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1

Performance test of Ti/Au bilayer TES microcalorimeter in combination with continuous ADR  

SciTech Connect

Performance test of a Ti/Au bilayer TES microcalorimeter has been made in combination with a continuous adiabatic demagnetization refrigerator (CADR). The CADR has four stages of ADR to produce continuous cooling by recycling them in dedicated order, and is cryogen-free utilizing a 4K-GM refrigerator. We installed a Ti/Au bilayer TES microcalorimeter and 420-series SQUID array to readout the X-ray signal on the 1st (coldest) stage of the CADR. We successfully operated the CADR at temperature of 120 mK in continuous mode more than 27 hr, however, FWHM energy resolution of the TES microcalorimeter was degraded to 45 eV at 6 keV, as compared to 10 eV when measured in a dilution refrigerator. This is mainly because the temperature stability was not good enough (about 0.6 mK) and the operation temperature was not sufficiently lower than the transition temperature T{sub c} = 135mK of the TES. We operated the TES microcalorimeter at the operation temperature of 105 mK in one-shot mode and the resolution was improved to 30 eV. We also found that the operating point of the TES was affected by the magnetic field of the 3rd and 4th ADR recycle. More complete shielding of the magnetic field is essential for further improvement of the performance of the TES microcalorimeter.

Ishisaki, Y.; Akamatsu, H.; Hoshino, A. [Department of Physics, Tokyo Metropolitan University 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397 (Japan); Numazawa, T.; Kamiya, K. [Tsukuba Magnet Laboratory, NIMS, 3-13 Sakura, Tsukuba 305-0003 (Japan); Fujimoto, R.; Kojima, Y. [Faculty of Mathematics and Physics, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192 (Japan); Shinozaki, K. [Aerospace Research and Development Directorate, JAXA, 1-1 Sengen, Tsukuba, Ibaraki 305-8505 (Japan); Institute of Space and Astronautical Science, JAXA, 3-1-1 Yoshinodai, Sagamihara, Kanagawa 229-8510 (Japan); Mitsuda, K. [Institute of Space and Astronautical Science, JAXA, 3-1-1 Yoshinodai, Sagamihara, Kanagawa 229-8510 (Japan); Shirron, P. [NASA/Goddard Space Flight Center (GSFC), Greenbelt, MD 20771 (United States)

2009-12-16T23:59:59.000Z

2

Asymmetry of radiation damage properties in Al-Ti nanolayers...  

NLE Websites -- All DOE Office Websites (Extended Search)

reveal significant and important asymmetries in defect production with sim60% of vacancies created in Al layers compared to Ti layers within the Al-Ti multilayer system. The...

3

Structure and ductility of TiAl  

SciTech Connect

The effect of structural factors (grain size and grain boundary structure) and strain rate on the deformation mechanism and ductility of TiAl in the temperature range of brittle-to-ductile transition and at room temperature was systematically investigated. It has been established that it is possible to substantially affect the deformation mechanism and ductility of this intermetallic by controlling structural factors, particularly the grain size, and varying the strain rate.

Imayev, R.; Salishchev, G.; Imayev, V.; Shagiev, M.; Kuznetzov, A. [Inst. for Metals Superplasticity Problems, Ufa (Russian Federation)

1995-12-31T23:59:59.000Z

4

Nanolayered CrAlTiN and multilayered CrAlTiN–AlTiN coatings for solid particle erosion protection  

Science Journals Connector (OSTI)

Abstract Applying hard coatings on airfoil surfaces is proven to be an effective approach to mitigating erosion damage to engine components. Nanolayered or multilayered coatings, because of their capability of tailoring hardness and toughness through modifications in the chemistry and architecture of layer constituents, have been explored as potential candidates for this specific application. In this study, nanolayered CrAlTiN (CrN/AlTiN) coatings with different modulation periods, along with multilayered CrAlTiN–AlTiN coatings having different number of layers and different thickness of individual layers, were fabricated, characterized and evaluated. All the coatings significantly outperformed the CrN baseline in erosion resistance, and their performance was strongly affected by the bilayer period of the nanolayered coatings or the layer architectural characteristics of multilayered coatings.

Q. Yang; R. McKellar

2015-01-01T23:59:59.000Z

5

Site preferences of indium impurity atoms in intermetallics having Al3Ti and Al3Zr crystal structures  

E-Print Network (OSTI)

Site preferences of indium impurity atoms in intermetallics having Al3Ti and Al3Zr crystal-04843 (Metals Program) and Praveen Sinha Fund for Physics Research. L12 DO22 DO23 Cu3Au Al3Ti Al3Zr #12;Outline · Indium was doped in samples of Al3V and Al3Ti (Al3Ti structure) and Al3Zr (Al3Zr structure) by arc

Collins, Gary S.

6

TI--CR--AL--O thin film resistors  

DOE Patents (OSTI)

Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

2000-01-01T23:59:59.000Z

7

Dynamic recrystallization and superplasticity in TiAl  

SciTech Connect

The effect of structural factors (grain size, grain boundary structure and fraction of the second phase) on dynamic recrystallization and superplasticity in the TiAl intermetallic alloy was studied. The possibilities of the formation of submicrocrystalline structure and the abrupt decrease of the superplastic temperature were shown. It was established that the occurrence of dynamic recrystallization and superplastic flow led to the formation of homogeneous microstructure and the improvement of low-temperature ductility in TiAl.

Salishchev, G.; Imayev, R.; Imayev, V.; Shagiev, M. [Inst. for Metals Superplasticity Problems, Ufa (Russian Federation)

1995-12-31T23:59:59.000Z

8

Carbide precipitation in gamma-TiAl alloys  

SciTech Connect

Carbide precipitation in gamma-TiAl is observed and found to involve the formation of coherent, rod-shaped perovskite precipitates as a metastable transition phase. At temperatures above 750 deg C, the formation of plate-shaped H-phase particles on dislocations and grain boundaries is accompanied by dissolution of the perovskite precipitate dispersions. This temperature regime includes possible service temperatures for gamma-TiAl-based alloys. 10 refs.

Chen, S.; Beaven, P.A.; Wagner, R. (GKSS-Forschungszentrum Geesthacht GmbH, (Germany))

1992-04-01T23:59:59.000Z

9

Laser Cladding of TiAl Intermetallic Alloy on Ti6Al4V -Process Optimization and Properties  

Science Journals Connector (OSTI)

Abstract In order to improve Ti6Al4V high-temperature resistance and its tribological properties, the deposition of TiAl intermetallic (Ti-48Al-2Cr-2Nb) coating on a Ti6Al4V substrate by coaxial laser cladding has been investigated. Laser cladding by powder injection is an emerging laser material processing technique that allows the deposition of thick protective coatings on substrates,using a high power laser beam as heat source. Laser cladding is a multiple-parameter-dependent process. The main process parameters involved (laser power, powder feeding rate, scanning speed and preheating temperature) has been optimized. The microstructure and geometrical quantities (clad area and dilution) of the coating was characterized by optical microscopy and scanning electron microscopy (SEM). In addition the cooling rate of the clad during the process was measured by a dual-color pyrometer. This result has been related to defectology and mechanical coating properties.

B. Cárcel; A. Serrano; J. Zambrano; V. Amigó; A.C. Cárcel

2014-01-01T23:59:59.000Z

10

Compton Profile Study of Intermetallic Ti{sub 3}Al  

SciTech Connect

The Compton scattering measurement on intermetallic alloy Ti{sub 3}Al is reported in this work. The measurement is made using 59.54 keV gamma-rays from Am{sup 241} source. Theoretical calculation of Compton profile is also performed employing CRYSTAL code within the framework of density functional theory to compare with the measurement. The theoretical profile of the alloy is also synthesized following the superposition model taking the published Compton profiles of elemental solids from the APW method. The experimental study of charge transfer in the alloys has also been done by performing the experimental Compton profile measurements on Ti and Al following the superposition model and charge transfer from Al to Ti is clearly seen on the alloy formation.

Vyas, V.; Sharma, G. [Department of Physics, Banasthali University, Banasthali-304022 (India); Mishra, M. C.; Sharma, B. K. [Department of Physics, University of Rajasthan, Jaipur-302004 (India); Joshi, K. B. [Department of Physics, University College of Science, M.L.Sukhadia University, Udaipur-313 002 (India)

2011-10-20T23:59:59.000Z

11

Investigation of the reaction zone between TiAl and Mo  

SciTech Connect

Pure Mo was incorporated in TiAl matrix via two different routes: (1) hot pressing of alternately sandwiched Ti-Al sheets and Mo foils; and (2) coextrusion and heat treatment of Ti-Al green compact and Mo rod. The reaction zone between TiAl and Mo is found to contain two intermetallic phases: {beta}-(Mo,Ti)Al and {rho}-(Mo,Ti){sub 3}Al. The {beta}-{rho} boundary is incoherent, whereas the TiAl-{beta} and {rho}-Mo boundaries are semicoherent. The reaction zone grows with increasing heat-treatment time in a parabolic form. The incorporated Mo exhibits lower hardness than the TiAl matrix, implying that ductilizing and toughening of TiAl by introducing Mo as a ductile reinforcement are possible.

Hsu, F.Y.; Klaar, H.J. [Aachen Univ. of Technology (Germany); Wang, G.X. [Zhejiang Univ., Hangzhou (China). Dept. of Materials Science and Engineering; Pirwitz, F. [GKSS Research Center, Geesthacht (Germany). Inst. for Materials Research

1996-08-01T23:59:59.000Z

12

Textures and plastic anisotropy in gamma-TiAl  

SciTech Connect

Specimens of a Ti-36 wt pct Al alloy consisting primarily of gamma TiAl were deformed in compression at 450 C and in rolling at 1050 C. The textures of the deformed specimens were measured and analyzed in terms of orientation distribution functions. After hot rolling, the texture is strongly influenced by recrystallization and shows a cube-like component with an alignment of the c-axis with the transverse direction. The measured compression textures are compared with those simulated on the basis of the Taylor theory of polycrystal deformation. 36 refs.

Hartig, C.H.; Fang, X.F.; Mecking, H.; Dahms, M. (Hamburg, Technische Universitaet, (Germany) GKSS-Forschungszentrum Geesthacht GmbH, (Germany))

1992-08-01T23:59:59.000Z

13

Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials  

E-Print Network (OSTI)

Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials Abdullah Al storage processes. Here we analyze the role of atomic Ti catalysts in the hydrogenation of Al-based hydrogen storage materials. We show that Ti atoms near the Al surface activate gas-phase H2, a key step

Ciobanu, Cristian

14

Topotaxial growth of Ti{sub 2}AlN by solid state reaction in AlN/Ti(0001) multilayer thin films  

SciTech Connect

The formation of Ti{sub 2}AlN by solid state reaction between layers of wurtzite-AlN and {alpha}-Ti was characterized by in situ x-ray scattering. The sequential deposition of these layers by dual magnetron sputtering onto Al{sub 2}O{sub 3}(0001) at 200 deg. C yielded smooth, heteroepitaxial (0001) oriented films, with abrupt AlN/Ti interfaces as shown by x-ray reflectivity and Rutherford backscattering spectroscopy. Annealing at 400 deg. C led to AlN decomposition and diffusion of released Al and N into the Ti layers, with formation of Ti{sub 3}AlN. Further annealing at 500 deg. C resulted in a phase transformation into Ti{sub 2}AlN(0001) after only 5 min.

Hoeglund, C.; Beckers, M.; Schell, N.; Borany, J. v.; Birch, J.; Hultman, L. [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linkoeping University, S-581 83 Linkoeping (Sweden); GKSS Research Center Geesthacht, Max-Planck-Str. 1, D-21502 Geesthacht (Germany); Institute of Ion Beam Physics and Materials Research, Forschungszentrum Dresden-Rossendorf, P.O. Box 510119, D-01314 Dresden (Germany); Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linkoeping University, S-581 83 Linkoeping (Sweden)

2007-04-23T23:59:59.000Z

15

Thermal stability and oxidation resistance of TiCrAlYO coatings...  

NLE Websites -- All DOE Office Websites (Extended Search)

stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications. Thermal stability and oxidation resistance of TiCrAlYO...

16

Superplastic foaming of titanium and Ti-6Al-4V  

SciTech Connect

Solid-state foaming of metals can be achieved by hot-isostatic pressing of powders in presence of argon followed by expansion of the resulting high-pressure argon bubbles at ambient pressure and elevated temperature. This foaming technique was first demonstrated by Kearns et al. for Ti-6Al-4V, but is limited by its low creep rate and ductility, which lead to early cell wall fracture. The authors address these issues by performing the foaming step under superplastic conditions. Rather than using microstructural superplasticity (requiring fine grains which are difficult to achieve in porous powder-metallurgy materials), they used transformation superplasticity, which occurs at all grain sizes by biasing with a deviatoric stress (from the pore pressure) of internal stresses (from the allotropic mismatch during thermal cycling about the allotropic temperature range). As compared to control experiments performed under isothermal creep conditions, superplastic foaming under temperature cycling of unalloyed titanium and alloyed Ti-6Al-4V led to a significantly higher pore volume fraction and higher foaming rate.

Dunand, D.C. [Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering; Teisen, J. [Swiss Federal Inst. of Tech., Zuerich (Switzerland). Dept. of Materials

1998-12-31T23:59:59.000Z

17

On elongated stacking fault loops in TiAl  

SciTech Connect

Depending upon strain, load orientation, alloy composition and test temperature, the deformation microstructure of TiAl contains a varied density of stacking faults ribbons. The presence of these ribbons is correlated with that of superdislocations with 1/2{l_angle}112[square bracket] Burgers vector. They are elongated along any of the {l_angle}011[square bracket] directions. The present paper focuses on their formation mechanism, especially on the reasons which make that such dipolar defects, though intrinsically unstable, tend to exhibit a reasonably constant width.

Hug, G.; Veyssiere, P. [CNRS-ONERA, Chatillon (France)

1995-12-31T23:59:59.000Z

18

Low thermal expansion behavior and thermal durability of ZrTiO4Al2TiO5Fe2O3 ceramics between 750 and 1400  

E-Print Network (OSTI)

2002 Abstract The thermal-shock-resistant materials in the system Al2TiO5­ZrTiO4 (ZAT) were synthesized Aluminum titanate (Al2TiO5) is well-known as an excellent thermal shock-resistant material, resulting from. All rights reserved. Keywords: Al2TiO5; Thermal expansion; Thermal shock resistance 1. Introduction

Cao, Guozhong

19

Influence of Si content on microstructure of TiAl alloys  

SciTech Connect

A systematic study of four ternary TiAl-based alloys with constant Ti content of 52.2 at. % and variable Si content ranging from 0.3 to 2.7 at. % (Al in balance) was conducted. The alloys were prepared from elemental powders via a route including powder mixing, precompaction, cold extrusion, and reactive hot-isostatic pressing. All investigated alloys contain the intermetallic compounds {gamma}-TiAl, {alpha}{sub 2}-Ti{sub 3}Al, and {zeta}-Ti{sub 5}(Si,Al){sub 3}. The microstructure can be described as a duplex structure (i.e., lamella {gamma}/{alpha}{sub 2} regions distributed in a {gamma} matrix) containing {zeta} precipitates. With increasing Si content, the number of primary {zeta} precipitates increased and the {gamma} grain size became finer while the lamellar volume fraction decreased slightly.

Hsu, F.Y.; Klaar, H.J. [Aachen Univ. of Technology (Germany). Central Lab. of Electron Microscopy] [Aachen Univ. of Technology (Germany). Central Lab. of Electron Microscopy; Wang, G.X. [Zhejiang Univ., Hangzhou (China)] [Zhejiang Univ., Hangzhou (China); Dahms, M. [GKSS Research Center, Geesthacht (Germany)] [GKSS Research Center, Geesthacht (Germany)

1996-04-01T23:59:59.000Z

20

Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy study  

E-Print Network (OSTI)

Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy, Texas 77843-3255 Received 14 October 1997; accepted 6 April 1998 Al clusters supported on TiO2(110) have been investigated using scanning tunneling microscopy. Al interacts strongly with the TiO2(110) surface

Goodman, Wayne

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

On the Liquid/Solid Phase Equilibria in the Al-Rich Corner of the Al-Si-Ti Ternary System  

E-Print Network (OSTI)

On the Liquid/Solid Phase Equilibria in the Al-Rich Corner of the Al-Si-Ti Ternary System O; published online February 5, 2014) The nature of liquid-solid phase equilibria in the Al-rich corner of the Al-Si-Ti system are determined by drawing three isothermal sections at 620, 680 and 727 °C

Paris-Sud XI, Université de

22

Flat panel display using Ti-Cr-Al-O thin film  

DOE Patents (OSTI)

Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solan Beach, CA)

2002-01-01T23:59:59.000Z

23

Atomistic simulation of dislocation core structures in ordered TiAl  

SciTech Connect

Interatomic potentials of the Embedded Atom type were used in the simulation of the dislocation core structures in TiAl. Different orientations of the dislocation line were simulated for the most commonly observed TiAl slip systems. Low-temperature dislocation behavior is interpreted in terms of ordinary dislocation motion. The effect of applied stress on the shape of the dislocation core and its mobility is examined as well. For the superdislocations several possible types of dissociations were studied.

Panova, J.; Farkas, D. [Virginia Polytechnic Inst., Blacksburg, VA (United States). Dept. of Materials Science and Engineering

1995-12-31T23:59:59.000Z

24

Preparation and properties of Al-PILC supported SO42?/TiO2 superacid catalyst  

Science Journals Connector (OSTI)

SO42?/TiO2/Al-pillared clay (ST/Al-PILC) superacid catalyst was prepared by loading active component SO42?/TiO2 on Al-pillared clay. The texture structure properties of the catalyst were studied by means of X-ray powder diffraction and the adsorption of N2. Acidity properties of the catalyst were tested by Hammett indicator method and FT-IR spectra of absorbed pyridine technique. The characterization results indicated that Al-PILC carrier could inhibit the formation of anatase TiO2 and the transformation of anatase TiO2 into rutile TiO2. ST/Al-PILC catalyst possesses both Lewis and Brönsted acid sites, and the number of acid sites on ST/Al-PILC is much larger than that on Al-PILC carrier, but its acid strength is lower than that of ST. Experimental results show that ST/Al-PILC is an effective catalyst for esterification of n-pentanol with benzoic acid.

Yue-Xiu Jiang; Xiao-Mei Chen; Yun-Fen Mo; Zhang-Fa Tong

2004-01-01T23:59:59.000Z

25

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides  

E-Print Network (OSTI)

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage the dissociative chemisorption of hydrogen in Ti-doped alanate storage materials. © 2007 American Institute

Ciobanu, Cristian

26

Investigation of the {gamma}-Ti(Cr,Al)2 phase at 800 C and 1000 C  

SciTech Connect

A section of the Ti-Al-Cr ternary system, centered around the {gamma}-TiCr{sub 2} phase was examined using five quenched bulk alloy samples and three diffusion couples. Due to the sluggishness of diffusion both at 800 and 1,000 C in the TiCr{sub 2} phase fields, the heat treatment produced a state of near-equilibrium in the samples rather than complete equilibrium, as desired. However, as previous studies have made use of similar, or shorter, processing schedules, the results of the present study should be considered as valid as the earlier works. As a confirmation of the phase composition obtained from the near-equilibrium bulk alloys, the results of a diffusion couple analysis, yielded similar compositions. It is clear, based on the above results that the {gamma}-TiCr{sub 2}, with a C14 crystal structure, does indeed extend into the Ti-Al-Cr ternary system as indicated by Suprunenko et al. The {gamma}-TiCr{sub 2} phase advances into the ternary as the b solid solution pulls away from the Ti-Cr binary system with decreasing temperature. Solubility into the ternary system is made possible by Al atoms substituting onto Cr sites, as is observed for the Al-Cr-Nb ternary system. Although the solubility of the {gamma}-TiCr{sub 2} phase extends from about 3--19at% Al at 1,000 C and from 6--24at% Al at 800 C, the exact limits of solubility are yet to be determined.

Jewett, T.J.; Dahms, M. [GKSS Research Centre, Geesthacht (Germany)] [GKSS Research Centre, Geesthacht (Germany)

1995-05-15T23:59:59.000Z

27

Simply AlF3-treated Li4Ti5O12 composite anode materials for stable...  

NLE Websites -- All DOE Office Websites (Extended Search)

Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh...

28

Microstructure and fracture toughness aspects of diffusion bonded interface between Ti and Al  

SciTech Connect

This study was undertaken to identify the microstructural characteristics of the intermetallic phases formed at the interface during the bonding process and determine the mechanical properties of Ti-Al dissimilar diffusion bonded joints, namely strength and fracture toughness. Furthermore, the effect of the intermetallic phases on the strength and fracture toughness of the joint was also determined. The effect of strength mis-match between Ti and Al on the fracture process will also be discussed. This investigation is the first phase of a larger project on the characterization of the intermetallics formed and their influence on strength and fracture toughness of the joints between TiAl-TiAl. A series of diffusion bonds of 25mm {times} 25 mm thick Ti bars were produced using aluminum foils of different thicknesses as interlayer. The bonded joints were tested to determine the fracture toughness properties of the interface formed and the effect of intermetallic phase formation on the fracture toughness was evaluated. Four-point bend specimens containing a crack introduced into the interface during the bonding process were tested to determine the diffusion-bonded interface fracture toughness. Tensile tests of the joints were also conducted to determine their strengths. The bonding conditions required to obtain a sound joint between Ti and Al were also evaluated.

Cam, G.; Dobi, D.; Kocak, M. [GKSS Research Center, Geesthacht (Germany); Heikinheimo, L.; Siren, M. [VTT Manufacturing Technology, Espoo (Finland)

1996-12-31T23:59:59.000Z

29

Al–Ge–Ti: Phase equilibria and structural characterization of new ternary compounds  

Science Journals Connector (OSTI)

Abstract Phase equilibria of Al–Ge–Ti have been investigated using scanning electron microscopy (SEM), powder X-ray diffraction (XRD) and differential thermal analysis (DTA). Partial isothermal sections at 400 °C, 520 °C and 1000 °C were obtained with focus on the titanium-poor part up to 50 at.% titanium. Three ternary compounds were found to exist. The compound Al3GeTi (?1) crystallizes in an own structure type (P4/nmm, tP10). Two structurally closely related compounds were found at the composition Al1?xGe1+xTi: ?2 (0.61 ? x ? 0.73), Al4Si5Zr3-type, I41/amd, tI24 and ? 2 ? (0.36 ? x ? 0.57), Si2Zr-type, Cmcm, oC12. DTA data were used to construct a ternary reaction scheme (Scheil diagram) up to approximately 1300 °C, a partial liquidus projection and two vertical sections, at 10 at.% Ti and at a constant Al:Ti ratio of 1:1. A total number of 12 ternary invariant reactions were identified.

Roland W. Bittner; Matthias Gürth; Liliana I. Duarte; Christian Leinenbach; Herta S. Effenberger; Klaus W. Richter

2014-01-01T23:59:59.000Z

30

Effect of Reactive Sputtering Parameters on TiAlN Nanocoating Structure and Morphology  

SciTech Connect

The effect of substrate bias and nitrogen flow rate on the TiAlN nanocoating structure and morphology has been investigated by using reactive unbalance DC magnetron sputtering. TiAlN nanocoating was deposited on the tungsten carbide insert tool and the structure and morphology were characterized by using XRD and AFM, respectively. The substrate bias was varied between 0 to -221 V and the nitrogen flow rate was varied between 30 to 72 sccm. The results showed that the structure of TiAlN nanocoating consisted of mainly (111) and (200) plane. The structure was significatly influenced by substrate bias in promoting finer crystal size and increased crystal plane spacing while the rms roughness of nanocoating was influenced by substrate bias and nitrogen flow rate.

Budi, Esmar [Jurusan Fisika FMIPA Universitas Negeri Jakarta Jl. Pemuda No. 10 Rawamangun Jakarta 13220 (Indonesia); Razali, M. Mohd.; Nizam, A. R. Md. [Faculty of Manufacturing Engineering Universiti Teknikal Malaysia Melaka (UTeM) Karung Berkunci No 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

2010-10-24T23:59:59.000Z

31

Preparation of Al2O3/TiO2-containing Coating on Aluminium Alloys by Micro-arc Oxidation  

Science Journals Connector (OSTI)

TiO2-containing ceramic coatings were deposited on the surface of aluminium alloys by micro-arc oxidition. Surface and cross-section topograph of ceramic coating were observed using scanning electron microscopy (SEM). The phase composition of ceramic ... Keywords: Micro-arc oxidation, TiO2 additive, Al2O3/TiO2 phase, antiwear behavior

Cheng Gao; Jinyong Xu; Yusheng Lan; Yonghui Ma; Weixiang Su; Yajuan Liu

2010-03-01T23:59:59.000Z

32

Lattice variations of Ti-6Al-4V alloy with hydrogen content  

SciTech Connect

Effect of hydrogen content on the lattice parameter of Ti-6Al-4V alloy has been investigated by X-ray diffraction. The experimental results show that the solution of hydrogen in the Ti-6Al-4V alloy affects significantly on the lattice parameters of {alpha}, {beta} and {delta} phases, especially the {beta} phase. Furthermore, the critical hydrogen content of {delta} hydride formation for Ti-6Al-4V alloy is 0.385 wt.%. When the hydrogen content is lower than the critical hydrogen content, the {delta} hydride cannot precipitate and the lattice parameter ({alpha}) of {beta} phase linearly increases with the increasing of hydrogen content. When the hydrogen content is higher than the critical hydrogen content, the {delta} hydride precipitates and the lattice parameter ({alpha}) of {beta} phase varies inconspicuously with hydrogen content. In addition, the effects of lattice variations and {delta} hydride formation on microstructure are discussed. The {alpha}/{beta} interfaces of lamellar transformed {beta} phase become fuzzy with the increasing of hydrogen content because of the lattice expansion of {beta} phase. Compared with that of the Ti-6Al-4V alloy at low hydrogen content ({<=} 0.385 wt.%), the contrasts of primary {alpha} phase and transformed {beta} phase of Ti-6Al-4V alloy at high hydrogen content ({>=} 0.385 wt.%) were completely reversed due to the formation of {delta} hydride. - Research Highlights: {yields} A novel method for determining {delta} hydride in Ti-6Al-4V alloy is presented. {yields} The critical hydrogen content of {delta} hydride formation is 0.385 wt.%. {yields} The lattice parameter of {beta} phase can be expressed as follows: a=0.323(1+9.9x10{sup -2}C{sub H}) . {yields} Precipitation of {delta} hydride has a significant influence on the microstructure. {yields} The {alpha}/{beta} interfaces of transformed {beta} phase became fuzzy in the hydrogenated alloy.

Zhu Tangkui, E-mail: zhutangkui@sohu.com; Li, Miaoquan, E-mail: honeymli@nwpu.edu.cn

2011-07-15T23:59:59.000Z

33

Photodissociation measurements of bond dissociation energies: D0(Al2-Al), D0(TiO -Mn), and D0(V2 -V)  

E-Print Network (OSTI)

Photodissociation measurements of bond dissociation energies: D0(Al2-Al), D0(TiO -Mn), and D0(V2 -VV was obtained by adding the energy of the 4 A2 state to the measured predissociation threshold. For Ti studies may be used to measure bond lengths and deduce term symbols. As one proceeds to higher energies

Morse, Michael D.

34

Microstructure and tensile properties of spray formed gamma Ti48.9at.%Al  

SciTech Connect

Until now only a limited number of spray forming experiments on TiAl were reported, and the mechanical data of sprayed material of these alloys are rather rare. In this paper, the application of the EIGA-technique (Electrode Induction Melting Gas Atomization) for spray forming of binary Ti48.9Al(at.%) is reported. Sprayed deposits, obtained under near optimum conditions are tensile tested at room temperature and microstructurally characterized. The results are compared to similar alloys obtained by other process routes.

Liu, K.W. [GKSS Forschungszentrum, Geesthacht (Germany)] [GKSS Forschungszentrum, Geesthacht (Germany); [Univ. of Science and Technology, Beijing (China). State Kay Lab for Advanced Metals and Materials; Gerling, R.; Schimansky, F.P. [GKSS Forschungszentrum, Geesthacht (Germany)] [GKSS Forschungszentrum, Geesthacht (Germany)

1999-02-05T23:59:59.000Z

35

Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of Ti for Effect of Ti for Hydrogen Cycling in NaAlH 4 Mei-Yin Chou School of Physics Georgia Institute of Technology (DE-FG02-05ER46229) Acknowledgment: Yan Wang, Roland Stumpf Why is NaAlH 4 interesting? A viable candidate for hydrogen-storage material: High theoretical weight-percent hydrogen content of 5.55% and low cost But (before 1997) Dehydrogenation occurs at high temperature; rehydrogenation is difficult. Bogdanovic and Schwickardi, 1997 Hydrogen can be reversibly absorbed and desorbed from NaAlH 4 under moderate conditions by the addition of catalysts (compounds containing Ti, Zr, etc.) High Hydrogen Contents in Complex Hydrides Hydride wt% Hydride wt% Be(BH 4 ) 2 20.8 Mg(AlH 4 ) 2 9.3 LiBH 4 18.2 Ca(AlH 4 ) 2 7.9 Mg(BH 4 ) 2 14.9 KBH 4 7.5 Ca(BH 4 ) 2 11.6 NaAlH 4 7.5 NaBH4 10.7 Ga(AlH

36

Application of FIB microsampling technique to long-period ordered TiAl single crystal with composition gradient  

Science Journals Connector (OSTI)

......and 3 Department of Materials Science and Engineering...for Electronics and Materials, Kyushu University...Transmission Specimen Handling Titanium chemistry...for Electronics and Materials and 2 Art, Science...In a Ti-Al phase diagram, a g-TiAl intermetallic......

Satoshi Hata; Kohjiro Shiraishi; Masaru Itakura; Noriyuki Kuwano; Takayoshi Nakano; Yukichi Umakoshi

2004-10-01T23:59:59.000Z

37

Performance of Mo/Au TES microcalorimeters  

Science Journals Connector (OSTI)

We are developing X-ray calorimeters to meet the specifications of the Constellation-X mission. Each calorimeter consists of a transition-edge-sensor (TES) thermometer which is suspended on a silicon-nitride membrane. Our TES thermometers are Mo/Au bilayer films that are biased in the sharp phase transition between the superconducting and normal-metal states. These calorimeters have demonstrated very good energy resolutions: 2.4 eV at 1.5 keV and 3.7 eV at 3.3 keV. The energy resolutions are limited by thermal noise and Johnson noise (which are intrinsic to any resistive calorimeter) plus excess noise. The excess noise which is several times larger than the Johnson noise is consistent with frequency-independent voltage noise in the TES. Detailed measurements of one Mo/Au TES demonstrate that the excess noise is independent of the voltage applied to the TES over a range of biases at the same TES resistance. The magnitude of the excess noise is smallest at the high-resistance end of the phase transition. We also compared noise in square Mo/Au TES’s ranging in size from 300 microns to 600 microns to learn how the excess noise is affected by the geometry of the TES.

Mark A. Lindeman; Regis P. Brekosky; Enectali Figueroa-Feliciano; Fred M. Finkbeiner; Mary Li; Caroline K. Stahle; Carl M. Stahle; Nilesh Tralshawala

2002-01-01T23:59:59.000Z

38

Surface Engineering to Improve the Durability and Lubricity of Ti-6Al-4V Alloy  

SciTech Connect

Titanium alloys offer high strength, high corrosion resistance, and the opportunity to reduce the weight of heavy vehicle engine components, but they do not perform well as bearing surfaces without further treatments or coatings. This paper explores a series of surface engineering treatments to improve the friction and wear behavior of Ti-6Al-4V alloy under diesel engine oil-lubricated conditions.

Bansal, Dinesh G [ORNL; Eryilmaz, Osman L [Argonne National Laboratory (ANL); Blau, Peter Julian [ORNL

2011-01-01T23:59:59.000Z

39

Microscopic mechanisms of metastable phase formation during ball milling of intermetallic TiAl phases  

SciTech Connect

Powders of the intermetallic equilibrium phases {alpha}{sub 2}-Ti{sub 3}Al, {gamma}-TiAl and TiAl{sub 3} were ball milled in order to investigate the microscopic origins of the energetic destabilization and the transformation into metastable phases during the milling process. It was found that the intermetallic phases were chemically partially disordered on milling followed by the transformation into solid solution phases after long milling. In detail, for the {gamma} phase, the formation of numerous deformation twins, thin h.c.p. lamellae and lamellae of the 9R phase formed by an antitwin operation was observed by TEM. The disordering of the D0{sub 22}-TiAl{sub 3} phase occurred inhomogeneously in the material via the formation of antiphase boundaries on (001) planes, resulting in a f.c.c. solid solution in the final state. In summary, it can be concluded that the formation of the observed metastable phases results from chemical disordering, whereas the excess enthalpy of grain boundaries plays only a minor role for the energetical destabilization of the intermetallic compounds during milling in this case.

Klassen, T.; Oehring, M.; Bormann, R. [GKSS Research Centre, Geesthacht (Germany)] [GKSS Research Centre, Geesthacht (Germany)

1997-09-01T23:59:59.000Z

40

Crack initiation and crack growth resistance of Ti-48Al-2Cr sheet material  

SciTech Connect

The present paper reports on the fracture toughness tests conducted on Ti-48Al-2Cr sheet material with near-gamma microstructure produced by hot rolling. Compact tension specimens were sectioned from sheet material and tested at room temperature to determine the fracture toughness and crack growth resistance curves. The deformation and fracture behavior were studied on tested specimens.

Dogan, B.; Schwalbe, K.H. [GKSS Research Centre, Geesthacht (Germany)] [GKSS Research Centre, Geesthacht (Germany); Clemens, H. [Plansee AG, Reutte (Austria)] [Plansee AG, Reutte (Austria)

1998-03-03T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Deformation and fracture behavior of composite structured Ti-Nb-Al-Co(-Ni) alloys  

SciTech Connect

Tensile ductility of the Ti-based composites, which consist of a ?-Ti phase surrounded by ultrafine structured intermetallics, is tunable through the control of intermetallics. The two Ti-based alloys studied exhibit similar compressive yield strength (about 1000?MPa) and strain (about 35%–40%) but show a distinct difference in their tensile plasticity. The alloy Ti{sub 71.8}Nb{sub 14.1}Ni{sub 7.4}Al{sub 6.7} fractures at the yield stress while the alloy Ti{sub 71.8}Nb{sub 14.1}Co{sub 7.4}Al{sub 6.7} exhibits about 4.5% of tensile plastic deformation. To clarify the effect of microstructure on the deformation behavior of these alloys, tensile tests were carried out in the scanning electron microscope. It is shown that the distribution as well as the type of intermetallics affects the tensile ductility of the alloys.

Okulov, I. V., E-mail: i.okulov@ifw-dresden.de; Marr, T.; Schultz, L.; Eckert, J. [IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Institut für Werkstoffwissenschaft, Technische Universität Dresden, D-01062 Dresden (Germany); Kühn, U. [IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Freudenberger, J. [IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Institut für Werkstoffwissenschaft, Technische Universität Bergakademie Freiberg, Gustav-Zeuner-Str. 5, D-09599 Freiberg (Germany); Oertel, C.-G.; Skrotzki, W. [Institut für Strukturphysik, Technische Universität Dresden, D-01062 Dresden (Germany)

2014-02-17T23:59:59.000Z

42

Structural, textural and catalytic properties of Al-, Ti-pillared clays  

SciTech Connect

Al-, Ti- and Zr-pillared clays were characterized and NiMo/Pilc`s were tested in HDS reactions. The combination of activity measurements with Moessbauer Spectroscopy and x-ray microanalysis at microscopical scale give insight in the metal phases migration during pillaring, reaction and regeneration steps. {Alpha}-Fe phase in free Fe{sub 2}O{sub 3} islands predominate together with structural Fe{sup 3+} phase, but during the catalytic reaction Fe{sup 2+} forms. Delamination of the Ti- and Zr-Clay supports, together with high Lewis acidity might enhance their catalytic properties.

Ramos-Galvan, C.E.; Dominguez, J.M.; Sandoval-Robles, G.; Castillo-Mares, A.; Nava E, N.

1996-12-31T23:59:59.000Z

43

Thermodynamic properties and stability of AlF-bearing titanite CaTiOSiO4–CaAlFSiO4  

Science Journals Connector (OSTI)

Calorimetric and experimental data on AlF-bearing titanite are presented that yield thermodynamic properties of CaAlFSiO4, as well as activity-composition relations of binary titanite CaTiOSiO4–CaAlFSiO4. The hea...

Ulrike Troitzsch; David J. Ellis

2002-02-01T23:59:59.000Z

44

Micro-Raman spectroscopic study of nanolaminated Ti{sub 5}Al{sub 2}C{sub 3}  

SciTech Connect

Micro-Raman spectroscopic study and lattice dynamics calculations were conducted to study a recently identified layered ternary carbide, Ti{sub 5}Al{sub 2}C{sub 3}. The experimental Raman shifts were remarkably consistent with the calculated values. Polarized Raman spectrum was collected in the polycrystalline sample, which confirmed the theoretical symmetry assignment of the Raman modes. In addition, the atomic vibrations of the peaks at 192?cm{sup ?1}, 311?cm{sup ?1}, and 660?cm{sup ?1} were identified to be the combination of the counterparts in Ti{sub 2}AlC and Ti{sub 3}AlC{sub 2}.

Zhang, H.; Li, Z. J. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Wang, X. H. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Xiang, H. M.; Zhou, Y. C, E-mail: yczhou714@gmail.com [Science and Technology of Advanced Functional Composite Laboratory, ARIMPT, No.1 South Dahongmen Road, Beijing 100076 (China)

2014-03-31T23:59:59.000Z

45

Surface characterization and mechanical property evaluation of thermally oxidized Ti-6Al-4V  

SciTech Connect

The present study concerns development of a thin and adherent oxide film on the surface of Ti-6Al-4V by thermal oxidation. Thermal oxidation was carried out over a range of temperature between 400 to 600 deg. C and a time from 25 h to 60 h. A detailed characterization of the surface and cross section of the oxidized surface was carried out by optical/scanning electron microscopy and X-ray diffraction techniques. Finally, the mechanical properties of the oxidized surface in terms of microindentation hardness and wear resistance were evaluated as a function of oxidation parameters. Surface oxidation of Ti-6Al-4V at 600 deg. C for 36 h offered a defect free oxide scale with improved hardness and wear resistance.

Biswas, Amit [Department of Metal. and Maters. Engg., I. I. T. Kharagpur, W. B. - 721302 (India); Dutta Majumdar, Jyotsna, E-mail: jyotsna@metal.iitkgp.ernet.in [Department of Metal. and Maters. Engg., I. I. T. Kharagpur, W. B. - 721302 (India)

2009-06-15T23:59:59.000Z

46

Cold compaction study of Armstrong Process Ti-6Al-4V powders  

SciTech Connect

This work investigates the cold compaction behavior of Ti-6Al-4V powders produced by Armstrong Process . As-received as well as milled powders were characterized and these powders were uniaxially die-pressed at designated pressures up to 690 MPa to form disk samples with different aspect ratios. Samples with high aspect ratio exhibited non-uniform density along the pressing axis and the density distribution is in consistent with the result predicted by finite element analysis. The linear regression analysis on the experimental density data can be used to predict density of compacts with different aspect ratios. In the studied pressure range, an empirical powder compaction equation represents the green density pressure relationship very well for both the as-received and 1-hr milled Armstrong Ti-6Al-4V powders.

Chen, Wei [ORNL; Yamamoto, Yukinori [ORNL; Peter, William H [ORNL; Gorti, Sarma B [ORNL; Sabau, Adrian S [ORNL; Clark, Michael B [ORNL; Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Blue, Craig A [ORNL; Fuller, Brian [International Titanium Powder; Akhtar, Kamal [International Titanium Powder

2011-01-01T23:59:59.000Z

47

The early stages of solid-state reactions in Ti/Al multilayer films  

SciTech Connect

The authors have investigated the solid-state reaction of Ti/Al multilayer films by x-ray diffraction (XRD) and differential scanning calorimetry (DSC), with focus on the early stages of the reaction provided by samples with pair thicknesses in the range 5--40 nm. This reaction, which results in formation of TiAl{sub 3} with metastable L1{sub 2} structure, can be modeled by a nucleation and growth process on the basis of the Johnson-Mehl-Avrami theory, with a reaction-order parameter n {approx} 1. These observations indicate the significance of nucleation barriers even at early stages of solid-state reactions, and suggests that the phenomena of phase selection and formation of metastable phases can result from the presence of nucleation barriers.

Michaelsen, C.; Woehlert, S.; Bormann, R. [GKSS Research Center, Geesthacht (Germany). Inst. for Materials Research; Barmak, K. [Lehigh Univ., Bethlehem, PA (United States). Dept. of Materials Science and Engineering

1996-12-31T23:59:59.000Z

48

Consolidation Process in Near Net Shape Manufacturing of Armstrong CP-Ti/Ti-6Al-4V Powders  

SciTech Connect

This paper summarizes our recent efforts to develop the manufacturing technologies of consolidated net-shape components by using new low-cost commercially pure titanium (CP-Ti) and Ti-6Al-4V alloy powders made by the Armstrong process. Fabrication processes of net shape/ near net shape components, such as uniaxial die-pressing, cold isostatic pressing (CIP), sintering, roll compaction and stamping, have been evaluated. The press-and-sinter processing of the powders were systematically investigated in terms of theoretical density and microstructure as a function of time, pressure, and temperature. Up to 96.4% theoretical density has been achieved with the press-and-sinter technology. Tensile properties of the consolidated samples exhibit good ductility as well as equivalent yield/ultimate tensile strengths to those of fully consolidate materials, even with the presence of a certain amount of porosity. A consolidation model is also under development to interpret the powder deformation during processing. Net shape components made of the Armstrong powder can successfully be fabricated with clearer surface details by using press-and-sinter processing.

Yamamoto, Yukinori [ORNL; Kiggans, Jim [ORNL; Clark, Michael B [ORNL; Nunn, Stephen D [ORNL; Sabau, Adrian S [ORNL; Peter, William H [ORNL

2010-01-01T23:59:59.000Z

49

Synthesis of nanostructured multiphase (Ti,Al)N/a-Si3N4 thin films using dense plasma focus device  

Science Journals Connector (OSTI)

A 2.3 kJ pulsed plasma focus device was used to prepare thin films of nc-(Ti,Al)N/a-Si3N4 at room temperature. The plasma focus device, fitted with copper anode encapsulated with Ti0.5Al0.5 anode, was operated with nitrogen as the filling gas. Films were deposited with various number of focus shots, at 90 mm from top of the anode and at zero angular position with respect to anode axis. XRD patterns show the growth of polycrystalline (Ti,Al)N thin films with orientations in the (1 1 1), (2 0 0), (2 2 0) and (3 1 1) crystallographic planes. Behavior of lattice constant, grain size and film roughness of deposited film as a function of variation in number of focus shots is discussed. SEM micrographs of film deposited with 15 number of focus shots exhibit well-developed net like structure of nc-(Ti,Al)N/a-Si3N4 and possibly nc-(Ti,Al)N/a-Si3N4/a-AlN or nc-TiN/a-Si3N4/a-AlN. Surface Roughness ranging 64 nm to 89 nm was also observed.

Tousif Hussain; R. Ahmad; Nida Khalid; Z.A. Umar; A. Hussnain

2011-01-01T23:59:59.000Z

50

Properties of two-phase intermetallic (Ti, Nb){sub 3} (Al, Si) + (Ti, Nb){sub 5} (Si, Al){sub 3} P/M bulk and sheet material  

SciTech Connect

Intermetallic Ti-based alloy powder with nominal composition Ti 23.5Al5.5Si 10 Nb(at.%) was produced by argon gas atomization. This dual phase alloy is composed of the {alpha}{sub 2}-(Ti, Nb){sub 3} (Al,Si)-matrix phase and a eutectic mixture of {alpha}{sub 2}-(Ti, Nb){sub 3}(Al, Si) + {xi}-(Ti, Nb){sub 5} (Si, Al){sub 3}. The powder was compacted by hot isostatic pressing, subsequently hot rolled into sheets, and heat treated. The microstructures of the HIPed compacts and of the sheet materials were metallographically characterized and correlated with tensile properties at temperatures between 20 and 1,000 C. Due to networks of the brittle {xi}-silicide phase, the HIPed state showed no ductility at 20 C. Break-down of the silicide network during rolling led to an improved ductility at 20 C. After post rolling annealing, the yield strengths at 20 and 700 C were between 750--490 MPa and 700--420 MPa for specimens taken parallel and perpendicular to the rolling direction, respectively. These values are considerably higher than those reported for {gamma}-TiAl sheets. At 1,000 C the sheet material could be superplastically deformed.

Gerling, R.; Oehring, M.; Schimansky, F.P. [GKSS-Forschungszentrum, Geesthacht (Germany)] [GKSS-Forschungszentrum, Geesthacht (Germany); Bartels, A. [TU Hamburg-Harburg (Germany)] [TU Hamburg-Harburg (Germany); Clemens, H. [Plansee Aktiengesellschaft, Reutte (Austria). Technology Center] [Plansee Aktiengesellschaft, Reutte (Austria). Technology Center

1997-10-01T23:59:59.000Z

51

Composition, morphology and mechanical properties of sputtered TiAlN coating  

SciTech Connect

TiAlN coating was deposited on the tungsten carbide cutting tool by using DC magnetron sputtering system to study the influence of substrate bias and nitrogen flow rate on the composition, morphology and mechanical properties. The negatively substrate bias and nitrogen flow rate was varied from about ?79 to ?221 V and 30 sccm to 72 sccm, respectively. The coating composition and roughness were characterized by using SEM/EDX and Atomic Force Microscopy (AFM), respectively. The dynamic ultra micro hardness tester was used to measure the mechanical properties. The coating hardness increases to about 10-12 GPa with an increase of the negatively substrate bias up to ? 200 V and it tend to decrease with an increase in nitrogen flow rate up to 70 sccm. The increase of hardness follows the increase of Ti and N content and rms coating roughness.

Budi, Esmar, E-mail: esmarbudi@unj.ac.id [Department of Physics, Faculty of Science and Mathematics, Universitas Negeri Jakarta, Jl. Pemuda No. 10, Jakarta 13220 (Indonesia); Razali, M. Mohd. [Faculty of Manufacturing Engineering, Universiti Teknikal Malaysia Melaka, Karung Berkunci No. 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia); Nizam, A. R. Md. [Faculty of Manufacturing Engineering, UniversitiTeknikal Malaysia Melaka, Karung Berkunci No. 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

2014-03-24T23:59:59.000Z

52

Effect of aluminum content on synthesis of Ti2AlC and Ti3AlC2 during treatment in a high-energy mill and hot pressing  

Science Journals Connector (OSTI)

Treatment of initial powders of titanium, carbon and aluminum in a high-energy mill and pressure sintering are used for...2AlC and Ti3AlC2 ceramics. The effect of the content of aluminum and of the sintering temp...

