copper(I) mercaptide and phosphine in an inert organic solvent.

  13. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  14. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, Tetsuo; Squires, Thomas G.; Venier, Clifford G.

    1985-02-05

    A process for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  15. Spray drying for high-sulfur coal

    SciTech Connect (OSTI)

    Rhudy, R.

    1988-09-01

    Recent pilot plant tests indicate that spray drying, now used to control SO/sub 2/ emissions from low-sulfur coal, can also be effective for high-sulfur coal. Spray drying coupled with baghouse particulate removal is the most effective configuration tested to date, removing over 90% of SO/sub 2/ while easily meeting New Source Performance Standards for particulate emissions. 2 figures, 1 table.

  16. World copper smelter sulfur balance-1988

    SciTech Connect (OSTI)

    Towle, S.W. )

    1993-01-01

    In 1989, the US Bureau of Mines initiated a contract to gather engineering, operating, and environmental cost data for 1988 for 30 major foreign primary copper smelters in market economy countries. Data were collected for 29 of the designated smelters together with information on applicable environmental regulations. Materials balance data obtained were used with available data for the eight US smelters to determine the approximate extent of copper smelter sulfur emission control in 1988. A broad characterization of the status of sulfur emission control regulation was made. The 37 US and foreign smelters represented roughly 73.2% of world and 89.3% of market economy primary copper production in 1988. The 29 non-US smelters attained 55.3% control of their input sulfur in 1988. Combined with the 90.4% control of US smelters, an aggregate 63.4% sulfur control existed. Roughly 1,951,100 mt of sulfur was emitted from the 37 market economy smelters in 1988. Identifiable SO[sub 2] control regulations covered 72.4% of the 29 foreign smelters, representing 65.5% of smelting capacity. Including US smelters, 78.4% of the major market economy smelters were regulated, representing 73.1% of smelting capacity. Significant changes since 1988 that may increase sulfur emission control are noted.

  17. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  18. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore » cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  19. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; Yang, Xiao-Qing; Zhang, Ji-Guang; Liu, Jun; Xiao, Jie

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  20. Electrostatic self-assembly of graphene oxide wrapped sulfur particles for lithium–sulfur batteries

    SciTech Connect (OSTI)

    Wu, Haiwei; Huang, Ying Zong, Meng; Ding, Xiao; Ding, Juan; Sun, Xu

    2015-04-15

    Highlights: • Researched graphene oxide wrapped sulfur particles for lithium–sulfur batteries. • New approach for core–shell GO/S composites by electrostatic self-assembly method. • Both core–shell structure and the GO support help to retard the diffusion of polysulfides during the electrochemical cycling process of GO/S cathode. - Abstract: A novel graphene oxide (GO)/sulfur (S) composite is developed by electrostatic self-assembly method. Remarkably, the core–shell structure of the composite and the GO support helps to retard the diffusion of polysulfides during the electrochemical cycling process. The GO/sulfur cathode presents enhanced cycling ability. Specific discharge capacities up to 494.7 mAh g{sup −1} over 200 cycles at 0.1 C is achieved with enhanced columbic efficiency around 95%, representing a good cathode material for lithium–sulfur batteries.

  1. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  2. Effect of sulfur content in a sulfur-activated carbon composite on the electrochemical properties of a lithium/sulfur battery

    SciTech Connect (OSTI)

    Park, Jin-Woo; Kim, Changhyeon; Ryu, Ho-Suk; Cho, Gyu-Bong; Cho, Kwon-Koo; Kim, Ki-Won; Ahn, Jou-Hyeon; Wang, Guoxiu; Ahn, Jae-Pyeung; Ahn, Hyo-Jun

    2015-09-15

    Highlights: • The content of sulfur in activated carbon was controlled by solution process. • The sulfur electrode with low sulfur content shows the best performance. • The Li/S battery has capacity of 1360 mAh/g at 1 C and 702 mAh/g at 10 C. - Abstract: The content of sulfur in sulfur/activated carbon composite is controlled from 32.37 wt.% to 55.33 wt.% by a one-step solution-based process. When the sulfur content is limited to 41.21 wt.%, it can be loaded into the pores of an activated carbon matrix in a highly dispersed state. On the contrary, when the sulfur content is 55.33 wt.%, crystalline sulfur can be detected on the surface of the activated carbon matrix. The best electrochemical performance can be obtained for a sulfur electrode with the lowest sulfur content. The sulfur/activated carbon composite with 32.37 wt.% sulfur afforded the highest first discharge capacity of 1360 mAh g{sup −1} at 1 C rate and a large reversible capacity of 702 mAh g{sup −1} at 10 C (16.75 A/g)

  3. SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-07-03

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for

  4. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Vehicle Technologies ...

  5. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Protection of Li Anodes ...

  6. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Richland Operations Office Newsroom Press Releases Richland Operations Office Richland Operations Office River Corridor Central Plateau Groundwater Mission Support Newsroom Press Releases News Calendar

  7. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of River Protection Newsroom Press Releases Office of River Protection About ORP ORP Projects & Facilities Newsroom Photos & Multimedia ORP Events Press Releases Contracts & ...

  8. Latest News Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Release Release Date: Contact: Shelley Martin, DOE National Energy Technology Laboratory, 304-285-0228, contact.publicaffairs@netl.doe.gov 2016 2015 2014 2013

  9. Photodissociation spectroscopy of the carbonyl sulfide ion with momentum analysis of the sulfur product ion

    SciTech Connect (OSTI)

    Snow, K.B.

    1993-01-01

    A Nuclide 12-90-G mass spectrometer was modified for use as a photofragment momentum spectrometer. The resultant apparatus was capable of obtaining both absolute cross sections for photodissociation with respect to wavelength and relative cross sections for photodissociation with respect to kinetic energy release. The kinetic energy release for the photodissociation reaction of the nitrous oxide cation (leading to the production of the nitric oxide cation and the nitrogen atom), was studied at 3080.4 [angstrom], 3371.3 [angstrom], and 3381.4 [angstrom]. When a nitrogen atom was produced in the [sup 4]S state, the nitric oxide cation was found to be formed predominantly with 5 to 7 quanta of vibrational energy. Nitrogen atoms were formed preferentially in the [sup 2]D state when it was energetically feasible at 3371.3 [angstrom] and 3080.4 [angstrom]. The kinetic energy release for the photodissociation reaction of the carbonyl sulfide cation (leading to the production of carbon monoxide and a sulfur cation), was studied at 2822.2 [angstrom], 2921.8 [angstrom], 2991.0 [angstrom], 2991.9 [angstrom], 3080.4 [angstrom], 3104.3 [angstrom], 3127.9 [angstrom], 3184.9 [angstrom], 3351.8 [angstrom], 3371.3 [angstrom], and 3393.0 [angstrom]. When sulfur cations were produced in the [sup 4]S state, the carbon monoxide products were formed predominantly with 5 to 7 quanta of vibrational energy. Sulfur cations were formed preferentially in the [sup 2]D state from hot bands at 3351.8 [angstrom], 3080.4 [angstrom], and 2991.9 [angstrom]. Sulfur cations were also produced in the [sup 2]D state at 2921.8 [angstrom] and 2822.2 [angstrom], where it was energetically feasible from the ground state of carbonyl sulfide cations.

  10. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  11. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, Perry E.

    1981-01-01

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another.

  12. Heat Release Rates

    Broader source: Energy.gov [DOE]

    Supporting Technical Document for the Radiological Release Accident Investigation Report (Phase II Report)

  13. Effect of Sulfur on Solid Oxide Fuel Cell (SOFC) Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effect of Sulfur on SOFC Performance Using Diesel Reformate R. Kerr March 6-7, 2014 Workshop on Gas Cleanup for Fuel Cell Applications, ANL, March 6-7, 2014 Sulfur Poisoning Effect ...

  14. EPA Diesel Rule and the Sulfur Effects (DECSE) Project

    SciTech Connect (OSTI)

    2009-05-08

    The VT program collaborated with industry stakeholders and the EPA (in an effort initiated in 1998 called Diesel Emission Control – Sulfur Effects study, otherwise known as DECSE) to quantify the effects of fuel sulfur on emission control technologies.

  15. Potential Release Sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PRS Potential Release Sites Legacy sites where hazardous materials are found to be above acceptable levels are collectively called potential release sites. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Less than 10 percent of the total number of potential release sites need to go through the full corrective action process. What are potential release sites? Potential release sites are areas around the Laboratory and

  16. Sulfuric acid thermoelectrochemical system and method

    DOE Patents [OSTI]

    Ludwig, Frank A.

    1989-01-01

    A thermoelectrochemical system in which an electrical current is generated between a cathode immersed in a concentrated sulfuric acid solution and an anode immersed in an aqueous buffer solution of sodium bisulfate and sodium sulfate. Reactants consumed at the electrodes during the electrochemical reaction are thermochemically regenerated and recycled to the electrodes to provide continuous operation of the system.

  17. Anodes for Rechargeable Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Xu, Wu; Lu, Dongping; Xiao, Jie; Zhang, Jiguang

    2015-04-10

    In this work, we will review the recent developments on the protection of Li metal anode in Li-S batteries. Various strategies used to minimize the corrosion of Li anode and reducing its impedance increase will be analyzed. Other potential anodes used in sulfur based rechargeable batteries will also be discussed.

  18. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T.; Chang, John C. S.

