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1

Sulfur Release from Cement Raw Materials during Solid Fuel Combustion  

Science Journals Connector (OSTI)

The fuels were tire rubber, pine wood, petcoke, sewage sludge, and polypropylene. ... The sequence of SO2 release for fuel particles in the size interval 1–2 mm was found to be tire rubber granulate > sewage sludge > pine wood sawdust > petcoke > polypropylene flakes. ... Five different solid fuels have been tested: tire rubber, pine wood, polypropylene, petcoke, and sewage sludge. ...

Anders R. Nielsen; Morten B. Larsen; Peter Glarborg; Kim Dam-Johansen

2011-08-15T23:59:59.000Z

2

Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)  

Reports and Publications (EIA)

On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

2006-01-01T23:59:59.000Z

3

CUSSSFIC4TION CMUXLLq  

Office of Legacy Management (LM)

CUSSSFIC4TION CMUXLLq CUSSSFIC4TION CMUXLLq RITE AUG 1 7 1962 Fcx the Atomic. Energy Commisaion~ Chief. Declaseifle@tlon Brar\qh F-mm A. B. Grsaingsr (Other ends tifmtioel) The die wae foutq3 to workvery satiafactorilywiti thlanew Qpeof incert, andncm,of tbepmvLouedsfeotaofeoo+tH&' iOitYwaslmd. D&e& ._: . . ..YG ~Kl.3. i>ro;rid3 -&I:: clcsuro on bct.k.mds of the .plece m & Die #l, is also to be tried outoo 4zgust22. Barr~l~or~~~Die~~hadalaobeenawlLfiedta' plwidesd~do~- rwrdaM,thatSibs.of~~oouldbe~etoflow~gbtheLliearoundtbe surface of the wend overf'lo~lnto abarrel lvcatedundemeath the die. Under th?3e conditions "b8rre.l type' aaatjngs sere made with hardly any plvmure at all andrefaulthg ooatiiage were,of mums, vergporousand~eot. However, the

4

NETL: News Release - Florida Demo Tames High Sulfur Coal: Delivers Power at  

NLE Websites -- All DOE Office Websites (Extended Search)

March 11, 2005 March 11, 2005 Florida Demo Tames High Sulfur Coal: Delivers Power at Very Low Emissions Shows that New Technology Cuts Pollutants to Fractions of Federal Clean Air Limits JACKSONVILLE, FL - Recent tests with one of the nation's mid- to high-sulfur coals have further verified that a new electric generation technology in its first large-scale utility demonstration here is one of the world's cleanest coal-based power plants. This city's municipal utility JEA logged the achievement at its Northside Generating Station using Illinois No. 6 coal in a 300 megawatt demonstration of circulating fluidized bed (CFB) combustion, which is the largest application yet of the new form in the United States. It almost triples the size of a previous demonstration and scales up the technology to the sizes preferred for adding new plants and replacing old ones, also called repowering.

5

The SpallaTion  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

SpallaTion neuTron Source projecT When the Department of Energy (DOE) set out in the 1990s to develop a neutron scattering research facility that was ten times more powerful than the state of the art, the concept for the project that it chose was as ambitious as the scientific capability it sought to deliver. The Spallation Neutron Source (SNS) Project called for unprecedented collaboration among six national laboratories as well as significant

6

Why sequence Alkaliphilic sulfur oxidizing bacteria for sulfur pollution  

NLE Websites -- All DOE Office Websites (Extended Search)

Alkaliphilic sulfur oxidizing Alkaliphilic sulfur oxidizing bacteria for sulfur pollution remediation? Burning sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such as air pollution and acid rain, besides contributing to the loss of the ozone layer. One method of managing sulfur compounds released as byproducts from industrial processes is to scrub them out using chemical treatments and activated charcoal beds. A lower-cost solution relies on incorporating alkaliphic sulfur-oxidizing bacteria into biofilters to convert the volatile and toxic compounds into insoluble sulfur for easier removal. Discovered in the last decade, these bacteria have been found to thrive in habitats that span the full pH range. The bacteria could have applications

7

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

...amounts of coal, because...Director-Mineral Re-sources...of Gas from Coal through a...on coals of high ash-fusion temperature...per ton of high-sulfur coal burned. Absorp-tion...particulate matter as well as...capable of remov-ing up to...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

8

UTICA 4, NEW YORK COFIPOR~TION  

Office of Legacy Management (LM)

DROf fORGE & TOOL DROf fORGE & TOOL UTICA 4, NEW YORK COFIPOR~TION PHONE 3- 2331 July 5, 1955 ?:r. E. J. Block Director of Production Division United Staton Atomic ::norgy Commission Yiashington, D. C. Dear Xr. 1310~1~: Xe had a visit last Thursday from Kr. R. C. Sale11 of the: Atomic Energy Commission who inspected our vacuum melting facilities. EIz suggested that we should get in touch with you and that you r+ht be interested in the use of our facilities for the i>roduction of uranium fuel elements. Xe have at the present time the largest coxnercial vacuum installation in the country and m have been producin; high tc~poraturc alloys for the aircraft industry for over txro 'years. ;Is have produced to date Over 400,000 pounds of mtal. Our present rate of production is of the order

9

Offshore Sulfur Comes In  

Science Journals Connector (OSTI)

Offshore Sulfur Comes In ... "The deposit is a major new source of sulfur," say Hines H. Baker, president of Humble Oil, and Langbourne M. Williams, president of Freeport Sulphur. ... Humble's deposit, known as Grand Isle (Block 18), was discovered in the course of offshore oil exploration and it ranks among the most important sulfur discoveries of recent years. ...

1956-10-01T23:59:59.000Z

10

ADVANCED SULFUR CONTROL CONCEPTS  

SciTech Connect

Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

2003-01-01T23:59:59.000Z

11

Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single...

12

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur...  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for LithiumSulfur Cells Lawrence Berkeley National...

13

Elemental sulfur recovery process  

DOE Patents (OSTI)

An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

Flytzani-Stephanopoulos, M.; Zhicheng Hu.

1993-09-07T23:59:59.000Z

14

Chapter 11 - Sulfur Recovery  

Science Journals Connector (OSTI)

Abstract Sulfur is present in many raw industrial gases and in natural gas in the form of hydrogen sulfide. Sulfur removal facilities are located at the majority of oil and gas processing facilities throughout the world. The sulfur recovery unit does not make a profit for the operator but it is an essential processing step to allow the overall facility to operate, as the discharge of sulfur compounds to the atmosphere is severely restricted by environmental regulations. Concentration levels of H2S vary significantly depending upon their source. H2S produced from absorption processes, such as amine treating of natural gas or refinery gas, can contain 50–75% H2S by volume or higher. This chapter provides information about fundamentals of sulfur removal facilities in the natural gas industry.

Alireza Bahadori

2014-01-01T23:59:59.000Z

15

An Aerosol Condensation Model for Sulfur Trioxide  

SciTech Connect

This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

Grant, K E

2008-02-07T23:59:59.000Z

16

Bacterial Sulfur Storage Globules  

NLE Websites -- All DOE Office Websites (Extended Search)

by I. J. Pickering and G. N. George by I. J. Pickering and G. N. George Sulfur is essential for all life, but it plays a particularly central role in the metabolism of many anaerobic microorganisms. Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for use when food is in short supply (Fig. 1). The chemical nature of the sulfur in these globules has been an enigma since they were first described as far back as 1887 (1); all known forms (or allotropes) of elemental sulfur are solid at room temperature, but globule sulfur has been described as "liquid", and it apparently has a low density – 1.3 compared to 2.1 for the common yellow allotrope a-sulfur. Various exotic forms of sulfur have been proposed to explain these properties, including micelles (small bubble-like structures) formed from long-chain polythionates, but all of these deductions have been based upon indirect evidence (for example the density was estimated by flotation of intact cells), and many questions remained.

17

Sulfur removal and comminution of carbonaceous material  

DOE Patents (OSTI)

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

Narain, N.K.; Ruether, J.A.; Smith, D.N.

1987-10-07T23:59:59.000Z

18

Sulfur removal and comminution of carbonaceous material  

DOE Patents (OSTI)

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

1988-01-01T23:59:59.000Z

19

A novel mechanism and kinetic model to explain enhanced xylose yields from dilute sulfuric acid compared to hydrothermal pretreatment of corn stover  

E-Print Network (OSTI)

significant poten- tial as a feedstock for conversion to liquid fuels such as ethanol and biodiesel (Kadam to be limited. However, dilute sulfuric acid pretreatment has proven to be a very effective in recov- ering most of these pretreatments to corn stover include dilute-sulfuric acid in a high-solids percola- tion reactor (Zhu et al

California at Riverside, University of

20

SANDIA COKPOK4TION SANDIA BASE, .QLDUQUERQUE. N. M.  

Office of Legacy Management (LM)

SANDIA COKPOK4TION SANDIA COKPOK4TION SANDIA BASE, .QLDUQUERQUE. N. M. To : DISTRIBUTION Re: Disposition of t h e Shoal S i t e Attached herewith i s a study which has been made s w g e s t i n g p o s s i b l e f u r t h e r uses of t h e Shoal S i t e . I - ! e have a l s o b r i e f l y described how permanent d i s p o s i t i o n might be made. The study has been made with t h e hope t h a t it w i l l evolce f u r t h e r considerc~tion of t h e s i t e and l e a d t o a plan f o r continued use and eventual d i s p o s i t i o n . W i l l you please review t h e study and forward your comments and any o t h e r suggestions f o r t h e s i t e . Your r e p l i e s w i l l be used t o help formulate a f i n a l d i s p o s i t i o n plan. Copy t o : Brig. Cen. D. L. Crowson, D M , \.lash., D. C. Attn: Lt. Col. W . C. H a l l < < J. 3. Reeves, ivkr. I ' A C - W O O R. E. Piiller, P S C - W O O : a ! . W . t

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Freeport Begins Offshore Sulfur Plant  

Science Journals Connector (OSTI)

Freeport Begins Offshore Sulfur Plant ... Discovered by Humble Oil & Refining, the sulfur deposit off Grand Isle is believed by industry observers to be one of the largest discovered in recent years. ...

1958-07-07T23:59:59.000Z

22

EERE PROJECT MANAGEMENT CENTER NEPA DETTIUlIIN .... TION PROJECT  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chicago Chicago u.s. DEP .... RTIIIENT OF ENERGY EERE PROJECT MANAGEMENT CENTER NEPA DETTIUlIIN .... TION PROJECT TITLE: Chicago Climate Action Plan Advanced Transportation Technologies Initiative STATE: IL Funding Opportunity Announcement Number nla Procurement Instrument Number DE-FG3&-060860S2 NEPA Control Number GFO-G086052-001 Page 1 of2 ClD Number G086052 Based on my review oftbe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 4S1.1A), I bave made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: 65.1 Actions to conserve energy, demonstrate potential energy conservation, and promote energy-efficiency that do not increase the indoor concentrations of potentially harmful substances. These actions may involve financial and technical

23

sulfur dioxide emissions | OpenEI  

Open Energy Info (EERE)

sulfur dioxide emissions sulfur dioxide emissions Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides

24

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

25

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur.  

SciTech Connect

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-06-01T23:59:59.000Z

26

It's Elemental - The Element Sulfur  

NLE Websites -- All DOE Office Websites (Extended Search)

Phosphorus Phosphorus Previous Element (Phosphorus) The Periodic Table of Elements Next Element (Chlorine) Chlorine The Element Sulfur [Click for Isotope Data] 16 S Sulfur 32.065 Atomic Number: 16 Atomic Weight: 32.065 Melting Point: 388.36 K (115.21°C or 239.38°F) Boiling Point: 717.75 K (444.60°C or 832.28°F) Density: 2.067 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 3 Group Number: 16 Group Name: Chalcogen What's in a name? From the Sanskrit word sulvere and the Latin word sulphurium. Say what? Sulfur is pronounced as SUL-fer. History and Uses: Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a

27

Why sequence purple sulfur bacteria?  

NLE Websites -- All DOE Office Websites (Extended Search)

purple sulfur bacteria? purple sulfur bacteria? The process by which plants and some bacteria can convert light energy to sugar, or photosynthesis, is crucial to global food webs, and complicated. Very little is known about the photosynthetic bacteria in the purple sulfur bacteria group, which may represent one of the most primitive photosynthetic organisms and are capable of carbon fixation and sequestration in both light and dark conditions with the help of sulfur compounds. Purple sulfur bacteria are autotrophic and can synthesize organic compounds from inorganic sources. Researchers hope to learn more by sequencing nine type strains of purple sulfur bacteria that are found in freshwater, brackish and marine systems. The information would lead to a better understanding of the process of photosynthesis as well as the global

28

Microbial transformations of sulfur compounds  

Science Journals Connector (OSTI)

Oct 13, 1978 ... tains a large part of the chemical energy transferred ... ical energy is partly preserved in the bio- mass of .... ethanol to remove elemental sulfur.

2000-01-10T23:59:59.000Z

29

Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes  

SciTech Connect

Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

2014-06-17T23:59:59.000Z

30

Assessing Potential Acidification of Marine Archaeological Wood Based on Concentration of Sulfur Species  

SciTech Connect

The presence of sulfur in marine archaeological wood presents a challenge to conservation. Upon exposure to oxygen, sulfur compounds in waterlogged wooden artifacts are being oxidized, producing sulfuric acid. This speeds the degradation of the wood, potentially damaging specimens beyond repair. Sulfur K-edge x-ray absorption spectroscopy was used to identify the species of sulfur present in samples from the timbers of the Mary Rose, a preserved 16th century warship known to undergo degradation through acidification. The results presented here show that sulfur content varied significantly on a local scale. Only certain species of sulfur have the potential to produce sulfuric acid by contact with oxygen and seawater in situ, such as iron sulfides and elemental sulfur. Organic sulfurs, such as the amino acids cysteine and methionine, may produce acid but are integral parts of the wood's structure and may not be released from the organic matrix. The sulfur species contained in the sample reflect the exposure to oxygen while submerged, and this exposure can differ greatly over time and position. A better understanding of the species pathway to acidifications required, along with its location, in order to suggest a more customized and effective preservation strategy. Waterlogged archaeological wood, frequently in the form of shipwrecks, is being excavated for historical purposes in many countries around the world. Even after extensive efforts towards preservation, scientists are discovering that accumulation of sulfate salts results in acidic conditions on the surfaces of the artifacts. Sulfuric acid degrades structural fibers in the wood by acid hydrolysis of cellulose, accelerating the decomposition of the ship timbers. Determining the sulfur content of waterlogged wood is now of great importance in maritime archaeology. Artifact preservation is often more time consuming and expensive than the original excavation; but it is key to the availability of objects for future study as well as maintaining the integrity of historical data and preserving the value of museum pieces. Sulfur occurs in a wide number of oxidation states from -2 to +6, and appears in numerous organic and inorganic compounds in nature. However, it is a very minor component of wood. Sulfur K-edge x-ray absorption spectroscopy (XAS) is a valuable technique because it has the ability to detect very low concentrations of sulfur in the specimen. XAS is also sensitive to differences in oxidation states, as well as long and short range order in molecules.

Not Available

2011-06-22T23:59:59.000Z

31

Sulfur minimization in bacterial leaching  

SciTech Connect

The production of sewage biosolids in Ontario in 1989 was estimated to be 7 million m{sup 3} of wet sludge per year. Of this amount, land application accounts for between 20 and 30% of the total. Unfortunately, the use of sewage biosolids on agricultural land is often prohibited because of heavy metal contamination of the biosolids. High cost and operational problems have made chemical methods of metal extraction unattractive. Consequently, microbiological methods of leaching of heavy metals have been studied for over a decade. A relatively simple microbiological process has been investigated in recent years in flask level experiments and recently in a semicontinuous system. The process exploits nonacidophilic and acidophilic indigenous thiobacilli to extract heavy metals from sewage biosolids. These thiobacilli use elemental sulfur as the energy source, producing sulfuric acid. However, the resulting decontaminated biosolids can cause environmental problems like acidification of the soil, when acid is generated from the residual sulfur in the biosolids. The present study examines the possibility of reducing the amount of sulfur added in batch and semicontinuous bacterial leaching systems, and maximizing sulfur oxidation efficiency, thereby reducing the residual sulfur in leached biosolids.

Seth, R.; Prasad, D.; Henry, J.G. [Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering

1996-11-01T23:59:59.000Z

32

Sulfur capture in combination bark boilers  

SciTech Connect

A review of sulfur dioxide emission data for eight combination bark boilers in conjunction with the sulfur contents of the fuels reveals significant sulfur capture ranging from 10% to over 80% within the solid ash phase. Wood ash characteristics similar to activated carbon as well as the significant wood ash alkali oxide and carbonate fractions are believed responsible for the sulfur capture. Sulfur emissions from combination bark-fossil fuel firing are correlated to the sulfur input per ton of bark or wood residue fired.

Someshwar, A.V.; Jain, A.K. (National Council of the Paper Industry for Air and Stream Improvement, Gainesville, FL (United States))

1993-07-01T23:59:59.000Z

33

Original article Effects of arginine, growth hormone-releasing  

E-Print Network (OSTI)

release of ARG (1 g/kg body weight, infused between times-15 and -5 min), growth hormone-releasing hormone Growth hormone (GH) secretion is regu- lated by many factors including nutrients. Arginine (ARG) infused infusions of ARG can stimulate GH secre- tion in lambs (Davenport et al, 1990a, 1995), adult sheep

Boyer, Edmond

34

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Fifth quarterly technical progress report, December 1996  

SciTech Connect

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1996-12-01T23:59:59.000Z

35

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Sixth quarterly technical progress report, January - March 1997  

SciTech Connect

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-03-01T23:59:59.000Z

36

Molecular Structures of Polymer/Sulfur Composites for Lithium...  

NLE Websites -- All DOE Office Websites (Extended Search)

Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

37

Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of Lithium–Sulfur Battery  

Science Journals Connector (OSTI)

Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of Lithium–Sulfur Battery ... An amylopectin wrapped graphene oxide-sulfur composite was prepared to construct a 3-dimensionally cross-linked structure through the interaction between amylopectin and graphene oxide, for stabilizing lithium sulfur batteries. ...

Weidong Zhou; Hao Chen; Yingchao Yu; Deli Wang; Zhiming Cui; Francis J. DiSalvo; Héctor D. Abruña

2013-09-05T23:59:59.000Z

38

Sulfur: its clinical and toxicologic aspects  

Science Journals Connector (OSTI)

Although there is no known dietary requirement for inorganic sulfur, it is an essential element for all animal species in as much as they all require the sulfur-containing amino acid methionine. There are three predominate forms of organic sulfur in animals and humans: 1) the thiomethyl of methionine residues in protein; 2) the sulfhydryl disulfides of protein; and 3) the compounds containing ester or amide bound sulfates of glycosaminoglycans, steroids, and many xenobiotic metabolites. Thus, sulfur becomes an important constituent of amino acids, proteins, enzymes, vitamins and other biomolecules. Unlike mammalian species, plants can use inorganic sulfur and synthesize methionine from which are synthesized all the other important sulfur compounds. Hence, sulfur deficiency occurs mainly when plants are grown in sulfur-depleted soils and when humans and animals consume low-protein diets. In recent times, however, the increasing prevalence of refining petroleum and smelting sulfur compounds of metallic minerals into free metals are having a large impact on the balance of sulfur in the environment. Sulfur toxicity is associated mainly with high levels of the element and its toxic volatile substances in the environment. Sulfur dioxide (SO2), a major air pollutant, may adversely affect animal and human health by causing bronchitis, bronchoconstriction, and increased pulmonary resistance.

Lioudmila A Komarnisky; Robert J Christopherson; Tapan K Basu

2003-01-01T23:59:59.000Z

39

Two stage sorption of sulfur compounds  

DOE Patents (OSTI)

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, William E. (Manassas, VA)

1992-01-01T23:59:59.000Z

40

,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"  

U.S. Energy Information Administration (EIA) Indexed Site

Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","9/2013","1/15/1985" ,"Release Date:","11/27/2013" ,"Next Release Date:","Last Week of December 2013" ,"Excel File Name:","pet_pnp_crq_a_epc0_ycs_pct_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_crq_a_epc0_ycs_pct_m.htm" ,"Source:","Energy Information Administration"

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Why Sequence Sulfur-Oxidizing Bacteria?  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur-Oxidizing Bacteria? Sulfur-Oxidizing Bacteria? Several environmental problems, such as acid rain, biocorrosion, etc., are caused by sulfur compounds, such as sulfur dioxide (SO2) and hydrogen sulfide (H2S). A sustainable process to remove these sulfur compounds is the production of elemental sulfur from H2S-containing gas streams by the use of sulfide-oxidizing bacteria. In this process, H2S is absorbed into the alkaline solution in the scrubber unit, followed by the biological oxidation of H2S to elemental sulfur and the recycling of water. With this two-step process, a variety of gas streams (i.e., natural gas, synthesis gas, biogas, and refinery gas) can be treated. For the treatment of sulfate-containing waste streams, an extra step has to be introduced: the transformation of sulfate into H2S by sulfate-reducing bacteria. In

42

Cooperative Spectrum Sensing and Localiza-tion in Cognitive Radio Systems using Com-  

E-Print Network (OSTI)

Cooperative Spectrum Sensing and Localiza- tion in Cognitive Radio Systems using Com- pressed features in cog- nitive radio systems (CRS): spectrum sensing and location awareness in a single compressed implementing a cognitive radio system. The major problem for spectrum sensing arises in wideband radio, when

Gesbert, David

43

China For all ages a MulTi-generaTional exPloraTion  

E-Print Network (OSTI)

China For all ages a MulTi-generaTional exPloraTion The greaT Wall, TerraCoTTa Warriors & The MighCTuresque China Experience the Delights of a Well-Crafted Family Tour Dear Princetonian, Join Princeton Journeys, June 27 ­ July 9, 2013, for a comprehensive tour of China designed with families in mind. Explore

Rowley, Clarence W.

44

SEASONAL V A R IA TIONS IN STRUCTURE AND CIRCULATION IN THE RED SEA  

E-Print Network (OSTI)

SEASONAL V A R IA TIONS IN STRUCTURE AND CIRCULATION IN THE RED SEA A DISSERTATION SUBMITTE D and surface circulation in the Red Sea, occur r ing along the north-south axis of the Sea and extending fr om on in the northern Red Sea is frorn the nor th-northwest throughout the year' during the winter ( fr om October

Luther, Douglas S.

45

Tag der InnovaTIon Fokus WerksToFFWIssenschaFTen  

E-Print Network (OSTI)

Tag der InnovaTIon Fokus WerksToFFWIssenschaFTen auFTakTveransTalTung zur MITarbe erfolg. ein beitrag dazu soll der,,Tag der Innovation ­ Fokus Werkstoffwissenschaften" sein, der am 26 des zentralinstitutes für neue Materialien und Prozesstechnik und des Fraunhofer-Institutes ezr

Fiebig, Peter

46

analogies to proteins as a func-tion of nanoparticle size and  

E-Print Network (OSTI)

analogies to proteins as a func- tion of nanoparticle size and surface charge, and lipid composition and phase state. The focus will be on engineered nanoparticles common to environmental and biomedical applications, and examples will be provided where fundamental knowledge of nanoparticle

Subramanian, Venkat

47

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries 2011 DOE...

48

Improve reformer operation with trace sulfur removal  

SciTech Connect

Modern bimetallic reforming catalysts typically have feed specifications for sulfur of 0.5 to 1 wppm in the reformer naphtha carge. Sulfur in the raw naphtha is reduced to this level by naphtha hydrotreating. While most naphtha hydrotreating operations can usually obtain these levels without substantial problems. It is difficult to obtain levels much below 0.5 to 1 wppm with this process. Revamp of a constrained existing hydrotreater to reduce product sulfur slightly can be extremely costly typically entailing replacement or addition of a new reactor. At Engelhard the authors demonstrated that if the last traces of sulfur remaining from hydrotreating can be removed, the resulting ultra-low sulfur feed greatly improves the reformer operation and provides substantial economic benefit to the refiner. Removal of the remaining trace sulfur is accomplished in a simple manner with a special adsorbent bed, without adding complexity to the reforming operation.

McClung, R.G.; Novak, W.J.

1987-01-01T23:59:59.000Z

49

Contribution of isotopologue self-shielding to sulfur mass-independent fractionation during sulfur dioxide photolysis  

E-Print Network (OSTI)

Signatures of sulfur mass-independent fractionation (S-MIF) are observed for sulfur minerals in Archean rocks, and for modern stratospheric sulfate aerosols (SSA) deposited in polar ice. Ultraviolet light photolysis of ...

Lyons, J. R.

50

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

SciTech Connect

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

51

Sulfur-Free Selective Pulping  

E-Print Network (OSTI)

Technoeconomic Appraisal," December 1991. 5. DOE Annual Report on Contract No. AC02-83CH10093, Bozell, J. J., Hames, B., Chum, H. L., Dimmel, D. R, Althen, E., Caldwell, P. L., Daube, Oxidation ;; Diels-Alder .. I I -Methanol .. ~ 5 I 3 (C~O) OCH... - Hydrogen 3 (Q-IP) # Q-I 3 o o ~ o 1 2 ~ (H) Lignin DMBQ =two OCH3 groups Anthraquinone MMBQ =one OCH3 group A. K, and Kuroda, K-I.,"Sulfur-free Selective Pulping," March 1992. 6. DOE Annual Report on Contrac No. DE-AC02-83CH10093, Bozell, J. J...

Dimmel, D. R.; Bozell, J. J.

52

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network (OSTI)

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

53

Graphene-wrapped sulfur nanospheres with ultra-high sulfur loading for high energy density lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithium–sulfur (Li–S) battery with high theoretical energy density is one of the most promising energy storage systems for electric vehicles and intermittent renewable energy. However, due to the poor conductivity of the active material, considerable weight of the electrode is occupied by the conductive additives. Here we report a graphene-wrapped sulfur nanospheres composite (S-nanosphere@G) with sulfur content up to 91 wt% as the high energy density cathode material for Li–S battery. The sulfur nanospheres with diameter of 400–500 nm are synthesized through a solution-based approach with the existence of polyvinylpyrrolidone (PVP). Then the sulfur nanospheres are uniformly wrapped by conductive graphene sheets through the electrostatic interaction between graphene oxide and PVP, followed by reducing of graphene oxide with hydrazine. The design of graphene wrapped sulfur nanoarchitecture provides flexible conductive graphene coating with void space to accommodate the volume expansion of sulfur and to minimize polysulfide dissolution. As a result, the S-nanosphere@G nanocomposite with 91 wt% sulfur shows a reversible initial capacity of 970 mA h g?1 and an average columbic efficiency > 96% over 100 cycles at a rate of 0.2 C. Taking the total mass of electrode into account, the S-nanosphere@G composite is a promising cathode material for high energy density Li–S batteries.

Ya Liu; Jinxin Guo; Jun Zhang; Qingmei Su; Gaohui Du

2015-01-01T23:59:59.000Z

54

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

High-Sulfur...FLUIDIZED-BED COMBUSTORS, COMBUSTION...MAY FLUE GAS DES S E...1971 ). High-sulfur...was brief. Natural gas became...overdependent on natural gas and oil to...elevated pressure with a downward...coals of high ash-fusion...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

55

Preliminary Release: March 28, 2011",,,,,,,,,,,,"Released: April 2013","Released  

U.S. Energy Information Administration (EIA) Indexed Site

,,,,,,,,,,,,"Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 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56

--PRESS RELEASE--  

NLE Websites -- All DOE Office Websites (Extended Search)

NEWS RELEASE NEWS RELEASE Global Energy, Inc. For Immediate Release GLOBAL ENERGY INC. AND WABASH VALLEY POWER RELAUNCH WABASH GASIFICATION FACILITY AS SG SOLUTIONS LLC Cincinnati and Indianapolis, February 7, 2005 - Global Energy Inc. and Wabash Valley Power Association announced today that they have formed SG Solutions LLC to move the Wabash Gasification Facility forward to achieve base load operations and future growth. SG Solutions LLC (SGS) is owned 50/50 by Wabash Valley Power Association and Wabash River Energy, a unit of Global Energy Inc. In recent years the Wabash Gasification Facility has operated under a demanding market-based contract which challenged the operation to make very low cost synthetic gas. As a result, Wabash has consistently produced synthetic gas with a

57

Method of removal of sulfur from coal and petroleum products  

DOE Patents (OSTI)

A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

1995-01-01T23:59:59.000Z

58

Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of...

59

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

60

Manipulating the Surface Reactions in Lithium Sulfur Batteries...  

NLE Websites -- All DOE Office Websites (Extended Search)

Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode...

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Press Release  

NLE Websites -- All DOE Office Websites (Extended Search)

Press Release Press Release LLNL garners 'Best in Class' award from NNSA April 30, 2012 WASHINGTON, D.C. - The National Nuclear Security Administration (NNSA) today congratulated its national laboratories and sites for achievements in environmental stewardship, awarding a total of 24 Pollution Prevention (P2) Awards for innovative initiatives across the enterprise. The P2 Awards recognize performance in integrating environmental stewardship practices that helps to reduce risk, protect natural resources and enhance site operations. "I applaud the work done at NNSA's sites in finding creative ways to reduce the environmental impact of our work," said NNSA's Deputy Administrator for

62

Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content  

SciTech Connect

In the hydrotreating and steam reforming of an oxygen and sulfur bearing hydrocarbon fuel, the oxygen is first removed in an oxidizer containing a bed of platinum catalyst, the inlet temperature being well below 1000/sup 0/F and preferably on the order of 300/sup 0/F. The sulfur in the fuel does not harm the oxidizer catalyst and may be removed downstream by known hydrodesulfurization techniques prior to reforming. A process is described for removing oxygen from an oxygen and sulfur bearing hydrocarbon fuel, such as peak shared natural gas, upstream in the process so that sulfur can be removed later. The fuel and some hydrogen are introduced into an oxidizer at a temperature of 350/sup 0/F or less down to the minimum ignition temperature. The oxidizer consists of a platinum bed catalyst which catalyzes the oxidation of the oxygen to water with accompanying heat release to raise the exit gas temperature to less than 650/sup 0/F. The temperature desorbs the sulfur from the catalyst, and the exit gases are passed downstream to nickel subsulfide or molybdenum desfulfide catalysts where the hydrosulfurization process takes place. (BLM)

Lesieur, R.R.; Setzer, H.J.; Hawkins, J.R.

1980-01-01T23:59:59.000Z

63

Sulfur nanocrystals anchored graphene composite with highly improved electrochemical performance for lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract Two kinds of graphene–sulfur composites with 50 wt% of sulfur are prepared using hydrothermal method and thermal mixing, respectively. Transmission Electron Microscopy (TEM) and Energy Dispersive X-ray Spectra mapping show that sulfur nanocrystals with size of ?5 nm dispersed on graphene sheets homogeneously for the sample prepared by hydrothermal method (NanoS@G). While for the thermal mixed graphene–sulfur composite (S–G mixture), sulfur shows larger and uneven size (50–200 nm). X-ray Photoelectron Spectra (XPS) reveals the strong chemical bonding between the sulfur nanocrystals and graphene. Comparing with the S–G mixture, the NanoS@G composite shows highly improved electrochemical performance as cathode for lithium–sulfur (Li–S) battery. The NanoS@G composite delivers an initial capacity of 1400 mAh g?1 with the sulfur utilization of 83.7% at a current density of 335 mA g?1. The capacity keeps above 720 mAh g?1 over 100 cycles. The strong adherence of the sulfur nanocrystals on graphene immobilizes sulfur and polysulfides species and suppressed the “shuttle effect”, resulting higher coulombic efficiency and better capacity retention. Electrochemical impedance also suggests that the strong bonding enabled rapid electronic/ionic transport and improved electrochemical kinetics, therefore good rate capability is obtained. These results demonstrate that the NanoS@G composite is a very promising candidate for high-performance Li–S batteries.

Jun Zhang; Zimin Dong; Xiuli Wang; Xuyang Zhao; Jiangping Tu; Qingmei Su; Gaohui Du

2014-01-01T23:59:59.000Z

64

Catalyst for elemental sulfur recovery process  

DOE Patents (OSTI)

A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

Flytzani-Stephanopoulos, M.; Liu, W.

1995-01-24T23:59:59.000Z

65

Unlimited Release  

Office of Scientific and Technical Information (OSTI)

Unlimited Release Unlimited Release Printed November 1987 Proceedings of The Wellbore Sampling Workshop Richard K. Traeger, Barry W. Harding Prepared by Sandia National Laboratories Albuquerque, New Mexico 87185 and Livermore, California 9 4 5 5 0 f o r the United States Department of Energy . under Contract DE-AC04-76DP00789 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately

66

Sulfur-graphene oxide material for lithium-sulfur battery cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur-graphene oxide material for lithium-sulfur battery cathodes Sulfur-graphene oxide material for lithium-sulfur battery cathodes Theoretical specific energy and theoretical energy density Scanning electron micrograph of the GO-S nanocomposite June 2013 Searching for a safer, less expensive alternative to today's lithium-ion batteries, scientists have turned to lithium-sulfur as a possible chemistry for next-generation batteries. Li/S batteries have several times the energy storage capacity of the best currently available rechargeable Li-ion battery, and sulfur is inexpensive and nontoxic. Current batteries using this chemistry, however, suffer from extremely short cycle life-they don't last through many charge-discharge cycles before they fail. A research team led by Elton Cairns and Yuegang Zhang has developed a new

67

Phosphazene groups modified sulfur composites as active cathode materials for rechargeable lithium/sulfur batteries  

Science Journals Connector (OSTI)

A novel phosphazene groups modified sulfur composites cathode [triphosphazene sulfide composite (PS) or nitroaniline–triphosphazene disulfide composite (NPS)] which can give good affinity with electrolytes was...