Jianfeng Zhu; Guoquan Qi; Fen Wang; Haibo Yang; Ying Li

2011-05-01T23:59:59.000Z

53

Effects of processing on texture, microstructure and related properties of TiAl alloys  

SciTech Connect

Depending on factors such as processing conditions, stoichiometry and initial microstructure a variety of different textures has been found in TiAl alloys. They give insight into the origin of the generation of preferred orientations during solidification and recrystallization and by rotation of orientations during deformation. A comparison of measured and simulated textures on the basis of current models of polycrystal deformation leads to general conclusions about the crystallography of slip and on the strength of the different slip systems. The knowledge of texture is profitable for an understanding as well as for an explanation of the anisotropy of mechanical properties such as elastic constants, plastic behavior and fracture parameters.

Mecking, H.; Hartig, C. [Technical Univ. Hamburg-Harburg, Hamburg (Germany)

1995-12-31T23:59:59.000Z

54

Time-dependent stress concentration and microcrack nucleation in TiAl  

SciTech Connect

Localized stress evolution associated with the interaction of slip or twinning with an interface is treated by means of a superposition of the internal loading of a crystalline subsystem by dynamic dislocation pile-up and the stress relaxation by climb of interfacial dislocations. The peak value of a stress concentration factor depends on both the angular function that includes the effect of mode mixity and the ratio of characteristic times for stress relaxation and internal loading. The available experimental data on orientation and strain rate dependences of interfacial fracture mode in polysynthetically twinned TiAl crystals are discussed in view of the theoretical concepts presented in this paper.

Yoo, M.H. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Division

1995-12-31T23:59:59.000Z

55

Improved Hydrogen Storage Kinetics of Nanoconfined NaAlH4 Catalyzed with TiCl3 Nanoparticles  

Science Journals Connector (OSTI)

Improved Hydrogen Storage Kinetics of Nanoconfined NaAlH4 Catalyzed with TiCl3 Nanoparticles ... We demonstrate that NaAlH4 confined within the nanopores of a titanium-functionalized metal–organic framework (MOF) template MOF-74(Mg) can reversibly store hydrogen with minimal loss of capacity. ...

Thomas K. Nielsen; Marek Polanski; Dariusz Zasada; Payam Javadian; Flemming Besenbacher; Jerzy Bystrzycki; Jørgen Skibsted; Torben R. Jensen

2011-03-29T23:59:59.000Z

56

High-Temperature Galling Characteristics of Ti-6Al-4V with and without Surface Treatments  

SciTech Connect

Galling is a severe form of surface damage in metals and alloys that typically arises under relatively high normal force, low-sliding speed, and in the absence of effective lubrication. It can lead to macroscopic surface roughening and seizure. The occurrence of galling can be especially problematic in high-temperature applications like diesel engine exhaust gas recirculation system components and adjustable turbocharger vanes, because suitable lubricants may not be available, moisture desorption promotes increased adhesion, and the yield strength of metals decreases with temperature. Oxidation can counteract these effects to some extent by forming lubricative oxide films. Two methods to improve the galling resistance of titanium alloy Ti-6Al-4V were investigated: (a) applying an oxygen diffusion treatment, and (b) creating a metal-matrix composite with TiB2 using a high-intensity infrared heating source. A new, oscillating three-pin-on-flat, high-temperature test method was developed and used to characterize galling behavior relative to a cobalt-based alloy (Stellite 6B ). The magnitude of the oscillating torque, the surface roughness, and observations of surface damage were used as measures of galling resistance. Owing to the formation of lubricative oxide films, the galling resistance of the Ti-alloy at 485o C, even non-treated, was considerably better than it was at room temperature. The IR-formed composite displayed reduced surface damage and lower torque than the substrate titanium alloy.

Blau, Peter Julian [ORNL; ERDMAN III, DONALD L [ORNL; Ohriner, Evan Keith [ORNL; Jolly, Brian C [ORNL

2011-01-01T23:59:59.000Z

57

A transmission electron microscopy study of the deformation behavior underneath nanoindents in nano-scale Al-TiN multilayered composites  

SciTech Connect

Nano-scale multilayered Al-TiN composites were deposited with DC magnetron sputtering technique in two different layer thickness ratios - Al:TiN = 1:1 and Al:TiN = 9:1. The Al layer thickness varied from 2 nm to 450 nm. The hardness of the samples was tested by nanoindentation using a Berkovich tip. Cross-sectional Transmission Electron Microscopy (TEM) was carried out on samples extracted with Focused Ion Beam (FIB) from below the nanoindents. This paper presents the results of the hardness tests in the Al-TiN multilayers with the two different thickness ratios and the observations from the cross-sectional TEM studies of the regions underneath the indents. These studies showed remarkable strength in the multilayers, as well as some very interesting deformation behavior in the TiN layers at extremely small length scales, where the hard TiN layers undergo co-deformation with the Al layers.

Bhattacharyya, Dhriti [Los Alamos National Laboratory; Mara, Nathan A [Los Alamos National Laboratory; Dickerson, Patricia O [Los Alamos National Laboratory; Misra, Amit [Los Alamos National Laboratory; Hoagland, R G [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

58

Investigating surface roughness, material removal rate and corrosion resistance in PMEDM of ?-TiAl intermetallic  

Science Journals Connector (OSTI)

Titanium aluminide intermetallics offer an attractive combination of low density and good oxidation, corrosion and ignition resistance with unique mechanical properties. In this study two series of machining tests are designed. Firstly the powder mixed electrical discharge machining (PMEDM) of ?-TiAl by means of different powders such as aluminum, chrome, silicon carbide, graphite and iron is performed to investigate the output characteristics of surface roughness and topography, material removal rate (MRR), electrochemical corrosion resistance of machined samples and also the machined surfaces are investigated by means of EDS and XRD analyses. Secondly after selection the aluminum powder as the most appropriate kind of powder, the current, pulse on time, powder size and powder concentration are changed in different levels for overall comparison between EDM and PMEDM output characteristics. In the first setting of input machining parameters, aluminum powder improves the surface roughness of TiAl sample about 32% comparing with EDM case and also aluminum particles with the size of 2 ?m, in the second setting of input parameters lead to 54% enhancement of MRR comparing with EDM case. The electrochemical corrosion results show that, corrosion resistance of the samples which are machined by graphite and chrome powders respectively are about three and two times more than the sample which is machined without powder.

Behzad Jabbaripour; Mohammad Hossein Sadeghi; Mohammad Reza Shabgard; Hossein Faraji

2013-01-01T23:59:59.000Z

59

Analysis of defect generation in Ti–6Al–4V parts made using powder bed fusion additive manufacturing processes  

Science Journals Connector (OSTI)

Abstract Ti–6Al–4V parts made using additive manufacturing processes such as selective laser melting (SLM) and electron beam melting (EBM) are subject to the inclusion of defects. This study purposely fabricated Ti–6Al–4V samples with defects by varying process parameters from the factory default settings in both SLM and EBM systems. Process parameters are classified according to their tendency to create certain types of porosity. Finally, defect characteristics are discussed with respect to defect generation mechanisms; and effective process windows for SLM and EBM system are discussed.

Haijun Gong; Khalid Rafi; Hengfeng Gu; Thomas Starr; Brent Stucker

2014-01-01T23:59:59.000Z

60

Laser cladding Al-Si/Al2O3-TiO2 composite coatings on AZ31B magnesium alloy  

Science Journals Connector (OSTI)

To improve the wear resistance and corrosion resistance of magnesium alloys, a 5 kW continuous wave CO2 laser was used to investigate the laser surface cladding on AZ31B magnesium alloys with Al-Si/...2O3 -TiO2.....

Zeqin Cui ???; Hongwei Yang…

2012-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The investigation of die-pressing and sintering behavior of ITP CP-Ti and Ti-6Al-4V powders  

SciTech Connect

This paper investigated the die-pressing and sintering behavior of the low-cost CP-Ti and Ti-6Al- 4V powders made by the Armstrong Process . The Armstrong powders have an irregular coral like, dendritic morphology, with a dendrite size of approximately 2-5 m. As-received as well as milled powders were uniaxially pressed at designated pressures up to 690 MPa to form disk samples with different aspect ratios. In the studied pressure range, an empirical powder compaction equation was applied to linearize the green density pressure relationship, and powder compaction parameters were obtained. The Armstrong Ti-64 powder exhibited a significantly higher sinterability than the CP-Ti powder. This was explained to be due to the higher diffusivity of V at the sintering temperature. The Ti-64 samples with a green density of 71.0% increased to 99.6% after sintering at 1300oC for 1 hour. An ex-situ technique was used to track the powder morphology change before and after sintering.

Chen, Wei [ORNL; Yamamoto, Yukinori [ORNL; Peter, William H [ORNL; Clark, Michael B [ORNL; Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Muth, Thomas R [ORNL; Blue, Craig A [ORNL; Williams, James C [Ohio State University; Fuller, Brian [International Titanium Powder; Akhtar, Kamal [International Titanium Powder

2012-01-01T23:59:59.000Z

62

Statistical simulation of small fatigue crack nucleation and coalescence in a lamellar TiAl alloy  

SciTech Connect

This article examines the possibility of fatigue failure as the result of fatigue crack nucleation and coalescence at stress ranges below the fatigue limit and the large crack threshold where fatigue cracks are expected not to grow. By representing the material as a two-dimensional array of beam elements, the nucleation of nonpropagating small cracks at various material locations is modeled via a statistical approach that considers fatigue crack nucleation by accumulation of damage at randomly distributed weak regions. Once nucleated, the fatigue cracks do not propagate but extend only by linking with fatigue cracks subsequently formed in the contiguous elements. Result of the computer simulation suggests that fatigue failure by crack nucleation and coalescence is feasible, but the cycles-to-coalescence is much longer than the cycles-to-initiation for the first crack. Implications of the results in fatigue life assessment based on the Kitagawa diagram are discussed for TiAl alloys.

Chan, K.S. [Southwest Research Inst., San Antonio, TX (United States); Wittowsky, B. [Proctor and Gamble European Service GmbH, Euskirchen (Germany); Pfuff, M. [GKSS Research Center, Geesthacht (Germany)

1999-05-01T23:59:59.000Z

63

Elastic properties of low density core (LDC) Ti-6Al-4V sandwich cores  

SciTech Connect

Lightweight, structurally efficient low density core (LDC) sandwich structures can be produced by entrapping argon gas within a finely dispersed distribution of pores in a microstructure and using a high temperature anneal to cause pore growth by gas expansion. This results in a porous microstructure with a relative density as low as {approximately}0.70. Laser ultrasonic methods have been used to measure the longitudinal and shear wave velocities and hence the elastic properties of LDC Ti-6Al-4V cores prior to, and after gas expansion treatments of up to 48 hr at 920 C. The data were compared with several analytical models for predicting the volume fraction of porosity dependent elastic properties of porous materials.

Queheillalt, D.T.; Wadley, H.N.G. [Univ. of Virginia, Charlottesville, VA (United States). IPM Lab.; Schwartz, D.S. [Boeing Co., St. Louis, MO (United States)

1998-12-31T23:59:59.000Z

64

Upper critical field of Ti and ?-TiAl alloys: Evidence of an intrinsic type-II superconductivity in pure Ti  

Science Journals Connector (OSTI)

The upper critical field Hc2 of ?-Ti1-xAlx(0Fermi velocity obtained here is substantially lower than predicted by band calculation. The present work gives clear evidence that pure Ti is an intrinsic type-II superconducting element due to its very low renormalized Fermi velocity.

Liu Shumei; Zhang Dianlin; Jing Xiunian; Lu Li; Li Shanlin; Kang Ning; Wu Xiaosong; J. J. Lin

2000-10-01T23:59:59.000Z

65

Development and Characterization of Hard and Wear Resistant MMC Coating on Ti-6Al-4V Substrate by Laser Cladding  

Science Journals Connector (OSTI)

Abstract Ti-6Al-4V, due to its high specific strength and resistance to corrosion, is one of the highly useful materials in aerospace, automobile and chemical industries. Poor hardness and wear resistance properties restrict its further applications. So surface modification of Ti-6Al-4V is necessary surface to enhance its tribological properties. Multi-phase and multi component coating development is one of the present research trends in surface engineering arena. In the present study it was attempted to develop a multi-component coating by laser cladding process using a pre-placed powder mixture containing Ni5Al (50 vol%) + hBN (10 vol%) + B4C (20 vol%) + SiC (20 vol%) on substrate of Ti-6Al-4V to improve its tribological performance. A nano-structured coating was formed with micro hardness (780 HV0.05). X-ray diffraction (XRD) identified the presence of compounds like TiC, BN, TiB2, SiC, and intermetallics of Ni-Ti in the coating. The wear behaviour of the composite coating was assessed by ball on disc type wear and friction monitor at 10 N load at 300 RPM taking a track diameter of 5 mm. Specific wear rate and coefficient of friction (?) were found to vary from 0.6E-12 to 2.2E-12 m3/N-m and from 0.15 to 0.45, respectively, due to rubbing of coated surface against tungsten carbide ball. The microstructure was explored by Scanning Electron Microscopy (SEM).

Mandeep Dhanda; Barun Haldar; P. Saha

2014-01-01T23:59:59.000Z

66

Long period structures in Ti1+xAl3-x alloys : experimental evidence of a devil's staircase ?  

E-Print Network (OSTI)

595 Long period structures in Ti1+xAl3-x alloys : experimental evidence of a devil's staircase ? A of a so-called devil's staircase. The experimental results are compared with those obtained in Ag3Mg domain size M depends on temperature; this dependence corresponds to a simple (harmless) staircase below

Boyer, Edmond

67

Electronic and atomic structures of Ti{sub 1-x}Al{sub x}N thin films related to their damage behavior  

SciTech Connect

Ti and Al K-edge x-ray absorption spectroscopy is used to investigate the electronic structure of Ti{sub 1-x}Al{sub x}N thin films deposited by reactive magnetron sputtering. The experimental near edge spectra of TiN and AlN are interpreted in the light of unoccupied density of state band structure calculations. The comparison of the structural parameters derived from x-ray absorption fine structure and x-ray diffraction reveals segregation between Al-rich and Ti-rich domains within the Ti{sub 1-x}Al{sub x}N films. Whereas x-ray diffraction probes only the crystallized domains, the structural information derived from extended x-ray absorption fine structure analysis turns on both crystalline and grain boundaries. The results are discussed by considering the damage behavior of the films depending on the composition.

Tuilier, M.-H.; Pac, M.-J.; Girleanu, M.; Covarel, G.; Arnold, G.; Louis, P. [Laboratoire de Mecanique, Materiaux et Procedes de Fabrication, Universite de Haute Alsace, 61 rue Albert Camus, F-68093 Mulhouse cedex (France); Rousselot, C. [Institut FEMTO-ST (UMR CNRS 6174), Universite de Franche-Comte, BP 71427, F-25211 Montbeliard cedex (France); Flank, A.-M. [CNRS--UR1 SOLEIL, F-91192 Gif sur Yvette cedex (France)

2008-04-15T23:59:59.000Z

68

Development of absorber coupled TES polarimeter at millimeter wavelengths.  

SciTech Connect

We report an absorber coupled TES bolometric polarimeter, consisting of an absorptive metal grid and a Mo/Au bi-layer TES on a suspended silicon nitride membrane disk. The electromagnetic design of the polarization sensitive absorbers, the heat transport modeling of the detector, the thermal response of the TES, and the micro-fabrication processes are presented. We also report the results of laboratory tests of a single pixel prototype detector, and compare with theoretical expectations.

Wang, G.; Yefremenko, V.; Novosad, V.; Bleem, L.; Chang, C.; McMahon, J.; Datesman, A.; Pearson, J.; Divan, R.; Downes, T.; Crites, A. T.; Meyer, S. S.; Carlstrom, J. E.; Univ. of Chicago

2009-06-01T23:59:59.000Z

69

X-ray diffraction line profile analysis of deformation microstructure in boron modified Ti-6Al-4V alloy  

SciTech Connect

X-ray diffraction line profile analysis (XRDLPA) techniques have been applied to investigate the deformed microstructure of a recently developed boron modified two-phase titanium alloy Ti-6Al-4V. The alloy was hot compressed at 750 deg. C up to 50% height reduction at two different strain rates (10{sup -3} S{sup -1} and 1 S{sup -1}). Microstructural parameters like average domain size, average microstrain within the domain and dislocation density of the two phases were determined using X-ray diffraction line profile analysis. The results indicate an increase in the microstrain and dislocation density for the {alpha}-phase and decrease for the {beta}-phase in the case of boron modified alloys as compared to the normal material. Microstructural modifications viz. the grain refinement and the presence of hard, brittle TiB particles in the case of boron modified alloy are held responsible for the observed difference in the dislocation density. - Research Highlights: {yields} Microstructural examination of hot compressed Ti64 with and without boron addition by XRDLPA. {yields} Smaller average domain size in alpha-phase compared to the corresponding alpha-phase in all cases. {yields} Higher microstrain and dislocation density for {alpha} phase and lower for {beta} phase in case of Ti64+B. {yields} Decrease in domain size while increase in micro-strain and dislocation density with strain rate. {yields} Strain accumulation around TiB particles responsible for high dislocation density in {alpha} phase.

Sarkar, Apu; Roy, Shibayan; Suwas, Satyam, E-mail: satyamsuwas@materials.iisc.ernet.in

2011-01-15T23:59:59.000Z

70

Silicide precipitation in a {gamma}-based Ti-47Al-2W-0.5Si alloy  

SciTech Connect

Although some work on microstructure of silicides in {gamma}-TiAl alloys has been done, it is restricted to the alloys containing high content of silicon ({approximately}3at.%). Furthermore, to the authors` knowledge, the crystal orientation relation between silicide and {beta} matrix that is stabilized to room temperature in the alloys containing transition elements (such as Nb, V, W, Cr), has not been reported yet. The present investigation was undertaken /to study the silicides in a {gamma}-TiAl base alloy with 2 at.% W addition containing 0.28--0.59 at.% Si after different heat treatments, to understand the effects of silicon content and heat treatment on the formation and morphology of silicides.

Yin, W.M. [CNR-ITM, Cinisello Balsamo (Italy)] [CNR-ITM, Cinisello Balsamo (Italy); [Chinese Academy of Sciences, Shenyang (China). Inst. of Metal Research; Lupinc, V. [CNR-ITM, Cinisello Balsamo (Italy)] [CNR-ITM, Cinisello Balsamo (Italy)

1997-07-15T23:59:59.000Z

71

In-situ sensing of the expansion of low density core (LDC) Ti-6Al-4V sandwich structures  

SciTech Connect

A combination multifrequency eddy current and laser ultrasonic sensors have been used to measure the pore expansion kinetics and elastic moduli evolution during the annealing of low density core (LDC) Ti-6Al-4V sandwich structures. The LDC samples were heated to 920 C and held there for up to 12 hr. The eddy current sensor measured the sample thickness (i.e., relative density) and revealed that the samples began to expand early during heating and was nearly complete after 4 hr at 920 C. The laser ultrasonic sensor measurements indicated a concomitant decrease in the elastic moduli with the reduction in relative density. The combination of an eddy current and laser ultrasonic sensor is therefore able to measure both the density and the elastic moduli independently during the annealing stage of LDC Ti-6Al-4V sandwich structure processing providing a simple method for directly controlling the parameters most critical to aerospace applications of these new materials.

Queheillalt, D.T.; Choi, B.W.; Wadley, H.N.G. [Univ of Virginia, Charlottesville, VA (United States). IPM Lab.; Schwartz, D.S. [Boeing Co., St. Louis, MO (United States)

1998-12-31T23:59:59.000Z

72

Fabricating superconducting interfaces between artificially grown LaAlO{sub 3} and SrTiO{sub 3} thin films  

SciTech Connect

Realization of a fully metallic two-dimensional electron gas (2DEG) at the interface between artificially grown LaAlO{sub 3} and SrTiO{sub 3} thin films has been an exciting challenge. Here we present for the first time the successful realization of a superconducting 2DEG at interfaces between artificially grown LaAlO{sub 3} and SrTiO{sub 3} thin films. Our results highlight the importance of two factors—the growth temperature and the SrTiO{sub 3} termination. We use local friction force microscopy and transport measurements to determine that in normal growth conditions the absence of a robust metallic state at low temperature in the artificially grown LaAlO{sub 3}/SrTiO{sub 3} interface is due to the nanoscale SrO segregation occurring on the SrTiO{sub 3} film surface during the growth and the associated defects in the SrTiO{sub 3} film. By adopting an extremely high SrTiO{sub 3} growth temperature, we demonstrate a way to realize metallic, down to the lowest temperature, and superconducting 2DEG at interfaces between LaAlO{sub 3} layers and artificially grown SrTiO{sub 3} thin films. This study paves the way to the realization of functional LaAlO{sub 3}/SrTiO{sub 3} superlattices and/or artificial LaAlO{sub 3}/SrTiO{sub 3} interfaces on other substrates.

Li, Danfeng, E-mail: Danfeng.Li@unige.ch; Gariglio, Stefano; Cancellieri, Claudia; Fête, Alexandre; Stornaiuolo, Daniela; Triscone, Jean-Marc [DPMC, University of Geneva, 24 Quai Ernest Ansermet, 1211 Geneva (Switzerland)

2014-01-01T23:59:59.000Z

73

Influence of Microstructure on High-Cycle Fatigue of Ti-6Al-4V: Bimodal vs. Lamellar Structures  

E-Print Network (OSTI)

for such failures in Ti-6Al-4V, a commonly used turbine blade alloy, specifically for fan and compressor blades.K. NALLA, B.L. BOYCE, J.P. CAMPBELL, J.O. PETERS, and R.O. RITCHIE The high-cycle fatigue (HCF) of titanium] HCF can result in essentially unpredictable used for blade and disk applications in the front (low

Ritchie, Robert

74

INVESTIGATION OF NOVEL ALLOY TiC-Ni-Ni3Al FOR SOLID OXIDE FUEL CELL INTERCONNECT APPLICATIONS  

SciTech Connect

Solid oxide fuel cell interconnect materials must meet stringent requirements. Such interconnects must operate at temperatures approaching 800 C while resisting oxidation and reduction, which can occur from the anode and cathode materials and the operating environment. They also must retain their electrical conductivity under these conditions and possess compatible coefficients of thermal expansion as the anode and cathode. Results are presented in this report for fuel cell interconnect candidate materials currently under investigation based upon nano-size titanium carbide (TiC) powders. The TiC is liquid phase sintered with either nickel (Ni) or nickel-aluminide (Ni{sub 3}Al) in varying concentrations. The oxidation resistance of the submicron grain TiC-metal materials is presented as a function weight change versus time at 700 C and 800 C for varying content of metal/intermetallic in the system. Electrical conductivity at 800 C as a function of time is also presented for TiC-Ni to demonstrate the vitality of these materials for interconnect applications. TGA studies showed that the weight gain was 0.8 mg/cm{sup 2} for TiC(30)-Ni(30wt.%) after 100 hours in wet air at 800 C and the weight gain was calculated to be 0.5205 mg/cm{sup 2} for TiC(30)- Ni(10 wt.%) after 100 hours at 700 C and 100 hours at 800 C. At room temperature the electrical conductivity was measured to be 2444 1/[ohm.cm] for TiC-Ni compositions. The electrical conductivities at 800 C in air was recorded to be 19 1/[ohm.cm] after 125 hours. Two identical samples were supplied to PNNL (Dr. Jeff Stevenson) for ASR testing during the pre-decision period and currently they are being tested there. Fabrication, oxidation resistance and electrical conductivity studies indicate that TiC-Ni-Ni{sub 3}Al ternary appears to be a very important system for the development of interconnect composition for solid oxide fuel cells.

Rasit Koc; Geoffrey Swift; Hua Xie

2005-01-25T23:59:59.000Z

75

Statistical evaluation of potential damage to the Al(OH)3 layer on nTiO2 particles in the presence of swimming pool and seawater  

Science Journals Connector (OSTI)

Nanosized TiO2 particles (nTiO2) are usually coated with an Al(OH)3 layer when used in sunscreen to shield against the harmful effects of free radicals that are generated when these particles are exposed to UV r...

Jurate Virkutyte; Souhail R. Al-Abed

2012-03-01T23:59:59.000Z

76

Investment casting of {gamma}-TiAl-based alloys: Microstructure and data base for gas turbine applications  

SciTech Connect

Investment casting is regarded as an economic processing technology for the production of {gamma}-TiAl based components for gas turbine applications. Near net-shape parts can be cast such that they are free from pores and flaws after adequate `HIP`ping. The inhomogeneous cast microstructure which results from locally varying cooling rates (e.g. in the root and foil of a blade), however, is often retained even after heat-treatments necessary to achieve a balance of properties for a given application. Appropriate modifications of the alloy chemistry may lead to an improved microstructural homogeneity in the cast parts. Data bases of properties (tensile properties, creep, fatigue and rupture strength, fracture and impact toughness, oxidation and corrosion resistance) which are relevant for potential gas turbine applications have been assessed for different cast {gamma}-TiAl alloys with different microstructures. These are compared with corresponding properties of nickel-based and iron-based superalloys {gamma}-TiAl is competing with for substitution.

Wagner, R.; Appel, F.; Dogan, B. [GKSS Research Center, Geesthacht (Germany). Inst. for Materials Research] [and others

1995-12-31T23:59:59.000Z

77

Thermal Energy Storage (TES): Past, Present and Future  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Energy Storage (TES): Past, Present and Future Thermal Energy Storage (TES): Past, Present and Future Speaker(s): Klaus Schiess Date: June 10, 2011 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Sila Kiliccote Thermal Energy Storage (TES) is a technology that stores "cooling" energy in a thermal storage mass. In the eighties and early nineties the utilities in California incentivised this technology to shift electrical on-peak power to off-peak. Thereafter, for various reasons TES became the most neglected permanent load shifting opportunity. It is only now with the challenges that the renewables provide that TES may have a come- back because it is basically the best and most economical AC battery available with a round trip efficiency of 100% or even better. This presentation gives some background to this development and shows the interdependence of

78

An Investigation into the evolution of damage and residual stresses in Ti6Al4V-Al?Ti metal intermetallic laminate (MIL) composites  

E-Print Network (OSTI)

good creep resistance, and relatively low material density.strengthened materials are toughened since the resistance toresistance of interfaces in NiAl/Mo model laminates, Materials

Li, Tiezheng

2006-01-01T23:59:59.000Z

79

Characterization of Ti diffusion in PVD deposited WTi/AlCu metallization on monocrystalline Si by means of secondary ion mass spectroscopy  

Science Journals Connector (OSTI)

The diffusion behavior of Titanium in Al0.5Cu/W18Ti (at.%) metallization stacks on monocrystalline Silicon has been investigated. The metallization system was prepared by in situ sputtering deposition. It is demonstrated that \\{WTi\\} is not stable as a diffusion barrier between Al0.5Cu and Si in temperature ranges between 623 K and 673 K due to Ti depletion. The Ti diffusion in Al0.5Cu is characterized by diffusion profiles prepared by secondary ion mass spectroscopy after annealing. The activation energy derived from this data is 2.28 eV for Ti diffusion into Al0.5Cu. The causal chain of detecting this behavior is described application-oriented.

M. Plappert; O. Humbel; A. Koprowski; M. Nowottnick

2012-01-01T23:59:59.000Z

80

Inuence of foreign-object damage on crack initiation and early crack growth during high-cycle fatigue of Ti6Al4V  

E-Print Network (OSTI)

; Ti±6Al±4V 1. Introduction The high-cycle fatigue (HCF) of aircraft gas-turbine engine components has of small surface fatigue cracks in a Ti±6Al±4V alloy, processed for typical turbine blade applications microcracks in the damaged zone (seen only at the higher impact velocities). Furthermore, the eect of residual

Ritchie, Robert

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

+ 2AlH 3 3 NaAlH 4 M. Mamula et al., Coll. Czechoslov. Chem. Commun. 32, 884 (1967). Atomic Hydrogen Interacting with Al Surfaces "H adsorption and the formation of alane...

82

On the preparation of TiAl alloy by direct reduction of the oxide mixtures in calcium chloride melt  

SciTech Connect

In recent years, TiAl-based intermetallic alloys are being increasingly considered for application in areas such as (i) automobile/transport sector (passenger cars, trucks and ships) (ii) aerospace industry (jet engines and High Speed Civil Transport propulsion system) and (iii) industrial gas turbines. These materials offer excellent (i) high temperature properties (at higher than 6000C) (ii) mechanical strength and (iii) resistance to corrosion and as a result have raised renewed interest. The combination of these properties make them possible replacement materials for traditional nickel-based super-alloys, which are nearly as twice as dense (than TiAl based alloys). Since the microstructures of these intermetallic alloys affect, to a significant extent, their ultimate performance, further improvements (by way of alteration/modification of these microstructures), have been the subject matter of intense research investigations. It has now been established that the presence of alloy additives, such as niobium, tantalum, manganese, boron, chromium, silicon, nickel and yttrium etc, in specific quantities, impart marked improvement to the properties, viz. fatigue strength, fracture toughness, oxidation resistance and room temperature ductility, of these alloys. From a number of possible alloy compositions, {gamma}-TiAl and Ti-Al-Nb-Cr have, of late, emerged as two promising engineering alloys/materials. . The conventional fabrication process of these alloys include steps such as melting, forging and heat treatment/annealing of the alloy compositions. However, an electrochemical process offers an attractive proposition to prepare these alloys, directly from the mixture of the respective oxides, in just one step. The experimental approach, in this new process, was, therefore, to try to electrochemically reduce the (mixed) oxide pellet to an alloy phase. The removal of oxygen, from the (mixed) oxide pellet, was effected by polarizing the oxide pellet against a graphite electrode in a pool of molten calcium chloride at a temperature of 9000C. The dominant mechanism of the oxygen removal was the ionization of oxygen followed by its subsequent discharge, as CO2/CO, at the anode surface. The removal of oxygen from the oxide mixture helped form the alloy in situ. The presentation shall cover the detailed experimental results pertaining to the preparation, evaluation and characterization of Ti-47Al-2Nb-2Cr (atom%) alloy.

Prabhat K. Tripathy; Derek J. Fray

2011-11-01T23:59:59.000Z

83

Substrate orientation effects on the nucleation and growth of the M{sub n+1}AX{sub n} phase Ti{sub 2}AlC  

SciTech Connect

The M{sub n+1}AX{sub n} (MAX) phases are ternary compounds comprising alternating layers of a transition metal carbide or nitride and a third ''A-group'' element. The effect of substrate orientation on the growth of Ti{sub 2}AlC MAX phase films was investigated by studying pulsed cathodic arc deposited samples grown on sapphire cut along the (0001), (1010), and (1102) crystallographic planes. Characterization of these samples was by x-ray diffraction, atomic force microscopy, and cross-sectional transmission electron microscopy. On the (1010) substrate, tilted (1018) growth of Ti{sub 2}AlC was found, such that the TiC octahedra of the MAX phase structure have the same orientation as a spontaneously formed epitaxial TiC sublayer, preserving the typical TiC-Ti{sub 2}AlC epitaxial relationship and confirming the importance of this relationship in determining MAX phase film orientation. An additional component of Ti{sub 2}AlC with tilted fiber texture was observed in this sample; tilted fiber texture, or axiotaxy, has not previously been seen in MAX phase films.

Tucker, Mark D.; Guenette, Mathew C.; Bilek, Marcela M. M.; McKenzie, David R. [School of Physics, University of Sydney, New South Wales 2006 (Australia); Persson, Per O. A.; Rosen, Johanna [School of Physics, University of Sydney, New South Wales 2006 (Australia); Thin Film Physics, Linkoepings Universitet, 58183 Linkoeping (Sweden)

2011-01-01T23:59:59.000Z

84

E-Print Network 3.0 - al si ti Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

and SiC. Internal grains of SiC and kamaciteiron silicide are also found independent of TiC. The grain... by volume. V and Si were also present in ... Source: Washington...

85

Conducting and insulating LaAlO{sub 3}/SrTiO{sub 3} interfaces: A comparative surface photovoltage investigation  

SciTech Connect

Surface photovoltage (SPV) spectroscopy, which is a versatile method to analyze the energetic distribution of electronic defect states at surfaces and interfaces of wide-bandgap semiconductor (hetero-)structures, is applied to comparatively investigate heterostructures made of 5-unit-cell-thick LaAlO{sub 3} films grown either on TiO{sub 2}- or on SrO-terminated SrTiO{sub 3}. As shown in a number of experimental and theoretical investigations in the past, these two interfaces exhibit dramatically different properties with the first being conducting and the second insulating. Our present SPV investigation reveals clearly distinguishable interface defect state distributions for both configurations when interpreted within the framework of a classical semiconductor band scheme. Furthermore, bare SrTiO{sub 3} crystals with TiO{sub 2} or mixed SrO/TiO{sub 2} terminations show similar SPV spectra and transients as do LaAlO{sub 3}-covered samples with the respective termination of the SrTiO{sub 3} substrate. This is in accordance with a number of recent works that stress the decisive role of SrTiO{sub 3} and the minor role of LaAlO{sub 3} with respect to the electronic interface properties.

Beyreuther, E., E-mail: elke.beyreuther@iapp.de; Thiessen, A.; Grafström, S.; Eng, L. M. [Institut für Angewandte Photophysik, Technische Universität Dresden, D-01062 Dresden (Germany); Paparo, D. [CNR-SPIN and Dipartimento di Fisica, Università di Napoli “Federico II,” Compl. Univ. di Monte S. Angelo, via Cintia, I-80126 Napoli (Italy)

2013-12-28T23:59:59.000Z

86

Dissimilar-alloy laser welding of titanium: Ti6Al-4V to Beta-C{trademark}  

SciTech Connect

Beta-C{sup TM} is a metastable-beta titanium alloy (nominal composition: Ti-3wt%Al-8wt%V-6wtTCr-4wt%Mo-4wt%Zr) which can be thermomechanically processed and heat treated to provide excellent combinations of strength, ductility, and fracture toughness. Recently, the increased application of metastable-beta titanium alloys in aerospace and commercial applications has resulted in the necessity to join these alloys to conventional alpha-beta titanium alloys. Based on this previous work, two approaches were considered for improving the ductility of dissimilar-alloy welds between Ti-6Al-4V and Beta-C{sup TM} in the present study: (1) application of a low heat input welding process to minimize the fusion zone and heat-affected zone (HAZ) beta grain size and (2) modification of the fusion zone chemical composition to allow greater microstructural optimization through postweld aging. CO{sub 2} laser welds were produced between Ti-6Al-4V and Beta-C{sup TM} sheet. Three different nominal fusion zone chemical compositions were obtained by varying the laser beam locations relative to the joint centerline and thereby melting different quantities of each base metal. For comparable postweld aging conditions, the laser welds exhibited ductilities superior to those of coarse-grained gas tungsten arc welds. Fracture analysis of the weld zone revealed a transition from a predominantly transgranular fracture in the low-temperature aged conditions to increasingly intergranular fracture following aging at higher temperature. This transition was promoted by an increase in the thickness and continuity of alpha phase at beta grain boundaries.

Liu, P.S.; Baeslack, W.A. III; Hurley, J.

1994-12-31T23:59:59.000Z

87

Validation of TES Temperature and Water Vapor Retrievals with ARM  

NLE Websites -- All DOE Office Websites (Extended Search)

Validation of TES Temperature and Water Vapor Retrievals with ARM Validation of TES Temperature and Water Vapor Retrievals with ARM Observations Cady-Pereira, Karen Atmospheric and Environmental Research, Inc. Shephard, Mark Atmospheric and Environmental Research, Inc. Clough, Shepard Atmospheric and Environmental Research Mlawer, Eli Atmospheric & Environmental Research, Inc. Turner, David University of Wisconsin-Madison Category: Atmospheric State and Surface The primary objective of the TES (Tropospheric Emission Spectrometer) instrument on the Aura spacecraft is the retrieval of trace gases, especially water vapor and ozone. The TES retrievals extremely useful for global monitoring of the atmospheric state, but they must be validated. The ARM sites are well instrumented and provide continuous measurements, which

88

Comparison of \\{WTi\\} and WTi(N) as diffusion barriers for Al and Cu metallization on Si with respect to thermal stability and diffusion behavior of Ti  

Science Journals Connector (OSTI)

Abstract The thermal stability of \\{WTi\\} and WTi(N) as diffusion barriers for Al and Cu metallization on Si (1 0 0) was investigated by time of flight secondary ion mass spectrometry (ToF-SIMS) depth profiling, X-ray diffraction (XRD), electron microscopy (SEM and TEM) and X-ray photoelectron spectroscopy (XPS). For both, Al and Cu, Ti diffusion out of \\{WTi\\} into the metal was proved to occur at elevated temperatures (400 °C for Al and 600 °C for Cu) which further results in barrier film failure. Nitrogen incorporation into \\{WTi\\} leads to an elimination of the Ti diffusion and consequently to a better thermal stability of the barrier film. It is shown that besides crystal structure, Ti diffusion into the metallization is an essential factor of the barrier failure mechanism. The failure temperature for Al is lower than for Cu.

M. Fugger; M. Plappert; C. Schäffer; O. Humbel; H. Hutter; H. Danninger; M. Nowottnick

2014-01-01T23:59:59.000Z

89

Electrospark deposition of Al2O3–TiB2/Ni composite-phase surface coatings on Cu–Cr–Zr alloy electrodes  

Science Journals Connector (OSTI)

Abstract To improve electrode life during the resistance spot welding of galvanized steel plates, an Al2O3–TiB2 composite coating was synthesized on the surfaces of spot-welding electrodes through an electrospark deposition process. The microstructure, elemental composition, phase structure, and mechanical properties of the coating were characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction analysis, and microhardness testing. It was found that extensive cracking occurred in the monolithic Al2O3–TiB2 coating and at the coating–electrode interface. When the Al2O3–TiB2 coating was deposited on electrodes precoated with Ni, the number of defects decreased significantly. Further, delamination did not occur, and fewer cracks were formed. The average hardness of the multilayered Al2O3–TiB2/Ni coating was approximately 2200 HV and higher than that of the monolithic Al2O3–TiB2 coating (1100 HV).

Ping Luo; Shijie Dong; Anzhuo Yangli; Shixuan Sun; Zhong Zheng; Huihu Wang

2014-01-01T23:59:59.000Z

90

Octahedral rotations in strained LaAlO{sub 3}/SrTiO{sub 3} (001) heterostructures  

SciTech Connect

Many complex oxides display an array of structural instabilities often tied to altered electronic behavior. For oxide heterostructures, several different interfacial effects can dramatically change the nature of these instabilities. Here, we investigate LaAlO{sub 3}/SrTiO{sub 3} (001) heterostructures using synchrotron x-ray scattering. We find that when cooling from high temperature, LaAlO{sub 3} transforms from the Pm3{sup ¯}m to the Imma phase due to strain. Furthermore, the first 4 unit cells of the film adjacent to the substrate exhibit a gradient in rotation angle that can couple with polar displacements in films thinner than that necessary for 2D electron gas formation.

Fister, T. T.; Hruszkewycz, S. O.; Proffit, D. L.; Eastman, J. A.; Fuoss, P. H.; Baldo, P. M.; Fong, D. D. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Zhou, H. [X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Luo, Z. [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Seo, S. S. A.; Lee, H. N. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2014-02-01T23:59:59.000Z

91

Modulation of conductance and superconductivity by top-gating in LaAlO{sub 3}/SrTiO{sub 3} 2-dimensional electron systems  

SciTech Connect

We report the electrical top-gating of a 2-dimensional electron gas (2DEG) formed at the LaAlO{sub 3}/SrTiO{sub 3} interface, using electron-beam evaporated Au gate electrodes. In these structures, epitaxial LaAlO{sub 3} films grown by pulsed laser deposition induce the 2DEGs at the interface to the SrTiO{sub 3} substrate and simultaneously act as the gate dielectric. The structured top-gates enable a local tuning and complete on/off switching of the interface (super-)conductivity, while maintaining the usual, intrinsic characteristics for these LaAlO{sub 3}/SrTiO{sub 3} interfaces when no gate voltage is applied.

Eerkes, P. D.; Wiel, W. G. van der; Hilgenkamp, H. [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)] [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

2013-11-11T23:59:59.000Z

92

Detailed characterization of Mo/Au TES microcalorimeters  

Science Journals Connector (OSTI)

We are optimizing Mo/Au transition-edge-sensor (TES) calorimeters to meet the specifications of NASA’s Constellation-X mission. Our calorimeters have already demonstrated very good energy resolution of X rays (2.4 eV at 1.5 keV). We wish to further improve the energy resolution by reducing excess noise in the calorimeters. Development of a detailed model and understanding of the noise is instrumental to reaching this goal. Towards that end we employ a linear model that describes the response of a calorimeter to signal and various sources of noise. The model is based on detailed measurements of the parameters that affect the calorimeter’s performance such as current-voltage characteristics of the TES thermal conductance of our silicon-nitride membranes and inductance in the electronic circuit used to bias the TES. We determine the sharpness of the superconducting phase transition by fitting the model to the measured responsivity of the calorimeter. The model relates sources of noise such as phonon noise Johnson noise and hypothetical sources of excess noise to measurements of noise in the TES. Based on this analysis we find that the excess noise is consistent with frequency-independent voltage noise in the TES

Mark A. Lindeman; Regis P. Brekosky; Enectali Figueroa-Feliciano; Fred M. Finkbeiner; Mary Li; Caroline K. Stahle; Carl M. Stahle; Nilesh Tralshawala

2002-01-01T23:59:59.000Z

93

Wide-Range Bolometer with RF Readout TES  

E-Print Network (OSTI)

To improve both scalability and noise-filtering capability of a Transition-Edge Sensor (TES), a new concept of a thin-film detector is suggested, which is based on embedding a microbridge TES into a high-Q planar GHz range resonator weakly coupled to a 50 Ohm-readout transmission line. Such a TES element is designed as a hot-electron microbolometer coupled to a THz range antenna and as a load of the resonator at the same time. A weak THz signal coupled to the antenna heats the microbridge TES, thus reducing the quality factor of the resonator and leading to a power increment in the readout line. The power-to-power conversion gain, an essential figure of merit, is estimated to be above 10. To demonstrate the basic concept, we fabricated and tested a few submicron sized devices from Nb thin films for operation temperature about 5 K. The dc and rf characterization of the new device is made at a resonator frequency about 5.8 GHz. A low-noise HEMT amplifier is used in our TES experiments without the need for a SQU...

Shitov, S V; Kuzmin, A A; Merker, M; Arndt, M; Wuensch, S H; Ilin, K S; Erhan, E; Ustinov, A; Siegel, M

2014-01-01T23:59:59.000Z

94

Selective Laser Melting Additive Manufacturing of TiC/AlSi10Mg Bulk-form Nanocomposites with Tailored Microstructures and Properties  

Science Journals Connector (OSTI)

Abstract The nanoscale TiC particle reinforced AlSi10Mg nanocomposite parts were produced by selective laser melting (SLM) additive manufacturing process. The influence of laser energy density (LED) on densification behavior, microstructural evolution, microhardness and wear properties of SLM-processed TiC/AlSi10Mg nanocomposites was studied. It showed that the near fully dense nanocomposite parts (>98% theoretical density) were achieved with increasing the applied LED. The TiC reinforcement in SLM-processed parts experienced a microstructural change from the standard nanoscale particle morphology (the average size 77-93 nm) to the relatively coarsened submicron structure (the mean particle size 154 nm) as the LED increased.The sufficiently high densification rate combined with the homogeneousdistribution of nanoscale TiC reinforcement throughout the matrix led to a high microhardness of 181.2 HV0.2, a considerably low coefficient of friction (COF) of 0.36, and a reduced wear rate of 2.94×10-5 mm3N-1m-1 for SLM-processed TiC/AlSi10Mg nanocomposite parts.

Dongdong Gu; Hongqiao Wang; Fei Chang; Donghua Dai; Pengpeng Yuan; Yves-Christian Hagedorn; Wilhelm Meiners

2014-01-01T23:59:59.000Z

95

Stability of the L1{sub 2} phase at 800 C in the Ti-Al-Cr system  

SciTech Connect

Interest in the L1{sub 2} phase, in the Ti-Al-Cr ternary system, continues due to the search for enhanced mechanical properties in light weight materials for possible structural applications. Additionally, recent work has indicated that alloys based in part on this phase may find use as protective alumina-forming coatings for {gamma}-based titanium-aluminides. In order to aid in the development of structural materials and coatings, the actual phase equilibria must be determined so that the correct processing schemes may be designed. Towards this end, the present work seeks to clarify some of the confusion pertaining to the phase equilibria of the L1{sub 2} phase.

Jewett, T.J.; Ahrens, B. [GKSS Research Centre, Geesthacht (Germany)] [GKSS Research Centre, Geesthacht (Germany); Dahms, M. [FH-Flensburg (Germany)] [FH-Flensburg (Germany)

1996-02-01T23:59:59.000Z

96

Solution Processed Al-Doped ZnO Nanoparticles/TiOx Composite for Highly Efficient Inverted Organic Solar Cells  

Science Journals Connector (OSTI)

Solution Processed Al-Doped ZnO Nanoparticles/TiOx Composite for Highly Efficient Inverted Organic Solar Cells ... This metal-oxide composition, called AZOTi, has two important elements that benefit production of low cost devices. ... After successful utilization of AZOTi in the fabrication of optimized single layer P3HT/PCBM-inverted solar cells, we also fabricated tandem cells comprising ITO/AZOTi/P3HT/PCBM in the front cell and a blend of a low band gap polymer [2,1,3-benzothiadiazole-4,7-diyl [4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b?]dithiophene-2,6-diyl

Abay Gadisa; Travis Hairfield; Leila Alibabaei; Carrie L. Donley; Edward T. Samulski; Rene Lopez

2013-08-27T23:59:59.000Z

97

Feasibility study on preparation of coatings on Ti–6Al–4V by combined ultrasonic impact treatment and electrospark deposition  

Science Journals Connector (OSTI)

Abstract A novel method combining ultrasonic impact treatment (UIT) with electrospark deposition was developed to prepare coatings on Ti–6Al–4V substrates. The microstructure, phase composition, residual stress, microhardness, and wear performance of the coating were studied, and new amorphous and nanocrystalline phases (titanium carbide nitride and iron titanium oxide) were found. In addition, the residual stress in the coating and in the substrate near the coating is compressive stress. The maximum compressive residual stress is about ?717 MPa, and its depth is about 470 ?m. Because of contributions from multiple factors, the wear volume loss of the sample subjected to combined UIT and electrospark processing was reduced by four orders of magnitude compared with that of the base material.

Yang Liu; Dongpo Wang; Caiyan Deng; Lixing Huo; Lijun Wang; Shu Cao

2014-01-01T23:59:59.000Z

98

Formation mechanism of linear friction welded Ti-6Al-4V alloy joint based on microstructure observation  

SciTech Connect

The microstructure of the linear friction welded Ti-6Al-4V titanium alloy joint was investigated by optical microscope, scanning electronic microscope and transmission electron microscope. Results show that the dynamic recovery and recrystallization resulting from the intensive plastic deformation and fast heating and cooling processes during linear friction welding account for the superfine {alpha} + {beta} grains in the weld center. Fine {alpha} grains distribute in the {beta} matrix or at the boundaries of {beta} grains. A mass of dislocations networks and metastructures present within the {alpha} and {beta} grains. - Research Highlights: {yields} TEM is employed in the analysis. {yields} The dynamic recovery is the main mechanism in thermal deformation of TC4. {yields} Superfine grains in the weld result from dynamic recovery and dynamic recrystallizaion, but the recrystallization is inadequate.

