National Library of Energy BETA

Sample records for throughput hydrothermal pretreatment

  1. The fate of lignin during hydrothermal pretreatment

    E-Print Network [OSTI]

    Trajano, Heather L; Engle, Nancy L; Foston, Marcus; Ragauskas, Arthur J; Tschaplinski, Timothy J; Wyman, Charles E

    2013-01-01

    straw pretreated for bioethanol production. Biotechnologyof woody biomass for bioethanol production. Bioresources

  2. The fate of lignin during hydrothermal pretreatment

    E-Print Network [OSTI]

    Trajano, Heather L; Engle, Nancy L; Foston, Marcus; Ragauskas, Arthur J; Tschaplinski, Timothy J; Wyman, Charles E

    2013-01-01

    pretreated for bioethanol production. Biotechnology forwoody biomass for bioethanol production. Bioresources 2011,

  3. High Throughput Pretreatment and Enzyme Hydrolysis of Biomass: Screening Recalcitrance in Large Sample Populations (Presentation)

    SciTech Connect (OSTI)

    Decker, S. R.

    2010-10-01

    Presentation on the execution of the first high-throughput thermochemical pretreatment/enzyme digestion pipeline for screening biomass for recalcitrance.

  4. Investigation of Lignin Deposition on Cellulose During Hydrothermal Pretreatment, Its Effect on

    E-Print Network [OSTI]

    California at Riverside, University of

    Investigation of Lignin Deposition on Cellulose During Hydrothermal Pretreatment, Its Effect on Cellulose Hydrolysis, and Underlying Mechanisms Hongjia Li,1,2,4 Yunqiao Pu,3,4 Rajeev Kumar,1,2,4 Arthur J to form droplets that deposit on the cellulose surface and retard enzymatic digestion of cellulose

  5. Rheological study of comingled biomass and coal slurries with hydrothermal pretreatment

    SciTech Connect (OSTI)

    Wei He; Chan S. Park; Joseph M. Norbeck [University of California, Riverside, CA (United States). Bourns College of Engineering Center for Environmental Research and Technology

    2009-09-15

    Gasification of comingled biomass and coal feedstock is an effective means of reducing the net life cycle greenhouse gas emissions in the coal gasification process while maintaining its inherent benefits of abundance and high-energy density. However, feeding a comingled biomass and coal feedstock into a pressurized gasification reactor poses a technical problem. Conventional dry feeding systems, such as lock hoppers and pressurized pneumatic transport, are complex and operationally expensive. A slurry formation of comingled biomass and coal feedstock can be easily fed into the gasification reactor but, in normal conditions, only allows for a small portion of biomass in the mixture. This is a consequence of the hydroscopic and hydrophilic nature of the biomass. The College of Engineering Center for Environmental Research and Technology (CE-CERT) at the University of California, Riverside, has developed a process producing high solid content biomass-water slurry using a hydrothermal pretreatment process. In this paper, the systematic investigation of the rheological properties (e.g., shear rate, shear stress, and viscosity) of coal-water slurries, biomass-water slurries, and comingled biomass and coal-water slurries is reported. The solid particle size distribution in the slurry and the initial solid/water ratio were investigated to determine the impact on shear rate and viscosity. This was determined using a rotational rheometer. The experimental results show that larger particle size offers better pumpability. The presence of a high percentage of biomass in solid form significantly decreases slurry pumpability. It is also shown that the solid loading of the biomass-water slurry can be increased to approximately 35 wt % with viscosity of less than 0.7 Pa.s after the pretreatment process. The solid loading increased to approximately 45 wt % when the biomass is comingled with coal. 18 refs., 7 figs., 3 tabs.

  6. Co-hydrolysis of hydrothermal and dilute acid pretreated Populus slurries to support development of a high-throughput pretreatment system

    E-Print Network [OSTI]

    Studer, Michael H; Brethauer, Simone; DeMartini, Jaclyn D; McKenzie, Heather L; Wyman, Charles E

    2011-01-01

    process samples. National Renewable Energy Laboratory, NREL/at the National Renewable Energy Laboratory for approxi-the standard National Renewable Energy Laboratory method [

  7. Comparison of microwaves to fluidized sand baths for heating tubular reactors for hydrothermal and dilute acid batch pretreatment of corn stover

    E-Print Network [OSTI]

    California at Riverside, University of

    heated pretreatment led to faster xylan, lignin, and acetyl removal as well as ear- lier xylan technology was developed in 1940's driven by military needs and was later intro- duced into civilian markets

  8. Hydrothermal Processing

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2011-03-11

    This chapter is a contribution to a book on Thermochemical Conversion of Biomass being edited by Prof. Robert Brown of Iowa State University. It describes both hydrothermal liquefaction and hydrothermal gasification of biomass to fuels.

  9. Biomass pretreatment

    DOE Patents [OSTI]

    Hennessey, Susan Marie; Friend, Julie; Elander, Richard T; Tucker, III, Melvin P

    2013-05-21

    A method is provided for producing an improved pretreated biomass product for use in saccharification followed by fermentation to produce a target chemical that includes removal of saccharification and or fermentation inhibitors from the pretreated biomass product. Specifically, the pretreated biomass product derived from using the present method has fewer inhibitors of saccharification and/or fermentation without a loss in sugar content.

  10. Hydrothermal Resources Fact Sheet

    SciTech Connect (OSTI)

    U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy

    2012-08-31

    This two-page fact sheet provides an overview of hydrothermal resources and hydrothermal reservoir creation and operation.

  11. The fate of lignin during hydrothermal pretreatment

    E-Print Network [OSTI]

    Trajano, Heather L; Engle, Nancy L; Foston, Marcus; Ragauskas, Arthur J; Tschaplinski, Timothy J; Wyman, Charles E

    2013-01-01

    followed by a dioxane water extraction, while Trajano et al.water, limited condensation reactions for both substrates, as evidenced by greater lignin extraction

  12. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    editors. Handbook on bioethanol: production and utilization.Salix for the production of bioethanol. Bioresource Technol.editor. Handbook on bioethanol: production and utilization.

  13. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    such as pectin or arabinoxylan during the in vitro synthesisin the presence of arabinoxylan more closely resembles that

  14. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    an increase in carbon dioxide emissions for ethanol asscenarios, the carbon dioxide emissions are most sensitivethe resulting carbon dioxide emissions for ethanol also

  15. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    such as the Canadian oil sands, extra-heavy Venezuelan oilhydrocarbons such as oil sands, oil shale, methane or coal.blend that is 2% Canadian oil sands, 6.86% Alaskan crude,

  16. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    surfaces and heat transfer in bubbling fluidized beds- II.of heat transfer in bubbling fluidized beds. Chem. Eng. Sci.coefficient in bubbling fluidized bed with fast response

  17. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    parameter. Appl. Biochem. Biotech. 1990; 24/25: 1-14. WymanASPEN-Plus®. Appl. Biochem. Biotech. 2004; 115: 1087-1102. (hydrolysis. Appl. Biochem. Biotech. 2001; 92: 377-386.

  18. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    less recalcitrant biomass feedstocks and improved enzymes.of less recalcitrant biomass feedstocks and improvedpotential of improved biomass feedstocks and enzymes for the

  19. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    editors. Handbook on bioethanol: production and utilization.editor. Handbook on bioethanol: production and utilization.of aspen chips for bioethanol production: optimization of

  20. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    Venezuelan oil or coal to liquids, is growing 3 but theseBrandt and Farrell 2 . Coal to liquid (CTL) fuel productionE-04 ii Middle East Coal to Liquid 2.10 E-04 i 3.62 E-04 ii

  1. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    degradation products with lignin products. However in this study, with the exception of Pt4, more phenols

  2. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    2.3. Effects of low pH on biomass solids……………………………. ………………of effects of low pH on biomass……………………………. ….25 2.4. Low pHof low pH biomass reactions………………………. ……………..46

  3. Pretreatment of microbial sludges

    DOE Patents [OSTI]

    Rivard, C.J.; Nagle, N.J.

    1995-01-10

    Methods are described for pretreating microbial sludges to break cells and disrupt organic matter. One method involves the use of sonication, and another method involves the use of shear forces. The pretreatment of sludge enhances bioconversion of the organic fraction. This allows for efficient dewatering of the sludge and reduces the cost for final disposal of the waste.

  4. Pretreatment of microbial sludges

    DOE Patents [OSTI]

    Rivard, Christopher J. (Lakewood, CO); Nagle, Nicholas J. (Louisville, CO)

    1995-01-01

    Methods are described for pretreating microbial sludges to break cells and disrupt organic matter. One method involves the use of sonication, and another method involves the use of shear forces. The pretreatment of sludge enhances bioconversion of the organic fraction. This allows for efficient dewatering of the sludge and reduces the cost for final disposal of the waste.

  5. GREET Pretreatment Module

    SciTech Connect (OSTI)

    Adom, Felix K.; Dunn, Jennifer B.; Han, Jeongwoo

    2014-09-01

    A wide range of biofuels and biochemicals can be produced from biomass via different pretreatment technologies that yield sugars. This report documents the material and energy flows that occur when fermentable sugars from four lignocellulosic feedstocks (corn stover, miscanthus, switchgrass, and poplar) are produced via dilute acid pretreatment and ammonia fiber expansion. These flows are documented for inclusion in the pretreatment module of the Greenhouses Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. Process simulations of each pretreatment technology were developed in Aspen Plus. Material and energy consumption data from Aspen Plus were then compiled in the GREET pretreatment module. The module estimates the cradle-to-gate fossil energy consumption (FEC) and greenhouse gas (GHG) emissions associated with producing fermentable sugars. This report documents the data and methodology used to develop this module and the cradle-to-gate FEC and GHG emissions that result from producing fermentable sugars.

  6. Hazard Analysis for the Pretreatment Engineering Platform (PEP)

    SciTech Connect (OSTI)

    Sullivan, Robin S.; Geeting, John GH; Lawrence, Wesley E.; Young, Jonathan

    2008-07-10

    The Pretreatment Engineering Platform (PEP) is designed to perform a demonstration on an engineering scale to confirm the Hanford Waste Treatment Plant Pretreatment Facility (PTF) leaching and filtration process equipment design and sludge treatment process. The system will use scaled prototypic equipment to demonstrate sludge water wash, caustic leaching, oxidative leaching, and filtration. Unit operations to be tested include pumping, solids washing, chemical reagent addition and blending, heating, cooling, leaching, filtration, and filter cleaning. In addition, the PEP will evaluate potential design changes to the ultrafiltration process system equipment to potentially enhance leaching and filtration performance as well as overall pretreatment throughput. The skid-mounted system will be installed and operated in the Processing Development Laboratory-West at Pacific Northwest National Laboratory (PNNL) in Richland, Washington.

  7. Whole Algae Hydrothermal Liquefaction Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Whole Algae Hydrothermal...

  8. Hydrothermal Liquefaction of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international collaboration with Canada to investigate kelp (seaweed) as a biomass feedstock. The collaborative project includes process testing of the kelp in HydroThermal Liquefaction in the bench-scale unit at PNNL. HydroThermal Liquefaction at PNNL is performed in the hydrothermal processing bench-scale reactor system. Slurries of biomass are prepared in the laboratory from whole ground biomass materials. Both wet processing and dry processing mills can be used, but the wet milling to final slurry is accomplished in a stirred ball mill filled with angle-cut stainless steel shot. The PNNL HTL system, as shown in the figure, is a continuous-flow system including a 1-litre stirred tank preheater/reactor, which can be connected to a 1-litre tubular reactor. The product is filtered at high-pressure to remove mineral precipitate before it is collected in the two high-pressure collectors, which allow the liquid products to be collected batchwise and recovered alternately from the process flow. The filter can be intermittently back-flushed as needed during the run to maintain operation. By-product gas is vented out the wet test meter for volume measurement and samples are collected for gas chromatography compositional analysis. The bio-oil product is analyzed for elemental content in order to calculate mass and elemental balances around the experiments. Detailed chemical analysis is performed by gas chromatography-mass spectrometry and 13-C nuclear magnetic resonance is used to evaluate functional group types in the bio-oil. Sufficient product is produced to allow subsequent catalytic hydroprocessing to produce liquid hydrocarbon fuels. The product bio-oil from hydrothermal liquefaction is typically a more viscous product compared to fast pyrolysis bio-oil. There are several reasons for this difference. The HTL bio-oil contains a lower level of oxygen because of more extensive secondary reaction of the pyrolysis products. There are less amounts of the many light oxygenates derived from the carbohydrate structures as they have been further reacted to phenolic Aldol condensation products. The bio-oil

  9. Hydrothermal Processing of Wet Wastes

    Broader source: Energy.gov [DOE]

    Breakout Session 3A—Conversion Technologies III: Energy from Our Waste—Will we Be Rich in Fuel or Knee Deep in Trash by 2025? Hydrothermal Processing of Wet Wastes James R. Oyler, President, Genifuel Corporation

  10. Biomass shock pretreatment

    DOE Patents [OSTI]

    Holtzapple, Mark T.; Madison, Maxine Jones; Ramirez, Rocio Sierra; Deimund, Mark A.; Falls, Matthew; Dunkelman, John J.

    2014-07-01

    Methods and apparatus for treating biomass that may include introducing a biomass to a chamber; exposing the biomass in the chamber to a shock event to produce a shocked biomass; and transferring the shocked biomass from the chamber. In some aspects, the method may include pretreating the biomass with a chemical before introducing the biomass to the chamber and/or after transferring shocked biomass from the chamber.

  11. Vertical Pretreatment Reactor System (Poster)

    SciTech Connect (OSTI)

    Not Available

    2012-09-01

    IBRF poster developed for the IBRF showcase. Describes the two-vessel system for primary and secondary pretreatment of biomass solids at different temperatures.

  12. High throughput optical scanner

    DOE Patents [OSTI]

    Basiji, David A. (Seattle, WA); van den Engh, Gerrit J. (Seattle, WA)

    2001-01-01

    A scanning apparatus is provided to obtain automated, rapid and sensitive scanning of substrate fluorescence, optical density or phosphorescence. The scanner uses a constant path length optical train, which enables the combination of a moving beam for high speed scanning with phase-sensitive detection for noise reduction, comprising a light source, a scanning mirror to receive light from the light source and sweep it across a steering mirror, a steering mirror to receive light from the scanning mirror and reflect it to the substrate, whereby it is swept across the substrate along a scan arc, and a photodetector to receive emitted or scattered light from the substrate, wherein the optical path length from the light source to the photodetector is substantially constant throughout the sweep across the substrate. The optical train can further include a waveguide or mirror to collect emitted or scattered light from the substrate and direct it to the photodetector. For phase-sensitive detection the light source is intensity modulated and the detector is connected to phase-sensitive detection electronics. A scanner using a substrate translator is also provided. For two dimensional imaging the substrate is translated in one dimension while the scanning mirror scans the beam in a second dimension. For a high throughput scanner, stacks of substrates are loaded onto a conveyor belt from a tray feeder.

  13. Processes for pretreating lignocellulosic biomass: A review

    SciTech Connect (OSTI)

    McMillan, J.D.

    1992-11-01

    This paper reviews existing and proposed pretreatment processes for biomass. The focus is on the mechanisms by which the various pretreatments act and the influence of biomass structure and composition on the efficacy of particular pretreatment techniques. This analysis is used to identify pretreatment technologies and issues that warrant further research.

  14. Hydrothermal Exploration Best Practices and Geothermal Knowledge...

    Open Energy Info (EERE)

    Knowledge Exchange on Openei Abstract Though exploring for hydrothermal resources is not new, advances in exploration technologies and the pursuit of less visible resources have...

  15. Stratigraphy, Structure, Hydrothermal Alteration and Ore Mineralizatio...

    Open Energy Info (EERE)

    Stratigraphy, Structure, Hydrothermal Alteration and Ore Mineralization Encountered in CSDP (Continental Scientific Drilling Program) Corehole VC-2A, Sulphur Springs Area, Valles...

  16. Structural Settings Of Hydrothermal Outflow- Fracture Permeability...

    Open Energy Info (EERE)

    long-lived hydrothermal flow despite potential clogging of fractures due to mineral precipitation. As fault systems evolve, propagation, interaction, and linkage of fault segments...

  17. Efficient Algebraic Representations for Throughput-Oriented Algorithms

    E-Print Network [OSTI]

    McKinlay, Christopher E.

    2013-01-01

    Algorithm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Algorithm . . . . . . . . . . . . . . . . . . . . . . . . . . . .Throughput-Oriented Algorithm Design Multilinear

  18. Hydrothermal System | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam:on Openei | Open Energy InformationHydrothermal System

  19. Carbonic Acid Pretreatment of Biomass

    SciTech Connect (OSTI)

    G. Peter van Walsum; Kemantha Jayawardhana; Damon Yourchisin; Robert McWilliams; Vanessa Castleberry

    2003-05-31

    This project sought to address six objectives, outlined below. The objectives were met through the completion of ten tasks. 1) Solidify the theoretical understanding of the binary CO2/H2O system at reaction temperatures and pressures. The thermodynamics of pH prediction have been improved to include a more rigorous treatment of non-ideal gas phases. However it was found that experimental attempts to confirm theoretical pH predictions were still off by a factor of about 1.8 pH units. Arrhenius experiments were carried out and the activation energy for carbonic acid appears to be substantially similar to sulfuric acid. Titration experiments have not yet confirmed or quantified the buffering or acid suppression effects of carbonic acid on biomass. 2) Modify the carbonic acid pretreatment severity function to include the effect of endogenous acid formation and carbonate buffering, if necessary. It was found that the existing severity functions serve adequately to account for endogenous acid production and carbonate effects. 3) Quantify the production of soluble carbohydrates at different reaction conditions and severity. Results show that carbonic acid has little effect on increasing soluble carbohydrate concentrations for pretreated aspen wood, compared to pretreatment with water alone. This appears to be connected to the release of endogenous acids by the substrate. A less acidic substrate such as corn stover would derive benefit from the use of carbonic acid. 4) Quantify the production of microbial inhibitors at selected reaction conditions and severity. It was found that the release of inhibitors was correlated to reaction severity and that carbonic acid did not appear to increase or decrease inhibition compared to pretreatment with water alone. 5) Assess the reactivity to enzymatic hydrolysis of material pretreated at selected reaction conditions and severity. Enzymatic hydrolysis rates increased with severity, but no advantage was detected for the use of carbonic acid compared to water alone. 6) Determine optimal conditions for carbonic acid pretreatment of aspen wood. Optimal severities appeared to be in the mid range tested. ASPEN-Plus modeling and economic analysis of the process indicate that the process could be cost competitive with sulfuric acid if the concentration of solids in the pretreatment is maintained very high (~50%). Lower solids concentrations result in larger reactors that become expensive to construct for high pressure applications.

  20. Catalytic Hydrothermal Gasification of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2008-05-06

    A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

  1. Biomass reforming processes in hydrothermal media

    E-Print Network [OSTI]

    Peterson, Andrew A

    2009-01-01

    While hydrothermal technologies offer distinct advantages in being able to process a wide variety of biomass feedstocks, the composition of the feedstock will have a large effect on the processing employed. This thesis ...

  2. Correlation of hydrothermal sericite composition with permeability...

    Open Energy Info (EERE)

    of aqueous species in the geothermal fluids were combined with activity phase diagrams accounting for hydrothermal sericite compositions to determine a pH of 6.1 for the...

  3. High throughput protein production screening

    DOE Patents [OSTI]

    Beernink, Peter T. (Walnut Creek, CA); Coleman, Matthew A. (Oakland, CA); Segelke, Brent W. (San Ramon, CA)

    2009-09-08

    Methods, compositions, and kits for the cell-free production and analysis of proteins are provided. The invention allows for the production of proteins from prokaryotic sequences or eukaryotic sequences, including human cDNAs using PCR and IVT methods and detecting the proteins through fluorescence or immunoblot techniques. This invention can be used to identify optimized PCR and WT conditions, codon usages and mutations. The methods are readily automated and can be used for high throughput analysis of protein expression levels, interactions, and functional states.

  4. Hydrothermal industrialization: direct heat development. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-05-01

    A description of hydrothermal resources suitable for direct applications, their associated temperatures, geographic distribution and developable capacity are given. An overview of the hydrothermal direct-heat development infrastructure is presented. Development activity is highlighted by examining known and planned geothermal direct-use applications. Underlying assumptions and results for three studies conducted to determine direct-use market penetration of geothermal energy are discussed.

  5. Ensemble Jobs for Better Throughput - Videoconference | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ensemble Jobs for Better Throughput - Videoconference Event Sponsor: Argonne National Laboratory Start Date: Sep 24 2015 - 1:00pm BuildingRoom: Online Videoconference Location:...

  6. High Throughput Materials Characterization John M. Gregoire

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    White Paper for Establishing a User Facility for Synchrotron-based High Throughput Materials Characterization John M. Gregoire 1 , Matthew J. Kramer 2 , Apurva Mehta 3 1 Joint...

  7. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    emissions in the coal gasification process while maintainingbased fuels or coal gasification. 1 The transportation andbe very efficient for gasification of both coal and biomass

  8. Dilute Acid Hydrolysis of Oligomers in Hydrothermal Pretreatment Hydrolyzate into Monomers with High Yields

    E-Print Network [OSTI]

    Tsai, Yueh-Du

    2012-01-01

    Renewable Energy Laboratory, September Chapter 6 Conclusions and Recommendations 6.1 Summary of thesis objectives The main motivation

  9. Dilute Acid Hydrolysis of Oligomers in Hydrothermal Pretreatment Hydrolyzate into Monomers with High Yields

    E-Print Network [OSTI]

    Tsai, Yueh-Du

    2012-01-01

    578. Hsu T. 1996. Bioethanol: Production and Utilization.design and costing of bioethanol technology: a tool for9 Bioethanol

  10. Dilute Acid Hydrolysis of Oligomers in Hydrothermal Pretreatment Hydrolyzate into Monomers with High Yields

    E-Print Network [OSTI]

    Tsai, Yueh-Du

    2012-01-01

    Industrial and Engineering Chemistry 37: 43-52. Saha B.production. Industrial & Engineering Chemistry Research 48:Industrial and Engineering Chemistry 37: 43-52. Saulnier L,

  11. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    April 16, 2009 Gasification of comingled biomass and coalof biomass for pressurized entrained flow gasification. Fuelcomingled biomass and coal feedstock into the gasification

  12. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    entrained flow gasification. Fuel Process. Technol. 2009, inratio is 3:1 when using our gasification process. Thus, withas a feedstock for gasification. Table 3 shows the results

  13. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    Dincer, H. The effect of coal properties on the viscosity ofthat the rheological properties of coal-water slurries areshear thickening property of coal-water slurry was rarely

  14. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    oil demand and increasing concerns about energy security. Gasification and subsequent conversion of the gasification products

  15. Dilute Acid Hydrolysis of Oligomers in Hydrothermal Pretreatment Hydrolyzate into Monomers with High Yields

    E-Print Network [OSTI]

    Tsai, Yueh-Du

    2012-01-01

    1998. Biomass for renewable energy, fuels, and chemicals.Elsevier. The National Renewable Energy Laboratory.2003,Golden, CO: National Renewable Energy Laboratory, 2007.

  16. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    of Chemical and Environmental Engineering, University ofCollege of Engineering Center for Environmental Research andCollege of Engineering Center for Environmental Research and

  17. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    4) Bridgwater, T. Biomass for energy. J. Sci. Food Agric.A. Method for high energy density biomass-water slurry. U.S.substituting biomass for fossil fuels. Energy (2) Henrich,

  18. Dilute Acid Hydrolysis of Oligomers in Hydrothermal Pretreatment Hydrolyzate into Monomers with High Yields

    E-Print Network [OSTI]

    Tsai, Yueh-Du

    2012-01-01

    Klass DL. 1998. Biomass for renewable energy, fuels, andNational Renewable Energy Laboratory.2003, Biomass feedstockKlass DL. 1998. Biomass for Renewable Energy, Fuels and

  19. Dilute Acid Hydrolysis of Oligomers in Hydrothermal Pretreatment Hydrolyzate into Monomers with High Yields

    E-Print Network [OSTI]

    Tsai, Yueh-Du

    2012-01-01

    578. Hsu T. 1996. Bioethanol: Production and Utilization.as a feedstock for bioethanol production for many years. Thebioethanol commercially in the U.S. Unlike sugar, production

  20. Dilute Acid Hydrolysis of Oligomers in Hydrothermal Pretreatment Hydrolyzate into Monomers with High Yields

    E-Print Network [OSTI]

    Tsai, Yueh-Du

    2012-01-01

    for corn stover. Report No. NREL/TP-510-32438. Golden, CO:of corn stover report No. NREL/TP- 5100-47764. Golden, CO:future scenarios. Report No. NREL/TP-580-26157. Golden, CO:

  1. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    April 16, 2009 Gasification of comingled biomass and coalfor gasification of both coal and biomass feedstock, eitherof biomass for pressurized entrained flow gasification. Fuel

  2. Rheological Study of Comingled Biomass and Coal Slurries with HydrothermalPretreatment

    E-Print Network [OSTI]

    He, W; Park, C S; Norbeck, J N

    2009-01-01

    to synthetic liquid fuel from a comingled biomass and coalliquid fuels while potentially reducing the overall net life cycle greenhouse gas emissions when compared to petroleum-based fuels or coal

  3. ASYNCHRONOUS WAVE PIPELINES FOR HIGH THROUGHPUT DATAPATHS

    E-Print Network [OSTI]

    Huss, Sorin A.

    ASYNCHRONOUS WAVE PIPELINES FOR HIGH THROUGHPUT DATAPATHS O. Hauck and S. A. Huss fhauck j hussg pipeline architecture for high­speed clockless computation is proposed. It features gate­level pipelining the advantages of wave pipelining and asynchronous operation, i. e. very high throughput at low latency while

  4. On Achieving Optimal Throughput with Network Coding

    E-Print Network [OSTI]

    Li, Baochun

    to the problem of optimizing end-to- end throughput in undirected data networks. We first illustrate the powerOn Achieving Optimal Throughput with Network Coding Zongpeng Li, Baochun Li, Dan Jiang, Lap Chi Lau Abstract-- With the constraints of network topologies and link capacities, achieving the optimal end

  5. Chain Replication for Supporting High Throughput and Availability

    E-Print Network [OSTI]

    Keinan, Alon

    Chain Replication for Supporting High Throughput and Availability Robbert van Renesse rvr services that exhibit high throughput and availability with- out sacrificing strong consistency guarantees the perfor- mance characteristics of a prototype implementa- tion. Throughput, availability, and several

  6. Waste Treatment and Immobilation Plant Pretreatment Facility

    Office of Environmental Management (EM)

    7 Technology Readiness Assessment for the Waste Treatment and Immobilization Plant (WTP) Pretreatment Facility L. Holton D. Alexander M. Johnson H. Sutter August 2007 Prepared by...

  7. The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrothermal Agingon a Commercial Cu SCR Catalyst Examines the effect of hydrothermal aging on the Nox reduction over a commercial Cu-zeolite SCR catalyst. deer11lee.pdf More...

  8. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robust, High-Throughput Analysis of Protein Structures Robust, High-Throughput Analysis of Protein Structures Print Wednesday, 28 October 2009 00:00 Scientists have developed a...

  9. High-Throughput and Combinatorial Screening of Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Throughput and Combinatorial Screening of Hydrogen Storage Materials (presentation) High-Throughput and Combinatorial Screening of Hydrogen Storage Materials (presentation)...

  10. Potential of High-Throughput Experimentation with Ammonia Borane...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials (presentation) Potential of High-Throughput Experimentation with Ammonia Borane Solid...

  11. High-Throughput/Combinatorial Techniques in Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D (presentation) High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D (presentation)...

  12. High Throughput/Combinatorial Screening of Hydrogen Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials: UOP Approaches High ThroughputCombinatorial Screening of Hydrogen Storage Materials: UOP Approaches Presentation by Adriaan Sachtler from the High Throughput...

  13. Calibrated Hydrothermal Parameters, Barrow, Alaska, 2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Atchley, Adam; Painter, Scott; Harp, Dylan; Coon, Ethan; Wilson, Cathy; Liljedahl, Anna; Romanovsky, Vladimir

    A model-observation-experiment process (ModEx) is used to generate three 1D models of characteristic micro-topographical land-formations, which are capable of simulating present active thaw layer (ALT) from current climate conditions. Each column was used in a coupled calibration to identify moss, peat and mineral soil hydrothermal properties to be used in up-scaled simulations. Observational soil temperature data from a tundra site located near Barrow, AK (Area C) is used to calibrate thermal properties of moss, peat, and sandy loam soil to be used in the multiphysics Advanced Terrestrial Simulator (ATS) models. Simulation results are a list of calibrated hydrothermal parameters for moss, peat, and mineral soil hydrothermal parameters.

  14. The BGU/CERN solar hydrothermal reactor

    E-Print Network [OSTI]

    Bertolucci, Sergio; Caspers, Fritz; Garb, Yaakov; Gross, Amit; Pauletta, Stefano

    2014-01-01

    We describe a novel solar hydrothermal reactor (SHR) under development by Ben Gurion University (BGU) and the European Organization for Nuclear Research CERN. We describe in broad terms the several novel aspects of the device and, by extension, of the niche it occupies: in particular, enabling direct off-grid conversion of a range of organic feedstocks to sterile useable (solid, liquid) fuels, nutrients, products using only solar energy and water. We then provide a brief description of the high temperature high efficiency panels that provide process heat to the hydrothermal reactor, and review the basics of hydrothermal processes and conversion taking place in this. We conclude with a description of a simulation of the pilot system that will begin operation later this year.

  15. Calibrated Hydrothermal Parameters, Barrow, Alaska, 2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Atchley, Adam; Painter, Scott; Harp, Dylan; Coon, Ethan; Wilson, Cathy; Liljedahl, Anna; Romanovsky, Vladimir

    2015-01-29

    A model-observation-experiment process (ModEx) is used to generate three 1D models of characteristic micro-topographical land-formations, which are capable of simulating present active thaw layer (ALT) from current climate conditions. Each column was used in a coupled calibration to identify moss, peat and mineral soil hydrothermal properties to be used in up-scaled simulations. Observational soil temperature data from a tundra site located near Barrow, AK (Area C) is used to calibrate thermal properties of moss, peat, and sandy loam soil to be used in the multiphysics Advanced Terrestrial Simulator (ATS) models. Simulation results are a list of calibrated hydrothermal parameters for moss, peat, and mineral soil hydrothermal parameters.

  16. Geothermal reservoirs in hydrothermal convection systems

    SciTech Connect (OSTI)

    Sorey, M.L.

    1982-01-01

    Geothermal reservoirs commonly exist in hydrothermal convection systems involving fluid circulation downward in areas of recharge and upwards in areas of discharge. Because such reservoirs are not isolated from their surroundings, the nature of thermal and hydrologic connections with the rest of the system may have significant effects on the natural state of the reservoir and on its response to development. Conditions observed at numerous developed and undeveloped geothermal fields are discussed with respect to a basic model of the discharge portion of an active hydrothermal convection system. Effects of reservoir development on surficial discharge of thermal fluid are also delineated.

  17. Ionic Liquid Pretreatment Process for Biomass Is Successfully...

    Energy Savers [EERE]

    Ionic Liquid Pretreatment Process for Biomass Is Successfully Implemented at Larger Scale Ionic Liquid Pretreatment Process for Biomass Is Successfully Implemented at Larger Scale...

  18. High-throughput in vivo vertebrate screening

    E-Print Network [OSTI]

    Pardo-Martin, Carlos

    We demonstrate a high-throughput platform for cellular-resolution in vivo chemical and genetic screens on zebrafish larvae. The system automatically loads zebrafish from reservoirs or multiwell plates, and positions and ...