J. D. Liu; S. Q. Zhang; S. B. Yang; Z. F. Shi; S. T. Zhang; L. K. Wu

2013-11-01T23:59:59.000Z

68

STATEM ENT OF CONSIDER TIONS CLASS WAIVER OF TH E GOVERNMENT'S DOMESTIC AN  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

STATEM STATEM ENT OF CONSIDER TIONS CLASS WAIVER OF TH E GOVERNMENT'S DOMESTIC AN D FO REIGN PATENT RIGHTS AND ALLOCATION OF DATA RIGHTS ARJSING FROM TI-lE:: USE OF DOE FACJLJTIES AND FACIL ITY CONT'l~ACTORS BY OR FOR THIR D PARTY FUND ING SPONSORS UNDER AGREEMENTS FO R COMMERCIALIZING TECHNOLOGY (ACT): DOE WAIVER NO. W(C)-201 l-013 The D..:partrnent of Energ.} (and its predecessor agencies) (col lectively. ''DO E" or · Department") considers each or its DO E Facilities (i.e., Nati onal Laboratories. single-purpose research fac ilities. and other Department facili ties, hereinafter referred to individually as ·'Facil ity" or collect ively as '·Facilities'') to be a unique and valuab le national resource that should be made avail· ble to the extent fea

69

Energy Levels in Sulfur Nuclei  

Science Journals Connector (OSTI)

A study has been made of the proton groups from the reaction of 3.22-Mev deuterons with sulfur in the form, primarily, of H2S gas. The following Q values have been assigned to the reaction S32(dp)S33:6.48, 5.69, 4.58, 4.31, 3.63, 3.33, 2.60, 2.33, 2.06, 1.78, 1.37, 0.85, and 0.18 Mev, corresponding to the ground state and twelve excited states of S33. Four of these groups have been investigated for proton gamma-ray coincidences to confirm this assignment. The yield as a function of deuteron energy has been observed for the six highest energy groups and indication of the presence of some broad resonances found. A qualitative measurement of the variation with angle of relative yields of the groups has indicated a proton intensity distribution that is symmetric for some groups and asymmetric for others. The cross section for the reaction for 90° observation has been found to be 1.2 barns. The mass difference S33-S32 has been calculated to be 0.99963 mass unit.Two low intensity, high energy groups have been assigned to the reaction S33(dp)S34 with Q values of 8.67 and 7.85 Mev. This, together with the above observation, leads to a value of 1.99691 for the mass difference S34-S32.

Perry W. Davison

1949-03-01T23:59:59.000Z

70

Steam reforming utilizing sulfur tolerant catalyst  

SciTech Connect

This patent describes a steam reforming process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of: adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalyst of platinum supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. It also describes a steam process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of steam to the hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalysts consisting essentially of iridium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. In addition a steam reforming process is described for converting hydrocarbon material to hydrogen gas in the presence of sulfur comprising adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity sulfur tolerant catalysts consisting essentially of palladium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina.

Setzer, H.J.; Karavolis, S.; Bett, J.A.S.

1987-09-15T23:59:59.000Z

71

Preliminary Release: March 28, 2011",,,,,,,,,,,,"Released: April...  

U.S. Energy Information Administration (EIA) Indexed Site

Energy Consumption Survey: Final Housing Characteristics Tables" "Preliminary Release: March 28, 2011" "Final Release: April 2013" "Table HC5.6 Computers and Other Electronics in...

72

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NOX control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-03-04T23:59:59.000Z

73

SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS  

SciTech Connect

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

Gary M. Blythe; Richard McMillan

2002-07-03T23:59:59.000Z

74

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NO{sub x} control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two First Energy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-02-04T23:59:59.000Z

75

The reaction kinetics of gasoline sulfur compounds: Catalytic mechanisms for sulfur reduction  

SciTech Connect

One of the key elements of reformulated gasoline is the reduction of the sulfur compounds produced by fluid catalytic cracking. This paper probes the reaction kinetics of refractory gasoline-range thiophene derivatives (thiophene, tetrahydrothiophene, and alkylthiophenes) in an effort to determine the mechanisms of sulfur compound cracking in the FCC unit. The gasoline-range sulfur compounds were analyzed using gas chromatography with an atomic emission detector. The authors` results show that the FCC catalysts affects the cracking of sulfur compounds through both hydrogen transfer and zeolite pore restriction mechanisms. An experimental FCC catalyst is shown to reduce gasoline sulfur content in the Davidson Circulating Riser (DCR{sup TM}) pilot unit. Model compound tests show that the activity of the catalyst is due to both its catalytic and adsorptive properties. Tetrahydrothiophene, which is produced from thiophenes by hydrogen transfer, is completely removed by the experimental catalyst.

Harding, R.H.; Gatte, R.R.; Albro, T.G.; Wormsbecher, R.F. [W.R. Grace & Co. Conn, Columbia, MD (United States)

1993-12-31T23:59:59.000Z

76

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries...

77

Safety considerations for the use of sulfur in sulfur-modified pavement materials  

E-Print Network (OSTI)

on the surround1ng environment. As sulfur-modified paving materials were being developed, there was a corresponding concern for studying the amounts of gaseous emiss1ons that were generated. The Texas Trans- portat1on Inst1tute (TTI) was one of the first... organizations in the United States to become 1nvolved in the research and development of sulfur-modified pavements, Throughout 1ts laboratory stud1es TTI cont1nually mon1tored hydrogen sulf1de (H25) and sulfur d1oxide (502) em1ssions produced during mix...

Jacobs, Carolyn Yuriko

2012-06-07T23:59:59.000Z

78

Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline  

Energy.gov (U.S. Department of Energy (DOE))

Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of sulfur in gasoline (Tier 2 standards)....

79

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

...made historically by heating bitumi-nous coal in...heart of the anthracite district only about 5 years ago...energy, wind, and geothermal steam and brines, will...15.7 Nuclear 3.1 Geothermal Negligible 1973, use...home and commercial heating, transporta-tion...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

80

DRIFT BOTTLE RELEASES DRIFT BOTTLE RELEASES  

E-Print Network (OSTI)

FISH AND WILDLIFE SERVICE #12;Explanatory Note The series embodies results of investigations, usually January 1950 ^ #12;United States Department of the Interior Oscar Le Chapman, Secretary Fish and Wildlife on the influence of wind and drags 17 Simimary and conclusion 18 Literature cited 21 #12;ILLUSTRA.TIONS FIGURE page

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

ORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation  

E-Print Network (OSTI)

). Methylotrophs and iron oxidizers were also active in plume waters and expressed key proteins for methane by bacteria (especially, alpha-, gamma- and epsilon-proteobacteria) that likely participate in the oxidationORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation at a biogeochemical hot spot in the dark

Hansell, Dennis

82

Short communication Influence of molybdenum and sulfur on copper  

E-Print Network (OSTI)

Short communication Influence of molybdenum and sulfur on copper metabolism in sheep: comparison of molybdenum able to trigger the copper sulfur molybdenum interference in sheep was measured with either only) and 4 increasing molybdenum doses. The sulfur-molybdenum-copper interference was quantified

Paris-Sud XI, Université de

83

A novel lithium/sulfur battery based on sulfur/graphene nanosheet composite cathode and gel polymer electrolyte  

Science Journals Connector (OSTI)

A novel sulfur/graphene nanosheet (S/GNS) composite was prepared ... ball milling of sulfur with commercial multi-layer graphene nanosheet, followed by a heat treatment. ... of irregularly interlaced nanosheet-li...

Yongguang Zhang; Yan Zhao; Zhumabay Bakenov

2014-03-01T23:59:59.000Z

84

A simple approach to synthesize nanosized sulfur/graphene oxide materials for high-performance lithium/sulfur batteries  

Science Journals Connector (OSTI)

We report on a simple and facile synthesis route for the sulfur/graphene oxide composite via ultrasonic mixing of the nano-sulfur and graphene oxide aqueous suspensions followed by a low-temperature heat treat...

Yongguang Zhang; Yan Zhao; Zhumabay Bakenov

2014-07-01T23:59:59.000Z

85

The GraduaTe school of educaTion newsleTTer | suMMer 2013 Project learn  

E-Print Network (OSTI)

The The GraduaTe school of educaTion newsleTTer | suMMer 2013 Project learn: Vision to Reality . . . One Project at a Time continued on page 3 f or the second year, Dr. Erin Washburn, from Project LEARN, along with the Windsor Central School District and the Liberty Partnership Program (LPP) at Binghamton

Suzuki, Masatsugu

86

Use of pectino-cellulolytic enzymes for improving extrac-tion of phloem-limited plant viruses as exemplified by  

E-Print Network (OSTI)

Use of pectino-cellulolytic enzymes for improving extrac- tion of phloem-limited plant viruses-persistent manner ; it has been successfully purified using pectino-cellulolytic enzymes. The enzymes (driselaseH 6 along with enzyme or a mixture of enzymes and incubated with shaking. The filtrate was adjusted

Paris-Sud XI, Université de

87

Summary We examined the effects of increased transpira-tion demand on xylem hydraulic conductivity and vulnerabil-  

E-Print Network (OSTI)

in response to high evaporative demand and prevent xylem tensions from reaching values that cause catastrophicSummary We examined the effects of increased transpira- tion demand on xylem hydraulic conductivity potential and water potential differences between the soil and the shoot were similar for desert and montane

Maherali, Hafiz

88

Quand les TIC russissent trop bien dans les organisa-tions : le cas du courrier lectronique chez les managers  

E-Print Network (OSTI)

Quand les TIC réussissent trop bien dans les organisa- tions : le cas du courrier électronique chez dès lors comme un objet de recherche approprié pour étudier la problématique darticulation des TIC un point nodal structurant dans le portefeuille technologique des managers. Mots clefs : TIC

Paris-Sud XI, Université de

89

Volume 83, number 1 CHEMICAL PKYSICS LEZTERS 1 October 1981 BASIS SET CONSIDERATIONS FOR THE CALCULA TION OF GRADIENTS  

E-Print Network (OSTI)

FOR THE CALCULA TION OF GRADIENTS IN THE LCAO FORMALISM Jan ALMLGF and Trygve HELGAKER Department of Ghemist In these expressions, h and g( 1.2) are the one- and &Vo-eleCtrOnparts Of the hamiltonian, `&i and rii,,k[ are the fit

Helgaker, Trygve

90

The newesT addiTion To The UniversiTy of MinnesoTa's BioMedical  

E-Print Network (OSTI)

The newesT addiTion To The UniversiTy of MinnesoTa's BioMedical discovery disTricT is designed The BUilding's collegial and physical relaTionship To neighBoring faciliTies in The U's BioMedical discovery in the U's Biomedical Discovery District. "The brick, precast concrete, and curtain wall vocabulary

Weiblen, George D

91

Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability  

Science Journals Connector (OSTI)

Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability ... The resulting graphene–sulfur composite showed high and stable specific capacities up to ?600 mAh/g over more than 100 cycles, representing a promising cathode material for rechargeable lithium batteries with high energy density. ...

Hailiang Wang; Yuan Yang; Yongye Liang; Joshua Tucker Robinson; Yanguang Li; Ariel Jackson; Yi Cui; Hongjie Dai

2011-06-24T23:59:59.000Z

92

Acoustic plug release indicator  

SciTech Connect

The present invention comprises an acoustic plug release indicator system. The acoustic plug release indicatior system comprises a microphone, recording system and operator listening device.

Carter, E.E. Jr.

1984-09-04T23:59:59.000Z

93

CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER  

SciTech Connect

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

Hobbs, D; Hector Colon-Mercado, H

2007-01-31T23:59:59.000Z

94

Method to prevent sulfur accumulation in membrane electrode assembly  

DOE Patents (OSTI)

A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

Steimke, John L; Steeper, Timothy J; Herman, David T

2014-04-29T23:59:59.000Z

95

Changes in luteinizing hormone-releasing hormone-induced luteinizing hormone release during the estrous cycle using anesthetized cattle  

E-Print Network (OSTI)

- for their assistance and friendship during my program. TABLE OF CONTENTS INTRODUCTION LITERATURE REVIEW Estrual/Menstrual Cycle Regulation Ovarian Steroid Feedback Action in Livestock Ovarian Steroid Feedback Action in Rats Ovarian Steroid Feedback Action... of the pituitary to available LHRH. Ovarian steroids participate in gonadotropin regula- tion, as evidenced by ovariectomy and steroid replacement studies. Removal of all ovarian factors increased LHRH release in rats (Sarkar and Fink, 1980) and sheep (Levine...

Keech, Cheryl Ann

2012-06-07T23:59:59.000Z

96

Sulfur-isotope separation by distillation  

SciTech Connect

Sulfur-isotope separation by low-temperature distillation of hydrogen sulfide was studied in an 8-m, 25-mm diameter distillation column. Column temperature was controlled by a propane-propylene heat pipe. Column packing HETP was measured using nitric oxide in the column. The column was operated at pressures from 45 to 125 kPa. The relative volatility of S-32 vs. S-34 varied from 1.0008 to 1.0014.

Mills, T.R.

1982-01-01T23:59:59.000Z

97

Sulfur/three-dimensional graphene composite for high performance lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract A sulfur/graphene composite is prepared by loading elemental sulfur into three-dimensional graphene (3D graphene), which is assembled using a metal ions assisted hydrothermal method. When used as cathode materials for lithium–sulfur (Li–S) batteries, the sulfur/graphene composite (S@3D-graphene) with 73 wt % sulfur shows a significantly enhanced cycling performance (>700 mAh g?1 after 100 cycles at 0.1C rate with a Coulombic efficiency > 96%) as well as high rate capability with a capacity up to 500 mAh g?1 at 2C rate (3.35 A g?1). The superior electrochemical performance could be attributed to the highly porous structure of three-dimensional graphene that not only enables stable and continue pathway for rapid electron and ion transportation, but also restrain soluble polysulfides and suppress the “shuttle effect”. Moreover, the robust structure of 3D graphene can keep cathode integrity and accommodate the volume change during high-rate charge/discharge processes, making it a promising candidate as cathode for high performance Li–S batteries.

Chunmei Xu; Yishan Wu; Xuyang Zhao; Xiuli Wang; Gaohui Du; Jun Zhang; Jiangping Tu

2015-01-01T23:59:59.000Z

98

Development of the Hybrid Sulfur Thermochemical Cycle  

SciTech Connect

The production of hydrogen via the thermochemical splitting of water is being considered as a primary means for utilizing the heat from advanced nuclear reactors to provide fuel for a hydrogen economy. The Hybrid Sulfur (HyS) Process is one of the baseline candidates identified by the U.S. Department of Energy [1] for this purpose. The HyS Process is a two-step hybrid thermochemical cycle that only involves sulfur, oxygen and hydrogen compounds. Recent work has resulted in an improved process design with a calculated overall thermal efficiency (nuclear heat to hydrogen, higher heating value basis) approaching 50%. Economic analyses indicate that a nuclear hydrogen plant employing the HyS Process in conjunction with an advanced gas-cooled nuclear reactor system can produce hydrogen at competitive prices. Experimental work has begun on the sulfur dioxide depolarized electrolyzer, the major developmental component in the cycle. Proof-of-concept tests have established proton-exchange-membrane cells (a state-of-the-art technology) as a viable approach for conducting this reaction. This is expected to lead to more efficient and economical cell designs than were previously available. Considerable development and scale-up issues remain to be resolved, but the development of a viable commercial-scale HyS Process should be feasible in time to meet the commercialization schedule for Generation IV gas-cooled nuclear reactors.

Summers, William A.; Steimke, John L

2005-09-23T23:59:59.000Z

99

RMOTC - News - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

Press Releases Press Releases January Sale of Equipment and Materials Janurary 2014 | Press Releases Read Press Release here. Department of Energy to Sell NPR-3 July 2013 | Press Releases Read Press Release here. View Secretary of Energy Ernest Moniz's Report to Congress here. Press Releases Archive STWA, Inc. to determine the performance of its Applied Oil Technology (AOT(tm)) in reducing crude oil's viscosity to lower transportation costs (PDF) June 2011 | Press Releases Geothermal research initiative at RMOTC (PDF) October 2009 | Press Releases RMOTC partner receives award for tech tested at Teapot Dome (PDF) August 2009 | Press Releases Summer interns work with RMOTC engineers August 2009 | Articles | Casper Journal College, business, government officials launch wind project

100

Process for production of synthesis gas with reduced sulfur content  

DOE Patents (OSTI)

A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Sulfide catalysts for reducing SO2 to elemental sulfur  

DOE Patents (OSTI)

A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

2001-01-01T23:59:59.000Z

102

Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Advanced Materials Find More Like This Return to Search LithiumSulfur Batteries Based on Doped Mesoporous Carbon Oak Ridge National Laboratory Contact ORNL About...

103

Analyses of sulfur-asphalt field trials in Texas  

E-Print Network (OSTI)

128 LIST OF FIGURES FIGURE PAGF Layout of SNPA sulfur bitumen binder pavem nt test ? U. S. Highway 69, Lufkin, Texas 15 Col 1oi d mi 1 1 furnished by SNPA for preparation of sul fur-asphalt emulsions View of mixing station showing sulfur... designed to investigate the advantage of using a colloid mill to prepare sulfur-asphalt binders as compared to comingling the asphalt and molten sulfur in a pipeline leading directly to the pug mill. After only six months of testing, the results...

Newcomb, David Edward

1979-01-01T23:59:59.000Z

104

Development of sulfur cathode material for Li-S batteries.  

E-Print Network (OSTI)

??M.S. Efforts were taken to fabricate a cathode material having Sulfur as the active material. First step is composed of identifying potential ways of fabricating… (more)

Dharmasena, Ruchira Ravinath, 1984-

2014-01-01T23:59:59.000Z

105

Project Profile: Baseload CSP Generation Integrated with Sulfur...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Related Links FAQs Contact Us Offices You are here Home Concentrating Solar Power Project Profile: Baseload CSP Generation Integrated with Sulfur-Based...

106

SULFUR-TOLERANT CATALYST FOR THE SOLID OXIDE FUEL CELL.  

E-Print Network (OSTI)

??JP-8 fuel is easily accessible, transportable, and has hydrogen content essential to solid oxide fuel cell (SOFC) operation. However, this syngas has sulfur content which… (more)

Bozeman, Joe Frank, III

2010-01-01T23:59:59.000Z

107

Fundamental Studies of Lithium-Sulfur Cell Chemistry  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Studies of Lithium-Sulfur Cell Chemistry PI: Nitash Balsara LBNL June 17, 2014 Project ID ESS224 This presentation does not contain any proprietary, confidential, or otherwise...

108

Abatement of Air Pollution: Control of Sulfur Compound Emissions  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Abatement of Air Pollution: Control of Sulfur Compound Emissions Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection These regulations set limits on the sulfur content of allowable fuels (1.0%

109

Sulfur isotopes in coal constrain the evolution of the Phanerozoic sulfur cycle  

Science Journals Connector (OSTI)

...obviously influence the average isotope values. For the other data, samples...pp 87–105 . 19 Price FT Casagrande DJ ( 1991 ) Sulfur...coals. Geology of Fossil Fuels, Proc 30th Int Geol Congress...Jersey Pinelands and its effect on stream water chemistry...223 – 248 . 29 Price FT Shieh YN ( 1979 ) Fractionation...

Donald E. Canfield

2013-01-01T23:59:59.000Z

110

SYNTHESIS OF SULFUR-BASED WATER TREATMENT AGENT FROM SULFUR DIOXIDE WASTE STREAMS  

SciTech Connect

We propose a process that uses sulfur dioxide from coal combustion as a raw material to synthesize polymeric ferric sulfate (PFS), a water treatment agent. The process uses sodium chlorate as an oxidant and ferrous sulfate as an absorbent. The major chemical mechanisms in this reaction system include oxidation, hydrolysis, and polymerization. Oxidation determines sulfur conversion efficiency while hydrolysis and polymerization control the quality of product. Many factors, including SO{sub 2} inlet concentration, flow rate of simulated flue gas, reaction temperature, addition rate of oxidant and stirring rate, may affect the efficiencies of SO{sub 2} removal. Currently, the effects of SO{sub 2} inlet concentration, the flow rate of simulated flue gas and addition rate of flue gas on removal efficiencies of SO{sub 2}, are being investigated. Experiments shown in this report have demonstrated that the conversion efficiencies of sulfur dioxide with ferrous sulfate as an absorbent are in the range of 60-80% under the adopted process conditions. However, the conversion efficiency of sulfur dioxide may be improved by optimizing reaction conditions to be investigated. Partial quality indices of the synthesized products, including Fe{sup 2+} concentration and total iron concentration, have been evaluated.

Robert C. Brown; Maohong Fan

2001-12-01T23:59:59.000Z

111

SRS - News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

6/2014 6/2014 SEARCH GO spacer News Releases govDELIVERY Video Releases Fact Sheets Photo Gallery Speakers Media Contacts SRS Home SRS News Releases News releases are in PDF format (requires Acrobat Reader - click here to download). * 2013 News Releases * 2012 News Releases * 2011 News Releases * 2010 News Releases 2013: 12.31.13 Dr. Sam Fink Earns Donald Orth Lifetime Achievement Award 12.31.13 Savannah River Remediation Issues Fiscal Year 2013 Annual Report 12.18.13 Prototype System Brings Advantages of Wireless Technology to Secure Environment 12.16.13 Registration for the 2014 SRS Public Tour Program Begins December 30 12.12.13 Area Children to Benefit from SRS "Toys for Tots" Campaign 12.10.13 Ruth Patrick's Work Opens Doors for SRNL Environmental Remediation

112

DOCUMENT RELEASE FORM  

NLE Websites -- All DOE Office Websites (Extended Search)

Change El Complete Revision (6) Document Title: Visual Inspection Plan for Single-Shell Tanks and Double-Shell Tanks (7) ChangeRelease Initial Release Description: (8) Change NA...

113

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

NEWS MEDIA CONTACTS (Fermilab) Donald Sena, 630840-5678 Judy Jackson, 630840-3351 December 8, 1997 For immediate release Attached and below is the joint press release from the...

114

Preliminary Release: August 19, 2011",,,,,,,,,,,,,"Released: April 2013","Releas  

U.S. Energy Information Administration (EIA) Indexed Site

,,,,,,,,,,,,,"Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 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115

Lithium–sulfur batteries: Influence of C-rate, amount of electrolyte and sulfur loading on cycle performance  

Science Journals Connector (OSTI)

Abstract In the past four years major improvement of the lithium sulfur battery technology has been reported. Novel carbon cathode materials offer high sulfur loading, sulfur utilization and cycle stability. An often neglected aspect is that sulfur loading and amount of electrolyte strongly impact the performance. In this paper, we demonstrate how the amount of electrolyte, sulfur loading, lithium excess and cycling rate influences the cycle stability and sulfur utilization. We chose vertically aligned carbon nanotubes (VA-CNT) as model system with a constant areal loading of carbon. For a high reproducibility, decreased weight of current collector and good mechanical adhesion of the VA-CNTs we present a layer transfer technique that enables a light-weight sulfur cathode. The sulfur loading of the cathode was adjusted from 20 to 80 wt.-%. Keeping the total amount of electrolyte constant and varying the C-rate, we are able to demonstrate that the capacity degradation is reduced for high rates, high amount of electrolyte and low sulfur loading. In addition idle periods in the cycling regiment and lower rates result in an increased degradation. We attribute this to the redox-reaction between reactive lithium and polysulfides that correlates with the cycling time, rather than cycle number.

Jan Brückner; Sören Thieme; Hannah Tamara Grossmann; Susanne Dörfler; Holger Althues; Stefan Kaskel

2014-01-01T23:59:59.000Z

116

NEWS RELEASE PRESSOFFICE  

E-Print Network (OSTI)

NEWS RELEASE PRESSOFFICE Release Date: April 18, 2008 Contact: Christine Mangi (202) 205-6948 Release Number: 08-35 Internet Address: www.sba.gov/news/ SBA TO PARTNER WITH THE U.S.-INDIA BUSINESS development programs and services, disseminate current SBA news and information, provide speakers for SBA

117

Using ISC & GIS to predict sulfur deposition from coal-fired power plants  

E-Print Network (OSTI)

The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power...

Lopez, Jose Ignacio

2012-06-07T23:59:59.000Z

118

STATEMENT OF C01 SIDER.!;.TIONS RE Q UE ST BY INVENTOR FOR THE WAIVER OF DOMESTIC AN  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

C01 SIDER.!;.TIONS C01 SIDER.!;.TIONS RE Q UE ST BY INVENTOR FOR THE WAIVER OF DOMESTIC AN D FOREIGN RTGHTS TO AN IDE. TIFIED [NVEN'fl0'\1 ENTiTLED "RESONANT-CAVITY APPA.RATUS FOR CYTOM.GTRY OR PARTICLE ANA L'YS iS'' US P 5,793,485, DEVELOPI·:D UNDER DOE CONTRACT NO. DE-AC04-94AL85000; DOE r:\"VENTfON DISCLOSU RE NO. S-85,819 (SD-5797 ); DOE WAIV ER NO. V.l ( ) 201 l-oo_,; rv3 The Petitioner, Paul L. Gourley (Inventor), has requested a \\'aive of the Government's domestic and fo eign patent rights in a subject invention entitled "Resonant-Cavi ty Apparatus for Cytome ry or Particle Analy·sis." The invention v,·as conceived by the inventor while an employee of the Sandia Corporation (Sandia). ,'andia is the M&O contractor for the Sandia a ional Laboratories (S L), a government-0\vned, contracto

119

Integrated boiler, superheater, and decomposer for sulfuric acid decomposition  

DOE Patents (OSTI)

A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

2010-01-12T23:59:59.000Z

120

HEALTH AND CLIMATE POLICY IMPACTS ON SULFUR EMISSION CONTROL  

E-Print Network (OSTI)

the climate and health effects of sulfate aerosol into an integrated-assessment model of fossil fuel emission warming and health simultaneously will support more stringent fossil fuel and sulfur controls control. Our simulations show that a policy that adjusts fossil fuel and sulfur emissions to address both

Russell, Lynn

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Metal-sulfur type cell having improved positive electrode  

DOE Patents (OSTI)

An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

Dejonghe, Lutgard C. (Berkeley, CA); Visco, Steven J. (Berkeley, CA); Mailhe, Catherine C. (Berkeley, CA); Armand, Michel B. (St. Martin D'Uriage, FR)

1989-01-01T23:59:59.000Z

122

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

May 2011 CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries "This presentation does not contain any proprietary, confidential, or otherwise...

123

E-Print Network 3.0 - amoco sulfur recovery process Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Medicine 80 Sulfur and oxygen isotope composition of the atmosphere in Saxony (Germany) Tichomirowa et al. Summary: ? a) Mixing processes 12;Sulfur and oxygen isotope...

124

The solubility of sulfur hexafluoride in water and seawater  

Science Journals Connector (OSTI)

The concentration of sulfur hexafluoride (SF6) in the atmosphere has been rapidly increasing during the past several decades. This long-lived compound enters the surface ocean by air–sea gas exchange and is potentially a very useful transient tracer for studying ocean circulation and mixing. SF6 has also been directly injected into the ocean at a minimal number of locations as a part of deliberate tracer release experiments to study gas exchange and sub-surface mixing rates. In this study, laboratory measurements of the solubility of SF6 in water and seawater were made over the temperature range of ??0.5°C to 40°C. Volumes of water and seawater held at constant temperature in glass chambers were equilibrated with a gas mixture containing SF6 and CFC-12 (CF2Cl2) at parts-per-trillion levels in nitrogen. Small volume water samples were analyzed by electron capture gas chromatography. Using the method of least squares, equations previously used in describing gas solubility as a function of temperature and salinity were fit to the SF6 and CFC-12 measurements. The CFC-12 results were in good agreement with previous work, while substantial differences were found between these SF6 results and those reported in earlier studies. The mean error for the analytical measurements is estimated to be ?0.5%. Based on errors in the fits and the analytical errors, we estimate the overall accuracy of the SF6 solubility function to be of the order of 2%. The results from this work should be useful in determining equilibrium concentrations for SF6 in ocean observation and modeling studies.

John L Bullister; David P Wisegarver; Frederick A Menzia

2002-01-01T23:59:59.000Z

125

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

126

Campus Sustainability Planetary Health Ecological Design Social and Environmental Enterprise Incuba-tion EcoVillages Sustainable Food Systems Ecoliteracy Solutions Journal Campus Systems Model Energy  

E-Print Network (OSTI)

Villages Sustainable Food Systems Ecoliteracy Solutions Journal Campus Systems Model Energy Conservation, Efficiency1 Campus Sustainability Planetary Health Ecological Design Social and Environmental Enterprise Incuba- tion EcoVillages Sustainable Food Systems Ecoliteracy Solutions Journal Campus Systems Model

Hayden, Nancy J.

127

Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Final technical report, 1 September, 1992--31 August, 1993  

SciTech Connect

The goals of this project are to investigate the behavior of sulfur and chlorine during pyrolysis and combustion of Illinois coals, the chemistry and mineralogy of boiler deposits, the effects of combustion gases on boiler materials, and remedial measures to reduce the sulfur and chlorine compounds in combustion gases. Replicate determinations of chlorine and sulfur evolution during coal pyrolysis-gas combustion were conducted using a pyrolysis apparatus in conjunction with a quadrupole gas analyzer. HCl is the only gaseous chlorine species measured in combustion gases. Pyrolysis of coal IBC-109 spiked with NaCl solution shows a strong peak of HCl evolution above 700C. The absence of this peak during pyrolysis of Illinois coal indicates that little chlorine in Illinois coal occurs in the NaCl form. Evolution of sulfur during coal pyrolysis was studied; the sulfur evolution profile may be explained by the sulfur forms in coal. To determine the fate of sulfur and chlorine during combustion, a set of six samples of boiler deposits from superheater and reheater tubes of an Illinois power plant was investigated. Scanning electron microscopy shows microscopic calcium sulfate droplets on cenospheres. Superheater deposits are high in mullite, hematite, and cristobalite, whereas a reheater deposit is enriched in anhydrite. The chlorine content is very low, indicating that most of the chlorine in the feed coal is lost as volatile HCl during he combustion process. The profiles of SO{sub 2} released during combustion experiments at 825 C indicate that calcium hydroxide added to the coal has a significant effect on reducing the SO{sub 2} vapors in combustion gases.

Chou, C.L.; Hackley, K.C.; Cao, J.; Moore, D.M.; Xu, J.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Upchurch, M.L.; Cao, H.B. [Western Kentucky Univ., Bowling Green, KY (United States)

1993-12-31T23:59:59.000Z

128

ORISE: Current News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

News Releases News Releases Official announcements released by the Oak Ridge Institute for Science and Education (ORISE) are listed below. News releases are sortable by date, headline or topic. For news releases from previous years, please visit our News Archives. Recent News Releases Date Title 07/15/2013 College of American Pathologists renews accreditation of beryllium laboratory managed by ORAU 06/12/2013 Top graduate students from U.S. convene with Nobel Laureates in Lindau, Germany 12/03/2012 DOE recognizes partnership with ORAU for long-time management of Tennessee Science Bowl 09/10/2012 Evasius selected as ORAU's vice president and director of science education programs 03/12/1012 ORAU Receives Another Safety Site Star of Excellence 01/18/2012 Study finds foreign doctorate recipients' stay rates remain high

129

Potential Release Sites  

NLE Websites -- All DOE Office Websites (Extended Search)

PRS PRS Potential Release Sites Legacy sites where hazardous materials are found to be above acceptable levels are collectively called potential release sites. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Less than 10 percent of the total number of potential release sites need to go through the full corrective action process. What are potential release sites? Potential release sites are areas around the Laboratory and the town of Los Alamos at which hazardous materials from past activities have been found. Some examples of potential release sites include septic tanks and associated drain lines chemical storage areas wastewater outfalls material disposal areas incinerators sumps firing ranges

130

NREL: News - News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

Releases Releases NREL's Public Relations Office works with media outlets on news stories about the laboratory and renewable energy and energy efficiency technologies. You may subscribe to receive new NREL releases by email or via RSS feed. NREL News Releases RSS Feed (XML) Search All News Releases Search Help 2014 News Releases January 6, 2014 NREL Expert Honored for Energy Systems Innovations The Energy Department's National Renewable Energy Laboratory (NREL) recently won several prestigious awards, including honors for innovations in window air-conditioning efficiency, data sharing, and its energy-efficient computer data center. January 2, 2014 NREL Finds a New Cellulose Digestion Mechanism by a Fast-eating Enzyme Researchers at the Energy Department's National Renewable Energy

131

Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3  

SciTech Connect

The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

132

NETL 2007 News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

7 News Releases 7 News Releases News Releases issued in: 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 December 18, 2007 Energy Department Awards $66.7 Million for Large-Scale Carbon Sequestration Project DOE awarded $66.7 million to the Midwest Geological Sequestration Consortium for the Department's fourth large scale carbon sequestration project. December 06, 2007 DOE Estimates Future Water Needs for Thermoelectric Power Plants The Office of Fossil Energy's National Energy Technology Laboratory has released a 2007 update to its groundbreaking study, "Estimating Freshwater Needs to Meet Future Thermoelectric Generation Requirements." December 05, 2007 Tax Credit Program Promotes Advanced Coal Power Generation and Gasification Technologies

133

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

RELEASE Press Contacts Judy Treend, Fermilab, (630) 840 3351 New exhibit on accelerators in medicine at Fermilab A new exhibit, Pulse: Accelerator Science in Medicine...

134

WIPP News Releases - 1999  

NLE Websites -- All DOE Office Websites (Extended Search)

9 News Releases DOE's Barbara Smith Returns to Carlsbad -- December 13 Nine WIPP Employees Taken to Hospital as Precaution Following Acid Spill -- December 8 Project Management...

135

Accidental Release Program (Delaware)  

Energy.gov (U.S. Department of Energy (DOE))

The Delaware Accidental Release Prevention Regulation contains requirements for owners or operators of stationary sources having regulated extremely hazardous substances onsite to develop and...

136

The use of starch matrices in slow release fungicide formulations and their efficacy in controlling Phymatotrichum omnivorum on cotton  

E-Print Network (OSTI)

P. omnivorum 23 First Experiment ? In Vitro Analysis of Hyphal Inhibition. Second Experiment - In Vitro Analysis of Inhib1tion of Sclerotial Germination. . . . . 23 24 Evaluation of the Release of Propiconazole from the Starch Matrices under... pesticide. . . . . . . . . . . . 14 Growth of Ph matotr1chum omnivorum hyphae on potato dextrose agar amended w1th decanted incubation water of slow release starch matrices with entrapped propiconazo le. . . . . . . . 46 Ouench curves for three starch...

Small, Theresa Marie

1984-01-01T23:59:59.000Z

137

Terpolymerization of ethylene, sulfur dioxide and carbon monoxide  

DOE Patents (OSTI)

This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

1981-01-01T23:59:59.000Z

138

Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams  

SciTech Connect

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjan

1999-09-30T23:59:59.000Z

139

Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams  

DOE Patents (OSTI)

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjani

2004-06-01T23:59:59.000Z

140

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents (OSTI)

A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

2013-08-13T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Fate of Sulfur, Chlorine, Alkali Metal, and Vanadium Species during High-Temperature Gasification of Canadian Tar Sand Products  

Science Journals Connector (OSTI)

Co-feed of alternative fuels, e.g., petcoke, gains increasing importance for energy conversion in not only Germany but also worldwide. ... The aim of this work was to obtain detailed information on the influence of fuel composition of the refinery product line tar sand, bitumen, and petcoke in comparison to the standard fuel hard coal on the release of sodium, potassium, chlorine, sulfur, and vanadium species during high-temperature gasification. ... In addition to the pure fuels, blends of hard coal and petcoke were gasified in lab-scale experiments in a helium/oxygen atmosphere at 1500 °C. ...

