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1

U.S. DEPARTMENT OF ENERGY EERE PROJECT MA.i\IAGE\tiE~TCE~TER  

Broader source: Energy.gov (indexed) [DOE]

MA.i\IAGE\tiE~TCE~TER MA.i\IAGE\tiE~TCE~TER NEPA DETERMINATION Page 1 of2 RECIPIENT:Brayton Energy STATE: MA PROJECT TITLE: High-Efficiency Low-Cost Solar Receiver for use in a Supercritical C02 Recompression Cycle Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CID Number DE-FOA-0000595 DE-EE0005799 GF0-0005799-{)01 G05799 Based on my review of the information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the foUowing determination: CX, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering, analysis, and dissemination Information gathering (including, 'but not limited to, literature surveys, inventories, site vrsits, and audits}, data analysis (including, but not limited to, computer modeling}, document preparation

2

MA.+'  

Office of Legacy Management (LM)

MA.+' MA.+' t -@ . ;' OAK RIDGE NATIONAL LABORATORY i OPtRATED BY MARTIN MARIETTA ENERGY SYSTEMS, INC. FOR THE UNITE0 STATES DEPARTMENT OF ENERGY ,,y , - IhI of ORNL/TM-10053 RESULTS OF THE RADIOLOGICAL SURVEY AT THE VENTRON SITE, BEVERLY, MASSACHUSETTS W. D. Cottrell R. F. Carrier -.- _ ..-. - . . . -~~.- ~~- Printed in the United States of America. Available from National Technical Information Service U.S. Department of Commerce 5285 Port Royal Road, Springfield, Virginia 22161 NTIS price codes-Printed Copy: ~06 Microfiche A01 This report was prepared as an account of work sponsored by an agency of the United StatesGovernment. Neither the U nited StatesGovernment nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or

3

MA 16020 -- CALCULATOR POLICY  

E-Print Network [OSTI]

MA 16020 -- CALCULATOR POLICY. A ONE-LINE scientific calculator is REQUIRED. No other calculator is allowed. RECOMMENDED: TI-30Xa calculator

OwenDavis

2014-08-20T23:59:59.000Z

4

Ma Bell Losing Grip on Old Markets  

Science Journals Connector (OSTI)

...be feasible, even in cold-er parts of the country...so tight against the weather as not to require a furnace...two portable electric heaters could be enough to keep...comfortable on even the coldest days. A number of such...telephone line was put into operation between New York and...

WILLIAM J. BROAD

1980-08-15T23:59:59.000Z

5

ON SOLAR NEUTRINO PROBLEM TIAN MA AND SHOUHONG WANG  

E-Print Network [OSTI]

ON SOLAR NEUTRINO PROBLEM TIAN MA AND SHOUHONG WANG Abstract. The current neutrino oscillation an alternative resolution to the solar neutrino loss problem. Contents 1. Introduction 1 2. Discrepancy of Solar, there are three flavors of neutrinos: the electron neutrino e, the tau neutrino and the mu neutrino µ. The solar

6

Characterization of TiN, TiC and TiCN coatings on Ti50.6 at.% Ni alloy deposited by PIII and deposition technique  

E-Print Network [OSTI]

high content of nickel [1]. In addition, its wear resistance is expected to be improved by transition-metal as nitride, carbide and carbonitride, respectively. Based on the electrochemical measurement and ion carbides and nitrides coatings at a rather broad composition range, such as TiN, TiC and TiC1-xNx (0bÃ?b1

Zheng, Yufeng

7

MA FAshiON bUsiNEss MA FAshiON MArKETiNg ANd cOMMUNicATiON  

E-Print Network [OSTI]

and South Korea. jhy1492@naver.com Image: Tesco, Retail Fashion Brand. By: Hyeyoun Jun #12;yU li (AMy) MA, and the influence it has on fashion brands and the future of this technology. psk_sawa@hotmail.com Image: 3-D Transform Themselves in the Thai Fashion Market, by creating their Own Brand. My project researches new

Evans, Paul

8

MA 22100  

E-Print Network [OSTI]

MA 22100 002 - UNIV 017 MWF 08:30am - Smith, Gabriel (MATH 741); MA 22100 003 - UNIV 017 MWF 09:30am - Naughton, Dominic (MATH 848); MA 22100 ...

9

Ti-based composite coatings with gradient TiC x reinforcements on TC4 titanium alloy prepared by laser cladding  

Science Journals Connector (OSTI)

TiC x -NiTi2/Ti cermet composite coatings C1 and C2 with gradient TiC x ...reinforcements were prepared on TC4 titanium alloy by laser cladding ...

ShuNv Liu; ZongDe Liu; Yang Wang; Peng Yue

2014-07-01T23:59:59.000Z

10

Deposition and characterization of YBa2Cu3O7 /LaMnO3 / MgO/TiN heterostructures on Cu metal substrates for  

E-Print Network [OSTI]

-on-cube epitaxy is observed. While the Cu/TiN and TiN/MgO interfaces are rough, the MgO and LaMnO3 layers . Reduced Jc of approximately 1 MA/cm2 on rolled Cu tapes is limited by damage to the tape surface during- ity of the coatings, reliability of these conductors against thermal transients, and limitation

Pennycook, Steve

11

Ookie Ma | Department of Energy  

Energy Savers [EERE]

Ookie Ma About Us Ookie Ma - Policy and Analysis, Portfolio Manager, Office of Energy Efficiency and Renewable Energy Most Recent Fun Fact Friday: Geeking Out on Energy Data...

12

MA 16100  

E-Print Network [OSTI]

MA 16100, Fall 2014. Plane Analytic Geometry And Calculus I. Course Info. Syllabus · Emergency Preparedness Syllabus Attachment · Course Calendar ...

13

Condensing Effect of Palmitic Acid on DPPC in Mixed Langmuir Gang Ma and Heather C. Allen*  

E-Print Network [OSTI]

Condensing Effect of Palmitic Acid on DPPC in Mixed Langmuir Monolayers Gang Ma and Heather C in the liquid-expanded and condensed phases is explored. A condensing effect of PA on DPPC is observed with VSFG ordering of DPPC chains and causes DPPC to transition from the expanded phase into the condensed phase

14

MA 26100  

E-Print Network [OSTI]

Differential calculus of several variables; multiple integrals. Introduction to vector calculus. Not open to students with credit in MA 174 or 271. Typically offered ...

15

MA 221  

E-Print Network [OSTI]

MA 22100-22200 is a two-semester sequence in the technique of calculus for students enrolled in certain technical curricula. Not available for credit toward ...

16

MA 222  

E-Print Network [OSTI]

MA 222, Spring 2008. Calculus For Technology II ... Contact the Webmaster for technical and content concerns about this webpage. Copyright© 2010, Purdue ...

17

MA 30300  

E-Print Network [OSTI]

Course Description. Credit Hours: 3.00. This is a methods course for juniors in any branch of engineering and science, designed to follow MA 262.

18

Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Abstract: Understanding hydrogen formation on TiO2...

19

MA Doping Analysis on Breeding Capability and Protected Plutonium Production of Large FBR  

SciTech Connect (OSTI)

Spent fuel from LWR can be seen as long-live waste if it is not recycled or as a 'new fuel' resource if it is recycled into the reactors. Uranium and plutonium have been used for 'new fuel' resources from LWR spent fuel as MOX fuel type which is loaded into thermal reactor or fast reactor types. Other actinides from the spent fuel such as neptunium, americium and curium as minor actinide (MA) are considered to be loaded into the reactors for specific purposes, recently. Those purposes such as for increasing protected plutonium production and breeding capability for protected plutonium as well as in the same time those amount of MA can be reduced to a small quantity as a burner or transmutation purpose. Some investigations and scientific approaches are performed in order to increase a material ''barrier'' in plutonium isotope composition by increasing the even mass number of plutonium isotope such as Pu-238, Pu-240 and Pu-242 as plutonium protected composition. Higher material barrier which related to intrinsic properties of plutonium isotopes with even mass number (Pu-238, Pu-240 and Pu-242), are recognized because of their intense decay heat (DH) and high spontaneous fission neutron (SFN) rates. Those even number mass of plutonium isotope contribute to some criteria of plutonium characterization which will be adopted for present study such as IAEA, Pellaud and Kessler criteria (IAEA, 1972; Pellaud, 2002; and Kessler, 2007). The present paper intends to evaluate the breeding capability as a fuel sustainability index of the reactors and to analyze the composition of protected plutonium production of large power reactor based on the FaCT FBR as reference (Ohki, et al., 2008). Three dimensional FBR core configuration has been adopted which is based on the core optimization calculation of SRAC-CITATION code as reactor core analysis and JENDL-3.3 is adopted for nuclear data library. Some MA doping materials are loaded into the blanket regions which can be considered as breeding region for protected plutonium production. Breeding capability of the reactor can be increased effectively by increasing MA doping rate while criticality condition of the reactor is reduced by doping MA. Adopting MA cycle is also effective to increase the isotopic Pu-238 production in plutonium vector composition for denaturing purpose of plutonium.

Permana, Sidik; Suzuki, Mitsutoshi; Kuno, Yusuke [Japan Atomic Energy Agency, Nuclear Non-proliferation Science and Technology Center, 2-4 Shirane Shirakata, Tokai-mura, Ibaraki, 319-1195 (Japan)

2010-06-22T23:59:59.000Z

20

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

MA 152 Exam 1 Memo  

E-Print Network [OSTI]

that evening on the MA 15910 web page (www.math.purdue.edu/MA15910). 3) The exam is self-explanatory. No questions will be allowed unless a student ...

math

2015-01-21T23:59:59.000Z

22

Electrochemistry properties of multilayer TiN/Ti coatings on NiTi alloy for cardiac occluder application  

E-Print Network [OSTI]

-elasticity, thermal shape memory, high corrosion and fatigue resistance, make NiTi alloy especially suitableTi alloy is a subject of numerous recent studies to improve the material's corrosion resistance as well,b , D.Y. Zhang e a Center for Biomedical Materials and Tissue Engineering, Academy for Advanced

Zheng, Yufeng

23

MA.2  

Office of Legacy Management (LM)

IS .:,I. ;' IS .:,I. ;' MA.2 0 y-AU Mr. M ichael Matt W a tertown Redevelopment Authority 319 Arlington Street W a tertown, Massachusetts 02172 Dear Mr. Matt: The Department of Energy is evaluating the radiological condition of sites that were utilized under the Manhattan Engineer District and/or the Atomic Energy C o m m ission in the early years of nuclear energy development to determine whether they need remedial action and whether the Department has authority to perform such action. As you know from information previously sent to you, portions of the W a tertown Arsenal in W a tertown, Massachusetts, were identified as possible sites. The areas investigated included those areas which were the sites of Buildings 34, 41, and 421 and the GSA site. The enclosed documents, which represent the Department's review of the

24

Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on...

25

Acetone Chemistry on Oxidized and Reduced TiO2(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acetone Chemistry on Oxidized and Reduced TiO2(110). Acetone Chemistry on Oxidized and Reduced TiO2(110). Abstract: The chemistry of acetone on the oxidized and reduced surfaces of...

26

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

27

Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles  

Science Journals Connector (OSTI)

Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles ... Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles” ... Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles” ...

Toshiyuki Abe; Eiji Suzuki; Kentaro Nagoshi; Kohichi Miyashita; Masao Kaneko:

2000-03-24T23:59:59.000Z

28

Formaldehyde Polymerization on (WO3)3/TiO2(110) Model Catalyst...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formaldehyde Polymerization on (WO3)3TiO2(110) Model Catalyst. Formaldehyde Polymerization on (WO3)3TiO2(110) Model Catalyst. Abstract: Polymerization of formaldehyde, H2CO, was...

29

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Abstract: The chemistry and photochemistry...

30

Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Chemistry of 2-Propanol on TiO2(110): Low and High...

31

cONNEcTiONS SPriNG 2015  

E-Print Network [OSTI]

curricular cONNEcTiONS GuiDE SPriNG 2015 Aquila Theatre Wuthering Heights Photo Credit: Richard Termine (top) Susan Brandeis Design Class at the Gregg Museum Photo Credit: Matthew Gay (bottom) #12G) is a great way to integrate the arts into academic work, to foster a well-rounded education where art

Velev, Orlin D.

32

Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1....  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CO2 on Rutile TiO2(110)-1×1. Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1. Abstract: Adsorption, binding, and diffusion of CO2 molecules on rutile TiO2(110)...

33

Characterization and catalytic performance of vanadium supported on sulfated Ti-PILC catalysts issued from different Ti-precursors in selective catalytic reduction of nitrogen oxide by ammonia  

Science Journals Connector (OSTI)

Vanadium supported on sulfated Ti-pillared clay catalysts (STi-PILCs) issued from different Ti-precursors were investigated for selective catalytic reduction (SCR) of NO by NH3 in the presence of O2. The STi-PILC...

J. Arfaoui; L. Khalfallah Boudali; A. Ghorbel; G. Delahay

2009-12-01T23:59:59.000Z

34

Laser Cladding of TiAl Intermetallic Alloy on Ti6Al4V -Process Optimization and Properties  

Science Journals Connector (OSTI)

Abstract In order to improve Ti6Al4V high-temperature resistance and its tribological properties, the deposition of TiAl intermetallic (Ti-48Al-2Cr-2Nb) coating on a Ti6Al4V substrate by coaxial laser cladding has been investigated. Laser cladding by powder injection is an emerging laser material processing technique that allows the deposition of thick protective coatings on substrates,using a high power laser beam as heat source. Laser cladding is a multiple-parameter-dependent process. The main process parameters involved (laser power, powder feeding rate, scanning speed and preheating temperature) has been optimized. The microstructure and geometrical quantities (clad area and dilution) of the coating was characterized by optical microscopy and scanning electron microscopy (SEM). In addition the cooling rate of the clad during the process was measured by a dual-color pyrometer. This result has been related to defectology and mechanical coating properties.

B. Cárcel; A. Serrano; J. Zambrano; V. Amigó; A.C. Cárcel

2014-01-01T23:59:59.000Z

35

The Influence of Ni-Coated TiC on Laser-Deposited IN625 Metal Matrix Composites  

E-Print Network [OSTI]

The In?uence of Ni-Coated TiC on Laser-Deposited IN625 Metalwith Ni-coated and uncoated TiC reinforcement particles toand spatial distribution of TiC particles in the deposited

2010-01-01T23:59:59.000Z

36

DOE - Office of Legacy Management -- Shpack Landfill - MA 06  

Office of Legacy Management (LM)

Shpack Landfill - MA 06 Shpack Landfill - MA 06 FUSRAP Considered Sites Shpack Landfill, NY Alternate Name(s): Attleboro, MA Metals and Controls Site Norton Landfill area MA.06-2 MA.06-3 Location: 68 Union Road, Norton, Massachusetts MA.06-2 Historical Operations: No AEC activities were conducted on site. Contamination was suspected from disposal of materials containing uranium and zirconium ash. MA.06-2 MA.06-3 Eligibility Determination: Eligible MA.06-1 Radiological Survey(s): Assessment Surveys MA.06-4 MA.06-5 MA.06-6 Site Status: Cleanup in progress by U.S. Army Corps of Engineers. MA.06-7 MA.06-8 USACE Website Long-term Care Requirements: To be determined upon completion. Also see Documents Related to Shpack Landfill, NY MA.06-1 - DOE Memorandum; Meyers to Hart; Subject: Shpack Landfill,

37

MaRIE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Science MaRIE aboutassetsimagesicon-faces.jpg MaRIE MaRIE is the experimental facility needed to control the time-dependent properties of materials for national...

38

InThrMa | Open Energy Information  

Open Energy Info (EERE)

InThrMa InThrMa Jump to: navigation, search Tool Summary LAUNCH TOOL Name: InThrMa Agency/Company /Organization: InThrMa Sector: Energy Focus Area: - HVAC Resource Type: Software/modeling tools User Interface: Website, Mobile Device Website: www.inthrma.com/ Web Application Link: www.inthrma.com/ Cost: Paid Language: English InThrMa Screenshot References: InThrMa[1] Logo: InThrMa Web based HVAC EMS for Internet connected thermostats, focusing on energy efficiency, including Auto Demand Response capabilities. Harnessing Data & Technology To Derive HVAC Efficiency Overview InThrMa's HVAC Energy Management Suite (EMS) allows users to manage and optimize their HVAC systems from any web browser or mobile phone. The InThrMa EMS provides various tools for programming, monitoring and

39

NREL: Energy Sciences - Jie Ma  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Jie Ma Jie Ma Postdoctoral Researcher Photo of Jie Ma Phone: (303) 384-6511 Email: jie.ma@nrel.gov At NREL Since: 2010 Dr. Ma graduated from the University of Science and Technology of China in 2004 and received a Ph.D. degree from Institute of Physics, Chinese Academy of Sciences in 2009. Jie joined the Computational Materials Science Team at NREL as a postdoctoral researcher in March, 2010. He is currently working on computational design and characterization of nanoscale materials for doping, water splitting, and solar cells, using quantum mechanical electronic structure calculation and molecular dynamics simulation techniques. Research Interests Low-dimensional systems (quantum dots, nanotube and nanowires, and surfaces) Doping in semiconductors. Solar cell and water splitting.

40

Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles”  

Science Journals Connector (OSTI)

Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles” ... We can suggest at least three more likely (than Ti4+) sources for their mysterious electron donor:? (1) an overlooked inorganic species, (2) Ti3+, and/or (3) organic impurities. ...

Craig L. Perkins; Michael A. Henderson; David E. McCready; Greg S. Herman

2000-12-05T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

On elongated stacking fault loops in TiAl  

SciTech Connect (OSTI)

Depending upon strain, load orientation, alloy composition and test temperature, the deformation microstructure of TiAl contains a varied density of stacking faults ribbons. The presence of these ribbons is correlated with that of superdislocations with 1/2{l_angle}112[square bracket] Burgers vector. They are elongated along any of the {l_angle}011[square bracket] directions. The present paper focuses on their formation mechanism, especially on the reasons which make that such dipolar defects, though intrinsically unstable, tend to exhibit a reasonably constant width.

Hug, G.; Veyssiere, P. [CNRS-ONERA, Chatillon (France)

1995-12-31T23:59:59.000Z

42

Effects of TiCl4 Purity on the Sinterability of Armstrong-Processed Ti Powder  

SciTech Connect (OSTI)

A series of high purity and low purity powders were synthesized from TiCl4 by the Armstrong process. While both powders displayed swelling when consolidated and sintered, the lower purity powder exhibited this phenomenon in significantly lower degree. The improvement is attributed to the increase in the onset of sintering temperature, which mitigates the entrapment of volatile impurities that would otherwise lead to pore formation and growth. The net effect is that the use of a lower purity TiCl4 may beneficial in two ways: (1) it is a potentially lower cost precursor to Ti powder production and (2) the trace impurities allow higher density components to be fabricated via a typical low-cost press and sinter approach.

Weil, K. Scott; Hovanski, Yuri; Lavender, Curt A.

2009-04-03T23:59:59.000Z

43

Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CO2 with Oxygen Adatoms on Rutile TiO2(110). Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). Abstract: The interactions of CO2 with oxygen adatoms (Oa’s) on...

44

DOE - Office of Legacy Management -- Watertown Arsenal - MA 02  

Office of Legacy Management (LM)

Watertown Arsenal - MA 02 Watertown Arsenal - MA 02 FUSRAP Considered Sites Site: WATERTOWN ARSENAL (MA.02 ) Eliminated from consideration under FUSRAP - Referred to EPA, State of Massachusetts, and the NRC Designated Name: Not Designated Alternate Name: None Location: Building Site 421 , Watertown , Massachusetts MA.02-1 Evaluation Year: 1985 MA.02-2 MA.02-3 Site Operations: Building 421 was used in the late 1940's and early 1950's by M.I.T. under Contract #AT (30-1)-956 for work on African Ores, and a modified ion-exchange technique was developed. Activities at Buildings 34, 41 and the GSA Site were conducted under AEC licensed. MA.02-4 MA.02-5 MA.02-6 Site Disposition: Eliminated - No Authority MA.02-6 MA.02-7 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MA.02-4

45

DOE - Office of Legacy Management -- Beverly MA Site - MA 04  

Office of Legacy Management (LM)

Beverly MA Site - MA 04 Beverly MA Site - MA 04 FUSRAP Considered Sites Beverly, MA Alternate Name(s): Metal Hydrides, Inc. Ventron Corporation MA.04-1 Location: Congress Street, Beverly, Massachusetts MA.04-4 Historical Operations: Provided uranium metal production under contract with MED. Thorium and radium contamination occurred from non-MED operations. MA.04-6 Eligibility Determination: Eligible MA.04-1 Radiological Survey(s): Assessment Survey, Verification Survey MA.04-4 MA.04-7 Site Status: Certified- Certification Basis, Federal Register Notice included MA.04-5 MA.04-6 MA.04-7 Long-term Care Requirements: Long-Term Surveillance and Maintenance Requirements for Remediated FUSRAP Sites S07566_FUSRAP Also see Beverly, MA, Site Documents Related to Beverly, MA Beverly Site Aerial Photograph

46

Au/PO43-/TiO2 and PO43-/Au/TiO2 catalysts for CO oxidation: effect of synthesis details on catalytic performance  

SciTech Connect (OSTI)

Supported gold catalysts are active for CO oxidation, but the high-temperature deactivation is a shortcoming that may constrain their applications. Herein, we attempted to address this problem by using phosphate-doped Au/TiO{sub 2} synthesized via two routes. In route I, Au/PO{sub 4}{sup 3-}/TiO{sub 2} catalysts were prepared by treating TiO{sub 2} (Degussa P25) with diluted H{sub 3}PO{sub 4}, followed by loading gold via deposition-precipitation. In route II, PO{sub 4}{sup 3-}/Au/TiO{sub 2} catalysts were prepared by treating H{sub 2}-reduced Au/TiO{sub 2} with diluted H{sub 3}PO{sub 4}. These catalysts were systematically pretreated at 200 or 500 C before reaction testing. The overall CO conversion on 200 C-pretreated Au/PO43-/TiO2 or PO43-/Au/TiO2 was always lower than that on 200 C-pretreated Au/TiO2. However, the advantage of the phosphate addition became apparent after thermal treatment at a higher temperature. Both Au/PO43-/TiO2 and PO43-/Au/TiO2 pretreated at 500 C retained significant activities at room temperature, whereas 500 C-pretreated Au/TiO2 lost its activity. Control experiments and catalyst characterization were performed to investigate the impact of synthesis details on catalytic performance.

Ma, Zhen [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2007-01-01T23:59:59.000Z

47

Preparation of K2Ti6O13/TiO2 bio-ceramic on titanium substrate by micro-arc oxidation  

Science Journals Connector (OSTI)

K2Ti6O13/TiO2 bio-ceramic coatings are prepared successfully by micro-arc oxidation on titanium substrate in pure KOH electrolyte...2) and in KOH electrolyte with different concentrations (0.5–1.2 mol/L). The com...

Zhongwei Zhao; Xingyu Chen; Ailiang Chen; Guangsheng Huo…

2009-12-01T23:59:59.000Z

48

Effect of TiO2 Content on Ethanol Electrooxidation in Alkaline Media Using Pt Nanoparticles Supported on Physical Mixtures of Carbon and TiO2 as Electrocatalysts  

Science Journals Connector (OSTI)

Pt nanoparticles supported on physical mixtures of carbon and TiO2 (Pt/(C?+?TiO2) electrocatalyst) were tested for ethanol electrooxidation in alkaline media. The electrocatalysts were...2 mass ratios using boroh...

R. F. B. De Souza; G. S. Buzzo; J. C. M. Silva; E. V. Spinacé…

2014-04-01T23:59:59.000Z

49

On the remarkable optical and structural transformations in Mg-Ti-H thin  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

On the remarkable optical and structural transformations in Mg-Ti-H thin On the remarkable optical and structural transformations in Mg-Ti-H thin films Speaker(s): Dana Borsa Date: October 16, 2006 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Venkat Srinivasan In searching for battery electrode materials, Mg-Ti-H thin films triggered much interest with its hydrogen storage capacity of approx. 4 times larger than that of conventional NiMH batteries [1]. Besides this, the same system has also absolutely remarkable optical properties [2]. Highly reflective in the metallic state, the films become highly absorbing upon hydrogen absorption. Mg0.80Ti0.20Hx thin films combine a high absorption (87% of the solar spectrum) with a low thermal emissivity (only 10%), while after removal of hydrogen Mg0.80Ti0.20 absorbs no more than 1/3 of the solar

50

TiO2 nanoparticles on nitrogen-doped graphene as anode material for lithium ion batteries  

Science Journals Connector (OSTI)

Anatase TiO2...nanoparticles in situ grown on nitrogen-doped, reduced graphene oxide (rGO) have been successfully synthesized ... as an anode material for the lithium ion battery. The nanosized TiO2 particles wer...

Dan Li; Dongqi Shi; Zongwen Liu; Huakun Liu…

2013-04-01T23:59:59.000Z

51

The Allende meteorite: evidence for a new cosmothermometer based on Ti3+/Ti4+  

Science Journals Connector (OSTI)

... 1,765 Perovskite CaTiO3 1,647 1,393 Melilite Ca2Al2SiO7- 1,625 1,450 Ca2MgSi2O7 Spinel MgAl2O4 1,513 1,362 Metallic iron Fe(Fe-Ni) 1,473 Diopside CaMgSi2O6 ... rhonite and fassaite compositions are for rhonites that have decomposed to fassaite + perovskite + spinel. Open circles represent intra-crystalline fassaites. The dashed line marked ALL-4 is the ...

Stephen E. Haggerty

1978-11-16T23:59:59.000Z

52

Measurement of neutron capture on 50Ti at thermonuclear energies  

E-Print Network [OSTI]

At the Karlsruhe and Tuebingen 3.75 MV Van de Graaff accelerators the thermonuclear 50Ti(n,gamma)51Ti(5.8 min) cross section was measured by the fast cyclic activation technique via the 320.852 and 928.65 keV gamma-ray lines of the 51Ti-decay. Metallic Ti samples of natural isotopic composition and samples of TiO2 enriched in 50Ti by 67.53 % were irradiated between two gold foils which served as capture standards. The capture cross-section was measured at the neutron energies 25, 30, 52, and 145 keV, respectively. The direct capture cross section was determined to be 0.387 +/- 0.011 mbarn at 30 keV. We found evidence for a bound state s-wave resonance with an estimated radiative width of 0.34 eV which destructively interfers with direct capture. The strength of a suggested s-wave resonance at 146.8 keV was determined. The present data served to calculate, in addition to the directly measured Maxwellian averaged capture cross sections at 25 and 52 keV, an improved stellar 50Ti(n,gamma)51Ti rate in the thermonuclear energy region from 1 to 250 keV. The new stellar rate leads at low temperatures to much higher values than the previously recommended rate, e.g., at kT=8 keV the increase amounts to about 50 %. The new reaction rate therefore reduces the abundance of 50Ti due to s-processing in AGB stars.

P. V. Sedyshev; P. Mohr; H. Beer; H. Oberhummer; Yu. P. Popov; W. Rochow

1999-07-28T23:59:59.000Z

53

Investigation on the delaminated-pillared structure of TiO2-PILC synthesized by TiCl4 hydrolysis method  

Science Journals Connector (OSTI)

TiO2-PILCs were synthesized by the reaction between montmorillonite and acidic solutions of hydrolyzed TiCl4. Unlike commonly reported microporous pillared structure, a meso–microporous delaminated structure containing pillared fragments was observed in the resulting TiO2-PILC, based on the combined analyses of powder X-ray diffraction (XRD), nitrogen adsorption–desorption isotherms, chemical analysis, thermogravimetric (TG) and differential scanning calorimetry (DSC) analyses. Air-drying after ethanol extraction (EAD) is shown to be more effective than air-drying (AD) in preserving the delaminated structure in the resultant Ti-clay. A broad XRD peak at low 2? angle with a high d-spacing of ?6.6 nm was firstly reported and it was proposed to be correlated with the mesoporous delaminated structure rather than the (0 0 1) reflection of intercalated/pillared periodic structure. The resulting TiO2-PILC exhibits a good thermal stability as indicated by its surface area after calcination at 600 °C. Moreover, calcination above 300 °C results in the formation of nanocrystalline anatase in the TiO2-PILC, and the grain size of anatase increases with the increment of calcination temperature. However, no phase transformation from anatase to rutile was observed even under calcination at 1000 °C. These fundamental results provide new insights about the structure of TiO2-PILC synthesized by TiCl4 hydrolysis method.

Peng Yuan; Xiaoling Yin; Hongping He; Dan Yang; Linjiang Wang; Jianxi Zhu

2006-01-01T23:59:59.000Z

54

Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy study  

E-Print Network [OSTI]

Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy, Texas 77843-3255 Received 14 October 1997; accepted 6 April 1998 Al clusters supported on TiO2(110) have been investigated using scanning tunneling microscopy. Al interacts strongly with the TiO2(110) surface

Goodman, Wayne

55

US NE MA Site Consumption  

Gasoline and Diesel Fuel Update (EIA)

NE MA NE MA Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 $3,000 US NE MA Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 2,000 4,000 6,000 8,000 10,000 12,000 US NE MA Site Consumption kilowatthours $0 $250 $500 $750 $1,000 $1,250 $1,500 US NE MA Expenditures dollars ELECTRICITY ONLY average per household * Massachusetts households use 109 million Btu of energy per home, 22% more than the U.S. average. * The higher than average site consumption results in households spending 22% more for energy than the U.S. average. * Less reliance on electricity for heating, as well as cool summers, keeps average site electricity consumption in the state low relative to other parts of the U.S. However, spending on electricity is closer to the national average due to higher

56

US NE MA Site Consumption  

U.S. Energy Information Administration (EIA) Indexed Site

NE MA NE MA Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 $3,000 US NE MA Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 2,000 4,000 6,000 8,000 10,000 12,000 US NE MA Site Consumption kilowatthours $0 $250 $500 $750 $1,000 $1,250 $1,500 US NE MA Expenditures dollars ELECTRICITY ONLY average per household * Massachusetts households use 109 million Btu of energy per home, 22% more than the U.S. average. * The higher than average site consumption results in households spending 22% more for energy than the U.S. average. * Less reliance on electricity for heating, as well as cool summers, keeps average site electricity consumption in the state low relative to other parts of the U.S. However, spending on electricity is closer to the national average due to higher

57

MA transmutation performance in the optimized MYRRHA  

SciTech Connect (OSTI)

MYRRHA (multi-purpose hybrid research reactor for high-tech applications) is a multipurpose research facility currently being developed at SCK-CEN. It will be able to work in both critical and subcritical modes and, cooled by lead-bismuth eutectic. In this paper the minor actinides (MA) transmutation capabilities of MYRRHA are investigated. (Pu + Am, U) MOX fuel and (Np + Am + Cm, Pu) Inert Matrix Fuel test samples have been loaded in the central channel of the MYRRHA critical core and have been irradiated during five cycles, each one consisting of 90 days of operation at 100 MWth and 30 days of shutdown. The reactivity worth of the test fuel assembly was about 1.1 dollar. A wide range of burn-up level has been achieved, extending from 42 to 110 MWd/kg HM, the samples with lower MA-to-Pu ratios reaching the highest burn-up. This study has highlighted the importance of the initial MA content, expressed in terms of MA/Pu ratio, on the transmutation rate of MA elements. For (Pu + Am, U) MOX fuel samples, a net build-up of MA is observed when the initial content of MA is very low (here, 1.77 wt% MA/Pu) while a net decrease in MA is observed in the sample with an initial content of 5 wt%. This suggests the existence of some 'equilibrium' initial MA content value beyond which a net transmutation is achievable.

Malambu, E.; Van den Eynde, G.; Fernandez, R.; Baeten, P.; Ait Abderrahim, H. [SCK-CEN, Boeretang 200, BE-2400 Mol (Belgium)

2013-07-01T23:59:59.000Z

58

Hydrothermal ethanol conversion on Ag, Cu, Au/TiO2  

Science Journals Connector (OSTI)

The effect UV irradiation and silver, copper, and gold ions (M z+) supported on titania (anatase) have on the activity of M/TiO2 samples in ethanol conversion at 150–400°C is examined....2 and A...

Do Tkhyui Mai; I. I. Mikhalenko; A. I. Pylinina

2014-10-01T23:59:59.000Z

59

Effect of WC/TiC grain size ratio on microstructure and mechanical properties of WCTiCCo cemented carbides  

E-Print Network [OSTI]

of TiC powder as 1 lm. The microstructures of sintered WC­TiC­10 wt%Co cemented carbides were than that expected by modified Hall­Petch type equation. Transverse rupture strength of WC­20TiC­10 wt for decades [1]. Generally, cemented carbides are based on the WC­Co and some cubic carbide such as TiC, Ta

Hong, Soon Hyung

60

Preparation of Al2O3/TiO2-containing Coating on Aluminium Alloys by Micro-arc Oxidation  

Science Journals Connector (OSTI)

TiO2-containing ceramic coatings were deposited on the surface of aluminium alloys by micro-arc oxidition. Surface and cross-section topograph of ceramic coating were observed using scanning electron microscopy (SEM). The phase composition of ceramic ... Keywords: Micro-arc oxidation, TiO2 additive, Al2O3/TiO2 phase, antiwear behavior

Cheng Gao; Jinyong Xu; Yusheng Lan; Yonghui Ma; Weixiang Su; Yajuan Liu

2010-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Comparative study on the corrosion behavior of TiNb and TMA alloys for dental application in various artificial solutions  

E-Print Network [OSTI]

Comparative study on the corrosion behavior of Ti­Nb and TMA alloys for dental application 2011 Keywords: Ti­Nb alloy TMA Corrosion Fluoride Artificial saliva The corrosion behavior of Ti the corrosion resistance of experimental alloys, with the corroded surface being further characterized

Zheng, Yufeng

62

DOE - Office of Legacy Management -- National Fireworks Ordnance Corp - MA  

Office of Legacy Management (LM)

Fireworks Ordnance Corp - Fireworks Ordnance Corp - MA 13 FUSRAP Considered Sites Site: NATIONAL FIREWORKS ORDNANCE CORP (MA.13) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: American Potash and Chemical Corporation MA.13-3 Location: West Hanover , Massachusetts MA.13-1 Evaluation Year: 1991 MA.13-1 Site Operations: Performed bench scale research and development on uranium forming during the 1960s. MA.13-2 MA.13-3 Site Disposition: Eliminated - Potential for contamination considered remote based on the limited quantity of materials handled MA.13-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium Metal and Powders MA.13-3 Radiological Survey(s): None Indicated MA.13-2 Site Status: Eliminated from consideration under FUSRAP

63

DOE - Office of Legacy Management -- Fenwal Inc - MA 14  

Office of Legacy Management (LM)

Fenwal Inc - MA 14 Fenwal Inc - MA 14 FUSRAP Considered Sites Site: Fenwal, Inc. (MA.14 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Ashland , Massachusetts MA.14-1 Evaluation Year: 1994 MA.14-2 MA.14-3 Site Operations: Performed pilot scale explosion suppression tests on uranium contaminated magnesium fluoride powder in the late 1960s. MA.14-1 MA.14-3 Site Disposition: Eliminated - Potential for contamination considered remote based on the limited quantity of materials handled MA.14-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MA.14-1 Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to Fenwal, Inc.

64

Effect of Aging Heat Treatments on Ni52Ti48 Shape Memory Alloy  

E-Print Network [OSTI]

Ni-rich NiTi shape memory alloys (SMAs) are capable of attaining a wide range of transformation temperatures depending on the heat treatment conditions and superior thermo-mechanical cycling stability, which are desired for repeated solid...

Akin, Erhan

2011-10-21T23:59:59.000Z

65

Lucas-Kanade Optical Flow Estimation on the TI C66x Digital Signal Processor  

E-Print Network [OSTI]

technology for lightweight mobile platforms. The C66x DSP is based on TI's Keystone architecture and consists, scratchpad, or a mixture of both. Like other VLIW archi- tectures, the compiler must software pipeline each

Bakos, Jason D.

66

Electron Source in Photoinduced Hydrogen Production on Pt-supported TiO2 Particles  

Science Journals Connector (OSTI)

Electron Source in Photoinduced Hydrogen Production on Pt-supported TiO2 Particles ... After recovering the TiO2/Pt particles used in the long-term reaction, they were reused in a photocatalytic H+ reduction by adding methanol as an electron donor, but no H2 production was observed showing that the TiO2/Pt particles have lost their photocatalytic activity after the long-term reaction. ... A 100 W high-pressure Hg lamp was used as a light source. ...

Toshiyuki Abe; Eiji Suzuki; Kentaro Nagoshi; Kohichi Miyashita; Masao Kaneko

1999-02-04T23:59:59.000Z

67

Solar–absorber antireflector on the eye of an Eocene fly (45 Ma)  

Science Journals Connector (OSTI)

7 May 1998 research-article Solar-absorber antireflector on the eye of an Eocene fly...normal. A comparable antireflector is employed on solar absorbers. antireector|grating|solar absorber|y|eye|amber| georef;2013040204 2013-040204...

1998-01-01T23:59:59.000Z

68

Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110)  

SciTech Connect (OSTI)

Understanding hydrogen formation on TiO2 surfaces is of great importance as it could provide fundamental insight into water splitting for hydrogen production using solar energy. In this work, hydrogen formation from glycols having different numbers of methyl end-groups have been studied using temperature pro-grammed desorption on reduced, hydroxylated, and oxidized TiO2(110) surfaces. The results from OD-labeled glycols demon-strate that gas-phase molecular hydrogen originates exclusively from glycol hydroxyl groups. The yield is controlled by a combi-nation of glycol coverage, steric hindrance, TiO2(110) order and the amount of subsurface charge. Combined, these results show that proximal pairs of hydroxyl aligned glycol molecules and subsurface charge are required to maximize the yield of this redox reaction. These findings highlight the importance of geometric and electronic effects in hydrogen formation from adsorbates on TiO2(110).

Chen, Long; Li, Zhenjun; Smith, R. Scott; Kay, Bruce D.; Dohnalek, Zdenek

2014-04-16T23:59:59.000Z

69

MaRIE Presentations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

certifiable, flexible, and low-cost product-based solutions to many materials problems. MaRIE 1.0 Matter Radiation Interactions in Extremes 1.0 70th Anniversary (pdf) July 27, 2013...

70

Effect of crystal phases of titanium dioxide on adsorption performance of H2TiO3-lithium adsorbent  

Science Journals Connector (OSTI)

Abstract Different crystal phases of TiO2 were produced by calcinations of metatitanic acid at various temperatures. H2TiO3-lithium adsorbent was obtained from the acid-modified adsorbent precursor Li2TiO3 which was synthesized by a solid-phase reaction between TiO2 and LiOH·H2O. Effects of crystal phases of TiO2 on the pull-out rate of Li+ from Li2TiO3 and adsorption properties of lithium adsorbent were studied. The results indicate that anatase structure rather than rutile reacted with LiOH·H2O aids the extraction of Li+ and the adsorption performance of lithium adsorbent. The maximum Li+ drawn out ratio from Li2TiO3 reaches 98.69%, and the maximum saturated adsorptive capacity comes up to 39.2 mg g?1.

Liyuan Zhang; Dali Zhou; Gang He; Fanhou Wang; Jiabei Zhou

2014-01-01T23:59:59.000Z

71

Transition metal atoms pathways on rutile TiO{sub 2} (110) surface: Distribution of Ti{sup 3+} states and evidence of enhanced peripheral charge accumulation  

SciTech Connect (OSTI)

Charge transfer between metal nanoparticles and the supported TiO{sub 2} surface is primarily important for catalytic applications as it greatly affects the catalytic activity and the thermal stability of the deposited nanoparticles on the surface. Herein, systematic spin-polarized density functional and HSE06 calculations are performed to evaluate the adsorption, diffusion, and charge state of several transition metal monomers on both stoichiometric and reduced rutile TiO{sub 2} (110) surface. Although the presence of oxygen vacancy (O{sub v}) increases the binding of Au, Pt and Pd on the surface, it weakens the interaction thus enhancing the diffusion for Fe, Co, Ni, Ag, and Cu adatoms on the surface. For pristine reduced surface, only a small portion (around 5%) of the excess electrons occupy the topmost surface, which are mainly delocalized at the second nearest and third nearest fivefold coordinated Ti (Ti{sub 5c}) atoms. Excess electrons populating at the Ti{sub 5c} atoms on the basal plane can be transferred to strongly electronegative adsorbates like Au and Pt thus enabling a moderate adsorption at this site, whereas no stable adsorption is found for other less electronegative transition metal adatoms (Ag, Cu, Fe, Co, Ni, and Pd) on the reduced surface and for all the adatoms on stoichiometric surface. This result clarifies the origin of the experimental observation of the adsorption of O{sub 2} and CO molecules at Ti{sub 5c} sites in connection with charge transfer. In addition, the spatial redistribution of the excess electrons around the O{sub v} upon the adsorption of the monomers is thoroughly examined. Our finding of an accumulation of excess electrons at the Ti{sub 5c} sites around the monomers explains the critical role of the perimeter interface of the deposited nanoparticles in promoting the adsorption and activation of reactants observed in experiments.

Cai Yongqing; Bai Zhaoqiang; Chintalapati, Sandhya; Feng Yuanping [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Zeng Qingfeng [School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072 (China)

2013-04-21T23:59:59.000Z

72

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Title Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Publication Type Journal Article Year of Publication 2013 Authors Rosseler, Olivier, Mohamad Sleiman, Nahuel V. Montesinos, Andrey Shavorskiy, Valerie Keller, Nicolas Keller, Marta I. Litter, Hendrik Bluhm, Miquel Salmeron, and Hugo Destaillats Journal J. Phys. Chem. Lett. Volume 4 Start Page 536 Issue 3 Pagination 536-541 Date Published 01/2013 Abstract Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3-, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO3- conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3- in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds.

73

Impact of point defects on electronic structure in Y2Ti2O7  

SciTech Connect (OSTI)

With many technologies and applications downscaling to nanometer dimensions, the influence of single point defects on electronic structure has shown increasingly profound impact on optical and electrical properties, and advancing fundamental understanding is critical to defect engineering and control of materials properties. In the present study, first-principles calculations based on density functional theory (DFT) are carried out to study the effects of Ti point defects on the electronic structure of Y2Ti2O7. In the literature, it has been demonstrated that conventional DFT tends to produce delocalized holes and electrons in defective oxide materials due to insufficient cancellation of the self-interaction energy and underestimation of the band gap, which results in an incorrect description of the electronic structure of the system. In an effort to better understand the accuracy of DFT in describing the behavior of Y2Ti2O7 with point defects, the calculated results obtained from using DFT and DFT+U methods are compared, including the geometrical distortion, the localization of the defect states and the position of the defect levels in the band gap. Using DFT, distorted geometries around the Ti vacancy and interstitial are found, along with localized oxygen holes and Ti electrons, both of which compare well with the DFT+U results, suggesting that the conventional DFT can be used to describe the localization of the Ti defects in Y2Ti2O7. One major difference in the DFT and DFT+U calculations is the energy position of the defect levels, for which DFT+U results in the states positioned deep in the band gap. Since the DFT+U method suffers from the dependence of the results on the empirical parameter U and no experimental results on the energy position of the defect states are available to tune this U value, care must be taken in applying DFT+U to electronic structure calculations of Y2Ti2O7 with point defects. Based on the DFT method, the most preferred charge state is determined by the formation energies for charged point defects. Moving the Fermi level across the band gap has slight effects on the charge state, and the Ti vacancy and interstitial are found to be in -4 and +4 charge states, respectively.

Xiao, Haiyan [University of Tennessee, Knoxville (UTK); Zhang, Yanwen [ORNL; Weber, William J [ORNL

2012-01-01T23:59:59.000Z

74

Impact of Point Defects on Electronic Structure in Y?Ti?O?  

SciTech Connect (OSTI)

With many technologies and applications downscaling to nanometer dimensions, the influence of single point defects on electronic structure has shown an increasingly profound impact on optical and electrical properties, and advancing fundamental understanding is critical to defect engineering and control of materials properties. In the present study, first-principles calculations based on density functional theory (DFT) are carried out to study the effects of Ti point defects on the electronic structure of Y?Ti?O?. In the literature, it has been demonstrated that conventional DFT tends to produce delocalized holes and electrons in defective oxide materials due to insufficient cancellation of the self-interaction energy and underestimation of the band gap, which results in an incorrect description of the electronic structure of the system. In an effort to better understand the accuracy of DFT in describing the behavior of Y?Ti?O? with point defects, the calculated results obtained from DFT and DFT+U methods are compared, including the geometrical distortion, the localization of the defect states and the position of the defect levels in the band gap. Using DFT, distorted geometries around the Ti vacancy and interstitial are found, along with localized oxygen holes and Ti electrons, both of which compare well with the DFT+U results, suggesting that the conventional DFT can be used to describe the localization of the Ti defects in Y?Ti?O?. One major difference in the DFT and DFT+U calculations is the energy position of the defect levels, for which DFT+U results in the states positioned deep in the band gap. Since the DFT+U method suffers from the dependence of the results on the empirical parameter U and no experimental results on the energy position of the defect states are available to tune this U value, care must be taken in applying DFT+U to electronic structure calculations of Y?Ti?O? with point defects. Based on the DFT method, the most preferred charge state is determined by the formation energies for charged point defects. Moving the Fermi level across the band gap has slight effects on the charge state, and the Ti vacancy and interstitial are found to be in 24 and +4 charge states, respectively.

Xiao, Haiyan Y.; Zhang, Yanwen; Weber, William J.

2012-06-13T23:59:59.000Z

75

Combined Investigation of Water Sorption on TiO2 Rutile (110) Single Crystal Face: XPS vs. Periodic DFT  

E-Print Network [OSTI]

1 Combined Investigation of Water Sorption on TiO2 Rutile (110) Single Crystal Face: XPS vs(0)169157150; e-mail: roques@ipno.in2p3.fr Keywords: water, sorption, rutile TiO2, (110), XPS, DFT. Abstract XPS and periodic DFT calculations have been used to investigate water sorption on the TiO2 rutile (110) face. Two

Paris-Sud XI, Université de

76

Assessment of the compositional influences on the toughness of TiCr{sub 2}-base laves phase alloys  

SciTech Connect (OSTI)

Systematic studies of alloys based on TiCr{sub 2} have been performed in order to improve the toughness of Laves phase intermetallics. The extent to which alloy compositions and annealing treatments influence the toughness was quantified by Vickers indentation. The single-phase Laves behavior was first established by studying stoichiometric and nonstoichiometric TiCr{sub 2}. Next, alloying effects were investigated with ternary Laves phases based on TiCr{sub 2}. Different microstructures of two-phase alloys consisting of (Ti,Cr)-bcc+TiCr{sub 2} were also examined. Various toughening theories based on vacancies, site-substitutions, crystal structure (C14, C36, or C15) stabilization, and the presence of a second phase were evaluated. The most effective factors improving the toughness of TiCr{sub 2} were determined, and toughening mechanisms are suggested.

Chen, K.C.; Allen, S.M.; Livingston, J.D.

1997-03-01T23:59:59.000Z

77

Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 catalyst Formation, stability and CO  

E-Print Network [OSTI]

1 Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 are the activation of molecular oxygen, the active site for this reaction step, and the nature of the catalytically active oxygen species present under working conditions.[3;9-15] Stiehl et al. had shown that molecularly

Pfeifer, Holger

78

Molecular beam epitaxial growth and characterization of mixed (Ti,Nb)O{sub 2} rutile films on TiO{sub 2}(100)  

SciTech Connect (OSTI)

Epitaxial films of mixed (Nb,Ti)O{sub 2} rutile have been grown on TiO{sub 2}(100) rutile at 600{degree}C by molecular beam epitaxy. These films grow in a laminar fashion for Nb mole fractions up to {approximately}0.10. In addition, reflection high-energy and low-energy electron diffraction, along with x-ray photoelectron diffraction and Rutherford backscattering reveal that the overlayers possess excellent long- and short-range structure order up to 10 at.{percent}. However, strain-induced disorder becomes prevalent for higher Nb mole fractions, and the surfaces roughen and become defected accordingly. X-ray photoelectron diffraction and Rutherford backscattering reveal that Nb atoms substitutionally incorporate at cation sites in the rutile lattice for all Nb mole fractions investigated, leading to a mixed rutile Nb{sub {ital x}}Ti{sub 1{minus}{ital x}}O{sub 2} phase. Analysis of Nb 3{ital d} and Ti 2{ital p} core-level binding energies reveals that the oxidation state of both Ti and Nb is +4. {copyright} {ital 1996 American Vacuum Society}

Chambers, S.A.; Gao, Y.; Thevuthasan, S.; Liang, Y. [Environmental Molecular Sciences Laboratory, Pacific Northwest Laboratory, Richland, Washington 99352 (United States)] [Environmental Molecular Sciences Laboratory, Pacific Northwest Laboratory, Richland, Washington 99352 (United States); Shivaparan, N.R.; Smith, R.J. [Department of Physics, Montana State University, Bozeman, Montana 59717 (United States)] [Department of Physics, Montana State University, Bozeman, Montana 59717 (United States)

1996-05-01T23:59:59.000Z

79

Acetone-Assisted Oxygen Vacancy Diffusion on TiO2(110)  

SciTech Connect (OSTI)

We have studied the dynamic relationship between acetone and bridge-bonded oxygen (Ob) vacancy (VO) defect sites on the TiO2(110)-1 × 1 surface using scanning tunneling microscopy (STM) and density function theory (DFT) calculations. We report an adsorbate-assisted VO diffusion mechanism. The STM images taken at 300 K show that acetone preferably adsorbs on the VO site and is mobile. The sequential isothermal STM images directly show that the mobile acetone effectively migrates the position of VO by a combination of two acetone diffusion channels: one is the diffusion along the Ob row and moving as an alkyl group, which heals the initial VO; another is the diffusion from the Ob row to the fivecoordinated Ti4+ row and then moving along the Ti4+ row as an acetone, which leaves a VO behind. The calculated acetone diffusion barriers for the two channels are comparable and agree with experimental results.