  19. Approaches to High Throughput Physical Organic Chemistry 

    E-Print Network [OSTI]

    Portal, Christophe

    2008-01-01

    Over the past ten years, the development of High Throughput (HT) synthetic chemistry techniques has allowed the rapid preparation of libraries of hundreds to thousands of compounds. These tools are now extensively used for drug and material...

  20. Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C; Oyler, James

    2013-12-17

    Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogenous catalyst for gasification.

  1. Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C; Oyler, James R

    2014-11-04

    Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  2. Hydrothermal stability of high silica zeolites 

    E-Print Network [OSTI]

    Young, David

    1988-01-01

    This thesis concerns the hydrothermal stability of two zeolite molecular sieves with the MFI structure, ZSM-5 and its 'aluminium free' form silicalite. Silicalite was synthesised from low pH alkali metal free aqueous gels at 95°C and characterised...

  3. Whole Algae Hydrothermal Liquefaction Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  4. Hydrothermally Deposited Rock | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources JumpNewTexas:Hydrothermally Deposited Rock Jump to: navigation,

  5. Whole Algae Hydrothermal Liquefaction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternationalReport FY2014 -Energy Costs by IncreasingWhole Algae Hydrothermal

  6. Hydrothermal Exploration Data Gap Analysis Update

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls -Hydro-PacHydronic Systems:TechnologyHydrothermal

  7. Hydrothermal Resources Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof Energy ServicesContractingManagement »Hydrogen and FuelHydrothermal

  8. Stable Throughput in a Cognitive Wireless Network

    E-Print Network [OSTI]

    Fanous, Anthony

    2012-01-01

    We study, from a network layer perspective, the effect of an Ad-Hoc secondary network with N nodes randomly accessing the spectrum licensed to a primary node during the idle slots of the primary user. If the sensing is perfect, then the secondary nodes do not interfere with the primary node and hence do not affect its stable throughput. In case of imperfect sensing, it is shown that if the primary user's arrival rate is less than some calculated finite value, cognitive nodes can employ any transmission power or probabilities without affecting the primary user's stability; otherwise, the secondary nodes should control their transmission parameters to reduce the interference on the primary. It is also shown that in contrast with the primary's maximum stable throughput which strictly decreases with increased sensing errors, the throughput of the secondary nodes might increase with sensing errors as more transmission opportunities become available to them. Finally, we explore the use of the secondary nodes as rel...

  9. Hydrothermal reaction of fly ash. Final report

    SciTech Connect (OSTI)

    Brown, P.W.

    1994-12-31

    The reactions which occur when fly ash is treated under hydrothermal conditions were investigated. This was done for the following primary reasons. The first of these is to determine the nature of the phases that form to assess the stabilities of these phases in the ambient environment and, finally, to assess whether these phases are capable of sequestering hazardous species. The second reason for undertaking this study was whether, depending on the composition of the ash and the presence of selected additives, it would be possible under hydrothermal conditions to form compounds which have cementitious properties. Formation of four classes of compounds, which bracket likely fly ash compositional ranges, were selected for study. The classes are calcium silicate hydrates, calcium selenates, and calcium aluminosulfates, and silicate-based glasses. Specific compounds synthesized were determined and their stability regions assessed. As part of stability assessment, the extent to which selected hazardous species are sequestered was determined. Finally, the cementing properties of these compounds were established. The results obtained in this program have demonstrated that mild hydrothermal conditions can be employed to improve the reactivity of fly ash. Such improvements in reactivity can result in the formation of monolithic forms which may exhibit suitable mechanical properties for selected applications as building materials. If the ashes involved are considered hazardous, the mechanical properties exhibited indicated the forms could be handled in a manner which facilitates their disposal.

  10. Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal...

    Open Energy Info (EERE)

    Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal System- A Case Study Of The Geysers Geothermal Field, Usa Jump to: navigation, search OpenEI Reference...

  11. The Hydrothermal Outflow Plume of Valles Caldera, New Mexico...

    Open Energy Info (EERE)

    are parents to mixed fluids flowing in the hydrothermal plume. However, isotopic data, borehole data, basic geology, and inverse relations between temperature and chloride...

  12. Hydrothermal Heat Discharge In The Cascade Range, Northwestern...

    Open Energy Info (EERE)

    United States Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Hydrothermal Heat Discharge In The Cascade Range, Northwestern United States...

  13. GEOLOGY AND HYDROTHERMAL ALTERATION OF THE RAFT RIVER GEOTHERMAL...

    Open Energy Info (EERE)

    GEOLOGY AND HYDROTHERMAL ALTERATION OF THE RAFT RIVER GEOTHERMAL SYSTEM, IDAHO Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: GEOLOGY...

  14. New Evidence On The Hydrothermal System In Long Valley Caldera...

    Open Energy Info (EERE)

    Hydrothermal System In Long Valley Caldera, California, From Wells, Fluid Sampling, Electrical Geophysics, And Age Determinations Of Hot-Spring Deposits Jump to: navigation,...

  15. Altered Tectonic and Hydrothermal Breccias in Corehole VC-1,...

    Open Energy Info (EERE)

    origin. Hydrothermal breccias and associated crackle zones or stockworks created by hydraulic fracturing can provide significant secondary permeability, as demonstrated by...

  16. Development of a Hydrothermal Spallation Drilling System for EGS

    Broader source: Energy.gov [DOE]

    Project objective: Build and demonstrate a working prototype hydrothermal spallation drilling unit that will accelerate commercial deployment of EGS as a domestic energy resource.

  17. Temporal Relations of Volcanism and Hydrothermal Systems in Two...

    Open Energy Info (EERE)

    Geology, 1989 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Temporal Relations of Volcanism and Hydrothermal Systems in Two Areas of...

  18. Volatiles in hydrothermal fluids- A mass spectrometric study...

    Open Energy Info (EERE)

    Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  19. An Overview of Hydrothermal Alteration and Vein Mineralization...

    Open Energy Info (EERE)

    Overview of Hydrothermal Alteration and Vein Mineralization in Continental Scientific Drilling Program Core Hole VC-2B, Valles Caldera, New Mexico Jump to: navigation, search...

  20. Robust optimization based self scheduling of hydro-thermal Genco ...

    E-Print Network [OSTI]

    Dec 29, 2013 ... Abstract: This paper proposes a robust optimization model for optimal self scheduling of a hydro-thermal generating company. The proposed ...

  1. Hydrology of Hydrothermal Systems in the Long Valley Caldera Hydrothermal activity in the Long Valley Caldera has had many different periods in its history of

    E-Print Network [OSTI]

    Polly, David

    the temperatures of the hydrothermal fluid. The geothermal systems and hydrothermal systems have been documented that the temperatures would be extremely high, akin to Yellowstone. But what they found were temperatures much lower). Hydrothermal Systems Summary Geothermal systems and the hydrothermal systems are an occurrence that happens

  2. An overlay architecture for throughput optimal multipath routing

    E-Print Network [OSTI]

    Jones, Nathaniel M.

    Legacy networks are often designed to operate with simple single-path routing, like shortest-path, which is known to be throughput suboptimal. On the other hand, previously proposed throughput optimal policies (i.e., ...

  3. Throughput Analysis of Wireless Ad-Hoc Cognitive Radio Networks 

    E-Print Network [OSTI]

    Banaei, Armin

    2014-04-25

    In this dissertation we consider the throughput performance of cognitive radio networks and derive the optimal sensing and access schemes for secondary users that maximizes their sum-throughput while guaranteeing certain ...

  4. Chemistry & Biology Genome-Wide High-Throughput Mining

    E-Print Network [OSTI]

    Yin, Jun

    Chemistry & Biology Article Genome-Wide High-Throughput Mining of Natural-Product Biosynthetic Gene.01.006 SUMMARY We have developed a phage-display method for high-throughput mining of bacterial gene clus- ters

  5. High-Throughput/Combinatorial Techniques in Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D On June 26, 2007 the Hydrogen...

  6. Statistical Algorithms for High-throughput Biological Data /

    E-Print Network [OSTI]

    Jeong, Kyowon

    2013-01-01

    Statistical Algorithms for High-throughput Biological Data by Kyowon Jeong Doctor of Philosophy in Electrical Engineering (Communication Theory

  7. Throughput Maximization in Wireless Powered Communication Networks with Energy Saving

    E-Print Network [OSTI]

    Brown III, Donald R.

    Throughput Maximization in Wireless Powered Communication Networks with Energy Saving Rui Wang, D and energy allocation to maximize the sum throughput for the case when the nodes can save energy for later with energy saving provides improved sum throughput increasing with the number of transmission blocks. Index

  8. The Design of High-Throughput Asynchronous Pipelines

    E-Print Network [OSTI]

    The Design of High-Throughput Asynchronous Pipelines Montek Singh Department of Computer Science UNIVERSITY December 2001 #12;The Design of High-Throughput Asynchronous Pipelines Montek Singh ABSTRACT is on high-throughput asynchronous pipelines, since pipelining is at the heart of most high

  9. The Design of HighThroughput Asynchronous Pipelines

    E-Print Network [OSTI]

    The Design of High­Throughput Asynchronous Pipelines Montek Singh Department of Computer Science UNIVERSITY December 2001 #12; The Design of High­Throughput Asynchronous Pipelines Montek Singh ABSTRACT is on high­throughput asynchronous pipelines, since pipelining is at the heart of most high

  10. Hydrothermal synthesis of hexagonal magnesium hydroxide nanoflakes

    SciTech Connect (OSTI)

    Wang, Qiang, E-mail: qwchem@gmail.com [Laboratory for Micro-sized Functional Materials and College of Elementary Education, Capital Normal University, Beijing 100048 (China); Li, Chunhong [National Laboratory for Superconductivity, Institute of Physics and Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guo, Ming [Laboratory for Micro-sized Functional Materials and College of Elementary Education, Capital Normal University, Beijing 100048 (China); Sun, Lingna [ShenZhen Key Laboratory of Functional Polymer, College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060 (China); Hu, Changwen [Key Laboratory of Cluster Science of Ministry of Education of China, The Institute for Chemical Physics and Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)

    2014-03-01

    Graphical abstract: Hexagonal Mg(OH){sub 2} nanoflakes were synthesized via hydrothermal method in the presence of PEG-20,000. Results show that PEG-20,000 plays an important role in the formation of this kind of nanostructure. The SAED patterns taken from the different positions on a single hexagonal Mg(OH){sub 2} nanoflake yielded different crystalline structures. The structure of the nanoflakes are polycrystalline and the probable formation mechanism of Mg(OH){sub 2} nanoflakes is discussed. - Highlights: • Hexagonal Mg(OH){sub 2} nanoflakes were synthesized via hydrothermal method. • PEG-20,000 plays an important role in the formation of hexagonal nanostructure. • Mg(OH){sub 2} nanoflakes show different crystalline structures at different positions. • The probable formation mechanism of hexagonal Mg(OH){sub 2} nanoflakes was reported. - Abstract: Hexagonal magnesium hydroxide (Mg(OH){sub 2}) nanoflakes were successfully synthesized via hydrothermal method in the presence of the surfactant polyethylene glycol 20,000 (PEG-20,000). Results show that PEG-20,000 plays an important role in the formation of this kind of nanostructure. The composition, morphologies and structure of the Mg(OH){sub 2} nanoflakes were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HRTEM), and selected area electron diffraction (SAED). The SAED patterns taken from the different positions on a single hexagonal Mg(OH){sub 2} nanoflake show different crystalline structures. The structure of the nanoflakes are polycrystalline and the probable formation mechanism of Mg(OH){sub 2} nanoflakes is discussed. Brunauer–Emmett–Teller (BET) analysis were performed to investigate the porous structure and surface area of the as-obtained nanoflakes.

  11. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    SciTech Connect (OSTI)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  12. Pretreatment of high solid microbial sludges

    DOE Patents [OSTI]

    Rivard, C.J.; Nagle, N.J.

    1998-07-28

    A process and apparatus are disclosed for pretreating microbial sludges in order to enhance secondary anaerobic digestion. The pretreatment process involves disrupting the cellular integrity of municipal sewage sludge through a combination of thermal, explosive decompression and shear forces. The sludge is pressurized and pumped to a pretreatment reactor where it is mixed with steam to heat and soften the sludge. The pressure of the sludge is suddenly reduced and explosive decompression forces are imparted which partially disrupt the cellular integrity of the sludge. Shear forces are then applied to the sludge to further disrupt the cellular integrity of the sludge. Disrupting cellular integrity releases both soluble and insoluble organic constituents and thereby renders municipal sewage sludge more amenable to secondary anaerobic digestion. 1 fig.

  13. Pretreatment of high solid microbial sludges

    DOE Patents [OSTI]

    Rivard, Christopher J. (Lakewood, CO); Nagle, Nicholas J. (Broomfield, CO)

    1998-01-01

    A process and apparatus for pretreating microbial sludges in order to enhance secondary anaerobic digestion. The pretreatment process involves disrupting the cellular integrity of municipal sewage sludge through a combination of thermal, explosive decompression and shear forces. The sludge is pressurized and pumped to a pretreatment reactor where it is mixed with steam to heat and soften the sludge. The pressure of the sludge is suddenly reduced and explosive decompression forces are imparted which partially disrupt the cellular integrity of the sludge. Shear forces are then applied to the sludge to further disrupt the cellular integrity of the sludge. Disrupting cellular integrity releases both soluble and insoluble organic constituents and thereby renders municipal sewage sludge more amenable to secondary anaerobic digestion.

  14. Investigations of Biomass Pretreatment and Submerged Fixed-bed Fermentation 

    E-Print Network [OSTI]

    Meysing, Daniel

    2012-02-14

    To improve the MixAlco process and biomass pretreatment, five studies were conducted. Three studies related to fermentation, whereas the other two investigated the effectiveness of shock tube pretreatment (STP) coupled ...

  15. Pretreatment and Process Hydrolysis Presentation for BETO 2015...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    effective upgrading * Utilize all carbon * Increase rural employment opportunities * Lower petroleum imports * Decrease carbon footprint. 2 Project Overview Pretreatment and...

  16. New hydrocracking catalysts increase throughput, run length

    SciTech Connect (OSTI)

    Huizinga, T. [Shell Internationale Petroleum Mij., The Hague (Netherlands); Theunissen, J.M.H. [Rayong Refinery Co. Ltd., Rayong (Thailand); Minderhoud, H.; Veen, R. van [Koninklijke/Shell-Lab., Amsterdam (Netherlands)

    1995-06-26

    An improved, second-stage hydrocracking catalyst has been developed by combining stabilized Y zeolites with amorphous silica alumina cracking components. A commercial application of this catalyst, along with a new, first-stage zeolitic hydrocracking catalyst, resulted in increased unit throughput and cycle length. The paper discusses the hydrocracking process, first-stage catalysts, second-stage catalysts, hydrogenation process, commercial results, and product properties.

  17. ILLITE-SMECTITE MIXED-LAYER MINERALS IN HYDROTHERMAL ALTERATION OF VOLCANIC ROCKS

    E-Print Network [OSTI]

    Boyer, Edmond

    diagenesis, low-grade metamorphism, contact metamorphism and hydrothermal alteration. Despite extensive

  18. High throughput chemical munitions treatment system

    DOE Patents [OSTI]

    Haroldsen, Brent L. (Manteca, CA); Stofleth, Jerome H. (Albuquerque, NM); Didlake, Jr., John E. (Livermore, CA); Wu, Benjamin C-P (San Ramon, CA)

    2011-11-01

    A new High-Throughput Explosive Destruction System is disclosed. The new system is comprised of two side-by-side detonation containment vessels each comprising first and second halves that feed into a single agent treatment vessel. Both detonation containment vessels further comprise a surrounding ventilation facility. Moreover, the detonation containment vessels are designed to separate into two half-shells, wherein one shell can be moved axially away from the fixed, second half for ease of access and loading. The vessels are closed by means of a surrounding, clam-shell type locking seal mechanisms.

  19. Automated High Throughput Drug Target Crystallography

    SciTech Connect (OSTI)

    Rupp, B

    2005-02-18

    The molecular structures of drug target proteins and receptors form the basis for 'rational' or structure guided drug design. The majority of target structures are experimentally determined by protein X-ray crystallography, which as evolved into a highly automated, high throughput drug discovery and screening tool. Process automation has accelerated tasks from parallel protein expression, fully automated crystallization, and rapid data collection to highly efficient structure determination methods. A thoroughly designed automation technology platform supported by a powerful informatics infrastructure forms the basis for optimal workflow implementation and the data mining and analysis tools to generate new leads from experimental protein drug target structures.

  20. Self-excited hydrothermal waves in evaporating sessile drops 

    E-Print Network [OSTI]

    Sefiane K.; Moffat J.R.; Matar O.K.; Craster R.V.

    2008-08-01

    Pattern formation driven by the spontaneous evaporation of sessile drops of methanol, ethanol, and FC-72 using infrared thermography is observed and, in certain cases, interpreted in terms of hydrothermal waves. Both ...

  1. Direct use of hydrothermal energy: a review of environmental aspects

    SciTech Connect (OSTI)

    O'Banion, K.; Layton, D.

    1981-08-28

    The potential environmental impacts of the exploration, development, and production of hydrothermal geothermal energy for direct use applications are reviewed and evaluated. Mitigation strategies and research and development needs are included. (MHR)

  2. Hydrothermal Alteration and Past and Present Thermal Regimes...

    Open Energy Info (EERE)

    Long Valley Caldera Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Hydrothermal Alteration and Past and Present Thermal Regimes in the Western...

  3. Spatial And Temporal Geochemical Trends In The Hydrothermal System...

    Open Energy Info (EERE)

    analysis also suggests that it might be more feasible to detect large-scale heating or cooling of the hydrothermal system by tracking changes in gas and steam flux than by...

  4. Whole Algae Hydrothermal Liquefaction: 2014 State of Technology

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Snowden-Swan, Lesley J.; Anderson, Daniel; Hallen, Richard T.; Schmidt, Andrew J.; Albrecht, Karl O.; Elliott, Douglas C.

    2014-07-30

    This report describes the base case yields and operating conditions for converting whole microalgae via hydrothermal liquefaction and upgrading to liquid fuels. This serves as the basis against which future technical improvements will be measured.

  5. Seismic Evidence For A Hydrothermal Layer Above The Solid Roof...

    Open Energy Info (EERE)

    Seismic Evidence For A Hydrothermal Layer Above The Solid Roof Of The Axial Magma Chamber At The Southern East Pacific Rise Jump to: navigation, search OpenEI Reference LibraryAdd...

  6. Rational control of hydrothermal nanowire synthesis and its applications

    E-Print Network [OSTI]

    Joo, Jaebum

    2010-01-01

    Hydrothermal nanowire synthesis is a rapidly emerging nanowire discipline that enables low temperature growth and batch process. It has a major impact on the development of novel energy conversion devices, high density ...

  7. Hydrothermal vents of Yellowstone Lake, Yellowstone National Park, Wyoming

    SciTech Connect (OSTI)

    Kaplinski, M.A.; Morgan, P. (Northern Arizona Univ., Flagstaff, AZ (United States). Geology Dept.)

    1993-04-01

    Hydrothermal vent systems within Yellowstone Lake are located within the Yellowstone caldera in the northeastern and West Thumb sections of the lake. The vent systems lie within areas of extremely high geothermal gradients (< 1,000 C/km) in the lake sediments and occur as clusters of individual vents that expel both hydrothermal fluids and gas. Regions surrounding the vents are colonized by unique, chemotropic biologic communities and suggest that hydrothermal input plays an important role in the nutrient dynamics of the lake's ecosystem. The main concentration of hydrothermal activity occurs in the northeast region of the main lake body in a number of locations including: (1) along the shoreline from the southern edge of Sedge Bay to the inlet of Pelican Creek; (2) the central portion of the partially submerged Mary Bay phreatic explosion crater, within deep (30--50 m) fissures; (3) along the top of a 3 km long, steep-sided ridge that extends from the southern border of Mary Bay, south-southeast into the main lake basin; and (4) east of Stevenson Island along the lower portion of the slope (50--107 m) into the lake basin, within an anastomosing series of north to northwest trending, narrow troughs or fissures. Hydrothermal vents were also located within, and surrounding the West Thumb of Yellowstone Lake, with the main concentration occurring the offshore of the West Thumb and Potts Geyser Basin. Hydrothermal vents in Yellowstone Lake occur along fractures that have penetrated the lake sediments or along the tops of ridges and near shore areas. Underneath the lake, rising hydrothermal fluids encounter a semi-permeable cap of lake sediments. Upwardly convecting hydrothermal fluid flow may be diverted by the impermeable lake sediments along the buried, pre-existing topography. These fluids may continue to rise along topography until fractures are encountered, or the lake sediment cover is thinned sufficiently to allow egress of the fluids.

  8. Methods to enhance the characteristics of hydrothermally prepared slurry fuels

    DOE Patents [OSTI]

    Anderson, Chris M. (Shakopee, MN); Musich, Mark A. (Grand Forks, ND); Mann, Michael D. (Thompson, ND); DeWall, Raymond A. (Grand Forks, ND); Richter, John J. (Grand Forks, ND); Potas, Todd A. (Plymouth, MN); Willson, Warrack G. (Fairbanks, AK)

    2000-01-01

    Methods for enhancing the flow behavior and stability of hydrothermally treated slurry fuels. A mechanical high-shear dispersion and homogenization device is used to shear the slurry fuel. Other improvements include blending the carbonaceous material with a form of coal to reduce or eliminate the flocculation of the slurry, and maintaining the temperature of the hydrothermal treatment between approximately 300.degree. to 350.degree. C.

  9. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast and efficient way to determine the structure of proteins, shortening a process that...

  10. High-throughput metagenomic technologies for complex microbial...

    Office of Scientific and Technical Information (OSTI)

    formats Prev Next Title: High-throughput metagenomic technologies for complex microbial community analysis. Open and closed formats You are accessing a document from...

  11. High Throughput/Combinatorial Screening of Hydrogen Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials (presentation) High ThroughputCombinatorial Screening of Hydrogen Storage Materials (presentation) Presented at the U.S. Department of Energy's Hydrogen Storage Meeting...

  12. High Throughput Combinatorial Screening of Biometic Metal-Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Throughput Combinatorial Screening of Biometic Metal-Organic Materials for Military Hydrogen-Storage Materials (New Joint Miami UNREL DoDDLA Project) (presentation) High...

  13. Waste Separations and Pretreatment Workshop report

    SciTech Connect (OSTI)

    Cruse, J.M.; Harrington, R.A.; Quadrel, M.J.

    1994-01-01

    This document provides the minutes from the Waste Separations and Pretreatment Workshop sponsored by the Underground Storage Tank-Integrated Demonstration in Salt Lake City, Utah, February 3--5, 1993. The Efficient Separations and Processing-Integrated Program and the Hanford Site Tank Waste Remediation System were joint participants. This document provides the detailed minutes, including responses to questions asked, an attendance list, reproductions of the workshop presentations, and a revised chart showing technology development activities.

  14. Composition and hydrothermal pretreatment and enzymatic saccharification performance of grasses and legumes from a mixed species prairie

    E-Print Network [OSTI]

    DeMartini, Jaclyn D; Wyman, Charles E

    2011-01-01

    procedure. National Renewable Energy Laboratory, Golden,in biomass. National Renewable Energy Laboratory, Golden,

  15. Rapid selection and identification of Miscanthus genotypes with enhanced glucan and xylan yields from hydrothermal pretreatment followed by enzymatic hydrolysis

    E-Print Network [OSTI]

    Zhang, Taiying; Wyman, Charles E; Jakob, Katrin; Yang, Bin

    2012-01-01

    sugar yields with various biomass feedstocks, such as cornand other selected biomass feedstocks Biomass Composition (%

  16. Rapid selection and identification of Miscanthus genotypes with enhanced glucan and xylan yields from hydrothermal pretreatment followed by enzymatic hydrolysis

    E-Print Network [OSTI]

    Zhang, Taiying; Wyman, Charles E; Jakob, Katrin; Yang, Bin

    2012-01-01

    Science 2005, 3. Kerr RA: Peak oil production may already beoil production might have already reached its peak instead

  17. Composition and hydrothermal pretreatment and enzymatic saccharification performance of grasses and legumes from a mixed species prairie

    E-Print Network [OSTI]

    DeMartini, Jaclyn D; Wyman, Charles E

    2011-01-01

    Society of Agronomy/Crop Science Society of America/SoilSociety of Agronomy/ Crop Science Society of America/SoilSociety of Agronomy/Crop Science Society of America/Soil

  18. Reconnaissance of the hydrothermal resources of Utah

    SciTech Connect (OSTI)

    Rush, F.E.

    1983-01-01

    Geologic factors in the Basin and Range province in Utah are more favorable for the occurrence of geothermal resources than in other areas on the Colorado Plateaus or in the Middle Rocky Mountains. These geologic factors are principally crustal extension and crustal thinning during the last 17 million years. Basalts as young as 10,000 years have been mapped in the area. High-silica volcanic and intrusive rocks of Quaternary age can be used to locate hydrothermal convection systems. Drilling for hot, high-silica, buried rock bodies is most promising in the areas of recent volcanic activity. Southwestern Utah has more geothermal potential than other parts of the Basin and Range province in Utah. The Roosevelt Hot Springs area, the Cove Fort-Sulphurdale area, and the area to the north as far as 60 kilometers from them probably have the best potential for geothermal development for generation of electricity. Other areas with estimated reservoir temperatures greater than 150/sup 0/C are Thermo, Monroe, Red Hill (in the Monroe-Joseph Known Geothermal Resource Area), Joseph Hot Springs, and the Newcastle area. The rates of heat and water discharge are high at Crater, Meadow, and Hatton Hot Springs, but estimated reservoir temperatures there are less than 150/sup 0/C. Additional exploration is needed to define the potential in three additional areas in the Escalante Desert. 28 figs., 18 tabs.

  19. Maximizing the Sustained Throughput of Distributed Continuous Queries

    E-Print Network [OSTI]

    Palpanas, Themis

    the query plans that maximize throughput and adhere to the input profile. Examples of data stream managementMaximizing the Sustained Throughput of Distributed Continuous Queries Ioana Stanoi, George Mihaila of execution time for every incoming data tuple, which leads to an upper bound on the rate at which tuples can

  20. Throughput of proportional fair scheduling over Rayleigh fading channels

    E-Print Network [OSTI]

    Leung, Kin K.

    Throughput of proportional fair scheduling over Rayleigh fading channels E. Liu and K.K. Leung The proportional fair scheduling (PFS) algorithm is implemented in current 3G wireless networks for high data rate of proportional fairness is NP-hard. An analytical expression is obtained to approximate the throughput of PFS

  1. High-Throughput Program for the Discovery of NOx Reduction Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Throughput Program for the Discovery of NOx Reduction Catalysts High-Throughput Program for the Discovery of NOx Reduction Catalysts 2004 Diesel Engine Emissions Reduction...

  2. Hydrothermal corrosion of SiC in LWR coolant environments in...

    Office of Scientific and Technical Information (OSTI)

    Article: Hydrothermal corrosion of SiC in LWR coolant environments in the absence of irradiation Citation Details In-Document Search Title: Hydrothermal corrosion of SiC in LWR...

  3. Distal transport of dissolved hydrothermal iron in the deep South Pacific Ocean

    E-Print Network [OSTI]

    Fitzsimmons, Jessica N.

    Until recently, hydrothermal vents were not considered to be an important source to the marine dissolved Fe (dFe) inventory because hydrothermal Fe was believed to precipitate quantitatively near the vent site. Based on ...

  4. Preservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal Plumes Preservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal Plumes Print Wednesday, 29 April 2009 00:00...

  5. Effects of physical and chemical pretreatments on the crystallinity of bagasse 

    E-Print Network [OSTI]

    Jones, Maxine Janette

    2009-05-15

    to improving product yields. The process uses lime pretreatment, which can be enhanced using new decrystallization pretreatment methods, namely hydrodynamic cavitation and shock tube pretreatment.Previous studies on biomass decrystallization showed an increase...

  6. Formulation, Pretreatment, and Densification Options to Improve Biomass Specifications for Co-Firing High Percentages with Coal

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; J Richard Hess; Richard D. Boardman; Shahab Sokhansanj; Christopher T. Wright; Tyler L. Westover

    2012-06-01

    There is a growing interest internationally to use more biomass for power generation, given the potential for significant environmental benefits and long-term fuel sustainability. However, the use of biomass alone for power generation is subject to serious challenges, such as feedstock supply reliability, quality, and stability, as well as comparative cost, except in situations in which biomass is locally sourced. In most countries, only a limited biomass supply infrastructure exists. Alternatively, co-firing biomass alongwith coal offers several advantages; these include reducing challenges related to biomass quality, buffering the system against insufficient feedstock quantity, and mitigating the costs of adapting existing coal power plants to feed biomass exclusively. There are some technical constraints, such as low heating values, low bulk density, and grindability or size-reduction challenges, as well as higher moisture, volatiles, and ash content, which limit the co-firing ratios in direct and indirect co-firing. To achieve successful co-firing of biomass with coal, biomass feedstock specifications must be established to direct pretreatment options in order to modify biomass materials into a format that is more compatible with coal co-firing. The impacts on particle transport systems, flame stability, pollutant formation, and boiler-tube fouling/corrosion must also be minimized by setting feedstock specifications, which may include developing new feedstock composition by formulation or blending. Some of the issues, like feeding, co-milling, and fouling, can be overcome by pretreatment methods including washing/leaching, steam explosion, hydrothermal carbonization, and torrefaction, and densification methods such as pelletizing and briquetting. Integrating formulation, pretreatment, and densification will help to overcome issues related to physical and chemical composition, storage, and logistics to successfully co-fire higher percentages of biomass ( > 40%) with coal.

  7. Hydro-thermal flow in a rough fracture EC Contract SES6-CT-2003-502706

    E-Print Network [OSTI]

    Toussaint, Renaud

    Hydro-thermal flow in a rough fracture EC Contract SES6-CT-2003-502706 PARTICIPANT ORGANIZATION NAME: CNRS Synthetic 2nd year report Related with Work Package............ HYDRO-THERMAL FLOW in the influence of a realistic geometry of the fracture on its hydro-thermal response. Several studies have

  8. Understanding Substrate Features Influenced by Pretreatments that Limit Biomass Deconstruction by Enzymes

    E-Print Network [OSTI]

    Gao, Xiadi

    2013-01-01

    pretreatment. Energy & Environmental Science 2011, 4:973-pretreatment. Energy & Environmental Science 2011, 4:973-production. Energy & Environmental Science 2011, Pattathil

  9. A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Pre-Treatment Model for Ethanol Production Using a Colorimetric Analysis of Starch Solutions (1 Activity) A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

  10. Anaerobic High-Throughput Cultivation Method for Isolation of Thermophiles Using Biomass-Derived Substrates

    SciTech Connect (OSTI)

    Hamilton-Brehm, Scott; Vishnivetskaya, Tatiana A; Allman, Steve L; Mielenz, Jonathan R; Elkins, James G

    2012-01-01

    Flow cytometry (FCM) techniques have been developed for sorting mesophilic organisms, but the difficulty increases if the target microbes are thermophilic anaerobes. We demonstrate a reliable, high-throughput method of screening thermophilic anaerobic organisms using FCM and 96-well plates for growth on biomass-relevant substrates. The method was tested using the cellulolytic thermophiles Clostridium ther- mocellum (Topt = 55 C), Caldicellulosiruptor obsidiansis (Topt = 78 C) and the fermentative hyperthermo- philes, Pyrococcus furiosus (Topt = 100 C) and Thermotoga maritima (Topt = 80 C). Multi-well plates were incubated at various temperatures for approximately 72 120 h and then tested for growth. Positive growth resulting from single cells sorted into individual wells containing an anaerobic medium was verified by OD600. Depending on the growth substrate, up to 80 % of the wells contained viable cultures, which could be transferred to fresh media. This method was used to isolate thermophilic microbes from Rabbit Creek, Yellowstone National Park (YNP), Wyoming. Substrates for enrichment cultures including crystalline cellulose (Avicel), xylan (from Birchwood), pretreated switchgrass and Populus were used to cultivate organisms that may be of interest to lignocellulosic biofuel production.