    1991-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  19. Preliminary Release: March 28, 2011",,,,,,,,,,,,"Released: April 2013","Released

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,,,,,,,,,,"Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April

  20. Tailoring Pore Size of Nitrogen-Doped Hollow Carbon Nanospheres for Confi ning Sulfur in LithiumSulfur Batteries

    SciTech Connect (OSTI)

    Zhou, Weidong; Wang, Chong M.; Zhang, Quiglin; Abruna, Hector D.; He, Yang; Wang, Jiangwei; Mao, Scott X.; Xiao, Xingcheng

    2015-08-19

    Three types of nitrogen-doped hollow carbon spheres with different pore sized porous shells are prepared to investigate the performance of sulfur confinement. The reason that why no sulfur is observed in previous research is determined and it is successfully demonstrated that the sulfur/polysulfide will overflow the porous carbon during the lithiation process.

  1. WIPP News Release Archives Index

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WIPP News Release Archives 2006 News Releases 2005 News Releases 2004 News Releases 2003 News Releases 2002 News Releases 2001 News Releases 2000 News Releases 1999 News Releases 1998 News Releases 1997 News Releases 1996 News Releases 1995 News Releases Back to 2007 News Releases If you have any questions regarding the above, contact: Dennis Hurtt, Team Leader Office of Public Affairs DOE, Carlsbad Field Office P.O. Box 3090 Carlsbad, NM 88221-3090 Phone: 505/234-7327 Fax: 505/234-7025 E-mail:

  2. CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H

    2007-01-31

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

  3. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  4. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  5. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Liu, Wei

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  6. ELECTROMAGNETIC RELEASE MECHANISM

    DOE Patents [OSTI]

    Michelson, C.

    1960-09-13

    An electromagnetic release mechanism is offered that may be used, for example, for supporting a safety rod for a nuclear reactor. The release mechanism is designed to have a large excess holding force and a rapid, uniform, and dependable release. The fast release is accomplished by providing the electromagnet with slotttd polts separated by an insulating potting resin, and by constructing the poles with a ferro-nickel alloy. The combination of these two features materially reduces the eddy current power density whenever the magnetic field changes during a release operation. In addition to these features, the design of the armature is such as to provide ready entrance of fluid into any void that might tend to form during release of the armature. This also improves the release time for the mechanism. The large holding force for the mechanism is accomplished by providing a small, selected, uniform air gap between the inner pole piece and the armature.

  7. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S.; Corbeels, Roger J.; Kokturk, Uygur

    1989-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  8. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  9. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current News Releases March 20, 2015 - Event News Release #2 WIPP Emergency Operations Center Deactivated March 20, 2015 - Event News Release #1 Emergency Operation Center Activated as Precautionary Measure for Offsite Event November 25, 2014 CBFO and WIPP Volunteerism Helps Little Ones This Winter Karing for Kids Koat Drive November 10, 2014 CBFO and WIPP Commemorations for Veterans Day 2014 Photo 1: Veterans Commeration at Skeen-Whitlock, Nov. 6, 2014 Photo 2: Veterans Commeration at

  10. Sulfur-impurity Induced Amorphization of Nickel | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility Sulfur-impurity Induced Amorphization of Nickel Authors: Yuan, Z., Chen, H.P, Wang, W., Nomura, K., Kalia, R.K., Nakano, A., Vashishta, P. Recent experimental and theoretical studies have shown an essential role of sulfur segregation-induced amorphization of crystalline nickel leading to its embrittlement at a critical sulfur concentration of ∼14%, but the atomistic mechanism of the amorphization remains unexplained. Here, molecular dynamics simulations reveal that the

  11. Removal of sulfur compounds from combustion product exhaust

    DOE Patents [OSTI]

    Cheng, Dah Y.

    1982-01-01

    A method and device are disclosed for removing sulfur containing contaminents from a combustion product exhaust. The removal process is carried out in two stages wherein the combustion product exhaust is dissolved in water, the water being then heated to drive off the sulfur containing contaminents. The sulfur containing gases are then resolublized in a cold water trap to form a concentrated solution which can then be used as a commercial product.

  12. Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Joint Center for Energy Storage Research August 24, 2016, Videos Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries As JCESR scientists work to develop lighter and less expensive chemistries than those used in current lithium-ion batteries, lithium-sulfur shows tremendous promise. However, current lithium-sulfur batteries require an excessive amount of electrolyte to achieve moderate cycle life. This perspective presents an alternate approach of

  13. Sulfide catalysts for reducing SO2 to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun; Yu, Qiquan; Chang, Shih-Ger

    2001-01-01

    A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

  14. Project Profile: Baseload CSP Generation Integrated with Sulfur-Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Heat Storage | Department of Energy Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage Project Profile: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage General Atomics logo General Atomics, under the Baseload CSP FOA, demonstrated the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power generation. Approach Graphic of a diagram of squares and

  15. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    email bland@fnal.gov For Immediate Release Fermilab Colloquium Series Offers Free Public Talks on World Energy Situation Beginning Wednesday, April 13 BATAVIA,...

  16. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sdahl@fnal.gov For Immediate Release Children's Science Adventures at Fermilab Offer Summer Fun - and Learning, Too BATAVIA, Illinois-Summertime is a bright season of...

  17. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    email mikep@fnal.gov For Immediate Release NRELs John Turner Explores The Sustainable Hydrogen Economy in Energy Colloquium Presentation at Fermilab on Wednesday, July 6;...

  18. Press Releases | JCESR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases New Hybrid Electrolyte for Solid-State Lithium Batteries December 21, 2015 Scientists at the U.S. Department of Energy's Lawrence Berkeley National Laboratory have...

  19. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    26, 1999 For immediate release PRESS ADVISORY: SIGN UP FOR COVERAGE OF MAIN INJECTOR DEDICATION ON TUESDAY, JUNE 1; RICHARDSON, HASTERT TO SPEAK Batavia, Ill.Secretary of...

  20. Extraction of Sulfur Mustard Metabolites from Urine Samples and...

    Office of Scientific and Technical Information (OSTI)

    Title: Extraction of Sulfur Mustard Metabolites from Urine Samples and Analysis by Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) Authors: Mayer, B P ; Williams, ...

  1. Microsoft Word - Updated Air Dispersion Modeling Table _sulfur...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DIVINE STRAKE AIR DISPERSION MODELING RESULTS for SULFUR DIOXIDE The attached table is ... within the Nevada Ambient Air Quality Standards at the boundary of the Nevada Test Site. ...

  2. Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of doped mesoporous carbon and elemental sulfur at a temperature inside a stainless steel vessel, which was used in lithiumsulfur batteries that were tested in ...

  3. Project Profile: Baseload CSP Generation Integrated with Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrating Solar Power Project Profile: Baseload CSP Generation Integrated with Sulfur-Based ... General Atomics is seeking a better thermal energy storage approach using ...

  4. Following the Transient Reactions in Lithium-Sulfur Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Following the Transient Reactions in Lithium-Sulfur Batteries Using an In Situ Nuclear ... cell electrochemical reactions in Li-S batteries using a microbattery design Interphase ...

  5. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  6. Nonflame, source-induced sulfur fluorescence detector for sulfur-containing compounds

    SciTech Connect (OSTI)

    Gage, D.R.; Farwell, S.O.

    1980-12-01

    Results of some preliminary investigations of the fluorescence spectra of S/sub 2/ and the non-flame production of S/sub 2/ from sulfur-containing molecules are reported. Passage of the gas to be analyzed through a catalyst-oven containing a plug of NiO/sub 2//Al/sub 2/O/sub 3/ catalyst containing 10 wt% NiO/sub 2/ and heated to 400/sup 0/C resulted in conversion of H/sub 2/S to S/sub 2/ and elemental sulfur. The S/sub 2/ was detected by measurement of its fluorescence bands at 260 and 310nm, and elemental sulfur condensed on the cool parts of the apparatus. However, determination of sulfur-content of gas mixtures with the apparatus described herein were not as repeatable as desired, and the work is being continued on various facets of the non-flame system with work being directed toward the evaluation of different catalysts, catalyst temperature, design of a smaller detector geometry utilizing a pulsed-light excitation source, a windowless cell, and optical filters instead of monochromators to select the S/sub 2/ excitation and emission wavelengths. (BLM)

  7. Audit Manual (Release 8)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deputy Inspector General for Audits and Inspections AUDIT MANUAL Release 8 Revised 2014 Revised 2014 TOC-1 Release 8 OFFICE OF INSPECTOR GENERAL OFFICE OF AUDITS AUDIT MANUAL TABLE OF CONTENTS Page List of Acronyms ...................................................................................................................LOA-1 PART I -- INTRODUCTION CHAPTER 1 -- INTRODUCTION TO THE AUDIT MANUAL A. Purpose of the Audit Manual

  8. Sodium sulfur container with chromium/chromium oxide coating

    DOE Patents [OSTI]

    Ludwig, Frank A.; Higley, Lin R.

    1981-01-01

    A coating of chromium/chromium oxide is disclosed for coating the surfaces of electrically conducting components of a sodium sulfur battery. This chromium/chromium oxide coating is placed on the surfaces of the electrically conducting components of the battery which are in contact with molten polysulfide and sulfur reactants during battery operation.

  9. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  10. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda; Janiak, Jerzy S.; Turak, Ali A.; Ignasiak, Boleslaw L.