Xia, Yaobiao; Zhang, Bo; Ye, Jingyun; Ge, Qingfeng; Zhang, Zhenrong

2012-10-18T23:59:59.000Z

80

Effect of Reactive Sputtering Parameters on TiAlN Nanocoating Structure and Morphology  

SciTech Connect (OSTI)

The effect of substrate bias and nitrogen flow rate on the TiAlN nanocoating structure and morphology has been investigated by using reactive unbalance DC magnetron sputtering. TiAlN nanocoating was deposited on the tungsten carbide insert tool and the structure and morphology were characterized by using XRD and AFM, respectively. The substrate bias was varied between 0 to -221 V and the nitrogen flow rate was varied between 30 to 72 sccm. The results showed that the structure of TiAlN nanocoating consisted of mainly (111) and (200) plane. The structure was significatly influenced by substrate bias in promoting finer crystal size and increased crystal plane spacing while the rms roughness of nanocoating was influenced by substrate bias and nitrogen flow rate.

Budi, Esmar [Jurusan Fisika FMIPA Universitas Negeri Jakarta Jl. Pemuda No. 10 Rawamangun Jakarta 13220 (Indonesia); Razali, M. Mohd.; Nizam, A. R. Md. [Faculty of Manufacturing Engineering Universiti Teknikal Malaysia Melaka (UTeM) Karung Berkunci No 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

2010-10-24T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Superior Corrosion Resistance Properties of TiN-Based Coatings on Zircaloy Tubes in Supercritical Water  

SciTech Connect (OSTI)

Thin films of TiN and Ti0.35Al0.65N nanocomposite were deposited on polished Zircaloy-4 tubes. After exposure to supercritical water for 48 h, the coated tubes are remarkably intact, while the bare uncoated tube shows severe oxidation and breakaway corrosion. X-ray diffraction patterns, secondary electron images, backscattered electron images, and energy dispersive X-ray spectroscopy data from the tube surfaces and cross-sections show that a protective oxide, formed on the film surface, effectively prevents further oxidation and corrosion to the Zircaloy-4 tubes. This result demonstrates the effectiveness of thin film ceramics as protective coatings under extreme environments.

Fauzia Khatkhatay; Liang Jiao; Jie Jian; Zhijie Jiao; Hongbin Zhang; Jian Gan; Haiyan Wang; Wenrui Zhang; Xinghang Zhang

2014-08-01T23:59:59.000Z

82

OH Group Dynamics of 1, 3-propanediol on TiO2(110)  

SciTech Connect (OSTI)

Variable-temperature scanning tunneling microscopy and dispersion-corrected density functional theory were employed to study the interaction of 1,3 propanediol with reduced TiO2(110) surfaces. We find that at 300 K, 1,3-propanediol molecules dissociate via O-H bond scission of one of the OH groups on bridge-bonded oxygen (Ob) vacancy (VO) defects forming pairs of monoalkoxide (Ob-(CH2)3-OH) and bridge-bonded bonded hydroxyl (HOb) species. The OH group of the monoalkoxide species is bound to the adjacent 5-coordinated Ti4+ (Ti5c) sites. The Ob-(CH2)3-OH species are observed to rotate around their Ob anchor, switching the position of the OH between the two adjacent Ti5c rows. The rotating species are found to assist the cross-Ob row HOb hydrogen transfer. The OH group of the monoalkoxide species is further observed to dissociate forming bidentate type dioxo (Ob-(CH2)3-"O" _(?"Ti" ?_"5c" )) species and an additional HOb. The reversible interconversion between the mono- and di-oxo species illustrates a formation of the equilibrium between these conjugate acid/base pairs.

Zhang, Zhenrong; Yoon, Yeohoon; Lin, Xiao; Acharya, Danda P.; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek

2012-11-15T23:59:59.000Z

83

First-principles study on negative thermal expansion of PbTiO{sub 3}  

SciTech Connect (OSTI)

It is well known that perovskite-type PbTiO{sub 3} behaves negative thermal expansion in a wide temperature range from room temperature to Curie temperature (763?K). The present study reports the first-principles study of the anisotropic thermal expansion of PbTiO{sub 3}, in the framework of the density-functional theory and the density-functional perturbation theory. The curve of temperature dependence of the unit cell volume is presented from 20 to 520?K through the calculation of the minimum of total free energy at each temperature point. The negative thermal expansion of PbTiO{sub 3} is calculated without empirical parameters. Furthermore, the distinctive thermodynamic act of PbTiO{sub 3} from expanding to contracting at tetragonal phase is reproduced. The ab-initio calculations reveal that this unique appearance depends on the phonon vibration. The dynamical contributions of various atoms are also calculated to account for the disparate role of Pb-O and Ti-O bond.

Wang, Fangfang; Chen, Jun; Xing, Xianran, E-mail: xing@ustb.edu.cn [Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083 (China)] [Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Xie, Ying; Fu, Honggang [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin 150080 (China)

2013-11-25T23:59:59.000Z

84

Microstructures and wear properties of TiN-based cermet coating deposited on 1Cr18Ni9Ti stainless steel by electrospark process  

Science Journals Connector (OSTI)

A simple and effective surface treatment technique, electrospark deposition (ESD), has been successfully applied to deposit TiN-based cermet coating on stainless steel substrate. The nitrided coating had an average thickness of about 30 ?m and formed metallurgical bonding with the substrate. The microstructure of the coating was mainly composed of TiN phase and ferrite (?-FeCr) phase. Its microhardness reached 889HV. The experimental results demonstrated that the nitrided coating had an excellent sliding wear resistance because the hard TiN phase distributed in the coating increased the resistance to micro-cutting and plowing during the sliding wear test, which effectively improves the surface performance of stainless steel substrate.

X. Li; D.Q. Sun; X.Y. Zheng; Z.A. Ren

2008-01-01T23:59:59.000Z

85

DOE - Office of Legacy Management -- Manufacturing Laboratories Inc - MA  

Office of Legacy Management (LM)

Manufacturing Laboratories Inc - MA Manufacturing Laboratories Inc - MA 0-04 FUSRAP Considered Sites Site: MANUFACTURING LABORATORIES, INC. (MA.0-04 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 272 Northampton Street , Boston , Massachusetts MA.0-04-1 Evaluation Year: 1987 MA.0-04-3 Site Operations: Developed a process for making projectiles from depleted uranium during the early 1950s. MA.0-04-3 Site Disposition: Eliminated - Potential for contamination considered remote based on limited scope of operations at the site MA.0-04-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MA.0-04-1 Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP

86

Influence of O2-induced surface roughening on the chemistry of water on TiO2(110)  

SciTech Connect (OSTI)

The impact of oxygen induced regrowth of TiO2 on the reduced rutile TiO2(110) surface has been studied using temperature programmed desorption (TPD) of adsorbed water multilayers. Pre-exposure of UHV annealed TiO2(110) surfaces to O2 at temperatures from 300 to 850 K induced changes in subsequent water TPDs that were interpreted in terms of the rougher surface morphologies resulting from the regrowth process. Water TPD from TiO2(110) previously oxidized at 300 K exhibited a new peak at *312 K due to reaction of water with O adatoms. These O adatoms were produced by dissociative adsorption of O2 at O-vacancy sites. Additionally, oxygen reacted (slowly) with surface Ti2O3 strands at RT. Water TPD from surfaces pre-oxidized at higher temperatures (P500 K) exhibited features reflective of desorption from rough surfaces, namely loss of peak resolution and eventual merger of the second layer and ice peaks, formation of a high temperature tail on the second layer peak, and broadening of the first layer TPD peak. The multiplicity of kinetically different adsorption sites on the roughened TiO2(110) surfaces contributed to the widening of the desorption features. Published by Elsevier B.V.

Zehr, Robert T.; Henderson, Michael A.

2008-04-15T23:59:59.000Z

87

Performance improvement of TiO2 supported on adsorbents for photocatalytic degradation of MEK in air  

Science Journals Connector (OSTI)

Photocatalytic degradation of Methyl Ethyl Ketone (MEK) was carried out in gas phase using TiO2 supported on different adsorbents. Based on size and surface area, three different adsorbents, montmorillonite, ?-zeolite and MCM-41 were tested. A fluidised bed annular photoreactor fitted with either 254 or 365 nm lamps was used for the photodegradation studies. The removal rates of MEK were higher for the catalysts supported on the adsorbent as compared to bare TiO2 (Degussa P25 and sol-gel TiO2) due to both improved adsorption and photocatalytic degradation. The photocatalytic activity of the supported TiO2 was maximum around 50 wt.% loading of TiO2. Among all the adsorbents tested, montmorillonite showed better removal rate than MCM-41 and ?-zeolite. Some limited experiments were conducted with Trichloroethylene (TCE) to evaluate the effect of polarity of the organic compound on overall degradation using the supported catalysts.

Pavan Kumar Puttamraju; Madhumita B. Ray

2008-01-01T23:59:59.000Z

88

(1) Biology Department, Woods Hole Oceanographic Institution, Woods Hole, MA 02543 USA(1) Biology Department, Woods Hole Oceanographic Institution, Woods Hole, MA 02543 USA (2) Harvard Medical School, Boston, MA 02114 USA(2) Harvard Medical School, Boston  

E-Print Network [OSTI]

(1) Biology Department, Woods Hole Oceanographic Institution, Woods Hole, MA 02543 USA(1) Biology Department, Woods Hole Oceanographic Institution, Woods Hole, MA 02543 USA (2) Harvard Medical School, Boston, MA 02114 USA(2) Harvard Medical School, Boston, MA 02114 USA (3) Section on Auditory Mechanics, NIDCD

89

IEEE TRANSACTIONS ON NANOTECHNOLOGY, VOL. 10, NO. 3, MAY 2011 499 TiSi2 Nanocrystal Metal Oxide Semiconductor Field  

E-Print Network [OSTI]

IEEE TRANSACTIONS ON NANOTECHNOLOGY, VOL. 10, NO. 3, MAY 2011 499 TiSi2 Nanocrystal Metal Oxide memory window, faster writing and erasing, and longer retention lifetime as a result of the metallic property of the silicide NCs. Due to thermally stable, CMOS compatible properties, TiSi2 NCs are highly

Yang, Zheng

90

First-principles study of hydrogen storage on Ti-decorated B{sub 2}C sheet  

SciTech Connect (OSTI)

The hydrogen storage capacity of Ti decorated B{sub 2}C sheet has been investigated by first-principles plane-wave calculation. It is revealed that a single Ti atom adsorbed on the B{sub 2}C sheet can strongly bind up to four hydrogen molecules. The adsorption energy is in the range of -0.36--0.82 eV/H{sub 2}, which is suitable for ambient temperature hydrogen storage. Considering the fact that Ti can be loaded on both sides of B{sub 2}C sheet, corresponding gravimetric storage capacity of Ti/B{sub 2}C system was also calculated and it can reach to about 7.0 wt%, exceeding the minimum requirement of 6.0 wt% for applications. - Graphical abstract: We investigated the hydrogen storage capacity of Ti decorated B{sub 2}C sheet. The most favorable adsorption geometries for every number of hydrogen molecules on Ti/B{sub 2}C complex are given in the figure. Highlights: Black-Right-Pointing-Pointer Ti decorated B{sub 2}C sheet serve as hydrogen storage medium. Black-Right-Pointing-Pointer A single Ti atom adsorbed on the B{sub 2}C sheet can strongly bind up to four hydrogen molecules. Black-Right-Pointing-Pointer The adsorption energy is in moderate range of -0.36--0.82 eV/H{sub 2}.

Guo, Y.H.; Xu, B.; Xia, Y.D.; Yin, J. [Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China); Liu, Z.G., E-mail: liuzg@nju.edu.cn [Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)

2012-06-15T23:59:59.000Z

91

Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a  

E-Print Network [OSTI]

to the surface properties and the adsorption reactions of titanium dioxide-anatase surface. Lin and Bai [3 reserved. Keywords: TiO2; Anatase; Adsorption; Water; Ammonia; DFT 1. Introduction Titanium oxides are usedAdsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a , Selim

Senkan, Selim M.

92

Effect of thin Mo2C layer on thermal stability of Si/SiO2/Ti/Cu system  

Science Journals Connector (OSTI)

The effect of introducing a thin Mo2C (30 nm) layer between Ti and Cu on the thermal stability of Si/SiO2/Ti/Cu system was studied using four-point probe (FPP), scanning electron microscopy (SEM), energy-dispersi...

C. C. Tripathi; Mukesh Kumar; Dinesh Kumar

2011-12-01T23:59:59.000Z

93

Theoretical Study on the Reaction of Ti+ with Acetone and the Role of Intersystem  

E-Print Network [OSTI]

the chemical reactions of a transition-metal ion with an organic molecule in the gas phase may provide useful investigations aiming at explaining the reaction mechanisms of the first-row transition-metal ions with organic appears to vary depending on the metal ion involved.5-8 Early transition-metal cations such as Ti+ and Sc

Ihee, Hyotcherl

94

Short communication Effect of vanadium redox species on photoelectrochemical behavior of TiO2  

E-Print Network [OSTI]

. Alternative and sustainable energy sources such as solar, wind, tidal power, geothermal, hydroelectricity implementation is hydrogen handling. Although molecular hydrogen has very high energy density on a mass basis and TiO2/WO3 photo-electrodes Dong Liu a , Fuqiang Liu a,*, Jianguo Liu b a Electrochemical Energy Lab

Liu, Fuqiang

95

Co-doped Anatase TiO? Heteroepitaxy on Si(001)  

SciTech Connect (OSTI)

Pure anatase TiO? and CoxTi?-x O? (0.01 < x < 0.04) epitaxial thin films were deposited by oxygen-plasma-assisted molecular beam epitaxy (OPA-MBE) on Si(001) for evaluation as a potential dilute magnetic semiconductor material suitable for Si-based spintronic devices. Epitaxial growth on Si(001) was facilitated by the deposition of ¼or ½ ML Sr metal on the clean Si(001) surface to form an oxidation resistant silicide layer, followed by deposition of a thin SrTiO? buffer layer. Using ½ ML Sr metal to form the silicide allowed the deposition of 10 ML SrTiO? without oxidation of the Si interface. Epitaxial anatase could be grown on this heterostructure, although use of the oxygen plasma during deposition resulted in significant SiO? formation. Pure anatase films consisted of epitaxial anatase surface particles on a continuous anatase film. For Co-doped films, Co segregation to surface particles of epitaxial anatase was observed by Auger electron spectroscopy and transmission electron microscopy (TEM); faceting of the particles was observed for low Co doping concentrations. Although no secondary phases containing Co were observed in Co-doped anatase films by x-ray diffraction or TEM, x-ray absorption near edge spectroscopy indicated Co was present in the films as a mixture of Co(0), Co(II), and Co(III). All samples were ferromagnetic at room temperature; for lower Co concentrations, the ferromagnetic remanence (9%) and coercive field (100 Oe) were similar to phase-pure Co:TiO? / LaAlO?. However, the presence of Co(0) under strongly oxidizing growth conditions known to oxidize the Si interface implies that under no deposition conditions can Co metal be eliminated while simultaneously protecting the Si interface from oxidation.

Kaspar, Tiffany C.; Droubay, Timothy C.; Wang, Chong M.; Heald, Steve M.; Lea, Alan S.; Chambers, Scott A.

2005-04-01T23:59:59.000Z

96

Thermodynamic and kinetic analyses of the CO2 chemisorption mechanism on Na2TiO3: Experimental and theoretical evidences  

SciTech Connect (OSTI)

ABSTRACT: Sodium metatitanate (Na2TiO3) was successfully synthesized via a solid-state reaction. The Na2TiO3 structure and microstructure were characterized using X-ray diffraction, scanning and transmission electron microscopy, and N2 adsorption. Then, the CO2 chemisorption mechanism on Na2TiO3 was systematically analyzed to determine the influence of temperature. The CO2 chemisorption capacity of Na2TiO3 was evaluated both dynamically and isothermally, and the products were reanalyzed to elucidate the Na2TiO3?CO2 reaction mechanism. Different chemical species (Na2CO3, Na2O, and Na4Ti5O12 or Na16Ti10O28) were identified during the CO2 capture process in Na2TiO3. In addition, some CO2 chemisorption kinetic parameters were determined. The ?H? was found to be 140.9 kJ/mol, to the Na2TiO3?CO2 system, between 600 and 780 °C. Results evidenced that CO2 chemisorption on Na2TiO3 highly depends on the reaction temperature. Furthermore, the experiments were theoretically supported by different thermodynamic calculations. The calculated thermodynamic properties of CO2 capture reactions by (Na2TiO3, Na4Ti5O12, and Na16Ti10O28) sodium titanates were fully investigated.

Duan, Yuhua [U.S. DOE

2014-01-01T23:59:59.000Z

97

The MBE growth and optical quality of BaTiO{sub 3} and SrTiO{sub 3} thin films on MgO  

SciTech Connect (OSTI)

High quality epitaxial BaTiO{sub 3} and SrTiO{sub 3} have been grown on MgO; stabilized at a one unit cell height; and grown to film thicknesses of 0.5--0.7 {mu}m. These relatively thick films remain adherent when thermally cycled between growth temperatures and room temperature, are crack free with high optical quality, and have both in-plane and out-of-plane X-ray rocking curves of 0.3--0.5{degree}. These films have been grown using molecular beam epitaxy (MBE) methods starting with the TiO{sub 2} layer of the perovskite structure. The TiO{sub 2}-layer/MgO interface uniquely satisfies electrostatic requirements for perovskite heteroepitaxy and provides the template structure that leads to the high quality films that are obtained. Wavelength dependence of optical loss has been characterized between 475 nm and 705 nm with loss coefficients < l dB/cm being obtained at the He-Ne wavelength.

McKee, R.A.; Specht, E.D.; Alexander, K.B. [Oak Ridge National Lab., TN (United States); Walker, F.J. [Tennessee Univ., Knoxville, TN (United States)

1994-05-01T23:59:59.000Z

98

Effect of laser irradiation on failure mechanism of TiCp reinforced titanium composite coating produced by laser cladding  

Science Journals Connector (OSTI)

Abstract Laser cladding is an effective technique to coat a metallic substrate with a layer of a different nature. It has been widely reported that the most important combined parameters controlling the quality of the coating are the specific energy (E) and the powder density (?). In the present work, clad deposits of Ti6Al4V + 60 wt.% TiC were prepared on a Ti6Al4V substrate using an optimum combination of Ec = 24 J/mm2 and ?c = 3 mg/mm2. These experiments were performed using a laser power of 400 and 600 W, in order to study the effect of laser power on the properties of the clad. The microstructure, phase composition and nanohardness of the coatings were investigated by optical microscopy, scanning electron microscopy and X-ray diffraction. During laser processing, TiC can be partially converted to TiCX (X = 0.5) due mainly to the TiC dissolution into the laser-generated melting pool and subsequent precipitation during cooling. It was observed that the lower laser power limit reduces primary TiC dissolution but it also promotes secondary carbide alignment at the interface. On the other hand, the damage mechanism induced by high laser power is dominated by primary TiC particle cracking by the high stress concentration at the particle–matrix interface followed by ductile failure of the matrix. It is also remarkable that irradiance affects the TiC/TiCx ratio despite Ec and ?c are fixed and it determines hardness distribution inside the coating.

J.J. Candel; J.A. Jimenez; P. Franconetti; V. Amigó

2014-01-01T23:59:59.000Z

99

Comparison of corrosion resistances between Fe{sub 2}O{sub 3}-TiO{sub 2} artificial passivation film and passivation film on Fe-Ti alloy  

SciTech Connect (OSTI)

Fe{sub 2}O{sub 3}-TiO{sub 2} double-oxide films were formed on Pt substrates by low-pressure metallorganic chemical vapor deposition using iron acetylacetonate and tetraisopropoxytitanium as precursors and O{sub 2} as a reaction gas. Fe-Ti alloys were fabricated by an ion-beam sputter and an arc-melting process. The corrosion resistances of the Fe{sub 2}O{sub 3}-TiO{sub 2} films and the Fe-Ti alloys were examined in acid solutions. The thinning rate of the Fe{sub 2}O{sub 3}-TiO{sub 2} films in 5 M HCl decreased with an increase in the formation temperature. Likewise, the dissolution rate decreased with increasing titanium cationic fraction in the films. The films hardly dissolved at anodic potentials, while significant dissolution occurred at cathodic potentials in 1 M H{sub 2}SO{sub 4} owing to the selective reduction of iron oxide components in the films. Sputter-deposited Fe-Ti alloy films containing more than 39 atom % Ti and arc-melted Fe-Ti alloys containing more than 57 atom % Ti showed high corrosion resistance when passivated anodically in 5 M HCl. The dissolution rates of the Fe{sub 2}O{sub 3}-TiO{sub 2} films in 5 M HCl appear to be significantly smaller than those of the passive films on the Fe-Ti alloy films and the Fe-Ti alloys in the same solution.

Kim, H.; Akao, Noboru; Hara, Nobuyoshi; Sugimoto, Katsuhisa [Tohoku Univ., Sendai (Japan)

1998-08-01T23:59:59.000Z

100

MA 23100 and MA 23200 - FINAL EXAM INFORMATION Fall 2009 ...  

E-Print Network [OSTI]

MSEE = Materials and Electrical Engineering. You may refer to the campus map for their locations. For MA 23100, there's a link (“Seating Arrangement”) in the ...

2009-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

DE-MA0002512  

Broader source: Energy.gov (indexed) [DOE]

Award No. 2. Modification No. 3. Effective Date Award No. 2. Modification No. 3. Effective Date 4. CFDA No. DE-MA0002512 03/27/2012 ASSISTANCE AGREEMENT 7. Period of Performance 6. Sponsoring Office 5. Awarded To Other Cooperative Agreement Grant test 10. Purchase Request or Funding Document No. 9. Authority 8. Type of Agreement 11. Remittance Address 12. Total Amount 13. Funds Obligated Govt. Share: $0.00 Cost Share : $0.00 Total : $0.00 This action: $0.00 Total : $0.00 test 14. Principal Investigator 15. Program Manager 16. Administrator test 19. Submit Reports To 18. Paying Office 17. Submit Payment Requests To 20. Accounting and Appropriation Data See Schedule 21. Research Title and/or Description of Project For the Recipient For the United States of America 22. Signature of Person Authorized to Sign

102

Effect of ion beam mixing on wear and friction of Fe?Ti multilayered structure on AISI 304 stainless steel  

Science Journals Connector (OSTI)

Dry sliding properties of ion beam mixed multilayered Fe?Ti structures deposited on AISI 304 stainless steel were studied over the composition range 0–100% Ti using samples with a linearly varying composition of constituents. Our measurements revealed that a ductilesurface was formed with good sliding properties over the wide composition range by ion beammixing of deposited layers. These beneficial effects were not obtained on as?deposited samples or by ion bombardment of either a substrate or pure iron layer deposited on a substrate. Thus it is concluded that both the ion beam processing and composition as well as the resulting microstructure are essential for improved tribology.

J?P. Hirvonen; M. Nastasi; J. W. Mayer

1986-01-01T23:59:59.000Z

103

Electric field and humidity effects on adsorbed water behavior on BaTiO3 ferroelectric domains studied by scanning probe microscopy  

E-Print Network [OSTI]

Electric field and humidity effects on adsorbed water behavior on BaTiO3 ferroelectric domains 2014; published online 28 August 2014) Distribution of the adsorbed water on BaTiO3 ferroelectric, which adsorb on the material surface, cause delayed cracking and fracture of ferroelectric ceramics.15

Volinsky, Alex A.

104

In-situ imaging of the nucleation and growth of epitaxial anatase TiO2(001) films on SrTiO3(001)  

SciTech Connect (OSTI)

The growth of TiO2 anatase films on Nb doped SrTiO3(001) by oxygen-assisted molecular beam epitaxy has been studied in-situ by scanning tunneling microscopy. We show that the initial growth follows the Stranski-Krastanov mode, where islands form on top of a wetting layer consisting of two monolayers (ML) of TiO2. The epitaxial islands subsequently nucleate and coalescence into large commonly-oriented crystallites. The (4x4) reconstruction observed by reflection high-energy electron diffraction (RHEED) is shown to result from the coexistence of individual (4x1) and (1x4) reconstructions present on different crystallite surfaces. The anatase grows in units of bilayers, resulting in a step height of 2 ML (~0.5 nm). This result explains the fact that the measured period of the RHEED specular-beam intensity oscillations corresponds to the time required for deposition of 2 ML. Ar ion sputtering and UHV annealing results in a transformation to coexisting (4x1) and (1x4) reconstructed terraces on individual crystallites, as commonly observed by ex-situ STM studies.

Du, Yingge; Kim, Dong Jun; Kaspar, Tiffany C.; Chamberlin, Sara E.; Lyubinetsky, Igor; Chambers, Scott A.

2012-09-30T23:59:59.000Z

105

Discovery and utilization of sorghum genes (Ma5/Ma6)  

DOE Patents [OSTI]

Methods and composition for the production of non-flowering or late flowering sorghum hybrid. For example, in certain aspects methods for use of molecular markers that constitute the Ma5/Ma6 pathway to modulate photoperiod sensitivity are described. The invention allows the production of plants having improved productivity and biomass generation.

Mullet, John E; Rooney, William L; Klein, Patricia E; Morishige, Daryl; Murphy, Rebecca; Brady, Jeff A

2012-11-13T23:59:59.000Z

106

Growth of single-crystalline rutile TiO2 nanorods on fluorine-doped tin oxide glass for organicinorganic  

E-Print Network [OSTI]

, 15] and CdS [2] have been explored and studied to overcome this shortcome, and used in organicGrowth of single-crystalline rutile TiO2 nanorods on fluorine-doped tin oxide glass for organic

Cao, Guozhong

107

Influence of anode area and electrode gap on the morphology of TiO2 nanotubes arrays  

Science Journals Connector (OSTI)

In order to fabricate the titanium dioxide (TiO2) nanotubes arrays which were used in the photocatalytic degradation of total volatile organic compounds (TVOC) by anodization, the influence of the electrode gap and anode area on the morphology ...

Min Wang; Li Jia; Shuangmei Deng

2013-01-01T23:59:59.000Z

108

A STUDY ON SOLUTION (THM) GROWN TI DOPED CdTe F. V. WALD and R. O. BELL  

E-Print Network [OSTI]

203 A STUDY ON SOLUTION (THM) GROWN TI DOPED CdTe F. V. WALD and R. O. BELL Mobil Tyco Solar Energy might, perhaps, expect somewhat different results. The growth was carried out by THM [3] with a furnace

Boyer, Edmond

109

Taught degree MA in Philosophy  

E-Print Network [OSTI]

Philosophy Taught degree MA in Philosophy 1 year full time/2 years part time This MA offers an advanced general grounding in philosophy, which forms a good basis for further research. It includes modules in both the analytic and continental traditions of philosophy, reflecting the wide range

Sussex, University of

110

MA Mortenson | Open Energy Information  

Open Energy Info (EERE)

Mortenson Mortenson Jump to: navigation, search Name MA Mortenson Place Minnesota Zip 55440-0710 Sector Solar, Wind energy Product Construction and building firm active in the installation of wind and solar farms. References MA Mortenson[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. MA Mortenson is a company located in Minnesota . References ↑ "MA Mortenson" Retrieved from "http://en.openei.org/w/index.php?title=MA_Mortenson&oldid=348551" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load)

111

Physisorption of N2, O2, and CO on Fully Oxidized TiO2(110)  

SciTech Connect (OSTI)

Physisorption of N2, O2 and CO was studied on fully oxidized TiO2(110) using beam reflection and temperature programmed desorption (TPD) techniques. Sticking coefficients for all three molecules are nearly equal (0.75 ± 0.05) and approximately independent of coverage suggesting that adsorption occurs via a precursor mediated mechanism. Excluding multilayer coverages, the TPD spectra for all three adsorbates exhibit three distinct coverage regimes that can be interpreted in accord with previous theoretical studies of N2 adsorption. At low coverages (0 to 0.5 N2/Ti4+), N2 molecules bind head-on to five-coordinated Ti4+ ions. The adsorption occurs preferentially on the Ti4+ sites that do not have neighboring adsorbates. This arrangement minimizes the repulsive interactions between the adsorbed molecules along the Ti4+ rows resulting in a relatively small shift of the TPD peak (105 ? 90 K) with increasing coverage. At higher N2 coverages (0 to 1.0 N2/Ti4+) the nearest-neighbor Ti4+ sites become occupied. The close proximity of the adsorbates results in strong repulsion thus giving rise to a significant shift of the TPD leading edges (90 ? 45 K) with increasing coverage. For N2/Ti4+ > 1, an additional low temperature peak (~ 43 K) is present and is ascribed to N2 adsorption on bridge-bonded oxygen rows. The results for O2 and CO are qualitatively similar. The repulsive adsorbate-adsorbate interactions largest for CO, most likely due to aligned CO dipole moments. The coverage dependent binding energies of O2, N2, and CO are determined by inverting TPD profiles.

Dohnalek, Zdenek; Kim, Jooho; Bondarchuk, Oleksander A.; White, J. M.; Kay, Bruce D.

2006-03-30T23:59:59.000Z

112

DOE - Office of Legacy Management -- Indian Orchard MA Site - MA 08  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Indian Orchard MA Site - MA 08 Indian Orchard MA Site - MA 08 FUSRAP Considered Sites Indian Orchard, MA Alternate Name(s): Chapman Valve Manufacturing Company Chapman Valve Site Crane Company MA.08-3 MA.08-4 Location: 203 Hampshire Street, Indian Orchard, Massachusetts MA.08-2 Historical Operations: Machined extruded natural uranium rods and supplied valves and other products to MED and AEC. Also machined natural uranium rods into slugs for Brookhaven National Laboratory. MA.08-6 MA.08-7 MA.08-8 MA.08-14 Eligibility Determination: Eligible MA.08-2 Radiological Survey(s): Assessment Survey, Verification Survey MA.08-11 MA.08-12 Site Status: Certified - Certification Basis, Federal Register Notice included. MA.08-13 MA.08-14 Long-term Care Requirements: Long-Term Surveillance and Maintenance Requirements for Remediated FUSRAP Sites S07566_FUSRAP

113

MA - Office of Management - Energy Conservation Plan  

Broader source: Energy.gov (indexed) [DOE]

MA Energy Conservation Plan MA Energy Conservation Plan January 2010 1 Office of Management Office-Level Energy Conservation Plan January 2010 I. BACKGROUND This energy conservation plan represents an effort to reduce energy consumption within Office of Management (MA) office spaces and to increase employee awareness of and participation in energy conservation measures. II. SCOPE The plan and procedures in this document apply to all Office of Management (MA) office suites in the Forrestal and Germantown Facilities as well as the 950 L'Enfant Plaza Building. The actions and procedures set forth in this plan apply to each separate MA office suite as follows: MA-1: 4A-107 MA-43: 1F-039 MA-70: 7E-074 MA-1.1: 7E-028 MA-43: 1F-037 MA-70: 7E-054 MA-30: GH-081 MA-43:

114

Category:Boston, MA | Open Energy Information  

Open Energy Info (EERE)

Boston, MA Boston, MA Jump to: navigation, search Go Back to PV Economics By Location Media in category "Boston, MA" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Boston MA Massachusetts Electric Co.png SVFullServiceRestauran... 67 KB SVHospital Boston MA Massachusetts Electric Co.png SVHospital Boston MA M... 65 KB SVLargeHotel Boston MA Massachusetts Electric Co.png SVLargeHotel Boston MA... 65 KB SVLargeOffice Boston MA Massachusetts Electric Co.png SVLargeOffice Boston M... 65 KB SVMediumOffice Boston MA Massachusetts Electric Co.png SVMediumOffice Boston ... 65 KB SVMidriseApartment Boston MA Massachusetts Electric Co.png SVMidriseApartment Bos... 65 KB SVOutPatient Boston MA Massachusetts Electric Co.png SVOutPatient Boston MA...

115

Effect of Ti seed layers on structure of self-organized epitaxial face-centered-cubic-Ag(001) oriented nanodots  

SciTech Connect (OSTI)

The influence of Ti seed layers on the structure of self-organized Ag nanodots, obtained with a Ti seed-layer-assisted thermal agglomeration method, has been investigated. The samples were grown on MgO(001) single crystal substrates by RF magnetron sputter deposition. The samples were deposited at room temperature and post-annealed at 350 °C for 4 h while maintaining the chamber vacuum conditions. The results of atomic force microscopy (AFM) observations indicated that the insertion of the Ti seed layer (0.6–5.0 nm) between the MgO substrate and Ag layer promotes the agglomeration process, forming the nanodot array. Comparisons between the AFM images revealed that the size of the Ag nanodots was increased with an increase in the Ti seed layer thickness. The atomic concentration of the film surface was confirmed by X-ray photoelectron spectroscopy (XPS). The XPS result suggested that the nanodot surface mainly consisted of Ag. Moreover, X-ray diffraction results proved that the initial deposition of the Ti seed layer (0.6–5.0 nm) onto MgO(001) prior to the Ag deposition yielded high-quality fcc-Ag(001) oriented epitaxial nanodots. The optical absorbance spectra of the fabricated Ag nanodots with various Ti seed layer thicknesses were obtained in the visible light range.

Kamiko, M.; Nose, K. [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan)] [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan); Suenaga, R.; Kyuno, K. [Department of Material Science, Shibaura Institute of Technology, 3-7-5 Toyosu, Koto-ku, Tokyo 135-8548 (Japan)] [Department of Material Science, Shibaura Institute of Technology, 3-7-5 Toyosu, Koto-ku, Tokyo 135-8548 (Japan); Koo, J.-W.; Ha, J.-G. [Department of Electronic Materials Engineering, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of)] [Department of Electronic Materials Engineering, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of)

2013-12-28T23:59:59.000Z

116

Effects of processing on texture, microstructure and related properties of TiAl alloys  

SciTech Connect (OSTI)

Depending on factors such as processing conditions, stoichiometry and initial microstructure a variety of different textures has been found in TiAl alloys. They give insight into the origin of the generation of preferred orientations during solidification and recrystallization and by rotation of orientations during deformation. A comparison of measured and simulated textures on the basis of current models of polycrystal deformation leads to general conclusions about the crystallography of slip and on the strength of the different slip systems. The knowledge of texture is profitable for an understanding as well as for an explanation of the anisotropy of mechanical properties such as elastic constants, plastic behavior and fracture parameters.

Mecking, H.; Hartig, C. [Technical Univ. Hamburg-Harburg, Hamburg (Germany)

1995-12-31T23:59:59.000Z

117

Co-doped Anatase TiO Heteroepitaxy on Si(001). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

layer, followed by deposition of a thin SrTiO&8323; buffer layer. Using ½ ML Sr metal to form the silicide allowed the deposition of 10 ML SrTiO&8323; without oxidation...

118

Adsorption and Reaction of CO and CO{sub 2} on Oxidized and Reduced SrTiO{sub 3} (100) Surfaces  

SciTech Connect (OSTI)

The adsorption and reaction of CO and CO{sub 2} on oxidized and reduced SrTiO{sub 3}(100) surfaces have been studied using temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy (XPS). XPS results indicate that the fully oxidized and vacuum annealed SrTiO{sub 3}(100) surfaces are nearly defect-free with predominantly Ti{sup 4+} ions whereas the sputter-reduced surfaces contain substantial amounts of defects ({approx} 40% reduced Ti sites). Both CO and CO{sub 2} are found to adsorb weakly on the oxidized SrTiO{sub 3}(100) surfaces. The desorption activation energies of CO and CO{sub 2} from the oxidized SrTiO{sub 3}(100) surfaces are 38 and 32 kJmol{sup -1}, respectively, following adsorption at 110 K. On sputter-reduced surfaces, enhanced reactivity of CO and CO{sub 2} is observed due to the presence of oxygen vacancy sites, causing dissociative adsorption of these molecules. Our studies indicate that CO and CO{sub 2} molecules exhibit relatively weaker binding to SrTiO{sub 3}(100) compared with TiO{sub 2}(110) and TiO{sub 2}(100) surfaces. These differences in reactivity can be attributed primarily to the influence of the Sr cations on the electronic structure of the mixed oxide of SrTiO{sub 3}.

Azad, Samina; Engelhard, Mark H.; Wang, Li Q.

2005-05-26T23:59:59.000Z

119

CAES MaCS Home  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is largely made possible through its partnership with the Advanced Test Reactor National Scientific User Facility (ATR NSUF). MaCS is complementary to the Boise State Center for...

120

MA Org Chart, January 15, 2015  

Energy Savers [EERE]

MA-66 MA-60 Paul Bosco, Director Pat Ferraro, Deputy Director Jay Glascock, Senior Advisor MA-80 Office of the Ombudsman Rita R. Franklin, Director Cathy Barchi, Dep. Director...

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Comment on "Structure and dynamics of liquid water on rutile TiO2(110)  

SciTech Connect (OSTI)

Liu and co-workers [Phys. Rev. B 82, 161415 (2010)] discussed the long-standing debate regarding whether H2O molecules on the defect-free (110) surface of rutile ( -TiO2) sorb associatively, or there is dissociation of some or all first-layer water to produce hydroxyl surface sites. They conducted static density functional theory (DFT) and DFT molecular dynamics (DFT-MD) investigations using a range of cell configurations and functionals. We have reproduced their static DFT calculations of the influence of crystal slab thickness on water sorption energies. However, we disagree with several assertions made by these authors: (a) that second-layer water structuring and hydrogen bonding to surface oxygens and adsorbed water molecules are weak ; (b) that translational diffusion of water molecules in direct contact with the surface approaches that of bulk liquid water; and (c) that there is no dissociation of adsorbed water at this surface in contact with liquid water. These assertions directly contradict our publishedwork, which compared synchrotron x-ray crystal truncation rod, second harmonic generation, quasielastic neutron scattering, surface charge titration, and classical MD simulations of rutile (110) single-crystal surfaces and (110)-dominated powders in contact with bulk water, and (110)-dominated rutile nanoparticles with several monolayers of adsorbed water.

Wesolowski, David J [ORNL; Sofo, Jorge O. [Pennsylvania State University; Bandura, Andrei V. [St. Petersburg State University, St. Petersburg, Russia; Zhang, Zhan [Argonne National Laboratory (ANL); Mamontov, Eugene [ORNL; Predota, M. [University of South Bohemia, Czech Republic; Kumar, Nitin [ORNL; Kubicki, James D. [Pennsylvania State University; Kent, Paul R [ORNL; Vlcek, Lukas [ORNL; Machesky, Michael L. [Illinois State Water Survey, Champaign, IL; Fenter, Paul [Argonne National Laboratory (ANL); Cummings, Peter T [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Skelton, A A [Vanderbilt University; Rosenqvist, Jorgen K [ORNL

2012-01-01T23:59:59.000Z

122

Probing Defect Sites on TiO_2 with H_3 Re_3 (CO)_12 : Spectroscopic Characterization of the Surface Species  

SciTech Connect (OSTI)

Samples of the anatase phase of titania were treated under vacuum to create Ti3+ surface-defect sites and surface O- and O2- species (indicated by electron paramagnetic resonance (EPR) spectra), accompanied by the disappearance of bridging surface OH groups and the formation of terminal Ti3+OH groups (indicated by IR spectra). EPR spectra showed that the probe molecule [Re3(CO)12H3] reacted preferentially with the Ti3+ sites, forming Ti4+ sites with OH groups as the [Re3(CO)12H3] was adsorbed. Extended X-ray absorption fine structure (EXAFS) spectra showed that these clusters were deprotonated upon adsorption, with the triangular metal frame remaining intact; EPR spectra demonstrated the simultaneous removal of surface O- and O2- species. The data determined by the three complementary techniques form the basis of a schematic representation of the surface chemistry. According to this picture, during evacuation at 773 K, defect sites are formed on hydroxylated titania as a bridging OH group is removed, forming two neighboring Ti3+ sites, or, when a Ti4+O bond is cleaved, forming a Ti3+ site and an O- species, with the Ti4+OH group being converted into a Ti3+OH group. When the probe molecule [Re3(CO)12H3] is adsorbed on a titania surface with Ti3+ defect sites, it reacts preferentially with these sites, becoming deprotonated, removing most of the oxygen radicals, and healing the defect sites.

Suriye,K.; Lobo-Lapidus, R.; Yeagle, G.; Praserthdam, P.; Britt, R.; Gates, B.

2008-01-01T23:59:59.000Z

123

Electrodeposition of U and Pu on Thin C and Ti Substrates  

SciTech Connect (OSTI)

Physics experiments aimed at deducing key parameters for use in a variety of programs critical to the mission of the National Laboratories require actinide targets placed onto various substrates. The target material quantity and the substrate desired depend upon the type of experiment being designed. The physicist(s) responsible for the experimental campaign will consult with the radiochemistry staff as to the feasibility of producing a desired target/substrate combination. In this report they discuss the production of U and Pu targets on very thin C and Ti substrates. The techniques used, plating cells designed for, tips, and limits is discussed.

Henderson, R A; Gostic, J M

2010-05-19T23:59:59.000Z

124

Electrically insulating films deposited on V-4%Cr-4%Ti by reactive CVD  

SciTech Connect (OSTI)

In the design of liquid-metal blankets for magnetic fusion reactors, corrosion resistance of structural materials and the magnetohydrodynamic forces and their influence on thermal hydraulics and corrosion are major concerns. Electrically insulating CaO films deposited on V-4%Cr-4%Ti exhibit high-ohmic insulator behavior even though a small amount of vanadium from the alloy become incorporated into the film. However, when vanadium concentration in the film is > 15 wt.%, the film becomes conductive. When the vanadium concentration is high in localized areas, a calcium vanadate phase that exhibits semiconductor behavior can form. The objective of this study is to evaluate electrically insulating films that were deposited on V-4%Cr-4%Ti by a reactive chemical vapor deposition (CVD) method. To this end, CaO and Ca-V-O coatings were produced on vanadium alloys by CVD and by a metallic-vapor process to investigate the electrical resistance of the coatings. The authors found that the Ca-V-O films exhibited insulator behavior when the ratio of calcium concentration to vanadium concentration R in the film > 0.9, and semiconductor or conductor behavior when R < 0.8. However, in some cases, semiconductor behavior was observed when CaO-coated samples with R > 0.98 were exposed in liquid lithium. Based on these studies, they conclude that semiconductor behavior occurs if a conductive calcium vanadate phase is present in localized regions in the CaO coating.

Park, J.H.

1998-04-01T23:59:59.000Z

125

MA Org Chart, October 9, 2014  

Broader source: Energy.gov (indexed) [DOE]

Montoya, Dep. Director Office of Administrative Management and Support Office of Logistics and Facility Operations Office Travel Management MA-45 Umeki Thorne, Director MA-42...

126

MA Org Chart, October 20, 2014  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Montoya, Dep. Director Office of Administrative Management and Support Office of Logistics and Facility Operations Office Travel Management MA-45 Umeki Thorne, Director MA-42...

127

Performance Degradation of TiN-and TiC-deposited AISI316 bipolar plates for proton exchange membrane fuel cells  

Science Journals Connector (OSTI)

TiN and TiC were deposited on AISI316 bipolar plates for proton exchange membrane fuel cells (PEMFCs) and their effects on the corrosion resistance and overall cell performance were investigated. TiN with a Ti...

Hee Yeol Lee; Jae Woong Choi; Gil Ho Hwang…

2006-04-01T23:59:59.000Z

128

In-operando hard X-ray photoelectron spectroscopy study on the impact of current compliance and switching cycles on oxygen and carbon defects in resistive switching Ti/HfO{sub 2}/TiN cells  

SciTech Connect (OSTI)

In this study, direct experimental materials science evidence of the important theoretical prediction for resistive random access memory (RRAM) technologies that a critical amount of oxygen vacancies is needed to establish stable resistive switching in metal-oxide-metal samples is presented. In detail, a novel in-operando hard X-ray photoelectron spectroscopy technique is applied to non-destructively investigates the influence of the current compliance and direct current voltage sweep cycles on the Ti/HfO{sub 2} interface chemistry and physics of resistive switching Ti/HfO{sub 2}/TiN cells. These studies indeed confirm that current compliance is a critical parameter to control the amount of oxygen vacancies in the conducting filaments in the oxide layer during the RRAM cell operation to achieve stable switching. Furthermore, clear carbon segregation towards the Ti/HfO{sub 2} interface under electrical stress is visible. Since carbon impurities impact the oxygen vacancy defect population under resistive switching, this dynamic carbon segregation to the Ti/HfO{sub 2} interface is suspected to negatively influence RRAM device endurance. Therefore, these results indicate that the RRAM materials engineering needs to include all impurities in the dielectric layer in order to achieve reliable device performance.

Sowinska, Malgorzata, E-mail: sowinska@ihp-microelectronics.com; Bertaud, Thomas; Walczyk, Damian; Calka, Pauline; Walczyk, Christian [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Thiess, Sebastian [Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg (Germany); Alff, Lambert [Institute of Materials Science, Technische Universität Darmstadt, 64287 Darmstadt (Germany); Schroeder, Thomas [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Brandenburgische Technische Universität, Konrad-Zuse-Strasse 1, 03046 Cottbus (Germany)

2014-05-28T23:59:59.000Z

129

Influence of ultraviolet light irradiation on corrosion behavior of weathering steel with and without TiO2-coating in 3 mass% NaCl solution  

Science Journals Connector (OSTI)

In this study the influence of ultraviolet (UV) light on the corrosion behavior of weathering steel with and without TiO2 coating has been investigated in 3% NaCl solution, using anodic polarization, dipping and dropping tests. In polarization tests a large negative shift of corrosion potential appeared for the TiO2-coated specimen in UV light. The weight loss of the steels with and without TiO2 film increased under UV light in the dipping test, while they decreased in the dropping test. The rust formed on the weathering steel showed a semiconductor like behavior, similar to that shown by TiO2 film.

Manal G. Mahmoud; Rongguang Wang; Masahiko Kato; Keijiro Nakasa

2005-01-01T23:59:59.000Z

130

Ceramic thick film humidity sensor based on MgTiO{sub 3} + LiF  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • The fabricated sensor based on MgTiO{sub 3} + LiF materials used the spin coating technology. • The response time is 70 s to detect variation between 5 and 95% relative humidity. • The addition of Scleroglucan controls the viscosity and decreases the roughness of thick film surface. • This humidity sensor is a promising, low-cost, high-quality, reliable ceramic films, that is highly sensitive to humidity. - Abstract: The feasibility of humidity sensor, consisting of a thick layer of MgTiO{sub 3}/LiF materials on alumina substrate, was studied. The thermal analysis TGA-DTGA and dilatometric analysis worked out to confirm the sintering temperature. An experimental plan was applied to describe the effects of different parameters in the development of the thick film sensor. Structural and microstructural characterizations of the developed thick film were made. Rheological study with different amounts of a thickener (scleroglucan “sclg”), showing the behavior variation, as a function of sclg weight % was illustrated and rapprochement with the results of thickness variation as a function of angular velocity applied in the spin coater. The electrical and dielectric measurements confirmed the sensitivity of the elaborated thick film against moisture, along with low response time.

