National Library of Energy BETA

Sample records for tion releases sulfur

  1. The SpallaTion

    Energy Savers [EERE]

    SpallaTion neuTron Source projecT When the Department of Energy (DOE) set out in the 1990s to develop a neutron scattering research facility that was ten times more powerful than the state of the art, the concept for the project that it chose was as ambitious as the scientific capability it sought to deliver. The Spallation Neutron Source (SNS) Project called for unprecedented collaboration among six national laboratories as well as significant research and development that would push the

  2. CUSSSFIC4TION CMUXLLq

    Office of Legacy Management (LM)

    CUSSSFIC4TION CMUXLLq RITE AUG 1 7 1962 Fcx the Atomic. Energy Commisaion~ Chief. Declaseifle@tlon Brar\qh F-mm A. B. Grsaingsr (Other ends tifmtioel) The die wae foutq3 to workvery satiafactorilywiti thlanew Qpeof incert, andncm,of tbepmvLouedsfeotaofeoo+tH&' iOitYwaslmd. D&e& ._: . . ..YG ~Kl.3. i>ro;rid3 -&I:: clcsuro on bct.k.mds of the .plece m & Die #l, is also to be tried outoo 4zgust22. Barr~l~or~~~Die~~hadalaobeenawlLfiedta' plwidesd~do~-

  3. CLASSIFICdTION CAWXL~ DAm

    Office of Legacy Management (LM)

    CLASSIFICdTION CAWXL~ DAm NAR 6 1969 For the Atomic EhergY hDh=+= ,' ROBERT L JACKSON /(\' t' for the Chief, Declassification B~Jx~

  4. UTICA 4, NEW YORK COFIPOR~TION

    Office of Legacy Management (LM)

    DROf fORGE & TOOL UTICA 4, NEW YORK COFIPOR~TION PHONE 3- 2331 July 5, 1955 ?:r. E. J. Block Director of Production Division United Staton Atomic ::norgy Commission Yiashington, D. C. Dear Xr. 1310~1~: Xe had a visit last Thursday from Kr. R. C. Sale11 of the: Atomic Energy Commission who inspected our vacuum melting facilities. EIz suggested that we should get in touch with you and that you r+ht be interested in the use of our facilities for the i>roduction of uranium fuel elements. Xe

  5. Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

  6. SANDIA COKPOK4TION SANDIA BASE, .QLDUQUERQUE. N. M.

    Office of Legacy Management (LM)

    SANDIA COKPOK4TION SANDIA BASE, .QLDUQUERQUE. N. M. To : DISTRIBUTION Re: Disposition of t h e Shoal S i t e Attached herewith i s a study which has been made s w g e s t i n g p o s s i b l e f u r t h e r uses of t h e Shoal S i t e . I - ! e have a l s o b r i e f l y described how permanent d i s p o s i t i o n might be made. The study has been made with t h e hope t h a t it w i l l evolce f u r t h e r considerc~tion of t h e s i t e and l e a d t o a plan f o r continued use and eventual

  7. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H. (LaJolla, CA)

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  8. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  9. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur...

    Office of Scientific and Technical Information (OSTI)

    Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be ...

  10. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery

    Office of Scientific and Technical Information (OSTI)

    electrodes (Patent) | SciTech Connect sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the

  11. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  12. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  13. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  14. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  15. Bacterial Sulfur Storage Globules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by I. J. Pickering and G. N. George Sulfur is essential for all life, but it plays a particularly central role in the metabolism of many anaerobic microorganisms. Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for use when food is in short supply (Fig. 1). The chemical nature of the sulfur in these globules has been an enigma since they were first described as

  16. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  17. Separation of sulfur isotopes

    DOE Patents [OSTI]

    DeWitt, Robert; Jepson, Bernhart E.; Schwind, Roger A.

    1976-06-22

    Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

  18. Sulfur removal and comminution of carbonaceous material

    SciTech Connect (OSTI)

    Narain, Nand K.; Ruether, John A.; Smith, Dennis N.

    1988-01-01

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

  19. Sulfur removal and comminution of carbonaceous material

    SciTech Connect (OSTI)

    Narain, N.K.; Ruether, J.A.; Smith, D.N.

    1987-10-07

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

  20. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Mikkor, Mati (Ann Arbor, MI)

    1981-01-01

    This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

  1. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

    1996-01-01

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

  2. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Topouzian, Armenag (Birmingham, MI)

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  3. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA)

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  4. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  5. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  6. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  7. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Jozewicz, Wojciech (Chapel Hill, NC)

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  8. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    globally distributed sulfur-oxidizing bacteria in the deep sea carry bacterial genes for the oxidation of elemental sulfur. Although such observations are common in...

  9. Grain Boundary Percolation Modeling of Fission Gas Release in Oxide Fuels

    SciTech Connect (OSTI)

    Paul C. Millett; Michael R. Tonks; S. B. Biner

    2012-05-01

    We present a new approach to fission gas release modeling in oxide fuels based on grain boundary network percolation. The method accounts for variability in the bubble growth and coalescence rates on individual grain boundaries, and the resulting effect on macroscopic fission gas release. Two-dimensional representa- tions of fuel pellet microstructures are considered, and the resulting gas release rates are compared with traditional two-stage Booth models, which do not account for long-range percolation on grain boundary net- works. The results show that the requirement of percolation of saturated grain boundaries can considerably reduce the total gas release rates, particularly when gas resolution is considered.

  10. Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    DOE Patents [OSTI]

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

    2015-04-07

    A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

  11. Martinez Sulfuric Acid Regeneration Plt Biomass Facility | Open...

    Open Energy Info (EERE)

    Martinez Sulfuric Acid Regeneration Plt Biomass Facility Jump to: navigation, search Name Martinez Sulfuric Acid Regeneration Plt Biomass Facility Facility Martinez Sulfuric Acid...

  12. Method of preparing graphene-sulfur nanocomposites for rechargeable...

    Office of Scientific and Technical Information (OSTI)

    and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur...

  13. WIPP News Release Archives Index

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WIPP News Release Archives 2006 News Releases 2005 News Releases 2004 News Releases 2003 News Releases 2002 News Releases 2001 News Releases 2000 News Releases 1999 News Releases...

  14. FINAL RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE AWARDEE: ____________________________________________________ The work under Award No. DE-__________________________, dated ______________, between the United States of America (represented by the Department of Energy, National Energy Technology Laboratory, and the undersigned awardee, having been completed and finally accepted , and in consideration of Final Payment thereunder, the United States of America, its officers, agents and employees are hereby released from all liabilities,

  15. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","12/2015","1/15/1985" ,"Release Date:","2/29/2016" ,"Next Release

  16. Seal for sodium sulfur battery

    DOE Patents [OSTI]

    Topouzian, Armenag (Birmingham, MI); Minck, Robert W. (Lathrup Village, MI); Williams, William J. (Northville, MI)

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  17. News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Releases /newsroom/_assets/images/legacy-icon-short.jpg News Releases Accessible by Topic, Keywords (See "Search Releases") or Chronologically (See "ALL") Health» Space» Computing» Energy» Earth» Materials» Science» Technology» The Lab» All» Inside the Los Alamos National Laboratory fuel cell test lab, graduate students and a post-doctoral researcher work on ElectroCat technology-at rear, Joseph Dumont, Ulises Martinez, Ling Lin. Argonne and Los Alamos national

  18. Two stage sorption of sulfur compounds

    DOE Patents [OSTI]

    Moore, William E.

    1992-01-01

    A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

  19. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key partsa positive and negative electrode and an electrolytethat exchange ions to store and release electricity. Using different materials for these components changes a batterys chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  20. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  1. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfurmore » were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.« less

  2. Method of preparing graphene-sulfur nanocomposites for rechargeable

    Office of Scientific and Technical Information (OSTI)

    lithium-sulfur battery electrodes (Patent) | SciTech Connect Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing

  3. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in LiS battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfur were the S42 and S52 species, while the widely accepted reduction products of S82 and S62 for the first reduction wave were in low abundance.

  4. On the formation of carbonyl sulfide in the reduction of sulfur dioxide by carbon monoxide on lanthanum oxysulfide catalyst: A study by XPS and TPR/MS

    SciTech Connect (OSTI)

    Lau, N.T.; Fang, M. [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center] [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center

    1998-10-25

    Both the X-ray photoelectron spectroscopy (XPS) and temperature-programmed reaction, coupled with mass spectrometry (TPR/MS), are used to study the formation of carbonyl sulfide in the reduction of sulfur dioxide on lanthanum oxysulfide catalyst. It was found that the lattice sulfur of the oxysulfide is released and reacts with carbon monoxide to form carbonyl sulfide when the oxysulfide is heated. The oxysulfide is postulated to form sulfur vacancies at a temperature lower than that for the formation of carbonyl sulfide and atomic sulfur is released in the process. The atomic sulfur can either enter the gas phase and leave the oxysulfide catalyst or react with carbon monoxide to form carbonyl sulfide.

  5. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An Evolutionary Arms Race for Sulfur An Evolutionary Arms Race for Sulfur Print Friday, 07 November 2014 10:49 On the Earth's surface, plants use photosynthesis to convert sunlight into food. In the deep oceans, however, where no light penetrates, microbes (e.g., bacteria) use chemosynthesis-chemical reactions involving inorganic materials like sulfur-to power the production of the organic compounds necessary for life. Such microbes drive key biogeochemical cycles that impact all life on earth.

  6. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  7. Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries

    DOE Patents [OSTI]

    Liang, Chengdu; Dudney, Nancy J; Howe, Jane Y

    2015-05-05

    The invention is directed in a first aspect to a sulfur-carbon composite material comprising: (i) a bimodal porous carbon component containing therein a first mode of pores which are mesopores, and a second mode of pores which are micropores; and (ii) elemental sulfur contained in at least a portion of said micropores. The invention is also directed to the aforesaid sulfur-carbon composite as a layer on a current collector material; a lithium ion battery containing the sulfur-carbon composite in a cathode therein; as well as a method for preparing the sulfur-composite material.

  8. Identification of Martian Regolith Sulfur Components In Shergottites...

    Office of Scientific and Technical Information (OSTI)

    Using Sulfur K XANES and FeS Ratios. Citation Details In-Document Search Title: Identification of Martian Regolith Sulfur Components In Shergottites Using Sulfur K XANES and FeS ...

  9. Stabilized sulfur binding using activated fillers

    DOE Patents [OSTI]

    Kalb, Paul D.; Vagin, Vyacheslav P.; Vagin, Sergey P.

    2015-07-21

    A method of making a stable, sulfur binding composite comprising impregnating a solid aggregate with an organic modifier comprising unsaturated hydrocarbons with at least one double or triple covalent bond between adjacent carbon atoms to create a modifier-impregnated aggregate; heating and drying the modifier-impregnated aggregate to activate the surface of the modifier-impregnated aggregate for reaction with sulfur.

  10. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  11. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  12. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  13. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  14. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Newsroom Press Releases Newsroom Press Releases Media Contacts Photo Gallery The Hanford Story Hanford Blog Hanford YouTube Channel

  15. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Batteries | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es105_liang_2011_o.pdf More Documents & Publications Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Protection of Li Anodes Using Dual Phase Electrolytes

  16. Definition of Non-Conventional Sulfur Utilization in Western Kazakhstan for Sulfur Concrete (Phase 1)

    SciTech Connect (OSTI)

    Kalb, Paul

    2007-05-31

    Battelle received a contract from Agip-KCO, on behalf a consortium of international oil and gas companies with exploration rights in the North Caspian Sea, Kazakhstan. The objective of the work was to identify and help develop new techniques for sulfur concrete products from waste, by-product sulfur that will be generated in large quantitites as drilling operations begin in the near future. BNL has significant expertise in the development and use of sulfur concrete products and has direct experience collaborating with the Russian and Kazakh partners that participated. Feasibility testing was successfully conducted for a new process to produce cost-effective sulfur polymer cement that has broad commerical applications.

  17. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    DOE Patents [OSTI]

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  18. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  19. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, Tetsuo (Ames, IA); Squires, Thomas G. (Gilbert, IA); Venier, Clifford G. (Ames, IA)

    1985-02-05

    A process for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  20. Spray drying for high-sulfur coal

    SciTech Connect (OSTI)

    Rhudy, R.

    1988-09-01

    Recent pilot plant tests indicate that spray drying, now used to control SO/sub 2/ emissions from low-sulfur coal, can also be effective for high-sulfur coal. Spray drying coupled with baghouse particulate removal is the most effective configuration tested to date, removing over 90% of SO/sub 2/ while easily meeting New Source Performance Standards for particulate emissions. 2 figures, 1 table.

  1. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  2. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; Yang, Xiao-Qing; Zhang, Ji-Guang; Liu, Jun; Xiao, Jie

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  3. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore » cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  4. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  5. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur ...

  6. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur ...

  7. Photodissociation spectroscopy of the carbonyl sulfide ion with momentum analysis of the sulfur product ion

    SciTech Connect (OSTI)

    Snow, K.B.

    1993-01-01

    A Nuclide 12-90-G mass spectrometer was modified for use as a photofragment momentum spectrometer. The resultant apparatus was capable of obtaining both absolute cross sections for photodissociation with respect to wavelength and relative cross sections for photodissociation with respect to kinetic energy release. The kinetic energy release for the photodissociation reaction of the nitrous oxide cation (leading to the production of the nitric oxide cation and the nitrogen atom), was studied at 3080.4 [angstrom], 3371.3 [angstrom], and 3381.4 [angstrom]. When a nitrogen atom was produced in the [sup 4]S state, the nitric oxide cation was found to be formed predominantly with 5 to 7 quanta of vibrational energy. Nitrogen atoms were formed preferentially in the [sup 2]D state when it was energetically feasible at 3371.3 [angstrom] and 3080.4 [angstrom]. The kinetic energy release for the photodissociation reaction of the carbonyl sulfide cation (leading to the production of carbon monoxide and a sulfur cation), was studied at 2822.2 [angstrom], 2921.8 [angstrom], 2991.0 [angstrom], 2991.9 [angstrom], 3080.4 [angstrom], 3104.3 [angstrom], 3127.9 [angstrom], 3184.9 [angstrom], 3351.8 [angstrom], 3371.3 [angstrom], and 3393.0 [angstrom]. When sulfur cations were produced in the [sup 4]S state, the carbon monoxide products were formed predominantly with 5 to 7 quanta of vibrational energy. Sulfur cations were formed preferentially in the [sup 2]D state from hot bands at 3351.8 [angstrom], 3080.4 [angstrom], and 2991.9 [angstrom]. Sulfur cations were also produced in the [sup 2]D state at 2921.8 [angstrom] and 2822.2 [angstrom], where it was energetically feasible from the ground state of carbonyl sulfide cations.

  8. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Richland Operations Office Newsroom Press Releases Richland Operations Office Richland Operations Office River Corridor Central Plateau Groundwater Mission Support Newsroom Press Releases News Calendar

  9. Latest News Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Release Release Date: Contact: Shelley Martin, DOE National Energy Technology Laboratory, 304-285-0228, contact.publicaffairs@netl.doe.gov 2016 2015 2014 2013

  10. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  11. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, Perry E.

    1981-01-01

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another.

  12. EPA Diesel Rule and the Sulfur Effects (DECSE) Project

    SciTech Connect (OSTI)

    2009-05-08

    The VT program collaborated with industry stakeholders and the EPA (in an effort initiated in 1998 called Diesel Emission Control Sulfur Effects study, otherwise known as DECSE) to quantify the effects of fuel sulfur on emission control technologies.

  13. Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation...

  14. Heat Release Rates

    Office of Energy Efficiency and Renewable Energy (EERE)

    Supporting Technical Document for the Radiological Release Accident Investigation Report (Phase II Report)

  15. Microsoft Word - Updated Air Dispersion Modeling Table _sulfur_.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DIVINE STRAKE AIR DISPERSION MODELING RESULTS for SULFUR DIOXIDE The attached table is updated to include estimated sulfur dioxide concentrations resulting from the Divine Strake Experiment. Output from the POLU4WN model was used to estimate quantities of all emissions from the proposed explosive experiment. All emissions of oxides of sulfur were combined to provide input into Open Burn/Open Detonation Model (OBODM) to model the dispersion; thus overestimating the concentration of sulfur dioxide

  16. Sulfuric acid thermoelectrochemical system and method

    DOE Patents [OSTI]

    Ludwig, Frank A. (Rancho Palos Verdes, CA)

    1989-01-01

    A thermoelectrochemical system in which an electrical current is generated between a cathode immersed in a concentrated sulfuric acid solution and an anode immersed in an aqueous buffer solution of sodium bisulfate and sodium sulfate. Reactants consumed at the electrodes during the electrochemical reaction are thermochemically regenerated and recycled to the electrodes to provide continuous operation of the system.

  17. Potential Release Sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PRS Potential Release Sites Legacy sites where hazardous materials are found to be above acceptable levels are collectively called potential release sites. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Less than 10 percent of the total number of potential release sites need to go through the full corrective action process. What are potential release sites? Potential release sites are areas around the Laboratory and

  18. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

    1991-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  19. Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication LBNL Commercial Analysis Report (1,062 KB) Technology Marketing Summary A Berkeley Lab team headed by Yuegang Zhang and Elton Cairns has developed

  20. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High

  1. Tailoring Pore Size of Nitrogen-Doped Hollow Carbon Nanospheres for Confi ning Sulfur in LithiumSulfur Batteries

    SciTech Connect (OSTI)

    Zhou, Weidong; Wang, Chong M.; Zhang, Quiglin; Abruna, Hector D.; He, Yang; Wang, Jiangwei; Mao, Scott X.; Xiao, Xingcheng

    2015-08-19

    Three types of nitrogen-doped hollow carbon spheres with different pore sized porous shells are prepared to investigate the performance of sulfur confinement. The reason that why no sulfur is observed in previous research is determined and it is successfully demonstrated that the sulfur/polysulfide will overflow the porous carbon during the lithiation process.

  2. Identification of Martian Regolith Sulfur Components In Shergottites Using

    Office of Scientific and Technical Information (OSTI)

    Sulfur K XANES and Fe/S Ratios. (Conference) | SciTech Connect Identification of Martian Regolith Sulfur Components In Shergottites Using Sulfur K XANES and Fe/S Ratios. Citation Details In-Document Search Title: Identification of Martian Regolith Sulfur Components In Shergottites Using Sulfur K XANES and Fe/S Ratios. Authors: Sutton, S.R. ; Ross, D.K. ; Rao, M.N. ; Nyquist, L.E. [1] ; ESCG Jacobs) [2] ; UC) [2] + Show Author Affiliations (NASA-JSC) [NASA-JSC ( Publication Date: 2014-02-26

  3. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  4. CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H

    2007-01-31

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

  5. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  6. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Liu, Wei (Cambridge, MA)

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  7. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

    1989-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  8. Removal of sulfur compounds from combustion product exhaust

    DOE Patents [OSTI]

    Cheng, Dah Y. (Palo Alto, CA)

    1982-01-01

    A method and device are disclosed for removing sulfur containing contaminents from a combustion product exhaust. The removal process is carried out in two stages wherein the combustion product exhaust is dissolved in water, the water being then heated to drive off the sulfur containing contaminents. The sulfur containing gases are then resolublized in a cold water trap to form a concentrated solution which can then be used as a commercial product.

  9. Project Profile: Baseload CSP Generation Integrated with Sulfur-Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Heat Storage | Department of Energy Concentrating Solar Power » Project Profile: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage Project Profile: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage General Atomics logo General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power

  10. Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Solar Photovoltaic Solar Photovoltaic Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon Oak Ridge National Laboratory Contact ORNL About This Technology Publications: PDF Document Publication 11-G00232_ID2519.pdf (729 KB) Technology Marketing SummaryA sulfur/carbon composite material was prepared by heat treatment of doped mesoporous carbon and elemental sulfur

  11. Sulfide catalysts for reducing SO2 to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

    2001-01-01

    A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

  12. Extraction of Sulfur Mustard Metabolites from Urine Samples and...

    Office of Scientific and Technical Information (OSTI)

    Extraction of Sulfur Mustard Metabolites from Urine Samples and Analysis by Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) Citation Details In-Document Search...

  13. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials Sulfur Effect and Performance Recovery of a DOC...

  14. Extraction of Sulfur Mustard Metabolites from Urine Samples and...

    Office of Scientific and Technical Information (OSTI)

    Title: Extraction of Sulfur Mustard Metabolites from Urine Samples and Analysis by Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) Authors: Mayer, B P ; Williams, ...

  15. All News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    All News Releases /newsroom/_assets/images/newsroom-icon.jpg All News Releases Accessible by Topic, Keywords (See "Search Releases") or Chronologically (See "ALL"). Health Space Computing Energy Earth Materials Science Technology The Lab All Inside the Los Alamos National Laboratory fuel cell test lab, graduate students and a post-doctoral researcher work on ElectroCat technology-at rear, Joseph Dumont, Ulises Martinez, Ling Lin. Argonne and Los Alamos national laboratories

  16. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current News Releases March 20, 2015 - Event News Release #2 WIPP Emergency Operations Center Deactivated March 20, 2015 - Event News Release #1 Emergency Operation Center Activated as Precautionary Measure for Offsite Event November 25, 2014 CBFO and WIPP Volunteerism Helps Little Ones This Winter Karing for Kids Koat Drive November 10, 2014 CBFO and WIPP Commemorations for Veterans Day 2014 Photo 1: Veterans Commeration at Skeen-Whitlock, Nov. 6, 2014 Photo 2: Veterans Commeration at

  17. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  18. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases October 29 WIPP Environmental Initiatives Earn DOE Recognition Click on photo below for larger image. October 24 WIPP Security Contractor Receives DOE Voluntary...

  19. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases December 18 CBFO Selects Quality Assurance Director Click on photo below for larger image. December 2 Carlsbad Field Office Deputy Manager Selected Click on photo...

  20. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    email mikep@fnal.gov For Immediate Release NRELs John Turner Explores The Sustainable Hydrogen Economy in Energy Colloquium Presentation at Fermilab on Wednesday, July 6;...

  1. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 News Releases December 1 State Renews WIPP Facility Permit November 18 National TRU Program Director Selected November 18 Waste Isolation Pilot Plant Receives Second EPA...

  2. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sdahl@fnal.gov For Immediate Release Children's Science Adventures at Fermilab Offer Summer Fun - and Learning, Too BATAVIA, Illinois-Summertime is a bright season of...

  3. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    email bland@fnal.gov For Immediate Release Fermilab Colloquium Series Offers Free Public Talks on World Energy Situation Beginning Wednesday, April 13 BATAVIA,...

  4. Released: December 2015

    U.S. Energy Information Administration (EIA) Indexed Site

    Levels of Price Difference that Would Cause a Switch from Electricity(c) Released: December 2015 Next ... Source: Energy Information Administration, Office of Energy Markets and End ...

  5. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    26, 1999 For immediate release PRESS ADVISORY: SIGN UP FOR COVERAGE OF MAIN INJECTOR DEDICATION ON TUESDAY, JUNE 1; RICHARDSON, HASTERT TO SPEAK Batavia, Ill.Secretary of...

  6. Nonflame, source-induced sulfur fluorescence detector for sulfur-containing compounds

    SciTech Connect (OSTI)

    Gage, D.R.; Farwell, S.O.

    1980-12-01

    Results of some preliminary investigations of the fluorescence spectra of S/sub 2/ and the non-flame production of S/sub 2/ from sulfur-containing molecules are reported. Passage of the gas to be analyzed through a catalyst-oven containing a plug of NiO/sub 2//Al/sub 2/O/sub 3/ catalyst containing 10 wt% NiO/sub 2/ and heated to 400/sup 0/C resulted in conversion of H/sub 2/S to S/sub 2/ and elemental sulfur. The S/sub 2/ was detected by measurement of its fluorescence bands at 260 and 310nm, and elemental sulfur condensed on the cool parts of the apparatus. However, determination of sulfur-content of gas mixtures with the apparatus described herein were not as repeatable as desired, and the work is being continued on various facets of the non-flame system with work being directed toward the evaluation of different catalysts, catalyst temperature, design of a smaller detector geometry utilizing a pulsed-light excitation source, a windowless cell, and optical filters instead of monochromators to select the S/sub 2/ excitation and emission wavelengths. (BLM)

  7. Audit Manual (Release 8)

    Energy Savers [EERE]

    Deputy Inspector General for Audits and Inspections AUDIT MANUAL Release 8 Revised 2014 Revised 2014 TOC-1 Release 8 OFFICE OF INSPECTOR GENERAL OFFICE OF AUDITS AUDIT MANUAL TABLE OF CONTENTS Page List of Acronyms ...................................................................................................................LOA-1 PART I -- INTRODUCTION CHAPTER 1 -- INTRODUCTION TO THE AUDIT MANUAL A. Purpose of the Audit Manual

  8. Sodium sulfur container with chromium/chromium oxide coating

    DOE Patents [OSTI]

    Ludwig, Frank A. (Irvine, CA); Higley, Lin R. (Santa Ana, CA)

    1981-01-01

    A coating of chromium/chromium oxide is disclosed for coating the surfaces of electrically conducting components of a sodium sulfur battery. This chromium/chromium oxide coating is placed on the surfaces of the electrically conducting components of the battery which are in contact with molten polysulfide and sulfur reactants during battery operation.