Marc Bläsing; Kaveh Nazeri; Michael Müller

2014-10-01T23:59:59.000Z

142

Martinez Sulfuric Acid Regeneration Plt Biomass Facility | Open Energy  

Open Energy Info (EERE)

Martinez Sulfuric Acid Regeneration Plt Biomass Facility Martinez Sulfuric Acid Regeneration Plt Biomass Facility Jump to: navigation, search Name Martinez Sulfuric Acid Regeneration Plt Biomass Facility Facility Martinez Sulfuric Acid Regeneration Plt Sector Biomass Facility Type Non-Fossil Waste Location Contra Costa County, California Coordinates 37.8534093°, -121.9017954° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.8534093,"lon":-121.9017954,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

143

Diesel Emissions Control-Sulfur Effects (DECSE) Program Status  

SciTech Connect

Determine the impact of fuel sulfur levels on emission control systems that could be implemented to lower emissions of NO{sub x} and PM from on-highway trucks in the 2002-2004 time frame.

None

1999-06-29T23:59:59.000Z

144

Hybrid Microfabricated Device for Field Measurement of Atmospheric Sulfur Dioxide  

Science Journals Connector (OSTI)

It is also now generally agreed that forthcoming major volcanic eruptions will sensitively monitored for increasing sulfur gas emissions as indicated by increasing seismic activity. ... (12)?Fish, B. R.; Durham, J. L. Environ. ...

Shin-Ichi Ohira; Kei Toda; Shin-Ichiro Ikebe; Purnendu K. Dasgupta

2002-10-10T23:59:59.000Z

145

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

146

Molten iron oxysulfide as a superior sulfur sorbent. Final report, [September 1989--1993  

SciTech Connect

The studies had as original objective the analysis of conditions for using liquid iron oxysulfide as a desulfuring agent during coal gasification. Ancillary was a comparison of iron oxysulfide with lime as sorbents under conditions where lime reacts with S-bearing gases to form Ca sulfate or sulfide. Primary thrust is to determine the thermodynamic requirements for desulfurization by iron additions (e.g., taconite concentrate) during combustion in gasifiers operating at high equivalence ratios. Thermodynamic analysis of lime-oxygen-sulfur system shows why lime is injected into burners under oxidizing conditions; reducing conditions forms CaS, requiring its removal, otherwise oxidation and release of S would occur. Iron as the oxysulfide liquid has a range of stability and can be used as a desulfurizing agent, if the burner/gasifier operates in a sufficiently reducing regime (high equivalence ratio); this operating range is given and is calculable for a coal composition, temperature, stoichiometry. High moisture or hydrogen contents of the coal yield a poorer degree of desulfurization. Kinetic tests on individual iron oxide particles on substrates or Pt cups with a TGA apparatus fail to predict reaction rates within a burner. Preliminary tests on the Dynamic Containment Burner with acetylene give some promise that this system can produce the proper conditions of coal gasification for use of added iron as a sulfur sorbent.

Hepworth, M.T.

1993-03-31T23:59:59.000Z

147

Novel Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells  

SciTech Connect

One of the unique advantages of SOFCs over other types of fuel cells is the potential for direct utilization of hydrocarbon fuels (it may involve internal reforming). Unfortunately, most hydrocarbon fuels contain sulfur, which would dramatically degrade SOFC performance at parts-per-million (ppm) levels. Low concentration of sulfur (ppm or below) is difficult to remove efficiently and cost-effectively. Therefore, knowing the exact poisoning process for state-of-the-art anode-supported SOFCs with Ni-YSZ cermet anodes, understanding the detailed anode poisoning mechanism, and developing new sulfur-tolerant anodes are essential to the promotion of SOFCs that run on hydrocarbon fuels. The effect of cell operating conditions (including temperature, H{sub 2}S concentration, cell voltage/current density, etc.) on sulfur poisoning and recovery of nickel-based anode in SOFCs was investigated. It was found that sulfur poisoning is more severe at lower temperature, higher H{sub 2}S concentration or lower cell current density (higher cell voltage). In-situ Raman spectroscopy identified the nickel sulfide formation process on the surface of a Ni-YSZ electrode and the corresponding morphology change as the sample was cooled in H{sub 2}S-containing fuel. Quantum chemical calculations predicted a new S-Ni phase diagram with a region of sulfur adsorption on Ni surfaces, corresponding to sulfur poisoning of Ni-YSZ anodes under typical SOFC operating conditions. Further, quantum chemical calculations were used to predict the adsorption energy and bond length for sulfur and hydrogen atoms on various metal surfaces. Surface modification of Ni-YSZ anode by thin Nb{sub 2}O{sub 5} coating was utilized to enhance the sulfur tolerance. A multi-cell testing system was designed and constructed which is capable of simultaneously performing electrochemical tests of 12 button cells in fuels with four different concentrations of H{sub 2}S. Through systematical study of state-of-the-art anode-supported SOFC button cells, it is seen that the long-term sulfur poisoning behavior of those cells indicate that there might be a second-stage slower degradation due to sulfur poisoning, which would last for a thousand hour or even longer. However, when using G-18 sealant from PNNL, the 2nd stage poisoning was effectively prohibited.

Lei Yang; Meilin Liu

2008-12-31T23:59:59.000Z

148

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Final report  

SciTech Connect

This project has investigated new metal oxide catalysts for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as CO. Significant progress in catalyst development has been made during the course of the project. We have found that fluorite oxides, CeO{sub 2} and ZrO{sub 2}, and rare earth zirconates such as Gd{sub 2}Zr{sub 2}O{sub 7} are active and stable catalysts for reduction Of SO{sub 2} by CO. More than 95% sulfur yield was achieved at reaction temperatures about 450{degrees}C or higher with the feed gas of stoichiometric composition. Reaction of SO{sub 2} and CO over these catalysts demonstrated a strong correlation of catalytic activity with the catalyst oxygen mobility. Furthermore, the catalytic activity and resistance to H{sub 2}O and CO{sub 2} poisoning of these catalysts were significantly enhanced by adding small amounts of transition metals, such as Co, Ni, Co, etc. The resulting transition metal-fluorite oxide composite catalyst has superior activity and stability, and shows promise in long use for the development of a greatly simplified single-step sulfur recovery process to treat variable and dilute SO{sub 2} concentration gas streams. Among various active composite catalyst systems the Cu-CeO{sub 2} system has been extensively studied. XRD, XPS, and STEM analyses of the used Cu-CeO{sub 2} catalyst found that the fluorite crystal structure of ceria was stable at the present reaction conditions, small amounts of copper was dispersed and stabilized on the ceria matrix, and excess copper oxide particles formed copper sulfide crystals of little contribution to catalytic activity. A working catalyst consisted of partially sulfated cerium oxide surface and partially sulfided copper clusters. The overall reaction kinetics were approximately represented by a first order equation.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1995-06-01T23:59:59.000Z

149

METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY  

SciTech Connect

HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

2009-06-22T23:59:59.000Z

150

Low temperature fracture evaluation of plasticized sulfur paving mixtures  

E-Print Network (OSTI)

May 1985 Major Subject: Civil Engineering LOW TEMPERATURE FRACTURE EVALUATION OF PLASTICIZED SULFUR PAVING MIXTURES A Thesis by KAMYAR MAHBOUB Approved as to style and content by: Dallas N. Li tie (Chai rman of Committee) Ro e . Lytto Member... modifications to the standard ASTM procedure. These modifications were required due to the nature of plasticized sulfur mixtures and asphalt cement mixtures. The J-integral version of Paris ' law was successfully used to characterize the fatigue...

Mahboub, Kamyar

2012-06-07T23:59:59.000Z

151

Recent advances in lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithium–sulfur (Li–S) batteries have attracted much attention lately because they have very high theoretical specific energy (2500 Wh kg?1), five times higher than that of the commercial LiCoO2/graphite batteries. As a result, they are strong contenders for next-generation energy storage in the areas of portable electronics, electric vehicles, and storage systems for renewable energy such as wind power and solar energy. However, poor cycling life and low capacity retention are main factors limiting their commercialization. To date, a large number of electrode and electrolyte materials to address these challenges have been investigated. In this review, we present the latest fundamental studies and technological development of various nanostructured cathode materials for Li–S batteries, including their preparation approaches, structure, morphology and battery performance. Furthermore, the development of other significant components of Li–S batteries including anodes, electrolytes, additives, binders and separators are also highlighted. Not only does the intention of our review article comprise the summary of recent advances in Li–S cells, but also we cover some of our proposals for engineering of Li–S cell configurations. These systematic discussion and proposed directions can enlighten ideas and offer avenues in the rational design of durable and high performance Li–S batteries in the near future.

Lin Chen; Leon L. Shaw

2014-01-01T23:59:59.000Z

152

Heat Transfer Characteristics of Sulfur and Sulfur Diluted with Hydrogen Sulfide Flowing Through Circular Tubes  

E-Print Network (OSTI)

is called the pumping-power advantage factor, and has the value 2. 5 x 10 for sodium. The only metals having a higher value of H are 13 lithium 7 and bismuth. Lithium 7 comprises 92. 5% of natural lithium, but the cost of separating it from lithium 6...-section for thermal neutrons being 0. 130 barns. For comparison, water has an absorption cross-section of 0. 58 barns for thermal neutrons (2) . Sulfur is not activated by exposure to neutron flux in such a way as to produce a radioactive isotope which...

Stone, Porter Walwyn

1960-01-01T23:59:59.000Z

153

S_ Science Service Feature Released on receipt  

E-Print Network (OSTI)

cavern has two openings at different levels. In winter the circula- tion is reversed, at the top as from

154

Polyaniline-modified cetyltrimethylammonium bromide-graphene oxide-sulfur nanocomposites with enhanced performance for lithium-sulfur batteries  

Science Journals Connector (OSTI)

Conductive polymer coatings can boost the power storage capacity of lithium-sulfur batteries. We report here on the design and ... polyaniline (PANI)-modified cetyltrimethylammonium bromide (CTAB)-graphene oxide ...

Yongcai Qiu; Wanfei Li; Guizhu Li; Yuan Hou; Lisha Zhou; Hongfei Li…

2014-09-01T23:59:59.000Z

155

COMPONENT DEVELOPMENT NEEDS FOR THE HYBRID SULFUR ELECTROLYZER  

SciTech Connect

Fiscal year 2008 studies in electrolyzer component development have focused on the characterization of membrane electrode assemblies (MEA) after performance tests in the single cell electrolyzer, evaluation of electrocatalysts and membranes using a small scale electrolyzer and evaluating the contribution of individual cell components to the overall electrochemical performance. Scanning electron microscopic (SEM) studies of samples taken from MEAs testing in the SRNL single cell electrolyzer test station indicates a sulfur-rich layer forms between the cathode catalyst layer and the membrane. Based on a review of operating conditions for each of the MEAs evaluated, we conclude that the formation of the layer results from the reduction of sulfur dioxide as it passes through the MEA and reaches the catalyst layer at the cathode-membrane interface. Formation of the sulfur rich layer results in partial delamination of the cathode catalyst layer leading to diminished performance. Furthermore we believe that operating the electrolyzer at elevated pressure significantly increases the rate of formation due to increased adsorption of hydrogen on the internal catalyst surface. Thus, identification of a membrane that exhibits much lower transport of sulfur dioxide is needed to reduce the quantity of sulfur dioxide that reaches the cathode catalyst and is reduced to produce the sulfur-rich layer. Three candidate membranes are currently being evaluated that have shown promise from preliminary studies, (1) modified Nafion{reg_sign}, (2) polybenzimidazole (PBI), and (3) sulfonated Diels Alder polyphenylene (SDAPP). Testing examined the activity for the sulfur dioxide oxidation of platinum (Pt) and platinum-alloy catalysts in 30 wt% sulfuric acid solution. Linear sweep voltammetry showed an increase in activity when catalysts in which Pt is alloyed with non-noble transition metals such as cobalt and chromium. However when Pt is alloyed with noble metals, such as iridium or ruthenium, the kinetic activity decreases. We recommend further testing to determine if these binary alloys will provide the increased reaction kinetic needed to meet the targets. We also plan to test the performance of these catalyst materials for both proton and sulfur dioxide reduction. The latter may provide another parameter by which we can control the reduction of sulfur dioxide upon transport to the cathode catalyst surface. A small scale electrolyzer (2 cm{sup 2}) has been fabricated and successfully installed as an additional tool to evaluate the effect of different operating conditions on electrolyzer and MEA performance. Currently this electrolyzer is limited to testing at temperatures up to 80 C and at atmospheric pressure. Selected electrochemical performance data from the single cell sulfur dioxide depolarized electrolyzer were analyzed with the aid of an empirical equation which takes into account the overpotential of each of the components. By using the empirical equation, the performance data was broken down into its components and a comparison of the potential losses was made. The results indicated that for the testing conditions of 80 C and 30 wt% sulfuric acid, the major overpotential contribution ({approx}70 % of all losses) arise from the slow reaction rate of oxidation of sulfur dioxide. The results indicate that in order to meet the target of hydrogen production at 0.5 A/cm{sup 2} at 0.6 V and 50 wt% sulfuric acid, identification of a better catalyst for sulfur dioxide oxidation will provide the largest gain in electrolyzer performance.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-05-30T23:59:59.000Z

156

News Releases | Biosciences Division  

NLE Websites -- All DOE Office Websites (Extended Search)

News Releases News Releases BIO Home Page About BIO News Releases Research Publications People Contact Us Organization Chart Site Index Inside BIO BIO Safety About Argonne Biosciences Division News Releases Protein crystal samples are placed on a small metal tip so X-rays from the adjacent beam pipe can pass through them and diffract off the atoms inside the crystal. Lessening X-ray damage is healthy for protein discovery data too December 16, 2013 - New recommendations for using X-rays promise to speed investigations aimed at understanding the structure and function of biologically important proteins - information critical to the development of new drugs. Read more. Kayakers and boats traverse the branch of the Chicago River in the downtown area Argonne partners with Metropolitan Water Reclamation District to study Chicago River microbe population

157

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

02-26 December 20, 2002 For immediate release Judy Treend, Fermilab, 630-840-3351 Elizabeth Clements, Fermilab, 630-840-3351 Holiday Special: Fermilab's Lederman Science Center...

158

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

03-26 December 19, 2003 For immediate release Press Contact: Elizabeth Clements, Fermilab, 630-840-3351 Fermilab Hosts Virtual Ask-a-Scientist on January 29, 2004 BATAVIA, Ill. -...

159

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

4-11 July 8, 2004 For immediate release Press contact: Tom Jordan, 630-840-4035, jordant@fnal.gov Fermilab Supports Energy Department Science Education Initiative Batavia,...

160

Press Release: Nuclear Power  

Science Journals Connector (OSTI)

Two nuclear physicists, a nuclear engineer, and an economistmmembers of the Union of Concerned Scientists--released a report today that examined a new problem with nuclear reactor safety. According to the repo...

Henry W. Kendall

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

FOR IMMEDIATE RELEASE March 21, 2005 Media contact: Kurt Riesselmann, 630-840-3351 Free tickets & information: 630-840-2787, M-F 9-4 Photos of Jack Liebeck and Brian Foster...

162

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

17 Sept. 28, 2007 Media Contact: Tona Kunz, Fermilab Office of Communication, 630-840-3351, tkunz@fnal.gov For immediate release Volunteers Welcome at Fermilab's Prairie Harvest on...

163

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

March 27 030711 Fermilab offers Family Open House on Sunday, Feb. 27 021611 Dark Energy Survey Poised to Probe Cosmic Speed-Up 011111 Archived Releases 2013 2012 2011 2010...

164

Rad-Release  

ScienceCinema (OSTI)

The R&D 100 Award winning Rad-Release Chemical Decontamination Technology is a highly effective (up to 99% removal rate), affordable, patented chemical-foam-clay decontamination process tailored to specific radiological and metal contaminants, which is applicable to a wide variety of substrates. For more information about this project, visit http://www.inl.gov/rd100/2011/rad-release/

None

2013-05-28T23:59:59.000Z

165

Hybrid Sulfur Thermochemical Process Development Annual Report  

SciTech Connect

The Hybrid Sulfur (HyS) Thermochemical Process is a means of producing hydrogen via water-splitting through a combination of chemical reactions and electrochemistry. Energy is supplied to the system as high temperature heat (approximately 900 C) and electricity. Advanced nuclear reactors (Generation IV) or central solar receivers can be the source of the primary energy. Large-scale hydrogen production based on this process could be a major contributor to meeting the needs of a hydrogen economy. This project's objectives include optimization of the HyS process design, analysis of technical issues and concerns, creation of a development plan, and laboratory-scale proof-of-concept testing. The key component of the HyS Process is the SO2-depolarized electrolyzer (SDE). Studies were performed that showed that an electrolyzer operating in the range of 500-600 mV per cell can lead to an overall HyS cycle efficiency in excess of 50%, which is superior to all other currently proposed thermochemical cycles. Economic analysis indicated hydrogen production costs of approximately $1.60 per kilogram for a mature nuclear hydrogen production plant. However, in order to meet commercialization goals, the electrolyzer should be capable of operating at high current density, have a long operating lifetime , and have an acceptable capital cost. The use of proton-exchange-membrane (PEM) technology, which leverages work for the development of PEM fuel cells, was selected as the most promising route to meeting these goals. The major accomplishments of this project were the design and construction of a suitable electrolyzer test facility and the proof-of-concept testing of a PEM-based SDE.

Summers, William A.; Buckner, Melvin R.

2005-07-21T23:59:59.000Z

166

2010 Report Released | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Released 2010 Report Released January 12, 1987 2010 Report Released Washington, DC White House releases "2010 Report," projecting requirements for maintaining and modernizing...

167

ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT  

SciTech Connect

The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

Amoroso, J.; Fox, K.

2011-09-07T23:59:59.000Z

168

Towards an InTerdIscIplInary approach To nexT-GeneraTIon BIofuels EnvironmEntal, tEchno-Economic, and GovErnancE  

E-Print Network (OSTI)

Towards an InTerdIscIplInary approach To nexT-GeneraTIon BIofuels EnvironmEntal, t. 2010. The Ecological Impact of Biofuels. Pages 351-377 in D. J. Futuyma, H. B. Shafer, and D. Huffer, S., Roche, C.M., Blanch, H.W., and Clark, D.S. (2012). Escherichia coli for biofuel production

Iglesia, Enrique

169

STEP Utility Data Release Form  

Energy.gov (U.S. Department of Energy (DOE))

STEP Utility Data Release Form, from the Tool Kit Framework: Small Town University Energy Program (STEP).

170

Feature - WATER Tool Released  

NLE Websites -- All DOE Office Websites (Extended Search)

Water Assessment for Transportation Energy Resources (WATER) Tool Released Water Assessment for Transportation Energy Resources (WATER) Tool Released Argonne National Laboratory recently released an open access online tool called WATER (Water Assessment for Transportation Energy Resources), which quantifies water footprint of fuel production stages from feedstock production to conversion process for biofuel with county, state, and regional level spatial resolution. WATER provides analysis on water consumption and its impact on water quality. It contains biofuel pathways for corn grain ethanol, soybean biodiesel, and cellulosic ethanol produced from corn stover and wheat straw. Perennial grass (Switchgrass and Miscanthus) and forest wood residue-based biofuel pathways are currently under development. The WATER tool enables users to conduct pathway comparison, scenario development, and regional specific feedstock analysis in supporting of biofuel industry development and planning. It is available at http://water.es.anl.gov/.

171

News Releases - 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

News Releases - 2013 News Releases - 2013 /newsroom/_assets/images/newsroom-icon.jpg News Releases - 2013 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. los alamos acheivements Dateline Los Alamos: Top Science News for 2013 HIV vaccine, Mars water, climate change, birth of a black hole, thwarting terrorists among topics of interest Los Alamos outstanding science and technology achievements for 2013 - 12/24/13 2014 Employee Giving Campaign Nearly $2 million pledged during Los Alamos National Laboratory's 2014 employee giving campaign Lab employee contributions will fund a wide range of programs offered by eligible nonprofit organizations. - 12/17/13 Bradbury Science Museum

172

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Press Release Archive 4 Press Release Archive Recent Releases Fermilab and Berkeley Lab Collaborate with Meyer Tool on Key Component for European Particle Accelerator 12/16/04 NIU launches Institute for Neutron Therapy at Fermilab 12/6/04 Pier Oddone of Berkeley Lab Named Fermilab Director 11/19/04 Fermilab To Host Girl Scout Badge Event on Saturday, November 6 11/4/04 Rocky Kolb to Direct New Fermilab Particle Astrophysics Center 11/1/04 Fermilab Director Witherell One of Eight Directors to Receive Energy Secretary's Gold Award 10/25/04 Fermilab Arts Series Celebrates 30th Anniversary 10/7/04 Fermilab Offers Tours of Antimatter Production Site, October 3 and 24 9/14/04 Fermilab Scientists Present New Physics Results at ICHEP Beijing 8/18/04 How They Spent Their Summer Vacation: QuarkNet Students Experience Real Work of Fermilab Scientists 8/3/04

173

NETL 2008 News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

8 News Releases 8 News Releases News Releases issued in: 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 December 23, 2008 Fossil Energy Research Grants Awarded to Four Minority Universities Continuing its long-standing minority university research program, DOE has selected four institutions where students and faculty will investigate projects dealing with sensors and controls, computational energy sciences, and advanced materials for use in fossil fuel power systems. December 19, 2008 NETLÂ’s Multiphase Flow Research Group Wins INCITE Award The Multiphase Flow Research Group at the National Energy Technology Laboratory (NETL) has won a 2009 Innovative and Novel Computational Impact on Theory and Experiment (INCITE) award from the U.S. Department of Energy for their proposal "Clean and Efficient Coal Gasifier Designs using Large-Scale Simulations."

174

SR 2000 News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

0 News Releases 0 News Releases Nuclear Security Oversight Panel Visits SRS As Part of NNSA Tour - SR-00-01 DOE Security Czar To Visit SRS - SR-00-02 DOE To Present SRS Fiscal Year 2001 Budget - SR-00-03 DOE Releases Accident Investigation Report On FB-Line Workers' Plutonium Intake - SR-00-04 Environmental Management Science Program National Workshop - SR-00-05 DOE Cleanup Science on Display In Atlanta - SR-00-06 Environmental Cleanup Technology Conference Held - SR-00-07 Wackenhut Receives Award Fee - SR-00-08 WSRC Receives Award Fee - SR-00-09 DOE Hosts Radioactive Materials Transportation Workshop - SR-00-10 Energy Secretary To Visit SRS - SR-00-11 "Melt & Dilute" Selected To Treat DOE's Spent Nuclear Fuel At SRS - SR-00-12 Savannah River Operations Office Wins Best Practices Award - SR-00-13

175

NETL 2003 Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

3 Releases 3 Releases News Releases issued in: 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 December 30, 2003 Advanced Natural Gas Turbine Hailed as Top Power Project of 2003 A power plant featuring a next-generation gas turbine developed as part of DOE's advanced turbine systems program has been selected by Power Engineering magazine as one of three 2003 Projects of the Year. December 8, 2003 Historically Black, Other Minority Colleges Encouraged to Compete for Grants for Fossil Energy Research DOE has issued its annual call for fossil fuel research proposals from historically black and other minority colleges and universities. December 5, 2003 Massachusetts Institute of Technology Professor is 2003 Lowry Award Winner The Energy Department's 2003 Homer H. Lowry Award will go to a Massachusetts Institute of Technology professor emeritus whose combustion research continues to influence the design and commercialization of cleaner, 'low NOx' combustors widely used in the power industry.

176

Why sequence Sulfur cycling in the Frasassi aquifer?  

NLE Websites -- All DOE Office Websites (Extended Search)

sulfur cycling in the Frasassi aquifer? sulfur cycling in the Frasassi aquifer? The terrestrial subsurface remains one of the least explored microbial habitats on earth, and is critical for understanding pollutant migration and attenuation, subsurface processes such as limestone dissolution (affecting porosity), and the search for life elsewhere in the solar system and beyond. The deep and sulfidic Frasassi aquifer (of Ancona, Italy) has emerged as a model system for studying sulfur cycling in the terrestrial subsurface, and this sequencing project has relevance for developing applications for wastewater treatment and capabilities relevant for radionuclide, metal and organic pollutant remediation that can be applied at environments at DOE subsurface sites. Principal Investigators: Jennifer Macalady, Penn State University

177

Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria  

NLE Websites -- All DOE Office Websites (Extended Search)

II. Phase Equilibria II. Phase Equilibria Title Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria Publication Type Journal Article Year of Publication 1996 Authors Ridgway, Paul L., Frank R. McLarnon, and John S. Newman Journal Journal of the Electrochemistry Society Volume 143 Issue 2 Pagination 412-417 Keywords 25 ENERGY STORAGE, 36 MATERIALS SCIENCE, ALUMINIUM OXIDES, equilibrium, performance, PHASE DIAGRAMS, PHOSPHIDES, PHOSPHORUS ADDITIONS, SODIUM COMPOUNDS, SODIUM SULFIDES, SODIUM-SULFUR BATTERIES Abstract Equilibrium open-circuit cell voltage data from a sodium/{beta}{double_prime}-alumina/phosphorus-sulfur cell utilizing P/S ratios of 0, 0.143, and 0.332 and a sodium atom fraction ranging from 0 to 0.4 were interpreted to construct ternary phase diagrams of the Na-P-S ternary system at 350 and 400 C.

178

Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results  

SciTech Connect

A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

2004-01-25T23:59:59.000Z

179

Indication of Meissner Effect in Sulfur-Substituted Strontium Ruthenates  

E-Print Network (OSTI)

Ceramic samples of Sr2RuO(4-y)Sy (y=0.03-1.2) with intended isovalent substitution of oxygen by sulfur have been synthesized and explored in the temperature range 4-300K. It is found that at a range of optimum sulfur substitution the magnetic response of ceramic samples reveals large diamagnetic signal with amplitudes approaching comparability with that of the YBCO-superconductors. Contrary to a pure ceramic Sr2RuO4, if properly optimized, the resistivity of sulfur-substituted samples has a metallic behavior except at lower temperatures where an upturn occurs. Both synthesis conditions and results of measurements are reported. The Meissner effect may point to high-temperature superconductivity.

Gulian, Armen

2011-01-01T23:59:59.000Z

180

HYBRID SULFUR ELECTROLYZER DEVELOPMENT FY09 SECOND QUARTER REPORT  

SciTech Connect

The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis that can be powered by heat from high temperature gas reactors. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. This report documents work during the first quarter of Fiscal Year 2009, for the period between January 1, 2009 and March 31, 2009. The HyS Process is a two-step hybrid thermochemical cycle that is part of the 'Sulfur Family' of cycles. As a sulfur cycle, it uses high temperature thermal decomposition of sulfuric acid to produce oxygen and to regenerate the sulfur dioxide reactant. The second step of the process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen by electrochemically reacting sulfur dioxide with H{sub 2}O. The SDE produces sulfuric acid, which is then sent to the acid decomposer to complete the cycle. The DOE NHI program is developing the acid decomposer at Sandia National Laboratory for application to both the HyS Process and the Sulfur Iodine Cycle. The SDE is being developed at SRNL. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency, small footprint and potential for low capital cost, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test with a 60-cm{sup 2} single cell electrolyzer, and designed and built a larger, multi-cell stack electrolyzer. During FY08, SRNL continued SDE development, including development and successful testing of a three-cell electrolyzer stack with a rated capacity of 100 liters per hour. The HyS program for FY09 program will address improving SDE performance by focusing on preventing or minimizing sulfur deposition inside the cell caused by SO{sub 2} crossover, reduction of cell voltage for improved efficiency, an extension of cell operating lifetime. During FY09 a baseline technology development program is being conducted to address each of these issues. Button-cell (2-cm{sup 2}) and single cell (60-cm{sup 2}) SDEs will be fabricated and tested. A pressurized button-cell test facility will be designed and constructed to facilitate addition testing. The single cell test facility will be upgraded for unattended operation, and later for operation at higher temperature and pressure. Work will continue on development of the Gas Diffusion Electrode (GDE), or Gap Cell, as an alternative electrolyzer design approach that is being developed under subcontract with industry partner Giner Electrochemical Systems. If successful, it could provide an alternative means of preventing sulfur crossover through the proton exchange membrane, as well as the possibility for higher current density operation based on more rapid mass transfer in a gas-phase anode. Promising cell components will be assembled into membrane electrode assemblies (MEAs) and tested in the single cell test facility. Upon modification for unattended operation, test will be conducted for 200 hours or more. Both the button-cell and modified single cell facility will be utilized to demonstrate electrolyzer operation without sulfur build-up limitations, which is a Level 1 Milestone.

Herman, D; David Hobbs, D; Hector Colon-Mercado, H; Timothy Steeper, T; John Steimke, J; Mark Elvington, M

2009-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October--December 1993  

SciTech Connect

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range (400--650{degree}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2} formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1993-12-31T23:59:59.000Z

182

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 4, April--June 1993  

SciTech Connect

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant(reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650{degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams, The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.; Williams, R.S.

1993-12-31T23:59:59.000Z

183

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report  

SciTech Connect

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

NONE

1997-01-01T23:59:59.000Z

184

SEPA Press Releases  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

sepa/press-releases Southeastern Power Administration sepa/press-releases Southeastern Power Administration 1166 Athens Tech Rd. Elberton, GA 30635-6711Phone: (706) 213-3800 en ENERGY EFFICIENCY AND RENEWABLE ENERGY REPORT - FY 2013 http://energy.gov/sepa/articles/energy-efficiency-and-renewable-energy-report-fy-2013 ENERGY EFFICIENCY AND RENEWABLE ENERGY REPORT - FY 2013

185

NE Press Releases  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

press-releases 1000 Independence Ave. SWWashington DC press-releases 1000 Independence Ave. SWWashington DC 20585202-586-5000 en Energy Department Announces New Investment in Innovative Small Modular Reactor http://energy.gov/articles/energy-department-announces-new-investment-innovative-small-modular-reactor Energy Department Announces New Investment in Innovative Small Modular Reactor

186

EM Press Releases  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

press-releases Office of Environmental Management 1000 press-releases Office of Environmental Management 1000 Independence Ave., SW Washington, DC 20585 202-586-7709 en Task Order Awarded to Small Business for Natural Gas Services http://energy.gov/em/articles/task-order-awarded-small-business-natural-gas-services Task Order Awarded to Small Business for Natural Gas Services

187

Benzene release. status report  

SciTech Connect

Scoping benzene release measurements were conducted on 4 wt percent KTPB `DEMO` formulation slurry using a round, flat bottomed 100-mL flask containing 75 mL slurry. The slurry was agitated with a magnetic stirrer bar to keep the surface refreshed without creating a vortex. Benzene release measurements were made by purging the vapor space at a constant rate and analyzing for benzene by gas chromatography with automatic data acquisition. Some of the data have been rounded or simplified in view of the scoping nature of this study.

Dworjanyn, L.O. [Westinghouse Savannah River Company, AIKEN, SC (United States); Rappe, K.G.; Gauglitz, P.A. [Pacific Northwest National Lab., Richland, WA (United States)

1997-11-04T23:59:59.000Z

188

Direct sulfur recovery during sorbent regeneration. Final report  

SciTech Connect

The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

1993-08-01T23:59:59.000Z

189

Extraction, separation, and analysis of high sulfur coal. Final report  

SciTech Connect

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. [comps.

1992-05-31T23:59:59.000Z

190

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. (comps.)

1992-05-31T23:59:59.000Z

191

Sulfur dioxide oxidation and plume formation at cement kilns  

SciTech Connect

Results of source sampling at the Glens Falls cement kiln in Glens Falls, N.Y., are reported for sulfur oxides, ammonia, hydrochloric acid, oxygen, and moisture content. The origin of a detached, high-opacity, persistent plume originating from the cement kiln stack is investigated. It is proposed that this plume is due to ammonium salts of SOx and sulfuric acid that have been formed in condensed water droplets in the plume by the pseudocatalytic action of ammonia. (1 diagram, 1 graph, 22 references, 7 tables)

Dellinger, B.; Grotecloss, G.; Fortune, C.R.; Cheney, J.L.; Homolya, J.B.

1980-10-01T23:59:59.000Z

192

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect

This second quarter report of 2002 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. Previous reports described development of a catalyst with the required selectivity and efficiency for producing sulfur dioxide from H{sub 2}S. In the laboratory, the catalyst was shown to be robust and stable in the presence of several intentionally added contaminants, including condensate from the pilot plant site. This report describes testing using the laboratory apparatus but operated at the pilot plant using the actual pilot plant gas, which contains far more contaminants than can be simulated in the laboratory. The results are very encouraging, with stable and efficient operation being obtained for a prolonged period of time.

Girish Srinivas; Steven C. Gebhard; David W. DeBerry

2002-07-01T23:59:59.000Z

193

Energy Release in Earthquakes  

Science Journals Connector (OSTI)

......and Dynamic Electricity. (McGraw-Hill Book Co., New York, 2nd Ed.). Starr A. T. , 1928. Slip in a Crystal...Electromagnetic Theory (McGraw-Hill Book Co., New York). Energy Release in Earthquakes Leon Knopoff (Received 1957......

Leon Knopoff

1958-03-01T23:59:59.000Z

194

Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Tier 2 Vehicle and Tier 2 Vehicle and Gasoline Sulfur Program to someone by E-mail Share Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Facebook Tweet about Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Twitter Bookmark Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Google Bookmark Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Delicious Rank Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Digg Find More places to share Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Tier 2 Vehicle and Gasoline Sulfur Program

195

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System effect and performance...

196

Revisit Carbon/Sulfur Composite for Li-S Batteries. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Revisit CarbonSulfur Composite for Li-S Batteries. Revisit CarbonSulfur Composite for Li-S Batteries. Abstract: To correlate the carbon properties e.g. surface area and porous...