Ma Tiejun; Chen Tao, E-mail: ctwc-13@163.com; Li Wenya; Wang Shiwei; Yang Siqian

2011-01-15T23:59:59.000Z

99

Microstructures and mechanical properties of Ti-6Al-4V welds with filler additions of tantalum and FS85  

SciTech Connect

Many applications in the nuclear industry require that titanium alloys be welded to refractory metal alloys. Because of the widely dissimilar properties of these materials, the homogeneity of the fusion zone os of particular concern. To address this issue, a study was conducted to characterize the fusion zones of Ti-6Al-4V welds made with filler additions of tantalum and FS85 (Nb-28Wt%Ta-10wt%W-1wt%Zr). A goal of this study was to evaluate the feasibility of making microstructural predictions based on calculated fusion zone electron/atom (e/a) ratios. The welds were made by placing tantalum or FS85 shims between two pieces of 2.5 mm (0.1 in.) thick Ti-6Al-4V and making an electron beam weld along the length of the shim. With complete mixing, these shims were expected to produce fusion zone e/a ratios of 3.63{emdash}4.14 for the Ta series and 3.63{emdash}4.06 for the FS85 series, and microstructures consisting of {alpha}`, {alpha}`, and perhaps {omega}. The weld macro- and microstructures were characterized using optical and electron microscopy, energy-dispersive spectroscopy, and x-ray diffraction. The mechanical properties of the welds were assessed using transverse and all-weld-metal tensile tests. The results showed a general increase in strength and decrease in ductility with increasing {beta} stabilizer level. As a result of this study, parameters were developed to increase the fusion zone size and increase mixing of the components. This work was performed at Sandia National Laboratories, supported by the U.S. Department of Energy under contract number DE-AC04-76DR00789, and at Los Alamos National Laboratory under contract number W-7405-ENG-36.

Damkroger, B.K.; Dixon, R.D.; Cotton, J.D.

1994-12-31T23:59:59.000Z

100

Characterization of solid-phase welds between Ti-6Al-2Sn-4Zr-2Mo-0. 01Si and Ti-13. 5A1-21. 5Nb titanium aluminide  

SciTech Connect

Dissimilar-alloy welds have been produced between Ti-6Al-2Sn-4Zr-2Mo-0.1Si (wt.%) and Ti-13.5Al-21.5Nb (wt.%) titanium aluminide using three different solid-phase welding processes that create significantly different thermo-mechanical conditions at the weld interface. Exposure to supertransus temperatures, appreciable deformation and rapid cooling of the weld interface region during linear-friction welding promote dynamic recrystallization of beta grains and beta decomposition to fine martensitic products. In contrast, diffusion welding at temperatures below the base metal beta transus temperatures and at relatively low pressures minimizes deformation and microstructural variations in the weld interface region relative to the unaffected base metal. During capacitor-discharge resistance spot welding, extremely rapid heating of the weld interface region to near-solidus temperatures, and subsequent rapid cooling, result in the formation of a metastable, ordered-beta microstructure in the Ti-13.5ASl-21.5Nb and fine alpha-prime martensite in the Ti-6Al-2Sn-4Zr-2Mo-0.1Si.

Baeslack, W.A. III; Juhas, M.; Fraser, H.L. (Ohio State Univ., Columbus, OH (United States)); Broderick, T.F. (Wright Labs., Wright Patterson AFB, OH (United States). Materials Directorate)

1994-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Web Based Training (WEB BT) TES employees can get free training on applications within  

E-Print Network (OSTI)

Web Based Training (WEB BT) TES employees can get free training on applications within office applications and more. Each tutorial can last up to 4 hours. TES schedules training time, in the TES Office to scheduling. Registration Criteria · Training must not conflict with your current assignment. (We suggest

Tsien, Roger Y.

102

Epitaxial growth of metastable multiferroic AlFeO{sub 3} film on SrTiO{sub 3} (111) substrate  

SciTech Connect

GaFeO{sub 3}-type AlFeO{sub 3} is consisted of oxygen octahedra and tetrahedra containing Al and Fe ions and is known to have a non-centrosymmetric polar structure with space group Pna2{sub 1}. We tried to grow epitaxial GaFeO{sub 3}-type AlFeO{sub 3} films on SrTiO{sub 3} (111) substrates by pulsed laser deposition technique. Both the atomic arrangement of close-packed and the atomic distance of the substrate surface played important roles in stabilizing GaFeO{sub 3}-type AlFeO{sub 3} on the substrate. Piezoresponse force microscopy measurements clearly showed that GaFeO{sub 3}-type AlFeO{sub 3} films have ferroelectricity at room temperature. In addition, AlFeO{sub 3} film also showed pinched-like hysteresis loop with T{sub N}???317?K.

Hamasaki, Yosuke; Shimizu, Takao; Taniguchi, Hiroki; Taniyama, Tomoyasu; Yasui, Shintaro; Itoh, Mitsuru, E-mail: itoh.m.aa@m.titech.ac.jp [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259-J2-19 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan)

2014-02-24T23:59:59.000Z

103

Thermo-Mechanical Model Development and Validation of DirectedEnergy Deposition Additive Manufacturing of Ti-6Al-4V  

Science Journals Connector (OSTI)

Abstract A thermo-mechanical model of directed energy deposition additive manufacturing of Ti-6Al-4V is developed using measurements of the surface convection generated by gasses flowing during the deposition. In directed energy deposition, material is injected into a melt pool that is traversed to fill in a cross-section of a part, building it layer-by-layer. This creates large thermal gradients that generate plastic deformation and residual stresses. Finite element analysis (FEA) is often used to study these phenomena using simple assumptions of the surface convection. This work proposes that a detailed knowledge of the surface heat transfer is required to produce more accurate FEA results. The surface convection generated by the deposition process is measured and implemented in the thermo-mechanical model. Three depositions with different geometries and dwell times are used to validate the model using in situ measurements of the temperature and deflection as well as post-process measurements of the residual stress. An additional model is developed using the assumption of free convection on all surfaces. The results show that a measurement-based convection model is required to produce accurate simulation results.

J.C. Heigel; P. Michaleris; E.W. Reutzel

2014-01-01T23:59:59.000Z

104

Analysis of Wear Mechanisms in Low Friction, Nanocomposite AlMgB14-TiB2 Coatings  

SciTech Connect

Recent developments in coating science and technology offer new opportunities to enhance the energy-efficiency and performance of industrial machinery such as hydraulic fluid pumps and motors. The lubricated friction and wear characteristics of two wear-resistant coatings, diamond-like carbon and a nanocomposite material based on AlMgB{sub 14}-50 vol.% TiB{sub 2}, were compared in pin-on-disk tribotests using Mobil DTE-24{trademark} oil as the lubricant. In each case, the pins were fixed 9.53 mm diameter spheres of AISI 52100 steel, the load was 10 N, and the speed 0.5 m/s in all tests. Average steady-state friction coefficient values of 0.10 and 0.08 were measured for the DLC and nanocomposite, respectively. The coatings and their 52100 steel counterfaces were analyzed after the tests by X-ray photoelectron and Auger spectroscopy for evidence of material transfer or tribo-chemical reactions. The low-friction behavior of the boride nanocomposite coating is due to the formation of lubricative boric acid, B(OH){sub 3}. In contrast, the low-friction behavior of the DLC coating is related to the relatively low dielectric constant of the oil-based lubricant, leading to desorption of surface hydrogen from the coating.

Cook, Bruce A [Ames Laboratory; Harringa, J [Ames Laboratory; Anderegg, A [Ames Laboratory; Russell, A M [Iowa State University; Qu, Jun [ORNL; Blau, Peter Julian [ORNL; Higdon, Clifton [Eaton Corporation; Elmoursi, Alaa A [Eaton Corporation

2010-01-01T23:59:59.000Z

105

On the effect of deep-rolling and laser-peening on the stress-controlled low- and high-cycle fatigue behavior of Ti-6Al-4V at elevated temperatures up to 550?C  

E-Print Network (OSTI)

and near-?-titanium alloys, especially for fan bladebehavior of a titanium Ti-6Al-4V turbine fan blade alloy isfan blades and disks in aircraft jet propulsion engines are commonly made from titanium

Ritchie, IAltenberger, RKNalla, YSano LWagner, RO

2013-01-01T23:59:59.000Z

106

Observation of strontium segregation in LaAlO{sub 3}/SrTiO{sub 3} and NdGaO{sub 3}/SrTiO{sub 3} oxide heterostructures by X-ray photoemission spectroscopy  

SciTech Connect

LaAlO{sub 3} and NdGaO{sub 3} thin films of different thicknesses have been grown by pulsed laser deposition on TiO{sub 2}-terminated SrTiO{sub 3} single crystals and investigated by soft X-ray photoemission spectroscopy. The surface sensitivity of the measurements has been tuned by varying photon energy h? and emission angle ?. In contrast to the core levels of the other elements, the Sr 3d line shows an unexpected splitting for higher surface sensitivity, signaling the presence of a second strontium component. From our quantitative analysis we conclude that during the growth process Sr atoms diffuse away from the substrate and segregate at the surface of the heterostructure, possibly forming strontium oxide.

Treske, Uwe; Heming, Nadine; Knupfer, Martin; Büchner, Bernd; Koitzsch, Andreas, E-mail: a.koitzsch@ifw-dresden.de [Institute for Solid State Research, IFW-Dresden, P.O. Box 270116, DE-01171 Dresden (Germany); Di Gennaro, Emiliano; Scotti di Uccio, Umberto; Miletto Granozio, Fabio [CNR-SPIN and Dipartimento di Fisica, Complesso Universitario di Monte S. Angelo, Via Cintia, 80126 Naples (Italy); Krause, Stefan [Helmholtz-Zentrum Berlin, BESSY, Albert-Einstein-Str. 15, 12489 Berlin (Germany)

2014-01-01T23:59:59.000Z

107

AL  

E-Print Network (OSTI)

AL. EMERGENCY PREPAREDNESS SYLLABUS ATTACHMENT. EMERGENCY NOTIFICATION PROCEDURES are based on a simple concept - if you hear a.

108

Quantum oscillations and subband properties of the two-dimensional electron gas at the LaAlO{sub 3}/SrTiO{sub 3} interface  

SciTech Connect

We have performed high field magnetotransport measurements to investigate the interface electron gas in a high mobility SrTiO{sub 3}/SrCuO{sub 2}/LaAlO{sub 3}/SrTiO{sub 3} heterostructure. Shubnikov-de Haas oscillations reveal several 2D conduction subbands with carrier effective masses of 0.9m{sub e} and 2m{sub e}, quantum mobilities of order 2000 cm{sup 2}/V s, and band edges only a few millielectronvolts below the Fermi energy. Measurements in tilted magnetic fields confirm the 2D character of the electron gas, and show evidence of inter-subband scattering.

McCollam, A., E-mail: A.McCollam@science.ru.nl; Guduru, V. K.; Zeitler, U.; Maan, J. C. [High Field Magnet Laboratory and Institute for Molecules and Materials, Radboud University Nijmegen, 6525 ED Nijmegen (Netherlands); Wenderich, S.; Kruize, M. K.; Molegraaf, H. J. A.; Huijben, M.; Koster, G.; Blank, D. H. A.; Rijnders, G.; Brinkman, A.; Hilgenkamp, H. [Faculty of Science and Technology and MESA Institute for Nanotechnology, University of Twente, 7500 AE Enschede (Netherlands)

2014-02-01T23:59:59.000Z

109

Excellent Passivation and Low Reflectivity Al2O3/TiO2 Bilayer Coatings for n-Wafer Silicon Solar Cells: Preprint  

SciTech Connect

A bilayer coating of Al2O3 and TiO2 is used to simultaneously achieve excellent passivation and low reflectivity on p-type silicon. This coating is targeted for achieving high efficiency n-wafer Si solar cells, where both passivation and anti-reflection (AR) are needed at the front-side p-type emitter. It could also be valuable for front-side passivation and AR of rear-emitter and interdigitated back contact p-wafer cells. We achieve high minority carrier lifetimes {approx}1 ms, as well as a nearly 2% decrease in absolute reflectivity, as compared to a standard silicon nitride AR coating.

Lee, B. G.; Skarp, J.; Malinen, V.; Li, S.; Choi, S.; Branz, H. M.

2012-06-01T23:59:59.000Z

110

Hematite spherules at Meridiani: Results from MI, Mini-TES, W. M. Calvin,1  

E-Print Network (OSTI)

Hematite spherules at Meridiani: Results from MI, Mini-TES, and Pancam W. M. Calvin,1 J. D on observations of hematite-bearing spherules at Meridiani Planum made using the Microscopic Imager (MI), Mini seen in MI, both Pancam and Mini-TES indices are highly variable based on the local surface

Glotch, Timothy D.

111

Effects of Reduction Temperature and Metal-Support Interactions on the Catalytic Activity of Pt/g-Al2O3 and Pt/TiO2 for the Oxidation of CO in the Presence and Absence of H2.  

SciTech Connect

TiO2- and -Al2O3-supported Pt catalysts were characterized by HRTEM, XPS, EXAFS, and in situ FTIR spectroscopy after activation at various conditions, and their catalytic properties were examined for the oxidation of CO in the absence and presence of H2 (PROX). When {gamma}-Al{sub 2}O{sub 3} was used as the support, the catalytic, electronic, and structural properties of the Pt particles formed were not affected substantially by the pretreatment conditions. In contrast, the surface properties and catalytic activity of Pt/TiO2 were strongly influenced by the pretreatment conditions. In this case, an increase in the reduction temperature led to higher electron density on Pt, altering its chemisorptive properties, weakening the Pt-CO bonds, and increasing its activity for the oxidation of CO. The in situ FTIR data suggest that both the terminal and bridging CO species adsorbed on fully reduced Pt are active for this reaction. The high activity of Pt/TiO2 for the oxidation of CO can also be attributed to the ability of TiO2 to provide or stabilize highly reactive oxygen species at the metal-support interface. However, such species appear to be more reactive toward H{sub 2} than CO. Consequently, Pt/TiO{sub 2} shows substantially lower selectivities toward CO oxidation under PROX conditions than Pt/{gamma}-Al{sub 2}O{sub 3}.

Alexeev,O.; Chin, S.; Engelhard, M.; Ortiz-Soto, L.; Amiridis, M.

2005-01-01T23:59:59.000Z

112

Nano-scratch behavior of a bulk Zr-10Al-5Ti-17.9Cu-14.6Ni amorphous alloy  

SciTech Connect

The tribological behavior of a Zr-10Al-5Ti-17.9Cu-14.6Ni (at.%) bulk amorphous alloy, in both the as-cast and annealed states, was investigated using nano-scratch tests, including ramping load scratch and multiple sliding wear techniques. The crystallization sequence of the alloy was also characterized. Mechanical properties, such as Young's modulus, hardness, friction coefficient, and tribological wear were measured. These properties were found to vary with microstructure. In general, an increase in annealing temperature results in an increase in hardness, which in turn produces a decrease in friction coefficient but an increase in wear resistance. Samples having a structure consisting of supercooled liquid matrix with dispersed nanocrystalline particles exhibit the best wear performance. (c) 2000 Materials Research Society.

Wang, J. G. [Chemistry and Materials Science, Lawrence Livermore National Laboratory, P.O. Box 808, L-350, Livermore, California 94551-9900 (United States); Choi, B. W. [Chemistry and Materials Science, Lawrence Livermore National Laboratory, P.O. Box 808, L-350, Livermore, California 94551-9900 (United States); Nieh, T. G. [Chemistry and Materials Science, Lawrence Livermore National Laboratory, P.O. Box 808, L-350, Livermore, California 94551-9900 (United States); Liu, C. T. [Metals and Ceramics Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831-6376 (United States)

2000-04-01T23:59:59.000Z

113

Role of oxygen vacancies in magnetic properties of LaAlO{sub 3}/SrTiO{sub 3} interface  

SciTech Connect

The interface of two band-insulators SrTiO{sub 3} and LaAlO{sub 3} exhibits a highly conducting two-dimensional electron gas which shows low-temperature superconductivity, ferromagnetism and many other novel properties. Several studies reveal that the oxygen vacancies at the interface have strong influence on the electronic and magnetic properties of the interface electrons. Here, we develop an insight into the effects of oxygen vacancies on the magnetic properties of the system; the oxygen vacancies help in establishing ferromagnetism which competes with superconductivity at low temperatures. Simulated Monte-Carlo annealing suggests an ordering of the oxygen vacant sites and sheds light on the experimental observation of the quenching of magnetic moment on annealing. A possible explanation for the coexistence of superconductivity and ferromagnetism is also discussed.

Mohanta, N., E-mail: nmohanta@phy.iitkgp.ernet.in [Department of Physics and Meteorology, Indian Institute of Technology Kharagpur, West Bengal-721302 (India); Taraphder, A. [Department of Physics and Meteorology, Indian Institute of Technology Kharagpur, West Bengal-721302, India and Centre for Theoretical Studies, Indian Institute of Technology Kharagpur, West Bengal-721302 (India)

2014-04-24T23:59:59.000Z

114

Structure and Properties of Composite Electrospark, Laser, and Magnetron Deposited AlN ? TiB2 Coatings  

Science Journals Connector (OSTI)

A comparative investigation of the coatings produced by electrospark alloying, laser gas-powder deposition, and magnetron sputtering using composite AlN ?...2...material was carried out. It is shown that the pres...

Irina A. Podchernyaeva

2001-09-01T23:59:59.000Z

115

Effect of the strain-induced melt activation (SIMA) process on the tensile properties of a new developed super high strength aluminum alloy modified by Al-5Ti-1B grain refiner  

SciTech Connect

In this study, the effect of Al-5Ti-1B grain refiners and modified strain-induced melt activation process on an Al-Zn-Mg-Cu alloy was studied. The optimum level of Ti was found to be 0.1 wt.%. The specimens subjected to deformation ratio of 40% (at 300 Degree-Sign C) and various heat treatment times (10-40 min) and temperature (550-600 Degree-Sign C) regimes were characterized in this study. Reheating condition to obtain a fine globular microstructure was optimized. Microstructural examinations were conducted by optical and scanning electron microscopy coupled with an energy dispersive spectrometry. The optimum temperature and time in strain-induced melt activation process are 575 Degree-Sign C and 20 min, respectively. T6 heat treatment including quenching to room temperature and aging at 120 Degree-Sign C for 24 h was employed to reach to the maximum strength. Significant improvements in mechanical properties were obtained with the addition of grain refiner combined with T6 heat treatment. After the T6 heat treatment, the average tensile strength increased from 283 MPa to 587 and 332 MPa to 617 for samples refined with 2 wt.% Al-5Ti-1B before and after strain-induced melt activation process and extrusion process, respectively. Ultimate strength of Ti-refined specimens without SIMA process has a lower value than globular microstructure specimens after SIMA and extrusion process. - Highlights: Black-Right-Pointing-Pointer The effect of Al-5Ti-1B on the aluminum alloy produced by SIMA process was studied. Black-Right-Pointing-Pointer Al-5Ti-1B is an effective in reducing the grain and reagent fine microstructure. Black-Right-Pointing-Pointer Reheating condition to obtain a fine globular microstructure was optimized. Black-Right-Pointing-Pointer The optimum temperature and time in SIMA process are 575 Degree-Sign C and 20 min respectively. Black-Right-Pointing-Pointer UTS of globular structure specimens have a more value than Ti-refined specimens.

Haghparast, Amin [School of Mechanical Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)] [School of Mechanical Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Nourimotlagh, Masoud [Young Researchers Club, Dareshahr Branch, Islamic Azad university (Iran, Islamic Republic of)] [Young Researchers Club, Dareshahr Branch, Islamic Azad university (Iran, Islamic Republic of); Alipour, Mohammad, E-mail: Alipourmo@ut.ac.ir [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)] [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

2012-09-15T23:59:59.000Z

116

U.S. CHP Installations Incorporating Thermal Energy Storage (TES) and/or Turbine Inlet Cooling (TIC), September 2003  

Energy.gov (U.S. Department of Energy (DOE))

Chart of Database of U.S. CHP Installations Incorporating Thermal Energy Storage (TES) and/or Turbine Inlet Cooling (TIC)

117

Tensile properties and strain rate sensitivity of Ti-47Al-2Cr-0.2Si sheet material with different microstructures  

SciTech Connect

New materials based on gamma titanium aluminides (gamma alloys) have emerged as potential candidates for high temperature applications such as aerospace structural components (e.g., airframes, turbine components, thermal protection systems) and automotive parts (e.g., exhaust valves, turbocharger rotors). Because of their low density, high Young`s modulus, high-temperature strength retention, good oxidation and burn resistance, the so-called second generation gamma alloys are able to exceed the application temperature of advanced titanium alloys and also to replace nickel- and iron-based superalloys up to 800C. However, poor formability and low room temperature (RT) ductility resulting in low fracture toughness have limited possible applications. The present paper deals with the dependence of tensile properties of Ti-47Al-2Cr-0.2Si (composition in atomic-%) sheet material on microstructure and test conditions. Four different microstructures, i.e., fine-grained primary annealed (PA), near gamma (NG), duplex (DU) as well as coarse-grained fully lamellar (FL) have been investigated with emphasis on the influence of grain size, phase distribution, and strain rate on tensile properties at 700 C. Fractography was conducted by scanning electron microscopy (SEM) to examine the influence of temperature on the fracture behavior and to determine the onset of dynamic recrystallization effects.

Clemens, H. [Plansee AG, Reutte (Austria)] [Plansee AG, Reutte (Austria); Glatz, W. [Montanuniversitaet, Leoben (Austria). Inst. fuer Metallkunde und Werkstoffpruefung] [Montanuniversitaet, Leoben (Austria). Inst. fuer Metallkunde und Werkstoffpruefung; Appel, F. [GKSS Research Centre, Geesthacht (Germany). Inst. for Materials Research] [GKSS Research Centre, Geesthacht (Germany). Inst. for Materials Research

1996-08-01T23:59:59.000Z

118

EFFECTS OF ION IRRADIATION ON Zr52.5Cu17.9Ni14.6Al10Ti5 (BAM-11) BULK METALLIC GLASS  

SciTech Connect

Bulk metallic glasses are intriguing candidates for nuclear applications due to their inherent amorphous structure, but their radiation response is largely unknown due to the relatively recent nature of innovations in bulk metallic glass fabrication. Here, microstructural and mechanical property evaluations have been performed on a Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glass (BAM-11) irradiated with 3 MeV Ni+ ions to 0.1 and 1.0 dpa at room temperature and 200 C. Nanoindentation hardness and Young s modulus both decreased by 6 to 20% in samples irradiated at room temperature, with the sample irradiated to 1.0 dpa experiencing the greatest change in mechanical properties. However, no significant changes in properties were observed in the samples irradiated at 200 C, and transmission electron microscopy showed no visible evidence of radiation damage or crystallization following ion irradiation at any of the tested conditions. These results suggest that BAM-11 bulk metallic glass may be useful for certain applications in nuclear environments.

Perez-Bergquist, Alex G [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Leonard, Keith J [ORNL] [ORNL; Zhang, Yanwen [ORNL] [ORNL; Zinkle, Steven J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

119

FTIR study of hydrogen and carbon monoxide adsorption on Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3}  

SciTech Connect

The Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} catalysts submitted to low-temperature reduction (LTR,200 C) and high-temperature reduction (HTR, 500 C) and exposed to hydrogen and carbon monoxide at room temperature were studied by infrared spectroscopy. There is a strong loss of transmission in the entire infrared spectra on Pt/TiO{sub 2} after its exposure to hydrogen, which is related to the reducibility of the support. A typical SMSI behavior (strong metal-support interaction), such as the decrease in carbon monoxide adsorption capacity, was detected on Pt/TiO{sub 2} and Pt/ZrO{sub 2} after exposure to hydrogen, even for the catalysts submitted to LTR treatment. Also a carbonyl band shift to lower wavenumber was observed on LTR-treated Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} after exposure to hydrogen. The authors interpreted this SMSI behavior as an electronic rather than morphological effect, which was induced by the presence of hydrogen spillover.

Benvenutti, E.V.; Franken, L.; Moro, C.C.; Davanzo, C.U.

1999-11-09T23:59:59.000Z

120

Fabrication and crystal line patterning of Li{sub 1.3}Al{sub 0.3}Ti{sub 1.7}(PO{sub 4}){sub 3} ion conductive glass by Ni atom heat processing method  

SciTech Connect

Li{sub 1.3}Al{sub 0.3}Ti{sub 1.7}(PO{sub 4}){sub 3} conductive crystal lines composed of closely compacted fine particles were patterned on the surface of 13.9Li{sub 2}O-8.9Al{sub 2}O{sub 3}-37.6TiO{sub 2}-38.6P{sub 2}O{sub 5}-1NiO (mol %) precursor glass by a continuous wave Yb fiber laser irradiation ({lambda}=1078 nm) using the nickel atom heat processing method. Homogeneous and smooth crystal lines with a uniform width of 30 {mu}m were obtained with a laser power of 1.3 W. The Li{sup +} ion conductivity of the laser patterned glass was about two orders of magnitude higher than that of the glass matrix due to the formation of Li{sub 1.3}Al{sub 0.3}Ti{sub 1.7}(PO{sub 4}){sub 3} conductive crystalline phase by Yb fiber laser irradiation.

Pang, Maolin; Suzuki, Ryota; Saito, Makoto; Machida, Ken-ichi; Hanzawa, Hiromasa; Nojiri, Yoshihiro; Tanase, Shigeo [Center for Advanced Science and Innovation, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan); Graduate School of Engineering Science, Osaka Univeristy, 1-3 Machikaneyama-cho, Toyonaka, Osaka 560-8531 (Japan); Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST), Kansai Center, 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577 (Japan)

2008-01-28T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Reducing Energy Costs And Minimizing Capital Requirements: Case Studies of Thermal Energy Storage (TES)  

E-Print Network (OSTI)

, and thus during those times when power has its highest cost or value. Thermal Energy Storage (TES) provides a means of de-coupling the generation of cooling from the provision of cooling to the peak cooling loads. In this manner, peak power demand...

Andrepont, J. S.

2007-01-01T23:59:59.000Z

122

Satellite observations of Mexico City pollution outflow from the Tropospheric Emissions Spectrometer (TES)  

E-Print Network (OSTI)

Satellite observations of Mexico City pollution outflow from the Tropospheric Emissions/INTEX-B aircraft campaigns in March 2006 aimed to investigate the emissions, transport, and physiochemical trans 12 November 2008 Keyword: Mega-city pollution TES O3­CO correlation INTEX-B Mexico city a b s t r a c

123

Model-Inspired Research. TES research uses modeling, prediction, and synthesis to identify  

E-Print Network (OSTI)

in Earth system models (ESMs). TES supports research to advance fundamental understanding of terrestrial-process models, ecosystem models, and the Community Earth System Model). This emphasis on the capture of advanced in Earth system models to increase the quality of climate model projections and to provide the scientific

124

Multiplexed readout demonstration of a TES-based detector array in a resistance locked loop  

E-Print Network (OSTI)

TES-based bolometer and microcalorimeter arrays with thousands of pixels are under development for several space-based and ground-based applications. A linear detector response and low levels of cross talk facilitate the calibration of the instruments. In an effort to improve the properties of TES-based detectors, fixing the TES resistance in a resistance-locked loop (RLL) under optical loading has recently been proposed. Earlier theoretical work on this mode of operation has shown that the detector speed, linearity and dynamic range should improve with respect to voltage biased operation. This paper presents an experimental demonstration of multiplexed readout in this mode of operation in a TES-based detector array with noise equivalent power values (NEP) of $3.5\\cdot 10^{-19} $W/$\\sqrt{\\mathrm{Hz}}$. The measured noise and dynamic properties of the detector in the RLL will be compared with the earlier modelling work. Furthermore, the practical implementation routes for future FDM systems for the readout of ...

van der Kuur, Jan; Kiviranta, Mikko; Akamatsu, Hiroki; Khosropanah, Pourya; Hartog, Roland den; Suzuki, Toyoaki; Jackson, Brian

2015-01-01T23:59:59.000Z

125

Domestic demand-side management (DSM): Role of heat pumps and thermal energy storage (TES) systems  

Science Journals Connector (OSTI)

Heat pumps are seen as a promising technology for load management in the built environment, in combination with the smart grid concept. They can be coupled with thermal energy storage (TES) systems to shift electrical loads from high-peak to off-peak hours, thus serving as a powerful tool in demand-side management (DSM). This paper analyzes heat pumps with radiators or underfloor heating distribution systems coupled with TES with a view to showing how a heat pump system behaves and how it influences the building occupants' thermal comfort under a DSM strategy designed to flatten the shape of the electricity load curve by switching off the heat pump during peak hours (16:00–19:00). The reference scenario for the analysis was Northern Ireland (UK). The results showed that the heat pump is a good tool for the purposes of DSM, also thanks to the use of TES systems, in particular with heating distribution systems that have a low thermal inertia, e.g. radiators. It proved possible to achieve a good control of the indoor temperature, even if the heat pump was turned off for 3 h, and to reduce the electricity bill if a “time of use” tariff structure was adopted.

A. Arteconi; N.J. Hewitt; F. Polonara

2013-01-01T23:59:59.000Z

126

PRODUCTION OF {sup 26}Al, {sup 44}Ti, AND {sup 60}Fe IN CORE-COLLAPSE SUPERNOVAE: SENSITIVITY TO THE RATES OF THE TRIPLE ALPHA AND {sup 12}C({alpha}, {gamma}){sup 16}O REACTIONS  

SciTech Connect

We have studied the sensitivity to variations in the triple alpha and {sup 12}C({alpha}, {gamma}){sup 16}O reaction rates of the production of {sup 26}Al, {sup 44}Ti, and {sup 60}Fe in core-collapse supernovae (SNe). We used the KEPLER code to model the evolution of 15 M {sub sun}, 20 M {sub sun}, and 25 M {sub sun} stars to the onset of core collapse and simulated the ensuing SN explosion using a piston model for the explosion and an explosion energy of 1.2 x 10{sup 51} erg. Calculations were performed for the Anders and Grevesse and Lodders abundances. Over a range of twice the experimental uncertainty, {sigma}, for each helium-burning rate, the production of {sup 26}Al, {sup 60}Fe, and their ratio vary by factors of 5 or more. For some species, similar variations were observed for much smaller rate changes, 0.5{sigma} or less. The production of {sup 44}Ti was less sensitive to changes in the helium-burning rates. Production of all three isotopes depended on the solar abundance set used for the initial stellar composition.

Tur, Clarisse; Austin, Sam M. [National Superconducting Cyclotron Laboratory, Michigan State University, 1 Cyclotron Laboratory, East Lansing, MI 48824-1321 (United States); Heger, Alexander, E-mail: tur@nscl.msu.ed, E-mail: austin@nscl.msu.ed, E-mail: alex@physics.umn.ed [School of Physics and Astronomy, University of Minnesota, Twin Cities, Minneapolis, MN 55455-0149 (United States)

2010-07-20T23:59:59.000Z

127

Phase Relations and Elemental Distribution Among Co-Existing Phases in the Ceramics of the Pseudobinary System CaZrTi{sub 2}O{sub 7}-LnAlO{sub 3} (Ln= Nd, Sm)  

SciTech Connect

In the ceramics in series (1-x) CaZrTi{sub 2}O{sub 7} - x NdAlO{sub 3} and (1-x) CaZrTi{sub 2}O{sub 7} - x SmAlO{sub 3} (x = 0.25, 0.5 and 0.75) produced by cold pressing and sintering at 1400, 1450 and 1500 deg. C zirconolite was found to be a major phase, perovskite was an extra phase and traces of residual baddeleyite occurred. At x = 0.75 the perovskite was major phase and zirconolite and cubic oxide of fianite or tazheranite type were extra phases. Major Nd and Sm host phase at x = 0.25 was found to be zirconolite (about 65% of total Nd{sub 2}O{sub 3} and 74% of total Sm{sub 2}O{sub 3}). With the x value increasing perovskite becomes major host phase for Nd and Sm accumulating of up to about 92% of total Nd and about 72% of total Sm. As follows from SEM/EDS data Nd and Sm contents in the zirconolite may reach {approx}1 formula unit (fu). (authors)

Mikhailenko, Natalia [SIA Radon, Moscow, 119121 (Russian Federation); Stefanovsky, Sergey [Center of Advanced Technologies, SIA Radon, 7th Rostovskii lane 2/14, Moscow, 119121 (Russian Federation); Ochkin, Alexander [D. Mendeleev University of Chemical Technology, Moscow (Russian Federation)

2007-07-01T23:59:59.000Z

128

Hai un'idea di impresa? La Regione Veneto ti aiuta a realizzarla La Direzione Lavoro della Regione Veneto partecipa al progetto I. E. SMART -Smart Training  

E-Print Network (OSTI)

Veneto partecipa al progetto I. E. SMART - Smart Training Network for Innovation and Entrepreneurship Competition è un concorso di idee che si svolge in più fasi: dal 1° agosto al 30 ottobre 2013 si raccolgono le idee presentate tramite il formulario on line che trovi collegandoti al seguente link: http

Romeo, Alessandro

129

Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95 (Cb (Nb) + Ta) - 2.5Ti - 0.70Al - 7.0Fe Consumable Electrode, Remelted or Vacuum Induction Melted, Solution Heat Treated, Precipitation-Hardenable  

E-Print Network (OSTI)

Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95 (Cb (Nb) + Ta) - 2.5Ti - 0.70Al - 7.0Fe Consumable Electrode, Remelted or Vacuum Induction Melted, Solution Heat Treated, Precipitation-Hardenable

SAE Aerospace Standards. London

2012-01-01T23:59:59.000Z

130

Microstructure and mechanical properties of Ni-based composite coatings reinforced by in situ synthesized TiB2 + TiC by laser cladding  

Science Journals Connector (OSTI)

A Ni-based composite coating reinforced by in situ synthesized TiB2...and TiC particles was fabricated on Ti6Al4V by laser cladding. An attempt was made to correlate the...2, flower-like or equiaxial TiC, and fin...

Jun Li; Xuan-jun Zhang; Hui-ping Wang…

2013-01-01T23:59:59.000Z

131

SIGNATURE OF THIS MEMORAND TES A RECORD OF THIS DECISION. NEPA Compliance Officer Signature:  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

MEMORAND MEMORAND TES A RECORD OF THIS DECISION. NEPA Compliance Officer Signature: EPA Compliance Officer Date: (93 Page 1 of 2 INIC*EF2a U.S. DEPARTI\ LENT OF ENERGY F.ERE PROJECT MANAGEMENT CENTER NFPA DETERI\ 11-NATION RECIPIENT:Tennessee Tech University STATE: TN PROJECT TITLE : Recovery Act: Multi-level Energy Storage and Controls for Large-scale Wind Energy Integration Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CID Number DE-PS36-09G099009 DE-EE0001 383 GF0-10-010 0 Based on my review of the information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.IA), I have made the following determination: CX, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering (including, but not limited to, literature surveys, inventories, audits), data analysis (including

132

Mechanism and kinetics of carbide dissolution in near alpha Ti-5.6Al-4.8Sn-2Zr-1Mo-0.35Si-0.7Nd titanium alloy  

SciTech Connect

The present work evaluates the influence of bulk carbon content and aging temperature on the stability of carbide in near alpha Ti-5.6Al-4.8Sn-2Zr-1Mo-0.35Si-0.7Nd titanium alloy. The carbide particles were formed during heat treatment in the {beta} phase field and preserved by water quenching. Subsequent aging treatments at 750-850 Degree-Sign C caused partial dissolution of these precipitates, as a result of the peritectoid reaction between the {beta} phase and carbide. The models based on interface reaction controlled dissolution, via uniform atomic detachment, dislocation mechanism or vacancy flow, yielded experimental predictions comparable to the observed dissolution kinetics. Furnace cooling after heat treatment in the {beta} phase field dissolved carbide particles completely, and the microstructure changed from acicular-like or block {alpha} to equiaxed {alpha} with increase of carbon content. - Highlights: Black-Right-Pointing-Pointer Carbide dissolution occurs at precipitate/matrix interfaces, forming {beta}-depleted zone. Black-Right-Pointing-Pointer Peritectoid reaction is responsible for drastic reduction of carbide volume fraction. Black-Right-Pointing-Pointer Slower dissolution rate is accounted by dislocation, vacancy flow, and curvature. Black-Right-Pointing-Pointer Lamellar changed to equiaxed {alpha} with increasing carbon from {beta} furnace cooling.

Zhang, S.Z., E-mail: szzhangyt@163.com [School of Environmental and Materials Engineering, Yantai University, 32 Qingquan Road, Yantai 264005 (China); Li, M.M. [School of Environmental and Materials Engineering, Yantai University, 32 Qingquan Road, Yantai 264005 (China); Yang, R. [Titanium Alloy Laboratory, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China)

2011-12-15T23:59:59.000Z

133

Additively manufactured 3D porous Ti-6Al-4V constructs mimic trabecular bone structure and regulate osteoblast proliferation, differentiation and local factor production in a porosity and surface roughness dependent manner  

Science Journals Connector (OSTI)

Additive manufacturing by laser sintering is able to produce high resolution metal constructs for orthopedic and dental implants. In this study, we used a human trabecular bone template to design and manufacture Ti-6Al-4V constructs with varying porosity via laser sintering. Characterization of constructs revealed interconnected porosities ranging from 15–70% with compressive moduli of 2579–3693 MPa. These constructs with macro porosity were further surface-treated to create a desirable multi-scale micro-/nano-roughness, which has been shown to enhance the osseointegration process. Osteoblasts (MG63 cells) exhibited high viability when grown on the constructs. Proliferation (DNA) and alkaline phosphatase specific activity, an early differentiation marker, decreased as porosity increased, while osteocalcin, a late differentiation marker, as well as osteoprotegerin, vascular endothelial growth factor and bone morphogenetic proteins 2 and 4 increased with increasing porosity. Three-dimensional (3D) constructs with the highest porosity and surface modification supported the greatest osteoblast differentiation and local factor production. These results indicate that additively manufactured 3D porous constructs mimicking human trabecular bone and produced with additional surface treatment can be customized for increased osteoblast response. Increased factors for osteoblast maturation and differentiation on high porosity constructs suggest the enhanced performance of these surfaces for increasing osseointegration in vivo.

Alice Cheng; Aiza Humayun; David J Cohen; Barbara D Boyan; Zvi Schwartz

2014-01-01T23:59:59.000Z

134

THE NRC HAS ISSUED Ati ACTION PLAN FOR CLEANUP OF 46 SfTES that;;ece  

Office of Legacy Management (LM)

NRC HAS ISSUED Ati ACTION PLAN FOR CLEANUP OF 46 SfTES that;;ece NRC HAS ISSUED Ati ACTION PLAN FOR CLEANUP OF 46 SfTES that;;ece :: ~,: : ..,.... ..,:y... included in the agency' s Site Decommissioning Managem&t Pian (SDMP) in.1990. The ., ,.;' -,; ;.L..z,. sites are all radioactive materials handling facilities in various stages of decommission- ~' ... ,' . .-_.... ..,: ,,~ ..,. -c : -: ing; some of them are slill under active Nuclear Regulatory Commission licenses,~some .~. . . . . . ...i.~ ,;::,: ' :-&-:' . -1.: : ;: _ :: .,,. >.r"!.-<,z...;::.~ ? ~' .._ .' l...' -i:i -::;.. c : of them were under licenses that are now terminated, and some were never licensed~, ,~: ,.~. ~~.. .,_. .i ' . In the Action Plan, which was published in the April 16 Federal Register, the NRC says' ;; *_: ._.:, :-.~:i:r~'

135

Structure, magnetic properties and magnetoelastic anisotropy in epitaxial Sr(Ti???Co?)O? films  

E-Print Network (OSTI)

We report the structure, magnetic properties and magnetoelastic anisotropy of epitaxial Sr(Ti???Co?)O? films grown on LaAlO? (001) and SrTiO? (001) substrates by pulsed laser deposition. Room temperature ferromagnetism was ...

Bi, Lei

136

Ti Plasmid  

NLE Websites -- All DOE Office Websites (Extended Search)

Ti Plasmid Ti Plasmid Name: Dixenia Location: N/A Country: N/A Date: N/A Question: What can you tell me about the Ti Plasmid? Replies: This plasmid is named for a plasmid found in a bacteria called Agrobacter tumefaciens. It causes "plant cancer" or what are known as galls. They are little tumors in which the bacteria can grow and live in the plant. Ti stands for tumor inducing. The bacterium gets into the plant through some kind of wound, ie. a scratch. It injects its plasmid into a plant cell and the plasmid inserts its DNA into the plant's DNA. Then the DNA directs the plant to make a hollow tumor where the bacteria can live. Scientists have taken advantage of this plant's ability to insert foreign DNA into a plant. They take the genes out of the plasmid that cause galls, and insert genes of interest, ie. genes for pest resistance and let the plasmid carry those genes into the plant. The plant will start making the product you want. You may have seen a picture of a tobacco plant glowing because firefly genes for glowing were inserted into the plant. They did this so they could know if the gene had made it into the plant. Once they are sure the gene they want has made it into the plant, they clone the plant cells. By the way, plant tissue culture is a procedure that is very common and has been done for years, this is not the same as cloning animals.

137

Prediction of flow stress in a wide temperature range involving phase transformation for as-cast Ti–6Al–2Zr–1Mo–1V alloy by artificial neural network  

Science Journals Connector (OSTI)

The isothermal compressions of as-cast Ti–6Al–2Zr–1Mo–1V titanium alloy in a wide temperature range of 1073–1323 K and strain rate range of 0.01–10 s?1 with a reduction of 60% were conducted on a Gleeble-1500 thermo-mechanical simulator. The flow stress shows a complex non-linear intrinsic relationship with strain, strain rate and temperature, meanwhile the strain-softening behavior articulates dynamic recrystallization mechanism in ? phase, dynamic recovery mechanism in ? phase and their comprehensive function during phase transformation (? + ?). Based on the experimental data, an artificial neural network (ANN) was trained with standard back-propagation learning algorithm to generalize the complex deformation behavior characteristics. In the present ANN model, strain and temperature were taken as inputs, and flow stress as output. A comparative study has been made on ANN model and improved Arrhenius-type constitutive model, and their predictability has been evaluated in terms of correlation coefficient (R) and average absolute relative error (ARRE). During ?, ? + ? and ? phase regime, R-value and ARRE-value for the improved Arrhenius-type model are 0.9824% and 6.02%, 0.9644% and 21.02%, and 0.9627% and 12.38%, respectively, while the R-value and ARRE-value for the ANN model are 0.9992% and 0.91%, 0.9996% and 1.47%, and 0.9975% and 2.17%, respectively. The predicted strain–stress curves outside of experimental conditions articulate the similar intrinsic relationships with experimental strain–stress curves. The results show that the feed-forward back-propagation ANN model can accurately tracks the experimental data in a wide temperature range and strain rate range associated with interconnecting metallurgical phenomena, and in further it has a good capacity to model complex hot deformation behavior of titanium alloy outside of experimental conditions.

Guo-zheng Quan; Wen-quan Lv; Yuan-ping Mao; Yan-wei Zhang; Jie Zhou

2013-01-01T23:59:59.000Z

138

Exploration of R2XM2 (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge): Structural Motifs, the novel Compound Gd2AlGe2 and Analysis of the U3Si2 and Zr3Al2 Structure Types  

SciTech Connect

In the process of exploring and understanding the influence of crystal structure on the system of compounds with the composition Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} several new compounds were synthesized with different crystal structures, but similar structural features. In Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, the main feature of interest is the magnetocaloric effect (MCE), which allows the material to be useful in magnetic refrigeration applications. The MCE is based on the magnetic interactions of the Gd atoms in the crystal structure, which varies with x (the amount of Si in the compound). The crystal structure of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} can be thought of as being formed from two 3{sup 2}434 nets of Gd atoms, with additional Gd atoms in the cubic voids and Si/Ge atoms in the trigonal prismatic voids. Attempts were made to substitute nonmagnetic atoms for magnetic Gd using In, Mg and Al. Gd{sub 2}MgGe{sub 2} and Gd{sub 2}InGe{sub 2} both possess the same 3{sup 2}434 nets of Gd atoms as Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, but these nets are connected differently, forming the Mo{sub 2}FeB{sub 2} crystal structure. A search of the literature revealed that compounds with the composition R{sub 2}XM{sub 2} (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge) crystallize in one of four crystal structures: the Mo{sub 2}FeB{sub 2}, Zr{sub 3}Al{sub 2}, Mn{sub 2}AlB{sub 2} and W{sub 2}CoB{sub 2} crystal structures. These crystal structures are described, and the relationships between them are highlighted. Gd{sub 2}AlGe{sub 2} forms an entirely new crystal structure, and the details of its synthesis and characterization are given. Electronic structure calculations are performed to understand the nature of bonding in this compound and how electrons can be accounted for. A series of electronic structure calculations were performed on models with the U{sub 3}Si{sub 2} and Zr{sub 3}Al{sub 2} structures, using Zr and A1 as the building blocks. The starting point for these models was the U{sub 3}Si{sub 2} structure, and models were created to simulate the transition from the idealized U{sub 3}Si{sub 2} structure to the distorted Zr{sub 3}Al{sub 2} structure. Analysis of the band structures of the models has shown that the transition from the U{sub 3}Si{sub 2} structure to the Zr{sub 3}Al{sub 2} structure lifts degeneracies along the {Lambda} {yields} Z direction, indicating a Peierls-type mechanism for the displacement occurring in the positions of the Zr atoms.

Sean William McWhorter

2006-05-01T23:59:59.000Z

139

Experimental Results and Modeling of Low-Heat-Capacity TES Microcalorimeters for Soft-X-ray Spectroscopy  

SciTech Connect

Transition-edge-sensor (TES) X-ray microcalorimeters have mostly been targeted at mid-band energies from 0.05-10 keV and high energies to above 100 keV. However, many other optimizations are possible. Here we present results from devices optimized for soft X-ray applications. For spectroscopy below 1 keV, the X-ray stopping power and heat capacity (C) of the TES itself are high enough that we can omit a separate absorber. The resulting devices have low C and the best-achievable energy resolution should be under 1 eV. We are interested in pursuing such devices primarily for astrophysical applications and laboratory astrophysics at LLNL's Electron-Beam Ion Trap. To this end, we have studied arrays in which 'bare' TESs are interspersed with broad-band pixels that have absorbers. By extending the absorbers to cover the area where the leads contact the low-energy pixels, we have eliminated a significant source of non-Gaussian detector response. The bare devices are in a different regime from our typical devices in that C is ten times lower and the conductance to the bath is four times lower. We have explored this regime through simultaneous fitting of noise and impedance data. These data cannot be fit by the simple model we employ to describe our typical broad-band devices. In this contribution we present X-ray spectra and the results from modeling.

