Sample records for ti al tes

  1. A=17Al (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See77AJ02) (See93TI07)Al

  2. A=20Al, etc. (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02) (See72AJ02)98TI06) (Not

  3. Thermal stability and oxidation resistance of TiCrAlYO coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications. Thermal stability and oxidation resistance of TiCrAlYO...

  4. The massive transformation in Ti-Al alloys: mechanistic observations

    SciTech Connect (OSTI)

    Zhang, X.D.; Godfrey, S.; Weaver, M.; Strangwood, M.; Kaufman, M.J.; Loretto, M.H. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; Threadgill, P. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; [TWI, Cambridge (United Kingdom)

    1996-09-01T23:59:59.000Z

    The massive {alpha}{yields}{gamma}{sub m} transformation, as observed using analytical transmission electron microscopy, in Ti-49Al, Ti-48Al-2Nb-2Mn, Ti-55Al-25Ta and Ti-50Al-20Ta alloys is described. Conventional solution heating and quenching experiments have been combined with the more rapid quenching possible using electron beam melting in order to provide further insight into the early stages of the transformation of these alloys. It is shown that the {gamma} develops first at grain boundaries as lamellae in one of the grains and that these lamellae intersect and spread into the adjacent grain in a massive manner. Consequently, there is no orientation relationship between the massive gamma ({gamma}{sub m}) and the grain being consumed whereas there is the expected relation between the {gamma}{sub m} and the first grain which is inherited from the lamellae. It is further shown that the {gamma}{sub m} grows as an f.c.c. phase after initially growing with the L1{sub 0} structure. Furthermore, it is shown that the massive f.c.c. phase then orders to the L1{sub 0} structure producing APDB-like defects which are actually thin 90{degree} domains separating adjacent domains that have the same orientation yet are out of phase. The advancing {gamma}{sub m} interface tends to facet parallel either to one of its four {l_brace}111{r_brace} planes or to the basal plane in the grain being consumed by impinging on existing {gamma} lamellae. Thin microtwins and {alpha}{sub 2} platelets then form in the {gamma}{sub m} presumably due, respectively, to transformation stresses and supersaturation of the {gamma}{sub m} with titanium for alloys containing {approximately}48% Al; indeed, there is a local depletion in aluminium across the {alpha}{sub 2} platelets as determined using fine probe microanalysis.

  5. High-temperature phase equilibria in the Al-rich corner of the Al-Ti-C system

    SciTech Connect (OSTI)

    Frage, N.; Frumin, N.; Levin, L.; Polak, M.; Dariel, M.P. [Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Materials Engineering

    1998-04-01T23:59:59.000Z

    A thermodynamic analysis of the Al-rich corner in the ternary Al-Ti-C diagram, providing phase relations and regions of phase stability, is presented. An invariant four-phase equilibrium between Al, Al{sub 4}C{sub 3}, Al{sub 3}Ti, and TiC{sub x} takes place at 0.53 at. pct Ti, 7.10{sup {minus}6} at. pct C, and TiC{sub 0.883} at 966 K. The carbon content of the TiC{sub x} phase, which extends from x = 0.48 to 0.98, exerts a significant effect on phase relationships in this ternary system. In particular, it is shown that stoichiometric TiC is not stable in the presence of liquid Al. For example, at 1,300 K, a two-phase equilibrium between Al{sub L} and TiC{sub x} exists only in the 0.91 < x < 0.82 range. Thus, the interaction of Al{sub L} with stoichiometric TiC leads to the formation of the Al{sub 4}C{sub 3} aluminum carbide phase, whereas for x < 0.82, only the intermetallic compound Al{sub 3}Ti can form at this temperature. The results of this analysis were confirmed by X-ray diffraction (XRD) measurements of relevant composites.

  6. Effect of aspect ratios of in situ formed TiB whiskers on the mechanical properties of TiBw/Ti6Al4V composites

    E-Print Network [OSTI]

    Hong, Soon Hyung

    ; In situ formed TiB whiskers; Spark plasma sintering Titanium alloys have been noted as promising high by a spark plasma sintering (SPS) process, which is highly useful when seeking to control the aniso- tropic) were synthesized through an in situ reac- tion between TiB2 and Ti­6Al­4V powders during a spark plasma

  7. Band gap structure modification of amorphous anodic Al oxide film by Ti-alloying

    SciTech Connect (OSTI)

    Canulescu, S., E-mail: stec@fotonik.dtu.dk; Schou, J. [Department of Photonics Engineering, Technical University of Denmark, 4000 Roskilde (Denmark); Rechendorff, K.; Pleth Nielsen, L. [Danish Technological Institute, Kongsvang Alle 29, 8000 Aarhus (Denmark); Borca, C. N. [Paul Scherrer Institute, 5232 Villigen (Switzerland); Jones, N. C.; Hoffmann, S. V. [ISA, Department of Physics and Astronomy, Aarhus University, 8000 Aarhus (Denmark); Bordo, K.; Ambat, R. [Department of Mechanical Engineering, Technical University of Denmark, 2800 Kongens Lyngby (Denmark)

    2014-03-24T23:59:59.000Z

    The band structure of pure and Ti-alloyed anodic aluminum oxide has been examined as a function of Ti concentration varying from 2 to 20 at.?%. The band gap energy of Ti-alloyed anodic Al oxide decreases with increasing Ti concentration. X-ray absorption spectroscopy reveals that Ti atoms are not located in a TiO{sub 2} unit in the oxide layer, but rather in a mixed Ti-Al oxide layer. The optical band gap energy of the anodic oxide layers was determined by vacuum ultraviolet spectroscopy in the energy range from 4.1 to 9.2?eV (300–135?nm). The results indicate that amorphous anodic Al{sub 2}O{sub 3} has a direct band gap of 7.3?eV, which is about ?1.4?eV lower than its crystalline counterpart (single-crystal Al{sub 2}O{sub 3}). Upon Ti-alloying, extra bands appear within the band gap of amorphous Al{sub 2}O{sub 3}, mainly caused by Ti 3d orbitals localized at the Ti site.

  8. Effect of Welding Speed and Defocusing Distance on the Quality of Laser Welded Ti-6Al-4V

    E-Print Network [OSTI]

    Medraj, Mamoun

    Effect of Welding Speed and Defocusing Distance on the Quality of Laser Welded Ti-6Al-4V A:YAG laser, Laser welding, Ti-6Al-4V alloy Abstract In this study, the weldability of 5.1-mm thick Ti-6Al-4V at various welding speeds and defocusing distances. The joint quality was characterized in terms of weld

  9. An Experimental and Theoretical Multi-Mbar Study of Ti-6Al-4V

    SciTech Connect (OSTI)

    Tegner, B E; Macleod, S G; CYNN, H; Proctor, J; Evans, W J; McMahon, M I; Ackland, G J

    2011-04-13T23:59:59.000Z

    We report results from an experimental and theoretical study of the room temperature (RT) compression of the ternary alloy Ti-6Al-4V. In this work, we have extended knowledge of the equation of state (EOS) from 40 GPa to 221 GPa, and observed a different sequence of phase transitions to that reported previously for pure Ti.

  10. Adhesion strength of sputtered TiAlN-coated WC insert tool

    SciTech Connect (OSTI)

    Budi, Esmar [Department of Physics, Faculty of Science and Mathematics, Universitas Negeri Jakarta, Jl. Pemuda No. 10, Jakarta 13220 (Indonesia)] [Department of Physics, Faculty of Science and Mathematics, Universitas Negeri Jakarta, Jl. Pemuda No. 10, Jakarta 13220 (Indonesia); Razali, M. Mohd.; Nizam, A. R. Md. [Faculty of Manufacturing Engineering, Universiti Teknikal Malaysia Melaka Karung Berkunci No 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)] [Faculty of Manufacturing Engineering, Universiti Teknikal Malaysia Melaka Karung Berkunci No 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

    2013-09-09T23:59:59.000Z

    The adhesion strength of TiAlN coating that deposited by using DC magnetron sputtering on WC insert tool are studied. TiAlN coating are deposited on Tungsten Carbide (WC) insert tool by varying negatively substrate bias from 79 to 221 volt and nitrogen flow rate from 30 to 72 sccm. The adhesion strength are obtained by using Rockwell indentation test method with a Brale diamond at applied load of 60,100 and 150 kgf. The lateral diameter of indentation is plotted on three different applied loads and the adhesion strength of TiAlN coating was obtained from the curved slopes at 100 and 150 kgf. The lower curve slop indicated better adhesion strength. The results shows that the adhesion strength of sputterred TiAlN coating tend to increase as the negatively substrate bias and nitrogen flow rate are increased.

  11. Flat panel display using Ti-Cr-Al-O thin film

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solan Beach, CA)

    2002-01-01T23:59:59.000Z

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  12. Process for producing Ti-Cr-Al-O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

    2001-01-01T23:59:59.000Z

    Thin films of Ti-Cr-Al-O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti-Cr-Al-O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti-Cr-Al-O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti-Cr-Al-O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  13. Wettability and phase formation in the TiC{sub x}/Al system

    SciTech Connect (OSTI)

    Frumin, N.; Frage, N.; Polak, M.; Dariel, M.P. [Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Materials Engineering] [Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Materials Engineering

    1997-10-15T23:59:59.000Z

    The introduction of reinforcements such as carbide or oxide ceramics into a metallic matrix improves high temperature strength, creep resistance and low temperature toughness. Modification of the ceramic phase can also be used in order to improve wetting in a metal/ceramic system. The wettability of ceramic surfaces by metallic melts is strongly dependent on the stoichiometry of the ceramic compound (oxide or carbide). Titanium carbide has a wide range of stability (0.55 < C/Ti {le} 1), and its chemical, physical and mechanical properties largely depend on the composition. For instance, chemical inertness and hardness increase with increasing C/Ti ratio. The use of TiC as a reinforcing phase in aluminum alloys or in TiC/Al cermets has not been exploited fully. Titanium carbide exhibits adequate wetting by Al{sub (L)} due to chemical interactions at high temperatures that may also lead to the formation of the Al{sub 4}C{sub 3} phase. The presence of this phase at the interface is undesirable because it is weak and brittle. Moreover, Al{sub 4}C{sub 3} decomposes in the presence of water to form Al{sub 2}O{sub 3} and methane gas. The present work was aimed at finding the proper conditions and the Ti/C ratio in non-stoichiometric TiC{sub x} that would improve wetting and prevent the formation of Al{sub 4}C{sub 3}.

  14. Corrosion protection and galvanic corrosion prevention for 7075 Al and Ti-6Al-6V-2Sn alloys. Final report

    SciTech Connect (OSTI)

    Clay, F.A.

    1980-07-01T23:59:59.000Z

    Sulfuric-acid-anodized and electroless-nickel-plated 7075 aluminum alloy panels successfully passed 96 hours of salt spray testing when galvanically coupled to duplex-annealed Ti-6Al-6V-2Sn alloy panels. Adherent paint deposits were produced on the titanium alloy and electroless nickel surfaces using a wash primer, an epoxy primer, and a urethane paint coating. A painted part survived 35 cycles of alternating salt spray and hot and freezing environments without blistering. A low chloride cutting fluid was selected for production machining of Ti-6Al-6V-2Sn, based on chemical analysis and stress-corrosion tests. A cleaning process was developed to remove both titanium and aluminum cutting fluids. Modified wedge-opening-loading specimens were used to verify that no stress-corrosion cracking problems occurred with the duplex-annealed Ti-6Al-6V-2Sn alloy because of residual titanium or aluminum cutting fluids.

  15. Analysis of the e-beam evaporation of titanium and Ti-6Al-4V

    SciTech Connect (OSTI)

    Westerberg, K.W.; Merier, T.C.; McClelland, M.A.; Braun, D.G.; Berzins, L.V.; Anklam, T.M.; Storer, J.

    1998-02-11T23:59:59.000Z

    An experimental and finite element analysis was performed for the electron-beam evaporation of Ti and Ti-6Al-4V from a bottom-feed system. The bulk evaporation rate was measured by feed consumption, and the pool elevation was held constant by adjusting the feed rate in a closed-loop control system. The instantaneous titanium and aluminum evaporation rates were determined by laser absorption in the vapor plume. Water temperature rises in cooling water circuits provided heat flows, and post-run cross sections revealed the location of the solidification zone. The MELT finite element code was applied to model the steady-state two-dimensional fluid flow and energy transport in the rod. There was good agreement between model and measured values of the heat flows and solidification boundaries for Ti. Measured bulk evaporation rates were similar for Ti and Ti-6-4 with greater variation observed for the Ti values. The model evaporation rates were higher than the measured values, but a similar linear dependence on e-beam power was observed in all cases. In a Ti-6-4 evaporation experiment with steady process conditions, laser absorption measurements showed much larger fluctuations in the evaporation rate for Al than Ti.

  16. Effect of Reactive Sputtering Parameters on TiAlN Nanocoating Structure and Morphology

    SciTech Connect (OSTI)

    Budi, Esmar [Jurusan Fisika FMIPA Universitas Negeri Jakarta Jl. Pemuda No. 10 Rawamangun Jakarta 13220 (Indonesia); Razali, M. Mohd.; Nizam, A. R. Md. [Faculty of Manufacturing Engineering Universiti Teknikal Malaysia Melaka (UTeM) Karung Berkunci No 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

    2010-10-24T23:59:59.000Z

    The effect of substrate bias and nitrogen flow rate on the TiAlN nanocoating structure and morphology has been investigated by using reactive unbalance DC magnetron sputtering. TiAlN nanocoating was deposited on the tungsten carbide insert tool and the structure and morphology were characterized by using XRD and AFM, respectively. The substrate bias was varied between 0 to -221 V and the nitrogen flow rate was varied between 30 to 72 sccm. The results showed that the structure of TiAlN nanocoating consisted of mainly (111) and (200) plane. The structure was significatly influenced by substrate bias in promoting finer crystal size and increased crystal plane spacing while the rms roughness of nanocoating was influenced by substrate bias and nitrogen flow rate.

  17. Ab initio investigation of Ti{sub 2}Al(C,N) solid solutions

    SciTech Connect (OSTI)

    Arroyave, Raymundo; Radovic, Miladin [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843-3123 (United States) and United States and Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843-3123 (United States)

    2011-10-01T23:59:59.000Z

    M{sub n+1}AX{sub n} phases (M: early transition metal, A: IIIA- or IVA-group element, X: carbon or nitrogen) are layered ternary compounds that possess both metal- and ceramic-like properties with numerous potential applications in bulk and thin film forms, particularly under high-temperature conditions. In this work, we use the cluster expansion formalism to investigate the energetics of C-N interactions across the entire Ti{sub 2}AlC-Ti{sub 2}AlN composition range. It is shown that there is a definite tendency for ordering in the C,N sublattice. However, the molar volume and bulk modulus of the ordered structures found along the Ti{sub 2}AlC-Ti{sub 2}AlN composition range show small deviations from the (linear) rule of mixing, indicating that despite the ordering tendencies, the C-N interactions are not strong and the solution becomes disordered at relatively low temperatures. Random solid solutions of Ti{sub 2}AlC{sub 1-x}N{sub x} are simulated using special quasirandom structures (SQS) with x=0.25, 0.50, and 0.75. The thermodynamic properties of these structures are compared to those of the structures found to belong to the ground state through the cluster expansion approach. It is found that the structural properties of these approximations to random alloys do not deviate significantly from Vegard's law. The trend in the structural parameters of these SQS are found to agree well with available experimental data and the predictions of the bulk modulus suggest a very weak alloying effect--with respect to Vegard's law--on the elastic properties of Ti{sub 2}AlC{sub 1-x}N{sub x}.

  18. al si ti: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de Extensin Universitaria Red Metropolitana Red Vsquez, Carlos 385 Graeber et al. 2014 1 Supporting Information (SI Appendix) Biology and Medicine Websites...

  19. Creep Expansion of Porous Ti-6Al-4V Sandwich Structures DOUGLAS T. QUEHEILLALT, BILL W. CHOI, DANIEL S. SCHWARTZ,

    E-Print Network [OSTI]

    Wadley, Haydn

    , and the microstructural evolution of Ti-6Al-4V sandwich panels during the annealing stage of low-density core (LDC first proposed by Kearns et al.[8,9] and Martin elastic properties of LDC sandwich structures.[15

  20. Effect of Elastic Stress on Phase Separation in Fe-20%Cr-6%Al-0.5%Ti ODS alloy

    E-Print Network [OSTI]

    Cambridge, University of

    Effect of Elastic Stress on Phase Separation in Fe- 20%Cr-6%Al-0.5%Ti ODS alloy C. Capdevila1, M. K Aldazabal from CEIT; and Monica Campos from Carlos III University (UC3) for their help with ODS for nuclear applications Acknowledgements Effect of Elastic Stress on Phase Separation in Fe-Cr-Al-Ti ODS alloy by C

  1. Evaluation of Ti-6Al-4V Parts Produced with Rapid Prototyping Technology: Electron Beam Melting Machine

    E-Print Network [OSTI]

    Abdeen, Dana

    2014-09-29T23:59:59.000Z

    The present study measured the corrosion properties of Ti-6Al-4V parts produced with Electron Beam Melting machine (EBM). Potentiodynamic and potentiostatic tests were applied on EBM Ti-6Al-4V in 3.5% mass NaCl solution, to determine the pitting...

  2. Dynamic response of conventional and hot isostatically pressed Ti6Al4V alloys: experiments and modeling

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    Dynamic response of conventional and hot isostatically pressed Ti±6Al±4V alloys: experiments of Mechanical and Aerospace Engineering, Center of Excellence for Advanced Materials, University of California thermomechanical response of Ti± 6Al±4V alloys with three dierent microstructures. Two of the alloys are produced

  3. Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides

    E-Print Network [OSTI]

    Ciobanu, Cristian

    - sition to a hydrogen economy.1 Solid-state storage in hydrogen-rich compounds, e.g., complex hydridesShort-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage

  4. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and...

  5. Evaluation of Ti-6Al-4V Parts Produced with Rapid Prototyping Technology: Electron Beam Melting Machine 

    E-Print Network [OSTI]

    Abdeen, Dana

    2014-09-29T23:59:59.000Z

    The present study measured the corrosion properties of Ti-6Al-4V parts produced with Electron Beam Melting machine (EBM). Potentiodynamic and potentiostatic tests were applied on EBM Ti-6Al-4V in 3.5% mass NaCl solution, to determine the pitting...

  6. Surface Engineering to Improve the Durability and Lubricity of Ti-6Al-4V Alloy

    SciTech Connect (OSTI)

    Bansal, Dinesh G [ORNL; Eryilmaz, Osman L [Argonne National Laboratory (ANL); Blau, Peter Julian [ORNL

    2011-01-01T23:59:59.000Z

    Titanium alloys offer high strength, high corrosion resistance, and the opportunity to reduce the weight of heavy vehicle engine components, but they do not perform well as bearing surfaces without further treatments or coatings. This paper explores a series of surface engineering treatments to improve the friction and wear behavior of Ti-6Al-4V alloy under diesel engine oil-lubricated conditions.

  7. Tailoring the surface properties of Ti6Al4V by controlled chemical oxidation

    E-Print Network [OSTI]

    activity at the surface of implants, mainly by modifying their topography and physicochemical properties, such as its surface chemistry and energy, roughness, and topography [6]. It is generally accepted that roughTailoring the surface properties of Ti6Al4V by controlled chemical oxidation Fabio Variola a,b , Ji

  8. Process Modeling of Ti-6Al-4V Linear Friction Welding (LFW)

    E-Print Network [OSTI]

    Grujicic, Mica

    Process Modeling of Ti-6Al-4V Linear Friction Welding (LFW) Mica Grujicic, G. Arakere, B finite-element analysis of the linear friction welding (LFW) process is combined with the basic physical in the open literature revealed that the weld region consists of a thermo- mechanically affected zone (TMAZ

  9. Processing and Mechanical Properties of Ti2AlC Reinforced with Alumina Fibers

    E-Print Network [OSTI]

    Jeon, Kwonguk

    2012-10-19T23:59:59.000Z

    , even at temperature as high as 1400 oC at which reaction between Ti2AlC and NextelTM 720 was observed. The double torsion (DT) tests were carried out at room temperature to measure the fracture toughness of the HIPed pure and 5vol% alumina fiber...

  10. An Experimental and Theoretical Study of Ti-6Al-4V to Multi-mbar Pressures

    SciTech Connect (OSTI)

    MacLeod, S G; Tegner, B E; Cynn, H; Evans, W J; Proctor, J; McMahon, M I; Ackland, G J

    2012-03-14T23:59:59.000Z

    We report results from an experimental and theoretical study of the ternary alloy Ti-6Al-4V to 221 GPa. We observe a phase transition to the hexagonal {omega}-phase at approximately 30 GPa, and then a further transition to the cubic {beta}-phase starting at 94-99 GPa. We do not observe the orthorhombic {gamma} and {delta} phases reported previously in pure Ti. Computational studies show that this sequence is possible only if there is significant local atomic ordering during the compression process, yet insufficient atomic diffusion to reach the phase separated thermodynamic equilibrium state.

  11. Structural, textural and catalytic properties of Al-, Ti-pillared clays

    SciTech Connect (OSTI)

    Ramos-Galvan, C.E.; Dominguez, J.M.; Sandoval-Robles, G.; Castillo-Mares, A.; Nava E, N.

    1996-12-31T23:59:59.000Z

    Al-, Ti- and Zr-pillared clays were characterized and NiMo/Pilc`s were tested in HDS reactions. The combination of activity measurements with Moessbauer Spectroscopy and x-ray microanalysis at microscopical scale give insight in the metal phases migration during pillaring, reaction and regeneration steps. {Alpha}-Fe phase in free Fe{sub 2}O{sub 3} islands predominate together with structural Fe{sup 3+} phase, but during the catalytic reaction Fe{sup 2+} forms. Delamination of the Ti- and Zr-Clay supports, together with high Lewis acidity might enhance their catalytic properties.

  12. Environmental effect on room-temperature ductility of isothermally forged TiAl-base alloys

    SciTech Connect (OSTI)

    Nakamura, Morihiko; Hashimoto, Kenki (National Research Inst. for Metals, Tokyo (Japan)); Itoh, Naoyuki (Nippon Steel Corp., Chiba (Japan)); Tsujimoto, Tokuzo (Ibaraki Univ. (Japan). Faculty of Engineering); Suzuki, Toshiyuki (Kougakuin Univ., Tokyo (Japan))

    1994-02-01T23:59:59.000Z

    Isothermally forged TiAl-base alloy (Al-rich, Mn-containing, and Cr-containing TiAl) were heat-treated in various conditions, and equiaxed grain structures consisting of [gamma] and [alpha][sub 2] or [beta] phases were obtained. The heat-treated alloys were tensile tested in vacuum and air at room temperature, and the environmental effect on tensile elongation was studied. The ductility of the alloys consisting of equiaxed [gamma] grains and a large amount of [alpha][sub 2] grains was not largely affecting by laboratory air, and a decrease in the amount of [alpha][sub 2] grains resulted in a large reduction of ductility in air. The [beta] phase in the Cr-containing alloy improved the ductility in vacuum, but it resulted in a large reduction of ductility in air.

  13. Micro-Raman spectroscopic study of nanolaminated Ti{sub 5}Al{sub 2}C{sub 3}

    SciTech Connect (OSTI)

    Zhang, H.; Li, Z. J. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Wang, X. H. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Xiang, H. M.; Zhou, Y. C, E-mail: yczhou714@gmail.com [Science and Technology of Advanced Functional Composite Laboratory, ARIMPT, No.1 South Dahongmen Road, Beijing 100076 (China)

    2014-03-31T23:59:59.000Z

    Micro-Raman spectroscopic study and lattice dynamics calculations were conducted to study a recently identified layered ternary carbide, Ti{sub 5}Al{sub 2}C{sub 3}. The experimental Raman shifts were remarkably consistent with the calculated values. Polarized Raman spectrum was collected in the polycrystalline sample, which confirmed the theoretical symmetry assignment of the Raman modes. In addition, the atomic vibrations of the peaks at 192?cm{sup ?1}, 311?cm{sup ?1}, and 660?cm{sup ?1} were identified to be the combination of the counterparts in Ti{sub 2}AlC and Ti{sub 3}AlC{sub 2}.

  14. Cold compaction study of Armstrong Process Ti-6Al-4V powders

    SciTech Connect (OSTI)

    Chen, Wei [ORNL; Yamamoto, Yukinori [ORNL; Peter, William H [ORNL; Gorti, Sarma B [ORNL; Sabau, Adrian S [ORNL; Clark, Michael B [ORNL; Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Blue, Craig A [ORNL; Fuller, Brian [International Titanium Powder; Akhtar, Kamal [International Titanium Powder

    2011-01-01T23:59:59.000Z

    This work investigates the cold compaction behavior of Ti-6Al-4V powders produced by Armstrong Process . As-received as well as milled powders were characterized and these powders were uniaxially die-pressed at designated pressures up to 690 MPa to form disk samples with different aspect ratios. Samples with high aspect ratio exhibited non-uniform density along the pressing axis and the density distribution is in consistent with the result predicted by finite element analysis. The linear regression analysis on the experimental density data can be used to predict density of compacts with different aspect ratios. In the studied pressure range, an empirical powder compaction equation represents the green density pressure relationship very well for both the as-received and 1-hr milled Armstrong Ti-6Al-4V powders.

  15. Colored hard coatings with AlN–TiN multilayer structures

    SciTech Connect (OSTI)

    Hong Lu, Jong, E-mail: jonghonglu@mail.mcut.edu.tw; Ying Chen, Bo [Department of Materials Engineering and Center for Thin Film Technologies and Applications, Ming Chi University of Technology, 84 Gungjuan Rd., Taishan Dist., New Taipei City 24301, Taiwan (China)

    2014-03-15T23:59:59.000Z

    AlN–TiN multilayer structures can be used to extend the color gamut of hard coatings while maintaining good hardness and corrosion resistance. This study used reactive magnetron sputtering on a glass substrate to produce coatings with a microhardness of 19?GPa as well as optical reflectance exceeding 80% and controllable saturation (chroma) for various hues of red, yellow, green, blue, and purple. The authors characterized the complex index of refraction of the TiN films using ellipsometry; the real refractive indices of the AlN films were derived from the reflectance values obtained using photometry. Finally, the colors of the samples were quantified using CIE-1931 chromaticity coordinates in the L*a*b* color space, and the microhardness of the films was measured using a nanoindenter. Simulation results using a multiple-beam-interference recursive method presented good consistency with experimental measurements with regard to the optical reflective spectra of AlN–TiN multilayer thin film samples.

  16. Understanding the mechanism of conductivity at the LaAlO3/SrTiO3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    two band insulators LaAlO3 and SrTiO3 is both fascinating and potentially useful for next-generation electronics. The reigning paradigm to explain the conductivity phenomenon is an...

  17. Brazing ZrO{sub 2} ceramic to Ti–6Al–4V alloy using NiCrSiB amorphous filler foil: Interfacial microstructure and joint properties

    SciTech Connect (OSTI)

    Cao, J., E-mail: cao_jian@hit.edu.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Song, X.G., E-mail: song_xiaoguohit@yahoo.com.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Li, C., E-mail: li_chun1989@yahoo.cn [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Zhao, L.Y., E-mail: Zhao_ly@163.com [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Feng, J.C., E-mail: feng_jicai@163.com [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China)

    2013-07-15T23:59:59.000Z

    Reliable brazing of ZrO{sub 2} ceramic and Ti–6Al–4V alloy was achieved using NiCrSiB amorphous filler foil. The interfacial microstructure of ZrO{sub 2}/Ti–6Al–4V joints was characterized by scanning electron microscope, energy dispersive spectrometer and micro-focused X-ray diffractometer. The effects of brazing temperature on the interfacial microstructure and joining properties of brazed joints were investigated in detail. Active Ti of Ti–6Al–4V alloy dissolved into molten filler metal and reacted with ZrO{sub 2} ceramic to form a continuous TiO reaction layer, which played an important role in brazing. Various reaction phases including Ti{sub 2}Ni, Ti{sub 5}Si{sub 3} and ?-Ti were formed in brazed joints. With an increasing of brazing temperature, the TiO layer thickened gradually while the Ti{sub 2}Ni amount reduced. Shear test indicated that brazed joints tend to fracture at the interface between ZrO{sub 2} ceramic and brazing seam or Ti{sub 2}Ni intermetallic layer. The maximum average shear strength reached 284.6 MPa when brazed at 1025 °C for 10 min. - Graphical Abstract: Interfacial microstructure of ZrO{sub 2}/TC4 joint brazed using NiCrSiB amorphous filler foil was: ZrO{sub 2}/TiO/Ti{sub 2}Ni + ?-Ti + Ti{sub 5}Si{sub 3}/?-Ti/Widmanstätten structure/TC4. - Highlights: • Brazing of ZrO{sub 2} ceramic and Ti-6Al-4V alloy was achieved. • Interfacial microstructure was TiO/Ti{sub 2}Ni + ? + Ti{sub 5}Si{sub 3}/?/Widmanstätten structure. • The formation of TiO produced the darkening effect of ZrO{sub 2} ceramic. • The highest joining strength of 284.6MPa was obtained.

  18. Composition, morphology and mechanical properties of sputtered TiAlN coating

    SciTech Connect (OSTI)

    Budi, Esmar, E-mail: esmarbudi@unj.ac.id [Department of Physics, Faculty of Science and Mathematics, Universitas Negeri Jakarta, Jl. Pemuda No. 10, Jakarta 13220 (Indonesia); Razali, M. Mohd. [Faculty of Manufacturing Engineering, Universiti Teknikal Malaysia Melaka, Karung Berkunci No. 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia); Nizam, A. R. Md. [Faculty of Manufacturing Engineering, UniversitiTeknikal Malaysia Melaka, Karung Berkunci No. 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

    2014-03-24T23:59:59.000Z

    TiAlN coating was deposited on the tungsten carbide cutting tool by using DC magnetron sputtering system to study the influence of substrate bias and nitrogen flow rate on the composition, morphology and mechanical properties. The negatively substrate bias and nitrogen flow rate was varied from about ?79 to ?221 V and 30 sccm to 72 sccm, respectively. The coating composition and roughness were characterized by using SEM/EDX and Atomic Force Microscopy (AFM), respectively. The dynamic ultra micro hardness tester was used to measure the mechanical properties. The coating hardness increases to about 10-12 GPa with an increase of the negatively substrate bias up to ? 200 V and it tend to decrease with an increase in nitrogen flow rate up to 70 sccm. The increase of hardness follows the increase of Ti and N content and rms coating roughness.

  19. Current TES Capabilities in TRNSYS (Presentation)

    SciTech Connect (OSTI)

    Price, H.; Blair, N.

    2003-02-01T23:59:59.000Z

    This presentation includes: a brief overview of TRNSYS, a review of current SolarPaces models, potential of other models appropriate for CSP TES, and a review of a project proposal.

  20. Microstructure analysis of melt-spun Al{sub 3}Ti intermetallics by XRD and EXAFS

    SciTech Connect (OSTI)

    Chen, J.; Barrera, E.V. [Rice Univ., Houston, TX (United States). Dept. of Mechanical Engineering and Materials Science; Frazier, W.E. [Naval Air Warfare Center, Patuxent River, MD (United States). Aircraft Div.

    1997-12-31T23:59:59.000Z

    In an effort to expand the composition range over which Al{sub 3}Ti is stable, various amounts of niobium were substituted for titanium and processed by melt-spinning. Several samples were annealed both at 600 C and 1,000 C for 24 hours. The effects of processing parameters such as wheel speed, the amount of niobium, and annealing temperatures on the structure were investigated by XRD and EXAFS. XRD showed that for all the samples the only structure present was DO{sub 22}. The DO{sub 22} structure was stable even after the high temperature heat treatments. By means of EXAFS, niobium atoms were observed to occupy titanium sites in the DO{sub 22} structure. Furthermore, in the unannealed samples, increasing wheel speed of the melt spinning process or the niobium concentration tended to distort the crystal structure. It was observed that Ti EXAFS had different results from the Nb EXAFS beyond their occupying similar sites, which suggested there may exist some composition zones, i.e., rich Nb zone or rich Ti zones, although the structures present were still DO{sub 22}. The samples were found to experience different distortions as a function of annealing temperatures.

  1. In situ corrosion analysis of Al-Zn-In-Mg-Ti-Ce sacrificial anode alloy

    SciTech Connect (OSTI)

    Ma Jingling, E-mail: majingling.student@sina.com; Wen Jiuba; Zhai Wenxia; Li Quanan

    2012-03-15T23:59:59.000Z

    The corrosion behaviour of Al-5Zn-0.02In-1Mg-0.05Ti-0.5Ce (wt.%) alloy has been investigated by immersion test, scanning electron microscopy, energy dispersive X-ray detector, electrochemical impedance spectroscopy and electrochemical noise. The results show that there exist different corrosion types of the alloy in 3.5% NaCl solution with the immersion time. At the initial stage of immersion, pitting due to the precipitates predominates the corrosion with a typical inductive loop at low frequencies in electrochemical impedance spectroscopy. The major precipitates of the alloy are MgZn{sub 2} and Al{sub 2}CeZn{sub 2} particles. The corrosion potentials of the bulk MgZn{sub 2} and Al{sub 2}CeZn{sub 2} alloys are negative with respect to that of {alpha}-Al, so the MgZn{sub 2} and Al{sub 2}CeZn{sub 2} precipitates can act as activation centre and cause the pitting. In the late corrosion, a relative uniform corrosion predominates the corrosion process controlled by the dissolution/precipitation of the In ions and characterized by a capacitive loop at medium-high frequencies in electrochemical impedance spectroscopy. The potential noise of the pitting shows larger amplitude fluctuation and lower frequency, but the potential noise of the uniform corrosion occurs with smaller amplitude fluctuation and higher frequency.

  2. Ab initio study of irradiation tolerance for different M{sub n+1}AX{sub n} phases: Ti{sub 3}SiC{sub 2} and Ti{sub 3}AlC{sub 2}

    SciTech Connect (OSTI)

    Zhao, Shijun; Xue, Jianming, E-mail: jmxue@pku.edu.cn; Wang, Yugang [State Key Laboratory of Nuclear Physics and Technology, School of Physics, Peking University, Beijing 100871 (China); Center for Applied Physics and Technology, Peking University, Beijing 100871 (China); Huang, Qing [Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang (China)

    2014-01-14T23:59:59.000Z

    Layered ternary M{sub n+1}AX{sub n} (MAX) materials are recently proposed to be promising candidates for future fission and fusion programmes because of their unique properties inherited from both ceramics and metals. However, different M{sub n+1}AX{sub n} materials demonstrate different behaviors when exposed to energetic neutron or ion irradiations. Based on first-principles calculations, we have investigated the irradiation tolerance of two typical M{sub n+1}AX{sub n} materials: Ti{sub 3}SiC{sub 2} and Ti{sub 3}AlC{sub 2} from two aspects. First, we make a detailed analysis on the interatomic bonding characters, which are believed to be responsible for the resistance to radiation-induced amorphization. Second, the formation energies of various intrinsic and antisite defects in these two compounds are calculated in order to elucidate their amorphization mechanism. Our results show that the absence of orbitals overlap of Al-C in Ti{sub 3}AlC{sub 2} renders it more resistant to amorphization compared to Ti{sub 3}SiC{sub 2}. In addition, the antisite defects Al{sub Ti(1)} and Al{sub Ti(2)} in Ti{sub 3}AlC{sub 2} have much lower formation energies compared to Si{sub Ti(1)} and Si{sub Ti(2)} in Ti{sub 3}SiC{sub 2}, which implies that the replacement of Ti with Al is easier than Si, thus providing an alternative way to accommodate the defects resulted from irradiation damage cascades. These results indicate that Ti{sub 3}AlC{sub 2} is more irradiation tolerant than Ti{sub 3}SiC{sub 2}, in accordance with experimental observations. Our results have profound implications for the choice of appropriate MAX phase with best performance to be used in next reaction reactors.

