National Library of Energy BETA

Sample records for ti ng opera

  1. Philosophy\tof\tNetwork\tOpera3ng Systems\tand\tIntent\tAPIs Inder...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and development * Scrip3ng interface, Python programming model * Focus on Intent APIs as ... Policy as a Service, uses SQL Policy Language, Interfaces to OpenStack modules * ...

  2. Blue Ng | Open Energy Information

    Open Energy Info (EERE)

    Ng Jump to: navigation, search Name: Blue-Ng Place: Bath, United Kingdom Zip: BA1 1SR Sector: Biomass Product: UK-based company that constructs and operates combined heat and...

  3. PVT-NG sensor final report.

    SciTech Connect (OSTI)

    Mitchell, Dean James; Brusseau, Charles A.

    2012-01-01

    This document is a final report for the polyvinyl toluene (PVT) neutron-gamma (PVT-NG) project, which was sponsored by the Domestic Nuclear Detection Office (DNDO). The PVT-NG sensor uses PVT detectors for both gamma and neutron detection. The sensor exhibits excellent spectral resolution and gain stabilization, which are features that are beneficial for detection of both gamma-ray and neutron sources. In fact, the ability to perform isotope identification based on spectra that were measured by the PVT-NG sensor was demonstrated. As described in a previous report, the neutron sensitivity of the first version of the prototype was about 25% less than the DNDO requirement of 2.5 cps/ng for bare Cf-252. This document describes design modifications that were expected to improve the neutron sensitivity by about 50% relative to the PVT-NG prototype. However, the project was terminated before execution of the design modifications after portal vendors demonstrated other technologies that enable neutron detection without the use of He-3. Nevertheless, the PVT-NG sensor development demonstrated several performance goals that may be useful in future portal designs.

  4. Test Report for NG Sensors GTX-1000.

    SciTech Connect (OSTI)

    Manginell, Ronald P.

    2015-02-01

    This report describes initial testing of the NG Sensor GTX-1000 natural gas monitoring system. This testing showed that the retention time, peak area stability and heating value repeatability of the GTX-1000 were promising for natural gas measurements in the field or at the well head. The repeatability can be less than 0.25% for LHV and HHV for the Airgas standard tested in this report, which is very promising for a first generation prototype. Ultimately this system should be capable of 0.1% repeatability in heating value at significant size and power reductions compared with competing systems.

  5. Testing the OPERA Superluminal Neutrino Anomaly at the LHC

    SciTech Connect (OSTI)

    Davoudiasl, Hooman; Rizzo, Thomas G.; /SLAC

    2012-03-15

    The OPERA collaboration has reported the observation of superluminal muon neutrinos, whose speed v{sub {nu}} exceeds that of light c, with (v{sub {nu}}-c)/c {approx_equal} 2.5 x 10{sup -5}. In a recent work, Cohen and Glashow (CG) have refuted this claim by noting that such neutrinos will lose energy, by pair-emission of particles, at unacceptable rates. Following the CG arguments, we point out that pair-emissions consistent with the OPERA anomaly can lead to detectable signals for neutrinos originating from decays of highly boosted top quarks at the LHC, allowing an independent test of the superluminal neutrino hypothesis.

  6. Detec%ng the Onset of Drizzle Using ARM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detec%ng the Onset of Drizzle Using ARM Observa%ons and a Steady-State 1-D Column Model PAVLOS KOLLIAS HAIYANG YU ANDREW LESAGE JINGJING TIAN ANDREW DZAMBO MIKAEL WITTE Outline * Mo%va%ons * Methods * Modeling the onset of drizzle * Observa%ons of drizzle onset * "Synergy" of Results * Conclusions Low, Drizzling Clouds * Near-surface radia%ve proper%es (e.g. scaWering, absorp%on, cloud "morphology"). * Drizzle affects aerosols' in/direct radia%ve effects. * Classic

  7. NEW ENGLAND NG SUPPLY LIMITED- FE Dkt. 16-103-NG- FOR LONG TERM AUTHORIZATION TO EXPORT NATURAL GAS TO CANADA

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy gives notice of receipt of an Application filed August 3, 2016 by New England NG Supply Limited (New England), requesting long-term authorization to export natural gas...

  8. FPDS-NG Change Management Notice for the Oklahoma Tornado and Storm

    Broader source: Energy.gov [DOE]

    A new National Interest Action value for the 'Oklahoma Tornado and Storm 2013' has been added to the FPDS-NG Production system.

  9. Next Generation * Natural Gas (NG)2 Information Requirements--Executive Summary

    Reports and Publications (EIA)

    2000-01-01

    The Energy Information Administration (EIA) has initiated the Next Generation * Natural Gas (NG)2 project to design and implement a new and comprehensive information program for natural gas to meet customer requirements in the post-2000 time frame.

  10. DOE/AMO NG Infrastructure R & D & Methane emissions Mitigation workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proprietary and Confidential to NYSEARCH/NGA DOE/AMO NG INFRASTRUCTURE R & D & METHANE EMISSIONS MITIGATION WORKSHOP November 2014 David Merte & Daphne D'Zurko, NYSEARCH/NGA dmerte@northeastgas.org ddzurko@northeastgas.org NYSEARCH 2 NYSEARCH Program Research Areas * Improved Installation, Maintenance & Repair * Pipeline Integrity/Direct & Remote Assessment * Pipe Location * Leak Detection * Real-time Sensing and Inspection for Distribution * Environment/Reducing Greenhouse

  11. A=17C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (See the Isobar Diagram for 17C) The atomic mass excess given by (1988WA18) for 17C is 21035 ± 17 keV. See also (1986AN07). 17C is then stable with respect to 16C + n by 0.73 MeV. Eβ- (max) to 17Ng.s. = 13.16 MeV. See also (1986BI1A). The half-life of 17C has been measured to be 202 ± 17 msec (1986CU01), 220 ± 80 msec (1986DU07), 180 ± 31 msec (1988SA04), and 174 ± 31 msec (1991RE02). Relative intensities of β-delayed gammas were measured by (1986DU07, 1986HU1A, 1986JEZY) [see

  12. Matrix effect on vibrational frequencies: Experiments and simulations for HCl and HNgCl (Ng = Kr and Xe)

    SciTech Connect (OSTI)

    Kalinowski, Jaroslaw; Rsnen, Markku; Lignell, Antti; Khriachtchev, Leonid; Gerber, R. Benny; Department of Physical Chemistry, Hebrew University, Jerusalem 91904, Israel and Department of Chemistry, University of California, Irvine, California 92697

    2014-03-07

    We study the environmental effect on molecules embedded in noble-gas (Ng) matrices. The experimental data on HXeCl and HKrCl in Ng matrices is enriched. As a result, the H?Xe stretching bands of HXeCl are now known in four Ng matrices (Ne, Ar, Kr, and Xe), and HKrCl is now known in Ar and Kr matrices. The order of the H?Xe stretching frequencies of HXeCl in different matrices is ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constant, in contrast to the classical order observed for HCl: ?(Xe) < ?(Kr) < ?(Ar) < ?(Ne). The order of the H?Kr stretching frequencies of HKrCl is consistently ?(Kr) < ?(Ar). These matrix effects are analyzed theoretically by using a number of quantum chemical methods. The calculations on these molecules (HCl, HXeCl, and HKrCl) embedded in single Ng{sup ?} layer cages lead to very satisfactory results with respect to the relative matrix shifts in the case of the MP4(SDQ) method whereas the B3LYP-D and MP2 methods fail to fully reproduce these experimental results. The obtained order of frequencies is discussed in terms of the size available for the Ng hydrides in the cages, probably leading to different stresses on the embedded molecule. Taking into account vibrational anharmonicity produces a good agreement of the MP4(SDQ) frequencies of HCl and HXeCl with the experimental values in different matrices. This work also highlights a number of open questions in the field.

  13. A=16Al (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not observed) See (1986AN07

  14. A=16Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not observed) See (1986AN07

  15. A=16Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not observed) See (1986AN07

  16. A=16Si (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not observed) See (1986AN07

  17. A=19Be (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not observed) See (1983ANZQ

  18. A=19He (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not observed) See (1983ANZQ

  19. A=19Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not observed) See (1983ANZQ

  20. Waterless TiO{sub 2} atomic layer deposition using titanium tetrachloride and titanium tetraisopropoxide

    SciTech Connect (OSTI)

    Anderson, Virginia R.; Cavanagh, Andrew S.; Abdulagatov, Aziz I.; Gibbs, Zachary M.; George, Steven M.

    2014-01-15

    The surface chemistry for TiO{sub 2} atomic layer deposition (ALD) typically utilizes water or other oxidants that can oxidize underlying substrates such as magnetic disks or semiconductors. To avoid this oxidation, waterless or oxidant-free surface chemistry can be used that involves titanium halides and titanium alkoxides. In this study, waterless TiO{sub 2} ALD was accomplished using titanium tetrachloride (TiCl{sub 4}) and titanium tetraisopropoxide (TTIP). In situ transmission Fourier transform infrared (FTIR) studies were employed to study the surface species and the reactions during waterless TiO{sub 2} ALD. At low temperatures between 125 and 225  °C, the FTIR absorbance spectra revealed that the isopropoxide species remained on the surface after TTIP exposures. The TiCl{sub 4} exposures then removed the isopropoxide species and deposited additional titanium species. At high temperatures between 250 and 300  °C, the isopropoxide species were converted to hydroxyl species by β-hydride elimination. The observation of propene gaseous reaction product by quadrupole mass spectrometry (QMS) confirmed the β-hydride elimination reaction pathway. The TiCl{sub 4} exposures then easily reacted with the hydroxyl species. QMS studies also observed the 2-chloropropane and HCl gaseous reaction products and monitored the self-limiting nature of the TTIP reaction. Additional studies examined the waterless TiO{sub 2} ALD growth at low and high temperature. Quartz crystal microbalance measurements observed growth rates of ∼3 ng/cm{sup 2} at a low temperature of 150  °C. Much higher growth rates of ∼15 ng/cm{sup 2} were measured at a higher temperature of 250  °C under similar reaction conditions. X-ray reflectivity analysis measured a growth rate of 0.55 ± 0.05 Å/cycle at 250  °C. X-ray photoelectron depth-profile studies showed that the TiO{sub 2} films contained low Cl concentrations <1 at. %. This waterless TiO{sub 2} ALD process

  1. Structure of Naegleria Tet-like dioxygenase (NgTet1) in complexes with a reaction intermediate 5-hydroxymethylcytosine DNA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hashimoto, Hideharu; Pais, June E.; Dai, Nan; Corrêa, Jr., Ivan R.; Zhang, Xing; Zheng, Yu; Cheng, Xiaodong

    2015-08-31

    The family of ten-eleven translocation (Tet) dioxygenases is widely distributed across the eukaryotic tree of life, from mammals to the amoeboflagellate Naegleria gruberi. Like mammalian Tet proteins, the Naegleria Tet-like protein, NgTet1, acts on 5-methylcytosine (5mC) and generates 5-hydroxymethylcytosine (5hmC), 5-formylcytosine (5fC) and 5-carboxylcytosine (5caC) in three consecutive, Fe(II)- and α-ketoglutarate-dependent oxidation reactions. The two intermediates, 5hmC and 5fC, could be considered either as the reaction product of the previous enzymatic cycle or the substrate for the next cycle. Here we present a new crystal structure of NgTet1 in complex with DNA containing a 5hmC. Along with the previously solvedmore » NgTet1–5mC structure, the two complexes offer a detailed picture of the active site at individual stages of the reaction cycle. In the crystal, the hydroxymethyl (OH-CH2-) moiety of 5hmC points to the metal center, representing the reaction product of 5mC hydroxylation. The hydroxyl oxygen atom could be rotated away from the metal center, to a hydrophobic pocket formed by Ala212, Val293 and Phe295. Such rotation turns the hydroxyl oxygen atom away from the product conformation, and exposes the target CH2 towards the metal-ligand water molecule, where a dioxygen O2 molecule would occupy to initiate the next round of reaction by abstracting a hydrogen atom from the substrate. The Ala212-to-Val (A212V) mutant profoundly limits the product to 5hmC, probably due to the reduced hydrophobic pocket size restricts the binding of 5hmC as a substrate.« less

  2. N,N'-DICYCLOHEXYL-N"-ISOTRIDECYLGUANIDINE AS SUPPRESSOR FOR THE NEXT GENERATION CAUSTIC SIDE SOLVENT EXTRACTION (NG-CSSX) PROCESS

    SciTech Connect (OSTI)

    Duncan, Nathan C; Roach, Benjamin D; Williams, Neil J; Bonnesen, Peter V; Rajbanshi, Arbin; Moyer, Bruce A

    2012-01-01

    ABSTRACT The purity, concentration, and source of the N,N'-dicyclohexyl-N"-isotridecylguanidine (DCiTG) suppressor (guanidine) used in the NG-CSSX process were found to influence solvent performance. As the starting isotridecanol used in the preparation of DCiTG is comprised of a mixture of branched-chain aliphatic alcohols, varying in composition with manufacturer, the resulting DCiTG itself is a mixture. Thus, it is necessary to address how the solvent performance will be affected by the different preparations of the DCiTG solvent component. In this study, four preparations of DCiTG from three sources were analyzed and evaluated for purity and performance, both in the absence and presence of an anionic surfactant impurity.

  3. Theoretical investigation of HNgNH{sub 3}{sup +} ions (Ng = He, Ne, Ar, Kr, and Xe)

    SciTech Connect (OSTI)

    Gao, Kunqi; Sheng, Li

    2015-04-14

    The equilibrium geometries, harmonic frequencies, and dissociation energies of HNgNH{sub 3}{sup +} ions (Ng = He, Ne, Ar, Kr, and Xe) were investigated using the following method: Becke-3-parameter-Lee-Yang-Parr (B3LYP), Boese-Matrin for Kinetics (BMK), second-order Mller-Plesset perturbation theory (MP2), and coupled-cluster with single and double excitations as well as perturbative inclusion of triples (CCSD(T)). The results indicate that HHeNH{sub 3}{sup +}, HArNH{sub 3}{sup +}, HKrNH{sub 3}{sup +}, and HXeNH{sub 3}{sup +} ions are metastable species that are protected from decomposition by high energy barriers, whereas the HNeNH{sub 3}{sup +} ion is unstable because of its relatively small energy barrier for decomposition. The bonding nature of noble-gas atoms in HNgNH{sub 3}{sup +} was also analyzed using the atoms in molecules approach, natural energy decomposition analysis, and natural bond orbital analysis.

  4. A=10F (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (Not illustrated) Not observed: see (1979AJ01). See also (1988AJ01

  5. A=10Ne (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (Not illustrated) Not observed: see (1979AJ01). See also (1988AJ01

  6. A=10O (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (Not illustrated) Not observed: see (1979AJ01). See also (1988AJ01

  7. A=17Al (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Al (1993TI07) (Not observed) See (1983ANZQ, 1988WA18, 1992AV03).

  8. A=17He (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not illustrated) Not observed: see (1986AJ04, 1988POZS

  9. A=17Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not illustrated) Not observed: see (1986AJ04, 1988POZS

  10. A=17Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mg (1993TI07) (Not observed) See (1983ANZQ, 1988WA18, 1992AV03).

  11. A=17P (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not observed) See (1983ANZQ, 1988WA18, 1992AV03

  12. A=17Si (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Si (1993TI07) (Not observed) See (1983ANZQ, 1988WA18, 1992AV03).

  13. A=18He (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not illustrated) Not observed: See (1982AV1A, 1983ANZQ

  14. A=20Al, etc. (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (Not observed) See (1972AJ02, 1983ANZQ, 1986AN07

  15. A=20Be (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (Not observed) See (1977CE05, 1983ANZQ, 1986AN07, 1987SIZX

  16. A=20n (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (Not observed) See (1977CE05, 1983ANZQ, 1986AN07, 1987SIZX

  17. A=20He (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    He (1998TI06) (Not observed) See (1977CE05, 1983ANZQ, 1986AN07, 1987SIZX).

  18. A=20Li (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1998TI06) (Not observed) See (1977CE05, 1983ANZQ, 1986AN07, 1987SIZX).

  19. A=5n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (Not illustrated) See also the A = 5 introductory discussion titled A = 5 resonance parameters.

  20. Structure of Naegleria Tet-like dioxygenase (NgTet1) in complexes with a reaction intermediate 5-hydroxymethylcytosine DNA

    SciTech Connect (OSTI)

    Hashimoto, Hideharu; Pais, June E.; Dai, Nan; Corrêa, Jr., Ivan R.; Zhang, Xing; Zheng, Yu; Cheng, Xiaodong

    2015-08-31

    The family of ten-eleven translocation (Tet) dioxygenases is widely distributed across the eukaryotic tree of life, from mammals to the amoeboflagellate Naegleria gruberi. Like mammalian Tet proteins, the Naegleria Tet-like protein, NgTet1, acts on 5-methylcytosine (5mC) and generates 5-hydroxymethylcytosine (5hmC), 5-formylcytosine (5fC) and 5-carboxylcytosine (5caC) in three consecutive, Fe(II)- and α-ketoglutarate-dependent oxidation reactions. The two intermediates, 5hmC and 5fC, could be considered either as the reaction product of the previous enzymatic cycle or the substrate for the next cycle. Here we present a new crystal structure of NgTet1 in complex with DNA containing a 5hmC. Along with the previously solved NgTet1–5mC structure, the two complexes offer a detailed picture of the active site at individual stages of the reaction cycle. In the crystal, the hydroxymethyl (OH-CH2-) moiety of 5hmC points to the metal center, representing the reaction product of 5mC hydroxylation. The hydroxyl oxygen atom could be rotated away from the metal center, to a hydrophobic pocket formed by Ala212, Val293 and Phe295. Such rotation turns the hydroxyl oxygen atom away from the product conformation, and exposes the target CH2 towards the metal-ligand water molecule, where a dioxygen O2 molecule would occupy to initiate the next round of reaction by abstracting a hydrogen atom from the substrate. The Ala212-to-Val (A212V) mutant profoundly limits the product to 5hmC, probably due to the reduced hydrophobic pocket size restricts the binding of 5hmC as a substrate.

  1. Development of the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) Process for Cesium Removal from High-Level Tank Waste

    SciTech Connect (OSTI)

    Moyer, Bruce A; Bonnesen, Peter V; Delmau, Laetitia Helene; Sloop Jr, Frederick {Fred} V; Williams, Neil J; Birdwell Jr, Joseph F; Lee, Denise L; Leonard, Ralph; Fink, Samuel D; Peters, Thomas B.; Geeting, Mark W

    2011-01-01

    This paper describes the chemical performance of the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) process in its current state of development for removal of cesium from the alkaline high-level tank wastes at the Savannah River Site (SRS) in the US Department of Energy (USDOE) complex. Overall, motivation for seeking a major enhancement in performance for the currently deployed CSSX process stems from needs for accelerating the cleanup schedule and reducing the cost of salt-waste disposition. The primary target of the NG-CSSX development campaign in the past year has been to formulate a solvent system and to design a corresponding flowsheet that boosts the performance of the SRS Modular CSSX Unit (MCU) from a current minimum decontamination factor of 12 to 40,000. The chemical approach entails use of a more soluble calixarene-crown ether, called MaxCalix, allowing the attainment of much higher cesium distribution ratios (DCs) on extraction. Concurrently decreasing the Cs-7SB modifier concentration is anticipated to promote better hydraulics. A new stripping chemistry has been devised using a vitrification-friendly aqueous boric acid strip solution and a guanidine suppressor in the solvent, resulting in sharply decreased DCs on stripping. Results are reported herein on solvent phase behavior and batch Cs distribution for waste simulants and real waste together with a preliminary flowsheet applicable for implementation in the MCU. The new solvent will enable MCU to process a much wider range of salt feeds and thereby extend its service lifetime beyond its design life of three years. Other potential benefits of NG-CSSX include increased throughput of the SRS Salt Waste Processing Facility (SWPF), currently under construction, and an alternative modular near-tank application at Hanford.

  2. Un~ted States Env~ronmental Monltor~ng EPA.600 '4-88, 021 Envtronmental Protect~on Systems Laboratory DOE/OP/00539/060

    Office of Legacy Management (LM)

    Env~ronmental Monltor~ng EPA.600 '4-88, 021 Envtronmental Protect~on Systems Laboratory DOE/OP/00539/060 Agency P 0. Box 93478 June 1988 Las Vegas NV 89193-5478 Research and Development Off-Site Environmental Monitoring Report Radiation Monitoring Around United States 1 ' 7 L 8 f Nuclear Test Areas This page intentionally left blank EPA-60014-88-021 DOE/DPI0053?-060 May 1988 OFF-SITE ENVIRONMENTAL MONITORING REPORT R a d i a t i o n M o n i t o r i n g Around U n i t e d States Nuclear Test

  3. Infrared spectroscopy of CaTiO3, SrTiO3, BaTiO3, Ba0.5Sr0.5TiO3...

    Office of Scientific and Technical Information (OSTI)

    Infrared spectroscopy of CaTiO3, SrTiO3, BaTiO3, Ba0.5Sr0.5TiO3 thin films, and (BaTiO3)5(SrTiO3)5 superlattice grown on SrRuO3SrTiO3(001) substrates Citation Details In-Document ...

  4. Magnetic Hardening of CeFe11Ti and the Effect of TiC Addition...

    Office of Scientific and Technical Information (OSTI)

    Magnetic Hardening of CeFe11Ti and the Effect of TiC Addition Citation ... Publication Date: 2015-04-01 OSTI Identifier: 1221660 Report Number(s): IS-J 8423 Journal ID: ISSN ...

  5. A=16He (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not illustrated) This nucleus has not been observed. See (1982AV1A, 1983ANZQ, 1986AJ04

  6. A=16Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1993TI07) (Not illustrated) This nucleus has not been observed. Shell model studies (1988POZS) are used to predict J and the magnetic dipole moment....

  7. A=19Mg (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mg (1995TI07) (Not observed) See (1987AJ02) and (1987GU1K, 1987PO01, 1993HI08

  8. Ng_NERSC_ASCR.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the cavity shape due to fabrication errors. This discovery was achieved as a team effort between SLAC, TOPS, and JLab which underscores the importance of the SciDAC...

  9. FPDS-NG National Interest Action (NIA) Code to Track Procurement Actions Made in Support of the Pacific Earthquake and Tsunami

    Broader source: Energy.gov [DOE]

    The purpose of this Policy Flash is to advise Contracting Officers of the establishment of a new National Interest Action (NIA) Code to track procurement actions made in support of the Pacific Earthquake and Tsunami. As explained below, this action does not trigger or otherwise authorize agencies to use any Emergency Acquisition Flexibilities in Federal Acquisition Regulation (FAR) 18.2. Effective immediately, procurement actions in direct response to the Pacific earthquake and tsunami should be reported in FPDS-NG using the NIA code "Pacific Earthquake/Tsunami 2011." The NIA value for Pacific Earthquake and Tsunami is currently valid from March 11, 2011, to September 12, 2011. Since responses to this incident may be conducted inside or outside the United States, Contracting Officers should ensure that "Place of Performance" data accurately reflects where the work will be performed. Note: This NIA Code should be used only to facilitate cost collection and reporting. Use of this NIA Code does not authorize or justify use of any Emergency Acquisition Flexibilities in FAR 18.2. However, the acquisition flexibilities described in FAR 18.1 may be available, as well as others in agency acquisition supplements, to support the response to the Pacific Earthquake and Tsunami.