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  11. News Releases - 2016

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases » News Releases - 2016 News Releases - 2016 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. August» July» June» May» April» March» February» January» James TenCate James TenCate elected Acoustical Society of America fellow TenCate's research focuses on nonlinear acoustics and elasticity, seismology and nonlinear imaging. - 8/30/16 The thermal traits of a leaf,

  12. DOCUMENT RELEASE FORM C

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE FORM C (1) Document Number: RPP-RPT-431 74 (2) Revision Number: (3) Effective Date: 9/30/2009 (4) Document Type: El Digital Image El Hard copy (a) Number of pages (including the DRF) or 107 E PDF E] Video number of digital images (5) Release Type 0 New El Cancel El Page Change El complete Revision (6) Document Title: 2009 Auto-TOR for Tank 241 -T-204 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c)

  13. Data Release Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Release Page This page provides links to data (histograms, error matrices, ntuples, etc.) released in association with MINERvA publications. MINERvA Collaboration, L. Aliaga, M. Kordosky, T. Golan et al,"Neutrino Flux Predictions for the NuMI Beam" hep-ex/1607.00704.[Data Release Page] MINERvA Collaboration, Z. Wang, C.M. Marshall et al.,"First Evidence of Coherent Production of K + in Neutrino Interactions on Carbon Nuclei"hep-ex/1606.08890. MINERvA Collaboration, C.M.

  14. Sulfur Speciation of Different Kerogens using XANES Spectroscopy

    SciTech Connect (OSTI)

    Wiltfong,R.; Mitra-Kirtley, S.; Mullins, O.; Andrews, B.; Fujisawa, G.; Larsen, J.

    2005-01-01

    X-ray absorption near-edge structure (XANES) methodology has been employed to quantify the different sulfur structures present in three Type I and three Type II kerogens. Kerogens from the Green River (3), Bakken (1), Woodford (1), and Indiana limestone (1) formations were studied. Both aliphatic (sulfide) and aromatic (thiophene) forms of sulfur exist in all these kerogen samples. Except for Woodford, all of the kerogens contain oxidized functional groups. Sulfur in Types I and II kerogens mimics the carbon chemistry in that the sulfur structures are more aromatic in Type II than in Type I. It was impossible to differentiate elemental sulfur from pyrite in these samples by using K-edge XANES.

  15. Metal-sulfur type cell having improved positive electrode

    DOE Patents [OSTI]

    Dejonghe, Lutgard C.; Visco, Steven J.; Mailhe, Catherine C.; Armand, Michel B.

    1989-01-01

    An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

  16. Metal-sulfur type cell having improved positive electrode

    DOE Patents [OSTI]

    DeJonghe, L.C.; Visco, S.J.; Mailhe, C.C.; Armand, M.B.

    1988-03-31

    A novel metal-sulfur type cell operable at a temperature of 200/degree/C or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S)/sub y/)n wherein y = 1 to 6; n = 2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprises one or more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon. 4 figs.

  17. Removal of sulfur contaminants in methanol for fuel cell applications

    SciTech Connect (OSTI)

    Lee, S.H.D.; Kumar, R.; Sederquist, R.

    1996-12-31

    Fuel cell power plants are being developed for transit bus and passenger car applications that use methanol as the on-board fuel. Commodity methanol by itself contains very little sulfur; however, it may occasionally be contaminated with up to about 1% diesel fuel or gasoline in current liquid-fuel distribution systems, leading to the presence of sulfur in the methanol fuel. This sulfur must be removed because of its deleterious effect on the reforming catalysts. International Fuel Cells has set the allowable sulfur limit in the methanol fuel at less than 1 ppm. The equilibrium adsorption isotherm and breakthrough data were used to assess the feasibility of developing a granular activated carbon adsorber for the removal of sulfur from transportation fuel cell systems.

  18. Multi-model mean nitrogen and sulfur deposition from the Atmospheric...

    Office of Scientific and Technical Information (OSTI)

    Multi-model mean nitrogen and sulfur deposition from the Atmospheric Chemistry and Climate ... Title: Multi-model mean nitrogen and sulfur deposition from the Atmospheric Chemistry and ...

  19. News Releases Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 cool science and technology stories from Argonne in 2015 http:www.anl.govarticles10-cool-science-and-technology-stories-argonne-2015 December 23, 2015 News Releases Feed...

  20. FOR IMMEDIATE RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IMMEDIATE RELEASE Media Contacts: January 23, 2012 Cameron Hardy, DOE , (509) 376-5365, Cameron.Hardy@rl.doe.gov DOE Considers Natural Gas Utility Service Options Proposal Includes...

  1. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    release MiniBooNE opens the box Results from Fermilab experiment resolve long-standing neutrino question BATAVIA, Illinois-Scientists of the MiniBooNE1 experiment at the...

  2. WIPP News Releases - 2006

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Back to current year news releases 2006 News Releases December 12 Idaho National Laboratory Waste Stream Cleared for Shipment to WIPP November 15 WIPP Reaches 4-Million-Hour Safety Milestone October 16 State of New Mexico Issues Permit for Remote-Handled Waste at WIPP September 11 WIPP receives 5,000th shipment March 29 DOE Waste Isolation Pilot Plant Receives EPA Recertification

  3. Rad-Release

    ScienceCinema (OSTI)

    None

    2013-05-28

    The R&D 100 Award winning Rad-Release Chemical Decontamination Technology is a highly effective (up to 99% removal rate), affordable, patented chemical-foam-clay decontamination process tailored to specific radiological and metal contaminants, which is applicable to a wide variety of substrates. For more information about this project, visit http://www.inl.gov/rd100/2011/rad-release/

  4. Rad-Release

    SciTech Connect (OSTI)

    2011-01-01

    The R&D 100 Award winning Rad-Release Chemical Decontamination Technology is a highly effective (up to 99% removal rate), affordable, patented chemical-foam-clay decontamination process tailored to specific radiological and metal contaminants, which is applicable to a wide variety of substrates. For more information about this project, visit http://www.inl.gov/rd100/2011/rad-release/

  5. Membranes for the Sulfur-Iodine Integrated Laboratory Scale Demonstration

    SciTech Connect (OSTI)

    Frederick F. Stewart

    2007-08-01

    INL has developed polymeric membrane-based chemical separations to enable the thermochemical production of hydrogen. Major activities included studies of sulfuric acid concentration membranes, hydriodic acid concentration membranes, SO2/O2 separation membranes, potential applications of a catalyst reactor system for the decomposition of HI, and evaluation of the chemical separation needs for alternate thermochemical cycles. Membranes for the concentration of sulfuric acid were studied using pervaporation. The goal of this task was to offer the sulfur-iodine (S-I) and the hybrid sulfur (HyS) cycles a method to concentrate the sulfuric acid containing effluent from the decomposer without boiling. In this work, sulfuric acid decomposer effluent needs to be concentrated from ~50 % acid to 80 %. This task continued FY 2006 efforts to characterize water selective membranes for use in sulfuric acid concentration. In FY 2007, experiments were conducted to provide specific information, including transmembrane fluxes, separation factors, and membrane durability, necessary for proper decision making on the potential inclusion of this process into the S-I or HyS Integrated Laboratory Scale demonstration.

  6. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard; Steinberg, Meyer

    1981-01-01

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  7. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, R.; Steinberg, M.

    This invention relates to high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280/sup 0/C and containing as little as 36 mo1% ethylene and about 41 to 51 mo1% sulfur dioxide, and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10 to 50/sup 0/C, and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  8. Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    via Surface Modification of SiO2 with TiO2 and ZrO2 | Department of Energy Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 This study demonstrates the feasibility of developing highly stable, sulfur-tolerant oxidation catalysts that use less Pt via surface modification of silica supports

  9. Altitude release mechanism

    DOE Patents [OSTI]

    Kulhanek, Frank C.

    1977-01-01

    An altitude release mechanism for releasing a radiosonde or other measuring instrument from a balloon carrying it up into the atmosphere includes a bottle partially filled with water, a tube sealed into the bottle having one end submerged in the water in the bottle and the free end extending above the top of the bottle and a strip of water-disintegrable paper held within the free end of the tube linking the balloon to the remainder of the package. As the balloon ascends, the lowered atmospheric air pressure causes the air in the bottle to expand, forcing the water in the bottle up the tubing to wet and disintegrate the paper, releasing the package from the balloon.

  10. Effects of sulfur loading on the corrosion behaviors of metal lithium anode in lithium–sulfur batteries

    SciTech Connect (OSTI)

    Han, Yamiao; Duan, Xiaobo; Li, Yanbing; Huang, Liwu; Zhu, Ding; Chen, Yungui

    2015-08-15

    Highlights: • The effects of sulfur loading on the corrosion behaviors were investigated systematically. • The corrosion became severer with increasing sulfur loading or cycle times. • The corrosion films are porous and loose and cannot prevent further reaction between lithium and polysulfides. - Abstract: The corrosion behaviors in rechargeable lithium–sulfur batteries come from the reactions between polysulfides and metal lithium anode, and they are significantly influenced by the sulfur loading. While there are limited papers reported on the effects of sulfur loading on the corrosion behaviors. In this paper, the effects have been investigated systematically. The corrosion films consisted of insulating lithium ion conductors are loose and porous, so that the corrosive reactions cannot be hindered. The thickness of the corrosion layers, consequently, increased along with increasing sulfur loading or cycle times. For instance, the thickness of corrosion layers after 50 cycles was 98 μm in the cell with 5 mg sulfur while it reached up to 518 μm when the loading increased to 15 mg. The continuous deposition of corrosion products gave rise to low active materials utilization and poor cycling performance.