  3. Microstructural evolution and characterisation of interfacial phases in Al2O3/Ag-Cu-Ti/Al2O3 braze joints

    E-Print Network [OSTI]

    Ali, M.; Knowles, K. M.; Mallinson, P. M.; Fernie, J. A.

    2015-06-14T23:59:59.000Z

    and alumina can generate residual stresses in the joints on cooling from Tp. The braze alloy is expected to help mitigate the mismatch in the coefficients of thermal expansion (CTE) by stress relaxation or creep deformation processes. High dislocation... ] attributed low flexural strengths obtained by four–point bend testing for Al2O3/Ti3Cu3O/Al2O3 joints that were held at 1290°C for 40 minutes to a lack of ductility in the Ti3Cu3O interlayer. The flexural strength values were not given, but it was stated...

  4. Tribological behavior of Ti-Al-Si-C-N hard coatings deposited by hybrid arc-enhanced magnetron sputtering

    SciTech Connect (OSTI)

    Wu Guizhi; Ma Shengli; Xu Kewei; Chu, Paul K [State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049 (China); Department of Physics and Materials Science, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon (Hong Kong)

    2012-03-15T23:59:59.000Z

    Ti-Al-Si-C-N hard coatings are deposited on high speed steel by hybrid arc-enhanced magnetron sputtering, and the hardness, adhesion, and tribological behavior are studied. On account of the nanocomposite structure, the coatings possess hardness of more than 30 GPa. Failure of the coating during the scratch test is due to the buckling and wedge spallation failure mechanism. Compared to Ti-Al-Si-N, the presence of C in the Ti-Al-Si-C-N coatings leads to reduced friction coefficient and wear rate, indicating effective lubrication rendered by amorphous C. According to the wear tracks examined by scanning electron microscopy, the wear mechanism can be explained by plowing abrasion.

  5. Tribological Characteristics of Single-phase AlMgB14 and Nanocomposite AlMgB14-TiB2 Superhard Coatings

    SciTech Connect (OSTI)

    Qu, Jun [ORNL; Blau, Peter Julian [ORNL; Zhu, Dong [Eaton Corporation; Cook, Bruce A [Ames Laboratory; Elmoursi, Alaa A [Eaton Corporation

    2008-01-01T23:59:59.000Z

    This study investigated the friction and wear characteristics of AlMgB14 and AlMgB14-TiB2 superhard coatings, produced by pulse laser deposition (PLD) and physical vapor deposition (PVD), respectively. Tests were conducted under unidirectional and reciprocating sliding against AISI 52100 bearing steel in both dry and oil-lubricated conditions. The AlMgB14 coating exhibited an encouraging but short-lived low friction stage (u = 0.2) in dry sliding. The AlMgB14-TiB2 coating reduced the wear rates by one order of magnitude for itself and three orders of magnitude for the counterface compared with the uncoated M2 tool steel in dry sliding. This nanocomposite coating also demonstrated significant extension (>2.5X) of the low friction (non-scuffing) stage in a lubricant starvation sliding.

  6. Microstructure characterization of laser welded Ti-6Al-4V fusion zones

    SciTech Connect (OSTI)

    Xu, Pei-quan; Li, Leijun, E-mail: leijun.li@ualberta.ca; Zhang, Chunbo

    2014-01-15T23:59:59.000Z

    The as-welded microstructure of laser-welded Ti-6Al-4V is characterized as a function of CO2 key-hole mode laser welding speed. Martensitic ?? is the predominant phase, with some ? and retained ?. Phase transformation is affected by the cooling rate through laser welding speed. A higher welding speed of 1.6 to 2.0 m/min produced more martensite ?? and less retained ? in the welds. 1.4 m/min welding speed produced small amounts of ?, besides the martensite ??. A trace of ? titanium hydride phase seems to have formed in the weld fusion zone. Moiré fringes are a common feature in the TEM microstructure, due to abundance of multi-phase interfaces. Tensile twins and clusters of dislocations indicate that plastic deformation has happened in the as-welded microstructure, indicating the local stress levels to be approaching the yield stress on-cooling during laser welding.

  7. Microstructure and Mechanical Behaviour of NbTiAl based alloys doped with low additions of silicon

    E-Print Network [OSTI]

    1 Microstructure and Mechanical Behaviour of NbTiAl based alloys doped with low additions Aerospace Lab, F-91761 Palaiseau, France zhao.zhao@onera.fr , anne.denquin@onera.fr , stefan.drawin@onera.fr , jonathan.barreau@onera.fr Keywords: Nb-base alloy; Silicides; Niobium aluminides; Phase transformation

  8. Interatomic potentials for atomistic simulations of the Ti-Al system Rajendra R. Zope and Y. Mishin*

    E-Print Network [OSTI]

    Mishin, Yuri

    In recent years, intermetallic alloys based on the gamma titanium aluminide TiAl have been the subject properties such as the nature of interatomic bonding, stability of crystal structures, elastic properties, dis- locations, grain boundaries, interfaces, as well as point de- fects and diffusion is therefore

  9. STATE OF CALIFORNIA THERMAL ENERGY STORAGE (TES) SYSTEM ACCEPTANCE

    E-Print Network [OSTI]

    STATE OF CALIFORNIA THERMAL ENERGY STORAGE (TES) SYSTEM ACCEPTANCE CEC-MECH-15A (Revised 07/10) CALIFORNIA ENERGY COMMISSION CERTIFICATE OF ACCEPTANCE MECH-15A NA7.5.14 Thermal Energy Storage (TES) System THERMAL ENERGY STORAGE (TES) SYSTEM ACCEPTANCE CEC-MECH-15A (Revised 07/10) CALIFORNIA ENERGY COMMISSION

  10. High-temperature phase transformation in Cr added TiAl base alloy

    SciTech Connect (OSTI)

    Abe, E.; Niinobe, K.; Nobuki, M.; Nakamura, M.; Tsujimoto, T.

    1999-07-01T23:59:59.000Z

    The authors have investigated a microstructure evolution of a Ti-48Al-3.5Cr (in at.%) alloy at high-temperatures ({gt} 1,473K). In the alloy annealed at 1673K for 1.8ks, followed by air-cooling, a characteristic microstructure with a feathery fashion was uniformly formed. From a cooling-rate-controlling study, it was found that formation of the feathery structure is accomplished during continuous cooling from 1673K to 1573K, within the {alpha} + {gamma} two-phase region. Transmission electron microscopy revealed that the feathery structure is composed of lamellar colonies (5--10{micro}m) which are crystallographically tilted slightly (a few degree) with their neighbors. A surprising fact is that lamellae in each colony are mostly the {gamma} phase with few {alpha}{sub 2} phase less than 5% in volume. This suggests that the feathery structure is a metastable product and has not resulted from the {alpha} {r{underscore}arrow} {alpha} + {gamma} transformation above 1,573 K. Instead, the feathery structure formation should be attributed to the non-equilibrium {alpha} {r{underscore}arrow} {gamma} transformation which occurs at high-temperatures with a small degree of supercooling. The authors discuss this interesting phase transformation in terms of the {alpha} {r{underscore}arrow} {gamma} massive transformation, based on the continuous-cooling-transformation (CCT) diagram constructed for the present alloy.

  11. XRCT characterisation of Ti particles inside porous Al{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Vasic, S., E-mail: srdan.vasic@unifr.ch [Technical Mineralogy Group, Institute of Mineralogy and Petrography, University of Fribourg, CH-1700 Fribourg (Switzerland); Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for High Performance Ceramics, Ueberlandstrasse 129, CH-8600 Duebendorf (Switzerland); Grobety, B. [Technical Mineralogy Group, Institute of Mineralogy and Petrography, University of Fribourg, CH-1700 Fribourg (Switzerland); Kuebler, J., E-mail: jakob.kuebler@empa.ch [Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for High Performance Ceramics, Ueberlandstrasse 129, CH-8600 Duebendorf (Switzerland); Graule, T. [Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for High Performance Ceramics, Ueberlandstrasse 129, CH-8600 Duebendorf (Switzerland); Baumgartner, L. [Institute of Mineralogy and Petrography, Earth Science, University of Lausanne, CH-1100 Lausanne (Switzerland)

    2010-06-15T23:59:59.000Z

    Computed X-ray tomography was used to characterise distribution and sphericity of Ti granules within highly porous (> 35%) Al{sub 2}O{sub 3} powder compacts, as they are key parameters for a successful infiltration by Fe-based alloys. Setting of reconstruction constraints, image editing as well as data processing are the most challenging parts of computed X-ray tomography and principal sources of errors that bias the generated data. Thus, corrective measures have to be applied and the reliability of generated data has to be proved with respect to statistical, stereological and volumetric aspects. Combining an adapted Interface Particle Treatment Algorithm with the Marching Cube Method, Equilibrium Random State Model, cluster splitting and conventional laser diffraction measurements a significant improvement of the three-dimensional reconstructed data was achieved. This study points out the need of the applied algorithms for the proof and improvement of generated data by computed X-ray tomography and gives a short survey of methods that can be applied.

  12. Arc distribution during the vacuum arc remelting of Ti-6Al-4V

    SciTech Connect (OSTI)

    Woodside, Charles Rigel [U.S. DOE; King, Paul E. [U.S. DOE; Nordlund, Chris [ATI Albany Operations

    2013-01-01T23:59:59.000Z

    Currently, the temporal distribution of electric arcs across the ingot during vacuum arc remelting (VAR) is not a known or monitored process parameter. Previous studies indicate that the distribution of arcs can be neither diffuse nor axisymmetric about the center of the furnace. Correct accounting for the heat flux, electric current flux, and mass flux into the ingot is critical to achieving realistic solidification models of the VAR process. The National Energy Technology Laboratory has developed an arc position measurement system capable of locating arcs and determining the arc distribution within an industrial VAR furnace. The system is based on noninvasive magnetic field measurements and a VAR specific form of the Biot–Savart law. The system was installed on a coaxial industrial VAR furnace at ATI Albany Operations in Albany, OR. This article reports on the different arc distributions observed during production of Ti-6Al-4V. It is shown that several characteristic arc distribution modes can develop. This behavior is not apparent in the existing signals used to control the furnace, indicating the measurement system is providing new information. It is also shown that the different arc distribution modes observed may impact local solidification times, particularly at the side wall.

  13. Fracture toughness of Ti-6Al-4V after welding and postweld heat treatment

    SciTech Connect (OSTI)

    Murthy, K.K.; Sundaresan, S. [Indian Inst. of Tech., Madras (India). Dept. of Metallurgical Engineering

    1997-02-01T23:59:59.000Z

    The fracture toughness (J{sub IC}) of the fusion zone of Ti-6Al-4V alloy welds was studied in terms of microstructural changes in the as-welded condition and following postweld heat treatment. Gas tungsten arc and electron beam welds were produced in sheet material over a limited range of heat input and subsequently heat treated at 700 C and 900 C. In the as-welded condition, the weld microstructure was a mixture of diffusional and martensitic alpha phases, whose proportion varied wit heat input and cooling rate. The fusion zone exhibited low ductility resulting from the highly acicular microstructure and a large prior-beta grain size. Postweld heat treatment tempered the martensite and coarsened the microstructure, but a beneficial effect on ductility was realized only after treatment at 900 C. Fracture toughness in the as-welded condition was greater than for the base metal and was attributed to the lamellar microstructure of the fusion zone and absence of continuous alpha film along the grain boundaries. Postweld heat treatment at 700 C reduced the fracture toughness considerably and, as in the case of ductility, it was necessary to heat treat at 900 C to produce an improvement.

  14. Influence of plasma density on the chemical composition and structural properties of pulsed laser deposited TiAlN thin films

    SciTech Connect (OSTI)

    Quiñones-Galván, J. G.; Camps, Enrique [Departamento de Física, Instituto Nacional de Investigaciones Nucleares, Apartado Postal 18-1027, México D.F. C.P. 11801 (Mexico); Muhl, S. [Instituto de Investigaciones en Materiales, UNAM, México D.F. C.P. 04510 (Mexico); Flores, M. [Departamento de Ingeniería de Proyectos, CUCEI, Universidad de Guadalajara, Apdo. Postal 307, C.P. 45101 Zapopan, Jalisco (Mexico); Campos-González, E. [Departamento de Física, CINVESTAV-IPN, Apdo. Postal 14-740, México D.F. 07360 (Mexico)

    2014-05-15T23:59:59.000Z

    Incorporation of substitutional Al into the TiN lattice of the ternary alloy TiAlN results in a material with improved properties compared to TiN. In this work, TiAlN thin films were grown by the simultaneous ablation of Ti and Al targets in a nitrogen containing reactive atmosphere. The deposit was formed on silicon substrates at low deposition temperature (200?°C). The dependence of the Al content of the films was studied as a function of the ion density of the plasma produced by the laser ablation of the Al target. The plasma parameters were measured by means of a planar Langmuir probe and optical emission spectroscopy. The chemical composition of the films was measured by energy dispersive X-ray spectroscopy. The results showed a strong dependence of the amount of aluminum incorporated in the films with the plasma density. The structural characterization of the deposits was carried out by Raman spectroscopy, X-ray diffraction, and transmission electron microscopy, where the substitutional incorporation of the Al into the TiN was demonstrated.

  15. Stoichiometry dependence of potential screening at La ( 1 - ? ) Al ( 1 + ? ) O 3 / SrTiO 3 interfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Weiland, Conan; Sterbinsky, George E.; Rumaiz, Abdul K.; Hellberg, C. Stephen; Woicik, Joseph C.; Zhu, Shaobo; Schlom, Darrell G.

    2015-04-01T23:59:59.000Z

    Hard x-ray photoelectron spectroscopy (HAXPES) and variable kinetic energy x-ray photoelectron spectroscopy (VKE-XPS) analyses have been performed on ten-unit-cell-thick La(1-?)Al(1+?)O? films, with La:Al ratios of 1.1, 1.0, and 0.9, deposited on SrTiO?. Only Al-rich films are known to have a conductive interface. VKE-XPS, coupled with maximum entropy analysis, shows significant differences in the compositional depth profile among the Al-rich, La-rich, and stoichiometric films: significant La enrichment at the interface is observed in the La-rich and stoichiometric films, while the Al-rich film shows little to no intermixing. Additionally, the La-rich and stoichiometric films show a high concentration of Al at the surface, which is not observed in the Al-rich film. HAXPES valence band (VB) analysis shows a broadening of the VB for the Al-rich sample relative to the stoichiometric and La-rich samples. This broadening is consistent with an electric field across the Al-rich film. These results are consistent with a defect-driven electronic reconstruction.

  16. On the preparation of TiAl alloy by direct reduction of the oxide mixtures in calcium chloride melt

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Derek J. Fray

    2011-11-01T23:59:59.000Z

    In recent years, TiAl-based intermetallic alloys are being increasingly considered for application in areas such as (i) automobile/transport sector (passenger cars, trucks and ships) (ii) aerospace industry (jet engines and High Speed Civil Transport propulsion system) and (iii) industrial gas turbines. These materials offer excellent (i) high temperature properties (at higher than 6000C) (ii) mechanical strength and (iii) resistance to corrosion and as a result have raised renewed interest. The combination of these properties make them possible replacement materials for traditional nickel-based super-alloys, which are nearly as twice as dense (than TiAl based alloys). Since the microstructures of these intermetallic alloys affect, to a significant extent, their ultimate performance, further improvements (by way of alteration/modification of these microstructures), have been the subject matter of intense research investigations. It has now been established that the presence of alloy additives, such as niobium, tantalum, manganese, boron, chromium, silicon, nickel and yttrium etc, in specific quantities, impart marked improvement to the properties, viz. fatigue strength, fracture toughness, oxidation resistance and room temperature ductility, of these alloys. From a number of possible alloy compositions, {gamma}-TiAl and Ti-Al-Nb-Cr have, of late, emerged as two promising engineering alloys/materials. . The conventional fabrication process of these alloys include steps such as melting, forging and heat treatment/annealing of the alloy compositions. However, an electrochemical process offers an attractive proposition to prepare these alloys, directly from the mixture of the respective oxides, in just one step. The experimental approach, in this new process, was, therefore, to try to electrochemically reduce the (mixed) oxide pellet to an alloy phase. The removal of oxygen, from the (mixed) oxide pellet, was effected by polarizing the oxide pellet against a graphite electrode in a pool of molten calcium chloride at a temperature of 9000C. The dominant mechanism of the oxygen removal was the ionization of oxygen followed by its subsequent discharge, as CO2/CO, at the anode surface. The removal of oxygen from the oxide mixture helped form the alloy in situ. The presentation shall cover the detailed experimental results pertaining to the preparation, evaluation and characterization of Ti-47Al-2Nb-2Cr (atom%) alloy.

  17. NON-CONTACT ACOUSTO-THERMAL SIGNATURES OF PLASTIC DEFORMATION IN TI-6AL-4V

    SciTech Connect (OSTI)

    Welter, J. T.; Jata, K. V.; Blodgett, M. P. [Materials and Manufacturing Directorate, Nondestructive Evaluation Branch Wright-Patterson AFB, OH 45433 (United States); Malott, G. [SOCHE, 3155 Research Blvd, Dayton, OH 45420 (United States); Schehl, N.; Sathish, S. [Structural Integrity Division, University of Dayton Research Institute, Dayton, OH 45469 (United States)

    2010-02-22T23:59:59.000Z

    Plastic deformation introduces changes in a material which include increases in: dislocations, strains, residual stress, and yield stress. However, these changes have a very small impact on the material properties such as elastic modulus, conductivity and ultrasonic wave speed. This is due to the fact that interatomic forces govern these properties, and they are not affected by plastic deformation to any large degree. This is evident from the fact that the changes in electrical resistance and ultrasonic velocity in plastically deformed and virgin samples are very small and can only be determined by highly controlled experiments. Except for X-ray diffraction, there are no direct nondestructive methods for measuring strain and the residual stress. This paper presents an application of the non-contact acousto-thermal signature (NCATS) NDE methodology to detect plastic deformation in flat dog bone Ti-6Al-4V samples. Results of the NCATS measurements on samples subjected to incremental amounts of plastic deformation are presented. The maximum temperature attained by the sample due to acoustic excitation is found to be sensitive to the amount of plastic strain. It is observed that the temperature induced by acoustic excitation increases to a peak followed by a decrease to failure. The maximum temperature peak occurs at plastic strains of 12-14%. It is observed that there is a correlation between the peak in maximum temperature rise and the strain at the experimentally determined ultimate tensile strength. A microstructural based explanation for this will be presented. The results are discussed in reference to utilizing this technique for detection and evaluation of plastic deformation.

  18. Materials Science and Engineering A311 (2001) 8399 Combustion synthesis/densification of an Al2O3 TiB2 composite

    E-Print Network [OSTI]

    Meyers, Marc A.

    2000 Abstract The self-propagating gasless combustion reaction 3TiO2 +3B2O3 +10Al5Al2O2 +3TiB2 was used of reaction. The densification was enabled by the high temperatures produced by the combustion reaction (:2000 studied in the US [5­11] and Japan [12­16]. A self-propagating gasless (virtually) combustion wave

  19. Low Phase-Noise 5 GHz AlGaN/GaN HEMT Oscillator Integrated with BaxSr1-xTiO3 Thin Films

    E-Print Network [OSTI]

    York, Robert A.

    Low Phase-Noise 5 GHz AlGaN/GaN HEMT Oscillator Integrated with BaxSr1-xTiO3 Thin Films Hongtao Xu -- A C-band MMIC oscillator in GaN HEMT technology with BaxSr1-xTiO3 (BST) film capacitors integrated with the common gate HEMT to generate negative resistance. The oscillator, based on AlGaN/GaN HEMT with 0.7um gate

  20. Tes Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with formSoutheasternInformation Tengchong CountyTerniEnergiaTersus EnergyTes

  1. Operation of ohmic Ti/Al/Pt/Au multilayer contacts to GaN at 600?°C in air

    SciTech Connect (OSTI)

    Hou, Minmin, E-mail: mmhou@stanford.edu [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States); Senesky, Debbie G. [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States); Department of Aeronautics and Astronautics, Stanford University, Stanford, California 94305 (United States)

    2014-08-25T23:59:59.000Z

    The high-temperature characteristics (at 600?°C) of Ti/Al/Pt/Au multilayer contacts to gallium nitride (GaN) in air are reported. Microfabricated circular-transfer-line-method test structures were subject to 10 h of thermal storage at 600?°C. Intermittent electrical characterization during thermal storage showed minimal variation in the contact resistance after 2 h and that the specific contact resistivity remained on the order of 10{sup ?5} ?-cm{sup 2}. In addition, the thermally stored multilayer contacts to GaN showed ohmic I-V characteristics when electrically probed at 600?°C. The microstructural analysis with atomic force microscopy showed minimal changes in surface roughness after thermal storage. Observations of the thermochemical reactions after thermal storage using Auger electron spectroscopy chemical depth profiling showed diffusion of Pt and minimal additional Al oxidation. The results support the use of Ti/Al/Pt/Au multilayer metallization for GaN-based sensors and electronic devices that will operate within a high-temperature and oxidizing ambient.

  2. Dissimilar-alloy laser welding of titanium: Ti6Al-4V to Beta-C{trademark}

    SciTech Connect (OSTI)

    Liu, P.S.; Baeslack, W.A. III; Hurley, J.

    1994-12-31T23:59:59.000Z

    Beta-C{sup TM} is a metastable-beta titanium alloy (nominal composition: Ti-3wt%Al-8wt%V-6wtTCr-4wt%Mo-4wt%Zr) which can be thermomechanically processed and heat treated to provide excellent combinations of strength, ductility, and fracture toughness. Recently, the increased application of metastable-beta titanium alloys in aerospace and commercial applications has resulted in the necessity to join these alloys to conventional alpha-beta titanium alloys. Based on this previous work, two approaches were considered for improving the ductility of dissimilar-alloy welds between Ti-6Al-4V and Beta-C{sup TM} in the present study: (1) application of a low heat input welding process to minimize the fusion zone and heat-affected zone (HAZ) beta grain size and (2) modification of the fusion zone chemical composition to allow greater microstructural optimization through postweld aging. CO{sub 2} laser welds were produced between Ti-6Al-4V and Beta-C{sup TM} sheet. Three different nominal fusion zone chemical compositions were obtained by varying the laser beam locations relative to the joint centerline and thereby melting different quantities of each base metal. For comparable postweld aging conditions, the laser welds exhibited ductilities superior to those of coarse-grained gas tungsten arc welds. Fracture analysis of the weld zone revealed a transition from a predominantly transgranular fracture in the low-temperature aged conditions to increasingly intergranular fracture following aging at higher temperature. This transition was promoted by an increase in the thickness and continuity of alpha phase at beta grain boundaries.

  3. Effects of rapid thermal annealing on the electrical properties of the AlGaN/AlN/GaN heterostructure field-effect transistors with Ti/Al/Ni/Au gate electrodes

    SciTech Connect (OSTI)

    Zhao, Jingtao; Lin, Zhaojun, E-mail: linzj@sdu.edu.cn; Luan, Chongbiao; Zhou, Yang; Yang, Ming [School of Physics, Shandong University, Jinan 250100 (China); Lv, Yuanjie; Feng, Zhihong [National Key Laboratory of Application Specific Integrated Circuit (ASIC), Hebei Semiconductor Research Institute, Shijiazhuang 050051 (China)

    2014-08-25T23:59:59.000Z

    In this study, we investigated the electrical properties of the AlGaN/AlN/GaN heterostructure field-effect transistors (HFETs) with Ti/Al/Ni/Au gate electrodes using the measured capacitance-voltage, current-voltage characteristics, and micro-Raman spectroscopy. We found that the uneven distribution of the strain caused by the Schottky metals was a major factor that generates the polarization Coulomb field scattering in AlGaN/AlN/GaN HFETs, and after appropriate rapid thermal annealing (RTA) processes, the polarization Coulomb field scattering was greatly weakened and the two-dimensional electron gas electron mobility was improved. We also found that the Schottky barrier height and the DC characteristics of the devices became better after appropriate RTA. Of course, the electrical performances mentioned above became deteriorated after excessive annealing.

  4. Octahedral rotations in strained LaAlO{sub 3}/SrTiO{sub 3} (001) heterostructures

    SciTech Connect (OSTI)

    Fister, T. T.; Hruszkewycz, S. O.; Proffit, D. L.; Eastman, J. A.; Fuoss, P. H.; Baldo, P. M.; Fong, D. D. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Zhou, H. [X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Luo, Z. [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Seo, S. S. A.; Lee, H. N. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

    2014-02-01T23:59:59.000Z

    Many complex oxides display an array of structural instabilities often tied to altered electronic behavior. For oxide heterostructures, several different interfacial effects can dramatically change the nature of these instabilities. Here, we investigate LaAlO{sub 3}/SrTiO{sub 3} (001) heterostructures using synchrotron x-ray scattering. We find that when cooling from high temperature, LaAlO{sub 3} transforms from the Pm3{sup ¯}m to the Imma phase due to strain. Furthermore, the first 4 unit cells of the film adjacent to the substrate exhibit a gradient in rotation angle that can couple with polar displacements in films thinner than that necessary for 2D electron gas formation.

  5. Modulation of conductance and superconductivity by top-gating in LaAlO{sub 3}/SrTiO{sub 3} 2-dimensional electron systems

    SciTech Connect (OSTI)

    Eerkes, P. D.; Wiel, W. G. van der; Hilgenkamp, H. [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)] [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2013-11-11T23:59:59.000Z

    We report the electrical top-gating of a 2-dimensional electron gas (2DEG) formed at the LaAlO{sub 3}/SrTiO{sub 3} interface, using electron-beam evaporated Au gate electrodes. In these structures, epitaxial LaAlO{sub 3} films grown by pulsed laser deposition induce the 2DEGs at the interface to the SrTiO{sub 3} substrate and simultaneously act as the gate dielectric. The structured top-gates enable a local tuning and complete on/off switching of the interface (super-)conductivity, while maintaining the usual, intrinsic characteristics for these LaAlO{sub 3}/SrTiO{sub 3} interfaces when no gate voltage is applied.

  6. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries

    SciTech Connect (OSTI)

    Xu, Wu; Chen, Xilin; Wang, Wei; Choi, Daiwon; Ding, Fei; Zheng, Jianming; Nie, Zimin; Choi, Young Joon; Zhang, Jiguang; Yang, Zhenguo

    2013-08-15T23:59:59.000Z

    The commercial Li4Ti5O12 (LTO) is successfully modified by AlF3 via a low temperature process. After being calcined at 400oC for 5 hours, AlF3 reacts with LTO to form a composite material which mainly consists of Al3+ and F- co-doped LTO with small amounts of anatase TiO2 and Li3AlF6. Al3+ and F- co-doped LTO demonstrates largely improved rate capability comparing to the pristine LTO. Since the amount of the byproduct TiO2 is relatively small, the modified LTO electrodes retain the main voltage characteristics of LTO with a minor feature similar to those of anatase TiO2. The doped LTO anodes deliver higher discharge capacity and significantly improved high-rate performance when compared to the pristine LTO anode. They also demonstrate excellent long-term cycling stability at elevated temperatures. Therefore, Al3+ and F- co-doped LTO synthesized at low temperature is an excellent anode for stable and ultra-high power lithium-ion batteries.

  7. Effect of oxygen incorporation on the structure and elasticity of Ti-Al-O-N coatings synthesized by cathodic arc and high power pulsed magnetron sputtering

    SciTech Connect (OSTI)

    Hans, M., E-mail: hans@mch.rwth-aachen.de; Baben, M. to; Music, D.; Ebenhöch, J.; Schneider, J. M. [Materials Chemistry, RWTH Aachen University, Kopernikusstr. 10, D-52074 Aachen (Germany); Primetzhofer, D. [Department of Physics and Astronomy, Uppsala University, Lägerhyddsvägen 1, S-75120 Uppsala (Sweden); Kurapov, D.; Arndt, M.; Rudigier, H. [Oerlikon Balzers Coating AG, Iramali 18, LI-9496 Balzers, Principality of Liechtenstein (Liechtenstein)

    2014-09-07T23:59:59.000Z

    Ti-Al-O-N coatings were synthesized by cathodic arc and high power pulsed magnetron sputtering. The chemical composition of the coatings was determined by means of elastic recoil detection analysis and energy dispersive X-ray spectroscopy. The effect of oxygen incorporation on the stress-free lattice parameters and Young's moduli of Ti-Al-O-N coatings was investigated by X-ray diffraction and nanoindentation, respectively. As nitrogen is substituted by oxygen, implications for the charge balance may be expected. A reduction in equilibrium volume with increasing O concentration is identified by X-ray diffraction and density functional theory calculations of Ti-Al-O-N supercells reveal the concomitant formation of metal vacancies. Hence, the oxygen incorporation-induced formation of metal vacancies enables charge balancing. Furthermore, nanoindentation experiments reveal a decrease in elastic modulus with increasing O concentration. Based on ab initio data, two causes can be identified for this: First, the metal vacancy-induced reduction in elasticity; and second, the formation of, compared to the corresponding metal nitride bonds, relatively weak Ti-O and Al-O bonds.

  8. Influence of oxygen pressure and aging on LaAlO{sub 3} films grown by pulsed laser deposition on SrTiO{sub 3} substrates

    SciTech Connect (OSTI)

    Park, Jihwey; Aeppli, Gabriel [London Centre for Nanotechnology, University College London, London WC1H 0AH (United Kingdom); Soh, Yeong-Ah, E-mail: yeongahsoh@gmail.com [London Centre for Nanotechnology, University College London, London WC1H 0AH (United Kingdom); Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom); David, Adrian; Lin, Weinan [Division of Physics and Applied Physics, Nanyang Technological University, Singapore 637371 (Singapore); Wu, Tom [Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955-6900 (Saudi Arabia)

    2014-02-24T23:59:59.000Z

    The crystal structures of LaAlO{sub 3} films grown by pulsed laser deposition on SrTiO{sub 3} substrates at oxygen pressure of 10{sup ?3} millibars or 10{sup ?5} millibars, where kinetics of ablated species hardly depend on oxygen background pressure, are compared. Our results show that the interface between LaAlO{sub 3} and SrTiO{sub 3} is sharper when the oxygen pressure is lower. Over time, the formation of various crystalline phases is observed while the crystalline thickness of the LaAlO{sub 3} layer remains unchanged. X-ray scattering as well as atomic force microscopy measurements indicate three-dimensional growth of such phases, which appear to be fed from an amorphous capping layer present in as-grown samples.

  9. Oxynitrided Surface Layer Produced On Ti6Al4V Titanium Alloy Under Low Temperature Glow Discharge Conditions For Medical Applications

    SciTech Connect (OSTI)

    Wierzchon, T.; Ossowski, M.; Borowski, T. [Faculty of Materials Science and Engineering, Warsaw University of Technology, 141 Woloska Str, 02-507 Warsaw (Poland); Morgiel, J. [Institute of Metallurgy and Materials Science, Polish Academy of Science, 25 Reymonta Str, 30-059 Cracow (Poland); Czarnowska, E. [Department of Pathology, The Children's Memorial Health Institute, 20 Dzieci Polskich Av., 04-730 Warsaw (Poland)

    2011-01-17T23:59:59.000Z

    In spite that titanium oxides increase biocompatibility of titanium implants but their functional life is limited due to the problems arising from brittles and metalosis. Therefore technology, that allow to produce composite surface layer with controlled microstructure, chemical and phase composition and surface morphology on titanium alloy and eliminates the oxides disadvantages has been existing till now is searched. The requirements of titanium and its alloys implants can be fulfill by the low-temperature glow discharge assisted oxynitriding.The paper describes the surface layer of TiO{sub 2}+TiN+Ti{sub 2}N+{alpha}Ti(N) type produced at temperature 680 deg. C that preserves mechanical properties of titanium alloy Ti6Al4V. Characteristics of produced diffusion multi-phase surface layers in range of phase composition, microstructure (SEM, TEM, XRD) and its properties, such as frictional wear resistance are presented. The biological properties in dependency to the applied sterilization method are also analyzed.Properties of produced surface layers are discussed with reference to titanium alloy. The obtained data show that produced surface layers improves titanium alloy properties both frictional wear and biological. Preliminary in vitro examinations show good biocompatibility and antithrombogenic properties.

  10. A study into effects of CO{sub 2} laser melting of nitrided Ti-6Al-4V alloy

    SciTech Connect (OSTI)

    Mohammed, M.A. [Saudi Aramco, Dhahran (Saudi Arabia); Hashmi, M.S.J. [Dublin City Univ. (Ireland); Yilbas, B.S. [KFDUPM, Dhahran (Saudi Arabia)

    1997-10-01T23:59:59.000Z

    Multiple treatment of engineering surfaces can provide improved surface properties that cannot be obtained by a single surface treatment. Consequently, this study investigates the effects of laser melting on the microstructures of plasma nitrided Ti-6Al-4V alloy. The study consists of two parts. In the first part, governing equations pertinent to the laser melting process are developed, and temperature variation across the melted zone is predicted. In the second, an experiment is conducted to nitride the surface of the alloy through plasma nitriding process and to melt the plasma nitrided and the untreated alloy surfaces with a CO{sub 2} laser beam. The resulting metallurgical changes are examined using x-ray diffraction (XRD), energy-dispersive spectrometry (EDS), and scanning electron microscopy (SEM) techniques. It is shown that three distinct nitride layers are formed in the vicinity of the alloy surface prior to the laser melting process, and that after the melting process nitrided species are depleted while cellular and dendritic structures are formed. In addition, the structure consisting of transformed {beta} containing coarse and fine acicular {alpha} is observed in the melted regions.

  11. Analysis of Wear Mechanisms in Low Friction, Nanocomposite AlMgB14-TiB2 Coatings

    SciTech Connect (OSTI)

    Cook, Bruce A [Ames Laboratory; Harringa, J [Ames Laboratory; Anderegg, A [Ames Laboratory; Russell, A M [Iowa State University; Qu, Jun [ORNL; Blau, Peter Julian [ORNL; Higdon, Clifton [Eaton Corporation; Elmoursi, Alaa A [Eaton Corporation

    2010-01-01T23:59:59.000Z

    Recent developments in coating science and technology offer new opportunities to enhance the energy-efficiency and performance of industrial machinery such as hydraulic fluid pumps and motors. The lubricated friction and wear characteristics of two wear-resistant coatings, diamond-like carbon and a nanocomposite material based on AlMgB{sub 14}-50 vol.% TiB{sub 2}, were compared in pin-on-disk tribotests using Mobil DTE-24{trademark} oil as the lubricant. In each case, the pins were fixed 9.53 mm diameter spheres of AISI 52100 steel, the load was 10 N, and the speed 0.5 m/s in all tests. Average steady-state friction coefficient values of 0.10 and 0.08 were measured for the DLC and nanocomposite, respectively. The coatings and their 52100 steel counterfaces were analyzed after the tests by X-ray photoelectron and Auger spectroscopy for evidence of material transfer or tribo-chemical reactions. The low-friction behavior of the boride nanocomposite coating is due to the formation of lubricative boric acid, B(OH){sub 3}. In contrast, the low-friction behavior of the DLC coating is related to the relatively low dielectric constant of the oil-based lubricant, leading to desorption of surface hydrogen from the coating.