  10. The permeation behavior of deuterium through 1Cr18Ni9Ti stainless steel with TiN+TiC-TiN multiple films

    SciTech Connect (OSTI)

    Xiong, Y.; Song, J.; Luo, D.; Lei, Q.; Chen, C.

    2015-03-15

    The prevention of tritium losses via permeation through structure components is an important issue in fusion technology. The production of thin layers on materials with low diffusivity and/or low surface recombination constants (so-called permeation barriers) seems to be the most practical method to reduce or hinder the permeation of tritium through materials. TiN+TiC+TiN multiple films are deposited on the surface of 1Cr18Ni9Ti stainless steel by ion-beam assisted deposition technology. The characteristics of films are tested by XPS ASEM and XRD, which shows that the film are compact and uniform with a thickness of about 15 μm, and have a good adherence with the substrate below 773 K. The diffraction peaks in the XRD patterns for TiC and TiN are broadened, implying that the multiple films are deposited on the surface of 1Cr18Ni9Ti stainless steel. Meanwhile, the C-H bonded CH{sub 4}-appears in the infrared spectra of multiple films, suggesting that the CH{sub 4}- is in a static state, so hydrogen atom cannot migrate from the site bonded with carbon to a neighboring site. The measured deuterium permeability in 1Cr18Ni9Ti stainless steel coated with multiple films is 2-3 orders of magnitude lower than that of pure 1Cr18Ni9Ti stainless steel substrate from 473 K to 773 K. However, this barrier is partly destroyed above 773 K.

  11. Ti Leggett | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ti Leggett Deputy Project Directcor & Deputy Director of Operations Argonne National Laboratory 9700 S. Cass Avenue Building 240 - Room 3132 Argonne, IL 60439 630-252-1937 tleggett

  12. A=10C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 10C) GENERAL: References to articles on general properties of 10C published since the previous review (1988AJ01) are grouped into...

  13. A=10N (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (Not illustrated) GENERAL: References to articles on general properties of 10N published since the previous review (1988AJ01) are grouped into categories and listed,...

  14. A=10Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 10Li) GENERAL: References to articles on general properties of 10Li published since the previous review (1988AJ01) are grouped into...

  15. A=10He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 10He) GENERAL: References to articles on general properties of 10He published since the previous review (1988AJ01) are grouped into...

  16. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1995TI07) (Not illustrated) 18Li has not been observed. Shell model calculations described in (1988POZS) predict the ground-state magentic dipole moment and charge and matter radii.

  17. A=18Mg, etc. (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not observed) See (1986AN07) and (1983ANZQ). See also the results of calculations of β+/electron capture half lives for neutron deficient nuclei in (1993HI08

  18. A=6B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (Not illustrated) Not observed: see ( 1984AJ01, 1989GR06 [6Li(π+, π-) at Eπ+ = 180, 240 MeV], 1993PO11 [properties of exotic light nuclei]) (1998SU18

  19. A=6C (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (Not illustrated) Not observed: see (1979AJ01, 1984AJ01, 1989GR06 [6Li(π+, π-) at Eπ+ = 180, 240 MeV], 1993PO11 [properties of exotic light nuclei]) (1998SU18

  20. Activity-based protein profiling of secreted cellulolytic enzyme activity dynamics in Trichoderma reesei QM6a, NG14, and RUT-C30

    SciTech Connect (OSTI)

    Anderson, Lindsey N.; Culley, David E.; Hofstad, Beth A.; Chauvigne-Hines, Lacie M.; Zink, Erika M.; Purvine, Samuel O.; Smith, Richard D.; Callister, Stephen J.; Magnuson, Jon M.; Wright, Aaron T.

    2013-12-01

    Development of alternative, non-petroleum based sources of bioenergy that can be applied in the short-term find great promise in the use of highly abundant and renewable lignocellulosic plant biomass.1 This material obtained from different feedstocks, such as forest litter or agricultural residues, can yield liquid fuels and other chemical products through biorefinery processes.2 Biofuels are obtained from lignocellulosic materials by chemical pretreatment of the biomass, followed by enzymatic decomposition of cellulosic and hemicellulosic compounds into soluble sugars that are converted to desired chemical products via microbial metabolism and fermentation.3, 4 To release soluble sugars from polymeric cellulose multiple enzymes are required, including endoglucanase, exoglucanase, and ?-glucosidase.5, 6 However, the enzymatic hydrolysis of cellulose into soluble sugars remains a significant limiting factor to the efficient and economically viable utilization of lignocellulosic biomass for transport fuels.7, 8 The primary industrial source of cellulose and hemicellulases is the mesophilic soft-rot fungus Trichoderma reesei,9 having widespread applications in food, feed, textile, pulp, and paper industries.10 The genome encodes 200 glycoside hydrolases, including 10 cellulolytic and 16 hemicellulolytic enzymes.11 The hypercellulolytic catabolite derepressed strain RUT-C30 was obtained through a three-step UV and chemical mutagenesis of the original T. reesei strain QM6a,12, 13 in which strains M7 and NG14 were intermediate, having higher cellulolytic activity than the parent strain but less activity and higher catabolite repression than RUT-C30.14 Numerous methods have been employed to optimize the secreted enzyme cocktail of T. reesei including cultivation conditions, operational parameters, and mutagenesis.3 However, creating an optimal and economical enzyme mixture for production-scale biofuels synthesis may take thousands of experiments to identify.

  1. A=20B (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (Not observed) The mass excess of 20B is predicted to be 69.08 MeV (1974TH01). 20B is then unstable with respect to breakup into 19B + n by 0.9 MeV: see 19B in (1995TI07) and (1978AJ03, 1983ANZQ) and see the work on effective interactions for the (0p1s0d) nuclear shell-model space (1992WA22

  2. Instability of Hydrogenated TiO2

    SciTech Connect (OSTI)

    Nandasiri, Manjula I.; Shutthanandan, V.; Manandhar, Sandeep; Schwarz, Ashleigh M.; Oxenford, Lucas S.; Kennedy, John V.; Thevuthasan, Suntharampillai; Henderson, Michael A.

    2015-11-06

    Hydrogenated TiO2 (H-TiO2) is toted as a viable visible light photocatalyst. We report a systematic study on the thermal stability of H-implanted TiO2 using X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), Rutherford backscattering spectrometry (RBS) and nuclear reaction analysis (NRA). Protons (40 keV) implanted at a ~2 atom % level within a ~120 nm wide profile of rutile TiO2(110) were situated ~300 nm below the surface. NRA revealed that this H-profile broadened preferentially toward the surface after annealing at 373 K, dissipated out of the crystal into vacuum at 473 K, and was absent within the beam sampling depth (~800 nm) at 523 K. Photoemission showed that the surface was reduced in concert with these changes. Similar anneals had no effect on pristine TiO2(110). The facile bulk diffusivity of H in rutile, as well as its activity toward interfacial reduction, significantly limits the utilization of H-TiO2 as a photocatalyst. This work was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. The research was performed using the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  3. Morphology, deformation, and defect structures of TiCr{sub 2} in Ti-Cr alloys

    SciTech Connect (OSTI)

    Chen, K.C.; Allen, S.M.; Livingston, J.D.

    1992-12-31

    The morphologies and defect structures of TiCr{sub 2} in several Ti-Cr alloys have been examined by optical metallography, x-ray diffraction, and transmission electron microscopy (TEM), in order to explore the room-temperature deformability of the Laves phase TiCr{sub 2}. The morphology of the Laves phase was found to be dependent upon alloy composition and annealing temperature. Samples deformed by compression have also been studied using TEM. Comparisons of microstructures before and after deformation suggest an increase in twin, stacking fault, and dislocation density within the Laves phase, indicating some but not extensive room-temperature deformability.

  4. Solution-Derived Bi(ZnTi)O3 - BaTiO3 Thin Films with Bulk-like...

    Office of Scientific and Technical Information (OSTI)

    Title: Solution-Derived Bi(ZnTi)O3 - BaTiO3 Thin Films with Bulk-like Permittivity. Abstract not provided. Authors: Meyer, Kelsey Elizabeth ; Kotula, Paul Gabriel ; Brennecka, ...

  5. Carrier-Controlled Ferromagnetism in SrTiO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moetakef, Pouya; Williams, James R.; Ouellette, Daniel G.; Kajdos, Adam P.; Goldhaber-Gordon, David; Allen, S. James; Stemmer, Susanne

    2012-06-27

    Magnetotransport and superconducting properties are investigated for uniformly La-doped SrTiO3 films and GdTiO3/SrTiO3 heterostructures, respectively. GdTiO3/SrTiO3 interfaces exhibit a high-density 2D electron gas on the SrTiO3 side of the interface, while, for the SrTiO3 films, carriers are provided by the dopant atoms. Both types of samples exhibit ferromagnetism at low temperatures, as evidenced by a hysteresis in the magnetoresistance. For the uniformly doped SrTiO3 films, the Curie temperature is found to increase with doping and to coexist with superconductivity for carrier concentrations on the high-density side of the superconducting dome. The Curie temperature of the GdTiO3/SrTiO3 heterostructures scales with themore » thickness of the SrTiO3 quantum well. The results are used to construct a stability diagram for the ferromagnetic and superconducting phases of SrTiO3.« less

  6. Giant persistent photoconductivity in BaTiO{sub 3}/TiO{sub 2} heterostructures

    SciTech Connect (OSTI)

    Plodinec, Milivoj; anti?, Ana; Gajovi?, Andreja; Zavanik, Janez; ?eh, Miran

    2014-10-13

    The persistent photoconductivity (PPC) effect in nanotube arrays of barium titanate and TiO{sub 2} (BTO/TiO{sub 2}NT) was studied at room temperature under daylight illumination. The BTO/TiO{sub 2}NT heterostructures exhibited a giant PPC effect that was six orders of magnitude higher than the dark conductivity, followed by a slow relaxation for 3 h. The PPC in this material was explained by the existence of defects at the surfaces and the interfaces of the investigated heterostructures. The sample was prepared using a two-step synthesis: the anodization of a Ti-foil and a subsequent hydrothermal synthesis. The structural and electrical characteristics were studied by micro-Raman spectroscopy, field-emission-gun scanning electron microscopy, and impedance spectroscopy.

  7. A=18C (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the 48Ca(18O, 18C)48Ti reaction. 18C is then bound by 4.188 MeV with respect to breakup into 17C + n. See also (1982FI10, 1987AJ02, 1992WA22). 1. 18C(-)18N Qm 11.807 The...

  8. A=18Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not observed) 18Na has not been observed; its atomic mass excess has been estimated to be 25.32 MeV (1993AU05); it is then unbound with respect to proton emission by 1.6 MeV: see (1978AJ03). See also (1986AN07) and (1983ANZQ

  9. A=5Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See the Isobar Diagram for 5Be) See also the A = 5 introductory discussion titled A = 5 resonance parameters. The absence of any group structure in the neutron spectrum in the reaction 3He(3He, n)5Be at E(3He) = 18.0 to 26.0 MeV indicates that 5Beg.s

  10. The corrosivity and passivity of sputtered Mg-Ti alloys

    SciTech Connect (OSTI)

    Song, Guang -Ling; Unocic, Kinga A.; Meyer, III, Harry M.; Cakmak, Ercan; Brady, Michael P.; Gannon, Paul E.; Himmer, Phil; Andrews, Quinn

    2015-11-30

    Our study explored the possibility of forming a “stainless” Mg–Ti alloy. The electrochemical behavior of magnetron-sputtered Mg–Ti alloys was measured in a NaCl solution, and the surface films on the alloys were examined by XPS, SEM and TEM. Increased corrosion resistance was observed with increased Ti content in the sputtered Mg–Ti alloys, but passive-like behavior was not reached until the Ti level (atomic %) was higher than the Mg level. Moreover, the surface film that formed on sputtered Mg–Ti based alloys in NaCl solution was thick, discontinuous and non-protective, whereas a thin, continuous and protective Mg and Ti oxide film was formed on a sputtered Ti–Mg based alloy.

  11. The corrosivity and passivity of sputtered Mg-Ti alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Song, Guang -Ling; Unocic, Kinga A.; Meyer, III, Harry M.; Cakmak, Ercan; Brady, Michael P.; Gannon, Paul E.; Himmer, Phil; Andrews, Quinn

    2015-11-30

    Our study explored the possibility of forming a “stainless” Mg–Ti alloy. The electrochemical behavior of magnetron-sputtered Mg–Ti alloys was measured in a NaCl solution, and the surface films on the alloys were examined by XPS, SEM and TEM. Increased corrosion resistance was observed with increased Ti content in the sputtered Mg–Ti alloys, but passive-like behavior was not reached until the Ti level (atomic %) was higher than the Mg level. Moreover, the surface film that formed on sputtered Mg–Ti based alloys in NaCl solution was thick, discontinuous and non-protective, whereas a thin, continuous and protective Mg and Ti oxide filmmore » was formed on a sputtered Ti–Mg based alloy.« less

  12. Effect of neutron irradiation on defect evolution in Ti3SiC2 and Ti2AlC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tallman, Darin J.; He, Lingfeng; Garcia-Diaz, Brenda L.; Hoffman, Elizabeth N.; Kohse, Gordon; Sindelar, Robert L.; Barsoum, Michel W.

    2015-10-23

    Here, we report on the characterization of defects formed in polycrystalline Ti3SiC2 and Ti2AlC samples exposed to neutron irradiation – up to 0.1 displacements per atom (dpa) at 350 ± 40 °C or 695 ± 25 °C, and up to 0.4 dpa at 350 ± 40 °C. Black spots are observed in both Ti3SiC2 and Ti2AlC after irradiation to both 0.1 and 0.4 dpa at 350 °C. After irradiation to 0.1 dpa at 695 °C, small basal dislocation loops, with a Burgers vector of b = 1/2 [0001] are observed in both materials. At 9 ± 3 and 10 ±more » 5 nm, the loop diameters in the Ti3SiC2 and Ti2AlC samples, respectively, were comparable. At 1 × 1023 loops/m3, the dislocation loop density in Ti2AlC was ≈1.5 orders of magnitude greater than in Ti3SiC2, at 3 x 1021 loops/m3. After irradiation at 350 °C, extensive microcracking was observed in Ti2AlC, but not in Ti3SiC2. The room temperature electrical resistivities increased as a function of neutron dose for all samples tested, and appear to saturate in the case of Ti3SiC2. The MAX phases are unequivocally more neutron radiation tolerant than the impurity phases TiC and Al2O3. Based on these results, Ti3SiC2 appears to be a more promising MAX phase candidate for high temperature nuclear applications than Ti2AlC.« less

  13. Structural and Morphological Difference Between Ti/TiN/TiCN Coatings Grown in Multilayer and Graded Form

    SciTech Connect (OSTI)

    Restrepo, E.; Baena, A.; Agudelo, C.; Castillo, H.; Devia, A.; Marino, A.

    2006-12-04

    Thin films can be grown in super-lattice, multilayers and graded form, having each one advantages and disadvantages. The difference between multilayer and graded coatings is the interface. In multilayers the interface is abrupt and in graded coatings it is diffuse. The interface influences many chemical and physical properties of the materials, and its choice depends on the application. Graded coatings have the advantage of having gradual properties such as thermal expansion coefficient and lattice parameter, avoiding adherence problems due to good match between their component materials. In this work the comparison between some properties of coatings grown as multilayer and graded is performed. The materials are produced using the sputtering DC technique because of its facility to control the deposition parameters and generate a slow growth. The target is a disc of titanium and the samples are made of stainless steel 304. The working gases are argon, nitrogen and methane, which are mixed according to the material to be produced, i.e. Ti layer is grown with argon, the TiN film is produced with a mixture of argon and nitrogen, and the TiCN material is obtained mixing argon, nitrogen and methane. These materials are characterized with AFM in order to determine grain size and with XPS studying the chemical composition and performing depth profiles.

  14. A=3n (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1987TI07) (Not illustrated) GENERAL: The weight of experimental evidence reviewed in the previous compilation of Fiarman and Hanna (1975FI08) is strongly against the existence of a bound state of the three-neutron system, and only controversial evidence of 3n resonances was cited. Several experiments carried out more recently have strengthened the evidence against the bound trineutron and have failed to discover resonance structure that cannot be otherwise explained. The most suggestive work is

  15. A Review Corrosion of TI Grade 7 and Other TI Alloys in Nuclear Waste Repository Environments

    SciTech Connect (OSTI)

    F. Hua; K. Mon; P. Pasupathi; G. Gordon

    2004-05-11

    Titanium alloy degradation modes are reviewed in relation to their performance in repository environments. General corrosion, localized corrosion, stress corrosion cracking, hydrogen induced cracking, microbially influenced corrosion, and radiation-assisted corrosion of Ti alloys are considered. With respect to the Ti Grade 7 drip shields selected for emplacement in the repository at Yucca Mountain, general corrosion, hydrogen induced cracking, and radiation-assisted corrosion will not lead to failure within the 10,000 year regulatory period; stress corrosion cracking (in the absence of disruptive events) is of no consequence to barrier performance; and localized corrosion and microbially influenced corrosion are not expected to occur. To facilitate the discussion, Ti Grades 2, 5, 7, 9, 11, 12, 16, 17, 18, and 24 are included in this review.

  16. Nature of Transactions (TI) Code | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    | (NNSA) Nature of Transactions (TI) Code U.S. Department of Energy / U.S. Nuclear Regulatory Commission Nuclear Materials Management & Safeguards System Nature of Transactions (TI) Code* Nature of Transactions (TI) Code* Code: Description: A Initiates lease and financial responsibility of DOE-owned material B Transfer of lease and financial responsiblity of DOE-owned material C Transfer of DOE-owned material with no change in lease or financial responsibility D Return to DOE for credit

  17. Thermoelastic Analysis of a Vibrating TiB/Ti Cantilever Beam Using Differential Thermography

    SciTech Connect (OSTI)

    Byrd, Larry; Wyen, Travis; Byrd, Alex

    2008-02-15

    Differential thermography has been used to detect the fluctuating temperatures due the thermoelastic effect for a number of years. This paper examines functionally graded TiB/Ti cantilever beams excited on an electromechanical shaker in fully reversed bending. Finite difference analysis of specimens was used to look at the effect of heat conduction, convection and the fundamental frequency on the surface temperature distribution and compared to experimental data. The thermoelastic effect was also used to detect cracking and the stress field at the tip of the fixture during fatigue.

  18. Ab initio Study of He Stability in hcp-Ti

    SciTech Connect (OSTI)

    Dai, Yunya; Yang, Li; Peng, SM; Long, XG; Gao, Fei; Zu, Xiaotao T.

    2010-12-20

    The stability of He in hcp-Ti was studied using ab initio method based on density functional theory. The results indicate that a single He atom prefers to occupy the tetrahedral site rather than the octahedral site. The interaction of He defects with Ti atoms has been used to explain the relative stabilities of He point defects in hcp-Ti. The relative stability of He defects in hcp-Ti is useful for He clustering and bubble nucleation in metal tritides, which provides the basis for development of improved atomistic models.

  19. Cathodic cage plasma deposition of TiN and TiO{sub 2} thin films on silicon substrates

    SciTech Connect (OSTI)

    Sousa, Romulo R. M. de; Sato, Patricia S.; Nascente, Pedro A. P.; Viana, Bartolomeu C.; Alves, Clodomiro; Nishimoto, Akio

    2015-07-15

    Cathodic cage plasma deposition (CCPD) was used for growing titanium nitride (TiN) and titanium dioxide (TiO{sub 2}) thin films on silicon substrates. The main advantages of the CCPD technique are the uniformity, tridimensionality, and high rate of the film deposition that occurs at higher pressures, lower temperatures, and lower treatment times than those used in conventional nitriding treatments. In this work, the influence of the temperature and gas atmosphere upon the characteristics of the deposited films was investigated. The TiN and TiO{sub 2} thin films were characterized by x-ray diffraction, scanning electron microscopy, and Raman spectroscopy to analyze their chemical, structural, and morphological characteristics, and the combination of these results indicates that the low-cost CCPD technique can be used to produce even and highly crystalline TiN and TiO{sub 2} films.

  20. Ferroelectric Self-assembled PbTiO3 Perovskite Nanostructures...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Perovskite Nanostructures onto (100)SrTiO3 Substrates from a Novel Microemulsion-aided Sol-Gel Preparation Figure 1. PbTiO3 nanostructures onto (100) SrTiO3 substrates....

  1. Optimizing optical absorption of TiO{sub 2} by alloying with...

    Office of Scientific and Technical Information (OSTI)

    Title: Optimizing optical absorption of TiOsub 2 by alloying with TiSsub 2 TiOsub 2 is an attractive material for photocatalytic water splitting, but its band gap is too ...

  2. Structure-Curie temperature relationships in BaTiO 3 -based ferroelect...

    Office of Scientific and Technical Information (OSTI)

    ferroelectric perovskites: Anomalous behavior of ( Ba , Cd ) TiO 3 from DFT, ... ferroelectric perovskites: Anomalous behavior of ( Ba , Cd ) TiO 3 from DFT, ...

  3. Effects of hydrochloric acid treatment of TiO{sub 2}nanoparticles...

    Office of Scientific and Technical Information (OSTI)

    Effects of hydrochloric acid treatment of TiOsub 2 nanoparticlesnanofibers bilayer film ... Title: Effects of hydrochloric acid treatment of TiOsub 2 nanoparticlesnanofibers ...

  4. Equation of State Model Quality Study for Ti and Ti64.

    SciTech Connect (OSTI)

    Wills, Ann Elisabet; Sanchez, Jason James

    2015-02-01

    Titanium and the titanium alloy Ti64 (6% aluminum, 4% vanadium and the balance ti- tanium) are materials used in many technologically important applications. To be able to computationally investigate and design these applications, accurate Equations of State (EOS) are needed and in many cases also additional constitutive relations. This report describes what data is available for constructing EOS for these two materials, and also describes some references giving data for stress-strain constitutive models. We also give some suggestions for projects to achieve improved EOS and constitutive models. In an appendix, we present a study of the 'cloud formation' issue observed in the ALEGRA code. This issue was one of the motivating factors for this literature search of available data for constructing improved EOS for Ti and Ti64. However, the study shows that the cloud formation issue is only marginally connected to the quality of the EOS, and, in fact, is a physical behavior of the system in question. We give some suggestions for settings in, and improvements of, the ALEGRA code to address this computational di culty.