Eckart, Megan E. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); NASA Postdoctoral Program Fellow (United States); Adams, Joseph S.; Smith, Stephen J. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); CRESST and University of Maryland, Baltimore County, MD 21250 (United States); Bandler, Simon R. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); CRESST and University of Maryland, College Park, MD 20742 (United States); Brekosky, Regis P.; Chervenak, James A.; Finkbeiner, Fred M.; Kelley, Richard L.; Kilbourne, Caroline A.; Scott Porter, F.; Sadleir, John E. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2009-12-16T23:59:59.000Z

140

Instability, intermixing and electronic structure at theepitaxialLaAl...  

NLE Websites -- All DOE Office Websites (Extended Search)

intermixing and electronic structure at the epitaxialLaAlO3SrTiO3(001) heterojunction. Instability, intermixing and electronic structure at the epitaxialLaAlO3...

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

ALS superbend magnet system  

SciTech Connect

The Lawrence Berkeley National Laboratory is preparing to upgrade the Advanced Light Source (ALS) with three superconducting dipoles (Superbends). In this paper we present the final magnet system design which incorporates R&D test results and addresses the ALS operational concerns of alignment, availability, and economy. The design incorporates conduction-cooled Nb-Ti windings and HTS current leads, epoxy-glass suspension straps, and a Gifford-McMahon cryocooler to supply steady state refrigeration. We also present the current status of fabrication and testing.

Zbasnik, J.; Wang, S.T.; Chen, J.Y.; DeVries, G.J.; DeMarco, R.; Fahmie, M.; Geyer, A.; Green, M.A.; Harkins, J.; Henderson, T.; Hinkson, J.; Hoyer, E.H.; Krupnick, J.; Marks, S.; Ottens, F.; Paterson, J.A.; Pipersky, P.; Portmann, G.; Robin, D.A.; Schlueter, R.D.; Steier, C.; Taylor, C.E.; Wahrer, R.

2000-09-15T23:59:59.000Z

142

Deformation mechanisms in TiAl/Ti{sub 3}Al structures  

SciTech Connect

The deformation behavior of two-phase titanium aluminide alloys with different microstructures has been investigated in a wide temperature range using deformation tests and electron microscope observations. The structure of lamellar interfaces was characterized with respect to their role as dislocation sources. Thermally activated processes governing the dislocation mobility were characterized in terms of activation volumes and activation energies. The analysis is aimed at the identification of the dislocation processes operating under deformation conditions which are relevant for practical applications.

Appel, F.; Wagner, R. [GKSS Research Center, Geesthacht (Germany). Inst. for Materials Research

1995-12-31T23:59:59.000Z

143

Phase equilibria, formation, crystal and electronic structure of ternary compounds in Ti-Ni-Sn and Ti-Ni-Sb ternary systems  

SciTech Connect

The phase equilibria of the Ti-Ni-Sn and Ti-Ni-Sb ternary systems have been studied in the whole concentration range by means of X-ray and EPM analyses at 1073 K and 873 K, respectively. Four ternary intermetallic compounds TiNiSn (MgAgAs-type), TiNi{sub 2-x}Sn (MnCu{sub 2}Al-type), Ti{sub 2}Ni{sub 2}Sn (U{sub 2}Pt{sub 2}Sn-type), and Ti{sub 5}NiSn{sub 3} (Hf{sub 5}CuSn{sub 3}-type) are formed in Ti-Ni-Sn system at 1073 K. The TiNi{sub 2}Sn stannide is characterized by homogeneity in the range of 50-47 at% of Ni. The Ti-Ni-Sb ternary system at 873 K is characterized by formation of three ternary intermetallic compounds, Ti{sub 0.8}NiSb (MgAgAs-type), Ti{sub 5}Ni{sub 0.45}Sb{sub 2.55} (W{sub 5}Si{sub 3}-type), and Ti{sub 5}NiSb{sub 3} (Hf{sub 5}CuSn{sub 3}-type). The solubility of Ni in Ti{sub 0.8}NiSb decreases number of vacancies in Ti site up to Ti{sub 0.91}Ni{sub 1.1}Sb composition. - Graphical abstract: Isothermal section of the Ti-Ni-Sn phase diagram and DOS distribution in hypothetical TiNi{sub 1+x}Sn solid solution. Highlights: Black-Right-Pointing-Pointer Ti-Ni-Sn phase diagram was constructed at 1073 K. Black-Right-Pointing-Pointer Four ternary compounds are formed: TiNiSn, TiNi{sub 2-x}Sn, Ti{sub 2}Ni{sub 2}Sn, and Ti{sub 5}NiSn{sub 3}. Black-Right-Pointing-Pointer Three ternary compounds exist in Ti-Ni-Sb system at 873 K. Black-Right-Pointing-Pointer The TiNi{sub 2}Sb compound is absent.

Romaka, V.V., E-mail: romakav@yahoo.com [Department of Materials Engineering and Applied Physics, Lviv Polytechnic National University, Ustyyanovycha Str. 5, 79013 Lviv (Ukraine); Rogl, P. [Institut fur Physikalische Chemie der Universitat Wien, Wahringerstrabe 42, A-1090 Wien (Austria); Romaka, L.; Stadnyk, Yu. [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya Str. 6, 79005 Lviv (Ukraine); Melnychenko, N.; Grytsiv, A.; Falmbigl, M. [Institut fur Physikalische Chemie der Universitat Wien, Wahringerstrabe 42, A-1090 Wien (Austria); Skryabina, N. [Perm State University, Bukireva Str. 15, 614990 Perm (Russian Federation)

2013-01-15T23:59:59.000Z

144

Darlington AL O'Reillys AL  

E-Print Network (OSTI)

CanungraCk Darlington AL Darlington Coom era R O'Reillys AL Beechmont AL Binna Burra AL BackCk Tyungun AL Numinbah Valley AL NerangR Natural Bridge Numinbah AL Little Nerang Dam AL Albert R Bromfleet AL Benobble AL Wolffdene AL Luscombe AL Wongawallan AL Mt Tamborine Canungra Pimpama R Laheys Lookout

Greenslade, Diana

145

O Ti-tE LOVE  

Office of Legacy Management (LM)

' ItqQtJulRl' IICt' O Ti-tE LOVE ~t?Al. . . At2D Al.CLkTED IChTTEtt~ . ' . . . : . ' . i I . . . . .mr TttE HOt\' ORAULE~ STANLEY FItZl:; SFCAKER ' . : ,J WE\J i' ORti STATE ASSH' rtrLY l r . . isay 29,.1980 Consultant to the Kew York ' , .' .I, " ..' . ,"' ! -. . . : . . . I.. . . . . ~. ,:- 9.. :. .' , * Ill . ,.. , ,i / All . ' %: : . : . . -. ;:. * :... . _ -. .' . . . I . ' J n' f armed. ?%c firtdingo and backup documentatiin embodied in thi preliminafy report compel the Task Yorao to call trprm ym; thr: . . I SpcnXer, to cwthorim crnd ompowcr the Assemly Sta?ding,CozmiCte I ' . : ,. . ..: .I' .,' :. .~.. ,:. :,-"'. ; ..d ::. . . .~~ ' .,' .' . : ' , ' ..,, -. . -. . . : : ? :. . . . .; *. . 1 ,.' .i. . . : \. .- :. " ' . . . c. : . I ! .'

146

E-Print Network 3.0 - al si ca Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: and Gibbs 1976). 12;KROEKER ET AL.: OXYGEN-17 NMR OF GLASSY AND CRYSTALLINE TITANITE 575 CaTiSiO5 glass... ; Lee and Stebbins 2000; Zhao et al. 2000). The spectra for...

147

Developing TiAIN Coatings for Intermediate Temperature-Solid Oxide Fuel Cell Interconnect Applications  

SciTech Connect

TiN-type coatings have potential to be used as SOFC interconnect coatings SOFC because of their low resistance and high temperature stability. In this research, various (Ti,Al)N coatings were deposited on stainless steels by filtered-arc method. ASR and XRD tests were conducted on these coatings, and SEM/EDAX analysis were conducted after ASR and XRD tests. SEM/EDAX analyses show that (Ti,Al)N remains stable at temperature up to 700°C. It is also indicated that Al has beneficial effect on the stability of TiN type coatings. At 900°C, (Ti-30Al)N is fully oxidized and some of (Ti-50Al)N coating still remains as nitride. The analyses on cross-sectional samples show that these coatings are effective barrier to the Cr migration. In summary, (Ti.Al)N coatings are good candidates for the SOFC interconnect applications at 700°C. The future directions of this research are to improve the stability of these coatings by alloy-doping and to develop multi-layer coatings.

Liu, X. (West Virginia University); Johnson, C.D.; Li, C. (West Virginia University); Xu, J. (West Virginia University); Cross, C.

2007-02-01T23:59:59.000Z

148

A Low Noise NbTiN-based 850 GHz SIS Receiver for the  

E-Print Network (OSTI)

the 350 micron atmospheric window. This frequency band lies entirely above the energy gap of niobium (700 that consists of two Nb/AlN/NbTiN tunnel junctions, NbTiN thin-film microstrip tuning elements, and a Nb window was deployed at the CSO. It used a novel 1 µm thick Silicon Nitride membrane which support an all

149

Micro artificial muscle fiber using NiTi spring for soft robotics Sangbae Kim, Elliot Hawkes, Kyujin Cho, Matthew Jolda, Joe Foley and Robert Wood  

E-Print Network (OSTI)

from shape memory alloy (NiTi) coiled springs. An enhanced spring NiTi model describes the combination of micro-coil spring, we present a novel mesh-worm prototype that utilizes bio-inspired antagonistic structure alteration, NiTi can be restructured into coil springs. Chang et al.[1], discuss the numerous

Wood, Robert

150

ALS@20  

NLE Websites -- All DOE Office Websites (Extended Search)

feed-image feed-image Digg: ALSBerkeleyLab Facebook Page: 208064938929 Flickr: advancedlightsource Twitter: ALSBerkeleyLab YouTube: AdvancedLightSource Home About the ALS ALS@20 ALS@20 ALS@20 Kick-Off Celebration Print On Friday, January 11, the Advanced Light Source celebrated the beginning of its 20th anniversary year with a brunch attended by more than 150 current and past staff members. After introductory remarks describing the trials and tribulations encountered during the construction of the ALS from former Director Jay Marx, current ALS Scientific Director Steve Kevan and Director Roger Falcone talked about the progress of the facility over the years. Attendees were then able to view more than 500 historical photos of the ALS and its staff displayed around the room.

151

Ann bay lodyans 7 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a  

E-Print Network (OSTI)

pou I pase akote. Ti djab la bare I: "Kwa kwa kwa! Ala chans m genyen jodi a. Mwen chita chita m, epi yon vyann vin jwenn mwen. Ki kote ou prale, ti neg?" Dyedone komanse tranble. Men li C^*M pran kouraj li ak 2 men, li pran chante pou ti djab... m pito pa vann." 2 Wa a karese Malis, li pwomet li tout pwoteksyon. Alafen, li louvri men Malis, li depoze san dola ladann. Le msye we bel fey lajan, li dako pou ba Wa a ti lanp la. Epi, nan denmen, Malis al achte yon vye bourik ak kob la...

Freeman, Bryant C., ed.

2000-01-01T23:59:59.000Z

152

Industry @ ALS  

NLE Websites -- All DOE Office Websites (Extended Search)

Industry @ ALS Industry @ ALS Industry @ ALS Concrete Industry Benefits from Ancient Romans and the ALS Print Thursday, 17 October 2013 14:24 New insights into the Romans' ingenious concrete harbor structures emerging from ALS beamline research could move the modern concrete industry toward its goal of a reduced carbon footprint. Summary Slide Read more... Moving Industry Forward: Finding the Environmental Opportunity in Biochar Print Thursday, 12 September 2013 08:41 Using ALS Beamlines 10.3.2 and 8.3.2, the Environmental Protection Agency (EPA) is currently investigating how biochar sorbs environmental toxins and which kinds of biochar are the most effective. The possibilities for widespread use have already launched entrepreneurial commercial ventures. Summary Slide

153

The Allende meteorite: evidence for a new cosmothermometer based on Ti3+/Ti4+  

Science Journals Connector (OSTI)

... 1,765 Perovskite CaTiO3 1,647 1,393 Melilite Ca2Al2SiO7- 1,625 1,450 Ca2MgSi2O7 Spinel MgAl2O4 1,513 1,362 Metallic iron Fe(Fe-Ni) 1,473 Diopside CaMgSi2O6 ... rhonite and fassaite compositions are for rhonites that have decomposed to fassaite + perovskite + spinel. Open circles represent intra-crystalline fassaites. The dashed line marked ALL-4 is the ...

Stephen E. Haggerty

1978-11-16T23:59:59.000Z

154

ALS Visitors  

NLE Websites -- All DOE Office Websites (Extended Search)

including Ethan Crumlin (at right) about current research in energy storage and battery efficiency. Berkeleyside Editor Lance Knoble toured the ALS and Berkeley Lab with...

155

ALS Visitors  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Visitors ALS Visitors ALS Visitors Print Wednesday, 29 July 2009 00:00 ALS staff members host a variety of scientific, educational, government, and community-related tours each month. November 2013 poneman U.S. Deputy Secretary of Energy Daniel Poneman visited Berkeley Lab on Friday, Nov. 15, during a brief stay in the Bay Area. Glenn Mara of the University of California Office of the President and Aundra Richards of the DOE Berkeley Site Office joined Deputy Laboratory Director Horst Simon's welcome. They updated Poneman on the lab's future initiatives and current capital projects and heard briefings on cyber security, computing, and the Joint BioEnergy Institute. As second-in-command at DOE, Poneman is responsible for assisting the Secretary of Energy in the management and operations of the agency and acting on his behalf when necessary.During his tour of the ALS, Poneman (right) spoke with Ken Goldberg (Materials Sciences Division) at the CXRO beamline.

156

ALS Visitors  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Visitors Print ALS Visitors Print ALS staff members host a variety of scientific, educational, government, and community-related tours each month. November 2013 poneman U.S. Deputy Secretary of Energy Daniel Poneman visited Berkeley Lab on Friday, Nov. 15, during a brief stay in the Bay Area. Glenn Mara of the University of California Office of the President and Aundra Richards of the DOE Berkeley Site Office joined Deputy Laboratory Director Horst Simon's welcome. They updated Poneman on the lab's future initiatives and current capital projects and heard briefings on cyber security, computing, and the Joint BioEnergy Institute. As second-in-command at DOE, Poneman is responsible for assisting the Secretary of Energy in the management and operations of the agency and acting on his behalf when necessary.During his tour of the ALS, Poneman (right) spoke with Ken Goldberg (Materials Sciences Division) at the CXRO beamline.

157

Al Weinrub  

NLE Websites -- All DOE Office Websites (Extended Search)

Al Weinrub Al Weinrub Author, "COMMUNITY POWER: Decentralized Renewable Energy in California" Member, Sierra Club California Clean Energy-Climate CommitteeMember, Steering Committee, Bay Area Clean Energy Alliance al.weinrub@comcast.net This speaker was a visiting speaker who delivered a talk or talks on the date(s) shown at the links below. This speaker is not otherwise associated with Lawrence Berkeley National Laboratory, unless specifically identified as a Berkeley Lab staff member. Al Weinrub is a member of the Sierra Club California Energy-Climate Committee and serves on the Steering Committee of the Bay Area's Local Clean Energy Alliance. He is the author of COMMUNITY POWER: Decentralized Renewable Energy in California (http://www.localcleanenergy.org/Community-Power-Publication)

158

Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 catalyst Formation, stability and CO  

E-Print Network (OSTI)

1 Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 are the activation of molecular oxygen, the active site for this reaction step, and the nature of the catalytically active oxygen species present under working conditions.[3;9-15] Stiehl et al. had shown that molecularly

Pfeifer, Holger

159

ALS Visitors  

NLE Websites -- All DOE Office Websites (Extended Search)

Quick Facts Quick Facts ALS Visitors Print ALS staff members host a variety of scientific, educational, government, and community-related tours each month. November 2013 poneman U.S. Deputy Secretary of Energy Daniel Poneman visited Berkeley Lab on Friday, Nov. 15, during a brief stay in the Bay Area. Glenn Mara of the University of California Office of the President and Aundra Richards of the DOE Berkeley Site Office joined Deputy Laboratory Director Horst Simon's welcome. They updated Poneman on the lab's future initiatives and current capital projects and heard briefings on cyber security, computing, and the Joint BioEnergy Institute. As second-in-command at DOE, Poneman is responsible for assisting the Secretary of Energy in the management and operations of the agency and acting on his behalf when necessary.During his tour of the ALS, Poneman (right) spoke with Ken Goldberg (Materials Sciences Division) at the CXRO beamline.

160

E-Print Network 3.0 - al hf ta Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

a JEOL electron microprobe and Ca, Ti, Nb, Ta, Hf and Zr abundances measured using laser ablation... for an Al-rich chon- drule. As Figure 1 shows there is little evidence for...

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Effects of Point Defects and Impurities on Kinetics in NaAlH4  

Energy.gov (U.S. Department of Energy (DOE))

A presentation showing that point defects play an important role in the kinetics of NaAlH4 including vacancies and interstitials consistent with observed effects of Ti.

162

E-Print Network 3.0 - al metal irradiated Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Accelerator Beams , H. Ludewig1 Summary: effects on CTE of super-Invar. Figure 3: "Gum Metal" material characterization in its non-irradiated state... driver. Ti-6Al-4V....

163

E-Print Network 3.0 - al bulk crystals Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

are homogeneously dispersed in the residual glass of the bulk for Tc... consists of titanite (CaTiSiO5) and anorthite (CaAl2Si2O8) crystals that have nucleated heterogeneously......

164

Formation of Ti-B surface alloys by excimer laser mixing  

SciTech Connect

We have formed a surface Ti-B alloy by excimer laser mixing of a single B layer on a Ti-6Al-4V alloy substrate. Rutherford backscattering spectroscopy indicates a uniform B:Ti ratio of approximately 0.7 in the surface layer. A Boron layer 60 nm thick resulted in an alloy layer approximately 200 nm thick. There is little indication, by either Auger electron spectroscopy or nuclear reaction analysis, of substantial oxygen incorporation in the surface alloy despite the fact that the processing was done in air. Transmission electron microscopy of the surface alloy shows a completely amorphous surface layer underlain by a martensitic structure.

Jervis, T.R.; Nastasi, M.; Hirvonen, J.P.; Zocco, T.G.

1990-01-01T23:59:59.000Z

165

AL. I  

Office of Legacy Management (LM)

AL. I AL. I Department of Energy Washington, DC 20545 OCT 13 Vii87 Mr. John T. Shields A214 National Fertilizer Development Center Tennessee Valley Authority Muscle Shoals, Alabama 35660 Dear Mr. Shields: As you may know, the Department of Energy (DOE) is evaluating the radiological condition of sites that were utilized under the Manhattan Engineer District and the Atomic Energy Commission (AEC) during the early years of nuclear development to determine whether they need remedial action and whether the Department has authority to perform such action. AEC work at the TVA during the period 1951 through 1955 involved the development of a process to recover uranium from the production of phosphate fertilizer. A laboratory and pilot plant were operated at the site, but very little

166

Thermodynamics of TiO{sub x} in blast furnace-type slags  

SciTech Connect

Equilibrium studies between CaO-SiO{sub 2}-10 pct MgO-Al{sub 2}O{sub 3}-TiO{sub 1.5}-TiO{sub 2} slags, carbon-saturated iron, and a carbon monoxide atmosphere were performed at 1773 K to determine the activities of TiO{sub 1.5} and TiO{sub 2} in the slag. These thermodynamic parameters are required to predict the formation of titanium carbonitride in the blast furnace. In order to calculate the activity of titanium oxide, the activity coefficient of titanium in carbon-saturated iron-carbon-titanium alloys was determined by measuring the solubility of titanium in carbon-saturated iron in equilibrium with titanium carbide. The solubility and the activity coefficient of titanium obtained were 1.3 pct and 0.023 relative to 1 wt pct titanium in liquid iron or 0.0013 relative to pure solid titanium at 1773 K, respectively. Over the concentration range studied, the effect of the TiO{sub x} content on its activity coefficient is small. In the slag system studied containing 35 to 50 pct CaO, 25 to 45 pct SiO{sub 2}, 7 to 22 pct Al{sub 2}O{sub 3}, and 10 pct MgO, the activity coefficients of TiO{sub 1.5} and TiO{sub 2} relative to pure solid standard states range from 2.3 to 8.8 and from 0.1 to 0.3, respectively. Using thermodynamic data obtained, the prediction of the formation of titanium carbonitride was made. Assuming hypothetical TiO{sub 2}, i.e., total titanium in the slag expressed as TiO{sub 2}, and using the values of the activity coefficients of TiO{sub 1.5} and TiO{sub 2} determined, the equilibrium distribution of titanium between blast furnace-type slags and carbon-saturated iron was computed. The value of [pct Ti]/(pct TiO{sub 2}) ranges from 0.1 to 0.2.

Morizane, Y.; Ozturk, B.; Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States). Dept. of Materials Science and Engineering

1999-02-01T23:59:59.000Z

167

Fabrication of functionally graded TiC/Ti composites by Laser Engineered Net Shaping  

E-Print Network (OSTI)

engineered net shaping (LENS), with compositions changing from pure Ti to approximately 95 vol% TiC; Microstructure; TiC carbide 1. Introduction Functionally graded materials (FGMs) are a class of advanced

DuPont, John N.

168

3d X 3d X SrTiO3Ti 2p 3d  

E-Print Network (OSTI)

XX 3d X 3d X X XX X XX SrTiO3Ti 2p 3d SrTiO3Ti 2p 3d 2p 2p SrTiO3 ts) 2p3/2 (t2g) 2p3/2 (e ) 2p1/2 (eg)2p SrTiO3 3d unit (t2g) (eg) (eg)2p1/2 (t2g)3d (Ti Fe Cu) arb. ( 2g) (Ti, Fe, Cu) y(ansitynten 3d In 3d 468464460456 · Photon Energy (e

Katsumoto, Shingo

169

AlGaN/GaN metal-oxide-semiconductor heterostructure field-effect transistors using barium strontium titanate  

E-Print Network (OSTI)

AlGaN/GaN metal-oxide-semiconductor heterostructure field-effect transistors using barium strontium-effect transistors have been formed by incorporating barium strontium titanate (BST) deposited by rf magnetron in increased leakage. Due to its large dielectric constant, barium strontium ti- tanate [Ba1-xSrxTiO3, (BST

York, Robert A.

170

Synergistic Effect of Nano-TiO2 and Nanoclay on the Ultraviolet Degradation and Physical Properties of Wood Polymer Nanocomposites  

Science Journals Connector (OSTI)

(7) The combination of nanoclay with other metal nanoparticles will influence the properties of the composites considerably, as reported by Laachachia et al. while studying the properties of poly(methyl methacrylate) (PMMA) nanocomposites prepared with TiO2 and nanoclay. ... (30) Mina et al. studied the XRD pattern of a polypropylene/titanium dioxide composite and reported a similar increase in the peak intensity of TiO2 in the composites. ...

Ankita Hazarika; Tarun K. Maji

2013-08-26T23:59:59.000Z

171

Surface characterization and mechanical property of TiN/Ti-coated NiTi alloy by PIIID  

E-Print Network (OSTI)

significantly reduces the friction coefficient and improves wear resistance of the NiTi alloy. © 2006 Elsevier B prosthesis, heart valve replacement and biosensors [6,7]. TiN surface coating has also been found

Zheng, Yufeng

172

Effect of laser irradiation on failure mechanism of TiCp reinforced titanium composite coating produced by laser cladding  

Science Journals Connector (OSTI)

Abstract Laser cladding is an effective technique to coat a metallic substrate with a layer of a different nature. It has been widely reported that the most important combined parameters controlling the quality of the coating are the specific energy (E) and the powder density (?). In the present work, clad deposits of Ti6Al4V + 60 wt.% TiC were prepared on a Ti6Al4V substrate using an optimum combination of Ec = 24 J/mm2 and ?c = 3 mg/mm2. These experiments were performed using a laser power of 400 and 600 W, in order to study the effect of laser power on the properties of the clad. The microstructure, phase composition and nanohardness of the coatings were investigated by optical microscopy, scanning electron microscopy and X-ray diffraction. During laser processing, TiC can be partially converted to TiCX (X = 0.5) due mainly to the TiC dissolution into the laser-generated melting pool and subsequent precipitation during cooling. It was observed that the lower laser power limit reduces primary TiC dissolution but it also promotes secondary carbide alignment at the interface. On the other hand, the damage mechanism induced by high laser power is dominated by primary TiC particle cracking by the high stress concentration at the particle–matrix interface followed by ductile failure of the matrix. It is also remarkable that irradiance affects the TiC/TiCx ratio despite Ec and ?c are fixed and it determines hardness distribution inside the coating.

J.J. Candel; J.A. Jimenez; P. Franconetti; V. Amigó

2014-01-01T23:59:59.000Z

173

E-Print Network 3.0 - aleaciones cu-zn-al estabilidad Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

C2, suppl6mentau Journal de Physique 111,Volume 5, f6vrier 1995 Summary: The shape memory alloys which are industrially used are based upon NiTi, CuZnAl and CuAlNi to which...

174

Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces  

E-Print Network (OSTI)

, naturally occurs in wood and volcanic gases. Decaying organic matter can also produce methanol. Paint. This report describes the photocatalytic degradation of formaldehyde and methanol, two common VOC's, by TiO2 and methanol tests (Land et al., 2008). A standardized aqueous solution of formaldehyde and methanol was used

Bergin, Mike

175

Characterization of TiN, TiC and TiCN coatings on Ti50.6 at.% Ni alloy deposited by PIII and deposition technique  

E-Print Network (OSTI)

high content of nickel [1]. In addition, its wear resistance is expected to be improved by transition-metal as nitride, carbide and carbonitride, respectively. Based on the electrochemical measurement and ion carbides and nitrides coatings at a rather broad composition range, such as TiN, TiC and TiC1-xNx (0bÃ?b1

Zheng, Yufeng

176

Au/MxOy/TiO2 catalysts for CO oxidation: promotional effect of main-group, transition, and rare-earth metal oxide additives.  

SciTech Connect

Au/TiO2 catalysts are active for CO oxidation, but they suffer from high-temperature sintering of the gold particles, and few attempts have been made to promote or stabilize Au/TiO2. Our recent communication addressed these issues by loading gold onto Al2O3/TiO2 prepared via surface-sol-gel processing of Al(sec-OC4H9)3 on TiO2. In our current full paper, Au/Al2O3/TiO2 catalysts were prepared alternatively by thermal decomposition of Al(NO3)3 on TiO2 followed by loading gold, and the influences of the decomposition temperature and Al2O3 content were systematically surveyed. This facile method was subsequently extended to the preparation of a battery of metal oxide-modified Au/TiO2 catalysts virtually not reported. It was found that Au/TiO2 modified by CaO, NiO, ZnO, Ga2O3, Y2O3, ZrO2, La2O3, Pr2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, Dy2O3, Ho2O3, Er2O3, or Yb2O3 could retain significant activity at ambient temperature even after aging in O2-He at 500 C, whereas unmodified Au/TiO2 lost its activity. Moreover, some 200 C-calcined promoted catalysts showed high activity even at about -100 C. The deactivation and regeneration of some of these new catalysts were studied. This work furnished novel catalysts for further fundamental and applied research.

Ma, Zhen [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2007-01-01T23:59:59.000Z

177

ALS Chemistry Lab  

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ALS Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for...

178

ALS Chemistry Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

Safety Safety for Users ALS Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These...

179

Stoichiometry-driven metal-to-insulator transition in NdTiO{sub 3}/SrTiO{sub 3} heterostructures  

SciTech Connect

By controlling stoichiometry via a hybrid molecular beam epitaxy approach, we report on the study of thin film growth and the electronic transport properties of phase-pure, epitaxial NdTiO{sub 3}/SrTiO{sub 3} heterostructures grown on (001) (La{sub 0.3}Sr{sub 0.7})(Al{sub 0.65}Ta{sub 0.35})O{sub 3} (LSAT) substrates as a function of cation stoichiometry in NdTiO{sub 3}. Despite the symmetry mismatch between bulk NdTiO{sub 3} and the substrate, NdTiO{sub 3} films grew in an atomic layer-by-layer fashion over a range of cation stoichiometry; however amorphous films resulted in cases of extreme cation non-stoichiometry. Temperature-dependent sheet resistance measurements were consistent with Fermi-liquid metallic behavior over a wide temperature range, but revealed a remarkable crossover from metal-to-insulator (M-I) type behavior at low temperatures for all compositions. A direct correlation between cation stoichiometry, transport behavior, and the temperature of M-I transition is established.

Xu, Peng; Phelan, Daniel; Seok Jeong, Jong; Andre Mkhoyan, K.; Jalan, Bharat, E-mail: bjalan@umn.edu [Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

2014-02-24T23:59:59.000Z

180

Superior Corrosion Resistance Properties of TiN-Based Coatings on Zircaloy Tubes in Supercritical Water  

SciTech Connect

Thin films of TiN and Ti0.35Al0.65N nanocomposite were deposited on polished Zircaloy-4 tubes. After exposure to supercritical water for 48 h, the coated tubes are remarkably intact, while the bare uncoated tube shows severe oxidation and breakaway corrosion. X-ray diffraction patterns, secondary electron images, backscattered electron images, and energy dispersive X-ray spectroscopy data from the tube surfaces and cross-sections show that a protective oxide, formed on the film surface, effectively prevents further oxidation and corrosion to the Zircaloy-4 tubes. This result demonstrates the effectiveness of thin film ceramics as protective coatings under extreme environments.

Fauzia Khatkhatay; Liang Jiao; Jie Jian; Zhijie Jiao; Hongbin Zhang; Jian Gan; Haiyan Wang; Wenrui Zhang; Xinghang Zhang

2014-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Oxygen Reduction Catalyzed by Au–TiO2 Nanocomposites in Alkaline Media  

Science Journals Connector (OSTI)

Au?TiO2 nanocomposite; oxygen reduction; alkaline media; RRDE; Tafel plot ... In another study, Kim et al.(14) prepared titanium oxide by heat treatment of titanium sheets in the temperature range of 600–1000 °C, and the best catalysts were identified as those prepared at 900 °C where ORR occurred at the potential of about +0.65 V versus RHE in 0.1 M H2SO4. ... In a typical measurement, 1 mg of the Au–TiO2 nanocomposite catalysts, 4 mg of carbon powder, and 10 ?L of Nafion were ultrasonically mixed in 1 mL of methanol. ...

Chan Lin; Yang Song; Lixin Cao; Shaowei Chen

2013-11-11T23:59:59.000Z

182

Ann bay lodyans 12 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a  

E-Print Network (OSTI)

a, Bondye fe yon bon ti melanj: li pran bwode ki gen nan pan, di ki gen nan woch, fines ki gen nan ke zwazo, douse ki gen nan siwo myel, mechanste ki gen nan tig, chale ki gen nan dife, fredi ki gen nan lanej. Bondye kontwole yo, sa pa ase.... Yo te viv ansanm pandan kek tan konsa. Men yon jou, msye a al devan Bondye ansanm ak fi a. Li pote I remet Bondye. Li di konsa: "Bondye, m pa kapab viv ak zanmi ou ban mwen an. Li pale san rete, li fatige m twop, menm yon ti poze m pa kab fe. Sa...

Freeman, Bryant C.

2000-01-01T23:59:59.000Z

183

Observation of TiH5 and TiH7 in Bulk-Phase TiH3 Gels for Kubas-Type Hydrogen Storage  

Science Journals Connector (OSTI)

Observation of TiH5 and TiH7 in Bulk-Phase TiH3 Gels for Kubas-Type Hydrogen Storage ... Table T2 provides the formulas and C, H, and Ti percentages of the hydrogenated materials in addition to those of representative stoichiometric compounds, including pure TiH3 and the starting material. ... In the TiH3 structure, the hydride ligands are a lightweight structural feature as opposed to a source of stored hydrogen, and additional hydrogen can bind via the Kubas interaction to access TiH5 and TiH7 species. ...

Tuan K. A. Hoang; Leah Morris; Daniel Reed; David Book; Michel L. Trudeau; David M. Antonelli

2013-11-14T23:59:59.000Z

184

Induction of Cytotoxicity by Photoexcited TiO2 Particles  

Science Journals Connector (OSTI)

...TiO2 in the suspension was measured with combustion analysis. The TiO2 aqueous suspension...photoexcited TiO2 particles. it did not produce heat at the irradiated site. Since TiO2 alone...Heterogeneous photocatalytic oxidation of hydrocarbons on platinized TiO2 powders. J. Phys...

Ruxiong Cai; Yoshinobu Kubota; Taro Shuin; Hideki Sakai; Kazuhito Hashimoto; and Akira Fujishima

1992-04-15T23:59:59.000Z

185

NbTiN Based SIS Multilayer Structures for SRF Applications  

SciTech Connect

For the past three decades, bulk niobium has been the material of choice for SRF cavities applications. RF cavity performance is now approaching the theoretical limit for bulk niobium. For further improvement of RF cavity performance for future accelerator projects, Superconductor ? Insulator - Superconductor (SIS) multilayer structures (as recently proposed by Alex Gurevich) present the theoretical prospect to reach RF performance beyond bulk Nb, using thinly layered higher-Tc superconductors with enhanced Hc1. Jefferson Lab (JLab) is pursuing this approach with the development of NbTiN and AlN based multilayer SIS structures. This paper presents the results on the characteristics of NbTiN films and the first RF measurements on NbTiN-based multilayer structure on thick Nb films.

Valente, Anne-marie; Eremeev, Grigory; Phillips, H.; Reece, Charles; Spradlin, Joshua; Yang, Qiguang; Lukaszew, Rosa

2013-09-01T23:59:59.000Z

186

Pulsed electrospark deposition of MAX phase Cr2AlC based coatings on titanium alloy  

Science Journals Connector (OSTI)

Abstract Coatings with a high amount of MAX phase were obtained onto Ti substrate using the pulsed electrospark deposition (PED) technique and Cr2AlC electrode material (??). The structure and phase formation of the coatings generated at different modes were studied. It was found, that a layer of titanium carbide was formed during the initial stage of the deposition at the interface as a result of chemical reaction between Cr2AlC electrode and Ti substrate which further acts as a diffusion barrier.

E.I. Zamulaeva; E.A. Levashov; T.A. Sviridova; N.V. Shvyndina; M.I. Petrzhik

2013-01-01T23:59:59.000Z

187

Electrochemistry properties of multilayer TiN/Ti coatings on NiTi alloy for cardiac occluder application  

E-Print Network (OSTI)

-elasticity, thermal shape memory, high corrosion and fatigue resistance, make NiTi alloy especially suitableTi alloy is a subject of numerous recent studies to improve the material's corrosion resistance as well,b , D.Y. Zhang e a Center for Biomedical Materials and Tissue Engineering, Academy for Advanced

Zheng, Yufeng

188

Highly uniform bipolar resistive switching characteristics in TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2} multilayer  

SciTech Connect

Nanoscale multilayer structure TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2} has been fabricated on Pt/Ti/SiO{sub 2}/Si substrate by chemical solution deposition method. Highly uniform bipolar resistive switching (BRS) characteristics have been observed in Pt/TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2}/Pt cells. Analysis of the current-voltage relationship demonstrates that the space-charge-limited current conduction controlled by the localized oxygen vacancies should be important to the resistive switching behavior. X-ray photoelectron spectroscopy results indicated that oxygen vacancies in TiO{sub 2} play a crucial role in the resistive switching phenomenon and the introduced TiO{sub 2}/BaTiO{sub 3} interfaces result in the high uniformity of bipolar resistive switching characteristics.

Ma, W. J.; Zhang, X. Y.; Wang, Ying; Zheng, Yue, E-mail: zhengy35@mail.sysu.edu.cn, E-mail: wangbiao@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China) [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Lin, S. P. [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China) [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Sino-French Institute of Nuclear Engineering and Technology, Zhuhai Campus, Sun Yat-Sen University, Zhuhai 519082 (China); Luo, J. M.; Wang, B., E-mail: zhengy35@mail.sysu.edu.cn, E-mail: wangbiao@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Li, Z. X. [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China)] [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China)

2013-12-23T23:59:59.000Z

189

ALS Chemistry Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for...

190

? decay of 40Ti and 41Ti and implication for solar-neutrino detection  

Science Journals Connector (OSTI)

The ? decay of 40Ti and 41Ti was studied by measuring the ?-delayed proton and ? emission. The half-lives for 40Ti and 41Ti were determined to be 54(2) and 82(3) ms, respectively. The experimental ?-decay strengths are compared with shell-model calculations and results from other measurements. The integrated Gamow-Teller strengths for 40Ti and 41Ti were found to be quenched, compared to the calculations, by factors of 0.79(3) and 0.93(3), respectively. Based on the experimental 40Ti??-decay strength, the neutrino absorption cross section and induced neutrino event rates for 40Ar were determined to be 14.3(3)×10-43?cm2 and 9.4±0.2(stat)-1.6+1.3(syst) SNU, respectively.

W. Liu; M. Hellström; R. Collatz; J. Benlliure; L. Chulkov; D. Cortina Gil; F. Farget; H. Grawe; Z. Hu; N. Iwasa; M. Pfützner; A. Piechaczek; R. Raabe; I. Reusen; E. Roeckl; G. Vancraeynest; A. Wöhr

1998-11-01T23:59:59.000Z

191

Patterned Growth of TiO2 Nanowires on Titanium Substrates Jong-Yoon Ha1;2  

E-Print Network (OSTI)

and short processing time utilizes the Ti foil both as a substrate and as a metal supply, thus eliminating transport methods. Adachi et al. have reported the synthesis of titania NWs using hydrothermal reactions, these methods typically require complex setups and processes, harsh environmental conditions, and extended

Lin, Liwei

192

Characteristics of vanadia on the surface of V2O5/Ti-PILC catalyst for the reduction of \\{NOx\\} by NH3  

Science Journals Connector (OSTI)

A series of vanadia catalysts impregnated on titania pillared interlayered clays (Ti-PILCs) were prepared to identify the characteristics of vanadia on the surface of Ti-PILC for the selective catalytic reduction (SCR) of NO by NH3. V2O5/Ti-PILC exhibited superior performance as a novel SCR catalyst compared to conventional catalysts including V2O5/TiO2 and V2O5/Al2O3. NO removal activity over the supported vanadia catalyst is strongly influenced by the structure of vanadia species on the catalyst surface. The structure of vanadia species on various supports including TiO2, Al2O3, and SiO2 along with Ti-PILC has been examined by XRD, NMR and Raman analyses for the comparative study. Increasing the content of vanadia up to the monolayer coverage of the surface of Ti-PILC catalyst enhanced the ratio of the polymerized surface vanadia species to the isolated ones. These results are well correlated with TOF of vanadia on the catalyst surface for the reduction of NO by NH3.

Ho Jeong Chae; In-Sik Nam; Sung-Won Ham; Suk Bong Hong

2004-01-01T23:59:59.000Z

193

Performance Degradation of TiN-and TiC-deposited AISI316 bipolar plates for proton exchange membrane fuel cells  

Science Journals Connector (OSTI)

TiN and TiC were deposited on AISI316 bipolar plates for proton exchange membrane fuel cells (PEMFCs) and their effects on the corrosion resistance and overall cell performance were investigated. TiN with a Ti...

Hee Yeol Lee; Jae Woong Choi; Gil Ho Hwang…

2006-04-01T23:59:59.000Z

194

Ti-based composite coatings with gradient TiC x reinforcements on TC4 titanium alloy prepared by laser cladding  

Science Journals Connector (OSTI)

TiC x -NiTi2/Ti cermet composite coatings C1 and C2 with gradient TiC x ...reinforcements were prepared on TC4 titanium alloy by laser cladding ...

ShuNv Liu; ZongDe Liu; Yang Wang; Peng Yue

2014-07-01T23:59:59.000Z

195

Narrow band defect luminescence from Al-doped ZnO probed by scanning tunneling cathodoluminescence  

E-Print Network (OSTI)

Institute of Physics. Related Articles Effect of CdS film thickness on the photoexcited carrier lifetime of TiO2/CdS core-shell nanowires Appl. Phys. Lett. 99, 153111 (2011) Current underestimationNarrow band defect luminescence from Al-doped ZnO probed by scanning tunneling cathodoluminescence

Russell, Kasey

196

E-Print Network 3.0 - al2o3 fgm joints Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

5 . D-10587 Berlin Summary: to such kind of FGMs as: some ce- ramicceramic FGMs, i.e. TiCSiC, MoSi2Al2O3 and MoSi2SiC, and also some ce... the behavior of cracks in a graded...

197

Ann bay lodyans 1 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a  

E-Print Network (OSTI)

Ian santi sa 11 ap manje a. Li pa menm di bonjou menm. Li di li konsa: "Granmoun, kote 2 pou m fe pou m al lakay Bondye?" Granmoun Ian we li malelve, li reponn: "Fe sa. Ou a twouve kay Bondye." Wout sa a mennen nan yon twou djab. Vwala, neg la... pou I rive lakay Bondye. Ti granmoun Ian di I menm bagay: "Fe sa." Msye a swiv menm wout la, e tchoup! Djab yo manje I menm jan. Le manman an pa we 2 pitit li yo, ke li sote. Tchikata, twazyem gason an, di: "Manman, kite m al we kote yo ye...

Freeman, Bryant C., ed.

2000-01-01T23:59:59.000Z

198

Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers  

E-Print Network (OSTI)

Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers Yuanyuan Cheng Polarization Fretting corrosion Ti/TiN multilayers were deposited on sintered NdFeB by radio frequency magnetron sputtering. The film grain size decreased with the number of multilayers in the stack. Corrosion

Volinsky, Alex A.

199

Science DMZ for ALS  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Science Engagement Move your data Programs & Workshops Science Requirements Reviews Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ @ UF Science DMZ @ CU...

200

Flüssiger Wasserstoff als Kraftstoff  

Science Journals Connector (OSTI)

Seit mehr als hundert Jahren stellen Kohlenwasserstoffe aus Rohöl fast ausschließlich die Basis für alle im Verkehr verwendeten Kraftstoffe dar. Ein Verkehr ohne Benutzung von Kraftstoffen auf Kohlenwasserstof...

Prof. Dr. Ing. habil. Walter Peschka

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Howes et al. Reply  

E-Print Network (OSTI)

Howes et al. Reply to Comment on "Kinetic Simulations of Magnetized Turbulence in Astrophysical Plasmas" arXiv:0711.4355

G. G. Howes; S. C. Cowley; W. Dorland; G. W. Hammett; E. Quataert; A. A. Schekochihin; T. Tatsuno

2008-12-12T23:59:59.000Z

202

Fabrication of TiO{sub 2} nanocrystallized glass  

SciTech Connect

Nanocrystallization of rutile and anatase was observed in a CaO-B{sub 2}O{sub 3}-Bi{sub 2}O{sub 3}-Al{sub 2}O{sub 3}-TiO{sub 2} crystallized glass. The color of the present crystallized glass was changed by the heat-treatment temperature, and x-ray diffraction (XRD) patterns of the crystallized glass show that the apparent color change is correlated with the formation of titania nanocrystallites. The particle size of crystallites observed in the transmission electron microscope image is comparable to that measured by XRD pattern. In addition, a large change of refractive index between the rutile particles and glass matrix, 0.8 or larger, was obtained. The present titania crystallized glass will be not only a photocatalytic material but also a promising candidate for random lasing devices.

Masai, Hirokazu; Fujiwara, Takumi; Mori, Hiroshi; Komatsu, Takayuki [Department of Applied Physics, Tohoku University, 6-6-05 Aoba, Sendai 980-8579 (Japan); Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka 940-2188 (Japan)

2007-02-19T23:59:59.000Z

203

Calculator Tips for TI-30XA  

E-Print Network (OSTI)

TI-30XA Calculator Tips. Calculator Memory. - To use the memory function, hit the STO key to store a number in either memory 1, 2, or 3. o To store the product of ...

Owen Davis

2013-01-04T23:59:59.000Z

204

Science DMZ for ALS  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS ALS About ESnet Overview ESnet Staff Governance Our Network Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ CU Science DMZ Penn State & VTTI Science DMZ NOAA Science DMZ NERSC Science DMZ ALS Multi-facility Workflow LCLS ESnet Strategic Plan ESnet Organizational Chart ESnet History Science Requirements Careers Contact Us Technical Assistance: 1 800-33-ESnet (Inside the US) 1 800-333-7638 (Inside the US) 1 510-486-7600 (Globally) 1 510-486-7607 (Globally) Report Network Problems: trouble@es.net Provide Web Site Feedback: info@es.net Science DMZ for ALS Many beamline scientists at Berkeley Lab's Advanced Light Source (ALS) are or will be experiencing slower network speeds because of instrument upgrades. These new instruments, or more specifically detectors, are

205

In-situ Spectroscopy of Water Oxidation at Ir Oxide Nanocluster Drivenby Visible TiOCr Charge-Transfer Chromophore in Mesoporous Silica  

SciTech Connect

An all-inorganic photocatalytic unit consisting of a binuclear TiOCr charge-transfer chromophore coupled to an Ir oxide nanocluster has been assembled on the pore surface of mesoporous silica AlMCM-41. In situ FT-Raman and EPR spectroscopy of an aqueous suspension of the resulting IrxOy-TiCr-AlMCM-41 powder reveal the formation of superoxide species when exciting the Ti(IV)OCr(III) --> Ti(III)OCr(IV) metal-to-metal charge-transfer chromophore with visible light. Use of H218O confirms that the superoxide species originates from oxidation of water. Photolysis in the absence of persulfate acceptor leads to accumulation of Ti(III) instead. The results are explained by photocatalytic oxidation of water at Ir oxide nanoclusters followed by trapping of the evolving O2 by transient Ti(III) centers to yield superoxide. Given the flexibility to select donor metals with appropriate redox potential, photocatalytic units consisting of a binuclear charge-transfer chromophore coupled to a water oxidation catalyst shown here constitute a step towards thermodynamically efficient visible light water oxidation units.

Frei, Heinz; Han, Hongxian; Frei, Heinz

2008-06-03T23:59:59.000Z

206

E-Print Network 3.0 - avastart ti traumade Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

University of South Carolina Collection: Mathematics 15 Characterization of TiN, TiC and TiCN coatings on Ti50.6 at.% Ni alloy deposited by PIII and deposition technique...

207

E-Print Network 3.0 - amorphous ni-ti alloys Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

044103 (6pp) doi:10.10881748-604134044103 Summary: .10881748-604134044103 Ti-TiC-TiCDLC gradient nano-composite film on a biomedical NiTi alloy Yufeng Zheng1,2, Dong...