  11. Development and optimization of high-throughput zebrafish screening platform

    E-Print Network [OSTI]

    Koo, Bryan Kyo

    2010-01-01

    The high-throughput zebrafish screening platform is a revolutionary tool that enables subcellular precision in vivo whole animal screening of Danio Rerio. It can perform laser surgery and/or imaging in less than twenty ...

  12. High-throughput vertebrate total analysis/screening platform

    E-Print Network [OSTI]

    Chang, Tsung-Yao, Ph. D. Massachusetts Institute of Technology

    2012-01-01

    High-throughput screening (HTS) is seen as one of the most promising technologies to facilitate biomedical studies and pharmaceutical discoveries. Although large varieties of in vitro HTS technologies have opened great ...

  13. Throughput-cost analysis of optical flow switching

    E-Print Network [OSTI]

    Chan, Vincent W. S.

    In this paper, we employ a cost model embodying major sources of capital expenditure (CapEx) to compare the throughput-cost tradeoff offered by optical flow switching to that of more traditional optical network architectures.

  14. Outage-based throughput in wireless packet networks

    E-Print Network [OSTI]

    Win, Moe Z.

    With the increased competition for the electromagnetic spectrum, it is important to characterize the impact of interference in the performance of a wireless packet network, which is traditionally measured by its throughput. ...

  15. New Tools for High Throughput Chemistry and Biology 

    E-Print Network [OSTI]

    Galveia, Luciano Paulo Rosa

    2011-01-01

    New strategies for the high-throughput determination of protease substrate specificity using a dual colour microarray based format with a small library of FRET-based peptides were developed. Integral to this process was ...

  16. Optimization of steam explosion pretreatment. Final report

    SciTech Connect (OSTI)

    Foody, P.

    1980-04-01

    Different operating conditions are required to optimize the yield from each of the various fractions in the substrate. Xylose recovery is maximized at short cooking times whereas maximum lignin recovery requires much longer cooking times. Peak glucose yield and rumen digestibility occur at intermediate times. If process conditions are set for maximum glucose yield we have achieved a yield of 68% of the theoretical, based on an average of a dozen substrates tested. Individual results ranged from 46 to 87%. If the process is optimized for maximum total sugars (i.e. glucose plus xylose) we have obtained an average yield of 60%, with a range of 31 to 75%. With rumen microflora, the average value of the in-vitro cellulose digestibility was 82%, with a range of 41 to 90%. The optimum operating conditions for total sugars are a pressure of 500 to 550 psig with a cooking time of 40 to 50 seconds and 35% starting moisture content. Particle size is not a significant factor, nor is pre-steaming or use of a constricting die in the gun nozzle. High quality lignin can be extracted with 80% yield. The Iotech lignin is very soluble, has a low molecular weight and is reactive. The unique properties of the lignin derive from the explosion at the end of the pretreatment. A lignin formaldehyde resin has been successfully formulated and tested. It represents a high value utilization of the lignin byproduct with immediate market potential. A detailed engineering design of the process gives an estimated operating cost of $7.50/OD ton of biomass. At this low cost, the Iotech process achieves many important pretreatment goals in a single step. The substrate has been sterilized; it has been pulverized into a powder; the cellulose has been accessible; and a highly reactive lignin fraction can be recovered and utilized.

  17. Hydrothermal venting of greenhouse gases triggering Early Jurassic global warming

    E-Print Network [OSTI]

    Svensen, Henrik

    Hydrothermal venting of greenhouse gases triggering Early Jurassic global warming Henrik Svensen a carbon cycle. The event lasted for approximately 200,000 years and was manifested by a global warming, and the Toarcian global warming. © 2007 Elsevier B.V. All rights reserved. Keywords: climate change; Toarcian

  18. Interconnected hydro-thermal systems Models, methods, and applications

    E-Print Network [OSTI]

    Interconnected hydro-thermal systems Models, methods, and applications Magnus Hindsberger Kgs. Lyngby 2003 IMM-PHD-2003-112 Interconnected hydro-thermalsystems #12;Technical University of Denmark 45882673 reception@imm.dtu.dk www.imm.dtu.dk IMM-PHD-2003-112 ISSN 0909-3192 #12;Interconnected hydro

  19. POWER SCHEDULING IN A HYDRO-THERMAL SYSTEM UNDER UNCERTAINTY

    E-Print Network [OSTI]

    Römisch, Werner

    POWER SCHEDULING IN A HYDRO-THERMAL SYSTEM UNDER UNCERTAINTY C.C. Car e1, M.P. Nowak2, W. Romisch2 and pumped-storage hydro units is developed. For its compu- tational solution two di erent decompo- sition-burning) thermal units, pumped-storage hydro plants and delivery con- tracts and describe an optimization model

  20. PROJECT W-551 INTERIM PRETREATMENT SYSTEM PRECONCEPTUAL CANDIDATE TECHNOLOGY DESCRIPTIONS

    SciTech Connect (OSTI)

    MAY TH

    2008-08-12

    The Office of River Protection (ORP) has authorized a study to recommend and select options for interim pretreatment of tank waste and support Waste Treatment Plant (WTP) low activity waste (LAW) operations prior to startup of all the WTP facilities. The Interim Pretreatment System (IPS) is to be a moderately sized system which separates entrained solids and 137Cs from tank waste for an interim time period while WTP high level waste vitrification and pretreatment facilities are completed. This study's objective is to prepare pre-conceptual technology descriptions that expand the technical detail for selected solid and cesium separation technologies. This revision includes information on additional feed tanks.

  1. Preliminary conceptual design for the destruction of organic/ferrocyanide constituents in the Hanford tank waste with low-temperature hydrothermal processing

    SciTech Connect (OSTI)

    Schmidt, A.J.; Jones, E.O.; Orth, R.J.; Cox, J.L.; Elmore, M.E.; Neuenschwander, G.G.; Hart, T.R. [Pacific Northwest Lab., Richland, WA (United States); Meng, C.D. [Westinghouse Hanford Co., Richland, WA (United States)

    1993-05-01

    Hydrothermal processing (HTP) is a thermal-chemical processing method that can be employed to destroy organic and ferrocyanide constituents in Hanford tank waste by using the abundant existing oxidants in the tank waste such as nitrite and nitrate. Use-temperature HTP effectively destroys organics at temperatures from 250{degree}C to 400{degree}C to eliminate safety hazards and improve further processing. This proposal describes a conceptual design of a low-temperature HTP system (including a preliminary flow diagram and plot plan, equipment descriptions and sizes, utility requirements, and costs); the experimental work supporting this effort at Pacific Northwest Laboratory (PNL); the reaction chemistry and kinetics; the technical maturity of the process; and a preliminary assessment of maintenance, operation, and safety of a system. Nitrate destruction using organic reductants is also described. The low-temperature hydrothermal program at PNL was initiated in January 1993. It is part of an overall program to develop organic destruction technologies, which was originally funded by Hanford`s Tank Waste Remediation System program and then was transferred to the Initial Pretreatment (IPM) project. As described in the document, low-temperature HTP (1) meets or exceeds system requirements in organic, ferrocyanide, and nitrate destruction, and processing rate; (2) is technically mature with little additional technology development required; (3) is a simple process with good operational reliability; (4) is flexible and can be easily integrated in the system; (5) has reasonable costs and utility requirements; and (6) is safe and environmentally-benign.

  2. Synthesis and characterization of four new metal 5-phosphonoisophthalates discovered by high-throughput experimentation

    SciTech Connect (OSTI)

    Bauer, Sebastian [Institute of Inorganic Chemistry, Christian-Albrechts-University, Otto-Hahn-Platz 6/7, D 24098 Kiel (Germany); Stock, Norbert [Institute of Inorganic Chemistry, Christian-Albrechts-University, Otto-Hahn-Platz 6/7, D 24098 Kiel (Germany)], E-mail: stock@ac.uni-kiel.de

    2007-11-15

    A new ligand, 5-diethylphosphonoisophthalic acid ((HOOC){sub 2}C{sub 6}H{sub 3}-PO{sub 3}(C{sub 2}H{sub 5}){sub 2}, H{sub 2}Et{sub 2}L), for the hydrothermal synthesis of inorganic-organic hybrid compounds was prepared and characterized by NMR-spectroscopy. Its in situ hydrolysis leads to the corresponding 5-phosphonoisophthalic acid ((HOOC){sub 2}C{sub 6}H{sub 3}-PO{sub 3}H{sub 2}, H{sub 4}L). Applying high-throughput methods, different di- and trivalent metal salts for the synthesis of crystalline metal phosphonates based on H{sub 2}Et{sub 2}L have been screened. From the resulting discovery library, single-crystals of four new compounds, [Sm{sub 2}(H{sub 2}O){sub 4}(H(OOC){sub 2}C{sub 6}H{sub 3}-PO{sub 3}){sub 2}].2H{sub 2}O (1), [Cu{sub 3}(H{sub 2}O)(H(OOC){sub 2}C{sub 6}H{sub 3}-PO{sub 3}){sub 2}].2H{sub 2}O (2), Ca{sub 2}(H{sub 2}O)[H(OOC){sub 2}C{sub 6}H{sub 3}-PO{sub 3}H]{sub 2} (3), and Ba{sub 2}(H{sub 2}O){sub 3}(OOC){sub 2}C{sub 6}H{sub 3}-PO{sub 3} (4), have been isolated. The single-crystal structure determination of the title compounds shows H{sub 4}L to be a versatile ligand, exhibiting different types of coordination modes between the functional groups and the metal ions. A comparison of the structural features of the title compounds shows a varying degree of M-O-M connectivities. Thus, isolated metal-oxygen clusters (compounds 1 and 2), infinite M-O-M chains (compound 3), and infinite M-O-M layers (compound 4) are observed. The title compounds 1, 2, and 3 were further characterized by IR-spectroscopy, TG-, EDX-, and elemental chemical analysis. - Graphical abstract: Applying high-throughput methods, the new ligand 5-diethylphosphonoisophtalic acid, (HOOC){sub 2}C{sub 6}H{sub 3}-PO{sub 3}(C{sub 2}H{sub 5}){sub 2} (H{sub 2}Et{sub 2}L), was reacted with several di- and trivalent metal salts under hydrothermal conditions. Single-crystals of four new inorganic-organic hybrid compounds were isolated from the discovery library. The single-crystal structure analysis shows a varying M-O-M connectivity.

  3. Method and apparatus for gasifying with a fluidized bed gasifier having integrated pretreating facilities

    DOE Patents [OSTI]

    Rice, Louis F. (Arcadia, CA)

    1981-01-01

    An integral gasifier including a pretreater section and a gasifier section separated by a distribution grid is defined by a single vessel. The pretreater section pretreats coal or other carbon-containing material to be gasified to prevent caking and agglomeration of the coal in the gasifier. The level of the coal bed of the pretreater section and thus the holding or residence time in said bed is selectively regulated by the amount of pretreated coal which is lifted up a lift pipe into the gasifier section. Thus, the holding time in the pretreater section can be varied according to the amount of pretreat necessary for the particular coal to be gasified.

  4. Evaluation of High Solids Alkaline Pretreatment of Rice Straw

    E-Print Network [OSTI]

    Cheng, Yu-Shen; Zheng, Yi; Yu, Chao Wei; Dooley, Todd M.; Jenkins, Bryan M.; VanderGheynst, Jean S.

    2010-01-01

    19. Oates, J. A. H. (2007). Lime and Limestone 207–211. 20.1–28. 41. Kim, S. H. (2005). Lime pretreatment and enzymaticunwashed biomass. Keywords Lime . Calcium hydroxide . Sodium

  5. Characterization and Pre-treatment of LLW in Turkey - 12572

    SciTech Connect (OSTI)

    Osmanlioglu, Ahmet Erdal

    2012-07-01

    Pre-treatment of radioactive waste is the first step in waste management program that occurs after waste generation from various applications in Turkey. Pre-treatment and characterization practices are carried out in Radioactive Waste Management Unit (RWMU) at Cekmece Nuclear Research and Training Center (CNRTC) in Istanbul. This facility has been assigned to take all low-level radioactive wastes generated by nuclear applications in Turkey. The wastes are generated from research and nuclear applications mainly in medicine, biology, agriculture, quality control in metal processing and construction industries. These wastes are classified as low- level radioactive wastes. Pre-treatment practices cover several steps. In this paper, main steps of pre-treatment and characterization are presented. Basically these are; collection, segregation, chemical adjustment, size reduction and decontamination operations. (author)

  6. Ammonia fiber explosion (AFEX) pretreatment of municipal solid waste components 

    E-Print Network [OSTI]

    Lundeen, Joseph Eric

    1991-01-01

    AMMONIA FIBER EXPLOSION (AFEX) PRETREATMENT OF MUNICIPAL SOLID WASTE COMPONENTS A Thesis by JOSEPH ERIC LUNDEEN Submitted to the Oflice of Graduate Studies of Texas A&M University in partial fulfdlment of the requirements for the degree... of MASTER OF SCIENCE December 1991 Major Subject: Chemical Engineering AMMONIA FIBER EXPLOSION (AFEX) PRETREATMENT OF MUNICIPAL SOLID WASTE COMPONENTS A Thesis Joseph Eric Lundeen Approved as to style and content by: Mark Hol pie ( tte R. W...

  7. Hydrothermal Processing of Macroalgal Feedstocks in Continuous-Flow Reactors

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Roesijadi, Guritno; Zacher, Alan H.; Magnuson, Jon K.

    2014-02-18

    Wet macroalgal slurries can be converted into a biocrude by hydrothermal liquefaction (HTL). High levels of carbon conversion to gravity-separable oil product were accomplished at relatively low temperature (350 ?C) in a pressurized (sub-critical liquid water) environment (20 MPa). As opposed to earlier work in batch reactors reported by others, direct oil recovery was achieved without the use of a solvent and biomass trace mineral components were removed by processing steps so that they did not cause processing difficulties. In addition, catalytic hydrothermal gasification was effectively applied for HTL byproduct water cleanup and fuel gas production from water soluble organics. As a result, high conversion of macroalgae to liquid and gas fuel products was found with low levels of organic contamination in byproduct water. Both process steps were accomplished in continuous-flow reactor systems such that design data for process scale-up was generated.

  8. Instabilities during liquid migration into superheated hydrothermal systems

    SciTech Connect (OSTI)

    Fitzgerald, Shaun D.; Woods, Andrew W.

    1995-01-26

    Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into fingers.

  9. Hydrothermal synthesis and characterization of zirconia based catalysts

    SciTech Connect (OSTI)

    Caillot, T. Salama, Z.; Chanut, N.; Cadete Santos Aires, F.J.; Bennici, S.; Auroux, A.

    2013-07-15

    In this work, three equimolar mixed oxides ZrO{sub 2}/CeO{sub 2}, ZrO{sub 2}/TiO{sub 2}, ZrO{sub 2}/La{sub 2}O{sub 3} and a reference ZrO{sub 2} have been synthesized by hydrothermal method. The structural and surface properties of these materials have been fully characterized by X-ray diffraction, transmission electron microscopy, surface area measurement, chemical analysis, XPS, infrared spectroscopy after adsorption of pyridine and adsorption microcalorimetry of NH{sub 3} and SO{sub 2} probe molecules. All investigated mixed oxides are amphoteric and possess redox centers on their surface. Moreover, hydrothermal synthesis leads to catalysts with higher surface area and with better acid–base properties than classical coprecipitation method. Both Lewis and Brønsted acid sites are present on the surface of the mixed oxides. Compared to the other samples, the ZrO{sub 2}/TiO{sub 2} material appears to be the best candidate for further application in acid–base catalysis. - Graphical abstract: Mesoporous amorphous phase with a high surface area of titania zirconia mixed oxide obtained by hydrothermal preparation. - Highlights: • Three zirconia based catalysts and a reference were prepared by hydrothermal synthesis. • Mixed oxides present larger surface areas than the reference ZrO{sub 2}. • ZrO{sub 2}/TiO{sub 2} catalyst presents a mesoporous structure with high surface area. • ZrO{sub 2}/TiO{sub 2} catalyst presents simultaneously strong acidic and basic properties.

  10. Hydrothermal Exploration Data Gap Analysis Update | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits the Bill FinancingDepartmentDatabase| Department ofHydropowerHydrothermal

  11. Aqueous geochemistry of the Thermopolis hydrothermal system, southern Bighorn Basin, Wyoming, U.S.A.

    SciTech Connect (OSTI)

    Kaszuba, John P. [Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics; Sims, Kenneth W.W. [Univ. of Wyoming, Laramie, WY (United States). School of Energy Resources; Pluda, Allison R. [Univ. of Wyoming, Laramie, WY (United States). Wyoming High-Precision Isotope Lab.

    2014-03-01

    The Thermopolis hydrothermal system is located in the southern portion of the Bighorn Basin, in and around the town of Thermopolis, Wyoming. It is the largest hydrothermal system in Wyoming outside of Yellowstone National Park. The system includes hot springs, travertine deposits, and thermal wells; published models for the hydrothermal system propose the Owl Creek Mountains as the recharge zone, simple conductive heating at depth, and resurfacing of thermal waters up the Thermopolis Anticline.

  12. Aqueous geochemistry of the Thermopolis hydrothermal system, southern Bighorn Basin, Wyoming, U.S.A.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaszuba, John P.; Sims, Kenneth W.W.; Pluda, Allison R.

    2014-06-01

    The Thermopolis hydrothermal system is located in the southern portion of the Bighorn Basin, in and around the town of Thermopolis, Wyoming. It is the largest hydrothermal system in Wyoming outside of Yellowstone National Park. The system includes hot springs, travertine deposits, and thermal wells; published models for the hydrothermal system propose the Owl Creek Mountains as the recharge zone, simple conductive heating at depth, and resurfacing of thermal waters up the Thermopolis Anticline.

  13. A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrotherm...

    Open Energy Info (EERE)

    Caldera, California Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrothermal...

  14. K-Ar Dates Of Hydrothermal Clays From Core Hole VC-2B, Valles...

    Open Energy Info (EERE)

    However, the range of ages obtained from illites in Permian sands and pebbles and from Precambrian crystalline rocks indicates that Valles hydrothermal activity is overwhelming...

  15. Metatranscriptomics reveal differences in in situ energy and nitrogen metabolism among hydrothermal vent snail symbionts

    E-Print Network [OSTI]

    Sanders, J. G.

    Despite the ubiquity of chemoautotrophic symbioses at hydrothermal vents, our understanding of the influence of environmental chemistry on symbiont metabolism is limited. Transcriptomic analyses are useful for linking ...

  16. Optimizing Throughput and Energy in Online Deadline Scheduling

    E-Print Network [OSTI]

    Wong, Prudence W.H.

    consider a processor that can vary its speed between 0 and a maximum speed T to minimize its energy usage usage. If we ignore energy usage, the best possible online algorithm is 4-competitive on throughput jobs; O(1)-competitive online algorithms with respect to energy usage have been known [Yao et al. 1995

  17. On the Throughput Capacity of Heterogeneous Wireless Networks

    E-Print Network [OSTI]

    Latchman, Haniph A.

    On the Throughput Capacity of Heterogeneous Wireless Networks Pan Li, Member, IEEE, and Yuguang of wireless networks. However, it is commonly assumed that all nodes in the network are identical. The issue of heterogeneous wireless networks with general network settings. Specifically, we consider an extended network

  18. Maximizing Throughput in Wireless Networks with Finite Internal Buffers

    E-Print Network [OSTI]

    Chang, Cheng-Shang

    Maximizing Throughput in Wireless Networks with Finite Internal Buffers Ching-Min Lien, Cheng of a discrete-time wireless network, where only certain sets of links can transmit simultaneously. It is well of the configuration vectors determines the capacity region of the wireless network. In the literature, packet

  19. Understanding TCP Incast Throughput Collapse in Datacenter Networks

    E-Print Network [OSTI]

    Joseph, Anthony D.

    Understanding TCP Incast Throughput Collapse in Datacenter Networks Yanpei Chen, Rean Griffith datacenters support a myriad of services and ap- plications. Companies like Google, Microsoft, Yahoo, and Amazon use datacenters for web search, storage, e-commerce, and large-scale general computations

  20. Storage Performance Virtualization via Throughput and Latency Control

    E-Print Network [OSTI]

    Riska, Alma

    Storage Performance Virtualization via Throughput and Latency Control JIANYONG ZHANG, ANAND storage systems. A consequence of this trend is the need to serve multiple users and/or workloads of the underlying storage system; (2) couple rate and latency allocation in a single scheduler, making them less

  1. FLUID: Improving Throughputs in Enterprise Wireless LANs through Flexible Channelization

    E-Print Network [OSTI]

    Liblit, Ben

    the usefulness of flexible channels in the context of 802.11-based networks. Current 802.11 hardware can provideFLUID: Improving Throughputs in Enterprise Wireless LANs through Flexible Channelization Shravan for designing 802.11 wireless LANs (WLANs) using flexible channelization -- the choice of an appropriate channel

  2. Low inlet gas velocity high throughput biomass gasifier

    SciTech Connect (OSTI)

    Feldmann, Herman F.; Paisley, Mark A.

    1989-01-01

    The present invention discloses a novel method of operating a gasifier for production of fuel gas from carbonaceous fuels. The process disclosed enables operating in an entrained mode using inlet gas velocities of less than 7 feet per second, feedstock throughputs exceeding 4000 lbs/ft.sup.2 -hr, and pressures below 100 psia.

  3. Systematic reconstruction of RNA functional motifs with high throughput microfluidics

    E-Print Network [OSTI]

    Quake, Stephen R.

    Systematic reconstruction of RNA functional motifs with high throughput microfluidics Lance Martin1 Hill, NC 27599 Abstract We present RNA-MITOMI, a microfluidic platform for integrated synthesis microfluidic platform such that the entire RNA library could be simultaneously synthesized and then assayed

  4. Thread Row Buffers: Improving Memory Performance Isolation and Throughput

    E-Print Network [OSTI]

    Tullsen, Dean M.

    and energy efficiency. Furthermore, concurrent execution of applications also has shown the needThread Row Buffers: Improving Memory Performance Isolation and Throughput in Multiprogrammed of performance isolation among threads in the memory controller to enforce a quality of service in virtualized

  5. Access Point Selection for Improving Throughput Fairness in Wireless LANs

    E-Print Network [OSTI]

    Siris, Vasilios A.

    Access Point Selection for Improving Throughput Fairness in Wireless LANs Vasilios A. Siris investigate the problem of access point selection in wireless LANs based on the IEEE 802.11 standard, when solely at the wireless stations, which passively monitor the activity of each access point's channel

  6. Enhanced resolution and throughput of Fresnel incoherent correlation holography (FINCH)

    E-Print Network [OSTI]

    Rosen, Joseph

    Enhanced resolution and throughput of Fresnel incoherent correlation holography (FINCH) using dual Montgomery County Campus, Rockville, Maryland 20850, USA * barakk@ee.bgu.ac.il Abstract: Fresnel incoherent Fresnel holography," Opt. Lett. 32(8), 912­914 (2007). 7. J. Rosen and G. Brooker, "Fluorescence

  7. Reliability and Throughput in Future Automotive Communication Networks

    E-Print Network [OSTI]

    Rajkumar, Ragunathan "Raj"

    Reliability and Throughput in Future Automotive Communication Networks John Liu, Timothy TaltyStar. This action created a new industry called automotive telematics, helping to save lives and providing, the automotive telematics industry has experienced a healthy growth in North America. During the current economic

  8. Dynamic Power Allocation For Maximizing Throughput in Energy Harvesting

    E-Print Network [OSTI]

    Vaze, Rahul

    1 Dynamic Power Allocation For Maximizing Throughput in Energy Harvesting Communication System general case of arbitrarily varying energy arrivals is considered, where neither the future energy arrival strategy that invests available energy uniformly over all remaining slots until the next energy arrival

  9. Methods of pretreating comminuted cellulosic material with carbonate-containing solutions

    DOE Patents [OSTI]

    Francis, Raymond

    2012-11-06

    Methods of pretreating comminuted cellulosic material with an acidic solution and then a carbonate-containing solution to produce a pretreated cellulosic material are provided. The pretreated material may then be further treated in a pulping process, for example, a soda-anthraquinone pulping process, to produce a cellulose pulp. The pretreatment solutions may be extracted from the pretreated cellulose material and selectively re-used, for example, with acid or alkali addition, for the pretreatment solutions. The resulting cellulose pulp is characterized by having reduced lignin content and increased yield compared to prior art treatment processes.

  10. High-Throughput Methodology for Discovery of Metal-Organic Frameworks...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Throughput Methodology for Discovery of Metal-Organic Frameworks with a High Binding Energy (New Joint UC-BerkeleySymyx DoDDLA Project) (presentation) High-Throughput...

  11. Agenda from the U.S. Department of Energy's High Throughput Screening...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from the U.S. Department of Energy's High Throughput Screening of Hydrogen Storage Materials Workshop on June 26, 2007 Agenda from the U.S. Department of Energy's High Throughput...

  12. Wireless Throughput and Energy Efficiency with Random Arrivals and Statistical Queueing Constraints

    E-Print Network [OSTI]

    Gursoy, Mustafa Cenk

    Wireless Throughput and Energy Efficiency with Random Arrivals and Statistical Queueing Constraints Mustafa Ozmen and M. Cenk Gursoy Abstract--Throughput and energy efficiency in fading channels are studied. Throughput is further studied in certain asymptotic regimes. Furthermore, energy efficiency is analyzed

  13. Pre-treating Seed to Enhance Germination of Desert Shrubs

    SciTech Connect (OSTI)

    W. K. Ostler; D. C. Anderson; D. J. Hansen

    2002-06-01

    Creosotebush [Larrea tridentata (D.C.) Cav.] and white bursage [Ambrosia dumosa (A. Gray) W.W. Payne] seeds were subjected to pre-treatments of rinsing and soaking in water and thiourea to enhance germination in laboratory experiments. The effects of darkness, temperature, seed source, and soil moisture were also evaluated in the laboratory. The best pre-treatment from the laboratory experiments, rinsing with water for 36 hours followed by drying, was field-tested at Fort Irwin, California. Two sites and two seeding dates (early March and mid April) were determined for each site. Five mulch treatments (no mulch, straw, gravel, chemical stabilizer, and plastic) were evaluated in combination with the seed pre-treatments. Field emergence was greatly enhanced with the seed pre-treatment for white bursage during the March (18-42% increase in germination) and April seedings (16-23% increase in germination). Creosotebush showed poor germination during March (2-5%) when soil temperatures averaged 15 C, but germination increased during the April trials (6-43%) when soil temperatures averaged 23 C. The seed pre-treatment during the April trials increased germination from 16-23%. The plastic mulch treatment increased germination dramatically during both the March and April trials. The plastic mulch increased soil temperatures (8-10 C)and maintained high humidity during germination. Both the chemical stabilizer and the gravel mulches improved germination over the control while the straw mulch decreased germination. These results suggest that seed pre-treatments combined with irrigation and mulch are effective techniques to establish these two dominant Mojave Desert species from seed.

  14. Products of an Artificially Induced Hydrothermal System at Yucca Mountain

    SciTech Connect (OSTI)

    S. Levy

    2000-08-07

    Studies of mineral deposition in the recent geologic past at Yucca Mountain, Nevada, address competing hypotheses of hydrothermal alteration and deposition from percolating groundwater. The secondary minerals being studied are calcite-opal deposits in fractures and lithophysal cavities of ash-flow tuffs exposed in the Exploratory Studies Facility (ESF), a 7.7-km tunnel excavated by the Yucca Mountain Site Characterization Project within Yucca Mountain. An underground field test in the ESF provided information about the minerals deposited by a short-lived artificial hydrothermal system and an opportunity for comparison of test products with the natural secondary minerals. The heating phase lasted nine months, followed by a nine-month cooling period. Natural pore fluids were the only source of water during the thermal test. Condensation and reflux of water driven away from the heater produced fluid flow in certain fractures and intersecting boreholes. The mineralogic products of the thermal test are calcite-gypsum aggregates of less than 4-micrometer crystals and amorphous silica as glassy scale less than 0.2 mm thick and as mounds of tubules with diameters less than 0.7 micrometers. The minute crystal sizes of calcite and gypsum from the field test are very different from the predominantly coarser calcite crystals (up to cm scale) in natural secondary-mineral deposits at the site. The complex micrometer-scale textures of the amorphous silica differ from the simple forms of opal spherules and coatings in the natural deposits, even though some natural spherules are as small as 1 micrometer. These differences suggest that the natural minerals, especially if they were of hydrothermal origin, may have developed coarser or simpler forms during subsequent episodes of dissolution and redeposition. The presence of gypsum among the test products and its absence from the natural secondary-mineral assemblage may indicate a higher degree of evaporation during the test than during the deposition of natural calcite-opal deposits.