197

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network (OSTI)

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

198

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents (OSTI)

A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

2012-03-06T23:59:59.000Z

199

Ultra-Low Sulfur diesel Update & Future Light Duty Diesel | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ultra-Low Sulfur diesel Update & Future Light Duty Diesel Ultra-Low Sulfur diesel Update & Future Light Duty Diesel Presentation given at DEER 2006, August 20-24, 2006, Detroit,...

200

Sulfur Degassing From Volcanoes: Source Conditions, Surveillance, Plume Chemistry and Earth System Impacts  

E-Print Network (OSTI)

of sulfur in magmas owes much to its multiple valence states (-II, 0, IV, VI), speciation (e.g., S2, H2S, SO on the redox chemistry of sulfur: by reducing sulfur, thiosulfate, sulfite and sulfate to H2S, or oxidizing sulfur and H2S to sulfate (e.g., Takano et al. 1997; Amend and Shock 2001; Shock et al. 2010

Boyer, Edmond

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Sulfur Pollution: Charges That EPA Distorted the Data Are Examined  

Science Journals Connector (OSTI)

...testi-mony on the charges and their implica-tions. It was a marathon session in-volving more than 20 witnesses, includ-ing some...support EPA's case for controls on power plants converting from oil or gas to coal, and to buttress EPA's opposition to the use...

PHILIP M. BOFFEY

1976-04-23T23:59:59.000Z

202

Sulfur behavior in chemical looping combustion with NiO/Al{sub 2}O{sub 3} oxygen carrier  

SciTech Connect

Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of NiO reduction with H{sub 2}S is higher than the one with CO. There are only Ni and Ni{sub 3}S{sub 2} phases of nickel species in the fully reduced oxygen carrier, and no evidence for the existence of NiS or NiS{sub 2}. The formation of Ni{sub 3}S{sub 2} is completely reversible during the process of oxygen carrier redox. A liquid phase sintering on the external surface of reduced oxygen carriers is mainly attributed to the production of the low melting of Ni{sub 3}S{sub 2} in the nickel-based oxygen carrier reduction with a gaseous fuel containing H{sub 2}S. Due to the sintering of metallic nickel grains on the external surface of the reduced oxygen carrier, further reaction of the oxygen carrier with H{sub 2}S is constrained, and there is no increase of the sulfidation index of the reduced oxygen carrier with the cyclical reduction number. Also, a continuous operation with a syngas of carbon monoxide and hydrogen containing H{sub 2}S is carried out in a 1 kW{sub th} CLC prototype based on the nickel-based oxygen carrier, and the effect of the fuel reactor temperature on the release of gaseous products of sulfur species is investigated. (author)

Shen, Laihong; Gao, Zhengping; Wu, Jiahua; Xiao, Jun [Thermoenergy Engineering Research Institute, Southeast University, Nanjing 210096 (China)

2010-05-15T23:59:59.000Z

203

Sulfur-deactivated steam reforming of gasified biomass  

SciTech Connect

The effect of hydrogen sulfide on the stream reforming of methane has been studied. Methane is the most difficult component to convert by steam reforming in the mixture of hydrocarbons, which is produced in biomass gasification. Two catalysts were subjected to hydrogen sulfide levels up to 300 ppm so as to study the effect of sulfur on their deactivation. These catalysts were the C11-9-061, from United Catalyst Inc., and the HTSR1, from Haldor Topsoee. The activation energy of the sulfur-deactivated steam-reforming reaction was calculated to be 280 and 260 kJ/mol, for each catalyst, respectively. The high values most probably originate from the fact that the degree of sulfur coverage of the nickel surface is close to 1 for these experiments. Even under these severe conditions, steam reforming of methane is possible without any carbon formation. The HTSR1 catalyst exhibits a very high sulfur-free activity, resulting in a performance in the presence of hydrogen sulfide higher than that for the C11-9-061 catalyst. By using the HTSR1 catalyst, the reactor temperature can be lowered by 60 C in order to reach comparable levels of conversion.

Koningen, J.; Sjoestroem, K. [Kungl Tekniska Hoegskolan, Stockholm (Sweden)] [Kungl Tekniska Hoegskolan, Stockholm (Sweden)

1998-02-01T23:59:59.000Z

204

Effect of sulfur on heavy duty diesel engine lubricants  

SciTech Connect

Diesel engine exhaust legislation has become quite onerous for heavy duty engines. Yet, these high thermal efficiency engines continue to meet lower exhaust particulate and NOx emissions limits, due to new engine designs and the complementary engine oil performance requirements of the API service categories. In addition, the EPA has mandated changes in on-highway diesel fuel to help meet particulate emissions regulations. On October 1, 1993, when the EPA outlawed high sulfur fuels for on-highway use, the development of the API CG-4 engine oil performance specification was already in progress. All the new diesel engine tests in the category were therefore designed to run with low (< 0.05% wt.) sulfur fuel. In some engine tests, this new fuel improved some lubricant performance characteristics and degraded others. An engine oil specification for low sulfur fuel brings new challenges to developing future specifications for diesel engine oils. Both higher and lower lubricant additive treat rate products, high performance single grade oils, and formulations to meet world-wide specifications become viable. This paper discusses the results of a diesel engine oil technology that performs well with the new, low sulfur fuel in both engine tests and in the field.

Hayden, T.E. [Texaco Fuels and Lubricants Research Dept., Beacon, NY (United States)

1996-12-01T23:59:59.000Z

205

Revisit Carbon/Sulfur Composite for Li-S Batteries  

SciTech Connect

To correlate the carbon properties e.g. surface area and porous structure, with the electrochemical behaviors of carbon/sulfur (C/S) composite cathodes for lithium-sulfur (Li-S) batteries, four different carbon frameworks including Ketjen Black (KB, high surface area and porous), Graphene (high surface area and nonporous), Acetylene Black (AB, low surface area and nonporous) and Hollow Carbon Nano Sphere (HCNS, low surface area and porous) are employed to immobilize sulfur (80 wt.%). It has been revealed that high surface area of carbon improves the utilization rate of active sulfur and decreases the real current density during the electrochemical reactions. Accordingly, increased reversible capacities and reduced polarization are observed for high surface area carbon hosts such as KB/S and graphene/S composites. The porous structure of KB or HCNS matrix promotes the long-term cycling stability of C/S composites but only at relatively low rate (0.2 C). Once the current density increases, the pore effect completely disappears and all Li-S batteries show similar trend of capacity degradation regardless of the different carbon hosts used in the cathodes. The reason has been assigned to the formation of reduced amount of irreversible Li2S on the cathode as well as shortened time for polysulfides to transport towards lithium anode at elevated current densities. This work provides valuable information for predictive selection on carbon materials to construct C/S composite for practical applications from the electrochemical point of view.

Zheng, Jianming; Gu, Meng; Wagner, Michael J.; Hays, Kevin; Li, Xiaohong S.; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

2013-07-23T23:59:59.000Z

206

Workshop on sulfur chemistry in flue gas desulfurization  

SciTech Connect

The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

Wallace, W.E. Jr.

1980-05-01T23:59:59.000Z

207

Auction design and the market for sulfur dioxide emissions  

E-Print Network (OSTI)

Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

Joskow, Paul L.

1996-01-01T23:59:59.000Z

208

Sulfur tolerant molten carbonate fuel cell anode and process  

DOE Patents (OSTI)

Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

Remick, Robert J. (Naperville, IL)

1990-01-01T23:59:59.000Z

209

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil  

DOE Patents (OSTI)

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08T23:59:59.000Z

210

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network (OSTI)

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

211

Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1  

E-Print Network (OSTI)

and 500 mbar CO2 with varying abundances of H2O and sulfur volatiles (H2S and SO2 mixing ratios of 10Ã?3Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1 Michael A. Mischna,2 melting model, we obtain a high sulfur solubility, approximately 1400 ppm, in Martian mantle melts. We

Zuber, Maria

212

FY08 MEMBRANE CHARACTERIZATION REPORT FOR HYBRID SULFUR ELECTROLYZER  

SciTech Connect

This report summarizes results from all of the membrane testing completed to date at the Savannah River National Laboratory (SRNL) for the sulfur dioxide-depolarized electrolyzer (SDE). Several types of commercially-available membranes have been analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid (PFSA), sulfonated polyether-ketone-ketone (SPEKK), and polybenzimidazole membranes (PBI). Of these membrane types, the poly-benzimidazole membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Several experimental membranes have also been analyzed including hydrated sulfonated Diels-Alder polyphenylenes (SDAPP) membranes from Sandia National Laboratory, perfluorosulfonimide (PFSI) and sulfonated perfluorocyclobutyl aromatic ether (S-PFCB) prepared by Clemson University, hydrated platinum-treated PFSA prepared by Giner Electrochemical Systems (GES) and Pt-Nafion{reg_sign} 115 composites prepared at SRNL. The chemical stability, SO{sub 2} transport and ionic conductivity characteristics have been measured for several commercially available and experimental proton-conducting membranes. Commercially available PFSA membranes such as the Nafion{reg_sign} series exhibited excellent chemical stability and ionic conductivity in sulfur dioxide saturated sulfuric acid solutions. Sulfur dioxide transport in the Nafion{reg_sign} membranes varied proportionally with the thickness and equivalent weight of the membrane. Although the SO{sub 2} transport in the Nafion{reg_sign} membranes is higher than desired, the excellent chemical stability and conductivity makes this membrane the best commercially-available membrane at this time. Initial results indicated that a modified Nafion{reg_sign} membrane incorporating Pt nanoparticles exhibited significantly reduced SO{sub 2} transport. Reduced SO{sub 2} transport was also measured with commercially available PBI membrane and several experimental membranes produced at SNL and Clemson. These membranes also exhibit good chemical stability and conductivity in concentrated sulfuric acid solutions and, thus, serve as promising candidates for the SDE. Therefore, we recommend further testing of these membranes including electrolyzer testing to determine if the reduced SO{sub 2} transport eliminates the formation of sulfur-containing films at the membrane/cathode interface. SO{sub 2} transport measurements in the custom built characterization cell identified experimental limitations of the original design. During the last quarter of FY08 we redesigned and fabricated a new testing cell to overcome the previous limitations. This cell also offers the capability to test membranes under polarized conditions as well as test the performance of MEAs under selected electrolyzer conditions.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-09-01T23:59:59.000Z

213

U.S. DEPARThIENT OF ENERGY EERE PROJECT MANAGEMENT CENTER NEP..I. DFTFRlIllN..I.TION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NEP..I. DFTFRlIllN..I.TION NEP..I. DFTFRlIllN..I.TION RECIPIENT:State of Nevada Office of Energy PROJECT TITLE: Nevada EECBG City $ubgrant: West Wendover Page 1 of2 STATE: NV Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CID Number DE-FOA.ooooo13 EEOOOO687.001 EEO Bssed on my review of the information conccrning the proposed action, as NEPA Compliance Officu (Iuthorlzed under DOE Order 451.IA), I have made the (ollowing determination: ex, EA, EIS APPENDIX AND NUMBER: Description: 85.1 Actions to conserve energy, demonstrate potential energy conservation, and promote energy-efficiency that do not increase the indoor concentrations of potentially harmful substances. These actions may involve financial and technical assIstance to Individuals (such as builders, owners, consultants, designers), organizations (such as utilities), and state

214

SEPA Press Releases  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

articles/181/1/SEPA Press Releases Southeastern Power articles/181/1/SEPA Press Releases Southeastern Power Administration 1166 Athens Tech Rd. Elberton, GA 30635-6711Phone: (706) 213-3800 en ENERGY EFFICIENCY AND RENEWABLE ENERGY REPORT - FY 2013 http://energy.gov/sepa/articles/energy-efficiency-and-renewable-energy-report-fy-2013 ENERGY EFFICIENCY AND RENEWABLE ENERGY REPORT - FY 2013

215

New Releases | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 Features Story Tips Audio Spots Honors and Awards Videos ORNL Review Magazine ORNL Reporter DOE Pulse Media Contacts Media Mentions RSS Feeds News Home | ORNL | News | News Releases News Releases ORNL's Office of Communications works with national, regional, and local media outlets on news stories about the laboratory. For more information on ORNL and its research and development activities, please refer to one of our Media Contacts. If you have a general media-related question or comment, you can send it to news@ornl.gov. 1-25 of 25 Results ORNL-UT researchers invent 'sideways' approach to 2-D hybrid materials ORNL-UT researchers invent 'sideways' approach to 2-D hybrid materials

216

JGI - News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

News Releases News Releases December 20, 2013 A gluttonous plant reveals how its cellular power plant devours foreign DNA. Amborella trichopoda, a sprawling shrub that grows on just a single island in the remote South Pacific, is the only plant in its family and genus. It is also one of the oldest flowering plants, having branched off from others about 200 million years ago. November 25, 2013 How Scavenging Fungi Became a Plant's Best Friend. Glomeromycota is an ancient lineage of fungi that has a symbiotic relationship with roots that goes back nearly 420 million years to the earliest plants. More than two thirds of the world's plants depend on this soil-dwelling symbiotic fungus to survive, including critical agricultural crops such as wheat, cassava, and rice. November 22, 2013

217

2009 WIPP News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

09 News Releases 09 News Releases December 21 Magnum Minerals to Buy WIPP Salt October 14 Agreement Reached Between WTS and Union Employees October 1 Truck Accident Did Not Involve WIPP Shipment September 18 WIPP Completes First RH-TRU Shipment from VNC July 24 DOE Issues Statement Concerning Debates Over Waste Disposal in Salt June 25 DOE Carlsbad Field Office Opens Local Recovery Act Office June 18 DOE Announces the Transfer of the WIPP Water Line to the City of Carlsbad June 3 Los Alamos National Laboratory Ships Remote-Handled Transuranic Waste to WIPP June 1 WIPP Mine Rescue Team Wins Best Overall at Competition April 24 Remote-Handled TRU Waste Shipments from the Savannah River Site Arrive Safely at WIPP March 31 Energy Secretary Chu Announces $384 Million in Recovery Act Funding for Environmental Cleanup in New Mexico

218

SR 2001 News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

SR 2001 News Releases SR 2001 News Releases Department of Energy Extends Contract at SRS - R-01-002 Savannah River Site's Martin Luther King, Jr. Day Observance - SR-01-01 DOE Announces Availability of Draft SEIS on Salt Processing Alternatives - SR-01-02 Media Availability For WIPP Shipment - SR-01-03 Savannah River Site Sends First Shipment Of Transuranic Waste To WIPP - SR-01-04 DOE Announces Availability Of Draft RFP On Salt Waste Processing Facility - SR-01-05 DOE Announces Wackenhut Services, Inc. - SR-01-06 DOE & DOL Hold Public Meeting For Energy Employees Occupational Illness Compensation Program Act - SR-01-07 DOE Announces Plans For Offsite Treatment & Disposal Of SRS Waste - SR-01-08 DOE Announces Availability Of Final Supplemental EIS And Identifies Preferred Salt Processing Alternative - SR-01-09

219

NACP Data Set Released  

NLE Websites -- All DOE Office Websites (Extended Search)

is pleased to announce the release of a data set associated is pleased to announce the release of a data set associated with The North American Carbon Program (NACP): NACP: MODIS Daily Land Incident 4-km PAR Images for North America, 2003-2005 . Data set prepared by S. Liang and D. Wang. This data set contains daily Moderate Resolution Imaging Spectroradiometer (MODIS) land incident photosynthetically active radiation (PAR) Images over North America for the years 2003 - 2005. The daily images were derived by integrating MODIS/Terra and MODIS/Aqua instantaneous PAR data where the instantaneous PAR data is estimated directly from Terra or Aqua MODIS 5-min L1b swath data (Liang et al., 2006 and Wang et al., 2010). The spatial distribution of this data set includes the MODIS tile subsets covering North America, Central America, portions of South America, and

220

WIPP News Releases - 1998  

NLE Websites -- All DOE Office Websites (Extended Search)

8 News Releases 8 News Releases DOE Notifies States and Tribes That First Shipment To WIPP Could Occur as Early as Mid-January - December 18, 1998 International Scientists, Engineers Make Stop in Carlsbad To Tour WIPP, Environmental Monitoring Center - November 19, 1998 WIPP Exercise Termed Success By Utah, DOE Officials - November 16, 1998 WIPP Contractor To Participate In Lea County Procurement Workshop - November 12, 1998 WIPP Crews Complete One Maintenance Project, On Schedule to Finish Second by Mid-December - November 10, 1998 Energy Department Awards $300,000 to City of Carlsbad To Help Boost Region's Economic Planning - November 4, 1998 Mansour Akbarzadeh Appointed WIPP Laboratories Manager - November 4, 1998 WIPP Mine Rescue Team Members Bring Home Four Awards From Missouri Competition - November 2, 1998

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221

Hometown News Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

Publications Hometown News Releases News Releases issued in: 2011, 2010, 2009, 2008 October 18, 2013 NETL Researcher Honored with 2013 Federal Laboratory Consortium Award Morgantown, W.Va. - Dr. Stephen E. Zitney of the National Energy Technology Laboratory (NETL) has been awarded a Mid-Atlantic region Federal Laboratory Consortium (FLC) award for Excellence in Technology Transfer for his work on the 3D Virtual Energy Plant Simulator and Immersive Training System. October 18, 2013 NETL Researcher Honored with 2013 Federal Laboratory Consortium Award Albany, Ore. - Jeffrey Hawk of the National Energy Technology Laboratory (NETL) has been awarded a Far West region Federal Laboratory Consortium (FLC) award for Outstanding Technology Development for his work on Superior Heat Resistant Alloys through Controlled Homogenization.

222

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

7 Press Release Archive 7 Press Release Archive The Midnight Ride of the CMS Tracking Detector 12/20/07 Industry and Research Heavyweights Collaborate to Demonstrate Data Transport Capability at SC07 11/12/07 Auger Observatory closes in on long-standing mystery, links highest-energy cosmic rays with violent black holes 11/08/07 Fermilab environmental program receives international recognition 10/15/07 Fermilab in Top 10 list of Chicagoland Scientific Achievements 10/02/07 Volunteers Welcome at Fermilab's Prairie Harvest on Oct. 6 and Nov. 3 09/28/07 Fermilab named one of the Chicago area's best places to work 09/25/07 Anna Zuccarini, Naperville, leads Department of Energy education program for undergraduates 08/10/07 Pierre Auger Observatory shares cosmic-ray data with public, students 07/03/07

223

WIPP News Releases - 2004  

NLE Websites -- All DOE Office Websites (Extended Search)

4 News Releases 4 News Releases November 4 Detwiler Resumes Position at DOE Headquarters October 14 WIPP Mine Rescue Team First in Missouri October 12 DOE Announces WIPP Contract Negotiations October 6 Washington TRU Solutions is Mine Operator of the Year September 28 Washington Group International Named Tops in Safety July 24 No Damage to WIPP Cargo in Roswell Traffic Accident July 22 WIPP Mine Rescue Team Wins "Overall Contest" at Nationals July 2 DOE Prevails in WIPP Court Case July 1 $1M to Fund Underground Science at WIPP April 6 NMED Approves Safer Testing Requirements for LANL Sealed Source Wastes April 1 WIPP Marks Five Years of Safe Operation March 30 EPA Approves Remote-Handled Waste Procedures for WIPP March 26 DOE Submits WIPP Compliance Recertification Application to EPA

224

EIA new releases  

SciTech Connect

This report was prepared by the Energy Information Administration. It contains news releases on items of interest to the petroleum, coal, nuclear, electric and alternate fuels industries ranging from economic outlooks to environmental concerns. There is also a listing of reports by industry and an energy education resource listing containing sources for free or low-cost energy-related educational materials for educators and primary and secondary students.

Not Available

1994-12-01T23:59:59.000Z

225

A modified release analysis procedure using advanced froth flotation mechanisms. Final technical report, September 1, 1995--August 31, 1996  

SciTech Connect

Recent studies indicate that the optimum separation performances achieved by multiple stage cleaning using various column flotation technologies and single stage cleaning using a Packed-Flotation Column are superior to the performance achieved by the traditional release procedure, especially in terms of pyritic sulfur rejection. This superior performance is believed to be the result of the advanced flotation mechanisms provided by column flotation technologies. Thus, the objective of this study was to develop a suitable process utilizing the advanced froth flotation mechanisms to characterize the true flotation response of a coal sample. This investigation resulted in the development of a modified coal flotation characterization procedure, termed as the Advanced Flotation Washability (AFW) technique. The apparatus used for this procedure is a batch operated Packed-Column device which provides enhanced selectivity due to a plug-flow environment and a deep froth zone. The separation performance achieved by the AFW procedure was found to be superior to those produced by the conventional tree and release procedures for three nominally -100 mesh coal samples and two micronized samples. The largest difference in separation performance was obtained on the basis of product pyritic sulfur content. A comparison conducted between the AFW and the release procedures at an 80% recovery value showed that the AFW technique provided a 19% improvement in the reduction of pyritic sulfur. For an Illinois No. 5 coal sample, this improvement corresponded to a reduction in pyritic sulfur content from 1.38% to 0.70% or a total rejection of 66%. Micronization of the sample improved the pyritic sulfur rejection to 85% while rejecting 92% of the ash-bearing material. In addition, the separation performance provided by the AFW procedure was superior to that obtained from multiple cleaning stages using a continuous Packed-Column under both kinetic and carrying-capacity limiting conditions.

Honaker, R.Q.; Mohanty, M.K. [Southern Illinois Univ., Carbondale, IL (United States)

1997-05-01T23:59:59.000Z

226

Enhanced electrochemical performance by wrapping graphene on carbon nanotube/sulfur composites for rechargeable lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract A novel graphene-wrapped carbon nanotube/sulfur structure was designed to improve the electrochemical performance of the lithium–sulfur (Li–S) batteries. Owing to the introduction of the reduced graphene oxide (rGO) with the aim to restrain the polysulfide anions diffusion phenomenon, increase the overall electronic conductivity of the electrode and accommodate volume expansion between the delithiated S and lithiated Li2S phases, the resulted graphene-wrapped carbon nanotube/sulfur (S/CNT@rGO) composite makes the cycling performance of the Li–S batteries better than that without rGO. The S/CNT@rGO composite showed an initial discharge capacity of ~1299 mA h g?1 at 0.2 C rate. After 100 cycles of charge/discharge, the S/CNT@rGO composite retained a high specific capacity of ~670 mA h g?1, much higher than that without rGO (graphene-wrapped carbon nanotube/sulfur composite could be a promising cathode material for high-rate performance Li–S batteries.

Yishan Wu; Chunmei Xu; Jinxin Guo; Qingmei Su; Gaohui Du; Jun Zhang

2014-01-01T23:59:59.000Z

227

Strong Sulfur Binding with Conducting Magneli-Phase TinO2n-1 Nanomaterials for Improving Lithium-Sulfur Batteries  

E-Print Network (OSTI)

will go through a series of soluble intermediate higher-order polysulfides (Li2S8, Li2S6, and Li2S4 of Li2S2, Li2S, and sulfur.6-8 In order to solve these challenges, there have been recent developmentsStrong Sulfur Binding with Conducting Magneli-Phase TinO2n-1 Nanomaterials for Improving Lithium-Sulfur

Cui, Yi

228

Media Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Release Media Contact Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen September 22, 2011 Communication Specialist (801) 819-7623 hrasmussen@wecc.biz WECC releases its first-ever transmission plan for the Western Interconnection The Western Electricity Coordinating Council (WECC) announced the release of its first 10-Year Regional Transmission Plan (Plan) for the Western Interconnection. Looking ahead to 2020, the Plan focuses on how to meet the Western Interconnection's transmission requirements; including transmission expansion, new generation development, adapting to local, state/provincial, and federal policy changes, and their associated financial and environmental costs.

229

Sulfur-tolerant anode materials for solid oxide fuel cell application  

SciTech Connect

This paper summarizes the degradation mechanisms for SOFC anodes in the presence of sulfur and recent developments in sulfur-tolerant anodes. There are two primary sulfur-degradation mechanisms for the anode materials: physical absorption of sulfur that blocks the hydrogen reaction sites, and chemical reaction that forms nickel sulfide. The sulfur-tolerant anodes are categorized into three kinds of materials: thiospinels and metal sulfides, metal cermets, and mixed ionic and electronic conductors. Each material has its own advantages and disadvantages, and the combined application of available materials to serve as different functional components in anodes through proper design may be effective to achieve a balance between stability and performance.

Gong, M. (West Virginia University, Morgantown, WV); Liu, X. (West Virginia University, Morgantown, WV); Trembly, J.; Johnson, C.

2007-06-01T23:59:59.000Z

230

Sulfur tolerant anode materials. Quarterly report, October 1--December 31, 1987  

SciTech Connect

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-02-01T23:59:59.000Z

231

Sulfur tolerant anode materials. Quarterly report, January 1--March 31, 1988  

SciTech Connect

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-05-01T23:59:59.000Z

232

Method of burning sulfur-containing fuels in a fluidized bed boiler  

DOE Patents (OSTI)

A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

Jones, Brian C. (Windsor, CT)

1982-01-01T23:59:59.000Z

233

Flue-gas sulfur-recovery plant for a multifuel boiler  

SciTech Connect

In October 1991, a Finnish fluting mill brought on stream a flue-gas desulfurization plant with an SO{sub 2} reduction capacity of 99%. The desulfurization plant enabled the mill to discontinue the use of its sulfur burner for SO{sub 2} production. The required makeup sulfur is now obtained in the form of sulfuric acid used by the acetic acid plant, which operates in conjunction with the evaporating plant. The mill`s sulfur consumption has decreased by about 6,000 tons/year (13.2 million lb/year) because of sulfur recycling.

Miettunen, J. [Tampella Power Inc., Tampere (Finland); Aitlahti, S. [Savon Sellu Oy, Kuopio (Finland)

1993-12-01T23:59:59.000Z

234

Annual Energy Review 2011 - Released September 2012  

Annual Energy Outlook 2012 (EIA)

and other manufactured and waste gases derived from fossil fuels. 2 Batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, miscellaneous technologies, and non-renewable...

235

Annual Energy Review 2008 - Released June 2009  

Gasoline and Diesel Fuel Update (EIA)

other manufactured and waste gases derived from fossil fuels. 2 Batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, miscellaneous technologies, and non-renewable waste...

236

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October 1993--December 1993  

SciTech Connect

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400-650 {degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought {open_quotes}Claus-alternative{close_quotes} for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1996-01-01T23:59:59.000Z

237

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997  

SciTech Connect

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

NONE

1997-12-31T23:59:59.000Z

238

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect

This final report describes the objectives, technical approach, results and conclusions for a project funded by the U.S. Department of Energy to test a hybrid sulfur recovery process for natural gas upgrading. The process concept is a configuration of CrystaTech, Inc.'s CrystaSulf{reg_sign} process which utilizes a direct oxidation catalyst upstream of the absorber tower to oxidize a portion of the inlet hydrogen sulfide (H{sub 2}S) to sulfur dioxide (SO{sub 2}) and elemental sulfur. This hybrid configuration of CrystaSulf has been named CrystaSulf-DO and represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day and more. This hybrid process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both onshore and offshore applications. CrystaSulf is a nonaqueous sulfur recovery process that removes H{sub 2}S from gas streams and converts it to elemental sulfur. In CrystaSulf, H{sub 2}S in the inlet gas is reacted with SO{sub 2} to make elemental sulfur according to the liquid phase Claus reaction: 2H{sub 2}S + SO{sub 2} {yields} 2H{sub 2}O + 3S. The SO{sub 2} for the reaction can be supplied from external sources by purchasing liquid SO{sub 2} and injecting it into the CrystaSulf solution, or produced internally by converting a portion of the inlet gas H{sub 2}S to SO{sub 2} or by burning a portion of the sulfur produced to make SO{sub 2}. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, the needed SO{sub 2} is produced by placing a bed of direct oxidation catalyst in the inlet gas stream to oxidize a portion of the inlet H{sub 2}S. Oxidation catalysts may also produce some elemental sulfur under these conditions, which can be removed and recovered prior to the CrystaSulf absorber. The CrystaSulf-DO process can utilize direct oxidation catalyst from many sources. Numerous direct oxidation catalysts are available from many suppliers worldwide. They have been used for H{sub 2}S oxidation to sulfur and/or SO{sub 2} for decades. It was believed at the outset of the project that TDA Research, Inc., a subcontractor, could develop a direct oxidation catalyst that would offer advantages over other commercially available catalysts for this CrystaSulf-DO process application. This project involved the development of several of TDA's candidate proprietary direct oxidation catalysts through laboratory bench-scale testing. These catalysts were shown to be effective for conversion of H{sub 2}S to SO{sub 2} and to elemental sulfur under certain operating conditions. One of these catalysts was subsequently tested on a commercial gas stream in a bench-scale reactor at CrystaTech's pilot plant site in west Texas with good results. However, commercial developments have precluded the use of TDA catalysts in the CrystaSulf-DO process. Nonetheless, this project has advanced direct oxidation catalyst technology for H{sub 2}S control in energy industries and led to several viable paths to commercialization. TDA is commercializing the use of its direct oxidation catalyst technology in conjunction with the SulfaTreat{reg_sign} solid scavenger for natural gas applications and in conjunction with ConocoPhillips and DOE for gasification applications using ConocoPhillips gasification technology. CrystaTech is commercializing its CrystaSulf-DO process in conjunction with Gas Technology Institute for natural gas applications (using direct oxidation catalysts from other commercial sources) and in conjunction with ChevronTexaco and DOE for gasification applications using ChevronTexaco's gasification technology.

Dennis Dalrymple

2004-06-01T23:59:59.000Z

239

In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine  

NLE Websites -- All DOE Office Websites (Extended Search)

In situ Observation of Sulfur in Living In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine into MDCK Cells Sulfur is essential for life. It plays important roles in the amino acids methionine and cysteine, and has a structural function in disulfide bonds. As a component of iron-sulfur clusters it takes part in electron and sulfur transfer reactions.1 Glutathione, a sulfur-containing tripeptide, is an important part of biological antioxidant systems.2 Another example for the biological relevance of sulfur is the amino acid taurine, which is present in high concentrations in algae and the animal kingdom. Taurine has been implicated in a range of physiological phenomena, but its osmolytic role in cell volume regulation has been studied in greatest detail.3 In situ information on sulfur is rare despite its important biological role. This is due to the fact that sulfur is not easily accessible with most biophysical techniques. In recent years, sulfur x-ray absorption spectroscopy (XAS) has become increasingly important in the study of sulfur species in biological systems.4 The near-edge region of the XAS spectrum is a sensitive probe of electronic structure and hence chemical form.5

240

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

NLE Websites -- All DOE Office Websites (Extended Search)

CSP Generation CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage to someone by E-mail Share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Facebook Tweet about SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Twitter Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Google Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Delicious Rank SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Digg Find More places to share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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241

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

SciTech Connect

Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

2012-06-20T23:59:59.000Z

242

SAND2000-1256 Unlimited Release  

National Nuclear Security Administration (NNSA)

models for continuous releases such as those from smokestacks (elevated releases) or pipeline leaks (ground-level releases) are inappropriate for use in transportation risk...

243

THE RAVE CATALOG OF STELLAR ELEMENTAL ABUNDANCES: FIRST DATA RELEASE  

SciTech Connect

We present chemical elemental abundances for 36,561 stars observed by the RAdial Velocity Experiment (RAVE), an ambitious spectroscopic survey of our Galaxy at Galactic latitudes |b| > 25 Degree-Sign and with magnitudes in the range 9 release of the RAVE chemical catalog is complementary to the third RAVE data release of radial velocities and stellar parameters, and it contains chemical abundances for the elements Mg, Al, Si, Ca, Ti, Fe, and Ni, with a mean error of {approx}0.2 dex, as judged from accuracy tests performed on synthetic and real spectra. Abundances are estimated through a dedicated processing pipeline in which the curve of growth of individual lines is obtained from a library of absorption line equivalent widths to construct a model spectrum that is then matched to the observed spectrum via a {chi}{sup 2} minimization technique. We plan to extend this pipeline to include estimates for other elements, such as oxygen and sulfur, in future data releases.

Boeche, C.; Williams, M.; De Jong, R. S.; Steinmetz, M. [Leibniz-Institut fuer Astrophysik Potsdam (AIP), D-14482 Potsdam (Germany); Siebert, A.; Bienayme, O. [Observatoire Astronomique de Strasbourg, Universite de Strasbourg, CNRS, UMR 7550, F-67000 Strasbourg (France); Fulbright, J. P.; Ruchti, G. R. [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218 (United States); Bland-Hawthorn, J. [Sydney Institute for Astronomy, School of Physics A28, University of Sydney, NSW 2006 (Australia); Campbell, R. [Department of Physics and Astronomy, Western Kentucky University, Bowling Green, KY (United States); Freeman, K. C. [Research School of Astronomy and Astrophysics, Australia National University, Weston Creek, Canberra ACT 2611 (Australia); Gibson, B. K. [Jeremiah Horrocks Institute, University of Central Lancashire, Preston PR1 2HE (United Kingdom); Gilmore, G. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Grebel, E. K. [Astronomisches Rechen-Institut, Zentrum fuer Astronomie der Universitaet Heidelberg, D-69120 Heidelberg (Germany); Helmi, A. [Kapteyn Astronomical Institute, University of Groningen, 9700 AV Groningen (Netherlands); Munari, U. [INAF Osservatorio Astronomico di Padova, Asiago I-36012 (Italy); Navarro, J. F. [Department of Physics and Astronomy, University of Victoria, Victoria BC V8W 3P6 (Canada); Parker, Q. A.; Reid, W. [Department of Physics and Astronomy, Faculty of Sciences, Macquarie University, Sydney, NSW 2109 (Australia); Seabroke, G. M. [Mullard Space Science Laboratory, University College London, Holmbury, St. Mary RH5 6NT (United Kingdom); and others

2011-12-15T23:59:59.000Z

244

Sulfur Lamps-The Next Generation of Efficient Light?  

NLE Websites -- All DOE Office Websites (Extended Search)

5 5 Sulfur Lamps-The Next Generation of Efficient Light? The figure above is a schematic of the system installed at the National Air and Space Museum and the DOE headquarters in Washington, D.C., Light from the sulfur lamp is focused by a parabolic reflector so that it enters the light pipe within a small angular cone. Light travels down the pipe, reflecting off the prismatic film (A) that lines the outer acrylic tube. The prismatic film reflects the light through total internal reflection (C), an intrinsically efficient process. Some of the light striking the film (at A) is not reflected and "leaks out" of the pipe walls (B), giving the pipe a glowing appearance. A light ray that travels all the way down the pipe will strike the mirror at the end (D) and return back up the pipe.