Kassas, Ahmad, E-mail: a.kassas.mcema@ul.edu.lb [Faculty of Agricultural Engineering and Veterinary Medicine, Laboratory of Materials, Catalysis, Environment and Analytical Methods (MCEMA), Faculty of Sciences and Doctoral School of Sciences and Technology (EDST), Lebanese University, Hariri Campus, Hadath, Beirut (Lebanon); Laboratoire Universitaire des Sciences Appliquées de Cherbourg (LUSAC), 50130 Cherbourg-Octeville (France); Bernard, Jérôme; Lelièvre, Céline; Besq, Anthony; Guhel, Yannick; Houivet, David; Boudart, Bertrand [Laboratoire Universitaire des Sciences Appliquées de Cherbourg (LUSAC), 50130 Cherbourg-Octeville (France); Lakiss, Hassan [Faculty of Agricultural Engineering and Veterinary Medicine, Laboratory of Materials, Catalysis, Environment and Analytical Methods (MCEMA), Faculty of Sciences and Doctoral School of Sciences and Technology (EDST), Lebanese University, Hariri Campus, Hadath, Beirut (Lebanon); Faculty of Engineering, Section III, Hariri Campus, Hadath, Beirut (Lebanon); Hamieh, Tayssir [Faculty of Agricultural Engineering and Veterinary Medicine, Laboratory of Materials, Catalysis, Environment and Analytical Methods (MCEMA), Faculty of Sciences and Doctoral School of Sciences and Technology (EDST), Lebanese University, Hariri Campus, Hadath, Beirut (Lebanon)

2013-10-15T23:59:59.000Z

131

Photoelectrochemical water splitting and simultaneous photoelectrocatalytic degradation of organic pollutant on highly smooth and ordered TiO{sub 2} nanotube arrays  

SciTech Connect (OSTI)

The photoelectrochemical water splitting and simultaneous photoelectrocatalytic degradation of organic pollutant were achieved on TiO{sub 2} nanotube electrodes with double purposes of environmental protection and renewable energy production under illumination of simulated solar light. The TiO{sub 2} nanotube arrays (TiO{sub 2} NTs) were fabricated by a two-step anodization method. The TiO{sub 2} NTs prepared in two-step anodization process (2-step TiO{sub 2} NTs) showed much better surface smoothness and tube orderliness than TiO{sub 2} NTs prepared in one-step anodization process (1-step TiO{sub 2} NTs). In the photoelectrochemical water splitting and simultaneous photoelectrocatalytic decomposition process, the 2-step TiO{sub 2} NTs electrode showed both highest photo-conversion efficiency of 1.25% and effective photodecomposition efficiency with existing of methylene blue (MB) as sacrificial agent and as pollutant target. Those results implied that the highly ordered nanostructures provided direct pathway and uniform electric field distribution for effective charges transfer, as well as superior capabilities of light harvesting. - Graphical Abstract: The photoelectrochemical water splitting for hydrogen generation and simultaneous photoelectrocatalytic degradation of organic pollutant (methylene blue) were achieved on TiO{sub 2} nanotube electrodes with double purposes of environmental protection and renewable energy production under illumination of simulated solar light. Highlights: Black-Right-Pointing-Pointer TiO{sub 2} nanotube arrays were fabricated by a two-step anodization method. Black-Right-Pointing-Pointer Hydrogen generation and organic pollutant degradation were achieved on TiO{sub 2} NTs. Black-Right-Pointing-Pointer Highest photoconversion efficiency of 1.25% was achieved. Black-Right-Pointing-Pointer Increasing orderliness will increase photocatalytic activity of TiO{sub 2} NTs.

Wu Hongjun [College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318 (China); Institute of Basic Energy Science and Technology, George Washington University, VA 20147 (United States); Zhang Zhonghai, E-mail: zhonghaizhangwill@gmail.com [Institute of Basic Energy Science and Technology, George Washington University, VA 20147 (United States); Graduate School of Science and Engineering for Research, University of Toyama, 3190 Gofuku, Toyama 930-8555 (Japan)

2011-12-15T23:59:59.000Z

132

DOE - Office of Legacy Management -- Tufts College - MA 0-05  

Office of Legacy Management (LM)

Tufts College - MA 0-05 Tufts College - MA 0-05 FUSRAP Considered Sites Site: TUFTS COLLEGE ( MA.0-05 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Medford , Massachusetts MA.0-05-1 Evaluation Year: 1987 MA.0-05-1 Site Operations: Research and development using only small quantities of radioactive material. MA.0-05-1 Site Disposition: Eliminated - Potential for contamination considered remote based on limited quantities of material handled MA.0-05-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MA.0-05-1 Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to TUFTS COLLEGE MA.0-05-1 - Aerospace Letter; Young to Wallo; Subject: Elimination

133

MA HEAT Loan Overview  

Broader source: Energy.gov [DOE]

Presents information on the success of Massachusetts's HEAT loan offerings and how the financing tool is funded.

134

Fabrication of TiO2 film with different morphologies on Ni anode and application in photoassisted water electrolysis  

Science Journals Connector (OSTI)

The anode of an alkaline electrolytic cell for water electrolysis was modified by TiO2 photocatalysts with different morphologies. The water electrolysis was coupled with photocatalytic decomposition of water by irradiation of UV light on the modified anode. And a feasible process for the hydrogen production of water electrolysis assisted by photocatalysis (WEAP) was proposed and experimentally confirmed. The results show that the highly ordered, vertically oriented tubular arrays structure on Ni anode surface has better hydrogen production performance than random TiO2. In WEAP process, the maximum rate of hydrogen production is 2.77 ml/(h*cm2) when the anode modified by ordered TiO2 nanotube arrays, compared to traditional alkaline electrolytic cell for water electrolysis with Ni anode, H2-production rate increased by 139%.

Hongbo He; Aiping Chen; Hui Lv; Haijun Dong; Ming Chang; Chunzhong Li

2013-01-01T23:59:59.000Z

135

Thermal Processing and Characterizations of Dye-Sensitized Solar Cells Based on Nanostructured TiO2  

Science Journals Connector (OSTI)

Thermal Processing and Characterizations of Dye-Sensitized Solar Cells Based on Nanostructured TiO2 ... This work reports an extensive study about the effects of thermal treatments on the performance of TiO2-based dye-sensitized solar cells. ... The current–voltage characteristics were measured using an Advantest R6243 current/voltage unit after a 10 min wait for achieving thermal equilibrium under AM 1.5G, simulated solar light of 100 mW cm–2 and irradiated from a WACOM super solar simulator. ...

Filippo Fabbri; Francesca Detto; Nicola Armani; Norifusa Satoh; Tullo Besagni; Maura Pavesi; Giancarlo Salviati

2013-01-04T23:59:59.000Z

136

Fretting Wear Study on Micro-Arc Oxidation TiO2 Coating on TC4 Titanium Alloys in Simulated Body Fluid  

Science Journals Connector (OSTI)

Tribological properties of TiO2 coatings synthesized by micro-arc oxidation (MAO) on the surface of TC4...2 coatings presented good tribological properties with lower friction coefficient in SBF. Less wear volume...

Guanghong Zhou; Hongyan Ding; Yue Zhang; Aihui Liu; Yuebin Lin…

2010-12-01T23:59:59.000Z

137

Effects of hydrochloric acid treatment of TiO{sub 2} nanoparticles/nanofibers bilayer film on the photovoltaic properties of dye-sensitized solar cells  

SciTech Connect (OSTI)

Highlights: ? The TiO{sub 2} nanoparticles/TiO{sub 2} nanofibers bilayer film was fabricated for DSSC. ? The effects of HCl treated TiO{sub 2} on the performance of DSSC were investigated. ? The potential methods of improving conversion efficiency are suggested. - Abstract: The TiO{sub 2} nanoparticles/nanofibers bilayer film has been fabricated via spin coating and electrospinning followed by calcination. The TiO{sub 2} bilayer film with thickness of about 6.0 ?m is composed of anatase TiO{sub 2} phase. Dye-sensitized solar cells (DSSC) were assembled by hydrochloric acid (HCl) treated TiO{sub 2} film. The results of the photocurrent action spectra, electrochemical impedance spectroscopy (EIS), and I–V curves showed that each photovoltaic parameter of DSSC increased with the concentration of HCl increasing, and reached a maximum value and afterwards decreased. The maximum incident monochromatic photo-to-electron conversion efficiency (at 350 nm) and maximum overall conversion efficiency (?) of 0.05 M HCl treated TiO{sub 2} based DSSC were enhanced to 48.0% and 4.75%, which were respectively increased by 14% and 6.3% than those of DSSC based on untreated TiO{sub 2} film.

Song, Lixin; Du, Pingfan; Shao, Xiaoli; Cao, Houbao; Hui, Quan [Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018 (China); Xiong, Jie, E-mail: jxiong@zstu.edu.cn [Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018 (China)

2013-03-15T23:59:59.000Z

138

MA Org Chart, August 01, 2013  

Broader source: Energy.gov (indexed) [DOE]

MA-1 MA-1 Ingrid Kolb, Director Chief Acquisition Officer (Vacant) Laurie Morman, Chief of Staff Office of Resource Management and Planning MA-1.1 Marilyn Dillon, Director Willie Mae Ingram, Dep. Director (Acting) Office of Acquisition & Project Management Paul Bosco, Director David Boyd, Dep. Director Jay Glascock, Senior Advisor Office of Policy MA-63 Berta Schreiber Director Office of Contract Management Patrick Ferraro Director Office of Project Management Michael Peek Director Office of Headquarters Procurement Services Mark Brady Director Office of Property Management Carmelo Melendez Director MA-60 Office of Scheduling and Advance Anthony Rediger, Director James Covey, Dep. Director MA-10 MA-30 MA-40 MA-70 MA-90 Office of Aviation

139

MA 692, Spring 2011  

E-Print Network [OSTI]

J. W. H. Liu, The multifrontal method for sparse matrix solution: Theory and practice, SIAM ... Slides: Jim Demmlel's lecture notes on multigrid; Matlab codes: Jim ... of nonnegative symmetric matrices and its application to graph theory, Czech.

140

Structure and dynamics of liquid water on rutile TiO2(110) Li-Min Liu, Changjun Zhang, Geoff Thornton, and Angelos Michaelides  

E-Print Network [OSTI]

those between water and titanium dioxide TiO2 . Water-TiO2 interfaces are relevant to photocatalysis on which adsorption state the water molecules are in at the interface: dissociated or molecular? Many, density-functional theory DFT studies predict either molecular or dissociative adsorption on the perfect

Alavi, Ali

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

XAFS Study of Active Tungsten Species on WO3/TiO2 as a Catalyst for Photo-SCR  

SciTech Connect (OSTI)

The activity of the photo-assisted selective catalytic reduction of NO with NH3 (photo-SCR) was enhanced by the addition of WO3 to TiO2. From the result of XAFS analysis, the W species on TiO2 had a WO4 tetrahedral structure and agglutination took place as the addition of WO3 was increased. We conclude that the isolated W species enhances the surface acidity and photo-SCR activity whereas the agglutinated W species is an inactive species.

Yamazoe, Seiji; Masutani, Yasuyuki; Shishido, Tetsuya; Tanaka, Tsunehiro [Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 615-8510 (Japan)

2007-02-02T23:59:59.000Z

142

Growing TiO2 nanowires on the surface of graphene sheets in supercritical CO2: characterization and photoefficiency  

Science Journals Connector (OSTI)

Tremendous interest exists towards synthesizing nanoassemblies for dye-sensitized solar cells (DSSCs) using earth-abundant and -friendly materials with green synthetic approaches. In this work, high surface area TiO2 nanowire arrays were grown on the surface of functionalized graphene sheets (FGSs) containing ?COOH functionalities acting as a template by using a sol–gel method in the green solvent, supercritical carbon dioxide (scCO2). The effect of scCO2 pressure (1500, 3000 and 5000 psi), temperature (40, 60 and 80?°C), acetic acid/titanium isopropoxide monomer ratios (HAc/TIP = 2, 4 and 6), functionalized graphene sheets (FGSs)/TIP weight ratios (1:20, 1:40 and 1:60 w/w) and solvents (EtOH, hexane) were investigated. Increasing the HAc/TIPweight ratio from 4 to 6 in scCO2 resulted in increasing the TiO2 nanowire diameter from 10 to 40 nm. Raman and high resolution XPS showed the interaction of TiO2 with the ?COOH groups on the surface of the graphene sheets, indicating that graphene acted as a template for polycondensation growth. UV–vis diffuse reflectance and photoluminescence spectroscopy showed a reduction in titania's bandgap and also a significant reduction in electron–hole recombination compared to bare TiO2 nanowires. Photocurrent measurements showed that the TiO2nanowire/graphene composites prepared in scCO2 gave a 5? enhancement in photoefficiency compared to bare TiO2 nanowires.

Nasrin Farhangi; Yaocihuatl Medina-Gonzalez; Rajib Roy Chowdhury; Paul A Charpentier

2012-01-01T23:59:59.000Z

143

Development and Characterization of Hard and Wear Resistant MMC Coating on Ti-6Al-4V Substrate by Laser Cladding  

Science Journals Connector (OSTI)

Abstract Ti-6Al-4V, due to its high specific strength and resistance to corrosion, is one of the highly useful materials in aerospace, automobile and chemical industries. Poor hardness and wear resistance properties restrict its further applications. So surface modification of Ti-6Al-4V is necessary surface to enhance its tribological properties. Multi-phase and multi component coating development is one of the present research trends in surface engineering arena. In the present study it was attempted to develop a multi-component coating by laser cladding process using a pre-placed powder mixture containing Ni5Al (50 vol%) + hBN (10 vol%) + B4C (20 vol%) + SiC (20 vol%) on substrate of Ti-6Al-4V to improve its tribological performance. A nano-structured coating was formed with micro hardness (780 HV0.05). X-ray diffraction (XRD) identified the presence of compounds like TiC, BN, TiB2, SiC, and intermetallics of Ni-Ti in the coating. The wear behaviour of the composite coating was assessed by ball on disc type wear and friction monitor at 10 N load at 300 RPM taking a track diameter of 5 mm. Specific wear rate and coefficient of friction (?) were found to vary from 0.6E-12 to 2.2E-12 m3/N-m and from 0.15 to 0.45, respectively, due to rubbing of coated surface against tungsten carbide ball. The microstructure was explored by Scanning Electron Microscopy (SEM).

Mandeep Dhanda; Barun Haldar; P. Saha

2014-01-01T23:59:59.000Z

144

WIND DATA REPORT Nantucket, MA  

E-Print Network [OSTI]

. Rogers Anthony F. Ellis July 12, 2006 Report template version 1.3 Renewable Energy Research Laboratory Research Laboratory (RERL) at the University of Massachusetts, Amherst in the course of performing work 12, 2006 Renewable Energy Research Laboratory Page 1 University of Massachusetts, Amherst Amherst, MA

Massachusetts at Amherst, University of

145

WIND DATA REPORT Wellfleet, MA  

E-Print Network [OSTI]

by the Renewable Energy Research Laboratory (RERL) at the University of Massachusetts, Amherst in the course, 2007 Renewable Energy Research Laboratory Page 1 University of Massachusetts, Amherst Amherst, MA 01003. Manwell Anthony L. Rogers Anthony F. Ellis May 2, 2007 Report template version 3.0 Renewable Energy

Massachusetts at Amherst, University of

146

WIND DATA REPORT Nantucket, MA  

E-Print Network [OSTI]

by the Renewable Energy Research Laboratory (RERL) at the University of Massachusetts, Amherst in the course L. Rogers Anthony F. Ellis March 30, 2006 Report template version 1.3 Renewable Energy Research Laboratory University of Massachusetts, Amherst 160 Governors Drive, Amherst, MA 01003 www

Massachusetts at Amherst, University of

147

Induction of Cytotoxicity by Photoexcited TiO2 Particles  

Science Journals Connector (OSTI)

...TiO2 in the suspension was measured with combustion analysis. The TiO2 aqueous suspension...photoexcited TiO2 particles. it did not produce heat at the irradiated site. Since TiO2 alone...Heterogeneous photocatalytic oxidation of hydrocarbons on platinized TiO2 powders. J. Phys...

Ruxiong Cai; Yoshinobu Kubota; Taro Shuin; Hideki Sakai; Kazuhito Hashimoto; and Akira Fujishima

1992-04-15T23:59:59.000Z

148

Influence of Si content on microstructure of TiAl alloys  

SciTech Connect (OSTI)

A systematic study of four ternary TiAl-based alloys with constant Ti content of 52.2 at. % and variable Si content ranging from 0.3 to 2.7 at. % (Al in balance) was conducted. The alloys were prepared from elemental powders via a route including powder mixing, precompaction, cold extrusion, and reactive hot-isostatic pressing. All investigated alloys contain the intermetallic compounds {gamma}-TiAl, {alpha}{sub 2}-Ti{sub 3}Al, and {zeta}-Ti{sub 5}(Si,Al){sub 3}. The microstructure can be described as a duplex structure (i.e., lamella {gamma}/{alpha}{sub 2} regions distributed in a {gamma} matrix) containing {zeta} precipitates. With increasing Si content, the number of primary {zeta} precipitates increased and the {gamma} grain size became finer while the lamellar volume fraction decreased slightly.

Hsu, F.Y.; Klaar, H.J. [Aachen Univ. of Technology (Germany). Central Lab. of Electron Microscopy] [Aachen Univ. of Technology (Germany). Central Lab. of Electron Microscopy; Wang, G.X. [Zhejiang Univ., Hangzhou (China)] [Zhejiang Univ., Hangzhou (China); Dahms, M. [GKSS Research Center, Geesthacht (Germany)] [GKSS Research Center, Geesthacht (Germany)

1996-04-01T23:59:59.000Z

149

On the Liquid/Solid Phase Equilibria in the Al-Rich Corner of the Al-Si-Ti Ternary System  

E-Print Network [OSTI]

On the Liquid/Solid Phase Equilibria in the Al-Rich Corner of the Al-Si-Ti Ternary System O; published online February 5, 2014) The nature of liquid-solid phase equilibria in the Al-rich corner of the Al-Si-Ti system are determined by drawing three isothermal sections at 620, 680 and 727 °C

Paris-Sud XI, Université de

150

Study of Interfacial Charge-Transfer Complex on TiO2 Particles in Aqueous Suspension by Second-Harmonic Generation  

E-Print Network [OSTI]

/mol. 1. Introduction Titanium dioxide (TiO2) is a wide band-gap semiconductor having two common crystal, the adsorption isotherm of catechol on the colloidal TiO2 suspension was obtained and gave an excellent fit to the Langmuir adsorption model. From this, we infer the free energy of the adsorption to be G° ) -6.8 kcal

Eisenthal, Kenneth B.

151

Synthesis of carbon nanocoil forests on BaSrTiO3 substrates with the aid of a Sn catalyst  

E-Print Network [OSTI]

Synthesis of carbon nanocoil forests on BaSrTiO3 substrates with the aid of a Sn catalyst Jingyu route for the Sn-assisted synthesis of carbon nanocoils (CNCs) by chemical vapor deposition of acetylene catalyst for CNC synthesis in conjunction with either perov- skite oxides (BST) or transition metals (Fe

Castell, Martin

152

Heterogeneous deposition of Cu2O nanoparticles on TiO2 nanotube array films in organic solvent  

Science Journals Connector (OSTI)

A novel method for decoration of anodic TiO2 nanotube array films (NAFs) with Cu2O nanoparticles has been reported. The method is based on the reduction of Cu(II) in a mixture of ethylene glycol and N, N-dimethylformamide at 120°C ...

Xinwen Huang; Zongjian Liu

2013-01-01T23:59:59.000Z

153

Evidence for the Predominance of Subsurface Defects on Reduced Anatase TiO2101 Yunbin He,1  

E-Print Network [OSTI]

numbers: 68.47.Gh, 68.35.Dv, 68.37.Ef Titanium dioxide, TiO2, finds applications in a wide range on well-characterized anatase sur- faces are available. STM [13] and adsorption [14] experiments indicated

Diebold, Ulrike

154

TEM and HAADF-STEM study of a Au catalyst supported on a TiO2 nano-rod  

Science Journals Connector (OSTI)

......gas chromatography. Au/TiO2 nano-rod catalysts for TEM observation were supported on a copper mesh with a carbon micro-grid. TEM and HAADF-STEM observations were performed with a JEOL JEM-3000F electron microscope at an accelerating voltage......

Tomoki Akita; Koji Tanaka; Kayoko Okuma; Tsuguo Koyanagi; Masatake Haruta

2001-11-01T23:59:59.000Z

155

Conversion of 1,3-Propylene Glycol on Rutile TiO2(110)  

SciTech Connect (OSTI)

The adsorption of 1,3-propylene glycol (1,3-PG) on partially reduced TiO2(110) and its conversion to products have been studied by a combination of molecular beam dosing and temperature programmed desorption (TPD). When the Ti surface sites are saturated by 1,3-PG, ~80% of the molecules undergo further reactions to yield products that are liberated during the TPD ramp. In contrast to ethylene glycol (EG) and 1,2- propylene glycol (1,2-PG) that yield only alkenes and water at very low coverages (< 0.05 ML), two additional products, HCHO and C2H4, along with propylene (CH3CHCH2) and water are observed for 1,3-PG. Identical TPD line shapes and desorption yields for HCHO and C2H4 suggest that these products result from C-C bond cleavage and are coupled. At higher 1,3-PG coverages (> 0.1 ML), propanal (CH3CH2CHO) and two additional products, 1-propanol (CH3CH2CH2OH) and acrolein (CH2CHCHO), are observed. The desorption of 1-propanol is found to be coupled with the desorption of acrolein, suggesting that these products are formed by the disproportionation of two 1,3-PG molecules. The coverage dependent TPD results further show that propylene formation dominates at low coverages (< 0.3 ML), while the decomposition and disproportionation channels increase rapidly at higher coverages and reach yields comparable to that of propylene at the 1,3-PG saturation coverage of 0.5 ML. The observed surface chemistry clearly shows how the molecular structure of glycols influences their reaction pathways on oxide surfaces.

Chen, Long; Li, Zhenjun; Smith, R. Scott; Kay, Bruce D.; Dohnalek, Zdenek

2014-10-09T23:59:59.000Z

156

Preparation of Ti O 2 thin films on the inner surface of a quartz tube using atmospheric-pressure microplasma  

Science Journals Connector (OSTI)

Titanium dioxide ( Ti O 2 ) thin films were prepared on the inner surface of a quartz tube with inner and outer diameters of 1 and 3 mm respectively using plasma-enhanced chemical vapor deposition with titanium tetraisopropoxide and oxygen ( O 2 ) as reactants and helium as the carrier gas at atmospheric pressure. A microplasma was generated inside the tube by rf ( 13.56 MHz ) excitation using externally attached parallel-plate electrodes. The characteristics of the depositedfilms were examined by scanning electron microscopy x-ray photoelectron spectroscopy and x-ray diffraction. A typical as-deposited film had an amorphous structure with a smooth surface and was transparent. With increasing O 2 concentration in the plasma gas phase the depositedfilmsurface was covered with a large number of Ti O 2 nanoparticles. However the depositedfilms were a mixture of Ti O 2 and amorphous carbon and showed rough surface in the absence of O 2 in the source gas. The effects of the O 2 concentration in the plasma gas on the characteristics of the deposited Ti O 2 films are discussed on the basis of the analysis of the gas species generated in the plasma using optical emission spectroscopy.

Hiroyuki Yoshiki; Taku Saito

2008-01-01T23:59:59.000Z

157

Photocatalytic and antibacterial properties of Au-TiO{sub 2} nanocomposite on monolayer graphene: From experiment to theory  

SciTech Connect (OSTI)

The formation of the Au-TiO{sub 2} nanocomposite on monolayer Graphene (GTA) by sequentially depositing titanium dioxide particles and gold nanoparticles on graphene sheet was synthesized and analyzed in our work. The structural, morphological, and physicochemical properties of samples were thoroughly investigated by UV-Vis spectrophotometer, Raman spectroscopy, Fourier transform infrared spectroscopy, atomic force microscopy, scanning electron microscope, and transmission electron microscope. Photocatalytic performance of GTA, graphene (GR), TiO{sub 2,} and TiO{sub 2} -graphene nanocomposite (GT) were comparatively studied for degradation of methyl orange, and it was found that GTA had highest performance among all samples. More importantly, antibacterial performance of this novel composite against Gram-positive bacteria, Gram-negative bacteria, and fungus was predominant compared to GR, TiO{sub 2}, and GT. And the result of biomolecules oxidation tests suggested that antimicrobial actions were contributed by oxidation stress on both membrane and antioxidant systems. Besides, the rate of two decisive processes during photocatalytic reaction, the rate of the charge transfer (k{sub CT}) and the rate of the electron-hole recombination (k{sub R}) have been studied by Perturbation theory, Radiation theory, and Schottky barrier theory. Calculation and derivation results show that GTA possesses superior charge separation and transfer rate, which gives an explanation for the excellent oxidation properties of GTA.

He, Wangxiao; Huang, Hongen; Yan, Jin [School of Life Sciences and Technology, Xi'an Jiaotong University, Xi'an 710049 (China)] [School of Life Sciences and Technology, Xi'an Jiaotong University, Xi'an 710049 (China); Zhu, Jian [School of Life Sciences and Technology, Xi'an Jiaotong University, Xi'an 710049 (China) [School of Life Sciences and Technology, Xi'an Jiaotong University, Xi'an 710049 (China); The Key Laboratory of Biomedical Information Engineering of Ministry of Education, Xi'an Jiaotong University, Xi'an 710049 (China)

2013-11-28T23:59:59.000Z

158

Off-normal CO2 desorption from the photooxidation of CO on reduced TiO2(110)  

SciTech Connect (OSTI)

Photo-induced reactions between O2 and CO on reduced rutile TiO2(110) are studied at low temperature (~30K). Photon stimulated desorption (PSD) of O2, CO2 and CO are observed with comparable yields. Isotope labeling experiments indicate that O2 chemisorbed in a vacancy is more active for photooxidation than O2 chemisorbed on a Ti5c site. The angular distribution for the desorbing CO2 is peaked at ~40º with respect to the surface normal in the azimuth (i.e. perpendicular to the bridging oxygen rows) suggesting that CO2 is produced from O2 occupying an oxygen vacancy and CO adsorbed on a Ti5c site next to it. The experimental results are consistent with CO2 being produced from a transition state complex that has been predicted theoretically. The CO PSD from TiO2(110) is enhanced dramatically by the presence of chemisorbed O2 suggesting that it is a by-product of the CO photooxidation process.

Petrik, Nikolay G.; Kimmel, Gregory A.

2010-09-02T23:59:59.000Z

159

Probing Hot Electron Flow Generated on Pt Nanoparticles with Au/TiO2 Schottky Diodes during Catalytic CO Oxidation  

SciTech Connect (OSTI)

Hot electron flow generated on colloid platinum nanoparticles during exothermic catalytic carbon monoxide oxidation was directly detected with Au/TiO{sub 2} diodes. Although Au/TiO{sub 2} diodes are not catalytically active, platinum nanoparticles on Au/TiO{sub 2} exhibit both chemicurrent and catalytic turnover rate. Hot electrons are generated on the surface of the metal nanoparticles and go over the Schottky energy barrier between Au and TiO{sub 2}. The continuous Au layer ensures that the metal nanoparticles are electrically connected to the device. The overall thickness of the metal assembly (nanoparticles and Au thin film) is comparable to the mean free path of hot electrons, resulting in ballistic transport through the metal. The chemicurrent and chemical reactivity of nanoparticles with citrate, hexadecylamine, hexadecylthiol, and TTAB (Tetradecyltrimethylammonium Bromide) capping agents were measured during catalytic CO oxidation at pressures of 100 Torr O{sub 2} and 40 Torr CO at 373-513 K. We found that chemicurrent yield varies with each capping agent, but always decreases with increasing temperature. We suggest that this inverse temperature dependence is associated with the influence of charging effects due to the organic capping layer during hot electron transport through the metal-oxide interface.

Park, Jeong Y.; Lee, Hyunjoo; Renzas, J. Russell; Zhang, Yawen; Somorjai, G.A.

2008-05-01T23:59:59.000Z

160

E-Print Network 3.0 - avastart ti traumade Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University of South Carolina Collection: Mathematics 15 Characterization of TiN, TiC and TiCN coatings on Ti50.6 at.% Ni alloy deposited by PIII and deposition technique...

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - amorphous ni-ti alloys Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

044103 (6pp) doi:10.10881748-604134044103 Summary: .10881748-604134044103 Ti-TiC-TiCDLC gradient nano-composite film on a biomedical NiTi alloy Yufeng Zheng1,2, Dong...

162

TiB2/Ni coatings on surface of copper alloy electrode prepared by electrospark deposition  

Science Journals Connector (OSTI)

In order to improve the lifespan of spot-welding electrodes used for welding zinc coated steel sheets, titanium diboride was deposited onto their surface after precoating nickel as an intermediate layer. The microstructures and phase compositions of TiB2 and Ni coatings were characterized by SEM and XRD. The coating hardness was measured using a microhardness tester. The results indicate that a satisfactory TiB2 coating is obtained as a result of the intermediate nickel layer acting as a good binder between the TiB2 coating and the copper alloy substrate. Owing to its capacity of deforming, the precoated nickel layer is dense and crack free, while cracks and pores are observed in the TiB2 coating. The hardness of the TiB2/Ni coating decreases with the increase of voltage and capacitance because of the diffusion of copper and nickel and the oxidation of the coating materials. Because of the good thermal and electrical conductivities and high hardness properties of TiB2, the deformation of the electrode with TiB2/Ni coating is reduced and its spot-welding life is by far prolonged than that of the uncoated one.

Cheng LUO; Xiang XIONG; Shi-jie DONG

2011-01-01T23:59:59.000Z

163

Longevity of the Permian Emeishan mantle plume (SW China): 1 Ma, 8 Ma or 18 Ma?  

Science Journals Connector (OSTI)

...GREGORY SHELLNUTT MEI-FU ZHOU DAN-PING YAN YANBIN WANG Author for correspondence...Bowring, S. A., Erwin, D. H., Jin, Y. G., Martin, M. W., Davidek...Hongge Fe-V-Ti deposit in the Pan-Xi area, southwestern China. Mineralium Deposita...

J. GREGORY SHELLNUTT; MEI-FU ZHOU; DAN-PING YAN; YANBIN WANG

164

Effect of plasma CVD operating temperature on nanomechanical properties of TiC nanostructured coating investigated by atomic force microscopy  

SciTech Connect (OSTI)

Highlights: ? The TiC{sub x} nanostructure coatings have been deposited by PACVD method. ? Dominant mechanism of growth structure at 490 °C is island-layer type. ? TiC{sub x} nanostructure coating applied at 490 °C, exhibits lowest friction coefficient. ? Young's moduli are 289.9, 400 and 187.6 GPa for 470, 490 and 510 °C, respectively. ? This higher elastic modulus and higher hardness of nanocoating obtain at 490 °C. -- Abstract: The structure, composition, and mechanical properties of nanostructured titanium carbide (TiC) coatings deposited on H{sub 11} hot-working tool steel by pulsed-DC plasma assisted chemical vapor deposition at three different temperatures are investigated. Nanoindentation and nanoscratch tests are carried out by atomic force microscopy to determine the mechanical properties such as hardness, elastic modulus, surface roughness, and friction coefficient. The nanostructured TiC coatings prepared at 490 °C exhibit lower friction coefficient (0.23) than the ones deposited at 470 and 510 °C. Increasing the deposition temperature reduces the Young's modulus and hardness. The overall superior mechanical properties such as higher hardness and lower friction coefficient render the coatings deposited at 490 °C suitable for wear resistant applications.

Shanaghi, Ali, E-mail: alishanaghi@gmail.com [Materials Engineering Department, Faculty of Engineering, Malayer University, P.O. Box: 95863-65719, Malayer (Iran, Islamic Republic of)] [Materials Engineering Department, Faculty of Engineering, Malayer University, P.O. Box: 95863-65719, Malayer (Iran, Islamic Republic of); Rouhaghdam, Ali Reza Sabour, E-mail: sabour01@modares.ac.ir [Surface Engineering Laboratory, Materials Engineering Department, Faculty of Engineering, Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of); Ahangarani, Shahrokh, E-mail: sh.ahangarani@gmail.com [Advanced Materials and Renewable Energies Department, Iranian Research Organization for Science and Technology, P.O. Box 15815-3538, Tehran (Iran, Islamic Republic of)] [Advanced Materials and Renewable Energies Department, Iranian Research Organization for Science and Technology, P.O. Box 15815-3538, Tehran (Iran, Islamic Republic of); Chu, Paul K., E-mail: paul.chu@cityu.edu.hk [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)

2012-09-15T23:59:59.000Z

165

Effect of ternary additions on the oxidation resistance of Ti{sub 5}Si{sub 3}  

SciTech Connect (OSTI)

Refractory intermetallic silicides are receiving increasing consideration for use as high temperature structural materials. Ti{sub 5}Si{sub 3}-based compositions are attractive due to their ability to incorporate a variety of interstitial ternary additions. These ternary additions present a unique opportunity to potentially tailor physical properties. Previous experimental work has shown that these additions significantly increase the otherwise poor oxidation resistance of undoped Ti{sub 5}Si{sub 3} above 700 C. Recent experimental work by the authors on the oxidation of small atom doped Ti{sub 5}Si{sub 3} is discussed. Interstitial additions of boron, carbon, and oxygen substantially improve the isothermal oxidation resistance of Ti{sub 5}Si{sub 3} at 1,000 C. In contrast, added nitrogen does not provide significant improvement. Even up to 1,306 C, interstitial oxygen imparts excellent oxidation resistance with a mass gain of 1.1 mg/cm{sup 2} after 240 hours.

Thom, A.J.; Akinc, M. [Ames Lab., IA (United States)]|[Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering

1995-10-01T23:59:59.000Z

166

Imaging Water Dissociation on TiO2(110): Evidence for Inequivalent...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OH Groups. Abstract: Identical regions of partially reduced TiO2(110) surfaces with bridge-bonded oxygen vacancy (BBOV) concentrations of 10 % ML (1 ML 5.2×1014 cm-2)...

167

Two Pathways for Water Interaction with Oxygen Adatoms on TiO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tunneling microscopy and density functional theory studies show that oxygen adatoms (Oa), produced during O2 exposure of reduced TiO2(110) surfaces, alter the water dissociation...

168

Two charged states of hydrogen on the SrTiO{sub 3}(001) surface  

SciTech Connect (OSTI)

The effects of hydrogen exposure on the electronic structure of two types of SrTiO{sub 3}(001) surfaces, oxygen-deficient (OD) and nearly-vacancy-free (NVF) surfaces, were investigated with ultraviolet photoemission spectroscopy and nuclear reaction analysis. Upon molecular hydrogen exposure to the OD surface which reveals in-gap states at 1.3 eV below the Fermi level, the in-gap state intensity was reduced to half the initial value at a hydrogen coverage of 0.9 ± 0.7 × 10{sup 14} cm{sup ?2}. On the NVF surface which has no in-gap state, on the other hand, atomic-hydrogen exposure induced in-gap states, and the hydrogen saturation coverage was evaluated to be 3.1 ± 0.8 × 10{sup 14} cm{sup ?2}. We argue that H is positively charged as H{sup ?0.3+} on the NVF surface by being coordinated to the O atom, whereas H is negatively charged as H{sup ?} on the OD surface by occupying the oxygen vacancy site. The stability of H{sup ?} at the oxygen vacancy site is discussed.

Takeyasu, Kotaro, E-mail: takeyasu@iis.u-tokyo.ac.jp; Fukada, Keisuke; Ogura, Shohei; Matsumoto, Masuaki; Fukutani, Katsuyuki, E-mail: fukutani@iis.u-tokyo.ac.jp [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153–8505 (Japan)] [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153–8505 (Japan)

2014-02-28T23:59:59.000Z

169

Characteristics of vanadia on the surface of V2O5/Ti-PILC catalyst for the reduction of \\{NOx\\} by NH3  

Science Journals Connector (OSTI)

A series of vanadia catalysts impregnated on titania pillared interlayered clays (Ti-PILCs) were prepared to identify the characteristics of vanadia on the surface of Ti-PILC for the selective catalytic reduction (SCR) of NO by NH3. V2O5/Ti-PILC exhibited superior performance as a novel SCR catalyst compared to conventional catalysts including V2O5/TiO2 and V2O5/Al2O3. NO removal activity over the supported vanadia catalyst is strongly influenced by the structure of vanadia species on the catalyst surface. The structure of vanadia species on various supports including TiO2, Al2O3, and SiO2 along with Ti-PILC has been examined by XRD, NMR and Raman analyses for the comparative study. Increasing the content of vanadia up to the monolayer coverage of the surface of Ti-PILC catalyst enhanced the ratio of the polymerized surface vanadia species to the isolated ones. These results are well correlated with TOF of vanadia on the catalyst surface for the reduction of NO by NH3.

Ho Jeong Chae; In-Sik Nam; Sung-Won Ham; Suk Bong Hong

2004-01-01T23:59:59.000Z

170

Taught degrees MA in Literature and Philosophy  

E-Print Network [OSTI]

Philosophy Taught degrees MA in Literature and Philosophy 1 year full time/2 years part time This degree is taught jointly by Philosophy and English faculty. Refer to page 87 for details. MA in Philosophy 1 year full time/2 years part time This MA offers an advanced general grounding in philosophy

Sussex, University of

171

Photooxidation and Photodesorption in the Photochemistry of Isobutene on TiO2(110)  

SciTech Connect (OSTI)

The photochemistry of isobutene was examined on the rutile TiO2(110) surface as a function of the surface pretreatment condition and irradiation temperature using temperature programmed desorption (TPD) and photon stimulated desorption (PSD). Isobutene adsorbs molecularly on the clean TiO2(110) surface without detectable thermal decomposition. Preadsorption of oxygen, either as atoms or chemisorbed molecules, did not promote thermal reactions with isobutene, but instead blocked isobutene adsorption sites. Ultraviolet (UV) light irradiation of isobutene adsorbed on the clean surface led to depletion through photodesorption without significant photodecomposition. Isobutene PSD yields increased with increasing surface temperature suggesting that activated molecules sample their physisorbed potential energy surface during photodesorption. Preadsorption of oxygen promoted partial photooxidation of adsorbed isobutene to acetone, methacrolein and isobutanal. Acetone was only detected when molecular oxygen was present, indicating that O2 addition occurred across the C=C bond. In contrast, results from use of D6-isobutene indicated that coadsorption with either O adatoms or O2 molecules led to photochemical production of methacrolein (and likely isobutanal) through C-H bond cleavage on a methyl group. Irradiation an adlayer comprised of isobutene isolated from the surface by 1 ML of preadsorbed O2 showed the most photoconversion of isobutene, which suggests that photoactivation of adsorbed O2 is a key step in partial photooxidation of isobutene. Comparison of the isobutene PSD and oxidation product yields as a function of surface temperature between 20 and 120 K indicates a competition between photooxidation and photodesorption that varies with temperature. ‘Direct’ charge transfer events between isobutene and the surface, favored at higher temperature, compete with partial oxidation pathways initiated by ‘indirect’ activation of isobutene by O2, which is favored at low temperature. Access of O2 to the surface is critical to achieving desired isobutene photooxidation rates and products, and isobutene photodesorption may provide a means of regulating the isobutene surface coverage. Work reported here was supported by the U.S. Department of Energy, Office of Basic Energy Science, Division of Chemical Sciences, Geosciences, and Biosciences, and performed in the Williams R. Wiley Environmental Molecular Science Laboratory (EMSL), a Department of Energy user facility funded by the Office of Biological and Environmental Research. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for the U.S. Department of Energy by the Battelle Memorial Institute under contract DEAC05-76RL01830.

Henderson, Michael A.

2013-07-11T23:59:59.000Z

172

Growth behavior and field-induced diffusion of Ni clusters/particles on SrTiO3 (001) observed by UHV-TEM/STM  

Science Journals Connector (OSTI)

The fundamental and technological importance of metal clusters and particles on oxide surfaces is growing. Here, room temperature deposited Ni clusters and particles on clean SrTiO3 (001) surfaces were analyzed w...

Miyoko Tanaka

2013-09-01T23:59:59.000Z

173

Corrosion of MA754 and MA956 in a Commercial Aluminum Melter  

SciTech Connect (OSTI)

The University of North Dakota Energy & Environmental Research Center is working with Oak Ridge National Laboratory to test two oxide dispersion-strengthened alloys that could be used to construct very high-temperature heat recuperators for the aluminum-melting industry. For the initial tests, uncooled rings of MA754 and MA956 piping were exposed for 5 months to gases leaving an aluminum melter furnace at 1200 1290 C. The MA956 suffered spotty areas of severe corrosion and lost 25% of its weight. Scanning electron microscopy showed that there were small spots of alkali-rich corrosion products on the alloy surfaces, indicating the impact of droplets of fluxing agents. The corrosion products in these areas were mixed Fe, Cr, and Al oxides, which were depleted in Cr near the gas surface. However, Al concentrations in the remaining metal were typically between 3.5% and 4.0%, so there was a sufficient reservoir of Al remaining in the alloy to prevent simple breakaway corrosion which could have occurred if the Al were significantly depleted. The MA754 lost approximately 15% of its weight and showed void formation within 2 mm of the gas metal surfaces. Within the porous area, the Cr had largely segregated into oxide precipitates up to 50 9m in diameter, leaving the remaining metal Ni-rich. Below the porous layer, the alloy composition was relatively unchanged. Remains of Na- and Al-rich particles that had impacted the surface sporadically were visible but had not obviously affected the surface scale as they had with the MA956.

Hurley, John P. [University of North Dakota Energy & Environmental Research Center] [University of North Dakota Energy & Environmental Research Center; Kelley, Carl [Nature’s Fuel, 410 East Cook Road, Fort Wayne, IN 46825, USA] [Nature’s Fuel, 410 East Cook Road, Fort Wayne, IN 46825, USA; Bornstein, Norman S. [Consultant] [Consultant; Wright, Ian G [ORNL] [ORNL

2008-01-01T23:59:59.000Z

174

Site-Specific Imaging of Elemental Steps in Dehydration of Diols on TiO2(110)  

SciTech Connect (OSTI)

The conversion of diols on partially reduced TiO2(110) at low coverage was studied using variable-temperature scanning tunneling microscopy, temperature programmed desorption and density functional theory calculations. We find, that below ~230 K, ethane-1,2-diol and propane-1,3-diol molecules adsorb predominantly on five-fold coordinated Ti5c atoms. The dynamic equilibrium between molecularly bound and dissociated species resulting from O-H bond scission and reformation is observed. As the diols start to diffuse on the Ti5c rows above ~230 K, they dissociate irreversibly upon encountering bridging oxygen (Ob) vacancy (VO’s) defects. Two dissociation pathways, one via O-H and the other via C-O bond scission leading to identical surface intermediates, hydroxyalkoxy, Ob-(CH2)n-OH (n = 2, 3) and bridging hydroxyl, HOb, are seen. For O-H bond scission, the Ob-(CH2)n-OH is found on the position of the original VO, while for C-O scission it is found on the adjacent Ob site. Theoretical calculations suggest that the observed mixture of C-O/O-H bond breaking processes are a result of the steric factors enforced upon the diols by the second OH group that is bound to a Ti5c site. At room temperature, rich dissociation/reformation dynamics of the second, Ti5c-bound O-H leads to the formation of dioxo, Ob-(CH2)n-OTi, species. Above ~400 K, both Ob-(CH2)n-OH and Ob-(CH2)n-OTi species convert into a new intermediate, that is centered on Ob row. Combined experimental and theoretical evidence shows that this intermediate is most likely a new dioxo, Ob-(CH2)2-Ob, species. Further annealing leads to sequential C-Ob bond cleavage and alkene desorption above ~ 500 K. Simulations find that the sequential C-O bond breaking process follows a homolytic diradical pathway with the first C-O bond breaking event accompanied by a non-adiabatic electron transfer within the TiO2(110) substrate.

Acharya, Danda P.; Yoon, Yeohoon; Li, Zhenjun; Zhang, Zhenrong; Lin, Xiao; Mu, Rentao; Chen, Long; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek

2013-11-26T23:59:59.000Z

175

A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed on MCM-48  

E-Print Network [OSTI]

A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed.932), suggesting the formation of oxygen vacancies. The fraction of Ti that could be reduced increased with TiO2 the TiO2 overlayer as the size of the titania patches increases. The amount of oxygen removed during

Bell, Alexis

176

Substrate orientation effects on the nucleation and growth of the M{sub n+1}AX{sub n} phase Ti{sub 2}AlC  

SciTech Connect (OSTI)

The M{sub n+1}AX{sub n} (MAX) phases are ternary compounds comprising alternating layers of a transition metal carbide or nitride and a third ''A-group'' element. The effect of substrate orientation on the growth of Ti{sub 2}AlC MAX phase films was investigated by studying pulsed cathodic arc deposited samples grown on sapphire cut along the (0001), (1010), and (1102) crystallographic planes. Characterization of these samples was by x-ray diffraction, atomic force microscopy, and cross-sectional transmission electron microscopy. On the (1010) substrate, tilted (1018) growth of Ti{sub 2}AlC was found, such that the TiC octahedra of the MAX phase structure have the same orientation as a spontaneously formed epitaxial TiC sublayer, preserving the typical TiC-Ti{sub 2}AlC epitaxial relationship and confirming the importance of this relationship in determining MAX phase film orientation. An additional component of Ti{sub 2}AlC with tilted fiber texture was observed in this sample; tilted fiber texture, or axiotaxy, has not previously been seen in MAX phase films.

Tucker, Mark D.; Guenette, Mathew C.; Bilek, Marcela M. M.; McKenzie, David R. [School of Physics, University of Sydney, New South Wales 2006 (Australia); Persson, Per O. A.; Rosen, Johanna [School of Physics, University of Sydney, New South Wales 2006 (Australia); Thin Film Physics, Linkoepings Universitet, 58183 Linkoeping (Sweden)

2011-01-01T23:59:59.000Z

177

Office of Information Resources (MA-90) | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Office of Information Resources (MA-90) Office of Information Resources (MA-90) Freedom of Information 2007 Annual Report Office of Information Resources (MA-90) More Documents &...

178

Ma-Brueckner correlation energy  

Science Journals Connector (OSTI)

We point out that the e2 dependence of the term in the correlation energy of a high-density electron gas, proportional to the gradient squared of the charge density, was rigorously derived by Ma and Brueckner only for infinitely long-wavelength variations in the charge density. We also correct an error made in obtaining the coefficient of this term which arose because of long-range Coulomb anomalies in the exchange energy which they subtracted from the exchange-correlation energy.

Leonard Kleinman and T. Tamura

1989-08-15T23:59:59.000Z

179

Microstructure and Wear Properties of Laser Coating Reinforced by Ti(CxN1-x on Adamite Roller  

Science Journals Connector (OSTI)

Fe-based layer with Ti(CINI-x) particulates on Adamite roller surface was obtained by a 5 kW traverse-flowing CO2 laser cladding technology. The microstructures of the layer were detected by optical microscopy (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microscopy analysis (EMPA). The tests of wear resistance was carried out on the test machine. It was seen that a good metallurgical bonding between the coating and the substrate was achieved. The microstructure contains bulky dendritic crystal and small size Ti(CINI-x) grains that are uniformly distributed in the solid solution matrix. The wear tests showed that the laser coating provided an excellent wear resistance property at room temperature.

Yong-tian QI; Zeng-da ZOU

2009-01-01T23:59:59.000Z

180

A new 40 MA ranchero explosive pulsed power system  

SciTech Connect (OSTI)

We are developing a new high explosive pulsed power (HEPP) system based on the 1.4 m long Ranchero generator which was developed in 1999 for driving solid density z-pinch loads. The new application requires approximately 40 MA to implode similar liners, but the liners cannot tolerate the 65 {micro}s, 3 MA current pulse associated with delivering the initial magnetic flux to the 200 nH generator. To circumvent this problem, we have designed a system with an internal start switch and four explosively formed fuse (EFF) opening switches. The integral start switch is installed between the output glide plane and the armature. It functions in the same manner as a standard input crowbar switch when armature motion begins, but initially isolates the load. The circuit is completed during the flux loading phase using post hole convolutes. Each convolute attaches the inner (coaxial) output transmission line to the outside of the outer coax through a penetration of the outer coaxial line. The attachment is made with the conductor of an EFF at each location. The EFFs conduct 0.75 MA each, and are actuated just after the internal start switch connects to the load. EFFs operating at these parameters have been tested in the past. The post hole convolutes must withstand as much as 80 kV at peak dl/dt during the Ranchero load current pulse. We describe the design of this new HEPP system in detail, and give the experimental results available at conference time. In addition, we discuss the work we are doing to test the upper current limits of a single standard size Ranchero module. Calculations have suggested that the generator could function at up to {approx}120 MA, the rule of thumb we follow (1 MA/cm) suggests 90 MA, and simple flux compression calculations, along with the {approx}4 MA seed current available from our capacitor bank, suggests 118 MA is the currently available upper limit.