  9. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  10. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  11. Metal-sulfur type cell having improved positive electrode

    DOE Patents [OSTI]

    DeJonghe, L.C.; Visco, S.J.; Mailhe, C.C.; Armand, M.B.

    1988-03-31

    A novel metal-sulfur type cell operable at a temperature of 200/degree/C or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S)/sub y/)n wherein y = 1 to 6; n = 2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprises one or more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon. 4 figs.

  12. Metal-sulfur type cell having improved positive electrode

    DOE Patents [OSTI]

    Dejonghe, Lutgard C.; Visco, Steven J.; Mailhe, Catherine C.; Armand, Michel B.

    1989-01-01

    An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

  13. DOCUMENT RELEASE FORM C

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE FORM C (1) Document Number: RPP-RPT-431 74 (2) Revision Number: (3) Effective Date: 9/30/2009 (4) Document Type: El Digital Image El Hard copy (a) Number of pages (including the DRF) or 107 E PDF E] Video number of digital images (5) Release Type 0 New El Cancel El Page Change El complete Revision (6) Document Title: 2009 Auto-TOR for Tank 241 -T-204 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c)

  14. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    release MiniBooNE opens the box Results from Fermilab experiment resolve long-standing neutrino question BATAVIA, Illinois-Scientists of the MiniBooNE1 experiment at the...

  15. WIPP News Releases - 1996

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases DOE to Hold Public Hearings Next Week in Albuquerque on WIPP SEIS - 123196 DOE to Hold Public Hearings Next Week in Santa Fe on WIPP SEIS - 123196 DOE Announces ...

  16. WIPP News Releases - 2005

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases December 27 Empty WIPP truck overturns December 12 Dr. Dave Moody to Lead the Carlsbad Field Office December 7 WIPP Satellite Tracking System Relocates to Carlsbad...

  17. WIPP News Releases - 2006

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases December 12 Idaho National Laboratory Waste Stream Cleared for Shipment to WIPP November 15 WIPP Reaches 4-Million-Hour Safety Milestone October 16 State of New Mexico...

  18. News Releases Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 cool science and technology stories from Argonne in 2015 http:www.anl.govarticles10-cool-science-and-technology-stories-argonne-2015 December 23, 2015 News Releases Feed...

  19. 2009 WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    09 News Releases December 21 Magnum Minerals to Buy WIPP Salt October 14 Agreement Reached Between WTS and Union Employees October 1 Truck Accident Did Not Involve WIPP Shipment...

  20. Rad-Release

    ScienceCinema (OSTI)

    None

    2013-05-28

    The R&D 100 Award winning Rad-Release Chemical Decontamination Technology is a highly effective (up to 99% removal rate), affordable, patented chemical-foam-clay decontamination process tailored to specific radiological and metal contaminants, which is applicable to a wide variety of substrates. For more information about this project, visit http://www.inl.gov/rd100/2011/rad-release/

  1. Emission of volatile sulfur compounds during composting of municipal solid waste (MSW)

    SciTech Connect (OSTI)

    Zhang, Hongyu; Schuchardt, Frank; Li, Guoxue; Yang, Jinbing; Yang, Qingyuan

    2013-04-15

    Highlights: ? We compare the volatile sulfur compounds (VSCs) emissions during three types of municipal solid wastes (MSWs) composting. ? The VSCs released from the kitchen waste composting was significantly higher than that from 1580 mm fraction of MSW. ? Among the five VSCs, H{sub 2}S was the most abundant compound with 39.043.0% of total VSCs released. ? Addition of 20% cornstalks could significantly reduce the VSCs emissions during kitchen waste composting. - Abstract: Volatile sulfur compounds (VSCs) are the main source for malodor from composting plants. In this study, the VSCs generated from composting of 1580 mm municipal solid waste (T0), kitchen waste (T1) and kitchen waste mixed dry cornstalks (T2) were measured in 60 L reactors with forced aeration for a period of 30 days. The VSCs detected in all treatments were hydrogen sulfide (H{sub 2}S), methyl mercaptan (MM), dimethyl sulfide (DMS), carbon bisulfide (CS{sub 2}) and dimethyl disulfide (DMDS). Over 90% of the VSCs emissions occurred during the first 15 days, and reached their peak values at days 47. The emission profiles of five VSCs species were significantly correlated with internal materials temperature and outlet O{sub 2} concentration (p < 0.05). Total emissions of the VSCs were 216.1, 379.3 and 126.0 mg kg{sup ?1} (dry matter) for T0, T1 and T2, respectively. Among the five VSCs, H{sub 2}S was the most abundant compound with 39.043.0% of total VSCs released. Composting of kitchen waste from separate collection posed a negative influence on the VSC and leachate production because of its high moisture content. An addition of dry cornstalks at a mixing ratio of 4:1 (wet weight) could significantly reduce the VSCs emissions and avoid leachate. Compared to pure kitchen waste, VSCs were reduced 66.8%.

  2. Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    via Surface Modification of SiO2 with TiO2 and ZrO2 | Department of Energy Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 This study demonstrates the feasibility of developing highly stable, sulfur-tolerant oxidation catalysts that use less Pt via surface modification of silica supports

  3. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

    1981-01-01

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  4. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  5. DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 (2) Revision Number: 0 1(3) Effective Date: 9/28/2009 (4) Document Type: [] Digital Image [] Hard copy (a) Number of pages (including the DRF) or 76 Z PDF E] Video number of digital images (5) Release Type Z New El cancel E] Page Change El complete Revision (6) Document Title: 2009 Auto-TCR for Tank 241-13-203 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c) Building Number: Structure, System, and Component

  6. DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 (2) Revision Number: 0 (3) Effective Date: 9/28/2009 (4) Document Type: [] Digital Image El Hard copy (a) Number of pages (including the DRF) or 74 0PDF E] Video number of digital images (5) Release Type E New El cancel l Page Change El complete Revision (6) Document Title: 2009 Auto-TCR for Tank 241-13-204 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c) Building Number: Structure, System, and Component N/A

  7. DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    31 97 (2) Revision Number: 0 -- (3) Effective Date: 9/30/2009 (4) Document Type: E] Digital Image l Hard copy (a) Number of pages (including the DRF) or 84 0 POE E Video number of digital images (5) Release Type Z New 1:1 Cancel liiPage Change Elcomplete Revision (6) Document Title: 2009 Auto-TOR for Tank 241 -TY-1 05 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c) Building Number: Structure, System, and

  8. ARM - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Related Links TWP-ICE Home Tropical Western Pacific Home ARM Data Discovery Browse Data Post-Experiment Data Sets Weather Summary (pdf, 6M) New York Workshop Presentations Experiment Planning TWP-ICE Proposal Abstract Detailed Experiment Description Science Plan (pdf, 1M) Operations Plan (pdf, 321K) Maps Contact Info Related Links Daily Report Report Archives Press Media Coverage TWP-ICE Fact Sheet (pdf, 211K) Press Releases TWP-ICE Images ARM flickr site <=""

  9. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  10. METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY

    SciTech Connect (OSTI)

    Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

    2009-06-22

    HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

  11. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  12. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  13. Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Sulfur Poisoning of NOx Adsorber (LNT) Materials Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_24_peden.pdf More Documents & Publications Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials

  14. 2015 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 21, 2015 NREL Research Advances Hydrogen Production Efforts Researchers at the Energy Department's National Renewable Energy Laboratory (NREL) have made advances toward affordable photoelectrochemical (PEC) production of hydrogen. December 11, 2015 A Metabolic Pathway in Cyanobacteria Could Yield Better Biofuels and Bioproducts from Photosynthesis Scientists from

  15. STEP Utility Data Release Form

    Broader source: Energy.gov [DOE]

    STEP Utility Data Release Form, from the Tool Kit Framework: Small Town University Energy Program (STEP).

  16. In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into MDCK Cells In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine into MDCK Cells Sulfur is essential for life. It plays important roles in the amino acids methionine and cysteine, and has a structural function in disulfide bonds. As a component of iron-sulfur clusters it takes part in electron and sulfur transfer reactions.1 Glutathione, a sulfur-containing tripeptide, is an important part of biological antioxidant systems.2 Another example for the biological

  17. NNSA Releases Annual Stockpile Stewardship & Management Plan...

    National Nuclear Security Administration (NNSA)

    NNSA Blog Home Library Press Releases NNSA Releases Annual Stockpile Stewardship & Management Plan NNSA Releases Annual Stockpile Stewardship & Management Plan Press Release...

  18. FOR IMMEDIATE RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FOR IMMEDIATE RELEASE CH2M HILL PLATEAU REMEDIATION COMPANY EXPANDS GROUNDWATER CLEANUP NEAR COLUMBIA RIVER Accelerated Efforts Expanding Hanford Site's Ability to Treat Contaminated Groundwater RICHLAND, WASH. - AUGUST 6, 2009 - U. S. Department of Energy (DOE) and contractor CH2M HILL Plateau Remediation Company (CH2M HILL) are accelerating groundwater cleanup efforts at Hanford's 100 Area. Hanford's 100 Area stretches 16,600 acres along the Columbia River and once housed nine plutonium

  19. FOR IMMEDIATE RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IMMEDIATE RELEASE Media Contacts: January 23, 2012 Cameron Hardy, DOE , (509) 376-5365, Cameron.Hardy@rl.doe.gov DOE Considers Natural Gas Utility Service Options Proposal Includes 30-mile Natural Gas Pipeline from Pasco to Hanford RICHLAND, WASH. - The U.S. Department of Energy (DOE) is considering natural gas transportation and distribution requirements to support the Waste Treatment Plant (WTP) and evaporator operations at the Hanford Site in southeastern Washington State. DOE awarded a task

  20. 1998 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Popular Science Recognizes Innovative Solar Technologies - (12/16/98) Kazmerski Leads National Center for Solar Research - (12/1/98) MRI, Battelle and Bechtel to Manage National Renewable Energy Lab - (11/19/98) Prestigious Council to Advise National Renewable Energy Lab - (11/19/98) Tour Opens Doors, Minds to Solar Energy - (10/5/98) MRI, Battelle, Bechtel Team Wins National

  1. 2000 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search NREL's Zunger Receives Top Scientific Honors - (11/29/00) Report Outlines Promising Opportunities for Addressing Climate Change - (11/15/00) Conference to Focus on Vast Need for 'Village Power' Solar, Wind Power Seen as Solutions for Developing World - (11/10/00) Energy Department Announces National Bioenergy Center - (11/01/00) NREL and California Air Agency to Test Clean

  2. 2002 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Director of National Bioenergy Center Named - (12/12/02) Scientific American' Recognizes Solar Cell Research - (11/11/02) UPS Fleet Study Quantifies the Reliability, Low Emissions of CNG Trucks - (10/29/02) Energy Department Honors Solar Decathlon Winners - (10/05/02) Winner of Solar Decathlon to be Announced - (10/04/02) Solar Decathlon Engineering Design Results Announced -

  3. 2003 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 22, 2003 Renewable Energy a Smart Choice for Farmers and Ranchers December 10, 2003 Georgia Tech's Rohatgi Wins Second Annual Rappaport Award December 9, 2003 Acclaim for Three Leaders at Annual NREL Stakeholders Reception November 14, 2003 World Renewable Energy Congress Provides International Forum November 12, 2003 NREL and Company Researchers Team Up on Thin-Film

  4. 2004 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 21, 2004 NREL Recognizes Solar Pioneer with National Honor November 23, 2004 NREL Recognizes Solar Pioneer with National Honor November 17, 2004 Basalt Middle School Teacher Recognized for Renewable Energy Efforts October 5, 2004 NREL Theorist Recognized for Highest Citation Impact September 24, 2004 NREL Selects Contractor for New Science & Technology Facility

  5. 2005 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search November 17, 2005 Lakewood High School Teacher Recognized for Introduction of Renewable Energy Curriculum Students taking technology classes at Lakewood High School this semester are learning about more than construction, technical theater and computer aided drafting (CAD); they are learning about energy issues within their community. October 31, 2005 Agreement Establishes

  6. 2006 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 14, 2006 Experimental "Wind to Hydrogen" System Up and Running Xcel Energy and the National Renewable Energy Laboratory unveiled a unique facility that uses electricity from wind turbines to produce and store pure hydrogen. November 28, 2006 University of Denver High School Teacher Recognized for Commitment to Renewable Energy Don Cameron, physics and

  7. 2007 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 4, 2007 Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) has pledged to reduce its greenhouse gas emissions by 75 percent from 2005 to 2009. The new goal is part of NREL's participation in the Environmental Protection Agency's (EPA) Climate Leaders program. November 8, 2007 Wakonda

  8. 2008 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 11, 2008 Alternative Fuels and Advanced Vehicle Data Center Creates New Tool to Calculate Ways to Cut Gas Use A business owner with a fleet of 10 heavy-duty diesel trucks wants to cut diesel use by 10 percent. Would using a biodiesel blend or investing in onboard power sources that reduce engine idling achieve the biggest drop in petroleum use? An average driver,

  9. 2010 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 17, 2010 NREL Employees Significantly Increase Their Community Support For the second year in a row, employees of the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) pledged significantly more to community organizations during its annual charitable giving campaign this holiday season. December 2, 2010 Scientists Generate Two Energetic

  10. 2011 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 20, 2011 NREL Licenses Technology to Increase Solar Cell Efficiency The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) announced today that Natcore Technology Inc. has been granted a patent license agreement to develop a line of black silicon products. December 15, 2011 NREL Scientists Report First Solar Cell Producing More Electrons In

  11. 2012 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 21, 2012 NREL Names New Executive The U.S. Department of Energy's National Renewable Energy Laboratory today named Barbara Goodman as Associate Laboratory Director for Renewable Fuels and Vehicle Systems to replace Dale Gardner who is retiring at the end of the year. December 20, 2012 Concentrated Solar Power with Thermal Energy Storage Can Help Utilities' Bottom

  12. 2013 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 12, 2013 NREL Seeks Leaders for National Executive Energy Academy The Energy Department's National Renewable Energy Laboratory (NREL) is accepting applications for its 2014 Executive Energy Leadership Academy. NREL's Executive Energy Leadership Academy, also known as Energy Execs, is a program for non-technical decision-makers throughout the country to learn about

  13. 2014 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search December 23, 2014 NREL Receives Editors' Choice Awards for Supercomputer Research Two prestigious scientific magazines have awarded the Energy Department's National Renewable Energy Laboratory (NREL) with Editors' Choice awards for the Peregrine high-performance computer and the groundbreaking research it made possible. December 18, 2014 Three New Fellows to Help Guide NREL

  14. Press Releases - 2016

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases - 2016 January 28, 2016 New research paper highlights visualization of high-energy electrons in fast-ignition targets In a paper published in Nature Physics, researchers report on the first visualization of fast electron spatial energy deposition in a laser-compressed cone-in-shell fast ignition target. January 22, 2016 Petawatt laser system passes a key milestone The High-Repetition-Rate Advanced Petawatt Laser System (HAPLS) under construction at LLNL recently achieved a key average

  15. Press Releases | JCESR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases New Hybrid Electrolyte for Solid-State Lithium Batteries December 21, 2015 Scientists at the U.S. Department of Energy's Lawrence Berkeley National Laboratory have developed a novel electrolyte for use in solid-state lithium batteries that overcomes many of the problems that plague other solid electrolytes while also showing signs of being compatible with next-generation cathodes. U-M Opens World-Class Battery Research Lab October 2, 2015 University of Michigan's new Battery Lab further

  16. 2016 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2016 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search March 10, 2016 NREL to Collaborate with Small Clean Energy Businesses as Part of DOE Pilot Program The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) will help the first group of small clean energy businesses advance their products under the Small Business Vouchers (SBV) pilot launched last July by DOE. February 29, 2016 NREL Collaboration

  17. Cryogenic hydrogen release research.

    SciTech Connect (OSTI)

    LaFleur, Angela Christine

    2015-12-01

    The objective of this project was to devolop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. The necessary infrastructure has been specified and laboratory modifications are currently underway. Once complete, experiments from this platform will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  18. Insight into Sulfur Reactions in LiS Batteries

    SciTech Connect (OSTI)

    Xu, Rui; Belharouak, Ilias; Zhang, Xiaofeng; chamoun, rita; Yu, Cun; Ren, Yang; Nie, Anmin; Reza, Shahbazian-Yassar; Lu, Jun; Li, James C.M.; Amine, Khalil

    2014-12-09

    Understanding and controlling the sulfur reduction species (Li2Sx, 1 ? x ? 8) under realistic battery conditions are essential for the development of advanced practical LiS cells that can reach their full theoretical capacity. However, it has been a great challenge to probe the sulfur reduction intermediates and products because of the lack of methods. This work employed various ex situ and in situ methods to study the mechanism of the LiS redox reactions and the properties of Li2Sx and Li2S. Synchrotron high-energy X-ray diffraction analysis used to characterize dry powder deposits from lithium polysulfide solution suggests that the new crystallite phase may be lithium polysulfides. The formation of Li2S crystallites with a polyhedral structure was observed in cells with both the conventional (LiTFSI) electrolyte and polysulfide-based electrolyte. In addition, an in situ transmission electron microscopy experiment observed that the lithium diffusion to sulfur during discharge preferentially occurred at the sulfur surface and formed a solid Li2S crust. This may be the reason for the capacity fade in LiS cells (as also suggested by EIS experiment in Supporting Information). The results can be a guide for future studies and control of the sulfur species and meanwhile a baseline for approaching the theoretical capacity of the LiS battery.

  19. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  20. ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Amoroso, J.; Fox, K.

    2011-09-07

    The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

  1. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  2. Media Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Media Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen September 22, 2011 Communication Specialist (801) 819-7623 hrasmussen@wecc.biz WECC releases its first-ever transmission plan for the Western Interconnection The Western Electricity Coordinating Council (WECC) announced the release of its first 10-Year Regional Transmission Plan (Plan) for the Western Interconnection. Looking ahead to 2020, the Plan focuses on how to meet the Western Interconnection's transmission requirements;

  3. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha; Meyer, Howard S.; Lynn, Scott; Leppin, Dennis; Wangerow, James R.

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  4. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  5. News Releases - 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    /newsroom/_assets/images/newsroom-icon.jpg News Releases - 2012 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. January» February» March» April» May» June» July» August» September» October» November» December» Laboratory space scientists use a combination of technologies to monitor Santa's progress as he speeds through the skies. Scientists to surveil Santa's sleigh

  6. News Releases - 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    /newsroom/_assets/images/newsroom-icon.jpg News Releases - 2014 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. January» February» March» April» May» June» July» August» September» October» November» December» A picture of a membrane protein called cysZ determined with Phenix software using data that could not previously be analyzed. Mysteries of 'molecular machines'

  7. FOR IMMEDIATE RELEASE CIV

    Energy Savers [EERE]

    _ FOR IMMEDIATE RELEASE CIV FRIDAY, AUGUST 21, 2015 (202) 514-2007 WWW.JUSTICE.GOV TTY (866) 544-5309 SANDIA CORPORATION AGREES TO PAY $4.7 MILLION TO RESOLVE ALLEGATIONS RELATED TO LOBBYING ACTIVITIES WASHINGTON - The Justice Department announced today that Sandia Corporation has agreed to pay $4,790,042 to resolve allegations that Sandia violated the Byrd Amendment and the False Claims Act by using federal funds for activities related to lobbying Congress and federal agencies to obtain a

  8. News Releases - 2016

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    /newsroom/_assets/images/newsroom-icon.jpg News Releases - 2016 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. March» February» January» Inside the Los Alamos National Laboratory fuel cell test lab, graduate students and a post-doctoral researcher work on ElectroCat technology-at rear, Joseph Dumont, Ulises Martinez, Ling Lin. Argonne and Los Alamos national laboratories

  9. Event Release-2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2:44 p.m. - Emergency response teams are responding to an operational emergency at the U.S. Department of Energy's (DOE) Waste Isolation Pilot Plant (WIPP). NEW INFORMATION * Personnel who were transported to a local hospital for possible smoke inhalation have been released * Officials at WIPP are working on a plan for safe re-entry to the WIPP underground * The plan must be approved by the U.S. Mine Safety and Health Administration * No time frame has been determined for the plan to be approved

  10. 1996 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Companies Selected for Small Wind Turbine Project - (11/27/96) DOE Forms National Center for Photovoltaics - (11/19/96) The Brightest in Solar Homes to Shine in Public Tour - (10/4/96) New NREL Research Facility Slashes Energy Use by 66 Percent - (10/3/96) Agreement Moves Nevada Solar Plant Step Closer to Reality - (10/3/96) Would-Be Solar Electric Homeowners Sought For

  11. 2001 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Customer Choice Would Advance Renewable Energy - (10/31/01) NREL Appointments Announced - (10/19/01) NREL Research Teams Win Three R&D 100 Awards - (10/04/01) Solar Home Tour and Exhibitor Showcase Open Doors to Renewable Energy Information - (10/04/01) Pricing Programs Spur Growth of Renewable Energy Technologies - (09/24/01) Awards to Boost Research into Cheaper Solar

  12. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    SciTech Connect (OSTI)

    Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

    2004-01-25

    A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

  13. Annual Energy Review 2011 - Released September 2012

    Gasoline and Diesel Fuel Update (EIA)

    other manufactured and waste gases derived from fossil fuels. 2 Batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, miscellaneous technologies, and non-renewable waste...

  14. Annual Energy Review 2008 - Released June 2009

    Gasoline and Diesel Fuel Update (EIA)

    other manufactured and waste gases derived from fossil fuels. 2 Batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, miscellaneous technologies, and non-renewable waste...

  15. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  16. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  17. Method for removing sulfur oxides from a hot gas

    SciTech Connect (OSTI)

    Morris, W.P.; Hurst, T.B.

    1984-06-05

    An improved method for removing sulfur oxides from a hot gas by introducing the gas into a first compartment of a spray drying reactor chamber for settleable particulate removal, by then directing the gas to a second compartment of the reactor chamber wherein the gas is contacted with an atomized alkali slurry for sulfur oxide removal by formation of a dry mixture of sulfite and sulfate compounds, by removing a portion of the dry mixture from the gas in the second compartment and by passing the gas from the second compartment to a dry particle collection zone for removal of substantially all of the remaining gas entrained dry mixture.

  18. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage - FY13 Q1 | Department of Energy Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 This document summarizes the progress of this General Atomics project, funded by SunShot, for the first quarter of fiscal year 2013. PDF icon progress_report_baseload_generalatomics_fy13_q1.pdf More Documents & Publications Baseload CSP Generation Integrated with

  19. Low Quality Natural Gas Sulfur Removal and Recovery CNG Claus Sulfur Recovery Process

    SciTech Connect (OSTI)

    Klint, V.W.; Dale, P.R.; Stephenson, C.

    1997-10-01

    Increased use of natural gas (methane) in the domestic energy market will force the development of large non-producing gas reserves now considered to be low quality. Large reserves of low quality natural gas (LQNG) contaminated with hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and nitrogen (N) are available but not suitable for treatment using current conventional gas treating methods due to economic and environmental constraints. A group of three technologies have been integrated to allow for processing of these LQNG reserves; the Controlled Freeze Zone (CFZ) process for hydrocarbon / acid gas separation; the Triple Point Crystallizer (TPC) process for H{sub 2}S / C0{sub 2} separation and the CNG Claus process for recovery of elemental sulfur from H{sub 2}S. The combined CFZ/TPC/CNG Claus group of processes is one program aimed at developing an alternative gas treating technology which is both economically and environmentally suitable for developing these low quality natural gas reserves. The CFZ/TPC/CNG Claus process is capable of treating low quality natural gas containing >10% C0{sub 2} and measurable levels of H{sub 2}S and N{sub 2} to pipeline specifications. The integrated CFZ / CNG Claus Process or the stand-alone CNG Claus Process has a number of attractive features for treating LQNG. The processes are capable of treating raw gas with a variety of trace contaminant components. The processes can also accommodate large changes in raw gas composition and flow rates. The combined processes are capable of achieving virtually undetectable levels of H{sub 2}S and significantly less than 2% CO in the product methane. The separation processes operate at pressure and deliver a high pressure (ca. 100 psia) acid gas (H{sub 2}S) stream for processing in the CNG Claus unit. This allows for substantial reductions in plant vessel size as compared to conventional Claus / Tail gas treating technologies. A close integration of the components of the CNG Claus process also allow for use of the methane/H{sub 2}S separation unit as a Claus tail gas treating unit by recycling the CNG Claus tail gas stream. This allows for virtually 100 percent sulfur recovery efficiency (virtually zero SO{sub 2} emissions) by recycling the sulfur laden tail gas to extinction. The use of the tail gas recycle scheme also deemphasizes the conventional requirement in Claus units to have high unit conversion efficiency and thereby make the operation much less affected by process upsets and feed gas composition changes. The development of these technologies has been ongoing for many years and both the CFZ and the TPC processes have been demonstrated at large pilot plant scales. On the other hand, prior to this project, the CNG Claus process had not been proven at any scale. Therefore, the primary objective of this portion of the program was to design, build and operate a pilot scale CNG Claus unit and demonstrate the required fundamental reaction chemistry and also demonstrate the viability of a reasonably sized working unit.

  20. Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in...

  1. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G.