245

Cost-cutting for offshore sulfur recovery processes studied  

SciTech Connect

An increasing portion of future US gas supply is likely to come from offshore, primarily Gulf of Mexico. Because this gas can be sour, the industry has sought lower cost H{sub 2}S-removal/recovery processes for treating it. Usually the gas contains < 5 tons/day (tpd) of sulfur. A study to compare several emerging sulfur-removal/recovery processes against a baseline Amine/LO-CAT II process has indicated that some emerging processes, though not yet commercialized, show considerable potential for reducing costs. Specifically, the major findings were that Double Loop and CrystaSulf, developed by Radian International LLC, Austin, were the least expensive capital-cost processes by a significant margin and that Marathon Oil Co.`s Hysulf`s cost has the potential to compete with Double Loop and CrystaSulf.

Quinlan, M.P.; Echterhoff, L.W. [M.W. Kellogg Co., Houston, TX (United States); Leppin, D.; Meyer, H.S. [Gas Research Inst., Chicago, IL (United States)

1997-07-21T23:59:59.000Z

246

Method of making sulfur-resistant composite metal membranes  

DOE Patents (OSTI)

The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

2012-01-24T23:59:59.000Z

247

Availability of heavy fuel oils by sulfur level, September 1981  

SciTech Connect

A narrative analysis of the status of the United States' total new supply of heavy fuel oils, is given with emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held, refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and refinery Districts. Imports are given by PAD District, by country of origin, and by importing State. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. Publication was discontinued with the December 1981 issue. 2 figures, 13 tables.

Wolfrey, J.

1981-01-01T23:59:59.000Z

248

Press Pass - Press Releases  

NLE Websites -- All DOE Office Websites (Extended Search)

5 Press Release Archive 5 Press Release Archive High Energy Physics Team Captures Network Prize at SC|05 12/6/05 Beyond Einstein: A live Webcast from around the Globe Thursday, December 1, 2005, from 5:00 a.m. to 5:00 p.m. CST 11/21/05 Pierre Auger Observatory Celebrates Progress on Detector Array and Presents First Science Results 11/10/05 Science and Reading Combine in Family Literacy Experience at Fermilab on Thursday, November 17 10/11/05 Media invited to attend Pierre Auger Observatory Celebration, to be held November 9-12, 2005 in Malargüe, Argentina 11/2/05 Science and Reading Combine in Family Literacy Experience at Fermilab on Thursday, November 17 10/11/05 Volunteers Welcome at Fermilab's Prairie Harvest on Oct. 1 and 29 9/26/05 Hot Topics Featured at World Year of Physics Symposium for Students and Teachers, Saturday, October 8 from 8 a.m. to 3:15 p.m. at Fermilab's Ramsey Auditorium 9/14/05

249

More Economical Sulfur Removal for Fuel Processing Plants  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

enabled TDA to develop and commercialize its direct oxidation process-a simple, catalyst-based system for removing sulfur from natural gas and petroleum-that was convenient and economical enough for smaller fuel processing plants to use. TDA Research, Inc. (TDA) of Wheat Ridge, CO, formed in 1987, is a privately-held R&D company that brings products to market either by forming internal business

250

Structure of Chemisorbed Sulfur on a Pt(111) Electrode  

Science Journals Connector (OSTI)

Contribution from the Department of Chemistry, University of Illinois and Frederick Seitz Materials Research Laboratory, 600 S. Mathews Ave., Urbana, Illinois 61801, and Département de Chimie, Université de Sherbrooke, Sherbrooke, Québec, J1K 2R1, Canada ... Sulfur was deposited from aqueous sulfide and bisulfide media on Pt(111), and the interrogations were conducted by low electron energy diffraction (LEED), Auger electron spectroscopy (AES), and core-level electron energy loss spectroscopy (CEELS). ...

Y.-E. Sung; W. Chrzanowski; A. Zolfaghari; G. Jerkiewicz; A. Wieckowski

1997-01-08T23:59:59.000Z

251

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network (OSTI)

HYDROGEN AND SULFUR PRODUCTION FROM HYDROGEN SULFIDE WASTES? John B.L. Harkness and Richard D. Doctor, Argonne National Laboratory, Argonne. IL ABSTRACT A new hydrogen sulfide waste-treatment process that uses microwave plasma... to be economically competitive. In addition, the experiments show-that. typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology. BACKGROUND In 1987, Argonne staff found the first...

Harkness, J.; Doctor, R. D.

252

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances  

SciTech Connect

The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

K. Coulter

2010-12-31T23:59:59.000Z

253

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect

Coal Reaction Study: The results of the reaction of aqueous cupric chloride with Illinois {number sign}6 coal are listed on page 21. These results indicate that the oxidative desulfurization of coal with cupric chloride is more complex and less effective than previously reported. Although almost all the pyritic and sulfate sulfur are removed from the coal, the organic sulfur is actually reported to have increased. This may be due to an actual increase in the organic sulfur through a side reaction of the pyrite, or it may be caused by inaccuracy of the ASTM method when large proportions of chloro substituents are present. The amount of chlorine added to the coal (from 0 to 3.18%) is quite large and counterproductive. Most importantly, the amount of non-combustible ash has increased from 15.48 to 51.21%, most likely in the form of copper. This will dramatically decrease both the efficiency of combustion in terms of altering the heat capacity of the coal as well as decrease the amount of energy produced per ton of coal. As a result, it is quite evident that this method of desulfurization needs some modification prior to further exploitation.

Olesik, S. (comp.)

1990-01-01T23:59:59.000Z

254

Removal of nitrogen and sulfur from oil-shale  

SciTech Connect

This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

Olmstead, W.N.

1986-01-28T23:59:59.000Z

255

RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION  

SciTech Connect

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

Hobbs, D.

2010-07-22T23:59:59.000Z

256

DOE Releases Electricity Subsector Cybersecurity Risk Management...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

DOE Releases Electricity Subsector Cybersecurity Risk Management Process (RMP) Guideline DOE Releases Electricity Subsector Cybersecurity Risk Management Process (RMP) Guideline...

257

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL  

SciTech Connect

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

Gary M. Blythe

2001-11-06T23:59:59.000Z

258

Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report  

SciTech Connect

More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

NONE

1996-07-01T23:59:59.000Z

259

ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION  

SciTech Connect

A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

Gorensek, M.; Edwards, T.

2009-06-11T23:59:59.000Z

260

News Releases - 2011  

NLE Websites -- All DOE Office Websites (Extended Search)

/newsroom/_assets/images/newsroom-icon.jpg News Releases - 2011 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory announces top 10 science stories of 2011 Stories include alternative energy research, magnetic fields, disease tracking, the study of Mars, climate change, fuel cells, solar wind, and magnetic reconnection. - 12/23/11 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials.

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

News Releases - 2010  

NLE Websites -- All DOE Office Websites (Extended Search)

/newsroom/_assets/images/newsroom-icon.jpg News Releases - 2010 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. Bradbury Science Museum Bradbury Science Museum announces winter opening hours Museum will be closed on Christmas Day (December 25) and New Year's Day (January 1, 2011). - 12/21/10 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. LANL announces Top 10 science & technology developments of 2010 Top 10 developments based on major programmatic milestones, strategic

262

Efficient Sugar Release  

NLE Websites -- All DOE Office Websites (Extended Search)

Sugar Sugar Release by the Cellulose Solvent-Based Lignocellulose Fractionation Technology and Enzymatic Cellulose Hydrolysis GEOFFREY MOXLEY, † ZHIGUANG ZHU, † AND Y.-H. PERCIVAL ZHANG* ,†,‡,§ Biological Systems Engineering Department, Virginia Polytechnic Institute and State University, 210-A Seitz Hall, Blacksburg, Virginia 24061, Institute for Critical Technology and Applied Science (ICTAS), Virginia Polytechnic Institute and State University, Virginia 24061, and Department of Energy (DOE) BioEnergy Science Center, Oak Ridge, Tennessee 37831 Efficient liberation of fermentable soluble sugars from lignocellulosic biomass waste not only decreases solid waste handling but also produces value-added biofuels and biobased products. Industrial hemp, a special economic crop, is cultivated for its high-quality fibers and high-value seed oil, but its hollow

263

News Releases - 2008  

NLE Websites -- All DOE Office Websites (Extended Search)

/newsroom/_assets/images/newsroom-icon.jpg News Releases - 2008 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. New airport liquid analysis system undergoes testing at Albuquerque International Sunport A new tool that distinguishes potential-threat liquids from the harmless shampoos and sodas a regular traveler might take aboard an aircraft. - 12/16/08 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials.

264

News Releases - 2009  

NLE Websites -- All DOE Office Websites (Extended Search)

/newsroom/_assets/images/newsroom-icon.jpg News Releases - 2009 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Science satellites seek Santa Los Alamos scientists will use two advanced science satellites to mark the course taken by the elfin traveler. - 12/16/09 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials.

265

Release Date: April 2010  

Gasoline and Diesel Fuel Update (EIA)

April 2010 DOE/EIA-0121 (2009/04Q) April 2010 DOE/EIA-0121 (2009/04Q) Next Release Date: June 2010 Quarterly Coal Report October - December 2009 April 2010 U.S. Energy Information Administration Office of Coal, Nuclear, Electric, and Alternate Fuels U.S. Department of Energy Washington, DC 20585 _____________________________________________________________________________ This report is available on the Web at: http://www.eia.doe.gov/cneaf/coal/quarterly/qcr.pdf _____________________________________________ This report was prepared by the U.S. Energy Information Administration (EIA), the independent statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States Government. The views in this

266

News Releases | Biosciences Division  

NLE Websites -- All DOE Office Websites (Extended Search)

Alaska Soil Research Alaska Soil Research BIO Home Page About BIO News Releases Research Publications People Contact Us Organization Chart Site Index Inside BIO BIO Safety About Argonne Alaska Soil Research Project Aiming to Improve Understanding of Global Climate November 26, 2012 A research team being led by Julie Jastrow, an ecologist at the U.S. Department of Energy's (DOE) Argonne National Laboratory, recently traveled to the North Slope of Alaska as part of a soil research project that aims to ultimately help improve and validate global climate models. Using jackhammer to dig a sampling pit in frozen soil After removing the seasonally thawed soil active layer in coastal plain tundra near Prudhoe Bay, members of the Argonne research team use a jackhammer to dig through frozen soil, creating a soil pit from which different soil layers can be viewed and sampled.

267

Quick release engine cylinder  

DOE Patents (OSTI)

A quick release engine cylinder allows optical access to an essentially unaltered combustion chamber, is suitable for use with actual combustion processes, and is amenable to rapid and repeated disassembly and cleaning. A cylinder member, adapted to constrain a piston to a defined path through the cylinder member, sealingly engages a cylinder head to provide a production-like combustion chamber. A support member mounts with the cylinder member. The support-to-cylinder mounting allows two relationships therebetween. In the first mounting relationship, the support engages the cylinder member and restrains the cylinder against the head. In the second mounting relationship, the cylinder member can pass through the support member, moving away from the head and providing access to the piston-top and head.

Sunnarborg, Duane A. (1123 Lucille St., Livermore, Alameda County, CA 94550)

2000-01-01T23:59:59.000Z

268

COMMERCIAL SNF ACCIDENT RELEASE FRACTIONS  

SciTech Connect

The purpose of this design analysis is to specify and document the total and respirable fractions for radioactive materials that are released from an accident event at the Monitored Geologic Repository (MGR) involving commercial spent nuclear fuel (CSNF) in a dry environment. The total and respirable release fractions will be used to support the preclosure licensing basis for the MGR. The total release fraction is defined as the fraction of total CSNF assembly inventory, typically expressed as an activity inventory (e.g., curies), of a given radionuclide that is released to the environment from a waste form. The radionuclides are released from the inside of breached fuel rods (or pins) and from the detachment of radioactive material (crud) from the outside surfaces of fuel rods and other components of fuel assemblies. The total release fraction accounts for several mechanisms that tend to retain, retard, or diminish the amount of radionuclides that are available for transport to dose receptors or otherwise can be shown to reduce exposure of receptors to radiological releases. The total release fraction includes a fraction of airborne material that is respirable and could result in inhalation doses. This subset of the total release fraction is referred to as the respirable release fraction. Potential accidents may involve waste forms that are characterized as either bare (unconfined) fuel assemblies or confined fuel assemblies. The confined CSNF assemblies at the MGR are contained in shipping casks, canisters, or disposal containers (waste packages). In contrast to the bare fuel assemblies, the container that confines the fuel assemblies has the potential of providing an additional barrier for diminishing the total release fraction should the fuel rod cladding breach during an accident. However, this analysis will not take credit for this additional bamer and will establish only the total release fractions for bare unconfined CSNF assemblies, which may however be conservatively applied to confined CSNF assemblies.

S.O. Bader

1999-10-18T23:59:59.000Z

269

NETL Releases Hydraulic Fracturing Study  

Energy.gov (U.S. Department of Energy (DOE))

The National Energy Technology Laboratory has released a technical report on the results of a limited field study that monitored a hydraulic fracturing operation in Greene County, PA.

270

Press Pass - Press Release Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

7 LHC Press Release - 120897 Fermilab's Science Center to Open of First Saturdays - 112197 U.S. Department of Energy and Fermilab Invite Public to Informational Meeting...

271

News Releases | Critical Materials Institute  

NLE Websites -- All DOE Office Websites (Extended Search)

Releases CMI hosts EU, Japan to discuss global critical materials strategy, September 10, 2014 Five Critical Materials Institute researchers named Most Influential Scientific Minds...

272

Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins  

NLE Websites -- All DOE Office Websites (Extended Search)

Solvent Tuning of Properties of Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in nature and catalyze one-electron transfer processes. These proteins have evolved into two classes that have large differences in their electrochemical potentials: high potential iron-sulfur proteins (HiPIPs) and bacterial ferredoxins (Fds). The role of the surrounding protein environment in tuning the redox potential of these iron sulfur clusters has been a persistent puzzle in biological electron transfer [1]. Although HiPIPs and Fds have the same iron sulfur structural motif - a cubane-type structure - (Figure 1), there are large differences in their electrochemical

273

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

NLE Websites -- All DOE Office Websites (Extended Search)

CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage General Atomics logo Graphic of a diagram of squares and circles connected by arrows. Sulfur-based TES can compensate for diurnal and seasonal insolation fluctuations. General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power generation. Approach There are three main project objectives under this award: Study the sulfur generating disproportionation reaction and develop it into a practical engineering process step. Carry out preliminary process components design and experimental validation. The engineering data will be used for process integration between the CSP plant, the sulfur processing and storage plant, and the electricity generation unit.

274

doi:10.1016/j.gca.2005.02.002 Sulfur diffusion in basaltic melts  

E-Print Network (OSTI)

doi:10.1016/j.gca.2005.02.002 Sulfur diffusion in basaltic melts CARMELA FREDA,1, * DON R. BAKER,1,2 February 3, 2005) Abstract--We measured the diffusion coefficients of sulfur in two different basaltic for sulfur diffusion in anhydrous basalts: D 2.19 10 4 exp 226.3 58.3 RT where D is the diffusion coefficient

Long, Bernard

275

Microsoft Word - Vapor Phase Elemental Sulfur Tech Brief DRAFT bbl 08-24.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

AT A GLANCE AT A GLANCE ï‚· eliminates excavation expense ï‚· applicable to large or small sites ï‚· straightforward deployment ï‚· uses heat to distribute sulfur throughout a soil ï‚· mercury reacts with sulfur to form immobile and insoluble minerals ï‚· patent applied for TechBrief Vapor Phase Elemental Sulfur Amendment for Sequestering Mercury in Contaminated Soil Scientists at the Savannah River National Laboratory (SRNL) have identified a method of targeting mercury in contaminated soil zone by use of sulfur vapor heated gas. Background Mercury contamination in soil is a common problem in the environment. The most common treatment is excavation - a method that works well for small sites where the

276

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

October 04, 2011 Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System DEER CONFERENCE 2011 Outline Introduction Zeolite-based SCR behavior -...

277

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

200 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

278

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

200 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

279

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

Energy Information Administration Petroleum Marketing Annual 1995 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

280

E-Print Network 3.0 - aqueous sulfuric acid Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

TRACE ATMOSPHERIC CONSTITUENTS Summary: . Reactions of Sulfur(IV) with Transition-Metal Ions in Aqueous Solutions Robert E. Huie and Norman C... . Peterson 3. Catalytic...

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

E-Print Network 3.0 - aqueous organic sulfur Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

TRACE ATMOSPHERIC CONSTITUENTS Summary: . Reactions of Sulfur(IV) with Transition-Metal Ions in Aqueous Solutions Robert E. Huie and Norman C... . Peterson 3. Catalytic...

282

E-Print Network 3.0 - ashless low-sulfur fuel Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Blendstocks for Low Sulfur Diesel Fuel in PADD III . . . . . . . . . . . . . . . . 17... markets for low ... Source: Oak Ridge National Laboratory, Center for Transportation...

283

E-Print Network 3.0 - aromatic sulfur heterocycles Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale Summary: . Polycyclic aromatic sulfur heterocycles IV. Determination of polycyclic...

284

Portable instrument and method for detecting reduced sulfur compounds in a gas  

DOE Patents (OSTI)

A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

1983-06-01T23:59:59.000Z

285

Sulfur behavior in the Sasol-Lurgi fixed-bed dry-bottom gasification process  

SciTech Connect

This article reports on the findings of a study regarding the sulfur behavior across a Sasol-Lurgi gasifier. This was undertaken to understand the behavior of the various sulfur-bearing components in the coal, as they are exposed to the conditions in the gasifier. In this study, conventional characterization techniques were employed to monitor the behavior of sulfur-bearing mineral matter across the gasifier. It was observed from the study that the sulfur-bearing mineral (pyrite) in the coal structure undergoes various changes with pyrite being transformed to pyrrhotite and then to various oxides of iron with the subsequent loss of sulfur to form H{sub 2}S. A low proportion of the sulfur species including the organically associated sulfur was encapsulated by a melt that was formed by the interaction between kaolinite and fluxing minerals (pyrite, calcite, and dolomite/ankerite) present in the coal at elevated temperatures and pressure, thereby ending up in the ash. The remaining small proportions of sulfur-bearing mineral matter including pyrite and organically bound sulfur in the unburned carbon in the carbonaceous shales also report to the ash. 18 refs., 8 figs., 2 tabs.

M. Pat Skhonde; R. Henry Matjie; J. Reginald Bunt; A. Christien Strydom; H. Schobert [Sasol Technology R& amp; D, Sasolburg (South Africa)

2009-01-15T23:59:59.000Z

286

Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program  

SciTech Connect

DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

George Sverdrup

1999-06-07T23:59:59.000Z

287

Sulfur-tolerant natural gas reforming for fuel-cell applications.  

E-Print Network (OSTI)

??An attractive simplification of PEM-FC systems operated with natural gas would be the use of a sulfur tolerant reforming catalyst, but such a catalyst has… (more)

Hennings, Ulrich

2010-01-01T23:59:59.000Z

288

E-Print Network 3.0 - absorbing sulfur dioxide Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

289

E-Print Network 3.0 - ambient sulfur dioxide Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

290

E-Print Network 3.0 - africa sulfur isotope Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: africa sulfur isotope Page: << < 1 2 3 4 5 > >> 1 Geobiology (2006), 4, 191201 2006 The...

291

Sulfur barrier for use with in situ processes for treating formations  

DOE Patents (OSTI)

Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

Vinegar, Harold J. (Bellaire, TX); Christensen, Del Scot (Friendswood, TX)

2009-12-15T23:59:59.000Z

292

Central Appalachia: Production potential of low-sulfur coal  

SciTech Connect

The vast preponderance of eastern US low sulfur and 1.2-lbs SO{sub 2}/MMBtu compliance coal comes from a relatively small area composed of 14 counties located in eastern Kentucky, southern West Virginia and western Virginia. These 14 counties accounted for 68% of all Central Appalachian coal production in 1989 as well as 85% of all compliance coal shipped to electric utilities from this region. A property-by-property analysis of total production potential in 10 of the 14 counties (Floyd, Knott, Letcher, Harlan, Martin and Pike in Kentucky and Boone, Kanawha, Logan and Mingo in West Virginia) resulted in the following estimates of active and yet to be developed properties: (1) total salable reserves for all sulfur levels were 5.9 billion tons and (2) 1.2-lbs. SO{sub 2}/MMBtu compliance'' reserves totaled 2.38 billion tons. This potential supply of compliance coal is adequate to meet the expanded utility demand expected under acid rain for the next 20 years. Beyond 2010, compliance supplies will begin to reach depletion levels in some areas of the study region. A review of the cost structure for all active mines was used to categorize the cost structure for developing potential supplies. FOB cash costs for all active mines in the ten counties ranged from $15 per ton to $35 per ton and the median mine cost was about $22 per ton. A total of 47 companies with the ability to produce and ship coal from owned or leased reserves are active in the ten-county region. Identified development and expansion projects controlled by active companies are capable of expanding the region's current production level by over 30 million tons per year over the next twenty years. Beyond this period the issue of reserve depletion for coal of all sulfur levels in the ten county region will become a pressing issue. 11 figs., 12 tabs.

Watkins, J. (Hill and Associates, Inc., Annapolis, MD (United States))

1991-09-01T23:59:59.000Z

293

AEO2014 Early Release Overview  

U.S. Energy Information Administration (EIA) Indexed Site

Administration | Annual Energy Outlook 2014 Early Release Overview Administration | Annual Energy Outlook 2014 Early Release Overview AEO2014 Early Release Overview Executive summary Projections in the Annual Energy Outlook 2014 (AEO2014) Reference case focus on the factors that shape U.S. energy markets through 2040, under the assumption that current laws and regulations remain generally unchanged throughout the projection period. The early release provides a basis for the examination and discussion of energy market trends and serves as a starting point for analysis of potential changes in U.S. energy policies, rules, or regulations or possible technology breakthroughs. Readers are encouraged to review the full range of cases that will be presented when the complete AEO2014 is released in 2014, exploring key

294

AEO2013 Early Release Overview  

Gasoline and Diesel Fuel Update (EIA)

3 Early Release Overview 3 Early Release Overview AEO2013 Early Release Overview Executive summary Projections in the Annual Energy Outlook 2013 (AEO2013) Reference case focus on the factors that shape U.S. energy markets through 2040, under the assumption that current laws and regulations remain generally unchanged throughout the projection period. This early release focuses on the AEO2013 Reference case, which provides the basis for examination and discussion of energy market trends and serves as a starting point for analysis of potential changes in U.S. energy policies, rules, or regulations or potential technology breakthroughs. Readers are encouraged to review the full range of cases that will be presented when the complete AEO2013 is released in early 2013, exploring key uncertainties in the Reference case. Major highlights in the AEO2013 Reference case include:

295

Sulfur polymer cement for macroencapsulation of mixed waste debris  

SciTech Connect

In FY 1997, the US DOE Mixed Waste Focus Area (MWFA) sponsored a demonstration of the macroencapsulation of mixed waste debris using sulfur polymer cement (SPC). Two mixed wastes were tested--a D006 waste comprised of sheets of cadmium and a D008/D009 waste comprised of lead pipes and joints contaminated with mercury. The demonstration was successful in rendering these wastes compliant with Land Disposal Restrictions (LDR), thereby eliminating one Mixed Waste Inventory Report (MWIR) waste stream from the national inventory.

Mattus, C.H.

1998-06-01T23:59:59.000Z

296

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents (OSTI)

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

297

DEP.-\RTUENT OF ENERG Y EERE PROJECT MANAG EM ENT CENTER NEP.-I. DETEIU.lIN.-I.TION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

-\RTUENT OF ENERG Y -\RTUENT OF ENERG Y EERE PROJECT MANAG EM ENT CENTER NEP.-I. DETEIU.lIN.-I.TION Page 1 of2 RECIPIENT:Govemor's Energy Office STATE: CO PROJECf TITLE: COLORADO SEP ARRA - Geothermal Power Direct Use Grant - Town of Rico Funding Opportunity Announcement Number OE-FOA-OOOOO52 Procurement Instrument Number DE-EE0000082 NEPA Control Number GF0..()()()()()82 -009 elD Number o Based on my review of the inCormation concerning the proposed action, as N[PA Compliance Officer (authorized under DOE Order 451.1;\), I have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A 11 Technical advice and planning assistance to international, national, state, and local organizations. A9 Information gathering (including, but not limited to, literature surveys, inventories, audits), data analysis (including

298

ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP  

SciTech Connect

Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-duty as well. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consists of four phases. Phase I will focus on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II we will concentrate on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III will study life cycle and regeneration options for the spent filter. Phase IV will focus on efficacy and life testing and component integration. The project team will include a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Mack Trucks Inc.), a filter recycler (American Wastes Industries), and a low-sulfur fuel supplier (Equilon, a joint venture between Shell and Texaco).

Ron Rohrbach; Gary Zulauf; Tim Gavin

2003-04-01T23:59:59.000Z

299

Availability of heavy fuel oils by sulfur levels, February 1981  

SciTech Connect

This monthly report includes a narrative analysis of the status of the United States' total new supply of heavy fuel oils, with an emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and Refinery Districts. Imports are given by PAD District, by country or origin, and by importing state. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. The December issue repeats the seven major tables with final data in all categories for the previous calendar year. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. 2 figs., 13 tabs.

Wolfrey, J.

1981-10-15T23:59:59.000Z

300

Availability of heavy fuel oils by sulfur levels, March 1981  

SciTech Connect

This monthly report includes a narrative analysis of the status of the United States' total new supply of heavy fuel oils, with an emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and Refinery Districts. Imports are given by PAD District, by country of origin, and by importing state. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. The December issue repeats the seven major tables with final data in all categories for the previous calendar year. This report was previously published by the Bureau of Mines in the Minerals Industries Survey Series under the same title. 2 figs., 13 tabs.

Wolfrey, J.

1981-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Availability of heavy fuel oils by sulfur level, August 1981  

SciTech Connect

A narrative analysis of the status of the United States' total new supply of heavy fuel oils, is given with emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and Refinery Districts. Imports are given by PAD District, by country of origin, and by importing State. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. Publication was discontinued with the December 1981 issue. 1 figure, 14 tables.

Wolfrey, J.

1981-01-01T23:59:59.000Z

302

Availability of heavy fuel oils by sulfur level, October 1981  

SciTech Connect

A narrative analysis of the status of the United States' total new supply of heavy fuel oils, is given with emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and refinery Districts. Imports are given by PAD District, by country of origin, and by importing State. Waterbone movements from PAD District III to other districts are detailed for the most recent month only. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. Publication was discontinued with the December 1981 issue. 1 figure, 14 tables.

Wolfrey, J.

1981-01-01T23:59:59.000Z

303

Extracellular iron-sulfur precipitates from growth of Desulfovibrio desulfuricans  

SciTech Connect

The authors have examined extracellular iron-bearing precipitates resulting from the growth of Desulfovibrio desulfuricans in a basal medium with lactate as the carbon source and ferrous sulfate. Black precipitates were obtained when D. desulfuricans was grown with an excess of FeSO{sub 4}. When D. desulfuricans was grown under conditions with low amounts of FeSO{sub 4}, brown precipitates were obtained. The precipitates were characterized by iron K-edge XAFS (X-ray absorption fine structure), {sup 57}Fe Moessbauer-effect spectroscopy, and powder X-ray diffraction. Both were noncrystalline and nonmagnetic (at room temperature) solids containing high-spin Fe(III). The spectroscopic data for the black precipitates indicate the formation of an iron-sulfur phase with 6 nearest S neighbors about Fe at an average distance of 2.24(1) {angstrom}, whereas the brown precipitates are an iron-oxygen-sulfur phase with 6 nearest O neighbors about Fe at an average distance of 1.95(1) {angstrom}.

Antonio, M. R.; Tischler, M. L.; Witzcak, D.

1999-12-20T23:59:59.000Z

304

Demonstration of Mixed Waste Debris Macroencapsulation Using Sulfur Polymer Cement  

SciTech Connect

This report covers work performed during FY 1997 as part of the Evaluation of Sulfur Polymer Cement Fast-Track System Project. The project is in support of the ``Mercury Working Group/Mercury Treatment Demonstrations - Oak Ridge`` and is described in technical task plan (TTP) OR-16MW-61. Macroencapsulation is the treatment technology required for debris by the U.S. Environmental Protection Agency Land Disposal Restrictions (LDR) under the Resource Conservation and Recovery Act. Based upon the results of previous work performed at Oak Ridge, the concept of using sulfur polymer cement (SPC) for this purpose was submitted to the Mixed Waste Focus Area (MWFA). Because of the promising properties of the material, the MWFA accepted this Quick Win project, which was to demonstrate the feasibility of macroencapsulation of actual mixed waste debris stored on the Oak Ridge Reservation. The waste acceptance criteria from Envirocare, Utah, were chosen as a standard for the determination of the final waste form produced. During this demonstration, it was shown that SPC was a good candidate for macroencapsulation of mixed waste debris, especially when the debris pieces were dry. The matrix was found to be quite easy to use and, once the optimum operating conditions were identified, very straightforward to replicate for batch treatment. The demonstration was able to render LDR compliant more than 400 kg of mixed wastes stored at the Oak Ridge National Laboratory.

Mattus, C.H.

1998-07-01T23:59:59.000Z

305

NETL: News Release - Department of Energy Releases Updated Report Tracking  

NLE Websites -- All DOE Office Websites (Extended Search)

Department of Energy Releases Updated Report Tracking Resurgence of Coal-Fired Power Plants Department of Energy Releases Updated Report Tracking Resurgence of Coal-Fired Power Plants Report Shows 151 Proposed and New Plants, 90 Gigawatts of Capacity by 2020 WASHINGTON, DC - A newly released Department of Energy report shows that many power producers are turning to coal as the most economic and abundant national resource for electricity generation. The report, titled Tracking New Coal-Fired Power Plants, was developed by the Office of Fossil Energy's National Energy Technology Laboratory (NETL) to provide a snapshot of coal's resurgence in the generation of electric power. The report was derived from a database that NETL maintains to track proposals for new coal-fired power plants. Created in 2002, the database is updated quarterly as new information is released and cataloged. The results contained in the database are derived from information publicly available from a variety of tracking organizations and news groups.

306

Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry  

SciTech Connect

This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt mixtures and compared with sodium-based binary and higher order systems. Predictions and measurements were demonstrated for both salt systems and for some more complex silicate-bearing systems, substantially exceeding the original scope of this work. 4. A multi-dimensional model of char bed reactivity developed under this project demonstrated that essentially all reactions in char beds occur on or near the surface, with the internal portions of the bed being essentially inert. The model predicted composition, temperature, and velocity profiles in the bed and showed that air jet penetration is limited to the immediate vicinity of the char bed, with minimal impact on most of the bed. The modeling efforts substantially exceeded the original scope of this project. 5. Near the completion of this project, DOE withdrew the BYU portion of a multiparty agreement to complete this and additional work with no advanced warning, which compromised the integration of all of this material into a commercial computer code. However, substantial computer simulations of much of this work were initiated, but not completed. 6. The gasification modeling is nearly completed but was aborted near its completion according to a DOE redirection of funds. This affected both this and the previous tasks.

Baxter, Larry L.

2008-06-09T23:59:59.000Z

307

Commercial SNF Accident Release Fractions  

SciTech Connect

The purpose of this analysis is to specify and document the total and respirable fractions for radioactive materials that could be potentially released from an accident at the repository involving commercial spent nuclear fuel (SNF) in a dry environment. The total and respirable release fractions are used to support the preclosure licensing basis for the repository. The total release fraction is defined as the fraction of total commercial SNF assembly inventory, typically expressed as an activity inventory (e.g., curies), of a given radionuclide that is released to the environment from a waste form. Radionuclides are released from the inside of breached fuel rods (or pins) and from the detachment of radioactive material (crud) from the outside surfaces of fuel rods and other components of fuel assemblies. The total release fraction accounts for several mechanisms that tend to retain, retard, or diminish the amount of radionuclides that are available for transport to dose receptors or otherwise can be shown to reduce exposure of receptors to radiological releases. The total release fraction includes a fraction of airborne material that is respirable and could result in inhalation doses; this subset of the total release fraction is referred to as the respirable release fraction. Accidents may involve waste forms characterized as: (1) bare unconfined intact fuel assemblies, (2) confined intact fuel assemblies, or (3) canistered failed commercial SNF. Confined intact commercial SNF assemblies at the repository are contained in shipping casks, canisters, or waste packages. Four categories of failed commercial SNF are identified: (1) mechanically and cladding-penetration damaged commercial SNF, (2) consolidated/reconstituted assemblies, (3) fuel rods, pieces, and debris, and (4) nonfuel components. It is assumed that failed commercial SNF is placed into waste packages with a mesh screen at each end (CRWMS M&O 1999). In contrast to bare unconfined fuel assemblies, the container that confines the fuel assemblies could provide an additional barrier for diminishing the total release fraction should the fuel rod cladding breach during an accident. This analysis, however, does not take credit for the additional barrier and establishes only the total release fractions for bare unconfined intact commercial SNF assemblies, which may be conservatively applied to confined intact commercial I SNF assemblies.

J. Schulz

2004-11-05T23:59:59.000Z

308

Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis  

E-Print Network (OSTI)

The oxidation of SO[subscript 2] to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to ...

Harris, E.

309

A composite material of uniformly dispersed sulfur on reduced graphene oxide: Aqueous one-pot synthesis, characterization and excellent performance as the cathode in rechargeable lithium-sulfur batteries  

Science Journals Connector (OSTI)

Sulfur-reduced graphene oxide composite (SGC) materials with uniformly dispersed sulfur on reduced graphene oxide sheets have been prepared by a ... the simultaneous oxidation of sulfide and reduction of graphene

Hui Sun; Gui-Liang Xu; Yue-Feng Xu; Shi-Gang Sun; Xinfeng Zhang…

2012-10-01T23:59:59.000Z

310

Separation and Detection of Sulfur-Containing Anions Using Single-Column Ion Chromatography  

Science Journals Connector (OSTI)

......principal sulfur-containing anions in oil shale retort by-product waters are separated...electrochemical detection in some of the oil shale retort by-product water matrices...principal sulfur-containing anions in oil shale retort by-product waters are separated......

Richard E. Poulson; Harry M. Borg

1987-09-01T23:59:59.000Z

311

Quantitative Determination of Aliphatic Sulfur-Containing Additives by Pyrolysis-Gas Chromatography  

Science Journals Connector (OSTI)

......pyrolysis (7), infrared (8), combustion to SO4 = with subsequent determination...Drushel. The Analytical Chemistry of Sulfur and Its Compounds...London, p. 358. Sulfur in Coal and Coke by the Bomb Washing...organic materials by oxygen bomb combustion. Anal. Chem. 33:1760......