Goforth, James [Los Alamos National Laboratory; Herrera, Dennis [Los Alamos National Laboratory; Oona, Hank [Los Alamos National Laboratory; Torres, David [Los Alamos National Laboratory; Atchison, W L [Los Alamos National Laboratory; Colgate, S A [Los Alamos National Laboratory; Griego, J R [Los Alamos National Laboratory; Guzik, J [Los Alamos National Laboratory; Holtkamp, D B [Los Alamos National Laboratory; Idzorek, G [Los Alamos National Laboratory; Kaul, A [Los Alamos National Laboratory; Kirkpatrick, R C [Los Alamos National Laboratory; Menikoff, R [Los Alamos National Laboratory; Reardon, P T [Los Alamos National Laboratory; Reinovsky, R E [Los Alamos National Laboratory; Rousculp, C L [Los Alamos National Laboratory; Sgro, A G [Los Alamos National Laboratory; Tabaka, L J [Los Alamos National Laboratory; Tierney, T E [Los Alamos National Laboratory; Watt, R G [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Sonosynthesis of nano TiO2 on wool using titanium isopropoxide or butoxide in acidic media producing multifunctional fabric  

Science Journals Connector (OSTI)

Abstract This study presents a novel idea to prepare nanocrystalline structure of TiO2 under ambient pressure at 60–65 °C using in situ sonochemical synthesis by hydrolysis of either titanium isopropoxide or titanium butoxide in an acidic aqueous solution. The nano titanium dioxide coated wool fabrics possess significant antibacterial/antifungal activity and self-cleaning property by discoloring Methylene blue stain under sunlight irradiation. This process has no negative effect on cytotoxicity and tensile strength of the sonotreated fabric even reduces alkaline solubility and photoyellowing and improves hydrophilicity. More titanium isopropoxide or titanium butoxide as a precursor led to higher photocatalytic activities of the treated fabrics. Also introducing more ethanol improved the adsorption of TiO2 on the wool fabric surface leading to enhanced photocatalytic activity. EDS and XRD patterns, SEM images, X-ray mapping confirmed the presence of nano TiO2 particles on the fabric surface. The role of both solvent and precursor concentrations on the various properties of the fabric was investigated and the optimized conditions were obtained using response surface methodology.

Amir Behzadnia; Majid Montazer; Abousaeid Rashidi; Mahnaz Mahmoudi Rad

2014-01-01T23:59:59.000Z

182

Direct preparation of CaTi4 (PO4)6 coatings on the surface of titanium substrate by micro arc oxidation  

Science Journals Connector (OSTI)

CaTi4 (PO4)6...coatings was prepared on the surface of CP (commercially pure) Titanium substrate via micro arc oxidation in a newly designed electrolyte system. The preparation method –micro arc oxidation, as wel...

Zhongwei Zhao; Shimei Wen

2007-12-01T23:59:59.000Z

183

Synergistic effect of nanoTiO2 and nanoclay on mechanical, flame retardancy, UV stability, and antibacterial properties of wood polymer composites  

Science Journals Connector (OSTI)

Wood–polymer nanocomposite (WPNC) based on styrene–acrylonitrile copolymer (SAN), ?-trimethoxy silyl propyl methacrylate-modified TiO2 nanoparticles, and nanoclay was prepared by impregnation. The flexural,...2 (...

Rashmi R. Devi; Krishna Gogoi; Bolin K. Konwar; Tarun K. Maji

2013-04-01T23:59:59.000Z

184

Identification of the Active Species in Photochemical Hole Scavenging Reactions of Methanol on TiO2  

SciTech Connect (OSTI)

Molecular and dissociative methanol adsorption species were prepared on rutile TiO2(110) surfaces to study photocatalytic oxidation of methanol in ultrahigh vacuum (UHV) using temperature-programmed desorption (TPD). Adsorbed methoxy groups (CH3O-) were found to be the photoactive form of adsorbed methanol converted to adsorbed formaldehyde and a surface OH group by hole-mediated C-H bond cleavage. These results suggest that adsorbed methoxy is the effective hole scavenger in photochemical reactions involving methanol.

Shen, Mingmin; Henderson, Michael A.

2011-11-03T23:59:59.000Z

185

Density functional theory study of oxygen and water adsorption on SrTiO3(001)  

E-Print Network [OSTI]

effortlessly leading to the formation of a pair of hydroxyl groups. For the titanium dioxide termina- tionDensity functional theory study of oxygen and water adsorption on SrTiO3(001) D I S S E R TAT I O N and they are computationally feasible. For the oxygen and water adsorption the binding energy is controlled by long-range sur

186

Optimization of nano TiO2 pretreatment on free acid dyeing of wool using central composite design  

Science Journals Connector (OSTI)

Abstract The aim of the research is to investigate nano technique of wool acid dyeing without the presence of acid auxiliary agent at temperatures lower than the boiling. The wool fabrics are first pretreated with nano TiO2 and BTCA at different concentrations. The dyeing process is then carried out on the pretreated fabrics with C. I. Acid Blue 113 and C. I. Acid Black 3 dyes. Also, the central composite design analysis is applied to design the relation between nano TiO2 and BTCA concentrations, and dye exhaustion. The response surface methodology is also applied to find the optimum conditions for the wool fabric pretreatment. The scanning electron microscopy and X-ray diffraction are employed to indicate the presence, crystal type and size of TiO2 nanoparticles on the wool surface. The pretreatment optimization on the wool surfaces considerably enhances the absorption of acid dyes. The suggested method demonstrates the improvement of fastness properties than control dyeing and could be introduced as a new route, disclosing various desirable multi-functional characteristics, to wool fabric. This technique is also free from some of the disadvantages of acid chemical involved in dyeing such as damage to wool fabrics than wool conventional dyeing.

Ali Nazari; Mohammad Mirjalili; Navid Nasirizadeh; Shahab Torabian

2014-01-01T23:59:59.000Z

187

Visible-Light Responsive Photocatalytic Fuel Cell Based on Ag/TiO2-NTs Photoanode and Cu2O/TiO2 Photocathode for Simultaneous Wastewater Treatment and Electricity Generation  

Science Journals Connector (OSTI)

A visible-light driven photocatalytic fuel cell (PFC) system comprised of Ag/TiO2-NTs photoanode and Cu2O/TiO2/Ti photocathode was established for providing a self-sustained and...

Liao, Wenjuan

188

Effect of TiN coatings on the rolling contact fatigue behavior of M50 bearing steel. Final report  

SciTech Connect (OSTI)

There is a continuing requirement for improved bearing performance for both commercial and military applications. Service temperatures are increasing steadily due to increased power requirements and corrosion of components remains a major concern as well, particularly for bearings in military systems. In our ongoing study, a number of different coatings were applied to VIM-VAR M50 bearing steel to improve both corrosion resistance and rolling contact fatigue behavior. This report deals specifically with coatings produced by the ion beam assisted deposition IBAD of TiN, details of the coating process, and test results obtained. The rolling contact fatigue performance of IBAD TiN coated M50 samples demonstrated increased lifetime performance and durability for a 1 micrometer thick coating. Preliminary data on corrosion properties is also presented.

Middleton, R.M.; Huang, P.J.; Wells, M.G.; Kant, R.A.

1992-12-01T23:59:59.000Z

189

Self-powered solid-state photodetector based on TiO{sub 2} nanorod/spiro-MeOTAD heterojunction  

SciTech Connect (OSTI)

A nanostructured solid-state photodetector based on an inorganic/organic semiconductor heterojunction of TiO{sub 2} nanorod/spiro-MeOTAD is constructed. Spiro-MeOTAD serves as the active absorption layer and TiO{sub 2} offers a direct pathway for electron transport. A maximum photoresponsivity of 0.01?A/W was observed under illumination of 410?nm at 0?V bias. The time response (decay time is 0.06?s and rise time is 0.12?s) was observed to be rapid. The self-powered device is a promising candidate for application in high-sensitivity and high-speed blue light photodetectors. These results provided a simple way to fabricate low-cost, high spectrum selectivity hybrid photodetector with large area.

Xie, Yanru; Li, Qinghao; Wei, Guodong; Wang, Dong; Chen, Yanxue, E-mail: cyx@sdu.edu.cn; Yan, Shishen; Liu, Guolei; Mei, Liangmo [School of Physics and State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100 (China)] [School of Physics and State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100 (China); Wei, Lin [School of Information Science and Engineering, Shandong University, Jinan 250100 (China)] [School of Information Science and Engineering, Shandong University, Jinan 250100 (China); Jiao, Jun [Department of Mechanical and Materials Engineering, Portland State University, P.O. Box 751, Portland, Oregon 97207-0751 (United States)] [Department of Mechanical and Materials Engineering, Portland State University, P.O. Box 751, Portland, Oregon 97207-0751 (United States)

2013-12-23T23:59:59.000Z

190

Solar Energy Materials & Solar Cells 71 (2002) 261271 Photoelectric behavior of nanocrystalline TiO2  

E-Print Network [OSTI]

Solar Energy Materials & Solar Cells 71 (2002) 261­271 Photoelectric behavior of nanocrystalline Ti 100101, People's Republic of China e Synchrotron Radiation Laboratory at Institute of High Energy Physics. A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6:1 mA cm�2

Huang, Yanyi

191

Offering Songs, Festive Songs, Processional Songs mGar-gLu, Khro-Glu, Phebsnga: Khang Lhamo, Yandol & Pema Dolma Music: Li phur ma laten pa’i, 'The belt on the boots'  

E-Print Network [OSTI]

phur ma laten pa’i Translation of title The belt on the boots Description (to be used in archive entry) Genre or type (i.e. epic, song, ritual) ‘khro glu (festive song) Medium (i.e. reel to reel, web-based file, DVD) Digital Recording Related... access (fully closed, fully open) Fully open for web streaming Notes and context (include reference to any related documentation, such as photographs) "This belt is really long on the boots. If we use it on the waist it's short. You can use...

Blumenthal, Katey

192

Effects of chromium addition on microstructure and properties of TiC–VC reinforced Fe-based laser cladding coatings  

Science Journals Connector (OSTI)

Abstract Effects of different addition of Cr on microstructure and properties (especially the corrosion resistance) of cladding layers were investigated by means of X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), potentio-dynamic polarization and electrochemical impedance spectroscopy (EIS). Results showed that Fe–Ti–V–C alloy powders with different addition of Cr formed good cladding layers without defects such as cracking and porosity. Phases of the cladding layers were ?-Fe, ?-Fe, TiC, VC and TiVC2. A certain amount of long strip Cr3C2 synthesized while the addition of Cr was 12.0% or more. Microhardness and corrosion resistance of cladding layer both improved greatly with a moderate amount of Cr. The cladding layer with 3.0% Cr showed a highest microhardness 1090HV0.2, and the variation tendency of the hardness is not a linearly relationship with increasing the chromium addition. The cladding layer with 12.0% Cr addition showed the best corrosion resistance, which was about 4.5 times than that of the cladding layer without Cr. EIS spectrum of the cladding layer without Cr was composed of an inductive arc at low frequency and a capacitive arc at high frequency. However, the inductive arc at low frequency transformed into a capacitive arc gradually with the addition of Cr increasing.

Hui Zhang; Yong Zou; Zengda Zou; Chuanwei Shi

2014-01-01T23:59:59.000Z

193

Feasibility study on preparation of coatings on Ti–6Al–4V by combined ultrasonic impact treatment and electrospark deposition  

Science Journals Connector (OSTI)

Abstract A novel method combining ultrasonic impact treatment (UIT) with electrospark deposition was developed to prepare coatings on Ti–6Al–4V substrates. The microstructure, phase composition, residual stress, microhardness, and wear performance of the coating were studied, and new amorphous and nanocrystalline phases (titanium carbide nitride and iron titanium oxide) were found. In addition, the residual stress in the coating and in the substrate near the coating is compressive stress. The maximum compressive residual stress is about ?717 MPa, and its depth is about 470 ?m. Because of contributions from multiple factors, the wear volume loss of the sample subjected to combined UIT and electrospark processing was reduced by four orders of magnitude compared with that of the base material.

Yang Liu; Dongpo Wang; Caiyan Deng; Lixing Huo; Lijun Wang; Shu Cao

2014-01-01T23:59:59.000Z

194

The influence of surface conductivity on the apparent zeta potential of TiO2 nanoparticles  

E-Print Network [OSTI]

Titanium dioxide is widely used as TiO2 nanoparticles and has a large variety of potential applications in of these properties, the surface ionization of titanium dioxide nanoparticles in contact with an electrolytic solution is a physico-chemical parameter of particular importance to describe ion adsorption and electrostatic

Paris-Sud XI, Université de

195

Characterization of Ti diffusion in PVD deposited WTi/AlCu metallization on monocrystalline Si by means of secondary ion mass spectroscopy  

Science Journals Connector (OSTI)

The diffusion behavior of Titanium in Al0.5Cu/W18Ti (at.%) metallization stacks on monocrystalline Silicon has been investigated. The metallization system was prepared by in situ sputtering deposition. It is demonstrated that \\{WTi\\} is not stable as a diffusion barrier between Al0.5Cu and Si in temperature ranges between 623 K and 673 K due to Ti depletion. The Ti diffusion in Al0.5Cu is characterized by diffusion profiles prepared by secondary ion mass spectroscopy after annealing. The activation energy derived from this data is 2.28 eV for Ti diffusion into Al0.5Cu. The causal chain of detecting this behavior is described application-oriented.

M. Plappert; O. Humbel; A. Koprowski; M. Nowottnick

2012-01-01T23:59:59.000Z

196

Ti Plasmid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ti Plasmid Ti Plasmid Name: Dixenia Location: N/A Country: N/A Date: N/A Question: What can you tell me about the Ti Plasmid? Replies: This plasmid is named for a plasmid found in a bacteria called Agrobacter tumefaciens. It causes "plant cancer" or what are known as galls. They are little tumors in which the bacteria can grow and live in the plant. Ti stands for tumor inducing. The bacterium gets into the plant through some kind of wound, ie. a scratch. It injects its plasmid into a plant cell and the plasmid inserts its DNA into the plant's DNA. Then the DNA directs the plant to make a hollow tumor where the bacteria can live. Scientists have taken advantage of this plant's ability to insert foreign DNA into a plant. They take the genes out of the plasmid that cause galls, and insert genes of interest, ie. genes for pest resistance and let the plasmid carry those genes into the plant. The plant will start making the product you want. You may have seen a picture of a tobacco plant glowing because firefly genes for glowing were inserted into the plant. They did this so they could know if the gene had made it into the plant. Once they are sure the gene they want has made it into the plant, they clone the plant cells. By the way, plant tissue culture is a procedure that is very common and has been done for years, this is not the same as cloning animals.

197

Highly uniform bipolar resistive switching characteristics in TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2} multilayer  

SciTech Connect (OSTI)

Nanoscale multilayer structure TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2} has been fabricated on Pt/Ti/SiO{sub 2}/Si substrate by chemical solution deposition method. Highly uniform bipolar resistive switching (BRS) characteristics have been observed in Pt/TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2}/Pt cells. Analysis of the current-voltage relationship demonstrates that the space-charge-limited current conduction controlled by the localized oxygen vacancies should be important to the resistive switching behavior. X-ray photoelectron spectroscopy results indicated that oxygen vacancies in TiO{sub 2} play a crucial role in the resistive switching phenomenon and the introduced TiO{sub 2}/BaTiO{sub 3} interfaces result in the high uniformity of bipolar resistive switching characteristics.

Ma, W. J.; Zhang, X. Y.; Wang, Ying; Zheng, Yue, E-mail: zhengy35@mail.sysu.edu.cn, E-mail: wangbiao@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China) [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Lin, S. P. [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China) [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Sino-French Institute of Nuclear Engineering and Technology, Zhuhai Campus, Sun Yat-Sen University, Zhuhai 519082 (China); Luo, J. M.; Wang, B., E-mail: zhengy35@mail.sysu.edu.cn, E-mail: wangbiao@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Li, Z. X. [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China)] [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China)

2013-12-23T23:59:59.000Z

198

Atomic Layer Deposition of TiO2 on Aerogel Templates: New Photoanodes for Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

Atomic layer deposition was employed to coat the aerogel template conformally with various thicknesses of TiO2 with subnanometer precision. ... The TiO2-coated aerogel membranes were incorporated as photoanodes in dye-sensitized solar cells. ...

Thomas W. Hamann; Alex B. F. Martinson; Jeffrey W. Elam; Michael J. Pellin; Joseph T. Hupp

2008-06-18T23:59:59.000Z

199

Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers  

E-Print Network [OSTI]

Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers Yuanyuan Cheng Polarization Fretting corrosion Ti/TiN multilayers were deposited on sintered NdFeB by radio frequency magnetron sputtering. The film grain size decreased with the number of multilayers in the stack. Corrosion

Volinsky, Alex A.

200

M.A. Silva Dias,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 a 260. 1 a 260. 1 Modelando o Impacto Climático Regional e Remoto do Desmatamento M.A. Silva Dias, 1 R. Avissar, 2 e P. Silva Dias 1,3 As observações e os modelos concordam que os níveis atuais e os padrões de desmatamento da Amazônia de fato intensificam as transferências de massa e energia entre a terra e a atmosfera por meio da criação de circulações impulsionadas termicamente com efeitos significativos sobre a precipitação, mas que variam sazonal e regionalmente. Isso também indicou a necessidade de identificar o limiar onde o aumento do desmatamento realmente implica a diminuição de pluviosidade, conforme apontado pela maioria dos modelos de circulação geral de baixa resolução. Grande parte dos estudos sobre o impacto remoto ainda é exploratória, mas indicam que

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

KwanliuMa_NERSC2011.ppt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analysis and Visualization Analysis and Visualization Computing Requirements A Case Study Kwan-Liu Ma University of California, Davis SciDAC Institute for Ultrascale Visualization Outline * SciDAC Institute for Ultrascale Visualization * Visualization Solutions for Turbulent Combustion Simulations * A Case Study on Particle Trajectories Data Visualization Turbulent Combustion Simulations  Jackie Chen, Sandia National Laboratory  Direct numerical simulation tools are being developed Turbulent Combustion Simulations * High fidelity modeling is required to reliably predict efficiency and pollutant emission for new engines and new fuels * The current simulation code running on a supercomputer like the Cray XT5 uses up to 48,000 cores and over 14 million CPU hours per run

202

M.A. POLITICAL SCIENCE Application Checklist  

E-Print Network [OSTI]

M.A. POLITICAL SCIENCE Application Checklist IMPORTANT NOTES 1. Please submit all Application below. 6. Applicants to the M.A. Political Science Program normally should have a four-year baccalaureate degree in Political Science. UNBC and the Political Science Program are committed

Northern British Columbia, University of

203

Influence of deposition pressure and pulsed dc sputtering on pumping properties of Ti-Zr-V nonevaporable getter films  

SciTech Connect (OSTI)

The performance of a UHV vessel can be improved with a new CERN technology nonevaporable getter (NEG) coating, which is already widely used for accelerator vacuum chambers. Better understanding of the processes involved in NEG film deposition, activation, and poisoning should allow optimization and engineering of the film properties, which are necessary for a particular application. Ti-Zr-V NEG films were created by magnetron sputtering from a single Ti-Zr-V target, and the NEG performance and morphology dependence on deposition pressure, sputtering conditions, and substrate surface roughness have been investigated. It was found that the average grain size of the Ti-Zr-V film was 5-6 nm and was broadly independent of the substrate material and deposition conditions. However, film topography and density were shown to depend very much on the substrate surface roughness and deposition conditions. Rough substrates, high working pressures, and the absence of ion bombardment produced open columnar structures, whereas smooth substrates, ion assistance, and low pressures produced much denser layers. X-ray photoelectron spectroscopy studies have shown that full regeneration occurred at 300 degree sign C but film activation started at temperatures of as low as 160 degree sign C. The CO sticking probability reaches its maximum after activation at 250 degree sign C and is found to be up to 0.3 with a pumping capacity in the range of 0.8-1.2 ML. The samples activated at 160 degree sign C have a reduced pumping speed and capacity by an order of magnitude.

Malyshev, O. B.; Valizadeh, R.; Colligon, J. S.; Hannah, A.; Middleman, K. J.; Patel, S.; Vishnyakov, V. M. [ASTeC Vacuum Science Group, STFC Daresbury Laboratory, Warrington WA4 4AD (United Kingdom); Department of Chemistry, Manchester Metropolitan University Manchester M1 5GD (United Kingdom); ASTeC Vacuum Science Group, STFC Daresbury Laboratory, Warrington WA4 4AD (United Kingdom); Department of Chemistry, Manchester Metropolitan University, Manchester, M1 5GD (United Kingdom)

2009-05-15T23:59:59.000Z

204

Synthesis and structural studies on (1?x)Bi(Mg{sub 1/2}Ti{sub 1/2})O{sub 3}?xPbTiO{sub 3} piezoceramics  

SciTech Connect (OSTI)

We present here the structural studies on (1?x)Bi(Mg{sub 1/2}Ti{sub 1/2})O{sub 3}?xPbTiO{sub 3} (BMT-xPT) piezoceramics with x=0.28, 0.37 and 0.45 using powder x-ray diffraction data. Rietveld refinement of powder x-ray diffraction data reveals the tetragonal structure (space group P4mm) for the compositions with x>0.40 and rhombohedral (space group R3m) for the compositions with x<0.30 of BMT-xPT ceramics. The morphotropic phase boundary is found for the intermediate composition with 0.30

Upadhyay, Ashutosh, E-mail: akhilesh-bhu@yahoo.com; Pandey, Rishikesh, E-mail: akhilesh-bhu@yahoo.com; Anand, Shashwat, E-mail: akhilesh-bhu@yahoo.com; Singh, Akhilesh K., E-mail: akhilesh-bhu@yahoo.com [School of Materials Science and Technology, Indian Institute of Technology (Banaras Hindu University), Varanasi-221005 (India)

2014-04-24T23:59:59.000Z

205

Influences of alcoholic solvents on spray pyrolysis deposition of TiO{sub 2} blocking layer films for solid-state dye-sensitized solar cells  

SciTech Connect (OSTI)

Influences of alcoholic solvents for titanium diisopropoxide bis(acetylacetonate) (TPA) precursor solutions on the spray pyrolysis deposited TiO{sub 2} films and the photovoltaic performance of the solid-state dye-sensitized solar cells (SDSCs) using these TiO{sub 2} films as the blocking layers were investigated. Smooth TiO{sub 2} films were obtained by spray pyrolysis deposition of a TPA solution in isopropanol (IPA) at a relatively low temperature of 260 Degree-Sign C. On the other hand, when ethanol was used as solvent, the TiO{sub 2} films fabricated at the same temperature showed much rougher surfaces with many pinholes. Our results showed that ethanol reacts with TPA to form titanium diethoxide bis(acetylacetonate) (TEA), which requires a higher thermal decomposition temperature than that of TPA. SDSCs with TiO{sub 2} blocking layer films fabricated using a TPA solution in IPA showed higher power conversion efficiencies with smaller variations. - Graphical abstract: Alcoholic solvents used for the TiO{sub 2} precursor play a critical role in determining the surface morphology of blocking layers and thus the photovoltaic performance of the SDSCs. Highlights: Black-Right-Pointing-Pointer Solvent influences morphology of spray pyrolysis deposited TiO{sub 2} blocking layer. Black-Right-Pointing-Pointer Ethanol reacts with TPA, resulting poor quality of blocking layer. Black-Right-Pointing-Pointer Isopropanol is better than ethanol for obtaining smooth blocking layer. Black-Right-Pointing-Pointer SDSC with blocking layer made with isopropanol showed better performance.

Jiang, Changyun, E-mail: jiangc@imre.a-star.edu.sg [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)] [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore); Koh, Wei Lin; Leung, Man Yin [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)] [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore); Hong, Wei [Department of Chemical Engineering and Waterloo Institute for Nanotechnology (WIN), University of Waterloo, 200 University Ave West ON, Waterloo, Canada N2L 3G1 (Canada)] [Department of Chemical Engineering and Waterloo Institute for Nanotechnology (WIN), University of Waterloo, 200 University Ave West ON, Waterloo, Canada N2L 3G1 (Canada); Li, Yuning, E-mail: yuning.li@uwaterloo.ca [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore) [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore); Department of Chemical Engineering and Waterloo Institute for Nanotechnology (WIN), University of Waterloo, 200 University Ave West ON, Waterloo, Canada N2L 3G1 (Canada); Zhang, Jie [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)] [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)

2013-02-15T23:59:59.000Z

206

N NE EX XT T G GE EN NE ER RA AT TI IO ON N S SA AF FE EG  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NE NE EX XT T G GE EN NE ER RA AT TI IO ON N S SA AF FE EG GU UA AR RD DS S I IN NI IT TI IA AT TI IV VE E ( (N NG GS SI I) ) O OP PP PO OR RT TU UN NI IT TI IE ES S F FO OR R S ST TU UD DE EN NT TS S A AN ND D Y YO OU UN NG G P PR RO OF FE ES SS SI IO ON NA AL LS S I IN NT TE ER RE ES ST TE ED D I IN N S SA AF FE EG GU UA AR RD DS S/ /N NO ON NP PR RO OL LI IF FE ER RA AT TI IO ON N The Next Generation Safeguards Initiative (NGSI) was launched by the National Nuclear Security Administration (NNSA) in FY 2008 to develop the policies, concepts, technologies, expertise, and infrastructure necessary to strengthen and sustain the international safeguards system as it evolves to meet new challenges over the next 25 years. NGSI's Human Capital Development subprogram 1 aims to revitalize and expand the international safeguards human capital base in the United States by attracting, educating, training, and retaining

207

Effect of annealing on SiO{sub x}-TiO{sub 2} axial heterostructure nanowires and improved photodetection  

SciTech Connect (OSTI)

Glancing angle deposition technique has been used to synthesize the axial heterostructure SiO{sub x}-TiO{sub 2} nanowires (NWs) on the Si substrate. The field emission gun scanning electron microscope image shows the formation of perpendicular NWs on Si substrate. A typical transmission electron microscope image confirms the heterostructure NW which consists of SiO{sub x} of length ?130?nm and TiO{sub 2} of length ?170?nm. The amorphous NWs transformed to polycrystalline nature after annealing. The trap assisted radiative recombination process is absent for the annealed NWs. An averagely 1.1 fold enhanced photoabsorption was exhibited by the annealed NWs in the 200–350?nm region and 1.5 fold in the 500–850?nm region. The leakage current (2.6?×?10{sup ?8} A/cm{sup 2} at ?0.5?V) significantly reduced for annealed NWs device. A maximum 1.4?×?10{sup 3} times enlarged photodetection has been observed for annealed device.

Dhar, J. C.; Singh, N. K. [Department of Electronics and Communication Engineering, National Institute of Technology Nagaland, Dimapur, Nagaland 797103 (India); Mondal, A., E-mail: aniruddhamo@gmail.com; Chakrabartty, S. [Department of Electronics and Communication Engineering, National Institute of Technology Agartala, Jirania, Tripura (West) 799055 (India); Bhattacharyya, A. [Department of Radio Physics and Electronics, University of Calcutta, Kolkata 700009 (India); Chattopadhyay, K. K. [Department of Physics, Jadavpur University, Kolkata 700032 (India)

2013-12-28T23:59:59.000Z

208

Electrospark deposition of Al2O3–TiB2/Ni composite-phase surface coatings on Cu–Cr–Zr alloy electrodes  

Science Journals Connector (OSTI)

Abstract To improve electrode life during the resistance spot welding of galvanized steel plates, an Al2O3–TiB2 composite coating was synthesized on the surfaces of spot-welding electrodes through an electrospark deposition process. The microstructure, elemental composition, phase structure, and mechanical properties of the coating were characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction analysis, and microhardness testing. It was found that extensive cracking occurred in the monolithic Al2O3–TiB2 coating and at the coating–electrode interface. When the Al2O3–TiB2 coating was deposited on electrodes precoated with Ni, the number of defects decreased significantly. Further, delamination did not occur, and fewer cracks were formed. The average hardness of the multilayered Al2O3–TiB2/Ni coating was approximately 2200 HV and higher than that of the monolithic Al2O3–TiB2 coating (1100 HV).

Ping Luo; Shijie Dong; Anzhuo Yangli; Shixuan Sun; Zhong Zheng; Huihu Wang

2014-01-01T23:59:59.000Z

209

Characterization of passive oxide film on a Ti-5%Ta-1.8%Nb alloy on exposure to severe oxidizing conditions  

SciTech Connect (OSTI)

This paper presents the results of a study on the characteristics of the passive oxide film that forms on the surface of an {alpha} + {beta} Ti-5%Ta-1.8%Nb alloy, which possesses good corrosion resistance in severe oxidizing environment of boiling 11.5 M nitric acid. Through systematic structure-property studies, the microstructure with low corrosion rate (< 1 mpy) in liquid, vapor and condensate phases of nitric acid was identified. The characteristics of the passive film, which imparts corrosion resistance to the alloy, are influenced by its microstructure, temperature and concentration of the acid. The microstructure, thickness and composition of the oxide film were characterized using different techniques. TiO{sub 2}, Nb{sub 2}O{sub 5} and Ta{sub 2}O{sub 5} formed on exposure to vapor and condensate phases, while TiO{sub 2} was observed on exposure to the liquid phase. Detailed microstructural studies showed that the passive film consists of nano-crystalline phases of titanium and tantalum oxides, predominantly anatase in an amorphous matrix. Based on these studies, the mechanism of corrosion of the alloy is derived. - Research Highlights: {yields}Liquid phase corrosion results in a thicker and protective oxide film. {yields}Oxide film is a mixture of amorphous and nano-crystalline anatase. {yields}Higher amounts of Nb{sub 2}O{sub 5} and Ta{sub 2}O{sub 5} form on vapor and condensate phase corrosion. {yields}High corrosion rate in condensate phase is due to selective dissolution of Ti in {alpha} phase.

Mythili, R.; Saroja, S., E-mail: saroja@igcar.gov.in; Vijayalakshmi, M.

2010-12-15T23:59:59.000Z

210

Institutions and Cross-border Mergers and Acquisitions (M&A) Value Creation  

E-Print Network [OSTI]

institutions on cross-border M&A value creation. I further examine the moderating effects of host country political institutions on the relationship between host country regulatory institutions and cross-border M&A value creation. Moreover, I investigate...

Zhu, Hong

2012-02-14T23:59:59.000Z

211

MA 232 Exam 1 (Green) Spring 2014  

E-Print Network [OSTI]

MA 23200 - Exam 1 (Green). 1. Find the area of the .... D. 4. E. Does not exist. 12. The velocity of a car over the time period 0 ? t ? 3 is given by the function.

2014-02-03T23:59:59.000Z

212

MA 16020 SI slide.pptx  

E-Print Network [OSTI]

SI Study Sessions for MA 16020 -? Spring 2015. Mondays. 4:30 – 5:20 KRCH 464. Tuesdays. 5:30 – 6:20 RHPH 162. Thursdays. 4:30 – 5:20 ARMS 1103.

OwenDavis

2015-01-12T23:59:59.000Z

213

REGISTRATION LIST P PR RE ES SO OL LI IC CI IT TA AT TI IO ON  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

REGISTRATION LIST REGISTRATION LIST P PR RE ES SO OL LI IC CI IT TA AT TI IO ON N C CO ON NF FE ER RE EN NC CE E August 9, 2011 Holiday Inn Capitol  550 C Street, SW  Washington, DC 20024 Page 1 of 9 Instructions: (iii) Please indicate (by checking the appropriate box) whether the organization you represent is a large business, small business, or not a business. (iv) Please indicate (by checking the appropriate box) whether your name or the name of your organization may be released on the NNSA website as an attendee of this conference. (v) Please provide an email address if you would like it to be released on the NNSA website. An email address cannot be released if you select neither in column (iv). Name Organization Name Large/Small (iii) Release Attendance? (iv) Email (to release)

214

Impact of Solvent on Photocatalytic Mechanisms: Reactions of Photodesorption Products with Ice Overlayers on the TiO2(110) Surface  

SciTech Connect (OSTI)

The effects of water and methanol ice overlayers on the photodecomposition of acetone on rutile TiO2(110) were evaluated in ultrahigh vacuum (UHV) using photon stimulated desorption (PSD) and temperature programmed desorption (TPD). In the absence of ice overlayers, acetone photodecomposed on TiO2(110) at 95 K by ejection of a methyl radical into the gas phase and formation of acetate on the surface. With ice overlayers, the methyl radicals are trapped at the interface between TiO2(110) and the ice. When water ice was present, these trapped methyl radicals reacted either with each other to form ethane or with other molecules in the ice (e.g., water or displaced acetone) to form methane (CH4), ethane (CH3CH3) and other products (e.g., methanol), with all of these products trapped in the ice. The new products were free to revisit the surface or depart during desorption of the ice. When methanol ice was present, methane formation came about only from reaction of trapped methyl radicals with the methanol ice. Methane and ethane slowly leaked through methanol ice overlayers into vacuum at 95 K, but not through water ice overlayers. Different degrees of site competition between water and acetone, and between methanol and acetone led to different hydrogen abstraction pathways in the two ices. These results provide new insights into product formation routes and solution-phase radical formation mechanisms that are important in heterogeneous photocatalysis.

Shen, Mingmin; Henderson, Michael A.

2011-04-07T23:59:59.000Z

215

On the development of high quality NiTi shape memory and pseudoelastic parts by additive manufacturing  

Science Journals Connector (OSTI)

Additive manufacturing provides an attractive processing method for nickel?titanium (NiTi) shape memory and pseudoelastic parts. In this paper, we show how the additive manufacturing process affects structural and functional properties of additively manufactured NiTi and how the process parameter set-up can be optimized to produce high quality NiTi parts and components. Comparisons of shape recovery due to shape memory and pseudoelasticity in additively manufactured and commercial NiTi exhibit promising potential for this innovative processing method.

Christoph Haberland; Mohammad Elahinia; Jason M Walker; Horst Meier; Jan Frenzel

2014-01-01T23:59:59.000Z

216

Effect of K and Ca on catalytic activity of Mn-CeO x /Ti-PILC  

Science Journals Connector (OSTI)

Mn-CeO x /Ti-pillared clay (PILC) is an attractive catalyst for selective catalytic... x at low temperature because of its low cost. The poison...

Boxiong Shen; Lidan Deng; Jianhong Chen

2013-08-01T23:59:59.000Z

217

MA in Modern Languages The School of Languages and Literatures invites applications for its taught MA in Modern  

E-Print Network [OSTI]

MA in Modern Languages. With dedicated academic staff in its subject areas of French, German, Italian courses on cultural and literary theory, choosing their remaining four from a broad range of options Theory Introduction to Literary Theory Minor Thesis (30 credits) Optional Modules (Four of:) French

218

DOE - Office of Legacy Management -- Woburn Landfill - MA 07  

Office of Legacy Management (LM)

Woburn Landfill - MA 07 FUSRAP Considered Sites Site: Woburn Landfill (MA.07) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name:...

219

Comparison of \\{WTi\\} and WTi(N) as diffusion barriers for Al and Cu metallization on Si with respect to thermal stability and diffusion behavior of Ti  

Science Journals Connector (OSTI)

Abstract The thermal stability of \\{WTi\\} and WTi(N) as diffusion barriers for Al and Cu metallization on Si (1 0 0) was investigated by time of flight secondary ion mass spectrometry (ToF-SIMS) depth profiling, X-ray diffraction (XRD), electron microscopy (SEM and TEM) and X-ray photoelectron spectroscopy (XPS). For both, Al and Cu, Ti diffusion out of \\{WTi\\} into the metal was proved to occur at elevated temperatures (400 °C for Al and 600 °C for Cu) which further results in barrier film failure. Nitrogen incorporation into \\{WTi\\} leads to an elimination of the Ti diffusion and consequently to a better thermal stability of the barrier film. It is shown that besides crystal structure, Ti diffusion into the metallization is an essential factor of the barrier failure mechanism. The failure temperature for Al is lower than for Cu.

M. Fugger; M. Plappert; C. Schäffer; O. Humbel; H. Hutter; H. Danninger; M. Nowottnick

2014-01-01T23:59:59.000Z

220

EFFECTS of DUAL DOPING OF C AND TiC NANOPARTICLES ON SUPERCONDUCTING PROPERTIES OF Fe-SHEATHED MgB{sub 2} TAPES  

SciTech Connect (OSTI)

Fe-sheathed MgB{sub 2} wires doped with C and TiC nanoparticles in the formula MgB{sub 2-x}C{sub x}+yTiC(x = 0, 0.05, 0.1, 0.15, 0.2, and y = 0, 2.5 wt.%, 5 wt.%) were investigated. X-ray diffraction patterns indicate that the core materials in the wires contain small amount of Fe{sub 2}B and MgO impurity phases, and the peaks shift with the variation of doping amount. It is found that the critical temperature T{sub c} decreases with the increase of doping amount. Strong in-field current carrying capability enhancement was observed on MgB{sub 1.95}C{sub 0.05}+2.5 wt.% TiC.

Fang, H.; Liang, G. [Department of Physics, Sam Houston State University, Huntsville, Texas, 77341-2267 (United States)

2010-04-08T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

An Integrated Power Pack of Dye-Sensitized Solar Cell and Li Battery Based on Double-Sided TiO2 Nanotube Arrays  

E-Print Network [OSTI]

is based on a silicon solar panel and a solid-state lithium battery as the two independent parts, whichAn Integrated Power Pack of Dye-Sensitized Solar Cell and Li Battery Based on Double-Sided TiO2 harvest and storage processes. This power pack incorporates a series-wound dye- sensitized solar cell

Wang, Zhong L.

222

U-178: VMware vMA Library Loading Error Lets Local Users Gain...  

Broader source: Energy.gov (indexed) [DOE]

A vulnerability was reported in VMware vMA PLATFORM: Version(s): vMA 4.0, 4.1, 5 patch 1 (5.0.0.1) ABSTRACT: A local user can obtain elevated privileges on the target...

223

? decay of 40Ti and 41Ti and implication for solar-neutrino detection  

Science Journals Connector (OSTI)

The ? decay of 40Ti and 41Ti was studied by measuring the ?-delayed proton and ? emission. The half-lives for 40Ti and 41Ti were determined to be 54(2) and 82(3) ms, respectively. The experimental ?-decay strengths are compared with shell-model calculations and results from other measurements. The integrated Gamow-Teller strengths for 40Ti and 41Ti were found to be quenched, compared to the calculations, by factors of 0.79(3) and 0.93(3), respectively. Based on the experimental 40Ti??-decay strength, the neutrino absorption cross section and induced neutrino event rates for 40Ar were determined to be 14.3(3)×10-43?cm2 and 9.4±0.2(stat)-1.6+1.3(syst) SNU, respectively.

W. Liu; M. Hellström; R. Collatz; J. Benlliure; L. Chulkov; D. Cortina Gil; F. Farget; H. Grawe; Z. Hu; N. Iwasa; M. Pfützner; A. Piechaczek; R. Raabe; I. Reusen; E. Roeckl; G. Vancraeynest; A. Wöhr

1998-11-01T23:59:59.000Z

224

A density functional theory study of atomic steps on stoichiometric rutile TiO{sub 2}(110)  

SciTech Connect (OSTI)

We present a detailed theoretical study of the energetics of stoichiometric steps on the (110) surface of rutile TiO{sub 2}. Step structures running along the ?001?, ?11{sup ¯}1?, and ?11{sup ¯}0? directions including bulk-terminations and possible reconstructions have been considered. A robust method for extracting surface and step energies of vicinal surfaces, where the surface energies converge slowly with respect to slab thickness, is outlined and used. Based on the calculated step energies a 2D Wulff-construction is presented from which it can be concluded that in equilibrium only oxygen terminated steps running along the ?001? directions and reconstructed steps along the ?11{sup ¯}1? directions should be present. Finally it is found that under conditions of stoichiometry the reconstructed ?11{sup ¯}1? steps should be more than twice as abundant as oxygen terminated ?001? steps.

Stausholm-Møller, Jess; Kristoffersen, Henrik Høgh; Martinez, Umberto; Hammer, Bjørk [Interdisciplinary Nanoscience Center (iNANO) and Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark)] [Interdisciplinary Nanoscience Center (iNANO) and Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark)

2013-12-21T23:59:59.000Z

225

In situ Characterization of Pt Catalysts Supported on Ceria Modified TiO(2) for the WGS reaction: Influence of Ceria Loading  

SciTech Connect (OSTI)

This work analyzes the influence of cerium content (6-15 wt%) on a TiO{sub 2} support over the structure and water gas shift (WGS) activity of Pt catalysts. The structural properties of these Pt/Ce-TiO{sub 2} catalysts were characterized by XRD, TEM and XANES. Physicochemical characterization of the catalysts showed differences in the structure and dispersion of Ce entities on the support with Ce loading. For the samples with low ceria content (6 wt%), cerium is deposited on the support in the form of CeO{sub x} clusters in a highly dispersed state in close interaction with the Ti atoms. The formation of CeO{sub x} clusters at low Ce-loading on the support facilitates the dispersion of small particles of Pt and improves the reducibility of ceria component at low temperatures. The changes in platinum dispersion and support reducibility with Ce-loading on the TiO{sub 2} support lead to significant differences in the WGS activity. Pt supported on the sample with lower Ce content (6 wt%) shows better activity than those corresponding to catalysts with higher Ce content (15 wt%). Activity measurements coupled with catalysts characterization suggest that the improvement in the reducibility of the support with lower Ce content was associated with the presence of CeO{sub x} clusters of high reducibility that improve the chemical activity of the oxide-metal interfaces at which the WGS reaction takes place.

Rodriguez J. A.; Barrio, L.; Zhou, G.; Gonzalez, I.D.; Estrella, M.; Hanson, J.; Navarro, R.M.; Fierro, J.L.G.

2012-01-01T23:59:59.000Z

226

DOE - Office of Legacy Management -- Tracerlab Inc - MA 11  

Office of Legacy Management (LM)

Tracerlab Inc - MA 11 Tracerlab Inc - MA 11 FUSRAP Considered Sites Site: TRACERLAB, INC. (MA.11 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 130 High Street , Boston , Massachusetts MA.11-1 Evaluation Year: 1987 MA.11-3 Site Operations: Research and development regarding uranium irradiation and cesium blocks during the early 1950s. MA.11-1 MA.11-3 Site Disposition: Eliminated - NRC licensed MA.11-2 MA.11-3 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium, Cesium MA.11-1 Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to TRACERLAB, INC. MA.11-1 - Tracerlab Letter; Epple to Mason; Subject: Steps to Secure

227

CO adsorption on (111) and (100) surfaces of the Pt/sub 3/Ti alloy: evidence for parallel binding and strong activation of CO  

SciTech Connect (OSTI)

An atom superposition and electron delocalization molecular orbital (ASED-MO) study has been made of CO adsorption on a 40-atom cluster model of the (111) surface and a 36-atom cluster model of the (100) surface of the Pt/sub 3/Ti alloy. Parallel binding to high-coordinate sites associated with Ti and low CO bond scission barriers are predicted for both surfaces. The preference for parallel adsorption is a consequence of the nature of the CO ..pi..=to-surface donation interactions. On Ti sites the ..pi.. orbitals donate to the early empty Ti 3d band and the antibonding counterpart orbitals are empty. Thus the ..pi.. donation makes substantial contributions to the adsorption bond order that are in addition to the contributions from 5 sigma donation and metal backbonding to the ..pi../sup */ orbitals. Altogether these bonding interactions favor the lying down orientation. On Pt sites, on the other hand, the ..pi.. donation antibonding counterpart orbitals are occupied so that the net interaction with Pt is a closed-shell repulsion. CO bonds upright in order to minimize the ..pi.. interaction, and concomitantly, the closed-shell repulsion, while maintaining 5sigma donation and ..pi../sup */ backbonding stabilizations. Comparisons are made with the results for a 40-atom cluster model of the unalloyed Pt(111) surface. It is shown that the extended Hueckel parameterization is inappropriate for studying CO and adsorption to Pt with ASED-MO theory because it incorrectly favors adsorption bonding through the oxygen end.

Mehandru, S.P.; Anderson, A.B.; Ross, P.N.

1986-07-01T23:59:59.000Z

228

Impact of Sr segregation on the electronic structure and oxygen reduction activity of SrTi[subscript 1?x]Fe[subscript x]O[subscript 3] surfaces  

E-Print Network [OSTI]

The correlation between the surface chemistry and electronic structure is studied for SrTi[subscript 1?x]Fe[subscript x]O[subscript 3] (STF), as a model perovskite system, to explain the impact of Sr segregation on the ...

Chen, Yan

229

Growth of two-dimensional ultrathin anatase TiO2 nanoplatelets on graphene for high-performance lithium-ion battery  

Science Journals Connector (OSTI)

Ultrathin 2-D anatase TiO2...nanoplatelets with a size of 15 nm and a thickness of only about 2 nm can be directly grown on the surface of graphene oxide support via a new facile one- ... , while the latter is si...

Yaodong Shen; Jun Song Chen; Jixin Zhu; Qingyu Yan…

2013-09-01T23:59:59.000Z

230

Laser cladding Al-Si/Al2O3-TiO2 composite coatings on AZ31B magnesium alloy  

Science Journals Connector (OSTI)

To improve the wear resistance and corrosion resistance of magnesium alloys, a 5 kW continuous wave CO2 laser was used to investigate the laser surface cladding on AZ31B magnesium alloys with Al-Si/...2O3 -TiO2.....

Zeqin Cui ???; Hongwei Yang…

2012-12-01T23:59:59.000Z

231

Water adsorption on SrTiO3(001): II. Water, water, everywhere A.E. Becerra-Toledo a,  

E-Print Network [OSTI]

Water adsorption on SrTiO3(001): II. Water, water, everywhere A.E. Becerra-Toledo a, , J January 2012 Available online 17 January 2012 Keywords: Strontium titanate Density functional theory Water adsorption Surface reconstruction X-ray photoelectron spectroscopy Oxide surfaces The role of water

Marks, Laurence D.

232

Interface structure and thermal stability of epitaxial SrTiO{sub 3} thin films on Si (001)  

SciTech Connect (OSTI)

We have used medium energy ion scattering, temperature programmed desorption, and atomic force microscopy to study the interface composition and thermal stability of epitaxial strontium titanate thin films grown by molecular-beam epitaxy on Si (001). The composition of the interface between the film and the substrate was found to be very sensitive to the recrystallization temperature used during growth, varying from a strontium silicate phase when the recrystallization temperature is low to a Ti-rich phase for a higher recrystallization temperature. The films are stable towards annealing in vacuum up to {approx}550 deg.C, where SrO desorption begins and the initially flat film starts to roughen. Significant film disintegration occurs at 850 deg.C, and is accompanied by SiO and SrO desorption, pinhole formation, and finally titanium diffusion into the silicon bulk.

Goncharova, L. V.; Starodub, D. G.; Garfunkel, E.; Gustafsson, T.; Vaithyanathan, V.; Lettieri, J.; Schlom, D. G. [Department of Physics and Astronomy, and Laboratory for Surface Modification, Rutgers University, Piscataway, New Jersey 08854 (United States); Department of Chemistry and Chemical Biology, and Laboratory for Surface Modification, Rutgers University, Piscataway, New Jersey 08854 (United States); Department of Physics and Astronomy, and Laboratory for Surface Modification, Rutgers University, Piscataway, New Jersey 08854 (United States); Department of Material Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States)

2006-07-01T23:59:59.000Z

233

Raman spectra and magnetization of all-ferromagnetic superlattices grown on (110) oriented SrTiO{sub 3}  

SciTech Connect (OSTI)

Superlattices consist of two ferromagnets La{sub 0.7}Sr{sub 0.3}MnO{sub 3} (LSMO) and SrRuO{sub 3} (SRO) were grown in (110)-orientation on SrTiO{sub 3} (STO) substrates. The x-ray diffraction and Raman spectra of these superlattices show the presence of in-plane compressive strain and orthorhombic structure of less than 4 u.c. thick LSMO spacer, respectively. Magnetic measurements reveal several features including reduced magnetization, enhanced coercivity, antiferromagnetic coupling, and switching from antiferromagnetic to ferromagnetic coupling with magnetic field orientations. These magnetic properties are explained by the observed orthorhombic structure of spacer LSMO in Raman scattering which occurs due to the modification in the stereochemistry of Mn at the interfaces of SRO and LSMO.