  11. DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 (2) Revision Number: 0 (3) Effective Date: 9/28/2009 (4) Document Type: [] Digital Image El Hard copy (a) Number of pages (including the DRF) or 74 0PDF E] Video number of digital images (5) Release Type E New El cancel l Page Change El complete Revision (6) Document Title: 2009 Auto-TCR for Tank 241-13-204 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c) Building Number: Structure, System, and Component N/A

  12. DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    31 97 (2) Revision Number: 0 -- (3) Effective Date: 9/30/2009 (4) Document Type: E] Digital Image l Hard copy (a) Number of pages (including the DRF) or 84 0 POE E Video number of digital images (5) Release Type Z New 1:1 Cancel liiPage Change Elcomplete Revision (6) Document Title: 2009 Auto-TOR for Tank 241 -TY-1 05 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c) Building Number: Structure, System, and

  13. ARM - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Related Links TWP-ICE Home Tropical Western Pacific Home ARM Data Discovery Browse Data Post-Experiment Data Sets Weather Summary (pdf, 6M) New York Workshop Presentations Experiment Planning TWP-ICE Proposal Abstract Detailed Experiment Description Science Plan (pdf, 1M) Operations Plan (pdf, 321K) Maps Contact Info Related Links Daily Report Report Archives Press Media Coverage TWP-ICE Fact Sheet (pdf, 211K) Press Releases TWP-ICE Images ARM flickr site <=""

  14. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  15. Lithium / Sulfur Cells with Long Cycle Life and High Specific...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Sulfur Cells with Long Cycle Life and High Specific Energy Lawrence Berkeley ... Song, M-K., Zhang, Y., Cairns, E.J., "A long-life, high-rate lithiumsulfur cell: a ...

  16. Sulfur Resistant Electrodes for Zirconia Oxygen Sensors - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide (Tb-YSZ) electrode have tested in a high-sulfur-coal fired power plant side by side against Zirconia-based O2 sensors with a standard platinum electrode. ...

  17. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  18. STEP Utility Data Release Form

    Broader source: Energy.gov [DOE]

    STEP Utility Data Release Form, from the Tool Kit Framework: Small Town University Energy Program (STEP).

  19. WIPP News Releases - 2002

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases September 30 Westinghouse Earns Mine Safety Award for 16th Consecutive Year July 9 Westinghouse TRU Solutions LLC Earns Corporate Award For Air Monitoring Initiative April 12 WIPP Receives Waste Characterized With Mobile System February 12 Ava Holland Joins DOE Carlsbad Field Office As Quality Assurance Manager January 7 WIPP Receives 500th Waste Shipment

  20. Gasoline from natural gas by sulfur processing

    SciTech Connect (OSTI)

    Erekson, E.J.; Miao, F.Q.

    1995-12-31

    The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process, called the HSM (Hydrogen Sulfide-Methane) Process, consists of two steps that each utilize a catalyst and sulfur-containing intermediates: (1) converting natural gas to CS{sub 2} and (2) converting CS{sub 2} to gasoline range liquids. Catalysts have been found that convert methane to carbon disulfide in yields up to 98%. This exceeds the target of 40% yields for the first step. The best rate for CS{sub 2} formation was 132 g CS{sub 2}/kg-cat-h. The best rate for hydrogen production is 220 L H{sub 2} /kg-cat-h. A preliminary economic study shows that in a refinery application hydrogen made by the HSM technology would cost $0.25-R1.00/1000 SCF. Experimental data will be generated to facilitate evaluation of the overall commercial viability of the process.

  1. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  2. Evaluation of Sulfur Spinel Compounds for Multivalent Battery Cathode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications - Joint Center for Energy Storage Research August 17, 2016, Research Highlights Evaluation of Sulfur Spinel Compounds for Multivalent Battery Cathode Applications A group of 3d transition-metal sulfur-spinel compounds were systematically assessed for MV cathode applications, based on their electrochemical and thermodynamic properties . Cr2S4, Ti2S4 and Mn2S4 spinel compounds exhibit superior Mg2+ mobility, and hence, emerge as the top three candidates. Scientific Achievement

  3. METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY

    SciTech Connect (OSTI)

    Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

    2009-06-22

    HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

  4. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  5. Molten iron oxysulfide as a superior sulfur sorbent. Final report, [September 1989--1993

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1993-03-31

    The studies had as original objective the analysis of conditions for using liquid iron oxysulfide as a desulfuring agent during coal gasification. Ancillary was a comparison of iron oxysulfide with lime as sorbents under conditions where lime reacts with S-bearing gases to form Ca sulfate or sulfide. Primary thrust is to determine the thermodynamic requirements for desulfurization by iron additions (e.g., taconite concentrate) during combustion in gasifiers operating at high equivalence ratios. Thermodynamic analysis of lime-oxygen-sulfur system shows why lime is injected into burners under oxidizing conditions; reducing conditions forms CaS, requiring its removal, otherwise oxidation and release of S would occur. Iron as the oxysulfide liquid has a range of stability and can be used as a desulfurizing agent, if the burner/gasifier operates in a sufficiently reducing regime (high equivalence ratio); this operating range is given and is calculable for a coal composition, temperature, stoichiometry. High moisture or hydrogen contents of the coal yield a poorer degree of desulfurization. Kinetic tests on individual iron oxide particles on substrates or Pt cups with a TGA apparatus fail to predict reaction rates within a burner. Preliminary tests on the Dynamic Containment Burner with acetylene give some promise that this system can produce the proper conditions of coal gasification for use of added iron as a sulfur sorbent.

  6. In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into MDCK Cells In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine into MDCK Cells Sulfur is essential for life. It plays important roles in the amino acids methionine and cysteine, and has a structural function in disulfide bonds. As a component of iron-sulfur clusters it takes part in electron and sulfur transfer reactions.1 Glutathione, a sulfur-containing tripeptide, is an important part of biological antioxidant systems.2 Another example for the biological

  7. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1-28 November 7, 2001 For immediate release Press contact: Judy Jackson (630-840-3351; jjackson@fnal.gov High resolution graphics at www.fnal.gov/pub/presspass/images/NuTev_images.html Neutrino Measurement Surprises Fermilab Physicists Batavia, Ill.-Scientists at the Department of Energy's Fermi National Accelerator Laboratory have found a surprising discrepancy between predictions for the behavior of neutrinos and the way the subatomic particles actually behave. Although the difference is tiny,

  8. Cryogenic hydrogen release research.

    SciTech Connect (OSTI)

    LaFleur, Angela Christine

    2015-12-01

    The objective of this project was to devolop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. The necessary infrastructure has been specified and laboratory modifications are currently underway. Once complete, experiments from this platform will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  9. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 News Releases December 1 State Renews WIPP Facility Permit November 18 National TRU Program Director Selected November 18 Waste Isolation Pilot Plant Receives Second EPA Recertification October 7 WIPP Receives 9,000th Shipment September 7 Carlsbad Field Office Manager Transition July 2 DOE Awards Technical Assistance Contract for Carlsbad Field Office June 14 WIPP Completes California Sites Cleanup May 3 DOE Extends Management and Operations Contract at Waste Isolation Pilot Plant May 3 DOE

  10. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 News Releases December 21 WIPP Receives First Remote-Handled Waste Shipment From Sandia Labs December 13 Carlsbad Field Office Recognized by New Mexico and DOE for Environmental Excellence at WIPP Click on photo below for larger image. November 10 Carlsbad Field Office Manager Selected November 9 WIPP Receives Top Safety Award November 9 Photos of New WIPP Transportation Exhibit's Debut at the National Museum of Nuclear Science and History Click on photos below for larger images. November 2

  11. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases October 29 WIPP Environmental Initiatives Earn DOE Recognition Click on photo below for larger image. October 24 WIPP Security Contractor Receives DOE Voluntary Protection Program Award Click on photo below for larger image. October 17 WIPP Employees Among Honorees for Nuclear Footprint Reduction October 3 DOE Exceeds 2012 TRU Waste Cleanup Goal at Los Alamos National Laboratory September 19 DOE Awards Grant to New Mexico Environment Department for Waste Isolation Pilot Plant

  12. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases December 18 CBFO Selects Quality Assurance Director Click on photo below for larger image. December 2 Carlsbad Field Office Deputy Manager Selected Click on photo below for larger image. September 20 WIPP Management and Operating Contractor Recognized for Continuous Safety Performance Click on photo below for larger image. September 18 WIPP Receives Top Mine Safety Award September 18 WIPP Honored for Sustainability August 2 WIPP Employee Inducted Into Mine Rescue Hall of Fame -

  13. WIPP News Releases - 2003

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases December 18 50,000 Containers Safety Disposed at WIPP August 14 Drum Involved in Idaho Incident Not Shippable to WIPP July 31 Marchetti New CEO of Washington TRU Solutions March 25 HUBZone, Great Opportunity for Small Businesses February 18 TRU Solutions Announces $20,500 in Scholarships For Eddy and Lea County Students January 14 Washington TRU Solutions LLC Announces New Name and New General Manager

  14. WIPP News Releases - 2005

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases December 27 Empty WIPP truck overturns December 12 Dr. Dave Moody to Lead the Carlsbad Field Office December 7 WIPP Satellite Tracking System Relocates to Carlsbad November 23 Statement of Vernon Daub, Acting Manager of DOE's Carlsbad Field Office, Regarding New Mexico Environment Department's Issuance of a Draft Hazardous Waste Facility Permit for WIPP October 7 DOE Awards WIPP Independent Oversight Contract August 11 DOE Awards Technical Assistance Contract to Support Carlsbad

  15. 1995 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search NREL Funding Reductions to Further Impact Lab's Work Force (12/22/95) World Renewable Energy Congress To Be Held In Denver In 1996 (12/18/95) NREL Researchers Use Sunlight to Power Laser (12/14/95) National Renewable Energy Laboratory To Reduce Staff (11/3/95)

  16. 1998 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Popular Science Recognizes Innovative Solar Technologies - (12/16/98) Kazmerski Leads National Center for Solar Research - (12/1/98) MRI, Battelle and Bechtel to Manage National Renewable Energy Lab - (11/19/98) Prestigious Council to Advise National Renewable Energy Lab - (11/19/98) Tour Opens Doors, Minds to Solar Energy - (10/5/98) MRI, Battelle, Bechtel Team Wins National