  15. Hydrothermal alteration mineral mapping using hyperspectral imagery in

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam:on Openei | Open Energy InformationHydrothermal

  16. Aalborg Universitet Hydrothermal Processing of Lignin for Bio-Crude Production

    E-Print Network [OSTI]

    Rosendahl, Lasse

    Aalborg Universitet Hydrothermal Processing of Lignin for Bio-Crude Production Grigoras, Ionela.aau.dk on: juli 04, 2015 #12;Hydrothermal Processing of Lignin for Bio-crude Production Ionela F. Grigoras) per day, and with an oil production capacity questioned constantly, together with the increasing CO2

  17. A new hydrothermal scenario for the 2006 Lusi eruption, Indonesia. Insights from gas geochemistry

    E-Print Network [OSTI]

    Mazzini, Adriano

    acquired a wide set of data of molecular and isotopic composition of gas sampled in several Lusi vents, in the surrounding mud volcanoes, in the closest natural gas field (Wunut), and in the hydrothermal ventsA new hydrothermal scenario for the 2006 Lusi eruption, Indonesia. Insights from gas geochemistry

  18. Depth determinations of shallow hydrothermal systems by self-potential and multi-scale wavelet tomography

    E-Print Network [OSTI]

    Williams-Jones, Glyn

    to significantly enhance our ability to locate geothermal systems and monitor active volcanoes. © 2010 Elsevier BDepth determinations of shallow hydrothermal systems by self-potential and multi-scale wavelet studies, the depth of the hydrothermal system is always required, but rarely known via traditional

  19. POWER MANAGEMENT IN A HYDRO-THERMAL SYSTEM UNDER UNCERTAINTY BY LAGRANGIAN

    E-Print Network [OSTI]

    Römisch, Werner

    POWER MANAGEMENT IN A HYDRO-THERMAL SYSTEM UNDER UNCERTAINTY BY LAGRANGIAN RELAXATION NICOLE GR power in a hydro-thermal system under uncertainty in load, inflow to reservoirs and prices for fuel to successive decom- position into single thermal and hydro unit subproblems that are solved by dynamic

  20. Impact-induced hydrothermal activity on early Mars Oleg Abramov and David A. Kring

    E-Print Network [OSTI]

    Abramov, Oleg

    Impact-induced hydrothermal activity on early Mars Oleg Abramov and David A. Kring Lunar time for colonization of impact-induced hydrothermal systems by thermophilic organisms, provided they existed on early Mars. The habitable volume reaches a maximum of 6,000 km3 8,500 years after the impact

  1. Discovery of new hydrothermal vent sites in Branseld Strait, G.P. Klinkhammer aY

    E-Print Network [OSTI]

    Keller, Randall A

    ¨ Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris, France Received 24 January 2001; accepted 1 October 2001 Abstract We carried out a search for hydrothermal vents in the Central Basin of Bransfield Strait of dredges. Hydrothermal plumes over Hook Ridge at the eastern end of the basin are confined to the E ridge

  2. Co-solvent Pretreatment Reduces Costly Enzyme Requirements for High Sugar and Ethanol Yields from

    E-Print Network [OSTI]

    California at Riverside, University of

    Co-solvent Pretreatment Reduces Costly Enzyme Requirements for High Sugar and Ethanol Yields from limits potential sugar yields.[7] Thus, it is desirable We introduce a new pretreatment called co-solvent

  3. Hydrothermal synthesis of hydroxyapatite nanorods using pyridoxal-5?-phosphate as a phosphorus source

    SciTech Connect (OSTI)

    Zhao, Xin-Yu; Zhu, Ying-Jie, E-mail: y.j.zhu@mail.sic.ac.cn; Lu, Bing-Qiang; Chen, Feng; Qi, Chao; Zhao, Jing; Wu, Jin

    2014-07-01

    Graphical abstract: Hydroxyapatite nanorods are synthesized using biocompatible biomolecule pyridoxal-5?-phosphate as a new organic phosphorus source by the hydrothermal method. - Highlights: • Hydrothermal synthesis of hydroxyapatite nanorods is reported. • Biocompatible pyridoxal-5?-phosphate is used as an organic phosphorus source. • This method is simple, surfactant-free and environmentally friendly. - Abstract: Hydroxyapatite nanorods are synthesized by the hydrothermal method using biocompatible biomolecule pyridoxal-5?-phosphate (PLP) as a new organic phosphorus source. In this method, PLP biomolecules are hydrolyzed to produce phosphate ions under hydrothermal conditions, and these phosphate ions react with pre-existing calcium ions to form hydroxyapatite nanorods. The effects of experimental conditions including hydrothermal temperature and time on the morphology and crystal phase of the products are investigated. This method is simple, surfactant-free and environmentally friendly. The products are characterized by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared (FTIR) spectroscopy, and thermogravimetric (TG) analysis.

  4. NREL Breaks New Ground in Plant Pretreatment for Biofuels (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-01-01

    NREL researchers use imaging technologies to broaden knowledge of plant cell wall structures and identify ideal pretreatment of plant material.

  5. BIOETHANOL PRODUCTION FROM WET OXIDSED CORN STOVER USING PRE-TREATED MANURE AS A NUTRIENT SOURCE

    E-Print Network [OSTI]

    and oxygen addition) were also applied for pre-treatment of manure. The manure was blended with water for the production of bioethanol. This pre-treatment method, similar to other hot water pre-treatments, acts, Roskilde, Denmark ABSTRACT: In the present study ethanol was produced from wet oxidised corn stover

  6. High-throughput screening for modulators of cellular contractile force

    E-Print Network [OSTI]

    Park, Chan Young; Tambe, Dhananjay; Chen, Bohao; Lavoie, Tera; Dowell, Maria; Simeonov, Anton; Maloney, David J; Marinkovic, Aleksandar; Tschumperlin, Daniel J; Burger, Stephanie; Frykenberg, Matthew; Butler, James P; Stamer, W Daniel; Johnson, Mark; Solway, Julian; Fredberg, Jeffrey J; Krishnan, Ramaswamy

    2014-01-01

    When cellular contractile forces are central to pathophysiology, these forces comprise a logical target of therapy. Nevertheless, existing high-throughput screens are limited to upstream signaling intermediates with poorly defined relationship to such a physiological endpoint. Using cellular force as the target, here we screened libraries to identify novel drug candidates in the case of human airway smooth muscle cells in the context of asthma, and also in the case of Schlemm's canal endothelial cells in the context of glaucoma. This approach identified several drug candidates for both asthma and glaucoma. We attained rates of 1000 compounds per screening day, thus establishing a force-based cellular platform for high-throughput drug discovery.

  7. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, Robert N. (Allentown, PA)

    1986-01-01

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300.degree. C. before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil.

  8. Effects of catalyst pretreatment for carbon nanotube growth

    E-Print Network [OSTI]

    Morgan, Caitlin D

    2007-01-01

    The effects of pretreatment of iron catalyst for carbon nanotube (CNT) growth was studied. CNTs were grown on Fe/A1203 (1/10 nm) thin-film catalyst deposited on silicon substrates via exposure to C2H4 in a thermal chemical ...

  9. Separations/pretreatment considerations for Hanford privatization phase 2

    SciTech Connect (OSTI)

    Hunt, R.D.; McGinnis, C.P.; Welch, T.D.

    1998-05-01

    The Tank Focus Area is funded to develop, demonstrate, and deploy technologies that will assist in the treatment and closure of its nuclear waste tanks. Pretreatment technologies developed to support the privatization effort by the Department of Energy are reviewed. Advancements in evaporation, solid-liquid separation, sludge treatment, solids controls, sodium management, and radionuclide removal are considered.

  10. Hydro unit commitment in hydro-thermal optimization

    SciTech Connect (OSTI)

    Li, C.; Hsu, E.; Svoboda, A.J.; Tseng, C.; Johnson, R.B. [Pacific Gas and Electric Co., San Francisco, CA (United States)

    1997-05-01

    In this paper the authors develop a model and technique for solving the combined hydro and thermal unit commitment problem, taking into full account the hydro unit dynamic constraints in achieving overall economy of power system operation. The combined hydrothermal unit commitment problem is solved by a decomposition and coordination approach. Thermal unit commitment is solved using a conventional Lagrangian relaxation technique. The hydro system is divided into watersheds, which are further broken down into reservoirs. The watersheds are optimized by Network Flow Programming (NFP). Priority-list-based Dynamic Programming is used to solve the Hydro Unit Commitment (HUC) problem at the reservoir level. A successive approximation method is used for updating the marginal water values (Lagrange multipliers) to improve the hydro unit commitment convergence, due to the large size and multiple couplings of water conservation constraints. The integration of the hydro unit commitment into the existing Hydro-Thermal Optimization (HTO) package greatly improves the quality of its solution in the PG and E power system.

  11. Characterization and catalytic properties of hydrothermally dealuminated MCM-22

    SciTech Connect (OSTI)

    Meriaudeau, P.; Tuan, V.A.; Nghiem, V.T.; Ha, V.T. [IRC/NCRS, Villeurbanne (France)] [IRC/NCRS, Villeurbanne (France); Lefevbre, F. [Univ. Claude Bernard, Villeurbanne (France)] [Univ. Claude Bernard, Villeurbanne (France)

    1999-07-25

    Zeolite MCM-22 was recently patented as a useful catalyst for alkylation and isomerization reactions and for conversion of methanol or olefins to hydrocarbons. MCM-22 has been synthesized and dealuminated by hydrothermal treatments. The resulting solids were characterized by different techniques in order to know how the acid properties of the dealuminated solids were modified. It appears that the number of acid sites was decreased by hydrothermal treatments but the acid strength was not modified. Nondealuminated and dealuminated solids were used in the n-octane hydroconversion. Results suggested that for both types of solids the hydroisomerization is mainly occurring in the 10-membered ring (MR) channels whereas the hydrocracking is mainly coming from acid sites located in 12-membered ring channels. According to the observed distribution of monobranched isomers, MCM-22 shows some ``shape-selective`` character typical of the pentasil family, whereas, according to the absolute yield of isopentane in the hydrocracked products at low hydrocracking conversions, MCM-22 behaves more like a 12 MR zeolite.

  12. Optical Multiplexing for High-Throughput Spectroscopic Analysis. 

    E-Print Network [OSTI]

    Ahmed, Saadiah

    2012-05-03

    in optical biosensor testing as it provides greater throughput and scalability while being an economical and compact solution. v NOMENCLATURE MFPF Multi Frequency Phase Fluorometer MUX Multiplexer LED Light Emitting Diode DIO Digital Input... oxidase in hybrid silicate microsphere that is coated with nanofilm and reference dye (RITC) (Fig. 1) [2]. The phosphorescent dye is excited by a green light from a LED (light emitting diode) to emit luminescence, the intensity of which is dependent...

  13. SAMDI Mass Spectrometry for High Throughput Discovery of Enzyme Function |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis of Protein StructuresMaintenance /

  14. Methods and apparatus for catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

    2012-08-14

    Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  15. Pretreatment Engineering Platform Phase 1 Final Test Report

    SciTech Connect (OSTI)

    Kurath, Dean E.; Hanson, Brady D.; Minette, Michael J.; Baldwin, David L.; Rapko, Brian M.; Mahoney, Lenna A.; Schonewill, Philip P.; Daniel, Richard C.; Eslinger, Paul W.; Huckaby, James L.; Billing, Justin M.; Sundar, Parameshwaran S.; Josephson, Gary B.; Toth, James J.; Yokuda, Satoru T.; Baer, Ellen BK; Barnes, Steven M.; Golovich, Elizabeth C.; Rassat, Scot D.; Brown, Christopher F.; Geeting, John GH; Sevigny, Gary J.; Casella, Amanda J.; Bontha, Jagannadha R.; Aaberg, Rosanne L.; Aker, Pamela M.; Guzman-Leong, Consuelo E.; Kimura, Marcia L.; Sundaram, S. K.; Pires, Richard P.; Wells, Beric E.; Bredt, Ofelia P.

    2009-12-23

    Pacific Northwest National Laboratory (PNNL) was tasked by Bechtel National Inc. (BNI) on the River Protection Project, Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to conduct testing to demonstrate the performance of the WTP Pretreatment Facility (PTF) leaching and ultrafiltration processes at an engineering-scale. In addition to the demonstration, the testing was to address specific technical issues identified in Issue Response Plan for Implementation of External Flowsheet Review Team (EFRT) Recommendations - M12, Undemonstrated Leaching Processes.( ) Testing was conducted in a 1/4.5-scale mock-up of the PTF ultrafiltration system, the Pretreatment Engineering Platform (PEP). Parallel laboratory testing was conducted in various PNNL laboratories to allow direct comparison of process performance at an engineering-scale and a laboratory-scale. This report presents and discusses the results of those tests.

  16. Pretreatment of neutralized cladding removal waste sludge: Status Report

    SciTech Connect (OSTI)

    Lumetta, G J; Swanson, J L

    1993-03-01

    This report describes the status of process development for pretreating Hanford neutralized cladding removal waste (NCRW) sludge, of which [approximately] 3.3 [times] 10[sup 6] L is stored in Tanks 103-AW and 105-AW at the Hanford Site. The initial baseline process chosen for pretreating NCRW sludge is to dissolve the sludge in nitric acid and extract the -transuranic (MU) elements from the dissolved sludge solution with octyl(phenyl)-N,N-diisobutylcarbamoyl methyl phosphine oxide (CNWO). This process converts the NCRW sludge into a relatively large volume of low-level waste (LLW) to be disposed of as grout, leaving only a small volume of high-level waste (HLW) requiring vitrification in the Hanford Waste Vitrification Plant (HWVP).

  17. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, R.N.

    1986-10-14

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

  18. Kinetic Modeling and Assessment of Lime Pretreatment of Poplar Wood 

    E-Print Network [OSTI]

    Sierra Ramirez, Rocio

    2012-02-14

    , industrial, and agricultural). 5. Appropriate selection of feedstock and conversion technology. 6. Improved efficiency of the production technology obtained through intensive research and development. 7. More efficient use of energy, including vehicle...-1 KINETIC MODELING AND ASSESSMENT OF LIME PRETREATMENT OF POPLAR WOOD A Dissertation by ROCIO SIERRA RAMIREZ Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree...

  19. Environmental characterization studies of a high-throughput wood gasifier

    SciTech Connect (OSTI)

    Chang, H.; Niemann, R.C.; Wilzbach, K.E.; Paisley, M.

    1983-01-01

    Potential environmental effects associated with thermochemical biomass gasification have been studied by Argonne National Laboratory in cooperation with Battelle Columbus Laboratories (BCL). A series of samples from the process research unit of an indirectly heated, high-throughput wood gasifier operated by BCL has been analyzed for potentially toxic organic compounds and trace elements. The results indicate that, under the test-run conditions, the gasification of both pine and hardwood is accompanied by the formation of some oil, the heavier fraction of which gives a positive response in the Ames assay for mutagenicity and contains numerous phenols and polycyclic aromatic hydrocarbons, including some carcinogens. The implications of these observations are discussed.

  20. High-throughput sequencing of cytosine methylation in plant DNA

    E-Print Network [OSTI]

    Hardcastle, Thomas J.

    2013-06-07

    . Genome Res 2008, 18(7):1051–1063. 66. Bormann Chung CA, Boyd VL, McKernan KJ, Fu Y, Monighetti C, Peckham HE, Barker M: Whole methylome analysis by ultra-deep sequencing using two-base encoding. PloS One 2010, 5(2):e9320. 67. Ondov BD, Cochran C, Landers... reads. Bioinformatics 2013, 29(2):268–270. 70. Minoche AE, Dohm JC, Himmelbauer H: Evaluation of genomic high-throughput sequencing data generated on Illumina HiSeq and genome analyzer systems. Genome Biol 2011, 12(11):R112. 71. Wang XV, Blades N, Ding J...

  1. Computational Proteomics: High-throughput Analysis for Systems Biology

    SciTech Connect (OSTI)

    Cannon, William R.; Webb-Robertson, Bobbie-Jo M.

    2007-01-03

    High-throughput (HTP) proteomics is a rapidly developing field that offers the global profiling of proteins from a biological system. The HTP technological advances are fueling a revolution in biology, enabling analyses at the scales of entire systems (e.g., whole cells, tumors, or environmental communities). However, simply identifying the proteins in a cell is insufficient for understanding the underlying complexity and operating mechanisms of the overall system. Systems level investigations are relying more and more on computational analyses, especially in the field of proteomics generating large-scale global data.

  2. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast and

  3. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast

  4. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis of Protein Structures Print Scientists have developed a

  5. Description of waste pretreatment and interfacing systems dynamic simulation model

    SciTech Connect (OSTI)

    Garbrick, D.J.; Zimmerman, B.D.

    1995-05-01

    The Waste Pretreatment and Interfacing Systems Dynamic Simulation Model was created to investigate the required pretreatment facility processing rates for both high level and low level waste so that the vitrification of tank waste can be completed according to the milestones defined in the Tri-Party Agreement (TPA). In order to achieve this objective, the processes upstream and downstream of the pretreatment facilities must also be included. The simulation model starts with retrieval of tank waste and ends with vitrification for both low level and high level wastes. This report describes the results of three simulation cases: one based on suggested average facility processing rates, one with facility rates determined so that approximately 6 new DSTs are required, and one with facility rates determined so that approximately no new DSTs are required. It appears, based on the simulation results, that reasonable facility processing rates can be selected so that no new DSTs are required by the TWRS program. However, this conclusion must be viewed with respect to the modeling assumptions, described in detail in the report. Also included in the report, in an appendix, are results of two sensitivity cases: one with glass plant water recycle steams recycled versus not recycled, and one employing the TPA SST retrieval schedule versus a more uniform SST retrieval schedule. Both recycling and retrieval schedule appear to have a significant impact on overall tank usage.

  6. Gasification performance of switchgrass pretreated with torrefaction and densification

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; Various

    2014-08-01

    The purpose of this study was to investigate gasification performance of four switchgrass pretreatments (torrefaction at 230 and 270 °C, densification, and combined torrefaction and densification) and three gasification temperatures (700, 800 and 900 °C). Gasification was performed in a fixed-bed externally heated reactor with air as an oxidizing agent. Switchgrass pretreatment and gasification temperature had significant effects on gasification performance such as gas yields, syngas lower heating value (LHV), and carbon conversion and cold gas efficiencies. With an increase in the gasification temperature, yields of H2 and CO, syngas LHV, and gasifier efficiencies increased whereas CH4, CO2 and N2 yields decreased. Among all switchgrass pretreatments, gasification performance of switchgrass with combined torrefaction and densification was the best followed by that of densified, raw and torrefied switchgrass. Gasification of combined torrefied and densified switchgrass resulted in the highest yields of H2 (0.03 kg/kg biomass) and CO (0.72 kg/kg biomass), highest syngas LHV (5.08 MJ m-3), CCE (92.53%), and CGE (68.40%) at the gasification temperature of 900 °C.

  7. Laboratory and field-based investigations of subsurface geochemical processes in seafloor hydrothermal systems

    E-Print Network [OSTI]

    Reeves, Eoghan

    2010-01-01

    This thesis presents the results of four discrete investigations into processes governing the organic and inorganic chemical composition of seafloor hydrothermal fluids in a variety of geologic settings. Though Chapters 2 ...

  8. Hydrothermal growth of single crystals of the quantum magnets: Clinoatacamite, paratacamite, and herbertsmithite

    E-Print Network [OSTI]

    Müller, Peter

    In this report, we describe crystal growth technology and characterizations of clinoata- camite, paratacamiteHydrothermal growth of single crystals of the quantum magnets: Clinoatacamite, paratacamite and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA 2 Department

  9. Geochemistry of deep-sea hydrothermal vent fluids from the Mid-Cayman Rise, Caribbean Sea

    E-Print Network [OSTI]

    McDermott, Jill Marie

    2015-01-01

    This thesis examines the controls on organic, inorganic, and volatile species distributions in hydrothermal fluids venting at Von Damm and Piccard, two recently discovered vent fields at the ultra slow spreading Mid-Cayman ...

  10. Soft inertial microfluidics for high throughput separation of bacteria from human blood cells

    E-Print Network [OSTI]

    Wu, Zhigang

    2009-01-01

    Soft inertial microfluidics for high throughput separation1 Introduction Microfluidics has gained significant advancesof mammalian cells using microfluidics 3,4 , there have been

  11. Automated MEMS-based Drosophila embryo injection system for high-throughput RNAi screens

    E-Print Network [OSTI]

    Scott, Matthew

    Automated MEMS-based Drosophila embryo injection system for high-throughput RNAi screens Stefan developed an automated system based on microelectromechanical systems (MEMS) injectors for reliable mass

  12. Rare earth oxide fluoride nanoparticles and hydrothermal method for forming nanoparticles

    DOE Patents [OSTI]

    Fulton, John L. (Richland, WA) [Richland, WA; Hoffmann, Markus M. (Richland, WA) [Richland, WA

    2001-11-13

    A hydrothermal method for forming nanoparticles of a rare earth element, oxygen and fluorine has been discovered. Nanoparticles comprising a rare earth element, oxygen and fluorine are also described. These nanoparticles can exhibit excellent refractory properties as well as remarkable stability in hydrothermal conditions. The nanoparticles can exhibit excellent properties for numerous applications including fiber reinforcement of ceramic composites, catalyst supports, and corrosion resistant coatings for high-temperature aqueous solutions.

  13. Rare Earth Oxide Fluoride Nanoparticles And Hydrothermal Method For Forming Nanoparticles

    DOE Patents [OSTI]

    Fulton, John L. (Richland, WA); Hoffmann, Markus M. (Richland, WA)

    2003-12-23

    A hydrothermal method for forming nanoparticles of a rare earth element, oxygen and fluorine has been discovered. Nanoparticles comprising a rare earth element, oxygen and fluorine are also described. These nanoparticles can exhibit excellent refractory properties as well as remarkable stability in hydrothermal conditions. The nanoparticles can exhibit excellent properties for numerous applications including fiber reinforcement of ceramic composites, catalyst supports, and corrosion resistant coatings for high-temperature aqueous solutions.

  14. Possible Origin of Improved High Temperature Performance of Hydrothermally Aged Cu/Beta Zeolite Catalysts

    SciTech Connect (OSTI)

    Peden, Charles HF; Kwak, Ja Hun; Burton, Sarah D.; Tonkyn, Russell G.; Kim, Do Heui; Lee, Jong H.; Jen, H. W.; Cavattaio, Giovanni; Cheng, Yisun; Lambert, Christine

    2012-04-30

    The hydrothermal stability of Cu/beta NH3 SCR catalysts are explored here. In particular, this paper focuses on the interesting ability of this catalyst to maintain and even enhance high-temperature performance for the "standard" SCR reaction after modest (900 °C, 2 hours) hydrothermal aging. Characterization of the fresh and aged catalysts was performed with an aim to identify possible catalytic phases responsible for the enhanced high temperature performance. XRD, TEM and 27Al NMR all showed that the hydrothermally aging conditions used here resulted in almost complete loss of the beta zeolite structure between 1 and 2 hours aging. While the 27Al NMR spectra of 2 and 10 hour hydrothermally-aged catalysts showed significant loss of a peak associated with tetrahedrally-coordinated Al species, no new spectral features were evident. Two model catalysts, suggested by these characterization data as possible mimics of the catalytic phase formed during hydrothermal aging of Cu/beta, were prepared and tested for their performance in the "standard" SCR and NH3 oxidation reactions. The similarity in their reactivity compared to the 2 hour hydrothermally-aged Cu/beta catalyst suggests possible routes for preparing multi-component catalysts that may have wider temperature windows for optimum performance than those provided by current Cu/zeolite catalysts.

  15. How Wood Chip Size Affects Pretreatment Effectiveness of Woody Biomass for Biological Processing

    E-Print Network [OSTI]

    Tam, Jerry

    2013-01-01

    explosion pretreatment of wood: effect of chip size, acid,In: Soltes, E.J. (Ed. ), Wood and Agriculture Residues –D. , Wegener, G. , 1984. Wood: Chemistry, Ultrastructure,

  16. Determination of saccharides and ethanol from biomass conversion using Raman spectroscopy: Effects of pretreatment and enzyme composition

    SciTech Connect (OSTI)

    Shih, Chien-Ju

    2010-05-16

    This dissertation focuses on the development of facile and rapid quantitative Raman spectroscopy measurements for the determination of conversion products in producing bioethanol from corn stover. Raman spectroscopy was chosen to determine glucose, xylose and ethanol in complex hydrolysis and fermentation matrices. Chapter 1 describes the motives and main goals of this work, and includes an introduction to biomass, commonly used pretreatment methods, hydrolysis and fermentation reactions. The principles of Raman spectroscopy, its advantages and applications related to biomass analysis are also illustrated. Chapter 2 and 3 comprise two published or submitted manuscripts, and the thesis concludes with an appendix. In Chapter 2, a Raman spectroscopic protocol is described to study the efficiency of enzymatic hydrolysis of cellulose by measuring the main product in hydrolysate, glucose. Two commonly utilized pretreatment methods were investigated in order to understand their effect on glucose measurements by Raman spectroscopy. Second, a similar method was set up to determine the concentration of ethanol in fermentation broth. Both of these measurements are challenged by the presence of complex matrices. In Chapter 3, a quantitative comparison of pretreatment protocols and the effect of enzyme composition are studied using systematic methods. A multipeak fitting algorithm was developed to analyze spectra of hydrolysate containing two analytes: glucose and xylose. Chapter 4 concludes with a future perspective of this research area. An appendix describes a convenient, rapid spectrophotometric method developed to measure cadmium in water. This method requires relatively low cost instrumentation and can be used in microgravity, such as space shuttles or the International Space Station. This work was performed under the supervision of Professor Marc Porter while at Iowa State University. Research related to producing biofuel from bio-renewable resources, especially bioethanol from biomass, has grown significantly in the past decade due to the high demand and rising costs of fossil fuels. More than 3 percent of the energy consumption in the U.S. is derived from renewable biomass, mostly through industrial heat and steam production by the pulp and paper industry, and electricity generation from municipal solid waste (MSW) and forest industry residues. The utilization of food-based biomass to make fuels has been widely criticized because it may increase food shortages throughout the world and raise the cost of food. Thus, nonfood-based and plentiful lignocellulosic feedstocks, such as corn stover, perennial grass, bagasse, sorghum, wheat/rice straw, herbaceous and woody crops, have great potential to be new bio-renewable sources for energy production. Given that many varieties of biomass are available, there is need for a rapid, simple, high-throughput method to screen the conversion of many plant varieties. The most suitable species for each geographic region must be determined, as well as the optimal stage of harvest, impacts of environmental conditions (temperature, soil, pH, etc.). Various genetically modified plants should be studied in order to establish the desired biomass in bioethanol production. The main screening challenge, however, is the complexity of plant cell wall structures that make reliable and sensitive analysis difficult. To date, one of the most popular methods to produce lignocellulosic ethanol is to perform enzymatic hydrolysis followed by fermentation of the hydrolysate with yeast. There are several vital needs related to the field of chemistry that have been suggested as primary research foci needed to effectively improve lignocellulosic ethanol production. These topics include overcoming the recalcitrance of cellulosic biomass, the pervasiveness of pretreatment, advanced biological processing and better feedstocks. In this thesis, a novel approach using Raman spectroscopy has been developed to address important issues related to bioethanol generation, which will aid the research aimed to solve the topics m

  17. Throughput-Lifetime Tradeoffs in Multihop Wireless Networks under an SINR-based

    E-Print Network [OSTI]

    Rosenberg, Catherine P.

    1 Throughput-Lifetime Tradeoffs in Multihop Wireless Networks under an SINR-based Interference crucial design objectives for a number of multihop wireless network applica- tions. As these two this tradeoff between the network throughput and lifetime, for the case of fixed wireless networks where link

  18. Maximizing Throughput of UAV-Relaying Networks with the Load-Carry-and-Deliver Paradigm

    E-Print Network [OSTI]

    Kung, H. T.

    Maximizing Throughput of UAV-Relaying Networks with the Load-Carry-and-Deliver Paradigm Chen Unmanned Aerial Vehicles (UAVs) to relay messages between two distant ground nodes. For delay-tolerant applications like latency-insensitive bulk data transfer, we seek to maximize throughput by having a UAV load

  19. Throughput Optimal Task Allocation under Thermal Constraints for Multi-core Processors

    E-Print Network [OSTI]

    Chatha, Karam S.

    Throughput Optimal Task Allocation under Thermal Constraints for Multi-core Processors Vinay and thermal hotspots affect the reliability of microprocessors. Temperature is also an important constraint. In this paper, we formulate the problem of throughput-optimal task allocation on thermally constrained multi

  20. Delay and throughput analysis of tree algorithms for random access over noisy collision channels

    E-Print Network [OSTI]

    /FS was also combined with the binary exponential backoff (BEB) algorithm in [5] in an 802.16 setting of the BEB algorithm. Furthermore, [5] also indicated that the saturation throughput of SICTA/FS degrades quickly as the number of users increases, while BEB-SICTA/FS still achieves high throughputs

  1. CONTINUOUS ROLL-TO-ROLL SERPENTINE DEPOSITION FOR HIGH THROUGHPUT a-Si PV MANUFACTURING

    E-Print Network [OSTI]

    Deng, Xunming

    CONTINUOUS ROLL-TO-ROLL SERPENTINE DEPOSITION FOR HIGH THROUGHPUT a-Si PV MANUFACTURING M. Izu, H. When this technique is incorporated into a continuous roll- to-roll PV manufacturing process a number of advantages in a fully automated high throughput PV module production plant [l-18

  2. Improving Bounds on the Football Pool Problem via Symmetry Reduction and High-Throughput Computing

    E-Print Network [OSTI]

    Linderoth, Jeffrey T.

    Improving Bounds on the Football Pool Problem via Symmetry Reduction and High-Throughput Computing of Wisconsin-Madison, 1210 W. Dayton St., Madison, WI 53706, USA, gthain@cs.wisc.edu The Football Pool Problem theory. Key words: Football Pool Problem; High-Throughput Computing; Branch-and-Bound; Con- dor; Master

  3. A Switch-Based Approach to Throughput Collapse and Starvation in Data Centers Alexander Shpiner

    E-Print Network [OSTI]

    Keslassy, Isaac

    A Switch-Based Approach to Throughput Collapse and Starvation in Data Centers Alexander Shpiner on small switch buffers. However, in case of congestion, data center switches may suffer from throughput link. Last, HCF also prevents packet reordering. Key words: TCP, Data centers, Switching. 1

  4. A Switch-Based Approach to Throughput Collapse and Starvation in Data Centers

    E-Print Network [OSTI]

    Keslassy, Isaac

    A Switch-Based Approach to Throughput Collapse and Starvation in Data Centers Alexander Shpiner, 32000, Israel {shalex@tx, isaac@ee}.technion.ac.il Abstract--Data center switches need to satisfy, in case of congestion, data center switches can incur throughput collapse for short TCP flows as well

  5. Opal: A Multi-radio Platform for High Throughput Wireless Sensor Networks

    E-Print Network [OSTI]

    Langendoen, Koen

    1 Opal: A Multi-radio Platform for High Throughput Wireless Sensor Networks Raja Jurdak, Kevin requirements. This letter presents the design of the versatile Opal platform that couples a Cortex M3 MCU sacrificing communication range. We present experiments that evaluate Opal's throughput and range when

  6. HPAZ: a High-throughput Pipeline Architecture of ZUC in Zongbin Liu1

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    HPAZ: a High-throughput Pipeline Architecture of ZUC in Hardware Zongbin Liu1 , Neng Gao1 , Jiwu@ist.psu.edu Abstract. In this paper, we propose a high-throughput pipeline architecture of the stream cipher ZUC which significantly reduces operating frequency. In this paper we design a mixed two-stage pipeline architecture which

  7. Assessing the Thermoelectric Properties of Sintered Compounds via High-Throughput Ab-Initio Calculations

    E-Print Network [OSTI]

    Curtarolo, Stefano

    Assessing the Thermoelectric Properties of Sintered Compounds via High-Throughput Ab Database have been considered as nanograined, sintered-powder thermoelectrics with the high-throughput ab the electronic band gap and the carrier effective mass, and that the probability of having large thermoelectric

  8. Final Report - "Foaming and Antifoaming and Gas Entrainment in Radioactive Waste Pretreatment and Immobilization Processes"

    SciTech Connect (OSTI)

    Wasan, Darsh T.

    2007-10-09

    The Savannah River Site (SRS) and Hanford site are in the process of stabilizing millions of gallons of radioactive waste slurries remaining from production of nuclear materials for the Department of Energy (DOE). The Defense Waste Processing Facility (DWPF) at SRS is currently vitrifying the waste in borosilicate glass, while the facilities at the Hanford site are in the construction phase. Both processes utilize slurry-fed joule-heated melters to vitrify the waste slurries. The DWPF has experienced difficulty during operations. The cause of the operational problems has been attributed to foaming, gas entrainment and the rheological properties of the process slurries. The rheological properties of the waste slurries limit the total solids content that can be processed by the remote equipment during the pretreatment and meter feed processes. Highly viscous material can lead to air entrainment during agitation and difficulties with pump operations. Excessive foaming in waste evaporators can cause carryover of radionuclides and non-radioactive waste to the condensate system. Experimental and theoretical investigations of the surface phenomena, suspension rheology and bubble generation of interactions that lead to foaming and air entrainment problems in the DOE High Level and Low Activity Radioactive Waste separation and immobilization processes were pursued under this project. The first major task accomplished in the grant proposal involved development of a theoretical model of the phenomenon of foaming in a three-phase gas-liquid-solid slurry system. This work was presented in a recently completed Ph.D. thesis (9). The second major task involved the investigation of the inter-particle interaction and microstructure formation in a model slurry by the batch sedimentation method. Both experiments and modeling studies were carried out. The results were presented in a recently completed Ph.D. thesis. The third task involved the use of laser confocal microscopy to study the effectiveness of three slurry rheology modifiers. An effective modifier was identified which resulted in lowering the yield stress of the waste simulant. Therefore, the results of this research have led to the basic understanding of the foaming/antifoaming mechanism in waste slurries as well as identification of a rheology modifier, which enhances the processing throughput, and accelerates the DOE mission. The objectives of this research effort were to develop a fundamental understanding of the physico-chemical mechanisms that produced foaming and air entrainment in the DOE High Level (HLW) and Low Activity (LAW) radioactive waste separation and immobilization processes, and to develop and test advanced antifoam/defoaming/rheology modifier agents. Antifoams/rheology modifiers developed from this research ere tested using non-radioactive simulants of the radioactive wastes obtained from Hanford and the Savannah River Site (SRS).