  5. A=10B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 10B) GENERAL: References to articles on general properties of 10B published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 10B located on our website at: (www.tunl.duke.edu/nucldata/General_Tables/10b.shtml). See also Table Prev. Table 10.18 preview 10.18 [Table of Energy Levels] (in PDF or PS). μ = +1.80064475 ± 0.00000057 μN: see (1989RA17); Q = +84.72

  6. A=19B (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not illustrated) 19B has been observed in the bombardment of Be by 12 MeV/A 56Fe ions (1984MU27) and in the fragmentation of 44 MeV/A 40Ar (1988GU1A) and 55 MeV/A 48Ca (1991MU19). See also (1989DE52). The mass excess adopted by (1993AU05) is 59.360 ± 0.400 MeV. Shell model predictions for low-lying levels are discussed in (1992WA22). See also (1989PO1K, 1990LO11

  7. A=20C (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (Not illustrated) 20C has been observed in heavy ion projectile fragmentation reactions (1987GI05, 1990MU06, 1991MU19) and in proton-induced target-fragmentation reactions (1987VI13, 1988MU08, 1993WOZZ). The atomic mass excess is 37.560 ± 0.200 MeV (1995AU04). It is then stable with respect to 19C + n and 18C + 2n by 3.3 and 3.5 MeV, respectively. β-delayed neutron emission has been observed (1987GI05, 1990MU06, 1991MU19). The half life and neutron emission probability have been

  8. A=20N (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (Not illustrated) 20N is particle stable. Its atomic mass excess is 21.770 ± 0.050 MeV (1995AU04). It has been observed in heavy-ion transfer (1989OR03) and projectile fragmentation reactions (1987GI05, 1988DUZT, 1988MU08, 1990MU06, 1991OR01) and in target fragmentation reactions (1988WO09, 1991RE02, 1993WOZZ). See also the review (1988VI1D). Mass measurements were reported in (1987GI05, 1988WO09, 1989OR03, 1991OR01, 1993WOZZ). Nuclear matter rms radii have been derived from

  9. A=3He (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1987TI07) GENERAL: Ground State: Jπ = 1/2+, μ = -2.127624 ± 0.0000011 nm, M - A = 14.93132 ± 0.00003 MeV. General properties of the ground state of the A = 3 system are under 3H above. The wave function is predominantly S-state (~ 90%) with S'-state (1 - 2%) and D-state (~ 9%) admixtures (1975FI08, 1980PA12, 1984CI05, 1984CI09). For 3He the measured magnetic moment is μ = -2.127624 ± 0.0000011 nm (1978LEZA, 1978NE12). Calculations which include both impulse and pion exchange contributions

  10. A=3Li (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1987TI07) GENERAL: The previous compilation (1975FI08) listed a small number of references reporting on the four reactions discussed below. Only one of the experiments cited contained any evidence for a 3p resonance, and the discussion suggested that the observed enhancement in 3He(p, n) was more likely a final state interaction. In the work reported since (1975FI08) and listed below, only (1974POZN) contains any mention of the tri-proton, and no evidence for its existence was observed. 1. 2H(p,

  11. A=4HE (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    He (1992TI02) (See Energy Level Diagrams for 4He) GENERAL: Ground state:Due to non-central forces, the wave function for the Jπ = 0+ ground state of 4He can be a positive-parity mixture of three 1S0, six 3P0, and five 5D0 orthogonal states (1967BE74). Of course, the symmetric S-wave component is the dominant part of the wavefunction, with significant D-wave and almost negligible P-wave contributions. Since the D-state admixture can be inferred from measurements such as the tensor analyzing

  12. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1992TI02) (See Energy Level Diagrams for 4Li) GENERAL: The stability of 8B against particle decay (1988AJ01), in particular against decay into 4He + 4Li, sets an upper limit of 1.7 MeV on the separation energy of 4Li into p + 3He (1952SH44). The instability of 4H against particle decay (see 4H, GENERAL section) makes the particle stability of 4Li very unlikely, since the Coulomb energy of 4Li is approximately 1.7 MeV larger than that of 4H (1963WE10), and the nuclear energies should be

  13. A=5H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (Not illustrated) See also the A = 5 introductory discussion titled A = 5 resonance parameters. The previous review (1988AJ01) noted that the 9Be(11B, 15O) reaction at E(11B) = 52 - 76 MeV showed no evidence for the formation of 5H (1986BE35, 1987BO40). For the earlier work see (1984AJ01). See also (1987KO47, 1988SEZJ). In several experiments on π- absorption at rest there is some evidence for the formation of a very broad (8 ± 3 MeV) resonance in the 5H system with Er = 7.4 ± 0.7

  14. A=5He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See Energy Level Diagrams for 5He) GENERAL: References to articles on general properties of 5He published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 5He located on our website at (www.tunl.duke.edu/NuclData/General_Tables/5he.shtml). See also Table Prev. Table 5.1 preview 5.1 [Table of Energy Levels] (in PDF or PS). See also the A = 5 introductory discussion titled A = 5 resonance

  15. A=5Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See Energy Level Diagrams for 5Li) GENERAL: References to articles on general properties of 5Li published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 5Li located on our website at (www.tunl.duke.edu/NuclData/General_Tables/5li.shtml). See also Table Prev. Table 5.3 preview 5.3 [Table of Energy Levels] (in PDF or PS). See also the A = 5 introductory discussion titled A = 5 resonance

  16. A=6Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See Energy Level Diagrams for 6Be) GENERAL: References to articles on general properties of 6Be published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 6Be located on our website at (www.tunl.duke.edu/NuclData/General_Tables/6be.shtml). See also Table Prev. Table 6.14 preview 6.14 [Table of Energy Levels] (in PDF or PS). 1. (a) 3He(3He, γ)6Be Qm = 11.4884 (b) 3He(3He, p)5Li Qm = 11.17

  17. A=6He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See Energy Level Diagrams for 6He) GENERAL: References to articles on general properties of 6He published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 6He located on our website at (www.tunl.duke.edu/NuclData/General_Tables/6he.shtml). See also Table Prev. Table 6.1 preview 6.1 [Table of Energy Levels] (in PDF or PS). Ground State Properties: The interaction radius of 6He, obtained

  18. A=6Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See Energy Level Diagrams for 6Li) GENERAL: References to articles on general properties of 6He published since the previous review (1988AJ01) are grouped into categories and isted, along with brief descriptions of each item, in the General Tables for 6Li located on our website at (www.tunl.duke.edu/NuclData/General_Tables/6li.shtml). See also Table Prev. Table 6.4 preview 6.4 [Table of Energy Levels] (in PDF or PS). Ground State Properties: μ = +0.8220473(6) nm, +0.8220567(3) nm:

  19. A=6n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (Not illustrated) 6n has not been observed. See (1979AJ01, 1988AJ01) and references cited there. More recently (1990AL40) reports a search for 6n in a 14C(7Li, 6n) activation experiment at E(7Li) = 82 MeV. No evidence for 6n was obtained. The method of angular potential functions was used by (1989GO18) in a calculation of the properties of multi-neutron systems which indicated that these systems have no bound states. The ground state energy of a six-neutron drop has been computed with

  20. A=7Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See Energy Level Diagrams for 7Be) GENERAL: References to articles on general properties of 7Be published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 7Be located on our website at (www.tunl.duke.edu/NuclData/General_Tables/7be.shtml). See also Table Prev. Table 7.7 preview 7.7 [Table of Energy Levels] (in PDF or PS). The interaction nuclear radius of 7Be is 2.22 ± 0.02 fm

  1. A=7He (2002TI10)

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    2002TI10) (See Energy Level Diagrams for 7He) GENERAL: References to articles on general properties of 7He published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 7He located on our website at (www.tunl.duke.edu/NuclData/General_Tables/7he.shtml). See also Table Prev. Table 7.1 preview 7.1 [Table of Energy Levels] (in PDF or PS). Mass of 7He: The atomic mass excess of 7He is 26.11 ± 0.03 MeV:

  2. A=8B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 8B) GENERAL: References to articles on general properties of 8B published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 8B located on our website at (www.tunl.duke.edu/nucldata/General_Tables/8b.shtml). See also Table Prev. Table 8.15 preview 8.15 [Table of Energy Levels] (in PDF or PS). μ = 1.0355 ± 0.0003 μN: see (1996FIZY). Q = 68.3 ± 2.1 mb

  3. A=8He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 8He) GENERAL: References to articles on general properties of 8He published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 8He located on our website at (www.tunl.duke.edu/nucldata/General_Tables/8he.shtml). See also Table Prev. Table 8.1 preview 8.1 [Table of Energy Levels] (in PDF or PS). Mass of 8He: The atomic mass excess of 8He adopted by us and by

  4. A=9B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 9B) GENERAL: References to articles on general properties of 9B published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 9B located on our website at (www.tunl.duke.edu/nucldata/General_Tables/9b.shtml). See also Table Prev. Table 9.13 preview 9.13 [Table of Energy Levels] (in PDF or PS). The low-lying levels of 9B have mainly [441] spatial symmetry and

  5. A=9Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 9Be) GENERAL: References to articles on general properties of 9Be published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 9Be located on our website at (www.tunl.duke.edu/nucldata/General_Tables/9be.shtml). See also Table Prev. Table 9.2 preview 9.2 [Table of Energy Levels] (in PDF or PS). μ = -1.1778 ± 0.0009 μN: see (1978LEZA); Q = 52.88 ± 0.38 mb:

  6. A=9C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 9C) GENERAL: References to articles on general properties of 9C published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 9C located on our website at (www.tunl.duke.edu/nucldata/General_Tables/9c.shtml). See also Table Prev. Table 9.16 preview 9.16 [Table of Energy Levels] (in PDF or PS). Ground state properties: μ = -1.3914 ± 0.0005 μN (1996MA38). See

  7. A=9He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See the Isobar Diagram for 9He) GENERAL: References to articles on general properties of 9He published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 9He located on our website at (www.tunl.duke.edu/nucldata/General_Tables/9he.shtml). Mass of 9He: Although the value adopted in the 2003 Atomic Mass Evaluation (2003AU02) for the 9He ground state is 40.939 ± 0.029 MeV based on the results

  8. A=9Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 9Li) GENERAL: References to articles on general properties of 9Li published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 9Li located on our website at (www.tunl.duke.edu/nucldata/General_Tables/9li.shtml). See also Table Prev. Table 9.1 preview 9.1 [Table of Energy Levels] (in PDF or PS). Ground state properties: μ = 3.4391 ± 0.0006 μN (1983CO11). See

  9. A=9N (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (Not illustrated) Not observed: see (1988AJ01). Mass excesses of 46.56 and 46.40 MeV have been estimated from two different mass formulae (2000PO32). 9N would then be proton unbound by ~ 4 MeV. However, mass formulae neither take into account the fact that the last occupied orbit(s) may change near the drip lines nor the fact that an extended low-l orbit leads to a lowered Coulomb energy. The suggested s-wave ground-state of 9He and a Coulomb energy estimated from the 11N ground state

  10. Fabrication of TiO{sub 2} Thick Film for Photocatalyst from Commercial TiO{sub 2} Powder

    SciTech Connect (OSTI)

    Asteti, S. Fuji; Syarif, D. Gustaman

    2008-03-17

    Photocatalytic activity of TiO{sub 2} thick film ceramics made of commercial TiO{sub 2} powder has been studied. The TiO{sub 2} powder was nano sized one that was derived from dried TiO{sub 2} suspension. The TiO{sub 2} suspension was made by pouring some blended commercial TiO{sub 2} powder into some amount of water. The paste of TiO{sub 2} was made by mixing the nano sized TiO{sub 2} powder with organic vehicle and glass frit. The paste was spread on a glass substrate. The paste was dried at 100 deg. C and heated at different temperatures (400 deg. C and 500 deg. C) for 60 minutes to produce thick film ceramics. The photocatalytic activity of these films was evaluated by measuring the concentration of a solution of methylene blue where the thick films were inside after being illuminated by UV light at various periods of times. The initial concentration of the methylene blue solution was 5 ppm. Structural analyses were carried out by X-ray diffraction (XRD). The XRD analyses showed that the produced thick film ceramic had mainly crystal structure of anatase. According to the photocatalytical data, it was known that the produced thick film ceramics were photocatalyst which were capable of decomposing an organic compound such as the methylene blue.

  11. Electrostatic carrier doping of GdTiO{sub 3}/SrTiO{sub 3} interfaces

    SciTech Connect (OSTI)

    Moetakef, Pouya; Cain, Tyler A.; Zhang, Jack Y.; Janotti, Anderson; Van de Walle, Chris G.; Stemmer, Susanne; Ouellette, Daniel G.; Allen, S. James; Klenov, Dmitri O.; Rajan, Siddharth

    2011-12-05

    Heterostructures and superlattices consisting of a prototype Mott insulator, GdTiO{sub 3}, and the band insulator SrTiO{sub 3} are grown by molecular beam epitaxy and show intrinsic electronic reconstruction, approximately 1/2 electron per surface unit cell at each GdTiO{sub 3}/SrTiO{sub 3} interface. The sheet carrier densities in all structures containing more than one unit cell of SrTiO{sub 3} are independent of layer thicknesses and growth sequences, indicating that the mobile carriers are in a high concentration, two-dimensional electron gas bound to the interface. These carrier densities closely meet the electrostatic requirements for compensating the fixed charge at these polar interfaces. Based on the experimental results, insights into interfacial band alignments, charge distribution, and the influence of different electrostatic boundary conditions are obtained.

  12. Phase equilibria, formation, crystal and electronic structure of ternary compounds in Ti-Ni-Sn and Ti-Ni-Sb ternary systems

    SciTech Connect (OSTI)

    Romaka, V.V.; Rogl, P.; Romaka, L.; Stadnyk, Yu.; Melnychenko, N.; Grytsiv, A.; Falmbigl, M.; Skryabina, N.

    2013-01-15

    The phase equilibria of the Ti-Ni-Sn and Ti-Ni-Sb ternary systems have been studied in the whole concentration range by means of X-ray and EPM analyses at 1073 K and 873 K, respectively. Four ternary intermetallic compounds TiNiSn (MgAgAs-type), TiNi{sub 2-x}Sn (MnCu{sub 2}Al-type), Ti{sub 2}Ni{sub 2}Sn (U{sub 2}Pt{sub 2}Sn-type), and Ti{sub 5}NiSn{sub 3} (Hf{sub 5}CuSn{sub 3}-type) are formed in Ti-Ni-Sn system at 1073 K. The TiNi{sub 2}Sn stannide is characterized by homogeneity in the range of 50-47 at% of Ni. The Ti-Ni-Sb ternary system at 873 K is characterized by formation of three ternary intermetallic compounds, Ti{sub 0.8}NiSb (MgAgAs-type), Ti{sub 5}Ni{sub 0.45}Sb{sub 2.55} (W{sub 5}Si{sub 3}-type), and Ti{sub 5}NiSb{sub 3} (Hf{sub 5}CuSn{sub 3}-type). The solubility of Ni in Ti{sub 0.8}NiSb decreases number of vacancies in Ti site up to Ti{sub 0.91}Ni{sub 1.1}Sb composition. - Graphical abstract: Isothermal section of the Ti-Ni-Sn phase diagram and DOS distribution in hypothetical TiNi{sub 1+x}Sn solid solution. Highlights: Black-Right-Pointing-Pointer Ti-Ni-Sn phase diagram was constructed at 1073 K. Black-Right-Pointing-Pointer Four ternary compounds are formed: TiNiSn, TiNi{sub 2-x}Sn, Ti{sub 2}Ni{sub 2}Sn, and Ti{sub 5}NiSn{sub 3}. Black-Right-Pointing-Pointer Three ternary compounds exist in Ti-Ni-Sb system at 873 K. Black-Right-Pointing-Pointer The TiNi{sub 2}Sb compound is absent.

  13. Development of Ti/Ti{sub 3}Sn functionally gradient material produced by eutectic bonding method

    SciTech Connect (OSTI)

    Kirihara, S.; Takeda, M.; Tsujimoto, T. [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering] [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering

    1996-07-15

    Although many materials which have a single function have been developed, future needs are anticipated to include materials which have various functions. A functionally gradient material (FGM) which has characteristics of two different materials is a promising candidate for multi-functional material. The present methods for production of FGM, however, are very complicated and costly. In this study the authors answer the serious problem of high production cost by fabricating the FGM by a eutectic bonding method. This fabrication method includes structural control of FGM by changing the cooling process. They describe Ti/Ti{sub 3}Sn FGM obtained by the eutectic bonding method, and tell how the structure of its composition gradient part is changed by controlling the cooling process.

  14. Application of Ti-alloys as compressor discs and blades

    SciTech Connect (OSTI)

    Helm, D.

    1999-07-01

    Ti-alloys are widely used as materials for compressor discs, blades, vanes and housings in modern aero-engines due to their excellent strength-to-weight ratio. Their high corrosion resistance and good weldability are additional factors for their application as main compressor components. A variety of different Ti-alloys have been developed in recent years and introduced into jet engines in order to fulfill the large spectrum of required mechanical properties. The main topic of the present paper is to describe the correlation between essential microstructural features of a number of Ti-alloys for compressor disc and blade applications and such mechanical properties as strength, creep and fatigue resistance, fracture toughness, and crack propagation behavior. It will be shown that for different engine requirements the choice of the suitable alloy, as well as tailoring of microstructural features with the aim to achieve an optimized balance of relevant mechanical properties, is necessary. The influence of thermomechanical treatment on morphology and dimensions of phases, and the resulting correlation to mechanical properties, will be discussed in detail for selected Ti-alloys, i.e., Ti-6Al-4V, Ti-6Al-2Sn-4Zr-2Mo and IMI 834 (Ti-5.8Al-4Sn-3.5Zr-0.5Mo-0.7Nb-0.35Si-0.06C). Additionally, effects of surface conditions caused by surface treatment (shot peening) or by service exposure (surface oxidation) will be presented.

  15. Nondestructive evaluation of Ni-Ti shape memory alloy

    SciTech Connect (OSTI)

    Meir, S.; Gordon, S.; Karsh, M.; Ayers, R.; Olson, D. L.; Wiezman, A.

    2011-06-23

    The nondestructive evaluation of nickel titanium (Ni-Ti) alloys for applications such as heat treatment for biomaterials applications (dental) and welding was investigated. Ni-Ti alloys and its ternary alloys are valued for mechanical properties in addition to the shape memory effect. Two analytical approaches were perused in this work. Assessment of the microstructure of the alloy that determines the martensitic start temperature (Ms) of Ni-Ti alloy as a function of heat treatment, and secondly, an attempt to evaluate a Friction Stir Welding, which involves thermo-mechanical processing of the alloy.

  16. A=16B (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not illustrated) This nucleus has not been observed in the 4.8 GeV proton bombardment of a uranium target. It is particle unstable. Its mass excess is predicted to be 37.97 MeV; it would then be unstable with respect to decay into 15B + n by 0.93 MeV. See (1985WA02, 1986AJ04). The ground state is predicted to have Jπ = 0- and the first three excited states are predicted to lie at 0.95, 1.10, and 1.55 MeV [Jπ = 2-, 3-, 4-] in a (0 + 1)ℏω space shell model calculation. See (1983ANZQ,

  17. A=16C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (See Energy Level Diagrams for 16C) GENERAL: See Table Prev. Table 16.1 preview 16.1 [General Table] (in PDF or PS) and Table Prev. Table 16.2 preview 16.2 [Table of Energy Levels] (in PDF or PS) here. 1. 16C(β-)16N Qm = 8.012 The half life of 16C is 0.747 ± 0.008 sec. It decays to 16N*(0.12, 3.35, 4.32) [Jπ = 0-, 1+, 1+]: see Table Prev. Table 16.3 preview 16.3 (in PDF or PS) and (1993CH06). See also (1986AJ04) and see (1986KI05, 1988WA1E, 1992WA1L) for theoretical discussions of

  18. A=16Ne (1993TI07)

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    93TI07) (See the Isobar Diagram for 16Ne) GENERAL: See Table Prev. Table 16.29 preview 16.29 [General Table] (in PDF or PS) and Table Prev. Table 16.32 preview 16.32 [Table of Energy Levels] (in PDF or PS). Mass of 16Ne: The Q-values of the 20Ne(α, 8He) and 16O(π+, π-) reactions lead to atomic mass excesses of 23.93 ± 0.08 MeV (1978KE06), 23.978 ± 0.024 MeV (1983WO01) and 24.048 ± 0.045 MeV (1980BU15) [recalculated using the (1985WA02) masses for 8He, 16O and 20Ne]. The weighted mean is

  19. A=17Ne (1993TI07)

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    93TI07) (See the Isobar Diagram for 17Ne) GENERAL: See Table Prev. Table 17.26 preview 17.26 [Table of Energy Levels] (in PDF or PS). 1. (a) 17Ne(β+)17F* → 16O + p Qm = 13.928 (b) 17Ne(β+)17F → 13N + α Qm = 8.711 (c) 17Ne(β+)17F Qm = 14.529 The half-life of 17Ne has been reported as 109.0 ± 1.0 msec (1971HA05) and 109.3 ± 0.6 msec (1988BO39): the weighted mean is 109.2 ± 0.6 and we adopt it. The decay is primarily to the proton unstable states of 17F at 4.65, 5.49, 6.04 and 8.08 MeV

  20. A=18B (1995TI07)

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    95TI07) (Not illustrated) 18B has not been observed in the bombardment of Ta by 44 MeV/A Ar ions (1985DE60, 1985LA03, 1986PO13) or in the bombardment of Be by 12 MeV/A 56Fe ions (1984MU27). 18B has been predicted to have a mass excess of 52.3 MeV (1993AU05). It would then be unstable with respect to 17B + n by 0.5 MeV: see (1978AJ03, 1985WA02). 18B is calculated to have Jπ = 4- and to have excited states at 0.62, 0.86 and 1.59 MeV with Jπ = 1-, 2- and 2- (1985PO10).The shell model calculations

  1. A=18F (1995TI07)

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    95TI07) (See Energy Level Diagrams for 18F) GENERAL: See Table Prev. Table 18.23 preview 18.23 [General Table] (in PDF or PS) and Table Prev. Table 18.24 preview 18.24 [Table of Energy Levels] (in PDF or PS). μ1.12 = +2.86 ± 0.03 nm [see (1983AJ01)] Q1.12 = 0.13 ± 0.03 b [see (1983AJ01)]. 1. 18F(β+)18O Qm = 1.655 The positron decay is entirely to the ground state of 18O [Jπ = 0+, T = 1]; the half-life is 109.77 ± 0.05 min [see Table Prev. Table 18.11 preview 18.11 (in PDF or PS) in

  2. A=18N (1995TI07)

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    95TI07) (See Energy Level Diagrams for 18N) GENERAL: See Table Prev. Table 18.3 preview 18.3 [General Table ] (in PDF or PS) and Table Prev. Table 18.4 preview 18.4 [Table of Energy Levels] (in PDF or PS). Mass of 18N: The atomic mass excess derived from the Q-value of the 18O(7Li, 7Be)18N reaction and adopted by (1993AU05) is 13.117 ± 0.020 MeV (1983PU01). 18N is then stable with respect to breakup into 17N + n by 2.825 MeV. See (1983AJ01) for the earlier work. 1. 18N(β-)18O Qm = -13.899 The

  3. A=18Ne (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (See Energy Level Diagrams for 18Ne) GENERAL: See Table Prev. Table 18.35 preview 18.35 [General Table] (in PDF or PS) and Table Prev. Table 18.36 preview 18.36 [Table of Energy Levels] (in PDF or PS). For B(E2) of 18Ne*(1.89) and other parameters see (1987RA01) and Table Prev. Table 2 preview 2 in the Introduction. 1. 18Ne(β+)18F Qm = 4.446 The half-life of 18Ne is 1672 ± 8 ms: see (1978AJ03) and (1983AD03). The decay is primarily to 18F*(0, 1.04, 1.70 MeV). In addition there is an