    2012-03-06

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  2. Quick release engine cylinder

    DOE Patents [OSTI]

    Sunnarborg, Duane A.

    2000-01-01

    A quick release engine cylinder allows optical access to an essentially unaltered combustion chamber, is suitable for use with actual combustion processes, and is amenable to rapid and repeated disassembly and cleaning. A cylinder member, adapted to constrain a piston to a defined path through the cylinder member, sealingly engages a cylinder head to provide a production-like combustion chamber. A support member mounts with the cylinder member. The support-to-cylinder mounting allows two relationships therebetween. In the first mounting relationship, the support engages the cylinder member and restrains the cylinder against the head. In the second mounting relationship, the cylinder member can pass through the support member, moving away from the head and providing access to the piston-top and head.

  3. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application PDF icon deer09_cheng.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite

  4. Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 4: June 9, 2014 EPA Sulfur Standards for Gasoline Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of sulfur in gasoline (Tier 2 standards). Separate standards were set for different entities, such as large refiners, small refiners, importers, downstream wholesalers, etc. In March 2014, Tier 3 standards were finalized by

  5. Development of High Energy Density Lithium-Sulfur Cells | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Density Lithium-Sulfur Cells Development of High Energy Density Lithium-Sulfur Cells 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es125_wang_2012_p.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2015: High Energy Lithium-Sulfur Cathodes Vehicle Technologies Office Merit Review 2014: Development of High Energy Density Lithium-Sulfur Cells

  6. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  7. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  8. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J. (Naperville, IL)

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  9. Catalyst added to Claus furnace reduces sulfur losses

    SciTech Connect (OSTI)

    Luinstra, E.A.; d'Haene, P.E. (Shell Canada Ltd., Toronto, ON (Canada). Oakville Research Centre)

    1989-07-01

    Several substances effectively catalyze the reduction of carbon disulfide in Claus gas streams at Claus reaction furnace conditions (about 1,000{sup 0}C). Some conversion of carbonyl sulfide also occurs. Carbon disulfide and carbonyl sulfide as well-known problem compounds that reduce sulfur recovery efficiency in many sulfur recovery plants. Installation of a suitable catalytic material in the reaction furnace promises significant improvement of Claus plant efficiency, and prolonged life of the catalytic converters. Almost every Claus sulfur recovery plant makes some carbon disulfide (CS/sub 2/) and carbonyl sulfide (COS) in the reaction furnace, and in many of these plants, these compounds constitute a significant problem. CS/sub 2/ and COS often comprise more than 50% of sulfur losses in the tail gas. This article reexamines the issue of CS/sub 2/ and COS in the Claus plant. The relative importance of these two troublesome components is explored with data accumulated from Shell Canada Claus plants. The authors discuss which factors tend to produce these components. Then a method for reducing CS/sub 2/ and COS virtually at the source will be introduced.

  10. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  11. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    DOE Patents [OSTI]

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  12. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  13. Preliminary Release: August 19, 2011",,,,,,,,,,,,,"Released: April 2013","Releas

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,,,,,,,,,,,"Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April

  14. COMMERCIAL SNF ACCIDENT RELEASE FRACTIONS

    SciTech Connect (OSTI)

    S.O. Bader

    1999-10-18

    The purpose of this design analysis is to specify and document the total and respirable fractions for radioactive materials that are released from an accident event at the Monitored Geologic Repository (MGR) involving commercial spent nuclear fuel (CSNF) in a dry environment. The total and respirable release fractions will be used to support the preclosure licensing basis for the MGR. The total release fraction is defined as the fraction of total CSNF assembly inventory, typically expressed as an activity inventory (e.g., curies), of a given radionuclide that is released to the environment from a waste form. The radionuclides are released from the inside of breached fuel rods (or pins) and from the detachment of radioactive material (crud) from the outside surfaces of fuel rods and other components of fuel assemblies. The total release fraction accounts for several mechanisms that tend to retain, retard, or diminish the amount of radionuclides that are available for transport to dose receptors or otherwise can be shown to reduce exposure of receptors to radiological releases. The total release fraction includes a fraction of airborne material that is respirable and could result in inhalation doses. This subset of the total release fraction is referred to as the respirable release fraction. Potential accidents may involve waste forms that are characterized as either bare (unconfined) fuel assemblies or confined fuel assemblies. The confined CSNF assemblies at the MGR are contained in shipping casks, canisters, or disposal containers (waste packages). In contrast to the bare fuel assemblies, the container that confines the fuel assemblies has the potential of providing an additional barrier for diminishing the total release fraction should the fuel rod cladding breach during an accident. However, this analysis will not take credit for this additional bamer and will establish only the total release fractions for bare unconfined CSNF assemblies, which may however be conservatively applied to confined CSNF assemblies.

  15. SEPA Press Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    News Press Releases Career Opportunities SEPA History SEPA Video

  16. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  17. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  18. Method of making sulfur-resistant composite metal membranes

    DOE Patents [OSTI]

    Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

    2012-01-24

    The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

  19. The South Karelia Air Pollution Study. The effects of malodorous sulfur compounds from pulp mills on respiratory and other symptoms

    SciTech Connect (OSTI)

    Jaakkola, J.J.; Vilkka, V.; Marttila, O.; Jaeppinen, P.H.; Haahtela, T. )

    1990-12-01

    The paper mills in South Karelia, the southeast part of Finland, are responsible for releasing a substantial amount of malodorous sulfur compounds such as hydrogen sulfide (H2S), methyl mercaptan (CH3SH), and methyl sulfides ((CH3)2S and (CH3)2S2), into ambient air. In the most polluted residential area the annual mean concentrations of hydrogen sulfide and methyl mercaptan are estimated to be 8 and 2 to 5 micrograms/m3 and the highest daily average concentration 100 and 50 micrograms/m3. The annual mean and highest daily concentrations of sulfur dioxide (SO2) are very low. We studied the effects of malodorous sulfur compounds on eye, nasal and respiratory symptoms, and headache in adults. A cross-sectional self-administered questionnaire was distributed in February 1987 and responded to by 488 adults living in a severely (n = 198), a moderately (n = 204), and a nonpolluted community (n = 86). This included questions about occurrence of the symptoms of interest during the previous 4 wk and 12 months and individual, behavioral, and other environmental determinants of the symptoms. The response rate was 83%. The odds ratios (OR) for symptoms experienced often or constantly in severely versus nonpolluted and moderately versus nonpolluted communities were estimated in logistic regression analysis controlling potential confounders. The odds ratios for eye (moderate exposure OR 11.70, Cl95% 2.33 to 58.65; severe exposure OR 11.78, Cl95% 2.35 to 59.09) and nasal symptoms (OR 2.01, Cl95% 0.97 to 4.15; OR 2.19, Cl95% 1.06 to 4.55) and cough (OR 1.89, Cl95% 0.61 to 5.86; OR 3.06, Cl95% 1.02 to 9.29) during the previous 12 months were increased, with a dose-response pattern.

  20. NREL Releases Updated Typical Meteorological Year Data Set - News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | NREL NREL Releases Updated Typical Meteorological Year Data Set May 1, 2008 The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) today released an updated typical meteorological year (TMY) data set derived from the 1991-2005 National Solar Radiation Data Base update. The TMY3 data and user's manual are available at http://rredc.nrel.gov/solar/old_data/nsrdb/1991-2005/tmy3. The new data sets update and expand the TMY2 data sets released by NREL in 1994. The TMY3 data

  1. Low-sulfur coal usage alters transportation strategies

    SciTech Connect (OSTI)

    Stein, H.

    1995-07-01

    As electricity production has grown, so has the amount of coal burned by US utilities. In order to comply with the 1990 Clean Air Act Amendments (CAAA), many utilities have changed from high-sulfur coal to lower-sulfur coal to reduce sulfur dioxide emissions. The primary mode of transporting coal to utilities remains the railroad, and coal represents the largest freight tonnage shipped - two out of every five tons. Since coal is so important to the railroads, it is logical that as utilities have changed their coal-buying strategies, the railroads` strategies have also changed. The increased demand for Western coal has caused rail lines some capacity problems which they are attempting to meet head-on by buying new railcars and locomotives and expanding track capacities. The new railcars typically have aluminum bodies to reduce empty weight, enabling them to carry larger loads of coal. Train locomotives are also undergoing upgrade changes. Most new locomotives have as motors to drive the wheels which deliver more motive power (traction) to the wheel trucks. In fact the motors are up to 30% more efficient at getting the traction to the trucks. Trackage is also being expanded to alleviate serious congestion on the tracks when moving Western coal.

  2. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    SciTech Connect (OSTI)

    Lin, Zhan; Liang, Chengdu

    2015-01-01

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and the electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.

  3. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P.; Lynn, Scott

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  4. Removal of nitrogen and sulfur from oil-shale

    SciTech Connect (OSTI)

    Olmstead, W.N.

    1986-01-28

    This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

  5. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Zhan; Liang, Chengdu

    2015-01-01

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and themore » electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.« less

  6. Utilizing the market to control sulfur dioxide emissions

    SciTech Connect (OSTI)

    Loeher, C.F. III

    1995-12-01

    Environmental policy in the United States is evolving; command and control approaches are being slowly replaced with market-based incentives. Market-based regulation is favorable because it provides the regulated community with flexibility in choosing between pollution control options. A recent application of a market-based approach is Title IV of the 1990 Clean Air Act Amendments. This paper evaluates the advantages of utilizing market-based incentives to control sulfur dioxide emissions. The evaluation embodies an extensive methodology, which provides an overview of the policy governing air quality, discusses pollution control philosophies and analyzes their associated advantages and limitations. Further, it describes the development and operation of a market for emissions trading, impediments to the market, and recommends strategies to improve the market. The evaluation concludes by analyzing the results of five empirical simulations demonstrating the cost-effectiveness of employing market-based incentives versus command-and-control regulation for controlling sulfur dioxide emissions. The results of the evaluation indicate that regulatory barriers and market impediments have inhibited allowance trading. However, many of these obstacles have been or are being eliminated through Federal and state regulations, and through enhancement of the market. Results also demonstrate that sulfur dioxide allowance trading can obtain identical levels of environmental protection as command-and-control approaches while realizing cost savings to government and industry.

  7. Glass surface deactivants for sulfur-containing gases

    SciTech Connect (OSTI)

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  8. Natural sulfur flux from the Gulf of Mexico: dimethyl sulfide, carbonyl sulfide, and sulfur dioxide. Technical report

    SciTech Connect (OSTI)

    Van Valin, C.C.; Luria, M.; Wellman, D.L.; Gunter, R.L.; Pueschel, R.F.

    1987-06-01

    Atmospheric measurements of natural sulfur compounds were performed over the northern Gulf of Mexico during the late summer months of 1984. Air samples were collected with an instrumented aircraft at elevations of 30-3500 m, during both day and night. Most air samples were representative of the clean maritime atmosphere, although some were from continental contaminated air during periods of offshore flow at the coastline. In all samples, carbonyl sulfide concentrations were within the range of 400-500 pptv. Conversely, the dimethyl sulfide concentrations showed significant variability: during clean atmospheric conditions the average of all measurements was 27 pptv, whereas under polluted conditions the average was 7 pptv. Measureable quantities of dimethyl sulfide (>5 pptv) were not observed above the boundary layer. The average sulfur dioxide concentration measured in the marine (clean) atmosphere was 215 pptv, which is consistent with the oxidation of dimethyl sulfide being its major source.

  9. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore » the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  10. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  11. High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances

    SciTech Connect (OSTI)

    K. Coulter

    2010-12-31

    The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

  12. Reduction of erythema in hairless guinea pigs after cutaneous sulfur mustard vapor exposure by pretreatment with niacinamide, promethazine and indomethacin

    SciTech Connect (OSTI)

    Yourick, J.J.; Dawson, J.S.; Mitcheltree, L.W.

    1995-12-31

    Erythema is the initial symptom that occurs after sulfur mustard (HD) cutaneous exposure. The time course of HD-induced erythema is similar to that observed after UV irradiation, which can be reduced by indomethacin. Sulfur mustard lethality is decreased by using promethazine, which is an antihistamine. Niacinamide can reduce microvesication after HD vapor exposure in hairless guinea pig (HGP) skin. The present study examines the effect of the combined administration of niacinamide, indomethacin and promethazine used alone or in all possible combinations on the degree of erythema and histopathologic skin damage after HD exposure in HGP. Niacinamide (750 mg kg%`, i.p.), promethazine (12.5 mg kg%1, i.m.) or indomethacin (4 mg kg%1, p.o.) used singly or in combination was given as a 30-min pretreatment before an 8-min HD vapor cup skin exposure. Using a combination pretreatment of niacinamide, promethazine and indomethacin, erythema was reduced at 4 (91%) and 6 (55%) h, but not 24 h after HD. The incidence of histopathological skin changes (microvesicles, follicular involvement, epidermal necrosis, intracellular edema and pustular epidermatitis) 24 h after HD was not reduced. This study indicates that HD (induced erythema) may result from several different mechanisms, including inflammation, histamine release and DNA damage. It is suggested that two phases of inflammation may occur: an early phase sensitive to antihistamines and non-steroidal antiinflammatory drugs and a late phase of extensive cell damage that was not sensitive to these drug pretreatments.

  13. NREL Releases New Version of Energy Evaluation Software - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL NREL Releases New Version of Energy Evaluation Software January 4, 2005 Golden, Colo. - Researchers at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) recently released Version 2.1 of HOMER, a micropower optimization software model that simplifies the task of evaluating design options for both off-grid and grid-connected power systems. Users supply information about electrical loads, renewable resources and component costs and HOMER simulates multiple designs

  14. ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Gorensek, M.; Edwards, T.

    2009-06-11

    A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

  15. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  16. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  17. Controlled release liquid dosage formulation

    DOE Patents [OSTI]

    Benton, Ben F. (Centerburg, OH); Gardner, David L. (Bellville, OH)

    1989-01-01

    A liquid dual coated dosage formulation sustained release pharmaceutic having substantial shelf life prior to ingestion is disclosed. A dual coating is applied over controlled release cores to form dosage forms and the coatings comprise fats melting at less than approximately 101.degree. F. overcoated with cellulose acetate phthalate or zein. The dual coated dosage forms are dispersed in a sugar based acidic liquid carrier such as high fructose corn syrup and display a shelf life of up to approximately at least 45 days while still retaining their release profiles following ingestion. Cellulose acetate phthalate coated dosage form cores can in addition be dispersed in aqueous liquids of pH <5.

  18. DOCUMENT RELEASE FORM G5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DOCUMENT RELEASE FORM G5 (1) Document Number: RPP-RPT-431 69 (2) Revision Number: 0 (3) Effective Date: 9/30/2009 (4) Document Type: E] Digital Image l Hard copy (a) Number of pages (including the IDRF) or 125 E PDF ElVideo number of digital images (5) Release Type Z New 0 Cancel El Page Change l complete Revision (6) Document Title: 2009 Auto-TCR for Tank 241 -T-1 11 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure

  19. Commercial SNF Accident Release Fractions

    SciTech Connect (OSTI)

    J. Schulz

    2004-11-05

    The purpose of this analysis is to specify and document the total and respirable fractions for radioactive materials that could be potentially released from an accident at the repository involving commercial spent nuclear fuel (SNF) in a dry environment. The total and respirable release fractions are used to support the preclosure licensing basis for the repository. The total release fraction is defined as the fraction of total commercial SNF assembly inventory, typically expressed as an activity inventory (e.g., curies), of a given radionuclide that is released to the environment from a waste form. Radionuclides are released from the inside of breached fuel rods (or pins) and from the detachment of radioactive material (crud) from the outside surfaces of fuel rods and other components of fuel assemblies. The total release fraction accounts for several mechanisms that tend to retain, retard, or diminish the amount of radionuclides that are available for transport to dose receptors or otherwise can be shown to reduce exposure of receptors to radiological releases. The total release fraction includes a fraction of airborne material that is respirable and could result in inhalation doses; this subset of the total release fraction is referred to as the respirable release fraction. Accidents may involve waste forms characterized as: (1) bare unconfined intact fuel assemblies, (2) confined intact fuel assemblies, or (3) canistered failed commercial SNF. Confined intact commercial SNF assemblies at the repository are contained in shipping casks, canisters, or waste packages. Four categories of failed commercial SNF are identified: (1) mechanically and cladding-penetration damaged commercial SNF, (2) consolidated/reconstituted assemblies, (3) fuel rods, pieces, and debris, and (4) nonfuel components. It is assumed that failed commercial SNF is placed into waste packages with a mesh screen at each end (CRWMS M&O 1999). In contrast to bare unconfined fuel assemblies, the container that confines the fuel assemblies could provide an additional barrier for diminishing the total release fraction should the fuel rod cladding breach during an accident. This analysis, however, does not take credit for the additional barrier and establishes only the total release fractions for bare unconfined intact commercial SNF assemblies, which may be conservatively applied to confined intact commercial I SNF assemblies.

  20. Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Lin, Zhan [ORNL] [ORNL; Liu, Zengcai [ORNL] [ORNL; Fu, Wujun [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2013-01-01

    Given the great potential for improving the energy density of state-of-the-art lithium-ion batteries by a factor of 5, a breakthrough in lithium-sulfur (Li-S) batteries will have a dramatic impact in a broad scope of energy related fields. Conventional Li-S batteries that use liquid electrolytes are intrinsically short-lived with low energy efficiency. The challenges stem from the poor electronic and ionic conductivities of elemental sulfur and its discharge products. We report herein lithium polysulfidophosphates (LPSP), a family of sulfur-rich compounds, as the enabler of long-lasting and energy-efficient Li-S batteries. LPSP have ionic conductivities of 3.0 10-5 S cm-1 at 25 oC, which is 8 orders of magnitude higher than that of Li2S (~10-13 S cm-1). The high Li-ion conductivity of LPSP is the salient characteristic of these compounds that impart the excellent cycling performance to Li-S batteries. In addition, the batteries are configured in an all-solid state that promises the safe cycling of high-energy batteries with metallic lithium anodes.

  1. Releases from the Heating Oil Reserve

    Broader source: Energy.gov [DOE]

    The Northeast Home Heating Oil Reserve (NEHHOR), a one million barrel supply of ultra low sulfur distillate (diesel), was created to build a buffer to allow commercial companies to compensate for...

  2. News Releases | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases Need rare-earths know-how? The Critical Materials Institute offers lower-cost access to experts and research, December 1, 2015 Get schooled in rare-earth metals: CMI, Iowa...

  3. Fermilab | Newsroom | Press Releases | [TITLE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Press Release PDF Click to read answers to FAQ about the Higgs boson. Med Res | Hi Res | EPS After more than 10 years of gathering and analyzing data produced by the U.S....

  4. Press Releases | Department of Energy

    Energy Savers [EERE]

    Press Releases Press Releases RSS March 18, 2016 DOE High Performance Computing for Manufacturing (HPC4Mfg) Program Seeks To Fund New Proposals To Jumpstart Energy Technologies A new U.S. Department of Energy (DOE) program designed to spur the use of high performance supercomputers to advance U.S. manufacturing is now seeking a second round of proposals from industry to compete for approximately $3 million in new funding. March 14, 2016 Brookhaven Lab Named an NVIDIA GPU Research Center:

  5. Media Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Media Releases Media Releases December 16, 2015 Two Men Charged With Wire Fraud December 15, 2015 Former Russian Nuclear Energy Official Sentenced to Four Years in Prison for Money Laundering Conspiracy October 21, 2015 OIG Receives Prestigious CIGIE Award September 24, 2015 Argonne National Laboratory Employee Arrested for Operating Illegal Steroid Lab September 11, 2015 Scientists Sentenced To Prison For Defrauding The Small Business Innovation Research Program September 10, 2015 Indictment

  6. Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System | Department of Energy Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System effect and performance recovery studies at system level with typical diesel emission control consisting of diesel oxidation catalyst, catalyzed soot filter, and selective catalytic reduction PDF icon deer11_tang.pdf More Documents & Publications Investigation of Sulfur Deactivation on Cu/Zeolite SCR

  7. DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur

    Office of Environmental Management (EM)

    Distillate | Department of Energy Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate February 1, 2011 - 12:00pm Addthis Washington, DC - The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy (DOE) said

  8. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy

    2011-08-20

    Problem drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. The U.S. Consumer Product Safety Commission's (CPSC) investigation of problem drywall incorporates three parallel tracks: (1) evaluating the relationship between the drywall and reported health symptoms; (2) evaluating the relationship between the drywall and electrical and fire safety issues in affected homes; and (3) tracing the origin and the distribution of the drywall. To assess the potential impact on human health and to support testing for electrical and fire safety, the CPSC has initiated a series of laboratory tests that provide elemental characterization of drywall, characterization of chemical emissions, and in-home air sampling. The chemical emission testing was conducted at Lawrence Berkeley National Laboratory (LBNL). The LBNL study consisted of two phases. In Phase 1 of this study, LBNL tested thirty drywall samples provided by CPSC and reported standard emission factors for volatile organic compounds (VOCs), aldehydes, reactive sulfur gases (RSGs) and volatile sulfur compounds (VSCs). The standard emission factors were determined using small (10.75 liter) dynamic test chambers housed in a constant temperature environmental chamber. The tests were all run at 25 C, 50% relative humidity (RH) and with an area-specific ventilation rate of {approx}1.5 cubic meters per square meter of emitting surface per hour [m{sup 3}/m{sup 2}/h]. The thirty samples that were tested in Phase 1 included seventeen that were manufactured in China in 2005, 2006 and 2009, and thirteen that were manufactured in North America in 2009. The measured emission factors for VOCs and aldehydes were generally low and did not differ significantly between the Chinese and North American drywall. Eight of the samples tested had elevated emissions of volatile sulfur-containing compounds with total RSG emission factors between 32 and 258 micrograms per square meter per hour [{micro}g/m{sup 2}/h]. The dominant sulfur containing compounds in the RSG emission stream were hydrogen sulfide with emission factors between 17-201 {micro}g/m{sup 2}/h, and sulfur dioxide with emission factors between 8-64 {micro}g/m{sup 2}/h. The four highest emitting samples also had a unique signature of VSC emissions including > 40 higher molecular weight sulfur-containing compounds although the emission rate for the VSCs was several orders of magnitude lower than that of the RSGs. All of the high emitting drywall samples were manufactured in China in 2005-2006. Results from Phase 1 provided baseline emission factors for drywall samples manufactured in China and in North America but the results exclude variations in environmental conditions that may exist in homes or other built structures, including various combinations of temperature, RH, ventilation rate and the influence of coatings such as texture and paints. The objective of Phase 2 was to quantify the effect of temperature and RH on the RSG emission factors for uncoated drywall, and to measure the effect of plaster and paint coatings on RSG emission factors from drywall. Additional experiments were also performed to assess the influence of ventilation rate on measured emission factors for drywall.

  9. Portable instrument and method for detecting reduced sulfur compounds in a gas

    DOE Patents [OSTI]

    Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

    1983-06-01

    A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

  10. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  11. Sulfur in the Timbers of Henry VIII's Warship Mary Rose: Synchrotrons...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sulfur in the Timbers of Henry VIII's Warship Mary Rose: Synchrotrons Illuminate Conservation Concerns Magnus Sandstrm,1 Farideh Jalilehvand,2 Emiliana Damian,1 Yvonne Fors,1...

  12. Sulfur barrier for use with in situ processes for treating formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Christensen, Del Scot (Friendswood, TX)

    2009-12-15

    Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

  13. Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program

    SciTech Connect (OSTI)

    George Sverdrup

    1999-06-07

    DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

  14. A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Life, High-Rate LithiumSulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Min-Kyu Song, , Yuegang Zhang,* ,, and Elton J. Cairns* ,, The...

  15. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Content, Sales Type, and PAD District 242 Energy Information Administration Petroleum Marketing Annual 1997 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  16. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Content, Sales Type, and PAD District 242 Energy Information Administration Petroleum Marketing Annual 1996 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  17. Press Releases | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Release Sep 22, 2015 NNSA Removes U.S.-Origin HEU from Jamaica, Makes the Caribbean HEU Free Press Release Sep 17, 2015 Gamma Shield Thunder Exercise Concludes Press Release Sep...

  18. A solvent system to provide selective removal of sulfur compounds

    SciTech Connect (OSTI)

    Pearce, R.L.; Bacon, T.R.

    1986-01-01

    Energy costs and SRU inefficiencies resulting from utilization of low strength MEA technology induced a large refinery to convert to MDEA. One of the seven product streams being treated required extremely low carbonyl sulfide in the treated product. This required careful consideration in making the decision to convert. However, the conclusions were that the advantages outweighed the disadvantages. When the initial converted operations verified a need to improve the carbonyl sulfide removal, GAS/SPEC Tech Service produced an innovative solution which allowed for efficient operation at acceptable COS specification, lower energy utilization, reduced solvent losses, and improved sulfur recovery unit operation.

  19. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  20. Webinar: Algal Biofuels Consortium Releases Groundbreaking Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Algal Biofuels Consortium Releases Groundbreaking Research Results Webinar: Algal Biofuels Consortium Releases Groundbreaking Research Results Dr. Jose Olivares of Los Alamos ...