  12. Wear Mechanism of Chemical Vapor Deposition (CVD) Carbide Insert in Orthogonal Cutting Ti-6Al-4V ELI at High Cutting Speed

    SciTech Connect (OSTI)

    Gusri, A. I.; Che Hassan, C. H.; Jaharah, A. G. [Mechanical and Material Engineering Department, Universiti Kebangsaan Malaysia, Bangi 43600 (Malaysia)

    2011-01-17T23:59:59.000Z

    The performance of Chemical Vapor Deposition (CVD) carbide insert with ISO designation of CCMT 12 04 04 LF, when turning titanium alloys was investigated. There were four layers of coating materials for this insert i.e.TiN-Al2O3-TiCN-TiN. The insert performance was evaluated based on the insert's edge resistant towards the machining parameters used at high cutting speed range of machining Ti-6Al-4V ELI. Detailed study on the wear mechanism at the cutting edge of CVD carbide tools was carried out at cutting speed of 55-95 m/min, feed rate of 0.15-0.35 mm/rev and depth of cut of 0.10-0.20 mm. Wear mechanisms such as abrasive and adhesive were observed on the flank face. Crater wear due to diffusion was also observed on the rake race. The abrasive wear occurred more at nose radius and the fracture on tool were found at the feed rate of 0.35 mm/rev and the depth of cut of 0.20 mm. The adhesion wear takes place after the removal of the coating or coating delaminating. Therefore, adhesion or welding of titanium alloy onto the flank and rake faces demonstrates a strong bond at the workpiece-tool interface.

  13. Structure and magnetic properties of L1{sub 0}-FePt thin films on TiN/RuAl underlayers

    SciTech Connect (OSTI)

    Yang En; Ratanaphan, Sutatch [Data Storage Systems Center, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); Zhu Jiangang [Data Storage Systems Center, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); ABB Professor of Engineering Department of Electrical and Computer Engineering, Data Storage Systems Center, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); Laughlin, David E. [Data Storage Systems Center, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); ALCOA Professor of Physical Metallurgy Materials Science and Engineering Department, Data Storage Systems Center, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)

    2011-04-01T23:59:59.000Z

    Highly ordered L1{sub 0} FePt-oxide thin films with small grains were prepared by using a RuAl layer as a grain size defining seed layer along with a TiN barrier layer. Different HAMR (Heat Assisted Magnetic Recording) favorable underlayers were studied to encourage perpendicular texture and preferred microstructure. It was found that the epitaxial and small grain growth from the RuAl/TiN underlayer results in small and uniform grains in the FePt layer with perpendicular texture. By introducing the grain size defining underlayers, the FePt grain size can be reduced from 30 to 6 nm with the same volume fraction (9%) of SiO{sub 2} in the film, excellent perpendicular texture, and very high order parameter at 520 deg. C.

  14. Web Based Training (WEB BT) TES employees can get free training on applications within

    E-Print Network [OSTI]

    Tsien, Roger Y.

    Web Based Training (WEB BT) TES employees can get free training on applications within office applications and more. Each tutorial can last up to 4 hours. TES schedules training time, in the TES Office to scheduling. Registration Criteria · Training must not conflict with your current assignment. (We suggest

  15. Spatial density profile of electrons near the LaAlO{sub 3}/SrTiO{sub 3} heterointerface revealed by time-resolved photoluminescence spectroscopy

    SciTech Connect (OSTI)

    Yamada, Yasuhiro, E-mail: yamada.yasuhiro.6c@kyoto-u.ac.jp; Kanemitsu, Yoshihiko [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan); Sato, Hiroki K. [SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, Menlo Park, California 94025 (United States); Department of Advanced Materials Science, The University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Hikita, Yasuyuki [SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, Menlo Park, California 94025 (United States); Hwang, Harold Y. [SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, Menlo Park, California 94025 (United States); Geballe Laboratory for Advanced Materials, Department of Applied Physics, Stanford University, Stanford, California 94305 (United States)

    2014-04-14T23:59:59.000Z

    The depth profile of the electron density near the LaAlO{sub 3}/SrTiO{sub 3} heterointerface has been studied by means of time-resolved photoluminescence (PL) spectroscopy. A broad blue PL band is observed at 2.9?eV, originating from the two-carrier radiative recombination of interface-induced electrons and photoexcited holes. The PL lifetime of LaAlO{sub 3}/SrTiO{sub 3} heterointerface is dominated by the three-carrier Auger recombination of electrons and holes and is sensitive to electron density. We tuned the probing depth by changing the excitation photon energy and evaluated the carrier-density profile using the relation between the carrier density and the PL lifetime. Our non-contact probe method based on PL spectroscopy indicates that the carriers are confined within several nanometers in depth near the LaAlO{sub 3}/SrTiO{sub 3} heterostructures.

  16. Dehydrogenation of pure and Ti-doped Na3AlH6 surfaces from first principles calculations

    E-Print Network [OSTI]

    Alfè, Dario

    5 October 2011 Keywords: Sodium alanates Titanium catalyst Hydrogen absorption First principles with Ti, we found that the segregation energy of Ti is negative, therefore favoring localization the energy barrier that the molecule needs to climb to leave the surface. Copyright ª 2011, Hydrogen Energy

  17. Infrared photorefractive passive phase conjugation with BaTiO/sub 3/: Demonstrations with GaAlAs and 1. 09-. mu. m Ar/sup +/ lasers

    SciTech Connect (OSTI)

    Cronin-Golomb, M.; Lau, K.Y.; Yariv, A.

    1985-09-15T23:59:59.000Z

    We report photorefractive passive phase conjugation of GaAlAs laser radiation at 815--865 nm and Ar/sup +/ laser radiation at 1090 nm. A ring passive phase conjugate mirror was used with BaTiO/sub 3/ as the real-time holographic gain medium. With GaAlAs lasers phase conjugate reflectivities of up to 16% uncorrected for Fresnel losses were recorded. Effects of the strong associated feedback to the laser and attempts at mode locking are described. At 1090 nm the reflectivity remains approximately the same, but with a significantly longer time constant.

  18. Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95Cb(Nb) - 2.5Ti - 0.70Al - 7.0Fe Annealed

    E-Print Network [OSTI]

    SAE Aerospace Standards. London

    2012-01-01T23:59:59.000Z

    Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95Cb(Nb) - 2.5Ti - 0.70Al - 7.0Fe Annealed

  19. First-principles study of site occupancy of 3d, 4d and 5d transition-metal elements in L10TiAl

    SciTech Connect (OSTI)

    Jiang, Chao [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    Using a statistical-mechanical Wagner-Schottky model parametrized by first-principles density-functional (DFT-GGA) calculations on 32-atom supercells, we predict the lattice site occupancy of 3d (Ti-Cu), 4d (Zr-Ag) and 5d (Hf-Au) transition-metal elements in L10 TiAl intermetallic compound as a function of both alloy composition and temperature. The effects of local atomic relaxations, anisotropic lattice distortions, as well as magnetism on point defect energetics are fully taken into account. Our calculations show that, at all alloy compositions and temperatures, Zr and Hf consistently show a preference for the Ti sublattice, while Co, Ru, Rh, Pd, Ag, Re, Os, Ir, Pt and Au consistently show a preference for the Al sublattice. In contrast, the site preference of V, Cr, Mn, Fe, Ni, Cu, Nb, Mo, Tc, Ta and W strongly depend on both alloy stoichiometry and temperature. Our calculated results compare favorably with the existing theoretical and experimental studies in the literature.

  20. Epitaxial properties of Al-doped ZnO thin films grown by pulsed laser deposition on SrTiO{sub 3}(001)

    SciTech Connect (OSTI)

    Karger, M.; Schilling, M. [Technische Universitaet Braunschweig, Institut fuer Elektrische Messtechnik und Grundlagen der Elektrotechnik, Hans-Sommer-Strasse 66, D-38106 Braunschweig (Germany)

    2005-02-15T23:59:59.000Z

    Undoped and Al-doped ZnO films with dopant concentrations of nominally 1% and 10% and a thickness of 100 nm have been grown on SrTiO{sub 3}(001) by pulsed laser deposition at substrate temperatures between 650 deg. C and 820 deg. C. The epitaxial conditions were examined with high pressure in-situ reflection high energy electron diffraction (RHEED) and ex-situ x-ray diffraction (XRD) measurements in different geometries. The films are highly (1120)-oriented with a lattice mismatch between the SrTiO{sub 3}[110] direction and the c-axis of about 3%. Atomic force microscopy (AFM) revealed smooth surfaces with a roughness of d{sub rms}<5 nm and different sized islands.

  1. Excellent Passivation and Low Reflectivity Al2O3/TiO2 Bilayer Coatings for n-Wafer Silicon Solar Cells: Preprint

    SciTech Connect (OSTI)

    Lee, B. G.; Skarp, J.; Malinen, V.; Li, S.; Choi, S.; Branz, H. M.

    2012-06-01T23:59:59.000Z

    A bilayer coating of Al2O3 and TiO2 is used to simultaneously achieve excellent passivation and low reflectivity on p-type silicon. This coating is targeted for achieving high efficiency n-wafer Si solar cells, where both passivation and anti-reflection (AR) are needed at the front-side p-type emitter. It could also be valuable for front-side passivation and AR of rear-emitter and interdigitated back contact p-wafer cells. We achieve high minority carrier lifetimes {approx}1 ms, as well as a nearly 2% decrease in absolute reflectivity, as compared to a standard silicon nitride AR coating.

  2. Stabilization of ordered zirconium titanates through the chemical substitution of Ti[sup 4+] by Al[sup 3+]/Ta[sup 5+

    SciTech Connect (OSTI)

    Zhang, Yan; Davies, P.K. (Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering)

    1994-03-01T23:59:59.000Z

    The authors have investigated the ZrO[sub 2]-AlTaO[sub 4] system to understand how selected chemical substitutions can be used to control cation-ordering transformations in zirconium titanate based dielectric ceramics. The complete replacement of the Ti content of Zr[sub x]Ti[sub 2[minus]x]O[sub 4] by a coupled Al[sup 3+]/Ta[sup 5+] substitution permits the synthesis of a wide range of isostructural Zr[sub x](Al[sub 0.5]Ta[sub 0.5])[sub 2[minus]x] solid solutions. At high temperatures a disordered [alpha]-PbO[sub 2] type of structure is formed for 0.375 [le] x [le] 1.03. Samples with 0.67 [le] x [le] 1.03 undergo a cation-ordering reaction to a structure in which the a and b axes of the parent disordered cell are doubled. The stabilities of these cation-ordered derivative structures are significantly greater than those of the ordered zirconium titanates. The ordering temperatures are composition dependent with a maximum of 1,393 C occurring for Zr[sub 0.86](Al[sub 0.5]Ta[sub 0.5])[sub 1.14]O[sub 4]. The higher transition temperatures also enhance the kinetics of the ordering transition; whereas the pure zirconium titanates require extended annealing to produce complete cation order, fully ordered Zr[sub x](Al[sub 0.5]Ta[sub 0.5])[sub 2[minus]x]O[sub 4] solid solutions are produced during a normal furnace cool.

  3. High Pressure Research, 2002, Vol. 22, pp. 127130 OPTICAL SPECTROSCOPIC STUDY OF Al2O3: Ti3

    E-Print Network [OSTI]

    Rodríguez, Fernando

    them, Ti3þ is the ion with the simplest electronic configuration, 3d1 . When this ion is introduced. ISSN 0895-7959 print; ISSN 1477-2299 online # 2002 Taylor & Francis Ltd DOI: 10 of the transition energy upon pressure is plotted in Fig. 2(b). The splittings related to the JT effect

  4. Technology Potential of Thermal Energy Storage (TES) Systems in Federal Facilities

    SciTech Connect (OSTI)

    Chvala, William D.

    2001-07-31T23:59:59.000Z

    This document presents the findings of a technology market assessment for thermal energy storage (TES) in space cooling applications. The potential impact of TES in Federal facilities is modeled using the Federal building inventory with the appropriate climatic and energy cost data. In addition, this assessment identified acceptance issues and major obstacles through interviews with energy services companies (ESCOs), TES manufacturers, and Federal facility staff.

  5. Laser damage properties of TiO{sub 2}/Al{sub 2}O{sub 3} thin films grown by atomic layer deposition

    SciTech Connect (OSTI)

    Wei Yaowei; Liu Hao; Sheng Ouyang; Liu Zhichao; Chen Songlin; Yang Liming

    2011-08-20T23:59:59.000Z

    Research on thin film deposited by atomic layer deposition (ALD) for laser damage resistance is rare. In this paper, it has been used to deposit TiO{sub 2}/Al{sub 2}O{sub 3} films at 110 deg. C and 280 deg. C on fused silica and BK7 substrates. Microstructure of the thin films was investigated by x-ray diffraction. The laser-induced damage threshold (LIDT) of samples was measured by a damage test system. Damage morphology was studied under a Nomarski differential interference contrast microscope and further checked under an atomic force microscope. Multilayers deposited at different temperatures were compared. The results show that the films deposited by ALD had better uniformity and transmission; in this paper, the uniformity is better than 99% over 100 mm {Phi} samples, and the transmission is more than 99.8% at 1064 nm. Deposition temperature affects the deposition rate and the thin film microstructure and further influences the LIDT of the thin films. As to the TiO{sub 2}/Al{sub 2}O{sub 3} films, the LIDTs were 6.73{+-}0.47 J/cm{sup 2} and 6.5{+-}0.46 J/cm{sup 2} at 110 deg. C on fused silica and BK7 substrates, respectively. The LIDTs at 110 deg. C are notably better than 280 deg. C.

  6. technology offer SandTES -High Temperature Sand Thermal Energy Storage

    E-Print Network [OSTI]

    Szmolyan, Peter

    technology offer SandTES - High Temperature Sand Thermal Energy Storage key words: High Temperature Energy Storage | Fluidized Bed | Sand | The invention consists of a fluidized bed with internal heat together with Dr. Eisl of ENRAG GmbH. Background Thermal energy storage (TES) systems are essential

  7. Demand-Side and Supply-Side Load Management: Optimizing with Thermal Energy Storage (TES) for the Restructuring Energy Marketplace

    E-Print Network [OSTI]

    Andrepont, J. S.

    -side regarding power generation. Thermal Energy Storage (TES) can provide the flexibility essential to the economical management of power. In large industrial applications, the added value of TES has been demonstrated, not only in managing operating costs...

  8. Potential-well depth at amorphous-LaAlO{sub 3}/crystalline-SrTiO{sub 3} interfaces measured by optical second harmonic generation

    SciTech Connect (OSTI)

    De Luca, Gabriele; Rubano, Andrea; Gennaro, Emiliano di; Khare, Amit; Granozio, Fabio Miletto; Uccio, Umberto Scotti di; Marrucci, Lorenzo; Paparo, Domenico, E-mail: domenico.paparo@spin.cnr.it [CNR-SPIN and Dipartimento di Fisica, Università di Napoli “Federico II,” Compl. Univ. di Monte S. Angelo, v. Cintia, 80126 Napoli (Italy)

    2014-06-30T23:59:59.000Z

    By a combination of optical second harmonic generation and transport measurements, we have investigated interfaces formed by either crystalline or amorphous thin films of LaAlO{sub 3} grown on TiO{sub 2}-terminated SrTiO{sub 3}(001) substrates. Our approach aims at disentangling the relative role of intrinsic and extrinsic doping mechanisms in the formation of the two-dimensional electron gas. The different nature of the two mechanisms is revealed when comparing the sample response variation as a function of temperature during annealing in air. However, before the thermal treatment, the two types of interfaces show almost the same intensity of the second harmonic signal, provided the overlayer thickness is the same. As we will show, the second harmonic signal is proportional to the depth of the potential well confining the charges at the interface. Therefore, our result demonstrates that this depth is about the same for the two different material systems. This conclusion supports the idea that the electronic properties of the two-dimensional electron gas are almost independent of the doping mechanism of the quantum well.

  9. Formation of mixed oxide powders in flames: Part II. SiO sub 2 --GeO sub 2 and Al sub 2 O sub 3 --TiO sub 2

    SciTech Connect (OSTI)

    Hung, C.; Miquel, P.F.; Katz, J.L. (Department of Chemical Engineering, The Johns Hopkins University, Baltimore, Maryland 21218 (United States))

    1992-07-01T23:59:59.000Z

    SiO{sub 2}--GeO{sub 2} and Al{sub 2}O{sub 3}--TiO{sub 2} mixed oxide powders were synthesized using a counterflow diffusion flame burner. SiCl{sub 4}, GeCl{sub 4}, Al(CH{sub 3}){sub 3}, and TiCl{sub 4} were used as source materials for the formation of oxide particles in hydrogen-oxygen flames. {ital In} {ital situ} particle sizes were determined using dynamic light-scattering. Powders were collected using two different methods, a thermophoretic method (particles are collected onto carbon coated TEM grids) and an electrophoretic method (particles are collected onto stainless steel strips). Their size, morphology, and crystalline form were examined using a transmission electron microscope and an x-ray diffractometer. A photomultiplier at 90{degree} to the argon ion laser beam was used to measure the light-scattering intensity. The formation of the mixed oxides was investigated using Si to Ge and Al to Ti ratios of 3:5 and 1:1, respectively. Heterogeneous nucleation of the SiO{sub 2} on the surface of the GeO{sub 2} was observed. In Al{sub 2}O{sub 3}--TiO{sub 2} mixtures, both oxide particles form at the same temperature. X-ray diffraction analysis of particles sampled at temperatures higher than 1553 K showed the presence of rutile, {gamma}--Al{sub 2}O{sub 3}, and aluminum titanate. Although the particle formation processes for SiO{sub 2}--GeO{sub 2} is very different from that for Al{sub 2}O{sub 3}--TiO{sub 2}, both mixed oxides result in very uniform mixtures.

  10. On the lateral crystal growth of laser irradiated NiTi thin films A. J. Birnbaum, Y. Lawrence Yao, U.-J. Chung, James. S. Im, X. Huang et al.

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    -aspect crystals via pulsed, melt-mediated laser crystallization in NiTi thin films. Sputter-deposited 200 nm Ni of Physics. DOI: 10.1063/1.3138782 Pulsed, melt-mediated laser crystallization techniques have been studied phase processing. Wang et al.6 and Bellouard and co-workers7 used a near IR cw laser to selectively

  11. Alpha phase precipitation from phase-separated beta phase in a model Ti-Mo-Al alloy studied by direct coupling of transmission electron microscopy and atom probe tomography

    SciTech Connect (OSTI)

    Devaraj, Arun; Nag, Soumya; Banerjee, Rajarshi

    2013-10-19T23:59:59.000Z

    The benefit of direct coupling of APT with TEM dark field imaging to investigate early stages of phase transformation in multicomponent alloys is demonstrated by analyzing alpha phase precipitated in a model Ti-10 at% Mo-10 at% Al alloy during annealing at 400oC. Through such a direct coupling approach a thermodynamically unexpected solute partitioning trend between beta matrix and alpha precipitate is observed in the early stages of precipitation, which is explained based on possible nucleation of alpha phase in the Ti rich (Mo and Al depleted regions) created as a result of phase separation in beta matrix. On further higher temperature annealing at 600oC for 1 hour, the alpha precipitates were shown to grow and get enriched in Al and further depleted in Mo reaching the thermodynamic equilibrium.

  12. al coated a2: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 AlTiN layer effect on mechanical properties of Ti-doped diamond-like carbon composite coatings Engineering Websites Summary: AlTiN layer effect on mechanical properties...

  13. EFFECTS OF ION IRRADIATION ON Zr52.5Cu17.9Ni14.6Al10Ti5 (BAM-11) BULK METALLIC GLASS

    SciTech Connect (OSTI)

    Perez-Bergquist, Alex G [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Leonard, Keith J [ORNL] [ORNL; Zhang, Yanwen [ORNL] [ORNL; Zinkle, Steven J [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Bulk metallic glasses are intriguing candidates for nuclear applications due to their inherent amorphous structure, but their radiation response is largely unknown due to the relatively recent nature of innovations in bulk metallic glass fabrication. Here, microstructural and mechanical property evaluations have been performed on a Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glass (BAM-11) irradiated with 3 MeV Ni+ ions to 0.1 and 1.0 dpa at room temperature and 200 C. Nanoindentation hardness and Young s modulus both decreased by 6 to 20% in samples irradiated at room temperature, with the sample irradiated to 1.0 dpa experiencing the greatest change in mechanical properties. However, no significant changes in properties were observed in the samples irradiated at 200 C, and transmission electron microscopy showed no visible evidence of radiation damage or crystallization following ion irradiation at any of the tested conditions. These results suggest that BAM-11 bulk metallic glass may be useful for certain applications in nuclear environments.

  14. ZnO-Al2O3 and ZnO-TiO2 Core-Shell Nanowire Dye-Sensitized Solar Cells Matt Law,, Lori E. Greene,, Aleksandra Radenovic, Tevye Kuykendall,,

    E-Print Network [OSTI]

    Yang, Peidong

    ZnO-Al2O3 and ZnO-TiO2 Core-Shell Nanowire Dye-Sensitized Solar Cells Matt Law,,§ Lori E. Greene the construction and performance of dye-sensitized solar cells (DSCs) based on arrays of ZnO nanowires coated loadings through an increase in nanowire array surface area. Introduction Dye-sensitized solar cells (DSCs

  15. Effect of build geometry on the ?-grain structure and texture in additive manufacture of Ti-6Al-4V by selective electron beam melting

    SciTech Connect (OSTI)

    Antonysamy, A.A., E-mail: alphons.antonysamy@GKNAerospace.com [Additive Manufacturing Centre, GKN Aerospace, P.O. Box 500, Golf Course Lane, Filton, BS34 9 AU (United Kingdom); Meyer, J., E-mail: jonathan.meyer@eads.com [EADS Innovation Works, 20A1 Building, Golf Course Lane, Filton, Bristol, BS997AR (United Kingdom); Prangnell, P.B., E-mail: philip.prangnell@manchester.ac.uk [School of Materials, University of Manchester, Manchester M13 9PL (United Kingdom)

    2013-10-15T23:59:59.000Z

    With titanium alloys, the solidification conditions in Additive Manufacturing (AM) frequently lead to coarse columnar ?-grain structures. The effect of geometry on the variability in the grain structure and texture, seen in Ti-6Al-4V alloy components produced by Selective Electron Beam Melting (SEBM), has been investigated. Reconstruction of the primary ?-phase, from ?-phase EBSD data, has confirmed that in bulk sections where in-fill “hatching” is employed growth selection favours columnar grains aligned with an <001> {sub ?} direction normal to the deposited powder layers; this results in a coarse ?-grain structure with a strong < 001 > {sub ?} fibre texture (up 8 x random) that can oscillate between a near random distribution around the fibre axis and cube reinforcement with build height. It is proposed that this behaviour is related to the highly elongated melt pool and the raster directions alternating between two orthogonal directions every layer, which on average favours grains with cube alignment. In contrast, the outline, or “contour”, pass produces a distinctly different grain structure and texture resulting in a skin layer on wall surfaces, where nucleation occurs off the surrounding powder and growth follows the curved surface of the melt pool. This structure becomes increasingly important in thin sections. Local heterogeneities have also been found within different section transitions, resulting from the growth of skin grain structures into thicker sections. Texture simulations have shown that the far weaker ?-texture (? 3 x random), seen in the final product, arises from transformation on cooling occurring with a near random distribution of ?-plates across the 12 variants possible from the Burgers relationship. - Highlights: • Distinctly different skin and bulk structures are produced by the contour and hatching passes. • Bulk sections contain coarse ?-grains with a < 001 > fibre texture in the build direction. • This oscillates between a random distribution around the axis and cube reinforcement. • In the skin layer nucleation occurs off the surrounding powder bed and growth occurs inwards. • Simulations show that a weak ?-texture results from a random distribution across habit variants.

  16. Reducing Energy Costs And Minimizing Capital Requirements: Case Studies of Thermal Energy Storage (TES)

    E-Print Network [OSTI]

    Andrepont, J. S.

    2007-01-01T23:59:59.000Z

    , and thus during those times when power has its highest cost or value. Thermal Energy Storage (TES) provides a means of de-coupling the generation of cooling from the provision of cooling to the peak cooling loads. In this manner, peak power demand...

  17. Tes$ng of the GFS EnKF for 2010's tropical cyclones

    E-Print Network [OSTI]

    Hamill, Tom

    Tes$ng of the GFS EnKF for 2010's tropical cyclones Tom Hamill, Jeff$ng TCVitals minimum SLP separately as posi$on / intensity data, rather than trea as last year 13 have not made switch yet with this to separate posi

  18. External review of the thermal energy storage (TES) cogeneration study assumptions. Final report

    SciTech Connect (OSTI)

    Lai, B.Y.; Poirier, R.N. [Chicago Bridge and Iron Technical Services Co., Plainfield, IL (United States)

    1996-08-01T23:59:59.000Z

    This report is to provide a detailed review of the basic assumptions made in the design, sizing, performance, and economic models used in the thermal energy storage (TES)/cogeneration feasibility studies conducted by Pacific Northwest Laboratory (PNL) staff. This report is the deliverable required under the contract.

  19. Satellite observations of Mexico City pollution outflow from the Tropospheric Emissions Spectrometer (TES)

    E-Print Network [OSTI]

    Satellite observations of Mexico City pollution outflow from the Tropospheric Emissions 12 November 2008 Keyword: Mega-city pollution TES O3­CO correlation INTEX-B Mexico city a b s t r a c regions were used to examine Mexico City pollution outflow on a regional scale. The pollution outflow from

  20. Quantifying global terrestrial methanol emissions using1 observations from the TES satellite sensor2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 Quantifying global terrestrial methanol emissions using1 observations from the TES Figure S1. December-January-Febuary (DJF, top) and June-July-August (JJA, bottom) biogenic3 methanol 1 Figure S4. Regions employed for quantifying terrestrial methanol fluxes (red) and for2

  1. Model-Inspired Research. TES research uses modeling, prediction, and synthesis to identify

    E-Print Network [OSTI]

    in Earth system models (ESMs). TES supports research to advance fundamental understanding of terrestrial-process models, ecosystem models, and the Community Earth System Model). This emphasis on the capture of advanced in Earth system models to increase the quality of climate model projections and to provide the scientific

  2. Phase Relations and Elemental Distribution Among Co-Existing Phases in the Ceramics of the Pseudobinary System CaZrTi{sub 2}O{sub 7}-LnAlO{sub 3} (Ln= Nd, Sm)

    SciTech Connect (OSTI)

    Mikhailenko, Natalia [SIA Radon, Moscow, 119121 (Russian Federation); Stefanovsky, Sergey [Center of Advanced Technologies, SIA Radon, 7th Rostovskii lane 2/14, Moscow, 119121 (Russian Federation); Ochkin, Alexander [D. Mendeleev University of Chemical Technology, Moscow (Russian Federation)

    2007-07-01T23:59:59.000Z

    In the ceramics in series (1-x) CaZrTi{sub 2}O{sub 7} - x NdAlO{sub 3} and (1-x) CaZrTi{sub 2}O{sub 7} - x SmAlO{sub 3} (x = 0.25, 0.5 and 0.75) produced by cold pressing and sintering at 1400, 1450 and 1500 deg. C zirconolite was found to be a major phase, perovskite was an extra phase and traces of residual baddeleyite occurred. At x = 0.75 the perovskite was major phase and zirconolite and cubic oxide of fianite or tazheranite type were extra phases. Major Nd and Sm host phase at x = 0.25 was found to be zirconolite (about 65% of total Nd{sub 2}O{sub 3} and 74% of total Sm{sub 2}O{sub 3}). With the x value increasing perovskite becomes major host phase for Nd and Sm accumulating of up to about 92% of total Nd and about 72% of total Sm. As follows from SEM/EDS data Nd and Sm contents in the zirconolite may reach {approx}1 formula unit (fu). (authors)

  3. Coexistence of Magnetic Order and Two-dimensional Superconductivity at LaAlO3/SrTiO3 Interfaces

    E-Print Network [OSTI]

    Li, Lu

    A two dimensional electronic system forms at the interface between the band insulators LaAlO[subscript 3]

  4. Interface and Size Effects on TiN-based Nanostructured Thin Films 

    E-Print Network [OSTI]

    Kim, Ickchan

    2012-07-16T23:59:59.000Z

    reactors. In order to enhance the material property, superlattices is one of artificially engineered protective coatings, such as AlN/TiN and TaN/TiN multilayered films. Epitaxial cubic multilayer films, TaN/TiN and AlN/TiN nanolayers were grown on Si(001...

  5. VEHICLE 1vlOBILITY TES'J'S SOFT SOIL SLOPES

    E-Print Network [OSTI]

    Rathbun, Julie A.

    VEHICLE 1vlOBILITY TES'J'S SOFT SOIL SLOPES June 2 5 , 1970 J E T P R O P U L S I O N L A B C A L f;760-51 FOREWORD The investigation documented in this report constitutes part of the Lunar Roving Vehicle (LRV. :;: These vehicle mobility tests have been performed to develop :: National Aeronautics and Space Administration

  6. Structure and Electrochemistry of LiNi1/3Co1/3-yMyMn1/3O2 (M=Ti, Al, Fe) Positive Electrode Materials

    SciTech Connect (OSTI)

    Wilcox, James; Patoux, Sebastien; Doeff, Marca

    2009-01-14T23:59:59.000Z

    A series of materials based on the LiNi1/3Co1/3-yMyMn1/3O2 (M = Ti,Al,Fe) system has been synthesized and examined structurally and electrochemically. It is found that the changes in electrochemical performance depend highly on the nature of the substituting atom and its effect on the crystal structure. Substitution with small amounts of Ti4+ (y = 1/12) leads to the formation of a high-capacity and high-rate positive electrode material. Iron substituted materials suffer from an increased antisite defect concentration and exhibit lower capacities and poor rate capabilities. Single-phase materials are found for LiNi1/3Co1/3-yAlyMn1/3O2 when y<_ 1/4 and all exhibit decreased capacities when cycled to 4.3 V. However, an increase in rate performance and cycle stability upon aluminum substitution is correlated with an improved lamellar structure.

  7. Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95 (Cb (Nb) + Ta) - 2.5Ti - 0.70Al - 7.0Fe Consumable Electrode, Remelted or Vacuum Induction Melted, Solution Heat Treated, Precipitation-Hardenable

    E-Print Network [OSTI]

    SAE Aerospace Standards. London

    2012-01-01T23:59:59.000Z

    Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95 (Cb (Nb) + Ta) - 2.5Ti - 0.70Al - 7.0Fe Consumable Electrode, Remelted or Vacuum Induction Melted, Solution Heat Treated, Precipitation-Hardenable

  8. Conductance control at the LaAlO{sub 3}/SrTiO{sub 3}-interface by a multiferroic BiFeO{sub 3} ad-layer

    SciTech Connect (OSTI)

    Mix, Christian; Finizio, Simone; Kläui, Mathias; Jakob, Gerhard [Institut für Physik, Johannes Gutenberg Universität Mainz, Staudingerweg 7, D-55128 Mainz (Germany)

    2014-06-30T23:59:59.000Z

    Multilayered BiFeO{sub 3} (BFO)/LaAlO{sub 3} (LAO) thin film samples were fabricated on SrTiO{sub 3} (STO) substrates by pulsed laser deposition. In this work, the ferroelectric polarization of a multiferroic BFO ad-layer on top of the quasi-two-dimensional electron gas (2DEG) at the LAO/STO interface is used to manipulate the conductivity of the quasi-2DEG. By microstructuring the conductive area of the LAO/STO-interface, a four-point geometry for the measurement of the resistivity was achieved. Piezo force microscopy allows for imaging and poling the spontaneous ferroelectric polarization of the multiferroic layer. The resistance changes showed a linear dependence on the area scanned and a hysteretic behavior with respect to the voltages applied in the scanning process. This is evidence for the ferroelectric polarization of the multiferroic causing the resistance changes. Coupling the antiferromagnetic BFO layer to another ferromagnetic layer could enable a magnetic field control of the conductance of the quasi-2DEG at the LAO/STO interface.

  9. Characterization, 1064 nm photon signals and background events of a tungsten TES detector for the ALPS experiment

    E-Print Network [OSTI]

    Dreyling-Eschweiler, Jan; Döbrich, Babette; Horns, Dieter; Januschek, Friederike; Lindner, Axel

    2015-01-01T23:59:59.000Z

    The high efficiency, low-background, and single-photon detection with transition-edge sensors (TES) is making this type of detector attractive in widely different types of application. In this paper, we present first characterizations of a TES to be used in the Any Light Particle Search (ALPS) experiment searching for new fundamental ultra-light particles. Firstly, we describe the setup and the main components of the ALPS TES detector (TES, millikelvin-cryostat and SQUID read-out) and their performances. Secondly, we explain a dedicated analysis method for single-photon spectroscopy and rejection of non-photon background. Finally, we report on results from extensive background measurements. Considering an event-selection, optimized for a wavelength of $1064~{\\rm nm}$, we achieved a background suppression of $\\sim 10^{-3}$ with a $\\sim 50~\\%$ efficiency for photons passing the selection. The resulting overall efficiency was $23~\\%$ with a dark count rate of $8.6 \\cdot 10^{-3}~{\\rm s}^{-1}$. We observed that pi...

  10. Characterization, 1064 nm photon signals and background events of a tungsten TES detector for the ALPS experiment

    E-Print Network [OSTI]

    Jan Dreyling-Eschweiler; Noemie Bastidon; Babette Döbrich; Dieter Horns; Friederike Januschek; Axel Lindner

    2015-02-27T23:59:59.000Z

    The high efficiency, low-background, and single-photon detection with transition-edge sensors (TES) is making this type of detector attractive in widely different types of application. In this paper, we present first characterizations of a TES to be used in the Any Light Particle Search (ALPS) experiment searching for new fundamental ultra-light particles. Firstly, we describe the setup and the main components of the ALPS TES detector (TES, millikelvin-cryostat and SQUID read-out) and their performances. Secondly, we explain a dedicated analysis method for single-photon spectroscopy and rejection of non-photon background. Finally, we report on results from extensive background measurements. Considering an event-selection, optimized for a wavelength of $1064~{\\rm nm}$, we achieved a background suppression of $\\sim 10^{-3}$ with a $\\sim 50~\\%$ efficiency for photons passing the selection. The resulting overall efficiency was $23~\\%$ with a dark count rate of $8.6 \\cdot 10^{-3}~{\\rm s}^{-1}$. We observed that pile-up events of thermal photons are the main background component.

  11. Development of a free boundary Tokamak Equilibrium Solver (TES) for Advanced Study of Tokamak Equilibria

    E-Print Network [OSTI]

    Jeon, Y M

    2015-01-01T23:59:59.000Z

    A free-boundary Tokamak Equilibrium Solver (TES), developed for advanced study of tokamak equilibra, is described with two distinctive features. One is a generalized method to resolve the intrinsic axisymmetric instability, which is encountered after all in equilibrium calculation with a free-boundary condition. The other is an extension to deal with a new divertor geometry such as snowflake or X divertors. For validations, the uniqueness of a solution is confirmed by the independence on variations of computational domain, the mathematical correctness and accuracy of equilibrium profiles are checked by a direct comparison with an analytic equilibrium known as a generalized Solovev equilibrium, and the governing force balance relation is tested by examining the intrinsic axisymmetric instabilities. As a valuable application, a snowflake equilibrium that requires a second order zero of the poloidal magnetic field is discussed in the circumstance of KSTAR coil system.