  9. Caustic-Side Solvent-Extraction Modeling for Hanford Interim Pretreatment System

    SciTech Connect (OSTI)

    Moyer, B.A.; Birdwell, J.F.; Delmau, L. H.; McFarlane, J.

    2008-06-01

    The purpose of this work is to examine the applicability of the Caustic-Side Solvent Extraction (CSSX) process for the removal of cesium from Hanford tank-waste supernatant solutions in support of the Hanford Interim Pretreatment System (IPS). The Hanford waste types are more challenging than those at the Savannah River Site (SRS) in that they contain significantly higher levels of potassium, the chief competing ion in the extraction of cesium. It was confirmed by use of the CSSX model that the higher levels of potassium depress the cesium distribution ratio (DCs), as validated by measurement of DCs values for four of eight specified Hanford waste-simulant compositions. The model predictions were good to an apparent standard error of ±11%. It is concluded from batch distribution experiments, physical-property measurements, equilibrium modeling, flowsheet calculations, and contactor sizing that the CSSX process as currently employed for cesium removal from alkaline salt waste at the SRS is capable of treating similar Hanford tank feeds. For the most challenging waste composition, 41 stages would be required to provide a cesium decontamination factor (DF) of 5000 and a concentration factor (CF) of 5. Commercial contacting equipment with rotor diameters of 10 in. for extraction and 5 in. for stripping should have the capacity to meet throughput requirements, but testing will be required to confirm that the needed efficiency and hydraulic performance are actually obtainable. Markedly improved flowsheet performance was calculated for a new solvent formulation employing the more soluble cesium extractant BEHBCalixC6 used with alternative scrub and strip solutions, respectively 0.1 M NaOH and 10 mM boric acid. The improved system can meet minimum requirements (DF = 5000 and CF = 5) with 17 stages or more ambitious goals (DF = 40,000 and CF = 15) with 19 stages. Potential benefits of further research and development are identified that would lead to reduced costs, greater adaptability of the process to DOE alkaline salt wastes, and greater readiness for implementation. Such benefits accrue from optimal sizing of centrifugal contactors for application of the CSSX process for the IPS; more accurate modeling of cesium extraction with greater flexibility and applicability to a variety of feeds and flowsheet conditions; and further improving and optimizing the alternative CSSX solvent and scrub/strip system.

  10. Pretreated densified biomass products (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding accessusers'(x≤2) surface:SciTechinvestigation (JournalPretreated

  11. Waste Treatment and Immobilation Plant Pretreatment Facility | Department

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'S FUTURE. regulators consumerWaste Isolationof Energy Pretreatment

  12. Access of Cellulase to Cellulose and Lignin for Poplar Solids Produced by Leading Pretreatment Technologies

    E-Print Network [OSTI]

    California at Riverside, University of

    Access of Cellulase to Cellulose and Lignin for Poplar Solids Produced by Leading Pretreatment. From this, Langmuir adsorption parameters, cellulose accessibility to cellulase, and the effectiveness (rsolids ¼ 56 mg/g solid). Lime pretreated sol- ids also had the highest cellulose accessibility

  13. PROJECT W-551 INTERIM PRETREATMENT SYSTEM TECHNOLOGY SELECTION SUMMARY DECISION REPORT AND RECOMMENDATION

    SciTech Connect (OSTI)

    CONRAD EA

    2008-08-12

    This report provides the conclusions of the tank farm interim pretreatment technology decision process. It documents the methodology, data, and results of the selection of cross-flow filtration and ion exchange technologies for implementation in project W-551, Interim Pretreatment System. This selection resulted from the evaluation of specific scope criteria using quantitative and qualitative analyses, group workshops, and technical expert personnel.

  14. Impact of Velocity on Corn Stover Pretreatment 977 Applied Biochemistry and Biotechnology Vol. 113116, 2004

    E-Print Network [OSTI]

    California at Riverside, University of

    with velocity, especially in the early reaction stage, suggests that chemical reaction is not the only factorImpact of Velocity on Corn Stover Pretreatment 977 Applied Biochemistry and Biotechnology Vol. 113 Velocity on Hot Water Only Pretreatment of Corn Stover in a Flowthrough Reactor CHAOGANG LIU AND CHARLES E

  15. Shaping Reactor Microbiomes to Produce the Fuel Precursor nButyrate from Pretreated Cellulosic Hydrolysates

    E-Print Network [OSTI]

    Angenent, Lars T.

    - butyrate production rate of 0.47 g COD l-1 d-1 in bioreactors that were fed with dilute-acid pretreatedShaping Reactor Microbiomes to Produce the Fuel Precursor nButyrate from Pretreated Cellulosic the production of carboxylic acids with open cultures of microbial consortia (reactor micro- biomes), we

  16. Benefit-cost analysis of DOE's Current Federal Program to increase hydrothermal resource utilization. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-12-10

    The impact of DOE's Current Federal Program on the commercialization of hydrothermal resources between 1980 and 2000 is analyzed. The hydrothermal resources of the United States and the types of DOE activities used to stimulate the development of these resources for both electric power and direct heat use are described briefly. The No Federal Program and the Current Federal Program are then described in terms of funding levels and the resultant market penetration estimates through 2000. These market penetration estimates are also compared to other geothermal utilization forecasts. The direct benefits of the Current Federal Program are next presented for electric power and direct heat use applications. An analysis of the external impacts associated with the additional hydrothermal resource development resulting from the Current Federal Program is also provided. Included are environmental effects, national security/balance-of-payments improvements, socioeconomic impacts and materials requirements. A summary of the analysis integrating the direct benefits, external impacts and DOE program costs concludes the report.

  17. Physical properties of upper oceanic crust: Ocean Drilling Program Hole 801C and the waning of hydrothermal circulation

    E-Print Network [OSTI]

    Abrams, Lewis J.

    alteration continues, at a decreasing rate, throughout the lifetime of oceanic crust. INDEX TERMS: 3015 Marine Geology and Geophysics: Heat flow (benthic) and hydrothermal processes; 7220 Seismology: Oceanic, decreased porosity and permeability, and oxidation of magnetic minerals [e.g., Jacobson, 1992]. Hydrothermal

  18. Process Design and Economics for the Conversion of Algal Biomass to Hydrocarbons: Whole Algae Hydrothermal Liquefaction and Upgrading

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Anderson, Daniel B.; Hallen, Richard T.; Elliott, Douglas C.; Schmidt, Andrew J.; Albrecht, Karl O.; Hart, Todd R.; Butcher, Mark G.; Drennan, Corinne; Snowden-Swan, Lesley J.; Davis, Ryan; Kinchin, Christopher

    2014-03-20

    This report provides a preliminary analysis of the costs associated with converting whole wet algal biomass into primarily diesel fuel. Hydrothermal liquefaction converts the whole algae into an oil that is then hydrotreated and distilled. The secondary aqueous product containing significant organic material is converted to a medium btu gas via catalytic hydrothermal gasification.

  19. Effects of pretreatment in steam on the pyrolysis behavior of Loy Yang brown coal

    SciTech Connect (OSTI)

    Cai Zeng; George Favas; Hongwei Wu; Alan L. Chaffee; Jun-ichiro Hayashi; Chun-Zhu Li [Monash University, Vic. (Australia). CRC for Clean Power from Lignite, Department of Chemical Engineering

    2006-02-01

    Dewatering/drying of Victorian brown coal will be an integral part of future brown coal utilization processes aimed at the reduction of greenhouse gas emissions. This study aims to investigate the effects of the thermal pretreatment of brown coal in the presence of steam/water on its subsequent pyrolysis behavior. A Victorian (Loy Yang) brown coal was thermally pretreated in pressurized steam and inert atmospheres. The pyrolysis behavior of these pretreated coal samples was investigated in a wire-mesh reactor. While the pretreatment in steam at temperatures higher than 250{sup o}C increased the char yield of the steam-treated coal, it did not affect the overall pyrolysis char yield at 1000{sup o} C s{sup -1} if the weight loss during the pretreatment in steam was also considered. However, the tar yield decreased significantly after the pretreatment in the presence of steam. The UV-fluorescence spectroscopy of tars revealed that the release of large aromatic systems from the steam-treated coal was only affected by the pretreatment in steam if the treatment temperature was very high (e.g. 350{sup o}C). The loss of NaCl and the use of high pressure during the pretreatment of brown coal in steam were not the main reasons for the changes in the observed tar yield. The hydrolysis of O-containing structures such as ethers, esters, and carboxylates during the pretreatment in the presence of steam plays an important role in the fates of these O-containing structures during pretreatment and subsequent pyrolysis, leading to changes in the pyrolysis behavior of the brown coal. 36 refs., 8 figs.

  20. Hydrothermal formation of Clay-Carbonate alteration assemblages in the Nili Fossae region of Mars

    E-Print Network [OSTI]

    Brown, Adrian J; Baldridge, Alice M; Crowley, James K; Bridges, Nathan T; Thomson, Bradley J; Marion, Giles M; Filho, Carlos R de Souza; Bishop, Janice L

    2014-01-01

    The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) has returned observations of the Nili Fossae region indicating the presence of Mg- carbonate in small (characterize these carbonate-bearing units. We applied absorption band mapping techniques to investigate a range of possible phyllosilicate and carbonate minerals that could be present in the Nili Fossae region. We also describe a clay-carbonate hydrothermal alteration mineral assemblage in the Archean Warrawoona Group of Western Australia that is a potential Earth analog to the Nili Fossae carbonate-bearing rock units. We discuss the geological and biological implications for hydrothermal processes on Noachian Mars.

  1. Enhanced performance of wearable piezoelectric nanogenerator fabricated by two-step hydrothermal process

    SciTech Connect (OSTI)

    Qiu, Yu; Lei, Jixue; Yin, Bing; Zhang, Heqiu; Ji, Jiuyu; Hu, Lizhong, E-mail: lizhongh@dlut.edu.cn [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); The Key Laboratory for Micro/Nano Technology and System of Liaoning Province, Dalian University of Technology, Dalian 116024 (China); Yang, Dechao [Department of Electronic Engineering, Dalian Neusoft University of Information, Dalian 116024 (China); Bian, Jiming; Liu, Yanhong; Zhao, Yu; Luo, Yingmin [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-03-17

    A simple two-step hydrothermal process was proposed for enhancing the performance of the nanogenerator on flexible and wearable terylene-fabric substrate. With this method, a significant enhancement in output voltage of the nanogenerator from ?10?mV to 7?V was achieved, comparing with the one by conventional one-step process. In addition, another advantage with the devices synthesized by two-step hydrothermal process was that their output voltages are only sensitive to strain rather than strain rate. The devices with a high output voltage have the ability to power common electric devices and will have important applications in flexible electronics and wearable devices.

  2. Low inlet gas velocity high throughput biomass gasifier

    SciTech Connect (OSTI)

    Feldmann, H.F.; Paisley, M.A.

    1989-05-09

    A method is described for operating a gasifier which comprises: introducing inlet gas at a velocity of about 0.5 to 7 ft/sec to fluidize a bed in a gasifier vessel; forming the bed into a fluidized bed in a first space region by means of the inlet gas, the fluidized bed containing a circulating hot relatively fine and inert solid bed particle component; inputting and throughputting carbonaceous material into and through the first space region with fluidized bed at a rate from 500-4400 lbs/ft/sup 2/-hr; endothermally pyrolyzing the carbonaceous material by means of the circulating hot inert particle component so as to form a product gas; forming contiguous to and above the fluidized bed a lower average density entrained space region containing an entrained mixture of inert solid particles, char, and carbonaceous material and the product gas; gradually and continuously removing the entrained mixture and the product gas from the lower average density entrained space region of the gasifier to a separator, residence time of the carbonaceous material in the gasifier not exceeding 3 minutes on average; separating the entrained mixture from the product gas; passing the entrained mixture containing inert solid particles, char, and carbonaceous material through an exothermic reaction zone to add heat; and returning at least the inert solid particles to the first space region.

  3. The Materials genome : rapid materials screening for renewable energy using high-throughput density functional theory

    E-Print Network [OSTI]

    Jain, Anubhav, Ph.D. Massachusetts Institute of Technology

    2011-01-01

    This thesis relates to the emerging field of high-throughput density functional theory (DFT) computation for materials design and optimization. Although highthroughput DFT is a promising new method for materials discovery, ...

  4. Molecular display of synthetic oligonucleotide libraries and their analysis with high throughput DNA sequencing

    E-Print Network [OSTI]

    Larman, Harry Benjamin

    2012-01-01

    High throughput methods in molecular biology have changed the landscape of biomedical research. In particular, advances in massively parallel DNA sequencing and synthesis technologies are defining our genomes and the ...

  5. CellVisualizer : exploring hierarchical, multi-dimensional data with applications to high-throughput microscopy

    E-Print Network [OSTI]

    Kang, InHan

    2006-01-01

    In this thesis, we present a system for visualizing hierarchical, multi-dimensional, memory-intensive datasets. Specifically, we designed an interactive system to visualize data collected by high-throughput microscopy and ...

  6. Cell bioprinting as a potential high-throughput method for fabricating cell-based biosensors (CBBs)

    E-Print Network [OSTI]

    Xu, F.

    Cell-based biosensors (CBBs) are becoming an important tool for biosecurity applications and rapid diagnostics. For current CBBs technology, cell immobilization and high throughput fabrication are the main challenges. To ...

  7. Infrastructure to support ultra high throughput biodosimetry screening after a radiological event

    E-Print Network [OSTI]

    Brenner, David Jonathan

    GUY GARTY1 , ANDREW KARAM2 , & DAVID J. BRENNER3 1 Radiological Research Accelerator Facility, Radiological Research Accelerator Facility, Nevis Laboratories, Columbia UniverInfrastructure to support ultra high throughput biodosimetry screening after a radiological event

  8. Engineering a single cell microarray platform for high throughput DNA damage and repair analysis

    E-Print Network [OSTI]

    Weingeist, David McGregor

    2012-01-01

    DNA damage contributes to cancer, aging, and heritable diseases. Ironically, DNA damaging agents are also commonly used in current cancer treatment. We therefore need robust, high throughput, and inexpensive tools for ...

  9. An instrument for high-throughput measurements of fiber mechanical properties

    E-Print Network [OSTI]

    Kristofek, Grant William, 1980-

    2005-01-01

    In this thesis, an instrument is designed and constructed for the purpose of measuring the mechanical properties of single fibers. The instrument is intended to provide high throughput measurement of single fiber geometric ...

  10. Stochastic Forecasts Achieve High Throughput and Low Delay over Cellular Networks

    E-Print Network [OSTI]

    Massachusetts Institute of Technology. Computer Science and Artificial Intelligence Laboratory; Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science; Balakrishnan, Hari; Winstein, Keith J.; Sivaraman Kaushalram, Anirudh; Balakrishnan, Hari

    Sprout is an end-to-end transport protocol for interactive applications that desire high throughput and low delay. Sprout works well over cellular wireless networks, where link speeds change dramatically with time, and ...

  11. Software for supporting large scale data processing for High Throughput Screening

    E-Print Network [OSTI]

    Tai, David

    2011-12-31

    High Throughput Screening for is a valuable data generation technique for data driven knowledge discovery. Because the rate of data generation is so great, it is a challenge to cope with the demands of post experiment data analysis. This thesis...

  12. Asymptotic Throughput of the FED-STD-1052 Data Link Protocol Eric E. Johnson

    E-Print Network [OSTI]

    Johnson, Eric E.

    Asymptotic Throughput of the FED-STD-1052 Data Link Protocol Eric E. Johnson New Mexico State. · Diurnal and seasonal variations in usable channels from hour to hour and day to day. · Solar cycle effects

  13. Inertio-elastic focusing of bioparticles in microchannels at high throughput

    E-Print Network [OSTI]

    Lim, Eugene J.

    Controlled manipulation of particles from very large volumes of fluid at high throughput is critical for many biomedical, environmental and industrial applications. One promising approach is to use microfluidic technologies ...

  14. A microfluidic device for high throughput bacterial biofilm studies Jeongyun Kim,a

    E-Print Network [OSTI]

    Wood, Thomas K.

    A microfluidic device for high throughput bacterial biofilm studies Jeongyun Kim,a Manjunath Hegde of biofilm community formation. Here, we describe the development of a PDMS-based two-layer microfluidic flow

  15. SAMNet: a network-based approach to integrate multi-dimensional high throughput datasets

    E-Print Network [OSTI]

    Spencer, Sarah J.

    The rapid development of high throughput biotechnologies has led to an onslaught of data describing genetic perturbations and changes in mRNA and protein levels in the cell. Because each assay provides a one-dimensional ...

  16. Beyond Proportional Fairness: A Resource Biasing Framework for Shaping Throughput Profiles in

    E-Print Network [OSTI]

    Belding-Royer, Elizabeth M.

    Beyond Proportional Fairness: A Resource Biasing Framework for Shaping Throughput Profiles of resources. While proportional fair allocation provides a significant improvement, we point out here connections than max-min fair or proportional fair resource allocations, with minimal impact

  17. Throughput Performance of Quantized Proportional Fair Scheduling with Adaptive Modulation and

    E-Print Network [OSTI]

    Ishizaki, Fumio

    Throughput Performance of Quantized Proportional Fair Scheduling with Adaptive Modulation where QPF (Quantized Proportional Fair) scheduling and AMC (adaptive modulation and coding) scheme condition [11]. To solve this unfair problem, the proportional fair (PF) scheduling was proposed where

  18. Methods and technologies for high-throughput and high-content small animal screening

    E-Print Network [OSTI]

    Rohde, Christopher, 1979-

    2012-01-01

    High-throughput and high-content screening (HTS and HCS) of whole animals requires their immobilization for high-resolution imaging and manipulation. Here we present methods to enable HTS and HCS of the nematode Caenorhabditis ...

  19. Attendees list from the U.S. Department of Energy's High Throughput...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Attendees list from the U.S. Department of Energy's High Throughput Screening of Hydrogen Storage Materials Workshop on June 26, 2007 Attendees list from the U.S. Department of...

  20. A microfabricated platform for high-throughput unconfined compression of micropatterned biomaterial arrays

    E-Print Network [OSTI]

    Sun, Yu

    A microfabricated platform for high-throughput unconfined compression of micropatterned biomaterial8, Canada b Institute of Biomaterials and Biomedical Engineering, University of Toronto, 164 College 16 September 2009 Available online 9 October 2009 Keywords: Hydrogel Micropatterning Biomaterial

  1. Throughput Optimal Scheduling in the Presence of Heavy-Tailed Traffic

    E-Print Network [OSTI]

    Jagannathan, Krishna Prasanna

    We investigate the tail behavior of the steady-state queue occupancies under throughput optimal scheduling in the presence of heavy-tailed traffic. We consider a system consisting of two parallel queues, served by a single ...

  2. First principles high throughput screening of oxynitrides for water-splitting photocatalysts

    E-Print Network [OSTI]

    Wu, Yabi

    2013-01-01

    In this paper, we present a first principles high throughput screening system to search for new water-splitting photocatalysts. We use the approach to screen through nitrides and oxynitrides. Most of the known photocatalytic ...

  3. Map Task Scheduling in MapReduce with Data Locality: Throughput and Heavy-Traffic Optimality

    E-Print Network [OSTI]

    Zhang, Junshan

    is throughput optimal and the outer bound coincides with the actual capacity region. Further, we study in a distributed and parallel fashion, and has been widely used in practice, including Google, Yahoo!, Facebook

  4. Development of High-Throughput Microfluidic Impedance Spectroscopy Platform for Analyzing Microdroplets in Droplet Microfluidic System 

    E-Print Network [OSTI]

    Sobahi, Nebras MohammedKamal A.

    2014-07-22

    This thesis presents the development of a high-throughput microfluidic impedance spectroscopy platform for electrically detecting analyzing impedance measurements of non-contact and label free microdroplets. This microfluidic impedance spectroscopy...

  5. Influence of mechanical-biological waste pre-treatment methods on the gas formation in landfills

    SciTech Connect (OSTI)

    Bockreis, A. [Technische Universitaet Darmstadt, Darmstadt University of Technology, Institute for Water Supply and Groundwater Protection, Wastewater Technology, Waste Management, Industrial Material Flows and Environmental Planning (Institute WAR), Chair of Waste Management and Waste Technology, Darmstadt (Germany)]. E-mail: a.bockreis@iwar.tu-darmstadt.de; Steinberg, I. [Technische Universitaet Darmstadt, Darmstadt University of Technology, Institute for Water Supply and Groundwater Protection, Wastewater Technology, Waste Management, Industrial Material Flows and Environmental Planning (Institute WAR), Chair of Waste Management and Waste Technology, Darmstadt (Germany)

    2005-07-01

    In order to minimise emissions and environmental impacts, only pre-treated waste should be disposed of. For the last six years, a series of continuous experiments has been conducted at the Institute WAR, TU Darmstadt, in order to determine the emissions from pre-treated waste. Different kinds of pre-treated waste were incubated in several reactors and various data, including production and composition of the gas and the leachate, were collected. In this paper, the interim results of gas production and the gas composition from different types of waste after a running time of six years are presented and discussed.

  6. Carbon geochemistry of serpentinites in the Lost City Hydrothermal System (30N, MAR)

    E-Print Network [OSTI]

    Gilli, Adrian

    Massif (Mid-Atlantic Ridge, 30°N) was exam- ined to characterize carbon sources and speciation in oceanic. The speciation of carbon de- pends on the chemical and physical conditions prevailing in the reservoir, and itsCarbon geochemistry of serpentinites in the Lost City Hydrothermal System (30°N, MAR) Ade

  7. Improvement of Hydrothermal Stability of Mesoporous Silica Using Salts: Reinvestigation for Time-Dependent Effects

    E-Print Network [OSTI]

    Kim, Ji Man

    compounds with aqueous solutions of hydrogen peroxide.5 However, the structure of the TiMCM-41 is reported and Center for Molecular Science, Korea AdVanced Institute of Science and Technology, Taejon 305-701, Korea of hydrothermal stability of mesoporous silica using salts solutions (Ryoo, R.; Jun, S. J. Phys. Chem. B 1997, 101

  8. Hydrothermal changes related to earthquake activity at Mud Volcano, Yellowstone National Park, Wyoming

    SciTech Connect (OSTI)

    Pitt, A.M.; Hutchinson, R.A.

    1982-04-10

    The Mud Volcano hydrothermal area in Yellowstone National Park is near the intersection of a 20-km-long zone of northeast trending normal faults with the eastern resurgent dome within the 600,000-year-odd Yellowstone caldera. Recent crustal uplift along the northeast trending axis of the caldera is at a maximum (700 mm since 1923) near the Mud Volcano area. From 1973 through April 1978, less than 10 earthquakes (largest M 2.4) were located within 3 km of the Mud Volcano area. In May 1978, earthquakes began occurring beneath the hydrothermal area at depths of 1 to 5 km. The seismic activity continued until the end of November with intense swarms (100 events per hour) occurring on October 23 and November 7. The largest event (M 3.1) occured on November 14 and at least 8 events were M 2.5 or larger. In December 1978, heat flux in the Mud Volcano hydrothermal features began increasing along a 2-km-long northeast trending zone. Existing mud cauldrons became more active, new mud cauldrons and fumeroles were formed, and vegetation (primarily lodgepole pine) was killed by increased soil temperature. The increase in heat flux continued through July 1979 then gradually declined, reaching the early 1978 level by June 1980. The spatial and temporal association of earthquakes and increased hydrothermal activity at Mud Volcano suggests that the seismic activity expanded preexisting fracture systems, premitting increased fluid flow from depths of several kilometers.

  9. Hydrothermal method of synthesis of rare-earth tantalates and niobates

    SciTech Connect (OSTI)

    Nyman, May D; Rohwer, Lauren E.S.; Martin, James E

    2012-10-16

    A hydrothermal method of synthesis of a family of rare-earth Group 5 oxides, where the Group 5 oxide is a niobate or tantalate. The rare-earth Group 5 oxides can be doped with suitable emitter ions to form nanophosphors.

  10. Textured catalysts, methods of making textured catalysts, and methods of catalyzing reactions conducted in hydrothermal conditions

    DOE Patents [OSTI]

    Werpy, Todd [West Richland, WA; Wang, Yong [Richland, WA

    2003-12-30

    A textured catalyst having a hydrothermally-stable support, a metal oxide and a catalyst component is described. Methods of conducting aqueous phase reactions that are catalyzed by a textured catalyst are also described. The invention also provides methods of making textured catalysts and methods of making chemical products using a textured catalyst.

  11. Silicic magma petrogenesis in Iceland by remelting of hydrothermally altered crust based on oxygen isotope diversity

    E-Print Network [OSTI]

    Bindeman, Ilya N.

    Silicic magma petrogenesis in Iceland by remelting of hydrothermally altered crust based on oxygen, University of Iceland, 101 Reykjavik, Iceland; 6 Laboratoire Magmas et Volcans, CNRS-Universite´ Blaise rocks (e.g. Gillis and Coogan, 2002; Jonasson, 2007; Wanless et al., 2010). Iceland represents the only

  12. Synthesis of ZrO{sub 2} nanoparticles by hydrothermal treatment

    SciTech Connect (OSTI)

    Machmudah, Siti Widiyastuti, W. Prastuti, Okky Putri Nurtono, Tantular Winardi, Sugeng; Wahyudiono,; Kanda, Hideki; Goto, Motonobu

    2014-02-24

    Zirconium oxide (zirconia, ZrO{sub 2}) is the most common material used for electrolyte of solid oxide fuel cells (SOFCs). Zirconia has attracted attention for applications in optical coatings, buffer layers for growing superconductors, thermal-shield, corrosion resistant coatings, ionic conductors, and oxygen sensors, and for potential applications including transparent optical devices and electrochemical capacitor electrodes, fuel cells, catalysts, and advanced ceramics. In this work, zirconia particles were synthesized from ZrCl{sub 4} precursor with hydrothermal treatment in a batch reactor. Hydrothermal treatment may allow obtaining nanoparticles and sintered materials with controlled chemical and structural characteristics. Hydrothermal treatment was carried out at temperatures of 150 – 200°C with precursor concentration of 0.1 – 0.5 M. Zirconia particles obtained from this treatment were analyzed by using SEM, PSD and XRD to characterize the morphology, particle size distribution, and crystallinity, respectively. Based on the analysis, the size of zirconia particles were around 200 nm and it became smaller with decreasing precursor concentration. The increasing temperature caused the particles formed having uniform size. Zirconia particles formed by hydrothermal treatment were monoclinic, tetragonal and cubic crystal.

  13. PRIMAL AND DUAL METHODS FOR UNIT COMMITMENT IN A HYDRO-THERMAL POWER SYSTEM

    E-Print Network [OSTI]

    Römisch, Werner

    PRIMAL AND DUAL METHODS FOR UNIT COMMITMENT IN A HYDRO-THERMAL POWER SYSTEM R. Gollmer1 , A. Moller comprising thermal and pumped-storage hydro units a large-scale mixed-integer optimization model is developed hydro units. The variable ut i 2 f0;1g; i = 1;:::;I;t = 1;:::;T indicates whether the thermal unit i

  14. Chemical structure and properties of low-rank coals treated by hydrothermal process

    SciTech Connect (OSTI)

    Ohki, A.; Xie, X.F.; Nakajima, Tsunenori; Maeda, Shigeru [Kagoshima Univ., Korimoto, Kagoshima (Japan). Dept. of Applied Chemistry and Chemical Engineering

    1998-12-31

    Several methods for upgrading low-rank coals, in which the hygroscopicity is irreversibly reduced into a level for high-rank coals, have been developed. A hydrothermal treatment of coal, such as hot water drying (HWD), is one of the most promising upgrading methods. The HWD method involves a treatment of low-rank coals under high temperature (300-350 C) and high pressure (80-180 kg/cm{sup 2}). Two low-rank coals, Loy Yang coal and Yallourn coal were hydrothermally treated at 150--350 C. The chemical structure and properties of these treated coals have been examined. The analysis of coal includes hygroscopicity, elemental analysis, the content of oxygenic functional groups measured by chemical analysis, FTIR analysis, CP/MAS {sup 13}C NMR analysis, specific surface area, maceral composition, and vitrinite reflectance. When the low-rank coals are hydrothermally treated, the hygroscopicity of coal remarkably decreases. The content of carboxyl group in coal greatly decreases as heat treatment temperature (HTT) is raised. The difference in carboxyl group content in the 350 C-treated coal between from the chemical analysis and from {sup 13}C NMR and FTIR analyses is explained. From these results, the change in chemical structure and properties of coal during the hydrothermal treatment is discussed.

  15. Effect of Acid, Alkali, and Steam Explosion Pretreatments on Characteristics of Bio-Oil Produced from Pinewood

    SciTech Connect (OSTI)

    Wang, Hui; Srinivasan, Radhakrishnan; Yu, Fei; Steele, Philip; Li, Qi; Mitchell, Brian

    2011-06-21

    Bio-oil produced from pinewood by fast pyrolysis has the potential to be a valuable substitute for fossil fuels. Pretreatment prior to the fast pyrolysis process has been shown to alter the structure and chemical composition of biomass. To determine the influence of biomass pretreatments on bio-oil produced during fast pyrolysis, we tested three pretreatment methods: dilute acid, dilute alkali, and steam explosion. Bio-oils were produced from untreated and pretreated pinewood feedstocks in an auger reactor at 450 C. The bio-oils�¢���� physical properties including pH, water content, acid value, density, viscosity, and heating value were measured. Chemical characteristics of the bio-oils were determined by gas chromatographymass spectrometry. Results showed that bio-oil yield and composition were influenced by biomass pretreatment. Of the three pretreatment methods, 1%H2SO4 pretreatment resulted in the highest bio-oil yield and best bio-oil quality.

  16. Supply of geothermal power from hydrothermal sources: A study of the cost of power in 20 and 40 years

    SciTech Connect (OSTI)

    Petty, S. (Petty (Susan) Consulting, Solano Beach, CA (United States)); Livesay, B.J. (Livesay Consultants, Inc., Encinitas, CA (United States)); Long, W.P. (Carlin Gold Co., Inc., Grass Valley, CA (United States)); Geyer, J. (Geyer (John) and Associates, Vancouver, WA (United States))

    1992-11-01

    This study develops estimates for the amount of hydrothermal geothermal power that could be on line in 20 and 40 years. This study was intended to represent a snapshot'' in 20 and 40 years of the hydrothermal energy available for electric power production should a market exist for this power. This does not represent the total or maximum amount of hydrothermal power, but is instead an attempt to estimate the rate at which power could be on line constrained by the exploration, development and support infrastructure available to the geothermal industry, but not constrained by the potential market for power.