  17. 2002 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Director of National Bioenergy Center Named - (12/12/02) Scientific American' Recognizes Solar Cell Research - (11/11/02) UPS Fleet Study Quantifies the Reliability, Low Emissions of CNG Trucks - (10/29/02) Energy Department Honors Solar Decathlon Winners - (10/05/02) Winner of Solar Decathlon to be Announced - (10/04/02) Solar Decathlon Engineering Design Results Announced -

  18. 2003 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 22, 2003 Renewable Energy a Smart Choice for Farmers and Ranchers December 10, 2003 Georgia Tech's Rohatgi Wins Second Annual Rappaport Award December 9, 2003 Acclaim for Three Leaders at Annual NREL Stakeholders Reception November 14, 2003 World Renewable Energy Congress Provides International Forum November 12, 2003 NREL and Company Researchers Team Up

  19. 2004 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 21, 2004 NREL Recognizes Solar Pioneer with National Honor November 23, 2004 NREL Recognizes Solar Pioneer with National Honor November 17, 2004 Basalt Middle School Teacher Recognized for Renewable Energy Efforts October 5, 2004 NREL Theorist Recognized for Highest Citation Impact September 24, 2004 NREL Selects Contractor for New Science & Technology

  20. 2005 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search November 17, 2005 Lakewood High School Teacher Recognized for Introduction of Renewable Energy Curriculum Students taking technology classes at Lakewood High School this semester are learning about more than construction, technical theater and computer aided drafting (CAD); they are learning about energy issues within their community. October 31, 2005 Agreement

  1. 2006 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 14, 2006 Experimental "Wind to Hydrogen" System Up and Running Xcel Energy and the National Renewable Energy Laboratory unveiled a unique facility that uses electricity from wind turbines to produce and store pure hydrogen. November 28, 2006 University of Denver High School Teacher Recognized for Commitment to Renewable Energy Don Cameron,

  2. 2007 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 4, 2007 Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) has pledged to reduce its greenhouse gas emissions by 75 percent from 2005 to 2009. The new goal is part of NREL's participation in the Environmental Protection Agency's (EPA) Climate Leaders program. November 8, 2007

  3. 2010 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 17, 2010 NREL Employees Significantly Increase Their Community Support For the second year in a row, employees of the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) pledged significantly more to community organizations during its annual charitable giving campaign this holiday season. December 2, 2010 Scientists Generate Two

  4. 2011 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 20, 2011 NREL Licenses Technology to Increase Solar Cell Efficiency The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) announced today that Natcore Technology Inc. has been granted a patent license agreement to develop a line of black silicon products. December 15, 2011 NREL Scientists Report First Solar Cell Producing More

  5. 2012 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 21, 2012 NREL Names New Executive The U.S. Department of Energy's National Renewable Energy Laboratory today named Barbara Goodman as Associate Laboratory Director for Renewable Fuels and Vehicle Systems to replace Dale Gardner who is retiring at the end of the year. December 20, 2012 Concentrated Solar Power with Thermal Energy Storage Can Help Utilities'

  6. 2013 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 12, 2013 NREL Seeks Leaders for National Executive Energy Academy The Energy Department's National Renewable Energy Laboratory (NREL) is accepting applications for its 2014 Executive Energy Leadership Academy. NREL's Executive Energy Leadership Academy, also known as Energy Execs, is a program for non-technical decision-makers throughout the country to

  7. Final Technical Report: Mercury Release from Organic Matter (OM) and OM-Coated Mineral Surfaces

    SciTech Connect (OSTI)

    Nagy, Kathryn L.

    2015-08-18

    Chemical reactions between mercury, a neurotoxin, and sulfur, an essential nutrient, in the environment control to a large extent the distribution and amount of mercury available for uptake by living organisms. The largest reservoir of sulfur in soils is in living, decaying, and dissolved natural organic matter. The decaying and dissolved organic matter can also coat the surfaces of minerals in the soil. Mercury (as a divalent cation) can bind to the sulfur species in the organic matter as well as to the bare mineral surfaces, but the extent of binding and release of this mercury is not well understood. The goals of the research were to investigate fundamental relationships among mercury, natural organic matter, and selected minerals to better understand specifically the fate and transport of mercury in contaminated soils downstream from the Y-12 plant along East Fork Poplar Creek, Tennessee, and more generally in any contaminated soil. The research focused on (1) experiments to quantify the uptake and release of mercury from two clay minerals in the soil, kaolinite and vermiculite, in the presence and absence of dissolved organic matter; (2) release of mercury from cinnabar under oxic and anoxic conditions; (3) characterization of the forms of mercury in the soil using synchrotron X-ray absorption spectroscopic techniques; and, (4) determination of molecular forms of mercury in the presence of natural organic matter. We also leveraged funding from the National Science Foundation to (5) evaluate published approaches for determining sulfur speciation in natural organic matter by fitting X-ray Absorption Near Edge Structure (XANES) spectra obtained at the sulfur K-edge and apply optimized fitting schemes to new measurements of sulfur speciation in a suite of dissolved organic matter samples from the International Humic Substances Society. Lastly, in collaboration with researchers at the University of Colorado and the U.S. Geological Survey in Boulder, Colorado, (6

  8. LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.

    SciTech Connect (OSTI)

    BATEY, J.E.; MCDONALD, R.J.

    2005-06-01

    This project was funded by NYSERDA and has clearly demonstrated many advantages of using low sulfur content heating oil to provide thermal comfort in homes. Prior laboratory research in the United States and Canada had indicated a number of potential benefits of using lower sulfur (0.05%) heating oil. However, this prior research has not resulted in the widespread use of low sulfur fuel oil in the marketplace. The research project described in this report was conducted with the assistance of a well-established fuel oil marketer in New York State (NYS) and has provided clear proof of the many real-world advantages of marketing and using low sulfur content No. 2 fuel oil. The very positive experience of the participating marketer over the past three years has already helped to establish low sulfur heating oil as a viable option for many other fuel marketers. In large part, based on the initial findings of this project and the experience of the participating NYS oilheat marketer, the National Oilheat Research Alliance (NORA) has already fully supported a resolution calling for the voluntary use of low sulfur (0.05 percent) home heating oil nationwide. The NORA resolution has the goal of converting eighty percent of all oil-heated homes to the lower sulfur fuel (0.05 percent by weight) by the year 2007. The Oilheat Manufacturers Association (OMA) has also passed a resolution fully supporting the use of lower sulfur home heating oil in the equipment they manufacture. These are important endorsements by prominent national oil heat associations. Using lower sulfur heating oil substantially lowers boiler and furnace fouling rates. Laboratory studies had indicated an almost linear relationship between sulfur content in the oil and fouling rates. The completed NYSERDA project has verified past laboratory studies in over 1,000 occupied residential homes over the course of three heating seasons. In fact, the reduction in fouling rates so clearly demonstrated by this project is

  9. Media Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Media Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen September 22, 2011 Communication Specialist (801) 819-7623 hrasmussen@wecc.biz WECC releases its first-ever transmission plan for the Western Interconnection The Western Electricity Coordinating Council (WECC) announced the release of its first 10-Year Regional Transmission Plan (Plan) for the Western Interconnection. Looking ahead to 2020, the Plan focuses on how to meet the Western Interconnection's transmission requirements;

  10. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  11. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H.; Stegen, Gary E.

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  12. ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Amoroso, J.; Fox, K.

    2011-09-07

    The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

  13. Insight into Sulfur Reactions in Li–S Batteries

    SciTech Connect (OSTI)

    Xu, Rui; Belharouak, Ilias; Zhang, Xiaofeng; chamoun, rita; Yu, Cun; Ren, Yang; Nie, Anmin; Reza, Shahbazian-Yassar; Lu, Jun; Li, James C.M.; Amine, Khalil

    2014-12-09

    Understanding and controlling the sulfur reduction species (Li2Sx, 1 ≤ x ≤ 8) under realistic battery conditions are essential for the development of advanced practical Li–S cells that can reach their full theoretical capacity. However, it has been a great challenge to probe the sulfur reduction intermediates and products because of the lack of methods. This work employed various ex situ and in situ methods to study the mechanism of the Li–S redox reactions and the properties of Li2Sx and Li2S. Synchrotron high-energy X-ray diffraction analysis used to characterize dry powder deposits from lithium polysulfide solution suggests that the new crystallite phase may be lithium polysulfides. The formation of Li2S crystallites with a polyhedral structure was observed in cells with both the conventional (LiTFSI) electrolyte and polysulfide-based electrolyte. In addition, an in situ transmission electron microscopy experiment observed that the lithium diffusion to sulfur during discharge preferentially occurred at the sulfur surface and formed a solid Li2S crust. This may be the reason for the capacity fade in Li–S cells (as also suggested by EIS experiment in Supporting Information). The results can be a guide for future studies and control of the sulfur species and meanwhile a baseline for approaching the theoretical capacity of the Li–S battery.

  14. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha; Meyer, Howard S.; Lynn, Scott; Leppin, Dennis; Wangerow, James R.