  4. A=19C (1995TI07)

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    95TI07) (See the Isobar Diagram for 19C) 19C has been observed in the 0.8 GeV proton bombardment of thorium (1986VI09, 1988WO09) and in the fragmentation of 66 MeV/A argon ions (1987GI05) and in 44 MeV/A 22Ne on 181Ta, and in 112 MeV/A 20Ne on 12C (1994RAZW, 1995OZ02). The mass excess adopted by (1993AU05) is 32.23 ± 0.11 MeV. See also (1986VI09, 1987GI05, 1988WO09, 1991OR01). 19C is then stable with respect to decay into 18C + n by 0.16 MeV and into 17C + 2n by 4.35 MeV. The half-life was

  5. A=19N (1995TI07)

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    95TI07) (See the Isobar Diagram for 19N) 19N has been produced in a number of different multinucleon transfer reactions (1983AJ01, 1987AJ02), and these results lead to an adopted value (1993AU05) of 15.860 ± 0.016 MeV for the mass excess. 19N is then stable with respect to decay into 18N + n by 5.33 MeV. The half-life has been measured to be 0.32 ± 0.10 s (1986DU07), 0.21+0.2-0.1 s (1988MU08), 0.235 ± 0.032 s (1988SA04), 0.300 ± 0.080 s (1988DUZT), 0.329 ± 0.019 s (1991RE02). The neutron

  6. A=19Na (1995TI07)

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    95TI07) (See the Isobar Diagram for 19Na) This nucleus was observed in the 24Mg(p, 6He)19Na reaction at Ep = 54.7 MeV (1969CE01). A study via the 24Mg(3He, 8Li)19Na reaction at E(3He) = 76.3 MeV leads to an atomic mass excess of 12.929 ± 0.012 MeV for 19Na; it is then unstable with respect to breakup into 18Ne + p by 321 ± 13 keV. An excited state at Ex = 120 ± 10 keV is also reported (1975BE38, 1993AU05). See also (1987AJ02) and (1987PO01, 1987SA24, 1988CO15, 1990PO04, 1992AV03

  7. A=19Ne (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (See Energy Level Diagrams for 19Ne) GENERAL: See Table Prev. Table 19.26 preview 19.26 [General Table] (in PDF or PS) and Table Prev. Table 19.27 preview 19.27 [Table of Energy Levels] (in PDF or PS) here. μg.s. = -1.88542 (8) nm (1982MA39) μ0.239 = -0.740 (8) nm (1978LEZA) 1. 19Ne(β+)19F Qm = 3.238 We adopt the half-life of 19Ne suggested by (1983AD03): 17.34 ± 0.09 s. See also (1978AJ03). The decay is principally to 19Fg.s.: see Table Prev. Table 19.29 preview 19.29 (in PDF or

  8. A=19O (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (See Energy Level Diagrams for 19O) GENERAL: See Table Prev. Table 19.1 preview 19.1 [General Table] (in PDF or PS) and Table Prev. Table 19.2 preview 19.2 [Table of Energy Levels] (in PDF or PS) here. 1. 19O(β-)19F Qm = 4.819 The weighted mean of several half-lives is 26.96 ± 0.07 s: see (1972AJ02, 1987AJ02). The decay is complex: see reaction 34 of 19F and Table Prev. Table 19.23 preview 19.23 (in PDF or PS) and Table Prev. Table 19.24 preview 19.24 (in PDF or PS). 2. 9Be(18O,

  9. A=20F (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (See Energy Level Diagrams for 20F) GENERAL: See Table Prev. Table 20.4 preview 20.4 [General Table] (in PDF or PS) and Table Prev. Table 20.5 preview 20.5 [Table of Energy Levels] (in PDF or PS) here. μ = +2.0935 (9) nm (1989RA17) Q = -0.042 (3) b (1989RA17) 1. 20F(β-)20Ne Qm = 7.025 The half-life of 20F is (11.163 ± 0.008) s (1992WA04), (11.11 ± 0.04) s (1995IT1C). For earlier measurements see (1987AJ02). 20F decays principally to 20Ne*(1.63): see 20Ne, reaction 37. 2. (a) 6Li(15N,

  10. A=20Mg (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (See the Isobar Diagram for 20Mg) 20Mg has been populated in the 24Mg(α, 8He) reaction at Eα = 127 and 156 MeV, in the 20Ne(3He, 3n) reaction at E(3He) = 70 MeV, and more recently in projectile fragmentation reactions. Reviews of proton rich nuclei and methods of production are presented in (1989AYZU, 1993SO13). See also (1990PO04). The super-allowed decay of 20Mg to the first T = 2 (Jπ = 0+) state of 20Na [Ex = 6.534 ± 0.013 MeV (1995PI03)] has been reported in early work (1979MO02,

  11. A=20Na (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (See Energy Level Diagrams for 20Na) GENERAL: See Table Prev. Table 20.32 preview 20.32 [General Table] (in PDF or PS) and Table Prev. Table 20.33 preview 20.33 [Table of Energy Levels] (in PDF or PS) here. μ = 0.3694 ± 0.0002 nm (1975SC20, 1989RA17) 1. 20Na(β+)20Ne Qm = 13.887 20Na decays by positron emission to 20Ne*(1.63) and to a number of other excited states of 20Ne: see Table Prev. Table 20.31 preview 20.31 (in PDF or PS) and reaction 59 in 20Ne. The half-life of 20Na is 447.9

  12. A=20O (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (See Energy Level Diagrams for 20O) GENERAL: See Table Prev. Table 20.1 preview 20.1 [General Table] (in PDF or PS) and Table Prev. Table 20.2 preview 20.2 [Table of Energy Levels] (in PDF or PS) here. 1. 20O(β-)20F Qm = 3.814 20O decays with a half-life of 13.51 ± 0.05 s to the 1+ states 20F*(1.06, 3.49) with branching ratios (99.973 ± 0.003) and (0.027 ± 0.003)%, log f0t = 3.740 ± 0.006 and 3.65 ± 0.06, respectively (1987AL06). Upper limits for the branching to other states of

  13. A=3H (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1987TI07) (Not illustrated) GENERAL: Ground State: Jπ = 1/2+, μ = 2.978960 ± 0.000001 nm, M - A = 14.94991 ± 0.00003 MeV. The wave function for the triton bound state is calculated to be mostly S-state (~ 90%) with S'-state (~ 1%) and D-state (~ 9%) admixtures depending on the potentials used (1979SA15, 1986IS06). See also (1980HA10, 1980LO091983FR19, 1984CI05, 1984CI09, 1984MU23). The measured magnetic moment for 3H is μ = 2.978960 ± 0.000001 nm (1978LEZA). Calculations which include both

  14. A=4n (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4n (1992TI02) GENERAL: The stability of 8He (1968BA48, 1968ME03, 1973FI04, 1988AJ01) sets an upper limit to the total binding energy of 4n, because the decay 8He → 4He + 4n does not occur (1964GO1B, 1964GO25). The most precisely determined mass excess of 8He (1988WA18) yields B(4n) ≤ 3.1 MeV. Noting that in all known nuclei the proton binding energy increases when two neutrons are added, (1964VL1A) show that B(4n) < -Q, where Q is the decay energy for 5H → 3H + 2n. Since Q > 0

  15. A=7B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See the Isobar Diagram for 7B) The mass excess of 7B adopted by (1997AU04) is 27.870 ± 0.070 MeV. It was obtained by averaging the values of 27.94 ± 0.10 MeV from the 10B(3He, 6He)7B reaction (1967MC14, 1988AJ01) and the value 27.800 ± 0.10 MeV obtained in the 7Li(π+, π-)7B reaction (1981SE1B). The width of the ground state is Γ = 1.4 ± 0.2 MeV: see (1967MC14, 1988AJ01). 7B is unbound with respect to 6Be + p, 5Li + 2p and 4He + 3p by 2.21, 1.61 and 3.38 MeV, respectively. The

  16. A=7H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (Not illustrated) 7H has not been observed. Attempts have been made to detect it in the spontaneous fission of 252Cf (1982AL33) and in the 7Li(π-, π+) reaction [see (1984AJ01)]. A study of 9Be(π-, 2p) (1987GO25) found no evidence for 7H. See also the review of (1989OG1B) and the 7Li(π-, π+) investigation reported in (1989GR06). The ground state is calculated to have Jπ = 1/2+ and to be unstable with respect to 1n, 2n, 3n and 4n emission. Excited states are predicted at 4.84, 5.00

  17. A=8Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 8Be) GENERAL: References to articles on general properties of 8Be published since the previous review (1988AJ01) are grouped into categories and listed, along with brief descriptions of each item, in the General Tables for 8Be located on our website at (www.tunl.duke.edu/nucldata/General_Tables/8be.shtml). See also Table Prev. Table 8.9 preview 8.9 [Table of Energy Levels] (in PDF or PS). 1. 8Be → 4He4He Qm = 0.0918 Γcm for 8Beg.s. = 5.57 ± 0.25 eV:

  18. A=8C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See the Isobar Diagram for 8C) Mass of 8C: The atomic mass excess of 8C is 35094 ± 23 keV (2003AU03); Γcm = 230 ± 50 keV [Jπ = 0+; T = 2]: see (1979AJ01). 8C is stable with respect to 7B + p (Q = -0.07 MeV) and unstable with respect to 6Be + 2p (Q = 2.14), 5Li + 3p (Q = 1.55) and 4He + 4p (Q = 3.51). At E(3He) = 76 MeV the differential cross section for formation of 8Cg.s. in the 14N(3He, 9Li) reaction is ~ 5 nb/sr at θlab = 10°. The 12C(α, 8He)8C reaction has been studied at

  19. Modeling and experimental studies of oxide covered metal surfaces: TiO{sub 2}/Ti a model system. Progress report

    SciTech Connect (OSTI)

    Smyrl, W.H.

    1991-12-31

    Prior work in our laboratories at the Corrosion Research Center has shown that thin, anodic TiO{sub 2} films formed by the Slow Growth Mode (SGM) on polycrystalline titanium and microcrystalline with a texture that varies from one metal grain to another. Furthermore, the underlying metal grains are mapped by the photoelectrochemical response of the oxide. The same characteristics have also been demonstrated in our laboratory for ZnO grown on Zn. The TiO{sub 2}/Ti system has been chosen for study both because of its importance in energy systems, and because it can serve as a model system for other metal-metal oxide couples. The investigations of anodic TiO{sub 2} films on Ti have shown that the properties of thin films are consistent with the rutile form of the oxide. Both experimental data and theoretical calculations show the close resemblance to results on single crystal TiO{sub 2}. Furthermore, the modeling studies reveal that the optical transitions near the bandedge arise from the bulk band structure. The photoelectrochemical properties of anodic TiO{sub 2} films have now been shown to obey the simple Gaertner-Butler model for the semiconductor-electrolyte interface, with a few modifications. The most important deviation has now been shown to be a result of multiple internal reflections in the oxide film.

  20. Modeling and experimental studies of oxide covered metal surfaces: TiO sub 2 /Ti a model system

    SciTech Connect (OSTI)

    Smyrl, W.H.

    1991-01-01

    Prior work in our laboratories at the Corrosion Research Center has shown that thin, anodic TiO{sub 2} films formed by the Slow Growth Mode (SGM) on polycrystalline titanium and microcrystalline with a texture that varies from one metal grain to another. Furthermore, the underlying metal grains are mapped by the photoelectrochemical response of the oxide. The same characteristics have also been demonstrated in our laboratory for ZnO grown on Zn. The TiO{sub 2}/Ti system has been chosen for study both because of its importance in energy systems, and because it can serve as a model system for other metal-metal oxide couples. The investigations of anodic TiO{sub 2} films on Ti have shown that the properties of thin films are consistent with the rutile form of the oxide. Both experimental data and theoretical calculations show the close resemblance to results on single crystal TiO{sub 2}. Furthermore, the modeling studies reveal that the optical transitions near the bandedge arise from the bulk band structure. The photoelectrochemical properties of anodic TiO{sub 2} films have now been shown to obey the simple Gaertner-Butler model for the semiconductor-electrolyte interface, with a few modifications. The most important deviation has now been shown to be a result of multiple internal reflections in the oxide film.

  1. TI--CR--AL--O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F.; Schmid, Anthony P.

    2000-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  2. Photoinduced electron transfer in perylene-TiO2 nanoassemblies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ABSTRACT: The photosensitization effect of three perylene dye derivatives on titanium dioxide nanoparticles (TiO2 NPs) has been investigated. The dyes used, 1,7-dibromoperylene-3,4...

  3. Martensite transformation of epitaxial Ni-Ti films

    SciTech Connect (OSTI)

    Buschbeck, J.; Kozhanov, A.; Kawasaki, J. K.; James, R. D.; Palmstroem, C. J.

    2011-05-09

    The structure and phase transformations of thin Ni-Ti shape memory alloy films grown by molecular beam epitaxy are investigated for compositions from 43 to 56 at. % Ti. Despite the substrate constraint, temperature dependent x-ray diffraction and resistivity measurements reveal reversible, martensitic phase transformations. The results suggest that these occur by an in-plane shear which does not disturb the lattice coherence at interfaces.

  4. A comparative study of precipitation effects in Ti only and Ti-V Ultra Low Carbon (ULC) strip steels

    SciTech Connect (OSTI)

    Ooi, S.W.; Fourlaris, G. . E-mail: g.fourlaris@swansea.ac.uk

    2006-04-15

    Two ULC steel grades were investigated, one based on combined vanadium and titanium additions and the other based on titanium only additions. It has been established that TiC formation during interphase precipitation retards grain growth of the {l_brace}111{r_brace} texture grains during continuous annealing and hence positively affects the r value of the Ti only steel. The formation of newly formed TiC precipitates on dislocations during continuous annealing has been found to result in an increase of the yield strength in both steel grades, as the annealing temperature is increased. It is also confirmed that VC particles formed during the coiling process dissolve during the continuous annealing cycles. Suitable continuous annealing cycles can be adopted to produce high formable steels with a bake hardening potential using the beneficial effects of combined Ti-V additions.

  5. Native SrTiO3 (001) surface layer from resonant Ti L2,3 reflectance spectroscopy

    SciTech Connect (OSTI)

    Valvidares, Manuel; Huijben, Mark; Yu, Pu; Ramesh, Ramamoorthy; Kortright, Jeffrey

    2010-11-03

    We quantitatively model resonant Ti L2,3 reflectivity Rs,p(q, hn) from several SrTiO3 (001) single crystals having different initial surface preparations and stored in ambient conditions before and between measurements. All samples exhibit unexpected 300 K Rs(hn) - Rp(hn) anisotropy corresponding to weak linear dichroism and tetragonal distortion of the TiO6 octahedra indicating a surface layer with properties different from cubic SrTiO3. Oscillations in Rs(q) confirm a ubiquitous surface layer 2-3 nm thick that evolves over a range of time scales. Resonant optical constant spectra derived from Rs,p(hn) assuming a uniform sample are refined using a single surface layer to fit measured Rs(q). Differences in surface layer and bulk optical properties indicate that the surface is significantly depleted in Sr and enriched in Ti and O. While consistent with the tendency of SrTiO3 surfaces toward non-stoichiometry, this layer does not conform simply to existing models for the near surface region and apparently forms via room temperature surface reactions with the ambient. This new quantitative spectral modeling approach is generally applicable and has potential to study near-surface properties of a variety of systems with unique chemical and electronic sensitivities.

  6. A=6H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See the Isobar Diagram for 6H) 6H was reported in the 7Li(7Li, 8B)6H reaction at E(7Li) = 82 MeV (1984AL08, 1985AL1G) [σ(θ) ~ 60 nb/sr at θ = 10°] and in the 9Be(11B, 14O)6H reaction at E(11B) = 88 MeV (1986BE35) [σ(θ) ~ 16 nb/sr at θ ~ 8°]. 6H is unstable with respect to breakup into 3H + 3n by 2.7 ± 0.4 MeV, Γ = 1.8 ± 0.5 MeV (1984AL08), 2.6 ± 0.5 MeV, Γ = 1.3 ± 0.5 MeV (1986BE35). The value adopted in the previous review (1988AJ01) is 2.7 ± 0.3 MeV, Γ = 1.6 ± 0.4

  7. Magneto-transport in LaTi{sub 1−x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures

    SciTech Connect (OSTI)

    Kumar, Pramod Dogra, Anjana Budhani, R. C.

    2014-04-24

    We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

  8. Incorporation of chromium into TiO{sub 2} nanopowders

    SciTech Connect (OSTI)

    Kollbek, Kamila; Sikora, Marcin; Kapusta, Czesław; Szlachetko, Jakub; Radecka, Marta; Lyson-Sypien, Barbara; Zakrzewska, Katarzyna

    2015-04-15

    Highlights: • Nanopowders of TiO{sub 2}:Cr with different amount of Cr dopant were obtained by flame spray synthesis, FSS. • Increase in the optical absorption and a shift of the absorption edge were observed upon Cr doping. • HERFD-XANES measurements indicated that the average valence state of titanium ions was preserved. • Increasing magnetic susceptibility of a paramagnetic character was observed upon Cr doping. - Abstract: The paper reports on the results of a study of optical, electronic and magnetic properties of TiO{sub 2} nanopowders doped with Cr ions. Diffused reflectance spectra reveal an increase in the optical absorption and a shift of the absorption edge towards lower energies upon Cr doping. Direct information on the Ti electronic state and the symmetry of its nearest environment is obtained from XANES Ti K-edge spectra. Magnetic behaviour is probed by means of the temperature dependence of DC magnetic susceptibility. Increasing magnetic susceptibility of a paramagnetic character is observed upon increasing chromium doping. The Curie constant of TiO{sub 2}:10 at.% Cr sample (0.12 emu K/mol Oe) is lower than that expected for Cr{sup 3+} (0.1875 emu K/mol Oe) possibly due to the appearance of Cr{sup 4+} or the presence of the orbital contribution to the magnetic moment.

  9. Morphology and structural development of reduced anatase-TiO{sub 2} by pure Ti powder upon annealing and nitridation: Synthesis of TiO{sub x} and TiO{sub x}N{sub y} powders

    SciTech Connect (OSTI)

    Bolokang, A.S.; Motaung, D.E.

    2015-02-15

    It is well known that nitriding of titanium is suitable for surface coating of biomaterials and in other applications such as anti-reflective coating, while oxygen-rich titanium oxynitride has been applied in thin film resistors and photocatalysis. Thus in this work anatase was reduced with pure titanium powder during annealing in argon. This was done to avoid any metallic contamination and unwanted residual metal doping. As a result, interesting and different types of particle morphology were synthesized when the pre-milled elemental anatase and titanium powders were mixed. The formation of metastable face centred cubic and monoclinic titanium monoxide was detected by the X-ray diffraction technique. The phases were confirmed by energy dispersive X-ray spectroscopy analysis. Raman analysis revealed weak intensity peaks for samples annealed in argon as compared to those annealed under nitrogen. - Graphical abstract: Display Omitted - Highlights: • Reaction of TiO{sub 2} and Ti induced metastable FCC and monoclinic TiO{sub x}. • Compositions of mixed powder were prepared from the unmilled and pre-milled powders. • Nitridation of TiO{sub x} yielded TiO{sub x}N{sub y} phase. • Mixed morphology was observed on all three powder samples.

  10. Water adsorption induced in-plane domain switching on BaTiO{sub 3} surface

    SciTech Connect (OSTI)

    Li, X.; Bai, Y.; Su, Y. J.; Wang, B. C.

    2015-09-07

    In this study, the influences of the adsorption of water molecules on the changes in the atomic and electric structures of BaTiO{sub 3} surface were investigated using ab initio calculation. Water molecules are molecularly and dissociatively adsorbed on the BaTiO{sub 3} surface, which makes electrons transfer from water molecules to the BaTiO{sub 3} surface. The redistribution of electrons in the BaTiO{sub 3} surface layers weakens the Ba-O interactions and strengthens the Ti-O interactions, so that the Ti atom shifts in TiO{sub 2} plane, i.e., an in-plane domain switching. The adsorption of water molecules on BaTiO{sub 3} surfaces also results in a reduction in the surface rumpling.

  11. High-Ti-concentration aerogels for bright x-ray sources (Technical...

    Office of Scientific and Technical Information (OSTI)

    Ti-concentration aerogels for bright x-ray sources Citation Details In-Document Search Title: High-Ti-concentration aerogels for bright x-ray sources Authors: Perez, F ; Patterson,...

  12. High-Ti-concentration aerogels for bright x-ray sources (Technical...

    Office of Scientific and Technical Information (OSTI)

    Ti-concentration aerogels for bright x-ray sources Citation Details In-Document Search Title: High-Ti-concentration aerogels for bright x-ray sources You are accessing a...

  13. Low temperature fabrication of perovskite solar cells with TiO...

    Office of Scientific and Technical Information (OSTI)

    the perovskite were fabricated from TiOsub 2 nanoparticles with different grain sizes. ... performance of solar cells was improved by combination of two TiOsub 2 nanoparticles. ...

  14. Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system...

    Office of Scientific and Technical Information (OSTI)

    Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Title: Ti3CrCu4: A possible ... Country of Publication: United States Language: English Word Cloud More Like This Free ...

  15. Conversion of 1,3-Propylene Glycol on Rutile TiO2(110) (Journal...

    Office of Scientific and Technical Information (OSTI)

    Conversion of 1,3-Propylene Glycol on Rutile TiO2(110) Citation Details In-Document Search Title: Conversion of 1,3-Propylene Glycol on Rutile TiO2(110) The adsorption of...

  16. Interface-Induced Polarization in SrTiO3-LaCrO3 Superlattices...

    Office of Scientific and Technical Information (OSTI)

    Through x-ray absorption near edge spectroscopy and aberration-corrected scanning transmission electron microscopy we show that the Ti cations are displaced off-center in the TiO6 ...

  17. FIRST-PRINCIPLES PHASE STABILITY IN THE TI-V ALLOY SYSTEM (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: FIRST-PRINCIPLES PHASE STABILITY IN THE TI-V ALLOY SYSTEM Citation Details In-Document Search Title: FIRST-PRINCIPLES PHASE STABILITY IN THE TI-V ALLOY SYSTEM ...

  18. Local Metal and Deuterium Ordering in the Deuterated ZrTiNi C14...

    Office of Scientific and Technical Information (OSTI)

    Local Metal and Deuterium Ordering in the Deuterated ZrTiNi C14 Laves Phase Citation Details In-Document Search Title: Local Metal and Deuterium Ordering in the Deuterated ZrTiNi ...

  19. Deformation behavior of Nb nanowires in TiNiCu shape memory alloy...

    Office of Scientific and Technical Information (OSTI)

    in TiNiCu shape memory alloy matrix This content will become publicly available on August 18, 2016 Title: Deformation behavior of Nb nanowires in TiNiCu shape memory alloy matrix ...