Behera, B. C.; Ravindra, A. V.; Padhan, P. [Department of Physics, Indian Institute of Technology Madras, Chennai 600036 (India); Prellier, W. [Laboratoire CRISMAT, CNRS UMR 6508, ENSICAEN, 6 Bd du Marehal Juin, F-14050 Caen Cedex (France)

2014-03-03T23:59:59.000Z

234

Preparation of TiO{sub 2} thin films on the inner surface of a quartz tube using atmospheric-pressure microplasma  

SciTech Connect (OSTI)

Titanium dioxide (TiO{sub 2}) thin films were prepared on the inner surface of a quartz tube, with inner and outer diameters of 1 and 3 mm, respectively, using plasma-enhanced chemical vapor deposition with titanium tetraisopropoxide and oxygen (O{sub 2}) as reactants and helium as the carrier gas at atmospheric pressure. A microplasma was generated inside the tube by rf (13.56 MHz) excitation using externally attached parallel-plate electrodes. The characteristics of the deposited films were examined by scanning electron microscopy, x-ray photoelectron spectroscopy, and x-ray diffraction. A typical as-deposited film had an amorphous structure with a smooth surface and was transparent. With increasing O{sub 2} concentration in the plasma gas phase, the deposited film surface was covered with a large number of TiO{sub 2} nanoparticles. However, the deposited films were a mixture of TiO{sub 2} and amorphous carbon and showed rough surface in the absence of O{sub 2} in the source gas. The effects of the O{sub 2} concentration in the plasma gas on the characteristics of the deposited TiO{sub 2} films are discussed on the basis of the analysis of the gas species generated in the plasma using optical emission spectroscopy.

Yoshiki, Hiroyuki; Saito, Taku [Department of Electrical and Electronic Engineering, Tsuruoka National College of Technology, 104 Inooka-Sawada, Tsuruoka, Yamagata 997-8511 (Japan)

2008-05-15T23:59:59.000Z

235

VIDEO SEMINAR of Ma Jun's 6/17/02 presentation: China's Water Resources:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

VIDEO SEMINAR of Ma Jun's 6/17/02 presentation: China's Water Resources: VIDEO SEMINAR of Ma Jun's 6/17/02 presentation: China's Water Resources: Crisis and Opportunity Speaker(s): Ma Jun Date: July 3, 2002 - 12:00pm Location: 90-3122 The rivers in China, and the hundreds of millions who depend on them, are in trouble. A water crisis looms large in most parts of China. In his book, China Water Crisis, Ma Jun traces 4,000 years of the history of China's watersheds, and their mis/management. Armed with scientific data and compelling stories, Ma reveals the causes and character of the looming ecological disaster. His book has been quoted in The Economist and many western media. Limited water resources pose a major threat to social and economic development in the 21st century. Three Gorges Dam and redirecting water from south to north occupy the main focus of the efforts to increase

236

Dampfdruckmessungen und Protonenresonanzuntersuchung an Hydriden der intermetallischen Phasen Ti2(Ni, Co) und Ti2(Ni, Fe)  

Science Journals Connector (OSTI)

NMR and hydrogen equilibrium pressure measurements were performed on hydrides of the intermetallic compounds Ti2(Ni, Co) and Ti2(Ni, Fe). The following values of enthalpy ?H and entropy ?S for the formation of th...

Engelbert Tuscher; Kurt Hiebl; Helmut Bittner

1981-02-01T23:59:59.000Z

237

Engineering study on TiSnSb-based composite negative electrode for Li-ion batteries  

Science Journals Connector (OSTI)

Abstract Micrometric TiSnSb is a promising negative electrode material for Li-ion batteries when formulated with carboxymethyl cellulose (CMC) binder and a mixture of carbon black and carbon nanofibers, and cycled in a fluoroethylene carbonate (FEC)-containing electrolyte. Here, other binder systems were evaluated, polyacrylic acid (PAAH) mixed with CMC, CMC in buffered solution at pH 3 and amylopectin. However CMC showed the better performance in terms of cycle life of the electrode. Whatever the binder, cycle life decreases with increasing the active mass loading, which is attributed to both the precipitation of liquid electrolyte degradation products and to the loss of electrical contacts within the composite electrode and with the current collector as a consequence of the active particles volume variations. Furthermore, calendaring the electrode unfortunately decreases the cycle life. The rate performance was studied as a function of the active mass loading and was shown to be determined by the electrode polarization resistance. Finally, full cells cycling tests with Li1Ni1/3Co1/3Mn1/3O2 at the positive electrode were done. 60% of the capacity is retained after 200 cycles at the surface capacity of 2.7 mAh cm?2.

H.A. Wilhelm; C. Marino; A. Darwiche; P. Soudan; M. Morcrette; L. Monconduit; B. Lestriez

2015-01-01T23:59:59.000Z

238

MA 152 Exam 1 Memo  

E-Print Network [OSTI]

Feb 13, 2014 ... (plan on arriving about 15 minutes early to find your assigned seat). 1) Exam 1 ... the study plan in. MyMathLab or the Review link from the MyMathLab gradebook.

math

2014-02-12T23:59:59.000Z

239

Film Coating Process Research and Characterization of TiN Coated Racetrack-type Ceramic Pipe  

E-Print Network [OSTI]

TiN film was coated on the internal face of racetrack-type ceramic pipe by three different methods: radio-frequency sputtering, DC sputtering and DC magnetron sputtering. The deposition rates of TiN film under different coating methods were compared. According to the AFM, SEM, XPS test results,these properties were analyzed, such as TiN film roughness and surface morphology. At the same time, the deposition rates were studied under two types' cathode, Ti wires and Ti plate. According to the SEM test results, Ti plate cathode can improve the TiN/Ti film deposition rate obviously.

Wang, Jie; Zhang, Bo; Wei, Wei; Fan, Le; Pei, Xiangtao; Hong, Yuanzhi; Wang, Yong

2015-01-01T23:59:59.000Z

240

MA 161 with 161E  

E-Print Network [OSTI]

\\Hf, ~ Q—VQ-O'? '- ixam' \\. Zoom-8%. SEATING CHART. 1 0 8 .SMITH. P 7 7/ .l 7 7 7 7 7 71 _/. A B .C D E F G H .I J K L M N 0 oo 8 oo 8 8 8? 8d 00a 8 8 oo.j on.

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

MA 22400: Online Homework Instructions  

E-Print Network [OSTI]

Friday, January 20, and is due by 7:00 pm on Monday, January 23. .... (Sorry, there is currently no way to keep it off the screen.) ... in; my browser keeps locking up; the answer box does not appear, it says to enter an answer, but I already have ...

odavis

2012-01-16T23:59:59.000Z

242

Development of a 6 degree-of-freedom manipulator arm for use on an urban search and rescue robot by Peter M.A. Henson.  

E-Print Network [OSTI]

??Includes abstract. This document reports on the design, construction and testing of the manipulator arm that is to be fitted to UCT's Urban Search and… (more)

Henson, Peter M.A.

2012-01-01T23:59:59.000Z

243

Microstructure and mechanical properties of Ni-based composite coatings reinforced by in situ synthesized TiB2 + TiC by laser cladding  

Science Journals Connector (OSTI)

A Ni-based composite coating reinforced by in situ synthesized TiB2...and TiC particles was fabricated on Ti6Al4V by laser cladding. An attempt was made to correlate the...2, flower-like or equiaxial TiC, and fin...

Jun Li; Xuan-jun Zhang; Hui-ping Wang…

2013-01-01T23:59:59.000Z

244

Fabrication technology for ODS Alloy MA957  

SciTech Connect (OSTI)

A successful fabrication schedule has been developed at Carpenter Technology Corporation for the production of MA957 fuel and blanket cladding. Difficulties with gun drilling, plug drawing and recrystallization were overcome to produce a pilot lot of tubing. This report documents the fabrication efforts of two qualified vendors and the support studies performed at WHC to develop the fabrication-schedule.

ML Hamilton; DS Gelles; RJ Lobsinger; MM Paxton; WF Brown

2000-03-16T23:59:59.000Z

245

Ma, Dong and Gress QUARTERLY PROGRESS REPORT  

E-Print Network [OSTI]

and Leachability of Coal Combustion Residues in Florida Principal investigator: Lena Q. Ma- Environmental soil of this study is to determine the physical and chemical characteristics of coal combustion residues (CCR chemistry (Professor) Affiliation: Soil and Water Science Department, UF, Gainesville, FL 32611 Associate

Ma, Lena

246

Grid Security: Expecting the Mingchao Ma  

E-Print Network [OSTI]

Grid Security: Expecting the Unexpected Mingchao Ma STFC � Rutherford Appleton Laboratory, UK #12;Slide 2 Overview � Security Service Challenges (SSC) Review � Grid Security Incident � What had happened of the LCG/EGEE Grid Sites (Dec 2008) http://www.gridpp.ac.uk/security/ssc/ https

University College London

247

EFFECT OF AGING ON THE PHASE TRANSFORMATION AND MECHANICAL BEHAVIOR OF Ti36Ni49Hf15 HIGH  

E-Print Network [OSTI]

and Engineering, Harbin Institute of Technology, Harbin 150001, People's Republic of China (Received August 19 the microstructure, transformation temperature, mechanical properties and shape memory effects (SMEs) for Ti36Ni49Hf

Zheng, Yufeng

248

Catalytic epoxidation of propene with H2O-O2 reactants on Au/TiO2  

SciTech Connect (OSTI)

Au/TiO{sub 2} catalysts form hydroperoxy species from H{sub 2}O-O{sub 2} mixtures at near-ambient temperatures. These species can be used in the selective epoxidation of propene to propylene oxide.

Ojeda, Manuel; Iglesia, Enrique

2008-11-05T23:59:59.000Z

249

Low-Temperature Desorption of N2O from NO on Rutile TiO2(110...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

decreases rapidly as the initially clean, reduced TiO2(110) surface with 5% oxygen vacancies (VO’s) becomes covered with oxygen adatoms and unreacted NO. The maximum...

250

Influence of Metal (Au, Ag) Micro-Grid on the Photocatalytic Activity of TiO2 Film  

Science Journals Connector (OSTI)

In this paper, we prepared TiO2...thin film with the surface modified by a connected Au micro-grid via a microsphere lithography strategy, and the...2 film. The photocatalytic activity improved as Au loading incr...

Chao Cai; Junying Zhang; Feng Pan; Weiwei Zhang; Hailing Zhu…

2008-06-01T23:59:59.000Z

251

2002 IEEE/ASEE Frontiers in Education Meeting, Boston MA The Creation of Web-Based Interactive Virtual Experiments on Microelectronics and Nanoscience  

E-Print Network [OSTI]

Virtual Experiments on Microelectronics and Nanoscience for Early Engineering Students John C. Bean and nanoscience though the use of web-based "Virtual Experiments." The website allows students to explore

Bean, John C.

252

Effect of boundary scattering on the thermal conductivity of TiNiSn-based half-Heusler alloys  

Science Journals Connector (OSTI)

TiNiSn-based half-Heusler alloys have been of significant interest for their potential as thermoelectric materials. They exhibit promising electronic transport properties as revealed through high Seebeck coefficient and moderate electrical resistivity values. The chief disadvantage of these materials is a comparatively high lattice thermal conductivity. Attempts to “tune” the lattice thermal conductivity (?L) in these materials have led to the comparison and analysis of the thermal conductivity of two series of Ti- and Zr-based half-Heusler alloys. In the first series, Ti1?yZryNiSn0.95Sb0.05, a significant reduction in ?L is observed, with the substitution of large concentrations of Zr (y?25%) at Ti site, which is most likely due to mass fluctuation scattering. In the second series, TiNiSn1?xSbx, a nonsystematic increase in ?L is observed, with minute amounts of Sb doping (x?5%) at the Sn site. Extensive microstructural analysis in a TiNiSn1?xSbx series reveals a correlation between ?L and the average grain diameter in these materials, which is in good agreement with theoretical predictions related to phonon boundary scattering. In addition, a comparison of the calculated phonon mean free path in each of the series of compounds shows some insight into the two different phonon scattering mechanisms.

S. Bhattacharya; M. J. Skove; M. Russell; T. M. Tritt; Y. Xia; V. Ponnambalam; S. J. Poon; N. Thadhani

2008-05-30T23:59:59.000Z

253

Metal-insulator-semiconductor structure on low-temperature grown GaAs M. Young, W. Li, and T. P. Ma  

E-Print Network [OSTI]

Metal-insulator-semiconductor structure on low-temperature grown GaAs A. Chen,a M. Young, W. Li Received 28 July 2006; accepted 30 October 2006; published online 7 December 2006 The metal-insulator dielectrics and metal-insulator-semiconductor MIS structures; for ex- ample, in situ deposited Ga2O3 Gd2O3

Woodall, Jerry M.

254

Comparison of the Photodesorption Activities of cis-Butene, trans-Butene and Isobutene on the Rutile TiO2(110) Surface  

SciTech Connect (OSTI)

The chemical and photochemical properties of three butene molecules (cis-butene, trans-butene and isobutene) were explored on the clean rutile TiO2(110) surface using temperature programmed desorption (TPD) and photon simulated desorption (PSD). At the low coverage limit, trans-butene was the most strongly bound butene on the TiO2(110) surface, desorbing at ~ 210 K, however increased intermolecular repulsions between trans-butene molecules at higher coverage diminished its binding. Both cis-butene and isobutene saturated the first layer on TiO2(110) at a coverage of ~0.50 ML in a single TPD feature at 184 and 192 K, respectively. In contrast, the maximum coverage that trans-butene could achieve in its 210 K peak was ~1/3 ML, with higher coverages resulting a low temperature desorption at ~137 K. Coverages of these molecules above 0.50 ML resulted in population of second layer and multilayer states. The instability of trans-butene at a coverage of 0.5 ML on the surface was linked to the inversion center in its symmetry. In the absence of coadsorbed oxygen, the primary photochemical pathway of each butene molecule on TiO2(110) was photodesorption. The photoactivities of these molecules on TiO2(110) at an initial coverage of 0.50 ML followed the trend: isobutene > cis-butene > trans-butene. In contrast, the photoactivities of low coverages of cis-butene and trans-butene exceeded those measured at 0.50 ML. These data suggest that intermolecular interactions (repulsions) play a significant role in diminishing the photoactivities of weakly bound molecules on TiO2 photocatalysts. Work reported here was supported by the U.S. Department of Energy, Office of Basic Energy Science, Division of Chemical Sciences, Geosciences, and Biosciences, and performed in the Williams R. Wiley Environmental Molecular Science Laboratory (EMSL), a Department of Energy user facility funded by the Office of Biological and Environmental Research. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for the U.S. Department of Energy by the Battelle Memorial Institute under contract DEAC05-76RL01830.

Henderson, Michael A.

2013-11-14T23:59:59.000Z

255

DOE - Office of Legacy Management -- Nuclear Metals Inc - MA 09  

Office of Legacy Management (LM)

Metals Inc - MA 09 Metals Inc - MA 09 FUSRAP Considered Sites Site: NUCLEAR METALS, INC. (MA.09) Eliminated from consideration under FUSRAP - Licensed facility - included in NRC action plan (Site Decommissioning Management Plan) in 1990 for cleanup Designated Name: Not Designated Alternate Name: None Location: 1555 Massachusetts Ave. , Cambridge , Massachusetts MA.09-2 Evaluation Year: 1987 MA.09-1 Site Operations: Produced natural uranium tubes for Savannah River reactor program and fabricated power reactor fuel elements under AEC/NRC license. MA.09-4 MA.09-3 Site Disposition: Eliminated - No Authority under FUSRAP - AEC licensed operation MA.09-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium, Thorium MA.09-1 Radiological Survey(s): None Indicated

256

Carrier-Controlled Ferromagnetism in SrTiO3  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Magnetotransport and superconducting properties are investigated for uniformly La-doped SrTiO3 films and GdTiO3/SrTiO3 heterostructures, respectively. GdTiO3/SrTiO3 interfaces exhibit a high-density 2D electron gas on the SrTiO3 side of the interface, while, for the SrTiO3 films, carriers are provided by the dopant atoms. Both types of samples exhibit ferromagnetism at low temperatures, as evidenced by a hysteresis in the magnetoresistance. For the uniformly doped SrTiO3 films, the Curie temperature is found to increase with doping and to coexist with superconductivity for carrier concentrations on the high-density side of the superconducting dome. The Curie temperature of the GdTiO3/SrTiO3 heterostructures scales with the thickness of the SrTiO3 quantum well. The results are used to construct a stability diagram for the ferromagnetic and superconducting phases of SrTiO3.

Moetakef, Pouya; Williams, James R.; Ouellette, Daniel G.; Kajdos, Adam P.; Goldhaber-Gordon, David; Allen, S. James; Stemmer, Susanne

2012-06-01T23:59:59.000Z

257

Influence of the Operating Parameters on the Selective Catalytic Reduction of NO with Hydrocarbons Using Cu-Ion-Exchanged Titanium-Pillared Interlayer Clays (Ti-PILCs)  

Science Journals Connector (OSTI)

General Ti-PILC Characterization. Figure 1 shows the XRD patterns of the parent Ti-PILC calcined at different temperatures and of the original clay. ... Figure 1 X-ray diffraction (XRD) patterns for the Ti-PILC catalyst calcined at different temperatures. ... Figure 2 N2 adsorption?desorption isotherms for the Ti-PILC catalyst and the original clay. ...

José L. Valverde; Antonio de Lucas; Fernando Dorado; Amaya Romero; Prado B. García

2005-03-18T23:59:59.000Z

258

E-Print Network 3.0 - alloy-ma-956 Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

<< < 1 2 > >> 1 UPDATE ON THE STATUS OF ODS ALLOYS FOR FOSSIL ENERGY APPLICATIONS I.G. Wright and B.A. Pint Summary: h cycles), starting at 1 to 2kh for ODS alloys MA956 and...

259

Atomic and electronic structures of single-layer FeSe on SrTiO3(001): The role of oxygen deficiency  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Using first-principles calculation, we propose an interface structure for single triple-layer FeSe on the SrTiO3(001) surface, a high-Tc superconductor found recently. The key component of this structure is the oxygen deficiency on the top layer of the SrTiO3 substrate, as a result of Se etching used in preparing the high-Tc samples. The O vacancies strongly bind the FeSe triple layer to the substrate giving rise to a (2×1) reconstruction, as observed by scanning tunneling microscopy. The enhanced binding correlates to the significant increase of Tc observed in experiment. The O vacancies also serve as the source of electron doping, which modifies the Fermi surface of the first FeSe layer by filling the hole pocket near the center of the surface Brillouin zone, as suggested from angle-resolved photoemission spectroscopy measurement.

Bang, Junhyeok; Li, Zhi; Sun, Y. Y.; Samanta, Amit; Zhang, Y. Y.; Zhang, Wenhao; Wang, Lili; Chen, X.; Ma, Xucun; Xue, Q.-K.; Zhang, S. B.

2013-06-01T23:59:59.000Z

260

Electroerosion resistance and structural phase transformations in electrospark and laser deposition of titanium alloys using composite ceramics based on ZrB2-ZrSi2 and TiN-Cr3C2 systems  

Science Journals Connector (OSTI)

The paper examines the mass transfer kinetics, structure, phase and chemical compositions, and micromechanical properties of electrospark and laser coatings on titanium alloys (including...2-ZrSi2 and TiN-Cr3C2 s...

I. A. Podchernyaeva; A. D. Panasyuk…

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

CO Oxidation on Aun/TiO2 Catalysts Produced by Size-Selected Cluster Sungsik Lee, Chaoyang Fan, Tianpin Wu, and Scott L. Anderson*  

E-Print Network [OSTI]

. Indeed, Fu et al.2 recently showed that activity for the water gas shift reaction on Au/CeO2 and Pt/CeO2 TiO2 in an ultrahigh vacuum (UHV-base pressure 1 Ã? 10-10 mbar). The kinetic energy spread of the Aun-8% of oxygen vacancies. (The XPS vacancy estimate was calibrated by a separate water dissociation experiment

Anderson, Scott L.

262

On LiF:Mg,Cu,P and LiF:Mg,Ti phosphors high & ultra-high dose features  

E-Print Network [OSTI]

LiF:Mg,Ti and LiF:Mg,Cu,P are well known thermoluminescence (TL) dosimetry materials since many years. A few years ago their properties seemed well known and it was widely believed that they are not suitable for the measurement of doses above the saturation level of the TL signal, which for both materials occur at about 1 kGy. The high-dose high-temperature TL emission of LiF:Mg,Cu,P observed at the IFJ in 2006, which above 30 kGy takes the form of the so-called TL peak B, opened the way to use this material for measuring the dose in the high and ultra-high range, in particular for the monitoring of ionizing radiation around the essential electronic elements of high-energy accelerators, also fission and fusion facilities, as well as for emergency dosimetry. This discovery initiated studies of high and ultra-high dose characteristics of both of these phosphors, which turned out to be significantly different in many aspects. These studies not only strive to refine the method for measuring high doses based on th...

Obryk, Barbara; de Barros, Vinicius S; Guzzo, Pedro L; Bilski, Pawe?

2013-01-01T23:59:59.000Z

263

^ ^ Cambridge Technology, Inc. -= 109 Smith Place, Cambridge, MA 02138  

E-Print Network [OSTI]

^ ^ Cambridge Technology, Inc. - = 109 Smith Place, Cambridge, MA 02138 Tel: 617-441-0600 Fax: 617. = 109 Smith Place, Cannbridge, MA 02138 Tel. 617-441-0600 Fax 617-497-8800 Cambridge Technology's line

Kleinfeld, David

264

DOE - Office of Legacy Management -- Norton Co - MA 12  

Office of Legacy Management (LM)

the File; Subject: Elimination Recommendation; October 26, 1987 MA.12-4 - AEC Letter; White to Warde; Subject: Thorium Samples; February 19, 1954 MA.12-5 - AEC Memorandum; Morgan...

265

Supplementary Figure 1 SHAPE-MaP data analysis pipeline.  

E-Print Network [OSTI]

Supplementary Figure 1 SHAPE-MaP data analysis pipeline. Outline of software pipeline that fully.1 GHz Intel Core i7 and 16 GB RAM). This strategy is implemented in the SHAPE-MaP Folding Pipeline

Cai, Long

266

CSC 1051 M.A. Papalaskari, Villanova University Conditional Statements  

E-Print Network [OSTI]

CSC 1051 M.A. Papalaskari, Villanova University Conditional Statements Dr. Mary-Angela Papalaskari); } CSC 1051 M.A. Papalaskari, Villanova University A boolean expression Review if true, do this if more statement 1 true false statement2 CSC 1051 M.A. Papalaskari, Villanova University condition evaluated

Papalaskari, Mary-Angela

267

Economics & Finance MA or BSc (Single Honours Degrees)  

E-Print Network [OSTI]

88 Economics & Finance MA or BSc (Single Honours Degrees) Applied Economics Economics Financial Economics BA (International Honours Degrees) Economics See page 13 MA or BSc (Joint Honours Degrees) Economics and one of: Management Mathematics MA (Joint Honours Degrees) Economics and one of: Ancient

Brierley, Andrew

268

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA July 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for July 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

269

Data Update for Mt. Tom, Holyoke, MA February 2006  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA February 2006 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Melissa Ray Monthly Data Summary for February 2005 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

270

Data Update for Mt. Tom, Holyoke, MA January 2006  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA January 2006 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Melissa Ray Monthly Data Summary for December 2005 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

271

Data Update for Mt. Tom, Holyoke, MA February 2008  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA February 2008 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for February 2008 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

272

Data Update for Mt. Tom, Holyoke, MA January 2007  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA January 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for January 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

273

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA June 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for June 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

274

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA March 2008 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for March 2008 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

275

Data Update for Mt. Tom, Holyoke, MA August 2007  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA August 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for August 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

276

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA April 2006 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Melissa Ray Monthly Data Summary for April 2006 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59.2" N, 72

Massachusetts at Amherst, University of

277

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA March 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for March 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

278

Data Update for Mt. Tom, Holyoke, MA February 2007  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA February 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for February 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

279

Data Update for Mt. Tom, Holyoke, MA November 2007  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA November 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for November 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

280

Data Update for Mt. Tom, Holyoke, MA September 2007  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA September 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for September 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Data Update for Mt. Tom, Holyoke, MA September 2005  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA September 2005 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Melissa Ray Monthly Data Summary for September 2005 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

282

Data Update for Mt. Tom, Holyoke, MA January 2008  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA January 2008 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for January 2008 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

283

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA April 2008 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for April 2008 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

284

Data Update for Mt. Tom, Holyoke, MA October 2005  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA October 2005 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Melissa Ray Monthly Data Summary for October 2005 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

285

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA March 2006 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Melissa Ray Monthly Data Summary for March 2006 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59.2" N, 72

Massachusetts at Amherst, University of

286

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA May 2008 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for May 2008 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

287

Data Update for Mt. Tom, Holyoke, MA October 2007  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA October 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for October 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

288

Data Update for Mt. Tom, Holyoke, MA Prepared for  

E-Print Network [OSTI]

Data Update for Mt. Tom, Holyoke, MA May 2007 Prepared for Massachusetts Technology Collaborative 75 North Drive, Westborough, MA 01581 By Puneet Malhotra Monthly Data Summary for May 2007 This update summarizes the monthly data results for the Mt. Tom monitoring site in Holyoke, MA, at 42° 14' 59

Massachusetts at Amherst, University of

289

Effects of testing and storage environments on mechanical properties of Ni-plated and bare U-3/4 wt% Ti  

SciTech Connect (OSTI)

It was found that storage environments with an adequate supply of oxygen can effectively minimize moisture corrosion of bare U-3/4 Ti. In particular, 0.75 cm/sup 3/ of dry air is calculated to protect 1 cm/sup 2/ of U-3/4 Ti for 20 years storage at room temperature. Consideration of the geometric details of U-3/4 Ti alloy specimens and the free volumes of air (and hence O/sub 2/) available can satisfactorily explain discrepancies in corrosion behavior between recent tests and previously reported data. The storage environment at 70/sup 0/C produces a minor strength increase in bare samples with increasing time. Decreases in ductility are observed for testing conditions of low temperature, low strain rate, and/or high humidity. Surface cracks occur under the same conditions conducive to corrosion, i.e., moderate temperatures, low strain rates, and high humidity. Significant increases in strength result under low-temperature and high-strain-rate conditions of tensile testing. Residual chloride contamination may be responsible for the occasional and otherwise unexplained large scatter in ductility for nominally similar specimens and test conditions. Nickel plating is observed to cause a statistically significant decrease in tensile strength, but no effect on the yield strength or ductility was observed and the presence of high explosive during the aging of tensile bars was observed to have no effect on mechanical properties.

Zehr, S.W.; Johnson, H.R.; Smugeresky, J.E.; Pashman, K.A.; Nagelberg, A.S.

1980-01-01T23:59:59.000Z

290

Highly efficient dye-sensitized solar cells based on HfO{sub 2} modified TiO{sub 2} electrodes  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? HfO{sub 2} has been used to modify TiO{sub 2} electrodes in dye sensitized solar cells. ? HfO{sub 2} layer increases the dye adsorption. ? Diffusion coefficient (D{sub e}) and lifetime (?{sub e}) of the photoelectrons were increased. ? Solar cell efficiency (?) was greatly improved from 5.67 to 9.59%. -- Abstract: In this article, we describe the use of hafnium oxide (HfO{sub 2}) as a new and efficient blocking layer material to modify TiO{sub 2} electrodes in dye sensitized solar cells. Different thicknesses of HfO{sub 2} over-layers were prepared by simple dip coating from two different precursors and their effects on the performance of DSSCs were studied. The HfO{sub 2} modification remarkably increases dye adsorption, resulting from the fact that the surface of HfO{sub 2} is more basic than that of TiO{sub 2}. Furthermore, the HfO{sub 2} coating demonstrated increased diffusion coefficient (D{sub e}) and lifetime (?{sub e}) of the photoelectrons, indicating the improved retardation of the back electron transfer, which increases short-circuit current (J{sub sc}) and open-circuit voltage (V{sub oc}). Thereby, the photo conversion efficiency (?) of the solar cell was greatly improved from 5.67 to 9.59% (an improvement of 69.02%) as the HfO{sub 2} layer was coated over TiO{sub 2} films.

Ramasamy, Parthiban [Department of Chemistry and GETRC, Kongju National University, 182 Singkwan, Kongju, Chungnam 314-701 (Korea, Republic of)] [Department of Chemistry and GETRC, Kongju National University, 182 Singkwan, Kongju, Chungnam 314-701 (Korea, Republic of); Kang, Moon-Sung; Cha, Hyeon-Jung [Department of Environmental Engineering, Sangmyung University, 300 Anseo-dong, Dongnam-gu, Cheonan-si, Chungnam 330-720 (Korea, Republic of)] [Department of Environmental Engineering, Sangmyung University, 300 Anseo-dong, Dongnam-gu, Cheonan-si, Chungnam 330-720 (Korea, Republic of); Kim, Jinkwon, E-mail: jkim@kongju.ac.kr [Department of Chemistry and GETRC, Kongju National University, 182 Singkwan, Kongju, Chungnam 314-701 (Korea, Republic of)] [Department of Chemistry and GETRC, Kongju National University, 182 Singkwan, Kongju, Chungnam 314-701 (Korea, Republic of)

2013-01-15T23:59:59.000Z

291

Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO{sub 3}  

SciTech Connect (OSTI)

Nickel oxide (NiO) nanocrystals epitaxially grown on (001) strontium titanate (SrTiO{sub 3}) single crystal substrates were characterized to investigate interface morphology and chemistry. Aberration corrected high angle annular dark field scanning transmission electron microscopy reveals the interface between the NiO nanocrystals and the underlying SrTiO{sub 3} substrate to be rough, irregular, and have a lower average atomic number than the substrate or the nanocrystal. Energy dispersive x-ray spectroscopy and electron energy loss spectroscopy confirm both chemical disorder and a shift of the energy of the Ti L{sub 2,3} peaks. Analysis of the O K edge profiles in conjunction with this shift, implies the presence of oxygen vacancies at the interface. This sheds light into the origin of the previously postulated minority carriers’ model to explain resistive switching in NiO [J. Sullaphen, K. Bogle, X. Cheng, J. M. Gregg, and N. Valanoor, Appl. Phys. Lett. 100, 203115 (2012)].

Cheng, Xuan; Sullaphen, Jivika; Valanoor, Nagarajan [School of Materials Science and Engineering, University of New South Wales, Sydney NSW 2052 (Australia); Weyland, Matthew [Department of Materials Engineering and Monash Centre for Electron Microscopy, Monash University, Melbourne VIC 3800 (Australia); Liu, Hongwei [Australian Centre for Microscopy and Microanalysis, University of Sydney, Sydney NSW 2006 (Australia)

2014-03-01T23:59:59.000Z

292

Facile method for synthesis of TiO{sub 2} film and its application in high efficiency dye sensitized-solar cell (DSSC)  

SciTech Connect (OSTI)

Dye-sensitized solar cells (DSSC) is a device which converts a solar energy to electrical energy. Different with semiconductor thin film based solar cell, DSSC utilize the sensitized-dye to absorb the photon and semiconductor such as titanium dioxide (TiO{sub 2}) and zinc oxide (ZnO) as a working electrode photoanode. In this report, the preparation of TiO{sub 2} film using a facile method of spray deposition and its application in DSSC have been presented. TiO{sub 2} photoanode was synthesized by growing the droplet of titanium tetraisopropoxide diluted in acid solution on the substrate of conductive glass flourine-doped tin oxide (FTO) with variation of precursor volume. DSSC was assemblied by sandwiching both of photoanode electrode and platinum counter electrode subsequently filling the area between these electrodes with triodine/iodine electrolite solution as redox pairs. The characterization of the as prepared DSSC using solar simulator (AM 1.5G, 100 mW/cm{sup 2}) and I-V source meter Keithley 2400 showed that the performance of DSSC was affected by the precursor volume.. The overall conversion efficiency of DSSC using the optimum TiO{sub 2} film was about 1.97% with the open circuit voltage (V{sub oc}) of 0.73 V, short circuit current density (J{sub sc}) of 4.61 mA and fill factor (FF) of 0.58.

Widiyandari, Hendri, E-mail: h.widiyandari@undip.ac.id; Gunawan, S. K.V.; Suseno, Jatmiko Endro [Department of Physics, Diponegoro University, Jl. Prof. H. Soedarto SH, Semarang, Central Java 50275 (Indonesia); Purwanto, Agus [Department of Chemical Engineering, Sebelas Maret University, Jl. Ir. Sutami No. 36 A, Surakarta (Indonesia); Diharjo, Kuncoro [Department of Mechanical Engineering, Sebelas Maret University, Jl. Ir. Sutami No. 36 A, Surakarta (Indonesia)

2014-02-24T23:59:59.000Z

293

Scaling relationship on macroscopic helical domains in NiTi tubes Y.J. He, Q.P. Sun *  

E-Print Network [OSTI]

that determines the size and shape of the helical domain and what is the effect of dry- friction type stress: Macroscopic helical domains Martensitic phase transformation NiTi shape memory alloy tube Energy minimization- ized in a helix-shaped macro-domain consisting of almost fully transformed grains whose statistical

Sun, Qing-Ping

294

In-situ X-ray diffraction activation study on an Fe/TiO2 pre-catalyst  

Science Journals Connector (OSTI)

It is well known that pre-treatment procedures affect catalyst performance. In situ X-ray diffraction was used in this study to monitor the changes in phase composition and crystallite size during the pre-treatment of Fe/TiO2 catalysts, yielding insight into crystalline and non-crystalline phase changes and metal-support interactions.

Rayner, M.K.

2014-05-31T23:59:59.000Z

295

Patterned Growth of TiO2 Nanowires on Titanium Substrates Jong-Yoon Ha1;2  

E-Print Network [OSTI]

and short processing time utilizes the Ti foil both as a substrate and as a metal supply, thus eliminating transport methods. Adachi et al. have reported the synthesis of titania NWs using hydrothermal reactions, these methods typically require complex setups and processes, harsh environmental conditions, and extended

Lin, Liwei

296

Role of Benzyl Alcohol in Controlling the Growth of TiO2 on Carbon Nanotubes David J. Cooke,*,  

E-Print Network [OSTI]

. Introduction Titanium dioxide (TiO2) is one of the most important transition-metal oxides with applications. First, the interface between graphene and BA, where we found that the adsorption layer is dominated interaction with the titanium sol.12,19 Such groups are commonly attached via covalent bonding upon

Elliott, James

297

The deposition of nanocrystalline TiO2 thin film on silicon using Sol-Gel technique and its characterization  

Science Journals Connector (OSTI)

TiO"2 thin films were deposited using Sol-Gel spin coating technique using titanium isoperoxide as the Titania precursor. The films were characterized using X-ray diffraction, capacitance voltage measurement and Raman characterization technique. The ... Keywords: Sol-Gel, Spin coating, Titanium dioxide, X-ray diffraction

Mukesh Kumar; Mukesh Kumar; Dinesh Kumar

2010-03-01T23:59:59.000Z

298

Chemically grown TiO2 on glass with superior photocatalytic properties G. Kenanakis a,b,  

E-Print Network [OSTI]

suspensions or in small-scale purification systems, thus limiting their practical use due to difficulties of photocatalysis for various applications such as water treatment, air purification and fuel cells [1­5]. TiO2 techniques [8­10]. Since then, many large scale deposition techniques, such as doctor blade and spray coating

299

First-principles insights on the magnetism of cubic SrTi1?xCoxO3??  

E-Print Network [OSTI]

We present hybrid density functional calculations suggesting that magnetism in cubic SrTi1 ? x Co x O3 ? ? (STCO) with x?=?0.25 is sensitive to the nearest neighbor arrangement of the Co and the presence of oxygen vacancies. ...

Florez Uribe, Juan Manuel

300

Comment on “Indications of a T=0 Quantum Phase Transition in SrTiO3”  

Science Journals Connector (OSTI)

A Comment on the Letter by Daniel E. Grupp and Allen M. Goldman, Phys. Rev. Lett. 78, 3511 (1997). The authors of the Letter offer a Reply.

Mario Maglione

1998-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Intrinsic Diffusion of Hydrogen on Rutile TiO2(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

images demonstrate a complex behavior of hydrogen formed by water dissociation on BBO vacancies. Different diffusion rates are observed for the two hydrogens in the original...

302

Photochemistry of 1,1,1-Trifluoroacetone on Rutile TiO2(110)...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

functional theory (DFT). TFA adsorbed molecularly on the reduced surface (8% oxygen vacancies) in states desorbing below 300 K with trace thermal decomposition observed in TPD....

303

El Ma Electronic Machining srl | Open Energy Information  

Open Energy Info (EERE)

Ma Electronic Machining srl Ma Electronic Machining srl Jump to: navigation, search Name El.Ma. Electronic Machining srl Place Riva del Garda (TN), Italy Zip 38066 Sector Hydro, Hydrogen, Solar, Wind energy Product String representation "Italy-based, in ... solar sectors." is too long. References El.Ma. Electronic Machining srl[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. El.Ma. Electronic Machining srl is a company located in Riva del Garda (TN), Italy . References ↑ "El.Ma. Electronic Machining srl" Retrieved from "http://en.openei.org/w/index.php?title=El_Ma_Electronic_Machining_srl&oldid=344591" Categories: Clean Energy Organizations Companies Organizations

304

2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is attributed to stoichiometry; twice as many OH groups form on surface BBO rows when H2O is used so twice as many vacancies are created when OH recombines. Citation: Kim YK,...

305

Interfacial Energy Conversion in RuII Polypyridyl-Derivatized Oligoproline Assemblies on TiO2  

Science Journals Connector (OSTI)

Da Ma †, Stephanie E. Bettis †, Kenneth Hanson †, Maria Minakova ‡, Leila Alibabaei †, William Fondrie †, Derek M. Ryan †, Garegin A. Papoian ‡, Thomas J. Meyer †, Marcey L. Waters *†, and John M. Papanikolas *† ... Stephanie E. Bettis, Kenneth Hanson, Li Wang, Melissa K. Gish, Javier J. Concepcion, Zhen Fang, Thomas J. Meyer, and John M. Papanikolas ... Stephanie E. Bettis, Kenneth Hanson, Li Wang, Melissa K. Gish, Javier J. Concepcion, Zhen Fang, Thomas J. Meyer, and John M. Papanikolas ...

Da Ma; Stephanie E. Bettis; Kenneth Hanson; Maria Minakova; Leila Alibabaei; William Fondrie; Derek M. Ryan; Garegin A. Papoian; Thomas J. Meyer; Marcey L. Waters; John M. Papanikolas

2013-03-20T23:59:59.000Z

306

Fusion materials irradiations at MaRIE's fission fusion facility  

SciTech Connect (OSTI)

Los Alamos National Laboratory's proposed signature facility, MaRIE, will provide scientists and engineers with new capabilities for modeling, synthesizing, examining, and testing materials of the future that will enhance the USA's energy security and national security. In the area of fusion power, the development of new structural alloys with better tolerance to the harsh radiation environments expected in fusion reactors will lead to improved safety and lower operating costs. The Fission and Fusion Materials Facility (F{sup 3}), one of three pillars of the proposed MaRIE facility, will offer researchers unprecedented access to a neutron radiation environment so that the effects of radiation damage on materials can be measured in-situ, during irradiation. The calculated radiation damage conditions within the F{sup 3} match, in many respects, that of a fusion reactor first wall, making it well suited for testing fusion materials. Here we report in particular on two important characteristics of the radiation environment with relevancy to radiation damage: the primary knock-on atom spectrum and the impact of the pulse structure of the proton beam on temporal characteristics of the atomic displacement rate. With respect to both of these, analyses show the F{sup 3} has conditions that are consistent with those of a steady-state fusion reactor first wall.

Pitcher, Eric J [Los Alamos National Laboratory

2010-10-06T23:59:59.000Z

307

The influence of TiSi2 and CoSi2 growth on Si native point defects: The role of the diffusing species  

E-Print Network [OSTI]

from codeposited metal and Si. The as-deposited films had the compositions Ti, TiSi0.8 , TiSi2 undersaturation.3 Nevertheless, the mechanism by which silicide films effect a perturbance in the point defect, causing a va- cancy supersaturation. The formation of CoSi2 from CoSi proceeds via diffusion of metal

Florida, University of

308

The effect of oxygen in the Si substrate on Mo, W, Ti, and Co silicide growth by infrared laser heating  

SciTech Connect (OSTI)

This study of the effect of implanted oxygen in the Si substrate was accomplished using an IR heating method and a combination of different materials analysis techniques. Principally, Auger electron spectroscopy combined with depth profiling was implemented to investigate the composition of the reacted metal-Si systems as well as the relative movement of the oxygen during silicide formation. The authors systematic study of these four metal-Si systems yielded some interesting results. First, for the three metals Mo, W, and Ti, we observed basically inhibited metal-Si reactions at laser processing conditions that yielded completely reacted metal silicides without implanted oxygen. Second, the evolution from inhibited reactions through partial, metal-rich silicides and finally to completely reacted metal silicide formation at high temperatures was observed and characterized. Last, a distinctly response to the presence of oxygen was observed for the Ti samples as compared to the Mo and W samples.

Lee, H.S.; Wolga, G.J. (School of Electrical Engineering, Cornell Univ., Ithaca, NY (US))

1990-08-01T23:59:59.000Z

309

Influence of Microstructure on High-Cycle Fatigue of Ti-6Al-4V: Bimodal vs. Lamellar Structures  

E-Print Network [OSTI]

for such failures in Ti-6Al-4V, a commonly used turbine blade alloy, specifically for fan and compressor blades.K. NALLA, B.L. BOYCE, J.P. CAMPBELL, J.O. PETERS, and R.O. RITCHIE The high-cycle fatigue (HCF) of titanium] HCF can result in essentially unpredictable used for blade and disk applications in the front (low

Ritchie, Robert

310

Effect of liquid phase composition on the microstructure and properties of (W,Ti)C cemented carbide cutting tools  

E-Print Network [OSTI]

comprises metal carbides (2­10 vol%), such as VC, ZrC, NbC, TaC, TiC, SiC, Cr3C2, and ThC2; this constituent, which controls the grain size and en- hance the metal carbides formations, is used to decrease the rate of refractory transition metals such as titanium. However, when alloying is attempted, the solid solubili- ties

Hong, Soon Hyung

311

On the preparation of TiAl alloy by direct reduction of the oxide mixtures in calcium chloride melt  

SciTech Connect (OSTI)

In recent years, TiAl-based intermetallic alloys are being increasingly considered for application in areas such as (i) automobile/transport sector (passenger cars, trucks and ships) (ii) aerospace industry (jet engines and High Speed Civil Transport propulsion system) and (iii) industrial gas turbines. These materials offer excellent (i) high temperature properties (at higher than 6000C) (ii) mechanical strength and (iii) resistance to corrosion and as a result have raised renewed interest. The combination of these properties make them possible replacement materials for traditional nickel-based super-alloys, which are nearly as twice as dense (than TiAl based alloys). Since the microstructures of these intermetallic alloys affect, to a significant extent, their ultimate performance, further improvements (by way of alteration/modification of these microstructures), have been the subject matter of intense research investigations. It has now been established that the presence of alloy additives, such as niobium, tantalum, manganese, boron, chromium, silicon, nickel and yttrium etc, in specific quantities, impart marked improvement to the properties, viz. fatigue strength, fracture toughness, oxidation resistance and room temperature ductility, of these alloys. From a number of possible alloy compositions, {gamma}-TiAl and Ti-Al-Nb-Cr have, of late, emerged as two promising engineering alloys/materials. . The conventional fabrication process of these alloys include steps such as melting, forging and heat treatment/annealing of the alloy compositions. However, an electrochemical process offers an attractive proposition to prepare these alloys, directly from the mixture of the respective oxides, in just one step. The experimental approach, in this new process, was, therefore, to try to electrochemically reduce the (mixed) oxide pellet to an alloy phase. The removal of oxygen, from the (mixed) oxide pellet, was effected by polarizing the oxide pellet against a graphite electrode in a pool of molten calcium chloride at a temperature of 9000C. The dominant mechanism of the oxygen removal was the ionization of oxygen followed by its subsequent discharge, as CO2/CO, at the anode surface. The removal of oxygen from the oxide mixture helped form the alloy in situ. The presentation shall cover the detailed experimental results pertaining to the preparation, evaluation and characterization of Ti-47Al-2Nb-2Cr (atom%) alloy.

Prabhat K. Tripathy; Derek J. Fray

2011-11-01T23:59:59.000Z

312

oe oe oe oe oe Mi ye ma lel gvu  

E-Print Network [OSTI]

& & V ? c c c c Soprano Alto Tenor Bass q»¡¶ oe oe oe oe oe Mi ye ma lel gvu oe oe oe oe oe rot yis ra el o oe oe oe oe oe Mi ye ma lel o tan mi tan mi oe oe oe oe oe Mi ye ma lel o yim ne? yim ne tan mi oe oe oe oe oe Mi ye ma lel gvu w ah oe oe oe oe oe Hen be chol dor ya yim ne w rot

Setiawan, Hendra

313

Photocatalytic H2 production from ethanol over Au/TiO2 and Ag/TiO2  

Science Journals Connector (OSTI)

This paper compares the photocatalytic activities of Au/TiO2 (Au loadings 0-4 wt.%) and Ag/TiO2 photocatalysts (Ag loadings 0-4 wt.%) for H2 production from ethanol-water mixtures under UV irradiation. Au and Ag nanoparticles were deposited on commercially available Degussa P25 TiO2 (85% anatase, 15% rutile) using deposition-precipitation and liquid impregnation methods, respectively. TEM analyses showed the average noble metal nanoparticle size to be ~5 nm for the Au/TiO2 photocatalysts and ~3 nm for the Ag/TiO2 photocatalysts. Au/TiO2 photocatalysts showed a strong localised surface plasmon resonance (LSPR) at 570 nm characteristic for nanocrystalline Au. Complementary XRD studies confirmed that Au and Ag nanoparticles were present in metallic form. Photoluminescence measurements revealed that Au and Ag nanoparticles effectively suppress electron-hole recombination in TiO2, thereby enhancing the photocatalytic activity of TiO2 for hydrogen production. Au/TiO2 photocatalysts were far more active for H2 production from ethanol-water mixtures than Ag/TiO2 photocatalysts. A 1 wt.% Au/TiO2 photocatalyst yielded the highest H2 production rate (34 mmol g?1 h?1). Amongst the Ag/TiO2 photocatalysts, the 2 wt.% Ag/TiO2 sample was the most active (3.7 mmol g?1 h?1). Results are rationalised in terms of differences in the electronic properties of supported Au and Ag nanoparticles, with the former being near ideal for H2 production.

Vedran Jovic; Pei-Huan Hsieh; Wan-Ting Chen; Dongxiao Sun-Waterhouse; Tilo Söhnel; Geoffrey I.N. Waterhouse

2014-01-01T23:59:59.000Z

314

Gold, Copper, and Platinum Nanoparticles Dispersed on CeOx/TiO2(110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level  

SciTech Connect (OSTI)

At small coverages of ceria on TiO{sub 2}(110), the CeO{sub x} nanoparticles have an unusual coordination mode. Scanning tunneling microscopy and density-functional calculations point to the presence of Ce{sub 2}O{sub 3} dimers, which form diagonal arrays that have specific orientations of 0, 24, and 42{sup o} with respect to the [1 -1 0] direction of the titania substrate. At high coverages of ceria on TiO{sub 2}(110), the surface exhibits two types of terraces. In one type, the morphology is not very different from that observed at low ceria coverage. However, in the second type of terrace, there is a compact array of ceria particles with structures that do not match the structures of CeO{sub 2}(111) or CeO{sub 2}(110). The titania substrate imposes on the ceria nanoparticles nontypical coordination modes, enhancing their chemical reactivity. This phenomenon leads to a larger dispersion of supported metal nanoparticles (M = Au, Cu, Pt) and makes possible the direct participation of the oxide in catalytic reactions. The M/CeO{sub x}/TiO{sub 2}(110) surfaces display an extremely high catalytic activity for the water-gas shift reaction that follows the sequence Au/CeO{sub x}/TiO{sub 2}(110) < Cu/CeO{sub x}/TiO{sub 2}(110) < Pt/CeO{sub x}/TiO{sub 2}(110). For low coverages of Cu and CeO{sub x}, Cu/CeO{sub x}/TiO{sub 2}(110) is 8-12 times more active than Cu(111) or Cu/ZnO industrial catalysts. In the M/CeO{sub x}/TiO{sub 2}(110) systems, there is a strong coupling of the chemical properties of the admetal and the mixed-metal oxide: The adsorption and dissociation of water probably take place on the oxide, CO adsorbs on the admetal nanoparticles, and all subsequent reaction steps occur at the oxide-admetal interface. The high catalytic activity of the M/CeO{sub x}/TiO{sub 2}(110) surfaces reflects the unique properties of the mixed-metal oxide at the nanometer level.