  12. Structure, magnetic properties and magnetoelastic anisotropy in epitaxial Sr(Ti???Co?)O? films

    E-Print Network [OSTI]

    Bi, Lei

    We report the structure, magnetic properties and magnetoelastic anisotropy of epitaxial Sr(Ti???Co?)O? films grown on LaAlO? (001) and SrTiO? (001) substrates by pulsed laser deposition. Room temperature ferromagnetism was ...

  13. First-principles insights on the magnetism of cubic SrTi1-xCoxO3-J. M. Florez, S. P. Ong, M. C. Onbali, G. F. Dionne, P. Vargas et al.

    E-Print Network [OSTI]

    Ceder, Gerbrand

    First-principles insights on the magnetism of cubic SrTi1-xCoxO3- J. M. Florez, S. P. Ong, M. C/APPLAB/v100/i25 Published by the American Institute of Physics. Related Articles Magnetic properties and magnetic properties of BaTi1-xMnxO3 multiferroics J. Appl. Phys. 111, 113913 (2012) Preparation of Fe2Ni2N

  14. A=16Al (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01) (See0AJ04)1AJ01)91AJ01) (See6 -

  15. Exploration of R2XM2 (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge): Structural Motifs, the novel Compound Gd2AlGe2 and Analysis of the U3Si2 and Zr3Al2 Structure Types

    SciTech Connect (OSTI)

    Sean William McWhorter

    2006-05-01T23:59:59.000Z

    In the process of exploring and understanding the influence of crystal structure on the system of compounds with the composition Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} several new compounds were synthesized with different crystal structures, but similar structural features. In Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, the main feature of interest is the magnetocaloric effect (MCE), which allows the material to be useful in magnetic refrigeration applications. The MCE is based on the magnetic interactions of the Gd atoms in the crystal structure, which varies with x (the amount of Si in the compound). The crystal structure of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} can be thought of as being formed from two 3{sup 2}434 nets of Gd atoms, with additional Gd atoms in the cubic voids and Si/Ge atoms in the trigonal prismatic voids. Attempts were made to substitute nonmagnetic atoms for magnetic Gd using In, Mg and Al. Gd{sub 2}MgGe{sub 2} and Gd{sub 2}InGe{sub 2} both possess the same 3{sup 2}434 nets of Gd atoms as Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, but these nets are connected differently, forming the Mo{sub 2}FeB{sub 2} crystal structure. A search of the literature revealed that compounds with the composition R{sub 2}XM{sub 2} (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge) crystallize in one of four crystal structures: the Mo{sub 2}FeB{sub 2}, Zr{sub 3}Al{sub 2}, Mn{sub 2}AlB{sub 2} and W{sub 2}CoB{sub 2} crystal structures. These crystal structures are described, and the relationships between them are highlighted. Gd{sub 2}AlGe{sub 2} forms an entirely new crystal structure, and the details of its synthesis and characterization are given. Electronic structure calculations are performed to understand the nature of bonding in this compound and how electrons can be accounted for. A series of electronic structure calculations were performed on models with the U{sub 3}Si{sub 2} and Zr{sub 3}Al{sub 2} structures, using Zr and A1 as the building blocks. The starting point for these models was the U{sub 3}Si{sub 2} structure, and models were created to simulate the transition from the idealized U{sub 3}Si{sub 2} structure to the distorted Zr{sub 3}Al{sub 2} structure. Analysis of the band structures of the models has shown that the transition from the U{sub 3}Si{sub 2} structure to the Zr{sub 3}Al{sub 2} structure lifts degeneracies along the {Lambda} {yields} Z direction, indicating a Peierls-type mechanism for the displacement occurring in the positions of the Zr atoms.

  16. Melt Processed Single Phase Hollandite Waste Forms For Nuclear Waste Immobilization: Ba{sub 1.0}Cs{sub 0.3}A{sub 2.3}Ti{sub 5.7}O{sub 16}; A = Cr, Fe, Al

    SciTech Connect (OSTI)

    Brinkman, Kyle [Savannah River National Laboratory, Aiken, SC 29808 (United States); Marra, James [Savannah River National Laboratory, Aiken, SC 29808 (United States); Amoroso, Jake [Savannah River National Laboratory, Aiken, SC 29808 (United States); Conradson, Steven D. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Tang, Ming [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2013-09-23T23:59:59.000Z

    Cs is one of the more problematic fission product radionuclides to immobilize due to its high volatility at elevated temperatures, ability to form water soluble compounds, and its mobility in many host materials. The hollandite structure is a promising crystalline host for Cs immobilization and has been traditionally fabricated by solid state sintering methods. This study presents the structure and performance of Ba{sub 1.0}Cs{sub 0.3}A{sub 2.3}Ti{sub 5.7}O{sub 16}; A = Cr, Fe, Al hollandite fabricated by melt processing. Melt processing is considered advantageous given that melters are currently in use for High Level Waste (HLW) vitrification in several countries. This work details the impact of Cr additions that were demonstrated to i) promote the formation of a Cs containing hollandite phase and ii) maintain the stability of the hollandite phase in reducing conditions anticipated for multiphase waste form processing.

  17. In situ NiTi/Nb(Ti) composite

    SciTech Connect (OSTI)

    Jiang, Daqiang, E-mail: dq80jiang@126.com; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-12-15T23:59:59.000Z

    Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength.

  18. High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study of their optical and interfacial characteristics

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study with unbalanced magnetrons, we deposited advanced inorganic functional thin films such as TiO2, TiN, and TiO2/Ti sputtering. The TiO2 101 and TiN 100 thin films were stoichiometric and polycrystalline but highly oriented

  19. Characterizations of a CERN NbTi Reference Wire at LBNL

    E-Print Network [OSTI]

    Godeke, A.; Dietderich, D.R.; Higley, H.C.; Liggins, N.L.

    2007-01-01T23:59:59.000Z

    et al. , report number LBNL-62392 Characterizations of aNbTi Reference Wire at LBNL ? A. Godeke † D. R. Dietderich,tests – and analysis – between LBNL, BNL and Fermilab within

  20. Ti (II) Mediated Reactions in Organic Chemistry

    E-Print Network [OSTI]

    Johnson, Jeff S.

    ' #12;Generation of Ti(II) from Ti(IV) · Bercaw accessed and characterized the first Ti'X -X Generation of Ti(II) via Reductive Alkylation · Ti(IV) converted to Ti(II) via reductive/Acetylene Functionalizations · Reductive Couplings #12;Advantages of Titanium · Titanium (IV) reagents are cheap and readily

  1. Ann bay lodyans 14 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01T23:59:59.000Z

    chante. A! chwal pati, men krapo pi vif pase I. Li bondi al tache nan gwo ke chwal la. F6 nou te we chwal kouri tout boulin. Li voltije ni rigol ni lantiray. Le li bouke, li fe yon ti rete. 10 Men, tou dousman, krapo fe yon ti "ef-6f." Chwal sezi... chwal, fe yon ti "ef-df" anko. Chwal rele: "Sa pa posib!" Epi li komanse galope vites boulin pou I ka rive pi vit. Nan yon ti moman, li paret nan bouk la. Men kay Melani. Chwal rele: "Cheri! cheri!" Yo tande vwa li. Tout moun vini pou yo ka resevwa...

  2. Giant resonances in Ti-46,Ti-48

    E-Print Network [OSTI]

    Tokimoto, Y.; Lui, Y. -W; Clark, H. L.; John, B.; Chen, X.; Youngblood, David H.

    2006-01-01T23:59:59.000Z

    PHYSICAL REVIEW C 74, 044308 (2006) Giant resonances in 46,48Ti Y. Tokimoto, Y.-W. Lui, H. L. Clark, B. John,* X. Chen, and D. H. Youngblood Cyclotron Institute, Texas A&M University, College Station, Texas 77843, USA (Received 30 June 2006... parameter sets using electro- magnetic B(E2) values [14] and collective model transition potentials successfully reproduced the angular distributions of 0556-2813/2006/74(4)/044308(9) 044308-1 ?2006 The American Physical Society TOKIMOTO, LUI, CLARK, JOHN...

  3. Magnetic anisotropy and order structure of L1{sub 0}-FePt(001) single-crystal films grown epitaxially on (001) planes of MgO, SrTiO{sub 3}, and MgAl{sub 2}O{sub 4} substrates

    SciTech Connect (OSTI)

    Hotta, A., E-mail: hotta@riec.tohoku.ac.jp; Hatayama, M.; Tsumura, K. [Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, Sendai 980-8578 (Japan); Ono, T. [Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, Sendai 980-8578 (Japan); Fuji Electric Co., Ltd., Tokyo 191-8502 (Japan); Kikuchi, N.; Okamoto, S.; Kitakami, O. [Institute of Multidisciplinary Research for Advanced Material, Tohoku University, Sendai 980-8577 (Japan); Shimatsu, T. [Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, Sendai 980-8578 (Japan); Research Institute of Electrical Communication, Tohoku University, Sendai 980-8577 (Japan)

    2014-05-07T23:59:59.000Z

    L1{sub 0}–FePt(001) single-crystal films were grown epitaxially on SrTiO{sub 3}(001), MgAl{sub 2}O{sub 4}(001), and MgO(001) substrates. Their uniaxial magnetic anisotropy K{sub u} and the order structure were examined for the film thickness t range of 2–14?nm. All series of films show large K{sub u} of 4?×?10{sup 7}?erg/cm{sup 3} in the thickness range higher than 10?nm, with order parameter S of 0.8 and saturation magnetization M{sub s} of 1120?emu/cm{sup 3}. K{sub u} decreased gradually as t decreased. The K{sub u} reduction was considerable when t decreased from 4?nm to 2?nm. No marked difference in the thickness dependence of K{sub u} was found in any series of films, although the lattice mismatch between FePt and the substrates was markedly different. K{sub u} reduction showed good agreement with the reduction of S for the films on MgAl{sub 2}O{sub 4} and MgO. The K{sub u}???S{sup 2} plot showed an almost linear relation, which is in good agreement with theoretical predictions. Transmission electron microscopy images for a FePt film on MgO substrate revealed that the lattice mismatch between FePt(001) and MgO(001) was relaxed in the initial 1 or 2 layers of FePt(001) lattices, which is likely to be true also for two other series of films.

  4. Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 catalyst Formation, stability and CO

    E-Print Network [OSTI]

    Pfeifer, Holger

    1 Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 are the activation of molecular oxygen, the active site for this reaction step, and the nature of the catalytically active oxygen species present under working conditions.[3;9-15] Stiehl et al. had shown that molecularly

  5. TES for Residential Settings

    SciTech Connect (OSTI)

    Rutberg, Michael; Hastbacka, Mildred; Bouza, Antonio

    2013-07-31T23:59:59.000Z

    The article discusses thermal energy storage approaches for residential buildings. This article addresses both brick bank storage and phase change material technologies. The energy savings and market potential of these thermal energy storage methods are reviewed as well.

  6. Pseudo-elastic deformation behavior in a Ti/Mo-based alloy , M. Aindow a,*, S.P. Alpay a

    E-Print Network [OSTI]

    Alpay, S. Pamir

    , and are increasingly finding applications in aerospace, oil well systems and automotive parts [1]. Alloys in the metaPseudo-elastic deformation behavior in a Ti/Mo-based alloy T. Zhou a , M. Aindow a,*, S.P. Alpay 2003 Abstract It is shown that the pseudo-elastic response in a series of Ti­Mo­V­Nb­Al alloys with 8

  7. The electrochemical behavior of a Ti50Ni47Fe3 shape memory alloy C. Li, Y.F. Zheng

    E-Print Network [OSTI]

    Zheng, Yufeng

    University, Beijing 100871, PR China Received 31 July 2005; accepted 28 November 2005 Available online 20 film consisting mainly of a layer of TiO2 which is deemed to be important for all biomaterials. © 2005 the effect of copper on the localized corrosion resistance of Ni­Ti shape memory alloy [6]. Wen et al. have

  8. Structure and hydrogen dynamics of pure and Ti-doped sodium alanate Jorge iguez,1,2

    E-Print Network [OSTI]

    Yildirim, Taner

    Structure and hydrogen dynamics of pure and Ti-doped sodium alanate Jorge Íñiguez,1,2 T. Yildirim,1, Honolulu, Hawaii 96822, USA (Received 2 June 2004; published 3 August 2004) We have studied the structure, energetics, and dynamics of pure and Ti-doped sodium alanate NaAlH4 , focusing on the possibility

  9. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01T23:59:59.000Z

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore »(Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached ?225?kV bias voltage while generating less than 100?pA of field emission (« less

  10. Formation of Ti-B surface alloys by excimer laser mixing

    SciTech Connect (OSTI)

    Jervis, T.R.; Nastasi, M.; Hirvonen, J.P.; Zocco, T.G.

    1990-01-01T23:59:59.000Z

    We have formed a surface Ti-B alloy by excimer laser mixing of a single B layer on a Ti-6Al-4V alloy substrate. Rutherford backscattering spectroscopy indicates a uniform B:Ti ratio of approximately 0.7 in the surface layer. A Boron layer 60 nm thick resulted in an alloy layer approximately 200 nm thick. There is little indication, by either Auger electron spectroscopy or nuclear reaction analysis, of substantial oxygen incorporation in the surface alloy despite the fact that the processing was done in air. Transmission electron microscopy of the surface alloy shows a completely amorphous surface layer underlain by a martensitic structure.

  11. (5.5) BRAZING OF METALLIC-INTERMETALLIC LAMINATE (MIL) Ti-6Al-4V/Al3Ti COMPOSITES

    E-Print Network [OSTI]

    Meyers, Marc A.

    , appropriate joining techniques must be developed. Welding, diffusion-bonding and brazing are all viable the cooling rates. Furthermore, diffusion-bonding is possible (e.g. Ref. 6, Ref. 7), but long processing times titanium and titanium alloys, makes these (MIL) composites attractive candidates for aerospace and high

  12. Using Encapsulated Phase Change Material in Thermal Energy Storage for Baseload Concentrating Solar Power (EPCM-TES)

    SciTech Connect (OSTI)

    Mathur, Anoop [Terrafore Technologies LLC, Minneapolis, MN (United States)

    2013-12-15T23:59:59.000Z

    Terrafore successfully demonstrated and optimized the manufacturing of capsules containing phase-changing inorganic salts. The phase change was used to store thermal energy collected from a concentrating solar-power plant as latent heat. This latent heat, in addition to sensible heat increased the energy density (energy stored per unit weight of salt) by over 50%, thus requiring 40% less salt and over 60% less capsule container. Therefore, the cost to store high-temperature thermal energy collected in a concentrating solar power plant will be reduced by almost 40% or more, as compared to conventional two-tank, sensible-only storage systems. The cost for thermal energy storage (TES) system is expected to achieve the Sun Shot goal of $15 per kWh(t). Costs associated with poor heat-transfer in phase change materials (PCM) were also eliminated. Although thermal energy storage that relies on the latent heat of fusion of PCM improves energy density by as much as 50%, upon energy discharge the salt freezes and builds on the heat transfer surfaces. Since these salts have low thermal conductivity, large heat-transfer areas, or larger conventional heat-exchangers are needed, which increases costs. By encapsulating PCM in small capsules we have increased the heat transfer area per unit volume of salt and brought the heat transfer fluid in direct contact with the capsules. These two improvements have increased the heat transfer coefficient and boosted heat transfer. The program was successful in overcoming the phenomenon of melt expansion in the capsules, which requires the creation of open volume in the capsules or shell to allow for expansion of the molten salt on melting and is heated above its melting point to 550°C. Under contract with the Department of Energy, Terrafore Inc. and Southwest Research Institute, developed innovative method(s) to economically create the open volume or void in the capsule. One method consists of using a sacrificial polymer coating as the middle layer between the salt prill and the shell material. The selected polymer decomposes at temperatures below the melting point of the salt and forms gases which escape through the pores in the capsule shell thus leaving a void in the capsule. We have demonstrated the process with a commonly used inorganic nitrate salt in a low-cost shell material that can withstand over 10,000 high-temperature thermal cycles, or a thirty-year or greater life in a solar plant. The shell used to encapsulate the salt was demonstrated to be compatible with molten salt heat transfer fluid typically used in CSP plants to temperatures up to 600 °C. The above findings have led to the concept of a cascaded arrangement. Salts with different melting points can be encapsulated using the same recipe and contained in a packed bed by cascading the salt melting at higher melting point at the top over the salt melting at lower melting point towards the bottom of the tank. This cascaded energy storage is required to effectively transfer the sensible heat collected in heat transfer fluids between the operating temperatures and utilize the latent heat of fusion in the salts inside the capsule. Mathematical models indicate that over 90% of the salts will undergo phase change by using three salts in equal proportion. The salts are selected such that the salt at the top of the tank melts at about 15°C below the high operating-temperature, and the salt at the bottom of the tank melts 15°C above the low operating-temperature. The salt in the middle of tank melts in-between the operating temperature of the heat transfer fluid. A cascaded arrangement leads to the capture of 90% of the latent-heat of fusion of salts and their sensible heats. Thus the energy density is increased by over 50% from a sensible-only, two-tank thermal energy storage. Furthermore, the Terrafore cascaded storage method requires only one tank as opposed to the two-tanks used in sensible heat storage. Since heat is transferred from the heat transfer fluid by direct contact with capsules, external heat-exchangers are not required

  13. Microstructure and mechanical properties of Ti/AlTiN/Ti-diamondlike carbon composite coatings on steel

    E-Print Network [OSTI]

    Volinsky, Alex A.

    such as dry high-speed milling, turning, tapping, and drilling, or when minimal lubrication is required of lubricant recycling along with eliminating the need to maintain complicated lubricating systems in modern.1, or even less in air,6­9 oil, and water.10 Metal-containing diamondlike carbon (Me-DLC) is a DLC film

  14. Oxygen migration in TiO{sub 2}-based higher-k gate stacks

    SciTech Connect (OSTI)

    Kim, Sang Bum; Brown, Stephen L.; Rossnagel, Stephen M.; Bruley, John; Copel, Matthew; Hopstaken, Marco J. P.; Narayanan, Vijay; Frank, Martin M. [IBM T.J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, New York 10598 (United States)

    2010-03-15T23:59:59.000Z

    We report on the stability of high-permittivity (high-k) TiO{sub 2} films incorporated in metal-oxide-silicon capacitor structures with a TiN metal gate electrode, focusing on oxygen migration. Titanium oxide films are deposited by either Ti sputtering [physical vapor deposition (PVD)] followed by radical shower oxidation or by plasma-enhanced atomic layer deposition (PEALD) from titanium isopropoxide (Ti{l_brace}OCH(CH{sub 3}){sub 2{r_brace}4}) and O{sub 2} plasma. Both PVD and PEALD films result in near-stoichiometric TiO{sub 2} prior to high-temperature annealing. We find that dopant activation anneals of TiO{sub 2}-containing gate stacks at 1000 deg. C cause 5 A or more of additional SiO{sub 2} to be formed at the gate-dielectric/Si-channel interface. Furthermore, we demonstrate for the first time that oxygen released from TiO{sub 2} diffuses through the TiN gate electrode and oxidizes the poly-Si contact. The thickness of this upper SiO{sub 2} layer continues to increase with increasing TiO{sub 2} thickness, while the thickness of the regrown SiO{sub 2} at the gate-dielectric/Si interface saturates. The upper SiO{sub 2} layer degrades gate stack capacitance, and simultaneously the oxygen-deficient TiO{sub x} becomes a poor insulator. In an attempt to mitigate O loss from the TiO{sub 2}, top and bottom Al{sub 2}O{sub 3} layers are added to the TiO{sub 2} gate dielectric as oxygen barriers. However, they are found to be ineffective, due to Al{sub 2}O{sub 3}-TiO{sub 2} interdiffusion during activation annealing. Bottom HfO{sub 2}/Si{sub 3}N{sub 4} interlayers are found to serve as more effective oxygen barriers, reducing, though not preventing, oxygen downdiffusion.

  15. ALS Spectrum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship inALSALS Spectrum PrintALS

  16. Reviw Al

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection TechnicalResonant Soft X-RayReview/Verify3 JuneReviw Al now ..

  17. ALS Spectrum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS Reveals New StateALS

  18. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS Reveals NewALSUsers'ALS

  19. AL. I

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -KWatertown Arsenal'.I Y.it ! ( , . /'-AL.

  20. THE NRC HAS ISSUED Ati ACTION PLAN FOR CLEANUP OF 46 SfTES that;;ece

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7 AugustAFRICAN3uj: ;;I : T' j-jE: iLie'Al ...NRC

  1. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For...

  2. Mechanical Properties of Al-based Amorphous Alloy Ribbons Chun-Kuo Huang & John J. Lewandowski

    E-Print Network [OSTI]

    Rollins, Andrew M.

    for structural materials. Significant interest has arisen in amorphous aluminum alloys in recent years because MATERIALS FATIGUE DUCTILY TEST Amorphous aluminum alloys Al alloys Ti alloys Mg alloys Steels InhomogeneousMechanical Properties of Al-based Amorphous Alloy Ribbons Chun-Kuo Huang & John J. Lewandowski

  3. As[sub 2]S[sub 3]/Sr(Ti[sub 0.7]Co[sub 0.3])O[sub 3] and As[sub 2]S[sub 3]/Sr(Ti[sub 0.6]Fe[sub 0.4])O[sub 3] strip-loaded waveguides for integrated magneto-optical isolator applications

    E-Print Network [OSTI]

    Bi, Lei

    Sr(Ti[sub 0.6]Fe[sub 0.4])O[sub 3] (STF) and Sr(Ti[sub 0.7]Co[sub 0.3])O[sub 3] (STC) room-temperature ferromagnetic oxides were grown epitaxially on LaAlO[sub 3](001), (LaSr)(AlTa)O[sub 3] (001) and Si (001) substrates. ...

  4. Superior Corrosion Resistance Properties of TiN-Based Coatings on Zircaloy Tubes in Supercritical Water

    SciTech Connect (OSTI)

    Fauzia Khatkhatay; Liang Jiao; Jie Jian; Zhijie Jiao; Hongbin Zhang; Jian Gan; Haiyan Wang; Wenrui Zhang; Xinghang Zhang

    2014-08-01T23:59:59.000Z

    Thin films of TiN and Ti0.35Al0.65N nanocomposite were deposited on polished Zircaloy-4 tubes. After exposure to supercritical water for 48 h, the coated tubes are remarkably intact, while the bare uncoated tube shows severe oxidation and breakaway corrosion. X-ray diffraction patterns, secondary electron images, backscattered electron images, and energy dispersive X-ray spectroscopy data from the tube surfaces and cross-sections show that a protective oxide, formed on the film surface, effectively prevents further oxidation and corrosion to the Zircaloy-4 tubes. This result demonstrates the effectiveness of thin film ceramics as protective coatings under extreme environments.

  5. Reproducible Automated Phosphopeptide Enrichment Using Magnetic TiO 2 and Ti-IMAC

    E-Print Network [OSTI]

    Tape, Christopher

    Reproducible, comprehensive phosphopeptide enrichment is essential for studying phosphorylation-regulated processes. Here, we describe the application of hyper-porous magnetic TiO2 and Ti-IMAC microspheres for uniform ...

  6. Sandia National Laboratories: TiO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News & Events, Photovoltaic, Research & Capabilities, Solar, Solid-State Lighting Titanium-dioxide (TiO2) nanoparticles show great promise as fillers to tune the refractive...

  7. NbTiN Based SIS Multilayer Structures for SRF Applications

    SciTech Connect (OSTI)

    Valente, Anne-marie; Eremeev, Grigory; Phillips, H.; Reece, Charles; Spradlin, Joshua; Yang, Qiguang; Lukaszew, Rosa

    2013-09-01T23:59:59.000Z

    For the past three decades, bulk niobium has been the material of choice for SRF cavities applications. RF cavity performance is now approaching the theoretical limit for bulk niobium. For further improvement of RF cavity performance for future accelerator projects, Superconductor ? Insulator - Superconductor (SIS) multilayer structures (as recently proposed by Alex Gurevich) present the theoretical prospect to reach RF performance beyond bulk Nb, using thinly layered higher-Tc superconductors with enhanced Hc1. Jefferson Lab (JLab) is pursuing this approach with the development of NbTiN and AlN based multilayer SIS structures. This paper presents the results on the characteristics of NbTiN films and the first RF measurements on NbTiN-based multilayer structure on thick Nb films.

  8. PANGEA n 41/42 COMMUNICATIONS Juin / Dcembre 2004 Abdelouahed Ben Mlih et al.

    E-Print Network [OSTI]

    Boyer, Edmond

    dolocrètes de la série permo-triasique du Haut-Atlas central (Maroc) Calcretes and dolocretes of the Permo, Rabat, Maroc. E-mail : benmlih@fsr.ac.ma Résumé Dans le Haut-Atlas central (Maroc), le Permo-Trias est : Maroc, Haut-Atlas, Permo-Trias, calcrètes, dolocrètes, épigénie. Abstract In the Central High Atlas

  9. Formation of mixed oxide powders in flames: Part I. TiO sub 2 --SiO sub 2

    SciTech Connect (OSTI)

    Hung, C.; Katz, J.L. (Department of Chemical Engineering, The Johns Hopkins University, Baltimore, Maryland 21218 (United States))

    1992-07-01T23:59:59.000Z

    Mixed oxide powders, e.g., Al{sub 2}O{sub 3}--TiO{sub 2}, SiO{sub 2}--GeO{sub 2}, and TiO{sub 2}--SiO{sub 2}, are used in industry to produce ceramics, optical fibers, catalysts, and paint opacifiers. The properties of these products depend upon the morphology of the powders. Ceramics and optical fibers are produced using either a uniform mixture of multicomponent particles or a uniform solution. The desired morphology for catalysts is a high surface area and many active sites. TiO{sub 2} coated with a layer of SiO{sub 2} is the desired structure for use as a paint opacifier. In this paper, TiO{sub 2}--SiO{sub 2} mixed oxide powders were synthesized using a counterflow diffusion flame burner. TiCl{sub 4} and SiCl{sub 4} were used as source materials for the formation of oxide particles in hydrogen-oxygen flames. In-situ particle sizes were determined using dynamic light scattering. A thermophoretic sampling method also was used to collect particles directly onto carbon coated grids, and their size, morphology, and crystalline form examined using a transmission electron microscope. A photomultiplier at 90{degree} to the argon ion laser beam was used to measure the light-scattering intensity. The effect of temperature and of Si to Ti concentration ratio on particle morphology was investigated. Strong temperature dependence was observed. At high temperatures, TiO{sub 2} particles were covered with discrete SiO{sub 2} particles. At low temperatures, the structure changes to TiO{sub 2} particles encapsulated by SiO{sub 2}. TEM diffraction pattern measurements showed that the TiO{sub 2} is rutile and the SiO{sub 2} is amorphous silica. At high Si to Ti ratios, SiO{sub 2}-encapsulated TiO{sub 2} particles form. At low Si to Ti ratios, one obtains TiO{sub 2} particles covered with discrete SiO{sub 2} particles.

  10. Femtosecond laser-induced periodic surface structure on the Ti-based nanolayered thin films

    SciTech Connect (OSTI)

    Petrovi?, Suzana M.; Gakovi?, B.; Peruško, D. [Institute of Nuclear Science—Vin?a, University of Belgrade, POB 522, 11001 Belgrade (Serbia)] [Institute of Nuclear Science—Vin?a, University of Belgrade, POB 522, 11001 Belgrade (Serbia); Stratakis, E. [Institute of Electronic Structure and Laser, Foundation for Research and Technology–Hellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece) [Institute of Electronic Structure and Laser, Foundation for Research and Technology–Hellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece); Department of Materials Science and Technology, University of Crete, 710 03 Heraklion, Crete (Greece); Bogdanovi?-Radovi?, I. [Ru?er Boškovi? Institute, P.O. Box 180, 10002 Zagreb (Croatia)] [Ru?er Boškovi? Institute, P.O. Box 180, 10002 Zagreb (Croatia); ?ekada, M. [Jožef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)] [Jožef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Fotakis, C. [Institute of Electronic Structure and Laser, Foundation for Research and Technology–Hellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece) [Institute of Electronic Structure and Laser, Foundation for Research and Technology–Hellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece); Department of Physics, University of Crete, 714 09 Heraklion, Crete (Greece); Jelenkovi?, B. [Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia)] [Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia)

    2013-12-21T23:59:59.000Z

    Laser-induced periodic surface structures (LIPSSs) and chemical composition changes of Ti-based nanolayered thin films (Al/Ti, Ni/Ti) after femtosecond (fs) laser pulses action were studied. Irradiation is performed using linearly polarized Ti:Sapphire fs laser pulses of 40 fs pulse duration and 800 nm wavelength. The low spatial frequency LIPSS (LSFL), oriented perpendicular to the laser polarization with periods slightly lower than the irradiation wavelength, was typically formed at elevated laser fluences. On the contrary, high spatial frequency LIPSS (HSFL) with uniform period of 155 nm, parallel to the laser light polarization, appeared at low laser fluences, as well as in the wings of the Gaussian laser beam distribution for higher used fluence. LSFL formation was associated with the material ablation process and accompanied by the intense formation of nanoparticles, especially in the Ni/Ti system. The composition changes at the surface of both multilayer systems in the LSFL area indicated the intermixing between layers and the substrate. Concentration and distribution of all constitutive elements in the irradiated area with formed HSFLs were almost unchanged.

  11. AlGaN/GaN Metal Oxide Semiconductor Field Effect Transistors using Titanium Dioxide P. J. HANSEN

    E-Print Network [OSTI]

    York, Robert A.

    AlGaN/GaN Metal Oxide Semiconductor Field Effect Transistors using Titanium Dioxide P. J. HANSEN 1 epitaxially on AlGaN/GaN HFET structures by molecular beam epitaxy (MBE). Growth was first performed on GaN templates to establish epitaxial growth conditions. X-ray diffraction showed [001] TiO2 || [1010]GaN

  12. Mechanical properties of near-{gamma} titanium aluminides reinforced with high volume percentages of TiB{sub 2}

    SciTech Connect (OSTI)

    VanMeter, M.L. [Naval Air Warfare center, Patuxent River, MD (United States). Aircraft Div.] [Naval Air Warfare center, Patuxent River, MD (United States). Aircraft Div.; Kampe, S.L. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)] [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States); Christodoulou, L. [Imperial Coll. of Science, Technology, and Medicine, London (United Kingdom)] [Imperial Coll. of Science, Technology, and Medicine, London (United Kingdom)

    1996-04-15T23:59:59.000Z

    Near-{gamma} ({alpha}{sub 2}-Ti{sub 3}Al + {gamma}-TiAl) titanium aluminide intermetallic compounds are presently undergoing extensive development as potential lower-density substitutes for conventional high temperature metallic alloys. In this article the authors describe the mechanical behavior of a series of binary near-{gamma} titanium aluminides (i.e., Ti-xAl, where x {approx} 43--48 atomic percent) reinforced with 40--50 volume percent (v%) of a discontinuous dispersion of titanium diboride (TiB{sub 2}) particulate. The composites were synthesized via XD{reg_sign} processing, and subsequently consolidated into bulk form using conventional powder metallurgy (P/M) techniques. For composites comprised of such large volume percentages of ceramic, it is suggested and will be shown that it is most appropriate to evaluate and offer a perspective of their evolved mechanical behavior through their comparison to traditional structural ceramics, e.g., silicon carbide (SiC) and alumina (Al{sub 2}O{sub 3}).

  13. On the lateral crystal growth of laser irradiated NiTi thin films A. J. Birnbaum,1,a

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    grown, large-aspect crystals via pulsed, melt-mediated laser crystallization in NiTi thin films. Sputter of Physics. DOI: 10.1063/1.3138782 Pulsed, melt-mediated laser crystallization techniques have been studied phase processing. Wang et al.6 and Bellouard and co-workers7 used a near IR cw laser to selectively

  14. Interface and Size Effects on TiN-based Nanostructured Thin Films

    E-Print Network [OSTI]

    Kim, Ickchan

    2012-07-16T23:59:59.000Z

    and theoretically. For example, microstructural changes caused by helium ion-irradiation in several multilayer systems, including immiscible Cu/Nb [16], Cu/V [7], and miscible Al/Nb [17], and Fe/W [8], have been systematically studied. It was reported... components. Further elaboration on the microstructure and composition of nitride films has improved dramatically some properties of these nitride films [26], a quick example shows that nanocrystalline quality of TiN films enhances grain boundary sliding...

  15. A=16N (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy93TI07)93TI07) (See

  16. A=18Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed)95TI07) (See Energy3AJ01)95TI07)

  17. A=18Ne (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed)95TI07)95TI07) (See Energy Level

  18. A=18O (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed)95TI07)95TI07)

  19. A=20Be (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02)98TI06) (Not observed)98TI06)

  20. A=4HE (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04)4He (1992TI02)

  1. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04)4He (1992TI02)Li

  2. Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers Yuanyuan Cheng Polarization Fretting corrosion Ti/TiN multilayers were deposited on sintered NdFeB by radio frequency magnetron sputtering. The film grain size decreased with the number of multilayers in the stack. Corrosion

  3. Calculator Tips for TI-30XA

    E-Print Network [OSTI]

    Owen Davis

    2013-01-04T23:59:59.000Z

    TI-30XA Calculator Tips. Calculator Memory. - To use the memory function, hit the STO key to store a number in either memory 1, 2, or 3. o To store the product of ...

  4. Un1ted S~tes Department of' the Interior, Oscar L. Chapnan, Secretary Fish and Wild11fe Service. Albert M. Day, D1rector

    E-Print Network [OSTI]

    million to approximately 20.2 m,illiono Seafood is the largest source of protein in the Korean diet, and its importance is emphasized by a lack in other protein-bearing foods in Korea, such as an~al meats and vegetable protein sources o Further, the fishing industry has during the past 40 years provided a livelihood

  5. Combustion synthesis/quasi-isostatic pressing of TiCNiTi cermets: processing and mechanical response

    E-Print Network [OSTI]

    Meyers, Marc A.

    Combustion synthesis/quasi-isostatic pressing of TiC­NiTi cermets: processing and mechanical and alumina particulate before initiation of the combustion reaction. The sample was ignited within the particulate and subjected to a uniaxial load immediately after passage of the combustion wave

  6. Motivation and Introduction Titanium alloys, including commercially pure Ti (cp-Ti), are

    E-Print Network [OSTI]

    Chen, Long-Qing

    Motivation and Introduction Titanium alloys, including commercially pure Ti (cp-Ti), are important-Isothermal Microstructure Evolution in Titanium Patrick Hrickoa,c, Yanzhou Jib, Todd Palmera,c and Long-Qing Chenb a. The energy functional f incorporates a double-well function and the temperature-dependent Gibb's free energy

  7. An Investigation into the evolution of damage and residual stresses in Ti6Al4V-Al?Ti metal intermetallic laminate (MIL) composites

    E-Print Network [OSTI]

    Li, Tiezheng

    2006-01-01T23:59:59.000Z

    criteria and failure analysis of composite structuralPuck A, Schürmann H. Failure analysis of FRP laminates byComposite laminate failure analysis using multicontinuum

  8. An Investigation into the evolution of damage and residual stresses in Ti6Al4V-Al?Ti metal intermetallic laminate (MIL) composites

    E-Print Network [OSTI]

    Li, Tiezheng

    2006-01-01T23:59:59.000Z

    in unidirectional ceramic-matrix composites, Compositesceramics fibers, they are chemically instable with many intermetallic matrices,ceramic reinforcements make them extremely susceptible to even small amounts of chemical interaction with the matrix.