  1. AIRMaster+ Release Notes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1.2.7) Release Notes PDF icon Release Notes (Version 1.2.7) More Documents & Publications AIRMaster+ Software Tool Brochure AIRMaster+ User Manual AIRMaster+ Tool Introduction...

  2. DOE Issues WIPP Radiological Release Investigation Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release Investigation Report Today, the Department of Energy's (DOE) Office of Environmental Management (EM) released the initial accident investigation report related to the...

  3. Bioenergy Technologies Office Releases Symbiosis Biofeedstock...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Releases Symbiosis Biofeedstock Conference Summary Report Bioenergy Technologies Office Releases Symbiosis Biofeedstock Conference Summary Report January 2, 2014 - 12:00am Addthis...

  4. Catalysts for the selective oxidation of hydrogen sulfide to sulfur

    DOE Patents [OSTI]

    Srinivas, Girish; Bai, Chuansheng

    2000-08-08

    This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

  5. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  6. ARM - Features and Releases Archive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CenterFeaturesFeatures and Releases Archive Media Contact Hanna Goss hanna-dot-goss-at-pnnl-dot-gov @armnewsteam Field Notes Blog Topics Field Notes107 AGU 3 AMIE 10 ARM Aerial Facility 2 ARM Mobile Facility 1 6 ARM Mobile Facility 2 47 ARM Mobile Facility 3 1 BAECC 1 BBOP 4 ENA 1 GOAMAZON 7 MAGIC 15 MC3E 17 PECAN 3 SGP 7 STORMVEX 29 TCAP 3 Search News Search Blog News Center All Categories What's this? Social Media Guidance News Center All Categories Features and Releases Facility News Field

  7. Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry

    SciTech Connect (OSTI)

    Baxter, Larry L.

    2008-06-09

    This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt mixtures and compared with sodium-based binary and higher order systems. Predictions and measurements were demonstrated for both salt systems and for some more complex silicate-bearing systems, substantially exceeding the original scope of this work. 4. A multi-dimensional model of char bed reactivity developed under this project demonstrated that essentially all reactions in char beds occur on or near the surface, with the internal portions of the bed being essentially inert. The model predicted composition, temperature, and velocity profiles in the bed and showed that air jet penetration is limited to the immediate vicinity of the char bed, with minimal impact on most of the bed. The modeling efforts substantially exceeded the original scope of this project. 5. Near the completion of this project, DOE withdrew the BYU portion of a multiparty agreement to complete this and additional work with no advanced warning, which compromised the integration of all of this material into a commercial computer code. However, substantial computer simulations of much of this work were initiated, but not completed. 6. The gasification modeling is nearly completed but was aborted near its completion according to a DOE redirection of funds. This affected both this and the previous tasks.

  8. Use of selective oxidation of petroleum residue for production of low-sulfur coke

    SciTech Connect (OSTI)

    Hairudinov, I.R.; Kul`chitskaya, O.V.; Imashev, U.B.

    1995-12-10

    The chemical nature of liquid-phase oxidation of sulfurous petroleum residues by cumene hydroperoxide was studied by a tracer technique. Sulfur compounds are selectively oxidized in the presence of catalytic additives of molybdenum salts. Desulfurization of distillate products and coke during coking of preoxidized raw materials was revealed.

  9. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Dioxide on Lean NOx Trap Catalysts Impact of Sulfur Dioxide on Lean NOx Trap Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of New Mexico PDF icon 2004_deer_hammache.pdf More Documents & Publications CLEERS Aftertreatment Modeling and Analysis CLEERS Aftertreatment Modeling and Analysis An Improvement of Diesel PM and NOx Reduction System

  10. Assessing historical global sulfur emission patterns for the period 1850--1990

    SciTech Connect (OSTI)

    Lefohn, A.S.; Husar, J.D.; Husar, R.B.; Brimblecombe, P.

    1996-07-19

    Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

  11. Adsorbed sulfur-gas methods for both near-surface exploration and downhole logging

    SciTech Connect (OSTI)

    Farwell, S.O.; Barinaga, C.J.; Dolenc, M.R.; Farwell, G.H.

    1986-08-01

    The use of sulfur-containing gases in petroleum exploration is supported by (1) the idea that sulfur may play a role in petroleum genesis, (2) the corresponding existence of sulfur-containing compounds in petroleum and the potential for vertical migration of the low-molecular-weight sulfur species from these reservoirs, (3) the production of H/sub 2/S by anaerobic microorganism populations that develop in the subsurface areas overlying petroleum reservoirs due to the concomitant supply of hydrocarbon nutrients, (4) the recent discovery of near-surface accumulations of pyrite and marcasite as the source of induction potential anomalies over certain fields, and (5) the strong adsorptive affinities of sulfur gases to solid surfaces, which enhance both the concentration and localization of such sulfur-expressed anomalies. During the past 3 years, numerous near-surface soil samples and well cuttings from the Utah-Wyoming Overthrust belt have been analyzed for adsorbed sulfur-gas content by two novel analytical techniques: thermal desorption/metal foil collection/flash desorption/sulfur-selective detection (TD/MFC/FD/SSD) and thermal desorption/cryogenic preconcentration/high-resolution-gas chromatography/optimized-flame photometry (TD/CP/HRGC/OFP).

  12. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  13. NREL Releases Analysis of Renewable Electricity Standards - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Releases Analysis of Renewable Electricity Standards May 18, 2009 The U.S. Department of Energy's National Renewable Energy Laboratory has completed a study comparing three proposed national renewable electricity standards, also known as renewable portfolio standards. To assess the potential impacts of the three proposed standards on the U.S. electricity sector, a team of senior NREL energy analysts used the Laboratory's Regional Energy Deployment System, a detailed least-cost

  14. NREL Releases Report Card on Environmental Efforts - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Releases Report Card on Environmental Efforts October 23, 2015 The Energy Department's National Renewable Energy Laboratory (NREL) continued to improve its environmental protection efforts at its South Table Mountain and National Wind Technology Center sites during 2014 by reducing greenhouse gas emissions, adding bird-safety features to campus structures, and assessing environmental impacts of potential laboratory development. NREL annually reports on the environmental performance and

  15. Press Releases | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Archive Publications Princeton Journal Watch Blog PPPL Experts Research at Princeton Events Research Education Organization Contact Us News Room News Archive American Fusion News Press Releases Press Releases Archive Publications Princeton Journal Watch Blog PPPL Experts Research at Princeton Press Releases Subscribe to Press Releases Archive March 9, 2016 DOE's Ed Synakowski traces key discoveries in the quest for fusion energy By Jeanne Jackson DeVoe The DOE's Associate

  16. Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities

    U.S. Energy Information Administration (EIA) Indexed Site

    (Percent) Type: Sulfur Content API Gravity Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Type Area Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History U.S. 1.39 1.36 1.36 1.37 1.44 1.44 1985-2015 PADD 1 0.85 0.97 0.62 0.83 0.75 0.75 1985-2015 East Coast 0.78 0.91 0.51 0.76 0.68 0.67 1985-2015 Appalachian No. 1 1.57 1.62 1.71 1.59 1.61 1.65 1985-2015 PADD 2 1.44 1.46 1.40 1.33 1.54 1.55

  17. Method of forming and starting a sodium sulfur battery

    DOE Patents [OSTI]

    Paquette, David G. (Costa Mesa, CA)

    1981-01-01

    A method of forming a sodium sulfur battery and of starting the reactive capability of that battery when heated to a temperature suitable for battery operation is disclosed. An anodic reaction zone is constructed in a manner that sodium is hermetically sealed therein, part of the hermetic seal including fusible material which closes up openings through the container of the anodic reaction zone. The hermetically sealed anodic reaction zone is assembled under normal atmospheric conditions with a suitable cathodic reaction zone and a cation-permeable barrier. When the entire battery is heated to an operational temperature, the fusible material of the hermetically sealed anodic reaction zone is fused, thereby allowing molten sodium to flow from the anodic reaction zone into reactive engagement with the cation-permeable barrier.

  18. Process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal sulfide sorbents

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY); Gal, Eli (Lititz, PA)

    1995-01-01

    A process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal-sulfur compound. Spent metal-sulfur compound is regenerated to re-usable metal oxide by moving a bed of spent metal-sulfur compound progressively through a single regeneration vessel having a first and second regeneration stage and a third cooling and purging stage. The regeneration is carried out and elemental sulfur is generated in the first stage by introducing a first gas of sulfur dioxide which contains oxygen at a concentration less than the stoichiometric amount required for complete oxidation of the spent metal-sulfur compound. A second gas containing sulfur dioxide and excess oxygen at a concentration sufficient for complete oxidation of the partially spent metal-sulfur compound, is introduced into the second regeneration stage. Gaseous sulfur formed in the first regeneration stage is removed prior to introducing the second gas into the second regeneration stage. An oxygen-containing gas is introduced into the third cooling and purging stage. Except for the gaseous sulfur removed from the first stage, the combined gases derived from the regeneration stages which are generally rich in sulfur dioxide and lean in oxygen, are removed from the regenerator as an off-gas and recycled as the first and second gas into the regenerator. Oxygen concentration is controlled by adding air, oxygen-enriched air or pure oxygen to the recycled off-gas.

  19. Ultra-low Sulfur Reduction Emission Control Device/Development of an On-board Fuel Sulfur Trap

    SciTech Connect (OSTI)

    Rohrbach, Ron; Barron, Ann

    2008-07-31

    Honeywell has completed working on a multiyear program to develop and demonstrate proof-of-concept for an 'on-vehicle' desulfurization fuel filter for both light duty and heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NOx adsorbers. The NOx adsorber may be required to meet the proposed new EPA Tier II and '2007-Rule' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters was also examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. In the second phase of the program a light duty diesel engine test was also demonstrated. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consisted of four phases. Phase I focused on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II concentrated on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III studied life cycle and regeneration options for the spent filter. Phase IV focused on efficacy and benefits in the desulfation steps of a NOx adsorber on both a heavy and light duty engine. The project team included a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Navistar Inc. (formerly International Truck & Engine Corporation) and Mack Trucks Inc.), and filter recycler (American Wastes Industries).

  20. Neutron-absorber release device

    DOE Patents [OSTI]

    VAN Erp, Jan B.; Kimont, Edward L.

    1976-01-01

    A resettable device is provided for supporting an object, sensing when an environment reaches a critical temperature and releasing the object when the critical temperature is reached. It includes a flexible container having a material inside with a melting point at the critical temperature. The object's weight is supported by the solid material which gives rigidity to the container until the critical temperature is reached at which point the material in the container melts. The flexible container with the now fluid material inside has insufficient strength to support the object which is thereby released. Biasing means forces the container back to its original shape so that when the temperature falls below the melting temperature the material again solidifies, and the object may again be supported by the device.

  1. 2012 Microgrid Workshop Summary Released

    Broader source: Energy.gov [DOE]

    The Department of Energy has released the summary report from the July 30-31, 2012 Microgrid Workshop presented by the Office of Electricity Delivery and Energy Reliability at the Illinois Institute of Technology in Chicago. The workshop was held in response to discussions at the preceding DOE Microgrid Workshop, held in August 2011, which called for sharing lessons learned and best practices for system integration from existing projects in the U.S. (including military microgrids) and internationally.

  2. Materials Man (Release) | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    https://www.jlab.org/news/articles/materials-man-release Materials Man ARC's new associate director sees a wealth of opportunity for bringing applied research to the martketplace Pass a laser light over a juice box and it can suddenly become impervious to microbes. Use the tool on a fabric and its colors become more intense. For Michael Kelley, lasers will be instrumental in developing the next generation of advanced materials used in everyday life, while facilities like the Applied Research

  3. FRESAR ReleaseFINAL.PDF

    National Nuclear Security Administration (NNSA)

    NEWS MEDIA CONTACT: FOR IMMEDIATE RELEASE Anson Franklin, 202/586-7332 September 20, 2001 Joint Venture Established Between Russian Weapons Plant And the Largest Dialysis Provider in the U.S. National Nuclear Security Administration Helping to Transform Former Weapons Manufacturing Complex to Civilian Work The first joint civilian company involving a former Russian weapons manufacturer was created when Russia's Avangard Electromechanical Plant and Fresenius Medical Care (FMC) --the largest

  4. L. Brooks Release.DOC

    National Nuclear Security Administration (NNSA)

    01-17 National Nuclear Security Administration NEWS MEDIA CONTACT: FOR IMMEDIATE RELEASE Jonathan Kiell, 202/586-7371 October 30, 2001 Linton Brooks Assumes Post as Deputy Administrator for NNSA Defense Nuclear Nonproliferation Office Ambassador Linton F. Brooks was sworn in today as the Deputy Administrator for the National Nuclear Security Administration's (NNSA) Defense Nuclear Nonproliferation Office. Ambassador Brooks was nominated by President Bush on July 19, 2001 and was confirmed by the

  5. Operations & Maintenance Best Practices Guide: Release 3.0

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    C � Resources � Appendix C Resources for Energy and Facilities Professionals The references and resources provided below are by no means all-inclusive. The listed organiza- tions are not endorsed by the authors of this guide and are provided for your information only. To locate additional resources, the authors of this guide recommend contacting relevant trade groups, databases, and the world-wide web. Organizations American Society for Healthcare Engineering (ASHE) � Website: www.ashe.org

  6. Emission of biogenic sulfur gases from Chinese paddy soil and rice plant

    SciTech Connect (OSTI)

    Zhen Yang [Nanjing Univ. of Science and Technology (China); Li Kong [Nanjing Agricultural Univ. (China)

    1996-12-31

    Biogenic sulfur gases emitted from terrestrial ecosystem may play in important role in global sulfur cycle and have a profound influence on global climate change. But very little is known concerning emissions from paddy soil and rice plant, which are abundant in many parts of the world. As a big agricultural country, this is about 33 million hectare rice planted in China. With laboratory incubation and closed chamber method in the field, the biogenic sulfur gases emitted from Chinese paddy soil and rice plant were detected in both conditions: hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), methyl mercaptan (MSH), carbon disulfide (CS{sub 2}), dimethyl sulfide (DMS) and dimethyl disulfide (DMDS). Among which, DMS was predominant part of sulfur emission. Emission of sulfur gases from different paddy field exhibit high spatial and temporal variability. The application of fertilizer and organic manure, total sulfur content in wetland, air temperature were positively correlated to the emission of volatile sulfur gases from paddy soil. Diurnal and seasonal variation of total volatile sulfur gases and DMS indicate that their emissions were greatly influenced by the activity of the rice plant. The annual emission of total volatile sulfur gases, from Nanjing paddy field is ranged from 4.0 to 9.5 mg S m{sup -2}yr{sup -1}, that of DMS is ranged from 3.1 to 6.5 mg S m{sup -2}yr{sup -1}. Rice plant could absorb COS gas, that may be one of the sinks of COS.

  7. Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Gregory F.; Kruger, Albert A.

    2014-10-01

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis). If the amount of sulfur exceeds its tolerance level a molten salt will accumulate and upset melter operations and potentially shorten melter useful life. Therefore relatively conservative limits have been placed on sulfur loading in melter feed which in-turn significantly impacts the amount of glass that will be produced, in particular at the Hanford site. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 312 individual glass compositions. This model was shown to well represent the data, accounting for over 80% of the variation in data and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed based on 19 scaled melter tests. The model is appropriate for control of waste glass processing which includes uncertainty quantification. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5 ? TiO2 < CaO < P2O5 ? ZnO. The components that most decrease sulfur solubility are Cl > Cr2O3 > SiO2 ? ZrO2 > Al2O3.

  8. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, Ragnar P. (Birmingham, MI); Winterbottom, Walter L. (Farmington Hills, MI); Wroblowa, Halina S. (West Bloomfield, MI)

    1987-01-01

    This specification is directed to a method of making a current collector (14) for a sodium/sulfur battery (10). The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material (16) formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500-1000 angstroms.

  9. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

    1987-03-10

    This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

  10. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E.; Jalan, Vinod M.

    1984-01-01

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  11. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  12. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  13. NERSC Releases Mobile Apps to Users

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases Mobile Apps to Users NERSC Releases Mobile Apps to Users Job Status, MOTD and Pilot of VASP Submission Available with More to Come April 23, 2012 In an effort to make...

  14. DOE Issues WIPP Radiological Release Investigation Report

    Broader source: Energy.gov [DOE]

    Today, the Department of Energy’s Office of Environmental Management (EM) released the initial accident investigation report related to the Feb. 14 radiological release at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico.

  15. I Unlimited Release UC-70

    Office of Scientific and Technical Information (OSTI)

    Unlimited Release UC-70 Proceedings of the Fifth Annual NEA-Seabed Working Group Meeting Bristol, England March 3 - 5, 1980 D. Richard Anderson, Editor *md by $wrdia W - I Labcratmks, A l b u q w - New Mmka '71@s - a d L - Cal&mla SrFSBDfm tfm Unitad S l w m D - 1 ird E W @ ~ : ya& CpFaJS Q & d - 7 - ~~&rS&emhw I B ~ D -a,J - . r , ~ : :>5:, ~ ~ 5 - r 1 - e . - - Q Sandia National Laboratories L - I . DISCLAIMER This report was prepared as an account of work sponsored by

  16. Media Contact: For Immediate Release:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Immediate Release: Cameron Hardy, DOE July 16, 2010 (509) 376-5365, Cameron_M_Hardy@rl.gov Dee Millikin, CH2M HILL Plateau Remediation Company (509) 376-1297, Dee_Millikin@rl.gov Radioactive Equipment Cleared From U Canyon Deck Recovery Act Funding Moves U Canyon Closer to First-of-a-Kind Demolition RICHLAND, WASH. - Using $35 million in additional funding through the American Recovery and Reinvestment Act, the U.S. Department of Energy (DOE) is preparing one of Hanford's massive

  17. Media Contacts: For Immediate Release:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cameron Hardy, DOE July 20, 2010 (509) 376-5365, Cameron.Hardy@rl.doe.gov Dee Millikin, CH2M HILL Plateau Remediation Company (509) 376-1297, Dee_Millikin@rl.gov **Photo Release** Helicopter Removes Aging Truck From Steep Rattlesnake Ravine RICHLAND, WASH. - A Sikorsky S-64 helicopter removed an old truck from a steep ravine on Rattlesnake Mountain today as part of the cleanup of the Arid Lands Ecology Reserve (ALE). The Department of Energy's contractor, CH2M HILL Plateau Remediation Company,

  18. Department of Energy Releases 2014 Strategic Plan

    Broader source: Energy.gov [DOE]

    The Department of Energy released its 2014 Strategic Plan, a comprehensive blueprint to guide the agency's core mission.

  19. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    57.8 42.0 See footnotes at end of table. 200 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  20. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.6 47.4 See footnotes at end of table. 200 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  1. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    51.8 See footnotes at end of table. 242 Energy Information Administration Petroleum Marketing Annual 1995 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  2. Sulfur dioxide-induced chronic bronchitis in beagle dogs

    SciTech Connect (OSTI)

    Greene, S.A.; Wolff, R.K.; Hahn, F.F.; Henderson, R.F.; Mauderly, J.L.; Lundgren, D.L.

    1984-01-01

    This study was done to produce a model of chronic bronchitis. Twelve beagle dogs were exposed to 500 ppm sulfur dioxide (SO/sub 2/) for 2 h/d, 5d/wk for 21 wk and 4 dogs were sham-exposed to filtered ambient air for the same period. Exposure effects were evaluated by periodically examining the dogs using chest radiographs, pulmonary function, tracheal mucous clearance, and the cellular and soluble components of bronchopulmonary lavage fluids. Dogs were serially sacrificed after 13 and 21 wk of exposure and after 6 and 14 wk of recovery. Clinical signs produced in the SO/sub 2/-exposed dogs included mucoid nasal discharge, productive cough, moist rales on auscultation, tonsilitis, and conjunctivitis. Chest radiographs revealed mild peribronchiolar thickening. Histopathology, tracheal mucous clearance measurements, and lavage cytology were consistent with a diagnosis of chronic bronchitis. It is concluded that repeated exposure to 500 ppm SO/sub 2/ for 21 wk produced chronic bronchitis in the beagle dog. Complete recovery occurred within 5 wk following cessation of SO/sub 2/ exposure. 43 references, 2 figures, 2 tables.

  3. Low-quality natural gas sulfur removal/recovery

    SciTech Connect (OSTI)

    Damon, D.A.; Siwajek, L.A.; Klint, B.W.

    1993-12-31

    Low quality natural gas processing with the integrated CFZ/CNG Claus process is feasible for low quality natural gas containing 10% or more of CO{sub 2}, and any amount of H{sub 2}S. The CNG Claus process requires a minimum CO{sub 2} partial pressure in the feed gas of about 100 psia (15% CO{sub 2} for a 700 psia feed gas) and also can handle any amount of H{sub 2}S. The process is well suited for handling a variety of trace contaminants usually associated with low quality natural gas and Claus sulfur recovery. The integrated process can produce high pressure carbon dioxide at purities required by end use markets, including food grade CO{sub 2}. The ability to economically co-produce high pressure CO{sub 2} as a commodity with significant revenue potential frees process economic viability from total reliance on pipeline gas, and extends the range of process applicability to low quality gases with relatively low methane content. Gases with high acid gas content and high CO{sub 2} to H{sub 2}S ratios can be economically processed by the CFZ/CNG Claus and CNG Claus processes. The large energy requirements for regeneration make chemical solvent processing prohibitive. The cost of Selexol physical solvent processing of the LaBarge gas is significantly greater than the CNG/CNG Claus and CNG Claus processes.

  4. Sulfur gas sensor using a calcium fluoride solid electrolyte

    SciTech Connect (OSTI)

    Toniguchi, M.; Wakihara, M.; Uchida, T.; Hirakawa, K.; Nii, J.

    1988-01-01

    The sulfur gas potentials in the H/sub 2/S + H/sub 2/ buffer gases were measured by a galvanic cell Ps/sub 2/(g),Au(Pt)/(MoS/sub 2/ + CaS)/CaF/sub 2//(Cu + Cu/sub 2/S + CaS)/Au(Pt) in the temperature range from 650/sup 0/ to 950/sup 0/C and Ps/sub 2/ region from 10/sup -2/ to 10/sup -10/ atm. A quick response time (within 5 to 10 min) in emf with the change of Ps/sub 2/ at a given temperature was observed by placing a MoS/sub 2/ and CaS mixed pellet auxiliary electrode at the bottom of the cylindrical single-crystal CaF/sub 2/ electrolyte. The observed emf's agreed well with with those calculated from the Nernst equation. Using this sensor, Ps/sub 2/ values in the SO/sub 2/ + H/sub 2/ + H/sub 2/S gas system were also evaluated from the measured emf at 827/sup 0/C and were found to be in close agreement with those calculated from the thermochemical tables.

  5. Longitudinal study of children exposed to sulfur oxides

    SciTech Connect (OSTI)

    Dodge, R.; Solomon, P.; Moyers, J.; Hayes, C.

    1985-05-01

    This study is a longitudinal comparison of the health of children exposed to markedly different concentrations of sulfur dioxide and moderately different concentrations of particulate sulfate. The four groups of subjects lived in two areas of one smelter town and in two other towns, one of which was also a smelter town. In the area of highest pollution, children were intermittently exposed to high SO/sub 2/ levels (peak three-hour average concentration exceeded 2,500 micrograms/m3) and moderate particulate SO/sub 4/= levels (average concentration was 10.1 micrograms/m3). When the children were grouped by the four gradients of pollution observed, the prevalence of cough (measured by questionnaire) correlated significantly with pollution levels (trend chi-square = 5.6, p = 0.02). No significant differences in the incidence of cough or other symptoms occurred among the groups of subjects over three years, and pulmonary function and lung function growth over the study were roughly equal among all the groups. These results suggest that intermittent elevations in SO/sub 2/ concentration, in the presence of moderate particulate SO/sub 4/= concentration, produced evidence of bronchial irritation in the subjects, but no chronic effect on lung function or lung function growth was detected.

  6. Facile synthesis, spectral properties and formation mechanism of sulfur nanorods in PEG-200

    SciTech Connect (OSTI)

    Xie, Xin-yuan; Li, Li-yun; Zheng, Pu-sheng; Zheng, Wen-jie; Bai, Yan; Cheng, Tian-feng; Liu, Jie

    2012-11-15

    Graphical abstract: Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of about 68 was obtained. The sulfur nanoparticles could self-assemble from spherical particles to nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift which was due to the production of nanorods. Highlights: ? A novel, facile and greener method to synthesize sulfur nanorods by the solubilizing and templating effect of PEG-200 was reported. ? S{sup 0} nanoparticles could self assemble in PEG-200 and finally form monodisperse and homogeneous rod-like structure with an average diameter of about 80 nm, the length ca. 600 nm. ? The absorption band showed a red shift and the RRS intensity enhanced continuously during the self-assembling process. ? PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. -- Abstract: The synthesis of nano-sulfur sol by dissolving sublimed sulfur in a green solvent-PEG-200 was studied. Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of 68 was obtained. The structure, morphology, size, and stability of the products were investigated by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering (DLS) measurements. The spectral properties of the products were investigated by ultraviolet-visible (UVvis) absorption and resonance Rayleigh scattering spectroscopy (RRS). The results showed that the spherical sulfur nanoparticles could self-assemble into nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift and the RRS intensity enhanced continuously. There was physical cross-linking between PEG and sulfur nanoparticles. PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. This research provides a greener and more environment-friendly synthetic method for the production of sulfur nanorods.