  17. Computer simulation and economic analysis for ammonia fiber explosion (AFEX) pretreatment process 

    E-Print Network [OSTI]

    Wang, Lin

    1996-01-01

    The ammonia fiber explosion (AFFECT) process is a promising new pretreatment for enhancing the reactivity of lignocerulose materials with many advantages over existing processes. The material is soaked in high-pressure ...

  18. A Pre-treatment Model for Ethanol Production Using a Colorimetric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Pre-treatment Model for Ethanol Production Using a Colorimetric Analysis of Starch Solutions AUTHORS: Eric Benson and Chris Ederer E-mail Addresses: eric.benson@theloganschool.o...

  19. Chars produced by slow pyrolysis and hydrothermal carbonization vary in carbon sequestration potential and greenhouse gases emissions

    E-Print Network [OSTI]

    Malghani, S; Malghani, S; Gleixner, G; Trumbore, SE

    2013-01-01

    of slow and fast pyrolysis biochar on soil C and N turnoverpyrolysis and hydrothermal carbonisation of corn stover. Soilmatter. Slow pyrolysis char is more stable in soil and had

  20. Geochemical tracers of processes affecting the formation of seafloor hydrothermal fluids and deposits in the Manus back-arc basin

    E-Print Network [OSTI]

    Craddock, Paul R

    2009-01-01

    Systematic differences in trace element compositions (rare earth element (REE), heavy metal, metalloid concentrations) of seafloor vent fluids and related deposits from hydrothermal systems in the Manus back-arc basin ...

  1. Biotic and abiotic interactions of deep-sea hydrothermal vent-endemic fish on the East Pacific Rise

    E-Print Network [OSTI]

    Buckman, Kate Lynn

    2009-01-01

    A study of the ecology of fish endemic to hydrothermal vents on the East Pacific Rise was undertaken utilizing a variety of techniques, focusing on the bythitid Thermichthys hollisi. Stable isotope and gut content analyses ...

  2. Spatial and temporal population genetics at deep-sea hydrothermal vents along the East Pacific Rise and Galápagos Rift

    E-Print Network [OSTI]

    Fusaro, Abigail Jean

    2008-01-01

    Ecological processes at deep-sea hydrothermal vents on fast-spreading mid-ocean ridges are punctuated by frequent physical disturbance. Larval dispersal among disjunct vent sites facilitates the persistence of sessile ...

  3. Chars produced by slow pyrolysis and hydrothermal carbonization vary in carbon sequestration potential and greenhouse gases emissions

    E-Print Network [OSTI]

    Malghani, S; Gleixner, G; Trumbore, SE

    2013-01-01

    of biochar from fast pyrolysis and gasi?cation systems.Effects of slow and fast pyrolysis biochar on soil C and Ncarbonaceous products obtained by pyrolysis and hydrothermal

  4. Sonochemical and hydrothermal synthesis of PbTe nanostructures with the aid of a novel capping agent

    SciTech Connect (OSTI)

    Fard-Fini, Shahla Ahmadian; Salavati-Niasari, Masoud; Mohandes, Fatemeh

    2013-10-15

    Graphical abstract: - Highlights: • PbTe nanostructures were prepared with the aid of Schiff-base compound. • Sonochemical and hydrothermal methods were employed to fabricate PbTe nanostrucrues. • The effect of preparation parameters on the morphology of PbTe was investigated. - Abstract: In this work, a new Schiff-base compound derived from 1,8-diamino-3,6-dioxaoctane and 2-hydroxy-1-naphthaldehyde marked as (2-HyNa)-(DaDo) was synthesized, characterized, and then used as capping agent for the preparation of PbTe nanostructures. To fabricate PbTe nanostructures, two different synthesis methods; hydrothermal and sonochemical routes, were applied. To further investigate, the effect of preparation parameters like reaction time and temperature in hydrothermal synthesis and sonication time in the presence of ultrasound irradiation on the morphology and purity of the final products was tested. The products were analyzed with the aid of SEM, TEM, XRD, FT-IR, and EDS. Based on the obtained results, it was found that pure cubic phased PbTe nanostructures have been obtained by hydrothermal and sonochemical approaches. Besides, SEM images showed that cubic-like and rod-like PbTe nanostructures have been formed by hydrothermal and sonochemical methods, respectively. Sonochemical synthesis of PbTe nanostructures was favorable, because the synthesis time of sonochemical method was shorter than that of hydrothermal method.

  5. Hydrothermal synthesis, characterization and up/down-conversion luminescence of barium rare earth fluoride nanocrystals

    SciTech Connect (OSTI)

    Jia, Li-Ping; Zhang, Qiang [Department of Chemistry, Tongji University, Shanghai 200092 (China); State Key Laboratory of Pollution Control and Resource Reuse (Tongji University) (China); Yan, Bing, E-mail: byan@tongji.edu.cn [Department of Chemistry, Tongji University, Shanghai 200092 (China); State Key Laboratory of Pollution Control and Resource Reuse (Tongji University) (China)

    2014-07-01

    Graphical abstract: Lanthanide ions doped bare earth rare earth fluoride nanocrystals are synthesized by hydrothermal technology and characterized. The down/up-conversion luminescence of them are discussed. - Highlights: • Mixed hydrothermal system H{sub 2}O–OA (EDA)–O-A(LO-A) is used for synthesis. • Barium rare earth fluoride nanocrystals are synthesized comprehensively. • Luminescence for down-conversion and up-conversion are obtained for these systems. - Abstract: Mixed hydrothermal system H{sub 2}O–OA (EDA)–O-A(LO-A) is developed to synthesize barium rare earth fluorides nanocrystals (OA = oleylamine, EDA = ethylenediamine, O-A = oleic acid and LO-A = linoleic acid). They are presented as BaREF{sub 5} (RE = Ce, Pr, Nd, Eu, Gd, Tb, Dy, Y, Tm, Lu) and Ba{sub 2}REF{sub 7} (RE = La, Sm, Ho, Er, Yb). The influence of reaction parameters (rare earth species, hydrothermal system and temperature) is checked on the phase and shape evolution of the fluoride nanocrystals. It is found that reaction time and temperature of these nanocrystals using EDA (180 °C, 6 h) is lower than those of them using OA (220 °C, 10 h). The photoluminescence properties of these fluorides activated by some rare earth ions (Nd{sup 3+}, Eu{sup 3+}, Tb{sup 3+}) are studied, and especially up-conversion luminescence of the four fluoride nanocrystal systems (Ba{sub 2}LaF{sub 7}:Yb, Tm(Er), Ba{sub 2}REF{sub 7}:Yb, Tm(Er) (RE = Gd, Y, Lu)) is observed.

  6. Numerical-Model Investigation of the Hydrothermal Regime of a Straight-Through Shallow Cooling Pond

    SciTech Connect (OSTI)

    Sokolov, A. S. [JSC 'VNIIG im. B. E. Vedeneeva' (Russian Federation)] [JSC 'VNIIG im. B. E. Vedeneeva' (Russian Federation)

    2013-11-15

    A mathematic model based on solution of hydrodynamics and heat-transfer equations by the finite-element method is constructed to predict the hydrothermal regime of a straight-through shallow cooling pond, which provides cooling circulating water to a repository of spent nuclear fuel. Numerical experiments made it possible to evaluate the influence exerted by wind conditions and flow rate of water in the river on the temperature of the circulating water.

  7. Solion ion source for high-efficiency, high-throughput solar cell manufacturing

    SciTech Connect (OSTI)

    Koo, John Binns, Brant; Miller, Timothy; Krause, Stephen; Skinner, Wesley; Mullin, James

    2014-02-15

    In this paper, we introduce the Solion ion source for high-throughput solar cell doping. As the source power is increased to enable higher throughput, negative effects degrade the lifetime of the plasma chamber and the extraction electrodes. In order to improve efficiency, we have explored a wide range of electron energies and determined the conditions which best suit production. To extend the lifetime of the source we have developed an in situ cleaning method using only existing hardware. With these combinations, source life-times of >200 h for phosphorous and >100 h for boron ion beams have been achieved while maintaining 1100 cell-per-hour production.

  8. Short-time hydrothermal synthesis and delamination of ion exchangeable Mg/Ga layered double hydroxides

    SciTech Connect (OSTI)

    Unal, Ugur [Department of Nano Science and Technology, Faculty of Engineering, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555 (Japan)], E-mail: ugurunal@chem.kumamoto-u.ac.jp

    2007-09-15

    The hydrothermal synthesis of magnesium-gallium layered double hydroxides (Mg/Ga LDHs) was studied under static and agitated conditions. Not only well-crystallized and large-sized Mg/Ga LDHs having hexagonal morphology were obtained but also the reaction time was comparatively decreased from 24 to 2 h by means of agitation during hydrothermal synthesis. In static conditions, mainly GaOOH and magnesite phases were formed. The elemental analysis results show that the final Mg/Ga ratio is significantly different from the initial ratio. The reason was attributed to the difference in the hydrolytic behavior of Mg{sup 2+} and Ga{sup 3+}. Furthermore, the anion exchange studies with glycine, dodecyl sulfate, ferrocyanide and ferricyanide were performed to investigate the intercalation behavior of the anions into Mg/Ga LDHs. In addition, delamination of Mg/Ga LDHs was performed in formamide for the glycine exchanged forms. Large size of nanosheets thus obtained can be utilized in the fabrication of functional thin films. - Graphical abstract: Hydrothermal synthesis under agitation resulted in highly crystalline Mg/Ga LDHs slabs in a short time. The LDHs slabs were delaminated into two-dimensional nanosize sheets.

  9. Hydrothermally altered and fractured granite as an HDR reservoir in the EPS-1 borehole, Alsace,

    SciTech Connect (OSTI)

    Genter, A.; Traineau, H.

    1992-01-01

    As part of the European Hot Dry Rocks Project, a second exploration borehole, EPS-1, has been cored to a depth of 2227 m at Soultz-sous-Forets (France). The target was a granite beginning at 1417 m depth, overlain by post-Paleozoic sedimentary cover. Structural analysis and petrographic examination of the 800-m porphyritic granite core, have shown that this rock has undergone several periods of hydrothermal alteration and fracturing. More than 3000 natural structures were recorded, whose distribution pattern shows clusters where low-density fracture zones (less than 1 per meter) alternate with zones of high fracture density (more than 20 per meter). Vein alteration, ascribed to paleohydrothermal systems, developed within the hydrothermally altered and highly fractured zones, transforming primary biotite and plagioclase into clay minerals. One of these zones at 2.2 km depth produced a hot-water outflow during coring, indicating the existence of a hydrothermal reservoir. Its permeability is provided by the fracture network and by secondary porosity of the granitic matrix resulting from vein alteration. This dual porosity in the HDR granite reservoir must be taken into account in the design of the heat exchanger, both for modeling the water-rock interactions and for hydraulic testing.

  10. Effect of pelleting on the recalcitrance and bioconversion of dilute-acid pretreated corn stover

    SciTech Connect (OSTI)

    Allison E Ray; Amber Hoover; Gary Gresham

    2012-07-01

    Background: Knowledge regarding the performance of densified biomass in biochemical processes is limited. The effects of densification on biochemical conversion are explored here. Methods: Pelleted corn stover samples were generated from bales that were milled to 6.35 mm. Low-solids acid pretreatment and simultaneous saccharification and fermentation were performed to evaluate pretreatment efficacy and ethanol yields achieved for pelleted and ground stover (6.35 mm and 2 mm) samples. Both pelleted and 6.35-mm ground stover were evaluated using a ZipperClave® reactor under high-solids, process-relevant conditions for multiple pretreatment severities (Ro), followed by enzymatic hydrolysis of the washed, pretreated solids. Results: Monomeric xylose yields were significantly higher for pellets (approximately 60%) than for ground formats (approximately 38%). Pellets achieved approximately 84% of theoretical ethanol yield (TEY); ground stover formats had similar profiles, reaching approximately 68% TEY. Pelleting corn stover was not detrimental to pretreatment efficacy for both low- and high-solids conditions, and even enhanced ethanol yields.

  11. nAture methods | VOL.12 NO.1 | JANUARY2015 | 71 high-throughput methods based on chromosome conformation

    E-Print Network [OSTI]

    Cai, Long

    that of hi-c. coupling this method with dnA-capture technology provides a high-throughput approachArticles nAture methods | VOL.12 NO.1 | JANUARY2015 | 71 high-throughput methods based for targeted mapping of fine-scale chromatin architecture. We applied targeted dnase hi-c to characterize the 3

  12. MEMORY SUB-BANKING SCHEME FOR HIGH THROUGHPUT TURBO DECODER Mayank Tiwari, Yuming Zhu and Chaitali Chakrabarti

    E-Print Network [OSTI]

    Kambhampati, Subbarao

    level are needed in order to design low-power high- throughput Turbo decoders for mobile systems, the sliding win- dow (SW) approach has been proposed as an effective means of reduc- ing the decoding delay-banked implemen- tation of the SW-based approach that achieves high throughput, low decoding latency and reduced

  13. Evaluation of high throughput screening methods in picking up differences between cultivars of

    E-Print Network [OSTI]

    California at Riverside, University of

    Sciences, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark c National Renewable Energy Laboratory, Riverside, 2) National Renewable Energy Laboratory (NREL), Colorado, and 3) University of Copenhagen (CPH of combined eco- nomic benefits of higher yields at milder pretreatment condi- tions and lower enzyme dosages

  14. Two-Dimensional Coordination Polymers with One-Dimensional Magnetic Chains: Hydrothermal Synthesis, Crystal Structure, and Magnetic and Thermal Properties of

    E-Print Network [OSTI]

    Li, Jing

    commonly employed in the synthesis of numerous solid-state inorganic materials. ComparablyTwo-Dimensional Coordination Polymers with One-Dimensional Magnetic Chains: Hydrothermal Synthesis

  15. Optical microplates for high-throughput screening of photosynthesis in lipid-producing algae{,

    E-Print Network [OSTI]

    Basu, Amar S.

    Optical microplates for high-throughput screening of photosynthesis in lipid- producing algae-producing algae of interest in 2nd generation biofuels. By conducting 96 experiments in parallel, photoirradiance the study of photosynthesis in algae. Societal challenges in energy sustainability have renewed interest

  16. High-throughput two-hybrid analysis The promise and the peril

    E-Print Network [OSTI]

    Dunham, Maitreya

    , reduction in reagent costs and further refinements of the approach. As throughput escalates, so does use. The first stage is the initial description of a method: the prototype version. Typically. For a large fraction of new technologies, few other examples beyond this proto- type are ever described

  17. Accounting for Memory Use, Cost, Throughput, and Latency in the Design of a Media Server

    E-Print Network [OSTI]

    Chang, Edward Y.

    : the per­stream costs and the worst­case initial latency before a new media request can be satisfied. WeAccounting for Memory Use, Cost, Throughput, and Latency in the Design of a Media Server Edward scheduling and data place­ ment ones. We show that, some disk latency reduction techniques can

  18. UFlood: High-Throughput Flooding over Wireless Mesh Networks Jayashree Subramanian, Robert Morris, and Hari Balakrishnan

    E-Print Network [OSTI]

    UFlood: High-Throughput Flooding over Wireless Mesh Networks Jayashree Subramanian, Robert Morris--This paper proposes UFlood, a flooding protocol for wireless mesh networks. UFlood targets situations of completion of a flood to the slowest receiving node and total time spent transmitting. The key to achieving

  19. User, Robot and Automation Evaluations in High-Throughput Biological Screening Processes

    E-Print Network [OSTI]

    Kaber, David B.

    User, Robot and Automation Evaluations in High-Throughput Biological Screening Processes Noa Segall Cognitive Ergonomics Laboratory North Carolina State University Raleigh, NC +1 (919) 513-4494 nsegall@ncsu.edu Rebecca S. Green Cognitive Ergonomics Laboratory North Carolina State University Raleigh, NC +1 (919) 513

  20. Parboil: A Revised Benchmark Suite for Scientific and Commercial Throughput Computing

    E-Print Network [OSTI]

    Hwu, Wen-mei W.

    are presented as challenges to the compiler and architecture research communities: to develop the technology Technical Report IMPACT-12-01 University of Illinois at Urbana-Champaign Center for Reliable and High computing applications useful for studying the performance of throughput computing architecture

  1. Distributed Throughput Optimization for ZigBee Cluster-Tree Networks

    E-Print Network [OSTI]

    Zhuang, Weihua

    1 Distributed Throughput Optimization for ZigBee Cluster-Tree Networks Yu-Kai Huang§, Ai-Chun Pang connectivity in inexpensive, portable, and mobile devices. Among the well-known ZigBee topologies, ZigBee will be generated. However, the restricted routing of a ZigBee cluster- tree network may not be able to provide

  2. Achieving High Throughput Ground-to-UAV Transport via Parallel Links

    E-Print Network [OSTI]

    Kung, H. T.

    Achieving High Throughput Ground-to-UAV Transport via Parallel Links Chit-Kwan Lin, H. T. Kung in unmanned aerial vehicle (UAV) applications, is a challenge due to varying channel quality and extended link diversity; 802.11; link layer; transport layer; UAV; network coding I. INTRODUCTION In this paper, we focus

  3. SCHEDULING ABOVE MAC TO MAXIMIZE BATTERY LIFETIME AND THROUGHPUT IN WLANS

    E-Print Network [OSTI]

    Simunic, Tajana

    SCHEDULING ABOVE MAC TO MAXIMIZE BATTERY LIFETIME AND THROUGHPUT IN WLANS Edoardo Regini, Daeseob Diego La Jolla, CA 92093 {eregini, dalim, tajana}@ucsd.edu ABSTRACT Maximizing battery lifetime. This is because in heavy traffic conditions, the chance of nodes to successfully transmit a packet decreases

  4. Droplet microfluidic technology for single-cell high-throughput screening

    E-Print Network [OSTI]

    Higgins, Darren

    , Lexington, MA 02421; and bGenetics Department, Harvard Medical School and cHoward Hughes Medical Institute oil and enables the digital manipulation of these reactors at a very high-throughput. Here, we by an immiscible oil. The advantages of this droplet- based technique include the physical and chemical isolation

  5. Comparison of High-Throughput Electrochemical Methods for Testing Direct Methanol Fuel Cell Anode Electrocatalysts

    E-Print Network [OSTI]

    power applications, fuel cells must compete with commodity power sources such as fossil fuels power sources, and mobile/portable applications, fuel cells that utilize liquid fuels can representComparison of High-Throughput Electrochemical Methods for Testing Direct Methanol Fuel Cell Anode

  6. Stealthy Traffic Analysis of Low-Latency Anonymous Communication Using Throughput Fingerprinting

    E-Print Network [OSTI]

    Singh, Jaswinder Pal

    such as Tor aim to enable users to com- municate in a manner that is untraceable by adversaries that control this leaks in- formation about the set of Tor relays in a circuit (path). We present attacks that, with high the bottleneck relay of any Tor circuit whose throughput can be observed, (b) exactly identify the guard relay

  7. A Dynamic Frame Sizing Algorithm for CICQ Switches with 100% Throughput

    E-Print Network [OSTI]

    Chang, Cheng-Shang

    A Dynamic Frame Sizing Algorithm for CICQ Switches with 100% Throughput Cheng-Shang Chang, Yu@ee.nthu.edu.tw lds@cs.nthu.edu.tw Abstract--A Combined Input and Crosspoint Queueing (CICQ) switch is a switch that has both buffers at the crosspoints of the switch fabric and buffers at the inputs. Inspired

  8. Dispatching Equal-length Jobs to Parallel Machines to Maximize Throughput

    E-Print Network [OSTI]

    Bunde, David

    models. Immediate dispatching is a natural model, for example when distributing incoming requestsDispatching Equal-length Jobs to Parallel Machines to Maximize Throughput David P. Bunde1 and a scheduler's goal is to maximize the number of completed jobs (Pm | rj, pj = p | P 1 - Uj). This problem has

  9. Dispatching Equal-length Jobs to Parallel Machines to Maximize Throughput

    E-Print Network [OSTI]

    Goldwasser, Michael

    Dispatching Equal-length Jobs to Parallel Machines to Maximize Throughput David P. Bunde1 and deadlines and a scheduler's goal is to maximize the number of completed jobs (Pm | rj, pj = p | P 1 - Uj dispatching is motivated by multiprocessor settings where incoming requests to a server farm or computer

  10. Knife-Edge Scanning Microscopy: High-throughput Imaging and Analysis of

    E-Print Network [OSTI]

    Choe, Yoonsuck

    : High-throughput Imaging and Analysis of Massive Volumes of Biological Microstructures Author 1 Yoonsuck Choe Author 1 - Address Department of Computer Science, Texas A&M Univ. 3112 TAMU, College Station, TX, 77843-3112, USA Author 1 - Email choe@tamu.edu Author 1 - Tel +1 979 845 5466 Author 2 Louise C. Abbott

  11. Grid Portal Interface for Interactive Use and Monitoring of High-Throughput Proteome

    E-Print Network [OSTI]

    Bourne, Philip E.

    Grid Portal Interface for Interactive Use and Monitoring of High-Throughput Proteome Annotation, #12;54 A. Shahab et al. portal solution for grid computing in life sciences under the auspices, and the use of a GridSpeed [6] generated iGAP application portal are described. The portal solution was part

  12. S-box pipelining using genetic algorithms for high-throughput AES implementations: How

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    S-box pipelining using genetic algorithms for high-throughput AES implementations: How fast can we. In this manuscript, we explore how Genetic Algorithms (GAs) can be used for pipelining the AES substitution box based the implementation area [5,6]. However, when considering fast hardware implementations, pipelining is an obvious

  13. Channel state-Adaptive techniques for Throughput Enhancement in Wireless Broadband Networks

    E-Print Network [OSTI]

    Koutsopoulos, Iordanis

    techniques is required. In this paper, we investigate the problem of enhancing channel throughput the modulation level and transmission power, based on instantaneous channel quality. Our algorithm constructs access techniques lead to efficient and flexible resource sharing and mitigate the impact of wireless

  14. TECHNICAL ADVANCE A high-throughput method for quantifying growth of

    E-Print Network [OSTI]

    Dangl, Jeff

    : Arabidopsis, resistance genes, Pseudomonas syringae, phytopathogenic bacteria, counting bacteria IntroductionTECHNICAL ADVANCE A high-throughput method for quantifying growth of phytopathogenic bacteria; email: dangl@email.unc.edu) Summary Measuring the growth of pathogenic bacteria in leaves is a mainstay

  15. ORIGINAL ARTICLE GeoChip 3.0 as a high-throughput tool for analyzing

    E-Print Network [OSTI]

    Thomas, David D.

    significantly changed with the plant species diversity. As expected, GeoChip 3.0 is a high-throughput powerful Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA and 8 Virtual Institute in microbial ecology Keywords: microarray; functional genes; microbial community; plant diversity Introduction

  16. ORIGINAL ARTICLE GeoChip 3.0 as a high-throughput tool for analyzing

    E-Print Network [OSTI]

    Hazen, Terry

    significantly changed with the plant species diversity. As expected, GeoChip 3.0 is a high-throughput powerful Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA and 8 Virtual Institute Keywords: microarray; functional genes; microbial community; plant diversity Introduction Microorganisms

  17. Short-Term Throughput Maximization for Battery Limited Energy Harvesting Nodes

    E-Print Network [OSTI]

    Yener, Aylin

    -term throughput of an energy harvesting transmitter node with power control and a limited energy storage capacity and the energy storage capacity of the node. A discrete model with packets of energy arrivals is considered that the harvested energy can be stored up to an energy level that we shall call the battery capacity. Energy beyond

  18. Throughput and Ergodic Capacity of Wireless Energy Harvesting Based DF Relaying Network

    E-Print Network [OSTI]

    Zhou, Xiangyun "Sean"

    Throughput and Ergodic Capacity of Wireless Energy Harvesting Based DF Relaying Network Ali A-and-forward (DF) relaying network based on wireless energy harvesting. The energy constrained relay node first (TSR) and ii) power splitting-based relaying (PSR). Con- sidering wireless energy harvesting constraint

  19. On Stability and Maximum Throughput of Exponential Backoff Mechanisms with Two Users

    E-Print Network [OSTI]

    Borgonovo, Flaminio

    Exponential Backoff (BEB) mechanism plays a key role in determining stability and efficiency of popular MAC of BEB under balanced load is equal to 0.6096. We also pro- vide the stability region when arrivals Exponential Backoff, Markov Chain, Throughput 1. INTRODUCTION The Binary Exponential Backoff (BEB) mechanism

  20. High-throughput imaging of heterogeneous cell organelles with an X-ray laser

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hantke, Max, F.

    Preprocessed detector images that were used for the paper "High-throughput imaging of heterogeneous cell organelles with an X-ray laser". The CXI file contains the entire recorded data - including both hits and blanks. It also includes down-sampled images and LCLS machine parameters. Additionally, the Cheetah configuration file is attached that was used to create the pre-processed data.

  1. High-throughput imaging of heterogeneous cell organelles with an X-ray laser

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hantke, Max, F.

    2014-11-17

    Preprocessed detector images that were used for the paper "High-throughput imaging of heterogeneous cell organelles with an X-ray laser". The CXI file contains the entire recorded data - including both hits and blanks. It also includes down-sampled images and LCLS machine parameters. Additionally, the Cheetah configuration file is attached that was used to create the pre-processed data.

  2. Using Machine Affinity to Increase Science Throughput (Machine Affinity Characterization of the HPCMP Workload)

    E-Print Network [OSTI]

    Snavely, Allan

    on the "Standard" benchmark input at 128 processors, then the machines are ranked (fastest to slowest) as shownUsing Machine Affinity to Increase Science Throughput (Machine Affinity Characterization San Diego Supercomputer Center, University of California, San Diego, CA {allans, lcarring, agamst

  3. Estimating Reliability and Throughput of Source-synchronous Wave-pipelined Interconnect

    E-Print Network [OSTI]

    Lemieux, Guy

    Destination Clk gen Data Forwarded clock (generated at source) (c) SSWP: Source synchronous, wave pipelinedEstimating Reliability and Throughput of Source-synchronous Wave-pipelined Interconnect Paul Teehan to distinguish between static and dynamic sources of tim- ing uncertainty, because source-synchronous wave

  4. Route Throughput Analysis with Spectral Reuse for Multi-Rate Mobile Ad Hoc Networks

    E-Print Network [OSTI]

    Tseng, Yu-Chee

    networks (MANETs) have received a lot of attention for its flexible network architecture. While many network (MANET) is a flexible and dynamic architecture that is attractive due to its ease in network1 Route Throughput Analysis with Spectral Reuse for Multi-Rate Mobile Ad Hoc Networks Lien-Wu Chen

  5. Journal of Power Sources 158 (2006) 6068 High throughput evaluation of perovskite-based anode catalysts

    E-Print Network [OSTI]

    Mukasyan, Alexander

    2006-01-01

    Journal of Power Sources 158 (2006) 60­68 High throughput evaluation of perovskite-based anode to 25 compositions simultaneously under DMFC conditions. It was found that the Sr-based perovskites.g. perovskites, cuprates, etc.) Corresponding author. Tel.: +1 765 494 4075; fax: +1 765 494 0805. E

  6. Oblique-incidence reflectivity difference microscope for label-free high-throughput detection of biochemical

    E-Print Network [OSTI]

    Zhu, Xiangdong

    Oblique-incidence reflectivity difference microscope for label-free high-throughput detection (OI-RD) microscope, a form of polarization-modulated imaging ellipsometer, for label on the polarizer­ compensator­sample­analyzer scheme and under the off-null condition, a polarization-modulated OI

  7. PARALLEL HIGH THROUGHPUT SOFT-OUTPUT SPHERE DECODER Q. Qi, C. Chakrabarti

    E-Print Network [OSTI]

    Kambhampati, Subbarao

    - putation complexity of only the list generator. Recently, a high speed systolic-like soft-output spherePARALLEL HIGH THROUGHPUT SOFT-OUTPUT SPHERE DECODER Q. Qi, C. Chakrabarti School of Electrical,chaitali}@asu.edu ABSTRACT Multiple-Input-Multiple-Output communication systems de- mand fast sphere decoding with high

  8. Throughput Analysis and Voltage-Frequency Island Partitioning for Streaming Applications under Process Variation

    E-Print Network [OSTI]

    Throughput Analysis and Voltage-Frequency Island Partitioning for Streaming Applications under in video decoding) in a system with Voltage-Frequency Island (VFI) partitions in the presence of process of synchronous blocks, communicating with each other on an asynchronous basis. The concept of Voltage

  9. Droplet microfluidic technology for single-cell high-throughput screening

    E-Print Network [OSTI]

    Perrimon, Norbert

    Droplet microfluidic technology for single-cell high-throughput screening Eric Brouzesa,b,1 (received for review March 31, 2009) We present a droplet-based microfluidic technology that enables high our droplet microfluidic platform is modular, robust, uses no moving parts, and has a wide range

  10. Effect of Height (Fresnel Clearance) on Signal Strength and Throughput for

    E-Print Network [OSTI]

    Liblit, Ben

    Effect of Height (Fresnel Clearance) on Signal Strength and Throughput for Medium and Long Distance obstruction height · Ignoring Fresnel Clearance For 20Km long Wireless Link, Fresnel Clearance requires around, height 4 m at Q ensures 100% Fresnel Clearance On Physical Inspection: No LOS even at 8 meters Distance

  11. Economic Plantwide Control Over a Wide Throughput Range: A Systematic Design Procedure

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Economic Plantwide Control Over a Wide Throughput Range: A Systematic Design Procedure Rahul Jagtap.com) A systematic top-down procedure to design an effective plantwide control system for economically (near) optimum for tight control of all the active constraints and economically sound controlled variables (CVs

  12. The New York Consortium on Membrane Protein Structure (NYCOMPS): a high-throughput platform for structural

    E-Print Network [OSTI]

    Hendrickson, Wayne A.

    The New York Consortium on Membrane Protein Structure (NYCOMPS): a high-throughput platform Springer Science+Business Media B.V. 2010 Abstract The New York Consortium on Membrane Protein Structure Core Laboratory, New York Structural Biology Center, New York, NY 10027, USA F. Mancia Á M. Zhou

  13. Hanford tank waste simulants specification and their applicability for the retrieval, pretreatment, and vitrification processes

    SciTech Connect (OSTI)

    GR Golcar; NG Colton; JG Darab; HD Smith

    2000-04-04

    A wide variety of waste simulants were developed over the past few years to test various retrieval, pretreatment and waste immobilization technologies and unit operations. Experiments can be performed cost-effectively using non-radioactive waste simulants in open laboratories. This document reviews the composition of many previously used waste simulants for remediation of tank wastes at the Hanford reservation. In this review, the simulants used in testing for the retrieval, pretreatment, and vitrification processes are compiled, and the representative chemical and physical characteristics of each simulant are specified. The retrieval and transport simulants may be useful for testing in-plant fluidic devices and in some cases for filtration technologies. The pretreatment simulants will be useful for filtration, Sr/TRU removal, and ion exchange testing. The vitrification simulants will be useful for testing melter, melter feed preparation technologies, and for waste form evaluations.

  14. PROJECT W-551 SUMMARY INFORMATION FOR EARLY LAW INTERIM PRETREATMENT SYSTEM SELECTION

    SciTech Connect (OSTI)

    TEDESCHI AR

    2008-08-11

    This report provides summary data for use by the decision board to assess and select the final technology for project W-551, Interim Pretreatment System. This project will provide early pretreated low activity waste feed to the Waste Treatment Plant to allow Waste Treatment Plan Low Activity Waste facility operation prior to construction completion of the Pretreatment and High Level Waste facilities. The candidate solids separations technologies are rotary microfiltration and crossflow filtration, and the candidate cesium separation technologies are fractional crystallization, caustic-side solvent extraction, and ion-exchange using spherical resorcinol-fonnaldebyde resin. This document provides a summary of comparative data against prior weighted criteria to support technology selection. Supporting details and background for this summary are documented in the separate report, RPP-RPT-37741.