Park, J.; Graciani, J; Evans, J; Stacchiola, D; Senanayake, S; Barrio, L; Liu, P; Fdez. Sanz, J; Hrbek, J; Rodriguez, J

2010-01-01T23:59:59.000Z

315

Gold, Copper and Platinum Nanoparticles Dispersed on CeOx/TiO2(110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level  

SciTech Connect (OSTI)

At small coverages of ceria on TiO{sub 2}(110), the CeO{sub x} nanoparticles have an unusual coordination mode. Scanning tunneling microscopy and density-functional calculations point to the presence of Ce{sub 2}O{sub 3} dimers, which form diagonal arrays that have specific orientations of 0, 24, and 42{sup o} with respect to the [1 -1 0] direction of the titania substrate. At high coverages of ceria on TiO{sub 2}(110), the surface exhibits two types of terraces. In one type, the morphology is not very different from that observed at low ceria coverage. However, in the second type of terrace, there is a compact array of ceria particles with structures that do not match the structures of CeO{sub 2}(111) or CeO{sub 2}(110). The titania substrate imposes on the ceria nanoparticles nontypical coordination modes, enhancing their chemical reactivity. This phenomenon leads to a larger dispersion of supported metal nanoparticles (M = Au, Cu, Pt) and makes possible the direct participation of the oxide in catalytic reactions. The M/CeO{sub x}/TiO{sub 2}(110) surfaces display an extremely high catalytic activity for the water-gas shift reaction that follows the sequence Au/CeO{sub x}/TiO{sub 2}(110) < Cu/CeO{sub x}/TiO{sub 2}(110) < Pt/CeO{sub x}/TiO{sub 2}(110). For low coverages of Cu and CeO{sub x}, Cu/CeO{sub x}/TiO{sub 2}(110) is 8-12 times more active than Cu(111) or Cu/ZnO industrial catalysts. In the M/CeO{sub x}/TiO{sub 2}(110) systems, there is a strong coupling of the chemical properties of the admetal and the mixed-metal oxide: The adsorption and dissociation of water probably take place on the oxide, CO adsorbs on the admetal nanoparticles, and all subsequent reaction steps occur at the oxide-admetal interface. The high catalytic activity of the M/CeO{sub x}/TiO{sub 2}(110) surfaces reflects the unique properties of the mixed-metal oxide at the nanometer level.

Rodriguez, J.A.; Park, J.B.; Graciani, J.; Evans, J.; Stacchiola, D.; Senanayake, S.D.; Barrio, L.; Liu, P.; Sanz, J.F.; Hrbek, J.

2010-01-13T23:59:59.000Z

316

U-178: VMware vMA Library Loading Error Lets Local Users Gain Elevated  

Broader source: Energy.gov (indexed) [DOE]

8: VMware vMA Library Loading Error Lets Local Users Gain 8: VMware vMA Library Loading Error Lets Local Users Gain Elevated Privileges U-178: VMware vMA Library Loading Error Lets Local Users Gain Elevated Privileges May 29, 2012 - 7:00am Addthis PROBLEM: A vulnerability was reported in VMware vMA PLATFORM: Version(s): vMA 4.0, 4.1, 5 patch 1 (5.0.0.1) ABSTRACT: A local user can obtain elevated privileges on the target system. Reference Links: SecurityTracker Alert ID: 1027099 CVE-2012-2752 Vendor Advisory IMPACT ASSESSMENT: High Discussion: A local user can exploit a library loading error to cause arbitrary code to be executed on the target system with elevated privileges. Impact: Privilege escalation Solution: The vendor has issued a fix (vSphere Management Assistant 5.0 Patch 2 (5.0.0.2)). Addthis Related Articles T-591: VMware vmrun Utility Lets Local Users Gain Elevated Privileges

317

Effect of aluminum content on synthesis of Ti2AlC and Ti3AlC2 during treatment in a high-energy mill and hot pressing  

Science Journals Connector (OSTI)

Treatment of initial powders of titanium, carbon and aluminum in a high-energy mill and pressure sintering are used for...2AlC and Ti3AlC2 ceramics. The effect of the content of aluminum and of the sintering temp...

Jianfeng Zhu; Guoquan Qi; Fen Wang; Haibo Yang; Ying Li

2011-05-01T23:59:59.000Z

318

Effects of Reduction Temperature and Metal-Support Interactions on the Catalytic Activity of Pt/g-Al2O3 and Pt/TiO2 for the Oxidation of CO in the Presence and Absence of H2.  

SciTech Connect (OSTI)

TiO2- and -Al2O3-supported Pt catalysts were characterized by HRTEM, XPS, EXAFS, and in situ FTIR spectroscopy after activation at various conditions, and their catalytic properties were examined for the oxidation of CO in the absence and presence of H2 (PROX). When {gamma}-Al{sub 2}O{sub 3} was used as the support, the catalytic, electronic, and structural properties of the Pt particles formed were not affected substantially by the pretreatment conditions. In contrast, the surface properties and catalytic activity of Pt/TiO2 were strongly influenced by the pretreatment conditions. In this case, an increase in the reduction temperature led to higher electron density on Pt, altering its chemisorptive properties, weakening the Pt-CO bonds, and increasing its activity for the oxidation of CO. The in situ FTIR data suggest that both the terminal and bridging CO species adsorbed on fully reduced Pt are active for this reaction. The high activity of Pt/TiO2 for the oxidation of CO can also be attributed to the ability of TiO2 to provide or stabilize highly reactive oxygen species at the metal-support interface. However, such species appear to be more reactive toward H{sub 2} than CO. Consequently, Pt/TiO{sub 2} shows substantially lower selectivities toward CO oxidation under PROX conditions than Pt/{gamma}-Al{sub 2}O{sub 3}.

Alexeev,O.; Chin, S.; Engelhard, M.; Ortiz-Soto, L.; Amiridis, M.

2005-01-01T23:59:59.000Z

319

J. Michael Starling, M.A. Department of Educational Psychology  

E-Print Network [OSTI]

J. Michael Starling, M.A. Department of Educational Psychology Ball State University Muncie.D. Ball State University 2014 (Expected) Educational Psychology (General) Cognate: Research Methodology M.A. Ball State University 2009 School Psychology B.A. Anderson University 2008 Psychology Graduate

Wu, Mingshen

320

FRACTIONAL SKEW MONOID RINGS P. ARA, M.A. GONZ  

E-Print Network [OSTI]

FRACTIONAL SKEW MONOID RINGS P. ARA, M.A. GONZ â?? ALEZ­BARROSO, K.R. GOODEARL, AND E. PARDO FQM­298 of the Junta de Andalucâ??�a. 1 #12; 2 P. ARA, M.A. GONZ â?? ALEZ­BARROSO, K.R. GOODEARL, AND E

Bigelow, Stephen

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Modeling Excited States in TiO2 Nanoparticles: On the Accuracy of a TD-DFT Based Description  

SciTech Connect (OSTI)

We have investigated the suitability of Time-Dependent Density Functional Theory (TD-DFT) to describe vertical low-energy excitations in naked and hydrated titanium dioxide nanoparticles through a comparison with results from Equation-of-Motion Coupled Cluster (EOM-CC) quantum chemistry methods. We demonstrate that for most TiO2 nanoparticles TD-DFT calculations with commonly used exchange-correlation (XC-)potentials (e.g. B3LYP) and EOM-CC methods give qualitatively similar results. Importantly, however, we also show that for an important subset of structures, TD-DFT gives qualitatively different results depending upon the XC-potential used and that in this case only TD-CAM-B3LYP and TD-BHLYP calculations yield results that are consistent with those obtained using EOM-CC theory. Moreover, we demonstrate that the discrepancies for such structures arise from a particular combination of defects, excitations involving which are charge-transfer excitations and hence are poorly described by XC-potentials that contain no or low fractions of Hartree-Fock like exchange. Finally, we discuss that such defects are readily healed in the presence of ubiquitously present water and that as a result the description of vertical low-energy excitations for hydrated TiO2 nanoparticles is hence non-problematic.

Berardo, Enrico; Hu, Hanshi; Shevlin, S. A.; Woodley, Scott M.; Kowalski, Karol; Zwijnenburg, Martijn A.

2014-03-11T23:59:59.000Z

322

Electrochemical modification of the passive oxide layer on a Ti film observed by in situ neutron reflectometry  

SciTech Connect (OSTI)

Anodization and the effect of subsequently applying cathodic potential to a thin-film Ti electrode in an aqueous NaCl solution have been studied with in situ neutron reflectometry. This new technique provides further insight into the processes underlying anodic oxide formation and hydrogen absorption under cathodic polarization. The results (Pilling-Bedworth ratio, anodization ratio, the onset of fluctuations in electrode current under cathodic potential, etc.) are generally in agreement with the literature, but this new technique provides further insight into the electrochemical processes. The anodized oxide is observed to be not porous, and has the density of the rutile structure for its entire thickness. However, it comprises two distinct regions: an inner region similar in thickness and composition to the original air-grown oxide, and an outer region containing a significant amount of hydrogen. The similarity of the inner region to the original oxide suggests that the underlying oxide growth mechanism for Ti is the point-defect model. Under applied cathodic potentials the overall oxide thickness remains constant, but the inner region is gradually converted to a material similar in hydrogen content to the outer region. The onset of massive hydrogen penetration seems to occur when the conversion is complete, or when the inner region has been reduced to only a few atomic layers.

Tun, Z. [National Research Council, Chalk River, Ontario (Canada). Chalk River Labs.] [National Research Council, Chalk River, Ontario (Canada). Chalk River Labs.; Noeel, J.J.; Shoesmith, D.W. [Atomic Energy of Canada Limited, Pinawa, Manitoba (Canada). Whiteshell Labs.] [Atomic Energy of Canada Limited, Pinawa, Manitoba (Canada). Whiteshell Labs.

1999-03-01T23:59:59.000Z

323

Effects of Nb doping level on the electronic transport, photoelectric effect and magnetoresistance across La{sub 0.5}Ca{sub 0.5}MnO{sub 3}/Nb:SrTiO{sub 3} junctions  

SciTech Connect (OSTI)

Heterojunctions composed of La{sub 0.5}Ca{sub 0.5}MnO{sub 3} and Nb doped SrTiO{sub 3} were fabricated, and the effects of the Nb doping level on their electronic transport, photoelectric effect, and magnetoresistance were investigated. A lower doping concentration of Nb led to better rectifying properties and higher open circuit voltages. The I-V curves for La{sub 0.5}Ca{sub 0.5}MnO{sub 3}/0.7?wt.?% Nb-SrTiO{sub 3} showed a negligible response to magnetic fields for all temperatures, whereas La{sub 0.5}Ca{sub 0.5}MnO{sub 3}/0.05?wt.?% Nb-SrTiO{sub 3} exhibited distinct magnetoresistance, which depended on both the bias voltage and temperature. These results are discussed with the assistance of conventional semiconductor theories.

Wang, J. F., E-mail: jifewang@gmail.com [Department of Physics, The University of Hong Kong, Pokfulam Road (Hong Kong); College of Science, China Jiliang University, Hangzhou, Zhejiang 310018 (China); Jiang, Y. C.; Gao, J., E-mail: jugao@hku.hk [Department of Physics, The University of Hong Kong, Pokfulam Road (Hong Kong); Chen, M. G. [College of Science, China Jiliang University, Hangzhou, Zhejiang 310018 (China)] [College of Science, China Jiliang University, Hangzhou, Zhejiang 310018 (China)

2013-12-16T23:59:59.000Z

324

Thermal stability and oxidation resistance of TiCrAlYO coatings...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications. Thermal stability and oxidation resistance of TiCrAlYO...

325

Irradiation behavior of SrTiO3 at temperatures close to the critical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for amorphization. Abstract: Damage accumulation on both the Sr and Ti sublattices in strontium titanate (SrTiO3) has been investigated under 1.0 MeV Au+ irradiation at 360 and 400...

326

Structure, magnetic properties and magnetoelastic anisotropy in epitaxial Sr(Ti???Co?)O? films  

E-Print Network [OSTI]

We report the structure, magnetic properties and magnetoelastic anisotropy of epitaxial Sr(Ti???Co?)O? films grown on LaAlO? (001) and SrTiO? (001) substrates by pulsed laser deposition. Room temperature ferromagnetism was ...

Bi, Lei

327

E-Print Network 3.0 - ar ti cr Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cu films were deposited on a steel substrate with thickness range of 200 - 2000... of TiC14, N2, HZ and Ar a t 520'C. The adhesion strength of TiN films was investigated by...

328

Effect of barium content on dielectric and energy storage properties of (Pb,La,Ba)(Zr,Sn,Ti)O3 ceramics  

Science Journals Connector (OSTI)

Abstract The effect of barium content on phase development, dielectric property and energy storage performance of (Pb0.925?xLa0.05Bax) (Zr0.52Sn0.39Ti0.09)O3 (PLBZST) ceramics synthesized by a solid state reaction method was investigated. X-ray diffraction patterns and scanning electron microscopy micrographs illustrated that the pyrochlore phase was effectively suppressed by the introduction of barium in the (Pb0.925La0.05) (Zr0.52Sn0.39Ti0.09)O3 (PLZST) ceramics. The increase in maximum dielectric constant and the decrease in both transition temperature and switching field with increasing barium content were due to the decrease in the stability of antiferroelectric phase. The energy storage performance of the barium doped PLZST ceramics was studied by measurements of polarization hysteresis loops and discharge curves. The increase of barium content led to the increase of the energy storage density at first and then slight decrease. The study of cyclic charge–discharge showed that barium doped PLZST ceramic capacitor can withstand up to 10,000 cycles with about 8% energy density loss.

Qian Zhang; Xiaolin Liu; Yong Zhang; Xiaozhen Song; Jia Zhu; Ivan Baturin; Jianfeng Chen

2014-01-01T23:59:59.000Z

329

Influence of film thickness, substrate temperature and nano-structural changes on the optical properties of UHV deposited Ti thin films  

Science Journals Connector (OSTI)

Titanium films of different thicknesses ranging from 18 to 210?nm were deposited on glass substrates, at different substrate temperatures (313 to 600?K) under UHV conditions. Their optical properties were measured by spectrophotometry in the spectral range of 200–2500?nm. The optical functions were obtained from the Kramers–Kronig analysis of the reflectivity curves. The effective medium approximation (EMA) analysis was employed to establish the relationship between the structure zone model (SZM) and EMA predictions. There was good agreement between SZM as a function of substrate temperature and film thickness and the values of volume fraction of voids was obtained from EMA analysis. The gettering property of Ti can play an important role in the nano-structure of the film and causes variations in the optical behaviour of thin Ti films, though films were produced under UHV condition and the XRD analysis did not show a detectable amount of oxidation. The over-layer thickness was calculated to be less than 2.0?nm, using the transfer matrix method.

Hadi Savaloni; Haleh Kangarloo

2007-01-01T23:59:59.000Z

330

Photophysical Characterization of a Helical Peptide Chromophore–Water Oxidation Catalyst Assembly on a Semiconductor Surface Using Ultrafast Spectroscopy  

Science Journals Connector (OSTI)

Stephanie E. Bettis , Derek M. Ryan , Melissa K. Gish , Leila Alibabaei , Thomas J. Meyer , Marcey L. Waters , and John M. Papanikolas * ... Ma, D.; Bettis, S. E.; Hanson, K.; Minakova, M.; Alibabaei, L.; Fondrie, W.; Ryan, D. M.; Papoian, G. A.; Meyer, T. J.; Waters, M. L.Interfacial Energy Conversion in RuII Polypyridyl-Derivatized Oligoproline Assemblies on TiO2 J. Am. ... Ma, Da; Bettis, Stephanie E.; Hanson, Kenneth; Minakova, Maria; Alibabaei, Leila; Fondrie, William; Ryan, Derek M.; Papoian, Garegin A.; Meyer, Thomas J.; Waters, Marcey L.; Papanikolas, John M. ...

Stephanie E. Bettis; Derek M. Ryan; Melissa K. Gish; Leila Alibabaei; Thomas J. Meyer; Marcey L. Waters; John M. Papanikolas

2014-03-04T23:59:59.000Z

331

RECIPIENT:Hull Municipal Light Plant STATE: MA PROJECT TITLE:  

Broader source: Energy.gov (indexed) [DOE]

: : Page 1 01 :L RECIPIENT:Hull Municipal Light Plant STATE: MA PROJECT TITLE: Hull Offshore Wind Research and Development Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CID Number 09EE0000326 DE-EE0000326 GFO-OO00326-001 0 Based on my review of the information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the foUowing determination: CX, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering (including, but not limited to, literature surveys, inventories, audits), data analysis (including computer modeling), document preparation (such as conceptual design or feasibility studies, analytical energy supply and demand studies), and dissemination (including, but not limited to, document mailings, publication, and distribution; and

332

Growth of individual carbon nanotubes on an array of TiN/Ni nanodots patterned by e-beam lithography and defined by dry etching for field emission application.  

E-Print Network [OSTI]

: Individual vertically aligned carbon nanotubes, Electron-beam lithography, Dry etching, Field emission and uniform electronic emission, cathodes based on vertically aligned carbon nanotubes (VACNTs) are patternedGrowth of individual carbon nanotubes on an array of TiN/Ni nanodots patterned by e

Boyer, Edmond

333

Magneto-transport in LaTi{sub 1?x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures  

SciTech Connect (OSTI)

We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

Kumar, Pramod, E-mail: pramodnpl2011@gmail.com; Dogra, Anjana, E-mail: pramodnpl2011@gmail.com; Budhani, R. C., E-mail: pramodnpl2011@gmail.com [Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Marg, New Delhi-110012 (India)

2014-04-24T23:59:59.000Z

334

Formation mechanism of linear friction welded Ti-6Al-4V alloy joint based on microstructure observation  

SciTech Connect (OSTI)

The microstructure of the linear friction welded Ti-6Al-4V titanium alloy joint was investigated by optical microscope, scanning electronic microscope and transmission electron microscope. Results show that the dynamic recovery and recrystallization resulting from the intensive plastic deformation and fast heating and cooling processes during linear friction welding account for the superfine {alpha} + {beta} grains in the weld center. Fine {alpha} grains distribute in the {beta} matrix or at the boundaries of {beta} grains. A mass of dislocations networks and metastructures present within the {alpha} and {beta} grains. - Research Highlights: {yields} TEM is employed in the analysis. {yields} The dynamic recovery is the main mechanism in thermal deformation of TC4. {yields} Superfine grains in the weld result from dynamic recovery and dynamic recrystallizaion, but the recrystallization is inadequate.

Ma Tiejun; Chen Tao, E-mail: ctwc-13@163.com; Li Wenya; Wang Shiwei; Yang Siqian

2011-01-15T23:59:59.000Z

335

Kinetic study on the catalytic performance of Rh/TiO/sub 2/ reduced at different temperatures in the CO-H/sub 2/ reaction  

SciTech Connect (OSTI)

Catalytic CO-H/sub 2/ reaction on Rh/TiO/sub 2/ reduced at 200, 400, and 500/sup 0/C (Cat-200, -400, -500) for 2 h was kinetically studied at 250/sup 0/C using a circulating reactor and Fourier transform-infrared (FT-IR) spectroscopy to determine how Cat-400 exhibited the highest activity. The rate equation distinguished the best catalyst with zero and first orders in CO and H/sub 2/, respectively, from other catalysts with negative order in CO. The adsorption ability of the catalyst at 200/sup 0/C was comparable to that of Cat-200, and two to three times larger than that of Cat-500, although the ability of Cat-200 was much larger at room temperature. Carbon monoxide adsorbed on the catalysts reversibly as well as irreversibly. IR spectroscopy revealed that the major form of irreversibly adsorbed CO was linear on Cat-200, whereas similar amounts of linear and bridge forms were observed on Cat-400 and Cat-500. These latter forms were highly reactive against hydrogen molecules when no carbon monoxide was present in the gas phase. Based on these results, the highest activity of Cat-400 is ascribed to rhodium metal modified by properly reduced TiO/sub 2/ to show the appropriate adsorption ability of carbon monoxide which least retards the activation of hydrogen according to first-order kinetics. Typical strong metal-support interaction decreases the catalytic activity by decreasing the active sites and strengthening the CO adsorption too much.

Fujitsu, H.; Ikeyama, N.; Mochida, I.

1986-08-01T23:59:59.000Z

336

Epitaxial growth of metastable multiferroic AlFeO{sub 3} film on SrTiO{sub 3} (111) substrate  

SciTech Connect (OSTI)

GaFeO{sub 3}-type AlFeO{sub 3} is consisted of oxygen octahedra and tetrahedra containing Al and Fe ions and is known to have a non-centrosymmetric polar structure with space group Pna2{sub 1}. We tried to grow epitaxial GaFeO{sub 3}-type AlFeO{sub 3} films on SrTiO{sub 3} (111) substrates by pulsed laser deposition technique. Both the atomic arrangement of close-packed and the atomic distance of the substrate surface played important roles in stabilizing GaFeO{sub 3}-type AlFeO{sub 3} on the substrate. Piezoresponse force microscopy measurements clearly showed that GaFeO{sub 3}-type AlFeO{sub 3} films have ferroelectricity at room temperature. In addition, AlFeO{sub 3} film also showed pinched-like hysteresis loop with T{sub N}???317?K.

Hamasaki, Yosuke; Shimizu, Takao; Taniguchi, Hiroki; Taniyama, Tomoyasu; Yasui, Shintaro; Itoh, Mitsuru, E-mail: itoh.m.aa@m.titech.ac.jp [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259-J2-19 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan)

2014-02-24T23:59:59.000Z

337

Study by in situ FTIR of the SCR of NO by propene on Cu2+ ion-exchanged Ti-PILC  

Science Journals Connector (OSTI)

Adsorption on Cu ion-exchanged titanium pillared clay (Cu-Ti-PILC) was investigated by in situ infrared spectroscopy to provide insight into the reaction intermediates present in the selective catalytic reduction (SCR) of NO by propene in the presence of oxygen. The NO/O2 adsorption produced different nitrate species due to the presence of terminal and bridged Cu2+–OH groups. These nitrates evolved into N2 and N2O in small amounts once the NO catalytic cycle was finished. It can be concluded that the Cu2+–OH groups reacted with the nitro group, thus forming nitrates. C3H6 adsorption was higher and stronger than NO adsorption on the active sites of the catalyst. C3H6 reacted in the active site producing hydrocarbon intermediates (an organic nitro compound and acetate), which were responsible for the NO reduction.

J.L. Valverde; A. de Lucas; F. Dorado; A. Romero; P.B. García

2005-01-01T23:59:59.000Z

338

Statistical evaluation of potential damage to the Al(OH)3 layer on nTiO2 particles in the presence of swimming pool and seawater  

Science Journals Connector (OSTI)

Nanosized TiO2 particles (nTiO2) are usually coated with an Al(OH)3 layer when used in sunscreen to shield against the harmful effects of free radicals that are generated when these particles are exposed to UV r...

Jurate Virkutyte; Souhail R. Al-Abed

2012-03-01T23:59:59.000Z

339

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature  

E-Print Network [OSTI]

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature Jia Zhang,ab Chao temperature oxygen sensor based on TiO2/graphene device was developed with an enhanced sensing performance­hole pairs in the TiO2 film and the photogenerated electrons were scavenged by graphene and percolated

Cao, Wenwu

340

Research on the effect of crystal structures on W-TiO{sub 2} nanotube array photoelectrodes by theoretical and experimental methods  

SciTech Connect (OSTI)

W-doped/undoped TiO{sub 2} nanotube array (TNAs) photoelectrodes with different nanostructures were successfully fabricated using the anodization method. Their morphology and characteristics were studied using scanning electron microscopy (SEM), energy dispersive X-ray (EDX), and ultra violet/visible light diffuse reflectance spectra (UV/vis/DRS). Their electronic structure and optical properties were studied by means of first-principle. Photocatalytic (PC) performance of W-TNAs photoelectrodes with different crystal structures was evaluated using the decomposition rates of Rhodamine B (Rh.B) under xenon light illumination. The results demonstrated that W substituting Ti broadened the width of conduction band (CB) and valence band (VB) of anatase and rutile TiO{sub 2}, reduced the band gap of rutile TiO{sub 2} and even caused its red-shift. W incorporated into TNAs photoelectrodes extended light absorption threshold and enhanced its utilization of solar light and PC activity, particularly, the PC performance of W-TNAs photoelectrodes with mixed crystal and rutile crystal structure.

Xin, Yanjun [College of Resource and Environment, Qingdao Agricultural University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China) [College of Resource and Environment, Qingdao Agricultural University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China); State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), Department of Environmental Science and Engineering Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090 (China); Wang, Yicheng; Ma, Dong [College of Resource and Environment, Qingdao Agricultural University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China)] [College of Resource and Environment, Qingdao Agricultural University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China); Liu, Huiling [State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), Department of Environmental Science and Engineering Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090 (China)] [State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), Department of Environmental Science and Engineering Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090 (China); Cheng, Wei [Library, Qingdao Agricultural University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China)] [Library, Qingdao Agricultural University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China)

2013-08-28T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

John R. Harrison, Ph.D. 1978 B.A. Salem State College, Salem, MA Biology  

E-Print Network [OSTI]

1994 Stimulation of prostaglandin E2 production by interleukin-1 and transforming growth factorJohn R. Harrison, Ph.D. Education 1978 B.A. Salem State College, Salem, MA Biology 1986 Ph.D of recombinant transforming growth factor and interleukin-1 on DNA synthesis, collagen #12;synthesis, procollagen

Oliver, Douglas L.

342

Perpendicular magnetic anisotropy of Mn{sub 4}N films on MgO(001) and SrTiO{sub 3}(001) substrates  

SciTech Connect (OSTI)

We grew Mn{sub 4}N epitaxial thin films capped with Au layers on MgO(001) and SrTiO{sub 3}(001) substrates by molecular beam epitaxy. Perpendicular magnetic anisotropy (PMA) was confirmed in all the samples at room temperature from the magnetization versus magnetic field curves using superconducting quantum interference device magnetometer. From the ?-2? x-ray diffraction (XRD) and ?-2?{sub ?} XRD patterns, the ratios of perpendicular lattice constant c to in-plane lattice constant a, c/a, were found to be about 0.99 for all the samples. These results imply that PMA is attributed to the in-plane tensile strain in the Mn{sub 4}N films.

Yasutomi, Yoko; Ito, Keita; Sanai, Tatsunori; Toko, Kaoru; Suemasu, Takashi, E-mail: suemasu@bk.tsukuba.ac.jp [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan)

2014-05-07T23:59:59.000Z

343

Epitaxial Ba{sub 2}IrO{sub 4} thin-films grown on SrTiO{sub 3} substrates by pulsed laser deposition  

SciTech Connect (OSTI)

We have synthesized epitaxial Ba{sub 2}IrO{sub 4} (BIO) thin-films on SrTiO{sub 3} (001) substrates by pulsed laser deposition and studied their electronic structure by dc-transport and optical spectroscopic experiments. We have observed that BIO thin-films are insulating but close to the metal-insulator transition boundary with significantly smaller transport and optical gap energies than its sister compound, Sr{sub 2}IrO{sub 4}. Moreover, BIO thin-films have both an enhanced electronic bandwidth and electronic-correlation energy. Our results suggest that BIO thin-films have great potential for realizing the interesting physical properties predicted in layered iridates.

Nichols, J., E-mail: john.nichols@uky.edu; Korneta, O. B.; Terzic, J.; Cao, G.; Brill, J. W.; Seo, S. S. A. [Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506 (United States)

2014-03-24T23:59:59.000Z

344

Universit Paris Descartes -UFR STAPS -Planning 2013-2014 (proposition 1B2) Arts Thrapies D 1 Ma 1 V 1 D 1 Me 1 S 1 S 1 Ma 1 J 1 D 1 Ma 1  

E-Print Network [OSTI]

Université Paris Descartes - UFR STAPS - Planning 2013-2014 (proposition 1B2) Arts Thérapies D 1 Ma 1 V 1 D 1 Me 1 S 1 S 1 Ma 1 J 1 D 1 Ma 1 L 2 Me 2 S 2 L 2 J 2 D 2 D 2 Me 2 V 2 L 2 Me 2 Ma 3 J 3 D 3 Ma 3 V 3 L 3 L 3 J 3 S 3 Ma 3 J 3 Me 4 V 4 L 4 Me 4 S 4 Ma 4 Ma 4 V 4 D 4 Me 4 V 4 J 5 S 5 Ma 5 J 5 D

Pellier, Damien

345

Johnston LFG (MA RPS Biomass Facility | Open Energy Information  

Open Energy Info (EERE)

LFG (MA RPS Biomass Facility LFG (MA RPS Biomass Facility Jump to: navigation, search Name Johnston LFG (MA RPS Biomass Facility Facility Johnston LFG (MA RPS Sector Biomass Facility Type Landfill Gas Location Rhode Island Coordinates 41.5800945°, -71.4774291° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.5800945,"lon":-71.4774291,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

346

Telecommunications Concentration: Grady College MA Thesis Program Planning Form  

E-Print Network [OSTI]

Telecommunications Concentration: Grady College MA Thesis Program Planning Form Student: Advisor ( ) Telecommunication Policy JRMC 8220 ( ) Telecommunications Programming and Criticism JRMC 8230 ( ) Emerging Telecommunication Technologies JRMC 8240 ( ) Special Topics in Telecommunications JRMC 8365 ( ) Media Economics JRMC

Arnold, Jonathan

347

Index of /~arshak/F04/MA266/matlab  

E-Print Network [OSTI]

Index of /~arshak/F04/MA266/matlab. [ICO], Name · Last modified · Size · Description. [DIR], Parent Directory, -. [ ], func1.m, 21-Sep-2004 23:46, 39. [ ], func2.

348

MaJIC: A Matlab Just-In-Time Compiler  

Science Journals Connector (OSTI)

This paper describes our experience with MaJIC, a just-intime compiler for MATLAB. In the recent past, several compiler projects claimed large performance improvements when processing MATLAB code. Most of these projects

George Almasi; David A. Padua

2001-01-01T23:59:59.000Z

349

TiSol | Open Energy Information  

Open Energy Info (EERE)

TiSol TiSol Jump to: navigation, search Name TiSol Place Pasadena, California Sector Solar Product California-based start up focused on the production of dye sensitized solar cells. Coordinates 29.690847°, -95.196308° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.690847,"lon":-95.196308,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

350

FTIR study of hydrogen and carbon monoxide adsorption on Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3}  

SciTech Connect (OSTI)

The Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} catalysts submitted to low-temperature reduction (LTR,200 C) and high-temperature reduction (HTR, 500 C) and exposed to hydrogen and carbon monoxide at room temperature were studied by infrared spectroscopy. There is a strong loss of transmission in the entire infrared spectra on Pt/TiO{sub 2} after its exposure to hydrogen, which is related to the reducibility of the support. A typical SMSI behavior (strong metal-support interaction), such as the decrease in carbon monoxide adsorption capacity, was detected on Pt/TiO{sub 2} and Pt/ZrO{sub 2} after exposure to hydrogen, even for the catalysts submitted to LTR treatment. Also a carbonyl band shift to lower wavenumber was observed on LTR-treated Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} after exposure to hydrogen. The authors interpreted this SMSI behavior as an electronic rather than morphological effect, which was induced by the presence of hydrogen spillover.

Benvenutti, E.V.; Franken, L.; Moro, C.C.; Davanzo, C.U.

1999-11-09T23:59:59.000Z

351

MA 125-4 CR PH 105-4 CR  

E-Print Network [OSTI]

490-3 CR Mechanical Engineering Design I I Proj Lab Proj Lab MA 125-4 CR Calculus I or Equivalent M MEMA 125-4 CR Calculus I or Equivalent PH 105-4 CR Gen Physics with Calculus MA 126-4 CR Calculus I I or Equivalent M Required Course Elective Course Prerequisite NS M W LAB Proj Lab Natural Science Mathematics

Carver, Jeffrey C.

352

MaRIE theory, modeling and computation roadmap executive summary  

SciTech Connect (OSTI)

The confluence of MaRIE (Matter-Radiation Interactions in Extreme) and extreme (exascale) computing timelines offers a unique opportunity in co-designing the elements of materials discovery, with theory and high performance computing, itself co-designed by constrained optimization of hardware and software, and experiments. MaRIE's theory, modeling, and computation (TMC) roadmap efforts have paralleled 'MaRIE First Experiments' science activities in the areas of materials dynamics, irradiated materials and complex functional materials in extreme conditions. The documents that follow this executive summary describe in detail for each of these areas the current state of the art, the gaps that exist and the road map to MaRIE and beyond. Here we integrate the various elements to articulate an overarching theme related to the role and consequences of heterogeneities which manifest as competing states in a complex energy landscape. MaRIE experiments will locate, measure and follow the dynamical evolution of these heterogeneities. Our TMC vision spans the various pillar science and highlights the key theoretical and experimental challenges. We also present a theory, modeling and computation roadmap of the path to and beyond MaRIE in each of the science areas.

Lookman, Turab [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

353

Influence of doping (Ti, V, Zr, W) and annealing on the sp{sup 2} carbon structure of amorphous carbon films  

SciTech Connect (OSTI)

The influence of the transition metal (Ti, V, Zr, W) doping on the carbon matrix nanostructuring during the thin film growth and subsequent annealing is investigated. Pure and metal-doped amorphous carbon films (a-C, a-C:Me) were deposited at room temperature by nonreactive magnetron sputtering. The carbon structure of as-deposited and postannealed (up to 1300 K) samples was analyzed by x-ray diffraction (XRD) and Raman spectroscopy. The existence of graphenelike regions in a-C is concluded from a (10) diffraction peak. A comparison of the XRD and Raman results suggests that XRD probes only the small amount of 2-3 nm large graphenelike regions, whereas the majority of the sp{sup 2} phase is present in smaller distorted aromatic clusters which are probed only by Raman spectroscopy. Annealing leads to an increase in the graphene size and the aromatic cluster size. During the carbon film growth the addition of metals enhances ordering of sp{sup 2} carbon in sixfold aromatic clusters compared to a-C; Ti, and Zr showing the strongest effect, W the lowest. This order qualitatively corresponds with the catalytic activity of the respective carbides found during graphitization of carbide-doped graphites published in the literature. With annealing, carbide crystallite formation and growth occurs in a-C:Me films, which destroys the initial carbon structure, reduces the size of the initially formed aromatic clusters and the differences in carbon structure introduced by different dopants. For high annealing temperatures the carbon structure of a-C:Me films is similar to that of a-C, and is determined only by the annealing temperature.

Adelhelm, C.; Balden, M. [Max-Planck-Institut fuer Plasmaphysik, Materials Research, EURATOM Association, Boltzmannstrasse 2, D-85748 Garching (Germany); Rinke, M.; Stueber, M. [Forschungszentrum Karlsruhe, Institute of Materials Research I, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen (Germany)

2009-02-01T23:59:59.000Z

354

Electron energy loss study of TiC[111].  

SciTech Connect (OSTI)

The electron energy loss (EEL) spectra of TiC (111) were measured over a wide range of electron primary energies. The electron energy losses below 16 eV were analyzed using the theoretical band calculations of Price and Cooper [11]. The volume and surface plasma excitations were identified from their electron primary energy dependence. Energy losses due to core electrons autoinization effects were identified above 35 eV. We observed a difference in the electronic structure of the surface vs. the bulk of TiC. The temperature dependence of the EEL spectra was studied between 300 to 1250 K. The reaction of the TiC surface with ethylene and oxygen was also investigated. The ethylene bonding to the TiC surface was found to be very weak. There is evidence of the formation of surface defects on the TiC (111) surface at high temperatures.

Chan, Y.; Lee, S. W.; Liao, D.; Cooper, B. R.; Montano, P. A.; Materials Science Division; Brooklyn Coll. of City Univ. of New York; West Virginia Univ.

1992-01-01T23:59:59.000Z

355

Development of ITER 15 MA ELMy H-mode Inductive Scenario  

SciTech Connect (OSTI)

The poloidal field (PF) coil system on ITER, which provides both feedforward and feedback control of plasma position, shape, and current, is a critical element for achieving mission performance. Analysis of PF capabilities has focused on the 15 MA Q = 10 scenario with a 300-500 s flattop burn phase. The operating space available for the 15 MA ELMy H-mode plasma discharges in ITER and upgrades to the PF coils or associated systems to establish confidence that ITER mission objectives can be reached have been identified. Time dependent self-consistent free-boundary calculations were performed to examine the impact of plasma variability, discharge programming, and plasma disturbances. Based on these calculations a new reference scenario was developed based upon a large bore initial plasma, early divertor transition, low level heating in L-mode, and a late H-mode onset. Equilibrium analyses for this scenario indicate that the original PF coil limitations do not allow low li (<0.8) operation or lower flux states, and the flattop burn durations were predicted to be less than the desired 400 s. This finding motivates the expansion of the operating space, considering several upgrade options to the PF coils. Analysis was also carried out to examine the feedback current reserve required in the CS and PF coils during a series of disturbances and a feasibility assessment of the 17 MA scenario was undertaken. Results of the studies show that the new scenario and modified PF system will allow a wide range of 15 MA 300-500 s operation and more limited but finite 17 MA operation.

Kessel, C. E.; Campbell, D.; Gribov, Y.; Saibene, G.; Ambrosino, G.; Casper, T.; Cavinato, M.; Fujieda, H.; Hawryluk, R.; Horton, L. D.; Kavin, A.; Kharyrutdinov, R.; Koechl, F.; Leuer, J.; Loarte, A.; Lomas, P. J.; Luce, T.; Lukash, V.; Mattei, M.; Nunes, I.; Parail, V.; Polevoi, A.; Portone, A.; Sartori, R.; Sips, A. C.C.; Thomas, P. R.; Welander, A.; Wesley, J.

2008-10-16T23:59:59.000Z

356

Much simplified ion-beam assisted deposition-TiN template for high-performance coated conductors  

SciTech Connect (OSTI)

A much simplified template, i.e., two nonsuperconducting layers between the superconducting YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) and the polycrystalline metal substrate, has been developed for high-performance coated conductors by using biaxially aligned TiN as a seed layer. A combination of a thin TiN ({approx}10 nm by ion-beam assisted deposition) layer and an epitaxial buffer LaMnO{sub 3} layer ({approx}120 nm) allows us to grow epitaxial YBCO films with values of full width at half-maximum around 3.5 deg. and 1.7 deg. for the {phi}-scan of (103) and rocking curve of (005) YBCO, respectively. The YBCO films grown on electropolished polycrystalline Hastelloy using this two-layer template exhibited a superconducting transition temperature of 89.5 K, a critical current density of 1.2 MA/cm{sup 2} at 75.5 K, and an {alpha} value (proportional factor of critical current density J{sub c}{approx}H{sup -}{alpha}) of around 0.33, indicating a high density of pinning centers and an absence of weak links.

Xiong, J. [Division of Materials Physics and Applications, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); State Key Lab of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Matias, V.; Zhai, J. Y.; Maiorov, B.; Trugman, D.; Jia, Q. X. [Division of Materials Physics and Applications, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Wang, H. [Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843-3128 (United States); Tao, B. W.; Li, Y. R. [State Key Lab of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China)

2010-10-15T23:59:59.000Z

357

ThePortugalMillenniumEcosystemAssessment(ptMA)(http://ecossistemas.org) is analyzing the condition of ecosystem services in Portugal, recent trends in  

E-Print Network [OSTI]

, cultivated, and urban. Montado, which is not a global MA system, is an ecolog- ical and economically the users interacted with the scientists, and how the scientists interacted with the local population into ecosystems based on the global MA systems: marine, coastal, inland water, forest, montado, island, mountain

Pereira, Henrique Miguel

358

Impact of Pt loading methods over mesoporous-assembled TiO{sub 2}–ZrO{sub 2} mixed oxide nanocrystal on photocatalytic dye-sensitized H{sub 2} production activity  

SciTech Connect (OSTI)

Graphical abstract: The Pt loading on the synthesized mesoporous-assembled 0.95TiO{sub 2}–0.05ZrO{sub 2} mixed oxide nanocrystal photocatalyst was comparatively investigated by two methods: single-step sol–gel (SSSG) and photochemical deposition (PCD). The Pt loading by the PCD method was found to be superior to that by the SSSG method in enhancing photocatalytic sensitized hydrogen production under visible light irradiation. The Pt loading amount and PCD conditions, i.e. light irradiation time and light intensity, also had a strong effect on the photocatalytic hydrogen production activity. Highlights: ? Pt-loaded mesoporous-assembled 0.95TiO{sub 2}–0.05ZrO{sub 2} nanocrystals were synthesized. ? Pt loading was performed by single-step sol–gel and photochemical deposition. ? Pt loading by photochemical deposition more enhanced photocatalytic H{sub 2} production. ? Pt loading amount and photochemical deposition conditions were optimized. -- Abstract: In this work, the photocatalytic water splitting under visible light irradiation for hydrogen production was investigated by using Eosin Y-sensitized Pt-loaded mesoporous-assembled TiO{sub 2}–ZrO{sub 2} mixed oxide nanocrystal photocatalysts. The mesoporous-assembled TiO{sub 2}–ZrO{sub 2} mixed oxide with the TiO{sub 2}-to-ZrO{sub 2} molar ratio of 95:5 (i.e. 0.95TiO{sub 2}–0.05ZrO{sub 2}) was synthesized by using a sol–gel process with the aid of a structure-directing surfactant. The Pt loading was comparatively performed via two different effective methods: single-step sol–gel (SSSG) and photochemical deposition (PCD). The synthesized photocatalysts were methodically characterized by N{sub 2} adsorption–desorption, XRD, UV–visible spectroscopy, SEM–EDX, TEM–EDX, TPR, and H{sub 2} chemisorption analyses. The results revealed that the Pt loading by the PCD method greatly enhanced the photocatalytic hydrogen production activity of the synthesized mesoporous-assembled 0.95TiO{sub 2}–0.05ZrO{sub 2} mixed oxide photocatalyst more than that by the SSSG method. The optimum Pt loading by the PCD method was experimentally observed at 0.5 wt.%, which was well associated with the maximum Pt dispersion. In addition, the PCD conditions, i.e. UV light irradiation time and UV light intensity, were investigated and optimized to be 2 h and 44 W, respectively.

Sreethawong, Thammanoon, E-mail: tsreethawong@hotmail.com [Baan Klangmuang Luzern, Soi On-nut 46, Sukhumvit 77 Road, Suanluang, Bangkok 10250 (Thailand)] [Baan Klangmuang Luzern, Soi On-nut 46, Sukhumvit 77 Road, Suanluang, Bangkok 10250 (Thailand); Yoshikawa, Susumu [Institute of Advanced Energy, Kyoto University, Uji, Kyoto 611-0011 (Japan)] [Institute of Advanced Energy, Kyoto University, Uji, Kyoto 611-0011 (Japan)

2012-06-15T23:59:59.000Z

359

Effect of the strain-induced melt activation (SIMA) process on the tensile properties of a new developed super high strength aluminum alloy modified by Al-5Ti-1B grain refiner  

SciTech Connect (OSTI)

In this study, the effect of Al-5Ti-1B grain refiners and modified strain-induced melt activation process on an Al-Zn-Mg-Cu alloy was studied. The optimum level of Ti was found to be 0.1 wt.%. The specimens subjected to deformation ratio of 40% (at 300 Degree-Sign C) and various heat treatment times (10-40 min) and temperature (550-600 Degree-Sign C) regimes were characterized in this study. Reheating condition to obtain a fine globular microstructure was optimized. Microstructural examinations were conducted by optical and scanning electron microscopy coupled with an energy dispersive spectrometry. The optimum temperature and time in strain-induced melt activation process are 575 Degree-Sign C and 20 min, respectively. T6 heat treatment including quenching to room temperature and aging at 120 Degree-Sign C for 24 h was employed to reach to the maximum strength. Significant improvements in mechanical properties were obtained with the addition of grain refiner combined with T6 heat treatment. After the T6 heat treatment, the average tensile strength increased from 283 MPa to 587 and 332 MPa to 617 for samples refined with 2 wt.% Al-5Ti-1B before and after strain-induced melt activation process and extrusion process, respectively. Ultimate strength of Ti-refined specimens without SIMA process has a lower value than globular microstructure specimens after SIMA and extrusion process. - Highlights: Black-Right-Pointing-Pointer The effect of Al-5Ti-1B on the aluminum alloy produced by SIMA process was studied. Black-Right-Pointing-Pointer Al-5Ti-1B is an effective in reducing the grain and reagent fine microstructure. Black-Right-Pointing-Pointer Reheating condition to obtain a fine globular microstructure was optimized. Black-Right-Pointing-Pointer The optimum temperature and time in SIMA process are 575 Degree-Sign C and 20 min respectively. Black-Right-Pointing-Pointer UTS of globular structure specimens have a more value than Ti-refined specimens.

Haghparast, Amin [School of Mechanical Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)] [School of Mechanical Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Nourimotlagh, Masoud [Young Researchers Club, Dareshahr Branch, Islamic Azad university (Iran, Islamic Republic of)] [Young Researchers Club, Dareshahr Branch, Islamic Azad university (Iran, Islamic Republic of); Alipour, Mohammad, E-mail: Alipourmo@ut.ac.ir [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)] [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

2012-09-15T23:59:59.000Z

360

Effects of surface miscuts on the epitaxy of YBa2Cu3O7-? and NdBa2Cu3O7-? on SrTiO3(001)  

Science Journals Connector (OSTI)

We report on the effects of small miscuts of the (001) SrTiO3 (STO) substrate surface, on the microstructure of epitaxial films of YBa2Cu3O7-? and NdBa2Cu3O7-? (NBCO). The most noticeable result is that, by growing NBCO films on miscut STO substrates with the steps intentionally oriented along a direction within 15° of [110], one reliably obtains NBCO films with a single [110] twinning variant (the [11¯0] is completely eliminated), which is a precious characteristic for all applications involving flux flow.

J.-L. Maurice, J. Briático, D.-G. Crété, J.-P. Contour, and O. Durand

2003-09-29T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

MA 165 EXAM 3 Fall 2009 Page 1/4  

E-Print Network [OSTI]

93—“ 3: “MW 0 4') iii .F/ it“ (m 11%“ 32);??? gr; Vim 5'36 A" Ti.) em ' we ... and points of in?ection, and give an equation for each asymptote. Write NONE Where.

362

DOE - Office of Legacy Management -- Metals and Controls Corp FSM Dept - MA  

Office of Legacy Management (LM)

and Controls Corp FSM Dept - and Controls Corp FSM Dept - MA 21 FUSRAP Considered Sites Site: METALS AND CONTROLS CORP., FSM DEPT. ( MA.21 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: M&C Texas Instruments MA.21-1 Location: Attleboro , Massachusetts MA.21-1 Evaluation Year: Circa 1987 MA.21-4 Site Operations: Nuclear fuel fabrication during the 1950s and 1960s. MA.21-2 Site Disposition: Eliminated - NRC licensed MA.21-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MA.21-3 Radiological Survey(s): Yes MA.21-3 Site Status: Eliminated from consideration under FUSRAP MA.21-2 Also see Documents Related to METALS AND CONTROLS CORP., FSM DEPT. MA.21-1 - Texas Instruments Letter; Veale to Duffy; Subject: Further

363

Enhanced power conversion efficiency of dye-sensitized solar cells with multifunctional photoanodes based on a three-dimensional TiO2 nanohelix array  

Science Journals Connector (OSTI)

Abstract Developments of metal oxide nanostructures for simultaneous improvements in light harvesting and charge collection can lead to a significant technical progress in various applications such as photoelectrodes for photoelectrochemical cells and various types of solar cells. Here we present an array of three-dimensional titanium dioxide (TiO2) nanohelixes infiltrated with TiO2 nanoparticles as a multifunctional photoanode for dye sensitized solar cells (DSSCs). The unique geometry and the near-single crystallinity of the vertically aligned TiO2 nanohelix array results simultaneously in strong light scattering and enhanced carrier transport and collection, while maintaining a comparable surface area accessible for dye molecules by the infiltrated TiO2 nanoparticles. Consequently, despite a ~40% reduction in dye loading, the overall photon conversion efficiency of the DSSC with the nanoparticle-infiltrated nanohelix-array photoanode is enhanced by 6.2% in comparison with the DSSC with the conventional nanoparticle photoanode.

Seung Hee Lee; Jeong Kwon; Dong Yeong Kim; Kyung Song; Sang Ho Oh; Jaehee Cho; E. Fred Schubert; Jong Hyeok Park; Jong Kyu Kim

2015-01-01T23:59:59.000Z

364

Chemical, Electronic and Nanostructure Dynamics on Sr(Ti[subscript 1 - x]FE[subscript x])O[subscript 3] Thin-Film Surfaces at High Temperatures  

E-Print Network [OSTI]

The surface structure, chemical composition and electronic structure of Sr(Ti1-xFex)O3 under different temperatures and oxygen pressures were studied by Scanning Tunneling Microscopy / Spectroscopy (STM/S) and X-ray ...