  9. An Investigation into the evolution of damage and residual stresses in Ti6Al4V-Al?Ti metal intermetallic laminate (MIL) composites

    E-Print Network [OSTI]

    Li, Tiezheng

    2006-01-01T23:59:59.000Z

    by the self-propagating high- temperature synthesis (SHS) byand self propagating high temperature synthesis [3 - 5] By

  10. AgriculturAl Development

    E-Print Network [OSTI]

    1 SLU Global AgriculturAl ScienceS for globAl Development -- Slu's contribution #12;2 the mission of the Swedish university of Agricultural Sciences (Slu) is "to develop the understanding, management for global Development (pgu). research capacity building provision of expertise Agricultural Sciences

  11. Aluminum Stabilized NbTi Conductor Test Coil Design, Fabrication, and Test Results

    SciTech Connect (OSTI)

    Andreev, N.; Chlachidze, G.; Evbota, D.; Kashikhin, V.S.; Lamm, M.; Makarov, A.; Tartaglia, M.; /Fermilab; Nakamoto, T.; Ogitsu, T.; Tanaka, K.; Yamamoto, A.; /KEK, Tsukuba

    2011-09-01T23:59:59.000Z

    A new generation of precision muon conversion experiments is planned at both Fermilab and KEK. These experiments will depend upon a complex set of solenoid magnets for the production, momentum selection and transport of a muon beam to a stopping target, and for tracking detector momentum analysis of candidate conversion electrons from the target. Baseline designs for the production and detector solenoids use NbTi cable that is heavily stabilized by an extruded high RRR aluminum jacket. A U.S.-Japan research collaboration has begun whose goal is to advance the development of optimized Al-NbTi conductors, gain experience with the technology of winding coils from this material, and test the conductor performance as modest length samples become available. For this purpose, a 'conductor test' solenoid with three coils was designed and built at Fermilab. A sample of the RIKEN Al-NbTi conductor from KEK was wound into a 'test' coil; this was sandwiched between two 'field' coils wound from doubled SSC cable, to increase the peak field on the RIKEN test coil. All three solenoid coils were epoxy impregnated, and utilized aluminum outer bandage rings to apply preload to the coils when cold. The design and fabrication details, and results of the magnet quench performance tests are presented and discussed.

  12. Tuning cationic composition of La:EuTiO{sub 3??} films

    SciTech Connect (OSTI)

    Shkabko, Andrey, E-mail: shkabko@gmail.com [Forschungszentrum Jülich, Peter Grünberg Institut (PGI-7), D-52425 Jülich (Germany); Empa, Solid State Chemistry and Catalysis, CH-8600 Dübendorf (Switzerland); Xu, Chencheng; Meuffels, Paul; Gunkel, Felix; Dittmann, Regina; Waser, Rainer [Forschungszentrum Jülich, Peter Grünberg Institut (PGI-7), D-52425 Jülich (Germany); Weidenkaff, Anke [Empa, Solid State Chemistry and Catalysis, CH-8600 Dübendorf (Switzerland)

    2013-11-01T23:59:59.000Z

    Eu{sub 1?x}La{sub x}TiO{sub 3??} (x = 0, 0.3, 0.5) films were deposited in a p(Ar(96%)/H{sub 2}(4%)) = 4 × 10{sup ?4} mbar atmosphere on (LaAlO{sub 3}){sub 0.3}-(Sr{sub 2}AlTaO{sub 6}){sub 0.7} vicinal substrates (0.1°). Reflection high-energy electron diffraction oscillation characteristics of a layer-by-layer growth mode were observed for stoichiometric and Ti-rich films and the laser fluence suited to deposit stoichiometric films was identified to be 1.25 J/cm{sup 2} independent of the La content. The variety of resulting film compositions follows the general trend of Eu-enrichment for low laser and Ti-enrichment for high laser fluence. X-ray diffraction confirms that all the films are compressively strained with a general trend of an increase of c-axis elongation for non-stoichiometric films. The surfaces of non-stoichiometric films have an increased roughness, the highest sheet resistances, exhibit the presence of islands, and are Eu{sup 3+} rich for films deposited at low laser fluence.

  13. Structure, Magnetism and Conductivity in Epitaxial Ti-doped ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conductivity in Epitaxial Ti-doped -Fe2O3 Hematite: Experiment and density functional theory Structure, Magnetism and Conductivity in Epitaxial Ti-doped -Fe2O3 Hematite:...

  14. The adhesion of electroless Ni(P) on alumina ceramic using a vacuum-deposited Ti-Pd activator layer

    SciTech Connect (OSTI)

    Severin, J.W.; Hokke, R.; Wel, H. van der; Johnson, M.T.; With, G. de (Philips Research Labs., Eindhoven (Netherlands))

    1993-06-01T23:59:59.000Z

    The adhesion of electrolessly deposited nickel on Al[sub 2]O[sub 3] ceramic substrates using sputtered and evaporated Ti-Pd activator films was studied. The adhesion was measured using the direct pull-off test and the 90[degree] peel test. The morphology and the chemical composition of the fracture surfaces of the samples with evaporated Ti-Pd activator film were studied with scanning electron microscopy/energy, dispersive x-ray, and static secondary ion mass spectroscopy. Failure did not occur along the metal-ceramic interface, but mainly in the alumina, and therefore the strength of the system is determined primarily by the substrate material. Cross-sectional transmission electron microscopy and high-resolution transmission electron microscopy were used to study the interface structure before failure. The oxidation state of Ti at the interface was measured with X-ray photoelectron spectroscopy. This was carried out in the (sub)monolayer range by using a Ti wedge deposited on alumina with a maximum thickness of 0.35 nm. It is concluded that the strong adhesion at the metal-ceramic interface is caused by chemical bonding of the first Ti monolayer with substrate oxygen atoms.

  15. La-doped BaTiO{sub 3} heterostructures: Compensating the polarization discontinuity

    SciTech Connect (OSTI)

    Kumah, D. P.; Clarke, R., E-mail: royc@umich.edu [Applied Physics Program, University of Michigan, Ann Arbor, Michigan 48109 (United States); Yacoby, Y. [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel); Pauli, S. A.; Willmott, P. R. [Swiss Light Source, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

    2013-12-01T23:59:59.000Z

    We demonstrate a route to manipulate the polarization and internal electric field of a complex oxide heterostructure using a layering sequence based on the LaAlO{sub 3}-SrTiO{sub 3} interface. By combining sensitive atomic-level mapping of the structure using direct x-ray phase-retrieval methods with theoretical modeling of the electrostatic charge and polarization, we have devised a novel single-domain polar heterostructure. We find that ionic rearrangement results in strain and free energy minimization, and eliminates the polarization discontinuity leading to a two-fold increase of the spontaneous polarization towards the surface of an ultra-thin single-domain BaTiO{sub 3} film.

  16. Spectral Content of 22Na/44Ti Decay Data: Implications for a Solar Influence

    E-Print Network [OSTI]

    Daniel O'Keefe; Brittany L. Morreale; Robert H. Lee; John B. Buncher; Ephraim Fischbach; Tom Gruenwald; Jere H. Jenkins; Daniel Javorsek II; Peter A. Sturrock

    2012-12-10T23:59:59.000Z

    We report a reanalysis of data on the measured decay rate ratio $^{22}$Na/$^{44}$Ti which were originally published by Norman et al., and interpreted as supporting the conventional hypothesis that nuclear decay rates are constant and not affected by outside influences. We find upon a more detailed analysis of both the amplitude and the phase of the Norman data that they actually favor the presence of an annual variation in $^{22}$Na/$^{44}$Ti, albeit weakly. Moreover, this conclusion holds for a broad range of parameters describing the amplitude and phase of an annual sinusoidal variation in these data. The results from this and related analyses underscore the growing importance of phase considerations in understanding the possible influence of the Sun on nuclear decays. Our conclusions with respect to the phase of the Norman data are consistent with independent analyses of solar neutrino data obtained at Super-Kamiokande-I and the Sudbury Neutrino Observatory (SNO).

  17. Carrier-Controlled Ferromagnetism in SrTiO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moetakef, Pouya; Williams, James R.; Ouellette, Daniel G.; Kajdos, Adam P.; Goldhaber-Gordon, David; Allen, S. James; Stemmer, Susanne

    2012-06-01T23:59:59.000Z

    Magnetotransport and superconducting properties are investigated for uniformly La-doped SrTiO3 films and GdTiO3/SrTiO3 heterostructures, respectively. GdTiO3/SrTiO3 interfaces exhibit a high-density 2D electron gas on the SrTiO3 side of the interface, while, for the SrTiO3 films, carriers are provided by the dopant atoms. Both types of samples exhibit ferromagnetism at low temperatures, as evidenced by a hysteresis in the magnetoresistance. For the uniformly doped SrTiO3 films, the Curie temperature is found to increase with doping and to coexist with superconductivity for carrier concentrations on the high-density side of the superconducting dome. The Curie temperature of the GdTiO3/SrTiO3 heterostructures scales with the thickness of the SrTiO3 quantum well. The results are used to construct a stability diagram for the ferromagnetic and superconducting phases of SrTiO3.

  18. A=16Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy93TI07) (Not observed)

  19. A=16O (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See77AJ02) (See93TI07) (See Energy

  20. A=16Si (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See77AJ02) (See93TI07)

  1. A=17Be (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See77AJ02)6AJ04)93TI07) (Not

  2. A=17He (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02) (Not86AJ04) (Not93TI07) (Not

  3. A=17Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02) (Not86AJ04)Mg (1993TI07)

  4. A=17Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02)71AJ02) (See93TI07) (Not

  5. A=18He (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See72AJ02)72AJ02) (See95TI07)

  6. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See72AJ02)72AJ02) (See95TI07)Li

  7. A=18Mg, etc. (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See72AJ02)72AJ02)95TI07) (Not

  8. A=18N (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed)95TI07) (See Energy Level

  9. A=19He (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not72AJ02) (See Energy95TI07)

  10. A=19Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not72AJ02) (See95TI07) (Not

  11. A=19Mg (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not72AJ02) (See95TI07)83AJ01)Mg

  12. A=19Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not72AJ02)Mg,3AJ01) (See95TI07)

  13. A=20B (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02)98TI06) (Not observed) The

  14. A=20C (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02)98TI06) (Not3AJ01)

  15. A=20F (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02)98TI06)78AJ03)

  16. A=20Li (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02)98TI06)78AJ03)72AJ02)

  17. A=20N (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the Isobar Diagram for3AJ01)98TI06)

  18. A=20Ne (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the Isobar72AJ02) (See98TI06) (See

  19. A=20O (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06) (See Energy Level

  20. A=20n (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06) (See Energy7AJ02)

  1. A=3H (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06) (See

  2. A=3He (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06) (See2010PU04)

  3. A=3Li (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)

  4. A=3n (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04) GENERAL:

  5. A=4H (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04)4

  6. A=4n (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04)4He

  7. A=5Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04)4He5

  8. A=5He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See8AJ01) The 9Be(11B,84AJ01)2002TI10)

  9. A=5n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See8AJ01) The66LA04)74AJ01)2002TI10)

  10. A=6n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01) (Not59AJ76) (See2002TI10) (Not

  11. A=7B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01) (Not59AJ76)2002TI10) (See the

  12. A=7Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)59AJ76) (See74AJ01)2002TI10) (See

  13. A=9C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram2004TI06)2004TI06) (See

  14. A=10Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06) (See8AJ01)2004TI06) (See Energy

  15. A=10N (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06) (See8AJ01)2004TI06)8AJ01)

  16. Electrochemical corrosion behavior of biomedical Ti22Nb and Ti22Nb6Zr alloys in saline medium

    E-Print Network [OSTI]

    Zheng, Yufeng

    Electrochemical corrosion behavior of biomedical Ti­22Nb and Ti­22Nb­6Zr alloys in saline medium B addition and potentiodynamic polarization on the microstructure and corrosion resistance of Ti­22Nb and Ti­22Nb­6Zr alloy samples.The corrosion tests were carried out in 0.9% NaCl at 37 8C and neutral p

  17. Recovery of Li from alloys of Al- Li and Li- Al using engineered scavenger compounds

    DOE Patents [OSTI]

    Riley, W. D. (Albany, OR); Jong, B. W. (Corvallis, OR); Collins, W. K. (Albany, OR); Gerdemann, S. J. (Albany, OR)

    1994-01-01T23:59:59.000Z

    A method of producing lithium of high purity from lithium aluminum alloys using an engineered scavenger compound, comprising: I) preparing an engineered scavenger compound by: a) mixing and heating compounds of TiO2 and Li2CO3 at a temperature sufficient to dry the compounds and convert Li.sub.2 CO.sub.3 to Li.sub.2 O; and b) mixing and heating the compounds at a temperature sufficient to produce a scavenger Li.sub.2 O.3TiO.sub.2 compound; II) loading the scavenger into one of two electrode baskets in a three electrode cell reactor and placing an Al-Li alloy in a second electrode basket of the three electrode cell reactor; III) heating the cell to a temperature sufficient to enable a mixture of KCl-LiCl contained in a crucible in the cell to reach its melting point and become a molten bath; IV) immersing the baskets in the bath until an electrical connection is made between the baskets to charge the scavenger compound with Li until there is an initial current and voltage followed by a fall off ending current and voltage; and V) making a connection between the basket electrode containing engineered scavenger compound and a steel rod electrode disposed between the basket electrodes and applying a current to cause Li to leave the scavenger compound and become electrodeposited on the steel rod electrode.

  18. Oriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Park, Byungwoo

    of highly-oriented anatase TiO2 nanocrystals, are adopted as photoelectrodes in dye-sensitized solar cells. [1­4]. In particular, lightweight and flexible dye-sensitized solar cells (DSSCs) have received muchOriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized

  19. Gas-phase transport of WF6 through annular nanopipes in TiN during chemical vapor deposition of W on TiN/Ti/SiO2 structures for integrated

    E-Print Network [OSTI]

    Allen, Leslie H.

    Gas-phase transport of WF6 through annular nanopipes in TiN during chemical vapor deposition of W through the 106-nm-thick TiN film. W piles up at the TiN/Ti interface, while F rapidly saturates the TiN-sectional and scanning transmission electron microscopy analyses demonstrate that WF6 penetrates into the TiN layer

  20. Si l ti f Eth l D h d ti 2013 9 23()

    E-Print Network [OSTI]

    Hong, Deog Ki

    Si l ti f Eth l D h d ti 2013 9 23() Simulation of Ethanol Dehydration Using Cyclohexane overhead. Ethanol is obtained as a top product from an extractive distillation with ethylene glycol point. Ethanol / Water System rMoleFractionofEthanol 0.3 0.4 0.5 0.6 0.7 0.8 0.9 Binary azeotropic

  1. Effect of Ti concentration on the structure and texture of SiTiOC glasses

    SciTech Connect (OSTI)

    Tellez, L. [Dpt. Ing. Metalurgica. ESIQIE-Instituto Politecnico Nacional. Zacatenco, 07738 Mexico D.F. (Mexico); Rubio, J. [Instituto de Ceramica y Vidrio. C.S.I.C. Campus de la Universidad Autonoma de Madrid, Canto Blanco 28049, Madrid (Spain); Valenzuela, M.A., E-mail: mavalenz@ipn.mx [Lab. Catalisis y Materiales, ESIQIE-Instituto Politecnico Nacional. Zacatenco, 07738 Mexico D.F. (Mexico); Rubio, F.; Oteo, J.L. [Instituto de Ceramica y Vidrio. C.S.I.C. Campus de la Universidad Autonoma de Madrid, Canto Blanco 28049, Madrid (Spain)

    2009-06-15T23:59:59.000Z

    Five different silicon-titanium organic-inorganic hybrid materials were prepared by the reaction of tetraethoxysilane, titanium tetrabutoxide and silanol-terminated polydimethylsiloxane. Si-Ti oxycarbide glasses were prepared by pyrolysis of the hybrid materials in nitrogen atmosphere in the range of 400 to 1500 deg. C. The obtained Si-Ti oxycarbide materials were characterized by Fourier Transform-Infra Red spectroscopy, X-ray-diffraction, mercury porosimetry and SEM. The study indicated that the reactivity towards water increases up to 1000 deg. C, at higher temperatures it decreases for all samples. During the pyrolysis, Ti atoms were incorporated into the silicate network leading to the formation of Si-Ti oxycarbide glasses, except with sample containing 7% of Ti which presented also the formation of {beta}-SiC and TiC crystalline phases. The porosity was increased up to 600 deg. C and then decreased tending to disappear at 1500 deg. C. When the titanium concentration increased from 1 to 3% in the oxycarbide glass, the porosity decreased; for higher concentration, an increase in the porosity was observed.

  2. L Al N l D t N dLos Alamos Nuclear Data Needs and Activities From Experiment

    E-Print Network [OSTI]

    Danon, Yaron

    L Al N l D t N dLos Alamos Nuclear Data Needs and Activities ­ From Experiment Th h A li ti Kawano, Patrick Talou, Morgan White LA-UR-11-10498LA UR 11 10498 Presented at: RPI Nuclear Data 2011 Symposium for Criticality Safety and Reactor Applications A il 27 2011 Operated by Los Alamos National

  3. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory ALS Evidence Confirms Combustion Theory Print Wednesday, 22 October 2014 11:43 Researchers recently uncovered the first step in the process...

  4. ALS Beamlines Directory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG,ALS Beamlines Directory PrintALS

  5. ALS User Meeting Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS Reveals NewALS TechniqueALS

  6. Measurement of the $^{44}$Ti($\\alpha$,p)$^{47}$V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed $^{44}$Ti.

    E-Print Network [OSTI]

    Murphy, Alexander

    2015-01-01T23:59:59.000Z

    Measurement of the $^{44}$Ti($\\alpha$,p)$^{47}$V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed $^{44}$Ti.

  7. Ultraviolet photoluminescence from Gd-implanted AlN epilayers

    SciTech Connect (OSTI)

    Zavada, J. M.; Nepal, N.; Lin, J. Y.; Jiang, H. X.; Brown, E.; Hoemmerich, U.; Hite, J.; Thaler, G. T.; Abernathy, C. R.; Pearton, S. J.; Gwilliam, R. [U.S. Army Research Office, Durham, North Carolina 27709 (United States); Department of Physics, Kansas State University, Manhattan, Kansas 66506-2601 (United States); Department of Physics, Hampton University, Hampton, Virginia 23668 (United States); Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Surrey Ion Beam Center, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)

    2006-10-09T23:59:59.000Z

    Deep ultraviolet emission from gadolinium (Gd)-implanted AlN thin films has been observed using photoluminescence (PL) spectroscopy. The AlN epilayers were ion implanted with Gd to a total dose of {approx}6x10{sup 14} cm{sup -2}. Using the output at 197 nm from a quadrupled Ti:sapphire laser, narrow PL emission was observed at 318 nm, characteristic of the trivalent Gd ion. A broader emission band, also centered at 318 nm, was measured with excitation at 263 nm. The PL emission intensity decreased by less than a factor of 3 over the sample temperature range of 10-300 K and decay transients were of the order of nanoseconds.

  8. Influence of fatigue on the nanohardness of NiTiCr-wires

    SciTech Connect (OSTI)

    Frotscher, M. [Ruhr University, Bochum, Germany; Young, M. L. [Ruhr University, Bochum, Germany; Bei, Hongbin [ORNL; George, Easo P [ORNL; Neuking, K. [Ruhr University, Bochum, Germany; Eggeler, G. [Ruhr University, Bochum, Germany

    2009-01-01T23:59:59.000Z

    Testing parameters, such as rotational speed and bending radius, have a strong influence on the fatigue life of pseudoelastic NiTi shape-memory alloys during bending rotation fatigue (BRF) experiments [M. F. X. Wagner, Int. J. Mat. Res. 97 (2006), p. 1687-1696. and M. Frotscher, et al., Thermomechanical processing, microstructure and bending rotation fatigue of ultra-fine grained NiTiCr-wires, Proceedings of the International Conference for Shape Memory and Superelastic Technologies (SMST 2007), Tsukuba, Japan, ASM International, (2008), p. 149-158.]. Previous studies showed a decrease in the fatigue life for smaller bending radius (i.e. higher equivalent strain) and larger rotational speed. This observation is associated with an increase of dislocation density, the stabilization of stressinduced martensite during cycling, and an increase of the plateau stresses due to self-heating. In the present study, we examine the influence of these fatigue parameters on the nanohardness and shape recovery of pseudoelastic NiTiCr shape-memory alloy wires by nanoindentation. We show that nanoindentation is a suitable method for the characterization of fatigue-related microstructural changes, which affect the mechanical properties.

  9. Structural and Morphological Difference Between Ti/TiN/TiCN Coatings Grown in Multilayer and Graded Form

    SciTech Connect (OSTI)

    Restrepo, E.; Baena, A.; Agudelo, C.; Castillo, H.; Devia, A. [Laboratorio de Fisica del Plasma, Universidad Nacional de Colombia Sede Manizales, Campus La Nubia, Manizales (Colombia); Marino, A. [Departamento de Fisica, Universidad Nacional de Colombia Sede Bogota, Av. Cra. 30 No. 45-03, Bogota (Colombia)

    2006-12-04T23:59:59.000Z

    Thin films can be grown in super-lattice, multilayers and graded form, having each one advantages and disadvantages. The difference between multilayer and graded coatings is the interface. In multilayers the interface is abrupt and in graded coatings it is diffuse. The interface influences many chemical and physical properties of the materials, and its choice depends on the application. Graded coatings have the advantage of having gradual properties such as thermal expansion coefficient and lattice parameter, avoiding adherence problems due to good match between their component materials. In this work the comparison between some properties of coatings grown as multilayer and graded is performed. The materials are produced using the sputtering DC technique because of its facility to control the deposition parameters and generate a slow growth. The target is a disc of titanium and the samples are made of stainless steel 304. The working gases are argon, nitrogen and methane, which are mixed according to the material to be produced, i.e. Ti layer is grown with argon, the TiN film is produced with a mixture of argon and nitrogen, and the TiCN material is obtained mixing argon, nitrogen and methane. These materials are characterized with AFM in order to determine grain size and with XPS studying the chemical composition and performing depth profiles.

  10. TiNi shape memory alloy thin films for microactuator application

    E-Print Network [OSTI]

    Fu, Yongqing

    TiNi films were prepared by co-sputtering TiNi target and a separate Ti target. Crystalline structure and phase transformation behaviors of TiNi films were investigated. Results showed that TiNi films had fine grain size ...

  11. Smith et al Supporting Information

    E-Print Network [OSTI]

    Jarvis, Erich D.

    Smith et al 1 Supporting Information for Smith et al. 2006, PLoS Computational Biology 2:e161-hyperpallium apicale; HF-hippocampal formation, and M-mesopallium. #12;Smith et al 2 FigureS2,nolinkswerefoundbetweenelectrodesindifferentbirds,andnolinkswerefoundintothesoundstimulusvariable. CombinedAnalysisofAllBirds'ElectrodesPlusSound #12;Smith et al 3 Analysis of Data from Subsections

  12. Microstructure and mechanical properties of Ti-40 wt pct Ta (Ti-15 at. pct Ta)

    SciTech Connect (OSTI)

    Cotton, J.D.; Bingert, J.F.; Dunn, P.S.; Patterson, R.A. (Los Alamos National Lab., NM (United States))

    1994-03-01T23:59:59.000Z

    Of the [beta]-isomorphous Ti-X alloy systems, Ti-Ta is one of the least studied. In the current work, the microstructure and mechanical properties of Ti-40 wt pct Ta (Ti-15 at. pct Ta) are investigated. Annealing at 810 C produces a two-phase microstructure consisting of Ti-rich [alpha] idiomorphs in a continuous Ta-rich [beta] matrix; this suggest the [beta]-transus temperature is higher than indicated by the most recently published phase diagram. Water quenching from 810 C caused the [beta] phase to partially transform to orthorhombic martensite ([alpha][double prime]), while furnace cooling yields secondary [alpha]. The primary [alpha] formed isothermally remains unchanged in both cases. Subsequent aging causes transformation of the martensite to type 1 [alpha] plus residual [beta], with a corresponding increase in strength and decrease in ductility. The maximum ductility (20 pct elongation) occurs in the water-quenched condition in which metastable [beta] is retained. Analysis of the true stress-true strain data suggests that transformation-induced plasticity may contribute to the enhanced ductility of the water-quenched material.

  13. A=20He (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02)98TI06)78AJ03)72AJ02) (SeeHe

  14. A=8C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)59AJ76)7n8Be (59AJ76)2004TI06)

  15. A=8He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)59AJ76)7n8Be79AJ01) (See2004TI06)

  16. Effect of N2 /Ar gas flow ratio on the deposition of TiN/Ti coatings on NiTi shape memory alloy by PIIID

    E-Print Network [OSTI]

    Zheng, Yufeng

    and deposition technique. The effect of nitrogen to argon gas flow ratio on the surface characteristics, chemical in standard uncoated titanium implants [7]. To date, NiTi alloy has found numerous clinical applica- tions. The nitrogen to argon ratio was changed in order to obtain the stoichiometric TiN coating. The surface

  17. anodized ti-6al-4v alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Battery Anode Material Chemistry Websites Summary: Template Synthesis of Hollow Sb Nanoparticles as a High-Performance Lithium Battery Anode Material the graphite...

  18. Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4

    Broader source: Energy.gov (indexed) [DOE]

    * mechanicalelastic properties * interatomic forces phonons, ab initio molecular dynamics * combined with other theories, e.g., calculating transition temperature Systems:...

  19. TEMPERATURE DEPENDENT CREEP EXPANSION OF Ti-6Al-4V LOW DENSITY CORE SANDWICH STRUCTURES

    E-Print Network [OSTI]

    Wadley, Haydn

    by their high manufacturing costs. Interest has therefore developed in an entrapped gas expansion process entrapped gas expansion processing the driving force governing the re-expansion step is the internal pore of the expansion itself (an increase in void volume lowers the gas pressure) or because of gas lost through

  20. Thermo-optical modulation for improved ultrasonic fatigue crack detection in Ti6Al4V

    E-Print Network [OSTI]

    Nagy, Peter B.

    scatterers, such as surface grooves, corrosion pits, coarse grains, etc. that might hide the fatigue crack to grow at unexpectedly high growth rates well below the large-crack threshold in aluminum, aluminum­lithium) and secondary irregulari- ties (e.g. uneven machining, mechanical wear, corrosion, etc.). Second

  1. al-ti-c master alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thi Hong Tam Maguire Jr., Gerald Q. 367 Hawaii Bioenergy Master Plan Bioenergy Technology Renewable Energy Websites Summary: technology assessment was conducted as part of the...

  2. Interactions Between Wear Mechanisms in a WC-Co / Ti-6Al-4V Machining Tribosystem

    E-Print Network [OSTI]

    Bai, Qiong

    2014-12-11T23:59:59.000Z

    The objective of this research work is to identify and analyze the interactions between wear mechanisms in a machining tribosystem, and to confirm the fundamental physicochemical material interaction behavior through tribometric tests. The machining...

  3. Characterisation of Mechanically Alloyed Ti-Al-B Nanocomposite Consolidated by Spark Plasma Sintering

    E-Print Network [OSTI]

    Han, Young Hwan

    2003-01-01T23:59:59.000Z

    consolidated by spark plasma sintering H. B. Lee, S. H. Kim,consolidated by spark plasma sintering of mechanicallyfollowed by SPS (spark plasma sintering) is well suited for

  4. Controllable giant dielectric constant in AlO{sub x}/TiO{sub y} nanolaminates.

    SciTech Connect (OSTI)

    Li, W.; Chen, Z.; Premnath, R. N.; Kabius, B.; Auciello, O. (Center for Nanoscale Materials); ( MSD); (Univ. of Puerto Rico)

    2011-01-01T23:59:59.000Z

    Dielectric materials exhibiting high dielectric constants play critical roles in a wide range of applications from microchip energy storage embedded capacitors for implantable biomedical devices to energy storage capacitors for a new generation of renewable energy generation/storage systems. Instead of searching for new materials, we demonstrate that giant dielectric constants can be achieved by integrating two simple oxides with low dielectric constants into nanolaminate structures. In addition, the obtained dielectric constant values are highly tunable by manipulating the sub-layer thicknesses of the component oxides to control the number of interfaces and oxygen redistribution. The work reported here opens a new pathway for the design and development of high dielectric constant materials based on the nanolaminate concept.

  5. alloyed al-ti powders: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - TxSpace Summary: The research in this thesis covers the design and implementation of a depleted uranium (DU) powder production system and the initial results of a DU-Zr-Mg alloy...

  6. Materials Data on TiAlAu2 (SG:225) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02T23:59:59.000Z

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof Energy Change RequestFirstchampions,Department ofConversion

  8. Effect of reinforcing particle type on morphology and age-hardening behavior of Al–4.5 wt.% Cu based nanocomposites synthesized through mechanical milling

    SciTech Connect (OSTI)

    Mostaed, A., E-mail: alimostaed@yahoo.com [Advanced Materials and Nanotechnology Research Center, Faculty of Mechanical Engineering, K.N. Toosi University of Technology, 16765-3381 Pardis Street, Tehran (Iran, Islamic Republic of); Saghafian, H.; Mostaed, E. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, 16846-13114 Narmak, Tehran (Iran, Islamic Republic of); Shokuhfar, A. [Advanced Materials and Nanotechnology Research Center, Faculty of Mechanical Engineering, K.N. Toosi University of Technology, 16765-3381 Pardis Street, Tehran (Iran, Islamic Republic of); Rezaie, H.R. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, 16846-13114 Narmak, Tehran (Iran, Islamic Republic of)

    2013-02-15T23:59:59.000Z

    The effects of reinforcing particle type (SiC and TiC) on morphology and precipitation hardening behavior of Al–4.5%Cu based nanocomposites synthesized via mechanical milling were investigated in the current work. In order to study the microstructure and morphology of mechanically milled powder, X-ray diffraction technique, scanning electron microscopy and high resolution transmission electron microscopy were utilized. Results revealed that at the early stages of mechanical milling, when reinforcing particles are polycrystal, the alloying process is enhanced more in the case of using the TiC particles as reinforcement. But, at the final stages of mechanical milling, when reinforcing particles are single crystal, the alloying process is enhanced more in the case of using the SiC ones. Transmission electron microscopy results demonstrated that Al–4.5 wt.%Cu based nanocomposite powders were synthesized and confirmed that the mutual diffusion of aluminum and copper occurs through the interfacial plane of (200). The hardness results showed that not only does introducing 4 vol.% of reinforcing particles (SiC or TiC) considerably decrease the porosity of the bulk composite samples, but also it approximately doubles the hardness of Al–4.5 wt.%Cu alloy (53.4 HB). Finally, apart from TEM and scanning electron microscopy observation which are localized, a decline in hardness in the TiC and SiC contained samples, respectively, after 1.5 and 2 h aging time at 473 K proves the fact that the size of SiC particles is smaller than the size of the TiC ones. - Highlights: ? HRTEM results show mutual diffusion of Al and Cu occurs through the (200) planes. ? TiC particles enhance alloying process more than the SiC ones at the early stages of MM. ? SiC particles enhance alloying process more than the TiC ones at the final stages of MM.

  9. Oxygen Vacancies and Ferromagnetism in CoxTi–x–y...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Ferromagnetism in CoxTi–x–y. Abstract: Abstract: Cobalt-doped titanium dioxide, or CTO, has emerged in the past two years as a semiconducting, transparent,...

  10. Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Abstract: Understanding hydrogen formation on TiO2...

  11. Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Abstract: Rutile TiO2 nanorods were synthesized by...

  12. Lithium Diffusion in Li4Ti5O12 at High Temperatures. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Diffusion in Li4Ti5O12 at High Temperatures. Lithium Diffusion in Li4Ti5O12 at High Temperatures. Abstract: Synthesis of the spinel lithium titanate Li4Ti5O12 by an...

  13. Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated Production of H-2 and O-2 in Amorphous Solid Water Films on TiO2 Nonthermal Water Splitting on Rutile TiO2:...

  14. Acetone and Water on TiO(110): H/D Exchange. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO(110): HD Exchange. Acetone and Water on TiO(110): HD Exchange. Abstract: Isotopic HD exchange between coadsorbed acetone and water on the TiO&8322;(110) surface was...

  15. The Influence of Ni-Coated TiC on Laser-Deposited IN625 Metal Matrix Composites

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    matrix and the TiC particles, the interaction between the laser beam and TiC ceramicmatrix and the TiC particles, the interaction between the laser beam and the TiC ceramic

  16. Microstructural Characterization and Shape Memory Response of Ni-Rich NiTiHf and NiTiZr High Temperature Shape Memory Alloys

    E-Print Network [OSTI]

    Evirgen, Alper

    2014-08-14T23:59:59.000Z

    NiTiHf and NiTiZr high temperature shape memory alloys (HTSMAs) have drawn a great deal of attention as cheaper alternatives to Pt, Pd and Au alloyed NiTi-based HTSMAs while NiTiZr alloys also providing at least 20% weight reduction then its Ni...

  17. Influence of Ni on Martensitic Phase Transformations in NiTi Shape Memory Alloys

    SciTech Connect (OSTI)

    Frenzel, J. [Ruhr University, Bochum, Germany; George, Easo P [ORNL; Dlouhy, A. [Institute of Physics of Materials, Brno, Czech Republic; Somsen, Ch. [Ruhr University, Bochum, Germany; Wagner, M. F.-X [Ruhr University, Bochum, Germany; Eggeler, G. [Ruhr University, Bochum, Germany

    2010-01-01T23:59:59.000Z

    High-precision data on phase transformation temperatures in NiTi, including numerical expressions for the effect of Ni on M{sub S}, M{sub F}, A{sub S}, A{sub F} and T{sub 0}, are obtained, and the reasons for the large experimental scatter observed in previous studies are discussed. Clear experimental evidence is provided confirming the predictions of Tang et al. 1999 regarding deviations from a linear relation between the thermodynamic equilibrium temperature and Ni concentration. In addition to affecting the phase transition temperatures, increasing Ni contents are found to decrease the width of thermal hysteresis and the heat of transformation. These findings are rationalized on the basis of the crystallographic data of Prokoshkin et al. 2004 and the theory of Ball and James. The results show that it is important to document carefully the details of the arc-melting procedure used to make shape memory alloys and that, if the effects of processing are properly accounted for, precise values for the Ni concentration of the NiTi matrix can be obtained.