  20. Electric control of magnetism at the Fe/BaTiO3 interface (Journal...

    Office of Scientific and Technical Information (OSTI)

    Electric control of magnetism at the FeBaTiO3 interface Citation Details In-Document Search Title: Electric control of magnetism at the FeBaTiO3 interface Interfacial ...

  1. Electric control of magnetism at the Fe/BaTiO3 interface (Journal...

    Office of Scientific and Technical Information (OSTI)

    Electric control of magnetism at the FeBaTiO3 interface Citation Details In-Document Search Title: Electric control of magnetism at the FeBaTiO3 interface You are accessing a ...

  2. Visible Light Absorption of N-Doped TiO2 Rutile Using (LR/RT...

    Office of Scientific and Technical Information (OSTI)

    N-Doped TiO2 Rutile Using (LRRT)-TDDFT and Active Space EOMCCSD Calculations Citation Details In-Document Search Title: Visible Light Absorption of N-Doped TiO2 Rutile Using ...

  3. Electrolyte Gate-Controlled Kondo Effect in SrTiO3 (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Electrolyte Gate-Controlled Kondo Effect in SrTiO3 Prev Next Title: Electrolyte Gate-Controlled Kondo Effect in SrTiO3 Authors: Lee, Menyoung ; Williams, J. R. ; Zhang, Sipei ...

  4. Coating power RF components with TiN

    SciTech Connect (OSTI)

    Kuchnir, M.; Hahn, E.

    1995-03-01

    A facility for coating RF power components with thin films of Ti and/or TiN has been in operation for some time at Fermilab supporting the Accelerator Division RF development work and the TESLA program. It has been experimentally verified that such coatings improve the performance of these components as far as withstanding higher electric fields. This is attributed to a reduction in the secondary electron emission coefficient of the surfaces when coated with a thin film containing titanium. The purpose of this Technical Memorandum is to describe the facility and the procedure used.

  5. High strength, light weight Ti-Y composites and method of making same

    DOE Patents [OSTI]

    Verhoeven, John D.; Ellis, Timothy W.; Russell, Alan M.; Jones, Lawrence L.

    1993-04-06

    A high strength, light weight "in-situ" Ti-Y composite is produced by deformation processing a cast body having Ti and Y phase components distributed therein. The composite comprises elongated, ribbon-shaped Ti and Y phase components aligned along an axis of the deformed body.

  6. High strength, light weight Ti-Y composites and method of making same

    DOE Patents [OSTI]

    Verhoeven, J.D.; Ellis, T.W.; Russell, A.M.; Jones, L.L.

    1993-04-06

    A high strength, light weight in-situ'' Ti-Y composite is produced by deformation processing a cast body having Ti and Y phase components distributed therein. The composite comprises elongated, ribbon-shaped Ti and Y phase components aligned along an axis of the deformed body.

  7. Resonance photoelectron spectroscopy of TiX{sub 2} (X = S, Se, Te) titanium dichalcogenides

    SciTech Connect (OSTI)

    Shkvarin, A. S. Yarmoshenko, Yu. M.; Skorikov, N. A.; Yablonskikh, M. V.; Merentsov, A. I.; Shkvarina, E. G.; Titov, A. N.

    2012-11-15

    The photoelectron valence band spectra of TiS{sub 2}, TiSe{sub 2}, and TiTe{sub 2} dichalcogenides are investigated in the Ti 2p-3d resonance regime. Resonance bands in the vicinity of the Fermi energy are found for TiS{sub 2} and TiTe{sub 2}. The nature of these bands is analyzed based on model calculations of the density of electronic states in TiS{sub 2}, TiSe{sub 2}, and TiTe{sub 2} compounds intercalated by titanium atoms. Analysis of experimental data and their comparison with model calculations showed that these bands have different origins. It is found that the resonance enhancement of an additional band observed in TiS{sub 2} is explained by self-intercalation by titanium during the synthesis of this compound. The resonance enhancement in TiTe{sub 2} is caused by occupation of the 3d band in Ti.

  8. Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures

    SciTech Connect (OSTI)

    Ngai, J. H.; Kumah, D. P.; Walker, F. J.; Ahn, C. H.

    2014-02-10

    We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

  9. Induced Ti magnetization at La0.7Sr0.3MnO3 and BaTiO3 interfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Yaohua; Tornos, J.; te Velthuis, S. G. E.; Freeland, J. W.; Zhou, H.; Steadman, P.; Bencok, P.; Leon, C.; Santamaria, J.

    2016-04-01

    In artificial multiferroics hybrids consisting of ferromagnetic La0.7Sr0.3MnO3 (LSMO) and ferroelectric BaTiO3 epitaxial layers, net Ti moments are found from polarized resonant soft x-ray reflectivity and absorption. Moreover, the Ti dichroic reflectivity follows the Mn signal during the magnetization reversal, indicating exchange coupling between the Ti and Mn ions. But, the Ti dichroic reflectivity shows stronger temperature dependence than the Mn dichroic signal. Besides a reduced ferromagnetic exchange coupling in the interfacial LSMO layer, this may also be attributed to a weak Ti-Mn exchange coupling that is insufficient to overcome the thermal energy at elevated temperatures.

  10. Dye sensitized solar cell applications of CdTiO{sub 3}–TiO{sub 2} composite thin films deposited from single molecular complex

    SciTech Connect (OSTI)

    Ehsan, Muhammad Ali; Khaledi, Hamid; Pandikumar, Alagarsamy; Huang, Nay Ming; Arifin, Zainudin; Mazhar, Muhammad

    2015-10-15

    A heterobimetallic complex [Cd{sub 2}Ti{sub 4}(μ-O){sub 6}(TFA){sub 8}(THF){sub 6}]·1.5THF (1) (TFA=trifluoroacetato, THF=tetrahydrofuran) comprising of Cd:Ti (1:2) ratio was synthesized by a chemical reaction of cadmium (II) acetate with titanium (IV) isopropoxide and triflouroacetic acid in THF. The stoichiometry of (1) was recognized by single crystal X-ray diffraction, spectroscopic and elemental analyses. Thermal studies revealed that (1) neatly decomposes at 450 °C to furnish 1:1 ratio of cadmium titanate:titania composite oxides material. The thin films of CdTiO{sub 3}–TiO{sub 2} composite oxides were deposited at 550 °C on fluorine doped tin oxide coated conducting glass substrate in air ambient. The micro-structure, crystallinity, phase identification and chemical composition of microspherical architectured CdTiO{sub 3}–TiO{sub 2} composite thin film have been determined by scanning electron microscopy, X-ray diffraction, Raman spectroscopy and energy dispersive X-ray analysis. The scope of composite thin film having band gap of 3.1 eV was explored as photoanode for dye-sensitized solar cell application. - Graphical abstarct: Microspherical designed CdTiO{sub 3}–TiO{sub 2} composite oxides photoanode film has been fabricated from single source precursor [Cd{sub 2}Ti{sub 4}(μ-O){sub 6}(TFA){sub 8}(THF){sub 6}]·1.5THF via aerosol assisted chemical vapor deposition technique for dye sensitized solar cell application. - Highlights: • Synthesis and characterization of a heterobimetallic Cd–Ti complex. • Fabrication of CdTiO{sub 3}–TiO{sub 2} thin film photoelectrode. • Application as dye sensitized photoanode for solar application.

  11. Epitaxial single-crystal thin films of MnxTi1-xO2-δ grown on...

    Office of Scientific and Technical Information (OSTI)

    Epitaxial single-crystal thin films of MnxTi1-xO2- grown on (rutile)TiO2 substrates with ... Title: Epitaxial single-crystal thin films of MnxTi1-xO2- grown on (rutile)TiO2 ...

  12. Woo-Sun Yang! NERSC User Engagement Group Vectorization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vectorization - 1 - March 23, 2016 NERSC User Group Mee9ng 2016 What's All This About Vectorization? * Vectoriza9on is an on-node, in-core way of exploi9ng data level parallelism in programs by applying the same opera9on to mul9ple data items in parallel. - 2 - DO I= 1, N Z(I) = X(I) + Y(I) ENDDO * Requires transforming a program so that a single instruc6on can launch many opera6ons on different data * Applies most commonly to array opera6ons in loops What is Required for Vectorization? * Code

  13. Adhesion evaluation of TiN and (Ti, Al)N coatings on titanium 6Al-4V

    SciTech Connect (OSTI)

    James, R.D.; Gruss, K.A.; Horie, Y.; Davis, R.F.; Paisley, D.L.; Parthasarthi, S.; Tittmann, B.R.

    1996-12-31

    The metallic components of gas turbine engines are continually subjected to hostile atmospheres. Nitride coatings improve the performance of the metallic compressor blades in these engines. To assess the adhesion of nitride coatings on metals, titanium 6% aluminum 4% vanadium substrates were coated with titanium nitride (TiN) using both cathodic arc and electron beam evaporation. Titanium aluminum nitride ((Ti, Al)N) was also deposited using cathodic arc evaporation. The interfaces of the coated samples were loaded in tension using a high speed shock wave which caused spallation either at the interface, in the coating or in the metal. Scanning acoustic microscopy analysis of the spalled samples detected delaminations at the interface in the samples deposited by cathodic arc evaporation. DYNA2D modeling of plate impact spallation experiments revealed the tensile adhesion strength for TiN deposited by both techniques was {approx} 2.0 GPa. The tensile adhesion strength for (Ti, Al)N was less than 1.5 GPa.

  14. Laser hydrothermal reductive ablation of titanium monoxide: Hydrated TiO particles with modified Ti/O surface

    SciTech Connect (OSTI)

    Blazevska-Gilev, Jadranka; Jandova, Vera; Kupcik, Jaroslav; Bastl, Zdenek; Subrt, Jan; Bezdicka, Petr; Pola, Josef

    2013-01-15

    IR laser- and UV laser-induced ablation of titanium monoxide (TM) in hydrogen (50 Torr) is compared to the same process induced in vacuum and shown to result in deposition of hydrated surface modified nanostructured titanium suboxide films. Complementary analyses of the films deposited in vacuum and in hydrogen by Fourier transform infrared, Raman and X-ray photoelectron spectroscopy, X-ray diffraction and electron microscopy allowed to determine different features of both films and propose a mechanism of surface modification of ejected particles, which involves hydrothermal reduction of TM and subsequent reactions of evolved water. The films exert good adhesion to metal and quartz surfaces and are hydrophobic in spite of having their surface coated with adsorbed water. - Graphical abstract: Laser ablation of titanium monoxide (TiO) in hydrogen involves a sequence of H{sub 2} and H{sub 2}O eliminations and additions and yields hydrated amorphous nanostructured titanium suboxide which is richer in oxygen than TiO. Highlights: Black-Right-Pointing-Pointer IR and UV laser ablated particles of titanium monoxide (TiO) undergo amorphization. Black-Right-Pointing-Pointer Films deposited in vacuum have TiO stoichiometry and are oxidized in atmosphere. Black-Right-Pointing-Pointer Films deposited in hydrogen are hydrated and have more O in topmost layers. Black-Right-Pointing-Pointer Films modification in hydrogen is explained by reactions in hydrogen plasma.

  15. Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries

    SciTech Connect (OSTI)

    Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

    2014-08-19

    Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

  16. Structural and chemical characterization of BaTiO{sub 3} nanorods

    SciTech Connect (OSTI)

    Zagar, K.; Recnik, A.; Sturm, S.; Gajovic, A.; Ceh, M.

    2011-03-15

    Research highlights: {yields} Polycrystalline BaTiO{sub 3} nanorods were synthesized with EPD into AAO templates. {yields} Nanorods are composed of crystalline, nanosized grains with pseudo-cubic structure. {yields} Integrowth of hexagonal BaTiO{sub 3} polymorph within pseudo-cubic structure was observed. -- Abstract: An electron-microscopy investigation was performed on BaTiO{sub 3} nanorods that were processed by sol-gel electrophoretic deposition (EPD) into anodic aluminium oxide (AAO) membranes. The BaTiO{sub 3} nanorods grown within the template membranes had diameters ranging from 150 to 200 nm, with an average length of 10-50 {mu}m. By using various electron-microscopy techniques we showed that the processed BaTiO{sub 3} nanorods were homogeneous in their chemical composition. The BaTiO{sub 3} nanorods were always polycrystalline and were composed of well-crystallized, defect-free, pseudo-cubic BaTiO{sub 3} grains, ranging from 10 to 30 nm. No intergranular phases were observed between the BaTiO{sub 3} grains. A low-temperature hexagonal polymorph that is coherently intergrown with the BaTiO{sub 3} perovskite matrix was also observed as a minor phase. When annealing the AAO templates containing the BaTiO{sub 3} sol in an oxygen atmosphere the presence of the hexagonal polymorph was diminished.

  17. Synthesis of visible light-activated TiO{sub 2} photocatalyst via surface organic modification

    SciTech Connect (OSTI)

    Jiang Dong Xu Yao Hou Bo; Wu Dong; Sun Yuhan

    2007-05-15

    A visible light-activated TiO{sub 2} photocatalyst was successfully synthesized by the surface organic modification to sol-gel-hydrothermal synthesized TiO{sub 2}. The surface hydroxyls of TiO{sub 2} nanoparticles reacted with the active -NCO groups of tolylene diisocyanate (TDI) to form a surface complex that was confirmed by the FT-IR and XPS spectra. Due to the existence of surface complex, the absorption edge of as-prepared TDI-modified TiO{sub 2} nanomaterial extended well into visible region. Compared with unmodified TiO{sub 2} and Degussa P25, the TDI-modified TiO{sub 2} photocatalysts showed higher activity for the photocatalytic degradation of methylene blue under visible light irradiation. - Graphical abstract: A visible light-activated TiO{sub 2} photocatalyst was successfully synthesized by the surface organic modification to TiO{sub 2}. The surface hydroxyls of TiO{sub 2} nanoparticles reacted with the active -NCO groups of tolylene diisocyanate (TDI) to form a surface complex. The TDI-modified TiO{sub 2} photocatalysts showed higher activity for the photocatalytic degradation of methylene blue under visible light irradiation.

  18. The Effect of Ramp Rate on the C49 to C54 Titanium Disilicide Phase Transformation from Ti and Ti(Ta)

    SciTech Connect (OSTI)

    BAILEY, GLENN A.; HU, YAO ZHI; SMITH, PAUL M.; TAY, SING PIN

    1999-09-22

    The C49 to C54 TiSi{sub 2} transformation temperature is shown to be reduced by increasing the ramp rate during rapid thermal processing and this effect is more pronounced for thinner initial Ti and Ti(Ta) films. Experiments were performed on blanket wafers and on wafers that had patterned polycrystalline Si lines with Si{sub 3}N{sub 4} sidewall spacers. Changing the ramp rate caused no change in the transformation temperature for 60 nm blanket Ti films. For blanket Ti films of 25 or 40 nm, however, increasing the ramp rate from 7 to 180 C/s decreased the transformation temperature by 15 C. Studies of patterned lines indicate that sheet resistance of narrow lines is reduced by increased ramp rates for both Ti and Ti(Ta) films, especially as the linewidths decrease below 0.4 {micro}m. This improvement is particularly pronounced for the thinnest Ti(Ta) films, which exhibited almost no linewidth effect after being annealed with a ramp rate of 75 C/s.

  19. Ti{sub 5}O{sub 5} superstructures of cubic titanium monoxide

    SciTech Connect (OSTI)

    Gusev, A. I.

    2013-08-15

    A cubic model is proposed for the Ti{sub 5}O{sub 5} (Ti{sub 5} Black-Small-Square O{sub 5}{open_square} {identical_to} Ti{sub 90} Black-Small-Square {sub 18}O{sub 90}{open_square}{sub 18}) superstructure of nonstoichiometric titanium monoxide Ti{sub x}O{sub z} with double imperfection. The unit cell of the cubic Ti{sub 5}O{sub 5} superstructure has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of Ti{sub x}O{sub z} monoxide and belongs to space group Pm 3-bar m . The channel of the disorder-order transition, i.e., Ti{sub x}O{sub z} (space group Fm 3-bar m)-Ti{sub 5}O{sub 5} (space group Pm 3-bar m), includes 75 superstructure vectors of seven stars (k{sub 10}), (k{sub 7}), (k{sub 6(1)}), (k{sub 6(2)}), (k{sub 4(1)}), (k{sub 4(2)}), and (k{sub 1}). The distribution functions of Ti and O atoms over the sites of the cubic Ti{sub 5}O{sub 5} superstructure are calculated. A comparison of the X-ray and electron diffraction data obtained for ordered TiO{sub 1.087} monoxide with the theoretical simulation results supports the existence of the cubic Ti{sub 5}O{sub 5} superstructure. The cubic (space group Pm 3-bar m) Ti{sub 5}O{sub 5} superstructure is shown to be a high-temperature structure relative to the well-known monoclinic (space group C2/m) superstructure of the same type.

  20. Effect of neutron irradiation on defect evolution in Ti3SiC2 and Ti2AlC

    SciTech Connect (OSTI)

    Tallman, Darin J.; He, Lingfeng; Garcia-Diaz, Brenda L.; Hoffman, Elizabeth N.; Kohse, Gordon; Sindelar, Robert L.; Barsoum, Michel W.

    2015-10-23

    Here, we report on the characterization of defects formed in polycrystalline Ti3SiC2 and Ti2AlC samples exposed to neutron irradiation – up to 0.1 displacements per atom (dpa) at 350 ± 40 °C or 695 ± 25 °C, and up to 0.4 dpa at 350 ± 40 °C. Black spots are observed in both Ti3SiC2 and Ti2AlC after irradiation to both 0.1 and 0.4 dpa at 350 °C. After irradiation to 0.1 dpa at 695 °C, small basal dislocation loops, with a Burgers vector of b = 1/2 [0001] are observed in both materials. At 9 ± 3 and 10 ± 5 nm, the loop diameters in the Ti3SiC2 and Ti2AlC samples, respectively, were comparable. At 1 × 1023 loops/m3, the dislocation loop density in Ti2AlC was ≈1.5 orders of magnitude greater than in Ti3SiC2, at 3 x 1021 loops/m3. After irradiation at 350 °C, extensive microcracking was observed in Ti2AlC, but not in Ti3SiC2. The room temperature electrical resistivities increased as a function of neutron dose for all samples tested, and appear to saturate in the case of Ti3SiC2. The MAX phases are unequivocally more neutron radiation tolerant than the impurity phases TiC and Al2O3. Based on these results, Ti3SiC2 appears to be a more promising MAX phase candidate for high temperature nuclear applications than Ti2AlC.

  1. Characterization of irradiation damage distribution near TiO{sub 2}/SrTiO{sub 3} interfaces using coherent acoustic phonon interferometry

    SciTech Connect (OSTI)

    Yarotski, Dmitry; Yan Li; Jia Quanxi; Taylor, Antoinette J.; Fu Engang; Wang Yongqiang; Uberuaga, Blas P.

    2012-06-18

    We apply ultrafast coherent acoustic phonon interferometry to characterize the distribution of the radiation damage near the TiO{sub 2}/SrTiO{sub 3} interfaces. We show that the optical and mechanical properties of anatase TiO{sub 2} remain unaffected by the radiation dosages in the 0.1 Division-Sign 5 dpa (displacements per atom) range, while the degraded optical response indicates a significant defect accumulation in the interfacial region of SrTiO{sub 3} at 0.1 dpa and subsequent amorphization at 3 dpa. Comparison between the theoretical simulations and the experimental results reveals an almost threefold reduction of the sound velocity in the irradiated SrTiO{sub 3} layer with peak damage levels of 3 and 5 dpa.

  2. Reactions of hydrogen with V-Cr-Ti alloys

    SciTech Connect (OSTI)

    DiStefano, J.R.; DeVan, J.H.; Chitwood, L.D.; Roehrig, D.H.

    1998-09-01

    In the absence of increases in oxygen concentration, additions of up to 400 ppm hydrogen to V-4 Cr-4 Ti did not result in significant embrittlement as determined by room temperature tensile tests. However, when hydrogen approached 700 ppm after exposure at 325 C, rapid embrittlement occurred. In this latter case, hydride formation is the presumed embrittlement cause. When oxygen was added during or prior to hydrogen exposure, synergistic effects led to significant embrittlement by 100 ppm hydrogen.

  3. LaTiO₃/KTaO₃ interfaces: A new two-dimensional electron gas system

    SciTech Connect (OSTI)

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO₃, and a band insulator, KTaO₃. For LaTiO₃/KTaO₃ interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO₃-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO₃ at room temperature. By using KTaO₃, we achieve mobilities in LaTiO₃/KTaO₃ interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO₃. By density functional theory, we attribute the higher mobility in KTaO₃ 2DEGs to the smaller effective mass for electrons in KTaO₃.

  4. LaTiO₃/KTaO₃ interfaces: A new two-dimensional electron gas system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO₃, and a band insulator, KTaO₃. For LaTiO₃/KTaO₃ interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO₃-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO₃ at room temperature. By using KTaO₃, we achieve mobilities in LaTiO₃/KTaO₃ interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO₃. By density functional theory, we attribute the higher mobilitymore » in KTaO₃ 2DEGs to the smaller effective mass for electrons in KTaO₃.« less

  5. Laser cladding of Ti-6Al-4V with various carbide powders

    SciTech Connect (OSTI)

    Folkes, J.A.; Shibata, K. )

    1994-06-01

    Laser cladding Ti-6Al-4V can be achieved with various weight percentages of different carbide powders. The microstructure and morphology of the clad layer is determined by the cladding powder composition, for a given set of laser parameters, such that 10 and 20 wt% Cr[sub 3]C[sub 2] results in a [beta] + TiC clad microstructure; 10 and 20 wt% WC results in an [alpha] + TiC clad microstructure (plus some original WC); and Mo[sub 2]C gives an [alpha] + [beta] + TiC or [beta] + TiC structure, depending on the weight percentage of Mo[sub 2]C. The morphology of the TiC in all cases is dendritic or feathery, depending on the carbide content. The microstructure observed in all cases agreed well with that theoretically predicted from the energetics of carbide formation and [beta]-stabilizing properties of each element.

  6. Heterojunction band offsets and dipole formation at BaTiO{sub 3}/SrTiO{sub 3} interfaces

    SciTech Connect (OSTI)

    Balaz, Snjezana; Zeng, Zhaoquan; Brillson, Leonard J.; Department of Physics, The Ohio State University, 191 West Woodruff, Columbus, Ohio 43210

    2013-11-14

    We used a complement of photoemission and cathodoluminescence techniques to measure formation of the BaTiO{sub 3} (BTO) on SrTiO{sub 3} (STO) heterojunction band offset grown monolayer by monolayer by molecular beam epitaxy. X-ray photoemission spectroscopy (XPS) provided core level and valence band edge energies to monitor the valence band offset in-situ as the first few crystalline BTO monolayers formed on the STO substrate. Ultraviolet photoemission spectroscopy (UPS) measured Fermi level positions within the band gap, work functions, and ionization potentials of the growing BTO film. Depth-resolved cathodoluminescence spectroscopy measured energies and densities of interface states at the buried heterojunction. Kraut-based XPS heterojunction band offsets provided evidence for STO/BTO heterojunction linearity, i.e., commutativity and transitivity. In contrast, UPS and XPS revealed a large dipole associated either with local charge transfer or strain-induced polarization within the BTO epilayer.