J.W. Sinclair; L. Schall; N.T. Crabb

1980-01-01T23:59:59.000Z

312

The sulfur content of volcanic gases on Mars Fabrice Gaillard, a  

E-Print Network (OSTI)

principles, we model here the likely sulfur contents of (1) the martian and terrestrial mantles and (2 a denser atmosphere are shown to be dominated by CO ± CO2 and H2 ± H2O species, depending on fO2, sulfur by H2S, which should have favored the acidification of any persistent water layer. The calculated

Boyer, Edmond

313

Evidence for a Plasma Core during Multibubble Sonoluminescence in Sulfuric Acid  

E-Print Network (OSTI)

.g., SOx, trace amounts of H2S, and elemental sulfur)7 are either highly soluble or solids. Prior MBSL to be problematic. These volatile products can have limited solubility in the liquid and therefore accumulate for the generation of higher temperatures during cavitation. Sulfuric acid is one such liquid because it has a very

Suslick, Kenneth S.

314

Toxicology Studies on Lewisite and Sulfur Mustard Agents: Subchronic Toxicity of Sulfur Mustard (HD) In Rats Final Report  

SciTech Connect

Occupational health standards have not been established for sulfur mustard [bis(2- chlorethyl)-sulfide], a strong alkylating agent with known mutagenic properties. Seventytwo Sprague-Dawley rats of each sex, 6-7 weeks old, were divided into six groups (12/group/ sex) and gavaged with either 0, 0.003 , 0.01 , 0.03 , 0.1 or 0.3 mg/kg of sulfur mustard in sesame oil 5 days/week for 13 weeks. No dose-related mortality was observed. A significant decrease (P ( 0.05) in body weight was observed in both sexes of rats only in the 0.3 mg/kg group. Hematological evaluations and clinical chemistry measurements found no consistent treatment-related effects at the doses studied. The only treatment-related lesion associated with gavage exposure upon histopathologic evaluation was epithelial hyperplasia of the forestomach of both sexes at 0.3 mg/kg and males at 0.1 mg/kg. The hyperplastic change was minimal and characterized by cellular disorganization of the basilar layer, an apparent increase in mitotic activity of the basilar epithelial cells, and thickening of the epithelial layer due to the apparent increase in cellularity. The estimated NOEL for HD in this 90-day study is 0.1 mg/kg/day when administered orally.

Sasser, L. B.; Miller, R. A.; Kalkwarf, D, R.; Buschbom, R. L.; Cushing, J. A.

1989-06-30T23:59:59.000Z

315

Press Releases | Stanford Synchrotron Radiation Lightsource  

NLE Websites -- All DOE Office Websites (Extended Search)

Press Releases Press Releases 2012 Press Releases December 10, 2012 Experiment Finds Ulcer Bug's Achilles' Heel (see Press Release) June 6, 2012 New secrets from "Bay of the Pirates" warship that sunk 2,300 years ago (see Press Release) March 5, 2012 X-rays Reveal How Soil Bacteria Carry Out Surprising Chemistry (see Press Release) 2011 Press Releases July 3, 2011 Researchers Decipher Protein Structure of Key Molecule in DNA Transcription System (see Press Release) June 30, 2011 X-rays Reveal Patterns in the Plumage of the First Birds (see Press Release) March 24, 2011 High-temperature Superconductor Spills Secret: A New Phase of Matter (see Press Release) March 23, 2011 First Image of Protein Residue in 50 Million Year Old Reptile Skin (see Press Release) 2010 Press Releases

316

Population, Economy and Energy Use’s Influence on Sulfur Emissions in the United States Since 1900  

E-Print Network (OSTI)

This paper seeks to identify how changes in population, economic activity, and energy use have influenced sulfur emissions during this century. A linear model is presented which characterizes sulfur emissions as the product of these driving forces...

Kissock, J. K.; Husar, R. B.

317

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation  

E-Print Network (OSTI)

The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

318

ARM - Features and Releases Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

CenterFeaturesFeatures and Releases Archive CenterFeaturesFeatures and Releases Archive Media Contact Lynne Roeder lynne-dot-roeder-at-pnnl-dot-gov @armnewsteam Field Notes Blog Topics Field Notes89 AGU 3 AMIE 10 ARM Aerial Facility 2 ARM Mobile Facility 1 6 ARM Mobile Facility 2 47 BAECC 1 BBOP 4 MAGIC 12 MC3E 17 SGP 2 STORMVEX 29 TCAP 3 Search News Search Blog News Center All Categories What's this? Social Media Guidance News Center All Categories Features and Releases Facility News Field Notes Blog feed Events feed Employment Research Highlights Data Announcements Education News Archive What's this? Social Media Guidance Features and Releases Archive 2013 Dec 30 Pole Position: New Field Campaigns Explore Arctic and Antarctic Atmosphere Nov 13 Research Flights Completed for Biomass Burning Field Campaign Nov 07 MAGIC Takes a Bow

319

PRESS RELEASE RARE FRUIT CONFERENCE  

E-Print Network (OSTI)

RELEASE RARE FRUIT CONFERENCE July 9 - 13, 2014 Sponsored by the Tropical Fruit & Vegetable Society of the Redland & the Fruit & Spice Park 24801 SW 187th Avenue, Homestead, Florida

Jawitz, James W.

320

DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate February 1, 2011 - 12:00pm Addthis Washington, DC - The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy (DOE) said today. The State of New York and other Northeastern states are implementing more stringent fuel standards that require replacement of high sulfur (2,000 parts per million) heating oil to ultra low sulfur fuel (15 parts per million). As a result, DOE will sell the current inventory of the Northeast

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Will Convert Northeast Home Heating Oil Reserve to Ultra Low Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate February 1, 2011 - 12:00pm Addthis Washington, DC - The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy (DOE) said today. The State of New York and other Northeastern states are implementing more stringent fuel standards that require replacement of high sulfur (2,000 parts per million) heating oil to ultra low sulfur fuel (15 parts per million). As a result, DOE will sell the current inventory of the Northeast Home Heating Oil Reserve, a total of approximately 2 million barrels, and

322

Direct determination of organic and inorganic sulfur in coal by controlled oxidation  

SciTech Connect

The overall objective of this project is to develop an analytical method to directly measure the forms of organic sulfur in coal. The method will provide a route to monitor the effectiveness of coal preparation research directed toward removal of organic sulfur in coal. The approach involves subjecting diluted coal samples simultaneously to an oxygen flow and a linear increase in temperature. Distinctive sulfur dioxide evolution patterns are observed among coals of different rank and between raw and treated coals. Assignments have been made relating each specific sulfur dioxide evolution to the non-aromatic organic, aromatic organic, and inorganic sulfur present in coals and treated coals. Work is progressing on schedule to optimize experimental conditions and to improve the efficiency of the controlled-atmosphere programmed-temperature oxidation (CAPTO) method by developing a multiple sample instrumental system.

LaCount, R.B.

1992-01-01T23:59:59.000Z

323

Direct determination of organic and inorganic sulfur in coal by controlled oxidation  

SciTech Connect

The overall objective of this project is to develop an analytical method to directly measure the forms of organic sulfur in coal. The method will provide a route to monitor the effectiveness of coal preparation research directed toward removal of organic sulfur in coal. The approach involves subjecting diluted coal samples simultaneously to an oxygen flow and a linear increase in temperature. Distinctive sulfur dioxide evolution patterns are observed among coals of different rank and between raw and treated coals. Assignments have been made relating each specific sulfur dioxide evolution to the non-aromatic organic, aromatic organic, and inorganic sulfur present in coals and treated coals. Work is progressing on schedule to optimize experimental conditions and to improve the efficiency of the controlled-atmosphere programmed-temperature oxidation (CAPTO) method by developing a multiple sample instrumental system.

LaCount, R.B.

1992-12-31T23:59:59.000Z

324

Effect of Sulfur Compounds and Higher Homologues of Methane on Hydrogen Cyanide Production by the Andrussow Method  

Science Journals Connector (OSTI)

The influence of sulfur compounds, higher homologues of methane on the parameters ofoxidative ammonolysis of methane was studied.

N. V. Trusov

2001-10-01T23:59:59.000Z

325

Sulfur dioxide and nitrogen dioxide levels inside and outside homes and the implications on health effects research  

Science Journals Connector (OSTI)

Sulfur dioxide and nitrogen dioxide levels inside and outside homes and the implications on health effects research ...

John D. Spengler; Benjamin G. Ferris Jr.; Douglas W. Dockery; Frank E. Speizer

1979-10-01T23:59:59.000Z

326

ORSSAB News Releases | Department of Energy  

Office of Environmental Management (EM)

ORSSAB News Releases ORSSAB News Releases December 1, 2014 The Oak Ridge Site Specific Advisory Board meets on the second Wednesday of the month. DOE seeks candidates for...

327

OREM Press Releases | Department of Energy  

Energy Savers (EERE)

Press Releases OREM Press Releases RSS November 14, 2014 The Oak Ridge Site Specific Advisory Board meets on the second Wednesday of the month. DOE seeks candidates for...

328

Geothermal Technologies Office Releases 2012 Annual Report |...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Geothermal Technologies Office Releases 2012 Annual Report Geothermal Technologies Office Releases 2012 Annual Report January 7, 2013 - 3:56pm Addthis The Geothermal Technologies...

329

MagLab - Press Release Archives  

NLE Websites -- All DOE Office Websites (Extended Search)

Releases Arrow News Archives 2013 News & Press Releases Date Subject Nov. 27 High Magnetic Field Science and Its Application in the United States: Current Status and Future...

330

Press Releases | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Areas Press Release Jan 16, 2015 NNSA Hosts Cybersecurity Consortium Members Following White House Announcement of 25 Million in Grants to 13 HBCUs Press Release Jan 13, 2015...

331

The Energy Department's Geothermal Technologies Office Releases...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

The Energy Department's Geothermal Technologies Office Releases 2013 Annual Report The Energy Department's Geothermal Technologies Office Releases 2013 Annual Report February 7,...

332

Changes in release cycles for EIA's  

Gasoline and Diesel Fuel Update (EIA)

Annual Energy Outlook Full Edition will be released in spring 2014, including analysis of energy issues and many alternative scenarios. Shorter will be released in late 2014 or...

333

Polymers in the Controlled Release of Agrochemicals  

Science Journals Connector (OSTI)

Chapter 3...describes the uses of polymeric materials in agriculture for controlled release formulations of agrochemicals, which are released into the environment of ... in agricultural application...

Ahmed Akelah

2013-01-01T23:59:59.000Z

334

Effects of Sulfur Dioxide on Formation of Fishy Off-Odor and Undesirable Taste in Wine Consumed with Seafood  

Science Journals Connector (OSTI)

Effects of Sulfur Dioxide on Formation of Fishy Off-Odor and Undesirable Taste in Wine Consumed with Seafood ... These results suggest that sulfur dioxide in wine participated in degradation of unsaturated fatty acids, causing an increase in undesirable taste and fishy off-odor in wine and seafood pairings. ... Wine; seafood; fishy off-odor; undesirable taste; unsaturated fatty acids; sulfur dioxide ...

Akiko Fujita; Atsuko Isogai; Michiko Endo; Hitoshi Utsunomiya; Shigeyoshi Nakano; Hiroshi Iwata

2010-03-10T23:59:59.000Z

335

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect

The work completed this past quarter has centered around the further study and characterization of the selective desulfurization of coal through the oxidative interaction of aqueous copper chloride. The reaction of the CuCl{sub 2} with the particular model compounds is conducted at a series of reaction times and reaction temperatures. The reaction times studied were 1, 3, 6, 12, and 24 hours. The reaction temperatures studied were 50, 130, 210, and 295{degree}C. After the reaction, the organic compounds were extracted with methylene chloride. These products were then analyzed via GC/IRD/MS and SFC/SCD (sulfur chemiluminescence detector). Model Coal Compounds reacted include: tetrahydrothiophene, methyl p-tolyl sulfide, cyclohexyl mercaptan, and thiophenol. At 130{degree}C, in addition to these compounds reacting, reactions were also detected for phenyl sulfide and benzo(b)thiophene. 14 figs.

Olesik, S. (comp.)

1990-01-01T23:59:59.000Z

336

Three-Dimensional Flower-Shaped Activated Porous Carbon/Sulfur Composites as Cathode Materials for Lithium–Sulfur Batteries  

Science Journals Connector (OSTI)

After the active sulfur impregnation, both the FESEM images (Figure 1e,f) and TEM images (Figure 2c) of the FA-PC/S composite demonstrate a flower-shaped 3D superstructure similar to the original FA-PC material. ... Early on, carbonaceous materials dominated the anode and hence most of the possible improvements in the cell were anticipated at the cathode terminal; on the other hand, major developments in anode materials made in the last portion of the decade with the introduction of nanocomposite Sn/C/Co alloys and Si-C composites have demanded higher capacity cathodes to be developed. ... The photodecompn. of methyl orange indicates that such ZnO superstructures possess excellent photocatalytic activity. ...

Lan Zhou; Tao Huang; Aishui Yu

2014-09-19T23:59:59.000Z

337

Five LBA Data Sets Released  

NLE Websites -- All DOE Office Websites (Extended Search)

Use-Land Change Data Sets Released Use-Land Change Data Sets Released The ORNL DAAC and the LBA DIS announce the release of three data sets from the Land Use-Land Change teams, components of the LBA-ECO Large Scale Biosphere-Atmosphere Experiment in Amazonia (LBA). LBA-ECO LC-09 Land Cover Transitions Maps for Study Sites in Para, Brazil: 1970-2001 . Data set prepared by E.S. Brondizio and E.F. Moran. This data set includes classified land cover transition maps at 30-m resolution derived from Landsat TM, MSS, ETM+ imagery and aerial photos of Altamira, Santarem, and Ponta de Pedras, in the state of Para, Brazil. The Landsat images were classified into several types of land use and subjected to change detection analysis to create transition matrices of land cover change. LBA-ECO LC-22 Post-deforestation Land Use, Mato Grosso, Brazil:

338

SAFARI 2000 Data Set Released  

NLE Websites -- All DOE Office Websites (Extended Search)

Set Released Set Released The ORNL DAAC announces the release of the data set "SAFARI 2000 MISR Level 2 Data, Southern Africa, Dry Season 2000". This data set is a product of the Southern African Regional Science Initiative containing 240 HDF-EOS formatted MISR Level 2 Top-of-Atmosphere/Cloud and Aerosol/Surface Products focused in a southern African study area which includes: Botswana, Lesotho, Malawi, Mozambique, Namibia, South Africa, Swaziland, Zambia, and Zimbabwe. The MISR Level 2 Products are geophysical measurements derived from the Level 1B2 data which consists of parameters that have been geometrically corrected and projected to a standard map grid. The products are in swaths, each derived from a single MISR orbit, where the imagery is 360 km wide and

339

Two Ecosystem Demography Models Released  

NLE Websites -- All DOE Office Websites (Extended Search)

Ecosystem Demography Models Released Ecosystem Demography Models Released The ORNL DAAC is pleased to announce the release of two Ecosystem Demography Models: Ecosystem Demography Model: U.S. Ecosystem Carbon Stocks and Fluxes, 1700-1990 . Data set prepared by G. Hurtt, S.W. Pacala, P.R. Moorcroft, J. Caspersen, E. Shevliakova, R.A. Houghton, B. Moore III, and J. Fisk. This model product contains the source code for the Ecosystem Demography Model (ED version 1.0) as well as model input and output data files for the conterminous United States. The ED is a mechanistic ecosystem model built around established sub-models of leaf level physiology, organic matter decomposition, hydrology, and functional biodiversity. It was used herein to estimate ecosystem carbon stocks and fluxes in the conterminous U.S. at

340

ORNL DAAC: Amazon Data Release  

NLE Websites -- All DOE Office Websites (Extended Search)

Amazon Data Released Amazon Data Released The ORNL DAAC announces the release of a data set associated with the LBA-ECO component of the Large-Scale Biosphere-Atmosphere Experiment in Amazonia (LBA). The data set "LBA-ECO CD-07 GOES-8 L3 Gridded Surface Radiation and Rain Rate for Amazonia: 1999" contains surface down-welling solar radiation, photosynthetically active radiation (PAR) and infrared radiation, as well as precipitation rates for the LBA study area at 8x8-km and half-hourly resolutions. The data cover the time periods March 1, 1999 - April 30, 1999, and September 1, 1999 - October 31, 1999. LBA is an international research initiative under the leadership of Brazil. The project focuses on the climatological, ecological, biogeochemical, and hydrological functions of Amazonia; the impact of land use change on these

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

News Releases | Advanced Materials | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

News & Awards News & Awards News Releases Honors & Awards News Features Advanced Materials Home | Science & Discovery | Advanced Materials | News & Awards | News Releases News Releases 1-7 of 7 Results ORNL devises recipe to fine-tune diameter of silica rods December 16, 2013 - OAK RIDGE, Tenn., Dec. 16, 2013 - By controlling the temperature of silica rods as they grow, researchers at the Department of Energy's Oak Ridge National Laboratory could be setting the stage for advances in anti-reflective solar cells, computer monitors, TV screens, eye glasses and more. ORNL's Bruce Pint elected 2014 NACE fellow December 13, 2013 - OAK RIDGE, Tenn., Dec. 13, 2013 - Bruce Pint, a research staff member at the Department of Energy's Oak Ridge National Laboratory, has been elected a 2014 National Association of Corrosion

342

Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestering Carbon Dioxide and Sulfur Dioxide Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,922,792 entitled "Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams." Disclosed in this patent is the invention of a neutralization/sequestration method that concomitantly treats bauxite residues from aluminum production processes, as well as brine wastewater from oil and gas production processes. The method uses an integrated approach that coincidentally treats multiple industrial waste by-product streams. The end results include neutralizing caustic

343

Method of making a current collector for a sodium/sulfur battery  

DOE Patents (OSTI)

This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

1987-03-10T23:59:59.000Z

344

The effect of sulfate sulfur on the yield and chemical composition of oats, vetch, and turnips  

E-Print Network (OSTI)

with sulfur and gypsum applications to alfalfa in Washington and Oregon. Subsequent vork showed that a large part of the ali'alfa land in Oregon vas deficient in sulfur. Experiments conducted over a period of several years on various soil types in southern... Oregon showed that, yields of ali'alf'a and cover crops could be increased from 50 percent to 1000 percent by the use of various fertilissrs containing sulfur (35). Other workers in Oregon ob- tained similar results with crops other than legumes...

Gipson, Jack Rogers

2012-06-07T23:59:59.000Z

345

Energy Dispersive X-ray Fluorescence Analysis of Sulfur in Biomass  

Science Journals Connector (OSTI)

An energy dispersive X-ray fluorescence (ED-XRF) spectroscopy method was developed to analyze low ppm level sulfur (S) in biomass feedstocks and in subsequent residues from pretreatment reactions. ... Representative biomass feedstocks and pretreatment residues were analyzed for S. ... The goal of this project was to determine whether an energy dispersive X-ray fluorescence (ED-XRF) spectroscopy method is effective in conducting sulfur analysis of woody biomass feedstocks at an appropriately useful sensitivity, especially when used to effectively monitor the extent of sulfur removal after biomass pretreatment reactions. ...

J. Michael Robinson; Staci R. Barrett; Kevin Nhoy; Rajesh K. Pandey; Joseph Phillips; Oscar M. Ramirez; Richard I. Rodriguez

2009-03-06T23:59:59.000Z

346

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

347

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

348

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

349

NEWS RELEASE FOR IMMEDIATE RELEASE Contact: Anthony Adornato  

E-Print Network (OSTI)

engineer named Burton Blatt Institute Fellow SYRACUSE, NY ­ James Abbott, professor of audio engineering of the renowned Music Engineering program at the University of Miami, Abbott's work can be heard on NPR, PBS. In 2010, a project he engineered for the Syracuse Society for New Music released on Innova Records

Mather, Patrick T.

350

EM Recovery Act Press Releases  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

press-releases Office of Environmental press-releases Office of Environmental Management 1000 Independence Ave., SW Washington, DC 20585 202-586-7709 en Idaho Site Completes Demolition of Cold War-era Nuclear Fuel Reprocessing Facility http://energy.gov/em/articles/idaho-site-completes-demolition-cold-war-era-nuclear-fuel-reprocessing Idaho Site Completes Demolition of Cold War-era Nuclear Fuel Reprocessing Facility

351

CSR Press Release Submitted by  

E-Print Network (OSTI)

CSR Press Release Submitted by: Categories: Posted: Energy Efficiency Listed as the Top important to their work. Across all five sectors included in the survey, energy efficiency was listed as by far the most important sustainability issue at hand, with water and land & soil falling to the bottom

352

MEDIA RELEASE 17 March 2011  

E-Print Network (OSTI)

's plan to build energy efficient rental housing for an additional 8,000 students on campus could resultMEDIA RELEASE 17 March 2011 Study suggests next step for BC's pioneering carbon neutral public sector British Columbia's pioneering move to create North America's first carbon neutral public sector

Pedersen, Tom

353

CSR Press Release Submitted by  

E-Print Network (OSTI)

in 2000, yet fuel consumption decreased by 3.2 million gallons. Fuel efficiency levels were improved, sophisticated routing technology and operational initiatives such as minimizing engine idling. Alternative fuelCSR Press Release Submitted by: Categories: Posted: UPS Sets New Automotive Goal to Improve Fuel

354

PRESS RELEASE January 28, 2013  

E-Print Network (OSTI)

PRESS RELEASE January 28, 2013 Media Contact Becky Kelly, FSU Panama City, Office of Advancement at (850) 770-2151 or rkelly@pc.fsu.edu. FLORIDA STATE UNIVERSITY PANAMA CITY SUMMER SCUBA LAB Panama City, FL--The Advanced Science Diving Program at Florida State University Panama City is offering a Summer

Weston, Ken

355

PRESS RELEASE February 13, 2013  

E-Print Network (OSTI)

PRESS RELEASE February 13, 2013 Media Contact Becky Kelly, FSU Panama City, Office of Advancement at (850) 770-2151 or rkelly@pc.fsu.edu. FLORIDA STATE UNIVERSITY PANAMA CITY SUMMER STEM CAMPS Panama City, FL--Florida State University Panama City STEM Institute's Summer STEM Camps are open to rising 8th

Weston, Ken

356

MEDIA ADVISORY FOR IMMEDIATE RELEASE  

E-Print Network (OSTI)

research to meet our changing energy goals, to market expansion of energy business solutions, to improved and vision in areas such as communications, energy, water, transportation, the environment, green jobs FOR IMMEDIATE RELEASE Media Contacts: CPUC: Terrie Prosper, 415-703-1366, news@cpuc.ca.gov California Energy

357

Sea Level Rise Media Release  

E-Print Network (OSTI)

Sea Level Rise Media Release Coverage Report 07/06/2009 Melting Ice Could Lead to Massive Waves 06/11/2009 Rising sea levels could see U.S. Atlantic coast cities make hard choices; Where to let Baltimore Chronicle & Sentinel, The 06/08/2009 Rapid rise in sea levels on East Coast predicted Pittsburgh

Hu, Aixue

358

CCPPressRelease October 2006  

E-Print Network (OSTI)

, which have been added to flight base prices since the unprecedented increases in the cost of oil they will be removed. In contrast to the conventional wisdom of pricing over the business cycle, a duopoly collusiveCCPPressRelease October 2006 Companies' Surcharges Make Higher Prices Possible W: www

Feigon, Brooke

359

Secondary Capture of Chlorine and Sulfur during Thermal Conversion of Biomass  

Science Journals Connector (OSTI)

Secondary Capture of Chlorine and Sulfur during Thermal Conversion of Biomass ... Six biomasses with different chemical compositions ... ... Therefore, different types of woody biomass and biomass residues (shells) were thermochemically converted in an atmospheric flow ... ...

Jacob N. Knudsen; Peter A. Jensen; Weigang Lin; Kim Dam-Johansen

2005-02-10T23:59:59.000Z

360

Structural analysis of sulfur in natural rubber using X-ray absorption near-edge spectroscopy  

Science Journals Connector (OSTI)

The opportunity to employ X-ray absorption near-edge spectroscopy techniques to investigate the alteration of the structural properties of sulfur in various vulcanized rubber sheets is presented.

Pattanasiriwisawa, W.

2008-07-11T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Cost-benefit analysis of ultra-low sulfur jet fuel  

E-Print Network (OSTI)

The growth of aviation has spurred increased study of its environmental impacts and the possible mitigation thereof. One emissions reduction option is the introduction of an Ultra Low Sulfur (ULS) jet fuel standard for ...

Kuhn, Stephen (Stephen Richard)

2010-01-01T23:59:59.000Z

362

Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and...  

Gasoline and Diesel Fuel Update (EIA)

EIA-782B, "Resellers'Retailers' Monthly Petroleum Product Sales Report." 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and Sales Type Energy Information Administration ...

363

E-Print Network 3.0 - aromatic sulfur compounds Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale Summary: . It has been also shown that most of the sulfur compounds in oil shale are...

364

Infrared and Raman Spectra of a Sulfur-resistant Methanation Catalyst  

Science Journals Connector (OSTI)

The infrared and Raman spectra of a sulfur-resistant NiO/Cr2O3/MgSiO3 methanation catalyst are presented and compared to the spectra of the catalyst...

Stencel, J M; Bradley, E B; Brown, Fred R

1980-01-01T23:59:59.000Z

365

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 1  

SciTech Connect

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim data report summarizes results as of August, 1999, on the status of the test programs being conducted on three technologies: lean-NO{sub x} catalysts, diesel particulate filters and diesel oxidation catalysts.

DOE; ORNL; NREL; EMA; MECA

1999-08-15T23:59:59.000Z

366

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India  

E-Print Network (OSTI)

High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

Chatterjee, A.

367

Effective hydrogen generation and resource circulation based on sulfur cycle system  

SciTech Connect

For the effective hydrogen generation from H{sub 2}S, it should be compatible that the increscent of the photocatalytic (or electrochemical) activities and the development of effective utilization method of by-products (poly sulfide ion). In this study, “system integration” to construct the sulfur cycle system, which is compatible with the increscent of the hydrogen and or electron energy generation ratio and resource circulation, is investigated. Photocatalytic hydrogen generation rate can be enhanced by using stratified photocatalysts. Photo excited electron can be transpired to electrode to convert the electron energy to hydrogen energy. Poly sulfide ion as the by-products can be transferred into elemental sulfur and/or industrial materials such as rubber. Moreover, elemental sulfur can be transferred into H{sub 2}S which is the original materials for hydrogen generation. By using this “system integration”, the sulfur cycle system for the new energy generation can be constructed.

Takahashi, Hideyuki; Mabuchi, Takashi; Hayashi, Tsugumi; Yokoyama, Shun; Tohji, Kazuyuki [Graduate School of Environmental Studies, Tohoku University 6-6-20, Aramaki, Aoba-ku, Sendai, 980-8579 (Japan)

2013-12-10T23:59:59.000Z

368

Project Profile: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage  

Energy.gov (U.S. Department of Energy (DOE))

General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power...

369

Electronic Transitions in Sulfur-Centered Radicals by Means of MSX? Calculations  

Science Journals Connector (OSTI)

Highly reactive sulfur-centered radicals, which play an important role in air pollution and in biological systems, are usually idientified by their UV/visible absorption and/or ESR spectra. Spectral informatio...

Maurizio Guerra

1990-01-01T23:59:59.000Z

370

Physicochemical aspects of the adsorption of sulfur dioxide by carbon adsorbents  

Science Journals Connector (OSTI)

Literature data on the chemistry of the adsorption of sulfur dioxide on carbon adsorbents are surveyed and described systematically. The influence of various factors (the nature of the carbon matrix, the activation method, the chemistry of the adsorbent surfaces, temperature, the composition of the gas stream, etc.) on the sorption of SO2 by activated carbons and semicokes is examined. The possible ways in which sulfur dioxide interacts with the carbon surface are discussed. The bibliography includes 128 references.

Sergey A Anurov

1996-01-01T23:59:59.000Z

371

Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation  

E-Print Network (OSTI)

SULFUR RESISTANCE OF GROUP VIII TRANSITION METAL PROMOTED NICKEL CATALYSTS FOR SYNTHESIS GAS METHANATION A Thesis by KELLEE HALL HAMLIN Submitted to the Graduate College of Texas AgrM University in partial fulfillment of the requirement...: Aydin Akger n (Chairman of Co 'ttee) Ahme M. Gadalla (Member) Michael . Rosynek (Member) aries D. Holland . ( ead of Department) May 1986 ABSTRACT Sulfur Resistance of Group VIII Transition Metal Promoted Nickel Catalysts For Synthesis Gas...

Hamlin, Kellee Hall

2012-06-07T23:59:59.000Z

372

The complete genome sequence of Staphylothermus marinus reveals differences in sulfur metabolism among heterotrophic Crenarchaeota  

SciTech Connect

Staphylothermus marinus is an anaerobic, sulfur-reducing peptide fermenter of the archaeal phylum Crenarchaeota. It is the third heterotrophic, obligate sulfur reducing crenarchaeote to be sequenced and provides an opportunity for comparative analysis of the three genomes. The 1.57 Mbp genome of the hyperthermophilic crenarchaeote Staphylothermus marinus has been completely sequenced. The main energy generating pathways likely involve 2-oxoacid:ferredoxin oxidoreductases and ADP-forming acetyl-CoA synthases. S. marinus possesses several enzymes not present in other crenarchaeotes including a sodium ion-translocating decarboxylase likely to be involved in amino acid degradation. S. marinus lacks sulfur-reducing enzymes present in the other two sulfur-reducing crenarchaeotes that have been sequenced - Thermofilum pendens and Hyperthermus butylicus. Instead it has three operons similar to the mbh and mbx operons of Pyrococcus furiosus, which may play a role in sulfur reduction and/or hydrogen production. The two marine organisms, S. marinus and H. butylicus, possess more sodium-dependent transporters than T. pendens and use symporters for potassium uptake while T. pendens uses an ATP-dependent potassium transporter. T. pendens has adapted to a nutrient-rich environment while H. butylicus is adapted to a nutrient-poor environment, and S. marinus lies between these two extremes. The three heterotrophic sulfur-reducing crenarchaeotes have adapted to their habitats, terrestrial vs. marine, via their transporter content, and they have also adapted to environments with differing levels of nutrients. Despite the fact that they all use sulfur as an electron acceptor, they are likely to have different pathways for sulfur reduction.

Anderson, iain J.; Dharmarajan, Lakshmi; Rodriguez, Jason; Hooper, Sean; Porat, Iris; Ulrich, Luke E.; Elkins, James G.; Mavromatis, Kostas; Sun, Hui; Land, Miriam; Lapidus, Alla; Lucas, Susan; Barry, Kerrie; Huber, Harald; Zhulin, Igor B.; Whitman, William B.; Mukhopadhyay, Biswarup; Woese, Carl; Bristow, James; Kyrpides, Nikos

2008-09-05T23:59:59.000Z

373

A Mathematical Model for a LithiumSulfur Cell Karthikeyan Kumaresan,a,  

E-Print Network (OSTI)

S8 l is reduced to S2- in steps. For example, S8 l is reduced to S8 2- , then to S6 2- , S4 2- , S2,4 Figure 1 presents a typical experimental discharge profile at a C/50 rate C = 2.5 Ah . The lithium/sulfur Development The schematic of the lithium/sulfur cell modeled in this work is shown in Fig. 2. The cell is made

374

Development of Efficient Flowsheet and Transient Modeling for Nuclear Heat Coupled Sulfur Iodine Cyclefor Hydrogen Production  

SciTech Connect

The realization of the hydrogen as an energy carrier for future power sources relies on a practical method of producing hydrogen in large scale with no emission of green house gases. Hydrogen is an energy carrier which can be produced by a thermochemical water splitting process. The Sulfur-Iodine (SI) process is an example of a water splitting method using iodine and sulfur as recycling agents.

Shripad T. Revankar; Nicholas R. Brown; Cheikhou Kane; Seungmin Oh

2010-05-01T23:59:59.000Z

375

EIA - Annual Energy Outlook 2013 Early Release  

Gasoline and Diesel Fuel Update (EIA)

AEO2013 Early Release Overview AEO2013 Early Release Overview Release Date: December 5, 2012 | Report Release Schedule: April 15 - May 2, 2013 | Report Number: DOE/EIA-0383ER(2013) This release is an abridged version of the Annual Energy Outlook that highlights changes in the AEO Reference case projections for key energy topics. The Early Release includes data tables for the Reference case only. The AEO2013 will be released between April 15 and May 2. See release schedule. . Download the AEO2013 Early Release Report Introduction In preparing the AEO2013 Reference case, the U.S. Energy Information Administration (EIA) evaluated a wide range of trends and issues that could have major implications for U.S. energy markets. This overview presents the AEO2013 Reference case and compares it with the AEO2012 Reference case

376

NETL: News Release - DOE Announces Release of Second Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

November 17, 2008 November 17, 2008 DOE Announces Release of Second Carbon Sequestration Atlas New Version Provides Additional Information on Carbon Dioxide Storage 2008 Carbon Sequestration Atlas II WASHINGTON, D. C.- The U.S. Department of Energy (DOE) today announced the release of its second Carbon Sequestration Atlas of the United States and Canada, which documents more than 3,500 billion metric tons of carbon dioxide (CO2) storage potential in oil and gas reservoirs, coal seams, and saline formations. Preliminary estimates suggest the availability of more than 1,100 years of CO2 storage for the United States and Canada in these geologic formations. "In the year since it was first published, the carbon sequestration atlas has proven to be an invaluable tool to the entire sequestration community," said Acting Assistant Secretary for Fossil Energy James Slutz. "The second edition will bolster our efforts to find environmentally sound, cost-effective methods to sequester carbon dioxide."

377

NETL: News Release -Treasury, Energy Departments Release New Advanced Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

7, 2007 7, 2007 Treasury, Energy Departments Release New Advanced Coal Project Tax Credit Applications for 2007-2008 WASHINGTON, DC - The Treasury Department and the Department of Energy (DOE) released today new instructions for applying for the tax credits for advanced coal projects and gasification projects. The new instructions provide additional time to submit applications for the credits. For the 2007-2008 allocation round, applications for DOE certification are not due to the Energy Department until October 31, 2007. "To further advance our nation's energy security, this Administration had made sustained investments in research, development, and wider use of advanced coal technologies a priority," Deputy Secretary of Energy Clay Sell said. "Through new and innovative programs such as the Clean Coal Power Initiative and FutureGen demonstration, private sector partnerships, and use of tax credits and loan guarantees, the Department of Energy is advancing research to further develop and deploy advanced coal technologies to meet growing energy demand."