  18. Experimental: Sample Preparation TiO2 compact (TiO2comp) anatase films (0.1

    E-Print Network [OSTI]

    state device based on the wealth of knowledge housed in the field of Dye Sensitized Solar Cells (20 min, 110 °C). Cell geometries : (1) ITO/TiO2comp/PbS/Pedot/Au (2) ITO/TiO2comp/TiO2nps and Development of Extremely Thin Absorber Solid State Solar Cells Matteo Biancardo*, Frederik Krebs The Danish

  19. ALS Activity Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG, APIL.AFTFutureALPES20thALS

  20. ALS Beamlines Directory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG,ALS Beamlines Directory Print

  1. ALS Beamlines Directory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG,ALS Beamlines Directory

  2. ALS Chemistry Lab

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  3. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG,ALS BeamlinesALSALSALSALSALSALS

  4. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG,ALS

  5. ALS Communications Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy, science,SpeedingWu,IntelligenceYou are70 Years ofAA-Z Index A B ALS

  6. About the ALS

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  7. ALS Communications Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALS Communications Group Print

  8. ALS Postdoctoral Fellowship Highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  9. ALS User Meeting Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  10. ALS in the News

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  11. 2013 ALS User Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruary 2004AugustApril 2013 Wed,SeptemberNovember33 ALS

  12. Access to the ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP7-0973 1 Introduction In theACME -ToggleAccess to the ALS Print

  13. Epitaxially grown sputtered LaAlO sub 3 films

    SciTech Connect (OSTI)

    Lee, A.E.; Platt, C.E.; Burch, J.F.; Simon, R.W. (TRW Space Technology Group, Redondo Beach, CA (USA)); Goral, J.P.; Al-Jassim, M.M. (Solar Energy Research Institute, Golden, CO (USA))

    1990-11-05T23:59:59.000Z

    We have grown crystalline thin films of LaAlO{sub 3} using off-axis rf sputtering from a single stoichiometric target. The films grow epitaxially on SrTiO{sub 3} and LaAlO{sub 3} (100) substrates as well as on YBa{sub 2}Cu{sub 3}O{sub 7} thin films. We report on the growth conditions used to make these films, the properties of the films, and the properties of bilayer and trilayer structures containing both LaAlO{sub 3} and YBa{sub 2}Cu{sub 3}O{sub 7} films. Transmission electron microscopy cross-sectional and x-ray diffraction analyses indicate that all the constituent films in the multilayers grow epitaxially and that the interfaces between the films are sharply defined. Preliminary transport measurements on these multilayers show that LaAlO{sub 3} can be used for dielectric layers in a variety of high-temperature superconductor electronic circuits.

  14. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

  15. Film Coating Process Research and Characterization of TiN Coated Racetrack-type Ceramic Pipe

    E-Print Network [OSTI]

    Wang, Jie; Zhang, Bo; Wei, Wei; Fan, Le; Pei, Xiangtao; Hong, Yuanzhi; Wang, Yong

    2015-01-01T23:59:59.000Z

    TiN film was coated on the internal face of racetrack-type ceramic pipe by three different methods: radio-frequency sputtering, DC sputtering and DC magnetron sputtering. The deposition rates of TiN film under different coating methods were compared. According to the AFM, SEM, XPS test results,these properties were analyzed, such as TiN film roughness and surface morphology. At the same time, the deposition rates were studied under two types' cathode, Ti wires and Ti plate. According to the SEM test results, Ti plate cathode can improve the TiN/Ti film deposition rate obviously.

  16. Size-Dependent Detachment-Limited Decay Kinetics of Two-Dimensional TiN Islands on TiN(111)

    E-Print Network [OSTI]

    Gall, Daniel

    Size-Dependent Detachment-Limited Decay Kinetics of Two-Dimensional TiN Islands on TiN(111) S kinetics of two-dimensional TiN adatom and vacancy islands on atomically smooth TiN(111) terraces. We numbers: 68.35.Md, 68.35.Fx, 68.37.Ef, 82.45.Mp B1-NaCl structure TiN is widely used as a hard wear

  17. A=16Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See

  18. A=16Ne (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See77AJ02) (See the

  19. A=17B (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See77AJ02)6AJ04) (Not

  20. A=17C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)

  1. A=17F (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02) (Not illustrated)6AJ04)

  2. A=17Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02) (Not86AJ04)

  3. A=17N (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02)

  4. A=17Ne (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02)71AJ02)6AJ04) (See the

  5. A=17O (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07)71AJ02)71AJ02)6AJ04)6AJ04)

  6. A=17P (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See (1983ANZQ, 1988WA18,

  7. A=17Si (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See (1983ANZQ, 1988WA18,Si

  8. A=18B (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See (1983ANZQ,8 -

  9. A=18Be (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See (1983ANZQ,8

  10. A=18C (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See

  11. A=18F (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See72AJ02)

  12. A=19B (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not

  13. A=19Be (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not observed) See

  14. A=19C (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not observed)

  15. A=19F (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not

  16. A=19N (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02) (Not72AJ02)Mg, etc.3AJ01)

  17. A=19Ne (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02) (See Energy Level

  18. A=19O (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not87AJ02)7AJ02) (See

  19. A=20Mg (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the Isobar Diagram for 20Mg)

  20. A=20Na (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the Isobar

  1. A=5H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See8AJ01) The 9Be(11B, 15O) reaction

  2. A=5Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See8AJ01) The66LA04) (See8AJ01)

  3. A=6B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See8AJ01)4AJ01) (Not

  4. A=6Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See8AJ01)4AJ01) (Not79AJ01)

  5. A=6C (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See8AJ01)4AJ01)79AJ01)

  6. A=6H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)

  7. A=6He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01) (Not illustrated) 6H

  8. A=6Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01) (Not

  9. A=7Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)

  10. A=7H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)59AJ76) (See the8AJ01) 7H has

  11. A=7He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)59AJ76) (See the8AJ01)8AJ01)

  12. A=8B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)59AJ76)7n (1979AJ01)

  13. A=8Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02)74AJ01)59AJ76)7n

  14. A=8n (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for 8Li)2004TI06) (Not

  15. A=9B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for2004TI06) (See Energy

  16. A=9Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram2004TI06) (See Energy Level

  17. A=9Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01) (See2004TI06)

  18. A=10B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06) (See Energy Level Diagrams for

  19. A=10Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06) (See Energy

  20. A=10C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06) (See Energy59AJ76)

  1. A=10F (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06) (See8AJ01) (Not illustrated)

  2. A=10He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06) (See8AJ01) (Not4AJ01)

  3. A=10Ne (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06)8AJ01) (Not illustrated)

  4. A=10O (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober2004TI06)8AJ01) (Not8AJ01) (Not

  5. A=16C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy Level Diagrams for 16C)

  6. A=16F (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy Level6AJ04) (See

  7. A=16He (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy Level6AJ04)6AJ04)

  8. A=16Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy Level6AJ04)6AJ04)Li

  9. TiSol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f <MaintainedInformationThe yearThermalSoulOaks,MileOpenfieldTiSol

  10. An Organometallic Synthesis of TiO2 Nanoparticles

    E-Print Network [OSTI]

    such as pigments, catalysts, catalyst supports, ceramics, energy storage, magnetic data storage, sensors Siegrist,# Louis E. Brus,, and Michael L. Steigerwald*,, Department of Chemistry, Department of Applied-sensitized TiO2 solar cells are inexpensive and have high photon to electron conversion efficiency.2 TiO2

  11. Facile synthesis of mesoporous core-shell TiO{sub 2} nanostructures from TiCl{sub 3}

    SciTech Connect (OSTI)

    Xue, Bin, E-mail: bxue@shou.edu.cn [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China)] [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China); Sun, Tao; Mao, Fang; Sun, Li-Chun; Yang, Wei [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China)] [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China); Xu, Zhu-De [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)] [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Zhang, Xin [Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051 (China)] [Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051 (China)

    2011-09-15T23:59:59.000Z

    Highlights: {yields} Stable TiCl{sub 3} solution is adopted as Ti sources. {yields} Low-cost glucose assisted facile solvothermal reactions. {yields} Exquisite core-shell morphology and mesoporous structure of TiO{sub 2} nanostructures. {yields} Superior photocatalytic activity of TiO{sub 2} nanostructures in UV light irradiation. -- Abstract: The present study reports the synthesis and formation process of mesoporous core-shell TiO{sub 2} nanostructures by employing a glucose-assisted solvothermal process using water-ethanol mixture as solvent and subsequent calcination process at 550 {sup o}C for 4 h. X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy and nitrogen adsorption-desorption analysis were used to investigate the structural properties of these nanostructures. By optimizing the preparation conditions, especially the contents of water and ethanol in the mixture solvent, mesoporous core-shell TiO{sub 2} nanostructures were obtained. These mesoporous nanostructures have anatase phase and exhibit the superior photocatalytic activity. This synthesis route is facile due to the usage of stable and low-cost Ti precursor such as TiCl{sub 3} and is thus applicable for large-scale production.

  12. Role of polaron hopping in leakage current behavior of a SrTiO3 single crystal Y. Cao, S. Bhattacharya, J. Shen, C. A. Randall, and L. Q. Chen

    E-Print Network [OSTI]

    Chen, Long-Qing

    Transmission Electron Microscopy (HRTEM) and Electron Energy Loss Spectroscopy (EELS), Yang et al. examined towards cathode. The simulated electric potential profile at steady state is in good agreement titanite (BaTiO3), have been widely utilized in various electronic devices such as sensors, actuators

  13. Electrical properties and thermal stability of Pd-doped copper nitride films A. L. Ji, N. P. Lu, L. Gao, W. B. Zhang, L. G. Liao et al.

    E-Print Network [OSTI]

    Zexian, Cao

    Electrical properties and thermal stability of Pd-doped copper nitride films A. L. Ji, N. P. Lu, L/JAPIAU/v113/i4 Published by the American Institute of Physics. Related Articles Photocarrier generation) Controlling interfacial states in amorphous/crystalline LaAlO3/SrTiO3 heterostructures by electric fields Appl

  14. Rutile films grown by molecular beam epitaxy on GaN and AlGaN/GaN P. J. Hansen

    E-Print Network [OSTI]

    York, Robert A.

    Rutile films grown by molecular beam epitaxy on GaN and AlGaN/GaN P. J. Hansen Materials Department March 2005 Titanium dioxide TiO2, with the rutile structure was grown on 0001 oriented GaN and 0001 Al0.33Ga0.67N/GaN heterostructure field effect transistor HFET structures by molecular beam epitaxy. X

  15. TesSol Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with formSoutheasternInformation Tengchong CountyTerniEnergiaTersus

  16. EPR study of Ti3+ ions formed under beta irradiation in silicate

    E-Print Network [OSTI]

    Boyer, Edmond

    1 EPR study of Ti3+ ions formed under beta irradiation in silicate glasses P. Lombard1* , N. Ollier in various silicate glasses have been studied by EPR spectroscopy at 20 K. Different parameters like the [Na of the Ti3+ ion EPR spectra in different Ti-doped silicate glasses has shown three different Ti3

  17. Low-Energy Electron Microscopy Studies of Interlayer Mass Transport Kinetics on TiN(111)

    E-Print Network [OSTI]

    Israeli, Navot

    Low-Energy Electron Microscopy Studies of Interlayer Mass Transport Kinetics on TiN(111) S annealing of three-dimensional (3D) TiN(111) mounds, consisting of stacked 2D islands, at temperatures-limited decay of 2D TiN islands on atomically-flat TiN(111) terraces [Phys. Rev. Lett. 89 (2002) 176102

  18. TiN for MEMS hotplate heaters J.F. Creemer1

    E-Print Network [OSTI]

    Technische Universiteit Delft

    TiN for MEMS hotplate heaters J.F. Creemer1 , P.M. Sarro2 , M. Laros2 , H. Schellevis2 , L, DIMES, ECTM, Mekelweg 4, 2628 CD Delft, Netherlands. Summary: Low-stress TiN has been investigated is required to protect the TiN against oxidation. Keywords: TiN thin films, micro heater, hot plate 1

  19. Development of Ti/Ti{sub 3}Sn functionally gradient material produced by eutectic bonding method

    SciTech Connect (OSTI)

    Kirihara, S.; Takeda, M.; Tsujimoto, T. [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering] [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering

    1996-07-15T23:59:59.000Z

    Although many materials which have a single function have been developed, future needs are anticipated to include materials which have various functions. A functionally gradient material (FGM) which has characteristics of two different materials is a promising candidate for multi-functional material. The present methods for production of FGM, however, are very complicated and costly. In this study the authors answer the serious problem of high production cost by fabricating the FGM by a eutectic bonding method. This fabrication method includes structural control of FGM by changing the cooling process. They describe Ti/Ti{sub 3}Sn FGM obtained by the eutectic bonding method, and tell how the structure of its composition gradient part is changed by controlling the cooling process.

  20. Isothermal nitridation kinetics of TiSi{sub 2} powders

    SciTech Connect (OSTI)

    Roger, J., E-mail: roger@lcts.u-bordeaux1.fr; Maillé, L.; Dourges, M.A.

    2014-04-01T23:59:59.000Z

    The aim of the present work is to determine the kinetics of reaction between TiSi{sub 2} powder and gaseous nitrogen. Isothermal nitridation of TiSi{sub 2} powders with fine (1.4 µm) and medium (4.5 µm) particle size has been studied in pure nitrogen atmosphere from 1000 to 1200 °C for duration up to 50 h. The isothermal nitridation kinetics of TiSi{sub 2} powders were investigated by thermogravimetry. The nitridation rate strongly depends on the particle size and temperature. Smaller size particle exhibits higher nitridation rate due to its larger surface area. The conversion process is complex with nucleation and growth of TiN at the surface of the grain and Si{sub 3}N{sub 4} inside the grain promoted by the Kirkendall effect with an influence of the volume increase. - Graphical abstract: Backscattered electrons image of a transverse TiSi{sub 2} grain nitrurated at 1100 °C for 50 h. - Highlights: • Influence of grain size on TiSi{sub 2} powder nitridation. • Influence of temperature on TiSi{sub 2} powder nitridation. • Experimental measurements of the nitridation kinetics. • An explanation of the nitridation mechanism.

  1. Measurement of neutron capture on 50Ti at thermonuclear energies

    E-Print Network [OSTI]

    P. V. Sedyshev; P. Mohr; H. Beer; H. Oberhummer; Yu. P. Popov; W. Rochow

    1999-07-28T23:59:59.000Z

    At the Karlsruhe and Tuebingen 3.75 MV Van de Graaff accelerators the thermonuclear 50Ti(n,gamma)51Ti(5.8 min) cross section was measured by the fast cyclic activation technique via the 320.852 and 928.65 keV gamma-ray lines of the 51Ti-decay. Metallic Ti samples of natural isotopic composition and samples of TiO2 enriched in 50Ti by 67.53 % were irradiated between two gold foils which served as capture standards. The capture cross-section was measured at the neutron energies 25, 30, 52, and 145 keV, respectively. The direct capture cross section was determined to be 0.387 +/- 0.011 mbarn at 30 keV. We found evidence for a bound state s-wave resonance with an estimated radiative width of 0.34 eV which destructively interfers with direct capture. The strength of a suggested s-wave resonance at 146.8 keV was determined. The present data served to calculate, in addition to the directly measured Maxwellian averaged capture cross sections at 25 and 52 keV, an improved stellar 50Ti(n,gamma)51Ti rate in the thermonuclear energy region from 1 to 250 keV. The new stellar rate leads at low temperatures to much higher values than the previously recommended rate, e.g., at kT=8 keV the increase amounts to about 50 %. The new reaction rate therefore reduces the abundance of 50Ti due to s-processing in AGB stars.

  2. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and...

  3. Nondestructive evaluation of Ni-Ti shape memory alloy

    SciTech Connect (OSTI)

    Meir, S.; Gordon, S.; Karsh, M.; Ayers, R.; Olson, D. L. [Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO (United States); Wiezman, A. [Netania (Israel)

    2011-06-23T23:59:59.000Z

    The nondestructive evaluation of nickel titanium (Ni-Ti) alloys for applications such as heat treatment for biomaterials applications (dental) and welding was investigated. Ni-Ti alloys and its ternary alloys are valued for mechanical properties in addition to the shape memory effect. Two analytical approaches were perused in this work. Assessment of the microstructure of the alloy that determines the martensitic start temperature (Ms) of Ni-Ti alloy as a function of heat treatment, and secondly, an attempt to evaluate a Friction Stir Welding, which involves thermo-mechanical processing of the alloy.

  4. Electrochemical characterization of a low modulus Ti-35.5Nb-7.3Zr-5.7Ta alloy in a simulated body fluid using EIS for biomedical applications

    SciTech Connect (OSTI)

    Bhola, R.; Bhola, S. M.; Mishra, B.; Ayers, R. A.; Olson, D. L. [Department of Metallurgical and Materials Engineering, Colorado School of Mines, 1500 Illinois Street, Golden, CO (United States)

    2011-06-23T23:59:59.000Z

    Electrochemical characterization of the low modulus Ti-35.5Nb-7.3Zr-5.7Ta beta alloy (TNZT) has been performed in phosphate buffer saline solution at 37 deg. C using the non destructive electrochemical impedance spectroscopy technique. Measurements were performed at various immersion intervals at the open circuit potential (OCP), which was also monitored with time. Results obtained for TNZT alloy have been compared with those for the commercially used Ti-6Al-4V mixed alloy (Ti64) and the commercially pure titanium (Ti2) alpha alloy. Potentiodynamic polarization was performed to supplement the data obtained from EIS analysis. The TNZT alloy exhibits a two time constant impedance response, whereas the Ti64 and Ti2 alloys display a one time constant behavior. Human fetal osteoblast cells show a better adhesion and a higher cell count for the TNZT alloy compared to the other two alloys. The present investigation is an effort to understand the correlation between the electrochemical, morphological and cellular characteristics of titanium alloys to qualify them for implant applications.

  5. Modeling and experimental studies of oxide covered metal surfaces: TiO{sub 2}/Ti a model system. Progress report

    SciTech Connect (OSTI)

    Smyrl, W.H.

    1991-12-31T23:59:59.000Z

    Prior work in our laboratories at the Corrosion Research Center has shown that thin, anodic TiO{sub 2} films formed by the Slow Growth Mode (SGM) on polycrystalline titanium and microcrystalline with a texture that varies from one metal grain to another. Furthermore, the underlying metal grains are mapped by the photoelectrochemical response of the oxide. The same characteristics have also been demonstrated in our laboratory for ZnO grown on Zn. The TiO{sub 2}/Ti system has been chosen for study both because of its importance in energy systems, and because it can serve as a model system for other metal-metal oxide couples. The investigations of anodic TiO{sub 2} films on Ti have shown that the properties of thin films are consistent with the rutile form of the oxide. Both experimental data and theoretical calculations show the close resemblance to results on single crystal TiO{sub 2}. Furthermore, the modeling studies reveal that the optical transitions near the bandedge arise from the bulk band structure. The photoelectrochemical properties of anodic TiO{sub 2} films have now been shown to obey the simple Gaertner-Butler model for the semiconductor-electrolyte interface, with a few modifications. The most important deviation has now been shown to be a result of multiple internal reflections in the oxide film.

  6. Modeling and experimental studies of oxide covered metal surfaces: TiO sub 2 /Ti a model system

    SciTech Connect (OSTI)

    Smyrl, W.H.

    1991-01-01T23:59:59.000Z

    Prior work in our laboratories at the Corrosion Research Center has shown that thin, anodic TiO{sub 2} films formed by the Slow Growth Mode (SGM) on polycrystalline titanium and microcrystalline with a texture that varies from one metal grain to another. Furthermore, the underlying metal grains are mapped by the photoelectrochemical response of the oxide. The same characteristics have also been demonstrated in our laboratory for ZnO grown on Zn. The TiO{sub 2}/Ti system has been chosen for study both because of its importance in energy systems, and because it can serve as a model system for other metal-metal oxide couples. The investigations of anodic TiO{sub 2} films on Ti have shown that the properties of thin films are consistent with the rutile form of the oxide. Both experimental data and theoretical calculations show the close resemblance to results on single crystal TiO{sub 2}. Furthermore, the modeling studies reveal that the optical transitions near the bandedge arise from the bulk band structure. The photoelectrochemical properties of anodic TiO{sub 2} films have now been shown to obey the simple Gaertner-Butler model for the semiconductor-electrolyte interface, with a few modifications. The most important deviation has now been shown to be a result of multiple internal reflections in the oxide film.

  7. A comparative first-principles study of martensitic phase transformations in TiPd2 and TiPd

    SciTech Connect (OSTI)

    Krcmar, Maja [Grand Valley State University (GVSU), Michigan] [Grand Valley State University (GVSU), Michigan; Morris, James R [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Martensitic phase transformations in TiPd2 and TiPd alloys are studied employing density-functional, first-principles calculations. We examine the transformation of tetragonal C11b TiPd2 to the low-temperature orthorhombic phase (C11b oI6), and the transformation of cubic B2 TiPd under orthorhombic (B2 B19) and subsequent monoclinic transformations (B19 B19 ) as the system is cooled. To evaluate the transition temperature for TiPd2 we employ a theoretical approach based on a phenomenological Landau theory of the structural phase transition and a mean-field approximation for the free energy, utilizing first-principles calculations to obtain the deformation energy as a function of strains and to deduce parameters for constructing the free energy. The predicted transition temperature for the TiPd2 C11b oI6 transition temperature is in good agreement with reported experimental results. To investigate the TiPd B2 B19 transformation, we employ both the Cauchy-Born rule and a soft-mode- based approach, and elucidate on the importance of coupling of lattice distortion and atomic displacements (i.e., shuffling) in the formation of the final structure. The estimated B2 B19 transition temperature for TiPd system agrees well with the experimental results. We also find that there exists a very small but finite (0.0005 eV/atom) energy barrier of B19 TiPd under monoclinic deformation for B19 B19 structural phase transformation.

  8. TiN Coatings on Fuel Cladding Tube 

    E-Print Network [OSTI]

    Yu, Zhichao 1987-

    2012-05-04T23:59:59.000Z

    demonstrate this new design and deposite TiN on the tubes. A systematic physical property study including surface characterization (SEM), mechanical testing (hardness and scratch test), thermal cycle test and thermal conductivity measurements, was conducted...

  9. TiNi-based thin films for MEMS applications

    E-Print Network [OSTI]

    Fu, Yongqing

    In this paper, some critical issues and problems in the development of TiNi thin films were discussed, including preparation and characterization considerations, residual stress and adhesion, frequency improvement, fatigue ...

  10. Internal Oxidation-Nitridation of Ferritic Fe(Al) Alloys in Air

    SciTech Connect (OSTI)

    Pint, Bruce A [ORNL; Dwyer, Matthew J [Lehigh University, Bethlehem, PA; Deacon, Ryan M [Lehigh University, Bethlehem, PA

    2008-01-01T23:59:59.000Z

    Exposure of undoped Fe(Al) and Fe(Al)+Cr ferritic alloys in laboratory air at 900-1,000 C resulted in significant internal attack after 5,000 h, including oxides and underlying nitrides. In the most severely attacked alloys, kinetics based on mass gain and maximum penetration depth were linear; also, the deepest penetrations were a significant fraction of the specimen thickness, and were thickness-dependent. Little internal attack was observed at 700-800 C where these compositions may be used as coatings. The extent of internal attack did not decrease with increasing Al or Cr content which may indicate that rather than classical internal oxidation this attack is related to the permeation of N through a defective external scale. No internal attack was observed in alloys doped with Y, Zr, Hf or Ti where the substrate-alumina scale interface was flatter.

  11. Seoul National UniversitySeoul National University http://bp.snu.ac.kr1 The Effect of TiCl4-Treated TiO2

    E-Print Network [OSTI]

    Park, Byungwoo

    TiO2 Compact Layer on the Performance of Dye-Sensitized Solar Cell #12;Seoul National UniversitySeoul National University http://bp.snu.ac.kr Dye-Sensitized Solar Cell 2 Schematic Diagram of the Electron Flow by the TiO2 compact layer. Electrolyte Hydrolysis of TiCl4 Solution Dye-Coated TiO2 Back Electron Transfere

  12. Martensite transformation of epitaxial Ni-Ti films

    SciTech Connect (OSTI)

    Buschbeck, J.; Kozhanov, A. [Department Electrical and Computer Engineering, University of California, Santa Barbara, CA 93106 (United States); Kawasaki, J. K. [Department of Materials, University of California, Santa Barbara, CA 93106 (United States); James, R. D. [Department of Aerospace Engineering and Mechanics, University of Minnesota, Minneapolis, MN 55455 (United States); Palmstroem, C. J. [Department Electrical and Computer Engineering, University of California, Santa Barbara, CA 93106 (United States); Department of Materials, University of California, Santa Barbara, CA 93106 (United States)

    2011-05-09T23:59:59.000Z

    The structure and phase transformations of thin Ni-Ti shape memory alloy films grown by molecular beam epitaxy are investigated for compositions from 43 to 56 at. % Ti. Despite the substrate constraint, temperature dependent x-ray diffraction and resistivity measurements reveal reversible, martensitic phase transformations. The results suggest that these occur by an in-plane shear which does not disturb the lattice coherence at interfaces.

  13. SECOND HARMONIC GENERATION OF Bi4Ti3O12 FILMS IN-SITU PROBING OF DOMAIN POLING IN Bi4Ti3O12 THIN

    E-Print Network [OSTI]

    Gopalan, Venkatraman

    SECOND HARMONIC GENERATION OF Bi4Ti3O12 FILMS IN-SITU PROBING OF DOMAIN POLING IN Bi4Ti3O12 THIN FILMS BY OPTICAL SECOND HARMONIC GENERATION YANIV BARAD, VENKATRAMAN GOPALAN Materials Research, of a ferroelectric Bi4Ti3O12 thin film using optical second harmonic generation as a probe. The ferroelectric

  14. Controlling Atomic Layer Deposition of TiO2 in Aerogels through Surface Functionalization

    SciTech Connect (OSTI)

    Ghosal, S; Baumann, T F; King, J S; Kucheyev, S; Wang, Y; Worsley, M A; Biener, J; Bent, S F; Hamza, A V

    2009-03-09T23:59:59.000Z

    This report demonstrates a chemical functionalization method for controlling atomic layer deposition (ALD) of TiO{sub 2} in low-density nanoporous materials. Functionalization of silica aerogel with trimethylsilane is shown to strongly suppress TiO{sub 2} growth via ALD. Subsequent modification of the functionalization through selective removal of the hydrocarbon groups reactivates the aerogel towards TiO{sub 2} deposition. These results demonstrate the potential use of ALD as a selective tool for creating novel nanoporous materials. Nanoporous materials present significant technological advantage for a wide range of applications, including catalysis, energy storage and conversion, nanoelectronics to name just a few (1-4). Hence, there is considerable interest in developing synthetic pathways for the fabrication of nanoporous materials with tailored properties. Aerogels (AGs) are unique low-density, open-cell porous materials consisting of submicrometer pores and ligaments that can be used as a robust material platform for designing novel nanoporous materials. In recent years, a synthetic approach based on ALD on AG templates has emerged as a promising method for the directed growth of nanoporous materials (5-11, 18). This approach has been used successfully to prepare millimeter-sized high aspect ratio aerogels coated uniformly with zinc oxide (ZnO), tungsten (W) and alumina (Al{sub 2}O{sub 3}) (10, 11). The ALD process utilizes two sequential, self-limiting surface reactions resulting in a layer-by-layer growth mode. The self limiting nature of the surface reactions makes ALD a particularly suitable technique for uniform deposition onto high aspect ratio porous substrates. Additionally, chemical specificity of the surface reactions in ALD enables one to control the deposition process through selective functionalization of the substrate surface. In fact the functionalization of planar substrates such as silicon wafers with organosilane groups (R{sub n}SiX{sub 4-n} (n = 1-3)) has been shown to deactivate the substrate towards ZrO{sub 2}, HfO{sub 2}, ZnO, and TiO{sub 2} ALD processes (12-16). A possible mechanism for the deactivation effect is the blocking of surface functional groups, such as hydroxyl (OH) moieties, which serve as chemisorption sites for the ALD precursors and hence are essential for nucleating the deposition process. Henceforth, we shall refer to these surface functional groups as nucleation sites for the ALD process.

  15. Sheet resistance under Ohmic contacts to AlGaN/GaN heterostructures

    SciTech Connect (OSTI)

    Haj?asz, M., E-mail: m.hajlasz@m2i.nl [Materials innovation institute (M2i), Mekelweg 2, 2628 CD, Delft (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE, Enschede (Netherlands); Donkers, J. J. T. M.; Sque, S. J.; Heil, S. B. S. [NXP Semiconductors Research, High Tech Campus 46, 5656 AE, Eindhoven (Netherlands); Gravesteijn, D. J. [NXP Semiconductors Research, High Tech Campus 46, 5656 AE, Eindhoven (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE, Enschede (Netherlands); Rietveld, F. J. R. [NXP Semiconductors, Gerstweg 2, 6534 AE, Nijmegen (Netherlands); Schmitz, J. [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE, Enschede (Netherlands)

    2014-06-16T23:59:59.000Z

    For the determination of specific contact resistance in semiconductor devices, it is usually assumed that the sheet resistance under the contact is identical to that between the contacts. This generally does not hold for contacts to AlGaN/GaN structures, where an effective doping under the contact is thought to come from reactions between the contact metals and the AlGaN/GaN. As a consequence, conventional extraction of the specific contact resistance and transfer length leads to erroneous results. In this Letter, the sheet resistance under gold-free Ti/Al-based Ohmic contacts to AlGaN/GaN heterostructures on Si substrates has been investigated by means of electrical measurements, transmission electron microscopy, and technology computer-aided design simulations. It was found to be significantly lower than that outside of the contact area; temperature-dependent electrical characterization showed that it exhibits semiconductor-like behavior. The increase in conduction is attributed to n-type activity of nitrogen vacancies in the AlGaN. They are thought to form during rapid thermal annealing of the metal stack when Ti extracts nitrogen from the underlying semiconductor. The high n-type doping in the region between the metal and the 2-dimensional electron gas pulls the conduction band towards the Fermi level and enhances horizontal electron transport in the AlGaN. Using this improved understanding of the properties of the material underneath the contact, accurate values of transfer length and specific contact resistance have been extracted.

  16. Shape memory behavior of ultrafine grained NiTi and TiNiPd shape memory alloys

    E-Print Network [OSTI]

    Kockar, Benat

    2009-05-15T23:59:59.000Z

    The cyclic instability in shape memory characteristics of NiTi-based shape memory alloys (SMAs), such as transformation temperatures, transformation and irrecoverable strains and transformation hysteresis upon thermal and mechanical cycling limits...

  17. Photocatalytic reduction of methylene blue by TiO2 nanotube arrays: effects of TiO2 crystalline phase

    E-Print Network [OSTI]

    Kang, Xiongwu; Chen, Shaowei

    2010-01-01T23:59:59.000Z

    reduction of methylene blue by TiO 2 nanotube arrays:the reduction of methylene blue in water as an illustratingpro?les of methylene blue exhibited apparent diminishment.

  18. Al Akhawayn University Al Akhawayn partner of TUM since 2002

    E-Print Network [OSTI]

    Cengarle, María Victoria

    Haddouti · Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW (TUM & AUI Alumni) · BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für

  19. Al Akhawayn University Al Akhawayn partner of TUM since 2002

    E-Print Network [OSTI]

    Cengarle, María Victoria

    Haddouti · Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW) · BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für Informatik TUM School

  20. Al Akhawayn University Al Akhawayn partner of TUM since 2002

    E-Print Network [OSTI]

    Cengarle, María Victoria

    Haddouti · Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW Alumni) · BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für Informatik TUM

  1. Magneto-transport in LaTi{sub 1?x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures

    SciTech Connect (OSTI)

    Kumar, Pramod, E-mail: pramodnpl2011@gmail.com; Dogra, Anjana, E-mail: pramodnpl2011@gmail.com; Budhani, R. C., E-mail: pramodnpl2011@gmail.com [Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Marg, New Delhi-110012 (India)

    2014-04-24T23:59:59.000Z

    We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

  2. Self-Organized Amorphous TiO2 Nanotube Arrays on Porous Ti Foam for Rechargeable Lithium and Sodium Ion Batteries

    SciTech Connect (OSTI)

    Bi, Zhonghe [ORNL; Paranthaman, Mariappan Parans [ORNL; Menchhofer, Paul A [ORNL; Dehoff, Ryan R [ORNL; Bridges, Craig A [ORNL; Chi, Miaofang [ORNL; Guo, Bingkun [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

    2013-01-01T23:59:59.000Z

    Self-organized amorphous TiO2 nanotube arrays (NTAs) were successfully fabricated on both Ti foil and porous Ti foam through electrochemical anodization techniques. The starting Ti foams were fabricated using ARCAM s Electron Beam Melting (EBM) technology. The TiO2 NTAs on Ti foam were used as anodes in lithium ion batteries; they exhibited high capacities of 103 Ahcm-2 at 10 Acm-2 and 83 Ahcm-2 at 500 Acm-2, which are two to three times higher than those achieved on the standard Ti foil, which is around 40 Ahcm-2 at 10 Acm-2 and 24 Ahcm-2 at 500 Acm-2, respectively. This improvement is mainly attributed to higher surface area of the Ti foam and higher porosity of the nanotube arrays layer grown on the Ti foam. In addition, a Na-ion half-cell composed of these NTAs anodes and Na metal showed a self-improving specific capacity upon cycling at 10 Acm-2. These results indicate that TiO2 NTAs grown on Ti porous foam are promising electrodes for Li-ion or Na-ion rechargeable batteries.

  3. Materials Science and Engineering A 374 (2004) 1026 Modeling the elastic properties and damage evolution in TiAl3Ti

    E-Print Network [OSTI]

    Meyers, Marc A.

    2004-01-01T23:59:59.000Z

    , where it is kept for 2­3 h. This enables diffusion bonding of the layers. The temperature is then raised). The MIL process [6] consists of stacking aluminum and titanium foils in alternating layers. and placing

  4. Effects of ductile phase volume fraction on the mechanical properties of Ti-Al?Ti metal-intermetallic laminate (MIL) composites

    E-Print Network [OSTI]

    Price, Richard David

    2010-01-01T23:59:59.000Z

    I. J. Light Alloys - Metallurgy of the Light Metals, 3rdformed by reactive foil metallurgy. ? Materials Science andformed by reactive foil metallurgy. HIP reaction at (a) 1300

  5. Effects of ductile phase volume fraction on the mechanical properties of Ti-Al?Ti metal-intermetallic laminate (MIL) composites

    E-Print Network [OSTI]

    Price, Richard David

    2010-01-01T23:59:59.000Z

    of Self-Propagating High-Temperature Synthesis. Volume 2,a self-propagating, high-temperature synthesis reaction (

  6. Summary Abstract: A study of roomtemperature CuAl2O3 and CuAlN interfacial reactions

    E-Print Network [OSTI]

    Rollins, Andrew M.

    . A 30, 061401 (2012) Gain and loss mechanisms for neutral species in low pressure fluorocarbon plasmas and selectivity between Ti and TiN in fluorocarbon plasmas for dielectric etch J. Vac. Sci. Technol. B 30, 041811

  7. Nucleation kinetics during homoepitaxial growth of TiN(001) by reactive magnetron sputtering Marcel A. Wall, David G. Cahill, I. Petrov, D. Gall, and J. E. Greene

    E-Print Network [OSTI]

    Gall, Daniel

    Nucleation kinetics during homoepitaxial growth of TiN(001) by reactive magnetron sputtering Marcel to study the nucleation of homoepitaxial TiN layers grown on TiN(001) by ultrahigh vacuum reactive kinet- ics of TiN, a two-component refractory ceramic, on TiN 001 . TiN, typically deposited by reactive

  8. Course Syllabus: Chemistry 3AL Course Information

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    Course Syllabus: Chemistry 3AL Course Information Course Name Chemistry 3AL Course Instructor are online. Chemistry 3AL Syllabus https://elearning.berkeley.edu/AngelUploads/Content/2013SUC... 1 of 5 5

  9. Importance of Diffusion in Methanol Photochemistry on TiO2(110...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Importance of Diffusion in Methanol Photochemistry on TiO2(110). Importance of Diffusion in Methanol Photochemistry on TiO2(110). Abstract: The photoactivity of methanol on the...

  10. Electrical transport properties of Ti-doped Fe2O3(0001) epitaxial...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrical transport properties of Ti-doped Fe2O3(0001) epitaxial films. Electrical transport properties of Ti-doped Fe2O3(0001) epitaxial films. Abstract: The electrical transport...