Chen, Yan

365

Inuence of foreign-object damage on crack initiation and early crack growth during high-cycle fatigue of Ti6Al4V  

E-Print Network [OSTI]

; Ti±6Al±4V 1. Introduction The high-cycle fatigue (HCF) of aircraft gas-turbine engine components has of small surface fatigue cracks in a Ti±6Al±4V alloy, processed for typical turbine blade applications microcracks in the damaged zone (seen only at the higher impact velocities). Furthermore, the eect of residual

Ritchie, Robert

366

Synergistic Effect of Nano-TiO2 and Nanoclay on the Ultraviolet Degradation and Physical Properties of Wood Polymer Nanocomposites  

Science Journals Connector (OSTI)

(7) The combination of nanoclay with other metal nanoparticles will influence the properties of the composites considerably, as reported by Laachachia et al. while studying the properties of poly(methyl methacrylate) (PMMA) nanocomposites prepared with TiO2 and nanoclay. ... (30) Mina et al. studied the XRD pattern of a polypropylene/titanium dioxide composite and reported a similar increase in the peak intensity of TiO2 in the composites. ...

Ankita Hazarika; Tarun K. Maji

2013-08-26T23:59:59.000Z

367

Role of ethylene on surface oxidation of TiO2(110) Y. Murata, V. Petrova, I. Petrov, C. V. Ciobanu, and S. Kodambaka  

E-Print Network [OSTI]

Institute of Physics. [http://dx.doi.org/10.1063/1.4767954] Transition-metal (TM) oxides,1 notably titanium dioxide (TiO2),2­4 have a wide variety of applications in photocataly- sis, for splitting of water5­13 and are essential to promote adsorption and reaction of gas molecules.14 As O atoms desorb from the sur- face of Ti

Ciobanu, Cristian

368

High sensitivity gravimetric sensor made of carbon fiber epoxy composite on Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystal substrate  

E-Print Network [OSTI]

High sensitivity gravimetric sensor made of carbon fiber epoxy composite on Pb(Mg1/3Nb2/3)O3-PbTiO3://apl.aip.org/authors #12;High sensitivity gravimetric sensor made of carbon fiber epoxy composite on Pb(Mg1/3Nb2/3)O3-Pb gravimetric sensor using unidirectional carbon fiber epoxy composite (CFEC) guiding layer on (1-x)Pb(Mg1/3Nb2

Cao, Wenwu

369

Studies on the sulfur poisoning of Ru-RuO{sub x}/TiO{sub 2} catalyst for the adsorption and methanation of carbon monoxide  

SciTech Connect (OSTI)

The effects of sulfur poisoning on the chemisorption and on the methanation of carbon monoxide over Ru/TiO{sub 2} catalyst were investigated by FTIR spectroscopy and volumetric gas adsorption measurements. The CS{sub 2} molecules are {eta}` bonded to Ru sites through one of the sulfur atoms and decompose to the constituent elements on thermal activation. Each S atom may deactivate 3 to 10 metal sites even at low coverages, the effect being more pronounced on the chemisorption of hydrogen. The deposited sulfur (and possibly carbon also) sterically hinders the formation of certain multicarbonyl and monocarbonyl species (vCO in 2055-2140 cm{sup -1} region), which otherwise transform to methane via surface methylene groups in the presence of chemisorbed hydrogen and are found to play an important role in the low-temperature methanation activity of the studied catalyst. The Ru-CO species giving rise to lower frequency vibrational bands are affected to a lesser extent. The presence of sulfur also results in the development of some new CO binding states which are weak and are identified with the CO and S coadsorbed at Ru sites of different oxidation states or of varying crystallographic nature. The CO adsorbed in these states is not reactive to hydrogen. 45 refs., 9 figs., 1 tab.

Kamble, V.S.; Londhe, V.P.; Gupta, N.M. [Bhambha Atomic Research centre, Bombay (India)] [and others] [Bhambha Atomic Research centre, Bombay (India); and others

1996-02-01T23:59:59.000Z

370

FTIR study of carbon monoxide oxidation and scrambling at room temperature over copper supported on ZnO and TiO{sub 2} No. 1  

SciTech Connect (OSTI)

An FTIR and quadrupole mass spectroscopic study of CO adsorption and oxidation with {sup 16}O{sub 2} and {sup 18}O{sub 2} on copper supported on ZnO and TiO{sub 2} is presented. The experimental results indicate that CO is adsorbed on the metallic particles dispersed on both oxides on two kinds of sites, on the normal terrace sites and on sites at the borderline of the particles. Moreover, on titania, a band at 2126 cm{sup -1}, assigned to CO adsorbed on isolated Cu atoms and/or on two-dimensional small clusters, is detected. A frequency shift of the bands of CO adsorbed on the metallic particles observed in the CO-O{sub 2} coadsorption experiments and the occurrence of a scrambling reaction between CO and {sup 18}O{sub 2} reveal that on all these samples, there are metallic sites which are able to adsorb at the same time oxygen atoms and carbon monoxide. Carbon dioxide and carbonate-like species are formed: the asymmetric stretching frequencies of CO{sub 2} and the quadrupole mass spectroscopic analysis reveal that with {sup 18}O{sub 2}, different isotopic molecular CO{sub 2}`s are formed, while the carbonate-like species have the same frequencies of those produced in {sup 16}O{sub 2}. Moreover, these species are completely lacking in the absence of oxygen in the gas phase. The experimental results indicate the there are, on these samples, two independent pathways for the CO oxidation, a direct oxidation of CO at the surface of the metallic particles and an induced oxidation with the surface lattice oxygen species of the supports. 46 refs., 8 figs.

Baccuzzi, F.; Chiorino, A. [Universita di Torino (Italy)] [Universita di Torino (Italy)

1996-02-29T23:59:59.000Z

371

SE-MA-NO Electric Coop | Open Energy Information  

Open Energy Info (EERE)

MA-NO Electric Coop MA-NO Electric Coop Jump to: navigation, search Name SE-MA-NO Electric Coop Place Missouri Utility Id 16851 Utility Location Yes Ownership C NERC Location SERC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Municipal HPS 100 W Lighting Municipal HPS 250 W Lighting Residential Residential Residential/Commercial HPS 100 W Lighting Residential/Commercial HPS 250 W Lighting Average Rates Residential: $0.0804/kWh Commercial: $0.0763/kWh Industrial: $0.0649/kWh References ↑ "EIA Form EIA-861 Final Data File for 2010 - File1_a"

372

PIA - Management and Administration (MA) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

PIA - Management and Administration (MA) PIA - Management and Administration (MA) PIA - Management and Administration (MA) The E-Government Act of 2002 requires Federal agencies to perform Privacy Impact Assessments (PIAs), an analysis of how information is handled, in order: (i) to ensure handling conforms to applicable legal, regulatory, and policy requirements regarding privacy, (ii) to determine the risks and effects of collecting, maintaining and disseminating information in identifiable form in an electronic information system, and (iii) to examine and evaluate protections and alternative processes for handling information to mitigate potential privacy risks. The DOE PIA process helps to ensure privacy protections are considered and implemented throughout the system life cycle. Following are all PIAs that have been done for Management and

373

Determination of crystallographic orientation of lead-free piezoelectric (K,Na)NbO{sub 3} epitaxial thin films grown on SrTiO{sub 3} (100) surfaces  

SciTech Connect (OSTI)

Crystallographic structure of sol-gel-processed lead-free (K,Na)NbO{sub 3} (KNN) epitaxial films on [100]-cut SrTiO{sub 3} single-crystalline substrates was investigated for a deeper understanding of its piezoelectric response. Lattice parameter measurement by high-resolution X-ray diffraction and transmission electron microscopy revealed that the orthorhombic KNN films on SrTiO{sub 3} (100) surfaces are [010] oriented (b-axis-oriented) rather than commonly identified c-axis orientation. Based on the crystallographic orientation and corresponding ferroelectric domain structure investigated by piezoresponse force microscopy, the superior piezoelectric property along b-axis of epitaxial KNN films than other orientations can be explained.

Yu, Qi; Zhu, Fang-Yuan; Cheng, Li-Qian; Wang, Ke; Li, Jing-Feng, E-mail: jingfeng@mail.tsinghua.edu.cn [State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, 100084 Beijing (China)] [State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, 100084 Beijing (China)

2014-03-10T23:59:59.000Z

374

GROUND RULES FOR MA 165 – FALL 2004  

E-Print Network [OSTI]

academic integrity and honesty. The students taking the exam are not allowed to seek or obtain any kind of help from anyone to answer questions on this test.

Purdue University

2013-08-16T23:59:59.000Z

375

STAT/MA 519 - Introduction to Probability  

E-Print Network [OSTI]

The lowest two homework scores will be dropped at the end of the semester. Collaboration on homework assginments is allowed and in fact encouraged, but.

2013-08-12T23:59:59.000Z

376

Nanolayered CrAlTiN and multilayered CrAlTiN–AlTiN coatings for solid particle erosion protection  

Science Journals Connector (OSTI)

Abstract Applying hard coatings on airfoil surfaces is proven to be an effective approach to mitigating erosion damage to engine components. Nanolayered or multilayered coatings, because of their capability of tailoring hardness and toughness through modifications in the chemistry and architecture of layer constituents, have been explored as potential candidates for this specific application. In this study, nanolayered CrAlTiN (CrN/AlTiN) coatings with different modulation periods, along with multilayered CrAlTiN–AlTiN coatings having different number of layers and different thickness of individual layers, were fabricated, characterized and evaluated. All the coatings significantly outperformed the CrN baseline in erosion resistance, and their performance was strongly affected by the bilayer period of the nanolayered coatings or the layer architectural characteristics of multilayered coatings.

Q. Yang; R. McKellar

2015-01-01T23:59:59.000Z

377

Modelling the coarsening behaviour of TiC precipitates in high-strength, low-alloy steels  

E-Print Network [OSTI]

Modelling the coarsening behaviour of TiC precipitates in high-strength, low-alloy steels Jae Hoon­sheet steels rely on a dispersion of fine precipitates based on TiC, generated during the major phase changes of the stoichiometry of titanium and carbon. The purpose was to assess the influences of interface energy and Ti/C

Cambridge, University of

378

Active oxygen species and mechanism for low-temperature CO oxidation reaction on a TiO{sub 2}-supported Au catalyst prepared from Au(PPh{sub 3})(NO{sub 3}) and as-precipitated titanium hydroxide  

SciTech Connect (OSTI)

The active oxygen species and mechanism for catalytic CO oxidation with O{sub 2} on a highly active TiO{sub 2}-supported Au catalyst (denoted as Au/Ti(OH){sub 4}{sup *}), which was prepared by supporting a Au-phophine complex on as-precipitated wet titanium hydroxide followed by calcination at 673 K, have been studied by means of oxygen isotope exchange, O{sub 2} temperature-programmed desorption (O{sub 2} TPD), electron spin resonance (ESR), and Fourier-transformed infrared spectroscopy (FT-IR). Surface lattice oxygen atoms on the Au/Ti(OH){sub 4}{sup *} catalyst were inactive for oxygen exchange with O{sub 2} and CO and also for CO oxidation at room temperature. The surface lattice oxygen atoms were exchanged only with the oxygen atoms of CO{sub 2}, probably via carbonates. O{sub 2} did not dissociate to atomic oxygen on the catalyst. The catalyst showed a paramagnetic signal at g = 2.002 due to unpaired electrons trapped at oxygen vacancies mainly at the surface. O{sub 2} adsorbed on the oxygen vacancies to form superoxide O{sub 2}{sup {minus}} with g{sub 1} = 2.020, g{sub 2} = 2.010, and g{sub 3} = 2.005, which are characteristic of O{sub 2}{sup {minus}} with an angular arrangement. Upon CO exposure, all the adsorbed oxygen species disappeared. The mechanism for the catalytic CO oxidation on the active Au/Ti(OH){sub 4}{sup *} catalyst is discussed in detail and compared with mechanisms reported previously.

Liu, H.; Kozlov, A.I.; Kozlova, A.P.; Shido, Takafumi; Asakura, Kiyotaka; Iwasawa, Yasuhiro [Univ. of Tokyo (Japan)] [Univ. of Tokyo (Japan)

1999-07-25T23:59:59.000Z

379

Ground Rules for MA 265, Spring 2014  

E-Print Network [OSTI]

ture of academic integrity and honesty. The students taking this exam are not allowed to seek or obtain any kind of help from anyone to answer questions on this ...

2013-12-13T23:59:59.000Z

380

MA373 S13 Test 4.pdf  

E-Print Network [OSTI]

May 2, 2013 ... borrow 1,000,000 at a floating interest rate that changes each year. Man enters into a swap in order to fix the interest rate that must be paid on ...

jeffb_000

2014-06-29T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

A novel hierarchical homogeneous nanoarchitecture of TiO2 nanosheets branched TiO2 nanosheet arrays for high efficiency dye-sensitized solar cells  

Science Journals Connector (OSTI)

Abstract We report a novel hierarchical homogeneous nanoarchitecture of TiO2 nanosheets branched TiO2 nanosheet arrays, which is formed directly on transparent conductive fluorine-doped tin oxide (FTO) glass substrate through a one-step facile hydrothermal reaction without the use of a seed layer. The hierarchical homogeneous nanoarchitecture is composed of long TiO2 nanosheet trunks grafted with a large number of TiO2 nanosheet branches, which is an effective structure to improve the charge transport with the increase of the specific surface area. Dye-sensitized solar cell (DSSC) based on TiO2 nanosheets branched TiO2 nanosheet arrays can achieve an outstanding power conversion efficiency of 6.66%, which is attributed to the specific performances such as higher specific surface area for adsorbing more dye molecules, superior light scattering capacity for boosting the light-harvesting efficiency and faster charge transport for efficient charge collection.

Bing-Xin Lei; Xiao-Feng Zheng; He-kang Qiao; Yi Li; Shu-Nuo Wang; Guo-Lei Huang; Zhen-Fan Sun

2014-01-01T23:59:59.000Z

382

Office of Informaiton Resources (MA-90)  

Broader source: Energy.gov (indexed) [DOE]

08 08 Melanie Pustay Director Office of Information and Privacy U.S. Department of Justice 1425 New York Ave., Suite 11050 Washington, DC 20530 Dear Ms. Pustay: Pursuant to the requirements set forth by Title 5, United States Code, Section 552(e), enclosed is a copy of the Annual Report on the administration of the Freedom of Information Act (FOIA) by the Department of Energy. The report will be made available on the World Wide Web through the FOIA Home Page of the Department. If you have any questions, please contact Mr. Chris Morris or Ms. Sheila Jeter of my staff at (202) 586-5955. Sincerely, yerlette L. aili in, Deputy Director FOIA and Privacy Act Office Office of Information Resources Enclosure @ Printed with soy ink on recycled paper U.S. Department of Energy

383

Studies on Structural and Dielectric Properties of ABi{sub 4}Ti{sub 4}O{sub 15} (A Ba, Sr and Pb) Ceramics  

SciTech Connect (OSTI)

Bismuth Titanate based electroceramics of layered perovskite structures are technologically important materials for high temperature piezoelectric and ferroelectric applications, due to their high Curie temperature (675 deg. C), Stable piezoelectric response and excellent dielectric properties. The compounds ABi{sub 4}Ti{sub 4}O{sub 15} (A = Ba, Sr and Pb) belongs to Aurivillius family (n = 4) in which BaBi{sub 4}Ti{sub 4}O{sub 15} crystallizes in tetragonal I4/mmm space group, Sr Bi{sub 4}Ti{sub 4}O{sub 15} and PbBi{sub 4}Ti{sub 4}O{sub 15} crystallizes in orthorhombic space group A2{sub 1}am. In the present work ABi{sub 4}Ti{sub 4}O{sub 15} (A = Ba, Sr and Pb) ceramic samples are prepared through the solid state reaction by conventional mixed oxides by calcination at high temperature. Dielectric constant ({epsilon}'{sub r}) and Dielectric Loss (D) for all the compositions as a function of temperature measured from frequencies 100 Hz to 100 KHz using a HIOKI 3532-50 LCR meter. The dielectric constant increases gradually with an increase in temperature up to transition temperature (T{sub c,} K) and then decreases.

Reddy, T. Gopal; Kumar, B. Rajesh; Rao, T. Subba [Materials Research Lab, Department of Physics, Sri Krishnadevaraya University, Anantapur-515055, A.P. (India)

2010-12-01T23:59:59.000Z

384

MA 26200 Linear Algebra & Differential Equations  

E-Print Network [OSTI]

To this end, Purdue has transitioned to online course evaluations. On Monday of the fifteenth week of classes, you will receive an official email from evaluation administrators with a link to the online evaluation site. You will have two weeks to

2013-08-18T23:59:59.000Z

385

127 Eastern Ave. Gloucester, MA 01930  

E-Print Network [OSTI]

instruction, paid to Project DEEP by the 3rd class meeting, = $150.00 ii)Open Water Instruction and gear and one of the two tanks necessary for the open water weekend WILL NOT be provided by Project DEEP. You rents these items for $75. D) Course fees to Project DEEP do not cover expenses to go on the open water

Schweik, Charles M.

386

Probing photochemical transformations at TiO{sub 2}/Pt and TiO{sub 2}/Ir interfaces using x-ray absorption spectroscopy  

SciTech Connect (OSTI)

Structural transformations at the TiO{sub 2}/Pt and TiO{sub 2}/Ir interfaces during UV-irradiation have been probed by X-ray absorption spectroscopy. Oxidation by the photogenerated holes results in the intercalation of Pt and Ir into the Titania matrix. The structural transformations observed with Pt and Ir nanoparticles anchored on TiO{sub 2} is different than the clustering of gold atoms observed in the TiO{sub 2}/Au system. Implications of such structural transformations on the photocatalytic activity of semiconductor photocatalyts are discussed.

Lahiri, Debdutta; Subramanian, V.; Bunker, Bruce A.; Kamat, Prashant V. [Synchrotron Radiation Section, Physics Group, Bhabha Atomic Research Centre, Mumbai 400085 (India); Department of Chemical Engineering, University of Illinois at Urbana-Champaign, Illinois 61801 (United States); Department of Physics, University of Notre Dame, Indiana 46556 (United States); Radiation Laboratory, University of Notre Dame, Indiana 46556 (United States)

2006-05-28T23:59:59.000Z

387

EFFECTS OF ION IRRADIATION ON Zr52.5Cu17.9Ni14.6Al10Ti5 (BAM-11) BULK METALLIC GLASS  

SciTech Connect (OSTI)

Bulk metallic glasses are intriguing candidates for nuclear applications due to their inherent amorphous structure, but their radiation response is largely unknown due to the relatively recent nature of innovations in bulk metallic glass fabrication. Here, microstructural and mechanical property evaluations have been performed on a Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glass (BAM-11) irradiated with 3 MeV Ni+ ions to 0.1 and 1.0 dpa at room temperature and 200 C. Nanoindentation hardness and Young s modulus both decreased by 6 to 20% in samples irradiated at room temperature, with the sample irradiated to 1.0 dpa experiencing the greatest change in mechanical properties. However, no significant changes in properties were observed in the samples irradiated at 200 C, and transmission electron microscopy showed no visible evidence of radiation damage or crystallization following ion irradiation at any of the tested conditions. These results suggest that BAM-11 bulk metallic glass may be useful for certain applications in nuclear environments.

Perez-Bergquist, Alex G [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Leonard, Keith J [ORNL] [ORNL; Zhang, Yanwen [ORNL] [ORNL; Zinkle, Steven J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

388

Microsoft Word - MA HCM Workforce Plan.doc  

Broader source: Energy.gov (indexed) [DOE]

HUMAN CAPITAL HUMAN CAPITAL MANAGEMENT WORKFORCE PLAN September 2006 This page left blank intentionally. MA Workforce Plan - September 2006 TABLE OF CONTENTS Table of Contents ........................................................................................................................... i Executive Summary ...................................................................................................................... 1 1.0 Introduction.......................................................................................................................... 3 1.1 Mission and Business Vision .........................................................................................3 1.2 Human Capital Management Strategy ...........................................................................4

389

Engineering Ethics Richard A. Burgess, M.A.  

E-Print Network [OSTI]

Engineering Ethics Richard A. Burgess, M.A. Texas Tech T-STEM Center and Deputy Director, National Institute for Engineering Ethics Summer 2012 #12;STEM includes Engineering · No single profession impacts the Rubble: An Introduction to Post-Disaster Engineering and Ethics by Sara Pfatteicher #12;Constraint

Gelfond, Michael

390

MA 387 ' SOIU' Lm Exam 2 April 16, 1982  

E-Print Network [OSTI]

MA 387 ' SOIU' Lm Exam 2 April 16, 1982. Name. (10) l _ 'Calculate each of the following; a) ?{(a,b)la < 0 and b 1 2} t: Cola) b) u{(a,b)l[a,b] 5 (1,2)}. : .Cl, 9.).

391

Ma, Bonzongo, Gao, Dong and Gress QUARTERLY PROGRESS REPORT  

E-Print Network [OSTI]

Characterization and Leachability of Coal Combustion Residues in Florida Principal investigator: Lena Q. Ma of coal combustion residues (CCR) and assess their metal leachability. The specific objectives are: 1- Environmental soil chemistry (Professor) Affiliation: Soil and Water Science Department, UF, Gainesville, FL

Ma, Lena

392

Index of /~jbeckley/WD/MA 373/F14  

E-Print Network [OSTI]

... 14-Jan-2015 15:16, 418K. [ ], MA373 F14 Test 4-1.pdf, 14-Jan-2015 15:27, 330K. Apache/2.2.3 (Red Hat) Server at www.math.purdue.edu Port 80.

393

Will This #Hashtag Be Popular Tomorrow? Zongyang Ma  

E-Print Network [OSTI]

Will This #Hashtag Be Popular Tomorrow? Zongyang Ma zma4@e.ntu.edu.sg Aixin Sun axsun@ntu.edu.sg Gao Cong gaocong@ntu.edu.sg School of Computer Engineering Nanyang Technological University, Singapore this prediction problem as a classification problem and evaluate the effectiveness of the extracted features

Aixin, Sun

394

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network [OSTI]

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Categorization and Decision Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Programming, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D

Maddox, W. Todd

395

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network [OSTI]

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Designing and constructing, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D., Chotibut, T

Maddox, W. Todd

396

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network [OSTI]

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Texas at Austin Austin, TX 78712 (512) 232-2883 e-mail: glass@mail.utexas.edu EDUCATION 2006 ­ Cognitive include: Designing and constructing experiments, statistical #12;Glass, Brian 2 analysis, manuscript

Maddox, W. Todd

397

DOE Zero Energy Ready Home Case Study, Transformation, Inc., Production House, Devens, MA  

Broader source: Energy.gov [DOE]

Case study of a DOE Zero Energy Ready Home in Devens, MA that scored HERS 35 without PV or HERS -37 with PV. This 2,508 ft2 custom home has R-46 double-stud walls with open–cell spray foam, a vented attic with R-67 blown cellulose, plus R-10 rigid XPS under the slab, R-20 closed-cell spray foam on basement walls, triple-pane windows, and one mini-split ductless heat pump.

398

DOE Zero Energy Ready Home Case Study, Transformations, Inc., Custom House, Devens, MA  

Broader source: Energy.gov [DOE]

Case study of a DOE Zero Energy Ready Home in Devens, MA that scored HERS 34 without PV or HERS -21 with PV. This 3,168 ft2 custom home has R-46 double-stud walls, a vented attic with R-67 blown cellulose, plus R-10 rigid XPS under the slab, R-20 closed-cell spray foam on basement walls, triple-pane windows, and mini-split ductless heat pumps.

399

The effects of Co-Ti co-doping on the magnetic, electrical, and magnetodielectric behaviors of M-type barium hexaferrites  

SciTech Connect (OSTI)

Magnetic, electrical and magnetodielectric properties have been studied in Co-Ti co-doped M-type hexaferrite BaCo{sub x}Ti{sub x}Fe{sub 12-2x}O{sub 19} (x = 0 ? 4). With the incorporation of Co-Ti, both their ferromagnetic magnetization and coercivity have been greatly changed. The temperature dependent magnetization curve shows a apparent hump at around 420 K, likely in association with more complicated cycloidal spin ordering, which is closely related to ferroelectric polarization. Interestingly, a significantly enhancement in resistivity (?3 orders in magnitude) can be obtained in co-doped samples (x > 2), which is beneficial for magnetoelectric properties. The magnetoelectric effect were examined by dielectric tunibility under external magnetic field, which shows apparent tunability up to ??3% for sample with x = 2 at 1T magnetic field, further supporting it is a room temperature single phase mutliferroic material.

Guan, Yujie; Lin, Yuanbin; Zou, Liangying; Miao, Qing; Zeng, Min; Gao, Xingsen, E-mail: xingsengao@scnu.edu.cn [Institute for Advanced Materials, South China Normal University, Guangzhou 510006 (China)] [Institute for Advanced Materials, South China Normal University, Guangzhou 510006 (China); Liu, Zhongwu [Department of Metallic Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China)] [Department of Metallic Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Liu, Junming [Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)] [Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)

2013-12-15T23:59:59.000Z

400

Fast Transporting ZnO–TiO2 Coaxial Photoanodes for Dye-Sensitized Solar Cells Based on ALD-Modified SiO2 Aerogel Frameworks  

Science Journals Connector (OSTI)

To circumvent this problem, we have explored here the idea of conformally coating the silica–ZnO aerogel structures with very thin layers of more robust metal oxides such as Al2O3, ZrO2, or TiO2 to create doubly coaxial structures. ... J–V characteristics of DSSCs featuring 25 ?m thick aerogel-based SiO2–ZnO films compared to similar films with ca. 3 and 4 Å coatings of Al2O3 and TiO2, respectively: (a) light performance; (b) dark performance. ... Figure 7. Plot showing the effects of increased layers of TiO2 coats over 6 nm ZnO-coated silica aerogels with respect to charge lifetimes from OCVD measurements. ...

Vennesa O. Williams; Nak Cheon Jeong; Chaiya Prasittichai; Omar K. Farha; Michael J. Pellin; Joseph T. Hupp

2012-06-21T23:59:59.000Z

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures  

SciTech Connect (OSTI)

We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

Ngai, J. H.; Kumah, D. P.; Walker, F. J. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Ahn, C. H. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Department of Mechanical Engineering and Materials Science, Yale University, 10 Hillhouse Avenue, New Haven, Connecticut 06520-8267 (United States)

2014-02-10T23:59:59.000Z

402

DOE_MA0518 December 2000  

Broader source: Energy.gov (indexed) [DOE]

was written in conjunction with the 50th was written in conjunction with the 50th anniversary commemoration of the Nevada Test Site. The history was released at the official celebration held in Las Vegas, Nevada, on December 18, 2000, fifty years after President Harry S. Truman formally designated the site as the location for conducting nuclear weapons tests within the continental United States. The history represents a unique partnership between a field office and two headquarters offices of the U.S. Department of Energy. The Department's Nevada Operations Office provided the initial impetus for the project and offered support and resources throughout the researching and writing of the history. The Office of Defense Programs of the Department's National Nuclear Security Administration provided funding for printing the history. The History

403

02-01-2011 Final MA Testimony  

Broader source: Energy.gov (indexed) [DOE]

CONTRACTING OVERSIGHT CONTRACTING OVERSIGHT COMMITTEE ON HOMELAND SECURITY AND GOVERNMENTAL AFFAIRS U.S. SENATE FEBRUARY 1, 2011 Madam Chairman and Members of the Subcommittee, my name is Ingrid Kolb. I serve as the Director, Office of Management at the U.S. Department of Energy. I am pleased to be here today to discuss with you how the Department uses audit services to detect and prevent waste, fraud, and abuse in government contracts, to provide contracting officers reasonable assurance whether contractor submissions are free of material misstatement, and provide them assistance and advice in the establishment of fair and reasonable prices for products and services. In fiscal years 2009 and 2010, the Department spent approximately $32 billion and $26

404

Continuously-tuned tunneling behaviors of ferroelectric tunnel junctions based on BaTiO{sub 3}/La{sub 0.67}Sr{sub 0.33}MnO{sub 3} heterostructure  

SciTech Connect (OSTI)

In this work, we fabricate BaTiO{sub 3}/La{sub 0.67}Sr{sub 0.33}MnO{sub 3} (BTO/LSMO) ferroelectric tunnel junction on (001) SrTiO{sub 3} substrate by pulsed laser deposition method. Combining piezoresponse force and conductive-tip atomic force microscopy, we demonstrate robust and reproducible polarization-controlled tunneling behaviors with the resulting tunneling electroresistance value reaching about 10{sup 2} in ultrathin BTO films (?1.2 nm) at room temperature. Moreover, local poling areas with different conductivity are finally achieved by controlling the relative proportion of upward and downward domains, and different poling areas exhibit stable transport properties.

Ou, Xin; Xu, Bo, E-mail: xubonju@gmail.com; Yin, Qiaonan; Xia, Yidong; Yin, Jiang; Liu, Zhiguo [National Laboratory of Solid State Microstructures and Department of Materials Science and Engineering, Nanjing University, Nanjing 210093 (China)] [National Laboratory of Solid State Microstructures and Department of Materials Science and Engineering, Nanjing University, Nanjing 210093 (China); Gong, Changjie; Lan, Xuexin [National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093 (China)] [National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093 (China)

2014-05-15T23:59:59.000Z

405

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides  

E-Print Network [OSTI]

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage the dissociative chemisorption of hydrogen in Ti-doped alanate storage materials. © 2007 American Institute

Ciobanu, Cristian

406

Preparation, characterization and applications of novel carbon and nitrogen codoped TiO{sub 2} nanoparticles from annealing TiN under CO atmosphere  

SciTech Connect (OSTI)

Graphical abstract: Carbon and nitrogen codoped TiO{sub 2} nanoparticles were firstly fabricated by calcining TiN powder under CO atmosphere at different temperatures between 400 and 600 °C, both the improved photocatalytic activity for degradation of methylene blue and enhanced photovoltaic performance for dye sensitized solar cells were demonstrated. - Highlights: • CN-codoped TiO{sub 2} nanoparticles were prepared by calcining TiN under CO atmosphere. • More visible light response was confirmed by UV–vis DRS and photocatalytic results. • Enhanced conversion efficiency was observed for the DSSCs from CN-TiO{sub 2} photoanode. • CN-codoping played an important role to improve the photocatalytic performance. - Abstract: Carbon and nitrogen codoped titania (CN-TiO{sub 2}) nanoparticles were fabricated by calcining titanium nitride (TiN) nanoparticles under carbon monoxide (CO) atmosphere at four different temperatures in a range of 400–600 °C. The as-prepared samples were characterized with X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and X-ray photoelectron spectroscopy (XPS). Enhanced light absorption in both the UV and visible light region was observed for the resulted CN-TiO{sub 2} nanoparticles in ultraviolet-visible diffuse reflectance spectroscopy (UV–vis DRS). Improved photocatalytic activity toward the degradation of methylene blue by the CN-TiO{sub 2} nanoparticles was demonstrated under UV and visible light, respectively. The highest degradation rate was achieved for CN-TiO{sub 2} nanoparticles (13%) compared to N-TiO{sub 2} (10%) and the commercial P25 (5%) under visible light illumination for 40 min. Furthermore, the improved photocatalytic activity of CN-TiO{sub 2} was also confirmed by the degradation of colorless resorcinol under UV–vis light irradiation. Dye-sensitized solar cells (DSSCs) were fabricated using P25, N-TiO{sub 2} and CN-TiO{sub 2} photoanodes, respectively. The highest conversion efficiency of 3.31% was achieved by the DSSCs based on the CN-TiO{sub 2} photoanodes in comparison with the commercial P25 (1.61%) and N-TiO{sub 2} (2.44%) photoanodes. This work demonstrates that thermal treatment of TiN nanoparticles under CO atmosphere has shown to be a rapid, direct and clean approach to synthesize photocatalysts with enhanced photocatalytic and photovoltaic performance.

Sun, Mingxuan; Song, Peng; Li, Jing; Cui, Xiaoli, E-mail: xiaolicui@fudan.edu.cn

2013-10-15T23:59:59.000Z

407

Characteristics of V2O5/Ti-PILC catalyst for the reduction of NO by NH3  

Science Journals Connector (OSTI)

Titania-pillared clay (Ti-PILC) as a catalyst support exhibited peculiar physicochemical characteristics compared to that of titania for the reduction of NO by NH3. The morphological variation of Ti-PILC was examined with respect to the preparation method. For the freeze-dried Ti-PILC, the development of needle-like crystallites, which may reveal the formation of a “house-of-cards” structure by delamination of Ti-PILC, has been observed. Ti-PILC catalyst contains high surface acidity examined by NH3 TPD. Without the impregnation of WO3 and MoO3 on V2O5/Ti-PILC catalyst as a promoter, the catalyst exhibits competitive NO removal performance to a commercial V2O5-WO3/TiO2 catalyst. In addition, Ti-PILC catalyst also exhibits the strong sulfur tolerance mainly attributed to the unique pore structure of the catalyst.

Ho Jeong Chae; In-Sik Nam; Young Gul Kim; Hee Sung Yang; Hyun Chul Choi{rk; Seok Lyong Song{rk

1999-01-01T23:59:59.000Z

408

u.s. DEPARTIIIENT OF ENERGY EERE PROJECT MA N A GE M E~ T CENT  

Broader source: Energy.gov (indexed) [DOE]

MA N A GE M E~ T CENT MA N A GE M E~ T CENT ER NEPA DETERlIlINATION Page 1 of2 RECIPIENT:Power Environmental Energy Research Institute STATE: CO PROJECT TITLE: Novel Multidimensional Tracers for Geolhermallnter-Well Diagnostics Funding Opportunity Announcement Number DE-PS36-09G099018 Procurement Instrument Number OE·EEOOO3032 NEPA Control Number GFO-1 0-345 CID Number G03032 Based on my review orlhe Information concerning the proposed action, as NEPA Compliance Officer (authoriud under DOE Order 4SI.IA),1 have made the following determination: ex, EA, [IS APPENDIX AND NUMBER: Description: 83.1 Onsile and offsite site characterization and environmental monitoring. including siting, construction (or modification), operation, and dismantlement or closing (abandonment) of characterization and monitoring devices and siting,

409

u.s. DEPARTMENT OF ENERGY EERE PROJECT MA->.IAGEMENT CENTER  

Broader source: Energy.gov (indexed) [DOE]

MA->.IAGEMENT CENTER MA->.IAGEMENT CENTER NEPA DETFRMINATION RECIPIENT;AWS Truepower, LlC Page 1 of2 STATE: NY PROJECT TITLE: National Offshore Wind Energy Resource and Design Data Campaign - Analysis and Collaboration Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CIO Number DE-FOA-0000414 DE-EEOOO5372 GF0-0005372-OO1 0 Based on my review oflhe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 4S1.1A), I have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering, analysis, and dissemination Information gathering (including, but not limited to, literature surveys, inventories, site visits, and audits), data analysis (including, but not limited to, computer modeling), document preparation (including, but not limited to, conceptual design,

410

u.s. DEPARTMENT OF ENERGY EERE PROJECT MA:-.IAGEMENT CENTER  

Broader source: Energy.gov (indexed) [DOE]

MA:-.IAGEMENT CENTER MA:-.IAGEMENT CENTER NEPA DETERMINATION RECIPIENT:Utah State University PROJECT TITLE: Alternative and Unconventional Energy Research and Development Page 1 of2 STATE: UT Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number cm Number COP DE-EEOOO3114 GF0-0003114-OO2 0 Based on my review or the information concerning the proposed action, as NEPA Compliance Officer (authorized under DO E Order 45 1.1A), I have made the following determination: CX, EA, [IS APPENDIX AND NUMBER: Description: B3.6 Siting. oonstruction (or modification), operation. and decommissioning of facilities for indoor bench-scale research projects and oonventionallaboratory operations (for example. preparation of chemical standards and sample analysis):

411

U.S. DEPARTMENT OF ENERGY EERE PROJECT MA>" AGEMENT CENTER NEPA DETERMINATION  

Broader source: Energy.gov (indexed) [DOE]

MA>" AGEMENT CENTER MA>" AGEMENT CENTER NEPA DETERMINATION RECIPIENT:Oregon Department of Energy PROJECT TITLE: Oregon EECBG Fonnula - City of Winston Page I of3 STATE: OR Funding Opportunity Announcement Number DE-FOA-OOOOO13 Procurement Instrument Number NEPA Control Number em Number EEO Based on my review crthe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 4Sl.I A), I have made the (ollowing determination: ex, EA, EIS APPENDIX AND NUMBER: Description : B1.3 Routine maintenance activities and custodial services for buildings, structures, rights-of-way, infrastructures (e.g .* pathways, roads, and railroads ), vehides and eqUipment, and localized vegetatJon and pest control, dunng which operations may be suspended and resumed. Custodial services are activities to preserve facility appearance, worl

412

U.S. DEPARTMENT OF ENERGY EERE PROJECT MA,"iAGEMENTCENTER NEPADETl!RMINATION  

Broader source: Energy.gov (indexed) [DOE]

MA,"iAGEMENTCENTER MA,"iAGEMENTCENTER NEPADETl!RMINATION RECIPIENT:CU Cfeantech -- University of Colorado PROJECT TITLE: CU Cleantech New Venture Challenge Page 1 of2 STATE: CO Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number elD Number DE-FOAOOOOS70 EE0005600 GFO-OOO5600-OO1 0 Based on my review of the information concerning tbe proposed action, as NEPA Compliance Officer (authorized under DOE Order 4Sl.1A), I have made the (ollowing determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering, analysis, and disseminatio n Information gathering (including, but not limited to, literature surveys, inventories, site visits, and audits). data analysis (including. but not limited to, computer modeling), document preparation (including. but not limited to, conceptual design,

413

u.s. DEPARTMENT OF ENERGY EERE PROJECT MA..\lAGEMENT CENTER  

Broader source: Energy.gov (indexed) [DOE]

lAGEMENT CENTER lAGEMENT CENTER NFPA DEl'ERAllNAIION RECIPIENT:MA DEPT. OF ENERGY RESOURCES PROJECT TITLE: STATE ENERGY PROGRAM (SEP) Page 1 of2 STATE: MA Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CIO Number DE·FOA.()()()()643 R130372 GF0-0130372-OO1 Based on my review of the information concerning the proposed action, as NEPA Compliance Officer (authori;.o;ed under DOE Order 45 1.lA), I have made the following de termination : ex, EA, EIS APPENDIX AND NUMBER: Description: A11 Technical advice and as sistance to o rganizations A9 Info rm at ion gathering, analysis, and d issemination Rational for detennination: Technical advice and planning assistance to international, national, state, and local organizations. Information gathering (including, but nollimited to, literature surveys, inventories, site visits, and

414

U.S. DEP.~TMENT OF ENERGY EERE PROJECT MA,\jAGEMENT CENTER  

Broader source: Energy.gov (indexed) [DOE]

MA,\jAGEMENT CENTER MA,\jAGEMENT CENTER NEPA DETERMINATION Page I of2 RECIPIENT: EECBG - American Samoa Government Territorial Energy Office STATE: AS PROJECT TITLE: Improving Recycling Capacity and Solid Waste Education in American Samoa Funding Opportunity Announcement Number PrO(urement Instrument Number DE-EEOOOOB34 NEPA Control Number GFO-OOOO634.Q01 em Number o Based on my review oftbe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 4S1.1A), I have made the (ollowing determination: ex, EA, EIS APPENDIX AND NUMBER: Description: 81 .31 installation or relocation of machinery and equipment Installation or relocation and operation of machinery and equipment (including, but not limited la, laboratory equipment, electronic hardware, manufacturing machinery, maintenance equipment, and health and safety equipment), provided that

415

MaGe - a Geant4-based Monte Carlo framework for low-background experiments  

E-Print Network [OSTI]

A Monte Carlo framework, MaGe, has been developed based on the Geant4 simulation toolkit. Its purpose is to simulate physics processes in low-energy and low-background radiation detectors, specifically for the Majorana and Gerda $^{76}$Ge neutrinoless double-beta decay experiments. This jointly-developed tool is also used to verify the simulation of physics processes relevant to other low-background experiments in Geant4. The MaGe framework contains simulations of prototype experiments and test stands, and is easily extended to incorporate new geometries and configurations while still using the same verified physics processes, tunings, and code framework. This reduces duplication of efforts and improves the robustness of and confidence in the simulation output.

Yuen-Dat Chan; Jason A. Detwiler; Reyco Henning; Victor M. Gehman; Rob A. Johnson; David V. Jordan; Kareem Kazkaz; Markus Knapp; Kevin Kroninger; Daniel Lenz; Jing Liu; Xiang Liu; Michael G. Marino; Akbar Mokhtarani; Luciano Pandola; Alexis G. Schubert; Claudia Tomei

2008-02-06T23:59:59.000Z

416

Dynamic recrystallization and superplasticity in TiAl  

SciTech Connect (OSTI)

The effect of structural factors (grain size, grain boundary structure and fraction of the second phase) on dynamic recrystallization and superplasticity in the TiAl intermetallic alloy was studied. The possibilities of the formation of submicrocrystalline structure and the abrupt decrease of the superplastic temperature were shown. It was established that the occurrence of dynamic recrystallization and superplastic flow led to the formation of homogeneous microstructure and the improvement of low-temperature ductility in TiAl.

Salishchev, G.; Imayev, R.; Imayev, V.; Shagiev, M. [Inst. for Metals Superplasticity Problems, Ufa (Russian Federation)

1995-12-31T23:59:59.000Z

417

Carbide precipitation in gamma-TiAl alloys  

SciTech Connect (OSTI)

Carbide precipitation in gamma-TiAl is observed and found to involve the formation of coherent, rod-shaped perovskite precipitates as a metastable transition phase. At temperatures above 750 deg C, the formation of plate-shaped H-phase particles on dislocations and grain boundaries is accompanied by dissolution of the perovskite precipitate dispersions. This temperature regime includes possible service temperatures for gamma-TiAl-based alloys. 10 refs.

Chen, S.; Beaven, P.A.; Wagner, R. (GKSS-Forschungszentrum Geesthacht GmbH, (Germany))

1992-04-01T23:59:59.000Z

418

TI--CR--AL--O thin film resistors  

DOE Patents [OSTI]

Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

2000-01-01T23:59:59.000Z

419

Formation of solar cells based on Ba{sub 0.5}Sr{sub 0.5}TiO{sub 3} (BST) ferroelectric thick film  

SciTech Connect (OSTI)

Growth of Ba{sub 0.5}Sr{sub 0.5}TiO{sub 3} (BST) 1 M thick films are conducted with variation of annealing hold time of 8 hours, 15 hours, 22 hours, and 29 hours at a constant temperature of 850 °C on p-type Si (100) substrate using sol-gel method then followed by spin coating process at 3000 rpm for 30 seconds. The BST thick film electrical conductivity is obtained to be 10{sup ?5} to 10{sup ?4} S/cm indicate that the BST thick film is classified as semiconductor material. The semiconductor energy band gap value of BST thick film based on annealing hold time of 8 hours, 15 hours, 22 hours, and 29 hours are 2.58 eV, 3.15 eV, 3.2 eV and 2.62 eV, respectively. The I-V photovoltaic characterization shows that the BST thick film is potentially solar cell device, and in accordance to annealing hold time of 8 hours, 15 hours, 22 hours and 29 hours have respective solar cell energy conversion efficiencies of 0.343%, 0.399%, 0.469% and 0.374%, respectively. Optical spectroscopy shows that BST thick film solar cells with annealing hold time of 8 hours, 15 hours, and 22 hours absorb effectively light energy at wavelength of ? 700 nm. BST film samples with annealing hold time of 29 hours absorb effectively light energy at wavelength of ? 700 nm. The BST thick film refraction index is between 1.1 to 1.8 at light wavelength between ±370 to 870 nm.

Irzaman,, E-mail: irzaman@yahoo.com; Syafutra, H., E-mail: irzaman@yahoo.com; Arif, A., E-mail: irzaman@yahoo.com; Alatas, H., E-mail: irzaman@yahoo.com [Department of Physics, FMIPA Bogor Agricultural Unversity, Campus Darmaga Gedung Wing S Bogor (Indonesia); Hilaluddin, M. N.; Kurniawan, A.; Iskandar, J.; Dahrul, M.; Ismangil, A.; Yosman, D.; Aminullah [Department of Biophysics, FMIPA Bogor Agricultural Unversity (Indonesia); Prasetyo, L. B. [Department of Forest Resources Conservation, FAHUTAN, Bogor Agricultural Unversity, Campus Darmaga Bogor (Indonesia); Yusuf, A.; Kadri, T. M. [LAPAN Rancabungur Ciampea Bogor (Indonesia)

2014-02-24T23:59:59.000Z

420

Dependence of Band Offset and Open-Circuit Voltage on the Interfacial Interaction between TiO2 and Carboxylated Polythiophenes  

E-Print Network [OSTI]

the open-circuit voltage. An attractive approach for making low-cost photovoltaic (PV) cells is to use bulk, 2005 The interface of planar TiO2/polymer photovoltaic cells was modified with two carboxylated to titania surfaces in photovoltaic cells. If the density of attachment groups is just enough to attach

McGehee, Michael

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Effects of Cu Diffusion from ZnTe:Cu/Ti Contacts on Carrier Lifetime of CdS/CdTe Thin Film Solar Cells: Preprint  

SciTech Connect (OSTI)

We study the performance of CdS/CdTe thin film PV devices processed with a ZnTe:Cu/Ti contact to investigate how carrier lifetime in the CdTe layer is affected by Cu diffusion from the contact.

Gessert, T. A.; Metzger, W. K.; Asher, S. E.; Young, M. R.; Johnston, S.; Dhere, R. G.; Duda, A.

2008-05-01T23:59:59.000Z

422

Fabrication of functionally graded TiC/Ti composites by Laser Engineered Net Shaping  

E-Print Network [OSTI]

engineered net shaping (LENS), with compositions changing from pure Ti to approximately 95 vol% TiC; Microstructure; TiC carbide 1. Introduction Functionally graded materials (FGMs) are a class of advanced

DuPont, John N.

423

Structure and ductility of TiAl  

SciTech Connect (OSTI)

The effect of structural factors (grain size and grain boundary structure) and strain rate on the deformation mechanism and ductility of TiAl in the temperature range of brittle-to-ductile transition and at room temperature was systematically investigated. It has been established that it is possible to substantially affect the deformation mechanism and ductility of this intermetallic by controlling structural factors, particularly the grain size, and varying the strain rate.

Imayev, R.; Salishchev, G.; Imayev, V.; Shagiev, M.; Kuznetzov, A. [Inst. for Metals Superplasticity Problems, Ufa (Russian Federation)

1995-12-31T23:59:59.000Z

424

Town of Danvers, MA Smart Grid Project | Open Energy Information  

Open Energy Info (EERE)

Smart Grid Project Smart Grid Project Jump to: navigation, search Project Lead Town of Danvers, MA Country United States Headquarters Location Danvers, Massachusetts Recovery Act Funding $8,476,800.00 Total Project Value $16,953,600.00 Coverage Area Coverage Map: Town of Danvers, MA Smart Grid Project Coordinates 42.5750946°, -70.9300507° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

425

EDeMa (Smart Grid Project) | Open Energy Information  

Open Energy Info (EERE)

EDeMa EDeMa Country Germany Headquarters Location Mülheim, Germany Coordinates 51.427074°, 6.886492° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":51.427074,"lon":6.886492,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

426

The Effect of Oxygen Contamination on the Amorphous Structure of Thermally Sprayed Coatings of Cu47Ti33Zr11Ni8Si1  

SciTech Connect (OSTI)

this research has shown that it is possible to deposit coatings of gas atomized Cu{sub 47}Ti{sub 33}Zr{sub 11}Ni{sub 8}Si{sub 1} powders containing various levels of oxygen contamination using plasma arc spray methods. The structure of the coating was found to depend primarily on the spray environment, with an argon atmosphere producing the most amorphous samples for a given starting powder. The oxygen content of the coatings reflected the relative levels of the oxygen contamination in the starting powders. The analysis of the starting powders displayed oxygen contents ranging from 0.125-0.79 wt.%. It was shown that higher oxygen levels lead to more crystalline structure in the starting powders as determined by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). This trend was found to be true for both the starting powders and for the plasma sprayed coatings. Chemical composition for all starting powders was very close to the nominal alloy composition. Chemical changes in the coatings involved the loss of Cu in coatings where high levels of oxidation were found. Cavitation erosion testing of selected coatings showed a weak trend that coatings prepared by vacuum plasma spray (VPS) had lower damage rates, but there was no clear data to indicate which coating parameters were superior. The range of data produced from testing duplicate coating was too wide to provide a good statistical measure of cavitation erosion resistance. of interest was the fact that when coatings began to show damage from cracking, all samples of a group showed similar damage and usually the damage pattern was somewhat unique to that group of samples. Failure of the coatings was due to features inherent to plasma arc spray (PAS) coating (i.e., pores, splat boundaries, oxide inclusions) rather than the mechanical characteristics of the amorphous alloy.