208

ALS Beamlines Directory  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Beamlines Directory Print ALS Beamlines Directory Print Beamlines, Parameters, Contact Information, and Schedules Download a high-resolution version of the ALS Beamclock. See Beamclock to view the ALS energy-related beamlines beamclock. Beamline Parameters Beamline and endstation technical information is available through the links below. Unless otherwise noted, all beamlines are currently operational. Individual beamline schedules are posted when available. Please contact the responsible beamline scientist for additional schedule information. When calling from off-site, all beamline (BL) phone numbers that begin with a "2" are preceded by 495- (i.e., 495-2014); all others are preceded by 486-. Beamline Number Source Technique/ Group Name Energy Range Beamline Contact Schedule/BL Phone

209

ALS Beamlines Directory  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Beamlines Directory Print ALS Beamlines Directory Print Beamlines, Parameters, Contact Information, and Schedules Download a high-resolution version of the ALS Beamclock. See Beamclock to view the ALS energy-related beamlines beamclock. Beamline Parameters Beamline and endstation technical information is available through the links below. Unless otherwise noted, all beamlines are currently operational. Individual beamline schedules are posted when available. Please contact the responsible beamline scientist for additional schedule information. When calling from off-site, all beamline (BL) phone numbers that begin with a "2" are preceded by 495- (i.e., 495-2014); all others are preceded by 486-. Beamline Number Source Technique/ Group Name Energy Range Beamline Contact Schedule/BL Phone

210

ALS User Meeting Archives  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS User Meeting Archives ALS User Meeting Archives Past User Meeting Agendas, Workshops, and Awards Year Agenda Workshops David A. Shirley (Science) Klaus Halbach (Instrumentation) Tim Renner (Service) 2012 2012 User Meeting Agenda 2012 User Meeting Workshops 2012 ALS User Meeting Awards Carl Percival, Dudley Shallcross, Craig Taatjes and David Osborn (Sandia), for making the first direct measurements of the reactions of Criegee intermediates, and showing that their impact on tropospheric chemistry and climate may be substantially greater than previously assumed. 2012 ALS User Meeting Awards Jeff Dickert and Simon Morton of Berkeley Lab's Physical Biosciences Division for the invention and implementation of the Compact Variable Collimator (CVC), which has led to a dramatic increase in productivity of protein crystallography.

211

Hacking als Grenzüberschreitung  

Science Journals Connector (OSTI)

In der Vergangenheit hat es sich als nützlich erwiesen, am Anfang eines Vortrages erst einmal ein paar Worte zu dem Verein zu verlieren, in dessen Vorstand ich mitwirke. Der Chaos Computer Club (CCC) ist viele...

Frank Simon

1994-01-01T23:59:59.000Z

212

ALS Staff Photo  

NLE Websites -- All DOE Office Websites (Extended Search)

Staff Photo Print On May 14, 2013, members of ALS staff posed for a group photo in front of the dome. A hi-res version can be downloaded here. The last staff photo was taken in...

213

Flachglas Als Baustoff  

Science Journals Connector (OSTI)

Der Werkstoff Glas bezeichnet ein Schmelzprodukt, das in der Natur als erstarrte vulkanische Schmelze vorkommt und dem Mensch bereits vor 5000 Jahren für die Herstellung von Schmuck und Werkstücken diente. Im ...

2007-01-01T23:59:59.000Z

214

Fast Transporting ZnO–TiO2 Coaxial Photoanodes for Dye-Sensitized Solar Cells Based on ALD-Modified SiO2 Aerogel Frameworks  

Science Journals Connector (OSTI)

To circumvent this problem, we have explored here the idea of conformally coating the silica–ZnO aerogel structures with very thin layers of more robust metal oxides such as Al2O3, ZrO2, or TiO2 to create doubly coaxial structures. ... J–V characteristics of DSSCs featuring 25 ?m thick aerogel-based SiO2–ZnO films compared to similar films with ca. 3 and 4 Å coatings of Al2O3 and TiO2, respectively: (a) light performance; (b) dark performance. ... Figure 7. Plot showing the effects of increased layers of TiO2 coats over 6 nm ZnO-coated silica aerogels with respect to charge lifetimes from OCVD measurements. ...

Vennesa O. Williams; Nak Cheon Jeong; Chaiya Prasittichai; Omar K. Farha; Michael J. Pellin; Joseph T. Hupp

2012-06-21T23:59:59.000Z

215

Structure, Magnetism and Conductivity in Epitaxial Ti-doped ...  

NLE Websites -- All DOE Office Websites (Extended Search)

Magnetism and Conductivity in Epitaxial Ti-doped -Fe2O3 Hematite: Experiment and density functional theory Structure, Magnetism and Conductivity in Epitaxial Ti-doped -Fe2O3...

216

Oxygen Vacancies and Ferromagnetism in CoxTi–x–y...  

NLE Websites -- All DOE Office Websites (Extended Search)

Vacancies and Ferromagnetism in CoxTi–x–y. Oxygen Vacancies and Ferromagnetism in CoxTi–x–y. Abstract: Abstract: Cobalt-doped titanium dioxide, or CTO, has...

217

Co-doped Anatase TiO? Heteroepitaxy on Si(001)  

SciTech Connect

Pure anatase TiO? and CoxTi?-x O? (0.01 < x < 0.04) epitaxial thin films were deposited by oxygen-plasma-assisted molecular beam epitaxy (OPA-MBE) on Si(001) for evaluation as a potential dilute magnetic semiconductor material suitable for Si-based spintronic devices. Epitaxial growth on Si(001) was facilitated by the deposition of ¼or ½ ML Sr metal on the clean Si(001) surface to form an oxidation resistant silicide layer, followed by deposition of a thin SrTiO? buffer layer. Using ½ ML Sr metal to form the silicide allowed the deposition of 10 ML SrTiO? without oxidation of the Si interface. Epitaxial anatase could be grown on this heterostructure, although use of the oxygen plasma during deposition resulted in significant SiO? formation. Pure anatase films consisted of epitaxial anatase surface particles on a continuous anatase film. For Co-doped films, Co segregation to surface particles of epitaxial anatase was observed by Auger electron spectroscopy and transmission electron microscopy (TEM); faceting of the particles was observed for low Co doping concentrations. Although no secondary phases containing Co were observed in Co-doped anatase films by x-ray diffraction or TEM, x-ray absorption near edge spectroscopy indicated Co was present in the films as a mixture of Co(0), Co(II), and Co(III). All samples were ferromagnetic at room temperature; for lower Co concentrations, the ferromagnetic remanence (9%) and coercive field (100 Oe) were similar to phase-pure Co:TiO? / LaAlO?. However, the presence of Co(0) under strongly oxidizing growth conditions known to oxidize the Si interface implies that under no deposition conditions can Co metal be eliminated while simultaneously protecting the Si interface from oxidation.

Kaspar, Tiffany C.; Droubay, Timothy C.; Wang, Chong M.; Heald, Steve M.; Lea, Alan S.; Chambers, Scott A.

2005-04-01T23:59:59.000Z

218

TiSol | Open Energy Information  

Open Energy Info (EERE)

TiSol TiSol Jump to: navigation, search Name TiSol Place Pasadena, California Sector Solar Product California-based start up focused on the production of dye sensitized solar cells. Coordinates 29.690847°, -95.196308° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.690847,"lon":-95.196308,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

219

Morphology, deformation, and defect structures of TiCr{sub 2} in Ti-Cr alloys  

SciTech Connect

The morphologies and defect structures of TiCr{sub 2} in several Ti-Cr alloys have been examined by optical metallography, x-ray diffraction, and transmission electron microscopy (TEM), in order to explore the room-temperature deformability of the Laves phase TiCr{sub 2}. The morphology of the Laves phase was found to be dependent upon alloy composition and annealing temperature. Samples deformed by compression have also been studied using TEM. Comparisons of microstructures before and after deformation suggest an increase in twin, stacking fault, and dislocation density within the Laves phase, indicating some but not extensive room-temperature deformability.

Chen, K.C.; Allen, S.M.; Livingston, J.D.

1992-12-31T23:59:59.000Z

220

Dampfdruckmessungen und Protonenresonanzuntersuchung an Hydriden der intermetallischen Phasen Ti2(Ni, Co) und Ti2(Ni, Fe)  

Science Journals Connector (OSTI)

NMR and hydrogen equilibrium pressure measurements were performed on hydrides of the intermetallic compounds Ti2(Ni, Co) and Ti2(Ni, Fe). The following values of enthalpy ?H and entropy ?S for the formation of th...

Engelbert Tuscher; Kurt Hiebl; Helmut Bittner

1981-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Synthesis of Ti-based electrodes using Ti-salt flocculated sludge and their application in lithium-ion batteries  

SciTech Connect

We report a simple strategy to synthesize the nanostructured TiO{sub 2} samples by a solid state reaction using Ti-salt flocculated sludge. The structure and morphology of the Ti-salt flocculated sludge, nanostructured TiO{sub 2} samples and pure commercial Aldrich TiO{sub 2} powder were characterized by powder X-ray diffraction and field emission scanning electron microscopy (FE-SEM). The electrochemical performances were evaluated in coin type cells. Nanostructured TiO{sub 2} samples, obtained by Ti-salt flocculated sludge shows a higher capacity and better cycling performances than pure commercial Aldrich TiO{sub 2} powder at the cutoff of 1.0–2.5 V especially at high current rate. The enhanced cycling performance can be attributed to the facts that their high crystallinity and uniform nano-sized distribution.

Kang, Jungwon; Rai, Alok Kumar; Kim, Sungjin; Choi, Eunseok; Yoo, Insun [Department of Materials Science and Engineering, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757 (Korea, Republic of)] [Department of Materials Science and Engineering, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757 (Korea, Republic of); Kim, Jongho [School of Applied Chemical Engineering and the Research Institute for Catalysis, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757 (Korea, Republic of)] [School of Applied Chemical Engineering and the Research Institute for Catalysis, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757 (Korea, Republic of); Kim, Jaekook, E-mail: jaekook@chonnam.ac.kr [Department of Materials Science and Engineering, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757 (Korea, Republic of)] [Department of Materials Science and Engineering, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757 (Korea, Republic of)

2012-10-15T23:59:59.000Z

222

Band Offsets at the Epitaxial Anatase TiO2/n-SrTiO3(001) Interface...  

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to measure valence band offsets at the epitaxial anatase TiO2(002)n-SrTiO3(001) heterojunction prepared by molecular beam epitaxy, Within experimental error, the valance band...

223

Carrier-Controlled Ferromagnetism in SrTiO3  

Magnetotransport and superconducting properties are investigated for uniformly La-doped SrTiO3 films and GdTiO3/SrTiO3 heterostructures, respectively. GdTiO3/SrTiO3 interfaces exhibit a high-density 2D electron gas on the SrTiO3 side of the interface, while, for the SrTiO3 films, carriers are provided by the dopant atoms. Both types of samples exhibit ferromagnetism at low temperatures, as evidenced by a hysteresis in the magnetoresistance. For the uniformly doped SrTiO3 films, the Curie temperature is found to increase with doping and to coexist with superconductivity for carrier concentrations on the high-density side of the superconducting dome. The Curie temperature of the GdTiO3/SrTiO3 heterostructures scales with the thickness of the SrTiO3 quantum well. The results are used to construct a stability diagram for the ferromagnetic and superconducting phases of SrTiO3.

Moetakef, Pouya; Williams, James R.; Ouellette, Daniel G.; Kajdos, Adam P.; Goldhaber-Gordon, David; Allen, S. James; Stemmer, Susanne

2012-06-01T23:59:59.000Z

224

Ab initio Molecular Dynamics and Elastic Properties of TiC and TiN Nanoparticles A. V. Postnikov and P. Entel  

E-Print Network (OSTI)

Ab initio Molecular Dynamics and Elastic Properties of TiC and TiN Nanoparticles A. V. Postnikov composition and compared to frozen phonon and molecular dynamics calculations for crystalline TiC and Ti range of frequencies, including the phonon band gap of pure crystalline TiC (near 15 THz). Similar

Entel, P.

225

ALS in the News  

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feed-image feed-image Digg: ALSBerkeleyLab Facebook Page: 208064938929 Flickr: advancedlightsource Twitter: ALSBerkeleyLab YouTube: AdvancedLightSource Home About the ALS ALS in the News ALS in the News Roman Seawater Concrete Holds the Secret to Cutting Carbon Emissions Print Tuesday, 04 June 2013 00:00 An international team led by Paulo Monteiro of the Advanced Light Source and UC Berkeley has analyzed samples of Roman concrete from harbor installations that have survived 2,000 years of chemical attack and wave action, "one of the most durable construction materials on the planet," says UC Berkeley's Marie Jackson, a leading member of the team. Says Monteiro, "It's not that modern concrete isn't good, but manufacturing Portland cement accounts for seven percent of the carbon dioxide that industry puts into the air." The carbon footprint of Roman concrete, made from lime, volcanic ash, and seawater, is much smaller.

226

ALS Beamlines Directory  

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Beamlines Directory Beamlines Directory ALS Beamlines Directory Print Beamlines, Parameters, Contact Information, and Schedules Download a high-resolution version of the ALS Beamclock. See Beamclock to view the ALS energy-related beamlines beamclock. Beamline Parameters Beamline and endstation technical information is available through the links below. Unless otherwise noted, all beamlines are currently operational. Individual beamline schedules are posted when available. Please contact the responsible beamline scientist for additional schedule information. When calling from off-site, all beamline (BL) phone numbers that begin with a "2" are preceded by 495- (i.e., 495-2014); all others are preceded by 486-. Beamline Number Source Technique/ Group Name Energy Range Beamline Contact Schedule/BL Phone

227

Unusual activation of novel Au/TiO2/AI2O3 xH2O catalysts by calcination  

SciTech Connect

Au/Al{sub 2}O{sub 3} {center_dot} xH{sub 2}O and Au/TiO{sub 2}/Al{sub 2}O{sub 3} {center_dot} xH{sub 2}O (x = 0-3) catalysts were prepared by assembling gold nanoparticles on neat and TiO{sub 2}-modified Al{sub 2}O{sub 3}, AlOOH, and Al(OH){sub 3} supports, and their catalytic activity in CO oxidation was tested either as synthesized or after on-line pretreatment in O{sub 2}-He at 500 C. A promotional effect of TiO{sub 2} on the activity of gold catalysts was observed upon 500 C-pretreatment. The catalyst stability as a function of time on stream was tested in the absence or presence of H{sub 2}, and physiochemical characterization applying BET, ICP-OES, XRD, TEM, and {sup 27}Al MAS NMR was conducted.

Yan, Wenfu [ORNL; Ma, Zhen [ORNL; Mahurin, Shannon Mark [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2008-01-01T23:59:59.000Z

228

Reaction Mechanisms in the Li3AlH6/LiBH4 and Al/LiBH4 Systems for Reversible Hydrogen Storage. Part 1: H capacity and Role of Al  

SciTech Connect

Lithium-based complex hydrides, including lithium aluminum hydrides (LiAlH4, Li3AlH6) and lithium borohydride (LiBH4), are some of the most attractive materials for hydrogen storage due to their high hydrogen contents. In the present work, we investigated the hydrogen storage properties of combined systems of Li3AlH6-LiBH4 and Al-LiBH4, both of which exhibit favorable hydrogen storage properties owing to the formation of AlB2 during dehydrogenation. TGA data showed that TiCl3-doped Li3AlH6/2LiBH4 and 0.5Al/LiBH4 release ~ 8.8 and ~ 8.4 wt.% H2, respectively, with ~ 3.8 and ~ 5.8 wt.% release after rehydrogenation of the dehydrogenation product. XRD results identified LiH and AlB2 phases in the dehydrogenated products, which has suggested a mechanism by which Al contributes to the remarkable improvement of the reversible storage properties of LiBH4 in terms of the temperature and pressure for H2 release/uptake.

Choi, Young Joon; Lu, Jun; Sohn, Hong Yong; Fang, Zhigang Zak

2011-04-07T23:59:59.000Z

229

Effects of preformed alumina scales on the behavior of FeCrAl alloys in simulated coal-gasifier atmospheres  

Science Journals Connector (OSTI)

Iron-based mechanical alloys containing 3.2–6.6 Al, 16.0–24.7 Cr, 0.5 Ti, and 0.5 Y2O3 (mass%) were preoxidized in air at 1373 K for 10–180 min. Alumina scales were formed. Scales were isolated and examined in a ...

J. K. Richard Weber; M. G. Hocking

1989-08-01T23:59:59.000Z

230

Brambilla, et al. Reply  

E-Print Network (OSTI)

Brambilla, et al. Reply: van Megen and Williams (vMW) question our recent claim that dense colloidal hard spheres enter at large volume fraction \\phi a dynamical regime not observed in earlier work and not described by the mode-coupling theory (MCT) of the glass transition.

Giovanni Brambilla; Djamel El Masri; Matteo Pierno; Ludovic Berthier; Luca Cipelletti; George Petekidis; Andrew B. Schofield

2010-08-27T23:59:59.000Z

231

Eine analytische Brennstoffzelle als Alkoholsensor  

Science Journals Connector (OSTI)

Es wird eine analytische Brennstoffzelle zur quantitativen Bestimmung von Alkoholen beschrieben. Als...

H. Huck

232

Smith et al Supporting Information  

E-Print Network (OSTI)

Smith et al 1 Supporting Information for Smith et al. 2006, PLoS Computational Biology 2:e161-hyperpallium apicale; HF-hippocampal formation, and M-mesopallium. #12;Smith et al 2 FigureS2,nolinkswerefoundbetweenelectrodesindifferentbirds,andnolinkswerefoundintothesoundstimulusvariable. CombinedAnalysisofAllBirds'ElectrodesPlusSound #12;Smith et al 3 Analysis of Data from Subsections

Jarvis, Erich D.

233

Combustion synthesis/quasi-isostatic pressing of TiC0.7NiTi cermets: microstructure and transformation characteristics  

E-Print Network (OSTI)

Combustion synthesis/quasi-isostatic pressing of TiC0.7­NiTi cermets: microstructure Abstract TiC0.7­NiTi cermets were produced by com- bustion synthesis followed by quasi-isostatic consolidation while the reaction products were still hot and ductile. The TiC0.7­NiTi cermets were characterized

Meyers, Marc A.

234

ALS Beamlines Directory  

NLE Websites -- All DOE Office Websites (Extended Search)

Beamlines Directory Print Beamlines Directory Print Beamlines, Parameters, Contact Information, and Schedules Download a high-resolution version of the ALS Beamclock. See Beamclock to view the ALS energy-related beamlines beamclock. Beamline Parameters Beamline and endstation technical information is available through the links below. Unless otherwise noted, all beamlines are currently operational. Individual beamline schedules are posted when available. Please contact the responsible beamline scientist for additional schedule information. When calling from off-site, all beamline (BL) phone numbers that begin with a "2" are preceded by 495- (i.e., 495-2014); all others are preceded by 486-. Beamline Number Source Technique/ Group Name Energy Range Beamline Contact Schedule/BL Phone

235

ALS User Meeting Archives  

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User Meeting Archives Print User Meeting Archives Print Past User Meeting Agendas, Workshops, and Awards Year Agenda Workshops David A. Shirley (Science) Klaus Halbach (Instrumentation) Tim Renner (Service) 2012 2012 User Meeting Agenda 2012 User Meeting Workshops 2012 ALS User Meeting Awards Carl Percival, Dudley Shallcross, Craig Taatjes and David Osborn (Sandia), for making the first direct measurements of the reactions of Criegee intermediates, and showing that their impact on tropospheric chemistry and climate may be substantially greater than previously assumed. 2012 ALS User Meeting Awards Jeff Dickert and Simon Morton of Berkeley Lab's Physical Biosciences Division for the invention and implementation of the Compact Variable Collimator (CVC), which has led to a dramatic increase in productivity of protein crystallography.

236

ALS Beamlines Directory  

NLE Websites -- All DOE Office Websites (Extended Search)

Beamlines Directory Print Beamlines Directory Print Beamlines, Parameters, Contact Information, and Schedules Download a high-resolution version of the ALS Beamclock. See Beamclock to view the ALS energy-related beamlines beamclock. Beamline Parameters Beamline and endstation technical information is available through the links below. Unless otherwise noted, all beamlines are currently operational. Individual beamline schedules are posted when available. Please contact the responsible beamline scientist for additional schedule information. When calling from off-site, all beamline (BL) phone numbers that begin with a "2" are preceded by 495- (i.e., 495-2014); all others are preceded by 486-. Beamline Number Source Technique/ Group Name Energy Range Beamline Contact Schedule/BL Phone

237

Effect of reinforcing particle type on morphology and age-hardening behavior of Al–4.5 wt.% Cu based nanocomposites synthesized through mechanical milling  

SciTech Connect

The effects of reinforcing particle type (SiC and TiC) on morphology and precipitation hardening behavior of Al–4.5%Cu based nanocomposites synthesized via mechanical milling were investigated in the current work. In order to study the microstructure and morphology of mechanically milled powder, X-ray diffraction technique, scanning electron microscopy and high resolution transmission electron microscopy were utilized. Results revealed that at the early stages of mechanical milling, when reinforcing particles are polycrystal, the alloying process is enhanced more in the case of using the TiC particles as reinforcement. But, at the final stages of mechanical milling, when reinforcing particles are single crystal, the alloying process is enhanced more in the case of using the SiC ones. Transmission electron microscopy results demonstrated that Al–4.5 wt.%Cu based nanocomposite powders were synthesized and confirmed that the mutual diffusion of aluminum and copper occurs through the interfacial plane of (200). The hardness results showed that not only does introducing 4 vol.% of reinforcing particles (SiC or TiC) considerably decrease the porosity of the bulk composite samples, but also it approximately doubles the hardness of Al–4.5 wt.%Cu alloy (53.4 HB). Finally, apart from TEM and scanning electron microscopy observation which are localized, a decline in hardness in the TiC and SiC contained samples, respectively, after 1.5 and 2 h aging time at 473 K proves the fact that the size of SiC particles is smaller than the size of the TiC ones. - Highlights: ? HRTEM results show mutual diffusion of Al and Cu occurs through the (200) planes. ? TiC particles enhance alloying process more than the SiC ones at the early stages of MM. ? SiC particles enhance alloying process more than the TiC ones at the final stages of MM.

Mostaed, A., E-mail: alimostaed@yahoo.com [Advanced Materials and Nanotechnology Research Center, Faculty of Mechanical Engineering, K.N. Toosi University of Technology, 16765-3381 Pardis Street, Tehran (Iran, Islamic Republic of); Saghafian, H.; Mostaed, E. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, 16846-13114 Narmak, Tehran (Iran, Islamic Republic of); Shokuhfar, A. [Advanced Materials and Nanotechnology Research Center, Faculty of Mechanical Engineering, K.N. Toosi University of Technology, 16765-3381 Pardis Street, Tehran (Iran, Islamic Republic of); Rezaie, H.R. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, 16846-13114 Narmak, Tehran (Iran, Islamic Republic of)

2013-02-15T23:59:59.000Z

238

Towards electrical spin injection into LaAlO3–SrTiO3  

Science Journals Connector (OSTI)

...their remarkable multi-functional and...already provide such building blocks for charge-based...found in the oxides family (e.g. superconductivity...from the outstanding multi-functional properties...their remarkable multi-functional and...already provide such building blocks for charge-based...

2012-01-01T23:59:59.000Z

239

E-Print Network 3.0 - alloys sistema ti-al-mo Sample Search Results  

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89 the machinist mar 2007 agnesium is 36 per cent Summary: alloys. Reducing the automobile weights by certain amount will result in similar percentage... a combination of...

240

XPS Analysis of Ti6Al4V Oxidation Under UHV Conditions  

Science Journals Connector (OSTI)

An alternative strategy to study the distribution of oxides in the passive layer is to monitor their growth directly on the metal surface. For this, previous oxide layers are removed by sputtering to obtain clean...

M. Hierro-Oliva; A. M. Gallardo-Moreno…

2014-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Thermodynamic Instability at the Stoichiometric LaAlO3/SrTiO3...  

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Instruments: Ultra-high Vacuum, Low-temperature Scanning Probe Microscope Instrument, or UHV LT SPM Tags: Nanoscope IIIa topographical nanostructures nanodevices oxides catalysis...

242

Optical Monitoring in Laser Cladding of Ti6Al4V  

Science Journals Connector (OSTI)

The TRUMPF 505 DMD machine with a 5-kW CO2 laser was used to enable scaling-up laser cladding (LC) to an industrial level. The ... powder. The variations of brightness temperature versus laser power and cladding ...

I. Smurov; M. Doubenskaia; S. Grigoriev; A. Nazarov

2012-12-01T23:59:59.000Z

243

Photocatalytic H2 production from ethanol over Au/TiO2 and Ag/TiO2  

Science Journals Connector (OSTI)

This paper compares the photocatalytic activities of Au/TiO2 (Au loadings 0-4 wt.%) and Ag/TiO2 photocatalysts (Ag loadings 0-4 wt.%) for H2 production from ethanol-water mixtures under UV irradiation. Au and Ag nanoparticles were deposited on commercially available Degussa P25 TiO2 (85% anatase, 15% rutile) using deposition-precipitation and liquid impregnation methods, respectively. TEM analyses showed the average noble metal nanoparticle size to be ~5 nm for the Au/TiO2 photocatalysts and ~3 nm for the Ag/TiO2 photocatalysts. Au/TiO2 photocatalysts showed a strong localised surface plasmon resonance (LSPR) at 570 nm characteristic for nanocrystalline Au. Complementary XRD studies confirmed that Au and Ag nanoparticles were present in metallic form. Photoluminescence measurements revealed that Au and Ag nanoparticles effectively suppress electron-hole recombination in TiO2, thereby enhancing the photocatalytic activity of TiO2 for hydrogen production. Au/TiO2 photocatalysts were far more active for H2 production from ethanol-water mixtures than Ag/TiO2 photocatalysts. A 1 wt.% Au/TiO2 photocatalyst yielded the highest H2 production rate (34 mmol g?1 h?1). Amongst the Ag/TiO2 photocatalysts, the 2 wt.% Ag/TiO2 sample was the most active (3.7 mmol g?1 h?1). Results are rationalised in terms of differences in the electronic properties of supported Au and Ag nanoparticles, with the former being near ideal for H2 production.

Vedran Jovic; Pei-Huan Hsieh; Wan-Ting Chen; Dongxiao Sun-Waterhouse; Tilo Söhnel; Geoffrey I.N. Waterhouse

2014-01-01T23:59:59.000Z

244

Magnetic properties of epitaxial Co-doped anatase TiO2 thin films with excellent structural quality  

SciTech Connect

The heteroepitaxy of Co-doped anatase TiO2 on LaAlO3(001) has been refined with the goal of determining the relationship between structural quality and magnetic ordering. By significantly reducing the deposition rate and substrate temperature, well-ordered Co:TiO2 films with unprecedented crystalline quality were obtained by oxygen-plasma-assisted molecular beam epitaxy, as characterized by x-ray diffraction. These films exhibit uniform Co doping, with no evidence of Co segregation or secondary phases throughout the film depth or on the surface. Despite the improvement in crystalline quality and Co distribution, the films exhibit negligible ferromagnetism, with saturation moments of only ~0.1 ?B/Co. This loss of ferromagnetism is in stark contrast to faster-grown Co:TiO2 films, where a higher growth rate and substrate temperature typically result in lower crystalline quality, a highly non-uniform Co distribution, and average saturation moments of ~1.2 ?B/Co. The presence of ferromagnetism in faster-grown Co:TiO2 does not appear to arise from intrinsic point defects present in the bulk material, such as charge-compensating oxygen vacancies, but is instead attributed to the presence of extended structural defects.

Kaspar, Tiffany C.; Droubay, Timothy C.; McCready, David E.; Nachimuthu, Ponnusamy; Heald, Steve M.; Wang, Chong M.; Lea, Alan S.; Shutthanandan, V.; Chambers, Scott A.; Toney, Michael F.

2006-07-26T23:59:59.000Z

245

Effects of TiCl4 Purity on the Sinterability of Armstrong-Processed Ti Powder  

SciTech Connect

A series of high purity and low purity powders were synthesized from TiCl4 by the Armstrong process. While both powders displayed swelling when consolidated and sintered, the lower purity powder exhibited this phenomenon in significantly lower degree. The improvement is attributed to the increase in the onset of sintering temperature, which mitigates the entrapment of volatile impurities that would otherwise lead to pore formation and growth. The net effect is that the use of a lower purity TiCl4 may beneficial in two ways: (1) it is a potentially lower cost precursor to Ti powder production and (2) the trace impurities allow higher density components to be fabricated via a typical low-cost press and sinter approach.

Weil, K. Scott; Hovanski, Yuri; Lavender, Curt A.

2009-04-03T23:59:59.000Z

246

Negative ion photodetachment spectroscopy of the Al3O2 , Al3O3 , Al4Ox , Al5Ox (x = 35), Al6O5 , and Al7O5 clusters  

E-Print Network (OSTI)

Negative ion photodetachment spectroscopy of the Al3O2 , Al3O3 , Al4Ox , Al5Ox (x = 3­5), Al6O5 , and Al7O5 clusters Giovanni Meloni, Michael J. Ferguson and Daniel M. Neumark Department of Chemistry as an Advance Article on the web 9th September 2003 The Al3O2 , Al3O3 , Al4Ox , Al5Ox (x ¼ 3­5), Al6O5 , and Al7

Neumark, Daniel M.

247

Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Abstract: Understanding hydrogen formation on TiO2...

248

2013 ALS User Meeting Highlights  

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2013 ALS User Meeting Highlights 2013 ALS User Meeting Highlights 2013 ALS User Meeting Highlights Print This year's ALS User Meeting launched with a welcome from Users' Executive Committee Chair Corie Ralston and LBNL Director Paul Alivisatos. ALS Director Roger Falcone followed with a "state of the ALS" presentation that began with a reminder of the ALS mission, which he noted remains true even in the midst of a government shutdown: "Supporting users in doing outstanding science in a safe environment." Falcone gave the 414 meeting attendees an update on the ALS beamlines, which included good news about increased user numbers thanks to the new RAPIDD access system, enhanced robotics, and remote capabilities. Falcone reflected that ALS metrics continue to represent our highly productive users-the number of journal articles and papers per user that come from ALS research have continued to grow in the past year. Looking forward, Falcone touched on how a proposed ALS upgrade to a diffraction-limited light source would increase scientific capabilities.

249

2013 ALS User Meeting Highlights  

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2013 ALS User Meeting Highlights 2013 ALS User Meeting Highlights 2013 ALS User Meeting Highlights Print Thursday, 24 October 2013 09:06 This year's ALS User Meeting launched with a welcome from Users' Executive Committee Chair Corie Ralston and LBNL Director Paul Alivisatos. ALS Director Roger Falcone followed with a "state of the ALS" presentation that began with a reminder of the ALS mission, which he noted remains true even in the midst of a government shutdown: "Supporting users in doing outstanding science in a safe environment." Falcone gave the 414 meeting attendees an update on the ALS beamlines, which included good news about increased user numbers thanks to the new RAPIDD access system, enhanced robotics, and remote capabilities. Falcone reflected that ALS metrics continue to represent our highly productive users-the number of journal articles and papers per user that come from ALS research have continued to grow in the past year. Looking forward, Falcone touched on how a proposed ALS upgrade to a diffraction-limited light source would increase scientific capabilities.

250

GAMETOPHYTIC SELF-INCOMPATIBILITY (Newbigin et al., 1993; Matton et al., 1994; Dodds et al., 1997)  

E-Print Network (OSTI)

GAMETOPHYTIC SELF-INCOMPATIBILITY (Newbigin et al., 1993; Matton et al., 1994; Dodds et al., 1997, but expressed at high levels in the style. d. There are high levels of this gene product in self-incompatible species, whereas very low levels in self-compatible species. f. Generalized features: #12;Self-incompatibility

Bhattacharyya, Madan Kumar

251

A New Method of Low Cost Production of Ti Alloys to Reduce Energy...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

or otherwise restricted information. Project Objective Develop a novel low cost method for manufacturing Ti Demonstrate the mechanical properties of Ti using the...

252

Film Coating Process Research and Characterization of TiN Coated Racetrack-type Ceramic Pipe  

E-Print Network (OSTI)

TiN film was coated on the internal face of racetrack-type ceramic pipe by three different methods: radio-frequency sputtering, DC sputtering and DC magnetron sputtering. The deposition rates of TiN film under different coating methods were compared. According to the AFM, SEM, XPS test results,these properties were analyzed, such as TiN film roughness and surface morphology. At the same time, the deposition rates were studied under two types' cathode, Ti wires and Ti plate. According to the SEM test results, Ti plate cathode can improve the TiN/Ti film deposition rate obviously.

Wang, Jie; Zhang, Bo; Wei, Wei; Fan, Le; Pei, Xiangtao; Hong, Yuanzhi; Wang, Yong

2015-01-01T23:59:59.000Z

253

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...  

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Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

254

N NE EX XT T G GE EN NE ER RA AT TI IO ON N S SA AF FE EG  

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NE NE EX XT T G GE EN NE ER RA AT TI IO ON N S SA AF FE EG GU UA AR RD DS S I IN NI IT TI IA AT TI IV VE E ( (N NG GS SI I) ) O OP PP PO OR RT TU UN NI IT TI IE ES S F FO OR R S ST TU UD DE EN NT TS S A AN ND D Y YO OU UN NG G P PR RO OF FE ES SS SI IO ON NA AL LS S I IN NT TE ER RE ES ST TE ED D I IN N S SA AF FE EG GU UA AR RD DS S/ /N NO ON NP PR RO OL LI IF FE ER RA AT TI IO ON N The Next Generation Safeguards Initiative (NGSI) was launched by the National Nuclear Security Administration (NNSA) in FY 2008 to develop the policies, concepts, technologies, expertise, and infrastructure necessary to strengthen and sustain the international safeguards system as it evolves to meet new challenges over the next 25 years. NGSI's Human Capital Development subprogram 1 aims to revitalize and expand the international safeguards human capital base in the United States by attracting, educating, training, and retaining

255

Erosion resistance of continuously reinforced SiC–Ti-based metal matrix composites by a SiC/water slurry jet  

Science Journals Connector (OSTI)

The erosion of a continuously reinforced SiC (Sigma 1140 plus)/Ti–6Al–4V composite was investigated with a SiC/water slurry jet at various angles on a plane perpendicular to the direction of the reinforcement. The results demonstrate the combination of both ceramic and metallic properties. Both the low-angle erosion resistance of ceramics as well as the high-angle resistance of a metallic alloy lead to an overall reduction in erosion rate at the various angles. Ti/SiC composite shows the best erosive wear resistance indicating that the combination effect between ductile Ti-based matrix and high strength SiC fibre for continuously fibre-reinforced Ti-based metal matrix composites (MMCs) plays a key role in increasing the erosive resistance. To gain a better understanding of the combination and synergistic enhancement of erosion resistance for two components in SiC/Ti composite materials, a shadowing effect and effect of reducing impact energy on SiC fibre during erosion are discussed. A simple theoretical model based on experimental data and a modified inverse rule-of-mixtures averaging law of erosion resistance for SiC fibre-reinforced \\{MMCs\\} are discussed.

Q Fang; P.S Sidky; G.M Hocking

1999-01-01T23:59:59.000Z

256

ENVIRONMENT AL REVI  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ENVIRONMENT ENVIRONMENT AL REVI EW for CATEG ORI CAL EXCLUS ION DETE RMINATION Rocky Mo unta in Region, Weste rn A rea Power Administra tion Stru cture Replace ment Fla min g Go rge-Vern a l No.3 138-kV tra nsmiss ion lin e (Struct ure No. 25/6) Spr ing 201 2 A. Ilricf J)cscription of Proposal: Western Area Power Adm inistration (Western) proposes to replace Structure No. 25/6 on the Flaming Gorge-Vernal No.3 138-kV transmission line. The structure is located on Bureau of Land Management lands in Uintah County. Utah (Township 3S, Range 22E, Section 7; Donkey Flat 7.5' USGS quadrangle). Work consists of removal and in-kind replacement of the wood H-frame structure and anchors utilizing rubber tired vehicles. crane, bucket truck, pole trucks/trailers, auger rig. and pick-up trucks. All work will be conducted on Western's existing

257

Microstructure and mechanical properties of Ni sub 3 Al-based alloys reinforced with particulates  

SciTech Connect

Hot-extrusion was used to produce Ni{sub 3}Al-based alloys to which 10 vol % TiN, NbC, HfO{sub 2}, or HfN was added for reinforcement. The TiN, NbC, and HfO{sub 2} particulates produced Ni{sub 3}Al-matrix composites in which no reaction was noted at the particle-matrix interface. However, the addition of HfN resulted in extensive reaction in which the hafnium appeared to diffuse into the matrix. Microstructures of this alloy showed a complex array of phases and voids where the HfN particles are presumed to have been originally. Hot hardness, compression, and compression creep tests were preformed on specimens cut from the extruded bar of each alloy. No significant strengthening was observed for the alloys containing TiN, NbC, or HfO{sub 2}. However the HfN-containing alloy did show significant strengthening in simple compression and compression creep. This presentation will include microstructures and the results of the mechanical properties tests. 26 refs., 5 figs.

McKamey, C.G.; Carmichael, C.A.

1990-01-01T23:59:59.000Z

258

Electron energy loss study of TiC[111].  

SciTech Connect

The electron energy loss (EEL) spectra of TiC (111) were measured over a wide range of electron primary energies. The electron energy losses below 16 eV were analyzed using the theoretical band calculations of Price and Cooper [11]. The volume and surface plasma excitations were identified from their electron primary energy dependence. Energy losses due to core electrons autoinization effects were identified above 35 eV. We observed a difference in the electronic structure of the surface vs. the bulk of TiC. The temperature dependence of the EEL spectra was studied between 300 to 1250 K. The reaction of the TiC surface with ethylene and oxygen was also investigated. The ethylene bonding to the TiC surface was found to be very weak. There is evidence of the formation of surface defects on the TiC (111) surface at high temperatures.

Chan, Y.; Lee, S. W.; Liao, D.; Cooper, B. R.; Montano, P. A.; Materials Science Division; Brooklyn Coll. of City Univ. of New York; West Virginia Univ.

1992-01-01T23:59:59.000Z

259

Energieversorgung als Dienstleistung—Elektrizitätswirtschaft  

Science Journals Connector (OSTI)

Im Herbst 1988 legte die VDEW ihren Hitgliedsunternehmen das Positionspapier “Die Stromversorger als Dienstleistungspartner” vor und machte es zugleich einer interessierten Öffentlichkeit bekannt. Das Position...

K. Bechthold

1991-01-01T23:59:59.000Z

260

Energieversorgung als Dienstleistung—Mineralölwirtschaft  

Science Journals Connector (OSTI)

Meine Damen, meine Herren, Energieversorgung als Dienstleistung, dieses Thema beherrscht die Energiediskussion seit einiger Zeit. Der Begriff ist etwas schillernd, seine genaue Eingrenzung schwierig, aber er k...

P. Schillmöller

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Transiträume als Orte des Konsums.  

E-Print Network (OSTI)

??Insbesondere seit den 1990er Jahren ist international eine wachsende Bedeutung der Transiträume Tankstelle, Flughafen und Bahnhof als Einzelhandels- und Dienstleistungsstandorte zu beobachten. Vielfältige Gründe sowohl… (more)

Korn, Juliane

2006-01-01T23:59:59.000Z

262

Thermodynamics of the solid solution of hydrogen in ?-titanium alloys: ?-TiMo and ?-TiRe  

Science Journals Connector (OSTI)

The solid solution of hydrogen has been investigated in a series of random ?-TiMo alloys ranging from 0–65 atom % Mo via determination of pressure-composition-temperature relationships; additionally, one (?-TiRe alloy (Ti37 atom % Re) was investigated. The thermodynamic parameters of hydrogen solution were generated from the p-c-T data. The relative partial molar enthalpy at infinite dilution, ?H?Ho, exhibited by ?-TiMo alloys were adjusted to conditions of fixed volume, that of pure ?-Ti. It was found that variations in the resulting ?E?Ho correlated roughly with variations in the electron density of states at the Fermi level. The relative partial molar entropy at infinite dilution was found to vary linearly with Mo content and it is suggested that this trend reflects a blocking of potentially available interstitial sites to hydrogen occupation by Mo atoms at small hydrogen contents. Examination of the excess free energy vs hydrogen content relationships indicates that effects resulting from accommodation of hydrogen electrons by the metal conduction band are significant even at small hydrogen contents in the TiMo alloys; thus, explicit determination of the H-H interaction is not possible in the alloys. By contrast, electronic effects in pure ?-Ti are negligible at small HM and under fixed volume conditions, the H-H interactions in ?-Ti are attractive.

J.F. Lynch; J. Tanaka

1981-01-01T23:59:59.000Z

263

CO Oxidation on Aun/TiO2 Catalysts Produced by Size-Selected Cluster Sungsik Lee, Chaoyang Fan, Tianpin Wu, and Scott L. Anderson*  

E-Print Network (OSTI)

. Indeed, Fu et al.2 recently showed that activity for the water gas shift reaction on Au/CeO2 and Pt/CeO2 TiO2 in an ultrahigh vacuum (UHV-base pressure 1 Ã? 10-10 mbar). The kinetic energy spread of the Aun-8% of oxygen vacancies. (The XPS vacancy estimate was calibrated by a separate water dissociation experiment

Anderson, Scott L.

264

EPR study of Ti3+ ions formed under beta irradiation in silicate  

E-Print Network (OSTI)

1 EPR study of Ti3+ ions formed under beta irradiation in silicate glasses P. Lombard1* , N. Ollier in various silicate glasses have been studied by EPR spectroscopy at 20 K. Different parameters like the [Na of the Ti3+ ion EPR spectra in different Ti-doped silicate glasses has shown three different Ti3

Boyer, Edmond

265

Measurement of neutron capture on 50Ti at thermonuclear energies  

E-Print Network (OSTI)

At the Karlsruhe and Tuebingen 3.75 MV Van de Graaff accelerators the thermonuclear 50Ti(n,gamma)51Ti(5.8 min) cross section was measured by the fast cyclic activation technique via the 320.852 and 928.65 keV gamma-ray lines of the 51Ti-decay. Metallic Ti samples of natural isotopic composition and samples of TiO2 enriched in 50Ti by 67.53 % were irradiated between two gold foils which served as capture standards. The capture cross-section was measured at the neutron energies 25, 30, 52, and 145 keV, respectively. The direct capture cross section was determined to be 0.387 +/- 0.011 mbarn at 30 keV. We found evidence for a bound state s-wave resonance with an estimated radiative width of 0.34 eV which destructively interfers with direct capture. The strength of a suggested s-wave resonance at 146.8 keV was determined. The present data served to calculate, in addition to the directly measured Maxwellian averaged capture cross sections at 25 and 52 keV, an improved stellar 50Ti(n,gamma)51Ti rate in the thermonuclear energy region from 1 to 250 keV. The new stellar rate leads at low temperatures to much higher values than the previously recommended rate, e.g., at kT=8 keV the increase amounts to about 50 %. The new reaction rate therefore reduces the abundance of 50Ti due to s-processing in AGB stars.

P. V. Sedyshev; P. Mohr; H. Beer; H. Oberhummer; Yu. P. Popov; W. Rochow

1999-07-28T23:59:59.000Z

266

Allegato "B" DOMANDA DI PARTECIPAZIONE AL CONCORSO DI AMMISSIONE AL  

E-Print Network (OSTI)

IN ROBOTICA, NEUROSCIENZE, NANOTECNOLOGIE E SCOPERTA FARMACI IN COLLABORAZIONE CON LA FONDAZIONE IIT Si prega'ammissione al Corso di Dottorato di Ricerca in Robotica, Neuroscienze, Nanotecnologie e Scoperta Farmaci

Sandini, Giulio

267

(12) United States Patent Harvey et al.  

E-Print Network (OSTI)

(12) United States Patent Harvey et al. (54) ANALYZING RETURN ON INVESTMENT OF ADVERTISING US 2009/0259518 Al Oct. 15,2009 Int. Cl. G06F 17/30 (2006.01) G07G 1/00 (2006.01) U.S. Cl et al. 911980 Block et al. 511982 Eskin et al. 1111982 Barber et al. 711985 Block et al. 111996

Shamos, Michael I.

268

Characterization and catalytic performance of vanadium supported on sulfated Ti-PILC catalysts issued from different Ti-precursors in selective catalytic reduction of nitrogen oxide by ammonia  

Science Journals Connector (OSTI)

Vanadium supported on sulfated Ti-pillared clay catalysts (STi-PILCs) issued from different Ti-precursors were investigated for selective catalytic reduction (SCR) of NO by NH3 in the presence of O2. The STi-PILC...

J. Arfaoui; L. Khalfallah Boudali; A. Ghorbel; G. Delahay

2009-12-01T23:59:59.000Z

269

??e¦ia e e ¡et ??? oa¦0 to 3i5¦ontinBoB5 Pie¦eFi5e Hinea ¢tiTiUation ...  

E-Print Network (OSTI)

Pie¦eFi5e Hinea ¢tiTiUation. I.R. de Farias JR., M. ?hao, and H. ?hao. State University of New York at jumalo. {defariasy m|haoy |hon??ia}@??ffalo.ed?.

270

AL PRO | Open Energy Information  

Open Energy Info (EERE)

AL PRO AL PRO Jump to: navigation, search Name AL-PRO Place Grossheide, Lower Saxony, Germany Zip 26532 Sector Wind energy Product AL-PRO is an inndependent expert office for wind forecasts, wind potential studies, turbulence inquiries, visualizations as well as sound and shade throw forecasts Coordinates 53.592743°, 7.34313° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":53.592743,"lon":7.34313,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

271

In Memory of Al Cameron  

E-Print Network (OSTI)

Al Cameron, who died recently (October 3, 2005) at 80, was one of the giants in astrophysics. His insights were profound and his interests were wide-ranging. Originally trained as a nuclear physicist, he made major contributions in a number of fields, including nuclear reactions in stars, nucleosynthesis, the abundances of the elements in the Solar System, and the origin of the Solar System and the Moon. In 1957, Cameron and, independently, Burbidge, Burbidge, Fowler and Hoyle, wrote seminal papers on nuclear astrophysics. Most of our current ideas concerning element formation in stars have followed from those two pioneering and historical works. Al also made many contributions in the field of Solar System physics. Particularly noteworthy in this regard was Cameron's work on the formation of the Moon. Al was also a good friend and mentor of young people. Al Cameron will be missed by many in the community both for his scientific contributions and for his friendship.

John J. Cowan; James W. Truran

2006-11-27T23:59:59.000Z

272

Nature of Transactions (TI) Code | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Nature of Transactions (TI) Code | National Nuclear Security Administration Nature of Transactions (TI) Code | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Nature of Transactions (TI) Code Home > About Us > Our Programs > Nuclear Security > Nuclear Materials Management & Safeguards System > NMMSS Information, Reports & Forms > Code Tables > Nature of Transactions (TI) Code

273

Aluminium alloy based hydrogen storage tank operated with sodium aluminium hexahydride Na3AlH6  

Science Journals Connector (OSTI)

Abstract Here we present the development of an aluminium alloy based hydrogen storage tank, charged with Ti-doped sodium aluminium hexahydride Na3AlH6. This hydride has a theoretical hydrogen storage capacity of 3 mass-% and can be operated at lower pressure compared to sodium alanate NaAlH4. The tank was made of aluminium alloy EN AW 6082 T6. The heat transfer was realised through an oil flow in a bayonet heat exchanger, manufactured by extrusion moulding from aluminium alloy EN AW 6060 T6. Na3AlH6 is prepared from 4 mol-% TiCl3 doped sodium aluminium tetrahydride NaAlH4 by addition of two moles of sodium hydride NaH in ball milling process. The hydrogen storage tank was filled with 213 g of doped Na3AlH6 in dehydrogenated state. Maximum of 3.6 g (1.7 mass-% of the hydride mass) of hydrogen was released from the hydride at approximately 450 K and the same hydrogen mass was consumed at 2.5 MPa hydrogenation pressure. 45 cycle tests (rehydrogenation and dehydrogenation) were carried out without any failure of the tank or its components. Operation of the tank under real conditions indicated the possibility for applications with stationary HT-PEM fuel cell systems.