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  15. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  16. WIPP News Releases - 1995

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases Westinghouse WID Earns DOE Quality Award - 11/08/95 DOE Accelerates WIPP Schedule - 10/20/95 WIPP Celebrates National Quality Month - 10/13/95 Assistant DOE Secretary Transfers WIPP Technology - 10/10/95 DOE Extends EIS Public Comment Period - 10/06/95 DOE Closes Underground Experimental Area - 09/28/95 SEIS Meetings Held For WIPP - 09/12/95 Lee Named Deputy GM For Westinghouse WID - 08/25/95 WIPP Transportation System At Trade Show - 07/11/95 Technology Transfer - 07/07/95

  17. WIPP News Releases - 1996

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases DOE to Hold Public Hearings Next Week in Albuquerque on WIPP SEIS - 12/31/96 DOE to Hold Public Hearings Next Week in Santa Fe on WIPP SEIS - 12/31/96 DOE Announces North Augusta Public Hearing for WIPP SEIS - 12/17/96 DOE Announces Denver Area Public Hearing for WIPP SEIS - 12/17/96 DOE Announces Richland Public Hearing for WIPP SEIS - 12/17/96 DOE Announces Santa Fe Public Hearings for WIPP SEIS - 12/17/96 DOE Announces Boise Public Hearing for WIPP SEIS - 12/17/96 DOE

  18. FOR IMMEDIATE RELEASE CIV

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    _ FOR IMMEDIATE RELEASE CIV FRIDAY, AUGUST 21, 2015 (202) 514-2007 WWW.JUSTICE.GOV TTY (866) 544-5309 SANDIA CORPORATION AGREES TO PAY $4.7 MILLION TO RESOLVE ALLEGATIONS RELATED TO LOBBYING ACTIVITIES WASHINGTON - The Justice Department announced today that Sandia Corporation has agreed to pay $4,790,042 to resolve allegations that Sandia violated the Byrd Amendment and the False Claims Act by using federal funds for activities related to lobbying Congress and federal agencies to obtain a

  19. WIPP News Releases - 2004

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 News Releases November 4 Detwiler Resumes Position at DOE Headquarters October 14 WIPP Mine Rescue Team First in Missouri October 12 DOE Announces WIPP Contract Negotiations October 6 Washington TRU Solutions is Mine Operator of the Year September 28 Washington Group International Named Tops in Safety July 24 No Damage to WIPP Cargo in Roswell Traffic Accident July 22 WIPP Mine Rescue Team Wins "Overall Contest" at Nationals July 2 DOE Prevails in WIPP Court Case July 1 $1M to Fund

  20. Manhattan Project app released

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    » Manhattan Project app released At the Bradbury Latest Issue:September 2016 all issues All Issues » submit Manhattan Project app available NOW! Downloadable through iTunes June 1, 2016 The opening graphic of the Los Alamos: Secret City of the Manhattan Project app Los Alamos: Secret City of the Manhattan Project is available through iTunes for free! We let you know about it. We provided a short video so you could get a feel for what the Los Alamos: Secret City of the Manhattan Project app is

  1. Pion Production Data Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pion Production Data Release This page gives the updated results for three different MINERvA Publications: Cross sections for neutrino and antineutrino induced pion production on hydrocarbon in the few-GeV region using MINERvA hep-ex/1606.07127 and Single neutral pion production by charged current antinu interactions on plastic scintillator at Enu ∼ 4 GeV hep-ex/1503.02107 and Charged Pion Production from CH in a Neutrino Beam hep-ex/1406.6415 Data Ancillary files for this result are available

  2. 1996 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Companies Selected for Small Wind Turbine Project - (11/27/96) DOE Forms National Center for Photovoltaics - (11/19/96) The Brightest in Solar Homes to Shine in Public Tour - (10/4/96) New NREL Research Facility Slashes Energy Use by 66 Percent - (10/3/96) Agreement Moves Nevada Solar Plant Step Closer to Reality - (10/3/96) Would-Be Solar Electric Homeowners Sought For

  3. 1997 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Local Middle School Receives School-to-Career Grant - (12/24/97) Free Consumer Workshops On Solar & Wind Power For Farm & Ranch At National Western Stock Show - (12/9/97) NREL Funds Research into Low-Cost Solar Electricity - (12/8/97) NREL Provides PV Holiday Lights for Christmas Tree - (12/2/97) Energy Saving Buildings Win National and Local Honors - (11/21/97)

  4. 1999 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Sunlight Helps Laboratory Get Ready for Y2K - (12/27/99) NREL Hosts Free Workshops on Solar and Wind Energy - (12/15/99) Seminar Explores Benefits of Using Solar Power for Disaster Management - (11/17/99) Choices for a Brighter Future - (11/12/99) Better "Bugs" Lead to Cheaper Ethanol from Biomass - New Agreements Could Boost U.S. Biofuels Industry - (11/10/99)

  5. 2008 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 11, 2008 Alternative Fuels and Advanced Vehicle Data Center Creates New Tool to Calculate Ways to Cut Gas Use A business owner with a fleet of 10 heavy-duty diesel trucks wants to cut diesel use by 10 percent. Would using a biodiesel blend or investing in onboard power sources that reduce engine idling achieve the biggest drop in petroleum use? An average

  6. 2009 WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    09 News Releases December 21 Magnum Minerals to Buy WIPP Salt October 14 Agreement Reached Between WTS and Union Employees October 1 Truck Accident Did Not Involve WIPP Shipment September 18 WIPP Completes First RH-TRU Shipment from VNC July 24 DOE Issues Statement Concerning Debates Over Waste Disposal in Salt June 25 DOE Carlsbad Field Office Opens Local Recovery Act Office June 18 DOE Announces the Transfer of the WIPP Water Line to the City of Carlsbad June 3 Los Alamos National Laboratory

  7. Analytical method for the evaluation of sulfur functionalities in American coals. Final report

    SciTech Connect (OSTI)

    Attar, A.

    1983-05-01

    This investigation consisted of the following 6 tasks: (1) improve the instrumentation for the sulfur functional groups analysis and make it more reliable. (2) create a set of reference standards of sulfur-containing compounds. (3) examine the sulfur groups distribution in untreated and desulfurized coals. (4) examine the sulfur functionalities in raw and processed coals, i.e., liquefied coals. (5) determine the distribution of sulfur functionalities in modified coals. (6) prepare computer programs for calculations related to the distribution of sulfur functional groups in coal. Each task is discussed and results are presented. Appendix A contains the computer program used to interpret the data. 31 references, 56 figures, 17 tables.

  8. Annual Energy Review 2011 - Released September 2012

    Gasoline and Diesel Fuel Update (EIA)

    other manufactured and waste gases derived from fossil fuels. 2 Batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, miscellaneous technologies, and non-renewable waste...

  9. Annual Energy Review 2008 - Released June 2009

    Gasoline and Diesel Fuel Update (EIA)

    other manufactured and waste gases derived from fossil fuels. 2 Batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, miscellaneous technologies, and non-renewable waste...

  10. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    SciTech Connect (OSTI)

    Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

    2004-01-25

    A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

  11. HYBRID SULFUR ELECTROLYZER DEVELOPMENT FY09 SECOND QUARTER REPORT

    SciTech Connect (OSTI)

    Herman, D; David Hobbs, D; Hector Colon-Mercado, H; Timothy Steeper, T; John Steimke, J; Mark Elvington, M

    2009-04-15

    The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis that can be powered by heat from high temperature gas reactors. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. This report documents work during the first quarter of Fiscal Year 2009, for the period between January 1, 2009 and March 31, 2009. The HyS Process is a two-step hybrid thermochemical cycle that is part of the 'Sulfur Family' of cycles. As a sulfur cycle, it uses high temperature thermal decomposition of sulfuric acid to produce oxygen and to regenerate the sulfur dioxide reactant. The second step of the process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen by electrochemically reacting sulfur dioxide with H{sub 2}O. The SDE produces sulfuric acid, which is then sent to the acid decomposer to complete the cycle. The DOE NHI program is developing the acid decomposer at Sandia National Laboratory for application to both the HyS Process and the Sulfur Iodine Cycle. The SDE is being developed at SRNL. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency, small footprint and potential for low capital cost, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test with a 60-cm{sup 2} single cell electrolyzer, and

  12. Graphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries

    SciTech Connect (OSTI)

    Chen, Renjie E-mail: chenrj@bit.edu.cn; Zhao, Teng; Tian, Tian; Fairen-Jimenez, David; Cao, Shuai; Coxon, Paul R.; Xi, Kai E-mail: chenrj@bit.edu.cn; Vasant Kumar, R.; Cheetham, Anthony K.

    2014-12-01

    A three-dimensional hierarchical sandwich-type graphene sheet-sulfur/carbon (GS-S/C{sub ZIF8-D}) composite for use in a cathode for a lithium sulfur (Li-S) battery has been prepared by an ultrasonic method. The microporous carbon host was prepared by a one-step pyrolysis of Zeolitic Imidazolate Framework-8 (ZIF-8), a typical zinc-containing metal organic framework (MOF), which offers a tunable porous structure into which electro-active sulfur can be diffused. The thin graphene sheet, wrapped around the sulfur/zeolitic imidazolate framework-8 derived carbon (S/C{sub ZIF8-D}) composite, has excellent electrical conductivity and mechanical flexibility, thus facilitating rapid electron transport and accommodating the changes in volume of the sulfur electrode. Compared with the S/C{sub ZIF8-D} sample, Li-S batteries with the GS-S/C{sub ZIF8-D} composite cathode showed enhanced capacity, improved electrochemical stability, and relatively high columbic efficiency by taking advantage of the synergistic effects of the microporous carbon from ZIF-8 and a highly interconnected graphene network. Our results demonstrate that a porous MOF-derived scaffold with a wrapped graphene conductive network structure is a potentially efficient design for a battery electrode that can meet the challenge arising from low conductivity and volume change.

  13. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L.; Gorski, Anthony J.; Daniels, Edward J.

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  14. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  15. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage - FY13 Q1 | Department of Energy Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 This document summarizes the progress of this General Atomics project, funded by SunShot, for the first quarter of fiscal year 2013. progress_report_baseload_generalatomics_fy13_q1.pdf (196.13 KB) More Documents & Publications Baseload CSP Generation Integrated with

  16. Method for removing sulfur oxides from a hot gas

    SciTech Connect (OSTI)

    Morris, W.P.; Hurst, T.B.