Matthew Frank Besser

2002-05-27T23:59:59.000Z

427

3d X 3d X SrTiO3Ti 2p 3d  

E-Print Network [OSTI]

XX 3d X 3d X X XX X XX SrTiO3Ti 2p 3d SrTiO3Ti 2p 3d 2p 2p SrTiO3 ts) 2p3/2 (t2g) 2p3/2 (e ) 2p1/2 (eg)2p SrTiO3 3d unit (t2g) (eg) (eg)2p1/2 (t2g)3d (Ti Fe Cu) arb. ( 2g) (Ti, Fe, Cu) y(ansitynten 3d In 3d 468464460456 · Photon Energy (e

Katsumoto, Shingo

428

Weldability and toughness assessment of Ti-microalloyed offshore steel  

SciTech Connect (OSTI)

The present study has been carried out to investigate the coarse-grained heat-affected zone (CGHAZ) microstructure and crack tip opening displacement (CTOD) toughness of grade StE 355 Ti-microalloyed offshore steels. Three parent plates (40-mm thick) were studied, two of which had Ti microalloying with either Nb + V or Nb also present. As a third steel, conventional StE 355 steel without Ti addition was welded for comparison purposes. Multipass tandem submerged arc weld (SAW) and manual metal arc weld (SMAW) welds were produced. Different heat-affected zone (HAZ) microstructures were simulated to ascertain the detrimental effect of welding on toughness. All HAZ microstructures were examined using optical and electron microscopy. It can be concluded that Ti addition with appropriate steel processing, which disperses fine TiN precipitates uniformly, with a fine balance of other microalloying elements and with a Ti/N weight ratio of about 2.2, is beneficial for HAZ properties of StE 355 grade steel.

Rak, I.; Gliha, V. [Univ. of Maribor (Slovenia). Faculty of Mechanical Engineering; Kocak, M. [GKSS Research Center Geesthacht (Germany)

1997-01-01T23:59:59.000Z

429

Landing of size-selected Agn clusters on single crystal TiO2 ,,110...-,,11...  

E-Print Network [OSTI]

-selected Agn + n=1,2,3 clusters with impact energy less than 2 eV per atom were deposited from the gas phase supports catalyze many reactions, including the oxidation of CO and small olefins1­4 has stimulated great interest in un- derstanding the nature of the catalytic activity, including the dependence on cluster size

Buratto, Steve

430

DOE - Office of Legacy Management -- E B Badger - MA 0-01  

Office of Legacy Management (LM)

E B Badger - MA 0-01 E B Badger - MA 0-01 FUSRAP Considered Sites Site: E.B. Badger (MA.0-01 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 75 Pitts Street , Boston , Massachusetts MA.0-01-1 Evaluation Year: 1987 MA.0-01-2 Site Operations: Construction contractor during the mid-1940s; constructed facility to refine pitchblende ore and produce feed materials at another location. MA.0-01-2 Site Disposition: Eliminated - No indication of radioactive materials handled at this site MA.0-01-2 Radioactive Materials Handled: No Primary Radioactive Materials Handled: None MA.0-01-2 Radiological Survey(s): No Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to E.B. Badger

431

E-Print Network 3.0 - ages 600-570 ma Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The former age signature is more... , zircons have 2850 Ma cores and 2730 Ma rims. Titanite ages are similar to those from zircon rims... and zircon using LA-ICP-MS. The oldest...

432

low Si p+-n junctions fabricated by focused ion beam Ga+ implantation through thin Ti and TiSi2 layers  

E-Print Network [OSTI]

metals and silicide layers, in conjunction with rapid thermal annealing (RTA) to complete metal silicides and it forms uniform thin films on Si. Most of the current research involving salicide+ implantation through Ti metal (ITM) and TiSi, (ITS) layers, followed by rapid thermal annealing (RTA), has been

Steckl, Andrew J.

433

Photocatalytic effects of wool fibers modified with solely TiO2 nanoparticles and N-doped TiO2 nanoparticles by using hydrothermal method  

Science Journals Connector (OSTI)

Abstract The surfaces of wool fibers are modified with N-doped TiO2 nanoparticles by treating the fibers with tetrabutyl titanate and ammonium chloride under low temperature hydrothermal conditions to obtain wool fibers with photocatalytic functions in the visible light spectrum. The effects of nitrogen and sulfur in amino acids in keratin on the photocatalytic activity of TiO2 particle coated wool fibers are investigated. Changes of various fiber properties such as tensile strength, photocatalytic activity, and self-cleaning performance of untreated, TiO2 coated and N-doped TiO2 coated wool fibers are studied. It is found that N-doped anatase TiO2 nanoparticles with an average grain size of 11.2 nm are synthesized and simultaneously grafted onto the wool fibers. After treatments, the crystallization index of the wool fibers is slightly reduced. The capability to protect against ultraviolet radiation is much enhanced. The performances of photocatalytic degradation of methylene blue dye and self-cleaning of red wine under both UV and visible light irradiation are endowed. It is also found that wool fibers coated with TiO2 particles without being doped by nitrogen still have apparent photocatalytic reactions and self-cleaning effects under visible light irradiation due to the formation of C-Ti3+, O-Ti3+, and N-Ti3+ bonds between TiO2 and wool keratin on the wool fiber surfaces. Thus wool fabrics might not need to be coated with N-doped TiO2 nanoparticles to realize its self-cleaning effect under visible light. Such important conclusions would provide wool materials with wide applications in clothing and technical products such as wastewater treatment.

Hui Zhang; Zhenwei Yang; Xingtao Zhang; Ningtao Mao

2014-01-01T23:59:59.000Z

434

Hanford External Dosimetry Technical Basis Manual PNL-MA-842  

SciTech Connect (OSTI)

The Hanford External Dosimetry Technical Basis Manual PNL-MA-842 documents the design and implementation of the external dosimetry system used at Hanford. The manual describes the dosimeter design, processing protocols, dose calculation methodology, radiation fields encountered, dosimeter response characteristics, limitations of dosimeter design under field conditions, and makes recommendations for effective use of the dosimeters in the field. The manual describes the technical basis for the dosimetry system in a manner intended to help ensure defensibility of the dose of record at Hanford and to demonstrate compliance with 10 CFR 835, DOELAP, DOE-RL, ORP, PNSO, and Hanford contractor requirements. The dosimetry system is operated by PNNL’s Hanford External Dosimetry Program (HEDP) which provides dosimetry services to all Hanford contractors. The primary users of this manual are DOE and DOE contractors at Hanford using the dosimetry services of PNNL. Development and maintenance of this manual is funded directly by DOE and DOE contractors. Its contents have been reviewed and approved by DOE and DOE contractors at Hanford through the Hanford Personnel Dosimetry Advisory Committee (HPDAC) which is chartered and chaired by DOE-RL and serves as means of coordinating dosimetry practices across contractors at Hanford. This manual was established in 1996. Since inception, it has been revised many times and maintained by PNNL as a controlled document with controlled distribution. Rev. 0 marks the first revision to be released through PNNL’s Electronic Records & Information Capture Architecture (ERICA) database. Revision numbers that are whole numbers reflect major revisions typically involving changes to all chapters in the document. Revision numbers that include a decimal fraction reflect minor revisions, usually restricted to selected chapters or selected pages in the document. Revision Log: Rev. 0 (2/25/2005) Major revision and expansion. Rev. 0.1 (3/12/2007) Minor revision. Updated Chapters 5, 6 and 9 to reflect change in default ring calibration factor used in HEDP dose calculation software. Factor changed from 1.5 to 2.0 beginning January 1, 2007. Pages on which changes were made are as follows: 5.23, 5.69, 5.78, 5.80, 5.82, 6.3, 6.5, 6.29, 9.2.

Rathbone, Bruce A.

2007-03-12T23:59:59.000Z

435

Optical Properties of TiO2 Suspensions:? Influence of pH and Powder Concentration on Mean Particle Size  

Science Journals Connector (OSTI)

An approximated form of the hyperbolic solution of the radiation transfer equation obtained by Kubelka and Munk can be applied for optically thick media; this solution assumes a simple expression of the kind of Lambert?Beer law with two adjustable parameters from which the optical coefficients can be readily calculated. ... The external surfaces of both vessels were covered by mirror-polished aluminum sheets. ... A very easy approach is the Schuster?Schwarzschild approximation22 based on the main assumptions that (i) the scattering and absorption phenomena are properties of a continuum irradiated layer;8 (ii) the Lambert cosine law holds involving isotropic distribution of scattering;23 (iii) the particles are randomly distributed, and their size is smaller than the thickness of the layer; and (iv) the layer is subjected to diffuse radiation. ...

Sedat Yurdakal; Vittorio Loddo; Bernardí Bayarri Ferrer; Giovanni Palmisano; Vincenzo Augugliaro; Jaime Giménez Farreras; Leonardo Palmisano

2007-05-16T23:59:59.000Z

436

CSC 1051 M.A. Papalaskari, Villanova University CSC 1051 Data Structures and Algorithms I  

E-Print Network [OSTI]

CSC 1051 M.A. Papalaskari, Villanova University Repetition CSC 1051 ­ Data Structures.6 Interactive Programs · 5.1 Boolean Expressions · 5.2 The if Statement · 5.4 The while Statement CSC 1051 M.A CSC 1051 M.A. Papalaskari, Villanova University #12;Flow of Control The order of statement execution

Papalaskari, Mary-Angela

437

CSC 1051 M.A. Papalaskari, Villanova University Data Representation and  

E-Print Network [OSTI]

CSC 1051 M.A. Papalaskari, Villanova University Data Representation and Applets CSC 1051 ­ Data conversions · Image representation · Java Applets CSC 1051 M.A. Papalaskari, Villanova University #12;Reverse CSC 1051 M.A. Papalaskari, Villanova University Review #12;Memory devices store data of all kinds 9278

Papalaskari, Mary-Angela

438

CSC 1051 M.A. Papalaskari, Villanova University CSC 1051 Data Structures and Algorithms I  

E-Print Network [OSTI]

CSC 1051 M.A. Papalaskari, Villanova University Repetition CSC 1051 ­ Data Structures 1051 M.A. Papalaskari, Villanova University statement 1 statement 2 statement 3 statement 4 boolean 1 statements: enable us to alter control flow CSC 1051 M.A. Papalaskari, Villanova University statement 1

Papalaskari, Mary-Angela

439

CSC 1051 M.A. Papalaskari, Villanova University CSC 1051 Data Structures and Algorithms I  

E-Print Network [OSTI]

CSC 1051 M.A. Papalaskari, Villanova University Repetition CSC 1051 ­ Data Structures 1051 M.A. Papalaskari, Villanova University statement 1 statement 2 statement 3 statement 4 boolean 1 does it take for the account balance to be double the original? CSC 1051 M.A. Papalaskari, Villanova

Papalaskari, Mary-Angela

440

MA47, a Fortran code for direct solution of indefinite sparse symmetric linear systems  

E-Print Network [OSTI]

-first search of the assembly tree ........................ 23 3.8 MA47M: calculate storage and operation countsRAL-95-001 MA47, a Fortran code for direct solution of indefinite sparse symmetric linear systems indefinite symmetric linear systems of equations. It is intended to complement the Harwell code MA27

Mihajlovic, Milan D.

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

DATA FUSION IN 2D AND 3D IMAGE PROCESSING: AN OVERVIEW Isabelle BLOCH, Henri MA^ITRE  

E-Print Network [OSTI]

DATA FUSION IN 2D AND 3D IMAGE PROCESSING: AN OVERVIEW Isabelle BLOCH, Henri MA^ITRE Ecole of the art in image fusion, with an emphasis on the emergence of new techniques, often issued from other the aim of data fusion and its speci city when image informationhas to be combined, with emphasis

442

Adsorption and Oxidation of Elemental Mercury over Ce-MnOx/Ti-PILCs  

Science Journals Connector (OSTI)

A series of innovative Ce–Mn/Ti-pillared-clay (Ce–Mn/Ti-PILC) catalysts combining the advantages of PILCs and Ce–Mn were investigated for elemental mercury (Hg0) capture at 100–350 °C in the absence of HCl in the flue gas. ... The catalyst characterization indicated that the 6%Ce-6%MnOx/Ti-PILC catalyst possessed a large specific surface area and high dispersion of Ce and Mn on the surface. ... The experimental results indicated that the 6%Ce-6%MnOx/Ti-PILC catalyst exhibited high Hg0 capture (>90%) at 100–350 °C. ...

Chuan He; Boxiong Shen; Jianhong Chen; Ji Cai

2014-06-23T23:59:59.000Z

443

Surface characterization and mechanical property of TiN/Ti-coated NiTi alloy by PIIID  

E-Print Network [OSTI]

significantly reduces the friction coefficient and improves wear resistance of the NiTi alloy. © 2006 Elsevier B prosthesis, heart valve replacement and biosensors [6,7]. TiN surface coating has also been found

Zheng, Yufeng

444

Cosmology on the Beach - Chung-Pei Ma, Lecture 3  

ScienceCinema (OSTI)

The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

Chung-Pei Ma

2010-01-08T23:59:59.000Z

445

Cosmology on the Beach - Chung-Pei Ma: Lecture 2  

ScienceCinema (OSTI)

The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009

Chung-Pei Ma

2010-01-08T23:59:59.000Z

446

Compton Profile Study of Intermetallic Ti{sub 3}Al  

SciTech Connect (OSTI)

The Compton scattering measurement on intermetallic alloy Ti{sub 3}Al is reported in this work. The measurement is made using 59.54 keV gamma-rays from Am{sup 241} source. Theoretical calculation of Compton profile is also performed employing CRYSTAL code within the framework of density functional theory to compare with the measurement. The theoretical profile of the alloy is also synthesized following the superposition model taking the published Compton profiles of elemental solids from the APW method. The experimental study of charge transfer in the alloys has also been done by performing the experimental Compton profile measurements on Ti and Al following the superposition model and charge transfer from Al to Ti is clearly seen on the alloy formation.

Vyas, V.; Sharma, G. [Department of Physics, Banasthali University, Banasthali-304022 (India); Mishra, M. C.; Sharma, B. K. [Department of Physics, University of Rajasthan, Jaipur-302004 (India); Joshi, K. B. [Department of Physics, University College of Science, M.L.Sukhadia University, Udaipur-313 002 (India)

2011-10-20T23:59:59.000Z

447

Prediction of a Dirac state in monolayer TiB2  

Science Journals Connector (OSTI)

We predict the existence of a Dirac state in a monolayer TiB2 sheet (m?TiB2), a two-dimensional metal diboride, based on first-principles calculations. The band structure of m?TiB2 is found to be characterized with anisotropic Dirac cones with the largest Fermi velocity of 0.57×106 m/s, which is about one-half of that of graphene. The Dirac point is located at the Fermi level between the K and ? points, with the Dirac states arising primarily from the d orbitals of Ti. Freestanding m?TiB2 exhibits a bending instability, so that a planar m?TiB2 needs to be stabilized on a substrate. The calculation of m?TiB2 on a h-BN substrate reveals a negligible influence of the h-BN substrate on the electronic properties of m?TiB2. Our findings extend the Dirac materials to metal diborides.

L. Z. Zhang; Z. F. Wang; S. X. Du; H.-J. Gao; Feng Liu

2014-10-03T23:59:59.000Z

448

Response to 'Comment on 'Controllable local modification of fractured Nb-doped SrTiO{sub 3} surfaces' [Appl. Phys. Lett. 98, 256102 (2011)'.  

SciTech Connect (OSTI)

In their comment, Chen et al. try to argue that the experimentally observed controllable voltage-induced surface modification, which was attributed to a local electric field-induced atom transfer from the surface to the tip, is rather caused by either an oxidation process and/or a resistance change. In this response, we will show that we can rule out these two effects in our experiment. The statements by Chen et al. are based on two arguments: (1) the tip modification after transferring an adatom should alter the dI/dV contrast, which was not seen in our experiments and (2) the vacuum conditions in our experiment are similar to earlier reports on resistance switching. First, Chen et al. discuss that the adsorption on the tip should alter the topographic contrast, as many papers have reported. In fact, in our experiments we frequently observed tip modifications at high bias voltage. These typically result in slight changes in scanning tunneling spectroscopy data [see, for example, the spectra in Fig. 3(b) in Ref. 4 and Fig. 2(d) of Ref. 5] but only weakly affected the topographic contrast. Second, Chen et al. claim that oxidation is another possible mechanism to explain our experimental observations. To support this claim, they compare our results to an earlier publication showing resistance switching. In fact, the resistance switching mechanism is related to oxygen vacancy migration or local surface oxidation. The mechanism of oxygen vacancy migration requires a 'forming' process with a threshold current in the order of microampere or even milliampere. In our experimental setup, however, we used tunneling currents in the order of 50 pA. Even during surface modification, which was performed at open feedback loop conditions with voltage pulse of up to 3 or -5 V, the maximum transient current did not exceed a few nanoampere. Therefore, we can safely exclude oxygen vacancy migration as a potential mechanism for the observed surface modification. As a second potential mechanism Chen et al. mention a local surface oxidation process. However, the total pressure at high-vacuum conditions used in experiments, where resistance switching was observed (10{sup -7} torr in Ref. 3) is three order magnitude higher than in our experiment performed under ultrahigh vacuum (UHV) conditions (below 10{sup -10} torr). Furthermore, mass spectra measured with a residual gas analyzer show that the main residue gas in our UHV system is hydrogen ({approx} 90%). Water, oxygen, and other oxygen-related gases are negligible with a partial pressure in the order of 10{sup -12} torr range or lower. Therefore, we can also exclude that local oxidation with reactants from the residual gas causes the observed modifications. In addition, in our experiment, the refilling of the modified areas at negative bias could not be observed with fresh tip, even for bias voltages as high as -10 V. In short, the mechanism for the modification on the UHV in situ fractured Nb:SrTiO{sub 3} (Nb-doped Strontium titanate) surfaces with scanning tunneling microscope (STM) tip is different from the mechanisms such as local surface oxidation or filament formation, used to explain the largecurrent induced resistance switching works.

Chien, T. Y.; Santos, T. S.; Bode, M.; Guisinger, N. P.; Freeland, J. W. (Center for Nanoscale Materials); ( XSD); (Univ. of Wurzburg)

2011-06-20T23:59:59.000Z

449

On the effect of deep-rolling and laser-peening on the stress-controlled low- and high-cycle fatigue behavior of Ti-6Al-4V at elevated temperatures up to 550?C  

E-Print Network [OSTI]

and near-?-titanium alloys, especially for fan bladebehavior of a titanium Ti-6Al-4V turbine fan blade alloy isfan blades and disks in aircraft jet propulsion engines are commonly made from titanium

Ritchie, IAltenberger, RKNalla, YSano LWagner, RO

2013-01-01T23:59:59.000Z

450

Small Au and Pt Clusters at the Anatase TiO2(101) Surface: Behavior at Terraces, Steps, and Surface Oxygen Vacancies  

E-Print Network [OSTI]

polymorph of titanium dioxide (TiO2). TiO2 is a versatile oxide material with important applications in many@ecust.edu.cn; diebold@tulane.edu Abstract: The adsorption properties of Au and Pt metal nanoclusters on TiO2 anatase edges. A preference for adsorption at type D-(112) steps is observed, which is probably a result

Diebold, Ulrike

451

Electric-field effect on phase transitions in Pb0.995La0.005[Zr0.9 ? y Sn0.1Ti y ]0.99875O3 and Pb0.9975[Zr0.895 ? y Sn0.1Ti y Nb0.005]O3 solid solutions  

Science Journals Connector (OSTI)

The phase diagrams of PbZrO3-PbTiO3-PbSnO3 solid solutions doped with $$ La_{Pb^{2 + } }^{3 + } $$ and ...

E. A. Bikyashev; E. A. Reshetnikova; I. V. Lisnevskaya…

2009-05-01T23:59:59.000Z

452

Fuel Cells Catalyst for Start-up and Shutdown Conditions: Electrochemical, XPS, and TEM Evaluation of Sputter-Deposited Ru, Ir, and Ti on Pt-Nano-Structured Thin Film (NSTF) Support  

SciTech Connect (OSTI)

Minute amounts of Ru, Ir and Ti (2 and 10 g/cm2) sputter-deposited over 3M Pt-coated nano-structured thin film (NSTF) substrate were evaluated as oxygen evolution reaction (OER) catalysts in a polymer electrolyte membrane (PEM) environment. The purpose of the study was to explore the suitability of these elements for modifying both the anode and the cathode catalysts in order to lower the overpotential for the oxidation of water during transient conditions. By keeping the electrode potential as close as possible to the thermodynamic potential for OER, other components in the fuel cell, such as platinum, the gas diffusion layer and the bipolar plates, will be less prone to degradation. While Ru and Ir were chosen due to their high OER activity in aqueous environment, Ti was also included due to its ability to stabilize the OER catalysts. The 3M Pt-NSTF was selected as a stable, carbon-free substrate. The surface chemistry and the morphology of OER catalysts on Pt-NSTF were examined by x-ray photoelectron spectroscopy (XPS) and scanning transmission electron microscopy (STEM). The OER catalytic activity of Ru and Ir in PEMs compares well with their behavior in aqueous environment. It was found that Ru is more active than Ir, that Ir is considerably more stable, while the mass activity of both is higher in comparison with similar OER catalyst.

Atanasoski, Radoslav [3M Industrial Mineral Products; Atanasoska, Liliana [3M Industrial Mineral Products; Cullen, David A [ORNL; Vernstrom, George [3M Industrial Mineral Products; More, Karren Leslie [ORNL; Haugen, Gregory [3M Industrial Mineral Products

2012-01-01T23:59:59.000Z

453

Direct real space observation of magneto-electronic inhomogeneity in ultra-thin film La{sub 0.5}Sr{sub 0.5}CoO{sub 3??} on SrTiO{sub 3}(001)  

SciTech Connect (OSTI)

Recent magnetotransport and neutron scattering measurements implicate interfacial magneto-electronic phase separation as the origin of the degradation in transport and magnetism in ultra-thin film La{sub 1?x}Sr{sub x}CoO{sub 3} on SrTiO{sub 3}(001). Here, using low temperature scanning tunneling microscopy and spectroscopy the first direct, real space observation of this nanoscopic electronic inhomogeneity is provided. Films of thickness 12.4?nm (32 unit cells) are found to exhibit spatially uniform conductance, in stark contrast to 4.7?nm (12 unit cell) films that display rich variations in conductance, and thus local density of states. The electronic heterogeneity occurs across a hierarchy of length scales (5–50?nm), with complex correlations with both topography and applied magnetic fields. These results thus provide a direct observation of magneto-electronic inhomogeneity in SrTiO{sub 3}(001)/La{sub 0.5}Sr{sub 0.5}CoO{sub 3} at thicknesses below 6–7?nm, in good agreement with less direct techniques.

Kelly, S.; Galli, F.; Aarts, J., E-mail: leighton@umn.edu, E-mail: aarts@physics.leidenuniv.nl [Department of Physics, Leiden University, 2300 RA Leiden (Netherlands); Bose, Shameek; Sharma, M.; Leighton, C., E-mail: leighton@umn.edu, E-mail: aarts@physics.leidenuniv.nl [Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

2014-09-15T23:59:59.000Z

454

Polarized neutron reflectometry study of the magnetization reversal process in YBa2Cu3O7/La2/3Ca1/3MnO3 superlattices grown on SrTiO3 substrates  

Science Journals Connector (OSTI)

Using polarized neutron reflectometry we investigated the reversal of the magnetization of a high-Tc superconductor/ferromagnet superlattice that consists of eight bilayers of YBa2Cu3O7(25.6?nm)/La2/3Ca1/3MnO3(25.6?nm) grown on a SrTiO3 substrate. The measurements were performed during a magnetization hysteresis loop at 5 K. We obtained evidence that the reversal in the vicinity of the coercive field proceeds via the switching of micrometer-sized magnetic domains that are considerably larger than the typical domains of La2/3Ca1/3MnO3. Furthermore, these large magnetic domains appear to be more strongly correlated along the vertical direction of the superlattice than along the lateral one. We provide evidence that this unusual behavior may be induced by the SrTiO3 substrate which undergoes a series of structural phase transitions, some of which give rise to the formation of micrometer-sized surface facets that are tilted with respect to each other. These facets and the resulting strain fields are transmitted throughout the superlattice and thus may act as templates for the large magnetic domains in the La2/3Ca1/3MnO3 layers whose magnetic properties are very susceptible to the lattice strain.

J. Hoppler; H. Fritzsche; V. K. Malik; J. Stahn; G. Cristiani; H.-U. Habermeier; M. Rössle; J. Honolka; A. Enders; C. Bernhard

2010-11-29T23:59:59.000Z

455

TiO{sub 2} nanotube-based field effect transistors and their application as humidity sensors  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Individual TiO{sub 2} nanotubes fabricated by directly anodizing a Ti foil followed by ultrasonification. Black-Right-Pointing-Pointer Individual TiO{sub 2} nanotubes used to construct field effect transistors. Black-Right-Pointing-Pointer Electrical properties measured from the TiO{sub 2} nanotube-based field effect transistors. Black-Right-Pointing-Pointer Sensitive response of the TiO{sub 2} nanotube-based field effect transistors to water vapor. -- Abstract: TiO{sub 2} nanotubes are the building units of various devices of energy- and environment-related applications and the property studies of individual TiO{sub 2} nanotubes are important to understand and improve the performance of TiO{sub 2} nanotubes-based devices. Here we report the electrical property study of individual TiO{sub 2} nanotubes enabled by the construction of field effect transistors based on individual TiO{sub 2} nanotubes. It is found that individual TiO{sub 2} nanotubes exhibit typical n-type electrical conduction characteristics, with electron mobility of 6.9 Multiplication-Sign 10{sup -3} cm{sup 2}/V s at V{sub ds} = 1 V, and electron concentration of 2.8 Multiplication-Sign 10{sup 17} cm{sup -3}. Moreover, the on-off ratio of the TiO{sub 2} nanotube-based field effect transistors is as high as 10{sup 3}. Humidity sensing test shows the sensitive response of the individual TiO{sub 2} nanotubes to water vapor.

Liang, Fengxia [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong Special Administrative Region (Hong Kong)] [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong Special Administrative Region (Hong Kong); Luo, Lin-Bao [School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui (China)] [School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui (China); Tsang, Chun-Kwan; Zheng, Lingxia; Cheng, Hua [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong Special Administrative Region (Hong Kong)] [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong Special Administrative Region (Hong Kong); Li, Yang Yang, E-mail: yangli@cityu.edu.hk [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong Special Administrative Region (Hong Kong)

2012-01-15T23:59:59.000Z

456

Textures and plastic anisotropy in gamma-TiAl  

SciTech Connect (OSTI)

Specimens of a Ti-36 wt pct Al alloy consisting primarily of gamma TiAl were deformed in compression at 450 C and in rolling at 1050 C. The textures of the deformed specimens were measured and analyzed in terms of orientation distribution functions. After hot rolling, the texture is strongly influenced by recrystallization and shows a cube-like component with an alignment of the c-axis with the transverse direction. The measured compression textures are compared with those simulated on the basis of the Taylor theory of polycrystal deformation. 36 refs.

Hartig, C.H.; Fang, X.F.; Mecking, H.; Dahms, M. (Hamburg, Technische Universitaet, (Germany) GKSS-Forschungszentrum Geesthacht GmbH, (Germany))

1992-08-01T23:59:59.000Z

457

Hydrogenated TiO{sub 2} film for enhancing photovoltaic properties of solar cells and self-sensitized effect  

SciTech Connect (OSTI)

Hydrogenated TiO{sub 2} film was obtained by annealing TiO{sub 2} film at 350?°C for 2?h with hydrogen, and TiO{sub 2} films were prepared by screen printing on fluorine-doped tin oxide glass. Structural characterization by X-ray diffraction and electron microscopy did not show obvious difference between hydrogenated TiO{sub 2} film and pristine TiO{sub 2} film. Through optical and electrochemical characterization, the hydrogenated TiO{sub 2} film showed enhanced absorption and narrowed band gap, as well as reduced TiO{sub 2} surface impedance and dark current. As a result, an obviously enhanced photovoltaic effect was observed in the solar cell with hydrogenated TiO{sub 2} as photoanode without adding any dye due to the self-sensitized effect of hydrogenated TiO{sub 2} film, which excited electrons injecting internal conduction band of TiO{sub 2} to generate more photocurrent.

He, Hongcai; Yang, Kui; Wang, Ning, E-mail: ning-wang@uestc.edu.cn; Luo, Feifei; Chen, Haijun [State Key Laboratory of Electronic Thin Films and Integrated Devices and School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China)

2013-12-07T23:59:59.000Z

458

Mixed cation phases in sputter deposited HfO{sub 2}-TiO{sub 2} nanolaminates  

SciTech Connect (OSTI)

Nanolaminate HfO{sub 2}-TiO{sub 2} films are grown by reactive sputter deposition on unheated fused SiO{sub 2}, sequentially annealed at 573 to 973 K, and studied by x-ray diffraction. A nanocrystalline structure of orthorhombic (o) HfTiO{sub 4} adjacent to an interface followed by monoclinic (m) Hf{sub 1-x}Ti{sub x}O{sub 2} is identified. m-Hf{sub 1-x}Ti{sub x}O{sub 2}, a metastable phase, is isomorphous with m-HfO{sub 2} and a high pressure phase, m-HfTiO{sub 4}. A Vegard's law analysis shows that the Ti atomic fraction in m-Hf{sub 1-x}Ti{sub x}O{sub 2} is much greater than Ti equilibrium solubility in m-HfO{sub 2}. A space group-subgroup argument proposes that m-Hf{sub 1-x}Ti{sub x}O{sub 2} arises from an o/m-HfTiO{sub 4} second order phase transition to accommodate the larger Hf atom.

Cisneros-Morales, M. C.; Aita, C. R. [Advanced Coatings Experimental Laboratory, College of Engineering and Applied Science, University of Wisconsin-Milwaukee, P.O. Box 784, Milwaukee, Wisconsin 53201 (United States)

2008-07-14T23:59:59.000Z

459

Observation of TiH5 and TiH7 in Bulk-Phase TiH3 Gels for Kubas-Type Hydrogen Storage  

Science Journals Connector (OSTI)

Observation of TiH5 and TiH7 in Bulk-Phase TiH3 Gels for Kubas-Type Hydrogen Storage ... Table T2 provides the formulas and C, H, and Ti percentages of the hydrogenated materials in addition to those of representative stoichiometric compounds, including pure TiH3 and the starting material. ... In the TiH3 structure, the hydride ligands are a lightweight structural feature as opposed to a source of stored hydrogen, and additional hydrogen can bind via the Kubas interaction to access TiH5 and TiH7 species. ...

Tuan K. A. Hoang; Leah Morris; Daniel Reed; David Book; Michel L. Trudeau; David M. Antonelli

2013-11-14T23:59:59.000Z

460

Index of /academic/files/courses/past/2003fall/ma265/MatLab  

E-Print Network [OSTI]

Index of /academic/files/courses/past/2003fall/ma265/MatLab. [ICO], Name · Last modified · Size · Description. [DIR], Parent Directory, -. [TXT], dotprod.

Note: This page contains sample records for the topic "ti ons ma" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus...  

Open Energy Info (EERE)

Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search OpenEI Reference...

462

E-Print Network 3.0 - alcon laboratories ma60 Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sample search results for: alcon laboratories ma60 Page: << < 1 2 3 4 5 > >> 1 Chemical Engineering Research Support 2007 Abitibi-Consolidated Inc. Summary: Agriculture &...

463

Model for Analysis of Energy Demand (MAED-2) | Open Energy Information  

Open Energy Info (EERE)

Analysis of Energy Demand (MAED-2) AgencyCompany Organization: International Atomic Energy Agency Sector: Energy Focus Area: Renewable Energy, Energy Efficiency Topics: Pathways...

464

MA511: PRACTICE TEST 2 Answer all questions. No calculators or ...  

E-Print Network [OSTI]

MA511: PRACTICE TEST 2. Answer all questions. No calculators or other electronic devices are allowed. For questions 1 to 3, you may write down the answers ...

2014-11-02T23:59:59.000Z

465

Deformation of depleted uranium ? 0.78 Ti under shock compression to 11.0 GPa at room temperature  

Science Journals Connector (OSTI)

The present work on depleted uranium alloyed with 0.78% titanium by weight (i.e. U?0.8 Ti) describes the nature of deformation it undergoes when subjected to shock compression at room temperature. The principal results emerging out of the present work are: (1) The stress limits of elastic deformation are dependent on the thickness of U?0.8Ti. The stress limit decreases from over 3.0 GPa at the impact surface to 1.2 GPa at a depth of 9 mm in U?0.8 Ti; (2) The lower limit of the stress agrees with the static yield stress in U?0.8 Ti; (3) Above the elastic stress limit the deformation of U?0.8 Ti proceeds in a manner of the ideal plastic solid; and (4) The pressure derivative of Lame’s parameter of U?0.8 Ti is estimated to be 3.8.

Dattatraya P. Dandekar; Anthony G. Martin; John V. Kelley

1980-01-01T23:59:59.000Z

466

The relationship between structural evolution and electrical percolation of the initial stages of tungsten chemical vapor deposition on polycrystalline TiN  

SciTech Connect (OSTI)

This paper presents experimental results and a geometric model of the evolution of sheet resistance and surface morphology during the transition from nucleation to percolation of tungsten chemical vapor deposition over ultrathin polycrystalline titanium nitride (TiN). We observed two mechanisms of reduction in sheet resistance. At deposition temperatures higher than 310 deg. C, percolation effect is formed at {approx}35% of surface coverage, {theta}, and characterized with a sharp drop in resistance. At temperature below 310 deg. C, a reduction in resistance occurs in two steps. The first step occurs when {theta} = 35% and the second step at {theta} = 85%. We suggest a geometric model in which the electrical percolation pass is modulated by the thickness threshold of the islands at the instant of collision.

Rozenblat, A. [Micron Semiconductors Israel Ltd., Qiryat-Gat 82109 (Israel); Department of Physical Electronics, Electrical Engineering, Tel Aviv University, Tel Aviv 69978 (Israel); Haimson, S. [Material Science Program, Tel Aviv University, Tel Aviv 69978 (Israel); Shacham-Diamand, Y. [Department of Physical Electronics, Electrical Engineering, Tel Aviv University, Tel Aviv 69978 (Israel); Horvitz, D. [Micron Semiconductors Israel Ltd., Qiryat-Gat 82109 (Israel)

2012-01-16T23:59:59.000Z

467

Untilting BiFeO{sub 3}: The influence of substrate boundary conditions in ultra-thin BiFeO{sub 3} on SrTiO{sub 3}  

SciTech Connect (OSTI)

We report on the role of oxygen octahedral tilting in the monoclinic-to-tetragonal phase transition in ultra-thin BiFeO{sub 3} films grown on (001) SrTiO{sub 3} substrates. Reciprocal space maps clearly show the disappearance of the integer-order Bragg peak splitting associated with the monoclinic phase when the film thickness decreases below 20 unit cells. This monoclinic-to-tetragonal transition is accompanied by the evolution of the half-order diffraction peaks, which reflects untilting of the oxygen octahedra around the [110] axis, proving that the octahedral tilting is closely correlated with the transition. This structural change is thickness-dependent, and different from a strain-induced transition in the conventional sense.

Yang, Yongsoo, E-mail: ysyang@umich.edu; Clarke, Roy [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States); Schlepütz, Christian M. [X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Adamo, Carolina [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Department of Applied Physics, Stanford University, Stanford, California 94305 (United States); Schlom, Darrell G. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Cornell University, Ithaca, New York 14853 (United States)

2013-11-01T23:59:59.000Z

468

Development of a Hydronic Rooftop Unit-HyPak-MA  

SciTech Connect (OSTI)

The majority of U.S. commercial floor space is cooled by rooftop HVAC units (RTUs). RTU popularity derives chiefly from their low initial cost and relative ease of service access without disturbing building occupants. Unfortunately, current RTUs are inherently inefficient due to a combination of characteristics that unnecessarily increase cooling loads and energy use. 36% percent of annual U.S. energy, and two-thirds of electricity, is consumed in and by buildings. Commercial buildings consume approximately 4.2 quads of energy each year at a cost of $230 billion per year, with HVAC equipment consuming 1.2 quads of electricity. More than half of all U.S. commercial floor space is cooled by packaged HVAC units, most of which are rooftop units (RTUs). Inefficient RTUs create an estimated 3.5% of U.S. CO{sub 2} emissions, thus contributing significantly to global warming5. Also, RTUs often fail to maintain adequate ventilation air and air filtration, reducing indoor air quality. This is the second HyPak project to be supported by DOE through NETL. The prior project, referred to as HyPak-1 in this report, had two rounds of prototype fabrication and testing as well as computer modeling and market research. The HyPak-1 prototypes demonstrated the high performance capabilities of the HyPak concept, but made it clear that further development was required to reduce heat exchanger cost and improve system reliability before HyPak commercialization can commence. The HyPak-1 prototypes were limited to about 25% ventilation air fraction, limiting performance and marketability. The current project is intended to develop a 'mixed-air' product that is capable of full 0-100% modulation in ventilation air fraction, hence it was referred to as HyPak-MA in the proposal. (For simplicity, the -MA has been dropped when referencing the current project.) The objective of the HyPak Project is to design, develop and test a hydronic RTU that provides a quantum improvement over conventional RTU performance. Our proposal targeted 60% and 50% reduction in electrical energy use by the HyPak RTU for dry and humid climates, respectively, when compared with a conventional unit, and reduction in peak energy consumption of 50% and 33% respectively. In addition to performance targets, our goal is to develop a production-ready design with durability, reliability and maintainability similar to air-cooled packaged equipment, and that can be commercialized immediately following the conclusion of this project.

Eric Lee; Mark Berman

2009-11-14T23:59:59.000Z

469

Developing TiAIN Coatings for Intermediate Temperature-Solid Oxide Fuel Cell Interconnect Applications  

SciTech Connect (OSTI)

TiN-type coatings have potential to be used as SOFC interconnect coatings SOFC because of their low resistance and high temperature stability. In this research, various (Ti,Al)N coatings were deposited on stainless steels by filtered-arc method. ASR and XRD tests were conducted on these coatings, and SEM/EDAX analysis were conducted after ASR and XRD tests. SEM/EDAX analyses show that (Ti,Al)N remains stable at temperature up to 700°C. It is also indicated that Al has beneficial effect on the stability of TiN type coatings. At 900°C, (Ti-30Al)N is fully oxidized and some of (Ti-50Al)N coating still remains as nitride. The analyses on cross-sectional samples show that these coatings are effective barrier to the Cr migration. In summary, (Ti.Al)N coatings are good candidates for the SOFC interconnect applications at 700°C. The future directions of this research are to improve the stability of these coatings by alloy-doping and to develop multi-layer coatings.

Liu, X. (West Virginia University); Johnson, C.D.; Li, C. (West Virginia University); Xu, J. (West Virginia University); Cross, C.

2007-02-01T23:59:59.000Z

470

Optical properties of hierarchical-nanostructured TiO{sub 2} and its time-dependent photo-degradation of gaseous acetaldehyde  

SciTech Connect (OSTI)

The TiO{sub 2} hierarchical nanostructures (HNs) composed of rutile TiO{sub 2} nanowires on anatase TiO{sub 2} nanofibers had higher photocatalytic activities of 62% and 48% than the commercial TiO{sub 2} nanoparticles (?21 nm diameter) in the continuous flow mode and closed-circulation mode, respectively, leading to an efficient degradation of gaseous acetaldehyde under UV-light irradiation. This behavior may be attributed to the effective TiO{sub 2} HNs with specific surface area of 85.1 m{sup 2}/g and lower radiative recombination of self-trapped excitons, enabling an effective electron-hole separation.

Ahn, Kyun; Jeong, Se-Young; Cho, Chae-Ryong [College of Nanoscience and Nanotechnology, Pusan National University, Busan 609-735 (Korea, Republic of)] [College of Nanoscience and Nanotechnology, Pusan National University, Busan 609-735 (Korea, Republic of); Kim, Min-Sun; Kim, Soon-Hyun; Hyun Kim, Jae [Division of Nano and Bio Technology, Daegu Gyeongbuk Institute of Science and Technology, Daegu 711-873 (Korea, Republic of)] [Division of Nano and Bio Technology, Daegu Gyeongbuk Institute of Science and Technology, Daegu 711-873 (Korea, Republic of); Kim, Jong-Pil; Sung Jin, Jong [Division of High Technology Materials Research, Korea Basic Science Institute, Busan 618-230 (Korea, Republic of)] [Division of High Technology Materials Research, Korea Basic Science Institute, Busan 618-230 (Korea, Republic of)

2013-12-23T23:59:59.000Z

471

U.S. DEPARTMENT OF ENERGY EERE PROJECT MA;"AGEMENT CENTER NEPA DET1!R1.IINATION  

Broader source: Energy.gov (indexed) [DOE]

O". )' O". )' U.S. DEPARTMENT OF ENERGY EERE PROJECT MA;"AGEMENT CENTER NEPA DET1!R1.IINATION RECIPIENT:Resolute Marine Energy, Inc. PROJECT TITLE: Wave-Actuated Power Take Off Device for Electricity Generation Page 1 of2 STATE: MA Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number em Number DE-FOA-OOOO293 DE-EEOOO4565 GFO-OOO4565-001 0 Based on my review orthe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Ordtr451.IA), I have made tbe rollowing determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering (including , but not limited to, literature surveys, inventories, audits), data analysis (including computer modeling), document preparation (such as conceptual design or feasibility studies, analytical energy supply

472

The effect of interface oxygen content on magnetoelectric effect of epitaxial La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/BaTiO{sub 3} bilayer  

SciTech Connect (OSTI)

The epitaxial La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/BaTiO{sub 3} (LSMO/BTO) bilayer films are grown on (001) oriented LaAlO{sub 3} substrate by pulsed laser deposition technique. The oxygen-rich interface is obtained through in-situ annealing process in oxygen, and the oxygen-deficient interface is obtained without the annealing process. The results show that the ferromagnetic properties of the LSMO film and the magnetoelectric effect (ME) of the bilayer films strongly correlate to the oxygen content at the interface of LSMO/BTO. The saturated magnetization and the ME voltage coefficient of the oxygen-rich bilayer film are higher than that of oxygen-deficient one. It suggests a more effective ME coupling at the LSMO/BTO interface, which are generated through not only the interface strain but also the spin polarized carriers.

Tingxian, Li, E-mail: wxlltx@126.com [College of Physics and Electrical Engineering, Anyang Normal University, Anyang 455002 (China); Kuoshe, Li [National Engineering Research Central for Rare Earth Materials, General Research Institute for Nonferrous Metals, The Grirem Advanced materials Co. Ltd., Beijing 100088 (China)

2014-01-28T23:59:59.000Z

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Inverse Tunnel Magnetoresistance in Co/SrTiO3/La0.7Sr0.3MnO3: New Ideas on Spin-Polarized Tunneling  

Science Journals Connector (OSTI)

We report tunnel magnetoresistance (TMR) measurements on Co/SrTiO3/La0.7Sr0.3MnO3 junctions. The half-metallic La0.7Sr0.3MnO3 electrode is used as a spin analyzer. The large (-50%) inverse TMR indicates a negative spin polarization of Co, in agreement with the density of states (DOS) of the d band in Co. The bias dependence of the TMR, with a maximum inverse TMR at -0.4 V and a crossover to normal TMR above +0.8 V, reflects the structure of this DOS. Our results demonstrate that the choice of the insulating barrier can strongly influence and even reverse the spin polarization of tunneling electrons.

J. M. De Teresa, A. Barthélémy, A. Fert, J. P. Contour, R. Lyonnet, F. Montaigne, P. Seneor, and A. Vaurès

1999-05-24T23:59:59.000Z

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The pottery from a fifth century B.C. shipwreck at Ma'agan Michael, Israel  

E-Print Network [OSTI]

Between 1988 and 1990 a shipwreck tentatively dated to the 5th century B.C. was excavated off the coast of Israel at Ma'agan Michael by Dr. Elisha Linder of the Center for Maritime Studies. This study presents one category of material from the Ma...

Lyon, Jerry Dean

2012-06-07T23:59:59.000Z

476

MaJIC: a Matlab Just-In-time Compiler ? George Almasi and David A. Padua  

E-Print Network [OSTI]

MaJIC: a Matlab Just-In-time Compiler ? George Almasi and David A. Padua galmasi experience with MaJIC, a just-in- time compiler for MATLAB. In the recent past, several compiler projects claimed large performance improvements when processing MATLAB code. Most of these projects are static

Padua, David

477

M.A. in Political Science Degree Requirements Department of Political Science, Florida Atlantic University  

E-Print Network [OSTI]

M.A. in Political Science Degree Requirements Department of Political Science, Florida Atlantic University Students pursuing a Master of Arts Degree in Political Science are required to meet the following as an undergraduate. 4. Students entering the M.A. program who did not major in political science as undergraduates

Fernandez, Eduardo

478

Photo 2008 Michigan State University Board of Trustees M.A. Advertising  

E-Print Network [OSTI]

Photo © 2008 Michigan State University Board of Trustees M.A. Advertising M.A. Public Relations GRADUATE HANDBOOK Department of Advertising + Public Relations MICHIGAN STATE UNIVERSITY #12;2 Revised July 2013 Table of Contents Program overview, 3 Two degrees: Advertising or PR, 3 Program structure, 4

479

Novel Au-TiC Catalysts for CO Oxidation and Desulfurization Processes  

SciTech Connect (OSTI)

Recent articles dealing with the physical and chemical properties of novel Au-TiC catalysts are reviewed. High-resolution photoemission, scanning tunneling microscopy and first-principles periodic density-functional calculations were used to study the deposition of gold on a TiC(0 0 1) surface. Gold grows forming two-dimensional (very low coverage) and three-dimensional (medium and large coverage) islands on the carbide substrate. A positive shift in the binding energy of the C 1s core level is observed after the deposition of Au on TiC(0 0 1). The results of the density-functional calculations corroborate the formation of Au-C bonds. In general, the bond between Au and the TiC(0 0 1) surface exhibits very little ionic character, but there is a substantial polarization of electrons around Au that facilitates bonding of the adatoms with electron-acceptor molecules (CO, O{sub 2}, C{sub 2}H{sub 4}, SO{sub 2}, thiophene, etc.). Experimental measurements indicate that Au/TiC(0 0 1) is a very good catalysts for the oxidation of CO, the destruction of SO{sub 2} and the hydrodesulfurization of thiophene. At temperatures below 200 K, Au/TiC(0 0 1) is able to perform the 2CO + O{sub 2} {yields} 2CO{sub 2} reaction and the full decomposition of SO{sub 2}. Furthermore, in spite of the very poor hydrodesulfurization performance of TiC(0 0 1) or Au(1 1 1), a Au/TiC(0 0 1) surface displays a hydrodesulfurization activity higher than that of conventional Ni/MoS{sub x} catalysts. Metal carbides are excellent supports for enhancing the chemical reactivity of gold. The Au/TiC system is more chemically active than systems generated by depositing Au nanoparticles on oxide surfaces.

J Rodriguez; P Liu; Y Takahashi; F Vines; L Feria; E Florez; K Nakamura

2011-12-31T23:59:59.000Z

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Market Acceptance of Advanced Automotive Technologies Model (MA3T) Consumer  

Open Energy Info (EERE)

Market Acceptance of Advanced Automotive Technologies Model (MA3T) Consumer Market Acceptance of Advanced Automotive Technologies Model (MA3T) Consumer Choice Model Jump to: navigation, search Tool Summary Name: Market Acceptance of Advanced Automotive Technologies Model (MA3T) Consumer Choice Model Agency/Company /Organization: Oak Ridge National Laboratory OpenEI Keyword(s): EERE tool, Market Acceptance of Advanced Automotive Technologies Model (MA3T) Consumer Choice Model, MA3T Project U.S. consumer demand for plug-in hybrid electric vehicles (PHEV) in competition among various light-duty vehicle technologies for hundreds of market segments based and multiple regions. For more information, contact the ORNL Energy and Transportation Science Division at http://www.ornl.gov/sci/ees/etsd/contactus.shtml References Retrieved from

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