  15. PROJECT W-551 DETERMINATION DATA FOR EARLY LAW INTERIM PRETREATMENT SYSTEM SELECTION

    SciTech Connect (OSTI)

    TEDESCHI AR

    2008-08-11

    This report provides the detailed assessment forms and data for selection of the solids separation and cesium separation technology for project W-551, Interim Pretreatment System. This project will provide early pretreated low activity waste feed to the Waste Treatment Plant to allow Waste Treatment Plan Low Activity Waste facility operation prior to construction completion of the Pretreatment and High Level Waste facilities. The candidate solids separations technologies are rotary microfiltration and crossflow filtration, and the candidate cesium separation technologies are fractional crystallization, caustic-side solvent extraction, and ion-exchange using spherical resorcinol-formaldehyde resin. This data was used to prepare a cross-cutting technology summary, reported in RPP-RPT-37740.

  16. Selection of Pretreatment Processes for Removal of Radionuclides from Hanford Tank Waste

    SciTech Connect (OSTI)

    CARREON, R.

    2002-01-01

    The U.S. Department of Energy's (DOE's), Office of River Protection (ORP) located at Hanford Washington has established a contract (1) to design, construct, and commission a new Waste Treatment and Immobilization Plant (WTP) that will treat and immobilize the Hanford tank wastes for ultimate disposal. The WTP is comprised of four major elements, pretreatment, LAW immobilization, HLW immobilization, and balance of plant facilities. This paper describes the technologies selected for pretreatment of the LAW and HLW tank wastes, how these technologies were selected, and identifies the major technology testing activities being conducted to finalize the design of the WTP.

  17. Pretreatment process for forming a smooth surface diamond film on a carbon-coated substrate

    DOE Patents [OSTI]

    Feng, Z.; Brewer, M.; Brown, I.; Komvopoulos, K.

    1994-05-03

    A process is disclosed for the pretreatment of a carbon-coated substrate to provide a uniform high density of nucleation sites thereon for the subsequent deposition of a continuous diamond film without the application of a bias voltage to the substrate. The process comprises exposing the carbon-coated substrate, in a microwave plasma enhanced chemical vapor deposition system, to a mixture of hydrogen-methane gases, having a methane gas concentration of at least about 4% (as measured by partial pressure), while maintaining the substrate at a pressure of about 10 to about 30 Torr during the pretreatment. 6 figures.

  18. Pretreatment process for forming a smooth surface diamond film on a carbon-coated substrate

    DOE Patents [OSTI]

    Feng, Zhu (Albany, CA); Brewer, Marilee (Goleta, CA); Brown, Ian (Berkeley, CA); Komvopoulos, Kyriakos (Orinda, CA)

    1994-01-01

    A process is disclosed for the pretreatment of a carbon-coated substrate to provide a uniform high density of nucleation sites thereon for the subsequent deposition of a continuous diamond film without the application of a bias voltage to the substrate. The process comprises exposing the carbon-coated substrate, in a microwave plasma enhanced chemical vapor deposition system, to a mixture of hydrogen-methane gases, having a methane gas concentration of at least about 4% (as measured by partial pressure), while maintaining the substrate at a pressure of about 10 to about 30 Torr during the pretreatment.

  19. The boron isotope systematics of the Yellowstone National Park (Wyoming) hydrothermal system: A reconnaissance

    SciTech Connect (OSTI)

    Palmer, M.R. (Bristol Univ. (England)); Sturchio, N.C. (Argonne National Lab., IL (USA))

    1990-10-01

    Boron concentrations and isotope compositions have been measured in fourteen hot spring waters, two drill hole waters, an unaltered rhyolite flow, and hydrothermally altered rhyolite from the geothermal system in Yellowstone National Park, Wyoming. The samples are representative of the major thermal areas within the park and span the range of fluid types. For the fluids, the B concentrations range from 0.043-2.69 mM/kg, and the {delta}{sup 11}B values range from {minus}9.3 to +4.4{per thousand}. There is no relationship between the dissolved B concentrations or isotope compositions with the concentration of any major element (other than Cl) or physical property. Each basin is characterized by a restricted range in B/Cl ratios and {delta}{sup 11}B values. Hot spring waters from the Norris Basin, Upper Geyser Basin, Calcite Springs, and Clearwater have {delta}{sup 11}B values close to that of unaltered rhyolite ({minus}5.2{per thousand}) and are interpreted to have derived their B from this source. Waters from Mammoth Hot Springs, Sheepeater, and Rainbow Springs have lower {delta}{sup 11}B values close to {minus}8{per thousand}. These lower values may reflect leaching of B from sedimentary rocks outside the Yellowstone caldera, but they are similar to the {delta}{sup 11}B value of hydrothermally altered rhyolite ({minus}9.7{per thousand}). Hence, the light boron isotope compositions recorded in these hot spring waters may reflect leaching of previously deposited hydrothermal minerals. Cooler springs along the Yellowstone River just outside the park boundary have lower B concentrations and higher {delta}{sup 11}B values that may reflect mixing with shallow meteoric water.

  20. Hydrothermal alteration in research drill hole Y-2, Lower Geyser Basin, Yellowstone National Park, Wyoming

    SciTech Connect (OSTI)

    Bargar, K.E.; Beeson, M.H.

    1981-05-01

    Y-2, a US Geological Survey research diamond-drill hole in Lower Geyser Basin, Yellowstone National Park, was drilled to a depth of 157.4 meters. The hole penetrated interbedded siliceous sinter and travertine to 10.2 m, glacial sediments of the Pinedale Glaciation interlayered with pumiceous tuff from 10.2 to 31.7 m, and rhyolitic lavas of the Elephant Back flow of the Central Plateau Member and the Mallard Lake Member of the Pleistocene Plateau Rhyolite from 31.7 to 157.4 m. Hydrothermal alteration is pervasive in most of the nearly continuous drill core. Rhyolitic glass has been extensively altered to clay and zeolite minerals (intermediate heulandite, clinoptilolite, mordenite, montmorillonite, mixed-layer illite-montmorillonite, and illite) in addition to quartz and adularia. Numerous veins, vugs, and fractures in the core contain these and other minerals: silica minerals (opal, ..beta..-cristobalite, ..cap alpha..-cristobalite, and chalcedony), zeolites (analcime, wairakite, dachiardite, laumontite, and yugawaralite), carbonates (calcite and siderite), clay (kaolinite and chlorite), oxides (hematite, goethite, manganite, cryptomelane, pyrolusite, and groutite), and sulfides (pyrhotite and pyrite) along with minor aegirine, fluorite, truscottite, and portlandite. Interbedded travertine and siliceous sinter in the upper part of the drill core indicate that two distinct types of thermal water are responsible for precipitation of the surficial deposits, and further that the water regime has alternated between the two thermal waters more than once since the end of the Pinedale Glaciation (approx. 10,000 years B.P.). Alternation of zones of calcium-rich and sodium- and potassium-rich hydrothermal minerals also suggests that the calcium-rich and sodium- and potassium-rich hydrothermal minerals also suggests that the water chemistry in this drill hole varies with depth.

  1. Fabrication of hollow mesoporous NiO hexagonal microspheres via hydrothermal process in ionic liquid

    SciTech Connect (OSTI)

    Zhao, Jinbo; School of Materials Science and Engineering, Shandong University, 250061, Jinan ; Wu, Lili; School of Materials Science and Engineering, Shandong University, 250061, Jinan ; Zou, Ke; School of Materials Science and Engineering, Shandong University, 250061, Jinan

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Ni(OH){sub 2} precursors were synthesized in ionic liquid and water solution by hydrothermal method. Black-Right-Pointing-Pointer NiO hollow microspheres were prepared by thermal treatment of Ni(OH){sub 2} precursors. Black-Right-Pointing-Pointer NiO hollow microspheres were self-assembled by mesoporous cubic and hexagonal nanocrystals with high specific surface area. Black-Right-Pointing-Pointer The mesoporous structure is stable at 773 K. Black-Right-Pointing-Pointer The ionic liquid absorbed on the O-terminate surface of the crystals to form hydrogen bond and played key roles in determining the final shape of the NiO novel microstructure. -- Abstract: The novel NiO hexagonal hollow microspheres have been successfully prepared by annealing Ni(OH){sub 2}, which was synthesized via an ionic liquid-assisted hydrothermal method. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), N{sub 2} adsorption-desorption and Fourier transform infrared spectrometer (FTIR). The results show that the hollow NiO microstructures are self-organized by mesoporous cubic and hexagonal nanocrystals. The mesoporous structure possessed good thermal stability and high specific surface area (ca. 83 m{sup 2}/g). The ionic liquid 1-butyl-3methylimidazolium tetrafluoroborate ([Bmim][BF{sub 4}]) was found to play a key role in controlling the morphology of NiO microstructures during the hydrothermal process. The special hollow mesoporous architectures will have potential applications in many fields, such as catalysts, absorbents, sensors, drug-delivery carriers, acoustic insulators and supercapacitors.

  2. Discernment of two opposing reports on the hydrological effects of a hydrothermal power plant

    SciTech Connect (OSTI)

    Williams, J.M.

    1986-06-01

    Two evaluations to determine the hydrological effects of a 50-megawatt hydrothermal power plant in the Jemez Mountains give dramatically different results. One shows little effect; the other, a large one. The treatments agree on some thermal-zone water supplies to the Jemez River but not on the expected changes in these flows. The primary areas of disagreement appear to be the total volume of water in the reservoir and the movement of this water to the point of withdrawal. The author (a nonhydrologist) has compared these reports but leaves final judgment of the accuracy of either evaluation for some erudite hydrologists, as some experimental data and model development are needed.

  3. Preservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal Plumes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal Plumes Print Despite the

  4. Preservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal Plumes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal Plumes Print Despite

  5. Automated High Throughput Protein Crystallization Screening at Nanoliter Scale and Protein Structural Study on Lactate Dehydrogenase

    SciTech Connect (OSTI)

    Fenglei Li

    2006-08-09

    The purposes of our research were: (1) To develop an economical, easy to use, automated, high throughput system for large scale protein crystallization screening. (2) To develop a new protein crystallization method with high screening efficiency, low protein consumption and complete compatibility with high throughput screening system. (3) To determine the structure of lactate dehydrogenase complexed with NADH by x-ray protein crystallography to study its inherent structural properties. Firstly, we demonstrated large scale protein crystallization screening can be performed in a high throughput manner with low cost, easy operation. The overall system integrates liquid dispensing, crystallization and detection and serves as a whole solution to protein crystallization screening. The system can dispense protein and multiple different precipitants in nanoliter scale and in parallel. A new detection scheme, native fluorescence, has been developed in this system to form a two-detector system with a visible light detector for detecting protein crystallization screening results. This detection scheme has capability of eliminating common false positives by distinguishing protein crystals from inorganic crystals in a high throughput and non-destructive manner. The entire system from liquid dispensing, crystallization to crystal detection is essentially parallel, high throughput and compatible with automation. The system was successfully demonstrated by lysozyme crystallization screening. Secondly, we developed a new crystallization method with high screening efficiency, low protein consumption and compatibility with automation and high throughput. In this crystallization method, a gas permeable membrane is employed to achieve the gentle evaporation required by protein crystallization. Protein consumption is significantly reduced to nanoliter scale for each condition and thus permits exploring more conditions in a phase diagram for given amount of protein. In addition, evaporation rate can be controlled or adjusted in this method during the crystallization process to favor either nucleation or growing processes for optimizing crystallization process. The protein crystals gotten by this method were experimentally proven to possess high x-ray diffraction qualities. Finally, we crystallized human lactate dehydrogenase 1 (H4) complexed with NADH and determined its structure by x-ray crystallography. The structure of LDH/NADH displays a significantly different structural feature, compared with LDH/NADH/inhibitor ternary complex structure, that subunits in LDH/NADH complex show open conformation or two conformations on the active site while the subunits in LDH/NADH/inhibitor are all in close conformation. Multiple LDH/NADH crystals were obtained and used for x-ray diffraction experiments. Difference in subunit conformation was observed among the structures independently solved from multiple individual LDH/NADH crystals. Structural differences observed among crystals suggest the existence of multiple conformers in solution.

  6. Comparative material balances around pretreatment technologies for the conversion of switchgrass to soluble sugars

    E-Print Network [OSTI]

    California at Riverside, University of

    92507, USA h Chemical and Biosciences Center, National Renewable Energy Laboratory, 1617 Cole Blvd a b s t r a c t For this project, six chemical pretreatments were compared for the Consortium. Introduction The world supply of fossil fuels is limited and will eventually fail to meet the global demand

  7. Rapid MALDI-TOF MS analysis of bacteriophage major capsid proteins with -mercaptoethanol sample pretreatment

    E-Print Network [OSTI]

    pretreatment Casey R. McAlpin1, Kent J. Voorhees1, Christopher R. Cox1, Stephanie Matyi1 1Advanced Biodetection structure caused by hydrogen bonding, it was hypothesized that other structural determinants bacteriophage -A1122 (which is utilized for plague detection) were analyzed by combining 100µL of phage solution

  8. Laboratory Demonstration of the Pretreatment Process with Caustic and Oxidative Leaching Using Actual Hanford Tank Waste

    SciTech Connect (OSTI)

    Fiskum, Sandra K.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Shimskey, Rick W.; Snow, Lanee A.

    2009-01-01

    This report describes the bench-scale pretreatment processing of actual tank waste materials through the entire baseline WTP pretreatment flowsheet in an effort to demonstrate the efficacy of the defined leaching processes on actual Hanford tank waste sludge and the potential impacts on downstream pretreatment processing. The test material was a combination of reduction oxidation (REDOX) tank waste composited materials containing aluminum primarily in the form of boehmite and dissolved S saltcake containing Cr(III)-rich entrained solids. The pretreatment processing steps tested included • caustic leaching for Al removal • solids crossflow filtration through the cell unit filter (CUF) • stepwise solids washing using decreasing concentrations of sodium hydroxide with filtration through the CUF • oxidative leaching using sodium permanganate for removing Cr • solids filtration with the CUF • follow-on solids washing and filtration through the CUF • ion exchange processing for Cs removal • evaporation processing of waste stream recycle for volume reduction • combination of the evaporated product with dissolved saltcake. The effectiveness of each process step was evaluated by following the mass balance of key components (such as Al, B, Cd, Cr, Pu, Ni, Mn, and Fe), demonstrating component (Al, Cr, Cs) removal, demonstrating filterability by evaluating filter flux rates under various processing conditions (transmembrane pressure, crossflow velocities, wt% undissolved solids, and PSD) and filter fouling, and identifying potential issues for WTP. The filterability was reported separately (Shimskey et al. 2008) and is not repeated herein.

  9. Comparative Sugar Recovery and Fermentation Data Following Pretreatment of Poplar Wood by Leading Technologies

    E-Print Network [OSTI]

    California at Riverside, University of

    , aqueous ammonia recycle, dilute sulfuric acid, lime, neu- tral pH, and sulfur dioxide were applied pretreatments to ethanol with similarly high yields. An Agricultural and Industrial Advisory Board followed of Chemical Engineers Biotechnol. Prog., 25: 333­339, 2009 Keywords: ammonia fiber expansion, ammonia recycle

  10. Comparative sugar recovery data from laboratory scale application of leading pretreatment technologies to corn stover

    E-Print Network [OSTI]

    California at Riverside, University of

    , East Lansing, MI 48824, USA c National Renewable Energy Laboratory, Golden, CO 80401, USA d Texas A support, and economic analyses were provided through Richard Elander of the National Renewable Energy societal benefits, but pretreatment operations essential to economically viable yields have a major impact

  11. In vacuo substrate pretreatments for enhancing nanodiamond formation in electron cyclotron resonance plasma

    SciTech Connect (OSTI)

    Teii, Kungen; Kouzuma, Yutaka; Uchino, Kiichiro

    2006-09-15

    Substrate pretreatment conditions at low pressures have been examined for enhancing nanocrystalline diamond formation on silicon in electron cyclotron resonance (ECR) plasma. Three kinds of pretreatments (I) exposure to an ECR H{sub 2} plasma with application of a substrate bias from -100 to +30 V (II) hot-filament heating in H{sub 2} gas, and (III) hot-filament heating in vacuum, were used alone or followed by carburization prior to a two-step process of ion-enhanced nucleation in an ECR plasma and subsequent growth in a hot-filament system. The number density of diamond particles after the final growth step was greatly increased up to the order of 10{sup 7}-10{sup 8} cm{sup -2} when applying pretreatment (I) at the bias of 0 V corresponding to the ion-bombardment energy of around 10 eV. In this treatment, a clean and smooth surface with minimal damage was made by the dominance of anisotropic etching by hydrogen ions over isotropic etching by hydrogen atoms. The number density of diamond particles was still more increased when applying pretreatment (II), but the treated surface was unfavorably contaminated and roughened.

  12. Underground storage tank integrated demonstration: Evaluation of pretreatment options for Hanford tank wastes

    SciTech Connect (OSTI)

    Lumetta, G.J.; Wagner, M.J.; Colton, N.G.; Jones, E.O.

    1993-06-01

    Separation science plays a central role inn the pretreatment and disposal of nuclear wastes. The potential benefits of applying chemical separations in the pretreatment of the radioactive wastes stored at the various US Department of Energy sites cover both economic and environmental incentives. This is especially true at the Hanford Site, where the huge volume (>60 Mgal) of radioactive wastes stored in underground tanks could be partitioned into a very small volume of high-level waste (HLW) and a relatively large volume of low-level waste (LLW). The cost associated with vitrifying and disposing of just the HLW fraction in a geologic repository would be much less than those associated with vitrifying and disposing of all the wastes directly. Futhermore, the quality of the LLW form (e.g., grout) would be improved due to the lower inventory of radionuclides present in the LLW stream. In this report, we present the results of an evaluation of the pretreatment options for sludge taken from two different single-shell tanks at the Hanford Site-Tanks 241-B-110 and 241-U-110 (referred to as B-110 and U-110, respectively). The pretreatment options examined for these wastes included (1) leaching of transuranic (TRU) elements from the sludge, and (2) dissolution of the sludge followed by extraction of TRUs and {sup 90}Sr. In addition, the TRU leaching approach was examined for a third tank waste type, neutralized cladding removal waste.

  13. Methods of hydrolyzing pretreated densified biomass particulates and systems related thereto

    SciTech Connect (OSTI)

    Bals, Bryan; Teymouri, Farzaneh; Campbell, Tim; Dale, Bruce

    2015-02-03

    A method is provided in which pretreated and densified cellulosic biomass particulates can be hydrolyzed at a high solids loading rate as compared with the solids loading rate of loose hydrolysable cellulosic biomass fibers. The resulting high concentration sugar-containing stream can be easily converted to biofuels or an entire suite of other useful bioproducts.

  14. Predicted Effect of Minerals on Pretreatment 1013 Applied Biochemistry and Biotechnology Vol. 113116, 2004

    E-Print Network [OSTI]

    California at Riverside, University of

    Predicted Effect of Minerals on Pretreatment 1013 Applied Biochemistry and Biotechnology Vol. 113 of Mineral Neutralization and Bisulfate Formation on Hydrogen Ion Concentration for Dilute Sulfuric Acid, such as agricultural residues and forest wastes, can have a significant mineral content. It has been shown

  15. Residence Time Distribution Measurement and Analysis of Pilot-Scale Pretreatment Reactors for Biofuels Production: Preprint

    SciTech Connect (OSTI)

    Sievers, D.; Kuhn, E.; Tucker, M.; Stickel, J.; Wolfrum, E.

    2013-06-01

    Measurement and analysis of residence time distribution (RTD) data is the focus of this study where data collection methods were developed specifically for the pretreatment reactor environment. Augmented physical sampling and automated online detection methods were developed and applied. Both the measurement techniques themselves and the produced RTD data are presented and discussed.

  16. Robust, high-throughput solution structural analyses by small angle X-ray scattering (SAXS)

    SciTech Connect (OSTI)

    Hura, Greg L.; Menon, Angeli L.; Hammel, Michal; Rambo, Robert P.; Poole II, Farris L.; Tsutakawa, Susan E.; Jenney Jr, Francis E.; Classen, Scott; Frankel, Kenneth A.; Hopkins, Robert C.; Yang, Sungjae; Scott, Joseph W.; Dillard, Bret D.; Adams, Michael W. W.; Tainer, John A.

    2009-07-20

    We present an efficient pipeline enabling high-throughput analysis of protein structure in solution with small angle X-ray scattering (SAXS). Our SAXS pipeline combines automated sample handling of microliter volumes, temperature and anaerobic control, rapid data collection and data analysis, and couples structural analysis with automated archiving. We subjected 50 representative proteins, mostly from Pyrococcus furiosus, to this pipeline and found that 30 were multimeric structures in solution. SAXS analysis allowed us to distinguish aggregated and unfolded proteins, define global structural parameters and oligomeric states for most samples, identify shapes and similar structures for 25 unknown structures, and determine envelopes for 41 proteins. We believe that high-throughput SAXS is an enabling technology that may change the way that structural genomics research is done.

  17. Method and apparatus for maximizing throughput of indirectly heated rotary kilns

    DOE Patents [OSTI]

    Coates, Ralph L; Smoot, L. Douglas; Hatfield, Kent E

    2012-10-30

    An apparatus and method for achieving improved throughput capacity of indirectly heated rotary kilns used to produce pyrolysis products such as shale oils or coal oils that are susceptible to decomposition by high kiln wall temperatures is disclosed. High throughput is achieved by firing the kiln such that optimum wall temperatures are maintained beginning at the point where the materials enter the heating section of the kiln and extending to the point where the materials leave the heated section. Multiple high velocity burners are arranged such that combustion products directly impact on the area of the kiln wall covered internally by the solid material being heated. Firing rates for the burners are controlled to maintain optimum wall temperatures.

  18. Increasing throughput of multiplexed electrical bus in pipe-lined architecture

    DOE Patents [OSTI]

    Asaad, Sameh; Brezzo, Bernard V; Kapur, Mohit

    2014-05-27

    Techniques are disclosed for increasing the throughput of a multiplexed electrical bus by exploiting available pipeline stages of a computer or other system. For example, a method for increasing a throughput of an electrical bus that connects at least two devices in a system comprises introducing at least one signal hold stage in a signal-receiving one of the two devices, such that a maximum frequency at which the two devices are operated is not limited by a number of cycles of an operating frequency of the electrical bus needed for a signal to propagate from a signal-transmitting one of the two devices to the signal-receiving one of the two devices. Preferably, the signal hold stage introduced in the signal-receiving one of the two devices is a pipeline stage re-allocated from the signal-transmitting one of the two devices.

  19. High-throughput metagenomic technologies for complex microbial community analysis. Open and closed formats

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Jizhong; He, Zhili; Yang, Yunfeng; Deng, Ye; Tringe, Susannah G.; Alvarez-Cohen, Lisa

    2015-01-27

    Understanding the structure, functions, activities and dynamics of microbial communities in natural environments is one of the grand challenges of 21st century science. To address this challenge, over the past decade, numerous technologies have been developed for interrogating microbial communities, of which some are amenable to exploratory work (e.g., high-throughput sequencing and phenotypic screening) and others depend on reference genes or genomes (e.g., phylogenetic and functional gene arrays). Here, we provide a critical review and synthesis of the most commonly applied “open-format” and “closed-format” detection technologies. We discuss their characteristics, advantages, and disadvantages within the context of environmental applications andmore »focus on analysis of complex microbial systems, such as those in soils, in which diversity is high and reference genomes are few. In addition, we discuss crucial issues and considerations associated with applying complementary high-throughput molecular technologies to address important ecological questions.« less

  20. Interleaving techniques for high-throughput chaotic noise generation in CMOS

    E-Print Network [OSTI]

    Sergio Callegari; Riccardo Rovatti; Gianluca Setti

    2015-07-01

    An interleaving technique is proposed to enhance the throughput of current-mode CMOS discrete time chaotic sources based on the iteration of unidimensional maps. A discussion of the reasons and the advantages offered by the approach is provided, together with analytical results about the conservation of some major statistical features. As an example, application to an FM-DCSK communication system is proposed. To conclude, a sample circuit capable of 20 Msample/s is presented.

  1. Hydrothermal synthesis of nanostructured zinc oxide and study of their optical properties

    SciTech Connect (OSTI)

    Moulahi, A.; Sediri, F.; Gharbi, N.

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Nanostructured ZnO were successfully obtained by a hydrothermal route. Black-Right-Pointing-Pointer Inorganic precursor and molar ratio are key factors for morphology and particle size. Black-Right-Pointing-Pointer Optical properties were also studied. -- Abstract: Nanostructured ZnO (nanorods, nanoshuttles) have been synthesized by hydrothermal approach using ZnCl{sub 2} or Zn(NO{sub 3}){sub 2}{center_dot}6H{sub 2}O as zinc sources and cetyltrimethylammonium bromide as structure-directing agent. Techniques X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-visible absorption, Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy have been used to characterize the structure, morphology and composition of the nanostructured zinc oxide. The optical properties of the as-obtained materials were also studied and showing that it is possible to apply the ZnO nanoshuttles and nanorods on the UV filter, photocatalysis, and special optical devices.

  2. A genetic algorithm for solving the unit commitment problem of a hydro-thermal power system

    SciTech Connect (OSTI)

    Rudolf, A.; Bayrleithner, R.

    1999-11-01

    The paper presents a two layer approach to solve the unit commitment problem of a hydro-thermal power system. The first layer uses a genetic algorithm (GA) to decide the on/off status of the units. The second layer uses a non-linear programming formulation solved by a Lagrangian relaxation to perform the economic dispatch while meeting all plant and system constraints. In order to deal effectively with the constraints of the problem and prune the search space of the GA in advance, the difficult minimum up/down-time constraints of thermal generation units and the turbine/pump operating constraint of storage power stations are embedded in the binary strings that are coded to represent the on/off-states of the generating units. The other constraints are handled by integrating penalty costs into the fitness function. In order to save execution time, the economic dispatch is only performed if the given unit commitment schedule is able to meet the load balance, energy, and begin/end level constraints. The proposed solution approach was tested on a real scaled hydro-thermal power system over a period of a day in half-hour time-steps for different GA-parameters. The simulation results reveal that the features of easy implementation, convergence within an acceptable execution time, and highly optimal solution in solving the unit commitment problem can be achieved.

  3. Ionic liquid assisted hydrothermal fabrication of hierarchically organized ?-AlOOH hollow sphere

    SciTech Connect (OSTI)

    Tang, Zhe; Liu, Yunqi; Li, Guangci; Hu, Xiaofu; Liu, Chenguang

    2012-11-15

    Highlights: ? The ?-AlOOH hollow spheres were synthesized via an ionic liquid-assisted hydrothermal treatment. ? Ionic liquid plays an important role in the morphology of the product. ? Ionic liquid can be easily removed from the product and reused in next experiment. ? A “aggregation–solution–recrystallization” formation mechanism may occur in the system. -- Abstract: Hierarchically organized ?-AlOOH hollow spheres with nanoflake-like porous surface texture have been successfully synthesized via an ionic liquid-assisted hydrothermal synthesis method in citric acid monohydrate (CAMs). It was found that ionic liquid [bmim]{sup +}Cl{sup ?} played an important role in the morphology of the product due to its strong interactions with reaction particles. The samples were characterized by X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscope (SEM) and Transmission Electron Microscopy (TEM). The results show that the product has narrow particle size distribution (500–900 nm particle diameter range), high specific surface area (240.5 m{sup 2}/g) and large pore volume (0.61 cm{sup 3}/g). The corresponding ?-Al{sub 2}O{sub 3} hollow spheres can be obtained by calcining it at 550 °C for 3 h. The proposed formation mechanism and other influencing factors of the ?-AlOOH hollow sphere material, such as reaction temperature, reaction duration, CAMs and urea, have also been investigated.

  4. Process Development for Hydrothermal Liquefaction of Algae Feedstocks in a Continuous-Flow Reactor

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Schmidt, Andrew J.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.; Albrecht, Karl O.; Hallen, Richard T.; Holladay, Johnathan E.

    2013-10-01

    Wet algae slurries can be converted into an upgradeable biocrude by hydrothermal liquefaction (HTL). High levels of carbon conversion to gravity-separable biocrude product were accomplished at relatively low temperature (350 ?C) in a continuous-flow, pressurized (sub-critical liquid water) environment (20 MPa). As opposed to earlier work in batch reactors reported by others, direct oil recovery was achieved without the use of a solvent and biomass trace components were removed by processing steps so that they did not cause process difficulties. High conversions were obtained even with high slurry concentrations of up to 35 wt% of dry solids. Catalytic hydrotreating was effectively applied for hydrodeoxygenation, hydrodenitrogenation, and hydrodesulfurization of the biocrude to form liquid hydrocarbon fuel. Catalytic hydrothermal gasification was effectively applied for HTL byproduct water cleanup and fuel gas production from water soluble organics, allowing the water to be considered for recycle of nutrients to the algae growth ponds. As a result, high conversion of algae to liquid hydrocarbon and gas products was found with low levels of organic contamination in the byproduct water. All three process steps were accomplished in bench-scale, continuous-flow reactor systems such that design data for process scale-up was generated.

  5. Sound field near hydrothermal vents on Axial Seamount, Juan de Fuca Ridge. Technical report

    SciTech Connect (OSTI)

    Little, S.A.; Stolzenbach, K.D.; Purdy, G.M.

    1990-08-10

    High-quality acoustic noise measurements were obtained by two hydrophones located 3 m and 40 m from an active hydrothermal vent on Axial Seamount, Juan de Fuca Ridge, in an effort to determine the feasibility of monitoring hydrothermal vent activity through flow noise generation. Most of the measured noise field could be attributed to ambient ocean noise sources of microseisms, distant shipping, and weather, punctuated by local ships and biological sources. Long-period, low-velocity, water/rock interface waves were detected with high amplitudes which rapidly decayed with distance from the seafloor. Detection of vent signals was hampered by unexpected spatial nonstationarity due to the shadowing effects of the calders wall. No continuous vent signals were deemed significant based on a criterion of 90% probability of detection and 5% probability of false alarm. However, a small signal near 40 Hz, with a power level of 0.0001 Pa sq/Hz was noticed on two records taken within 3 m of the Inferno black smoker. The frequency of this signal is consistent with predictions, and the power level suggests the occurrence of jet noise amplification due to convected density inhomogeneities. Keywords: Seamounts; Flow noise; Underwater acoustics; Acoustic measurement; Geothermy/noise; Ocean ridges; Underwater sound signals; Reprints; North Pacific Ocean. (EDC).

  6. Faults and gravity anomalies over the East Mesa hydrothermal-geothermal system

    SciTech Connect (OSTI)

    Goldstein, N.E.; Carle, S.

    1986-05-01

    Detailed interpretations of gravity anomalies over geothermal systems may be extremely useful for mapping the fracture or fault systems that control the circulation of the thermal waters. This approach seems to be particularly applicable in areas like the Salton Trough where reactions between the thermal waters and the porous sediments produce authigenic-hydrothermal minerals in sufficient quantity to cause distinct gravity anomalies at the surface. A 3-D inversion of the residual Bouguer gravity anomaly over the East Mesa geothermal field was made to examine the densified volume of rock. We show that the data not only resolve a north-south and an intersecting northwest structure, but that it may be possible to distinguish between the active present-day hydrothermal system and an older and cooler part of the system. The densified region is compared spatially to self-potential, thermal and seismic results and we find a good concordance between the different geophysical data sets. Our results agree with previous studies that have indicated that the main feeder fault recharging the East Mesa reservoir dips steeply to the west.