  11. Intrinsic Diffusion of Hydrogen on Rutile TiO2(110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diffusion of Hydrogen on Rutile TiO2(110). Intrinsic Diffusion of Hydrogen on Rutile TiO2(110). Abstract: The combined experimental and theoretical study of intrinsic hydrogen...

  12. Adsorption States and Mobility of TMAA Molecules on Reduced TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    States and Mobility of TMAA Molecules on Reduced TiO2(110) Surface. Adsorption States and Mobility of TMAA Molecules on Reduced TiO2(110) Surface. Abstract: Combined scanning...

  13. Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared via Carboxylic Acid Adsorption and Photolysis. Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared...

  14. Adsorption geometry of CO versus coverage on TiO2(110) from s...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of CO versus coverage on TiO2(110) from s- and p-polarized infrared spectroscopy. Adsorption geometry of CO versus coverage on TiO2(110) from s- and p-polarized infrared...

  15. Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on bridge-bonded oxygen vacancies of TiO2(110) (1×1) surface...

  16. Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1. Abstract: Adsorption, binding, and diffusion of CO2 molecules on rutile TiO2(110) model surfaces was...

  17. Evolution of ferroelectric domain structures embedded inside polychrystalline BaTiO3 during heating

    E-Print Network [OSTI]

    Varlioglu, Mesut

    2010-01-01T23:59:59.000Z

    Polycrystalline BaTiO 3 during Heating Mesut Varlioglu, 1under quasistatic heating by using polychromatic scanning X-180.47° or 0.47°. While heating the polycrystalline BaTiO 3

  18. Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Abstract: We used anionic...

  19. Methylene Bromide Chemistry and Photochemistry on Rutile TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such as CD2Br2 on TiO2 likely occurs via indirect processes (such as OH radical attack) as opposed to direct mechanisms involving charge carriers generated in TiO2 by...

  20. Epitaxial growth of NiTiO3 with a distorted ilmenite structure...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    growth of NiTiO3 with a distorted ilmenite structure. Epitaxial growth of NiTiO3 with a distorted ilmenite structure. Abstract: MTiO3 (M Fe, Mn, Ni) compounds have received...

  1. Study of Martensitic Phase transformation in a NiTiCu Thin Film...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Martensitic Phase transformation in a NiTiCu Thin Film Shape Memory Alloy Using Photoelectron Emission Microscopy. Study of Martensitic Phase transformation in a NiTiCu Thin Film...

  2. Two Pathways for Water Interaction with Oxygen Adatoms on TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    or adjacent Ti4+ rows, Oa facilitates H2O dissociation and proton transfer to form a terminal hydroxyl pair, positioned along- or across-Ti row, respectively. The latter process...

  3. Epitaxial Cr on n-SrTiO3(001)—An ideal Ohmic contact ....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    beam epitaxy are shown to result in an ordered interface with Cr bound to O in the terminal TiO2 layer, no reduction of the SrTiO3, and a near-perfect Ohmic contact. Cr...

  4. The Synthesis of Ag-Doped Mesoporous TiO2 . | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2 . The Synthesis of Ag-Doped Mesoporous TiO2 . Abstract: Ag-doped mesoporous titanium oxide was prepared using non-ionic surfactants and easily handled titanium...

  5. Ti(III) Doped Titanium Dioxide: an Effective Strategy to Improve the Visible Light Photocatalytic Activity

    E-Print Network [OSTI]

    Zuo, Fan

    2012-01-01T23:59:59.000Z

    types of surface titanium and oxygen atoms present. PageRIVERSIDE Ti(III) Doped Titanium Dioxide: an EffectiveDISSERTATION Ti(III) Doped Titanium Dioxide: an Effective

  6. The Synthesis of Cadmium Doped Mesoporous TiO2. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2. The Synthesis of Cadmium Doped Mesoporous TiO2. Abstract: Cd doped mesoporous titanium oxide was prepared using non-ionic surfactants and easily handled titanium...

  7. Water Interactions with Terminal Hydroxyls on TiO2 (110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interactions with Terminal Hydroxyls on TiO2 (110). Water Interactions with Terminal Hydroxyls on TiO2 (110). Abstract: A combination of scanning tunneling microscopy and density...

  8. Acetone and Water on TiO (110): Competition for Sites. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO (110): Competition for Sites. Acetone and Water on TiO (110): Competition for Sites. Abstract: The competitive interaction between acetone and water for surface sites on...

  9. Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Chemistry of 2-Propanol on TiO2(110): Low and High...

  10. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

  11. Chemical Reactivity of Reduced TiO2(110): The dominant role of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

  12. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking....

  13. Acetone-Assisted Oxygen Vacancy Diffusion on TiO2(110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acetone-Assisted Oxygen Vacancy Diffusion on TiO2(110). Acetone-Assisted Oxygen Vacancy Diffusion on TiO2(110). Abstract: We have studied the dynamic relationship between acetone...

  14. Growth of Cr-doped TiO Films in the Rutile and Anatase Structures...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Cr-doped TiO Films in the Rutile and Anatase Structures by Oxygen Plasma Assisted Molecular Beam Epitaxy . Growth of Cr-doped TiO Films in the Rutile and Anatase Structures by...

  15. Room-Temperature Ferromagnetism in Ion-Implanted Co-Doped TiO...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Room-Temperature Ferromagnetism in Ion-Implanted Co-Doped TiO(110) Rutile. Room-Temperature Ferromagnetism in Ion-Implanted Co-Doped TiO(110) Rutile. Abstract: Interest in diluted...

  16. Synthesis of Room-Temperature Ferromagnetic Cr-doped TiO(110...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Room-Temperature Ferromagnetic Cr-doped TiO(110) Rutile Single Crystals using Ion Implantation. Synthesis of Room-Temperature Ferromagnetic Cr-doped TiO(110) Rutile Single Crystals...

  17. Room Temperature Ferromagnetism in Ion-implanted Co-doped TiO...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Room Temperature Ferromagnetism in Ion-implanted Co-doped TiO(110) Rutile. Room Temperature Ferromagnetism in Ion-implanted Co-doped TiO(110) Rutile. Abstract: Ferromagnetic...

  18. WELDABILITY OF GRAIN-REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Morris Jr., J.W.

    2013-01-01T23:59:59.000Z

    of the Cryogenic Nickel Steels, WRC Bull, 205, May, 1975.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.E.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.

  19. Design, optimization, and applications of few-cycle Ti:Sapphire lasers

    E-Print Network [OSTI]

    880-01 Chen, Li jin

    2012-01-01T23:59:59.000Z

    Ti:Sapphire mode-locked lasers are a unique technology that enables a wide variety of applications. Owing to the ultrabroadband nature of the Ti:sapphire crystal and the invention of precisely engineered dispersion-compensating ...

  20. Ti(III) Doped Titanium Dioxide: an Effective Strategy to Improve the Visible Light Photocatalytic Activity

    E-Print Network [OSTI]

    Zuo, Fan

    2012-01-01T23:59:59.000Z

    1 An Overview of Photocatalysis and TiO 2 Photocatalyst 1.11 An Overview of Photocatalysis and TiO 2 Photocatalystthe heterogeneous photocatalysis for solar energy conversion

  1. Photocatalytic degradation of diethyl phthalate using TiO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Singla, Pooja, E-mail: pooja.singla@thapar.edu; Pandey, O. P., E-mail: pooja.singla@thapar.edu; Singh, K., E-mail: pooja.singla@thapar.edu [School of Physics and Materials Science, Thapar University, Patiala-147004 (India)

    2014-04-24T23:59:59.000Z

    TiO{sub 2} nanoparticles predominantly in rutile phase are synthesized by ultrasonication assisted sol-gel method. TiO{sub 2} powder is characterized using X-ray powder diffraction and UV-vis diffuse reflectance. TiO{sub 2} is used as catalyst in photocatalytic degradation of Diethyl Phthalate. TiO{sub 2} exhibits good photocatalytic activity for the degradation of diethyl phthalate.

  2. Corrosion behavior of newly developed TiAgFe dental alloys in neutral saline solution

    E-Print Network [OSTI]

    Zheng, Yufeng

    Corrosion behavior of newly developed Ti­Ag­Fe dental alloys in neutral saline solution B. B. Zhang, B. L. Wang, L. Li and Y. F. Zheng* The corrosion behavior of Ti­5Ag­xFe alloys (x ¼ 1, 2.5, 5 wt) Ti,Ti­ 5Ag­xFe alloys exhibited higher corrosion potentials, lower current densities, and larger

  3. Formby et al.: Integration Without Absolute Energy Cues 1285Journal of Speech, Language, and Hearing Research Vol. 45 12851296 December 2002 American Speech-Language-Hearing Association 1092-4388/02/4506-1285

    E-Print Network [OSTI]

    Heinz, Michael G.

    Formby et al.: Integration Without Absolute Energy Cues 1285Journal of Speech, Language Baltimore Temporal Integration of Sinusoidal Increments in the Absence of Absolute Energy Cues Classical temporal integration (TI) is often viewed as a frequency-dependent, energy-based detection process

  4. ALS Ceramics Materials Research Advances Engine Performance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Ceramics Materials Research Advances Engine Performance ALS Ceramics Materials Research Advances Engine Performance Print Thursday, 27 September 2012 00:00 ritchie ceramics...

  5. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship in ResidenceALS EvidenceALS

  6. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALS Communications GroupALS

  7. Hydrogen adsorption on Pd/TiFe (110) surface S.E. Kulkovaa

    E-Print Network [OSTI]

    Kim, Jai Sam

    Hydrogen adsorption on Pd/TiFe (110) surface S.E. Kulkovaa , S.V. Eremeeva,b,*, V.E. Egorushkinc February 2003 by E.L. Ivchenko Abstract Adsorption of hydrogen on the TiFe (110) surface covered the local density approximation. Influence of palladium coating to adsorption properties of the TiFe (110

  8. A Comparison of Auger Electron Spectra from Stoichiometric Epitaxial TiN,,001...

    E-Print Network [OSTI]

    Gall, Daniel

    , low electrical resistivity 300 K TiN 111 15 cm Ref. 2 due to the overlap of N 2p and Ti 3d bands see. In the experiments, the AES spectra were collected using primary electron beam energies of 3, 5, 10, and 20 ke, Inc. 660 Major Elements in Spectrum: Ti, N Minor Elements in Spectrum: none Printed Spectra: 4 Spectra

  9. Functionally grading the shape memory response in NiTi films: Laser irradiation

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    Functionally grading the shape memory response in NiTi films: Laser irradiation A. J. Birnbaum, G://jap.aip.org/about/rights_and_permissions #12;Functionally grading the shape memory response in NiTi films: Laser irradiation A. J. Birnbaum,a G and mechanism are presented for controlling the shape memory response spatially within monolithic NiTi thin film

  10. Mechanical characterization and comparison of different NiTi/silicone rubber interfaces

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Mechanical characterization and comparison of different NiTi/silicone rubber interfaces T. Rey(1 on the mechanical resistance of interface between wires of NiTi shape memory alloy and silicone rubber. Three of exposure to the plasma alone get the debonding force higher. Consequently, NiTi/silicone rubber interface

  11. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    3, 1976 LBL-5401 l NICKEL-FREE Fe-12Mn-O. 2Ti ALLOY STEELowned rights. I v LBL-540l NICKEL-FREE Fe-12Mn-0.2Ti ALLOY94720 USA ABSTRACT A nickel-free Fe-12Mn-0.2Ti alloy steel

  12. Crystallization and Martensitic Transformation Behavior of NiTi Shape Memory Alloy Thin Films

    E-Print Network [OSTI]

    Crystallization and Martensitic Transformation Behavior of NiTi Shape Memory Alloy Thin Films Alloy Thin Films Abstract The microstructure evolution and shape memory properties of near-equiatomic Ni-Ti thin films were investigated. Ni-Ti thin films sputter-deposited at room tem- perature are usually

  13. Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells Kadiatou photoanodes for dye- sensitized solar cells (DSCs), based on nanocrystalline TiO2 with limited addition applied (i.e., soaking in TiCl4 to boost open circuit photovoltage). INTRODUCTION Dye-sensitized solar

  14. Investigation into Photoconductivity in Single CNF/TiO2-Dye Core–Shell Nanowire Devices

    E-Print Network [OSTI]

    Li, Zhuangzhi; Rochford, Caitlin; Baca, F. Javier

    2010-06-15T23:59:59.000Z

    A vertically aligned carbon nanofiber array coated with anatase TiO2 (CNF/TiO2) is an attractive possible replacement for the sintered TiO2 nanoparticle network in the original dye-sensitized solar cell (DSSC) design due to the potential...

  15. Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a , Huisheng Keywords: TiN films Residual stress Hardness Fracture toughness Morphology, structure, residual stress, hardness, and fracture toughness of magnetron sputtered titanium nitride (TiN) thin films, deposited at 300

  16. Sputtered TiN films for superconducting coplanar waveguide resonators S. Ohya,1, a)

    E-Print Network [OSTI]

    Martinis, John M.

    Sputtered TiN films for superconducting coplanar waveguide resonators S. Ohya,1, a) B. Chiaro,2 A of the properties of TiN films by varying the deposition conditions in an ultra-high-vacuum reactive magnetron changes to weak tensile in-plane strain. The TiN films absorb a high concentration of contaminants

  17. First-principles calculations of step formation energies and step interactions on TiN(001)

    E-Print Network [OSTI]

    Ciobanu, Cristian

    First-principles calculations of step formation energies and step interactions on TiN(001) Cristian the formation energies and repulsive interactions of monatomic steps on the TiN(001) surface, using den- sity studies on different aspects related to thin film growth on TiN surfaces, few atomistic studies have been

  18. TiN surface dynamics: role of surface and bulk mass transport processes

    E-Print Network [OSTI]

    Khare, Sanjay V.

    TiN surface dynamics: role of surface and bulk mass transport processes J. Bareñoa , S. Kodambakab, USA Abstract. Transition-metal nitrides, such as TiN, have a wide variety of applications as hard/decay kinetics of two- and three-dimensional TiN(111) islands and the effect of surface-terminated dislocations

  19. Atomic layer deposition of TiN films Growth and electrical behavior down to

    E-Print Network [OSTI]

    Atomic layer deposition of TiN films Growth and electrical behavior down to sub-nanometer scale Hao Van Bui #12;ATOMIC LAYER DEPOSITION OF TiN FILMS GROWTH AND ELECTRICAL BEHAVIOR DOWN TO SUBD. Thesis - University of Twente, Enschede, the Netherlands Title: Atomic layer deposition of TiN films

  20. Mechanical properties of nanocrystalline and epitaxial TiN films on (100) silicon

    E-Print Network [OSTI]

    Wei, Qiuming

    Mechanical properties of nanocrystalline and epitaxial TiN films on (100) silicon H. Wang, A 2001) We investigated mechanical properties of TiN as a function of microstructure varying from nanocrystalline to single crystal TiN films deposited on (100) silicon substrates. By varying the substrate

  1. IMPROVE XRF Analysis TI 301A: LN2 Fill/Calibration

    E-Print Network [OSTI]

    Fischer, Emily V.

    IMPROVE XRF Analysis TI 301A: LN2 Fill/Calibration Page 1 of 5 TI 301A: LN2 Fills and Detector ................................................................................ 4 #12;IMPROVE XRF Analysis TI 301A: LN2 Fill/Calibration Page 2 of 5 that has been fully trained in the safety hazards of working with liquid nitrogen. #12;IMPROVE XRF

  2. UNCORRECTEDPROOF 2 Compression behavior of porous NiTi shape memory alloy

    E-Print Network [OSTI]

    Taya, Minoru

    Ti by self-propagating 41high temperature synthesis (SHS), and again the porous 42NiTi fabricated. The compression behavior of the 11 porous NiTi was examined with the aim of using it possibly as a high energy for possible application 30 in medical implant devices and as high energy absorp- 31 tion structural material

  3. A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics

    E-Print Network [OSTI]

    Chi, Ji

    2009-05-15T23:59:59.000Z

    Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

  4. Dopant-Free GaN/AlN/AlGaN Radial Nanowire Heterostructures as High

    E-Print Network [OSTI]

    Li, Yat

    Dopant-Free GaN/AlN/AlGaN Radial Nanowire Heterostructures as High Electron Mobility Transistors, 2006 ABSTRACT We report the rational synthesis of dopant-free GaN/AlN/AlGaN radial nanowire-organic chemical vapor deposition (MOCVD). Transmission electron microscopy (TEM) studies reveal that the GaN/ AlN/AlGaN

  5. Calorimetry study of the synthesis of amorphous Ni-Ti alloys by mechanical alloying. [Ni33 Ti67

    SciTech Connect (OSTI)

    Schwarz, R.B.; Petrich, R.R.

    1988-01-01T23:59:59.000Z

    We synthesized amorphous Ni/sub 33/Ti/sub 67/ alloy powder by ball milling (a) a mixture of elemental nickel and titanium powders and (b) powders of the crystalline intermetallic NiTi/sub 2/. We characterized the reaction products as a function of ball-milling time by differential scanning calorimetry and x-ray diffraction. The measurements suggest that in process (a) the amorphous alloy forms by a solid-state interdiffusion reaction at the clean Ni/Ti interfaces generated by the mechanical attrition. In process (b), the crystalline alloy powder stores energy in the form of chemical disorder and lattice and point defects. The crystal-to-amorphous transformation occurs when the stored energy reaches a critical value. The achievement of the critical stored energy competes with the dynamic recovery of the lattice. 23 refs., 7 figs.

  6. Preparation, characterization and applications of novel carbon and nitrogen codoped TiO{sub 2} nanoparticles from annealing TiN under CO atmosphere

    SciTech Connect (OSTI)

    Sun, Mingxuan; Song, Peng; Li, Jing; Cui, Xiaoli, E-mail: xiaolicui@fudan.edu.cn

    2013-10-15T23:59:59.000Z

    Graphical abstract: Carbon and nitrogen codoped TiO{sub 2} nanoparticles were firstly fabricated by calcining TiN powder under CO atmosphere at different temperatures between 400 and 600 °C, both the improved photocatalytic activity for degradation of methylene blue and enhanced photovoltaic performance for dye sensitized solar cells were demonstrated. - Highlights: • CN-codoped TiO{sub 2} nanoparticles were prepared by calcining TiN under CO atmosphere. • More visible light response was confirmed by UV–vis DRS and photocatalytic results. • Enhanced conversion efficiency was observed for the DSSCs from CN-TiO{sub 2} photoanode. • CN-codoping played an important role to improve the photocatalytic performance. - Abstract: Carbon and nitrogen codoped titania (CN-TiO{sub 2}) nanoparticles were fabricated by calcining titanium nitride (TiN) nanoparticles under carbon monoxide (CO) atmosphere at four different temperatures in a range of 400–600 °C. The as-prepared samples were characterized with X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and X-ray photoelectron spectroscopy (XPS). Enhanced light absorption in both the UV and visible light region was observed for the resulted CN-TiO{sub 2} nanoparticles in ultraviolet-visible diffuse reflectance spectroscopy (UV–vis DRS). Improved photocatalytic activity toward the degradation of methylene blue by the CN-TiO{sub 2} nanoparticles was demonstrated under UV and visible light, respectively. The highest degradation rate was achieved for CN-TiO{sub 2} nanoparticles (13%) compared to N-TiO{sub 2} (10%) and the commercial P25 (5%) under visible light illumination for 40 min. Furthermore, the improved photocatalytic activity of CN-TiO{sub 2} was also confirmed by the degradation of colorless resorcinol under UV–vis light irradiation. Dye-sensitized solar cells (DSSCs) were fabricated using P25, N-TiO{sub 2} and CN-TiO{sub 2} photoanodes, respectively. The highest conversion efficiency of 3.31% was achieved by the DSSCs based on the CN-TiO{sub 2} photoanodes in comparison with the commercial P25 (1.61%) and N-TiO{sub 2} (2.44%) photoanodes. This work demonstrates that thermal treatment of TiN nanoparticles under CO atmosphere has shown to be a rapid, direct and clean approach to synthesize photocatalysts with enhanced photocatalytic and photovoltaic performance.

  7. A Study of Selected Properties and Applications of AlMgB14 and Related Composites: Ultra-Hard Materials

    SciTech Connect (OSTI)

    Theron L. Lewis

    2002-05-28T23:59:59.000Z

    This research presents a study of the hardness, electrical, and thermal properties AlMgB{sub 14} containing Al{sub 2}MgO{sub 4} spinel. This research also investigated how much Al{sub 2}MgO{sub 4} spinel consistently forms with AlMgB{sub 14}, if AlMgB{sub 14} materials can be produced by hot isostatic pressing (HIP), what effects TiC and TiB{sub 2} have on this composite material, and the importance of mechanical alloying. Included also is a study of the variation in hardness measurements and how they relate to SI units. Heretofore, all ultra-hard materials (hardness > 40 GPA) have been found to be cubic in structure, electrical insulators, and expensive; the behavior of AlMgB{sub 14}, which in certain specimens and compositions can have hardness values greater than 40 GPa, is therefore quite unusual since it is non-cubic, conductive, and moderate in cost. This offers an opportunity to investigate the relationship between hardness, thermal, and electrical properties from a new perspective. The main purpose of this project was to characterize the different properties of the AlMgB{sub 14} materials and to demonstrate that this material can be made in bulk. The technologies used for this study include microhardness measurement techniques, scanning electron microscopy, energy dispersive spectroscopy, x-ray diffraction spectroscopy, x-ray diffraction spectroscopy at different temperatures, optical microscopy, thermomechanical analysis, differential thermal analysis, 4-point probe resistivity, density techniques, Seebeck Effect, and Hall Effect. This research may lead to use of this material for applications where high abrasion resistance along with electrical conduction is needed. Also this research gave more information about a material that could have a great impact on industrial applications.

  8. Kinetics of local probe oxidation of ultrathin V, Nb, Ta, Ti, TiN, and W metal films

    SciTech Connect (OSTI)

    Sagunova, I. V., E-mail: pcfme@miee.ru; Shevyakov, V. I.; Gavrilov, S. A.; Belov, A. N. [Moscow Institute of Electronic Technology (Technical University) (Russian Federation)

    2010-12-15T23:59:59.000Z

    The specific features of the kinetics of local probe oxidation of ultrathin V, Nb, Ta, Ti, TiN, and W metal films are studied. It is established that the kinetics of the oxidation process depends on such properties of the material to be oxidized as the resistivity, the presence of a natural surface oxide film and its thickness, the relationship between the densities of the metal and oxide, and the electrochemical constant of the oxidation process. For the material that provides a high efficiency of formation of local insulator nanoregions, vanadium is chosen, since this metal exhibits the maximum rate of anodic probe oxidation.

  9. Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures

    SciTech Connect (OSTI)

    Ngai, J. H.; Kumah, D. P.; Walker, F. J. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Ahn, C. H. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Department of Mechanical Engineering and Materials Science, Yale University, 10 Hillhouse Avenue, New Haven, Connecticut 06520-8267 (United States)

    2014-02-10T23:59:59.000Z

    We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

  10. C t ti N R t Construction News Report

    E-Print Network [OSTI]

    Cunz Hall C t ti N R t Renovation Construction News Report June 2010 Bid Package 301 Site Work! LEED credits will be obtained by creating a more energy efficient building. According to the U.S. Department of Energy, buildings use 39% of the energy and 74% of the electricity produced each year

  11. q www.Governo.it Ti trovi in: Rassegna stampa

    E-Print Network [OSTI]

    De Cindio, Fiorella

    #12;#12;#12;q www.Governo.it Ti trovi in: Rassegna stampa : STAMINALI, IN ARRIBO 12 MILIONI Da "IL. .......... .......................................... C2 www.unimi.it [.] Governo Italiano - Rassegna stampa http://rassegna.governo.it/testo.asp?d=3388912715/12/2008 13.50.59 www.Governo.it Home #12;BUR.it - Bollettino Università & Ricerca Rubriche Bandi

  12. TI 2013-055/III Tinbergen Institute Discussion Paper

    E-Print Network [OSTI]

    Chen, Yiling

    TI 2013-055/III Tinbergen Institute Discussion Paper Parallel Sequential Monte Carlo for Efficient Density Combination: The Deco Matlab Toolbox Roberto Casarin1 Stefano Grassi2 Francesco Ravazzolo3 Herman Mahlerplein 117 1082 MS Amsterdam The Netherlands Tel.: +31(0)20 525 8579 #12;PARALLEL SEQUENTIAL MONTE CARLO

  13. Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation of

    E-Print Network [OSTI]

    Brown, Eric

    Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation that an alizarin red S ~ARS! dye coating on TiO2 nanoparticles enables visible light activation coatings on TiO2 nanoparticles can serve to enhance imaging, by clearly showing that dye coatings on TiO2

  14. Abstract--Titanium nitride (TiN) has been investigated as a material for MEMS hotplate heaters operating at high

    E-Print Network [OSTI]

    Technische Universiteit Delft

    Abstract--Titanium nitride (TiN) has been investigated as a material for MEMS hotplate heaters widely available. A material similar to Ta5Si3 is titanium nitride (TiN). It combines a very high melting TiN Bond pad TiN Figure 1. Schematic cross section of the hotplate. Titanium Nitride for MEMS

  15. A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed on MCM-48

    E-Print Network [OSTI]

    Bell, Alexis

    A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed.932), suggesting the formation of oxygen vacancies. The fraction of Ti that could be reduced increased with TiO2 the TiO2 overlayer as the size of the titania patches increases. The amount of oxygen removed during

  16. Ordered Array of Gold Semishells on TiO2 Spheres: An Ultrasensitive and Recyclable SERS Substrate

    E-Print Network [OSTI]

    Xiong, Qihua

    more semiconductor-noble metal nanocomposites were fabricated, such as TiO2/Ag, ZnO/Ag, ZnO/Au, TiO2/AuOrdered Array of Gold Semishells on TiO2 Spheres: An Ultrasensitive and Recyclable SERS Substrate, 639798, Singapore ABSTRACT: Ordered array of Au semishells on TiO2 spheres with controlled size

  17. al tratamiento local: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and MEG data (Vigario et al., 1998; Tang et al., 2000a; Vigario et al., 1999, 2000; Wubbeler et al Pearlmutter, Barak 39 Independent Components of...

  18. Aging of {alpha}{prime}{sub a} martensite in U-0.77Ti

    SciTech Connect (OSTI)

    Speer, J.G. [Colorado School of Mines, Golden, CO (United States). Dept. of Metallurgical and Materials Engineering] [Colorado School of Mines, Golden, CO (United States). Dept. of Metallurgical and Materials Engineering; Edmonds, D.V. [Univ. of Leeds (United Kingdom). Dept. of Materials] [Univ. of Leeds (United Kingdom). Dept. of Materials

    1999-05-28T23:59:59.000Z

    A detailed examination of the aging response in a quenched U-077 wt% Ti alloy using transmission electron microscopy is presented. The acicular martensite in this alloy is supersaturated with Ti after quenching, and decomposes via coherent precipitation of U{sub 2}Ti which grows as rods parallel to [100]{sub {alpha}}, followed by coarsening via a cellular discontinuous mechanism. The {alpha}/U{sub 2}Ti orientation relationship for both the continuous and discontinuous precipitates may be described as: (001){sub U{sub 2}Ti}{parallel}(100){sub {alpha}}, (01{bar 1}0){sub U{sub 2}Ti}{parallel}(010){sub {alpha}}, (2{ovr 11}0){sub U{sub 2}Ti}{parallel}(001){sub {alpha}}.

  19. Scott Taylor, ALS Safety Manager

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiationImplementingnpitcheResearchPhysics LabwildfiresScott Taylor, ALS Safety

  20. Shape memory behavior of ultrafine grained NiTi and TiNiPd shape memory alloys 

    E-Print Network [OSTI]

    Kockar, Benat

    2009-05-15T23:59:59.000Z

    , (b) SAD pattern taken from the circled area in (a) showing the >compound twinning and )001( }111{ ? Type I twinning, respectively...... 59... martensite, respectively .................................................... 63 SIM ? M y Figure 4.9 Monotonic mechanical response of the hot rolled and ECAE processed Ni 49.7 Ti 50.3 samples under tension at to be thermodynamically same condition...

  1. Fabrication of TiN nanorods by electrospinning and their electrochemical properties

    SciTech Connect (OSTI)

    Sun, Dongfei; Lang, Junwei [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Yan, Xingbin, E-mail: xbyan@licp.cas.c [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Hu, Litian; Xue, Qunji [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

    2011-05-15T23:59:59.000Z

    TiN nanorods were synthesized using electrospinning technique followed by thermolysis in different atmospheres. A dimethyl formamide-ethanol solution of poly-(vinyl pyrrolidone) and Ti (IV)-isopropoxide was used as the electrospinning precursor solution and as-spun nanofibers were calcined at 500 {sup o}C in air to generate TiO{sub 2} nanofibers. Subsequently, a conversion from TiO{sub 2} nanofibers to TiN nanorods was employed by the nitridation treatment at 600{approx}1400 {sup o}C in ammonia atmosphere. A typical characteristic of the final products was that the pristine nanofibers were cut into nanorods. The conversion from TiO{sub 2} to TiN was realized when the nitridation temperature was above 800 {sup o}C. As-prepared nanorods were composed of TiN nano-crystallites and the average crystallite size gradually increased with the increase of the nitridation temperature. Electrochemical properties of TiN nanorods showed strong dependence on the nitridation temperature. The maximum value of the specific capacitance was obtained from the TiN nanorods prepared at 800 {sup o}C. -- Graphical Abstract: TiN nanorods were prepared using electrospinning followed by thermolysis under different atmospheres. Electrochemical properties of the TiN nanorods showed strong dependence on the nitridation temperature. Display Omitted Highlights: {yields} TiN nanorods were synthesized by a combination of electrospinning and thermolysis. {yields} Electrochemical properties showed strong dependence on the nitridation temperature. {yields} The TiN nanorods prepared at 800 {sup o}C possessed the highest specific capacitance.

  2. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries

    SciTech Connect (OSTI)

    Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

    2014-08-19T23:59:59.000Z

    Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12–TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12–TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

  3. ti,iri,,liiii Al 1'... Ji:'.\\ ?tJ11 Vodafone Stiftung frForschung '1' 40543 Dssetdorf

    E-Print Network [OSTI]

    Richner, Heinz

    Universität München ausgezeichnet. Der Förderpreis Natur- und lngenieunivissenschaft ging an Herrn Dr.-lng Technik, Vodafone DZ GmblJ: Pro[ Dr.lng Cerhard Fettweìs (stellv. Vorsitzender), TU Dresden: Andre Hramer, lnnovationspreisträger 201 1 ; Dr -lng Patrick Henkel, Förderpreisträger 201 1 (v. t. n, r

  4. The influence of hydrogen gas exposure and low temperature on the tribological characteristics of ti-6al-4v

    E-Print Network [OSTI]

    Gola, Ryan Travis

    2009-05-15T23:59:59.000Z

    and Group 4 was exposed and tested at low temperature. Average friction coefficients and the specific wear rate were calculated from the test data. Also high-resolution digital microscope imaging was used to observe and characterize the wear mechanisms...

  5. The influence of hydrogen gas exposure and low temperature on the tribological characteristics of ti-6al-4v 

    E-Print Network [OSTI]

    Gola, Ryan Travis

    2009-05-15T23:59:59.000Z

    and Group 4 was exposed and tested at low temperature. Average friction coefficients and the specific wear rate were calculated from the test data. Also high-resolution digital microscope imaging was used to observe and characterize the wear mechanisms...

  6. Nano-second UV laser processed micro-grooves on Ti6Al4V for biomedical applications

    E-Print Network [OSTI]

    Arnold, Craig B.

    .O. Soboyejo b,c, a Center for Energy Research & Development, Obafemi Awolowo University, Nigeria b Princeton

  7. al70ni10ti10zr5ta5 amorphous alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: alloy of composition correspond- ing to the metallic components of the superconduct- ing oxides respectivement. Abstract. - Previous quenching experiments on 2212...

  8. ORIGINAL PAPER Rutile/TiO2II phase equilibria

    E-Print Network [OSTI]

    Zhang, Youxue

    ­10 GPa. The phase diagram proposed by Dachille et al. (1968) was criticized by Jamieson and Olinger (1969

  9. Universidad Simn Bolivar Departamento de Computacin y TI

    E-Print Network [OSTI]

    Cardinale Villarreal, Yudith C.

    Prelaboratorio 2 Debido al cambio de moneda a Bs F en Venezuela, usted contratado para desarrollar un programa de

  10. Structural and chemical characterization of BaTiO{sub 3} nanorods

    SciTech Connect (OSTI)

    Zagar, K.; Recnik, A.; Sturm, S. [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)] [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Gajovic, A. [Molecular Physics Laboratory, Division of Materials Physics, Ruder Boskovic Institute, Bijenicka 54, HR-1002 Zagreb (Croatia)] [Molecular Physics Laboratory, Division of Materials Physics, Ruder Boskovic Institute, Bijenicka 54, HR-1002 Zagreb (Croatia); Ceh, M., E-mail: miran.ceh@ijs.si [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)

    2011-03-15T23:59:59.000Z

    Research highlights: {yields} Polycrystalline BaTiO{sub 3} nanorods were synthesized with EPD into AAO templates. {yields} Nanorods are composed of crystalline, nanosized grains with pseudo-cubic structure. {yields} Integrowth of hexagonal BaTiO{sub 3} polymorph within pseudo-cubic structure was observed. -- Abstract: An electron-microscopy investigation was performed on BaTiO{sub 3} nanorods that were processed by sol-gel electrophoretic deposition (EPD) into anodic aluminium oxide (AAO) membranes. The BaTiO{sub 3} nanorods grown within the template membranes had diameters ranging from 150 to 200 nm, with an average length of 10-50 {mu}m. By using various electron-microscopy techniques we showed that the processed BaTiO{sub 3} nanorods were homogeneous in their chemical composition. The BaTiO{sub 3} nanorods were always polycrystalline and were composed of well-crystallized, defect-free, pseudo-cubic BaTiO{sub 3} grains, ranging from 10 to 30 nm. No intergranular phases were observed between the BaTiO{sub 3} grains. A low-temperature hexagonal polymorph that is coherently intergrown with the BaTiO{sub 3} perovskite matrix was also observed as a minor phase. When annealing the AAO templates containing the BaTiO{sub 3} sol in an oxygen atmosphere the presence of the hexagonal polymorph was diminished.

  11. Application Of Ti-Based Self-Formation Barrier Layers To Cu Dual-Damascene Interconnects

    SciTech Connect (OSTI)

    Ito, Kazuhiro; Kohama, Kazuyuki [Department of Materials Science and Engineering, Kyoto University, Kyoto 606-8501 (Japan); Ohmori, Kazuyuki; Mori, Kenichi; Maekawa, Kazuyoshi; Asai, Koyu [Process Technology Div., Renesas Electronics Corporation, Hitachinaka, Ibaraki 312-8504 (Japan); Murakami, Masanori [The Ritsumeikan Trust, Nakagyo-ku, Kyoto 604-8520 (Japan)

    2010-11-24T23:59:59.000Z

    Cu interconnects have been used extensively in ULSI devices. However, large resistance-capacitance delay and poor device reliability have been critical issues as the device feature size has reduced to nanometer scale. In order to achieve low resistance and high reliability of Cu interconnects, we have applied a thin Ti-based self-formed barrier (SFB) using Cu(Ti) alloy seed to 45nm-node dual damascene interconnects and evaluated its performance. The line resistance and via resistance decreased significantly, compared with those of conventional Ta/TaN barriers. The stress migration performance was also drastically improved using the SFB process. A performance of time dependent dielectric breakdown revealed superior endurance. These results suggest that the Ti-based SFB process is one of the most promising candidates for advanced Cu interconnects. TEM and X-ray photoelectron spectroscopy observations for characterization of the Ti-based SFB structure were also performed. The Ti-based SFB consisted of mainly amorphous Ti oxides. Amorphous or crystalline Ti compounds such as TiC, TiN, and TiSi formed beneath Cu alloy films, and the formation varied with dielectric.