  7. H. R. 4177: A Bill to amend the Internal Revenue Code of 1986 to impose an excise tax on sulfur dioxide and nitrogen oxide emissions from utility plants. Introduced in the House of Representatives, One Hundredth First Congress, Second Session, March 5, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The tax imposed would begin in 1991 in the amount of 15 cents per pound of sulfur dioxide released and 10 cents per pound nitrogen oxide, and would increase so that the tax in 1997 and thereafter would be 45 cents per pound of sulfur dioxide and 30 cents per pound of nitrogen oxide released. An inflation adjustment is provided for years after 1997. The tax is imposed on emissions which exceed the exemption level for each pollutant, and these levels are specified herein as pounds exempted per million Btu's of fuel burned. No tax is imposed on units less than 75 megawatts, or units providing less than one-third of the electricity produced to a utility power distribution system for sale.

  8. Development of Efficient Flowsheet and Transient Modeling for Nuclear Heat Coupled Sulfur Iodine Cyclefor Hydrogen Production

    SciTech Connect (OSTI)

    Shripad T. Revankar; Nicholas R. Brown; Cheikhou Kane; Seungmin Oh

    2010-05-01

    The realization of the hydrogen as an energy carrier for future power sources relies on a practical method of producing hydrogen in large scale with no emission of green house gases. Hydrogen is an energy carrier which can be produced by a thermochemical water splitting process. The Sulfur-Iodine (SI) process is an example of a water splitting method using iodine and sulfur as recycling agents.

  9. Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2011-03-15

    Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

  10. Multi-model Mean Nitrogen and Sulfur Deposition from the Atmospheric

    Office of Scientific and Technical Information (OSTI)

    Chemistry and Climate Model Intercomparison Project (ACCMIP): Evaluation of Historical and Projected Future Changes (Journal Article) | SciTech Connect Multi-model Mean Nitrogen and Sulfur Deposition from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP): Evaluation of Historical and Projected Future Changes Citation Details In-Document Search Title: Multi-model Mean Nitrogen and Sulfur Deposition from the Atmospheric Chemistry and Climate Model Intercomparison

  11. Extraction of Sulfur Mustard Metabolites from Urine Samples and Analysis by

    Office of Scientific and Technical Information (OSTI)

    Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) (Technical Report) | SciTech Connect Sulfur Mustard Metabolites from Urine Samples and Analysis by Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) Citation Details In-Document Search Title: Extraction of Sulfur Mustard Metabolites from Urine Samples and Analysis by Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) Authors: Mayer, B P ; Williams, A M ; Leif, R N ; Udey, R N ; Vu, A K

  12. Low Temperature Sodium-Sulfur Grid Storage and EV Battery - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Low Temperature Sodium-Sulfur Grid Storage and EV Battery Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary Berkeley Lab researcher Gao Liu has developed an innovative design for a battery, made primarily of sodium and sulfur, that

  13. Sulfur tolerant highly durable CO.sub.2 sorbents (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Sulfur tolerant highly durable CO.sub.2 sorbents Citation Details In-Document Search Title: Sulfur tolerant highly durable CO.sub.2 sorbents A sorbent for the capture of carbon dioxide from a gas stream is provided, the sorbent containing calcium oxide (CaO) and at least one refractory dopant having a Tammann temperature greater than about 530.degree. C., wherein the refractory dopant enhances resistance to sintering, thereby conserving performance of the sorbent at temperatures of at

  14. Interaction of CuS and sulfur in Li-S battery system

    SciTech Connect (OSTI)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, under a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.

  15. Interaction of CuS and sulfur in Li-S battery system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, undermore » a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.« less

  16. Sulfur oxidation to sulfate coupled with electron transfer to electrodes by Desulfuromonas strain TZ1

    SciTech Connect (OSTI)

    Zhang, T; Bain, TS; Barlett, MA; Dar, SA; Snoeyenbos-West, OL; Nevin, KP; Lovley, DR

    2014-01-02

    Microbial oxidation of elemental sulfur with an electrode serving as the electron acceptor is of interest because this may play an important role in the recovery of electrons from sulfidic wastes and for current production in marine benthic microbial fuel cells. Enrichments initiated with a marine sediment inoculum, with elemental sulfur as the electron donor and a positively poised (+300 mV versus Ag/AgCl) anode as the electron acceptor, yielded an anode biofilm with a diversity of micro-organisms, including Thiobacillus, Sulfurimonas, Pseudomonas, Clostridium and Desulfuromonas species. Further enrichment of the anode biofilm inoculum in medium with elemental sulfur as the electron donor and Fe(III) oxide as the electron acceptor, followed by isolation in solidified sulfur/Fe(III) medium yielded a strain of Desulfuromonas, designated strain TZ1. Strain TZ1 effectively oxidized elemental sulfur to sulfate with an anode serving as the sole electron acceptor, at rates faster than Desulfobulbus propionicus, the only other organism in pure culture previously shown to oxidize S with current production. The abundance of Desulfuromonas species enriched on the anodes of marine benthic fuel cells has previously been interpreted as acetate oxidation driving current production, but the results presented here suggest that sulfur-driven current production is a likely alternative.

  17. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  18. Biomediated continuous release phosphate fertilizer

    DOE Patents [OSTI]

    Goldstein, A.H.; Rogers, R.D.

    1999-06-15

    A composition is disclosed for providing phosphate fertilizer to the root zone of plants. The composition comprises a microorganism capable of producing and secreting a solubilization agent, a carbon source for providing raw material for the microorganism to convert into the solubilization agent, and rock phosphate ore for providing a source of insoluble phosphate that is solubilized by the solubilization agent and released as soluble phosphate. The composition is provided in a physical form, such as a granule, that retains the microorganism, carbon source, and rock phosphate ore, but permits water and soluble phosphate to diffuse into the soil. A method of using the composition for providing phosphate fertilizer to plants is also disclosed. 13 figs.

  19. Biomediated continuous release phosphate fertilizer

    DOE Patents [OSTI]

    Goldstein, Alan H. (Beverly Hills, CA); Rogers, Robert D. (Idaho Falls, ID)

    1999-01-01

    A composition is disclosed for providing phosphate fertilizer to the root zone of plants. The composition comprises a microorganism capable of producing and secreting a solubilization agent, a carbon source for providing raw material for the microorganism to convert into the solubilization agent, and rock phosphate ore for providing a source of insoluble phosphate that is solubilized by the solubilization agent and released as soluble phosphate. The composition is provided in a physical form, such as a granule, that retains the microorganism, carbon source, and rock phosphate ore, but permits water and soluble phosphate to diffuse into the soil. A method of using the composition for providing phosphate fertilizer to plants is also disclosed.

  20. History of SPR Releases | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History of SPR Releases History of SPR Releases The Strategic Petroleum Reserve exists, first and foremost, as an emergency response tool the President can use should the United States be confronted with an economically-threatening disruption in oil supplies. A Presidentially-directed release has occurred three times under these conditions. First, in 1991, at the beginning of Operation Desert Storm, the United States joined its allies in assuring the adequacy of global oil supplies when war

  1. Department of Energy Releases 2011 Strategic Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. Department of Energy Office of Public Affairs News Media Contact: (202) 586-4940 For Immediate Release: Tuesday, May 10, 2011 Department of Energy Releases 2011 Strategic Plan Washington, D.C.� The Department of Energy today released its 2011 Strategic Plan, a comprehensive blueprint to guide the agency�s core mission of ensuring America�s security and prosperity by addressing its energy, environmental, and nuclear challenges through transformative science and technology solutions. In

  2. Department of Energy Releases WIPP Recovery Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Releases WIPP Recovery Plan Washington, D.C. - Today, the Department of Energy (DOE) released the Waste Isolation Pilot Plant (WIPP) Recovery Plan, outlining the necessary steps to resume operations at the transuranic waste disposal site outside of Carlsbad, N.M. WIPP operations were suspended following an underground truck fire and a radiological release earlier this year. "Safety is our top priority," said Mark Whitney, Acting Assistant Secretary for DOE's Office

  3. Environmental releases for calendar year 1996

    SciTech Connect (OSTI)

    Greager, E.M.

    1997-07-31

    This report presents data on radioactive and nonradioactive materials released into the environment during calendar year 1996 from facilities and activities managed by the Fluor Daniel Hanford, Incorporated (formerly the Westinghouse Hanford Company) and Bechtel Hanford, Incorporated. Fluor Daniel Hanford, Incorporated provides effluent monitoring services for Bechtel Hanford, Incorporated, which includes release reporting. Both summary and detailed presentations of the environmental releases are provided. When appropriate, comparisons to data from previous years are made.

  4. Environmental releases for calendar year 1995

    SciTech Connect (OSTI)

    Diediker, L.P., Westinghouse Hanford

    1996-07-30

    This report presents data on radioactive and nonradioactive materials released into the environment during calendar year 1995 from facilities managed by the Westinghouse Hanford Company (WHC) and monitored by Bechtel Hanford, Incorporated (BHI). WHC provides effluent monitoring services for BHI, which includes release reporting. Both summary and detailed presentations of the environmental releases are provided. When appropriate,comparisons to data from previous years are made.

  5. EM Press Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Press Releases EM Press Releases RSS December 29, 2015 DOE Releases Request for Information for the West Valley Demonstration Project Technical Services to Develop a Supplemental Environmental Impact Statement Procurement Cincinnati -- The U.S. Department of Energy (DOE) today issued a Request for Information (RFI) seeking to solicit input via capability statements from interested parties with the specialized capabilities necessary to meet the requirements of the Draft Performance Work Statement

  6. Involuntary Separation Program General Release and Waiver

    Office of Environmental Management (EM)

    Involuntary Separation Program General Release and Waiver This Involuntary Separation Program General Release and Waiver ("Release") is entered into by and between ______________________ ("Employee") and _________ ("Employer") in connection with the Employer's determination that the Employee is being laid off from employment by ________. IN EXCHANGE FOR THE PROMISES SET FORTH BELOW, THE PARTIES AGREE AS FOLLOWS: 1. Valuable Consideration: In exchange for Employee

  7. Climate Change Press Release | Department of Energy

    Office of Environmental Management (EM)

    Change Press Release Climate Change Press Release Community Leaders Institutes (CLIs) to be conducted to promote awareness of climate change impacts. PDF icon CLI Climate Change Press Release More Documents & Publications A Review of the Department of Energy's Implementation of Executive Order 12898 and Recommendations for a Second Five-Year Strategic Plan Program Update: 2nd Quarter 2015 Environmental Justice Five-Year Implementation Plan - First Annual Progress Report

  8. SRP RADIOACTIVE WASTE RELEASES S

    Office of Scientific and Technical Information (OSTI)

    .. . . . . -- SRP RADIOACTIVE WASTE RELEASES S t a r t u p t h r o u g h 1 9 5 9 September 1 9 6 0 _- R E C O R D - W O R K S T E C H N I C A L D E P A R T M E N T 1 J. E. C o l e , W i l n i 1 4 W. P. 3ebbii 3 H. Worthington, Wilm 16 C. $?. P~.t-Lei-s~:; - 5 J. D. E l l e t t - 17 E. C. Morris 6 F. H. Endorf 19 3 . L. &tier 7 K. W. F r e n c h 20 bi. C . 3 e i n i g 8 J. K. Lower 2 1 2. 3 . 3 G : - x r 9 K. W. M i l l e t t 22 R . FJ . V 2 x 7 : W ~ ~ C k 1 c - 2 J. B. Tinker, W i h L-, i .

  9. Guide to Geothermal Power Finance Released

    Broader source: Energy.gov [DOE]

    The National Renewable Energy Laboratory, funded by the U.S. Department of Energy’s Geothermal Technologies Program, today released the Guidebook to Geothermal Power Finance.

  10. Approved for Public Release; Further Dissemination Unlimited

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Public, See below. Approved for Public Release; Further Dissemination Unlimited By Janis D. Aardal at 8:25 am, Oct 15, 2015 10/15/2015

  11. DOE National Laboratory Releases Annual Accomplishments Report

    Broader source: Energy.gov [DOE]

    The National Energy Technology Laboratory has released its annual accomplishments report, highlighting breakthroughs in research and technology development to address the nation's energy, economic, and environmental challenges.

  12. Involuntary Separation Program General Release and Waiver

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... not selected in the same job classification or organizational unit. 12. Entire ... valid and enforceable. 13. Governing Law: This Release will be construed and ...

  13. NEWS MEDIA CONTACT: FOR IMMEDIATE RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigation Report Washington, D.C. - Today, the Department of Energy's Office of Environmental Management (EM) released the initial accident investigation report related to the...

  14. Press Releases Archive | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Subscribe to Press Releases Archive January 4, 2016 PPPL physicists simulate innovative method for starting up tokamaks without using a solenoid By Raphael Rosen PPPL Scientist...

  15. University of Delaware | CCEI Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases DOE Funding Leads to New Technology that is Revolutionizing Chemical Analysis (November 2015) CCEI's carbon detection technology is commercialized by Activated ...

  16. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stories and Releases New Mobile Atmospheric Laboratory Gathering Weather and Climate Change Data on the California Coast Bookmark and Share Are Aerosols Reducing Coastal Drizzle...

  17. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    26, 2013 Facility News, Feature Stories and Releases Climate Data Now Flowing from Oliktok, Alaska Bookmark and Share New climate observatory records atmospheric measurements at...

  18. 2017 Levelized Costs AEO 2012 Early Release

    Gasoline and Diesel Fuel Update (EIA)

    ... market dynamics such as refinery margins and petroleum ... Recent trade press reports indicate that Saudi Arabia is ... Bloomberg released the 2016 target weights for 22 ...

  19. Separation Programs Releases and Waivers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Separation Programs Releases and Waivers Separation Programs Releases and Waivers PDF icon Attachment 7 - Separation Programs Releases and Waivers More Documents & Publications Self-Select Voluntary Separation Plan Template Workforce Restructuring Policy Involuntary Separation Program General Release and Waiver

  20. Toward understanding the effect of low-activity waste glass composition on sulfur solubility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D.; Kim, Dong -Sang; Muller, Isabelle S.; Piepel, Greg F.; Kruger, Albert A.; Jantzen, C.

    2014-07-24

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which inmore » turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ≈ P2O5 > Na2O ≈ B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ≈ SnO2 > Others ≈ SiO2. As a result, the order of component effects is similar to previous literature data, in most cases.« less

  1. Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Greg F.; Kruger, Albert A.

    2014-07-24

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

  2. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  3. Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin

    SciTech Connect (OSTI)

    Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

    2011-02-28

    Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

  4. Effect of morphology of sulfurized materials in the retention of mercury from gas streams

    SciTech Connect (OSTI)

    Guijarro, M.I.; Mendioroz, S.; Munoz, V.

    1998-03-01

    Mercury pollution sources are chloralkali industries, metal sulfide ore smelting, gold refining, cement production, industrial applications of metals, and, especially, fossil fuel combustion and incineration of sewage sludge or municipal garbage. The retention of mercury vapor by sulfur supported on sepiolite has been studied, and the utility of sepiolite as a dispersant for the active phase, sulfur, has been thoroughly ascertained. Samples with 10% S supported on sepiolite of varying size and shape have been prepared from powders sulfurized by reaction/deposit, and their efficiency in depurating air streams with 95 ppm mercury has been tested in a dynamic system using a fixed-bed glass reactor and fluid velocities ranging from 3.1 to 18.9 cm/s. From breakthrough curves under various sets of conditions, the importance of mass transfer under the process conditions has been proven. The progress of the reaction is limited by the resistance to reactant diffusion inside the solid through the layer of product formed. Sulfur reaction to HgS is reduced to an external zone of the solid, giving rise to an egg-shell deposit whose extension is related to sulfur dispersion and porosity of the adsorbent. Then, conversion and capacity of the samples are related to their porosity and S/V ratio. The use of SEM helps to confirm those statements. The 10% S samples compare well with the more conventional S/activated carbon, with their use being advantageous for the low price and abundance of the substrate.

  5. Morphology of Gas Release in Physical Simulants

    SciTech Connect (OSTI)

    Daniel, Richard C.; Burns, Carolyn A.; Crawford, Amanda D.; Hylden, Laura R.; Bryan, Samuel A.; MacFarlan, Paul J.; Gauglitz, Phillip A.

    2014-07-03

    This report documents testing activities conducted as part of the Deep Sludge Gas Release Event Project (DSGREP). The testing described in this report focused on evaluating the potential retention and release mechanisms of hydrogen bubbles in underground radioactive waste storage tanks at Hanford. The goal of the testing was to evaluate the rate, extent, and morphology of gas release events in simulant materials. Previous, undocumented scoping tests have evidenced dramatically different gas release behavior from simulants with similar physical properties. Specifically, previous gas release tests have evaluated the extent of release of 30 Pa kaolin and 30 Pa bentonite clay slurries. While both materials are clays and both have equivalent material shear strength using a shear vane, it was found that upon stirring, gas was released immediately and completely from bentonite clay slurry while little if any gas was released from the kaolin slurry. The motivation for the current work is to replicate these tests in a controlled quality test environment and to evaluate the release behavior for another simulant used in DSGREP testing. Three simulant materials were evaluated: 1) a 30 Pa kaolin clay slurry, 2) a 30 Pa bentonite clay slurry, and 3) Rayleigh-Taylor (RT) Simulant (a simulant designed to support DSGREP RT instability testing. Entrained gas was generated in these simulant materials using two methods: 1) application of vacuum over about a 1-minute period to nucleate dissolved gas within the simulant and 2) addition of hydrogen peroxide to generate gas by peroxide decomposition in the simulants over about a 16-hour period. Bubble release was effected by vibrating the test material using an external vibrating table. When testing with hydrogen peroxide, gas release was also accomplished by stirring of the simulant.

  6. Connectivity To Atmospheric Release Advisory Capability

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-02-26

    To establish DOE and NNSA connectivity to Atmospheric Release Advisory Capability (ARAC) for sites and facilities that have the potential for releasing hazardous materials sufficient to generate certain emergency declarations and to promote efficient use of resources for consequence assessment activities at DOE sites, facilities, operations, and activities in planning for and responding to emergency events. No cancellations.

  7. Hydrogen Release Behavior | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Release Behavior Hydrogen Release Behavior 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon scs_06_moen.pdf More Documents & Publications US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen.PDF Safetygram Gaseous Hydrogen

  8. Method for releasing hydrogen from ammonia borane

    DOE Patents [OSTI]

    Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

    2013-02-19

    A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

  9. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J. (Bethel Park, PA)

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  10. Electrochemical separation and concentration of sulfur containing gases from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

    1981-01-01

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  11. Environmental release summary (ERS) database CY 1997

    SciTech Connect (OSTI)

    Gleckler, B.P.

    1998-07-01

    This report discusses the Environmental Release Summary (ERS) database. The current needs of the Effluent and Environmental database is continually modified to fulfill monitoring (EEM) program (managed by Waste Management Federal Services of Hanford, Incorporated, Air and Water Services Organization). Changes are made to accurately calculate current releases, to affect how past releases are calculated. This document serves as a snap-shot of the database and software for the CY-1997 data and releases. This document contains all of the relevant data for calculating radioactive-airborne and liquid effluent. The ERS database is the official repository for the CY-1997 ERS release reports and the settings used to generate those reports. As part of the Tri-Party Agreement, FDH is committed to provide a hard copy of the ERS database for Washington State Department of Ecology, upon request. This document also serves as that hard copy for the last complete calendar year.

  12. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  13. Press Releases Archive | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 2, 2012 PPPL wins Department of Energy award for reducing greenhouse gases By Jeanne Jackson DeVoe PPPL engineer Tim Stevenson checks for possible leaks of sulfur hexafluoride (SF6), the gas used to insulate electronic equipment that has the potential to cause global warming at many times the rate of carbon dioxide. PPPL reduced leaks of SF6 by 65 percent over three years - reducing overall greenhouse gas emissions by 48 percent between 2008 and 2011. The Department of Energy's Princeton

  14. Sulfur determination in blood from inhabitants of Brazil using neutron activation analysis

    SciTech Connect (OSTI)

    Oliveira, Laura C.; Zamboni, Cibele B.

    2013-05-06

    In this study the NAA technique was applied to analyze sulfur in blood from inhabitants of Brazil for the proposition of an indicative interval. The measurements were performed considering lifestyle factors (non-smokers, non-drinkers and no history of toxicological exposure) of Brazilian inhabitants. The influence of gender was also investigated considering several age ranges (18-29, 30-39, 40-49, >50 years). These data are useful in clinical investigations, to identify or prevent diseases caused by inadequate sulfur ingestion and for nutritional evaluation of Brazilian population.

  15. NO[sub x] reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1992-09-15

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter. 7 figs.

  16. NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

    1993-01-01

    This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  17. NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

    1992-01-01

    This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  18. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects | Department of Energy Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_parks.pdf More Documents & Publications The Next Regulatory Chapter for Commercial Vehicles Review of Diesel

  19. NOx reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1993-08-31

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  20. A reanalysis of carbonyl sulfide as a source of stratospheric background sulfur aerosol

    SciTech Connect (OSTI)

    Chin, M.; Davis, D.D. [Georgia Institute of Technology, Atlanta, GA (United States)] [Georgia Institute of Technology, Atlanta, GA (United States)

    1995-05-20

    The authors present an analysis of carbonyl sulfide (OCS) in the earth`s atmosphere, with the objective being to assess its role in the formation of sulfate aerosols in the stratosphere. They review the amount of OCS in the atmosphere, its distribution between the troposphere and stratosphere, the estimated source term for emission to the atmosphere, and from one-dimensional model calculations infer a stratospheric lifetime to photochemical reactions of ten years. Calculations infer a sulfur production rate from OCS oxidation which is a factor of 2 to 5 less than recent sulfur aerosol estimates would infer. They discuss a number of possible explanations for the discrepancy.

  1. Performance and economics of a spray-dryer FGD system used with high-sulfur coal

    SciTech Connect (OSTI)

    Livengood, C.D.; Farber, P.S.

    1986-04-01

    Flue-gas desulfurization (FGD) systems based on spray drying to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. Uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. This paper summarizes 4 years, operating and research experience with that system and describes the current research program, which includes an indepth characterization of an industrial scale dry scrubber with 3.5% sulfur coal.

  2. Preliminary analysis of patent trends for sodium/sulfur battery technology

    SciTech Connect (OSTI)

    Triplett, M.B.; Winter, C.; Ashton, W.B.

    1985-07-01

    This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.

  3. Lithium / Sulfur Cells with Long Cycle Life and High Specific Energy -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Lithium / Sulfur Cells with Long Cycle Life and High Specific Energy Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication Song, M-K., Zhang, Y., Cairns, E.J., "A long-life, high-rate lithium/sulfur cell: a multifaceted approach to enhancing cell performance," NanoLetters, November 12, 2013 (web). (437 KB) Technology Marketing Summary A team of Berkeley Lab battery researchers led by Elton Cairns has

  4. Ultra-Low Sulfur diesel Update & Future Light Duty Diesel | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Low Sulfur diesel Update & Future Light Duty Diesel Ultra-Low Sulfur diesel Update & Future Light Duty Diesel Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_leister.pdf More Documents & Publications Fueling U.S. Light Duty Diesel Vehicles Biodiesel_Fuel_Management_Best_Practices_Report.pdf A Life-Cycle Assessment Comparing Select

  5. HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS

    SciTech Connect (OSTI)

    Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

    2009-05-12

    This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

  6. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect (OSTI)

    Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-08-25

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  7. BONNEVILLE POWER ADMINISTRATION FOR IMMEDIATE RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    planned release of the collection, BPA postponed distribution in order to provide clean, digital transfers from the originals of the six films featured in the DVD set. Burke says...

  8. Use Release Instruction form in Site Forms

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release 77 TABLE OF CONTENTS September 23, 2015 Rev 1 Page 1 MAIN TABLE OF CONTENTS Effective Date 1.0 INTRODUCTION 042414 2.0 RESPONSIBILITIES 092315 3.0 CRITICAL, SPECIAL,...

  9. Municipal Consortium Releases Updated Model Specification for...

    Energy Savers [EERE]

    for LED Roadway Luminaires Municipal Consortium Releases Updated Model Specification for LED Roadway Luminaires July 10, 2014 - 10:23am Addthis The U.S. Department of Energy's ...

  10. Corrosion Tests of LWR Fuels - Nuclide Release

    SciTech Connect (OSTI)

    P.A. Finn; Y. Tsai; J.C. Cunnane

    2001-12-14

    Two BWR fuels [64 and 71 (MWd)/kgU], one of which contained 2% Gd, and two PWR fuels [30 and 45 (MWd)/kgU], are tested by dripping groundwater on the fuels under oxidizing and hydrologically unsaturated conditions for times ranging from 2.4 to 8.2 yr at 90 C. The {sup 99}Tc, {sup 129}I, {sup 137}Cs, {sup 97}Mo, and {sup 90}Sr releases are presented to show the effects of long reaction times and of gadolinium on nuclide release. This investigation showed that the five nuclides at long reaction times have similar fractional release rates and that the presence of 2% Gd reduced the {sup 99}Tc cumulative release fraction by about an order of magnitude over that of a fuel with a similar burnup.