378

NETL: News Release - DOE Releases Draft Funding Opportunity Announcement  

NLE Websites -- All DOE Office Websites (Extended Search)

October 4, 2007 October 4, 2007 DOE Releases Draft Funding Opportunity Announcement for CCPI Round 3 Washington, DC - The U.S. Department of Energy has released for public comment the draft Funding Opportunity Announcement (FOA), Model Cooperative Agreement, and Model Payment Agreement for Round 3 of the Clean Coal Power Initiative (CCPI). CCPI invites private industries to partner with Government to demonstrate new clean coal technologies at commercial scale. MORE INFO Read the Draft FOA Register for the Public Workshop [beginning 10.05.07] The draft FOA allows interested parties to voice concerns and seek answers to questions regarding the cost-shared partnership. The public comment period begins immediately and continues through November 9, 2007. In addition, a public meeting will be held on November 1, 2007, at the Hyatt

379

Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products  

SciTech Connect

A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

2011-11-17T23:59:59.000Z

380

Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks  

SciTech Connect

Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

Lopez-Lopez, D.; Wong-Moreno, A. [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1998-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

released  

NLE Websites -- All DOE Office Websites (Extended Search)

Arctic Arctic algae, a cereal crop whose genetic code is nearly equivalent to sequencing two full human genomes, and microbial communities in deep- sea hydrothermal vents are among the 35 projects selected by the U.S. Department of Energy (DOE) Joint Genome Institute (JGI) for its 2011 Community Sequencing Program (CSP) to be character- ized for bioenergy and environ- mental applications. Enabling scientists from universities and national labo- ratories around the world to probe the hidden world of microbes and plants to meet the DOE missions of bioenergy, carbon cycling and biogeo- chemistry, this year's CSP portfolio is composed mostly of large-scale projects, which DOE JGI Director Eddy Rubin said was in keeping with the facility's mission of large-scale genomics and analysis. "Advances in sequencing technologies are really chang- ing the landscape and have dramatically

382

BOREAS Release, Oct. 15, 1999  

NLE Websites -- All DOE Office Websites (Extended Search)

Oct. 15 Oct. 15 Six new data sets from the Boreal Ecosystem-Atmosphere Study (BOREAS) were released by the ORNL DAAC on October 15, 1999. The release brings the total number to 186 data sets currently available. The newest data are related to hydrology, remote sensing, and background measurements (called "staff science"): BOREAS HYD-09 Hourly and Daily Radar Rainfall Maps for the Southern Study Area - Radar data that can be used to construct hourly and daily rainfall maps. BOREAS RSS-02 Extracted Reflectance Factors Derived from ASAS Imagery - Reflectance factors for small homogeneous areas around ground measurement sites, derived from remote sensing imagery. BOREAS Daedalus TMS Level-0 Imagery Digital Counts in BIL Format - Remotely sensed images showing radiant energy in the visible,

383

NREL: News - Release Archives 2008  

NLE Websites -- All DOE Office Websites (Extended Search)

Printable Version Printable Version News Release Archives 2008 News releases covering laboratory activities, scientific discoveries, projects and more are archived below, chronologically. For more information about NREL and its research in renewable energy and energy efficiency technologies, e-mail public_affairs@nrel.gov. December 11, 2008 Alternative Fuels and Advanced Vehicle Data Center Creates New Tool to Calculate Ways to Cut Gas Use A business owner with a fleet of 10 heavy-duty diesel trucks wants to cut diesel use by 10 percent. Would using a biodiesel blend or investing in onboard power sources that reduce engine idling achieve the biggest drop in petroleum use? An average driver, using 600 gallons of gas a year in a typical sedan, wants to reduce gas consumption by 20 percent. Would using

384

National Atmospheric Release Advisory Center  

NLE Websites -- All DOE Office Websites (Extended Search)

NARAC TOC NARAC TOC The National Atmospheric Release Advisory Center, NARAC, provides tools and services to the Federal Government, that map the probable spread of hazardous material accidentally or intentionally released into the atmosphere. NARAC provides atmospheric plume predictions in time for an emergency manager to decide if taking protective action is necessary to protect the health and safety of people in affected areas. Located at the Lawrence Livermore National Laboratory, NARAC is a national support and resource center for planning, real-time assessment, emergency response, and detailed studies of incidents involving a wide variety of hazards, including nuclear, radiological, chemical, biological, and natural emissions. In an emergency situation (if lives are at risk), event-specific NARAC

385

AEO2010 Early Release Overview  

Gasoline and Diesel Fuel Update (EIA)

10 10 Early Release Overview December 2009 Energy Trends to 2035 In preparing the Annual Energy Outlook 2010 (AEO- 2010), the Energy Information Administration (EIA) evaluated a wide range of trends and issues that could have major implications for U.S. energy markets. This overview focuses primarily on one case, the AEO2010 reference case, which is presented and com- pared with the updated Annual Energy Outlook 2009 (updated AEO2009) reference case released in April 2009 1 (see Table 1). Because of the uncertainties in- herent in any energy market projection, particularly in periods of high price volatility, rapid market trans- formation, or active changes in legislation, the refer- ence case results should not be viewed in isolation. Readers are encouraged to review the alternative cases when the complete AEO2010 publication is re- leased in order to gain perspective on how variations

386

NREL: News - Release Archives 2009  

NLE Websites -- All DOE Office Websites (Extended Search)

Printable Version Printable Version News Release Archives 2009 News releases covering laboratory activities, scientific discoveries, projects and more are archived below, chronologically. For more information about NREL and its research in renewable energy and energy efficiency technologies, e-mail public_affairs@nrel.gov. December 23, 2009 New NREL Web Site Helps Campuses Go Green The U.S. Department of Energy's National Renewable Energy Laboratory and Cornell University have launched a Web site to help campus-based institutions develop clean energy and carbon-reduction strategies. December 22, 2009 NREL Evaluates UPS Hybrid-Electric Van Performance The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) has collected and analyzed fuel economy, maintenance and other

387

2012 Microgrid Workshop Summary Released  

Energy.gov (U.S. Department of Energy (DOE))

The Department of Energy has released the summary report from the July 30-31, 2012 Microgrid Workshop presented by the Office of Electricity Delivery and Energy Reliability at the Illinois Institute of Technology in Chicago. The workshop was held in response to discussions at the preceding DOE Microgrid Workshop, held in August 2011, which called for sharing lessons learned and best practices for system integration from existing projects in the U.S. (including military microgrids) and internationally.

388

Comparison of Comprehensive Two-Dimensional Gas Chromatography Coupled with Sulfur-Chemiluminescence Detector to Standard Methods for Speciation of Sulfur-Containing Compounds in Middle Distillates  

Science Journals Connector (OSTI)

......in seconds). The general elution profile was...sulfur-specific analysis of diesel oils. Comparison...different types of diesel oils by XRF and GC...and LCO, light cycle gasoil. Figure 2...components in a light cycle oil of catalytic...compounds in gasoline and diesel range process streams......

Rosario Ruiz-Guerrero; Colombe Vendeuvre; Didier Thiébaut; Fabrice Bertoncini; Didier Espinat

2006-10-01T23:59:59.000Z

389

Hydrogenase of the hyperthermophile Pyrococcus furiosus is an elemental sulfur reductase or sulfhydrogenase: evidence for a sulfur-reducing hydrogenase ancestor  

Science Journals Connector (OSTI)

...polysulfide reduction/geothermal biolog/evolution...appears to be an energy-conserving reaction...The publication costs of this article...sulfur-rich, geothermal environ- ments...fact, represent an energy- conserving reaction...the Department of Energy (FG09-88ER13901...

K Ma; R N Schicho; R M Kelly; M W Adams

1993-01-01T23:59:59.000Z

390

Comparison of Comprehensive Two-Dimensional Gas Chromatography Coupled with Sulfur-Chemiluminescence Detector to Standard Methods for Speciation of Sulfur-Containing Compounds in Middle Distillates  

Science Journals Connector (OSTI)

......discussed later (16,19). For straight-run samples (SR1 and SR2, Figures...identification of C4 and C5DBTs). For straight-run samples (SR1 and SR2), the...analysis of sulfur com- pounds in gasoline range petroleum products with......

Rosario Ruiz-Guerrero; Colombe Vendeuvre; Didier Thiébaut; Fabrice Bertoncini; Didier Espinat

2006-10-01T23:59:59.000Z

391

EIA - Annual Energy Outlook 2014 Early Release  

U.S. Energy Information Administration (EIA) Indexed Site

AEO2014 Early Release Overview AEO2014 Early Release Overview Release Date: December 16, 2013 | Full Report Release Date: Early Spring 2014 | correction | Report Number: DOE/EIA-0383ER(2014) This release is an abridged version of the Annual Energy Outlook that highlights changes in the AEO Reference case projections for key energy topics. The Early Release includes data tables for the Reference case only. The AEO2014 full version will be released early Spring 2014. Download the AEO2014 Early Release Report Introduction In preparing the AEO2014 Reference case, the U.S. Energy Information Administration (EIA) evaluated a wide range of trends and issues that could have major implications for U.S. energy markets. This overview presents the AEO2014 Reference case and compares it with the AEO2013 Reference case

392

News Releases & Features | Nuclear Science | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

News Releases SHARE News Releases and Features 1-2 of 2 Results U.S. Rep. Fleischmann touts ORNL as national energy treasure February 11, 2011 - OAK RIDGE, Tenn., Feb. 11, 2011 -...

393

BPA releases I-5 Corridor Reinforcement Project  

NLE Websites -- All DOE Office Websites (Extended Search)

RELEASE Tuesday, Nov. 13, 2012 CONTACT: Doug Johnson, 503-230-5840 or 503-230-5131 BPA releases I-5 Corridor Reinforcement Project Draft EIS and preferred alternative...

394

DOE Issues WIPP Radiological Release Investigation Report  

Energy.gov (U.S. Department of Energy (DOE))

Today, the Department of Energy’s Office of Environmental Management (EM) released the initial accident investigation report related to the Feb. 14 radiological release at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico.

395

Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities  

U.S. Energy Information Administration (EIA) Indexed Site

(Percent) (Percent) Type: Sulfur Content API Gravity Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Type Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 1.43 1.38 1.41 1.43 1.47 1.42 1985-2013 PADD 1 0.75 0.73 0.69 0.68 0.73 0.68 1985-2013 East Coast 0.67 0.66 0.61 0.63 0.66 0.57 1985-2013 Appalachian No. 1 2.0 1.72 1.52 1.40 1.55 1.74 1985-2013 PADD 2 1.42 1.34 1.44 1.46 1.61 1.49 1985-2013 Ind., Ill. and Ky. 1.45 1.36 1.47 1.56 1.75 1.67 1985-2013 Minn., Wis., N. Dak., S. Dak. 2.33 2.11 2.18 2.03 2.01 1.69 1985-2013 Okla., Kans., Mo. 0.89 0.89 0.92 0.82 0.87 0.85 1985-2013 PADD 3 1.54 1.48 1.51 1.52 1.54 1.48 1985-2013

396

Isotope shift in the sulfur electron affinity: Observation and theory  

SciTech Connect

The sulfur electron affinities {sup e}A(S) are measured by photodetachment microscopy for the two isotopes {sup 32}S and {sup 34}S (16 752.975 3(41) and 16 752.977 6(85) cm{sup -1}, respectively). The isotope shift in the electron affinity is found to be more probably positive, {sup e}A({sup 34}S)- {sup e}A({sup 32}S) =+0.0023(70) cm{sup -1}, but the uncertainty allows for the possibility that it may be either ''normal''[{sup e}A({sup 34}S) > {sup e}A({sup 32}S)] or ''anomalous''[{sup e}A({sup 34}S) < {sup e}A({sup 32}S)]. The isotope shift is estimated theoretically using elaborate correlation models, monitoring the electron affinity and the mass polarization term expectation value. The theoretical analysis predicts a very large specific mass shift (SMS) that counterbalances the normal mass shift (NMS) and produces an anomalous isotope shift {sup e}A({sup 34}S)- {sup e}A({sup 32}S) =-0.0053(24) cm{sup -1}, field shift corrections included. The total isotope shift can always be written as the sum of the NMS (here +0.0169 cm{sup -1}) and a residual isotope shift (RIS). Since the NMS has nearly no uncertainty, the comparison between experimental and theoretical RIS is more fair. With respective values of -0.0146(70) cm{sup -1} and -0.0222(24) cm{sup -1}, these residual isotope shifts are found to agree within the estimated uncertainties.

Carette, Thomas; Scharf, Oliver; Godefroid, Michel [Chimie Quantique et Photophysique, Universite Libre de Bruxelles - CP160/09, B-1050 Brussels (Belgium); Drag, Cyril; Blondel, Christophe; Delsart, Christian [Laboratoire Aime-Cotton, CNRS, Universite Paris-sud, F-91405 Orsay cedex (France); Froese Fischer, Charlotte [National Institute of Standards and Technology Gaithersburg, Maryland 20899-8420 (United States)

2010-04-15T23:59:59.000Z

397

The release of phosphorus during sediment resuspension  

Science Journals Connector (OSTI)

The release of phosphorus from sediments to overlaying water was studied during laboratory and in situ experiments.

Ryszard N. Wisniewski

1993-01-01T23:59:59.000Z

398

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992; Revision  

SciTech Connect

The initial technical goal in the project was to develop a chemical method for the cost effective removal of both inorganic and organic sulfur from Ohio coals. Verifying and using a process of reacting ethanol vapors with coal under conditions disclosed in U.S. Patent 4,888,029, the immediate technical objectives were to convert a small scale laborative batch process to a larger scale continuous process which can serve as the basis for commercial development of the technology. This involved getting as much information as possible from small scale batch autoclave or fluid bed laboratory reactors for use in pilot plant studies. The laboratory data included material balances on the coal and sulfur, temperature and pressure ranges for the reaction, minimum reaction times at different conditions, the effectiveness of different activators such as oxygen and nitric oxide, the amount and nature of by-products such as sulfur dioxide, hydrogen sulfide and acetaldehyde, the effect of coal particle size on the speed and completeness of the reaction, and the effectiveness of the reaction on different Ohio coals. Because the laboratory experiments using the method disclosed in U.S. 4,888,029 were not successful, the objective for the project was changed to develop a new laboratory process to use ethanol to remove sulfur from coal. Using copper as a catalyst and as an H{sub 2}S scavenger, a new laboratory procedure to use ethanol to remove sulfur from coal has been developed at Ohio University and a patent application covering this process was filed in March, 1993. The process is based on the use of copper as a catalyst for the dehydrogenation of ethanol to produce nascent hydrogen to remove sulfur from the coal and the use of copper as a scavenger to capture the hydrogen sulfide formed from the sulfur removed from coal.

Savage, R.L.; Lazarov, L.K.; Prudich, M.E.; Lange, C.A.; Kumar, N.

1994-03-10T23:59:59.000Z

399

Effects of Fuel Sulfur Content and Diesel Oxidation Catalyst on PM Emitted from Light-Duty Diesel Engine  

Science Journals Connector (OSTI)

This work aims at the particle number concentrations and size distributions, sulfate and trace metals emitted from a diesel engine fueled with three different sulfur content fuels, operating with and without DOC. ... Figure 2. Sulfate emission rate and fuel consumption as a function of sulfur content at engine speed of 2690 rpm. ... Thus, the use of low metal fuels and lubricating oil is as important to the environment and human health as low sulfur fuels, especially for engines with after-treatment devices. ...

Hong Zhao; Yunshan Ge; Xiaochen Wang; Jianwei Tan; Aijuan Wang; Kewei You

2010-01-05T23:59:59.000Z

400

TUDE DE L'ABSORPTION ULTRAVIOLETTE DU SULFURE DE CARBONE Par Mlles ODETTE AMIOT et HENRIETTE MARSAC.  

E-Print Network (OSTI)

dilué de plus en plus le sulfure de carbone dans un solvant inactif. Nous avons choisi l'hexane, liquide montage par autocollimation. 2. Purification du sulfure de carbone et prépa- ration des solutions. - On sait que le sulfure de car- bone est un liquide altérable et qu'il se décompose à la lumière avec

Boyer, Edmond

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Sulfur Degassing From Volcanoes: Source Conditions, Surveillance, Plume Chemistry and Earth System Impacts  

Science Journals Connector (OSTI)

...would therefore release 4-5 Gt of...especially energetic fire fountains and...substantial fraction of the released...ground-based or airborne ultraviolet...spontaneous releases of SO2 to the...substantial fractions of the total...Pinatubo. In: Fire and mud: eruptions...quantification of gas release during weak...

Clive Oppenheimer; Bruno Scaillet; Robert S. Martin

402

UNDERSTANDING OF CATALYST DEACTIVATION CAUSED BY SULFUR POISONING AND CARBON DEPOSITION IN STEAM REFORMING OF LIQUID HYDROCARBON FUELS.  

E-Print Network (OSTI)

??The present work was conducted to develop a better understanding on the catalyst deactivation in steam reforming of sulfur-containing liquid hydrocarbon fuels for hydrogen production.… (more)

Xie, Chao

2011-01-01T23:59:59.000Z

403

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation .  

E-Print Network (OSTI)

??The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test… (more)

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

404

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network (OSTI)

world-best-practice-energy- intensity-values-selected-World Best Practice Energy Intensity Values for Selectedof the Targets for Energy Intensity and Sulfur Dioxide in

Zhou, Nan

2013-01-01T23:59:59.000Z

405

The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen .  

E-Print Network (OSTI)

??The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming -… (more)

Miu, Kevin (Kevin K.)

2006-01-01T23:59:59.000Z

406

DOC-DOE China Mission Announcement Press Release | Department...  

Office of Environmental Management (EM)

China Mission Announcement Press Release DOC-DOE China Mission Announcement Press Release DOC-DOE China Mission Announcement Press Release DOC-DOE China Mission Announcement Press...

407

Toward Understanding the Effect of Nuclear Waste Glass Composition of Sulfur Solubility  

SciTech Connect

The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

Vienna, John D.; Kim, Dong-Sang; Muller, I. S.; Kruger, Albert A.; Piepel, Gregory F.

2014-02-13T23:59:59.000Z

408

THE EFFECT OF ANOLYTE PRODUCT ACID CONCENTRATION ON HYBRID SULFUR CYCLE PERFORMANCE  

SciTech Connect

The Hybrid Sulfur (HyS) cycle (Fig. 1) is one of the simplest, all-fluids thermochemical cycles that has been devised for splitting water with a high-temperature nuclear or solar heat source. It was originally patented by Brecher and Wu in 1975 and extensively developed by Westinghouse in the late 1970s and early 1980s. As its name suggests, the only element used besides hydrogen and oxygen is sulfur, which is cycled between the +4 and +6 oxidation states. HyS comprises two steps. One is the thermochemical (>800 C) decomposition of sulfuric acid (H{sub 2}SO{sub 4}) to sulfur dioxide (SO{sub 2}), oxygen (O{sub 2}), and water. H{sub 2}SO{sub 4} = SO{sub 2} + 1/2 O{sub 2} + H{sub 2}O. The other is the SO{sub 2}-depolarized electrolysis of water to H{sub 2}SO{sub 4} and hydrogen (H{sub 2}), SO{sub 2} + 2 H{sub 2}O = H{sub 2}SO{sub 4} + H{sub 2}, E{sup o} = -0.156 V, explaining the 'hybrid' designation. These two steps taken together split water into H{sub 2} and O{sub 2} using heat and electricity. Researchers at the Savannah River National Laboratory (SRNL) and at the University of South Carolina (USC) have successfully demonstrated the use of proton exchange membrane (PEM) electrolyzers (Fig. 2) for the SO{sub 2}-depolarized electrolysis (sulfur oxidation) step, while Sandia National Laboratories (SNL) successfully demonstrated the high-temperature sulfuric acid decomposition (sulfur reduction) step using a bayonet-type reactor (Fig. 3). This latter work was performed as part of the Sulfur-Iodine (SI) cycle Integrated Laboratory Scale demonstration at General Atomics (GA). The combination of these two operations results in a simple process that will be more efficient and cost-effective for the massive production of hydrogen than alkaline electrolysis. Recent developments suggest that the use of PEMs other than Nafion will allow sulfuric acid to be produced at higher concentrations (>60 wt%), offering the possibility of net thermal efficiencies around 50% (HHV basis). The effect of operation at higher anolyte concentrations on the flowsheet, and on the net thermal efficiency for a nuclear-heated HyS process, is examined and quantified.

Gorensek, M.; Summers, W.

2010-03-24T23:59:59.000Z

409

Sulfur-passivated nickel catalysts for carbon-free steam reforming of methane  

SciTech Connect

It has been observed that carbon-free steam reforming of methane can be obtained on a partly sulfur-passivated nickel catalyst under conditions which, without the presence of sulfur, would result in formation of whisker carbon. This effect has been studied by means of kinetic experiments and thermogravimetry. The kinetic data can be explained by simple blockage of the surface as reflected in the observed kinetic orders and activation energy. The studies of carbon formation confirm a threshold coverage of about 70% of full coverage below which the inhibition of carbon is not effective. Above this coverage, amorphous carbon structures may be formed at a very high carbon potentials. The retarding effect of sulfur on carbon formation is a dynamic phenomenon. Sulfur inhibits the rate of carbon formation more than the rate of the reforming reactions. The effects are explained by assuming that a large ensemble is involved in the nucleation of carbon, whereas the reforming reaction can proceed on the small ensembles left a high sulfur coverages. 6 figures, 6 tables.

Rostrup-Nielsen, J.R.

1984-01-01T23:59:59.000Z

410

Sulfur transformations in early diagenetic sediments from the Bay of Concepcion, off Chile  

SciTech Connect

Despite the recognition that both organic sulfur and pyrite form during the very early stages of diagenesis, and that the amount of H{sub 2}S generated in bacterial sulfate reduction primarily limits their formation, the mechanisms and the active species involved still are not clear. In this study, we quantified the major forms of sulfur distributed in sediments to assess the geochemical mechanisms involved in these transformations. XANES spectroscopy, together with elemental analysis, were used to measure sulfur speciation in the organic-rich sediments from the Bay of Concepcion, Chile. Organic polysulfides constituted the major fraction of the organic sulfur, and occurred maximally just below the sediment surface (1--3 cm), where intermediates from H{sub 2}S oxidation were likely to be generated most abundantly. Sulfonates, which could be formed through the reactions of sulfate and thiosulfate, also showed a sub-surface maximum in the vicinity of the ``oxic-anoxic interface``. These results strongly suggest a geochemical origin for organic polysulfides and sulfonates, and illustrate that intermediates from H{sub 2}S oxidation play a dominant role in incorporating sulfur into organic matter. Pyrite was absent in the surficial layer, and first appeared just below the H{sub 2}S maximum, where organic polysulfides began to decrease in abundance. From these results, we argue, that an iron monosulfide precursor formed first from reactions with H{sub 2}S, and then reacts with organic polysulfides, completing the synthesis of pyrite in the sediment column.

Vairavamurth, M.A.; Wang, Shengke; Khandelwal, B.; Manowitz, B. [Brookhaven National Lab., Upton, NY (United States); Ferdelman, T.; Fossing, H. [Max Plank Institute for Marine Microbiology, Bremen (Germany). Dept. of Biogeochemistry

1995-04-01T23:59:59.000Z

411

Computational studies of experimentally observed structures of sulfur on metal surfaces  

SciTech Connect

First-principles electronic structure calculations were carried out to examine the experimentally observed structures of sulfur on close packed surfaces of a number of important metals - Ag(111), Cu(111), Ni(111), Pt(111), Rh(111), Re(0001) and Ru(0001). At low coverages ({le} 1/3 ML), the prediction is consistent with the typical pattern of preferred sulfur occupancy of threefold hollow sites, notably the fcc site on the (111) surfaces and the hcp site on the (0001) surfaces. Theoretical confirmation for the existence of pure sulfur overlayer phases on Pt(111), Rh(111), Re(0001) and Ru(0001) at higher coverages (> 1/3 ML) was provided. For the ({radical}7 x {radical}7) phase seen on Ag(111), the most preferred structure identified for adsorbed S trimer consists of an S atom on the top site bonded to two S atoms situated on the nearest neighbor off-bridge site positions. Among the different densely packed mixed sulfur-metal overlayer models suggested for the ({radical}7 x {radical}7) phase on Cu(111), the structure which consists of metal and S atoms in a hexagonal-like arrangement on the top substrate was found to be the most energetically favorable. For the (5{radical}3 x 2) phase on Ni(111), the calculations confirm the existence of clock-reconstructed top layer metal atoms onto which sulfur atoms are adsorbed.

Alfonso, Dominic

2011-09-01T23:59:59.000Z

412

NREL: News - Release Archives 2004  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 News releases covering laboratory activities, scientific discoveries, projects and more are archived below, chronologically. For more information about NREL and its research in renewable energy and energy efficiency technologies, e-mail public_affairs@nrel.gov. December 21, 2004 NREL Recognizes Solar Pioneer with National Honor November 23, 2004 NREL Recognizes Solar Pioneer with National Honor November 17, 2004 Basalt Middle School Teacher Recognized for Renewable Energy Efforts October 5, 2004 NREL Theorist Recognized for Highest Citation Impact September 24, 2004 NREL Selects Contractor for New Science & Technology Facility August 26, 2004 NREL Praised for Efforts in Sustainable Pollution Prevention August 19, 2004 FLC Recognizes Laboratory's Technology Transfer Activities

413

A modified release analysis procedure using advanced froth flotation mechanisms: Technical report, March 1, 1996-May 31, 1996  

SciTech Connect

Recent studies indicate that the optimum separation performances achieved by multiple stage cleaning using various column flotation technologies and single stage cleaning using a Packed-Flotation Column are superior to the performance achieved by the traditional release procedure, especially in terms of pyritic sulfur rejection. This superior performance is believed to be the result of the advanced flotation mechanisms provided by column flotation technologies. Thus, the objective of this study is to develop a suitable process utilizing the advanced froth flotation mechanisms to characterize the true flotation response of a coal sample. Work in this reporting period concentrated on developing a modified coal flotation characterization procedure, termed as Advanced Flotation Washability (AFW) technique. The new apparatus used for this procedure is essentially a batch operated packed-column device equipped with a controlled wash water system. Several experiments were conducted using the AFW technique on a relatively high sulfur, -100 mesh Illinois No. 5 run-of-mine coal sample collected from a local coal preparation plant. Similar coal characterization experiments were also conducted using the traditional release and tree analysis procedures. The best performance curve generated using the AFW technique was found to be superior to the optimum curve produced by the traditional procedures. For example, at a combustible recovery of 80%, a 19% improvement in the reduction of the pyritic sulfur content was achieved by the AFW method while the ash reduction was also enhanced by 4%. Several tests are on-going to solidify the AFW procedure and verify the above finding by conducting Anova analyses to evaluate the repeatability of the AFW method and the statistical significance of the difference in the performance achieved from the traditional and modified coal characterization procedures.

Honaker, R.Q., Mohanty, M.K. [Southern Illinois Univ., Department of Mining Engineering, Carbondale, IL (United States)

1997-04-01T23:59:59.000Z

414

Sodium/Phosphorus-Sulfur Cells I. Cell Performance Paul L. Ridgway,  

NLE Websites -- All DOE Office Websites (Extended Search)

Sodium/Phosphorus-Sulfur Cells Sodium/Phosphorus-Sulfur Cells I. Cell Performance Paul L. Ridgway, Frank R. McLarnon, and Elton J. Cairns* Energy and Environment Division, Lawrence Berkeley National Laboratory, and Department of Chemical Engineering, University of California, Berkeley, California 94720, USA ABSTRACT Sodium/°-alumina/phosphorus-sulfur cells utilizing P/S ratios of 0, 0.143, 0.332, and 1.17 at temperatures from 350 to 500°C were studied by measurement of the equilibrium cell voltages at open circuit, and the steady-state cell voltages at current densities up to 70 mA/cm2. States of charge, represented by sodium atom fraction in the P-S electrode, ranged from 0 to 0.4. Open-circuit voltages up to 2.65 V were measured. Theoretical specific energies up to 825 Wh/kg were cal-

415

Electrochemical separation and concentration of sulfur containing gases from gas mixtures  

DOE Patents (OSTI)

A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

1981-01-01T23:59:59.000Z

416

Sulfur isotopes related to sedimentation conditions for metalliferous black shales of Pennsylvanian Age  

SciTech Connect

Sulfur isotope composition were determined for pyrite and sphalerite grains isolated from 8 metalliferous Missourian, Desmoinesian, and Atokan black shales from Missouri, Illinois, Kansas, and Indiana. The younger Missourian shales from the Forest City and Illinois basins contain consistently light sulfur as expected for euxinic conditions, but sulfides from the older shales show heavier and more erratic sulfur values. These isotope patterns suggest that younger shales accumulated slowly offshore, although older shales may have been deposited more quickly in shallower water. Isotope values, which also correlate with heavy metal patterns (e.g., higher molybdenum values for the eastern most older shales), may therefore reflect gradually deepening conditions for the epicontinental Pennsylvanian seas of the US Mid-Continent.

Coveney, R.M. Jr.; Shaffer, N.R.

1985-02-01T23:59:59.000Z

417

Evaluation of sulfur-reducing microorganisms for organic desulfurization. [Pyrococcus furiosus  

SciTech Connect

Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

Miller, K.W.

1991-01-01T23:59:59.000Z

418

Computational Study of Sulfur–nickel Interactions: A New S–Ni Phase Diagram  

SciTech Connect

Prediction of the interactions between H2S-contaminated hydrogen fuel and Ni surfaces under conditions similar to those for solid oxide fuel cell (SOFC) operation using DFT (density function theory) calculations (with thermodynamic corrections) has resulted in a new S–Ni phase diagram, which suggests the existence of an intermediate state between clean Ni surfaces and nickel sulfides – sulfur atoms adsorbed on Ni surfaces. This prediction is consistent with many experimental observations relevant to sulfur poisoning of Nibased anodes in SOFCs, which cannot be explained using the existing S–Ni bulk phase diagram from classical thermodynamics. The accurate prediction of the adsorption phase is vital to a fundamental understanding of the sulfur poisoning mechanism of Ni-based anodes under SOFC operating conditions.

Wang, Jeng-Han; Liu, Meilin

2007-06-22T23:59:59.000Z

419

U.S. Coal Reserves: An Update by Heat and Sulfur Content  

Gasoline and Diesel Fuel Update (EIA)

2) 2) Distribution Category UC-98 U.S. Coal Reserves: An Update by Heat and Sulfur Content February 1993 Energy Information Administration Office of Coal, Nuclear, Electric and Alternate Fuels U.S. Department of Energy Washington, DC 20585 Energy Information Administration/ U.S. Coal Reserves: An Update by Heat and Sulfur Content ii This report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should not be construed as advocating or reflecting any policy position of the Department of Energy or of any other organization. Energy Information Administration/ U.S. Coal Reserves: An Update by Heat and Sulfur Content iii Contacts This report was prepared by the staff of the Energy

420

Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions  

SciTech Connect

When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992  

SciTech Connect

In developing the new Ohio University procedure the thermodynamic limitations of the reactions for removal of both pyritic and organic sulfur from coal at 400--600{degrees}C were studied using copper as a very strong H{sub 2}S-acceptor. Copper serves as a catalyst for ethanol dehydrogenation to form nascent hydrogen. Copper also serves as a scavenger to form copper sulfide from the hydrogen sulfide evolved during the reaction. Copper sulfide in turn serves as a catalyst for organic sulfur hydrodesulfurization reactions. If the coal to be desulfurized contains pyrite (FeS{sub 2}) or FeS, the copper scavenger effect reduces any back reaction of hydrogen sulfide with the iron and increases the removal of sulfur from the carbonaceous material. The desired effect of using copper can be achieved by using copper or copper containing alloys as materials of construction or as liners for a regenerable reactor. During the time period that Ohio Coal Development Office supported this work, small scale (560 grams) laboratory experiments with coals containing about 3.5% sulfur have achieved up to 90% desulfurization at temperatures of 500{degrees}C when using a copper reactor. Results from the autoclave experiments have identified the nature of the chemical reactions taking place. Because the process removes both pyritic and organic sulfur in coal, the successful scale up of the process would have important economic significance to the coal industry. Even though this and other chemical processes may be relatively expensive and far from being commercial, the reason for further development is that this process may hold the promise of achieving much greater sulfur reduction and of producing a cleaner coal than other methods. This would be especially important for small or older power plants and industrial boilers.

Not Available

1993-04-15T23:59:59.000Z

422

Release Data Package for Hanford Site Assessments  

SciTech Connect

Beginning in fiscal year (FY) 2003, the U.S. Department of Energy (DOE) Richland Operations Office initiated activities, including the development of data packages, to support a Hanford assessment. This report describes the data compiled in FY 2003 through 2005 to support the Release Module of the System Assessment Capability (SAC) for the updated composite analysis. This work was completed as part of the Characterization of Systems Project, part of the Remediation and Closure Science Project, the Hanford Assessments Project, and the Characterization of Systems Project managed by Pacific Northwest National Laboratory. Related characterization activities and data packages for the vadose zone and groundwater are being developed under the remediation Decision Support Task of the Groundwater Remediation Project managed by Fluor Hanford, Inc. The Release Module applies release models to waste inventory data from the Inventory Module and accounts for site remediation activities as a function of time. The resulting releases to the vadose zone, expressed as time profiles of annual rates, become source terms for the Vadose Zone Module. Radioactive decay is accounted for in all inputs and outputs of the Release Module. The Release Module is implemented as the VADER (Vadose zone Environmental Release) computer code. Key components of the Release Module are numerical models (i.e., liquid, soil-debris, cement, saltcake, and reactor block) that simulate contaminant release from the different waste source types found at the Hanford Site. The Release Module also handles remediation transfers to onsite and offsite repositories.

Riley, Robert G.; Lopresti, Charles A.; Engel, David W.