  12. al films deposited: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sputtering. Highly oriented, crack-free, stoichiometric polycrystalline rutile TiO2 thin film; RF magnetron sputtering; Phase transition; Deposition parameter effects 1....

  13. AL2007-03.doc

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy China 2015ofDepartmentDepartment of Energy-ChapterDepartment6-04v2.pdf MoreAL 2007-03

  14. AL2007-05.doc

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy China 2015ofDepartmentDepartment of Energy-ChapterDepartment6-04v2.pdf MoreAL7-05

  15. ALS 20th Anniversary Celebration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG, APIL.AFTFutureALPES20thALS 20th

  16. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship in ResidenceALS Evidence

  17. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship in ResidenceALS

  18. ALS Scientific Advisory Committee Charter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship inALS Reveals NewScientific

  19. ALS Scientific Advisory Committee Charter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship inALS Reveals

  20. ALS Scientific Advisory Committee Charter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship inALS RevealsScientific

  1. AL PRO | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDIT REPORT Americium/Curium Vitrification4th Day EnergyADAPTItalyAL PRO

  2. 2012 ALS User Meeting Awards

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartment ofAugust 2011October 2012 Thu, 10/04/20122 ALS User

  3. 2012 ALS User Meeting Awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartment ofAugust 2011October 2012 Thu, 10/04/20122 ALS

  4. ALS Doctoral Fellowship in Residence

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALS Communications Group

  5. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALS Communications GroupALSALS

  6. Al Geist | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulase C. bescii CelA, adefault Sign InLeaksGreenAl

  7. Shape and strain-induced magnetization reorientation and magnetic anisotropy in thin film Ti/CoCrPt/Ti lines and rings

    E-Print Network [OSTI]

    Velazquez, D.

    The contributions to the magnetic anisotropy of thin-film rings and lines of width 50 nm and above made from Ti(5?nm)/Co[subscript 0.66]Cr[subscript 0.22]Pt[subscript 0.12] (10 and 20 nm)/Ti (3 nm) with a perpendicular ...

  8. The effect of TiCl4-treated TiO2 compact layer on the performance of dye-sensitized solar cell

    E-Print Network [OSTI]

    Park, Byungwoo

    The effect of TiCl4-treated TiO2 compact layer on the performance of dye-sensitized solar cell by a factor of five compared with the bare cell. Ã? 2011 Elsevier B.V. All rights reserved. 1. Introduction Dye-sensitized: Received 11 October 2011 Accepted 25 October 2011 Available online 4 November 2011 Keywords: Dye-sensitized

  9. Growth and Properties of (001)-oriented Pb(Zr?.??Ti?.??)O?/LaNiO? Films on Si(001) Substrates with TiN Buffer Layers

    E-Print Network [OSTI]

    Zhu, Tie-Jun

    Pulsed laser deposition has been used to grow Pb(Zr?.??Ti?.??)O? (PZT)/LaNiO? (LNO) heterostructures with restricted crystallographic orientations on bare Si(001) and SiO?-coated Si(001) substrates, using TiN buffer layers. ...

  10. Combustion synthesis/quasi-isostatic pressing of TiC0.7NiTi cermets: microstructure and transformation characteristics

    E-Print Network [OSTI]

    Meyers, Marc A.

    and objectives Combustion synthesis, also called self-propagating high- temperature synthesis (SHS), is a method, Borovinskaya, Gordopolov, and others [1­3] at the Institute for High-Temperature Synthesis. The subjectCombustion synthesis/quasi-isostatic pressing of TiC0.7­NiTi cermets: microstructure

  11. Pulsed laser deposition of epitaxial BeO thin films on sapphire and SrTiO{sub 3}

    SciTech Connect (OSTI)

    Peltier, Thomas; Takahashi, Ryota; Lippmaa, Mikk, E-mail: mlippmaa@issp.u-tokyo.ac.jp [Institute for Solid State Physics, University of Tokyo, Chiba 277-8581 (Japan)

    2014-06-09T23:59:59.000Z

    Epitaxial beryllia thin films were grown by pulsed laser deposition on Al{sub 2}O{sub 3}(001) and SrTiO{sub 3}(111) substrates. Nearly relaxed epitaxial films were obtained on both substrates at growth temperatures of up to about 600?°C. Crystalline films with expanded lattice parameters were obtained even at room temperature. The maximum growth temperature was limited by a loss of beryllium from the film surface. The volatility of beryllium appeared to be caused by the slow oxidation kinetics at the film surface and the re-sputtering effect of high-energy Be and BeO species in the ablation plume. Time-of-flight plume composition analysis suggested that the target surface became Be metal rich at low oxygen pressures, reducing the growth rate of beryllia films.

  12. Li overlayer formation, oxidation and sputtering characteristics of Al-Li alloys and W/Al-Li composites for fusion applications

    SciTech Connect (OSTI)

    Krauss, A.R. (Argonne National Lab., IL (USA)); DeWald, A.B.; Scott, P.; Savage, H. (Corium Industries, Inc., Atlanta, GA (USA))

    1990-01-01T23:59:59.000Z

    The next generation of long pulse fusion devices will impose severe requirements on the properties of plasma-facing materials. In devices such as ITER, a divertor design is being considered, using a divertor plate which would be either tungsten or a low-Z material such as graphite or beryllium. Strongly segregating lithium alloys have been proposed as a means of producing a self-sustaining low-Z overlayer which lowers plasma Z{sub eff} and resists self-sputtering. Aluminum-lithium alloys are among the better-characterized lithium-bearing alloys, and it has been demonstrated that lithium segregates strongly in aluminum. However, aluminum has a relatively low melting point, and for low lithium concentrations, the lithium diffusion rate is too slow to replenish lithium at the rate at which it is eroded by the incoming plasma. It has been suggested previously that the superionic {beta} phase Al-Li alloy (48--54 at. % Li) should have high enough diffusivity to be able to replenish surface lithium, and that incorporation of the {beta}-phase AlLi in a composite with tungsten would provide high temperature strength and melt layer stability, along with significantly better thermal conductivity than pure tungsten. Such a composite has been fabricated, as well as a variation containing titanium as a means of controlling oxidation at grain boundaries. The Li overlayer formation, erosion, and replenishment are characterized for the {beta}-phase LiAl alloy, and W-AlLi and W-Ti-AlLi composites. It is found that if there is no oxide layer to inhibit the Li segregation, Li diffusion is extremely rapid, and an oxygen-free Li overlayer is formed which is stable under continuous ion beam sputtering. 21 refs., 7 figs.

  13. April 27, 2015-Special ALS Colloquium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 27, 2015-Special ALS Colloquium Print Special Event on Monday, April 27 @ 12 noon, USB 15-253 X-Ray Microscopy: The First 120 Years Janos Kirz, ALS Abstract Rntgen's great...

  14. April 27, 2015-Special ALS Colloquium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 27, 2015-Special ALS Colloquium April 27, 2015-Special ALS Colloquium Print Wednesday, 22 April 2015 13:19 Special Event on Monday, April 27 @ 12 noon, USB 15-253 X-Ray...

  15. United States Patent [19] Church et al.

    E-Print Network [OSTI]

    Church, George M.

    United States Patent [19] Church et al. [54] CHARACTERIZATION OF INDIVIDUAL POLYMER MOLECULES BASED 1111111111111111111111111111111111111111111111111111111111111 US005795782A [11] Patent Number: [45] Date of Patent: 5,795,782 Aug. 18, 1998 Boulanger et al

  16. Current Status of Ti PM: Progress, Opportunities and Challenges

    SciTech Connect (OSTI)

    Peter, William H [ORNL; Chen, Wei [ORNL; Yamamoto, Yukinori [ORNL; Dehoff, Ryan R [ORNL; Muth, Thomas R [ORNL; Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Clark, Michael B [ORNL; Sabau, Adrian S [ORNL; Gorti, Sarma B [ORNL; Blue, Craig A [ORNL; Williams, James C [Ohio State University

    2012-01-01T23:59:59.000Z

    Utilization of titanium components made by powder metallurgy methods has had limited acceptance largely due to the high cost of titanium (Ti) powder. There has been renewed interest in lower cost powder and several Ti reduction methods that produce a particulate product show promise. This talk summarizes work done at Oak Ridge National Laboratory to consolidate these lower cost powders into mill products. Press and sinter consolidation, hot isostatic pressing (HIP) and direct roll consolidation to make sheet have been explored. The characteristics of the consolidated products will be described as a function of the consolidation parameters. Research sponsored by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Industrial Technologies Program, under contract DE-AC05-00OR22725 with UT-Battelle, LLC.

  17. (12) United States Patent Vertes et al.

    E-Print Network [OSTI]

    Vertes, Akos

    (12) United States Patent Vertes et al. (54) NANOPHOTONIC PRODUCTION, MODULATION AND SWITCHING to any disclaimer, the term ofthis patent is extended or adjusted under 35 U.S.c. 154(b) by 194 days. (21) References Cited U.S. PATENT DOCUMENTS 200910236512 Al * 912009 Naya et al. .................... 250/281 2009

  18. United States Patent [19] Miura et al.

    E-Print Network [OSTI]

    Shelnutt, John A.

    of Pyrrole--3,4--diacetic Acid and Its Derivatives", Synthesis, pp. 262--265 (1989). Coderre et al., "Boron/1992 OTHER PUBLICATIONS Japan . Japan . WIPO . WIPO . Miura et al.,, "Synthesis, Tissue Uptake, and Toxicity Therapy for Cancer, Kobe, Japan (Oct. 31--Nov. 4, 1994). Miura et al., "Synthesis and Spectroscopic

  19. Origin of photoactivity of oxygen-deficient TiO{sub 2} under visible light

    SciTech Connect (OSTI)

    Lo, H.-H.; Gopal, Neeruganti O.; Ke, S.-C. [Department of Physics and Nanotechnology Research Center, National Dong Hwa University, Hualien 974-01, Taiwan (China)

    2009-08-24T23:59:59.000Z

    As it is now well established that oxygen vacancies are spontaneously introduced during nitrogen doping of anatase TiO{sub 2}, there is a lively debate on whether nitrogen dopant or oxygen vacancy contributes to the visible light photoactivity of the doped catalyst. We showed that the coordinately unsaturated Ti site is integral to the visible light photoactivity in anatase oxygen-deficient TiO{sub 2} catalyst. Accordingly, oxygen vacancies may contribute to the visible light photoactivities in N-doped TiO{sub 2} and other nonmetallic ion-doped TiO{sub 2} as well. A redox active visible light photocatalyst has been developed based on oxygen-deficient structure in anatase TiO{sub 2}.

  20. Significant electrical control of amorphous oxide thin film transistors by an ultrathin Ti surface polarity modifier

    SciTech Connect (OSTI)

    Cho, Byungsu [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Samsung Display Co. Ltd., Tangjeong, Chungcheongnam-Do 336-741 (Korea, Republic of); Choi, Yonghyuk; Shin, Seokyoon [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Jeon, Heeyoung [Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Seo, Hyungtak, E-mail: hseo@ajou.ac.kr [Department of Materials Science and Engineering and Energy Systems Research, Ajou University, Suwon 443-739 (Korea, Republic of); Jeon, Hyeongtag, E-mail: hjeon@hanyang.ac.kr [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)

    2014-01-27T23:59:59.000Z

    We demonstrate an enhanced electrical stability through a Ti oxide (TiO{sub x}) layer on the amorphous InGaZnO (a-IGZO) back-channel; this layer acts as a surface polarity modifier. Ultrathin Ti deposited on the a-IGZO existed as a TiO{sub x} thin film, resulting in oxygen cross-binding with a-IGZO surface. The electrical properties of a-IGZO thin film transistors (TFTs) with TiO{sub x} depend on the surface polarity change and electronic band structure evolution. This result indicates that TiO{sub x} on the back-channel serves as not only a passivation layer protecting the channel from ambient molecules or process variables but also a control layer of TFT device parameters.

  1. Tribological behavior of NiTi alloy against 52100 steel and WC at elevated temperatures

    SciTech Connect (OSTI)

    Abedini, M. [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ghasemi, H.M., E-mail: hghasemi@ut.ac.ir [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ahmadabadi, M. Nili [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

    2010-07-15T23:59:59.000Z

    The dry tribological behavior of a Ti-50.3 at.% Ni alloy at temperatures of 25 deg. C, 50 deg. C and 200 deg. C was studied. The wear tests were performed on a high temperature pin-on-disk tribometer using 52100 steel and tungsten carbide pins. The worn surfaces of the NiTi alloy were examined by scanning electron microscope. The results showed that in the wear tests involving steel pins, the wear rate of the NiTi decreased as the wear testing temperature was increased. However, for the NiTi/WC contact, a reverse trend was observed. There was also a large decrease in the coefficient of friction for the NiTi/steel contact with increasing wear testing temperature. The formation of compact tribological layers could be the main reason for the reduction of the wear rate and coefficient of friction of the NiTi/steel contact at higher wear testing temperatures.

  2. Thermodynamic and mechanical properties of TiC from ab initio calculation

    SciTech Connect (OSTI)

    Dang, D. Y.; Fan, J. L.; Gong, H. R., E-mail: gonghr@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

    2014-07-21T23:59:59.000Z

    The temperature-dependent thermodynamic and mechanical properties of TiC are systematically investigated by means of a combination of density-functional theory, quasi-harmonic approximation, and thermal electronic excitation. It is found that the quasi-harmonic Debye model should be pertinent to reflect thermodynamic properties of TiC, and the elastic properties of TiC decease almost linearly with the increase of temperature. Calculations also reveal that TiC possesses a pronounced directional pseudogap across the Fermi level, mainly due to the strong hybridization of Ti 3d and C 2p states. Moreover, the strong covalent bonding of TiC would be enhanced (reduced) with the decrease (increase) of temperature, while the change of volume (temperature) should have negligible effect on density of states at the Fermi level. The calculated results agree well with experimental observations in the literature.

  3. Photoemission study of the electronic structure and charge density waves of Na?Ti?Sb?O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, S. Y.; Jiang, J.; Ye, Z. R.; Niu, X. H.; Song, Y.; Zhang, C. L.; Dai, P. C.; Xie, B. P.; Lai, X. C.; Feng, D. L.

    2015-04-30T23:59:59.000Z

    The electronic structure of Na?Ti?Sb?O single crystal is studied by photon energy and polarization dependent angle-resolved photoemission spectroscopy (ARPES). The obtained band structure and Fermi surface agree well with the band structure calculation of Na?Ti?Sb?O in the non-magnetic state, which indicates that there is no magnetic order in Na?Ti?Sb?O and the electronic correlation is weak. Polarization dependent ARPES results suggest the multi-band and multi-orbital nature of Na?Ti?Sb?O. Photon energy dependent ARPES results suggest that the electronic structure of Na?Ti?Sb?O is rather two-dimensional. Moreover, we find a density wave energy gap forms below the transition temperature and reaches 65 meV atmore »7 K, indicating that Na?Ti?Sb?O is likely a weakly correlated CDW material in the strong electron-phonon interaction regime. (author)« less

  4. LaTiO?/KTaO? interfaces: A new two-dimensional electron gas system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01T23:59:59.000Z

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO?, and a band insulator, KTaO?. For LaTiO?/KTaO? interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO?-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO? at room temperature. By using KTaO?, we achieve mobilities in LaTiO?/KTaO? interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO?. By density functional theory, we attribute the higher mobilitymore »in KTaO? 2DEGs to the smaller effective mass for electrons in KTaO?.« less

  5. Characterizing the cracking behavior of hard alpha defects in rotor grade Ti-6-4 alloy

    SciTech Connect (OSTI)

    McKeighan, P.C.; Perocchi, L.C.; Nicholls, A.E.; McClung, R.C.

    1999-07-01T23:59:59.000Z

    A program sponsored by the FAA is currently underway to develop predictive tools utilizing state-of-the-art damage tolerance and probabilistic methodologies that can be used in the life management of high energy rotors. The program is focusing on fatigue crack nucleation and growth from anomalies in titanium alloys known as hard alpha, an inclusion-like feature that can occur during the melting process. In the work detailed in this paper, two sizes of synthetic hard alpha defects are created in Ti-6Al-4V and subjected to static and fatigue loading. In addition, two different geometry anomalies are considered: one intersecting the surface of the specimen and another embedded internally. A number of crack detection transducers are used and shown to compare well to results from visual inspections on the surface defect specimens. These surface specimens tend to exhibit defect cracking at relatively low stress levels, typically on the order of 5--10 ksi. Although it appeared from the crack detection transducer that little or no cracking occurred in the interior anomaly specimens given an applied static stress of 100 ksi, subsequent metallographic sectioning demonstrated more extensive cracking and damage. The observed cracking behavior indicates that the diffusion zone may play an important role in the structural integrity of the hard alpha anomalies.

  6. High temperature superconductor step-edge Josephson junctions using Ti-Ca-Ba-Cu-O

    DOE Patents [OSTI]

    Ginley, D.S.; Hietala, V.M.; Hohenwarter, G.K.G.; Martens, J.S.; Plut, T.A.; Tigges, C.P.; Vawter, G.A.; Zipperian, T.E.

    1994-10-25T23:59:59.000Z

    A process is disclosed for formulating non-hysteretic and hysteretic Josephson junctions using HTS materials which results in junctions having the ability to operate at high temperatures while maintaining high uniformity and quality. The non-hysteretic Josephson junction is formed by step-etching a LaAlO[sub 3] crystal substrate and then depositing a thin film of TlCaBaCuO on the substrate, covering the step, and forming a grain boundary at the step and a subsequent Josephson junction. Once the non-hysteretic junction is formed the next step to form the hysteretic Josephson junction is to add capacitance to the system. In the current embodiment, this is accomplished by adding a thin dielectric layer, LaA1O[sub 3], followed by a cap layer of a normal metal where the cap layer is formed by first depositing a thin layer of titanium (Ti) followed by a layer of gold (Au). The dielectric layer and the normal metal cap are patterned to the desired geometry. 8 figs.

  7. Heterojunction band offsets and dipole formation at BaTiO{sub 3}/SrTiO{sub 3} interfaces

    SciTech Connect (OSTI)

    Balaz, Snjezana [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States)] [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States); Zeng, Zhaoquan [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States)] [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Brillson, Leonard J. [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States) [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Department of Physics, The Ohio State University, 191 West Woodruff, Columbus, Ohio 43210 (United States)

    2013-11-14T23:59:59.000Z

    We used a complement of photoemission and cathodoluminescence techniques to measure formation of the BaTiO{sub 3} (BTO) on SrTiO{sub 3} (STO) heterojunction band offset grown monolayer by monolayer by molecular beam epitaxy. X-ray photoemission spectroscopy (XPS) provided core level and valence band edge energies to monitor the valence band offset in-situ as the first few crystalline BTO monolayers formed on the STO substrate. Ultraviolet photoemission spectroscopy (UPS) measured Fermi level positions within the band gap, work functions, and ionization potentials of the growing BTO film. Depth-resolved cathodoluminescence spectroscopy measured energies and densities of interface states at the buried heterojunction. Kraut-based XPS heterojunction band offsets provided evidence for STO/BTO heterojunction linearity, i.e., commutativity and transitivity. In contrast, UPS and XPS revealed a large dipole associated either with local charge transfer or strain-induced polarization within the BTO epilayer.

  8. Oxygen vacancies in N doped anatese TiO2: Experiment and first principles calculations

    SciTech Connect (OSTI)

    Rumaiz, A.; Woicik, J.C.; Cockayne, E.; Lin, H.Y.; Hassnain, J.; Shah, S.I.

    2009-12-31T23:59:59.000Z

    We have determined the electronic and atomic structure of N doped TiO{sub 2} using a combination of hard x-ray photoelectron spectroscopy and first-principles density functional theory calculations. Our results reveal that N doping of TiO{sub 2} leads to the formation of oxygen vacancies and the combination of both N impurity and oxygen vacancies accounts for the observed visible light catalytic behavior of N doped TiO{sub 2}.

  9. MEMS Hotplates with TiN as a Heater Material J.F. Creemer1

    E-Print Network [OSTI]

    Technische Universiteit Delft

    MEMS Hotplates with TiN as a Heater Material J.F. Creemer1 , W. van der Vlist2 , C.R. de Boer2 , H investigated as a heater material for hotplates and microreactors. TiN is CMOS compatible, and has a higher melting point (2950 ºC) than conventional heaters of Pt and poly-Si. For the first time, TiN is tested

  10. Spin and orbital Ti magnetism at LaMnO3/SrTiO3 interfaces

    SciTech Connect (OSTI)

    Garcial-Barriocanal, J [Universidad Complutense, Spain; Cezar, J. C. [European Synchrotron Radiation Facility (ESRF); Bruno, F. Y. [Universidad Complutense, Spain; Thakur, P. [European Synchrotron Radiation Facility (ESRF); Brookes, N. B. [European Synchrotron Radiation Facility (ESRF); Utfeld, C. [University of Bristol, UK; Riviera-Calzada, A. [Universidad Complutense, Spain; Giblin, S. R. [ISIS Facility, Rutherford Appleton Laboratory; Taylor, J. W. [ISIS Facility, Rutherford Appleton Laboratory; Duffy, J. A. [University of Warwick, UK; Dugdale, S. B. [University of Bristol, UK; Nakamura, T. [Japan Synchrotron Radiation Research Institute, SPring-8; Kodama, K. [Japan Synchrotron Radiation Research Institute, SPring-8; Leon, C. [Universidad Complutense, Spain; Okamoto, Satoshi [ORNL; Santamaria, J. [Universidad Complutense, Spain

    2010-01-01T23:59:59.000Z

    In systems with strong electron-lattice coupling, such as manganites, orbital degeneracy is lifted, what causes a null expectation value of the orbital moment. Magnetic structure is thus determined by spin-spin superexchange. In titanates, however, with much smaller Jahn-Teller distortions, orbital degeneracy might allow non-zero values of the orbital magnetic moment. Accordingly, novel forms of ferromagnetic superexchange interaction unique to t2g electrons systems have been theoretically predicted, although their experimental observation has remained elusive. Here we report a new kind of Ti3+ ferromagnetism at LaMnO3/SrTiO3 epitaxial interfaces. It results from charge transfer to the empty conduction band of the titanate and has spin and orbital contributions evidencing the role played by orbital degeneracy. The possibility of tuning magnetic alignment (ferromagnetic or antiferromagnetic) of Ti and Mn moments by structural parameters is demonstrated. This result will provide important clues for the understanding of the effects of orbital degeneracy in superexchange coupling.

  11. Boron and nitrogen-codoped TiO{sub 2} nanorods: Synthesis, characterization, and photoelectrochemical properties

    SciTech Connect (OSTI)

    Zhou Xiaosong [School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640 (China); School of Chemistry and Technology, Zhanjiang Normal University, Zhanjiang 524048 (China); Peng Feng, E-mail: cefpeng@scut.edu.cn [School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640 (China); Wang Hongjuan; Yu Hao [School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640 (China)

    2011-11-15T23:59:59.000Z

    Boron and nitrogen codoped TiO{sub 2} nanorods (BNTRs) were synthesized via two-step hydrothermal reactions using TiN as a starting material. The as-prepared samples were characterized by X-ray diffraction, field-emission scanning electron microscope (SEM), transmission electron microscopy and X-ray photoelectron spectroscopy techniques. The results showed that TiO{sub 2} nanorods with the diameter of approximately 50-100 nm and the length of several micrometers were doped by the interstitial N and B. The nanorods were firstly formed in the hydrothermal synthesis of nitrogen doped TiO{sub 2}. The growing process of nanorods was observed by SEM and a most probable formation mechanism of the trititanate nanorods was proposed. The BNTRs showed a higher photocatalytic activity and a bigger photocurrent response than N-TiO{sub 2} nanorods under visible light irradiation. - Graphical abstract: Boron and nitrogen codoped TiO{sub 2} nanorods (BNTRs) were synthesized using TiN. The BNTRs showed a higher photocatalytic activity and a bigger photocurrent than N-TiO{sub 2} nanorods (NTRs) under visible light irradiation. Highlights: > Novel B- and N-codoped TiO{sub 2} nanorods (BNTRs) are designed and synthesized. > A most probable formation mechanism of the trititanate nanorods is proposed. > The BNTRs show an outstanding photocurrent response under visible light. > The BNTRs exhibit an improved visible light photocatalytic activity.

  12. Ferroelectric and ferromagnetic properties in BaTiO{sub 3} thin films on Si (100)

    SciTech Connect (OSTI)

    Singamaneni, Srinivasa Rao, E-mail: ssingam@ncsu.edu; Prater, John T. [Materials Science Division, Army Research Office, Research Triangle Park, North Carolina 27709 (United States); Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Punugupati, Sandhyarani; Hunte, Frank; Narayan, Jagdish [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2014-09-07T23:59:59.000Z

    In this paper, we report on the epitaxial integration of room temperature lead-free ferroelectric BaTiO{sub 3} thin (?1050?nm) films on Si (100) substrates by pulsed laser deposition technique through a domain matching epitaxy paradigm. We employed MgO and TiN as buffer layers to create BaTiO{sub 3}/SrRuO{sub 3}/MgO/TiN/Si (100) heterostructures. C-axis oriented and cube-on-cube epitaxial BaTiO{sub 3} is formed on Si (100) as evidenced by the in-plane and out-of-plane x-ray diffraction, and transmission electron microscopy. X-ray photoemission spectroscopic measurements show that Ti is in 4(+) state. Polarization hysteresis measurements together with Raman spectroscopy and temperature-dependent x-ray diffraction confirm the room temperature ferroelectric nature of BaTiO{sub 3}. Furthermore, laser irradiation of BaTiO{sub 3} thin film is found to induce ferromagnetic-like behavior but affects adversely the ferroelectric characteristics. Laser irradiation induced ferromagnetic properties seem to originate from the creation of oxygen vacancies, whereas the pristine BaTiO{sub 3} shows diamagnetic behavior, as expected. This work has opened up the route for the integration of room temperature lead-free ferroelectric functional oxides on a silicon platform.

  13. Grain boundary migration induced segregation in V-Cr-Ti alloys

    SciTech Connect (OSTI)

    Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States); Ohnuki, S.; Takahashi, H. [Univ. of Hokkaido (Japan)

    1996-10-01T23:59:59.000Z

    Analytical electron microscopy results are reported for a series of vanadium alloys irradiated in the HFIR JP23 experiment at 500{degrees}C. Alloys were V-5Cr-5Ti and pure vanadium which are expected to have transmuted to V-15Cr-5Ti and V-10Cr following irradiation. Analytical microscopy confirmed the expected transmutation occurred and showed redistribution of Cr and Ti resulting from grain boundary migration in V-5Cr-5Ti, but in pure V, segregation was reduced and no clear trends as a function of position near a boundary were identified.

  14. ccsd00001116 Nucleation of Al 3 Zr and Al 3 Sc in aluminum alloys

    E-Print Network [OSTI]

    ccsd­00001116 (version 1) : 4 Feb 2004 Nucleation of Al 3 Zr and Al 3 Sc in aluminum alloys: from 4, 2004) Zr and Sc precipitate in aluminum alloys to form the compounds Al3Zr and Al3Sc which

  15. Activated Al/Al{sub 2}O{sub 3} for transformation of chlorinated hydrocarbons

    SciTech Connect (OSTI)

    Lien, H.L.; Zhang, W.X.

    1999-07-01T23:59:59.000Z

    A method for the preparation of activated Al/Al{sub 2}O{sub 3} mixture has been developed in the laboratory. Al and Al{sub 2}O{sub 3} are infused and activated within an alkaline solution. Optimal Al to Al{sub 2}O{sub 3} ratio is in the range of 0.1 to 1. Batch experiments have demonstrated that the activated Al/Al{sub 2}O{sub 3} mixture can rapidly dechlorinate tetrachloroethylene (PCE), carbon tetrachloride (CT) and hexachlorobenzene (HCB). Due to the high reactivity, light density and low cost, the activated Al/Al{sub 2}O{sub 3} may be used as a remediation agent in ex-situ treatment of industrial effluent, in-situ treatment wall, and for direct injection into ground water.

  16. A novel 3D structure composed of strings of hierarchical TiO{sub 2} spheres formed on TiO{sub 2} nanobelts with high photocatalytic properties

    SciTech Connect (OSTI)

    Jiang, Yongjian [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China); Li, Meicheng, E-mail: mcli@ncepu.edu.cn [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China); Suzhou Institute, North China Electric Power University, Suzhou 215123 (China); Song, Dandan; Li, Xiaodan; Yu, Yue [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China)

    2014-03-15T23:59:59.000Z

    A novel hierarchical titanium dioxide (TiO{sub 2}) composite nanostructure with strings of anatase TiO{sub 2} hierarchical micro-spheres and rutile nanobelts framework (TiO{sub 2} HSN) is successfully synthesized via a one-step hydrothermal method. Particularly, the strings of hierarchical spheres are assembled by very thin TiO{sub 2} nanosheets, which are composed of highly crystallized anatase nanocrystals. Meanwhile, the HSN has a large surface area of 191 m{sup 2}/g, which is about 3 times larger than Degussa P25. More importantly, the photocatalytic activity of HSN and P25 were evaluated by the photocatalytic oxidation decomposition of methyl orange (MO) under UV light illumination, and the TiO{sub 2} HSN shows enhanced photocatalytic activity compared with Degussa P25, as result of its continuous hierarchical structures, special conductive channel and large specific surface area. With these features, the hierarchical TiO{sub 2} may have more potential applications in the fields of dye-sensitized solar cells and lithium ion batteries. -- Graphical abstract: Novel TiO{sub 2} with anatase micro-spheres and rutile nanobelts is synthesized. Enhanced photocatalysis is attributed to hierarchical structures (3D spheres), conductive channel (1D nanobelts) and large specific surface area (2D nanosheet). Highlights: • The novel TiO{sub 2} nanostructure (HSN) is fabricated for the first time. • HSN is composed of strings of anatase hierarchical spheres and rutile nanobelt. • HSN presents a larger S{sub BET} of 191 m{sup 2}/g, 3 times larger than the Degussa P25 (59 m{sup 2}/g). • HSN owns three kinds of dimensional TiO{sub 2} (1D, 2D and 3D) simultaneously. • HSN exhibits better photocatalytic performance compared with Degussa P25.

  17. A comparative study of TiN and TiC: Oxidation resistance and retention of xenon at high temperature and under degraded vacuum

    SciTech Connect (OSTI)

    Gavarini, S.; Bes, R.; Millard-Pinard, N.; Peaucelle, C.; Perrat-Mabilon, A.; Gaillard, C. [Universite de Lyon, Universite Claude Bernard Lyon 1, CNRS/IN2P3, UMR5822, IPNL, 69622 Villeurbanne Cedex (France); Cardinal, S.; Garnier, V. [Universite de Lyon, INSA de Lyon, MATEIS, CNRS UMR 5510, 7 Avenue Jean Capelle, 69621 Villeurbanne Cedex (France)

    2011-01-01T23:59:59.000Z

    Dense TiN and TiC samples were prepared by hot pressing using micrometric powders. Xenon species (simulating rare gas fission products) were then implanted into the ceramics. The samples were annealed for 1 h at 1500 deg. C under several degraded vacuums with P{sub O{sub 2}} varying from 10{sup -6} to 2x10{sup -4} mbars. The oxidation resistance of the samples and their retention properties with respect to preimplanted xenon species were analyzed using scanning electron microscopy, grazing incidence x-ray diffraction, Rutherford backscattering spectrometry, and nuclear backscattering spectrometry. Results indicate that TiC is resistant to oxidation and does not release xenon for P{sub O{sub 2{<=}}}6x10{sup -6} mbars. When P{sub O{sub 2}} increases, geometric oxide crystallites appear at the surface depending on the orientation and size of TiC grains. These oxide phases are Ti{sub 2}O{sub 3}, Ti{sub 3}O{sub 5}, and TiO{sub 2}. Apparition of oxide crystallites is associated with the beginning of xenon release. TiC surface is completely covered by the oxide phases at P{sub O{sub 2}}=2x10{sup -4} mbars up to a depth of 3 {mu}m and the xenon is then completely released. For TiN samples, the results show a progressive apparition of oxide crystallites (Ti{sub 3}O{sub 5} mainly) at the surface when P{sub O{sub 2}} increases. The presence of the oxide crystallites is also directly correlated with xenon release, the more oxide crystallites are growing the more xenon is released. TiN surface is completely covered by an oxide layer at P{sub O{sub 2}}=2x10{sup -4} mbars up to 1 {mu}m. A correlation between the initial fine microstructure of TiN and the properties of the growing layer is suggested.

  18. Quantitatively Probing the Al Distribution in Zeolites. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantitatively Probing the Al Distribution in Zeolites. Quantitatively Probing the Al Distribution in Zeolites. Abstract: The degree of substitution of Si4+ by Al3+ in the...

  19. Status of cross-section data for gas production from vanadium and {sup 26}AL from silicon carbide in a D-T fusion reactor.

    SciTech Connect (OSTI)

    Gomes, I. C.

    1998-08-11T23:59:59.000Z

    Current designs of fusion-reactor systems seek to use radiation-resistant, low-activation materials that support long service lifetimes and minimize radioactive-waste problems after decommissioning. Reliable assessment of fusion materials performance requires accurate neutron-reaction cross sections and radioactive-decay constants. The problem areas usually involve cross sections since decay parameters tend to be better known. The present study was motivated by two specific questions: (i) Why are the {sup 51}V(n,np){sup 50}Ti cross section values in the ENDF/B-VI library so large (a gas production issue)? (ii) How well known are the cross sections associated with producing 7.4 x 10{sup 5} y {sup 26}Al in silicon carbide by the process {sup 28}Si(n,np+d){sup 27} Al(n,2n){sup 26}Al (a long-lived radioactivity issue)? The energy range 14-15 MeV of the D-T fusion neutrons is emphasized. Cross-section error bars are needed so that uncertainties in the gas and radioactivity generated over the lifetime of a reactor can be estimated. We address this issue by comparing values obtained from prominent evaluated cross-section libraries. Small differences between independent evaluations indicate that a physical quantity is well known while the opposite signals a problem. Hydrogen from {sup 51}V(n,p){sup 51}Ti and helium from {sup 51}V(n,{alpha}){sup 48}Sc are also important sources of gas in vanadium, so they too were examined. We conclude that {sup 51}V(n,p){sup 51}Ti is adequately known but {sup 51}V(n,np+d){sup 50}Ti is not. The status for helium generation data is quite good. Due to recent experimental work, {sup 27}Al(n,2n){sup 26}Al seems to be fairly well known. However, the situation for {sup 28}Si(n,np+d){sup 27}Al remains unsatisfactory.

  20. Efficiency of clay-TiO2 nanocomposites on the photocatalytic elimination of a model hydrophobic air pollutant

    E-Print Network [OSTI]

    Kibanova, Daria

    2010-01-01T23:59:59.000Z

    Paris - Chemistry 2000, 3, 405-411. Clay-TiO 2 nanocompositenanocomposites Appl. Clay Sci. 2006, (28) Ooka, C. ;of TiO 2 -pillared clay on adsorption and photocatalysis of