  7. Anisotropic swelling and microcracking of neutron irradiated Ti3AlC2-Ti5Al2C3 materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ang, Caen K.; Silva, Chinthaka M.; Shih, Chunghao Phillip; Koyanagi, Takaaki; Katoh, Yutai; Zinkle, Steven J.

    2015-12-17

    Mn + 1AXn (MAX) phase materials based on Ti–Al–C have been irradiated at 400 °C (673 K) with fission neutrons to a fluence of 2 × 1025 n/m2 (E > 0.1 MeV), corresponding to ~ 2 displacements per atom (dpa). We report preliminary results of microcracking in the Al-containing MAX phase, which contained the phases Ti3AlC2 and Ti5Al2C3. Equibiaxial ring-on-ring tests of irradiated coupons showed that samples retained 10% of pre-irradiated strength. Volumetric swelling of up to 4% was observed. Phase analysis and microscopy suggest that anisotropic lattice parameter swelling caused microcracking. Lastly, variants of titanium aluminum carbide may bemore » unsuitable materials for irradiation at light water reactor-relevant temperatures.« less

  8. Effect Of The Plasma Deposition Parameters On The Properties Of Ti/TiN Multilayers For Hard Coatings Applications

    SciTech Connect (OSTI)

    Saoula, N.; Henda, K.; Kesri, R.

    2008-09-23

    In this study, we present the effect of the plasma deposition parameters on the mechanical properties of Ti/TiN multilayers. The elaboration of our films has been carried out by RF-Magnetron Sputtering (13.56 MHz) under nitrogen and argon reactive plasma at low pressure. The film depositions have been done on steel substrates. The first step of our study was the optimization of the depositions conditions in order to obtain good quality films. The amount of nitrogen in the sputtering gases being fixed at 10%. The total pressure was set between 2mTorr to 10mTorr. The deposited multilayers were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), atomic force microscopy (AFM) and micro-indentation.

  9. Spin and orbital Ti magnetism at LaMnO3/SrTiO3 interfaces

    SciTech Connect (OSTI)

    Garcial-Barriocanal, J; Cezar, J. C.; Bruno, F. Y.; Thakur, P.; Brookes, N. B.; Utfeld, C.; Riviera-Calzada, A.; Giblin, S. R.; Taylor, J. W.; Duffy, J. A.; Dugdale, S. B.; Nakamura, T.; Kodama, K.; Leon, C.; Okamoto, Satoshi; Santamaria, J.

    2010-01-01

    In systems with strong electron-lattice coupling, such as manganites, orbital degeneracy is lifted, what causes a null expectation value of the orbital moment. Magnetic structure is thus determined by spin-spin superexchange. In titanates, however, with much smaller Jahn-Teller distortions, orbital degeneracy might allow non-zero values of the orbital magnetic moment. Accordingly, novel forms of ferromagnetic superexchange interaction unique to t2g electrons systems have been theoretically predicted, although their experimental observation has remained elusive. Here we report a new kind of Ti3+ ferromagnetism at LaMnO3/SrTiO3 epitaxial interfaces. It results from charge transfer to the empty conduction band of the titanate and has spin and orbital contributions evidencing the role played by orbital degeneracy. The possibility of tuning magnetic alignment (ferromagnetic or antiferromagnetic) of Ti and Mn moments by structural parameters is demonstrated. This result will provide important clues for the understanding of the effects of orbital degeneracy in superexchange coupling.

  10. Synthesis of Highly Ordered TiO2 Nanotubes Using Ionic Liquids for Photovoltaics Applications

    SciTech Connect (OSTI)

    2009-04-01

    This factsheet describes a study that deals with a new, green approach of synthesizing highly ordered TiO2 nanotubes using ionic liquids for photovoltaics (PV) applications.

  11. A nano lamella NbTi–NiTi composite with high strength

    SciTech Connect (OSTI)

    Jiang, Jiang; Jiang, Daqiang; Hao, Shijie; Yu, Cun; Zhang, Junsong; Ren, Yang; Lu, Deping; Xie, Shifang; Cui, Lishan

    2015-05-01

    A hypereutectic Nb60Ti24Ni16 (at%) alloy was prepared by vacuum induction melting, and a nano lamellae NbTi-NiTi composite was obtained by hot-forging and wire-drawing of the ingot Microscopic analysis showed that NbTi and NiTi nano lamellae distributed alternatively in the composite, and aligned along the wire axial direction, with a high volume fraction (similar to 70%) of NbTi nano lamellae. In situ synchrotron X-ray diffraction analysis revealed that stress induced martensitic transformation occurred upon loading, which would effectively weaken the stress concentration at the interface and avoid the introduction of defects into the nano reinforced phase. Then the embedded NbTi nano lamellae exhibited a high elastic strain up to 2.72%, 1.5 times as high as that of the Nb nanowires embedded in a conventional plastic matrix, and the corresponding stress carried by NbTi was evaluated as 2.53 GPa. The high volume fraction of NbTi nano lamellae improved the translation of high strength from the nano reinforced phase into bulk properties of the composite, with a platform stress of similar to 1.7 GPa and a fracture strength of similar to 1.9 GPa. (C) 2015 Elsevier B.V. All rights reserved.

  12. QUANTIFYING COMPOSITIONAL HOMOGENEITY IN Pb(ZrTi)O3 USING ATOM...

    Office of Scientific and Technical Information (OSTI)

    Title: QUANTIFYING COMPOSITIONAL HOMOGENEITY IN Pb(ZrTi)O3 USING ATOM PROBE TOMOGRAPHY. Abstract not provided. Authors: Ihlefeld, Jon F. ; Kotula, Paul Gabriel ; Brennecka, ...

  13. Self-assembled Ni/TiO{sub 2} nanocomposite anodes synthesized...

    Office of Scientific and Technical Information (OSTI)

    Ni(core)TiOsub 2(shell) nanocomposite anodes were fabricated on three-dimensional, self-assembled nanotemplates of Tobacco mosaic virus using atomic layer deposition, exhibiting ...

  14. Large oriented arrays and continuous films of TiO2 based nanotubes.

    SciTech Connect (OSTI)

    Xu, Huifang; Liu, Jun; Voigt, James A.; Tian, Zhengrong Ryan; McKenzie, Bonnie Beth

    2003-08-01

    We report for the first time a one-step, templateless method to directly prepare large arrays of oriented TiO{sub 2}-based nanotubes and continuous films. These titania nanostructures can also be easily prepared as conformal coatings on a substrate. The nanostructured films were formed on a Ti substrate seeded with TiO{sub 2} nanoparticles. SEM and TEM results suggested that a folding mechanism of sheetlike structures was involved in the formation of the nanotubes. The oriented arrays of TiO{sub 2} nanotubes, continuous films, and coatings are expected to have potentials for applications in catalysis, filtration, sensing, photovoltaic cells, and high surface area electrodes.

  15. Impact of symmetry on the ferroelectric properties of CaTiO3...

    Office of Scientific and Technical Information (OSTI)

    properties of CaTiO3 thin films Citation Details ... Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA Department of Materials Science ...

  16. Mechanisms of Oriented Attachment of TiO2 Nanocrystals in Vacuum...

    Office of Scientific and Technical Information (OSTI)

    Mechanisms of Oriented Attachment of TiO2 Nanocrystals in Vacuum and Humid Environments: Reactive Molecular Dynamics Citation Details In-Document Search Title: Mechanisms of ...

  17. Epitaxial Cr on n-SrTiO3(001)An ideal Ohmic contact

    SciTech Connect (OSTI)

    Capan, Cigdem; Sun, Guangyuan; Bowden, Mark E.; Chambers, Scott A.

    2012-01-30

    Epitaxial Cr metallizations grown on n-SrTiO3(001) by molecular beam epitaxy are shown to result in an ordered interface with Cr bound to O in the terminal TiO2 layer, no reduction of the SrTiO3, and a near-perfect Ohmic contact. Cr/n-SrTiO3(001) thus constitutes an ideal interface between a pure metal and wide gap oxide in which interface redox chemistry does not occur, and the Fermi level remains unpinned.

  18. Epitaxial Cr on n-SrTiO{sub 3}(001) - An ideal Ohmic contact

    SciTech Connect (OSTI)

    Capan, C.; Sun, G. Y.; Bowden, M. E.; Chambers, S. A.

    2012-01-30

    Epitaxial Cr metallizations grown on n-SrTiO{sub 3}(001) by molecular beam epitaxy are shown to result in an ordered interface with Cr bound to O in the terminal TiO{sub 2} layer, no reduction of the SrTiO{sub 3}, and a near-perfect Ohmic contact. Cr/n-SrTiO{sub 3}(001) thus constitutes an ideal interface between a pure metal and wide gap oxide in which interface redox chemistry does not occur, and the Fermi level remains unpinned.

  19. Investigation of carbon-coated lithiated Li{sub 4+x}Ti{sub 5...

    Office of Scientific and Technical Information (OSTI)

    and capacity retention. * TiOsub 2 nanoparticles and carbon coating are necessary for ... LITHIUM OXIDES; LITHIUM TITANATES; NANOPARTICLES; NANOSTRUCTURES; STABILITY; SYNTHESIS; ...

  20. Features of a priori heavy doping of the n-TiNiSn intermetallic semiconductor

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Romaka, V. V.; Hlil, E. K.; Stadnyk, Yu. V.; Budgerak, S. M.

    2011-07-15

    The crystal structure, the distribution of electron density, and the energy, kinetic, and magnetic properties of the n-TiNiSn intermetallic semiconductor are investigated. It is shown that a priori doping of n-TiNiSn with donors originates from partial, up to 0.5 at %, redistribution of Ti and Ni atoms in crystallographic sites of Ti atoms. The correlation is established between the donor concentration, amplitude of modulation of the continuous energy bands, and degree of filling of low-scale fluctuation potential wells with charge carriers. The results obtained are discussed within the Shklovskii-Efros model of a heavily doped and compensated semiconductor.

  1. In situ investigation of the early stage of TiO{sub 2} epitaxy on (001) SrTiO{sub 3}

    SciTech Connect (OSTI)

    Radovic, M.; Salluzzo, M.; Vaglio, R.; Granozio, F. Miletto; Ristic, Z.; Di Capua, R.; Lampis, N.

    2011-07-21

    We report on a systematic study of the growth of epitaxial TiO{sub 2} films deposited by pulsed laser deposition on Ti-terminated SrTiO{sub 3} (001) single crystals. By using in situ reflection high energy electron diffraction, low energy electron diffraction, x-ray photoemission spectroscopy, and scanning probe microscopy, we show that the stabilization of the anatase (001) phase is preceded by the growth of a few nanometers thick pseudomorphic Sr{sub x}TiO{sub 2+y} (x, y < 1) intermediate layer. The data demonstrate that the formation of this intermediate phase is related to the activation of a long range Sr migration from the SrTiO{sub 3} substrate into the film. Our results enrich the phase diagram of the Sr-Ti-O system under epitaxial strain opening a route for the study of the electronic and dielectric properties of the reported Sr-deficient SrTiO{sub 3} phase.

  2. Differences in chemical doping matter: Superconductivity in Ti1-xTaxSe2 but not in Ti1-xNbxSe2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Huixia; Zhu, Yimei; Xie, Weiwei; Tao, Jing; Pletikosic, Ivo; Valla, Tonica; Sahasrabudhe, Girija S.; Osterhoudt, Gavin; Sutton, Eric; Burch, Kenneth S.; et al

    2016-02-21

    We report that 1T-TiSe2, an archetypical layered transition metal dichalcogenide, becomes superconducting when Ta is substituted for Ti but not when Nb is substituted for Ti. This is unexpected because Nb and Ta should be chemically equivalent electron donors. Superconductivity emerges near x = 0.02 for Ti1–xTaxSe2, while, for Ti1–xNbxSe2, no superconducting transitions are observed above 0.4 K. The equivalent chemical nature of the dopants is confirmed by X-ray photoelectron spectroscopy. ARPES and Raman scattering studies show similarities and differences between the two systems, but the fundamental reasons why the Nb and Ta dopants yield such different behavior are unknown.more » We present a comparison of the electronic phase diagrams of many electron-doped 1T-TiSe2 systems, showing that they behave quite differently, which may have broad implications in the search for new superconductors. Here, we propose that superconducting Ti0.8Ta0.2Se2 will be suitable for devices and other studies based on exfoliated crystal flakes.« less

  3. The role of double TiO2 layers at the interface of FeSe/SrTiO3 superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zou, Ke; Bozovic, Ian; Mandal, Subhasish; Albright, Stephen; Peng, Rui; Kumah, Divine; Simon, Georg; Dagdeviren, Omur; He, Xi; Schwarz, Udo; et al

    2016-05-16

    Here, we determine the surface reconstruction of SrTiO3 used to achieve superconducting FeSe films in experiments, which is different from the 1×1 TiO2-terminated SrTiO3 assumed by most previous theoretical studies. In particular, we identify the existence of a double TiO2 layer at the FeSe/SrTiO3 interface that plays two important roles. First, it facilitates the epitaxial growth of FeSe. Second, ab initio calculations reveal a strong tendency for electrons to transfer from an oxygen deficient SrTiO3 surface to FeSe when the double TiO2 layer is present. The double layer helps to remove the hole pocket in the FeSe at the Γmore » point of the Brillouin zone and leads to a band structure characteristic of superconducting samples. The characterization of the interface structure presented here is a key step towards the resolution of many open questions about this superconductor.« less

  4. A novel 3D structure composed of strings of hierarchical TiO{sub 2} spheres formed on TiO{sub 2} nanobelts with high photocatalytic properties

    SciTech Connect (OSTI)

    Jiang, Yongjian; Li, Meicheng; Song, Dandan; Li, Xiaodan; Yu, Yue

    2014-03-15

    A novel hierarchical titanium dioxide (TiO{sub 2}) composite nanostructure with strings of anatase TiO{sub 2} hierarchical micro-spheres and rutile nanobelts framework (TiO{sub 2} HSN) is successfully synthesized via a one-step hydrothermal method. Particularly, the strings of hierarchical spheres are assembled by very thin TiO{sub 2} nanosheets, which are composed of highly crystallized anatase nanocrystals. Meanwhile, the HSN has a large surface area of 191 m{sup 2}/g, which is about 3 times larger than Degussa P25. More importantly, the photocatalytic activity of HSN and P25 were evaluated by the photocatalytic oxidation decomposition of methyl orange (MO) under UV light illumination, and the TiO{sub 2} HSN shows enhanced photocatalytic activity compared with Degussa P25, as result of its continuous hierarchical structures, special conductive channel and large specific surface area. With these features, the hierarchical TiO{sub 2} may have more potential applications in the fields of dye-sensitized solar cells and lithium ion batteries. -- Graphical abstract: Novel TiO{sub 2} with anatase micro-spheres and rutile nanobelts is synthesized. Enhanced photocatalysis is attributed to hierarchical structures (3D spheres), conductive channel (1D nanobelts) and large specific surface area (2D nanosheet). Highlights: • The novel TiO{sub 2} nanostructure (HSN) is fabricated for the first time. • HSN is composed of strings of anatase hierarchical spheres and rutile nanobelt. • HSN presents a larger S{sub BET} of 191 m{sup 2}/g, 3 times larger than the Degussa P25 (59 m{sup 2}/g). • HSN owns three kinds of dimensional TiO{sub 2} (1D, 2D and 3D) simultaneously. • HSN exhibits better photocatalytic performance compared with Degussa P25.

  5. Solar photocatalytic activities of porous Nb-doped TiO{sub 2} microspheres by coupling with tungsten oxide

    SciTech Connect (OSTI)

    Kou, Yanqiang; Yang, Jikai; Li, Bing; Fu, Shencheng

    2015-03-15

    Highlights: Nb-TiO{sub 2}/WO{sub 3} was prepared by USP method combined impregnation method. Nb-doping extend the spectral absorption of TiO{sub 2} into visible spectrum. Nb-TiO{sub 2}/WO{sub 3} has a similar optical band gap as Nb-TiO{sub 2}. PL spectra indicate WO{sub 3} can accept the photoexcited electrons from Nb-TiO{sub 2}. Nb-TiO{sub 2}/WO{sub 3} shows higher activity than TiO{sub 2} and Nb-TiO{sub 2} under solar light. - Abstract: Nb doped TiO{sub 2} microspheres modified with WO{sub 3} (Nb-TiO{sub 2}/WO{sub 3}) was prepared by ultrasonic spray pyrolysis method combined with impregnation method. The microspheres were characterized with SEM, TEM, XRD, BET, photoluminescence and UVvis absorption spectra. The Nb-doping was observed to extend the spectral absorption of TiO{sub 2} into visible spectrum, and the absorption onset was red-shifted for about 88 nm compared to pristine TiO{sub 2} microspheres. Nb-TiO{sub 2}/WO{sub 3} microspheres do not display a red-shifted absorption edge compared with Nb doped TiO{sub 2} microspheres. Under solar irradiation, Nb-TiO{sub 2}/WO{sub 3} microspheres showed higher photocatalytic activity for methylene blue degradation compared with that of pure TiO{sub 2} microspheres and Nb doped TiO{sub 2} microspheres, which could be ascribed to the extended light absorption range and the suppression of electron-hole pair recombination.

  6. Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl: A rare example of Ti(IV) in a square pyramidal oxygen coordination

    SciTech Connect (OSTI)

    Batuk, Maria; Batuk, Dmitry; Abakumov, Artem M.; Hadermann, Joke

    2014-07-01

    A new oxychloride Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl has been synthesized using the solid state method. Its crystal and magnetic structure was investigated in the 1.5550 K temperature range using electron diffraction, high angle annular dark field scanning transmission electron microscopy, atomic resolution energy dispersive X-ray spectroscopy, neutron and X-ray powder diffraction. At room temperature Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl crystallizes in the P4/mmm space group with the unit cell parameters a=3.91803(3) and c=19.3345(2) . Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl is a new n=4 member of the oxychloride perovskite-based homologous series A{sub n+1}B{sub n}O{sub 3n?1}Cl. The structure is built of truncated Pb{sub 3}Fe{sub 3}TiO{sub 11} quadruple perovskite blocks separated by CsCl-type Pb{sub 2}Cl slabs. The perovskite blocks consist of two layers of (Fe,Ti)O{sub 6} octahedra sandwiched between two layers of (Fe,Ti)O{sub 5} square pyramids. The Ti{sup 4+} cations are preferentially located in the octahedral layers, however, the presence of a noticeable amount of Ti{sup 4+} in a five-fold coordination environment has been undoubtedly proven using neutron powder diffraction and atomic resolution compositional mapping. Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl is antiferromagnetically ordered below 450(10) K. The ordered Fe magnetic moments at 1.5 K are 4.06(4) ?{sub B} and 3.86(5) ?{sub B} on the octahedral and square-pyramidal sites, respectively. - Highlights: Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl has been synthesized using the solid state method. The structure has been refined using neutron powder diffraction data at 1.5550 K. It is a new n=4 member of the perovskite-related homologous series A{sub n+1}B{sub n}O{sub 3n?1}Cl. Ti{sup 4+} cations have both octahedral and square-pyramidal coordination environment. Pb{sub 5}Fe{sub 3}TiO{sub 11}Cl is antiferromagnetically ordered below T{sub N}?450 K.

  7. Structural and spectroscopic properties of high temperature prepared ZrO₂–TiO₂ mixed oxides

    SciTech Connect (OSTI)

    Gionco, Chiara; Battiato, Alfio; Vittone, Ettore; Paganini, Maria Cristina; Giamello, Elio

    2013-05-01

    ZrO₂-TiO₂ mixed oxides of various composition, with the molar fraction of TiO₂ ranging from 0.1% to 15%, have been prepared via sol-gel synthesis and then calcined at 1273 K to check both their thermal stability and physicochemical properties. These solids are usually employed in photocatalytic processes and as active phase supports in heterogeneous catalysis. As indicated by X-ray diffraction and Raman spectroscopy, solid solutions based on Ti ions diluted in the ZrO₂ matrix are formed in the whole range of Ti molar fraction examined. Materials with low Ti loading (0.1%–1%) are basically constituted by the monoclinic phase of ZrO₂ while the tetragonal phase becomes prevalent at 15% of TiO₂ molar fraction. The presence of Ti ions modify the electronic structure of the solid as revealed by investigation of the optical properties. The typical band gap transition of ZrO₂ undergoes, in fact, a red shift roughly proportional to the Ti loading which reach the remarkable value of 1.6 eV for the sample with 10% of molar Ti concentration. Comparing chemical analysis of the solids with XPS data it has been put into evidence that the titanium ions distribution into the solid is not uniform and the concentration of Ti⁴⁺ tend to be higher in subsurface layers than in the crystal bulk. The introduction of titanium ions in the structure increases the reducibility of the solid. Annealing under vacuum at various temperatures causes oxygen depletion with consequent reduction of the solid which shows up mainly in terms of formation of Ti³⁺ reduced centres which are characterized by a typical EPR signal. Ti³⁺ defects forms, as also forecast by theoretical modelling of the solid, as their energy is lower than that of other possible reduced defective centers. The reduced solids are able to transfer electrons to adsorbed oxygen molecules in mild condition resulting in the formation of surface superoxide anions (O₂⁻) which are stabilized on surface Zr

  8. Effect of different processes and Ti/Zn molar ratios on the structure, morphology, and enhanced photoelectrochemical and photocatalytic performance of Ti3+ self-doped titanium–zinc hybrid oxides

    SciTech Connect (OSTI)

    Fu, Rongrong; Wang, Qingyao; Gao, shanmin; Wang, Zeyan; Huang, Baibiao; Dai, Ying; Lu, Jun

    2015-07-01

    Ti3+ self-doped titanium–zinc hybrid oxides with different phase compositions and morphologies were successfully synthesized using Zn powder as the reductant and Zn source by a chemical-reduction precipitation method with subsequent thermal treatment. The fabricated Ti3+ self-doped TiO2(A)/TiO2(R), TiO2(A)/TiO2(R)/ZnTiO3, and TiO2(A)/ZnO heterojunctions were characterized by X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and UV–Vis diffuse reflectance spectroscopy. The effects of various Ti/Zn molar ratios and preparation processes on the structural, morphological, optical, photocurrent and photocatalytic properties of the resultant samples were investigated systematically. Results reveal that Ti3+ self-doping enhances the photoabsorption capability of titanium–zinc hybrid oxides in the visible-light region. Moreover, different processes and Ti/Zn molar ratios play great influences on the structure, morphology, optical, photocurrent and photocatalytic properties of the final products. Ti3+ self-doped titanium–zinc hybrid oxides exhibit excellent photocurrent and photocatalytic activity than pure TiO2 and ZnTiO3 under visible-light irradiation (λ ≥ 400 nm). The most active Ti3+ self-doped titanium–zinc hybrid oxides photoanode presents significantly improved water splitting performance. The synergistic effect between the Ti3+ self-doped and heterojunctions is responsible for the enhanced performance of these materials.

  9. Epitaxial single-crystal thin films of MnxTi1-xO2-δ grown on...

    Office of Scientific and Technical Information (OSTI)

    on (rutile)TiO2 substrates with pulsed laser deposition: Experiment and theory Citation ... on (rutile)TiO2 substrates with pulsed laser deposition: Experiment and theory ...