    1984-06-05

    An improved method for removing sulfur oxides from a hot gas by introducing the gas into a first compartment of a spray drying reactor chamber for settleable particulate removal, by then directing the gas to a second compartment of the reactor chamber wherein the gas is contacted with an atomized alkali slurry for sulfur oxide removal by formation of a dry mixture of sulfite and sulfate compounds, by removing a portion of the dry mixture from the gas in the second compartment and by passing the gas from the second compartment to a dry particle collection zone for removal of substantially all of the remaining gas entrained dry mixture.

  17. Quick release engine cylinder

    DOE Patents [OSTI]

    Sunnarborg, Duane A.

    2000-01-01

    A quick release engine cylinder allows optical access to an essentially unaltered combustion chamber, is suitable for use with actual combustion processes, and is amenable to rapid and repeated disassembly and cleaning. A cylinder member, adapted to constrain a piston to a defined path through the cylinder member, sealingly engages a cylinder head to provide a production-like combustion chamber. A support member mounts with the cylinder member. The support-to-cylinder mounting allows two relationships therebetween. In the first mounting relationship, the support engages the cylinder member and restrains the cylinder against the head. In the second mounting relationship, the cylinder member can pass through the support member, moving away from the head and providing access to the piston-top and head.

  18. Emission of volatile sulfur compounds during composting of municipal solid waste (MSW)

    SciTech Connect (OSTI)

    Zhang, Hongyu; Schuchardt, Frank; Li, Guoxue; Yang, Jinbing; Yang, Qingyuan

    2013-04-15

    Highlights: ► We compare the volatile sulfur compounds (VSCs) emissions during three types of municipal solid wastes (MSWs) composting. ► The VSCs released from the kitchen waste composting was significantly higher than that from 15–80 mm fraction of MSW. ► Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. ► Addition of 20% cornstalks could significantly reduce the VSCs emissions during kitchen waste composting. - Abstract: Volatile sulfur compounds (VSCs) are the main source for malodor from composting plants. In this study, the VSCs generated from composting of 15–80 mm municipal solid waste (T0), kitchen waste (T1) and kitchen waste mixed dry cornstalks (T2) were measured in 60 L reactors with forced aeration for a period of 30 days. The VSCs detected in all treatments were hydrogen sulfide (H{sub 2}S), methyl mercaptan (MM), dimethyl sulfide (DMS), carbon bisulfide (CS{sub 2}) and dimethyl disulfide (DMDS). Over 90% of the VSCs emissions occurred during the first 15 days, and reached their peak values at days 4–7. The emission profiles of five VSCs species were significantly correlated with internal materials temperature and outlet O{sub 2} concentration (p < 0.05). Total emissions of the VSCs were 216.1, 379.3 and 126.0 mg kg{sup −1} (dry matter) for T0, T1 and T2, respectively. Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. Composting of kitchen waste from separate collection posed a negative influence on the VSC and leachate production because of its high moisture content. An addition of dry cornstalks at a mixing ratio of 4:1 (wet weight) could significantly reduce the VSCs emissions and avoid leachate. Compared to pure kitchen waste, VSCs were reduced 66.8%.

  19. Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in...

  20. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G.

    2012-03-06

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  1. Low Quality Natural Gas Sulfur Removal and Recovery CNG Claus Sulfur Recovery Process

    SciTech Connect (OSTI)

    Klint, V.W.; Dale, P.R.; Stephenson, C.

    1997-10-01

    Increased use of natural gas (methane) in the domestic energy market will force the development of large non-producing gas reserves now considered to be low quality. Large reserves of low quality natural gas (LQNG) contaminated with hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and nitrogen (N) are available but not suitable for treatment using current conventional gas treating methods due to economic and environmental constraints. A group of three technologies have been integrated to allow for processing of these LQNG reserves; the Controlled Freeze Zone (CFZ) process for hydrocarbon / acid gas separation; the Triple Point Crystallizer (TPC) process for H{sub 2}S / C0{sub 2} separation and the CNG Claus process for recovery of elemental sulfur from H{sub 2}S. The combined CFZ/TPC/CNG Claus group of processes is one program aimed at developing an alternative gas treating technology which is both economically and environmentally suitable for developing these low quality natural gas reserves. The CFZ/TPC/CNG Claus process is capable of treating low quality natural gas containing >10% C0{sub 2} and measurable levels of H{sub 2}S and N{sub 2} to pipeline specifications. The integrated CFZ / CNG Claus Process or the stand-alone CNG Claus Process has a number of attractive features for treating LQNG. The processes are capable of treating raw gas with a variety of trace contaminant components. The processes can also accommodate large changes in raw gas composition and flow rates. The combined processes are capable of achieving virtually undetectable levels of H{sub 2}S and significantly less than 2% CO in the product methane. The separation processes operate at pressure and deliver a high pressure (ca. 100 psia) acid gas (H{sub 2}S) stream for processing in the CNG Claus unit. This allows for substantial reductions in plant vessel size as compared to conventional Claus / Tail gas treating technologies. A close integration of the components of the CNG Claus

  2. 2010 Report Released | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Report Released | National Nuclear Security Administration Facebook Twitter Youtube Flickr ... Home About Us Our History NNSA Timeline 2010 Report Released 2010 Report Released ...

  3. Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 4: June 9, 2014 EPA Sulfur Standards for Gasoline Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of sulfur in gasoline (Tier 2 standards). Separate standards were set for different entities, such as large refiners, small refiners, importers, downstream wholesalers, etc. In March 2014, Tier 3 standards were finalized by

  4. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application deer09_cheng.pdf (564.79 KB) More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials Sulfur Effect and Performance Recovery of a DOC + CSF +

  5. Chromium modified nickel-iron aluminide useful in sulfur bearing environments

    DOE Patents [OSTI]

    Cathcart, John V.; Liu, Chain T.

    1989-06-13

    An improved nickel-iron aluminide containing chromium and molybdenum additions to improve resistance to sulfur attack.

  6. Preliminary Release: August 19, 2011",,,,,,,,,,,,,"Released: April 2013","Releas

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,,,,,,,,,,,"Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April

  7. Hydroprocessing key issue in low-sulfur' era

    SciTech Connect (OSTI)

    Not Available

    1993-07-26

    Refiners gave heavy attention to hydroprocessing operations at the most recent National Petroleum Refiners Association annual question and answer session on refining and petrochemical technology. Among the topics covered were diesel color, blending to meet diesel sulfur specs, and ammonia injection in hydrocracking units. The panelists also related their experiences with increasing vacuum gas oil conversion in hydrocracking operations. These discussions are reproduced here.

  8. Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of SiO2 with TiO2 and ZrO2 Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 This study ...

  9. Sulfur isotope ratios in petroleum research and exploration: Williston basin

    SciTech Connect (OSTI)

    Thode, H.G.

    1981-09-01

    The three major types of crude oil in the Williston basin - the type I oils of the Winnipeg-Red River system, the type II oils of the Bakken-Madison system, and the type III oils of the Tyler-Pennsylvanian system - can be distinguished by their sulfur isotope compositions. They have characteristic delta/sup 34/S values of 5.8 +- 1.2 parts per thousand (ppt), 2.8 +- 0.8 ppt, and -4.0 +- 0.7 ppt respectively. Highly mature oils have less typical values. Type II oils which have migrated over a distance of some 150 km beyond the region of generation have maintained their characteristic delta/sup 34/S values even though sulfur may have been lost. This indicates little or no interaction with reservoir sulfates under normal circumstances. On the periphery of the basin, type II oils altered by water washing and biodegradation have altered delta/sup 34/S values which increase from +2.9 to +9.4 ppt with the increasing degree of crude oil degradation. The Bakken shales, source of the type II oils, have delta/sup 34/S distribution patterns in the reduced sulfur typical of marine sediments. The delta/sup 34/S values for the type II oils match most closely the delta/sup 34/S value of organic sulfur in the black bituminous shales of the lower Bakken.

  10. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  11. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  12. Catalyst added to Claus furnace reduces sulfur losses

    SciTech Connect (OSTI)

    Luinstra, E.A.; d'Haene, P.E. (Shell Canada Ltd., Toronto, ON (Canada). Oakville Research Centre)

    1989-07-01

    Several substances effectively catalyze the reduction of carbon disulfide in Claus gas streams at Claus reaction furnace conditions (about 1,000{sup 0}C). Some conversion of carbonyl sulfide also occurs. Carbon disulfide and carbonyl sulfide as well-known problem compounds that reduce sulfur recovery efficiency in many sulfur recovery plants. Installation of a suitable catalytic material in the reaction furnace promises significant improvement of Claus plant efficiency, and prolonged life of the catalytic converters. Almost every Claus sulfur recovery plant makes some carbon disulfide (CS/sub 2/) and carbonyl sulfide (COS) in the reaction furnace, and in many of these plants, these compounds constitute a significant problem. CS/sub 2/ and COS often comprise more than 50% of sulfur losses in the tail gas. This article reexamines the issue of CS/sub 2/ and COS in the Claus plant. The relative importance of these two troublesome components is explored with data accumulated from Shell Canada Claus plants. The authors discuss which factors tend to produce these components. Then a method for reducing CS/sub 2/ and COS virtually at the source will be introduced.

  13. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  14. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J.