2006-07-01T23:59:59.000Z

423

Sulfur determination in blood from inhabitants of Brazil using neutron activation analysis  

SciTech Connect

In this study the NAA technique was applied to analyze sulfur in blood from inhabitants of Brazil for the proposition of an indicative interval. The measurements were performed considering lifestyle factors (non-smokers, non-drinkers and no history of toxicological exposure) of Brazilian inhabitants. The influence of gender was also investigated considering several age ranges (18-29, 30-39, 40-49, >50 years). These data are useful in clinical investigations, to identify or prevent diseases caused by inadequate sulfur ingestion and for nutritional evaluation of Brazilian population.

Oliveira, Laura C.; Zamboni, Cibele B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN-CNEN/SP) Av. Professor Lineu Prestes 2242 05508-000 Sao Paulo, SP (Brazil)

2013-05-06T23:59:59.000Z

424

Bioprocessing of High-sulfur Crudes Via Appliaction of Critical Fluid Biocatalysis  

SciTech Connect

This experimental research project investigated protein-based biocatalysis in supercritical fluid solvents as an integrated process approach to catalyze the removal of sulfur atoms from crude oils and fuels. The work focused on the oxidation of model sulfur-containing compounds in supercritical reaction media and included three major tasks: microbiological induction experiments, proteincatalyzed biooxidation in supercritical solvents, and a work-in-kind cooperative research and development agreement (CRADA). This work demonstrated that the biooxidation reaction could be improved by an order-of-magnitude by carrying out the reaction in emulsions in supercritical fluids.

Ginosar, Daniel Michael; Bala, Greg Alan; Anderson, Raymond Paul; Fox, Sandra Lynn; Stanescue, Marina A.

2002-05-01T23:59:59.000Z

425

Structural and Functional Studies on Human Mitochondrial Iron-Sulfur Cluster Biosynthesis  

E-Print Network (OSTI)

. (2003) Formation of iron-sulfur clusters in bacteria: an emerging field in bioinorganic chemistry. Curr. Opin. Chem. Biol. 7, 166-173]. 3 as the nitrogen-fixation (NIF) machinery (8). The NIF pathway is often a specialized assembly system... of Fe?S Cluster Biogenesis in Human Mitochondria Name Essential in yeast Yeast homologs Bacterial homologs Proposed function & protein interactions Nfs1 Yes Nfs1 IscS, NifS, SufS Cysteine desulfurase, sulfur donor, Interacts with Isd11, Isu2...

Tsai, Chi-Lin

2012-07-16T23:59:59.000Z

426

NO[sub x] reduction by sulfur tolerant coronal-catalytic apparatus and method  

DOE Patents (OSTI)

This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter. 7 figs.

Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

1992-09-15T23:59:59.000Z

427

NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method  

DOE Patents (OSTI)

This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

1993-01-01T23:59:59.000Z

428

NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method  

DOE Patents (OSTI)

This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

1992-01-01T23:59:59.000Z

429

Sulfur adsorption on nickel(100) and its effect on carbon monoxide, nitric oxide, and deuterium chemisorption  

SciTech Connect

The adsorption of CO, NO, and D/sub 2/ was studied on clean and sulfided Ni(100) near 100K using Auger electron spectroscopy, thermal desorption spectroscopy, X-ray and ultraviolet photoelectron spectroscopies, and work function change measurements. The evidence suggests that sulfur's effects are predominantly steric in nature. Weak, short-range (approx.4 angstrom) electrostatic effects are also present, due to charge transfer of about 0.04 of an electron from nickel to sulfur. The blocking effect of S on the adsorption of each gas at various temperatures is discussed.

Hardegree, E.L.

1985-01-01T23:59:59.000Z

430

Sulfur Behavior in the Sasol?Lurgi Fixed-Bed Dry-Bottom Gasification Process  

Science Journals Connector (OSTI)

This article reports on the findings of a study regarding the sulfur behavior across a Sasol?Lurgi gasifier. ... (2) This ash, referred to as “coarse ash”, is a combination of red and white to gray sintered clinkers with heterogeneous texture varying from fine material to large irregularly shaped aggregates of sizes ranging from 4 to 75 mm. ... South African coals that are used for the Sasol?Lurgi gasification process are normally low-grade medium rank C (bituminous) coal with a total sulfur content of approximately 1?2 wt %, on an as-received basis. ...

M. Pat Skhonde; R. Henry Matjie; J. Reginald Bunt; A. Christien Strydom; Herold Schobert

2008-12-05T23:59:59.000Z

431

Thermodynamic Investigation of Carbon Deposition and Sulfur Evolution in Chemical Looping Combustion with Syngas  

Science Journals Connector (OSTI)

Thermodynamic Investigation of Carbon Deposition and Sulfur Evolution in Chemical Looping Combustion with Syngas ... Chemical looping combustion (CLC) with syngas, a synthesized gas mixture of CO, H2, CO2, H2O(g), N2, and H2S, was investigated using thermodynamic simulation, with focus on carbon deposition and sulfur evolution in CLC. ... Abad, A.; Garcia-Labiano, F.; de Diego, L. F.; Gayan, P.; Adanez, J. Reduction kinetics of Cu-,Ni-, and Fe-based oxygen carriers using syngas (CO+H2) for chemical-looping combustion Energy Fuels 2007 21 4 1854 1858 ...

Baowen Wang; Rong Yan; Dong Ho Lee; David Tee Liang; Ying Zheng; Haibo Zhao; Chuguang Zheng

2008-02-16T23:59:59.000Z

432

NONEQUILIBRIUM SULFUR CAPTURE AND RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR  

SciTech Connect

Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. They are deposited on the liquid slag layer on the combustor wall. Due to the low solubility of sulfur in slag, slag must be rapidly drained from the combustor to limit sulfur gas re-evolution. Analysis indicated that slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to perform a series of tests to determine the factors that control the retention of the sulfur in the slag. 36 days of testing on the combustor were completed prior to the end of this reporting period, 12/31/98. This compares with 16 tests required in the original project plan. Combustor tests in early 1997 with high (37%) ash, Indian coal confirmed that high slag mass flow rates of about 500 lb/hr resulted in retention in the slag of up to 20% of the injected sulfur content mineral matter. To further increase the slag flow rate, rice husks, which contain 20% ash, and rice husk char, which contain 70% ash, were co-fired with coal in the combustor. A series of 13 combustor tests were performed in fourth quarter of 1997 and a further 6 tests were performed in January 1998 and in the summer of 1998. The test objective was to achieve slag flow rates between 500 and 1,000 lb/hr. Due to the very low bulk density of rice husk, compared to pulverized coal, almost the entire test effort focused on developing methods for feeding the rice husks into combustor. In the last test of December 1997, a peak mineral matter, injection rate of 592 lb/hr was briefly achieved by injection of coal, rice husk char, gypsum, and limestone into the combustor. However, no significant sulfur concentration was measured in the slag removed from the combustor. The peak injection rate reached with biomass in the 1997 tests was 310 lb/hr with rice husk, and 584 lb/hr with rice husk char.

Dr. Bert Zauderer

1999-03-15T23:59:59.000Z

433

Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost and equipment  

E-Print Network (OSTI)

Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost gas instead of continuing to burn low-sulfur fuel oil, a report said. Switching to liquefied natural who switch from gasoline-powered vehicles to ones fueled by compressed natural gas could save as much

434

subm. to Surf. Sci. Ab initio molecular dynamics study of H2 adsorption on sulfur-and chlorine-covered  

E-Print Network (OSTI)

subm. to Surf. Sci. Ab initio molecular dynamics study of H2 adsorption on sulfur- and chlorine/Germany The adsorption of molecular hydrogen on sulfur- and chlorine-covered Pd(100) in a (2Ã?2) geometry is studied by ab initio molecular dynamics simulations. The potential energy surfaces of H2/S(2 Ã? 2)/Pd(100) and H2/Cl(2

Ulm, Universität

435

Effects of Switching to Lower Sulfur Marine Fuel Oil on Air Quality in the San Francisco Bay Area  

Science Journals Connector (OSTI)

Effects of Switching to Lower Sulfur Marine Fuel Oil on Air Quality in the San Francisco Bay Area ... Beginning in July 2009, an emission control area was put into effect at ports and along the California coastline, requiring use of lower sulfur fuels in place of heavy fuel oil in main engines of ships. ...

Ling Tao; David Fairley; Michael J. Kleeman; Robert A. Harley

2013-08-14T23:59:59.000Z

436

NREL: News - Release Archives 2007  

NLE Websites -- All DOE Office Websites (Extended Search)

7 7 News releases covering laboratory activities, scientific discoveries, projects and more are archived below, chronologically. For more information about NREL and its research in renewable energy and energy efficiency technologies, e-mail public_affairs@nrel.gov. December 4, 2007 Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) has pledged to reduce its greenhouse gas emissions by 75 percent from 2005 to 2009. The new goal is part of NREL's participation in the Environmental Protection Agency's (EPA) Climate Leaders program. November 8, 2007 Wakonda Technologies is the Clean Energy Entrepreneur of the Year A small company commercializing a novel solar energy technology has been

437

NREL: News - Release Archives 2003  

NLE Websites -- All DOE Office Websites (Extended Search)

2003 2003 News releases covering laboratory activities, scientific discoveries, projects and more are archived below, chronologically. For more information about NREL and its research in renewable energy and energy efficiency technologies, e-mail public_affairs@nrel.gov. December 22, 2003 Renewable Energy a Smart Choice for Farmers and Ranchers December 10, 2003 Georgia Tech's Rohatgi Wins Second Annual Rappaport Award December 9, 2003 Acclaim for Three Leaders at Annual NREL Stakeholders Reception November 14, 2003 World Renewable Energy Congress Provides International Forum November 12, 2003 NREL and Company Researchers Team Up on Thin-Film Solar Cells October 30, 2003 NREL's Art Nozik Elected AAAS Fellow October 21, 2003 Workshop Tackles Biological Hydrogen Production

438

Biomediated continuous release phosphate fertilizer  

DOE Patents (OSTI)

A composition is disclosed for providing phosphate fertilizer to the root zone of plants. The composition comprises a microorganism capable of producing and secreting a solubilization agent, a carbon source for providing raw material for the microorganism to convert into the solubilization agent, and rock phosphate ore for providing a source of insoluble phosphate that is solubilized by the solubilization agent and released as soluble phosphate. The composition is provided in a physical form, such as a granule, that retains the microorganism, carbon source, and rock phosphate ore, but permits water and soluble phosphate to diffuse into the soil. A method of using the composition for providing phosphate fertilizer to plants is also disclosed. 13 figs.

Goldstein, A.H.; Rogers, R.D.

1999-06-15T23:59:59.000Z

439

NREL: News - Release Archives 2006  

NLE Websites -- All DOE Office Websites (Extended Search)

6 6 News releases covering laboratory activities, scientific discoveries, projects and more are archived below, chronologically. For more information about NREL and its research in renewable energy and energy efficiency technologies, e-mail public_affairs@nrel.gov. December 14, 2006 Experimental "Wind to Hydrogen" System Up and Running Xcel Energy and the National Renewable Energy Laboratory unveiled a unique facility that uses electricity from wind turbines to produce and store pure hydrogen. November 28, 2006 University of Denver High School Teacher Recognized for Commitment to Renewable Energy Don Cameron, physics and astronomy teacher at the University of Denver High School (DUHS), earned this year's Renewable Energy Teacher Award from the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory's

440

Nolij Corporation Proprietary & Confidential Information Release Notes for Nolij Web  

E-Print Network (OSTI)

Nolij Corporation Proprietary & Confidential Information Release Notes for Nolij Web Release 6.3.x Web Release 6.3.x Copyright © 2010 - 2011, Nolij Corporation. All rights reserved. Revised 02Release Notes for Nolij Web Release 6.3.x Introduction These release notes provide information about new

Escher, Christine

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS  

SciTech Connect

This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

2009-05-12T23:59:59.000Z

442

ARM - Feature Stories and Releases Article  

NLE Websites -- All DOE Office Websites (Extended Search)

September 25, 2009 Feature Stories and Releases Nature Magazine Features Mobile Facility Deployment In China Bookmark and Share A news feature published in Vol. 461 of Nature...

443

Hometown News Release | netl.doe.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Emergency Communications LabNotes Archive Netlognews Archive News Releases NETL Staff Bios Features NETL Awards Fact Sheets NETL Logo Standards Research News...

444

SEPA Press Releases | Department of Energy  

Energy Savers (EERE)

of Southeastern Power Administration visited a local high school to discuss hydroelectric power and demonstrate power generation. News Press Releases Career Opportunities...

445

ARM - Feature Stories and Releases Article  

NLE Websites -- All DOE Office Websites (Extended Search)

5, 2014 Feature Stories and Releases Biogenic Aerosols Examined in Finland Forest Bookmark and Share The second ARM Mobile Facility (AMF2) is operating in Hyytil, Finland,...

446

NREL: Photovoltaics Research - News Release Archives  

NLE Websites -- All DOE Office Websites (Extended Search)

lower labor costs, drives China's current advantage in manufacturing photovoltaic (PV) solar energy systems, according to a new report released today by the Energy Department's...

447

NEWS MEDIA CONTACT: FOR IMMEDIATE RELEASE  

NLE Websites -- All DOE Office Websites (Extended Search)

investigation that focused on the release of radioactive material from the underground facility into the environment and related exposure to aboveground workers, as well as...

448

DOE National Laboratory Releases Annual Accomplishments Report...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Releases Annual Accomplishments Report NETL's netlognews and Carbon Sequestration Atlas win first-place awards from the National Association of Government Communicators. NETL...

449

NREL: Photovoltaics Research - News Release Archives  

NLE Websites -- All DOE Office Websites (Extended Search)

Shows Power Grid can Accommodate Large Increase in Wind and Solar Generation The National Renewable Energy Laboratory today released an initial study assessing the operational...

450

Sulfur Emissions from Volcanic A c t i v i t y i n 1985 and 1990 Carmen M. Benkovitz and M. A l t a f Mubaraki  

E-Print Network (OSTI)

APPENDIX C Sulfur Emissions from Volcanic A c t i v i t y i n 1985 and 1990 Carmen M. Benkovitz). Global estimates o f anthropogenic emissions o f sulfur f o r 1985 are approximately 65 Tg S y-l (Benkovi Anthropogenic Sulfur Emissions f o r 1985 and 1990 i n t h i s report). Sulfur from biogenic sources i s emitted

451

Effect of Water Transport on the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer  

E-Print Network (OSTI)

be developed that provides efficient production of clean hydrogen. The methods existing today for large-scale produc- tion of hydrogen typically involve hydrocarbon reforming of natural gas or coal gasification% , the overall efficiency is 40%.7 Two issues remain, however, that make the future of this technology un

Weidner, John W.

452

THE CULTURE, GENERAL PHYSIOLOGY, MORPHOLOGY, AND CLASSIFICATION OF THE NON-SULFUR PURPLE AND BROWN BACTERIA  

Science Journals Connector (OSTI)

...tion of oxygen by the green forms the conditions...as a source of radiant energy. Since Engelmann's...in contrast to the green plants, are capable...the supply of radiant energy would be a prerequisite...chemically closely related to green plant chlorophyll, has...

C. B. van Niel

1944-03-01T23:59:59.000Z

453

NETL: News Release - DOE Releases Feasibility Study for Conceptual  

NLE Websites -- All DOE Office Websites (Extended Search)

21 , 2007 21 , 2007 DOE Releases Feasibility Study for Conceptual Coal-to-Liquids Facility in Midwest Report Outlines the Path Toward Future Domestic Energy Facilities WASHINGTON, DC - The Office of Fossil Energy's National Energy Technology Laboratory has issued a report that examines the feasibility of a commercial 50,000 barrel per day coal-to-liquids (CTL) facility in the Illinois coal basin. The conceptual design study provides a performance baseline that can be used to show how CTL could capitalize on domestic energy resources while providing a much-needed bulwark against rising petroleum and natural gas prices. The price of coal-derived liquid fuels has traditionally been unable to compete with the price of fuels derived from crude oil. As oil prices continue to rise, however, domestic sources of transportation fuels are becoming more affordable. The economic and national security concerns related to non-domestic liquid fuels have more eyes turning to alternative sources of liquid fuels, and, with coal being America's most abundant energy resource, CTL facilities may provide a winning option.

454

Sulfur in the Timbers of Henry VIII's Warship Mary Rose: Synchrotrons  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur in the Timbers of Henry Sulfur in the Timbers of Henry VIII's Warship Mary Rose: Synchrotrons Illuminate Conservation Concerns Magnus Sandström,1 Farideh Jalilehvand,2 Emiliana Damian,1 Yvonne Fors,1 Ulrik Gelius,3 Mark Jones,4 and Murielle Salomé5 1Structural Chemistry, Stockholm University, Sweden 2Department of Chemistry, University of Calgary, Alberta, Canada 3Department of Physics, Uppsala University, Sweden 4The Mary Rose Trust, HM Naval Base, Portsmouth, UK 5European Synchrotron Radiation Facility (ESRF), Grenoble, France Figure 1.The starboard side of the Mary Rose (about ½ of the hull, ~280 tons oak timbers) is since 1994 being sprayed with an aqueous solution of PEG 200. Figure 2. Sulfur K-edge XANES spectrum of Mary Rose oak core surface (0-3 mm). Standard spectra used for model fitting: 1 (solution), 1' (solid) disulfides R-SS-R (cystine with peaks at 2472.7 and 2474.4 eV); 45%; 2: Thiols R-SH (cysteine, 2473.6 eV) 23%; 3: Elemental sulfur (S8 in xylene 2473.0 eV) 10%; 4: Sulfoxide R(SO)R' (methionine sulfoxide, 2476.4 eV) 5%; 5: Sulfonate R-SO3- (methyl sulfonate, 2481.2 eV) 10%; 6: Sulfate SO42- (sodium sulfate, 2482.6 eV) 7%.

455

Sonic enhanced ash agglomeration and sulfur capture. Technical progress report, January 1995--March 1995  

SciTech Connect

This program is focused on the process for bimodal ash agglomeration and simultaneous sulfur capture for the development of coal fired combustion gas turbines. The process also accommodates injection of alkali gettering materials. During this period, further dismantling of the existing bimodal test unit was performed. The design of a revised process development unit and hot gas cleanup unit have been completed.

NONE

1995-07-01T23:59:59.000Z

456

Sorbent utilization prediction methodology: sulfur control in fluidized-bed combustors  

SciTech Connect

The United States Government has embarked on an ambitious program to develop and commercialize technologies to efficiently extract energy from coal in an environmentally acceptable manner. One of the more promising new technologies for steam and power generation is the fluidized-bed combustion of coal. In this process, coal is burned in a fluidized bed composed mainly of calcined limestone sorbent. The calcium oxide reacts chemically to capture the sulfur dioxide formed during the combustion and to maintain the stack gas sulfur emissions at acceptable levels. The spent sulfur sorbent, containing calcium sulfate, is a dry solid that can be disposed of along with coal ash or potentially used. Other major advantages of fluidized-bed combustion are the reduction in nitrogen oxide emissions because of the relatively low combustion temperatures, the capability of burning wide varieties of fuel, the high carbon combustion efficiencies, and the high heat-transfer coefficients. A key to the widespread commercialization of fluidized-bed technology is the ability to accurately predict the amount of sulfur that will be captured by a given sorbent. This handbook meets this need by providing a simple, yet reliable, user-oriented methodology (the ANL method) that allows performance of a sorbent to be predicted. The methodology is based on only three essential sorbent parameters, each of which can be readily obtained from standardized laboratory tests. These standard tests and the subsequent method of data reduction are described in detail.

Fee, D.C.; Wilson, W.I.; Shearer, J.A.; Smith, G.W.; Lenc, J.F.; Fan, L.S.; Myles, K.M.; Johnson, I.

1980-09-01T23:59:59.000Z

457

Mercury and Sulfur Dynamics in the SPRUCE Experiment Brandy Toner1  

E-Print Network (OSTI)

Mercury and Sulfur Dynamics in the SPRUCE Experiment Brandy Toner1 , Randy Kolka2 , Steve Sebestyen will lead studies assessing the influence of SPRUCE treatments on the cycling of THg, MeHg and S. Mercury. Mercury levels are determined by complex interactions between deposition, chemical transformation

458

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

80.8 75.7 76.2 67.5 71.8 77.4 83.7 75.0 64.4 See footnotes at end of table. 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District 242 Energy Information...

459

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Annual Energy Outlook 2012 (EIA)

74.4 73.3 70.4 60.5 69.0 71.9 77.8 71.0 60.5 See footnotes at end of table. 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District 242 Energy Information...

460

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

Science Journals Connector (OSTI)

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification ... National Bioenergy Center, National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, Colorado 80401, United States ... Similar activation energies (9-10 kcal/mol) were measured for ZnO and Zn-Ti-O sulfidation. ...

Abhijit Dutta; Singfoong Cheah; Richard Bain; Calvin Feik; Kim Magrini-Bair; Steven Phillips

2012-05-23T23:59:59.000Z

Note: This page contains sample records for the topic "tion releases sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same  

DOE Patents (OSTI)

The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.

Way, J. Douglas; Hatlevik, Oyvind

2014-07-15T23:59:59.000Z

462

Apparatus for Determining Sulfur in Organic Compounds by Means of Gas Chromatography  

Science Journals Connector (OSTI)

......fuel, crude oil, and various grades of coal. However, our experience with the method...in the Schiiniger flask. The complete combustion of sulfur in pure oxygen is readily effected...moles origin- ally present. Classical chemistry allows one to cal- culate the percentage......

Philipp W. H. Schuessler

1969-12-01T23:59:59.000Z

463

Reserves and potential supply of low-sulfur Appalachian coal. Final report  

SciTech Connect

This project has two objectives. The first is to develop and test a methodology for determining economically mineable reserves of low-sulfur Appalachian coal. The second is to appraise the potential supply response to a very large increase in demand for low-sulfur Appalachian coal. The reserve determination procedure developed in the project applies criteria similar to those employed by mining engineers in assessing the commercial feasibility of mining properties. The procedure is relatively easy to apply, could be used to develop reserve estimates for a large sample of mining blocks for under $500,000, and produces reserve estimates very different from those produced from the criteria that have been used by the United States Bureau of Mines: with the more rigorous method developed in this project surface mineable reserves are much larger and deep mineable reserves are less than with the Bureau of Mines method. The appraisal of potential low-sulfur coal supply response assessed excess capacity, coal mining company outlook on reserves, and coal quality requirements. The appraisal concluded that ample coal meeting most buyers' requirements will probably be available in the near or long term at a price under $45 in 1984 dollars. However, coal quality requirements may prove a constraint for some buyers, and an upward surge in prices would probably occur in the event of legislation imposing requirements leading to greatly increased low-sulfur coal demand. 14 refs., 24 figs., 15 tabs.

Hughes, W.R.

1986-09-01T23:59:59.000Z

464

Two-dimensional kinetics of binary nucleation in sulfuric acidwater mixtures  

E-Print Network (OSTI)

. INTRODUCTION Binary homogeneous nucleation is a mechanism for gas- to-particle conversion that can result in significant rates of new particle formation even if both components are under- saturated in the gas phase. An important example is the at- mospheric production of sulfuric acid in the presence of am- bient water vapor

465

Sulfur-Selective Detection with the FPD: Current Enigmas, Practical Usage, and Future Directions  

Science Journals Connector (OSTI)

......flame species may be a factor. However, such absorption losses are probably not significant except when the sulfur levels ex ceed several tens of nanograms, since the known flame species have relatively low gas-phase molar absorptivities at the typical......

S.O. Farwell; C.J. Barinaga

1986-11-01T23:59:59.000Z

466

Ensemble Forecasting of Volcanic Sulfur Emissions in Hawai'i Andre Pattantyus and Steven Businger  

E-Print Network (OSTI)

of Hawai'i. The probabilistic forecast products show uncertainty in pollutant concentrations of pollution known as "vog" after volcanic smog. Prevailing northeast trade winds in Hawaii advectEnsemble Forecasting of Volcanic Sulfur Emissions in Hawai'i Andre Pattantyus and Steven Businger

Businger, Steven

467

Sandwich-Type Functionalized Graphene Sheet-Sulfur Nanocomposite for Rechargeable Lithium Batteries  

SciTech Connect

A sandwich structured graphene sheet-sulfur (GSS) nanocomposite was synthesized as the cathode material for lithium-sulfur batteries. The structure has a layer of graphene stacks and a layer of sulfur nanoparticles integrated into a three-dimensional architecture. This GSS nanoscale layered composite, making use of the efficient physical and electrical contact between sulfur and the large surface area, highly conductive graphene, provides a high loading of active materials of ~70 wt%, a high tape density of ~0.92 g?cm-3, and a high power with a reversible capacity of ~505 mAh?g-1 (~464 mAh?cm-3) at a current density of 1,680 mA?g-1 (1C). When coated with a thin layer of cation exchange Nafion film, the migration of dissolved polysulfide anions from the GSS nanocomposite was effectively alleviated, leading to a good cycling stability of 75% capacity retention over 100 cycles. This sandwich-structured composite conceptually provides a new strategy for designing electrodes in energy storage applications.

Cao, Yuliang; Li, Xiaolin; Aksay, Ilhan A.; Lemmon, John P.; Nie, Zimin; Yang, Zhenguo; Liu, Jun

2011-03-30T23:59:59.000Z

468

Sulfur in peridotites and gabbros at Lost City (30N, MAR): Implications for hydrothermal alteration  

E-Print Network (OSTI)

minerals in samples from near the base of hydrothermal carbonate towers at Lost City show d34 S valuesSulfur in peridotites and gabbros at Lost City (30°N, MAR): Implications for hydrothermal of serpentinized peridotites and gabbros beneath the Lost City Hydrothermal Field at the southern face

Gilli, Adrian

469

The effects of gas-to-oil rate in ultra low sulfur diesel hydrotreating  

Science Journals Connector (OSTI)

Hydrotreating has become a critical refining process as fuel sulfur specifications are tightened around the world. Recently, refiners in the United States have been learning how to optimize the performance of ultra low sulfur diesel (ulsd) hydrotreaters. The gas-to-oil feed rate ratio is known to be an important variable in this respect. It is well known that the gas-to-oil rate must be kept high enough to maintain the desired hydrogen partial pressure through the hydrotreating reactor, and to minimize the inhibiting effect of hydrogen sulfide. A lesser-known effect is the effect of gas-to-oil rate on the vapor–liquid equilibrium in the reactor. Changing the gas-to-oil rate alters the distribution of reactants between vapor and liquid in a way that changes the relative reaction rates of different sulfur compounds. This paper presents some pilot plant data and analysis showing this effect of phase equilibrium in deep diesel desulfurization. The effect can be modeled using the Frye–Mosby equation, which accounts for the effects of feed vaporization and phase equilibrium on the reaction rates of individual sulfur compounds in a trickle bed hydrotreater.

George Hoekstra

2007-01-01T23:59:59.000Z

470

Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor  

E-Print Network (OSTI)

monitoring, solid-oxide fuel cells, and coal gasification, require operation at much higher temperatures thanSulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor Yung Ho to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20­600 times greater

Tobin, Roger G.

471

Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants  

E-Print Network (OSTI)

,2 operated by fuel cells. Unfortunately, the lack of infrastructure, such as a network of hydrogen refueling of hydrogen sulfide (H2S), which poisons the anode in the fuel cell stack, leading to low SOFC efficiencyPerformance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel

Azad, Abdul-Majeed

472

Transport Properties and Performance of Polymer Electrolyte Membranes for the Hybrid Sulfur Electrolyzer  

E-Print Network (OSTI)

not consume fossil fuels or pro- duce CO2 while producing highly pure hydrogen.1-10 Gaseous SO2 fedTransport Properties and Performance of Polymer Electrolyte Membranes for the Hybrid Sulfur and Biological Systems Department, Albuquerque, New Mexico 87123, USA c Department of Materials Science

Weidner, John W.

473

Coral-Associated Bacteria and Their Role in the Biogeochemical Cycling of Sulfur  

Science Journals Connector (OSTI)

...the climate-changing gas, dimethyl sulphide...bacterial communities from natural and aquarium environments...dimethylsulfide and the natural sulfur cycle. Nature...New perspective on the natural microbial word: molecular microbial ecology. ASM News 62: 463-470. 45 Reshelf...

Jean-Baptiste Raina; Dianne Tapiolas; Bette L. Willis; David G. Bourne

2009-04-03T23:59:59.000Z

474

Use of Personal-Indoor-Outdoor Sulfur Concentrations to Estimate the Infiltration Factor and Outdoor Exposure Factor for Individual Homes and Persons  

Science Journals Connector (OSTI)

Use of Personal-Indoor-Outdoor Sulfur Concentrations to Estimate the Infiltration Factor and Outdoor Exposure Factor for Individual Homes and Persons ... Indoor?outdoor comparisons of sulfur concentrations thus provide a direct way to estimate Finf for each individual home. ... Of 36 homes, 22 had intercepts not significantly different from zero, indicating no apparent source of sulfur in the home. ...

Lance Wallace; Ron Williams

2005-01-26T23:59:59.000Z

475

Morphology of Gas Release in Physical Simulants  

SciTech Connect

This report documents testing activities conducted as part of the Deep Sludge Gas Release Event Project (DSGREP). The testing described in this report focused on evaluating the potential retention and release mechanisms of hydrogen bubbles in underground radioactive waste storage tanks at Hanford. The goal of the testing was to evaluate the rate, extent, and morphology of gas release events in simulant materials. Previous, undocumented scoping tests have evidenced dramatically different gas release behavior from simulants with similar physical properties. Specifically, previous gas release tests have evaluated the extent of release of 30 Pa kaolin and 30 Pa bentonite clay slurries. While both materials are clays and both have equivalent material shear strength using a shear vane, it was found that upon stirring, gas was released immediately and completely from bentonite clay slurry while little if any gas was released from the kaolin slurry. The motivation for the current work is to replicate these tests in a controlled quality test environment and to evaluate the release behavior for another simulant used in DSGREP testing. Three simulant materials were evaluated: 1) a 30 Pa kaolin clay slurry, 2) a 30 Pa bentonite clay slurry, and 3) Rayleigh-Taylor (RT) Simulant (a simulant designed to support DSGREP RT instability testing. Entrained gas was generated in these simulant materials using two methods: 1) application of vacuum over about a 1-minute period to nucleate dissolved gas within the simulant and 2) addition of hydrogen peroxide to generate gas by peroxide decomposition in the simulants over about a 16-hour period. Bubble release was effected by vibrating the test material using an external vibrating table. When testing with hydrogen peroxide, gas release was also accomplished by stirring of the simulant.

Daniel, Richard C.; Burns, Carolyn A.; Crawford, Amanda D.; Hylden, Laura R.; Bryan, Samuel A.; MacFarlan, Paul J.; Gauglitz, Phillip A.

2014-07-03T23:59:59.000Z

476

Comparison of modified sulfur cement and hydraulic cement for encapsulation of radioactive and mixed wastes  

SciTech Connect

The majority of solidification/stabilization systems for low-level radioactive waste (LLW) and mixed waste, both in the commercial sector and at Department of Energy (DOE) facilities, utilize hydraulic cement (such as portland cement) to encapsulate waste materials and yield a monolithic solid waste form for disposal. A new and innovative process utilizing modified sulfur cement developed by the US Bureau of Mines has been applied at Brookhaven National Laboratory (BNL) for the encapsulation of many of these problem'' wastes. Modified sulfur cement is a thermoplastic material, and as such, it can be heated above it's melting point (120{degree}C), combined with dry waste products to form a homogeneous mixture, and cooled to form a monolithic solid product. Under sponsorship of the DOE, research and development efforts at BNL have successfully applied the modified sulfur cement process for treatment of a range of LLWs including sodium sulfate salts, boric acid salts, and incinerator bottom ash and for mixed waste contaminated incinerator fly ash. Process development studies were conducted to determine optimal waste loadings for each waste type. Property evaluation studies were conducted to test waste form behavior under disposal conditions by applying relevant performance testing criteria established by the Nuclear Regulatory Commission (for LLW) and the Environmental Protection Agency (for hazardous wastes). Based on both processing and performance considerations, significantly greater waste loadings were achieved using modified sulfur cement when compared with hydraulic cement. Technology demonstration of the modified sulfur cement encapsulation system using production-scale equipment is scheduled for FY 1991. 12 refs., 8 figs., 3 tabs.

Kalb, P.D.; Heiser, J.H. III; Colombo, P.

1990-01-01T23:59:59.000Z

477

Development of a new FGD process that converts sulfur dioxide to salable ammonium phosphate fertilizer  

SciTech Connect

Rich mineral resources have enabled Chinese coal output and energy consumption to rank second and third in the world, respectively. In 1992, up to 70 percent of the country`s electric power was generated by the combustion of some 300 million tons of coal. Although the average sulfur content level in Chinese coals is only about 0.8 percent, the share of high- sulfur coals with 2 percent or more sulfur content is as high as 18 percent. As a result, air pollution accompanied by acid rain now occurs over most of the country, especially in southwestern China. Currently, the area comprising Guangdong, Guangxi, the Sichuan Basin, and the greater part of Gueizhou, where the sulfur content in coal is between 2 and 7 percent and the average pH values of rain water are between 4 and 5 per annum, has become one of the three biggest acid rain-affected areas in the world. In 1992, the national installed coal-fired electricity generation capacity exceeded 100,000 MWe. By the year 2000, it is expected to reach as much as 200,000 MWe, according to a new scheduled program. Environmental pollution caused by large-scale coal combustion is a very important issue that needs to be considered in the implementation of the program. To ensure that the effects of coal-fired power generation on the environment can be properly controlled in the near future, TPRI (Thermal Power Research Institute), the sole thermal power engineering research institution within the Ministry of Electric Power Industry (MOEPI), has conducted a long-term research program to develop sulfur emission control technologies suitable to the special conditions prevalent in China since the early 1970s. The details are summarized. The objective of this chapter is to describe the fundamental concept and major pilot test results and present an economic evaluation of a new process combining flue gas desulfurization (FGD) and ammonium phosphate fertilizer production.

Ji-lu Chen

1993-12-31T23:59:59.000Z

478

Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases  

SciTech Connect

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

2001-11-06T23:59:59.000Z

479

Method for releasing hydrogen from ammonia borane  

DOE Patents (OSTI)

A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

2013-02-19T23:59:59.000Z

480

Department of Energy Releases WIPP Recovery Plan  

Energy.gov (U.S. Department of Energy (DOE))

Washington, D.C. – Today, the Department of Energy (DOE) released the Waste Isolation Pilot Plant (WIPP) Recovery Plan, outlining the necessary steps to resume operations at the transuranic waste disposal site outside of Carlsbad, N.M. WIPP operations were suspended following an underground truck fire and a radiological release earlier this year.