R. Urbanczyk; K. Peinecke; M. Felderhoff; K. Hauschild; W. Kersten; S. Peil; D. Bathen

2014-01-01T23:59:59.000Z

274

E-Print Network 3.0 - al suolo al Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

DEI CAMBIAMENTI Summary: tradizionali rimboschimenti vincoli al dissodamento aumento delle provvigioni e dei turni riduzione degli... Commissione al Consiglio e al...

275

$Nb_{3}Al$ prototype conductor for the transmission line magnet  

E-Print Network (OSTI)

The Very Large Hadron Collider (VLHC), under consideration for construction at Fermilab in the next 1-2 decades, is a 100 TeV cm pp collider. A major cost driver is the magnet. R&D is underway on several possible magnet designs. A low-field (2T) superferric magnet, sometimes called a transmission line magnet, may be the most cost- effective route to the VLHC. Although NbTi is now the cheapest superconductor measured in cost/kA-meter, Nb/sub 3/Al has the potential advantage that it remains superconducting at higher temperature. It may be particularly suited to the single "turn" and long straight lengths of the transmission line design. The combination of the simple magnet design and the higher strain tolerance than e.g. Nb/sub 3/Sn allows a simple process of cable fabrication, reaction, and magnet assembly. This higher strain tolerance is an advantage for splicing in the field. Sumitomo Electric Industries is producing an Nb/sub 3/Al conductor for the Fermilab low-field magnet program. (9 refs).

Barzi, E; Malamud, E; Mazur, P O; Piekarz, H; Wake, M; Hayashi, K; Koganeya, M

1999-01-01T23:59:59.000Z

276

Superhydrophilic TiO2 surface without photocatalytic activation  

NLE Websites -- All DOE Office Websites (Extended Search)

Superhydrophilic TiO2 surface without photocatalytic activation Superhydrophilic TiO2 surface without photocatalytic activation Title Superhydrophilic TiO2 surface without photocatalytic activation Publication Type Journal Article Year of Publication 2010 Authors Zormpa, Vasileia, Xiaobo Chen, and Samuel S. Mao Journal Applied Physics Letter Volume 96 Issue 9 Date Published 12/2009 Abstract Since the discovery of extreme surface wetting phenomenon induced by ultraviolet photocatalysis, TiO2 has become the material of choice for environmental friendly applications such as self-cleaning coatings. Nevertheless, it remains a significant challenge to realize surfaces exhibiting persistent superhydrophilicity but without the need of external stimuli. We report a bioinspired TiO2 nanostructure that shows extreme superhydrophilicity without the need of light activation, and with stability against successive wetting-dewetting cycles. This ultimate TiO2 wetting surface exhibits high transmittance from near ultraviolet to the infrared, thus enabling practical antifogging technologies where transparency is critical.

277

Weldability and toughness assessment of Ti-microalloyed offshore steel  

SciTech Connect

The present study has been carried out to investigate the coarse-grained heat-affected zone (CGHAZ) microstructure and crack tip opening displacement (CTOD) toughness of grade StE 355 Ti-microalloyed offshore steels. Three parent plates (40-mm thick) were studied, two of which had Ti microalloying with either Nb + V or Nb also present. As a third steel, conventional StE 355 steel without Ti addition was welded for comparison purposes. Multipass tandem submerged arc weld (SAW) and manual metal arc weld (SMAW) welds were produced. Different heat-affected zone (HAZ) microstructures were simulated to ascertain the detrimental effect of welding on toughness. All HAZ microstructures were examined using optical and electron microscopy. It can be concluded that Ti addition with appropriate steel processing, which disperses fine TiN precipitates uniformly, with a fine balance of other microalloying elements and with a Ti/N weight ratio of about 2.2, is beneficial for HAZ properties of StE 355 grade steel.

Rak, I.; Gliha, V. [Univ. of Maribor (Slovenia). Faculty of Mechanical Engineering; Kocak, M. [GKSS Research Center Geesthacht (Germany)

1997-01-01T23:59:59.000Z

278

Shape memory behavior of ultrafine grained NiTi and TiNiPd shape memory alloys  

E-Print Network (OSTI)

The cyclic instability in shape memory characteristics of NiTi-based shape memory alloys (SMAs), such as transformation temperatures, transformation and irrecoverable strains and transformation hysteresis upon thermal and mechanical cycling limits...

Kockar, Benat

2009-05-15T23:59:59.000Z

279

Deposition of TiN and HfO{sub 2} in a commercial 200 mm remote plasma atomic layer deposition reactor  

SciTech Connect

The authors describe a remote plasma atomic layer deposition reactor (Oxford Instruments FlexAL trade mark sign ) that includes an inductively coupled plasma source and a load lock capable of handling substrates up to 200 mm in diameter. The deposition of titanium nitride (TiN) and hafnium oxide (HfO{sub 2}) is described for the combination of the metal-halide precursor TiCl{sub 4} and H{sub 2}-N{sub 2} plasma and the combination of the metallorganic precursor Hf[N(CH{sub 3})(C{sub 2}H{sub 5})]{sub 4} and O{sub 2} plasma, respectively. The influence of the plasma exposure time and substrate temperature has been studied and compositional, structural, and electrical properties are reported. TiN films with a low Cl impurity content were obtained at 350 deg. C at a growth rate of 0.35 A /cycle with an electrical resistivity as low as 150 {mu}{omega} cm. Carbon-free (detection limit <2 at. %) HfO{sub 2} films were obtained at a growth rate of 1.0 A /cycle at 290 deg. C. The thickness and resisitivity nonuniformity was <5% for the TiN and the thickness uniformality was <2% for the HfO{sub 2} films as determined over 200 mm wafers.

Heil, S. B. S.; Hemmen, J. L. van; Hodson, C. J.; Singh, N.; Klootwijk, J. H.; Roozeboom, F.; Sanden, M. C. M. van de; Kessels, W. M. M. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Oxford Instruments Plasma Technology, North End, Yatton BS49 4AP (United Kingdom); Philips Research Laboratories, High Tech Campus 4, 5656 AE Eindhoven (Netherlands); NXP Semiconductors Research, High Tech Campus 4, 5656 AE Eindhoven (Netherlands); Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

2007-09-15T23:59:59.000Z

280

Visible-Light Responsive Photocatalytic Fuel Cell Based on Ag/TiO2-NTs Photoanode and Cu2O/TiO2 Photocathode for Simultaneous Wastewater Treatment and Electricity Generation  

Science Journals Connector (OSTI)

A visible-light driven photocatalytic fuel cell (PFC) system comprised of Ag/TiO2-NTs photoanode and Cu2O/TiO2/Ti photocathode was established for providing a self-sustained and...

Liao, Wenjuan

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Plasma-sprayed CaTiSiO5 ceramic coating on Ti-6Al-4V with excellent bonding strength, stability and cellular bioactivity  

Science Journals Connector (OSTI)

...doi:10.1016/j.biomaterials.2004.09.019 . Wu, C , J Chang, S Ni, and J Wang2006 In vitro bioactivity of akermanite ceramics. J. Biomed. Mater. Res. A. 76, 73-80. Wu, C , J Chang, W Zhai, and S NiA novel bioactive porous bredigite...

2009-01-01T23:59:59.000Z

282

Microsoft Word - AL2005-01.doc  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Acquisition Letters (AL) that remain in effect are identified below. All other previously issued ALs have been superseded by a formal rule-making, incorporated into other...

283

Llanto al pie del Monte Carmelo  

E-Print Network (OSTI)

llantos feroces, llorando al pie de aquella fuente te estoySpring, 1988) Monte Carmelo al pie del Hay tiempo que no por

Ferrer, Juan José Prat

1988-01-01T23:59:59.000Z

284

Magneto-transport in LaTi{sub 1?x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures  

SciTech Connect

We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

Kumar, Pramod, E-mail: pramodnpl2011@gmail.com; Dogra, Anjana, E-mail: pramodnpl2011@gmail.com; Budhani, R. C., E-mail: pramodnpl2011@gmail.com [Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Marg, New Delhi-110012 (India)

2014-04-24T23:59:59.000Z

285

Hexaferrite M (Co, Ti) magnetic properties optimization  

SciTech Connect

Barium hexaferrites are anisotropic iron oxides which can present high values of permeability. We have studied Ba (Co, Ti){sub x}Fe{sub 12-2x}O{sub 19} compositions. Powders are synthesized using the ceramic method: stoichiometric amounts of basic components are ground and fired at high temperature (1170{degrees}C) to obtain the desired phase. The powders are then ground for 6 hours in order to reduce the particle size. The slurry is cast in a plaster matrix. This matrix is rotated between the poles of a stationary electromagnet. Fields of approximately 500 Oe are used for the orientation procedure. Samples are then sintered for different temperatures between 1200 and 1300{degrees}C. We present results (magnetization, permeability, permittivity, orientation rate) obtained for diverse compositions (1.1

Autissier, D.; Rousselle, D.; Podembski, A. [CEA-DAM, Bruyeres-le-Chatel (France)

1995-09-01T23:59:59.000Z

286

ALS Doctoral Fellowship in Residence  

NLE Websites -- All DOE Office Websites (Extended Search)

Doctoral Fellowship in Residence Print Doctoral Fellowship in Residence Print The Advanced Light Source (ALS), a division of Lawrence Berkeley National Laboratory, is a national user facility that generates intense x-ray radiation for scientific and technological research. As the world's first third-generation synchrotron radiation source, the ALS offers outstanding performance in the VUV-soft x-ray energy range and excellent performance into the hard x-ray region. The facility welcomes researchers from universities, industries, and government laboratories around the world. It is funded by the U.S. Department of Energy, Office of Basic Energy Sciences. Applications to Shape the Future of Synchrotron Radiation Science Synchrotron radiation is now an established tool in many areas of physical and biological science. The ALS Doctoral Fellowships will allow beginning researchers to work at the frontier of synchrotron radiation research and to help advance state-of-the-art applications.

287

Modeling of the ALS linac  

SciTech Connect

The ALS injector linac is used for the Beam Test Facility (BTF) and the Damping Experiments when it is available in between the ALS filings. These experiments usually require higher quality beams and a better characterization than is normally required for ALS operations. This paper focuses on the beam emittance, energy tilt, and especially the longitudinal variation of the beam parameters. For instance, the authors want to avoid longitudinal variations at the low beta section of the BTF. On the other hand, a large energy tilt is required for post-acceleration compression of the bunch using an alpha magnet. The PARMELA code was modified to calculate and display longitudinal variations of the emittance ellipse. Using the Microsoft Development Studio under Windows NT environment the code can handle a much larger number of particles than was previously possible.

Kim, C.H. [Lawrence Berkeley Lab., CA (United States). Advanced Light Source Center

1996-08-01T23:59:59.000Z

288

AlN/Fe/AlN nanostructures for magnetooptic magnetometry  

SciTech Connect

AlN/Fe/AlN/Cu nanostructures with ultrathin Fe grown by sputtering on Si substrates are evaluated as probes for magnetooptical (MO) mapping of weak currents. They are considered for a laser wavelength of ??=?410?nm (3.02?eV) and operate at oblique light incidence angles, ?{sup (0)}, to enable detection of both in-plane and out-of-plane magnetization. Their performance is evaluated in terms of MO reflected wave electric field amplitudes. The maximal MO amplitudes in AlN/Fe/AlN/Cu are achieved by a proper choice of layer thicknesses. The nanostructures were characterized by MO polar Kerr effect at ?{sup (0)}???5° and longitudinal Kerr effect spectra (?{sup (0)}?=?45°) at photon energies between 1 and 5?eV. The nominal profiles were refined using a model-based analysis of the spectra. Closed form analytical expressions are provided, which are useful in the search for maximal MO amplitudes.

Lišková-Jakubisová, E., E-mail: liskova@karlov.mff.cuni.cz; Viš?ovský, Š. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 12116 Prague 2 (Czech Republic); Široký, P.; Hrabovský, D.; Pištora, J. [Nanotechnology Center, Technical University of Ostrava, 17. listopadu 15/2172, 70833 Ostrava Poruba (Czech Republic); Harward, I.; Celinski, Z. [Center for Magnetism and Magnetic Nanostructures, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States)

2014-05-07T23:59:59.000Z

289

Correlation between Microstructure and Mechanical Properties of TiC Films Produced by Vacuum arc Deposition and Reactive Magnetron Sputtering  

E-Print Network (OSTI)

and mechanical properties of TiC films produced by vacuumstudied the synthesis of TiC films by vacuum arc depositionproduced a broad range of TiC x film compositions. In both

Monteiro, O.R.; Delplancke-Ogletree, M.P.; Winand, R.; Brown, I.G.

1999-01-01T23:59:59.000Z

290

The Influence of Ni-Coated TiC on Laser-Deposited IN625 Metal Matrix Composites  

E-Print Network (OSTI)

The In?uence of Ni-Coated TiC on Laser-Deposited IN625 Metalwith Ni-coated and uncoated TiC reinforcement particles toand spatial distribution of TiC particles in the deposited

2010-01-01T23:59:59.000Z

291

AL2007-08.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Environmentally Preferable Purchasing Through the Use of the Environmentally Preferable Purchasing Through the Use of the Electronic Product Environmental Assessment Tool (EPEAT) References: Presidential Executive Order 13423 Strengthening Federal Environmental, Energy, and Transportation Management Federal Acquisition Regulations (FAR) Subpart 23.7 Contracting for Environmentally Preferable Products and Services DOE Order 450.1, Chg 2, Environmental Protection Program DOE Acquisition Guide, Chapter 23, Greening the Government - Environmental Considerations in Acquisition Electronic Product Environmental Assessment Tool, IEEE Standard 1680-2006 for Environmental Assessment of Personal Computer Products. When is this Acquisition Letter (AL) Effective? This AL is effective immediately upon issuance.

292

Category:Montgomery, AL | Open Energy Information  

Open Energy Info (EERE)

Montgomery, AL Montgomery, AL Jump to: navigation, search Go Back to PV Economics By Location Media in category "Montgomery, AL" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Montgomery AL Alabama Power Co.png SVFullServiceRestauran... 88 KB SVHospital Montgomery AL Alabama Power Co.png SVHospital Montgomery ... 90 KB SVLargeHotel Montgomery AL Alabama Power Co.png SVLargeHotel Montgomer... 86 KB SVLargeOffice Montgomery AL Alabama Power Co.png SVLargeOffice Montgome... 87 KB SVMediumOffice Montgomery AL Alabama Power Co.png SVMediumOffice Montgom... 89 KB SVMidriseApartment Montgomery AL Alabama Power Co.png SVMidriseApartment Mon... 91 KB SVOutPatient Montgomery AL Alabama Power Co.png SVOutPatient Montgomer... 87 KB SVPrimarySchool Montgomery AL Alabama Power Co.png

293

Transformer Abdullah Al-Otaibi  

E-Print Network (OSTI)

Transformer Abdullah Al-Otaibi ID#242374 Section#2 Abstract- this is a brief description for transformer and how it works. I. DEFINITION A transformer is a device that transfers electrical energy from of the transformer in 1831. The transformer is used by Faraday only to demonstrate the principle of electromagnetic

Masoudi, Husain M.

294

A Study of Selected Properties and Applications of AlMgB14 and Related Composites: Ultra-Hard Materials  

SciTech Connect

This research presents a study of the hardness, electrical, and thermal properties AlMgB{sub 14} containing Al{sub 2}MgO{sub 4} spinel. This research also investigated how much Al{sub 2}MgO{sub 4} spinel consistently forms with AlMgB{sub 14}, if AlMgB{sub 14} materials can be produced by hot isostatic pressing (HIP), what effects TiC and TiB{sub 2} have on this composite material, and the importance of mechanical alloying. Included also is a study of the variation in hardness measurements and how they relate to SI units. Heretofore, all ultra-hard materials (hardness > 40 GPA) have been found to be cubic in structure, electrical insulators, and expensive; the behavior of AlMgB{sub 14}, which in certain specimens and compositions can have hardness values greater than 40 GPa, is therefore quite unusual since it is non-cubic, conductive, and moderate in cost. This offers an opportunity to investigate the relationship between hardness, thermal, and electrical properties from a new perspective. The main purpose of this project was to characterize the different properties of the AlMgB{sub 14} materials and to demonstrate that this material can be made in bulk. The technologies used for this study include microhardness measurement techniques, scanning electron microscopy, energy dispersive spectroscopy, x-ray diffraction spectroscopy, x-ray diffraction spectroscopy at different temperatures, optical microscopy, thermomechanical analysis, differential thermal analysis, 4-point probe resistivity, density techniques, Seebeck Effect, and Hall Effect. This research may lead to use of this material for applications where high abrasion resistance along with electrical conduction is needed. Also this research gave more information about a material that could have a great impact on industrial applications.

Theron L. Lewis

2002-05-28T23:59:59.000Z

295

Synthesis and Characterization of the Microporosity of Ion-Exchanged Al2O3-Pillared Clays  

Science Journals Connector (OSTI)

Although most PILC studies have focused on their use for catalytic application, there has also been other work in which PILCs have been studied as potential sorbents for gas separation applications. ... We have chosen Al2O3-pillared clay for this study because of the small pore size and interlayer spacing of this material compared with other types of pillared clays (e.g., TiO2-PILC, SiO2-PILC).1 ... The samples and analytical results are identified by the following convention:? the sample Li+?PILC represents Al2O3-pillared clay which has undergone postsynthesis ion exchange with the Li+ cation (in a solution of LiCl as described earlier). ...

Nick D. Hutson; Donald J. Gualdoni; Ralph T. Yang

1998-10-31T23:59:59.000Z

296

Dirac cones in artificial structures of 3d transitional-metals doped Mg-Al spinels  

SciTech Connect

Motivated by recent theoretical predications for Dirac cone in two-dimensional (2D) triangular lattice [H. Ishizuka, Phys. Rev. Lett. 109, 237207 (2012)], first-principles studies are performed to predict Dirac cones in artificial structures of 3d transitional-metals (TM?=?Ti, V, Cr, Mn, Fe, Co, Ni, and Cu) doped Mg-Al spinels. In investigated artificial structures, TM dopants substitute specific positions of the B sub-lattice in Mg-Al spinel, and form a quasi-2D triangular lattice in the a-b plane. Calculated results illustrate the existence of the spin-polarized Dirac cones formed in d-wave bands at (around) the K-point in the momentum space. The study provides a promising route for engineering Dirac physics in condensed matters.

Lu, Yuan; Zuo, Xu, E-mail: xzuo@nankai.edu.cn [College of Electronic Information and Optical Engineering, Nankai University, Tianjin 300071 (China); Feng, Min [School of Physics, Nankai University, Tianjin 300071 (China); Shao, Bin [Department of Physics, Tsinghua University, Beijing 100084 (China)

2014-05-07T23:59:59.000Z

297

(12) United States Patent Reardan et al.  

E-Print Network (OSTI)

(12) United States Patent Reardan et al. (54) SENSITIVE DRUG DISTRIBUTION SYSTEM AND METHOD (75 2004/0117205 Al Jun. 17,2004 (51) Int. Cl. G06Q 10/00 (2006.01) (52) U.S. Cl/231 4,976,351 A 1211990 Mangini et al. 5,737,539 A * 411998 Edelson et al. ................. 705/3 5

Shamos, Michael I.

298

(12) United States Patent Likourezos et al.  

E-Print Network (OSTI)

(12) United States Patent Likourezos et al. (54) SYSTEM AND METHOD FOR AUTOMATICALLY EFFECTING Publication Data US 2002/0095376 Al Jul. 18, 2002 Related U.S. Application Data Continuation Altman et al. ................ 705/36 5,715,314 A 211998 Payne et al. 5,794,219 A 811998 Brown 5

Shamos, Michael I.

299

et al. (2008) identified several additional methylation sites on FOXO1 that ap-  

E-Print Network (OSTI)

, it remains to be deter- mined how methylation alters the activity and posttranslational regulation. In this light, methylation could, therefore, play a very general role in the regulation of FOXO1 activity serve as a link between aging and age-related diseases such as diabe- tes and cancer. FOXO dysregulation

Hertel, Klemens J.

300

E-Print Network 3.0 - akot ti alloy Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

666670 Phase transformation and precipitation in aged TiNiHf Summary: in aged Ti-Ni-Hf high-temperature shape memory alloys X.L. Meng, W. Cai, Y.F. Zheng, L.C. Zhao...

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

The Synthesis of Ag-Doped Mesoporous TiO2 . | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

The Synthesis of Ag-Doped Mesoporous TiO2 . The Synthesis of Ag-Doped Mesoporous TiO2 . Abstract: Ag-doped mesoporous titanium oxide was prepared using non-ionic surfactants and...

302

The Synthesis of Cadmium Doped Mesoporous TiO2. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

The Synthesis of Cadmium Doped Mesoporous TiO2. The Synthesis of Cadmium Doped Mesoporous TiO2. Abstract: Cd doped mesoporous titanium oxide was prepared using non-ionic...

303

Synthesis of Room-Temperature Ferromagnetic Cr-doped TiO(110...  

NLE Websites -- All DOE Office Websites (Extended Search)

Ferromagnetic Cr-doped TiO(110) Rutile Single Crystals using Ion Implantation. Synthesis of Room-Temperature Ferromagnetic Cr-doped TiO(110) Rutile Single Crystals using Ion...

304

Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced...  

NLE Websites -- All DOE Office Websites (Extended Search)

TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Abstract: We used anionic...

305

NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS  

E-Print Network (OSTI)

O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS S'. Hwang, S.0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS by S. Hwang, S.was investigated for cryogenic applications. The systematic

Hwang, S.

2010-01-01T23:59:59.000Z

306

Formaldehyde Polymerization on (WO3)3/TiO2(110) Model Catalyst...  

NLE Websites -- All DOE Office Websites (Extended Search)

Formaldehyde Polymerization on (WO3)3TiO2(110) Model Catalyst. Formaldehyde Polymerization on (WO3)3TiO2(110) Model Catalyst. Abstract: Polymerization of formaldehyde, H2CO, was...

307

Irradiation behavior of SrTiO3 at temperatures close to the critical...  

NLE Websites -- All DOE Office Websites (Extended Search)

for amorphization. Abstract: Damage accumulation on both the Sr and Ti sublattices in strontium titanate (SrTiO3) has been investigated under 1.0 MeV Au+ irradiation at 360 and 400...

308

Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...  

NLE Websites -- All DOE Office Websites (Extended Search)

Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on...

309

BaTiO? based materials for piezoelectric and electro-optic applications  

E-Print Network (OSTI)

Ferroelectric materials are key to many modem technologies, in particular piezoelectric actuators and electro-optic modulators. BaTiO? is one of the most extensively studied ferroelectric materials. The use of BaTiO? for ...

Avrahami, Ytshak, 1969-

2003-01-01T23:59:59.000Z

310

Co-doped Anatase TiO Heteroepitaxy on Si(001). | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

layer, followed by deposition of a thin SrTiO&8323; buffer layer. Using ½ ML Sr metal to form the silicide allowed the deposition of 10 ML SrTiO&8323; without oxidation...

311

Phase constitution, Mechanical Property and Corrosion Resistance of the Ti-Nb Alloys  

E-Print Network (OSTI)

the Ti-Ni alloy in the dental application. In the non-oral condition, the Ti-52Nb alloy may be preferable, dentistry and interventional radiology because of their superior shape memory effect and superelasticity [1

Zheng, Yufeng

312

E-Print Network 3.0 - ar ti cr Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Cu films were deposited on a steel substrate with thickness range of 200 - 2000... of TiC14, N2, HZ and Ar a t 520'C. The adhesion strength of TiN films was investigated by...

313

Scanning tunneling microscopy investigation of the TiO2 anatase ,,101... surface Wilhelm Hebenstreit,1  

E-Print Network (OSTI)

of tunneling sites in STM. Titanium dioxide (TiO2) is a versatile material that finds uses as a promoter. Fourfold-coordinated Ti atoms at step edges are preferred adsorption sites and allow the identification

Diebold, Ulrike

314

Design, optimization, and applications of few-cycle Ti:Sapphire lasers  

E-Print Network (OSTI)

Ti:Sapphire mode-locked lasers are a unique technology that enables a wide variety of applications. Owing to the ultrabroadband nature of the Ti:sapphire crystal and the invention of precisely engineered dispersion-compensating ...

880-01 Chen, Li jin

2012-01-01T23:59:59.000Z

315

Thermodynamics of the Magnetite-Ulvöspinel (Fe3O4-Fe2TiO4...  

NLE Websites -- All DOE Office Websites (Extended Search)

the Magnetite-Ulvöspinel (Fe3O4-Fe2TiO4) Solid Solution. Thermodynamics of the Magnetite-Ulvöspinel (Fe3O4-Fe2TiO4) Solid Solution. Abstract: The thermodynamics of mixing...

316

TiO2 Nanoparticles as a Soft X-ray Molecular Probe  

E-Print Network (OSTI)

Figure 1. TEM image of PAA coated TiO 2 nanoparticles .TOPO with polyacrylic acid (PAA) . Preparation of TiO 2 -TOPO with polyacrylic acid (PAA) 2 . A solution of 0.1 g PAA

Ashcroft, Jared M.

2008-01-01T23:59:59.000Z

317

Growth of Cr-doped TiO Films in the Rutile and Anatase Structures...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Cr-doped TiO Films in the Rutile and Anatase Structures by Oxygen Plasma Assisted Molecular Beam Epitaxy . Growth of Cr-doped TiO Films in the Rutile and Anatase Structures by...

318

Chemical Reactivity of Reduced TiO2(110): The dominant role of...  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

319

Acetone Chemistry on Oxidized and Reduced TiO2(110). | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Acetone Chemistry on Oxidized and Reduced TiO2(110). Acetone Chemistry on Oxidized and Reduced TiO2(110). Abstract: The chemistry of acetone on the oxidized and reduced surfaces of...

320

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2...  

NLE Websites -- All DOE Office Websites (Extended Search)

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Abstract: The chemistry and photochemistry...

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...  

NLE Websites -- All DOE Office Websites (Extended Search)

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

322

Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature...  

NLE Websites -- All DOE Office Websites (Extended Search)

Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Chemistry of 2-Propanol on TiO2(110): Low and High...

323

Role of polaron hopping in leakage current behavior of a SrTiO3 ...  

E-Print Network (OSTI)

Dec 10, 2013 ... zirconate titanite (PZT), strontium titanite (SrTiO3), and bar- ium titanite (BaTiO3), have been widely utilized in various electronic devices such ...

2014-03-14T23:59:59.000Z

324

Microsoft Word - AL2007-01.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

AL-2007-01 (12/15/06) AL-2007-01 (12/15/06) 1 Department of Energy No. AL-2007-01 Acquisition Regulation Date 12/15/06 ACQUISITION LETTER This Acquisition Letter is issued by the Procurement Executive of DOE. Subject: Implementation of Functional Accountability Requirements References: Secretary of Energy Memorandum dated May 23, 2006, Functional Accountability When is this Acquisition Letter (AL) Effective? This AL, which includes the attached OPAM Implementation Plan and DOE Corporate Implementation Plan, are effective immediately. When does this AL Expire? This AL remains in effect until superseded or canceled and is subject to change as needed. Who is the Point of Contact?

325

Corrosion behavior of newly developed TiAgFe dental alloys in neutral saline solution  

E-Print Network (OSTI)

Corrosion behavior of newly developed Ti­Ag­Fe dental alloys in neutral saline solution B. B. Zhang, B. L. Wang, L. Li and Y. F. Zheng* The corrosion behavior of Ti­5Ag­xFe alloys (x ¼ 1, 2.5, 5 wt) Ti,Ti­ 5Ag­xFe alloys exhibited higher corrosion potentials, lower current densities, and larger

Zheng, Yufeng

326

Deuterium absorption in Mg70Al30 thin films with bilayer catalysts: A comparative neutron reflectometry study  

Science Journals Connector (OSTI)

We present a neutron reflectometry study of deuterium absorption in thin films of Al-containing Mg alloys capped with a Ta/Pd, Ni/Pd and Ti/Pd-catalyst bilayer. The measurements were performed at room temperature over the 0–1 bar pressure range under quasi-equilibrium conditions. The modeling of the measurements provided a nanoscale representation of the deuterium profile in the layers at different stages of the absorption process. The absorption mechanism observed was found to involve spillover of atomic deuterium from the catalyst layer to the Mg alloy phase, followed by the deuteration of the Mg alloy. Complete deuteration of the Mg alloy occurs in a pressure range between 100 and 500 mbar, dependent on the type of bilayer catalyst. The use of a Ti/Pd bilayer catalyst yielded the best results in terms of both storage density and kinetic properties.

Eric Poirier; Chris T. Harrower; Peter Kalisvaart; Adam Bird; Anke Teichert; Dirk Wallacher; Nico Grimm; Roland Steitz; David Mitlin; Helmut Fritzsche

2011-01-01T23:59:59.000Z

327

Optical and electrical characterization of the electron beam gun evaporated TiO2 lm  

E-Print Network (OSTI)

Optical and electrical characterization of the electron beam gun evaporated TiO2 ®lm V of TiO2 ®lms obtained by electron beam gun evaporation and annealed in an oxygen environment. A negative with TiO2 insulator ®lms deposited by electron beam gun evaporator. P-type Si wafers (1 0 0 orientation

Eisenstein, Gadi

328

Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1....  

NLE Websites -- All DOE Office Websites (Extended Search)

CO2 on Rutile TiO2(110)-1×1. Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1. Abstract: Adsorption, binding, and diffusion of CO2 molecules on rutile TiO2(110)...

329

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature  

E-Print Network (OSTI)

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature Jia Zhang,ab Chao temperature oxygen sensor based on TiO2/graphene device was developed with an enhanced sensing performance­hole pairs in the TiO2 film and the photogenerated electrons were scavenged by graphene and percolated

Cao, Wenwu

330

Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles  

Science Journals Connector (OSTI)

Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles ... Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles” ... Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles” ...

Toshiyuki Abe; Eiji Suzuki; Kentaro Nagoshi; Kohichi Miyashita; Masao Kaneko:

2000-03-24T23:59:59.000Z

331

AL2007-05.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7-05 7-05 Acquisition Regulation Date 03/29/2007 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Acquisition Letters (AL) that remain in effect are identified below. All other previously issued ALs have been superseded by a formal rule-making, incorporated into other guidance, and/or canceled. * * * * * * * * * * * * * * * * ACQUISITION LETTERS REMAINING IN EFFECT NUMBER DATE SUBJECT 93-4 04/07/93 Displaced Workers Benefits Program 94-19 12/09/94 Basic Labor Policies Fringe Benefits 95-06 06/28/95 Personal Property Letter System 95-14 11/17/95 Subcontracts under the New Independent States - Industrial Partnering Program

332

AL2007-03.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

AL 2007-03 AL 2007-03 Acquisition Regulation Date 03/30/07 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Interagency Acquisition References: FAR Part 7 Acquisition Planning FAR Part 8 Required Sources of Supplies and Services FAR Part 10 Market Research FAR Subpart 17.2 Options FAR Subpart 17.5 Interagency Acquisitions under the Economy Act FAR Part 37 Service Contracting FAR Part 38 Federal Supply Schedule Contracting FAR Part 42 Contract Management DEAR 970.1707 Work For Others Guide Chapter 7.1 Acquisition Planning Guide Chapter 17.1 Interagency Agreements Guide Chapter 38.1 Task Order Contracting Strategic Acquisition Transaction Guide

333

PROYECTO DE CAMBIOS AL DFL1 PRESENTADO AL CONGRESO EN 1999  

E-Print Network (OSTI)

PROYECTO DE CAMBIOS AL DFL1 PRESENTADO AL CONGRESO EN 1999 LEY GENERAL DE SERVICIOS ELECTRICOS hace, en materias de electricidad, gas y combustibles líquidos, al Ministerio del Interior o al Ministro del Interior, deberán entenderse referidas al Ministerio de Economía, Fomento y Reconstrucción o

Rudnick, Hugh

334

Preparation, characterization and applications of novel carbon and nitrogen codoped TiO{sub 2} nanoparticles from annealing TiN under CO atmosphere  

SciTech Connect

Graphical abstract: Carbon and nitrogen codoped TiO{sub 2} nanoparticles were firstly fabricated by calcining TiN powder under CO atmosphere at different temperatures between 400 and 600 °C, both the improved photocatalytic activity for degradation of methylene blue and enhanced photovoltaic performance for dye sensitized solar cells were demonstrated. - Highlights: • CN-codoped TiO{sub 2} nanoparticles were prepared by calcining TiN under CO atmosphere. • More visible light response was confirmed by UV–vis DRS and photocatalytic results. • Enhanced conversion efficiency was observed for the DSSCs from CN-TiO{sub 2} photoanode. • CN-codoping played an important role to improve the photocatalytic performance. - Abstract: Carbon and nitrogen codoped titania (CN-TiO{sub 2}) nanoparticles were fabricated by calcining titanium nitride (TiN) nanoparticles under carbon monoxide (CO) atmosphere at four different temperatures in a range of 400–600 °C. The as-prepared samples were characterized with X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and X-ray photoelectron spectroscopy (XPS). Enhanced light absorption in both the UV and visible light region was observed for the resulted CN-TiO{sub 2} nanoparticles in ultraviolet-visible diffuse reflectance spectroscopy (UV–vis DRS). Improved photocatalytic activity toward the degradation of methylene blue by the CN-TiO{sub 2} nanoparticles was demonstrated under UV and visible light, respectively. The highest degradation rate was achieved for CN-TiO{sub 2} nanoparticles (13%) compared to N-TiO{sub 2} (10%) and the commercial P25 (5%) under visible light illumination for 40 min. Furthermore, the improved photocatalytic activity of CN-TiO{sub 2} was also confirmed by the degradation of colorless resorcinol under UV–vis light irradiation. Dye-sensitized solar cells (DSSCs) were fabricated using P25, N-TiO{sub 2} and CN-TiO{sub 2} photoanodes, respectively. The highest conversion efficiency of 3.31% was achieved by the DSSCs based on the CN-TiO{sub 2} photoanodes in comparison with the commercial P25 (1.61%) and N-TiO{sub 2} (2.44%) photoanodes. This work demonstrates that thermal treatment of TiN nanoparticles under CO atmosphere has shown to be a rapid, direct and clean approach to synthesize photocatalysts with enhanced photocatalytic and photovoltaic performance.

Sun, Mingxuan; Song, Peng; Li, Jing; Cui, Xiaoli, E-mail: xiaolicui@fudan.edu.cn

2013-10-15T23:59:59.000Z

335

A novel hierarchical homogeneous nanoarchitecture of TiO2 nanosheets branched TiO2 nanosheet arrays for high efficiency dye-sensitized solar cells  

Science Journals Connector (OSTI)

Abstract We report a novel hierarchical homogeneous nanoarchitecture of TiO2 nanosheets branched TiO2 nanosheet arrays, which is formed directly on transparent conductive fluorine-doped tin oxide (FTO) glass substrate through a one-step facile hydrothermal reaction without the use of a seed layer. The hierarchical homogeneous nanoarchitecture is composed of long TiO2 nanosheet trunks grafted with a large number of TiO2 nanosheet branches, which is an effective structure to improve the charge transport with the increase of the specific surface area. Dye-sensitized solar cell (DSSC) based on TiO2 nanosheets branched TiO2 nanosheet arrays can achieve an outstanding power conversion efficiency of 6.66%, which is attributed to the specific performances such as higher specific surface area for adsorbing more dye molecules, superior light scattering capacity for boosting the light-harvesting efficiency and faster charge transport for efficient charge collection.

Bing-Xin Lei; Xiao-Feng Zheng; He-kang Qiao; Yi Li; Shu-Nuo Wang; Guo-Lei Huang; Zhen-Fan Sun

2014-01-01T23:59:59.000Z

336

Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures  

SciTech Connect

We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

Ngai, J. H.; Kumah, D. P.; Walker, F. J. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Ahn, C. H. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Department of Mechanical Engineering and Materials Science, Yale University, 10 Hillhouse Avenue, New Haven, Connecticut 06520-8267 (United States)

2014-02-10T23:59:59.000Z

337

cONNEcTiONS SPriNG 2015  

E-Print Network (OSTI)

curricular cONNEcTiONS GuiDE SPriNG 2015 Aquila Theatre Wuthering Heights Photo Credit: Richard Termine (top) Susan Brandeis Design Class at the Gregg Museum Photo Credit: Matthew Gay (bottom) #12G) is a great way to integrate the arts into academic work, to foster a well-rounded education where art

Velev, Orlin D.

338

Ni-Pt Silicide Formation Through Ti Mediating Layers  

SciTech Connect

With Ni1-xPtxSi, the variation in queue time between the final surface cleaning and Ni-Pt deposition represents a significant manufacturability issue. A short queue time is often difficult to maintain, leading to the formation of an oxide layer on the Si substrate prior to Ni-Pt deposition that can affect the formation of Ni1-xPtxSi and its texture. In this manuscript, it will be shown that an extended queue time prior to Ni-Pt deposition leads to morphological changes in the Ni1-xPtxSi formation sequence. A layer of Ti deposited between Ni-Pt and Si reduces the native oxide and may facilitate Ni1-xPtxSi formation. With increasing Ti thickness, the presence of metal-rich phases is gradually reduced and the formation temperature of Ni1-xPtxSi increases, suggesting a direct formation of Ni1-xPtxSi from Ni-Pt. In the presence of an interfacial oxide, an increase in formation temperature is also observed with increasing Ti interlayer thickness. When the Ti layer is sufficiently thick, the phase formation sequence becomes relatively insensitive to the presence of an interfacial oxide or extended queue time.

Besser,P.; Lavoie, C.; Ozcan, A.; Murray, C.; Strane, J.; Wong, K.; Gribelyuk, M.; Wang, Y.; Parks, C.; Jordan-Sweet, J.

2007-01-01T23:59:59.000Z

339

A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed on MCM-48  

E-Print Network (OSTI)

A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed.932), suggesting the formation of oxygen vacancies. The fraction of Ti that could be reduced increased with TiO2 the TiO2 overlayer as the size of the titania patches increases. The amount of oxygen removed during

Bell, Alexis

340

Probing photochemical transformations at TiO{sub 2}/Pt and TiO{sub 2}/Ir interfaces using x-ray absorption spectroscopy  

SciTech Connect

Structural transformations at the TiO{sub 2}/Pt and TiO{sub 2}/Ir interfaces during UV-irradiation have been probed by X-ray absorption spectroscopy. Oxidation by the photogenerated holes results in the intercalation of Pt and Ir into the Titania matrix. The structural transformations observed with Pt and Ir nanoparticles anchored on TiO{sub 2} is different than the clustering of gold atoms observed in the TiO{sub 2}/Au system. Implications of such structural transformations on the photocatalytic activity of semiconductor photocatalyts are discussed.

Lahiri, Debdutta; Subramanian, V.; Bunker, Bruce A.; Kamat, Prashant V. [Synchrotron Radiation Section, Physics Group, Bhabha Atomic Research Centre, Mumbai 400085 (India); Department of Chemical Engineering, University of Illinois at Urbana-Champaign, Illinois 61801 (United States); Department of Physics, University of Notre Dame, Indiana 46556 (United States); Radiation Laboratory, University of Notre Dame, Indiana 46556 (United States)

2006-05-28T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Supra-Canonical 26Al/27Al and the Residence Time of CAIs in the  

E-Print Network (OSTI)

Supra-Canonical 26Al/27Al and the Residence Time of CAIs in the Solar Protoplanetary Disk Edward D initial 26Al/27Al ratio of 4.5 � 10­5 has been a fiducial marker for the beginning of the solar system that some CAIs had initial 26Al/27Al values at least 25% greater than canonical and that the canonical

Harrison, Mark

342

Intrinsic metastability of orthorhombic HfTiO{sub 4} in thin film hafnia-titania  

SciTech Connect

Orthorhombic (o) HfTiO{sub 4} is crystallized when sputter deposited hafnia-titania nanolaminates with ultrathin layers and bilayer (HfO{sub 2}){sub 0.5}(TiO{sub 2}){sub 0.5} composition are annealed between 573 and 1173 K. However, o-HfTiO{sub 4} demixes after annealing at 1273 K, a result not predicted from bulk thermodynamics. X-ray diffraction and Raman microscopy are used here to study structural changes as o-HfTiO{sub 4} demixes upon long-term annealing at 1273 K into Ti-doped monoclinic HfO{sub 2} and Hf-doped rutile TiO{sub 2}. We conclude that o-HfTiO{sub 4} crystallized at low temperature is intrinsically metastable. A space group symmetry analysis shows that demixing can be accomplished by a continuous phase transition chain.

Cisneros-Morales, Massiel Cristina; Aita, Carolyn Rubin [Department of Chemistry and Biochemistry, University of Wisconsin-Milwaukee, P.O. Box 413, Milwaukee, Wisconsin 53201 (United States)

2011-01-31T23:59:59.000Z

343

Microsoft Word - AL2002-03.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

AL 2002-03 (3/13/2002) AL 2002-03 (3/13/2002) Subject: Public Relations Requirements References: Deputy Secretary Letter dated February 25, 2002 When is this Acquisition Letter (AL) Effective? This AL is effective 10 business days from the date of issuance. When does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Bob Webb of the Office of Procurement and Assistance Policy at (202) 586-8264, or via e-mail at robert.webb@hq.doe.gov Visit our website at www.pr.doe.gov for information on Acquisition Letters and other policy issues. What is the Purpose of this AL? The purpose of this AL is to provide guidance regarding the processing of procurement requests for obtaining contractual services from public relations

344

Al Corn Clean Fuel | Open Energy Information  

Open Energy Info (EERE)

search Name Al-Corn Clean Fuel Place Claremont, North Dakota Product Al-Corn is an ethanol plant located in Claremont, North Dakota, which is owned by local farmers and...

345

Teatro al Sur y la escena Argentina  

E-Print Network (OSTI)

140 LATIN AMERICAN THEATRE REVIEW Teatro al Sur y la escena Argentina Acaba de aparecer un nuevo número de Teatro al Sur, Revista Latinoamericana. Su título de tapa - Teatro Argentino a varias voces - resume la intención de esta nueva entrega...

Editors

2000-04-01T23:59:59.000Z

346

Promising Magnesium Battery Research at ALS  

NLE Websites -- All DOE Office Websites (Extended Search)

Promising Magnesium Battery Research at ALS Promising Magnesium Battery Research at ALS Print Wednesday, 23 January 2013 16:59 toyota battery a) Cross-section of the in situ...

347

AL2010-04.pdf | Department of Energy  

Energy Savers (EERE)

AL2010-04.pdf AL2010-04.pdf AL2010-04.pdf More Documents & Publications Microsoft Word - Section 311 AL FAL Feb 17 2010 Microsoft Word - Section 311 AL FAL Feb 17 2010 Microsoft...

348

(12) United States Patent Vertes et al.  

E-Print Network (OSTI)

(12) United States Patent Vertes et al. (54) THREE-DIMENSIONAL MOLECULAR IMAGING BY INFRARED LASER/0012831 Al Jan. 21, 2010 Related U.S. Application Data (63) Continuation-in-part of application No. 121176,656,690 B2 6,744,046 B2 6,991,903 B2 7,084,396 B2 12/2003 Crooke et al. 612004 Valaskovic et al. 112006 Fu

Vertes, Akos

349

(12) United States Patent Vertes et al.  

E-Print Network (OSTI)

(12) United States Patent Vertes et al. (54) LASER DESORPTION IONIZATION AND PEPTIDE SEQUENCING. (21) Appl. No.: 11/674,671 (22) Filed: Feb. 14,2007 (65) Prior Publication Data US 2009/0321626 Al Dec Suizdak et al. 6,589,485 B2 7/2003 Koster 6,794,196 B2 912004 Fonash et al. 6,846,681 B2 112005 Buriak et

Vertes, Akos

350

(12) United States Patent Reardan et al.  

E-Print Network (OSTI)

(12) United States Patent Reardan et al. (54) SENSITIVE DRUG DISTRIBUTION SYSTEM AND METHOD (75 US 2005/0090425 Al Apr. 28, 2005 Related U.S. Application Data Division of application No.1 0,847,764 A 711989 Halvorson 4,976,351 A 1211990 Mangini et al. 5,737,539 A 411998 Edelson et al. 5,845,255 A 1211998

Shamos, Michael I.

351

(12) United States Patent Fallon et al.  

E-Print Network (OSTI)

(12) United States Patent Fallon et al. (54) SYSTEM AND METHOD FOR DATA FEED ACCELERATION/131,631 (22) Filed: Jun. 2,2008 (65) Prior Publication Data US 200910287839 Al Nov. 19,2009 Related U References Cited U.S. PATENT DOCUMENTS 3,394,352 A 7/1968 Wernikoff et al. 3,490,690 A 111970 Apple et al. 4

Shamos, Michael I.

352

Clark et al., Supplemental Data SUPPLEMENTAL DATA  

E-Print Network (OSTI)

was then aliquoted to the PCR plate. Primer sequences: #12;Clark et al., Supplemental Data p. 2 C10_RT

Ptak, Susan

353

United States Patent [191 Jalali et al.  

E-Print Network (OSTI)

antennas: SPIE vol. 1703 (1992) 264-271. GA Magel et al.: "Phosphosilicate Glass waveguides for phased

Jalali. Bahram

354

Interaction of TiO{sub 2}{sup ?} with water: Photoelectron spectroscopy and density functional calculations  

SciTech Connect

The interactions of titania with water molecules were studied via photoelectron spectroscopy and density functional calculations of TiO(OH){sub 2}{sup ?} and Ti(OH){sub 4}(H{sub 2}O){sub n}{sup ?} (n = 0–5) clusters which are corresponding to the TiO{sub 2}(H{sub 2}O){sup ?} and TiO{sub 2}(H{sub 2}O){sub n+2}{sup ?} (n = 0–5) systems, respectively. Experimental observation and theoretical calculations confirmed that TiO(OH){sub 2}{sup ?} was produced when TiO{sub 2}{sup ?} interacts with one water molecule, and Ti(OH){sub 4}(H{sub 2}O){sub n}{sup ?} (n = 0–5) were produced successively when TiO{sub 2}{sup ?} interacts with two or more water molecules. The structures of Ti(OH){sub 4}(H{sub 2}O){sub n}{sup ?} with n = 4, 5 are slightly different from those of n = 1–3. The structures of Ti(OH){sub 4}(H{sub 2}O){sub 1-3}{sup ?} can be viewed as the water molecules interacting with the Ti(OH){sub 4}{sup ?} core through hydrogen bonds; however, in Ti(OH){sub 4}(H{sub 2}O){sub 4,5}{sup ?}, one of the water molecules interacts directly with the Ti atom via its oxygen atom instead of a hydrogen bond and distorted the Ti(OH){sub 4}{sup ?} core.