  11. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    26, 2015 Feature Stories and Releases Delineating the Sharp Edges of Clouds, Down to the Micrometer Bookmark and Share The HOLODEC, developed in part with funding from the ARM...

  12. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5, 2013 Facility News, Feature Stories and Releases New England Winter No Match for Science on the Cape Bookmark and Share Snow sticking to the sides of these playful statues in...

  13. Energy Department and Environmental Protection Agency Release...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Energy Department and the Environmental Protection Agency (EPA) today released a new label that features EPA fuel economy estimates and CO2 estimates for used vehicles sold...

  14. Emergency Response Planning for Radiological Releases

    SciTech Connect (OSTI)

    Biwer, B.M.; LePoire, D.J.; Lazaro, M.A.; Allison, T.; Kamboj, S.; Chen, S.Y.

    2006-07-01

    The emergency management planning tool RISK-RDD was developed to aid emergency response planners and decision makers at all levels of government to better understand and prepare for potential problems related to a radiological release, especially those in urban areas. Radioactive release scenarios were studied by using the RISK-RDD radiological emergency management program. The scenarios were selected to investigate the key aspects of radiological risk management not always considered in emergency planning as a whole. These aspects include the evaluation of both aerosolized and non-aerosolized components of an atmospheric release, methods of release, acute and chronic human health risks, and the concomitant economic impacts as a function of the risk-based cleanup level. (authors)

  15. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Feature Stories and Releases Ahoy It's MAGIC in the Pacific Bookmark and Share A crane operator carefully moves the AMF2's Roll-Pitch-Yaw stabilization platform into...

  16. Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

    DOE Patents [OSTI]

    Way, J. Douglas; Hatlevik, Oyvind

    2014-07-15

    The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.

  17. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents and methods of use thereof

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2006-06-27

    Reduced sulfur gas species (e.g., H.sub.2S, COS and CS.sub.2) are removed from a gas stream by compositions wherein a zinc titanate ingredient is associated with a metal oxide-aluminate phase material in the same particle species. Nonlimiting examples of metal oxides comprising the compositions include magnesium oxide, zinc oxide, calcium oxide, nickel oxide, etc.

  18. Study on removal of organic sulfur compound by modified activated carbon

    SciTech Connect (OSTI)

    Fan Huiling; Li Chunhu; Guo Hanxian [Taiyuan Univ. of Technology (China). Research Inst. for Chemical Engineering of Coal

    1997-12-31

    With the price of coal increasing in China, more and more small and medium scale chemical plants are turning to high sulfur coal as the raw material in order to cut cost. However, the major drawback is that the lifetime of the ammonia synthesis catalyst is then reduced greatly because of the high concentration of the sulfur compounds in the synthesis gas, especially organic sulfur, usually CS{sub 2} and COS. The effects of water vapor and experimental temperature on removal of organic sulfur compounds by using a modified activated carbon were studied in this paper. It was found that water vapor had a negative effect on removal of carbon disulfide by activated carbon impregnated with organic amine. The use of activated carbon impregnated with K{sub 2}CO{sub 3} for removal of carbonyl sulfide was also investigated over the temperature range 30--60, the results show a favorable temperature (40) existing for carbonyl sulfide removal. Fixed-bed breakthrough curves for the adsorbent bed were also offered in this paper.

  19. ORSSAB News Releases | Department of Energy

    Office of Environmental Management (EM)

    ORSSAB News Releases ORSSAB News Releases February 25, 2016 DOE and Advisory Board Recognize Retiring Members for Service Two ORSSAB members were recognized for service at the board's January 13 meeting. October 1, 2015 DOE and Advisory Board Recognize Retiring Member for Service DOE and ORSSAB recognize retiring member for service. September 24, 2015 Site Specific Advisory Board Elects Officers for FY 2016 ORSSAB elects officers for FY 2016. July 21, 2015 Heritage Is a Part of DOE Advisory

  20. Approved for Public Release; Further Dissemination Unlimited

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7:45 am, May 27, 2014 Approved for Public Release; Further Dissemination Unlimited Approved for Public Release; Further Dissemination Unlimited J. C. Fulton President and Chief Executive Officer April 2014 CHPRC-2014-04, Rev. 0 Monthly Performance Report U.S. Department of Energy Contract, DE-AC06-08RL14788 Deliverable C.3.1.3.1 - 1 1 CHPRC-2014-04, Rev. 0 * Overview CHPRC Monthly Performance Report April 2014 CONTENTS EXECUTIVE SUMMARY

  1. Microfabricated therapeutic actuators and release mechanisms therefor

    Office of Scientific and Technical Information (OSTI)

    (Patent) | SciTech Connect Microfabricated therapeutic actuators and release mechanisms therefor Citation Details In-Document Search Title: Microfabricated therapeutic actuators and release mechanisms therefor Microfabricated therapeutic actuators are fabricated using a shape memory polymer (SMP), a polyurethane-based material that undergoes a phase transformation at a specified temperature (Tg). At a temperature above temperature Tg material is soft and can be easily reshaped into another

  2. Knowledge Based Estimation of Material Release Transients

    Energy Science and Technology Software Center (OSTI)

    1998-07-29

    KBERT is an easy to use desktop decision support tool for estimating public and in-facility worker doses and consequences of radioactive material releases in non-reactort nuclear facilities. It automatically calculates release and respirable fractions based on published handbook data, and calculates material transport concurrently with personnel evacuation simulations. Any facility layout can be modeled easily using the intuitive graphical user interface.

  3. Expansion of ARAC for chemical releases

    SciTech Connect (OSTI)

    Baskett, R.L.; Blair, M.D.; Foster, C.S.; Taylor, A.G.

    1997-07-01

    In 1996 the Atmospheric Release Advisory Capability (ARAC) at Lawrence Livermore National Laboratory (LLNL) completed an effort to expand its national emergency response modeling system for chemical releases. Key components of the new capability include the integration of (1) an extensive chemical property database, (2) source modeling for tanks and evaporating pools, (3) denser-than-air dispersion, (4) public exposure guidelines, and (5) an interactive graphical user interface (GUI). Recent use and the future of the new capability are also discussed.

  4. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 9, 2010 [Feature Stories and Releases] Scientists Begin 5-month Study of Cloud Life Cycles Bookmark and Share Instruments at four mountain sites gather data to improve climate models. For Immediate Release: Thursday, December 9, 2010 Just outside Thunderhead Lodge in the Steamboat Springs ski area, one of the ARM Mobile Facility sites hosts a scanning cloud radar and several other instruments. Just outside Thunderhead Lodge in the Steamboat Springs ski area, one of the ARM Mobile

  5. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, 2006 [Feature Stories and Releases] ARM Program Develops Education Tool Focused on Tropical Climate Bookmark and Share Press Release Media Contact: Lynne Roeder, 509.372.4331 A new kiosk, provided by the ARM Program, is available in Darwin for visitors to learn about climate change in the region. A new educational kiosk on tropical climate, developed by the U.S. Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) Program and the Museum and Art Gallery of the Northern

  6. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 2006 [Feature Stories and Releases] Tropical Cloud Study Concludes; Science Students Play Key Role Bookmark and Share Press Release Media Contact: Lynne Roeder, 509.372.4331 Three and a half weeks after it started, the Tropical Warm Pool International Cloud Experiment has resulted in one of the most comprehensive data sets of tropical cloud properties ever collected. Co-led by scientist from the U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) Program and the Australian

  7. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 2006 [Feature Stories and Releases] Synchronized Flights by U.S. and International Research Aircraft Reveal Intriguing Information about Ice Particles in Clouds Bookmark and Share Press Release Media Contact: Lynne Roeder, ARM Public Information Officer U.S. Tel: 509.521.2921 Au Tel: +61 0406 754 686 In the clouds above Darwin, Australia, pilots guided by a team of international climate scientists are now one week into a series of carefully orchestrated flights to obtain key in situ data

  8. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8, 2005 [Feature Stories and Releases] International Climate Researchers Meet in U.S. to Simulate Flight Operations for Tropical Storm Cloud Experiment Bookmark and Share Press Release Media Contact: Lynne Roeder, 509.372.4331 Technical Contact: Mike Janes, 925.294.2447 The Southern Surveyor research vessel will be equipped with a full compliment of surface-based instrumentation for measuring atmospheric and oceanographic properties. The ship will also serve as one of the locations for launching

  9. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Feature Stories and Releases] U.S. Department of Energy Kicks Off Scientific Collaboration with India Bookmark and Share Instrumented sites will gather data to study impact of aerosols on cloud formation and precipitation For Immediate Release: June 10, 2011 ARM Mobile Facility instrumentation is installed in June 2011 at the ARIES Observatory in Nainital, India, for the Ganges Valley Aerosol Experiment (GVAX). Shown in this photo are the stack for the aerosol observing system (top) and the

  10. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2013 [Facility News, Feature Stories and Releases] DOE's Wanda Ferrell Receives Society Award for Leadership in Atmospheric Science Bookmark and Share For Immediate Release: Wednesday, January 9, 2013 Wanda Ferrell, U.S. Department of Energy Wanda Ferrell, U.S. Department of Energy AUSTIN, Texas-Today at the 2013 American Meteorological Society Annual Meeting, the U.S. Department of Energy's Wanda Ferrell is receiving the prestigious "Cleveland Abbe Award for Distinguished Service to

  11. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    July 8, 2013 [Feature Stories and Releases] Aerosol Research Heats Up During Summer Fire Season Bookmark and Share Smoke plumes rise from a forest fire. Smoke plumes rise from a forest fire. While the impacts of wildfires on people and the surrounding environment are apparent, the effect on the atmosphere from smoky soot particles-a type of aerosol-is much less so. Whether from grass, timber, or brush, each type of biological material releases its own sooty chemical signature that interacts

  12. Latest News Releases | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Latest News Releases Ames Laboratory scientists join consortium to research lightweight materials 03/11/2016 Contacts: For release: March 11, 2016 Iver Anderson, Materials Sciences and Engineering, (515)-294-9649 Steve Karsjen, Public Affairs, (515) 294-5643 Read More Ames Laboratory will lead new consortium to research caloric materials, advance refrigeration technology 02/24/2016 The U.S. Department of Energy's Ames Laboratory will be the home of a new research consortium for the discovery and

  13. NREL: Solar Research - News Release Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 December 2, 2013 NREL Reports Soft Costs Now Largest Piece of Solar Installation Total Cost Two reports offer more in-depth look at non-hardware costs November 21, 2013 NREL Releases Renewable Energy Data Book Detailing Growing Industry in 2012 The National Renewable Energy Laboratory (NREL) has released the 2012 Renewable Energy Data Book on behalf of the Energy Department's Office of Energy Efficiency and Renewable Energy. The annual report is an important assessment of U.S. energy

  14. NREL: Wind Research - News Release Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 October 27, 2010 Offshore Wind Energy Poised to Play a Vital Role in Future U.S. Energy Markets A new report analyzes the current state of the offshore wind energy industry in the United States. October 7, 2010 DOE Releases Comprehensive Report on Offshore Wind Power in the United States U.S. Energy Secretary Steven Chu announced today the release of a report from the Department of Energy's National Renewable Energy Laboratory (NREL), which comprehensively analyzes the key factors impacting

  15. EIA - Annual Energy Outlook 2014 Early Release

    Gasoline and Diesel Fuel Update (EIA)

    Annual Energy Outlook 2015 Release Date: April 14, 2015 | Next Release Date: June 2016 | correction | full report Overview Data Reference Case Side Cases Interactive Table Viewer By Section Executive summary Economic growth Prices Delivered energy consumption by sector Energy consumption by primary fuel Energy intensity Energy production, imports, and exports Electricity generation Energy-related carbon dioxide emissions Appendices Table Title Formats Summary Reference Case tables Year-by-year

  16. Press Releases | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Press Releases | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA

  17. 2010 Report Released | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Report Released | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA

  18. NPO News Releases | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    News Releases | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog

  19. Energy Department Releases Second Quadrennial Technology Review |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Second Quadrennial Technology Review Energy Department Releases Second Quadrennial Technology Review September 10, 2015 - 1:20pm Addthis NEWS MEDIA CONTACT (202) 586-4940 DOENews@hq.doe.gov Research Opportunities Highlighted in Report Lay Out Options for America's Clean Energy Future WASHINGTON, D.C. - Today, the Energy Department released its second Quadrennial Technology Review (QTR), which examines the current status of clean energy technologies and identifies

  20. NE Press Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Press Releases NE Press Releases RSS January 5, 2016 Energy Department selects Battelle team for a deep borehole field test in North Dakota The U.S. Department of Energy has selected a Battelle Memorial Institute-led team to drill a test borehole of over 16,000 feet into a crystalline basement rock formation near Rugby, North Dakota. December 10, 2015 Energy Department Announces New Investments in Supercritical Transformational Electric Power (STEP) Program The U.S. Department of Energy's

  1. OREM Press Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Press Releases OREM Press Releases RSS September 21, 2015 (From left to right) Dennis Wilson, Martha Deaderick, and Mike Ford joined the Oak Ridge Site Specific Advisory Board in Sept. 2015. DOE appoints three new members to environmental advisory board DOE has appointed three new members to its Oak Ridge Environmental Management advisory board. Martha Deaderick, Mike Ford, and Dennis Wilson were introduced at the Oak Ridge Site Specific Advisory Board's September meeting. September 17, 2015 DOE

  2. LPO Press Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Press Releases LPO Press Releases RSS August 24, 2015 President Obama Announces More Than a Billion Dollars in Energy Department Initiatives to Advance Innovative Clean Energy Technologies LPO and ARPA-E Initiatives Support America's Growing Low-Carbon Economy and Combat Climate Change June 24, 2015 Energy Department Issues Remaining $1.8 Billion in Loan Guarantees for Vogtle Advanced Nuclear Energy Project To further support the construction of two advanced nuclear reactors at the Alvin W.

  3. Eastern Interconnection Planning Collaborative News Release

    Office of Environmental Management (EM)

    1 NEWS RELEASE FOR IMMEDIATE RELEASE May 23, 2011 Contact: David Whiteley d.a.whiteley@att.net 314-753-6200 Eastern Interconnection Grid Planning Authorities to Study Set of Stakeholder-Identified Electric System Futures The Eastern Interconnection Planning Collaborative (EIPC) today announced that its diverse array of stakeholders has reached consensus on the final set of "resource expansion futures" to be studied as part of the electric system transmission planning effort funded by

  4. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 0.059-0.87 seconds at 125-155 C to evaluate effects of reaction temperature, H{sub 2}S concentration, reaction pressure, and catalyst loading on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 62-78 v% hydrogen, 3,000-7,000-ppmv hydrogen sulfide, 1,500-3,500 ppmv sulfur dioxide, and 10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 50 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the bubble reactor is maintained at 2 for all the reaction experiment runs.

  5. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2004-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 1-6 milliseconds at 125-155 C to evaluate effects of reaction temperature, moisture concentration, reaction pressure on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 70 v% hydrogen, 2,500-7,500-ppmv hydrogen sulfide, 1,250-3,750 ppmv sulfur dioxide, and 0-15 vol% moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 100 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia.

  6. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  7. Interfacial reaction dependent performance of hollow carbon nanosphere - sulfur composite as a cathode for Li-S battery

    SciTech Connect (OSTI)

    Zheng, Jianming; Yan, Pengfei; Gu, Meng; Wagner, Michael J.; Hays, Kevin A.; Chen, Junzheng; Li, Xiaohong S.; Wang, Chong M.; Zhang, Ji -Guang; Liu, Jun; Xiao, Jie

    2015-05-26

    Lithium-sulfur (Li-S) battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of challenges, such as low Coulombic efficiency and poor long-term cycling stability, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS) with highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S) which limits the reversibility of the interfacial reactions and results in poor electrochemical performance. In conclusion, these findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.

  8. Interfacial reaction dependent performance of hollow carbon nanosphere - sulfur composite as a cathode for Li-S battery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Jianming; Yan, Pengfei; Gu, Meng; Wagner, Michael J.; Hays, Kevin A.; Chen, Junzheng; Li, Xiaohong S.; Wang, Chong M.; Zhang, Ji -Guang; Liu, Jun; et al

    2015-05-26

    Lithium-sulfur (Li-S) battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of challenges, such as low Coulombic efficiency and poor long-term cycling stability, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS) withmore » highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S) which limits the reversibility of the interfacial reactions and results in poor electrochemical performance. In conclusion, these findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.« less

  9. Composition and method for storing and releasing hydrogen

    DOE Patents [OSTI]

    Thorn, David L.; Tumas, William; Ott, Kevin C.; Burrell, Anthony K.

    2010-06-15

    A chemical system for storing and releasing hydrogen utilizes an endothermic reaction that releases hydrogen coupled to an exothermic reaction to drive the process thermodynamically, or an exothermic reaction that releases hydrogen coupled to an endothermic reaction.

  10. HES Program Update and Scoring Tool v2014 Release | Department...

    Energy Savers [EERE]

    HES Program Update and Scoring Tool v2014 Release HES Program Update and Scoring Tool v2014 Release Program Update and Scoring Tool v2014 Release, a presentation from the U.S....

  11. Environmental Release Summary (ERS) database CY 1995 releases and supporting data

    SciTech Connect (OSTI)

    Gleckler, B.P., Westinghouse Hanford

    1996-08-05

    This document is a hard copy of the CY 1995 airborne and liquid effluent data contained in the Environmental Release Summary (ERS) computer database.

  12. Environmental Releases for Calendar Year 2001

    SciTech Connect (OSTI)

    DYEKMAN, D L

    2002-08-01

    This report fulfills the annual reporting requirements of US Department of Energy (DOE) Order 5400.1, General Environmental Protection Program. The report contains tabular data summaries on air emissions and liquid effluents released to the environment as well as nonroutine releases during calendar year (CY) 2001. These releases, bearing radioactive and hazardous substances, were from Bechtel Hanford, Inc. (BHI), CH2M HILL Hanford Group, Inc. (CHG), and Fluor Hanford (FH) managed facilities and activities. These data were obtained from direct sampling and analysis and from estimates based upon approved release factors. This report further serves as a supplemental resource to the Hanford Site Environmental Report (HSER PNNL-13910), published by the Pacific Northwest National Laboratory. HSER includes a yearly accounting of the impacts on the surrounding populace and environment from major activities at the Hanford Site. HSER also summarizes the regulatory compliance status of the Hanford Site. Tables ES-1 through ES-5 display comprehensive data summaries of CY2001 air emission and liquid effluent releases. The data displayed in these tables compiles the following: Radionuclide air emissions; Nonradioactive air emissions; Radionuclides in liquid effluents discharged to ground; Total volumes and flow rates of radioactive liquid effluents discharged to ground; and Radionuclides discharged to the Columbia River.

  13. Treasury, Energy Departments Release New Advanced Coal Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Treasury, Energy Departments Release New Advanced Coal Project Tax Credit Applications for 2007-2008 Treasury, Energy Departments Release New Advanced Coal Project Tax Credit...

  14. CEQ Releases Two Handbooks on Improving Efficiency of Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Releases Two Handbooks on Improving Efficiency of Federal Environmental Reviews CEQ Releases Two Handbooks on Improving Efficiency of Federal Environmental Reviews March 5, 2013 - ...

  15. DOE Releases Common Definition for Zero Energy Buildings, Campuses...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Releases Common Definition for Zero Energy Buildings, Campuses, and Communities DOE Releases Common Definition for Zero Energy Buildings, Campuses, and Communities September 16, ...

  16. Sandia Energy - Sandia Releases Open-Source Hydrokinetic Turbine...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases Open-Source Hydrokinetic Turbine Design Model, CACTUS Home Renewable Energy Energy Water Power News News & Events Computational Modeling & Simulation Sandia Releases...

  17. DOE Releases Comprehensive Report on Offshore Wind Power in the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Releases Comprehensive Report on Offshore Wind Power in the United States DOE Releases Comprehensive Report on Offshore Wind Power in the United States October 7, 2010 -...

  18. Low Temperature Heat Release Behavior of Conventional and Alternative...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Heat Release Behavior of Conventional and Alternative Fuels in a Motored Engine Low Temperature Heat Release Behavior of Conventional and Alternative Fuels in a ...

  19. DOE Street Lighting Consortium Releases Results of Public Street...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Street Lighting Consortium Releases Results of Public Street and Area Lighting Inventory Survey DOE Street Lighting Consortium Releases Results of Public Street and Area Lighting ...

  20. The Department of Energy Releases Strategy on Critical Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Department of Energy Releases Strategy on Critical Materials The Department of Energy Releases Strategy on Critical Materials December 15, 2010 - 12:00am Addthis The Department...

  1. Spatiotemporal organization of energy release events in the quiet...

    Office of Scientific and Technical Information (OSTI)

    Spatiotemporal organization of energy release events in the quiet solar corona Citation Details In-Document Search Title: Spatiotemporal organization of energy release events in ...

  2. Northeast Home Heating Oil Reserve - Guidelines for Release ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heating Oil Reserve Northeast Home Heating Oil Reserve - Guidelines for Release Northeast Home Heating Oil Reserve - Guidelines for Release The Energy Policy and Conservation ...

  3. Controlled Release from Core-Shell Nanoporous Silica Particles...

    Office of Scientific and Technical Information (OSTI)

    proved that the core-shell nanostructure delays the release process. The effective diffusion coefficient elucidated from release data for monodisperse particles in water was 1.0...

  4. Level-2 Milestone 4468: Lorenz Simulation Interface Beta Release...

    Office of Scientific and Technical Information (OSTI)

    Level-2 Milestone 4468: Lorenz Simulation Interface Beta Release Citation Details In-Document Search Title: Level-2 Milestone 4468: Lorenz Simulation Interface Beta Release You...

  5. Diffusion releases through one and two finite planar zones from...

    Office of Scientific and Technical Information (OSTI)

    Diffusion releases through one and two finite planar zones from a nuclear waste package Citation Details In-Document Search Title: Diffusion releases through one and two finite...

  6. Diffusion releases through one and two finite planar zones from...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Diffusion releases through one and two finite planar zones from a nuclear waste package Citation Details In-Document Search Title: Diffusion releases through one...

  7. Incinerator thermal release valve risk assessment

    SciTech Connect (OSTI)

    Stevens, J.B.

    1998-12-31

    Human health risk assessments were conducted on emissions from several types of incinerators--a hazardous waste combustor, a medical waste/tire combustor, and a refuse derived fuel combustor in three different states. As part of these studies, the short-term emissions from thermal release valves operating during upset conditions were additionally evaluated. The latter assessments addressed two specific risk-related questions: (1) what are the incremental long-term risks/hazards associated with these short-term emissions; (2) what are the acute health hazards associated with these emissions? For each study, emission estimates for both the incinerator stack and the thermal release valve were obtained from the facility. Stack testing was utilized to obtain stack gas concentrations of emissions at one facility; engineering estimates were used to ascertain emissions from the thermal release valve. The two facilities were proposed incinerators, so literature-derived emissions were used throughout.

  8. Environmental releases for calendar year 1994

    SciTech Connect (OSTI)

    Gleckler, B.P.

    1995-07-01

    This report fulfills the annual environmental release reporting requirements of US Department of Energy (DOE) Orders. This report provides supplemental information to the Hanford Site Environmental Report. The Hanford Site Environmental Report provides an update on the environmental status of the entire Hanford Site. The sitewide annual report summarizes the degree of compliance of the Hanford Site with applicable environmental regulations and informs the public about the impact of Hanford operations on the surrounding environment. Like the Hanford Site Environmental Report, this annual report presents a summary of the environmental releases from facilities managed by the Westinghouse Hanford Company (WHC) and monitored by Bechtel Hanford, Incorporated (BHI). In addition to the summary data, this report also includes detailed data on air emissions, liquid effluents, and hazardous substances released to the environment during calendar year 1994 from these facilities.

  9. Release Resistant Electrical Interconnections For Mems Devices

    DOE Patents [OSTI]

    Peterson, Kenneth A.; Garrett, Stephen E.; Reber, Cathleen A.

    2005-02-22

    A release resistant electrical interconnection comprising a gold-based electrical conductor compression bonded directly to a highly-doped polysilicon bonding pad in a MEMS, IMEMS, or MOEMS device, without using any intermediate layers of aluminum, titanium, solder, or conductive adhesive disposed in-between the conductor and polysilicon pad. After the initial compression bond has been formed, subsequent heat treatment of the joint above 363 C creates a liquid eutectic phase at the bondline comprising gold plus approximately 3 wt % silicon, which, upon re-solidification, significantly improves the bond strength by reforming and enhancing the initial bond. This type of electrical interconnection is resistant to chemical attack from acids used for releasing MEMS elements (HF, HCL), thereby enabling the use of a "package-first, release-second" sequence for fabricating MEMS devices. Likewise, the bond strength of an Au--Ge compression bond may be increased by forming a transient liquid eutectic phase comprising Au-12 wt % Ge.