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  15. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    SciTech Connect (OSTI)

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  16. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    SciTech Connect (OSTI)

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  17. FY08 MEMBRANE CHARACTERIZATION REPORT FOR HYBRID SULFUR ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

    2008-09-01

    This report summarizes results from all of the membrane testing completed to date at the Savannah River National Laboratory (SRNL) for the sulfur dioxide-depolarized electrolyzer (SDE). Several types of commercially-available membranes have been analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid (PFSA), sulfonated polyether-ketone-ketone (SPEKK), and polybenzimidazole membranes (PBI). Of these membrane types, the poly-benzimidazole membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Several experimental membranes have also been analyzed including hydrated sulfonated Diels-Alder polyphenylenes (SDAPP) membranes from Sandia National Laboratory, perfluorosulfonimide (PFSI) and sulfonated perfluorocyclobutyl aromatic ether (S-PFCB) prepared by Clemson University, hydrated platinum-treated PFSA prepared by Giner Electrochemical Systems (GES) and Pt-Nafion{reg_sign} 115 composites prepared at SRNL. The chemical stability, SO{sub 2} transport and ionic conductivity characteristics have been measured for several commercially available and experimental proton-conducting membranes. Commercially available PFSA membranes such as the Nafion{reg_sign} series exhibited excellent chemical stability and ionic conductivity in sulfur dioxide saturated sulfuric acid solutions. Sulfur dioxide transport in the Nafion{reg_sign} membranes varied proportionally with the thickness and equivalent weight of the membrane. Although the SO{sub 2} transport in the Nafion{reg_sign} membranes is higher than desired, the excellent chemical stability and conductivity makes this membrane the best commercially-available membrane at this time. Initial results indicated that a modified Nafion{reg_sign} membrane incorporating Pt nanoparticles exhibited significantly reduced SO{sub 2} transport. Reduced SO{sub 2} transport was also measured with commercially available PBI membrane and several experimental membranes produced

  18. COMMERCIAL SNF ACCIDENT RELEASE FRACTIONS

    SciTech Connect (OSTI)

    S.O. Bader

    1999-10-18

    The purpose of this design analysis is to specify and document the total and respirable fractions for radioactive materials that are released from an accident event at the Monitored Geologic Repository (MGR) involving commercial spent nuclear fuel (CSNF) in a dry environment. The total and respirable release fractions will be used to support the preclosure licensing basis for the MGR. The total release fraction is defined as the fraction of total CSNF assembly inventory, typically expressed as an activity inventory (e.g., curies), of a given radionuclide that is released to the environment from a waste form. The radionuclides are released from the inside of breached fuel rods (or pins) and from the detachment of radioactive material (crud) from the outside surfaces of fuel rods and other components of fuel assemblies. The total release fraction accounts for several mechanisms that tend to retain, retard, or diminish the amount of radionuclides that are available for transport to dose receptors or otherwise can be shown to reduce exposure of receptors to radiological releases. The total release fraction includes a fraction of airborne material that is respirable and could result in inhalation doses. This subset of the total release fraction is referred to as the respirable release fraction. Potential accidents may involve waste forms that are characterized as either bare (unconfined) fuel assemblies or confined fuel assemblies. The confined CSNF assemblies at the MGR are contained in shipping casks, canisters, or disposal containers (waste packages). In contrast to the bare fuel assemblies, the container that confines the fuel assemblies has the potential of providing an additional barrier for diminishing the total release fraction should the fuel rod cladding breach during an accident. However, this analysis will not take credit for this additional bamer and will establish only the total release fractions for bare unconfined CSNF assemblies, which may however be

  19. Press Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Press Releases Press Releases RSS August 1, 2016 Press Releases NREL Technique Leads to Improved Solar Cells Scientists at the Energy Department's National Renewable Energy Laboratory (NREL), in collaboration with researchers at Shanghai Jiao Tong University (SJTU), devised a method to improve perovskite solar cells, making them more efficient and reliable with higher reproducibility. July 28, 2016 Battery500 Consortium to Spark EV Innovations: Pacific Northwest National Laboratory-led, 5-year

  20. Accident Investigation Report- Radiological Release

    Broader source: Energy.gov [DOE]

    On February 14, 2014, an airborne radiological release occurred at the Department of Energy Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico. Because access to the underground was restricted following the event, the investigation was broken into two phases. The Phase 1 report focused on how the radiological material was released into the atmosphere and Phase 2, performed once limited access to the underground was re‐established, focused on the source of the released radiological material.

  1. Environmental Justice Interagency Working Group releases "Promising...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Justice Interagency Working Group releases "Promising Practices for EJ Methodologies in NEPA Reviews" Environmental Justice Interagency Working Group releases ...

  2. DOE Releases Electricity Subsector Cybersecurity Risk Management...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Releases Electricity Subsector Cybersecurity Risk Management Process (RMP) Guideline DOE Releases Electricity Subsector Cybersecurity Risk Management Process (RMP) Guideline May ...

  3. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C.

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  4. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  5. CLOSEOUT REPORT FOR HYBRID SULFUR PRESSURIZED BUTTON CELL TEST FACILITY

    SciTech Connect (OSTI)

    Steeper, T.

    2010-09-15

    This document is the Close-Out Report for design and partial fabrication of the Pressurized Button Cell Test Facility at Savannah River National Laboratory (SRNL). This facility was planned to help develop the sulfur dioxide depolarized electrolyzer (SDE) that is a key component of the Hybrid Sulfur Cycle for generating hydrogen. The purpose of this report is to provide as much information as possible in case the decision is made to resume research. This report satisfies DOE Milestone M3GSR10VH030107.0. The HyS Cycle is a hybrid thermochemical cycle that may be used in conjunction with advanced nuclear reactors or centralized solar receivers to produce hydrogen by watersplitting. The HyS Cycle utilizes the high temperature (>800 C) thermal decomposition of sulfuric acid to produce oxygen and regenerate sulfur dioxide. The unique aspect of HyS is the generation of hydrogen in a water electrolyzer that is operated under conditions where dissolved sulfur dioxide depolarizes the anodic reaction, resulting in substantial voltage reduction. Low cell voltage is essential for both high thermodynamic efficiency and low hydrogen cost. Sulfur dioxide is oxidized at the anode, producing sulfuric acid that is sent to the high temperature acid decomposition portion of the cycle. Sulfur dioxide from the decomposer is cycled back to electrolyzers. The electrolyzer cell uses the membrane electrode assembly (MEA) concept. Anode and cathode are formed by spraying a catalyst, typically platinized carbon, on both sides of a Proton Exchange Membrane (PEM). SRNL has been testing SDEs for several years including an atmospheric pressure Button Cell electrolyzer (2 cm{sup 2} active area) and an elevated temperature/pressure Single Cell electrolyzer (54.8 cm{sup 2} active area). SRNL tested 37 MEAs in the Single Cell electrolyzer facility from June 2005 until June 2009, when funding was discontinued. An important result of the final months of testing was the development of a method that

  6. UTICA 4, NEW YORK COFIPOR~TION

    Office of Legacy Management (LM)

    H. J. Zmjian, GE", of the ncmbers of our orzaniza- has a "Q" cl:arance and our President is rcqueoting an 'L" clearance for some of us. -'n would appreciate it very much if you ...

  7. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification

    SciTech Connect (OSTI)

    Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

    2012-06-20

    Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

  8. NREL Releases Updated Typical Meteorological Year Data Set - News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | NREL NREL Releases Updated Typical Meteorological Year Data Set May 1, 2008 The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) today released an updated typical meteorological year (TMY) data set derived from the 1991-2005 National Solar Radiation Data Base update. The TMY3 data and user's manual are available at http://rredc.nrel.gov/solar/old_data/nsrdb/1991-2005/tmy3. The new data sets update and expand the TMY2 data sets released by NREL in 1994. The TMY3 data

  9. The South Karelia Air Pollution Study. The effects of malodorous sulfur compounds from pulp mills on respiratory and other symptoms

    SciTech Connect (OSTI)

    Jaakkola, J.J.; Vilkka, V.; Marttila, O.; Jaeppinen, P.H.; Haahtela, T. )

    1990-12-01

    The paper mills in South Karelia, the southeast part of Finland, are responsible for releasing a substantial amount of malodorous sulfur compounds such as hydrogen sulfide (H2S), methyl mercaptan (CH3SH), and methyl sulfides ((CH3)2S and (CH3)2S2), into ambient air. In the most polluted residential area the annual mean concentrations of hydrogen sulfide and methyl mercaptan are estimated to be 8 and 2 to 5 micrograms/m3 and the highest daily average concentration 100 and 50 micrograms/m3. The annual mean and highest daily concentrations of sulfur dioxide (SO2) are very low. We studied the effects of malodorous sulfur compounds on eye, nasal and respiratory symptoms, and headache in adults. A cross-sectional self-administered questionnaire was distributed in February 1987 and responded to by 488 adults living in a severely (n = 198), a moderately (n = 204), and a nonpolluted community (n = 86). This included questions about occurrence of the symptoms of interest during the previous 4 wk and 12 months and individual, behavioral, and other environmental determinants of the symptoms. The response rate was 83%. The odds ratios (OR) for symptoms experienced often or constantly in severely versus nonpolluted and moderately versus nonpolluted communities were estimated in logistic regression analysis controlling potential confounders. The odds ratios for eye (moderate exposure OR 11.70, Cl95% 2.33 to 58.65; severe exposure OR 11.78, Cl95% 2.35 to 59.09) and nasal symptoms (OR 2.01, Cl95% 0.97 to 4.15; OR 2.19, Cl95% 1.06 to 4.55) and cough (OR 1.89, Cl95% 0.61 to 5.86; OR 3.06, Cl95% 1.02 to 9.29) during the previous 12 months were increased, with a dose-response pattern.

  10. Method of making sulfur-resistant composite metal membranes

    DOE Patents [OSTI]

    Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

    2012-01-24

    The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.