  10. Visible light photocatalytic degradation of 4-chlorophenol using vanadium and nitrogen co-doped TiO{sub 2}

    SciTech Connect (OSTI)

    Jaiswal, R.; Kothari, D. C.; Patel, N.; Miotello, A.

    2013-02-05

    Vanadium and Nitrogen were codoped in TiO{sub 2} photocatalyst by Sol-gel method to utilize visible light more efficiently for photocatalytic reactions. A noticeable shift of absorption edge to visible light region was obtained for the singly-doped namely V-TiO{sub 2}, N-TiO{sub 2} and codoped V-N-TiO{sub 2} samples in comparison with undoped TiO{sub 2}, with smallest band gap obtained with codoped-TiO{sub 2}. The photocatalytic activities for all TiO{sub 2} photocatalysts were tested by 4-chlorophenol (organic pollutant) degradation under visible light irradiation. It was found that codoped TiO{sub 2} exhibits the best photocatalytic activity, which could be attributed to the synergistic effect produced by V and N dopants.

  11. High temperature tensile properties of V-4Cr-4Ti

    SciTech Connect (OSTI)

    Zinkle, S.J.; Rowcliffe, A.F.; Stevens, C.O.

    1998-09-01

    Tensile tests have been performed on V-4Cr-4Ti at 750 and 800 C in order to extend the data base beyond the current limit of 700 C. From comparison with previous measurements, the yield strength is nearly constant and tensile elongations decrease slightly with increasing temperature between 300 and 800 C. The ultimate strength exhibits an apparent maximum near 600 C (attributable to dynamic strain aging) but adequate strength is maintained up to 800 C. The reduction in area measured on tensile specimens remained high ({approximately}80%) for test temperatures up to 800 C, in contrast to previous reported results.

  12. Stable atomic structure of NiTi austenite

    SciTech Connect (OSTI)

    Zarkevich, Nikolai A; Johnson, Duane D

    2014-08-01

    Nitinol (NiTi), the most widely used shape-memory alloy, exhibits an austenite phase that has yet to be identified. The usually assumed austenitic structure is cubic B2, which has imaginary phonon modes, hence it is unstable. We suggest a stable austenitic structure that on average has B2 symmetry (observed by x-ray and neutron diffraction), but it exhibits finite atomic displacements from the ideal B2 sites. The proposed structure has a phonon spectrum that agrees with that from neutron scattering, has diffraction spectra in agreement with x-ray diffraction, and has an energy relative to the ground state that agrees with calorimetry data.

  13. Injection mode-locking Ti-sapphire laser system

    DOE Patents [OSTI]

    Hovater, James Curtis; Poelker, Bernard Matthew

    2002-01-01

    According to the present invention there is provided an injection modelocking Ti-sapphire laser system that produces a unidirectional laser oscillation through the application of a ring cavity laser that incorporates no intracavity devices to achieve unidirectional oscillation. An argon-ion or doubled Nd:YVO.sub.4 laser preferably serves as the pump laser and a gain-switched diode laser serves as the seed laser. A method for operating such a laser system to produce a unidirectional oscillating is also described.

  14. HNF-SD-WM-TI-740, Rev. OA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    84045. HNF-SD-WM-TI-740, Rev. OA Standard Inventories of Chemicals and Radionuclides in Hanford Site Ta nk Wastes M. J. Kupfer, A. L. Boldt, B. A. Higley, K. M. Hodgson, L. W. Shelton, B. C. Simpson, and R. A. Watrous (LMHC); M. 0. LeClair (SAIC); G. 1. Borsheim (BA); R. T. Winward (MA); R. M. Orme (NHC); N. 6. Colton (PNNL); S. 1. Lambert and D. E. Place (SESC); and W. W. SchulZ (W 2 S) Lockheed Martin Hanford Corporation, Richland, WA 99352 U.S. Department of Energy Contract DE-AC06-96RL13200

  15. HNF-SD-WM-TI-740, Rev. OC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    84047 HNF-SD-WM-TI-740, Rev. OC Standard Inventories of Chemicals and Radionuclides in Hanford Site Tank Wastes M. J. Kupfer, A. L. Boldt, K. N. Hodgson, L. W. Shelton, B. C. Simpson, and R. A. Watrous (LMHC); M. D. LeClair (SAIC); G. 1. Borsheim (BA); R. T. Winward (MA); B. A. Higley and R. M. Orme (NHC); N. G. Colton (PNNL); S. L. Lambert and D. E. Place (Cogema); and W. W. Schulz (112S) Lockheed Martin Hanford Corporation, Richland, WA 99352 U.S. Department of Energy Contract

  16. Ferroelectric-like response from the surface of SrTiO₃ crystals at high temperatures

    SciTech Connect (OSTI)

    Jyotsna, Shubhra; Arora, Ashima; Sekhon, Jagmeet S.; Sheet, Goutam

    2014-09-14

    Since SrTiO₃ has a high dielectric constant, it is used as a substrate for a large number of complex physical systems for electrical characterization. Since SrTiO₃ crystals are known to be non-ferroelectric/non-piezoelectric at room temperature and above, SrTiO₃ has been believed to be a good choice as a substrate/base material for PFM (Piezoresponse Force Microscopy) on novel systems at room temperature. In this paper, from PFM-like measurement using an atomic force microscope on bare crystals of (110) SrTiO₃ we show that ferroelectric and piezoelectric-like response may originate from bare SrTiO₃ at remarkably high temperatures up to 420 K. Electrical domain writing and erasing are also possible using a scanning probe tip on the surface of SrTiO₃ crystals. This observation indicates that the role of the electrical response of SrTiO₃ needs to be revisited in the systems where signature of ferroelectricity/piezoelectricity has been previously observed with SrTiO₃ as a substrate/base material.

  17. An Experimental and Theoretical Multi-Mbar Study of Ti-6Al-4V

    SciTech Connect (OSTI)

    Tegner, B E; Macleod, S G; CYNN, H; Proctor, J; Evans, W J; McMahon, M I; Ackland, G J

    2011-04-13

    We report results from an experimental and theoretical study of the room temperature (RT) compression of the ternary alloy Ti-6Al-4V. In this work, we have extended knowledge of the equation of state (EOS) from 40 GPa to 221 GPa, and observed a different sequence of phase transitions to that reported previously for pure Ti.

  18. Preparation and properties of ce-doped TiO{sub 2} photocatalyst

    SciTech Connect (OSTI)

    Yan, Ningning; Zhu, Zhongqi; Zhang, Jin; Zhao, Zongyan; Liu, Qingju

    2012-08-15

    Highlights: ? The cerium ion doped TiO{sub 2} (Ce-TiO{sub 2}) powders were prepared and characterized. ? The spectrum absorption region of Ce-TiO{sub 2} is red-shifted to visible light. ? The recombination of photo-generated electron-hole pairs of Ce-TiO{sub 2} is inhibited. ? The photocatalytic activity was effected by Ce ion content and greatly improved. -- Abstract: TiO{sub 2} nanoparticles doped with different content of Ce ion were prepared by solgel method. The samples were characterized by XRD, XPS, TEM, UVVis, and PL, the photocatalytic activity was evaluated by photocatalytic degradation of methylene blue (MB) under the irradiation of fluorescent lamp. The results indicate that Ce ion is incorporated into the lattice of TiO{sub 2}, which can restrain the increase of grain size, broaden the absorption region to visible light, and inhibit the recombination of the photo-generated electron and hole pairs. Moreover, the photocatalytic activity of Ce-TiO{sub 2} in MB degradation is evidently enhanced. The MB degradation rate of the sample with Ce:Ti = 0.33% (molar ratio) in 8 h is 90.03%, which is much higher than that of P25 (68.19%).

  19. Structural properties of Ge on SrTiO{sub 3} (001) surface and Ge/SrTiO{sub 3} interface

    SciTech Connect (OSTI)

    Pu, Long; Wang, Jianli Tang, Gang; Zhang, Junting

    2015-03-14

    Germanium−perovskite oxide heterostructures have a strong potential for next-generation low-voltage and low-leakage metal-oxide semiconductor field-effect transistors. We investigated the atomic structure and electronic properties of Ge on perfect and defective (001) SrTiO{sub 3} by first-principle calculations. The specific adsorption sites at the initial growth stage and the atomic structure of Ge on the SrTiO{sub 3} (001) substrate have been systematically investigated. The surface grand potential was calculated and compared as a function of the relative chemical potential. The complete surface phase diagram was presented. The energetically favorable interfaces were pointed out among the atomic arrangements of the Ge/SrTiO{sub 3} (001) interfaces. The atomic structure and electronic properties of the intrinsic point defects were calculated and analyzed for the Ge/SrTiO{sub 3} (001) interfaces.

  20. Stoichiometric growth of SrTiO3 films by sequential pulsed laser deposition from SrO and TiO2 targets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herklotz, A; Dorr, Kathrin; Biegalski, Michael D

    2015-01-01

    We report the growth of stoichiometric SrTiO3 films by sequential pulsed laser deposition from SrO and TiO2 targets. In-situ reflection high-energy electron diffraction is used to control the growth and achieve films with excellent structural quality. The growth shows similarities to the case of molecular beam epitaxy of SrTiO3 from Sr and Ti sources. In order to further demonstrate the capability of the approach, we grow artificial Srn+1TinO3n+1 Ruddlesden-Popper phases with n = 2 and 3. Our result has potential to be extendable to other perovskite-type oxides, enabling one to grow epitaxial films with improved structural quality and electronic functionality.

  1. Enhanced hardness in epitaxial TiAlScN alloy thin films and rocksalt TiN/(Al,Sc)N superlattices

    SciTech Connect (OSTI)

    Saha, Bivas; Lawrence, Samantha K.; Bahr, David F.; Schroeder, Jeremy L.; Birch, Jens; Sands, Timothy D.

    2014-10-13

    High hardness TiAlN alloys for wear-resistant coatings exhibit limited lifetimes at elevated temperatures due to a cubic-AlN to hexagonal-AlN phase transformation that leads to decreasing hardness. We enhance the hardness (up to 46 GPa) and maximum operating temperature (up to 1050 °C) of TiAlN-based coatings by alloying with scandium nitride to form both an epitaxial TiAlScN alloy film and epitaxial rocksalt TiN/(Al,Sc)N superlattices on MgO substrates. The superlattice hardness increases with decreasing period thickness, which is understood by the Orowan bowing mechanism of the confined layer slip model. These results make them worthy of additional research for industrial coating applications.

  2. TiO{sub 2} nanorods branched on fast-synthesized large clearance TiO{sub 2} nanotube arrays for dye-sensitized solar cells

    SciTech Connect (OSTI)

    Hu Anzheng; Li Haina; Jia Zhiyong; Xia Zhengcai

    2011-11-15

    A large clearance TiO{sub 2} nanotube arrays (LTAs) has been synthesized by a not more than 12 h anodization duration and based on this a branched TiO{sub 2} nanotube arrays (BLTs) has been achieved through TiO{sub 2} nanorods branch-like grown on the LTAs. Some key factors and probable mechanisms of the fabrication processes on two novel nanoarchitectures are discussed. Exhilaratingly, it is found that the obtained LTAs has demonstrated large pore diameter and void spaces (pore diameter {approx}350 nm; void spaces {approx}160 nm; and tube length {approx}3.5 {mu}m), and the synthesized hierarchical BLTs, compared with conventional TiO{sub 2} nanotube arrays, has shown a much stronger dye absorption performance and an approximately double of the solar cell efficiency (in our case from 1.62% to 3.18% under simulated AM 1.5 conditions). - Graphical Abstract: The schematic diagram of synthesis process for LTAs and BLTs is on the above and the corresponding FESEM images of obtained photoanodes samples are shown below. Highlights: > Large clearance TiO{sub 2} nanotube arrays (LTAs) was synthesized by a fast anodization process of 12 h. > Anodization time of 12 h is just 10% of about 120 h reported in the previous references. > Branch-like TiO{sub 2} nanotube arrays (BLTs) was achieved by growing TiO{sub 2} nanorods on the LTAs. > Obtained BLTs and LTAs show impressive morphology and noticeable improvement of surface area. > BLTs shows about more than 1 times higher solar cell efficiency than that of TiO{sub 2} nanotube arrays.

  3. TiN/VN composites with core/shell structure for supercapacitors

    SciTech Connect (OSTI)

    Dong, Shanmu; Chen, Xiao; Gu, Lin; Zhou, Xinhong; Wang, Haibo; Liu, Zhihong; Han, Pengxian; Yao, Jianhua; Wang, Li; Cui, Guanglei; Chen, Liquan; Institute of Physics, Chinese Academy of Sciences, Beijing 100080

    2011-06-15

    Research highlights: {yields} Vanadium and titanium nitride nanocomposite with core-shell structure was prepared. {yields} TiN/VN composites with different V:Ti molar ratios were obtained. {yields} TiN/VN composites can provide promising electronic conductivity and favorable capacity storage. -- Abstract: TiN/VN core-shell composites are prepared by a two-step strategy involving coating of commercial TiN nanoparticles with V{sub 2}O{sub 5}.nH{sub 2}O sols followed by ammonia reduction. The highest specific capacitance of 170 F g{sup -1} is obtained when scanned at 2 mV s{sup -1} and a promising rate capacity performance is maintained at higher voltage sweep rates. These results indicate that these composites with good electronic conductivity can deliver a favorable capacity performance.

  4. Nanocrystalline BaTiO3 powder via ambient conditions sol process (Prop.2001-071)

    SciTech Connect (OSTI)

    Payzant, E Andrew; Wang, X.; Hu, Michael Z.; Blom, Douglas Allen

    2005-01-01

    Nanocrystalline BaTiO{sub 3} particles have been prepared by ambient condition sol (ACS) process starting from soluble precursors of barium and titanium yielding a mixed oxide/hydroxide gel. The gel was peptized and crystallized in water under a refluxing condition. Higher initial pH and Ba/Ti ratio led to smaller crystallite sizes of BaTiO{sub 3} powders. Organic mineralizer, tetramethylammonium hydroxide (TMAH), can adsorb on the BaTiO{sub 3} nuclei and inhibited further growth of the particles. Adding a polymer during BaTiO{sub 3} synthesis led to a smaller particle size and increased redispersibility of the particles in water.

  5. Active wear and failure mechanisms of TiN-coated high speed steel and TiN-coated cemented carbide tools when machining powder metallurgically made stainless steels

    SciTech Connect (OSTI)

    Jiang, L.; Haenninen, H.; Paro, J.; Kauppinen, V.

    1996-09-01

    In this study, active wear and failure mechanisms of both TiN-coated high speed steel and TiN-coated cemented carbide tools when machining stainless steels made by powder metallurgy in low and high cutting speed ranges, respectively, have been investigated. Abrasive wear mechanisms, fatigue-induced failure, and adhesive and diffusion wear mechanisms mainly affected the tool life of TiN-coated high speed steel tools at cutting speeds below 35 m/min, between 35 and 45 m/min, and over 45 m/min, respectively. Additionally, fatigue-induced failure was active at cutting speeds over 45 m/min in the low cutting speed range when machining powder metallurgically made duplex stainless steel 2205 and austenitic stainless steel 316L. In the high cutting speed range, from 100 to 250 m/min, fatigue-induced failure together with diffusion wear mechanism, affected the tool life of TiN-coated cemented carbide tools when machining both 316L and 2205 stainless steels. It was noticed that the tool life of TiN-coated high speed steel tools used in the low cutting speed range when machining 2205 steel was longer than that when machining 316L steel, whereas the tool life of TiN-coated cemented carbide tools used in the high cutting speed range when machining 316L steel was longer than that when machining 2205 steel.

  6. Structural Study And Optical Properties Of TiO{sub 2} Thin Films Elaborated By Thermal Oxidation Of RF Magnetron Sputtered Ti Films

    SciTech Connect (OSTI)

    Guitoume, D.; Achour, S.; Guittoum, A.; Abaidia, S. E. H.

    2008-09-23

    We report on the effect of thickness on the structural and optical properties of TiO{sub 2} thin films obtained by direct exposure of Ti metal film to thermal oxidation. Ti thin films with thicknesses ranging from 87 nm to 484 nm were deposited onto glass substrate by RF magnetron sputtering. Thereafter, the as-deposited Ti films were annealed in air at temperature equal to 520 deg. C. The structural evolution and optical properties of obtained TiO{sub 2} films were studied by means of Rutherford backscattering spectrometry (RBS), grazing incidence X-ray diffraction (GIXRD), scanning electron microscopy (SEM) and UV-Visible spectroscopy. The films thicknesses were extracted from RBS spectra. From X-ray diffraction spectra, we can see that all the films present three TiO{sub 2} phases (anatase, rutile and Brookite). The anatase and rutile phases exhibit a strong preferred orientation along (004) and (210) planes respectively. The grain sizes, D (nm), did not change much with increasing thickness. The average value of (nm) was equal to 29 nm for anatase and 26 nm for rutile. The micrographs taken from SEM experiments indicate that the films present a dense micro structure with very small grains. Transmittance spectra show that all the films present a good transparency in the visible region. The dependence of transmittance, optical band gap and refractive index on the thickness of the films was also studied.

  7. Revealing the atomic and electronic structure of a SrTiO{sub 3}/LaNiO{sub 3}/SrTiO{sub 3} heterostructure interface

    SciTech Connect (OSTI)

    Zhang, Zaoli; Soltan, S.; Schmid, H.; Habermeier, H.-U.; Keimer, B.; Kaiser, U.

    2014-03-14

    The atomic structures of SrTiO{sub 3} (STO)/LaNiO{sub 3} (LNO)/STO heterostructure interfaces were investigated by spherical aberration-corrected (C{sub S}) (scanning) transmission electron microscopy. Atomic displacement and lattice distortion measurements and electron energy loss spectroscopy (EELS) were used to quantitatively analyze the distortion of the interfacial octahedra and the bond length at the interfaces. Combined with high-resolution transmission electron microscopy (HRTEM) and scanning transmission electron microscopy analyses, two distinct interfacial atomic terminating layers are unambiguously determined. Ensuing quantitative HRTEM measurements revealed that the Ni-O bond length in the interfacial octahedral is elongated at the bottom interface (NiO{sub 2}-SrO). Atomic displacement shows structural relaxation effects when crossing the interfaces and lattice distortions across the interface is more pronounced in LNO than in STO. The Ti/O atomic ratio, La and Ti relative atomic ratio as derived by EELS quantification indicate non-stoichiometric composition at the interfaces. Distinct fine structures of Ti-L{sub 2,3} edge and O-K edge at the bottom and top interfaces are observed. By comparison, we are able to estimate Ti valency at both interfaces. Combining the structural distortions and Ti valency, the polar discontinuity and charge transfer at the interfaces are discussed.

  8. Preparation and lithium intercalation behavior of TiO{sub 2} in aqueous solutions

    SciTech Connect (OSTI)

    Li, Yunjiao, E-mail: yunjiaoli6601@hotmail.com; Li, Lin; Chen, Lingpeng; Wang, Xuanyu; Xu, Cang

    2014-04-01

    Highlights: The poor crystalline anatase phase or amorphous TiO{sub 2} was prepared by TiCl{sub 4} hydrolysis under different pH conditions. Phase transition behavior and lithium intercalation ability of the obtained TiO{sub 2} were found to be related to TiO{sub 2} property. The results indicate that TiO{sub 2} products obtained from TiCl{sub 4} hydrolysis at lower pH are favorable for lithium intercalation. - Abstract: The low crystalline or amorphous TiO{sub 2} was prepared by TiCl{sub 4} hydrolysis in aqueous solutions under different pH conditions at 45 C. The products obtained at lower pH (1.233.10) appear to be nano-sized particles with poor crystalline anatase structure and an uniform particle size distribution, while the product prepared at pH 4.10 presents in a poor crystalline anatase structure and the regular morphology starts to disappear, and the products obtained at higher pH (>6.00) are amorphous and irregular morphology. The hydrolysis products obtained at pH 2.60 and 8.80 were heat-treated at 300, 400, 600, 700 and 800 C for 3 h, respectively, to figure out the phase transition. The differences in phase transition process were observed, which verified the properties difference. The lithium intercalation abilities of the obtained TiO{sub 2} were studied. The results indicated that the TiO{sub 2} obtained at lower pH are more favorable for lithium intercalation and are better precursors.

  9. Fabrication and characterization of photovoltaic devices based on perovskite compounds with TiO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Kanayama, Masato Oku, Takeo Suzuki, Atsushi; Yamada, Masahiro; Sakamoto, Hiroki; Fukunishi, Sakiko; Kohno, Kazufumi

    2015-02-27

    Perovskite-type photovoltaic devices were fabricated by a spin-coating method using a mixture solution. The compact and meso-porous TiO{sub 2} of the solar cells were fabricated from TiO{sub 2} nanoparticles and sol, and the photovoltaic properties and microstructures were characterized. The conversion efficiencies were improved by the combination of TiO{sub 2} nanoparticles and sol. Current density was also improved by increasing numbers of spin-coatings of meso-porous TiO{sub 2}. Thick meso-porous TiO2 layers would assist the construction of perovskite layers and block of the leak current.

  10. Brazing ZrO{sub 2} ceramic to Ti6Al4V alloy using NiCrSiB amorphous filler foil: Interfacial microstructure and joint properties

    SciTech Connect (OSTI)

    Cao, J., E-mail: cao_jian@hit.edu.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Song, X.G., E-mail: song_xiaoguohit@yahoo.com.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Li, C., E-mail: li_chun1989@yahoo.cn [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Zhao, L.Y., E-mail: Zhao_ly@163.com [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Feng, J.C., E-mail: feng_jicai@163.com [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China)

    2013-07-15

    Reliable brazing of ZrO{sub 2} ceramic and Ti6Al4V alloy was achieved using NiCrSiB amorphous filler foil. The interfacial microstructure of ZrO{sub 2}/Ti6Al4V joints was characterized by scanning electron microscope, energy dispersive spectrometer and micro-focused X-ray diffractometer. The effects of brazing temperature on the interfacial microstructure and joining properties of brazed joints were investigated in detail. Active Ti of Ti6Al4V alloy dissolved into molten filler metal and reacted with ZrO{sub 2} ceramic to form a continuous TiO reaction layer, which played an important role in brazing. Various reaction phases including Ti{sub 2}Ni, Ti{sub 5}Si{sub 3} and ?-Ti were formed in brazed joints. With an increasing of brazing temperature, the TiO layer thickened gradually while the Ti{sub 2}Ni amount reduced. Shear test indicated that brazed joints tend to fracture at the interface between ZrO{sub 2} ceramic and brazing seam or Ti{sub 2}Ni intermetallic layer. The maximum average shear strength reached 284.6 MPa when brazed at 1025 C for 10 min. - Graphical Abstract: Interfacial microstructure of ZrO{sub 2}/TC4 joint brazed using NiCrSiB amorphous filler foil was: ZrO{sub 2}/TiO/Ti{sub 2}Ni + ?-Ti + Ti{sub 5}Si{sub 3}/?-Ti/Widmansttten structure/TC4. - Highlights: Brazing of ZrO{sub 2} ceramic and Ti-6Al-4V alloy was achieved. Interfacial microstructure was TiO/Ti{sub 2}Ni + ? + Ti{sub 5}Si{sub 3}/?/Widmansttten structure. The formation of TiO produced the darkening effect of ZrO{sub 2} ceramic. The highest joining strength of 284.6MPa was obtained.