  10. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  11. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, Mitchell R. (Troy, NY); Gal, Eli (Lititz, PA)

    1993-01-01

    A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

  12. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2006-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

  13. Temperature actuated automatic safety rod release

    DOE Patents [OSTI]

    Hutter, Ernest (Wilmette, IL); Pardini, John A. (Brookfield, IL); Walker, David E. (Naperville, IL)

    1987-01-01

    A temperature-actuated apparatus is disclosed for releasably supporting a safety rod in a nuclear reactor, comprising a safety rod upper adapter having a retention means, a drive shaft which houses the upper adapter, and a bimetallic means supported within the drive shaft and having at least one ledge which engages a retention means of the safety rod upper adapter. A pre-determined increase in temperature causes the bimetallic means to deform so that the ledge disengages from the retention means, whereby the bimetallic means releases the safety rod into the core of the reactor.

  14. NERSC Releases Mobile Apps to Users

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases Mobile Apps to Users NERSC Releases Mobile Apps to Users Job Status, MOTD and Pilot of VASP Submission Available with More to Come April 23, 2012 In an effort to make NERSC resources more accessible to its users, the facility is rolling out a number of applications that allow researchers to access scientific data on their web browsers, tablets and smart phones. This month, NERSC announced two new applications now available to its users: The NERSC mobile user portal (http://m.nersc.gov)

  15. Helium Release Behavior of Aged Titanium Tritides

    SciTech Connect (OSTI)

    SHANAHAN, KIRKL.

    2004-07-27

    One sample of bulk Ti has been loaded with a 50 per cent / 50 per cent deuterium/tritium mixture and statically aged for 6.5 years. Thermal desorption of the sample shows an initial release of hydrogen isotopes followed by 3He release. Subsequent D2 loading/desorption was used to quantify the trapped tritium heel. The sample shows an excess hydrogen capacity as a second thermal desorption peak that partially disappears and shifts with annealing at 923-973K. The main hydrogen desorption peak also shifts to higher temperature, indicating a partial reversal of the tritium-decay induced damage by annealing.

  16. Xyce parallel electronic simulator release notes.

    SciTech Connect (OSTI)

    Keiter, Eric Richard; Hoekstra, Robert John; Mei, Ting; Russo, Thomas V.; Schiek, Richard Louis; Thornquist, Heidi K.; Rankin, Eric Lamont; Coffey, Todd Stirling; Pawlowski, Roger Patrick; Santarelli, Keith R.

    2010-05-01

    The Xyce Parallel Electronic Simulator has been written to support, in a rigorous manner, the simulation needs of the Sandia National Laboratories electrical designers. Specific requirements include, among others, the ability to solve extremely large circuit problems by supporting large-scale parallel computing platforms, improved numerical performance and object-oriented code design and implementation. The Xyce release notes describe: Hardware and software requirements New features and enhancements Any defects fixed since the last release Current known defects and defect workarounds For up-to-date information not available at the time these notes were produced, please visit the Xyce web page at http://www.cs.sandia.gov/xyce.

  17. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8, 2011 [Feature Stories and Releases] The World's Largest Radar Laboratory Bookmark and Share New suite of scanning radars document life and death of clouds For Immediate Release: Thursday, December 8, 2011 Deployed in pairs, the new scanning cloud radars share a common pedestal and can scan 180 degrees in every direction. To see the radars in motion, view <a href='http://www.youtube.com/watch?v=137V1cczMt4\'>this video</a>. Deployed in pairs, the new scanning cloud radars share a

  18. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 20, 2013 [Feature Stories and Releases] Taking the Heat in the U.S. Great Plains Bookmark and Share When the National Weather Service released their predictions for the summer of 2013, it was difficult to miss the zone of warm colors centered over the U.S. Great Plains. Higher than average temperatures are expected in this part of the country. This comes as no surprise, especially after Oklahoma registered record-breaking heat last summer. Scientists have known for some time now that ground

  19. Heat release analysis of engine pressure data

    SciTech Connect (OSTI)

    Gatowski, J.A.; Balles, E.N.; Chun, K.M.; Nelson, F.E.; Ekchian, J.A.; Heywood, J.B.

    1984-01-01

    In analyzing the processes inside the cylinder of an internal combustion engine, the principal diagnostic at the experimenter's disposal is a measured time history of the cylinder pressure. This paper develops, tests, and applies a heat release analysis procedure that maintains simplicity while including the effects of heat transfer, crevice flows and fuel injection. The heat release model uses a one zone description of the cylinder contents with thermodynamic properties represented by a linear approximation. Applications of the analysis to a single-cylinder spark-ignition engine, a special square cross-section visualization spark-ignition engine, and a direct-injection stratified charge engine are presented.

  20. Temperature actuated automatic safety rod release

    DOE Patents [OSTI]

    Hutter, E.; Pardini, J.A.; Walker, D.E.

    1984-03-13

    A temperature-actuated apparatus is disclosed for releasably supporting a safety rod in a nuclear reactor, comprising a safety rod upper adapter having a retention means, a drive shaft which houses the upper adapter, and a bimetallic means supported within the drive shaft and having at least one ledge which engages a retention means of the safety rod upper adapter. A pre-determined increase in temperature causes the bimetallic means to deform so that the ledge disengages from the retention means, whereby the bimetallic means releases the safety rod into the core of the reactor.

  1. EPICS release 3.11 specific documentation -- EPICS release notes for 3.11

    SciTech Connect (OSTI)

    1994-01-19

    EPICS release 3.11 is now ready for user testing. A person who wants to set up a simplified application environment to boot an IOC and create databases using R3.11 should follow the directions in Appendix B, page 27, of the EPICS Source/Release Control Manual, Sept. 20, 1993. The R3.11 EPICS path at ANL/APS is /net/phebos/epics/R3.11 so the command to get the new release is /net/phebos/epics/R3.11/Unix/share/bin/getrel /net/phebos/epics/R3.11. An existing R3.8 short form report can be copied to this new directory and used to create a database. ANL/APS is currently testing an Application Developers Source/Release control system. It is not yet ready for general distribution. Attached are the EPICS R3.11 release notes.

  2. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  3. Sulfurization behavior of cerium doped uranium oxides by CS{sub 2}

    SciTech Connect (OSTI)

    Sato, Nobuaki; Kato, Shintaro; Kirishima, Akira; Tochiyama, Osamu

    2007-07-01

    For the recovery of nuclear materials from the spent nuclear fuel, the sulfide process has been proposed and the voloxidation of spent fuel and selective sulfurization rare-earth elements has been proposed. In this paper, cerium was used as a stand-in of plutonium and sulfurization behavior of cerium doped uranium dioxide by CS{sub 2} was studied. UO{sub 2} was oxidized to U{sub 3}O{sub 8} in air, while the Ce doped UO{sub 2} solid solution was formed in the presence of CeO{sub 2} by the heat treatment in air. The effect of heating time, temperature and the ratio of uranium to cerium on the formation of solid solution was analyzed. The results were also compared with those of thermodynamic consideration. (authors)

  4. Sodium/sulfur battery engineering for stationary energy storage. Final report

    SciTech Connect (OSTI)

    Koenig, A.; Rasmussen, J.

    1996-04-01

    The use of modular systems to distribute power using batteries to store off-peak energy and a state of the art power inverter is envisioned to offer important national benefits. A 4-year, cost- shared contract was performed to design and develop a modular, 300kVA/300-kWh system for utility and customer applications. Called Nas-P{sub AC}, this system uses advanced sodium/sulfur batteries and requires only about 20% of the space of a lead-acid-based system with a smaller energy content. Ten, 300-VDC, 40-kWh sodium/sulfur battery packs are accommodated behind a power conversion system envelope with integrated digital control. The resulting design facilities transportation, site selection, and deployment because the system is quiet and non-polluting, and can be located in proximity to the load. This report contains a detailed description of the design and supporting hardware development performed under this contract.

  5. ZnO-based regenerable sulfur sorbents for fluid-bed/transport reactor applications

    DOE Patents [OSTI]

    Slimane, Rachid B.; Abbasian, Javad; Williams, Brett E.

    2004-09-21

    A method for producing regenerable sulfur sorbents in which a support material precursor is mixed with isopropanol and a first portion of deionized water at an elevated temperature to form a sol mixture. A metal oxide precursor comprising a metal suitable for use as a sulfur sorbent is dissolved in a second portion of deionized water, forming a metal salt solution. The metal salt solution and the sol mixture are mixed with a sol peptizing agent while heating and stirring, resulting in formation of a peptized sol mixture. The metal oxide precursor is dispersed substantially throughout the peptized sol mixture, which is then dried, forming a dry peptized sol mixture. The dry peptized sol mixture is then calcined and the resulting calcined material is then converted to particles.

  6. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, Krishnamurti (Naperville, IL)

    1992-01-01

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

  7. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  8. Effects on crystal structure of CZTS thin films owing to deionized water and sulfurization treatment

    SciTech Connect (OSTI)

    Nadi, Samia Ahmed; Chelvanathan, Puvaneswaran; Islam, M. A.; Sopian, Kamruzzaman; Yusoff, Yulisa; Amin, Nowshad

    2015-05-15

    To condense the cost and increase the production, using abundantly obtainable non-toxic elements, Cu{sub 2}ZnSnS{sub 4} (CZTS) seem to be a strong contender among the photovoltaic thin film technologies. Cu{sub 2}ZnSnS{sub 4} thin films were fabricated by RF magnetron sputtering system. CZTS were sputtered on Molybdenum (Mo) coated soda lime glass (SLG) using a single target sputtering technique. The sputtering parameters (base pressure, working pressure, Argon (Ar) flow rate, RF power and sputtering time) were kept same for all three types of films. For sulfurization, the temperature used was 500 C. Finally, As-deposited film was immersed in DIW before undergoing identical sulfurization profile. As-deposited film (Sample A), sulfurized films (Sample B) and sulfurized plus DIW treated (Sample C) were compared in terms of their structural properties by means of X-Ray Diffraction (XRD) measurement and Atomic Force Microscopy (AFM). Sample B and C showed peak of (1 1 2) planes of CZTS which are characteristics of stannite structure. Post deposition treatment on CZTS films proved to be beneficial as evident from the observed enhancement in the crystallinity and grain growth. Significant difference on grain size and area roughness could be observed from the AFM measurement. The roughness of Sample A, B and C increased from 5.007?nm to 20.509?nm and 14.183?nm accordingly. From XRD data secondary phases of Cu{sub x}MoS{sub x} could be observed.

  9. COS-forming reaction between CO and sulfur: A high-temperature intrinsic kinetics study

    SciTech Connect (OSTI)

    Karan, K.; Mehrotra, A.K.; Behie, L.A. [Univ. of Calgary, Alberta (Canada). Dept. of Chemical and Petroleum Engineering] [Univ. of Calgary, Alberta (Canada). Dept. of Chemical and Petroleum Engineering

    1998-12-01

    Carbonyl sulfide is formed in the front end (i.e., the reaction furnace and the waste heat boiler) of Claus plants which are commonly used to recover sulfur from acid gases. Moreover, COS along with CS{sub 2}, are recognized as the problematic sulfur compounds that contribute significantly to plant sulfur emissions. Further, there is limited kinetic information on the important reaction for the formation of these two compounds. Now, it is well-known that one of the important COS-forming reactions is that between CO and sulfur. In this laboratory, the authors conducted an experimental study to measure the intrinsic kinetics of this homogeneous gas-phase reaction in the temperature range of 600--1150 C and over a residence time of 0.5--2.0 s. The overall reaction was found to be second order with a reaction rate constant k{sub f} = (3.18 {+-} 0.36) {times} 10{sup 5} exp[{minus}(6700 {+-} 108 K)/T] m{sup 3}/(kmol{center_dot}s). In addition, a kinetic model was developed to account for both the COS formation and the COS decomposition reactions. And, finally, for the reverse reaction, the COS decomposition reaction rate constant (k{sub r}) was regressed to match the equilibrium data of experiments at high temperatures giving a second-order reaction rate constant as k{sub r} = (2.18 {+-} 1.12) {times} 10{sup 9} exp[{minus}(21630 {+-} 160 K)/T] m{sup 3}/(kmol{center_dot}s).

  10. Aqueous process for recovering sulfur from hydrogen sulfide-bearing gas

    DOE Patents [OSTI]

    Basu, Arunabha

    2015-05-05

    A process for recovering sulfur from a hydrogen sulfide-bearing gas utilizes an aqueous reaction medium, a temperature of about 110-150.degree. C., and a high enough pressure to maintain the aqueous reaction medium in a liquid state. The process reduces material and equipment costs and addresses the environmental disadvantages associated with known processes that rely on high boiling point organic solvents.

  11. Hybrid sulfur cycle operation for high-temperature gas-cooled reactors

    DOE Patents [OSTI]

    Gorensek, Maximilian B

    2015-02-17

    A hybrid sulfur (HyS) cycle process for the production of hydrogen is provided. The process uses a proton exchange membrane (PEM) SO.sub.2-depolarized electrolyzer (SDE) for the low-temperature, electrochemical reaction step and a bayonet reactor for the high-temperature decomposition step The process can be operated at lower temperature and pressure ranges while still providing an overall energy efficient cycle process.

  12. Evaluation of an enhanced gravity-based fine-coal circuit for high-sulfur coal

    SciTech Connect (OSTI)

    Mohanty, M.K.; Samal, A.R.; Palit, A.

    2008-02-15

    One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m{sup 2}, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The 'linear screen + enhanced gravity separator + screen-bowl circuit' provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61 %, respectively.

  13. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1999-06-22

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  14. HYBRID SULFUR FLOWSHEETS USING PEM ELECTROLYSIS AND A BAYONET DECOMPOSITION REACTOR

    SciTech Connect (OSTI)

    Gorensek, M; William Summers, W

    2008-05-30

    A conceptual design is presented for a Hybrid Sulfur process for the production of hydrogen using a high-temperature nuclear heat source to split water. The process combines proton exchange membrane-based SO{sub 2}-depolarized electrolyzer technology being developed at Savannah River National Laboratory with silicon carbide bayonet decomposition reactor technology being developed at Sandia National Laboratories. Both are part of the US DOE Nuclear Hydrogen Initiative. The flowsheet otherwise uses only proven chemical process components. Electrolyzer product is concentrated from 50 wt% sulfuric acid to 75 wt% via recuperative vacuum distillation. Pinch analysis is used to predict the high-temperature heat requirement for sulfuric acid decomposition. An Aspen Plus{trademark} model of the flowsheet indicates 340.3 kJ high-temperature heat, 75.5 kJ low-temperature heat, 1.31 kJ low-pressure steam, and 120.9 kJ electric power are consumed per mole of H{sub 2} product, giving an LHV efficiency of 35.3% (41.7% HHV efficiency) if electric power is available at a conversion efficiency of 45%.

  15. Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge

    SciTech Connect (OSTI)

    Wang, Bin; Alhassan, Saeed M.; Pantelides, Sokrates T

    2014-01-01

    Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

  16. Influence of sulfur and welding conditions on penetration in thin strip stainless steel

    SciTech Connect (OSTI)

    Scheller, P.R. ); Brooks, R.F.; Mills, K.C. . Division of Materials Metrology)

    1995-02-01

    Welding trials and surface tension measurements have been carried out on 304 stainless steels with sulfur (S) contents between 20 and 100 ppm. Surface tension measurements, determined by the levitated drop method, indicated that the temperature coefficient of surface tension (d[gamma]/dT) changed from negative to positive values at S contents exceeding approximately 50 ppm. Strips with a thickness of approximately 1 mm were GTA welded on both single-electrode, small-scale and multi-electrode industrial-scale units. Welding speeds of 1 to 2 m min[sup [minus]1] were used on the small-scale unit and up to 5 m min[sup [minus]1] on the industrial unit. The weld penetration was found to increase, for both full and partial penetration welds, with (1) increasing sulfur contents; and (2) increasing linear energy. On the small scale-unit markedly higher penetration was observed in heats with S contents > 60 ppm. But the influence of S contents was only of minor importance for welds obtained on the industrial unit. It was found that the similar weld geometry could be obtained for both low ([<=] 60 ppm) and high (> 60 ppm) sulfur contents by careful adjustment of welding parameters. The observed changes in weld geometry are consistent with the proposition that the fluid flow in the weld pool is dominated by thermo-capillary (Marangoni) forces during the GTA welding of thin strips.

  17. Fast-regenerable sulfur dioxide absorbents for lean-burn diesel engine emission control

    SciTech Connect (OSTI)

    Li, Liyu; King, David L.

    2010-01-23

    It is known that sulfur oxides contribute significantly and deleteriously to the overall performance of lean-burn diesel engine aftertreatment systems, especially in the case of NOx traps. A Ag-based, fast regenerable SO2 absorbent has been developed and will be described. Over a temperature range of 300oC to 550oC, it absorbs almost all of the SO2 in the simulated exhaust gases during the lean cycles and can be fully regenerated by the short rich cycles at the same temperature. Its composition has been optimized as 1 wt% Pt-5wt%Ag-SiO2, and the preferred silica source for the supporting material has been identified as inert Cabosil fumed silica. The thermal instability of Ag2O under fuel-lean conditions at 230oC and above makes it possible to fast regenerate the sulfur-loaded absorbent during the following fuel-rich cycles. Pt catalyst helps reducing Ag2SO4 during rich cycles at low temperatures. And the chemically inert fumed SiO2 support gives the absorbent long term stability. This absorbent shows great potential to work under the same lean-rich cycling conditions as those imposed on the NOx traps, and thus, can protect the downstream particulate filter and the NOx trap from sulfur poisoning.

  18. Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.; Hawk, Jeffrey A.

    2005-01-01

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 C to ~750 C may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

  19. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, George (Lafayette, CA); Orr, Thomas Robert (Castro Valley, CA); Greene, Charles Maurice (Oakland, CA); Crawford, Douglas Gordon (Orinda, CA); Berman, Samuel Maurice (San Francisco, CA)

    1999-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  20. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1998-10-20

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  1. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, George (820 Skywood Rd., Lafayette, CA 94549); Orr, Thomas Robert (2285 Vestal, Castro Valley, CA 94546); Greene, Charles Maurice (6450 Regent St., Oakland, CA 94618); Crawford, Douglas Gordon (33 Longridge Rd., Orinda, CA 94563); Berman, Samuel Maurice (2832 Union St., San Francisco, CA 94123)

    1998-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  2. A class of polysulfide catholytes for lithium-sulfur batteries: energy density, cyclability, and voltage enhancement

    SciTech Connect (OSTI)

    Yu, XW; Manthiram, A

    2015-01-01

    Liquid-phase polysulfide catholytes are attracting much attention in lithium-sulfur (Li-S) batteries as they provide a facile dispersion and homogeneous distribution of the sulfur active material in the conductive matrix. However, the organic solvents used in lithium-polysulfide (Li-PS) batteries play an important role and have an impact on the physico-chemical characteristics of polysulfides. For instance, significantly higher voltages (similar to 2.7 V) of the S/S-n(2-) (4 <= n <= 8) redox couple are observed in Li-PS batteries with dimethyl sulfoxide (DMSO) and N-methyl-2-pyrrolidone (NMP) solvents. Accordingly, high power Li-PS batteries are presented here with the catholyte prepared with NMP solvent and operated with the highly reversible sulfur/long-chain polysulfide redox couple. On the other hand, a remarkable cyclability enhancement of the Li-PS battery is observed with the long-chain, ether-based tetraglyme (TEGDME) solvent. The voltage enhancement and the cyclability enhancement of the Li-PS batteries are attributed to the solvation effect, viscosity, and volatility of the solvents. Finally, highly concentrated polysulfide catholytes are successfully synthesized, with which high energy density Li-PS batteries are demonstrated by employing a multi-walled carbon nanotube (MWCNT) fabric electrode.

  3. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  4. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  5. NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance

    SciTech Connect (OSTI)

    Rangan, M.; Yung, M. M.; Medlin, J. W.

    2012-06-01

    Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

  6. Airborne measurements of total sulfur gases during NASA global tropospheric experiment/chemical instrumentation test and evaluation 3

    SciTech Connect (OSTI)

    Farwell, S.O.; MacTaggart, D.L.; Chatham, W.H.

    1995-04-20

    A metal foil collection/flash desorption/flame photometric detection (MFC/FD/FPD) technique was used by investigators from the University of Idaho (UI) to measure ambient total sulfur gas concentrations from an aircraft platform during the NASA Global Tropospheric Experiment/Chemical Instrumentation Test and Evaluation 3 (GTE/CITE 3) program. The MFC/FD/FPD technique allowed rapid quantitation of tropospheric background air masses using sample integration times of 1-3 min with little or no gap between measurements. The rapid and continual sampling nature of this technique yielded data covering approximately 75% of the entire CITE 3 program`s air track. Ambient air measurement data obtained during northern hemisphere (NH) flights often exhibited relatively high total sulfur gas values (up to 19 ppb) and an extremely high degree of sample heterogeneity, especially in coastal locations. Data from southern hemisphere (SH) flights typically exhibited relatively low total sulfur gas concentrations and a low degree of sample heterogeneity. A bimodal interhemispheric total sulfur gas gradient was observed using data obtained during transit flights between the two CITE 3 program ground bases. Comparisons were made of UI total sulfur gas measurements with composite sulfur gas values generated using speciated sulfur gas measurements from other CITE 3 participants. Only a relatively small number of overlap periods for comparison were obtained from all the available CITE 3 data because of large differences in measurement integration times and lack of synchronization of sample start/stop times for the various investigators. These effects were compounded with extreme sample heterogeneity in the NH and the speed at which the aircraft traversed the air masses being sampled. Comparison of NH UI total with composite sulfur gas values showed excellent correlation and linear curve fit, indicating substantial qualitative agreement. 20 refs., 10 figs., 7 tabs.

  7. Passive ice freezing-releasing heat pipe

    DOE Patents [OSTI]

    Gorski, Anthony J. (Lemont, IL); Schertz, William W. (Batavia, IL)

    1982-01-01

    A heat pipe device has been developed which permits completely passive ice formation and periodic release of ice without requiring the ambient temperature to rise above the melting point of water. This passive design enables the maximum amount of cooling capacity to be stored in the tank.

  8. Hydrogen Release from Simulated Sludge and Saltcake

    SciTech Connect (OSTI)

    Peterson, R.A.

    1999-01-05

    This report describes the results of the Savannah River Technology Center (SRTC) program to address bubble gas release potential as requested by Concentration, Storage and Transfer Engineering. Researchers from the Waste Processing Technology Section (WPTS) and Immobilization Technology Section (ITS) contributed to the results presented.

  9. Historical Document Released for Public Availability

    Office of Scientific and Technical Information (OSTI)

    Released 1994 Prepared for the U.S. Department of Energy under C o n t r a c t DE-AC06-76RlQ 1830 Pacific Northwest laboratory Operated for the U.S Department of Energy by Battelle ...

  10. 2014 Vehicle Technologies Market Report Released

    Broader source: Energy.gov [DOE]

    Oak Ridge National Laboratory recently released the Vehicle Technologies Market Report, which details the past years major trends in light-, medium-, and heavy-duty car and truck markets as well as patterns in the underlying economic and transportation systems. The report specifically focuses on developments in high-efficiency and alternative-fuel vehicle technologies over the course of 2014.

  11. Involuntary Separation Program General Release and Waiver | Department of

    Energy Savers [EERE]

    Energy Program General Release and Waiver Involuntary Separation Program General Release and Waiver PDF icon Attachment 9 - Involuntary Separation Program General Release and Waiver More Documents & Publications Separation Programs Releases and Waivers Workforce Restructuring Policy AFGE Local 928

  12. Hybridization and Selective Release of DNA Microarrays

    SciTech Connect (OSTI)

    Beer, N R; Baker, B; Piggott, T; Maberry, S; Hara, C M; DeOtte, J; Benett, W; Mukerjee, E; Dzenitis, J; Wheeler, E K

    2011-11-29

    DNA microarrays contain sequence specific probes arrayed in distinct spots numbering from 10,000 to over 1,000,000, depending on the platform. This tremendous degree of multiplexing gives microarrays great potential for environmental background sampling, broad-spectrum clinical monitoring, and continuous biological threat detection. In practice, their use in these applications is not common due to limited information content, long processing times, and high cost. The work focused on characterizing the phenomena of microarray hybridization and selective release that will allow these limitations to be addressed. This will revolutionize the ways that microarrays can be used for LLNL's Global Security missions. The goals of this project were two-fold: automated faster hybridizations and selective release of hybridized features. The first study area involves hybridization kinetics and mass-transfer effects. the standard hybridization protocol uses an overnight incubation to achieve the best possible signal for any sample type, as well as for convenience in manual processing. There is potential to significantly shorten this time based on better understanding and control of the rate-limiting processes and knowledge of the progress of the hybridization. In the hybridization work, a custom microarray flow cell was used to manipulate the chemical and thermal environment of the array and autonomously image the changes over time during hybridization. The second study area is selective release. Microarrays easily generate hybridization patterns and signatures, but there is still an unmet need for methodologies enabling rapid and selective analysis of these patterns and signatures. Detailed analysis of individual spots by subsequent sequencing could potentially yield significant information for rapidly mutating and emerging (or deliberately engineered) pathogens. In the selective release work, optical energy deposition with coherent light quickly provides the thermal energy to single spots to release hybridized DNA. This work leverages LLNL expertise in optics, microfluids, and bioinformatics.