Li, Ren-Zhong [College of Electronics and Information, Xi'an Polytechnic University, Xi'an 710048 (China) [College of Electronics and Information, Xi'an Polytechnic University, Xi'an 710048 (China); Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China); Xu, Hong-Guang; Cao, Guo-Jin; Xu, Xi-Ling; Zheng, Wei-Jun, E-mail: zhengwj@iccas.ac.cn [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)

2013-11-14T23:59:59.000Z

355

Aluminium distribution in ZSM-5 revisited: The role of Al-Al interactions  

SciTech Connect

We present a theoretical study of the distribution of Al atoms in zeolite ZSM-5 with Si/Al=47, where we focus on the role of Al-Al interactions rather than on the energetics of Al/Si substitutions at individual sites. Using interatomic potential methods, we evaluate the energies of the full set of symmetrically independent configurations of Al siting in a Si{sub 94}Al{sub 2}O{sub 192} cell. The equilibrium Al distribution is determined by the interplay of two factors: the energetics of the Al/Si substitution at an individual site, which tends to populate particular T sites (e.g., the T14 site), and the Al-Al interaction, which at this Si/Al maximises Al-Al distances in general agreement with Dempsey's rule. However, it is found that the interaction energy changes approximately as the inverse of the square of the distance between the two Al atoms, rather than the inverse of the distance expected if this were merely charge repulsion. Moreover, we find that the anisotropic nature of the framework density plays an important role in determining the magnitude of the interactions, which are not simply dependent on Al-Al distances. - Graphical abstract: Role of Al-Al interactions in high silica ZSM-5 is shown to be anisotropic in nature and not dependent solely on Coulombic interactions. Highlights: Black-Right-Pointing-Pointer Si-Al distribution in ZSM-5 is revisited, stressing the role of the Al-Al interaction. Black-Right-Pointing-Pointer Coulomb interactions are not the key factors controlling the Al siting. Black-Right-Pointing-Pointer Anisotropy of the framework is identified as a source of departure from Dempsey's rule.

Ruiz-Salvador, A. Rabdel, E-mail: rabdel@imre.oc.uh.cu [Group of Materials Developed by Design, Division of Chemistry and Technology of Materials, Institute of Materials Science and Engineering (IMRE), University of Havana, Havana 10400 (Cuba); Grau-Crespo, Ricardo; Gray, Aileen E.; Lewis, Dewi W. [Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ (United Kingdom)] [Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ (United Kingdom)

2013-02-15T23:59:59.000Z

356

Effect of Al-Si-Al and Al-Si-Si-Al Pairs in the ZSM-5 Zeolite Framework on the 27 NMR Spectra. A Combined High-Resolution 27  

E-Print Network (OSTI)

Effect of Al-Si-Al and Al-Si-Si-Al Pairs in the ZSM-5 Zeolite Framework on the 27 Al NMR Spectra. A Combined High-Resolution 27 Al NMR and DFT/MM Study Jiri´ Dedecek, Stepan Sklenak,*, Chengbin Li, Blanka of the presence of Al-O-Si-O-Al and Al-O-Si-O-Si-O-Al sequences in the ZSM-5 zeolite framework on the local

Sklenak, Stepan

357

Deutsch als Zweitsprache in der Lehrerausbildung  

E-Print Network (OSTI)

Deutsch als Zweitsprache in der Lehrerausbildung Bedarf ­ Umsetzung ­ Perspektiven Dokumentation. Jörg Roche, Ludwig-Maximilians-Universität München Deutsch als Zweitsprache in der Lehrerausbildung Deutsch als Fremdsprache, Ludwig- Maximilians-Universität München Wie wird die Qualität der Da

Prediger, Susanne

358

SMERDON ET AL.: AUXILIARY MATERIAL Auxiliary Material  

E-Print Network (OSTI)

run [Ammann et al., 2007; hereinafter CCSM] and the GKSS ECHO-g ERIK2 run [González-Rouco et al., 2006; hereinafter ECHO-g]. The annual means of the modeled temperature fields are interpolated to 5° latitude;SMERDON ET AL.: AUXILIARY MATERIAL 2 ECHO-g simulations, respectively. The above conventions

Smerdon, Jason E.

359

AUTORIT ACCADEMICHE Situazione al 27 settembre 2012  

E-Print Network (OSTI)

AUTORIT� ACCADEMICHE Situazione al 27 settembre 2012 Presidenti dei Comitati di direzione delle Facoltà e Scuole Facoltà di Giurisprudenza Prof. Francesco Denozza dal 10.9.2012 al 30.9.2014 Facoltà di Scienze politiche, economiche e sociali Prof.ssa Laura Ammannati dal 10.9.2012 al 30.9.2014 Facoltà di

De Cindio, Fiorella

360

United States Patent [19] Church et al.  

E-Print Network (OSTI)

United States Patent [19] Church et al. [54] CHARACTERIZATION OF INDIVIDUAL POLYMER MOLECULES BASED al.. "ANeutral Amino Acid Change in Segment TIS4 Dramatically Alters the Gating Properties of the Volt- age-Dependent Sodium Channel". 1990, Proc. Natl. Acad. Sci. USA, 87:323-27. Bensirnon. A.. et al

Church, George M.

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

(12) United States Patent Likourezos et al.  

E-Print Network (OSTI)

(12) United States Patent Likourezos et al. (54) SYSTEM AND METHOD FOR EFFECTING A REAL: Nov. 14, 2001 (65) Prior Publication Data US 2002/0095377 Al Jul. 18, 2002 Related U.S. Application Cited U.S. PATENT DOCUMENTS 4,799,156 A 4,876,648 A 111989 Shavit et al. 1011989 Lloyd 102 102 111111

Shamos, Michael I.

362

Anomalous magneto-transport at the superconducting interface between LaAlO3 and SrTiO3  

E-Print Network (OSTI)

be controlled by solely varying the number of charge carriers at the interface using a gate volt- age [4). The resistance was measured in a dilution refrigerator using Lakeshore 370 AC resistance bridge and at liquid He temperatures using a standard four wire DC resis- tivity method. In Fig. 1 we present the number of charge

Palevski, Alexander

363

Integrated Control of Solidification Microstructure and Melt Pool Dimensions In Additive Manufacturing Of Ti - 6Al - 4V.  

E-Print Network (OSTI)

??Additive manufacturing (AM) offers reduced material waste and energy usage, as well as an increase in precision. Direct metal AM is used not only for… (more)

Gockel, Joy E.

2014-01-01T23:59:59.000Z

364

Understanding the mechanism of conductivity at the LaAlO3/SrTiO3...  

NLE Websites -- All DOE Office Websites (Extended Search)

Instruments: Ultra-high Vacuum, Low-temperature Scanning Probe Microscope Instrument, or UHV LT SPM Tags: Nanoscope IIIa topographical nanostructures nanodevices oxides catalysis...

365

Electric field control of the LaAlO3/SrTiO3 interface ground state  

Science Journals Connector (OSTI)

... identified: a magnetic state and a two-dimensional superconducting condensate. Here we use the electric field effect to explore the phase diagram of the system. The electrostatic tuning of ... insulating state are consistent with weak localization and do not provide evidence for magnetism. The electric field control of superconductivity demonstrated here opens the way to the development of new mesoscopic ...

A. D. Caviglia; S. Gariglio; N. Reyren; D. Jaccard; T. Schneider; M. Gabay; S. Thiel; G. Hammerl; J. Mannhart; J.-M. Triscone

2008-12-04T23:59:59.000Z

366

Photocatalytic effects of wool fibers modified with solely TiO2 nanoparticles and N-doped TiO2 nanoparticles by using hydrothermal method  

Science Journals Connector (OSTI)

Abstract The surfaces of wool fibers are modified with N-doped TiO2 nanoparticles by treating the fibers with tetrabutyl titanate and ammonium chloride under low temperature hydrothermal conditions to obtain wool fibers with photocatalytic functions in the visible light spectrum. The effects of nitrogen and sulfur in amino acids in keratin on the photocatalytic activity of TiO2 particle coated wool fibers are investigated. Changes of various fiber properties such as tensile strength, photocatalytic activity, and self-cleaning performance of untreated, TiO2 coated and N-doped TiO2 coated wool fibers are studied. It is found that N-doped anatase TiO2 nanoparticles with an average grain size of 11.2 nm are synthesized and simultaneously grafted onto the wool fibers. After treatments, the crystallization index of the wool fibers is slightly reduced. The capability to protect against ultraviolet radiation is much enhanced. The performances of photocatalytic degradation of methylene blue dye and self-cleaning of red wine under both UV and visible light irradiation are endowed. It is also found that wool fibers coated with TiO2 particles without being doped by nitrogen still have apparent photocatalytic reactions and self-cleaning effects under visible light irradiation due to the formation of C-Ti3+, O-Ti3+, and N-Ti3+ bonds between TiO2 and wool keratin on the wool fiber surfaces. Thus wool fabrics might not need to be coated with N-doped TiO2 nanoparticles to realize its self-cleaning effect under visible light. Such important conclusions would provide wool materials with wide applications in clothing and technical products such as wastewater treatment.

Hui Zhang; Zhenwei Yang; Xingtao Zhang; Ningtao Mao

2014-01-01T23:59:59.000Z

367

Au/PO43-/TiO2 and PO43-/Au/TiO2 catalysts for CO oxidation: effect of synthesis details on catalytic performance  

SciTech Connect

Supported gold catalysts are active for CO oxidation, but the high-temperature deactivation is a shortcoming that may constrain their applications. Herein, we attempted to address this problem by using phosphate-doped Au/TiO{sub 2} synthesized via two routes. In route I, Au/PO{sub 4}{sup 3-}/TiO{sub 2} catalysts were prepared by treating TiO{sub 2} (Degussa P25) with diluted H{sub 3}PO{sub 4}, followed by loading gold via deposition-precipitation. In route II, PO{sub 4}{sup 3-}/Au/TiO{sub 2} catalysts were prepared by treating H{sub 2}-reduced Au/TiO{sub 2} with diluted H{sub 3}PO{sub 4}. These catalysts were systematically pretreated at 200 or 500 C before reaction testing. The overall CO conversion on 200 C-pretreated Au/PO43-/TiO2 or PO43-/Au/TiO2 was always lower than that on 200 C-pretreated Au/TiO2. However, the advantage of the phosphate addition became apparent after thermal treatment at a higher temperature. Both Au/PO43-/TiO2 and PO43-/Au/TiO2 pretreated at 500 C retained significant activities at room temperature, whereas 500 C-pretreated Au/TiO2 lost its activity. Control experiments and catalyst characterization were performed to investigate the impact of synthesis details on catalytic performance.

Ma, Zhen [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2007-01-01T23:59:59.000Z

368

Exergy analysis of hydrocarbons mixture refrigerants R436A and R436B as a drop in replacement for R134a with TiO2 nanoparticles  

Science Journals Connector (OSTI)

The refrigerator exergy efficiency (EE) with nanoparticles in the working fluid was investigated experimentally. Mineral oil (MO) with TiO2 nanoparticles mixtures were used as the lubricant instead of Polyol ester (POE) oil in the R134a, R436A (R290/R600a-56/44-weight %) and R436B (R290/R600a-52/48-weight %) refrigerator. The results indicate that R134a, R436A and R436B and MO with TiO2 nanoparticles work normally and safely in the refrigerator. The refrigerator EE (34.1, 40.1 and 41.6%) was better than the R134a, R436A and R436B and POE oil system (23.4, 35.3 and 37.7%). The same tests with Al2O3 nanoparticles showed that the different nanoparticles properties have little effect on the refrigerator EE. Thus, TiO2 nanoparticles can be used in refrigerator to considerably increase the EE.

Venkataramana Murthy V. Padmanabhan; Senthil Kumar Palanisamy

2013-01-01T23:59:59.000Z

369

E-Print Network 3.0 - al mg fe Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

(2004); MC simulations Al: Fe3+: Mg 2:1:3 o (also Fe3+ clustering) Phase transition temperatures... Al Al Al Al Al Al Al Al ... Source: Collins, Gary S. - Department of...

370

Microsoft Word - AL2006-01.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6-01 6-01 Acquisition Regulation Date 10/27/05 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Electronic Subcontracting Reporting System (eSRS) References: FAR Subpart 19.7 The Small Business Subcontracting Program DEAR 919.705-6 Postaward responsibilities of the contracting officer AL 2005-07 Small Business Procurement Goals What is the Effective date of this Acquisition Letter (AL)? This AL is effective immediately after the eSRS goes online. When does this AL Expire? This AL remains in effect until superseded or canceled. What are the Points of Contact?

371

Das Standard Modell als Theorie  

NLE Websites -- All DOE Office Websites (Extended Search)

as a Theory as a Theory Ungelöste Rätsel Das Standard Modell als Theorie Auch wenn das Standard Modell die im Experiment beobachteten Phänomene sehr gut beschreibt, so ist es dennoch eine unvollständige Theorie. Das Problem liegt darin, dass das Standard Modell nicht erklären kann, warum einige Teilchen gerade diejenigen Eigenschaften haben, die wir beobachten. Zum Beispiel, auch wenn den Physikern die Massen aller Quarks - mit Ausnahme derjenigen des top Quarks - seit Jahren bekannt waren, so war es dennoch nicht möglich die Masse des top Quarks ohne die Hilfe experimenteller Daten genau vorherzusagen. Das ist deshalb so, weil das Standard Modell keine Erklärung dafür geben kann, warum die Liste der Teilchenmassen gerade diese Zahlenwerte aufweist.

372

UW Cosmogenic Isotopes Al-Be 1 EXTRACTION OF Al & Be FROM QUARTZ FOR ISOTOPIC ANALYSIS  

E-Print Network (OSTI)

UW Cosmogenic Isotopes Al-Be 1 EXTRACTION OF Al & Be FROM QUARTZ FOR ISOTOPIC ANALYSIS Summary This method is used to separate Al and Be for AMS analysis from pure quartz samples. After adding Be carrier, quartz is dissolved in HF. The solution is sub-sampled for determination of total Al content, then dried

Stone, John

373

ccsd00001116 Nucleation of Al 3 Zr and Al 3 Sc in aluminum alloys  

E-Print Network (OSTI)

ccsd­00001116 (version 1) : 4 Feb 2004 Nucleation of Al 3 Zr and Al 3 Sc in aluminum alloys: from 4, 2004) Zr and Sc precipitate in aluminum alloys to form the compounds Al3Zr and Al3Sc which

374

Application Of Ti-Based Self-Formation Barrier Layers To Cu Dual-Damascene Interconnects  

SciTech Connect

Cu interconnects have been used extensively in ULSI devices. However, large resistance-capacitance delay and poor device reliability have been critical issues as the device feature size has reduced to nanometer scale. In order to achieve low resistance and high reliability of Cu interconnects, we have applied a thin Ti-based self-formed barrier (SFB) using Cu(Ti) alloy seed to 45nm-node dual damascene interconnects and evaluated its performance. The line resistance and via resistance decreased significantly, compared with those of conventional Ta/TaN barriers. The stress migration performance was also drastically improved using the SFB process. A performance of time dependent dielectric breakdown revealed superior endurance. These results suggest that the Ti-based SFB process is one of the most promising candidates for advanced Cu interconnects. TEM and X-ray photoelectron spectroscopy observations for characterization of the Ti-based SFB structure were also performed. The Ti-based SFB consisted of mainly amorphous Ti oxides. Amorphous or crystalline Ti compounds such as TiC, TiN, and TiSi formed beneath Cu alloy films, and the formation varied with dielectric.

Ito, Kazuhiro; Kohama, Kazuyuki [Department of Materials Science and Engineering, Kyoto University, Kyoto 606-8501 (Japan); Ohmori, Kazuyuki; Mori, Kenichi; Maekawa, Kazuyoshi; Asai, Koyu [Process Technology Div., Renesas Electronics Corporation, Hitachinaka, Ibaraki 312-8504 (Japan); Murakami, Masanori [The Ritsumeikan Trust, Nakagyo-ku, Kyoto 604-8520 (Japan)

2010-11-24T23:59:59.000Z

375

Preparation of K2Ti6O13/TiO2 bio-ceramic on titanium substrate by micro-arc oxidation  

Science Journals Connector (OSTI)

K2Ti6O13/TiO2 bio-ceramic coatings are prepared successfully by micro-arc oxidation on titanium substrate in pure KOH electrolyte...2) and in KOH electrolyte with different concentrations (0.5–1.2 mol/L). The com...

Zhongwei Zhao; Xingyu Chen; Ailiang Chen; Guangsheng Huo…

2009-12-01T23:59:59.000Z

376

low Si p+-n junctions fabricated by focused ion beam Ga+ implantation through thin Ti and TiSi2 layers  

E-Print Network (OSTI)

metals and silicide layers, in conjunction with rapid thermal annealing (RTA) to complete metal silicides and it forms uniform thin films on Si. Most of the current research involving salicide+ implantation through Ti metal (ITM) and TiSi, (ITS) layers, followed by rapid thermal annealing (RTA), has been

Steckl, Andrew J.

377

Shape and strain-induced magnetization reorientation and magnetic anisotropy in thin film Ti/CoCrPt/Ti lines and rings  

E-Print Network (OSTI)

The contributions to the magnetic anisotropy of thin-film rings and lines of width 50 nm and above made from Ti(5?nm)/Co[subscript 0.66]Cr[subscript 0.22]Pt[subscript 0.12] (10 and 20 nm)/Ti (3 nm) with a perpendicular ...

Velazquez, D.

378

Investigation on the delaminated-pillared structure of TiO2-PILC synthesized by TiCl4 hydrolysis method  

Science Journals Connector (OSTI)

TiO2-PILCs were synthesized by the reaction between montmorillonite and acidic solutions of hydrolyzed TiCl4. Unlike commonly reported microporous pillared structure, a meso–microporous delaminated structure containing pillared fragments was observed in the resulting TiO2-PILC, based on the combined analyses of powder X-ray diffraction (XRD), nitrogen adsorption–desorption isotherms, chemical analysis, thermogravimetric (TG) and differential scanning calorimetry (DSC) analyses. Air-drying after ethanol extraction (EAD) is shown to be more effective than air-drying (AD) in preserving the delaminated structure in the resultant Ti-clay. A broad XRD peak at low 2? angle with a high d-spacing of ?6.6 nm was firstly reported and it was proposed to be correlated with the mesoporous delaminated structure rather than the (0 0 1) reflection of intercalated/pillared periodic structure. The resulting TiO2-PILC exhibits a good thermal stability as indicated by its surface area after calcination at 600 °C. Moreover, calcination above 300 °C results in the formation of nanocrystalline anatase in the TiO2-PILC, and the grain size of anatase increases with the increment of calcination temperature. However, no phase transformation from anatase to rutile was observed even under calcination at 1000 °C. These fundamental results provide new insights about the structure of TiO2-PILC synthesized by TiCl4 hydrolysis method.

Peng Yuan; Xiaoling Yin; Hongping He; Dan Yang; Linjiang Wang; Jianxi Zhu

2006-01-01T23:59:59.000Z

379

Wettability of Ti3SiC2 by Ag-Cu and Ag-Cu-Ti O. Dezellus,a*  

E-Print Network (OSTI)

ternary ceramics Mn+1AXn (where M corresponds to an early transition metal, A is an A-group element, and X of metals and ceramic properties [1]. Among these compounds, titanium silicon carbide (Ti3SiC2) has gained, the ternary carbide Ti3SiC2 has gained much attention due to its unique characteristics combining

Boyer, Edmond

380

Preparation of Highly Transparent TiO2-based Thin Film Photocatalysts by an Ion Engineering Method: Ionized Cluster Beam Deposition  

Science Journals Connector (OSTI)

Highly transparent TiO2 and TiO2-based binary oxide (TiO2/SiO2 and TiO2/B2O3) thin films of different TiO2 contents were successfully prepared by using an ion engineering technique as a dry process. These transpa...

Masato Takeuchi; Masakazu Anpo

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Comparative Genomic Discovery of miRNAs Grad et al.  

E-Print Network (OSTI)

Comparative Genomic Discovery of miRNAs Grad et al. Computational and Experimental Identification throughout the adult life cycle (Feinbaum and Ambros, 1999; Lee et al., 1993; Reinhart et al., 2000 al., 1993; Wightman et al., 1993; Reinhart et al., 2000; Slack et al., 2000). Both lin-4 and let-7

Church, George M.

382

High temperature superconductor step-edge Josephson junctions using Ti-Ca-Ba-Cu-O  

SciTech Connect

A process is disclosed for formulating non-hysteretic and hysteretic Josephson junctions using HTS materials which results in junctions having the ability to operate at high temperatures while maintaining high uniformity and quality. The non-hysteretic Josephson junction is formed by step-etching a LaAlO[sub 3] crystal substrate and then depositing a thin film of TlCaBaCuO on the substrate, covering the step, and forming a grain boundary at the step and a subsequent Josephson junction. Once the non-hysteretic junction is formed the next step to form the hysteretic Josephson junction is to add capacitance to the system. In the current embodiment, this is accomplished by adding a thin dielectric layer, LaA1O[sub 3], followed by a cap layer of a normal metal where the cap layer is formed by first depositing a thin layer of titanium (Ti) followed by a layer of gold (Au). The dielectric layer and the normal metal cap are patterned to the desired geometry. 8 figs.

Ginley, D.S.; Hietala, V.M.; Hohenwarter, G.K.G.; Martens, J.S.; Plut, T.A.; Tigges, C.P.; Vawter, G.A.; Zipperian, T.E.

1994-10-25T23:59:59.000Z

383

High temperature superconductor step-edge Josephson junctions using Ti-Ca-Ba-Cu-O  

SciTech Connect

A process for formulating non-hysteretic and hysteretic Josephson junctions using HTS materials which results in junctions having the ability to operate at high temperatures while maintaining high uniformity and quality. The non-hysteretic Josephson junction is formed by step-etching a LaAlO.sub.3 crystal substrate and then depositing a thin film of TlCaBaCuO on the substrate, covering the step, and forming a grain boundary at the step and a subsequent Josephson junction. Once the non-hysteretic junction is formed the next step to form the hysteretic Josephson junction is to add capacitance to the system. In the current embodiment, this is accomplished by adding a thin dielectric layer, LaA1O.sub.3, followed by a cap layer of a normal metal where the cap layer is formed by first depositing a thin layer of titanium (Ti) followed by a layer of gold (Au). The dielectric layer and the normal metal cap are patterned to the desired geometry.

Ginley, David S. (Evergreen, CO); Hietala, Vincent M. (Placitas, NM); Hohenwarter, Gert K. G. (Madison, WI); Martens, Jon S. (Sunnyvale, CA); Plut, Thomas A. (Albuquerque, NM); Tigges, Chris P. (Albuquerque, NM); Vawter, Gregory A. (Albuquerque, NM); Zipperian, Thomas E. (Albuquerque, NM)

1994-10-25T23:59:59.000Z

384

Coordinatively unsaturated Al3+ centers as binding sites for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coordinatively unsaturated Al3+ centers as binding sites for active catalyst phases on ?-Al2O3. Coordinatively unsaturated Al3+ centers as binding sites for active catalyst...

385

Interlaboratory Comparisons of NbTi Critical Current Measurements  

SciTech Connect

We report on a multi-institute comparison of critical current data measured on a modern NbTi wire for the Large Hadron Collider (LHC), which has shown a standard deviation below 1% in critical current density spread in more than 1500 measurements. Interlaboratory comparisons on Nb{sub 3}Sn wires have shown ambiguities that could be attributable to strain related differences in critical current density, originating from differences in sample handling, reaction, and mounting techniques, or also to differences in the magnetic field and current calibrations between the institutes. A round robin test of a well characterized NbTi wire provides a baseline variance in critical current results that is presumed to be attributable only to differences in the characterization systems. Systematic differences on the order of 3.5% are found in the comparison. The most likely cause for the observed differences is a small diameter holder that brings the wire into a strain regime in which strain effects can no longer be ignored. A NbTi round robin test, when performed properly, will separate system differences from sample specific differences and provide laboratories with an opportunity to calibrate equipment against a standard measurement.

Godeke, A.; Turrioni, D.; Boutboul, T.; Cheggour, N.; Goodrich, L.F.; Ghosh, A.; Den Ouden, A.; Meinesz, M.

2009-08-16T23:59:59.000Z

386

Microsoft Word - Final MR AL.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

No. AL 2009-01 No. AL 2009-01 Acquisition Regulation Date: 10/06/2008 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Management Reserve and Contingency References: FAR Subpart 15.4 Contract Pricing FAR Part 31 Contract Cost Principles and Procedures FAR 31.205-7 Contingencies DEAR 915.404-4-70-2 Weighted Guidelines System DOE Order 413.3A Program and Project Management for the Acquisition of Capital Assets DOE Acquisition Guide Weighted Guidelines Chapter 15.4-2 When is this Acquisition Letter (AL) effective? This AL is effective upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled.

387

Microsoft Word - AL2008-05.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Department of Energy No. AL 2008-05 Department of Energy No. AL 2008-05 Acquisition Regulation Date 04/03/2008 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Environmental, Energy, and Transportation Management References: Executive Order 13423, dated January 24, 2007 Implementing Instructions, dated March 28, 2007 When is this Acquisition Letter (AL) effective? This AL is effective upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled by amendments of the Federal Acquisition Regulation (FAR) or the Department of Energy Acquisition Regulation (DEAR). Whom do you Contact for More Information? For Department of Energy (DOE) contracts, contact Richard Langston, Office of Procurement

388

ALS Ceramics Materials Research Advances Engine Performance  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Ceramics Materials Research ALS Ceramics Materials Research Advances Engine Performance ALS Ceramics Materials Research Advances Engine Performance Print Thursday, 27 September 2012 00:00 LBNL senior materials scientist and UC Berkeley professor Rob Ritchie has been researching the fracture behavior of a wide array of materials for the past 40 years, the last ten of them using the facilities at the ALS. From human bone to synthetic engineering materials such as shape-memory metals and composites, Ritchie has illuminated groundbreaking cracking patterns and the underlying mechanistic processes using the x-ray synchrotron micro-tomography at ALS Beamline 8.3.2. Summary Slide ritchie ceramics This 3D image of a ceramic composite specimen imaged under load at 1750C shows the detailed fracture patterns that researchers are able to view using ALS Beamline 8.3.2. The vertical white lines are the individual silicon carbide fibers in this sample about 500 microns in diameter.

389

Microsoft Word - AL2006-10.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

AL-2006-10 AL-2006-10 Acquisition Regulation Date 08/11/06 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: CLASS DEVIATION FOR CERTAIN DEAR INTELLECTUAL PROPERTY CLAUSES References: DEAR 970.2704 Rights in Data DEAR 970.2770 Technology Transfer DEAR 970.5227-2 Rights in Data-Technology Transfer DEAR 970.5227-3 Technology Transfer Mission When is this Acquisition Letter (AL) Effective? This AL is effective upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Robert M. Webb of the Office of Procurement and Assistance Policy at (202)287-1338 or Robert.Webb@hq.doe.gov.

390

Status of cross-section data for gas production from vanadium and {sup 26}AL from silicon carbide in a D-T fusion reactor.  

SciTech Connect

Current designs of fusion-reactor systems seek to use radiation-resistant, low-activation materials that support long service lifetimes and minimize radioactive-waste problems after decommissioning. Reliable assessment of fusion materials performance requires accurate neutron-reaction cross sections and radioactive-decay constants. The problem areas usually involve cross sections since decay parameters tend to be better known. The present study was motivated by two specific questions: (i) Why are the {sup 51}V(n,np){sup 50}Ti cross section values in the ENDF/B-VI library so large (a gas production issue)? (ii) How well known are the cross sections associated with producing 7.4 x 10{sup 5} y {sup 26}Al in silicon carbide by the process {sup 28}Si(n,np+d){sup 27} Al(n,2n){sup 26}Al (a long-lived radioactivity issue)? The energy range 14-15 MeV of the D-T fusion neutrons is emphasized. Cross-section error bars are needed so that uncertainties in the gas and radioactivity generated over the lifetime of a reactor can be estimated. We address this issue by comparing values obtained from prominent evaluated cross-section libraries. Small differences between independent evaluations indicate that a physical quantity is well known while the opposite signals a problem. Hydrogen from {sup 51}V(n,p){sup 51}Ti and helium from {sup 51}V(n,{alpha}){sup 48}Sc are also important sources of gas in vanadium, so they too were examined. We conclude that {sup 51}V(n,p){sup 51}Ti is adequately known but {sup 51}V(n,np+d){sup 50}Ti is not. The status for helium generation data is quite good. Due to recent experimental work, {sup 27}Al(n,2n){sup 26}Al seems to be fairly well known. However, the situation for {sup 28}Si(n,np+d){sup 27}Al remains unsatisfactory.

Gomes, I. C.

1998-08-11T23:59:59.000Z

391

Microsoft Word - AL2005-03.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

AL 2005-03 AL 2005-03 Acquisition Regulation Date 10/08/04 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Independent Peer Review Program for Contractors' Purchasing Systems References: FAR 44.3, Contractors' Purchasing Systems Reviews DEAR Subpart 970.44 - Management and Operating Contractor Purchasing DOE Acquisition Guide, Chapter 1.2, Balanced Scorecard Performance Assessment Program (DOE only) DOE Acquisition Guide, Chapter 70.7, Contract Administration, Reference Book for Contract Administrators, Chapter 10 (DOE only) When is this Acquisition Letter (AL) effective? This AL is effective 10 business days from the date of issuance.

392

Microsoft Word - AL2006-07.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Department of Energy No. AL-2006-07 Acquisition Regulation Date 08/23/06 ACQUISITION LETTER This Acquisition Letter is issued by the Procurement Executives of DOE and NNSA. Subject: DOE Order 361.1A, Acquisition Career Development Program References: DOE O 361.1A, Acquisition Career Development (ACD) Program Office of Federal Procurement Policy (OFPP) Policy Letter 05-01, Developing and Managing the Acquisition Workforce OFPP Policy Letter 06-01 OFPP Memoranda, The Federal Acquisition Certification in Contracting Program, dated January 20, 2006, When is this Acquisition Letter (AL) Effective? This AL is effective immediately When does this AL Expire?

393

Märchenfilme im Unterricht Deutsch als Fremdsprache.  

E-Print Network (OSTI)

??Diese Masterarbeit befasst sich mit dem Einsatz von Märchenfilmen im Unterricht Deutsch als Fremdsprache und versucht folgende Fragen zu beantworten: Welches Potential stellen Märchenfilme für… (more)

Serdinsky, Andrea

2014-01-01T23:59:59.000Z

394

Optical properties of ??-CoAl  

Science Journals Connector (OSTI)

The optical absorptance of ??-CoAl in the (0.1-2.5)-eV region was measured and analyzed by the Kramers-Kronig method. The optical conductivity shows interband features beginning below 0.1 eV, with several structures below 2 eV. These structures agree with those calculated from the energy bands of Moruzzi, Williams, and Gelatt. The experimentally observed systematics in CoAl and NiAl confirm our previous interpretation of the spectra of ??-NiAl, and disagree with other experimental and theoretical attempts to understand the optical properties of these compounds.

D. W Lynch; B. R. Boeke; D. J. Peterman

1982-04-15T23:59:59.000Z

395

Wasserstoff als Kraftstoff im Deutschen Verkehrssektor  

Science Journals Connector (OSTI)

Wasserstoff ist ein Grundelement der (petro-)chemischen Industrie. Darüber hinaus ist der Einsatz von Wasserstoff als Treibstoff für Brennstoffzellenfahrzeuge in der Erprobung. Er soll helfen, insbesondere Tre...

Christina Wulf; Martin Kaltschmitt

2013-06-01T23:59:59.000Z

396

Al Tayyar Energy | Open Energy Information  

Open Energy Info (EERE)

Tayyar Energy Jump to: navigation, search Name: Al Tayyar Energy Place: Abu Dhabi, United Arab Emirates Sector: Renewable Energy Product: Provides development capital and equity...

397

Photoelectrochemical Water Splitting of Nitrogen and Hydrogen Treated P25 TiO2 Films  

E-Print Network (OSTI)

CdS and CdSe have been successfully employed in the sensitization of TiO 2 . Although sensitization and doping

Zavodivker, Liat Shari

2014-01-01T23:59:59.000Z

398

Oxygen-Isotope Exchange between CO2 and Solid Ti18O2  

Science Journals Connector (OSTI)

Oxygen-Isotope Exchange between CO2 and Solid Ti18O2 ... Analysis of the isotopic composition of the gases produced has revealed ... ...

Svatopluk Civis?; Martin Ferus; Pavel Kuba?t; Marke?ta Zukalova?; Ladislav Kavan

2011-05-17T23:59:59.000Z

399

Phase separation and charge localization in UHV-lithiated anatase TiO{sub 2} nanoparticles  

SciTech Connect

The insertion of lithium in anatase TiO{sub 2} nanoparticles under ultrahigh vacuum (UHV) conditions is studied using x-ray absorption spectroscopy (XAS) and resonant photoelectron spectroscopy (RPES) at the Ti L{sub 2,3} edge. It is demonstrated that XAS can be used to monitor the separation into an anatase phase and a lithium titanate phase of formal stoichiometry Li{sub 0.5}TiO{sub 2}. The initial state properties of the Ti 3d states of the lithium titanate phase are investigated using ab initio electronic structure calculations. The calculations show a correlation driven separation of Ti 3d states from the conduction band in agreement with previous studies. It is shown that Ti in different oxidation states (Ti{sup 3+} and Ti{sup 4+}) is formed as a direct consequence of the electron-electron interaction. RPES and XAS spectra confirm the presence of electronically inequivalent Ti sites. The site-sensitivity of the RPES spectra at selected electron binding energies is found to be consistent with the calculations.

Richter, J.H.; Henningsson, A.; Sanyal, B.; Karlsson, P.G.; Siegbahn, H.; Eriksson, O.; Sandell, A. [Department of Physics, Uppsala University, P.O. Box 530, S-751 21 Uppsala (Sweden); Andersson, M. P.; Uvdal, P. [Chemical Physics, Department of Chemistry, Lund University, P.O. Box 124, S-221 00 Lund (Sweden)

2005-06-15T23:59:59.000Z

400

Adsorption and Oxidation of Elemental Mercury over Ce-MnOx/Ti-PILCs  

Science Journals Connector (OSTI)

A series of innovative Ce–Mn/Ti-pillared-clay (Ce–Mn/Ti-PILC) catalysts combining the advantages of PILCs and Ce–Mn were investigated for elemental mercury (Hg0) capture at 100–350 °C in the absence of HCl in the flue gas. ... The catalyst characterization indicated that the 6%Ce-6%MnOx/Ti-PILC catalyst possessed a large specific surface area and high dispersion of Ce and Mn on the surface. ... The experimental results indicated that the 6%Ce-6%MnOx/Ti-PILC catalyst exhibited high Hg0 capture (>90%) at 100–350 °C. ...

Chuan He; Boxiong Shen; Jianhong Chen; Ji Cai

2014-06-23T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Structure of epitaxial (Fe,N) codoped rutile TiO2 thin films...  

NLE Websites -- All DOE Office Websites (Extended Search)

No evidence of structural disorder associated with a high concentration of oxygen vacancies is observed. Substitution of Fe for Ti could not be confirmed, although secondary...

402

Growth of Epitaxial gamma-Al2O3 Films on Rigid Single-Crystal Ceramic Substrates and Flexible, Single-Crystal-Like Metallic Substrates by Pulsed Laser Deposition  

SciTech Connect

Epitaxial -Al2O3 thin films were grown on diverse substrates using pulsed laser deposition. The high quality of epitaxial growth and cubic structure of -Al2O3 films was confirmed by x-ray diffraction. SrTiO3 and MgO single crystal substrates were used to optimize the growth conditions for epitaxial -Al2O3 film. Under the optimized conditions, epitaxial -Al2O3 thin films were grown on flexible, single-crystal-like, metallic templates. These included untextured Hastelloy substrates with a biaxially textured MgO layer deposited using ion-beam-assisted-deposition and biaxially textured Ni-W metallic tapes with epitaxially grown and a biaxially textured, MgO buffer layer. These biaxially textured, -Al2O3 films on flexible, single-crystal-like substrates are promising for subsequent epitaxial growth of various complex oxide films used for electrical, magnetic and electronic device applications.

Shin, Junsoo [ORNL; Goyal, Amit [ORNL; Wee, Sung Hun [ORNL

2009-01-01T23:59:59.000Z

403

Microsoft Word - AL2003-04.doc | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Word - AL2003-04.doc Microsoft Word - AL2003-04.doc More Documents & Publications Microsoft Word - AL2006-08.doc AL2004-01r2.pdf City of Tulare Renewable Biogas Fuel Cell Project...

404

Microsoft Word - AL2004-02.doc | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

4-02.doc Microsoft Word - AL2004-02.doc Microsoft Word - AL2004-02.doc More Documents & Publications Microsoft Word - AL2005-02.doc flash2004-07.pdf Microsoft Word - AL-Omnibus FY...

405

AL2007-05.doc | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

5.doc&0; AL2007-05.doc&0; AL2007-05.doc&0; More Documents & Publications Microsoft Word - AL2006-08.doc Policy Flash 2012-1 Microsoft Word - AL 2010-07 Acquistion Letters...

406

Microsoft Word - AL2005-02.doc | Department of Energy  

Energy Savers (EERE)

2.doc Microsoft Word - AL2005-02.doc Microsoft Word - AL2005-02.doc More Documents & Publications Microsoft Word - AL2004-02.doc Microsoft Word - AL-Omnibus FY 2009 Apr 22 2009 all...

407

AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT Acquisition Letters (AL)...

408

Ultraviolet and Visible Photochemistry of Methanol at 3D Mesoporous Networks: TiO2 and Au–TiO2  

Science Journals Connector (OSTI)

A higher excited-state electron density arises for UV-irradiated TiO2 aerogel relative to commercial nanoparticulate TiO2, indicating that 3D networked TiO2 more efficiently separates electron–hole pairs. ... For both UV and visible irradiation, the same light source was employed: a high-pressure 350-W mercury arc lamp (Oriel Corp.) equipped with a water filter to remove IR radiation. ... For visible irradiation, three bandpass filters (70 nm full-width at half-maximum transmission profile) were used with peak transmissions centered at 400, 500, or 550 nm. ...

Dimitar A. Panayotov; Paul A. DeSario; Jeremy J. Pietron; Todd H. Brintlinger; Lindsey C. Szymczak; Debra R. Rolison; John R. Morris

2013-05-23T23:59:59.000Z

409

An application of Ti-K X-ray absorption edges and fine structures to the study of substoichiometric titanium carbide TiC1-x  

E-Print Network (OSTI)

of substoichiometric titanium carbide TiC1-x V. Moisy-Maurice and C. H. de Novion C.E.A./IRDI/DMECN/DTech, Laboratoire des échantillons de TiC1-x, (0,5 ~ 1 - x ~ 0,97). Quand la teneur x en lacunes de carbone augmente, (i 4p du titane (situé à 10-15 eV au-dessus du niveau de Fermi EF dans TiC0,97) se déplace

Paris-Sud XI, Université de

410

Measurement of the 44Ti(alpha,p)47V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed 44Ti from radioactive waste  

E-Print Network (OSTI)

Measurement of the 44Ti(alpha,p)47V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed 44Ti from radioactive waste

Murphy, A; Davinson, T; Dressler, R; Fallis, J; Kankainen, A; Laird, A; Murphy, C; Seiffert, C; Schumann, D; Stowasser, T; Stora, T; Wang, C; Woods, P

2014-01-01T23:59:59.000Z

411

Effect of TiO2 Content on Ethanol Electrooxidation in Alkaline Media Using Pt Nanoparticles Supported on Physical Mixtures of Carbon and TiO2 as Electrocatalysts  

Science Journals Connector (OSTI)

Pt nanoparticles supported on physical mixtures of carbon and TiO2 (Pt/(C?+?TiO2) electrocatalyst) were tested for ethanol electrooxidation in alkaline media. The electrocatalysts were...2 mass ratios using boroh...

R. F. B. De Souza; G. S. Buzzo; J. C. M. Silva; E. V. Spinacé…

2014-04-01T23:59:59.000Z

412

Quantitatively Probing the Al Distribution in Zeolites  

SciTech Connect

The degree of substitution of Si4+ by Al3+ in the oxygen-terminated tetrahedra (Al T-sites) of zeolites determines the concentration of ion-exchange and Brønsted acid sites. As the location of the tetrahedra and the associated subtle variations in bond angles influence the acid strength, quantitative information about Al T-sites in the framework is critical to rationalize catalytic properties and to design new catalysts. A quantitative analysis is reported that uses a combination of extended X-ray absorption fine structure (EXAFS) analysis and 27Al MAS NMR spectroscopy supported by DFT-based molecular dynamics simulations. To discriminate individual Al atoms, sets of ab initio EXAFS spectra for various T-sites are generated from DFT-based molecular dynamics simulations allowing quantitative treatment of the EXAFS single- and multiple-photoelectron scattering processes out to 3-4 atom shells surrounding the Al absorption center. It is observed that identical zeolite types show dramatically different Al-distributions. A preference of Al for T-sites that are part of one or more 4-member rings in the framework over those T-sites that are part of only 5- and 6-member rings in the HBEA150 sample has been determined from a combination of these methods. This work was supported by the U. S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences.

Vjunov, Aleksei; Fulton, John L.; Huthwelker, Thomas; Pin, Sonia; Mei, Donghai; Schenter, Gregory K.; Govind, Niranjan; Camaioni, Donald M.; Hu, Jian Z.; Lercher, Johannes A.

2014-06-11T23:59:59.000Z

413

Soziale Beziehungen und Unterrichtsklima im Deutsch als Fremdsprache–/Deutsch als Zweitsprache–Unterricht.  

E-Print Network (OSTI)

??In der vorliegenden Arbeit wird das Konzept „Klima“ in Bezug auf den Deutsch als Fremdsprache–/Deutsch als Zweitsprache–Unterricht untersucht. Es wird dargestellt, welchen Stellenwert ein positives… (more)

Tischler, Christina

2013-01-01T23:59:59.000Z

414

A new step size rule in Yan et al.'s self-adaptive projection method  

E-Print Network (OSTI)

Jan 29, 2015 ... Abstract: In this paper, we propose a new step size rule to accelerate Yan et al.'s self-adaptive projection method. Under the new step size ...

Gao Bin

2015-01-29T23:59:59.000Z

415

Crystallographic Consulting Brings Research to the ALS  

NLE Websites -- All DOE Office Websites (Extended Search)

Crystallographic Consulting Brings Crystallographic Consulting Brings Research to the ALS Crystallographic Consulting Brings Research to the ALS Print Wednesday, 06 February 2013 15:50 cc Tom Pauly and Josh Stillwell, managing partners at Crystallographic Consulting, have a rich history as synchrotron users. It is likely because of this that they're entrusted with the protein crystallography research for about 15 cutting-edge pharmaceutical companies. They conduct most of their research at ALS Beamline 5.0.2. Crystallographic Consulting has a varied client base that includes many of the participating research team (PRT) members at the Berkeley Center for Structural Biology (BCSB), which operates five ALS beamlines. As PRT members, companies are guaranteed a certain amount of beam time. Crystallographic Consulting also contracts beam time for another 10-12 companies. Pauly spends about 15-20 hours a week at the ALS, with most of his research supporting pharmaceutical companies working on new treatments for metabolic diseases and cancer.

416

ALS Ceramics Materials Research Advances Engine Performance  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Ceramics Materials Research ALS Ceramics Materials Research Advances Engine Performance ALS Ceramics Materials Research Advances Engine Performance Print Thursday, 27 September 2012 00:00 ritchie ceramics This 3D image of a ceramic composite specimen imaged under load at 1750C shows the detailed fracture patterns that researchers are able to view using ALS Beamline 8.3.2. The vertical white lines are the individual silicon carbide fibers in this sample about 500 microns in diameter. LBNL senior materials scientist and U.C. Berkeley professor Rob Ritchie has been researching the fracture behavior of a wide array of materials for the past 40 years, the last ten of them using the facilities at the ALS. From human bone to synthetic engineering materials such as shape-memory metals

417

ALS Ceramics Materials Research Advances Engine Performance  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Ceramics Materials Research ALS Ceramics Materials Research Advances Engine Performance ALS Ceramics Materials Research Advances Engine Performance Print Thursday, 27 September 2012 00:00 ritchie ceramics This 3D image of a ceramic composite specimen imaged under load at 1750C shows the detailed fracture patterns that researchers are able to view using ALS Beamline 8.3.2. The vertical white lines are the individual silicon carbide fibers in this sample about 500 microns in diameter. LBNL senior materials scientist and U.C. Berkeley professor Rob Ritchie has been researching the fracture behavior of a wide array of materials for the past 40 years, the last ten of them using the facilities at the ALS. From human bone to synthetic engineering materials such as shape-memory metals

418

Microsoft Word - AL2005-07.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Order 361.1A, Acquisition Career Development DOE Order 361.1A, Acquisition Career Development Program, Chapter I, Contracting and Purchasing Career Development Program Module Revised DOE Core Curriculum References: DOE Order 361.1A Acquisition Career Development Program When is this Acquisition Letter (AL) Effective? This AL is effective immediately. The information and guidance provided in the AL does not apply to the National Nuclear Security Administration (NNSA). When Does This AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Cynthia Yee, Director, Acquisition Career Development Program, Office of Procurement and Assistance Management at (202) 287-1666 or by email at Cynthia.Yee@hq.doe.gov. Visit our website at www.pr.doe.gov for additional information on Acquisition

419

Boston University AccelerAted MedicAl And dentAl ProgrAMs  

E-Print Network (OSTI)

Boston University AccelerAted MedicAl And dentAl ProgrAMs teAcher evAlUAtion To the applicant: Applicants to any of the College of Arts & Sciences' accelerated medical or dental programs must submit three (last, first, middle initial) Date of birth Accelerated Program of application (please check one

Finzi, Adrien

420

Advanced Visible-Light-Driven Self-Cleaning Cotton by Au/TiO2/SiO2 Photocatalysts  

Science Journals Connector (OSTI)

Synergy of Low-Energy {101} and High-Energy {001} TiO2 Crystal Facets for Enhanced Photocatalysis ... Synergy of Low-Energy {101} and High-Energy {001} TiO2 Crystal Facets for Enhanced Photocatalysis ...

RongHua Wang; XiaoWen Wang; John H. Xin

2009-10-29T23:59:59.000Z

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Preparation of TiO2(110)-(1x1) Surface via UHV Cleavage: An scanning...  

NLE Websites -- All DOE Office Websites (Extended Search)

Preparation of TiO2(110)-(1x1) Surface via UHV Cleavage: An scanning tunneling microscopy study. Preparation of TiO2(110)-(1x1) Surface via UHV Cleavage: An scanning tunneling...

422

TiO2 nanoparticles on nitrogen-doped graphene as anode material for lithium ion batteries  

Science Journals Connector (OSTI)

Anatase TiO2...nanoparticles in situ grown on nitrogen-doped, reduced graphene oxide (rGO) have been successfully synthesized ... as an anode material for the lithium ion battery. The nanosized TiO2 particles wer...