  11. Photo-oxidative degradation of TiO{sub 2}/polypropylene films

    SciTech Connect (OSTI)

    Garca-Montelongo, X.L.; Martnez-de la Cruz, A.; Vzquez-Rodrguez, S.; Torres-Martnez, Leticia M.

    2014-03-01

    Graphical abstract: - Highlights: Photo-oxidative degradation of polypropylene is accelerated by TiO{sub 2} incorporation. Weight loss, FTIR, SEM and GPC shown high degree of degradation of polypropylene. A mechanism of the photo-degradation of polypropylene by TiO{sub 2} is proposed. - Abstract: Photo-oxidative degradation of polypropylene films with TiO{sub 2} nanoparticles incorporated was studied in a chamber of weathering with Xenon lamps as irradiation source. TiO{sub 2} powder with crystalline structure of anatase was synthesized by thermal treatments at 400 and 500 C starting from a precursor material obtained by solgel method. Composites of TiO{sub 2}/polypropylene were prepared with 0.1, 0.5 and 1.0 wt% of TiO{sub 2}. The mixture of components was performed using a twin screw extruder, the resulting material was pelletized by mechanical fragmenting and then hot-pressed in order to form polypropylene films with TiO{sub 2} dispersed homogeneously. Photo-oxidative degradation process was followed by visual inspection, weight loss of films, scanning electron microscopy (SEM), infrared spectroscopy with Fourier transformed (FTIR), and gel permeation chromatography (GPC)

  12. Graphene oxide modified TiO2 nanotube arrays?enhanced visible light photoelectrochemical properties

    SciTech Connect (OSTI)

    Song, Peng; Zhang, Xiao-Yan; Sun, Mingxun; Cui, Xiao-Li; Lin, Yuehe

    2012-03-01

    Novel nanocomposite films based on graphene oxide (GO) and TiO{sub 2} nanotube arrays were synthesized by assembling GO on the surface of self-organized TiO{sub 2} nanotube arrays through a simple assembling method. The composite films were characterized with field emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and UV-vis diffuse reflectance spectroscopy. Photoelectrochemical properties of the composite nanotube arrays were investigated under visible light illumination. Remarkably enhanced visible light photoelectrochemical response was observed for the GO decorated TiO{sub 2} nanotube composite electrode compared with pristine TiO{sub 2} nanotube arrays. Sensitizing effect of GO on the photoelectrochemical response of TiO{sub 2} nanotube arrays was demonstrated and about 15 times enhanced maximum photoconversion efficiency was obtained with the presence of GO. Enhanced photocatalytic activity of TiO{sub 2} nanotube arrays towards degradation of methyl blue was also demonstrated after modification of GO. The results presented here demonstrate GO to be efficient for the improvement of utilization of visible light for TiO{sub 2} nanotube arrays.

  13. Location Of Hole And Electron Traps On Nanocrystalline Anatase TiO2

    SciTech Connect (OSTI)

    Mercado, Candy C.; Knorr, Fritz J.; McHale, Jeanne L.; Usmani, Shirin M.; Ichimura, Andrew S.; Saraf, Laxmikant V.

    2012-05-17

    The defect photoluminescence from TiO2 nanoparticles in the anatase phase is reported for nanosheets which expose predominantly (001) surfaces, and compared to that from conventional anatase nanoparticles which expose mostly (101) surfaces. Also reported is the weak defect photoluminescence of TiO2 nanotubes, which we find using electron back-scattered diffraction to consist of walls which expose (110) and (100) facets. The nanotubes exhibit photoluminescence that is blue-shifted and much weaker than that from conventional TiO2 nanoparticles. Despite the preponderance of (001) surfaces in the nanosheet samples, they exhibit photoluminescence similar to that of conventional nanoparticles. We assign the broad visible photoluminescence of anatase nanoparticles to two overlapping distributions: hole trap emission associated with oxygen vacancies on (101) exposed surfaces, which peaks in the green, and a broader emission extending into the red which results from electron traps on under-coordinated titanium atoms, which are prevalent on (001) facets. The results of this study suggest how morphology of TiO2 nanoparticles could be optimized to control the distribution and activity of surface traps. Our results also shed light on the mechanism by which the TiCl4 surface treatment heals traps on anatase and mixed-phase TiO2 films, and reveals distinct differences in the trap-state distributions of TiO2 nanoparticles and nanotubes. The molecular basis for electron and hole traps and their spatial separation on different facets is discussed.

  14. Direct Evidence of Lithium-Induced Atomic Ordering in Amorphous TiO2 Nanotubes

    SciTech Connect (OSTI)

    Gao, Qi; Gu, Meng; Nie, Anmin; Mashayek, Farzad; Wang, Chong M.; Odegard, Gregory M.; Shahbazian-Yassar, Reza

    2014-01-27

    In this paper, we report the first direct chemical and imaging evidence of lithium-induced atomic ordering in amorphous TiO2 nanomaterials and propose new reaction mechanisms that contradict the many works in the published literature on the lithiation behavior of these materials. The lithiation process was conducted in situ inside an atomic resolution transmission electron microscope. Our results indicate that the lithiation started with the valence reduction of Ti4+ to Ti3+ leading to a LixTiO2 intercalation compound. The continued intercalation of Li ions in TiO2 nanotubes triggered an amorphous to crystalline phase transformation. The crystals were formed as nano-islands and identified to be Li2Ti2O4 with cubic structure (a = 8.375 ). The tendency for the formation of these crystals was verified with density functional theory (DFT) simulations. The size of the crystalline islands provides a characteristic length scale (?5 nm) at which the atomic bonding configuration has been changed within a short time period. This phase transformation is associated with local inhomogeneities in Li distribution. On the basis of these observations, a new reaction mechanism is proposed to explain the first cycle lithiation behavior in amorphous TiO2 nanotubes.

  15. Nanoscale compositional analysis of NiTi shape memory alloy films deposited by DC magnetron sputtering

    SciTech Connect (OSTI)

    Sharma, S. K.; Mohan, S.; Bysakh, S.; Kumar, A.; Kamat, S. V.

    2013-11-15

    The formation of surface oxide layer as well as compositional changes along the thickness for NiTi shape memory alloy thin films deposited by direct current magnetron sputtering at substrate temperature of 300 °C in the as-deposited condition as well as in the postannealed (at 600 °C) condition have been thoroughly studied by using secondary ion mass spectroscopy, x-ray photoelectron spectroscopy, and scanning transmission electron microscopy-energy dispersive x-ray spectroscopy techniques. Formation of titanium oxide (predominantly titanium dioxide) layer was observed in both as-deposited and postannealed NiTi films, although the oxide layer was much thinner (8 nm) in as-deposited condition. The depletion of Ti and enrichment of Ni below the oxide layer in postannealed films also resulted in the formation of a graded microstructure consisting of titanium oxide, Ni{sub 3}Ti, and B2 NiTi. A uniform composition of B2 NiTi was obtained in the postannealed film only below a depth of 200–250 nm from the surface. Postannealed film also exhibited formation of a ternary silicide (Ni{sub x}Ti{sub y}Si) at the film–substrate interface, whereas no silicide was seen in the as-deposited film. The formation of silicide also caused a depletion of Ni in the film in a region ∼250–300 nm just above the film substrate interface.

  16. Composite WO3/TiO2 nanostructures for high electrochromic activity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Reyes-Gil, Karla R.; Stephens, Zachary D.; Stavila, Vitalie; Robinson, David B.

    2015-01-06

    A composite material consisting of TiO2 nanotubes (NT) with WO3 electrodeposited on its surface has been fabricated, detached from its Ti substrate, and attached to a fluorine-doped tin oxide (FTO) film on glass for application to electrochromic (EC) reactions. Several adhesion layers were tested, finding that a paste of TiO2 made from commercially available TiO2 nanoparticles creates an interface for the TiO2 NT film to attach to the FTO glass, which is conductive and does not cause solution-phase ions in an electrolyte to bind irreversibly with the material. The effect of NT length and WO3 concentration on the EC performancemore » were studied. As a result, the composite WO3/TiO2 nanostructures showed higher ion storage capacity, better stability, enhanced EC contrast, and longer memory time compared with the pure WO3 and TiO2 materials« less

  17. Effect of the top electrode materials on the resistive switching characteristics of TiO{sub 2} thin film

    SciTech Connect (OSTI)

    Oh, Sang Chul; Jung, Ho Yong; Lee, Heon

    2011-06-15

    Various metals, such as Pt, stainless steel (SUS), Al, Ni, and Ti, were used as a top electrode (TE) to evaluate the dependency of the resistive switching characteristics on the TE of the metal/TiO{sub 2}/Pt structure. The variation of the chemical composition of TiO{sub 2} in the metal/TiO{sub 2}/Pt structure before and after switching was examined to identify the factors affecting the resistive switching characteristics of the samples with various TE materials. In the case of TE/TiO{sub 2}/Pt structures showing unstable resistive switching behavior, e.g., those with the Al, Ni, and Ti TEs, secondary ion mass spectrometry revealed an increase in the oxygen concentration at the interface area between the TE metal and TiO{sub 2}. This suggests that the oxidation reaction at the interface between the TE metal and TiO{sub 2} might cause the TE/TiO{sub 2}/Pt structure to exhibit unstable resistive switching characteristics. According to these results, the oxidation reaction at the interface between the metal TE and TiO{sub 2} thin film is a primary factor affecting the resistive switching characteristics of TiO{sub 2}-based Resistive Random Access Memory devices.

  18. Tailoring the crystal structure of TiO{sub 2} thin films from the anatase to rutile phase

    SciTech Connect (OSTI)

    Kotake, Haruka; Jia, Junjun; Nakamura, Shin-ichi; Shigesato, Yuzo; Okajima, Toshihiro

    2015-07-15

    TiO{sub 2} films with various Sn concentrations were deposited on quartz substrates using rf reactive magnetron sputtering. The crystal structure was investigated by using x-ray diffraction, Raman spectroscopy, and transmission electron microscopy, and the chemical states of Ti and Sn were analyzed by x-ray absorption near edge structure (XANES) spectroscopy. Without Sn doping, TiO{sub 2} films change the crystal structure from rutile to anatase as the total gas pressure increases in the sputtering deposition. On the other hand, Sn doping induces the transformation of TiO{sub 2} crystalline structure from anatase to rutile phase, where the XANES spectra implied that Sn substitutes into Ti site of rutile TiO{sub 2}. Atomic force microscope analyses revealed that the Sn-doped TiO{sub 2} films exhibited a flat surface with the roughness of approximately 2 nm.

  19. Characterization of oxygen and titanium diffusion at the anatase TiO2(001) surface

    SciTech Connect (OSTI)

    Herman, Gregory S.; Zehr, Robert T.; Henderson, Michael A.

    2013-06-01

    The diffusion of intrinsic defects in a single crystal anatase TiO2(001) film was explored by isotopic labeling and static secondary ion mass spectrometry. Using both 46Ti and 18O as isotopic labels, we show that the anatase surface responds to redox imbalances by diffusion of both Ti and O into the bulk under vacuum reduction and (at least) Ti from the bulk to the surface during oxidation. The diffusion of Ti between the bulk and surface in anatase TiO2(001) closely resembles what was observed in the literature for the rutile TiO2(110) surface, however the latter is not known to have oxygen diffusion between the bulk and surface under typical ultrahigh vacuum conditions. We speculate that the open lattice of the anatase bulk structure may facilitate independent diffusion of both point defects (Ti interstitials and O vacancies) or concerted diffusion of "TiO" subunits. The authors gratefully acknowledge S.A. Chambers of Pacific Northwest National Laboratory (PNNL) for providing the anatase samples. This research was supported by the U.S. Department of Energy (DOE) Office of Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division, the Office of Naval Research Contract Number 200CAR262, and the Oregon Nanoscience and Microtechnologies Institute. PNNL is operated for the U.S. DOE by Battelle under Contract Number DE05-AC76RL0 1830. The research was performed in the William R. Wiley Environmental Molecular Sciences Laboratory, a national scientific user facility funded by the U.S. DOE Office of Biological and Environmental Research.

  20. Electrochromism in sol-gel deposited TiO(sub 2) films

    SciTech Connect (OSTI)

    Bell, J.M.; Barczynska, J.; Evans, L.A.; MacDonald, K.A.; Wang, J.; Green, D.C.; Smith, G.B.

    1994-12-31

    Electrochromism in sol-gel deposited TiO{sub 2} films and films containing TiO{sub 2} and WO{sub 3} has been observed. The films are deposited by dip-coating from a precursor containing titanium isopropoxide in ethanol or titanium propoxide in ethanol, and after deposition the films are heat treated to between 250 C and 300 C. The films do not show any signs of crystallinity. However substantial coloration is observed using Li{sup +} ions in a non-aqueous electrolyte, both in pure TiO{sub 2} films and in mixed metal oxide films (WO{sub 3}:TiO{sub 2}), although the voltage required to produce coloration is different in the two cases. Results will be presented detailing the optical switching and charge transport properties of the films during cyclic voltammetry. These results will be used to compare the performance of the TiO{sub 2} films with other electrochromics. The TiO{sub 2} and mixed metal films all color cathodically, and the colored state is a neutral greyish color for TiO{sub 2}, while the bleached state is transparent and colorless. Results on coloration efficiency and the stability under repeated electrochemical cycling will also be presented. The neutral color of the TiO{sub 2} films and mixed-metal films means that electrochromic windows based on TiO{sub 2} may have significant advantages over WO{sub 3}-based windows. A detailed analysis of the optical properties of the colored state of the films will be presented. The dynamics of coloration for these films is also under investigation, and preliminary results will be presented.

  1. Atomic structure of nanometer-sized amorphous TiO2

    SciTech Connect (OSTI)

    Zhang, H.; Chen, B.; Banfield, J.F.; Waychunas, G.A.

    2008-10-15

    Amorphous titania (TiO{sub 2}) is an important precursor for synthesis of single-phase nanocrystalline anatase. We synthesized x-ray amorphous titania by hydrolysis of titanium ethoxide at the ice point. Transmission electron microscopy examination and nitrogen gas adsorption indicated the particle size of the synthesized titania is {approx} 2 nm. Synchrotron wide-angle x-ray scattering (WAXS) was used to probe the atomic correlations in this amorphous sample. Atomic pair-distribution function (PDF) derived from Fourier transform of the WAXS data was used for reverse Monte Carlo (RMC) simulations of the atomic structure of the amorphous TiO{sub 2} nanoparticles. Molecular dynamics simulations were used to generate input structures for the RMC. X-ray absorption spectroscopy (XAS) simulations were used to screen candidate structures obtained from the RMC by comparing with experimental XAS data. The structure model that best describes both the WAXS and XAS data shows that an amorphous TiO{sub 2} particle consists of a highly distorted shell and a small strained anatase-like crystalline core. The average coordination number of Ti is 5.3 and most Ti-O bonds are populated around 1.940 {angstrom}. Relative to bulk TiO{sub 2}, the reduction of the coordination number is primarily due to the truncation of the Ti-O octahedra at the amorphous nanoparticle surface and the shortening of the Ti-O bond length to the bond contraction in the distorted shell. The preexistence of the anatase-like core may be critical to the formation of single-phase nanocrystalline anatase in crystallization of amorphous TiO{sub 2} upon heating.

  2. Efficient photocatalytic degradation of gaseous formaldehyde by the TiO{sub 2}/tourmaline composites

    SciTech Connect (OSTI)

    Zhang, Gaoke Qin, Xi

    2013-10-15

    Graphical abstract: - Highlights: The TiO{sub 2}/tourmaline composites were prepared by a solgel method. The composites exhibited excellent photocatalytic activity and good stability. The physicochemical property of tourmaline may be favor for the degradation of HCHO. The mixed-phase of anatase and rutile TiO{sub 2} may be favor for the degradation of HCHO. - Abstract: The TiO{sub 2} supported tourmaline composites were prepared by a solgel method and used as a photocatalyst for the degradation of formaldehyde (HCHO). The composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), N{sub 2} adsorptiondesorption, Fourier transform infrared (FT-IR) spectroscopy and UVvis diffuse reflectance spectroscopy (UVvis DRS). The results indicate that the mixed-phase of anatase and rutile exists in the TiO{sub 2}/tourmaline composites. The specific surface area of the TiO{sub 2}/tourmaline composites is much higher than that of the pure TiO{sub 2}. The TiO{sub 2}/tourmaline composites exhibited excellent photocatalytic activity for the degradation of HCHO, which was 6 times higher than that of the pure TiO{sub 2}. Moreover, the excellent photocatalytic activity of the composites was fully maintained after five photocatalytic cycles, which may be attributed to the physicochemical property of tourmaline and the mixed-phase of anatase and rutile in the TiO{sub 2}/tourmaline composites.

  3. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-Na₀̣₅Bi₀̣₅TiO₃ piezoelectric materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26

    We synthesized grain-oriented lead-free piezoelectric materials in (K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-xNa₀̣₅Bi₀̣₅TiO₃ (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d₃₃ ~ 190pC/N) and high temperature stability (~160°C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180° domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectricmore » materials.« less

  4. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K???Bi???TiO?-BaTiO?-Na???Bi???TiO? piezoelectric materials

    SciTech Connect (OSTI)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26

    We synthesized grain-oriented lead-free piezoelectric materials in (K???Bi???TiO?-BaTiO?-xNa???Bi???TiO? (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d?? ~ 190pC/N) and high temperature stability (~160C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180 domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectric materials.

  5. Design of highly ordered Ag-SrTiO{sub 3} nanotube arrays for photocatalytic degradation of methyl orange

    SciTech Connect (OSTI)

    Sun Yue; Liu Jiawen; Li Zhonghua

    2011-08-15

    Ag-SrTiO{sub 3} nanotube arrays were successfully prepared for the degradation of methyl orange (MO) under ultraviolet irradiation. In order to form highly ordered SrTiO{sub 3} nanotube arrays, the preparation of TiO{sub 2} nanotube arrays by anodic oxidation of titanium foil in different electrolytes was investigated. The selected organic solvents in electrolytes include glycerol, dimethyl sulfoxide and glycol. The results indicate that the morphology of TiO{sub 2} nanotube arrays prepared in glycol containing ammonium fluoride electrolyte is more regular. Then SrTiO{sub 3} nanotube arrays were synthesized by a hydrothermal method using TiO{sub 2} nanotube arrays as the precursor. In order to further improve the photocatalytic activity of SrTiO{sub 3} nanotube arrays, Ag nanoparticles were loaded on SrTiO{sub 3} nanotube arrays by two sets of experiments. The loaded Ag results in an enhancement of photocatalytic activity of SrTiO{sub 3} nanotube arrays. Moreover, the effect of pH on the photocatalytic degradation of MO was also studied. - Graphical abstract: Ag-SrTiO{sub 3} nanotube arrays were successfully prepared. The photocatalytic activity was evaluated by degradation of methyl orange under ultraviolet irradiation. Highlights: > TiO{sub 2} nanotube arrays prepared in glycol+NH{sub 4}F electrolyte are more regular. > Highly ordered Ag-SrTiO{sub 3} nanotube arrays were successfully synthesized. > Ag loading could enhance the photocatalytic activity of SrTiO{sub 3} nanotube arrays. > Ag-SrTiO{sub 3} nanotube arrays show excellent catalytic activity at a low pH value.

  6. Transparent TiO2 nanotube array photoelectrodes prepared via two-step anodization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Jin Young; Zhu, Kai; Neale, Nathan R.; Frank, Arthur J.

    2014-04-04

    Two-step anodization of transparent TiO2 nanotube arrays has been demonstrated with aid of a Nb-doped TiO2 buffer layer deposited between the Ti layer and TCO substrate. Enhanced physical adhesion and electrochemical stability provided by the buffer layer has been found to be important for successful implementation of the two-step anodization process. As a result, with the proposed approach, the morphology and thickness of NT arrays could be controlled very precisely, which in turn, influenced their optical and photoelectrochemical properties.

  7. Doping of TiO 2 Polymorphs for Altered Optical and Photocatalytic Properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nie, Xiliang; Zhuo, Shuping; Maeng, Gloria; Sohlberg, Karl

    2009-01-01

    Tmore » his paper reviews recent investigations of the influence of dopants on the optical properties of TiO 2 polymorphs.he common undoped polymorphs of TiO 2 are discussed and compared.he results of recent doping efforts are tabulated, and discussed in the context of doping by elements of the same chemical group. Dopant effects on the band gap and photocatalytic activity are interpreted with reference to a simple qualitative picture of the TiO 2 electronic structure, which is supported with first-principles calculations.« less

  8. Structural characterization and electronic structure of laser treated TiN thin film

    SciTech Connect (OSTI)

    Soni, Sheetal; Nair, K. G. M.; Phase, D. M.; Gupta, Ratnesh

    2012-06-05

    TiN thin films prepared by laser treatment using Kr-F excimer laser in the controlled atmosphere. The depth distribution and composition of nitrogen and contaminated oxygen have been determined by non-Rutherford proton backscattering using 1.7 MeV Tendetron accelerator. The electronic structure of TiN thin film have been characterized by resonant photoelectron spectroscopy using indus-I synchrotron radiation. Specifically, complex resonance profile that shows the enhancement at 45 eV which is consistent with the resonant photoemission of Ti 3d states involved in the Titanium nitride and oxide.

  9. Photo-induced wettability of TiO{sub 2} film with Au buffer layer

    SciTech Connect (OSTI)

    Purkayastha, Debarun Dhar; Sangani, L. D. Varma; Krishna, M. Ghanashyam; Madhurima, V.

    2014-04-24

    The effect of thickness of Au buffer layer (15-25 nm) between TiO{sub 2} film and substrate on the wettability of TiO{sub 2} films is reported. TiO{sub 2} films grown on Au buffer layer have a higher contact angle of 96-;100 as compared to 47.6o for the film grown without buffer layer. The transition from hydrophobicity to hydrophilicity under UV irradiation occurs within 10 min. for the buffer layered films whereas it is almost 30 min. for the film grown without buffer layer. The enhanced photo induced hydrophilicity is shown to be surface energy driven.

  10. On the origins of hardness of Cu–TiN nanolayered composites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pathak, S.; Li, N.; Maeder, X.; Hoagland, R. G.; Baldwin, J. K.; Michler, J.; Misra, A.; Wang, J.; Mara, N. A.

    2015-07-18

    We investigated the mechanical response of physical vapor deposited Cu–TiN nanolayered composites of varying layer thicknesses from 5 nm to 200 nm. Both the Cu and TiN layers were found to consist of single phase nanometer sized grains. The grain sizes in the Cu and TiN layers, measured using transmission electron microscopy and X-ray diffraction, were found to be comparable to or smaller than their respective layer thicknesses. Indentation hardness testing revealed that the hardness of such nanolayered composites exhibits a weak dependence on the layer thickness but is more correlated to their grain size.