  13. FISCAL YEAR 2006 REPORT ON ELECTROLYZER COMPONENT DEVELOPMENT FOR THE HYBRID SULFUR PROJECT

    SciTech Connect (OSTI)

    Colon-Mercado, H; David Hobbs, D; Daryl Coleman, D; Amy Ekechukwu, A

    2006-08-03

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In FY05, testing at the Savannah River National Laboratory (SRNL) explored a low temperature fuel cell design concept for the SDE. The advantages of this design concept include high electrochemical efficiency and small volumetric footprint that is crucial for successful implementation on a commercial scale. A key component of the SDE is the ion conductive membrane through which protons produced at anode migrate to the cathode and react to produce hydrogen. An ideal membrane for the SDE should have both low ionic resistivity and low sulfur dioxide transport. These features allow the electrolyzer to perform at high currents with low potentials, along with preventing contamination of both the hydrogen output and poisoning of the catalysts involved. Another key component is the electrocatalyst material used for the anode and cathode. Good electrocatalysts should be chemically stable and low overpotential for the desired electrochemical reactions. This report summarizes results from activities to evaluate different membrane and electrocatalyst materials for the SDE. Several different types of commercially-available membranes were analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid, sulfonated poly-etherketone-ketone, and poly-benzimidazole membranes. Of these membrane types, the poly-benzimidazole (PBI) membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Testing examined the activity and stability of platinum and palladium as electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by concentration of the sulfuric acid. Various cell configurations were examined with respect to the deposition of electrocatalyst and use of conductive carbon materials such as carbon cloth and carbon paper. Findings from these evaluations and the results of the membrane and electrocatalyst testing, we prepared three different membrane electrode assemblies (MEA) for electrolyzer testing. The first MEA consisted of a Nafion{reg_sign} membrane with platinum electrocatalyst deposited on carbon cloths, which were heat pressed onto the membrane, an assembly identical to those used in proton exchange membrane fuel cells. The second MEA also used a Nafion membrane with the electrocatalysts deposited directly onto the membrane. The third MEA proved similar to the second but utilized a PBI membrane in place of the Nafion{reg_sign} membrane. Tailor of the membrane and catalysts properties for the SDE system was concluded as a required step for the technology to move forward. It was also recommended the evaluation of the tested and new developed materials at conditions closer to the SDE operating conditions and for longer period of time.

  14. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

  15. Deep Sludge Gas Release Event Analytical Evaluation

    SciTech Connect (OSTI)

    Sams, Terry L.

    2013-08-15

    Long Abstract. Full Text. The purpose of the Deep Sludge Gas Release Event Analytical Evaluation (DSGRE-AE) is to evaluate the postulated hypothesis that a hydrogen GRE may occur in Hanford tanks containing waste sludges at levels greater than previously experienced. There is a need to understand gas retention and release hazards in sludge beds which are 200 -300 inches deep. These sludge beds are deeper than historical Hanford sludge waste beds, and are created when waste is retrieved from older single-shell tanks (SST) and transferred to newer double-shell tanks (DST).Retrieval of waste from SSTs reduces the risk to the environment from leakage or potential leakage of waste into the ground from these tanks. However, the possibility of an energetic event (flammable gas accident) in the retrieval receiver DST is worse than slow leakage. Lines of inquiry, therefore, are (1) can sludge waste be stored safely in deep beds; (2) can gas release events (GRE) be prevented by periodically degassing the sludge (e.g., mixer pump); or (3) does the retrieval strategy need to be altered to limit sludge bed height by retrieving into additional DSTs? The scope of this effort is to provide expert advice on whether or not to move forward with the generation of deep beds of sludge through retrieval of C-Farm tanks. Evaluation of possible mitigation methods (e.g., using mixer pumps to release gas, retrieving into an additional DST) are being evaluated by a second team and are not discussed in this report. While available data and engineering judgment indicate that increased gas retention (retained gas fraction) in DST sludge at depths resulting from the completion of SST 241-C Tank Farm retrievals is not expected and, even if gas releases were to occur, they would be small and local, a positive USQ was declared (Occurrence Report EM-RP--WRPS-TANKFARM-2012-0014, "Potential Exists for a Large Spontaneous Gas Release Event in Deep Settled Waste Sludge"). The purpose of this technical report is to (1) present and discuss current understandings of gas retention and release mechanisms for deep sludge in U.S. Department of Energy (DOE) complex waste storage tanks; and (2) to identify viable methods/criteria for demonstrating safety relative to deep sludge gas release events (DSGRE) in the near term to support the Hanford C-Farm retrieval mission. A secondary purpose is to identify viable methods/criteria for demonstrating safety relative to DSGREs in the longer term to support the mission to retrieve waste from the Hanford Tank Farms and deliver it to the Waste Treatment and Immobilization Plant (WTP). The potential DSGRE issue resulted in the declaration of a positive Unreviewed Safety Question (USQ). C-Farm retrievals are currently proceeding under a Justification for Continued Operation (JCO) that only allows tanks 241-AN-101 and 241-AN-106 sludge levels of 192 inches and 195 inches, respectively. C-Farm retrievals need deeper sludge levels (approximately 310 inches in 241-AN-101 and approximately 250 inches in 241-AN-106). This effort is to provide analytical data and justification to continue retrievals in a safe and efficient manner.

  16. Sandia Labs releases wavelet variability model (WVM)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    releases wavelet variability model (WVM) - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  17. SAND2011-3779 Unlimited Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11-3779 Unlimited Release Printed June 2011 THE SANDIA 100-METER ALL-GLASS BASELINE WIND TURBINE BLADE: SNL100-00 D. Todd Griffith Analytical Structural Dynamics Department Thomas D. Ashwill Wind Energy Technologies Department Sandia National Laboratories P.O. Box 5800 Albuquerque, New Mexico 87185-0557 Abstract Sandia National Laboratories (SNL) Wind Energy Technologies Department, as part of its ongoing R&D efforts, creates and evaluates innovative large blade concepts for horizontal axis

  18. Approved for Public Release; Further Dissemination Unlimited

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8:22 am, Feb 24, 2015 Approved for Public Release; Further Dissemination Unlimited J. A. Ciucci President and Chief Executive Officer January 2015 CHPRC-2015-01, Revision 0 Monthly Performance Report U.S. Department of Energy Contract, DE-AC06-08RL14788 Deliverable C.3.1.3.1 - 1 1 CHPRC-2015-01, Rev. 0 * Overview CHPRC Monthly Performance Report January 2015 CONTENTS EXECUTIVE SUMMARY ..............................................................................................................2

  19. HIPAA Authorization for Release of Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HIPAA AUTHORIZATION FOR RELEASE OF INFORMATION I. Information about the Use or Disclosure I hereby authorize the use and disclosure of protected health information as described below. Patient's full name: Date of Birth: Persons/organizations (or class of persons/organizations) authorized to use and disclose the information: Argonne National Laboratory Employee Benefits Department Persons/organizations (or class of persons/organizations) authorized to receive and use the information: Specific

  20. Hometown News Release | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hometown News Release October 3, 2014 NETL Researcher Honored with 2014 FLC Mid-Atlantic Regional STEM Award Dr. Kirk Gerdes of the National Energy Technology Laboratory (NETL) has been awarded a 2014 FLC Mid-Atlantic Regional STEM Award for his work furthering NETL's STEM education efforts in West Virginia. October 3, 2014 NETL Outreach Specialist Honored with 2014 FLC Mid-Atlantic Regional STEM Award Lilas Soukup of the National Energy Technology Laboratory (NETL) has been awarded a 2014 FLC

  1. NEWS MEDIA CONTACT: FOR IMMEDIATE RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FOR IMMEDIATE RELEASE Craig Stevens, (202) 586-4940 Wednesday, March 29, 2006 DOE Waste Isolation Pilot Plant Receives EPA Recertification CARLSBAD, N.M - The U.S. Department of Energy's (DOE) Carlsbad Field Office today reached a significant milestone when its Waste Isolation Pilot Plant (WIPP) was recertified by the U.S. Environmental Protection Agency (EPA). This decision indicates that after a thorough evaluation of the physical state and performance of the facility, the WIPP meets EPA

  2. NREL: Biomass Research - News Release Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    09 November 5, 2009 NREL's Clean Energy Forum Attracts National Investment Community The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) 22nd Clean Energy Industry Growth Forum this week attracted nearly 600 investors, entrepreneurs, scientists and policymakers to Denver. October 13, 2009 Web Portal Makes Finding Ways to Drive Green Even Easier The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) has released a convenient online directory of

  3. NEWS MEDIA CONTACT FOR IMMEDIATE RELEASE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CONTACT FOR IMMEDIATE RELEASE Craig Stevens, (202) 586-4940 Tuesday, December 19, 2006 U.S and Russia Develop Action Plan to Enhance Global and Bilateral Nuclear Energy Cooperation WASHINGTON, DC - U.S. Secretary of Energy Samuel W. Bodman and Russian Federal Atomic Energy Agency (Rosatom) Director Sergey V. Kiriyenko last week submitted to U.S. President George W. Bush and Russian President Vladimir Putin a joint work plan that will provide a framework for further bilateral cooperation in the

  4. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 26, 2007 [Feature Stories and Releases] Arctic Winter Provides Window of Opportunity to Improve Climate Models Bookmark and Share Dry winter conditions allows scientists to explore elusive portions of the electromagnetic spectrum Contact: Lynne Roeder, 509.372.4331 In conjunction with other scientific activities taking place during International Polar Year 2007-2008, today an international research team begins a three-week field campaign in Barrow, Alaska. The experiment, which is

  5. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 16, 2010 [Feature Stories and Releases] Future Field Campaigns Span Atlantic Ocean to Indian Ocean Bookmark and Share Each year, the ARM Climate Research Facility reviews proposals to use key components of the Facility for extended field campaigns. The Department of Energy recently announced the selection of major ARM field campaigns that will take place from 2011 through 2014. Studies led by principal investigators Chuck Long, Carl Berkowitz, and Scot Martin will examine atmospheric

  6. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 7, 2010 [Feature Stories and Releases] User Facility Highlights at 2010 AGU Fall Meeting Bookmark and Share Scientists from around the world use data from the U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) Climate Research Facility to study the interactions between clouds, aerosol, and radiation. At this year's American Geophysical Union (AGU) Fall Meeting, ARM's scientific users are presenting dozens of oral and poster sessions describing their research using data

  7. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 12, 2006 [Feature Stories and Releases] U.S. Climate Scientists Join Collaborators in Australia to Begin Tropical Cloud Experiment Bookmark and Share Media Advisory Media Contact: Lynne Roeder, 509.372.4331 More than 100 researchers from around the world are gathering in Darwin, Australia, as they prepare to launch simultaneous ground, sea and sky operations during the Tropical Warm Pool International Cloud Experiment. The experiment, organized jointly by the U.S. Department of Energy

  8. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2005 [Feature Stories and Releases] Climate Scientists Gather at Sandia National Laboratories to Simulate Tropical Cloud Experiment Bookmark and Share Media Advisory Media Contact: Lynne Roeder, 509.372.4331 Technical Contact: Mike Janes, 925.294.2447 The ARM Program-the Department of Energy's largest global change research program-was created to help resolve scientific uncertainties related to global climate change. Its specific focus is on the crucial role of clouds and their influence on

  9. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facility News, Feature Stories and Releases] Mobile Facility Anchors U.S.-India Collaboration for Cloud-Aerosol Studies Bookmark and Share In early June, installation of the ARM Mobile Facility instrument suite is underway at the ARIES Observatory in Nainital, India. In early June, installation of the ARM Mobile Facility instrument suite is underway at the ARIES Observatory in Nainital, India. The past few decades have seen rapid increases in economic activity in many Asian countries. This is

  10. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    28, 2011 [Feature Stories and Releases] Storm Study in Oklahoma Records Extreme Weather Events Bookmark and Share During MC3E, convective clouds like these were measured by NASA research aircraft and numerous radars throughout the ARM Southern Great Plains site, including these radars at the SGP Central Facility. During MC3E, convective clouds like these were measured by NASA research aircraft and numerous radars throughout the ARM Southern Great Plains site, including these radars at the SGP

  11. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 28, 2011 [Facility News, Feature Stories and Releases, Publications] Pass the lotion; new study shows drying trend over Great Plains Bookmark and Share Analysis of infrared energy levels useful for similar evaluations at local scale Illustration of seasonal infrared energy trends observed at the ARM Southern Great Plains site between 1996 and 2010. Click on image to enlarge. Illustration of seasonal infrared energy trends observed at the ARM Southern Great Plains site between 1996 and

  12. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 4, 2004 [Feature Stories and Releases] Media Advisory: New Climate Education Resource Available Online for Teachers and Students Bookmark and Share Media Contact: Lynne Roeder, 509.372.4331 Technical Contact: Andrea Maestas, 505.665.7997 LOS ALAMOS, N.M.-A newly designed education website sponsored by the U.S. Department of Energy (DOE) features activities and information about climate change and atmospheric science for students and teachers. Education and outreach staff involved in

  13. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 14, 2011 [Feature Stories and Releases] New Study Reveals and Quantifies Magnitude of Long-term Aerosol Effects on Clouds and Precipitation Bookmark and Share Cloud radars measure an incoming storm at the ARM Southern Great Plains site in Oklahoma. Cloud radars measure an incoming storm at the ARM Southern Great Plains site in Oklahoma. 10 years of data from ARM Southern Great Plains site corroborate satellite measurements; match model A study published in Nature Geoscience this week

  14. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2011 [Feature Stories and Releases] User Facility Highlights at AGU 2011 Fall Meeting Bookmark and Share Researchers around the world use data from the U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) Climate Research Facility to study the interactions between clouds, aerosols, and radiation. At this year's American Geophysical Union Fall Meeting, ARM's scientific users are presenting dozens of oral and poster sessions describing their research using data from the user

  15. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 31, 2012 [Feature Stories and Releases] Expanding Horizons for Climate Research Bookmark and Share New observation sites in Arctic, Atlantic Ocean provide details of important climate regimes One of the continuing challenges for scientists trying to understand and predict the future of Earth's climate system is the lack of accurate, long-term reference data sets from the various types of climate regimes. In a few months, the U.S. Department of Energy's Atmospheric Radiation Measurement

  16. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 2012 [Feature Stories and Releases] SGP Site Staff Share Successes, Challenges in the Name of Science Bookmark and Share Large-scale observation network in Korea opens door to new collaborations Daniel Hartsock and Dr. Kyungjeen Park look on as Pat Dowell describes the operation of a disdrometer at the SGP site. A sensor under the instrument's 'hood' measures rain rate and drop size distribution. Daniel Hartsock and Dr. Kyungjeen Park look on as Pat Dowell describes the operation of a

  17. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0, 2012 [Feature Stories and Releases] ARM Mobile Facility Completes Aerosol Campaign in India Bookmark and Share First-ever Indo-U.S. collaboration for climate research sets stage for future joint scientific endeavors Clouds gather in the foothills below the ARIES Observatory in Nainital, India, where the ARM Mobile Facility operated from June 2011 through March 2012. Clouds gather in the foothills below the ARIES Observatory in Nainital, India, where the ARM Mobile Facility operated from June

  18. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    July 26, 2012 [Feature Stories and Releases] Capturing Aerosol Evolution at Cape Cod Bookmark and Share From July 2012 to June 2013, nearly sixty instruments are obtaining atmospheric data from the ARM Mobile Facility site at Cape Cod National Seashore in Massachusetts. From July 2012 to June 2013, nearly sixty instruments are obtaining atmospheric data from the ARM Mobile Facility site at Cape Cod National Seashore in Massachusetts. Starting this month and lasting through June 2013, the ARM

  19. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 13, 2012 [Feature Stories and Releases] Up Close and Personal at Cape Cod National Seashore Bookmark and Share Visitors make their way to the ARM Mobile Facility, located on a coastal bluff near the Highlands Center at Cape Cod National Seashore. Visitors make their way to the ARM Mobile Facility, located on a coastal bluff near the Highlands Center at Cape Cod National Seashore. Enjoying fair skies and ocean breezes, a large and enthusiastic crowd gathered at the Highlands Center at Cape

  20. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23, 2008 [Feature Stories and Releases] Field Campaigns for 2010 Range from the Arctic to the Azores Bookmark and Share With the recent awards, the ARM Mobile Facility deployment on Graciosa Island in the Azores is extended from its original 9-month duration, beginning in May 2009 and now lasting through November 2010. The Department of Energy recently announced the selection of major ARM field campaigns that will take place in 2010. Studies led by principal investigators Rob Wood, Hans

  1. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 20, 2012 [Education, Feature Stories and Releases] Education Collaboration Provides Motivation for Science Exploration Bookmark and Share Kids and adults flock to Cape Cod National Seashore for close-up look at science facility Cathy Skowron (far left), ARM Ranger, describes a weather balloon launch to visitors from the Carroll Center for the Blind during a tour of the ARM Mobile Facility site at Cape Cod National Seashore. Barbara Dougan, education specialist at the park who

  2. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    29, 2013 [Feature Stories and Releases] New Field Campaigns Move Mobile Facility to Finland Forest and California Coast; Aircraft to Explore Aerosol and Gases Bookmark and Share Each year, the ARM Climate Research Facility receives proposals to use key components of the Facility for extended or intensive field campaigns to improve understanding of atmospheric processes that are relevant to regional and global climate. The Department of Energy (DOE) has selected the following new field campaigns

  3. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    17, 2013 [Facility News, Feature Stories and Releases] Popular Science's Brilliant 10 Includes ARM Radar Meteorologist Bookmark and Share To the casual observer, radars for weather and climate research silently go about their business, sending pulses of energy into the sky to bounce off of clouds and other particles overhead. The return signals feed into a computer where they are converted to data. Simple. Scott Collis (image courtesy Argonne National Laboratory) Scott Collis (image courtesy

  4. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 17, 2013 [Feature Stories and Releases] New Climate Research Site in the Azores Fills Critical Data Gap Bookmark and Share Newly installed on Graciosa Island in the North Atlantic Ocean, instruments at this Department of Energy research site measure incoming and outgoing energy, clouds, aerosols, and precipitation for climate studies. Newly installed on Graciosa Island in the North Atlantic Ocean, instruments at this Department of Energy research site measure incoming and outgoing

  5. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13, 2013 [Facility News, Feature Stories and Releases] Research Flights Completed for Biomass Burning Field Campaign Bookmark and Share The Gulstream-1 heads toward a smoke plume during a research flight for the Biomass Burning Observation Project. The Gulstream-1 heads toward a smoke plume during a research flight for the Biomass Burning Observation Project. In late October, the ARM Aerial Facility wrapped up a busy season of research flights for the Biomass Burning Observation Project, using a

  6. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 5, 2009 [Feature Stories and Releases] What's the Skinny on Thin Clouds? Bookmark and Share Flights Obtain Long-term Statistics to Improve Data Sets for Climate Models Unlike the wispy blankets of icy cirrus clouds that appear very high in the sky, thin clouds closer to Earth's surface contain water-but often not much. They are frequently patchy and contain small amounts of water. This combination makes them difficult for ground-based instruments to accurately measure, which decreases

  7. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 30, 2013 [Feature Stories and Releases] Pole Position: New Field Campaigns Explore Arctic and Antarctic Atmosphere Bookmark and Share Each year, the ARM Climate Research Facility receives proposals to use key components of the Facility for extended or intensive field campaigns to improve understanding of atmospheric processes that are relevant to regional and global climate. The Department of Energy has selected the following field campaigns that take place from 2014 through 2016. ARM

  8. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5, 2014 [Feature Stories and Releases] Biogenic Aerosols Examined in Finland Forest Bookmark and Share The second ARM Mobile Facility (AMF2) is operating in Hyytiälä, Finland, from February through September 2014 for the Biogenic Aerosols - Effects on Clouds and Climate field campaign. The second ARM Mobile Facility (AMF2) is operating in Hyytiälä, Finland, from February through September 2014 for the Biogenic Aerosols - Effects on Clouds and Climate field campaign. Biogenic aerosols are

  9. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 27, 2009 [Facility News, Feature Stories and Releases] Ceremony in the Azores Recognizes Scientific Collaborations Bookmark and Share A mix of green pastures and isolated white-housed villages dot the landscape of Graciosa Island. The ARM Mobile Facility will be located near the airport at the northern end of the island. In a signing ceremony at the Laboratorio Regional Engenharia Civil in Ponta Delgada, the Azores, government officials from the United States and Portugal formally

  10. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2014 [Facility News, Feature Stories and Releases] A Richly Deserved Retirement; a Job Well Done Bookmark and Share June 30, 2014, marks another key milestone in the progress and evolution of the ARM Climate Research Facility. After 20 years of leadership, Wanda Ferrell, DOE Program Director for the ARM Facility, is retiring. Under her strong and astute guidance, what began in 1989 with a 10-year vision as an observational testbed network is now entering its third decade and going strong,

  11. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 14, 2014 [Facility News, Feature Stories and Releases] Around the World in 52 Months Bookmark and Share ARM's New Research on Climate Spans the Globe Each year, the ARM Climate Research Facility receives proposals to use key components of the Facility for extended or intensive field campaigns to improve understanding of atmospheric processes that are relevant to regional and global climate. The Department of Energy has selected six field campaigns to take place from 2015 through most of

  12. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2015 [Facility News, Feature Stories and Releases] Studying the Amazon Basin's Climate by Air and by Land Bookmark and Share Second Intensive Operational Period Concludes for Green Ocean Amazon Campaign Partially obscured by aerosols in the atmosphere due to a large forest fire northeast of Manaus, the sun sets over the ARM Facility's Mobile Aerosol Observing System (MAOS) located southwest of Manaus, Brazil, at the T-3 site in Manacapuru where a Cimel Sunphotometer measures the optical

  13. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2015 [Facility News, Feature Stories and Releases] Seeing the Forest Through the Trees-And to the Aerosols Bookmark and Share End of the Biogenic Aerosols - Effects on Clouds and Climate Campaign in Finland Finnish scientists are measuring aerosols on branches as they grow in the boreal forests. Image courtesy of Juho Aalto. Finnish scientists are measuring aerosols on branches as they grow in the boreal forests. Image courtesy of Juho Aalto. Nine months in the icy, cold forests of Finland

  14. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, 2015 [Facility News, Feature Stories and Releases] Eastern North Atlantic Site Expands Data Capabilities Bookmark and Share First Year of Operations Completed in the Azores Situated near the airport on Graciosa Island, the newest ARM facility operates 24/7 to collect climate data. Situated near the airport on Graciosa Island, the newest ARM facility operates 24/7 to collect climate data. Situated off the coast of Portugal in the Azores, Graciosa Island hosts one of ARM's newest observation

  15. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 23, 2015 [Feature Stories and Releases] Chasing Aerosols and Atmospheric Rivers Bookmark and Share ARM Cloud Aerosol Precipitation Experiment (ACAPEX) sets sail and takes flight An atmospheric river branches off an equatorial storm, stretching from Hawaii to the U.S. West Coast, transporting as much moisture as 10-20 times the flow in the Mississippi River. An atmospheric river branches off an equatorial storm, stretching from Hawaii to the U.S. West Coast, transporting as much moisture

  16. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 25, 2015 [Facility News, Feature Stories and Releases] Nature Article: Carbon Dioxide's Greenhouse Effect at Earth's Surface Confirmed Using ARM Data Bookmark and Share Researchers link rising carbon dioxide levels from fossil fuels to an upward trend in radiative forcing at two locations From 2000 to the end of 2010, 3300 measurements were obtained at ARM's North Slope of Alaska site for the study. From 2000 to the end of 2010, 3300 measurements were obtained at ARM's North Slope of

  17. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2015 [Facility News, Feature Stories and Releases] Pilot Phase Begins for Routine Large-Eddy Simulations Bookmark and Share William Gustafson, Pacific Northwest National Laboratory William Gustafson, Pacific Northwest National Laboratory Researchers target observation and modeling together for a new level of scientific analysis on climate When it comes to clouds, the Earth's energy budget, and tiny aerosols, scientists don't have all the answers. However, each atmospheric model improvement

  18. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 14, 2015 [Feature Stories and Releases] Nocturnal Storm Chasers Collect "Fantastic" Data Set to Improve Forecasts Bookmark and Share PECAN campaign ends after scientists spend more than 30 nights monitoring storms with remote sensing instruments Approaching storm at sunset near Sawyer, Kansas, typifies the weather researchers pursued during PECAN campaign. Image courtesy of Jacob DeFlitch, Pennsylvania State University. Approaching storm at sunset near Sawyer, Kansas,

  19. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 16, 2015 [Feature Stories and Releases] Taking Stock of the Atmosphere Bookmark and Share ARM-ACME VI field campaign will chart changes in greenhouse gas levels Scientists are taking air samples at different heights above the Southern Great Plains site in this Cessna 206 aircraft. Scientists are taking air samples at different heights above the Southern Great Plains site in this Cessna 206 aircraft. For the next year, a Cessna 206 aircraft from the Atmospheric Radiation Measurement

  20. ARM - Feature Stories and Releases Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 16, 2015 [Feature Stories and Releases] Getting an Inside View of Arctic Clouds Bookmark and Share Researchers investigate the polar atmosphere's unique properties Researchers are using unmanned aerial systems to study Arctic atmospheric processes, especially where the tundra and ocean meet. Researchers are using unmanned aerial systems to study Arctic atmospheric processes, especially where the tundra and ocean meet. On the north coast of Alaska, where the barren tundra meets the icy