Dan Li; Dongqi Shi; Zongwen Liu; Huakun Liu…

2013-04-01T23:59:59.000Z

423

Characteristics of V2O5/Ti-PILC catalyst for the reduction of NO by NH3  

Science Journals Connector (OSTI)

Titania-pillared clay (Ti-PILC) as a catalyst support exhibited peculiar physicochemical characteristics compared to that of titania for the reduction of NO by NH3. The morphological variation of Ti-PILC was examined with respect to the preparation method. For the freeze-dried Ti-PILC, the development of needle-like crystallites, which may reveal the formation of a “house-of-cards” structure by delamination of Ti-PILC, has been observed. Ti-PILC catalyst contains high surface acidity examined by NH3 TPD. Without the impregnation of WO3 and MoO3 on V2O5/Ti-PILC catalyst as a promoter, the catalyst exhibits competitive NO removal performance to a commercial V2O5-WO3/TiO2 catalyst. In addition, Ti-PILC catalyst also exhibits the strong sulfur tolerance mainly attributed to the unique pore structure of the catalyst.

Ho Jeong Chae; In-Sik Nam; Young Gul Kim; Hee Sung Yang; Hyun Chul Choi{rk; Seok Lyong Song{rk

1999-01-01T23:59:59.000Z

424

Atomic Layer Deposition of TiO2 on Aerogel Templates: New Photoanodes for Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

Atomic layer deposition was employed to coat the aerogel template conformally with various thicknesses of TiO2 with subnanometer precision. ... The TiO2-coated aerogel membranes were incorporated as photoanodes in dye-sensitized solar cells. ...

Thomas W. Hamann; Alex B. F. Martinson; Jeffrey W. Elam; Michael J. Pellin; Joseph T. Hupp

2008-06-18T23:59:59.000Z

425

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First-Principles  

E-Print Network (OSTI)

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First The present study reinvestigates the Al-Ce and Al-Nd phase diagrams and reoptimizes their thermody- namics results and theoretical calculations show that Al2Nd (or Al2Ce) should be treated as a stoichiometric

Widom, Michael

426

Comment on “Pb1?xCaxTiO3 solid solution (x=0.0, 0.25, 0.50, and 0.75): A theoretical and experimental approach”  

Science Journals Connector (OSTI)

The evolution of different phases in the important ferroelectric material Pb1?xCaxTiO3 for different values of x has recently been studied by de Lazaro et al. [Phys. Rev. B 75, 144111 (2007)] using x-ray diffraction (XRD) and Raman techniques, arriving at self-contradictory results (pseudocubic from XRD and noncubic from Raman). A “tailing” of many Bragg peaks can be seen in the XRD data of de Lazaro et al., similar to that observed by Chandra and Pandey [J. Mater. Res. 18, 407 (2003)], but this has not been included in their analysis. Our detailed Rietveld analysis has shown that for 0.40?x?0.56, the orthorhombic (Pbnm) and tetragonal (P4mm) phases coexist. We also present our Raman data, which differ with those of de Lazaro et al. but follow an expected sequential change in the entire compositional range.

Amreesh Chandra

2008-01-04T23:59:59.000Z

427

Stable atomic structure of NiTi austenite  

SciTech Connect

Nitinol (NiTi), the most widely used shape-memory alloy, exhibits an austenite phase that has yet to be identified. The usually assumed austenitic structure is cubic B2, which has imaginary phonon modes, hence it is unstable. We suggest a stable austenitic structure that “on average” has B2 symmetry (observed by x-ray and neutron diffraction), but it exhibits finite atomic displacements from the ideal B2 sites. The proposed structure has a phonon spectrum that agrees with that from neutron scattering, has diffraction spectra in agreement with x-ray diffraction, and has an energy relative to the ground state that agrees with calorimetry data.

Zarkevich, Nikolai A [Ames Laboratory; Johnson, Duane D [Ames Laboratory

2014-08-01T23:59:59.000Z

428

Effect of WC/TiC grain size ratio on microstructure and mechanical properties of WCTiCCo cemented carbides  

E-Print Network (OSTI)

of TiC powder as 1 lm. The microstructures of sintered WC­TiC­10 wt%Co cemented carbides were than that expected by modified Hall­Petch type equation. Transverse rupture strength of WC­20TiC­10 wt for decades [1]. Generally, cemented carbides are based on the WC­Co and some cubic carbide such as TiC, Ta

Hong, Soon Hyung

429

Real-WoRld Technology TesTs  

NLE Websites -- All DOE Office Websites (Extended Search)

Electric submersible pumps (ESPs) are a versatile means of Electric submersible pumps (ESPs) are a versatile means of artificial lift used in oil and water wells. A drawback to an ESP installation is that it is a complex operation with considerable equipment, personnel and time required. When a remove/re- pair/replace operation is necessary, the same considerations are required. The conventional methodology requires a service rig and crew to pull and re-install the tubing; a cable spooler for the electric cable; and banding personnel and equipment. In addition to the time and expense, there are safety and risk is- sues associated with handling the tubing and cable. Zeitecs Inc. developed a technology consisting of a perma- nent component installed at the bottom of the tubing and a retrievable component. The pump, seal and motor of the ESP

430

Real-WoRld Technology TesTs  

NLE Websites -- All DOE Office Websites (Extended Search)

volumes of contaminated water are typically pro- duced during the course of oil and gas operations, from drill- ing, completion and production activities. Disposal or treat-...

431

Vous tes tous les bienvenus. Responsable : Clara Santato  

E-Print Network (OSTI)

-thin Film Solid-Oxide Fuel Cell Technology Development: Status, Challenges, and Opportunities Solid oxide-thin solid oxide fuel cell that offers dramatic cost reduction and reliability improvement. The use of ultra. In this talk, recent advancement in thin film solid oxide fuel cell research and development will be reviewed

Meunier, Michel

432

Vous tes tous les bienvenus. Responsable : Clara Santato  

E-Print Network (OSTI)

flexibility are over ten times thinner, lighter and more flexible than any other solar cell of any technology as yellow and magenta charges in ink-jet printers. Ultrathin and lightweight organic solar cells with high to date. They reversibly withstand extreme mechanical deformation and have unprecedented solar cell

Meunier, Michel

433

Holographically Defined TiO2 Electrodes for Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

Holographically Defined TiO2 Electrodes for Dye-Sensitized Solar Cells ... We analyze the morphological features of the h-TiO2 electrodes and consider their applicability to dye-sensitized solar cells (DSSCs). ... holographic lithography; solar cells ...

Woo-Min Jin; Ju-Hwan Shin; Chang-Yeol Cho; Ji-Hwan Kang; Jong Hyeok Park; Jun Hyuk Moon

2010-10-27T23:59:59.000Z

434

Prediction of a Dirac state in monolayer TiB2  

Science Journals Connector (OSTI)

We predict the existence of a Dirac state in a monolayer TiB2 sheet (m?TiB2), a two-dimensional metal diboride, based on first-principles calculations. The band structure of m?TiB2 is found to be characterized with anisotropic Dirac cones with the largest Fermi velocity of 0.57×106 m/s, which is about one-half of that of graphene. The Dirac point is located at the Fermi level between the K and ? points, with the Dirac states arising primarily from the d orbitals of Ti. Freestanding m?TiB2 exhibits a bending instability, so that a planar m?TiB2 needs to be stabilized on a substrate. The calculation of m?TiB2 on a h-BN substrate reveals a negligible influence of the h-BN substrate on the electronic properties of m?TiB2. Our findings extend the Dirac materials to metal diborides.

L. Z. Zhang; Z. F. Wang; S. X. Du; H.-J. Gao; Feng Liu

2014-10-03T23:59:59.000Z

435

Solar Energy Materials & Solar Cells 71 (2002) 261271 Photoelectric behavior of nanocrystalline TiO2  

E-Print Network (OSTI)

Solar Energy Materials & Solar Cells 71 (2002) 261­271 Photoelectric behavior of nanocrystalline Ti 100101, People's Republic of China e Synchrotron Radiation Laboratory at Institute of High Energy Physics. A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6:1 mA cm�2

Huang, Yanyi

436

Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). ...  

NLE Websites -- All DOE Office Websites (Extended Search)

CO2 with Oxygen Adatoms on Rutile TiO2(110). Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). Abstract: The interactions of CO2 with oxygen adatoms (Oa’s) on...

437

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications  

E-Print Network (OSTI)

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications by anodic oxidation of titanium foil followed with O2 and CO annealing were employed as matrices consisted of Ti3+ defects with carbon-doping and exhibited well defined quasi-reversible cyclic voltammetric

Cao, Guozhong

438

Highly ordered TiO2 macropore arrays as transparent photocatalysts  

Science Journals Connector (OSTI)

Highly ordered transparent TiO2 macropore arrays were synthesized via a simple glass-clamping method at room temperature. The as-synthesized TiO2 macropore arrays show high transmittance in the visible light region and can be used ...

Yuan Dong; Junfeng Chao; Zhong Xie; Xin Xu; Zhuoran Wang; Di Chen

2012-01-01T23:59:59.000Z

439

Non-linear Damage Accumulation in Au-irradiated SrTiO3. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Damage Accumulation in Au-irradiated SrTiO3. Abstract: Ion-induced damage in strontium titanate (SrTiO3) has been investigated using 1.0 MeV Au ions at 150 K and room...

440

Surface studies of nitrogen implanted TiO2 Matthias Batzill a,*, Erie H. Morales b  

E-Print Network (OSTI)

.V. All rights reserved. Keywords: Titanium dioxide; Doping; Nitrogen; Surface science 1. IntroductionSurface studies of nitrogen implanted TiO2 Matthias Batzill a,*, Erie H. Morales b , Ulrike Diebold Available online 3 August 2007 Abstract Rutile TiO2(110) single crystals have been doped by nitrogen

Diebold, Ulrike

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

E-Print Network 3.0 - as-cast zr ti Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

page cl-733 Summary: par ajout de ZrOz(Y20,) e t de matdriaux monoxydes t e l s que Sic, Tic, TiN e t B4C. Un renforcement... 304 344 247 344 Composite A120,-ZrO,OY-TiN...

442

Preparation of BaTiO3 nanoparticles by combustion spray pyrolysis Sangjin Leea  

E-Print Network (OSTI)

], hydrothermal [6], and spray pyrolysis [7­9] have been developed to prepare stoichiometric, ultra- fine BaTiO3 process. Hydrothermal BaTiO3 powders [6] are usually a paraelectric cubic phase, which needs additional freedom from hydrocarbon-based chem- icals, and thus avoiding carbon-contamination problems. As a result

Messing, Gary L.

443

Surface Structure of TiO2011-2 1 T. J. Beck,1  

E-Print Network (OSTI)

.43.Bc, 68.47.Gh Titanium dioxide is a promising photocatalyst for the remediation of pollutants of metal oxides [9,10]. In bulk TiO2 the titanium atoms are surrounded by octahedra of six oxygen atoms of the model in Fig. 1.) Such undercoordinated Ti(5) atoms are preferred adsorption sites for a variety

Diebold, Ulrike

444

Li4Ti5O12 heattreated under nitrogen ambient with outstanding rate capabilities  

Science Journals Connector (OSTI)

The powders of spinel Li4Ti5O12 were prepared by heat treating the mixture of rutile TiO2 and Li acetate at 800°C for 3 h under a nitrogen atmosphere and, for comparison, under air as well. The powders ...

Rui Xu; Junrong Li; Zilong Tang; Zhongtai Zhang

2011-01-01T23:59:59.000Z

445

Candidato Situao/Financ. Regime Thiago Marques Toledo Aceito com bolsa de fomento TI  

E-Print Network (OSTI)

/Rec. Prop. TI Diogo Guimarães Rocha Aceito/Rec. Prop. TP Taissa Abdala Filgueiras de Sousa Aceito TI Michele Marcelo de Medeiros Soares Aceito/Rec. Prop. TP Sergio Luiz Rodrigues da Cunha Aceito/Rec. Prop. TP Antônio Francisco da Silva Junior Aceito/Rec. Prop. TP Carlos Lima Dias Aceito/Rec. Prop. TP Fabio da

Rodriguez, Noemi

446

Modulation of over 10{sup 14}?cm{sup ?2} electrons in SrTiO{sub 3}/GdTiO{sub 3} heterostructures  

SciTech Connect

We demonstrate charge modulation of over 10{sup 14}?cm{sup ?2} electrons in a two-dimensional electron gas formed in SrTiO{sub 3}/GdTiO{sub 3} inverted heterostructure field-effect transistors. Increased charge modulation was achieved by reducing the effect of interfacial region capacitances through thick SrTiO{sub 3} cap layers. Transport and device characteristics of the heterostructure field-effect transistors were found to match a long channel field effect transistor model. SrTiO{sub 3} impurity doped metal–semiconductor field effect transistors were also demonstrated with excellent pinch-off and current density exceeding prior reports. The work reported here provides a path towards oxide-based electronics with extreme charge modulation exceeding 10{sup 14}?cm{sup ?2}.

Boucherit, M.; Shoron, O.; Polchinski, C. [Department of Electrical and Computer Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Jackson, C. A.; Cain, T. A.; Buffon, M. L. C.; Stemmer, S. [Materials Department, University of California, Santa Barbara, California 93106-5050 (United States); Rajan, S. [Department of Electrical and Computer Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Department of Materials Science and Engineering, The Ohio State University, Columbus, Ohio 43210 (United States)

2014-05-05T23:59:59.000Z

447

CdS quantum dot sensitized nanocrystalline Gd-doped TiO2 thin films for photoelectrochemical solar cells  

Science Journals Connector (OSTI)

CdS quantum dot sensitized Gd-doped TiO2 nanocrystalline thin films have been prepared by chemical method. X-ray diffraction analysis reveals that TiO2 and Gd-doped TiO2...nanocrystalline thin films are of anatas...

A. Ranjitha; N. Muthukumarasamy…

2013-08-01T23:59:59.000Z

448

Characterization for strontium titinateFe3O4 and TiNFe3O4 interfaces A. Lussiera)  

E-Print Network (OSTI)

Characterization for strontium titinateÃ?Fe3O4 and TiNÃ?Fe3O4 interfaces A. Lussiera) and Y. U The interface formation between different thicknesses of strontium titanate (SrTiO3) or titanium nitride Ti

Idzerda, Yves

449

Modelling the coarsening behaviour of TiC precipitates in high-strength, low-alloy steels  

E-Print Network (OSTI)

Modelling the coarsening behaviour of TiC precipitates in high-strength, low-alloy steels Jae Hoon­sheet steels rely on a dispersion of fine precipitates based on TiC, generated during the major phase changes of the stoichiometry of titanium and carbon. The purpose was to assess the influences of interface energy and Ti/C

Cambridge, University of

450

Hydrothermal Synthesis of Dy-Doped BaTiO3 Powders ERSIN E. OREN and A. CUNEYT TAS  

E-Print Network (OSTI)

. Hydrothermal processing sis method used and temperature, may exhibit four different of BaTiO3 powders has) are "ferroelectric." hydrothermal processing required a pH 12 in the aqueous BaTiO3 is of the tetragonal symmetryHydrothermal Synthesis of Dy-Doped BaTiO3 Powders ERSIN E. OREN and A. CUNEYT TAS Submicron

Tas, A. Cuneyt

451

Comparative study on the corrosion behavior of TiNb and TMA alloys for dental application in various artificial solutions  

E-Print Network (OSTI)

Comparative study on the corrosion behavior of Ti­Nb and TMA alloys for dental application 2011 Keywords: Ti­Nb alloy TMA Corrosion Fluoride Artificial saliva The corrosion behavior of Ti the corrosion resistance of experimental alloys, with the corroded surface being further characterized

Zheng, Yufeng

452

Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles”  

Science Journals Connector (OSTI)

Comment on “Electron Source in Photoinduced Hydrogen Production on Pt-Supported TiO2 Particles” ... We can suggest at least three more likely (than Ti4+) sources for their mysterious electron donor:? (1) an overlooked inorganic species, (2) Ti3+, and/or (3) organic impurities. ...

Craig L. Perkins; Michael A. Henderson; David E. McCready; Greg S. Herman

2000-12-05T23:59:59.000Z

453

On the remarkable optical and structural transformations in Mg-Ti-H thin  

NLE Websites -- All DOE Office Websites (Extended Search)

On the remarkable optical and structural transformations in Mg-Ti-H thin On the remarkable optical and structural transformations in Mg-Ti-H thin films Speaker(s): Dana Borsa Date: October 16, 2006 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Venkat Srinivasan In searching for battery electrode materials, Mg-Ti-H thin films triggered much interest with its hydrogen storage capacity of approx. 4 times larger than that of conventional NiMH batteries [1]. Besides this, the same system has also absolutely remarkable optical properties [2]. Highly reflective in the metallic state, the films become highly absorbing upon hydrogen absorption. Mg0.80Ti0.20Hx thin films combine a high absorption (87% of the solar spectrum) with a low thermal emissivity (only 10%), while after removal of hydrogen Mg0.80Ti0.20 absorbs no more than 1/3 of the solar

454

The 40Ca(alpha,gamma)44Ti reaction in the energy regime of supernova nucleosynthesis  

E-Print Network (OSTI)

The 44Ti(t1/2 = 59 y) nuclide, an important signature of supernova nucleosynthesis, has recently been observed as live radioactivity by gamma-ray astronomy from the Cas A remnant. We investigate in the laboratory the major 44Ti production reaction, 40Ca(alpha,gamma)44Ti (E_cm = 0.6-1.2 MeV/u), by direct off- line counting of 44Ti nuclei. The yield, significantly higher than inferred from previous experiments, is analyzed in terms of a statistical model using microscopic nuclear inputs. The associated stellar rate has important astrophysical consequences, increasing the calculated supernova 44Ti yield by a factor ~2 over previous estimates and bringing it closer to Cas A observations.

H. Nassar; M. Paul; I. Ahmad; Y. Ben-Dov; J. Caggiano; S. Ghelberg; S. Goriely; J. P. Greene; M. Hass; A. Heger; A. Heinz; D. J. Henderson; R. V. F. Janssens; C. L. Jiang; Y. Kashiv; B. S. Nara Singh; A. Ofan; R. C. Pardo; T. Pennington; K. E. Rehm; G. Savard; R. Scott; R. Vondrasek

2006-01-11T23:59:59.000Z

455

Ni{sub 3}Al aluminide alloys  

SciTech Connect

This paper provides a brief review of the recent progress in research and development of Ni{sub 3}Al and its alloys. Emphasis has been placed on understanding low ductility and brittle fracture of Ni{sub 3}Al alloys at ambient and elevated temperatures. Recent studies have resulted in identifying both intrinsic and extrinsic factors governing the fracture behavior of Ni{sub 3}Al alloys. Parallel efforts on alloy design using physical metallurgy principles have led to properties for structural use. Industrial interest in these alloys is high, and examples of industrial involvement in processing and utilization of these alloys are briefly mentioned.

Liu, C.T.

1993-10-01T23:59:59.000Z

456

Carbon Hard Coatings of Al-Alloys for UHV Application  

Science Journals Connector (OSTI)

The investigations were focused on properties of Me-C:H coatings (where Me — Ti, Cr, W) produced by Reactive Magnetron Sputtering (RMS) and Cathodic Arc Plasma Deposition (CAPD) methods on aluminium alloys substr...

W. Precht; A. Czyzniewski; P. My?li?ski…

1998-01-01T23:59:59.000Z

457

R ES0 L U TI(it; 1  

NLE Websites -- All DOE Office Websites (Extended Search)

ES0 L U TI(it; 1\ (;. ______ ES0 L U TI(it; 1\ (;. ______ lH T the i\£ '-'yor of tl,e Ctty of AmarHlo i.lli hE'rretr\ IHlthortzeti ~.nd directed to execute on oot~lf of the City ci:~ n,l!lnllo a contract between the Vnited :3rates o.f j\ ITJerica, reoresented by the l:"nited. Statf'8 p, tomie Ener~y CommiluJion. Amari.no .f~rea (,(fice, and dest!5nsted as Contract '1 (2~)-2) 224.9 ar"d the Citj Dr /\r:rarillo. Te:k.1ll8. authorilol.n'l the use of certain oroperty located a.t the .Amarino ,,\ir J'o:rc. Base by the Atorr,ic J~n~r~.v Co.n.lmiesion of the United Staws.. .). .. ~ 1/ . * 13.' .. ·If? . Contract AT(29-2)2249 CONTRACT This CONTRACT, entered into effective as hereinafter provided, by and between THE UNITED STATES OF AMERICA (hereinafter called the "Government

458

Microsoft Word - AL2006-09.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6-09 (07/24/06) 6-09 (07/24/06) 1 Subject: Energy Efficiency of Energy Consuming Products - Implementation of Section 104 of the Energy Policy Act of 2005 References: Energy Policy Act of 2005, Section 104 Executive Order 13123, Greening the Government through Energy Efficient Management, Section 403 DOE Acquisition Guide Chapter 23, Greening the Government - Environmental Considerations in Contracting FAR Subpart 23.2, Energy and Water Efficiency and Renewable Energy When is this Acquisition Letter (AL) Effective? This AL is effective immediately upon issuance. When does this AL Expire? The AL remains in effect until superseded by anticipated FAR coverage or it is canceled. Who are the Points of Contact? Richard Langston, Office of Procurement and Assistance Policy, MA-61, (202) 287-1339 or

459

Microsoft Word - AL2000-05.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Παγε 1 οφ 2 Παγε 1 οφ 2 Subject: DOE Authorized Subcontract for Use by DOE Management and Operating (M&O) Contractors with New Independent States' Scientific Institutes through the Science and Technology Center in Ukraine References: DEAR 970.7103 - Contractor Purchasing System When is this Acquisition Letter (AL) Effective? This AL is effective 10 business days from the date of issuance. When Does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Robert Webb of the Office of Procurement and Assistance Policy at (202) 586-8264, or via e-mail at Robert.Webb@hq.doe.gov Visit our website at www.pr.doe.gov for information on Acquisition Letters and other policy

460

Microsoft Word - AL2005-16.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6 6 Acquisition Regulation Date 10/04/05 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Implementation of HSPD-12 References: Homeland Security Presidential Directive 12 (HSPD-12) Federal Information Processing Standard Publication 201 (FIPS Pub 201) DOE Notice 206.2 Identity Proofing Acquisition Letter 2005-10 dated July 7, 2005 When is this Acquisition Letter (AL) Effective? This AL is effective upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Robert M. Webb of the Office of Procurement and Assistance Policy at (202) 287-1338 or

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Microsoft Word - AL2005-15.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

5 5 Acquisition Regulation Date 10/05/05 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Implementation of the Price-Anderson Amendments Act of 2005 References: DEAR 970.250-70, Nuclear Hazards Indemnification Agreement. The Price-Anderson Amendments Act of 2005, §§ 601-611 of the Energy Policy Act, 2005, Pub.L. 109-58. When is this Acquisition Letter (AL) Effective? This AL is effective upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Robert M. Webb of the Office of Procurement and Assistance Policy at

462

Microsoft Word - AL2005-13.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Department of Energy No. 2005-13 Department of Energy No. 2005-13 Acquisition Regulation Date 09/30/05 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE Procurement Executive. Subject: Performance-Based Service Acquisition References: FAR 37.6 Performance-Based Contracting DEAR 970.1100-1 Performance-Based Contracting DOE Acquisition Guide Chapter 37.2 Performance-Based Service Acquisition DOE Acquisition Guide Chapter 70.8 Performance-Based Contracting When is this Acquisition Letter (AL) Effective? This AL is effective 10 business days from the date of issuance. When Does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact?

463

ALS Reveals New State of Matter  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Reveals New State of Matter Print ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum properties that manifest themselves macroscopically. The discovery of a "second generation" of topological insulators that robustly retain these properties well above room temperature has spurred a rising tide of theoretical proposals for potential applications in nanoscale spintronic devices and fault-tolerant quantum computers. In addition, it's also been suggested that topological insulators may serve as a test bed for studies of never-before-seen particles predicted by high-energy physics.

464

ALS Reveals New State of Matter  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Reveals New State of Matter Print ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum properties that manifest themselves macroscopically. The discovery of a "second generation" of topological insulators that robustly retain these properties well above room temperature has spurred a rising tide of theoretical proposals for potential applications in nanoscale spintronic devices and fault-tolerant quantum computers. In addition, it's also been suggested that topological insulators may serve as a test bed for studies of never-before-seen particles predicted by high-energy physics.

465

Microsoft Word - al2005-06.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2005-06 2005-06 Acquisition Regulation Date 03/11/05 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Small Business Procurement Goals References: FAR Subpart 19.7 The Small Business Subcontracting Program 13 CFR Chapter 1 Small Business Administration OFPP Letter 99-1 Small Business Procurement Goals Small Business Administration (SBA) Goaling guidelines for the Small Business Preference Programs for Prime When is this Acquisition Letter (AL) Effective? This AL is effective immediately upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Stephen Zvolensky of the Department of Energy (DOE) Office of Procurement and

466

Microsoft Word - AL2000-01.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Letters (AL) that remain in effect are identified below. All other previously issued ALs have been Letters (AL) that remain in effect are identified below. All other previously issued ALs have been superseded by a formal rulemaking, incorporated into other guidance, and/or canceled. * * * * * * * * * * * * * * * Acquisition Letters Remaining In Effect Number Date Subject 93-4 04/07/93 Displaced Workers Benefits Program 94-19 12/09/94 Basic Labor Policies Fringe Benefits 95-06 06/28/95 Personal Property Letter System 95-14 11/17/95 Subcontracts under the New Independent States - Industrial Partnering Program 96-05 05/10/96 Trade Agreements 96-09 09/16/96 Full and Open Competition - Management and Operating Contracts 97-02 01/20/97 M&O Legal Services Subcontracts

467

ALS Reveals New State of Matter  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Reveals New State of Matter Print ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum properties that manifest themselves macroscopically. The discovery of a "second generation" of topological insulators that robustly retain these properties well above room temperature has spurred a rising tide of theoretical proposals for potential applications in nanoscale spintronic devices and fault-tolerant quantum computers. In addition, it's also been suggested that topological insulators may serve as a test bed for studies of never-before-seen particles predicted by high-energy physics.

468

Microsoft Word - al2005-04.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 1 Subject: CLASS DEVIATION TO REFLECT CHANGES TO THE COOPERATIVE AUDIT STRATEGY References: DEAR 970.5203-1 Management Controls DEAR 970.5232-3 Accounts, Records, and Inspection DOE Acquisition Guide Chapter 70.4 Cooperative Audit Strategy When is this Acquisition Letter (AL) Effective? This AL is effective upon issuance. The use of the clauses authorized by the attached class deviation shall be used in all solicitations and contracts in place of the parallel clauses currently contained in the DEAR. When Does This AL Expire? This AL remains in effect until superseded by the publication of a final rule incorporating the clauses that are the subject of the class deviation into the DEAR. Who is the Point of Contact?

469

ALS User Meeting Highlights Challenges, Accomplishments  

NLE Websites -- All DOE Office Websites (Extended Search)

Saphire, brought some audience members to tears with her discussion of the current Ebola virus outbreak and the race for a cure. Saphire is an ALS user whose x-ray...

470

Al Husseini Amelio JV | Open Energy Information  

Open Energy Info (EERE)

Husseini Amelio JV Jump to: navigation, search Name: Al-Husseini & Amelio JV Place: Jordan Sector: Solar Product: JV company to develop a 1GW solar plant in Jordan and an...

471

ALS Ceramics Materials Research Advances Engine Performance  

NLE Websites -- All DOE Office Websites (Extended Search)

image of a ceramic composite specimen imaged under load at 1750C shows the detailed fracture patterns that researchers are able to view using ALS Beamline 8.3.2. The vertical...

472

Western Baldwin County, AL Grid Interconnection Project  

SciTech Connect

The Objective of this Project was to provide an additional supply of electricity to the affected portions of Baldwin County, AL through the purchase, installation, and operation of certain substation equipment.

Thomas DeBell

2011-09-30T23:59:59.000Z

473

Der Palast von Iraq al-Amir.  

E-Print Network (OSTI)

??In der vorliegenden Arbeit wurde der Qasr el-Abd von Iraq al-Amir nach typologischen und stilistischen Kriterien untersucht und eine Verbindung mit dem antiken Bericht des… (more)

Bürge, Teresa

2011-01-01T23:59:59.000Z

474

Microsoft Word - AL2005-10.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0 0 Acquisition Regulation Date 07/07/05 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Implementation of HSPD-12 References: Homeland Security Presidential Directive 12 (HSPD-12) Federal Information Processing Standard Publication 201 (FIPS Pub 201) When is this Acquisition Letter (AL) Effective? This AL is effective upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Robert M. Webb of the Office of Procurement and Assistance Policy at (202)287-1338 or Robert.Webb@hq.doe.gov. Visit our website at www.pr.doe.gov for information on Acquisition Letters and other policy issues.

475

Microsoft Word - AL2005-11.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 1 Acquisition Regulation Date 07/15/05 _ ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Home Office Expenses for Management and Operating Contracts References: DEAR 970.3102-3-70 Home office expenses FAR 15.404-1 Proposal analysis techniques FAR 31.109 Advance agreements FAR Appendix B Subpart 9904.403 Allocation of home office expenses to segments When is this Acquisition Letter (AL) Effective? This AL is effective immediately upon issuance. When does this AL Expire? This AL remains in effect until superseded or canceled. Who is the Point of Contact? Contact Michael Righi of the Department of Energy (DOE) Office of Procurement and Assistance Policy at

476

Transport properties of LiAl  

Science Journals Connector (OSTI)

In "real" LiAl (NaTl structure: Fd3m), the majority carriers govern the transport properties are holes at 77 and 300 K. The decrease in Hall coefficients and the increase in electrical resistivity with the increase of Li composition are understood in terms of the "defect" structure of LiAl. The relationship between the transport properties and band structure is discussed using the semimetallic band structure proposed by Zunger.

K. Kuriyama; T. Kamijoh; T. Nozaki

1980-05-15T23:59:59.000Z

477

Magnetism of Al-Mn quasicrystals  

Science Journals Connector (OSTI)

The effect of symmetry and concentration of Mn on the magnetism of Al-Mn quasicrystals has been investigated through self-consistent density-functional calculations using molecular clusters and supercell band-structure schemes. A single Mn atom surrounded by 54 Al atoms in an icosahedral or a cuboctahedral structure is found to be nonmagnetic. However, as the Mn concentration is increased, moments develop on Mn sites whose magnitude and coupling depend on their location.

Feng Liu; S. N. Khanna; L. Magaud; P. Jena; V. de Coulon; F. Reuse; S. S. Jaswal; X.-G. He; F. Cyrot-Lackman

1993-07-01T23:59:59.000Z

478

17th Annual ALS Users' Association Meeting  

SciTech Connect

It's not exactly Russian roulette, but scheduling October events outdoors is not risk-free, even in usually sunny California. An overflow crowd of more than 400 registered users, ALS staff, and vendors enjoyed a full indoor program featuring science highlights and workshops spread over two and a half days from October 18 to October 20. However, a major storm, heralding the onset of the San Francisco Bay Area rainy season, posed a few weather challenges for the events on the ALS patio.

Robinson, Art; Tamura, Lori

2004-11-29T23:59:59.000Z

479

Adhesion, Atomic Structure, and Bonding at theAdhesion, Atomic Structure, and Bonding at the ----AlAl22OO33(0001)/Al(111) Interface:(0001)/Al(111) Interface  

E-Print Network (OSTI)

Adhesion, Atomic Structure, and Bonding at theAdhesion, Atomic Structure, and Bonding at the ----AlAl22OO33(0001)/Al(111) Interface:(0001)/Al(111) Interface: A First Principles StudyA First Principles--ceramic interfaces are ubiquitous in many industrial applications: ­ Microelectronics ­ Al and other metals

Adams, James B

480

LBNL-4183E-rev1 N NA AT TU UR RA AL L G GA AS S V VA AR RI  

NLE Websites -- All DOE Office Websites (Extended Search)

4183E-rev1 4183E-rev1 N NA AT TU UR RA AL L G GA AS S V VA AR RI IA AB BI IL LI IT TY Y I IN N C CA AL LI IF FO OR RN NI IA A: : E EN NV VI IR RO ON NM ME EN NT TA AL L I IM MP PA AC CT TS S A AN ND D D DE EV VI IC CE E P PE ER RF FO OR RM MA AN NC CE E E EX XP PE ER RI IM ME EN NT TA AL L E EV VA AL LU UA AT TI IO ON N O OF F I IN NS ST TA AL LL LE ED D C CO OO OK KI IN NG G E EX XH HA AU US ST T F FA AN N P PE ER RF FO OR RM MA AN NC CE E Brett C. Singer, William W. Delp and Michael G. Apte Indoor Environment Department Atmospheric Sciences Department Environmental Energy Technologies Division July 2011 (Revised February 2012) Disclaimer 1 This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor The Regents of the University of California, nor any of

Note: This page contains sample records for the topic "ti al tes" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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481

High-Resolution Soft X-Ray Spectral Analysis in the CK Region of Titanium Carbide (TiC) using the DV-X alpha Molecular Orbital Method  

E-Print Network (OSTI)

1 XRD pattern of the measured TiC powder sample. Figure 2XAS. Intensity (arb. units) TiC X-ray: Cu K? voltage: 40 kVintensity (arb. units) CK-XES TiC b a c HOPG e f CK-XAS TiC

Shimomura, Kenta

2010-01-01T23:59:59.000Z

482

Influence of the Operating Parameters on the Selective Catalytic Reduction of NO with Hydrocarbons Using Cu-Ion-Exchanged Titanium-Pillared Interlayer Clays (Ti-PILCs)  

Science Journals Connector (OSTI)

General Ti-PILC Characterization. Figure 1 shows the XRD patterns of the parent Ti-PILC calcined at different temperatures and of the original clay. ... Figure 1 X-ray diffraction (XRD) patterns for the Ti-PILC catalyst calcined at different temperatures. ... Figure 2 N2 adsorption?desorption isotherms for the Ti-PILC catalyst and the original clay. ...

José L. Valverde; Antonio de Lucas; Fernando Dorado; Amaya Romero; Prado B. García

2005-03-18T23:59:59.000Z

483

On the Al-Si, Al-Ge, and Al-Ge-Si systems and their application to brazing in high power semiconductor devices  

Science Journals Connector (OSTI)

Results of the Smith thermal analysis studies13 of the Al-Si, Al-Ge, and Al-Ge-Si systems are presented and compared with ... . Isothermal and vertical sections for the Al-Ge-Si system, computed from thermodynami...

F. H. Hayes; R. D. Longbottom; E. Ahmad; G. Chen

1993-08-01T23:59:59.000Z

484

TiB2/Ni coatings on surface of copper alloy electrode prepared by electrospark deposition  

Science Journals Connector (OSTI)

In order to improve the lifespan of spot-welding electrodes used for welding zinc coated steel sheets, titanium diboride was deposited onto their surface after precoating nickel as an intermediate layer. The microstructures and phase compositions of TiB2 and Ni coatings were characterized by SEM and XRD. The coating hardness was measured using a microhardness tester. The results indicate that a satisfactory TiB2 coating is obtained as a result of the intermediate nickel layer acting as a good binder between the TiB2 coating and the copper alloy substrate. Owing to its capacity of deforming, the precoated nickel layer is dense and crack free, while cracks and pores are observed in the TiB2 coating. The hardness of the TiB2/Ni coating decreases with the increase of voltage and capacitance because of the diffusion of copper and nickel and the oxidation of the coating materials. Because of the good thermal and electrical conductivities and high hardness properties of TiB2, the deformation of the electrode with TiB2/Ni coating is reduced and its spot-welding life is by far prolonged than that of the uncoated one.

Cheng LUO; Xiang XIONG; Shi-jie DONG

2011-01-01T23:59:59.000Z

485

Transition metal atoms pathways on rutile TiO{sub 2} (110) surface: Distribution of Ti{sup 3+} states and evidence of enhanced peripheral charge accumulation  

SciTech Connect

Charge transfer between metal nanoparticles and the supported TiO{sub 2} surface is primarily important for catalytic applications as it greatly affects the catalytic activity and the thermal stability of the deposited nanoparticles on the surface. Herein, systematic spin-polarized density functional and HSE06 calculations are performed to evaluate the adsorption, diffusion, and charge state of several transition metal monomers on both stoichiometric and reduced rutile TiO{sub 2} (110) surface. Although the presence of oxygen vacancy (O{sub v}) increases the binding of Au, Pt and Pd on the surface, it weakens the interaction thus enhancing the diffusion for Fe, Co, Ni, Ag, and Cu adatoms on the surface. For pristine reduced surface, only a small portion (around 5%) of the excess electrons occupy the topmost surface, which are mainly delocalized at the second nearest and third nearest fivefold coordinated Ti (Ti{sub 5c}) atoms. Excess electrons populating at the Ti{sub 5c} atoms on the basal plane can be transferred to strongly electronegative adsorbates like Au and Pt thus enabling a moderate adsorption at this site, whereas no stable adsorption is found for other less electronegative transition metal adatoms (Ag, Cu, Fe, Co, Ni, and Pd) on the reduced surface and for all the adatoms on stoichiometric surface. This result clarifies the origin of the experimental observation of the adsorption of O{sub 2} and CO molecules at Ti{sub 5c} sites in connection with charge transfer. In addition, the spatial redistribution of the excess electrons around the O{sub v} upon the adsorption of the monomers is thoroughly examined. Our finding of an accumulation of excess electrons at the Ti{sub 5c} sites around the monomers explains the critical role of the perimeter interface of the deposited nanoparticles in promoting the adsorption and activation of reactants observed in experiments.

Cai Yongqing; Bai Zhaoqiang; Chintalapati, Sandhya; Feng Yuanping [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Zeng Qingfeng [School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072 (China)

2013-04-21T23:59:59.000Z

486

Effect of crystal phases of titanium dioxide on adsorption performance of H2TiO3-lithium adsorbent  

Science Journals Connector (OSTI)

Abstract Different crystal phases of TiO2 were produced by calcinations of metatitanic acid at various temperatures. H2TiO3-lithium adsorbent was obtained from the acid-modified adsorbent precursor Li2TiO3 which was synthesized by a solid-phase reaction between TiO2 and LiOH·H2O. Effects of crystal phases of TiO2 on the pull-out rate of Li+ from Li2TiO3 and adsorption properties of lithium adsorbent were studied. The results indicate that anatase structure rather than rutile reacted with LiOH·H2O aids the extraction of Li+ and the adsorption performance of lithium adsorbent. The maximum Li+ drawn out ratio from Li2TiO3 reaches 98.69%, and the maximum saturated adsorptive capacity comes up to 39.2 mg g?1.

Liyuan Zhang; Dali Zhou; Gang He; Fanhou Wang; Jiabei Zhou

2014-01-01T23:59:59.000Z

487

WANG ET AL. VOL. 7 ' NO. 10 ' 93759383 ' 2013 www.acsnano.org  

E-Print Network (OSTI)

(0.3 cm2 VÃ?1 sÃ?1 for rutile TiO2).12 In addition, compared to TiO2 nanoparticles (NPs)13 during the synthesis step of the TiO2 nanostructures, such as hydrothermal growth,4 solÃ?gel,13 the postgrowth doping of metal ions, such as the codoping of TiO2 NWs with tungsten and carbon by a flame

Gong, Xingao

488

Novel Au-TiC Catalysts for CO Oxidation and Desulfurization Processes  

SciTech Connect

Recent articles dealing with the physical and chemical properties of novel Au-TiC catalysts are reviewed. High-resolution photoemission, scanning tunneling microscopy and first-principles periodic density-functional calculations were used to study the deposition of gold on a TiC(0 0 1) surface. Gold grows forming two-dimensional (very low coverage) and three-dimensional (medium and large coverage) islands on the carbide substrate. A positive shift in the binding energy of the C 1s core level is observed after the deposition of Au on TiC(0 0 1). The results of the density-functional calculations corroborate the formation of Au-C bonds. In general, the bond between Au and the TiC(0 0 1) surface exhibits very little ionic character, but there is a substantial polarization of electrons around Au that facilitates bonding of the adatoms with electron-acceptor molecules (CO, O{sub 2}, C{sub 2}H{sub 4}, SO{sub 2}, thiophene, etc.). Experimental measurements indicate that Au/TiC(0 0 1) is a very good catalysts for the oxidation of CO, the destruction of SO{sub 2} and the hydrodesulfurization of thiophene. At temperatures below 200 K, Au/TiC(0 0 1) is able to perform the 2CO + O{sub 2} {yields} 2CO{sub 2} reaction and the full decomposition of SO{sub 2}. Furthermore, in spite of the very poor hydrodesulfurization performance of TiC(0 0 1) or Au(1 1 1), a Au/TiC(0 0 1) surface displays a hydrodesulfurization activity higher than that of conventional Ni/MoS{sub x} catalysts. Metal carbides are excellent supports for enhancing the chemical reactivity of gold. The Au/TiC system is more chemically active than systems generated by depositing Au nanoparticles on oxide surfaces.

J Rodriguez; P Liu; Y Takahashi; F Vines; L Feria; E Florez; K Nakamura

2011-12-31T23:59:59.000Z

489

Nuclear Magnetic Resonance in FeAl and CoAl  

Science Journals Connector (OSTI)

We have investigated the Al27 nuclear magnetic resonance in Ni3Al, NiAl, FeAl, and both the Al27 and Co59 resonances in CoAl. The cobalt resonance in CoAl exhibits a weakly temperature-dependent, positive shift. This shift (?1.5%) is too large to be accounted for solely by the hyperfine field from conduction electrons polarized by the external magnetic field, and orbital paramagnetic effects appear to be the dominant factor, core polarization playing a relatively minor role. The aluminum Knight shift in CoAl is small (0.014%) and temperature-independent. This is to be contrasted with aluminum in FeAl which exhibits a large, negative, temperature-dependent shift (-0.38% at 293°K). It is shown that both the large aluminum Knight shift in FeAl and the small aluminum Knight shift in CoAl are consistent with the predictions of the Ruderman-Kittel-Yosida (RKY) theory. However, it is now believed that the small shift observed in CoAl results from a lack of s character in the conduction-electron wave functions rather than from a node anticipated in the conduction-electron polarization. The temperature dependence of the resonance in FeAl can also be accounted for by the RKY mechanism if it is assumed that the temperature dependence of the magnetic susceptibility is associated with disorder in the material. This assumption is necessary because the Knight shift is not linearly related to the bulk susceptibility of the sample. The aluminum linewidth in FeAl increases as the temperature is lowered. At room temperature the linewidth is independent of magnetic field but greater than the calculated dipolar linewidth. At 77 and 4.2°K the linewidth increases with increasing magnetic field. This effect is attributed mainly to inhomogeneous Knight-shift broadening, although inhomogeneous magnetization broadening also contributes. A similar situation is observed in CoAl. At room temperature the cobalt and aluminum resonances have essentially the same width. The linewidths are independent of magnetic field but greater than the dipolar values. As the temperature is lowered the linewidths increase and become magnetic-field-dependent. The cobalt resonance broadens more severely than the aluminum resonance. It is believed that inhomogeneous Knight-shift broadening and inhomogeneous magnetization broadening determine the cobalt linewidth at low temperatures. The aluminum nuclei in CoAl do not exhibit appreciable hyperfine coupling with the conduction electrons, so that only inhomogeneous magnetization broadening contributes to the linewidth.

J. A. Seitchik and R. H. Walmsley

1965-01-04T23:59:59.000Z

490

A new step size rule in Yan et al.'s self-adaptive projection method  

E-Print Network (OSTI)

Jan 29, 2015 ... ... which can be viewed as a combination of Li and Yuan's manipulation idea of step size and descending direction presented by Yan et al. [14].

2015-01-29T23:59:59.000Z

491

DOE - Office of Legacy Management -- Southern Research Institute - AL 03  

NLE Websites -- All DOE Office Websites (Extended Search)

Southern Research Institute - AL 03 Southern Research Institute - AL 03 FUSRAP Considered Sites Site: SOUTHERN RESEARCH INSTITUTE (AL.03) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 917 South 20th Street , Birmingham , Alabama AL.03-1 AL.03-2 Evaluation Year: 1993 AL.03-3 Site Operations: Licensed for the period 11/10/55 - 6/1/58. Basic license and three amendments for possession and title to up to 140# of refined source material for research on properties of Uranium-liquid metal fuel elements; conducted research on Uranium in the early 1960's. AL.03-4 AL.03-1 AL.03-5 Site Disposition: Eliminated - No Authority - AEC license to handle nuclear materials AL.03-3 AL.03-6 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium AL.03-1

492

ALS Data Visualization Lab Serves Up Computing Power  

NLE Websites -- All DOE Office Websites (Extended Search)

ALS Data Visualization Lab Serves Up Computing Power ALS Data Visualization Lab Serves Up Computing Power Print Even though the ALS has been in shutdown mode for almost two months,...

493

Microsoft Word - AL2000-01.doc | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

0-01.doc Microsoft Word - AL2000-01.doc Microsoft Word - AL2000-01.doc More Documents & Publications ALFAL 99-01 Department of Energy No Microsoft Word - al2005...

494

Microsoft Word - AL2005-14.doc | Department of Energy  

Office of Environmental Management (EM)

4.doc Microsoft Word - AL2005-14.doc Microsoft Word - AL2005-14.doc More Documents & Publications Microsoft Word - AL-Omnibus FY 2009 Apr 22 2009 all sections.doc Microsoft Word -...

495

Microsoft Word - Final MR AL.doc | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Final MR AL.doc Microsoft Word - Final MR AL.doc Microsoft Word - Final MR AL.doc More Documents & Publications DOE F 4220.23 Weighted Guidelines Weighted Guidelines...

496

Microsoft Word - Section 311 AL FAL Feb 17 2010 | Department...  

Office of Environmental Management (EM)

Section 311 AL FAL Feb 17 2010 Microsoft Word - Section 311 AL FAL Feb 17 2010 Microsoft Word - Section 311 AL FAL Feb 17 2010 More Documents & Publications Microsoft Word -...

497

Microsoft Word - AL2008-05.doc | Department of Energy  

Office of Environmental Management (EM)

5.doc Microsoft Word - AL2008-05.doc Microsoft Word - AL2008-05.doc More Documents & Publications EXECUTIVE ORDER 13514 Microsoft Word - AL 2010-07 Acquistion Letters Remaining in...

498

Microsoft Word - AL-ARRASafetyALREDO3 | Department of Energy  

Office of Environmental Management (EM)

ARRASafetyALREDO3 Microsoft Word - AL-ARRASafetyALREDO3 Microsoft Word - AL-ARRASafetyALREDO3 More Documents & Publications Microsoft Word - AL-ARRASafetyALREDO3.doc DOE Handbook:...

499

Microsoft Word - AL2007-01.doc | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AL2007-01.doc Microsoft Word - AL2007-01.doc Microsoft Word - AL2007-01.doc More Documents & Publications Microsoft Word - Rev5functionalaccountabilityimplementationplan..doc...

500

AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT Acquisition Letters (AL) that remain in effect are identified below. All other...