  7. Pencil-like zinc oxide micro/nano-scale structures: Hydrothermal synthesis, optical and photocatalytic properties

    SciTech Connect (OSTI)

    Moulahi, A.; Sediri, F.

    2013-10-15

    Graphical abstract: - Highlights: • Zinc oxide micro/nanopencils have been synthesized hydrothermally. • Photocatalytic activity has been evaluated by the degradation of methylene blue under UV light irradiation. • ZnO nanopencils exhibit much higher photocatalytic activity than the commercial ZnO. - Abstract: Zinc oxide micro/nanopencils have been successfully synthesized by hydrothermal process using zinc acetate and diamines as structure-directing agents. The morphology, the structure, the crystallinity and the composition of the materials were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The optical properties of synthesized ZnO were investigated by UV–vis spectroscopy. The photocatalytic activity of the material has been evaluated by the degradation of methylene blue under UV irradiation. As a result, after the lapse of 150 min, around 82% bleaching was observed, with ZnO nanopencils yielding more photodegradation compared to that of commercial ZnO (61%)

  8. Mineral formation and redox-sensitive trace elements in a near-surface hydrothermal alteration system

    SciTech Connect (OSTI)

    Gehring, A.U.; Schosseler, P.M.; Weidler, P.G.

    1999-07-01

    A recent hydrothermal mudpool at the southwestern slope of the Rincon de la Vieja volcano in Northwest Costa Rica exhibits an argillic alteration system formed by intense interaction of sulfuric acidic fluids with wall rock materials. Detailed mineralogical analysis revealed an assemblage with kaolinite, alunite, and opal-C as the major mineral phases. Electron paramagnetic resonance spectroscopy (EPR) showed 3 different redox-sensitive cations associated with the mineral phases, Cu{sup +} is structure-bound in opal-C, whereas VO{sup 2+} and Fe{sup 3+} are located in the kaolinite structure. The location of the redox-sensitive cations in different minerals of the assemblage is indicative of different chemical conditions. The formation of the alteration products can be described schematically as a 2-step process. In a first step alunite and opal-C were precipitated in a fluid with slightly reducing conditions and a low chloride availability. The second step is characterized by a decrease in K{sup +} activity and subsequent formation of kaolinite under weakly oxidizing to oxidizing redox conditions as indicated by structure-bound VO{sup 2+} and Fe{sup 3+}. The detection of paramagnetic trace elements structure-bound in mineral phases by EPR provide direct information about the prevailing redox conditions during alteration and can, therefore, be used as additional insight into the genesis of the hydrothermal, near-surface system.

  9. A 96-well microplate incorporating a replica molded microfluidic network integrated with photonic crystal biosensors for high throughput kinetic

    E-Print Network [OSTI]

    Cunningham, Brian

    crystal biosensors for high throughput kinetic biomolecular interaction analysis{; Charles J. Choi microfluidic channels, with integrated label-free photonic crystal biosensors as the bottom surface the volume of reagent required to functionalize the biosensor surface, while retaining compatibility

  10. Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing

    E-Print Network [OSTI]

    Mueller, Tim

    Cathode materials with structure similar to the mineral tavorite have shown promise for use in lithium-ion batteries, but this class of materials is relatively unexplored. We use high-throughput density-functional-theory ...

  11. High-throughput data mined prediction of inorganic compounds and computational discovery of new lithium-ion battery cathode materials

    E-Print Network [OSTI]

    Hautier, Geoffroy (Geoffroy T. F.)

    2011-01-01

    The ability to computationally predict the properties of new materials, even prior to their synthesis, has been made possible due to the current accuracy of modern ab initio techniques. In some cases, high-throughput ...

  12. High Throughput Plasmid Sequencing with Illumina and CLC Bio (Seventh Annual Sequencing, Finishing, Analysis in the Future (SFAF) Meeting 2012)

    ScienceCinema (OSTI)

    Athavale, Ajay [Monsanto

    2013-01-25

    Ajay Athavale (Monsanto) presents "High Throughput Plasmid Sequencing with Illumina and CLC Bio" at the 7th Annual Sequencing, Finishing, Analysis in the Future (SFAF) Meeting held in June, 2012 in Santa Fe, NM.

  13. Advances in high-throughput speed, low-latency communication for embedded instrumentation ( 7th Annual SFAF Meeting, 2012)

    ScienceCinema (OSTI)

    Jordan, Scott [Physik Instrumente

    2013-02-11

    Scott Jordan on "Advances in high-throughput speed, low-latency communication for embedded instrumentation" at the 2012 Sequencing, Finishing, Analysis in the Future Meeting held June 5-7, 2012 in Santa Fe, New Mexico.

  14. High Throughput Computing Impact on Meta Genomics (Metagenomics Informatics Challenges Workshop: 10K Genomes at a Time)

    SciTech Connect (OSTI)

    Gore, Brooklin [Morgridge Institute for Research] [Morgridge Institute for Research

    2011-10-12

    This presentation includes a brief background on High Throughput Computing, correlating gene transcription factors, optical mapping, genotype to phenotype mapping via QTL analysis, and current work on next gen sequencing.

  15. High Throughput Computing Impact on Meta Genomics (Metagenomics Informatics Challenges Workshop: 10K Genomes at a Time)

    ScienceCinema (OSTI)

    Gore, Brooklin [Morgridge Institute for Research

    2013-01-22

    This presentation includes a brief background on High Throughput Computing, correlating gene transcription factors, optical mapping, genotype to phenotype mapping via QTL analysis, and current work on next gen sequencing.

  16. Stable throughput of cognitive radios with relaying capability Osvaldo Simeone, Yeheskel Bar-Ness and Umberto Spagnolini

    E-Print Network [OSTI]

    Spagnolini, Umberto

    Stable throughput of cognitive radios with relaying capability Osvaldo Simeone, Yeheskel Bar-Ness "transparency" of the activity of the secondary link. O. Simeone and Y. Bar-Ness are with CCSPR, New Jersey In

  17. MapTask Scheduling in MapReduce with Data Locality: Throughput and Heavy-Traffic Optimality

    E-Print Network [OSTI]

    Zhang, Junshan

    with the actual capacity region and the proposed algorithm is throughput optimal. Further, we study the number Google, Yahoo!, Facebook, Amazon and IBM. A production MapReduce cluster may consist of tens of thousands

  18. High Throughput Plasmid Sequencing with Illumina and CLC Bio (Seventh Annual Sequencing, Finishing, Analysis in the Future (SFAF) Meeting 2012)

    SciTech Connect (OSTI)

    Athavale, Ajay [Monsanto] [Monsanto

    2012-06-01

    Ajay Athavale (Monsanto) presents "High Throughput Plasmid Sequencing with Illumina and CLC Bio" at the 7th Annual Sequencing, Finishing, Analysis in the Future (SFAF) Meeting held in June, 2012 in Santa Fe, NM.

  19. Ionic liquid pretreatment of poplar wood at room temperature: swelling and incorporation of nanoparticles

    SciTech Connect (OSTI)

    Lucas, Marcel [Los Alamos National Laboratory; Macdonald, Brian A [Los Alamos National Laboratory; Wagner, Gregory L [Los Alamos National Laboratory; Joyce, Steven A [Los Alamos National Laboratory; Rector, Kirk D [Los Alamos National Laboratory

    2010-01-01

    Lignocellulosic biomass represents a potentially sustainable source of liquid fuels and commodity chemicals. It could satisfy the energy needs for transportation and electricity generation, while contributing substantially to carbon sequestration and limiting the accumulation of greenhouse gases in the atmosphere. Potential feedstocks are abundant and include crops, agricultural wastes, forest products, grasses, and algae. Among those feedstocks, wood is mainly constituted of three components: cellulose, hemicellulose, and lignin. The conversion process of lignocellulosic biomass typically consists of three steps: (1) pretreatment; (2) hydrolysis of cellulose and hemicellulose into fermentable sugars; and (3) fermentation of the sugars into liquid fuels (ethanol) and other commodity chemicals. The pretreatment step is necessary due to the complex structure of the plant cell wall and the chemical resistance of lignin. Most current pretreatments are energy-intensive and/or polluting. So it is imperative to develop new pretreatments that are economically viable and environmentally friendly. Recently, ionic liquids have attracted considerable interest, due to their ability to dissolve biopolymers, such as cellulose, lignin, native switchgrass, and others. Ionic liquids are also considered green solvents, since they have been successfully recycled at high yields for further use with limited efficiency loss. Also, a few microbial cellulases remain active at high ionic liquid concentration. However, all studies on the dissolution of wood in ionic liquids have been conducted so far at high temperatures, typically above 90 C. Development of alternative pretreatments at room temperature is desirable to eliminate the additional energy cost. In this study, thin sections of poplar wood were swollen at room temperature by a 3 h ionic liquid (1-ethyl-3-methylimidazolium acetate or EMIMAc) pretreatment. The pretreated sample was then exposed to an aqueous suspension of nanoparticles that resulted in the sample contraction and the deposition of nanoparticles onto the surface and embedded into the cell wall. To date, both silver and gold particles ranging in size from 40-100 nm have been incorporated into wood. Penetration of gold nanoparticles of 100 nm diameter in the cell walls was best confirmed by near-infrared confocal Raman microscopy, since the deposition of gold nanoparticles induces a significant enhancement of the Raman signal from the wood in their close proximity, an enhancement attributed to the surface-enhanced Raman effect (SERS). After rinsing with water, scanning electron microscopy (SEM) and Raman images of the same areas show that most nanoparticles remained on the pretreated sample. Raman images at different depths reveal that a significant number of nanoparticles were incorporated into the wood sample, at depths up to 4 {micro}m, or 40 times the diameter of the nanoparticles. Control experiments on an untreated wood sample resulted in the deposition of nanoparticles only at the surface and most nanoparticles were removed upon rinsing. This particle incorporation process enables the development of new pretreatments, since the nanoparticles have a high surface-to-volume ratio and could be chemically functionalized. Other potential applications for the incorporated nanoparticles include isotope tracing, catalysis, imaging agents, drug-delivery systems, energy-storage devices, and chemical sensors.

  20. TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT

    SciTech Connect (OSTI)

    RAMSEY AA; THORSON MR

    2010-12-28

    At-tank supplemental pretreatment including both filtration and small column ion exchange is currently under evaluation to facilitate salt waste retrieval and processing in the Hanford tank farms. Spherical resorcinol formaldehyde (sRF) resin is the baseline ion exchange resin for use in the Waste Treatment and Immobilization Plant (WTP). This document provides background and technical rationale to assist in determining whether spherical resorcinol formaldehyde (sRF) is also the appropriate ion exchange resin for supplemental LAW pretreatment processes and compares sRF with crystalline silicotitanate (CST) as potential supplemental pretreatment ion exchange media.

  1. Sodium dodecyl benzene sulfonate-assisted synthesis through a hydrothermal reaction

    SciTech Connect (OSTI)

    Sobhani, Azam; Salavati-Niasari, Masoud; Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran

    2012-08-15

    Graphical abstract: Reaction of a SeCl{sub 4} aqueous solution with a NiCl{sub 2}·6H{sub 2}O aqueous solution in presence of sodium dodecyl benzene sulfonate (SDBS) as capping agent and hydrazine (N{sub 2}H{sub 4}·H{sub 2}O) as reductant, produces nanosized nickel selenide through a hydrothermal method. The effect of temperature, reaction time and amounts of reductant on the morphology, particle sizes of NiSe nanostructures has been investigated. Highlights: ? NiSe nanostructures were synthesized by hydrothermal method. ? A novel Se source was used to synthesize NiSe. ? SDBS as capping agent plays a crucial role on the morphology of products. ? A mixture of Ni{sub 3}Se{sub 2} and NiSe was prepared in the presence of 2 ml hydrazine. ? A pure phase of NiSe was prepared in the presence of 4 or 6 ml hydrazine. -- Abstract: The effects of the anionic surfactant on the morphology, size and crystallization of NiSe precipitated from NiCl{sub 2}·6H{sub 2}O and SeCl{sub 4} in presence of hydrazine (N{sub 2}H{sub 4}·H{sub 2}O) as reductant were investigated. The products have been successfully synthesized in presence of sodium dodecyl benzene sulfonate (SDBS) as surfactant via an improved hydrothermal route. A variety of synthesis parameters, such as reaction time and temperature, capping agent and amount of reducing agent have a significant effect on the particle size, phase purity and morphology of the obtained products. The sample size became bigger with decreasing reaction temperature and increasing reaction time. In the presence of 2 ml hydrazine, the samples were found to be the mixture of Ni{sub 3}Se{sub 2} and NiSe. With increasing the reaction time and amount of hydrazine a pure phase of hexagonal NiSe was obtained. X-ray diffraction analysis (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM) images indicate phase, particle size and morphology of the products. Chemical composition and purity of the products were characterized by X-ray energy dispersive spectroscopy (EDS). Photoluminescence (PL) was used to study the optical properties of NiSe samples.

  2. Effects of glacial ice on subsurface temperatures of hydrothermal systems in Yellowstone National Park, Wyoming: Fluid-inclusion evidence

    SciTech Connect (OSTI)

    Bargar, K.E.; Fournier, R.O. (Geological Survey, Menlo Park, CA (USA))

    1988-12-01

    Hydrothermal quartz and fluorite crystals containing liquid-rich fluid inclusions (coexisting vapor-rich fluid inclusions were not observed) were found in drill cores from eight relatively shallow research holes drilled by the US Geological Survey in and near major geyser basins of Yellowstone National Park. Homogenization temperatures (T{sub h}) for mostly secondary fluid inclusions show variations in temperature that have occurred at give depths since precipitation of the host minerals. Within major hydrothermal upflow zones, fluid-inclusion T{sub h} values all were found to be equal to or higher (commonly 20-50 C and up to 155 C higher) than present temperatures at the depths sampled. During periods when thick glacial ice covered the Yellowstone National Park region, pore-fluid pressures in the underlying rock were increased in proportion to the weight of the overlying column of ice. Accordingly, theoretical reference boiling-point curves that reflect the maximum temperature attainable in a hot-water geothermal system at a given depth were elevated, and temperatures within zones of major hydrothermal upflow (drill holes Y-2, Y-3, Y-6, Y-11, Y-13, and upper part of Y-5) increased. The thicknesses of ice required to elevate boiling-point curves sufficiently to account for the observed fluid-inclusion T{sub h} values are within the ranges estimated by glacial geologic studies. At the margins of major hydrothermal upflow zones (drill holes Y-4 and Y-9), fluid-inclusion T{sub h} values at given depths range from 57 C lower to about the same as the current temperature measurements because of a previous decrease in the rate of discharge of warm water and/or an increase in the rate of recharge of cold water into the hydrothermal system.

  3. HANFORD MEDIUM & LOW CURIE WASTE PRETREATMENT PROJECT PHASE 1 LAB REPORT

    SciTech Connect (OSTI)

    HAMILTON, D.W.

    2006-01-30

    A fractional crystallization (FC) process is being developed to supplement tank waste pretreatment capabilities provided by the Waste Treatment and Immobilization Plant (WTP). FC can process many tank wastes, separating wastes into a low-activity fraction (LAW) and high-activity fraction (HLW). The low-activity fraction can be immobilized in a glass waste form by processing in the bulk vitrification (BV) system.

  4. Method for aqueous gold thiosulfate extraction using copper-cyanide pretreated carbon adsorption

    DOE Patents [OSTI]

    Young, Courtney; Melashvili, Mariam; Gow, Nicholas V

    2013-08-06

    A gold thiosulfate leaching process uses carbon to remove gold from the leach liquor. The activated carbon is pretreated with copper cyanide. A copper (on the carbon) to gold (in solution) ratio of at least 1.5 optimizes gold recovery from solution. To recover the gold from the carbon, conventional elution technology works but is dependent on the copper to gold ratio on the carbon.

  5. Hanford Waste Treatment Plant places first complex piping module in Pretreatment Facility

    Broader source: Energy.gov [DOE]

    Crews at the Hanford Waste Treatment Plant, also known as the "Vit Plant," placed a 19-ton piping module inside the Pretreatment Facility. The module was lifted over 98-foot-tall walls and lowered into a space that provided less than two inches of clearance on each side and just a few feet on each end. It was set 56 feet above the ground.

  6. Thermal Pretreatment of Wood for Cogasification/cofiring of Biomass and Coal

    SciTech Connect (OSTI)

    Wang, Ping; Howard, Bret; Hedges, Sheila; Morreale, Bryan; Van Essendelft, Dirk; Berry, David

    2013-10-29

    Utilization of biomass as a co-feed in coal and biomass co-firing and co-gasification requires size reduction of the biomass. Reducing biomass to below 0.2 mm without pretreatment is difficult and costly because biomass is fibrous and compressible. Torrefaction is a promising thermal pretreatment process and has the advantages of increasing energy density, improving grindability, producing fuels with more homogenous compositions and hydrophobic behavior. Temperature is the most important factor for the torrefaction process. Biomass grindability is related to cell wall structure, thickness and composition. Thermal treatment such as torrefaction can cause chemical changes that significantly affect the strength of biomass. The objectives of this study are to understand the mechanism by which torrefaction improves the grindability of biomass and discuss suitable temperatures for thermal pretreatment for co-gasification/cofiring of biomass and coal. Wild cherry wood was selected as the model for this study. Samples were prepared by sawing a single tangential section from the heartwood and cutting it into eleven pieces. The samples were consecutively heated at 220, 260, 300, 350, 450 and 550oC for 0.5 hr under flowing nitrogen in a tube furnace. Untreated and treated samples were characterized for physical properties (color, dimensions and weight), microstructural changes by SEM, and cell wall composition changes and thermal behaviors by TGA and DSC. The morphology of the wood remained intact through the treatment range but the cell walls were thinner. Thermal treatments were observed to decompose the cell wall components. Hemicellulose decomposed over the range of ~200 to 300oC and resulted in weakening of the cell walls and subsequently improved grindability. Furthermore, wood samples treated above 300oC lost more than 39% in mass. Therefore, thermal pretreatment above the hemicelluloses decomposition temperature but below 300oC is probably sufficient to improve grindability and retain energy value.

  7. Eruptive history and petrochemistry of the Bulusan volcanic complex: Implications for the hydrothermal system and volcanic hazards of Mt. Bulusan, Philippines

    SciTech Connect (OSTI)

    Delfin, F.G. Jr.; Panem, C.C.; Defant, M.J.

    1993-10-01

    Two contrasting conceptual models of the postcaldera magmatic system of the Bulusan volcanic complex are constructed on the basis of a synthesis of volcanological, petrochemical, and petrologic data. These models predict that hydrothermal convection below the complex will occur either in discrete, structurally-focused zones or over a much broader area. Both models, however, agree that hydrothermal fluids at depth will be highly acidic and volcanic-related. Future ash-fall eruptions and mudflows are likely to affect the area previously chosen for possible drilling. Such risks, combined with the expected acidic character of the hydrothermal system, argue against drilling into this system.

  8. A core hole into the hydrothermal system of the Long Valley caldera

    SciTech Connect (OSTI)

    Wollenberg, H.; White, A.; Flexser, S.; Sorey, M.; Farrar, C.

    1987-03-01

    To investigate the present-day hydrothermal system, the ''Shady Rest'' hole was continuously cored 715m into the southwestern moat of the Long Valley caldera. The hole intersected 100m of glacial till and 300m of postcaldera rhyolite before entering the welded Bishop Tuff and bottoming in that unit. A sharp temperature rise over the upper 350m, and near-isothermal conditions below reflect the presence of approx.200/sup 0/C water moving through open, calcite-lined fractures in silicified Early Rhyolite and Bishop Tuff. The depth to the Bishop is the shallowest encountered in holes in the caldera, and the temperatures measured are among the hottest observed in wells drilled within the caldera.

  9. Evaluation of hydrothermal resources of North Dakota. Phase III final technical report

    SciTech Connect (OSTI)

    Harris, K.L.; Howell, F.L.; Wartman, B.L.; Anderson, S.B.

    1982-08-01

    The hydrothermal resources of North Dakota were evaluated. This evaluation was based on existing data on file with the North Dakota Geological Survey (NDGS) and other state and federal agencies, and field and laboratory studies conducted. The principal sources of data used during the study were WELLFILE, the computer library of oil and gas well data developed during the Phase I study, and WATERCAT, a computer library system of water well data assembled during the Phase II study. A field survey of the shallow geothermal gradients present in selected groundwater observation holes was conducted. Laboratory determinations of the thermal conductivity of core samples were done to facilitate heat-flow calculations on those holes-of-convenience cased.

  10. Improvement of thermal properties of low-rank coals treated by hydrothermal process

    SciTech Connect (OSTI)

    Xie, X.F.; Ohki, A.; Maeda, S.

    1999-07-01

    Australian low-rank coals, Loy Yang coal, Yallourn coal and Indonesian Adaro coal are hydrothermally treated at 200-350 C. The simultaneous TG/DTA is used to investigate the thermal properties, which include the volatile release profile under a nitrogen atmosphere and the burning profile under an air atmosphere. It is found that the temperature of volatile matter combustion (Ti1) of the hot water dried coals (upgraded coals) increases with heat treatment temperature (HTT), whereas the temperature of char combustion (Ti2), the temperature of maximum reaction (Tmax) and the temperature of char burn out (Tout) do not have large increase on the HTT. These results suggest that the HWD process can raise the volatile matter ignition temperature, resulting in improving the spontaneous ignition temperature, but it still maintains the original combustion behavior. Results from TG-DTA measurements are consistent with those determined by FTIR and solid state {sup 13}C CP/MAS NMR.

  11. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction

    SciTech Connect (OSTI)

    Song, C.; Saini, A.K.; Wenzel, K.; Huang, L.; Hatcher, P.G.; Schobert, H.H.

    1993-04-01

    This work is a fundamental study of catalytic pretreatments as a potential preconversion step to low-severity liquefaction. The ultimate goal of this work is to provide the basis for the design of an improved liquefaction process and to facilitate our understanding of those processes that occur when coals are initially dissolved. The main objectives of this project are to study the effects of low-temperature pretreatments on coal structure and their impacts on the subsequent liquefaction. The effects of pretreatment temperatures, catalyst type, coal rank and influence of solvent will be examined. We have made significant progress in the following four aspects during this quarterly period: (1) influence of drying and oxidation of coal on the conversion and product distribution in catalytic liquefaction of Wyodak subbituminous coal using a dispersed catalyst; (2) spectroscopic characterization of dried and oxidized Wyodak coal and the insoluble residues from catalytic and thermal liquefaction; (3) the structural alteration of low-rank coal in low-severity liquefaction with the emphasis on the oxygen-containing functional groups; and (4) effects of solvents and catalyst dispersion methods in temperature-programmed and non-programmed liquefaction of three low-rank coals.

  12. Radioactive waste tank Initial Pretreatment Module (IPM) technology development and selection

    SciTech Connect (OSTI)

    Beeman, G.H. [Pacific Northwest Lab., Richland, WA (United States); Hansrote, G. [Westinghouse Hanford Co., Richland, WA (United States)

    1994-03-01

    The processing of nuclear materials at the Hanford Site has resulted in the accumulation of radioactive wastes stored in 177 single- and double-shell tanks (SSTs and DSTs). Fifty-four of the 177 tanks are currently on a tank watch list because organic chemicals and ferrocyanide compounds in the tanks present a potential fire or explosion hazard. In addition, one additional SST is under consideration for placement on the watch list because of high organic concentration. Seventeen of the watch list tanks require pretreatment, and two DST complexant concentrate waste tanks not on the watch list may also need pretreatment. The proposed Initial Pretreatment Module (IPM) is expected to resolve the safety concerns by destroying the organics and ferrocyanide compounds in the tank wastes. The primary objective of the IPM is to destroy or modify constituents that cause safety concerns in the watch list tanks. A secondary objective is to enhance the cost effectiveness of processing the wastes by performing additional processing. Overall, IPM will achieve organic/ferrocyanide destruction (the primary goal) and will assist in the separation of cesium, strontium, and technetium from the tank wastes.

  13. Pretreatment status report on the identification and evaluation of alternative processes. Milestone Report No. C064

    SciTech Connect (OSTI)

    Sutherland, D.G.; Brothers, A.J.; Beary, M.M.; Nicholson, G.A.

    1993-09-01

    The purpose of this report is to support the development and demonstration of a pretreatment system that will (1) destroy organic materials and ferrocyanide in tank wastes so that the wastes can be stored safely, (2) separate the high-activity and low-activity fractions, (3) remove radionuclides and remove or destroy hazardous chemicals in LLW as necessary to meet waste form feed requirements, (4) support development and demonstration of vitrification technology by providing representative feeds to the bench-scale glass melter, (5) support full-scale HLW vitrification operations, including near-term operation, by providing feed that meets specifications, and (6) design and develop pretreatment processes that accomplish the above objectives and ensure compliance with environmental regulations. This report is a presentation of candidate technologies for pretreatment of Hanford Site tank waste. Included are descriptions of studies by the Pacific Northwest Laboratory of Battelle Memorial Institute; Science Applications International Corporation, an independent consultant; BNFL, Inc. representing British technologies; Numatec, representing French technologies; and brief accounts of other relevant activities.

  14. Improved Multivariate Calibration Models for Corn Stover Feedstock and Dilute-Acid Pretreated Corn Stover

    SciTech Connect (OSTI)

    Wolfrum, E. J.; Sluiter, A. D.

    2009-01-01

    We have studied rapid calibration models to predict the composition of a variety of biomass feedstocks by correlating near-infrared (NIR) spectroscopic data to compositional data produced using traditional wet chemical analysis techniques. The rapid calibration models are developed using multivariate statistical analysis of the spectroscopic and wet chemical data. This work discusses the latest versions of the NIR calibration models for corn stover feedstock and dilute-acid pretreated corn stover. Measures of the calibration precision and uncertainty are presented. No statistically significant differences (p = 0.05) are seen between NIR calibration models built using different mathematical pretreatments. Finally, two common algorithms for building NIR calibration models are compared; no statistically significant differences (p = 0.05) are seen for the major constituents glucan, xylan, and lignin, but the algorithms did produce different predictions for total extractives. A single calibration model combining the corn stover feedstock and dilute-acid pretreated corn stover samples gave less satisfactory predictions than the separate models.

  15. Interim data quality objectives for waste pretreatment and vitrification. Revision 1

    SciTech Connect (OSTI)

    Kupfer, M.J.; Conner, J.M.; Kirkbride, R.A.; Mobley, J.R.

    1994-09-15

    The Tank Waste Remediation System (TWRS) is responsible for storing, processing, and immobilizing the Hanford Site tank wastes. Characterization information on the tank wastes is needed so that safety concerns can be addressed, and retrieval, pretreatment, and immobilization processes can be designed, permitted, and implemented. This document describes the near-term tank waste sampling and characterization needs of the Pretreatment, High-Level Waste (HLW) Disposal, and Low-Level Waste (LLW) Disposal Programs to support the TWRS disposal mission. The final DQO (Data Quality Objective) will define specific waste tanks to be sampled, sample timing requirements, an appropriate analytical scheme, and a list of required analytes. This interim DQO, however, focuses primarily on the required analytes since the tanks to be sampled in FY 1994 and early FY 1995 are being driven most heavily by other considerations, particularly safety. The major objective of this Interim DQO is to provide guidance for tank waste characterization requirements for samples taken before completion of the final DQO. The characterization data needs defined herein will support the final DQO to help perform the following: Support the TWRS technical strategy by identification of the chemical and physical composition of the waste in the tanks and Guide development efforts to define waste pretreatment processes, which will in turn define HLW and LLW feed to vitrification processes.

  16. Tank Waste Remediation System tank waste pretreatment and vitrification process development testing requirements assessment

    SciTech Connect (OSTI)

    Howden, G.F.

    1994-10-24

    A multi-faceted study was initiated in November 1993 to provide assurance that needed testing capabilities, facilities, and support infrastructure (sampling systems, casks, transportation systems, permits, etc.) would be available when needed for process and equipment development to support pretreatment and vitrification facility design and construction schedules. This first major report provides a snapshot of the known testing needs for pretreatment, low-level waste (LLW) and high-level waste (HLW) vitrification, and documents the results of a series of preliminary studies and workshops to define the issues needing resolution by cold or hot testing. Identified in this report are more than 140 Hanford Site tank waste pretreatment and LLW/HLW vitrification technology issues that can only be resolved by testing. The report also broadly characterizes the level of testing needed to resolve each issue. A second report will provide a strategy(ies) for ensuring timely test capability. Later reports will assess the capabilities of existing facilities to support needed testing and will recommend siting of the tests together with needed facility and infrastructure upgrades or additions.

  17. Characterizing Microbial Community and Geochemical Dynamics at Hydrothermal Vents Using Osmotically Driven Continuous Fluid Samplers

    SciTech Connect (OSTI)

    Robidart, Julie C.; Callister, Stephen J.; Song, Peng F.; Nicora, Carrie D.; Wheat, Charles G.; Girguis, Peter R.

    2013-05-07

    Microbes play a key role in mediating all aquatic biogeochemical cycles, and ongoing efforts are aimed at better understanding the relationships between microbial phylogenetic and physiological diversity, and habitat physical and chemical characteristics. Establishing such relationships is facilitated by sampling and studying microbiology and geochemistry at the appropriate spatial and temporal scales, to access information on the past and current environmental state that contributes to observed microbial abundances and activities. A modest number of sampling systems exist to date, few of which can be used in remote, harsh environments such as hydrothermal vents, where the ephemeral nature of venting underscores the necessity for higher resolution sampling. We have developed a robust, continuous fluid sampling system for co-registered microbial and biogeochemical analyses. The osmosis-powered bio-osmosampling system (BOSS) use no electricity, collects fluids with daily resolution or better, can be deployed in harsh, inaccessible environments and can sample fluids continuously for up to five years. Here we present a series of tests to examine DNA, RNA and protein stability over time, as well as material compatability, via lab experiments. We also conducted two field deployments at deep-sea hydrothermal vents to assess changes in microbial diversity and protein expression as a function of the physico-chemical environment. Our data reveal significant changes in microbial community composition co-occurring with relatively modest changes in the geochemistry. These data additionally provide new insights into the distribution of an enigmatic sulfur oxidizing symbiont in its free-living state. Data from the second deployment reveal differences in the representation of peptides over time, underscoring the utility of the BOSS in meta-proteomic studies. In concert, these data demonstrate the efficacy of this approach, and illustrate the value of using this method to study microbial and geochemical phenomena.

  18. High-throughput method for optimum solubility screening for homogeneity and crystallization of proteins

    DOE Patents [OSTI]

    Kim, Sung-Hou (Moraga, CA); Kim, Rosalind (Moraga, CA); Jancarik, Jamila (Walnut Creek, CA)

    2012-01-31

    An optimum solubility screen in which a panel of buffers and many additives are provided in order to obtain the most homogeneous and monodisperse protein condition for protein crystallization. The present methods are useful for proteins that aggregate and cannot be concentrated prior to setting up crystallization screens. A high-throughput method using the hanging-drop method and vapor diffusion equilibrium and a panel of twenty-four buffers is further provided. Using the present methods, 14 poorly behaving proteins have been screened, resulting in 11 of the proteins having highly improved dynamic light scattering results allowing concentration of the proteins, and 9 were crystallized.

  19. The role of oxalic acid on the dissolution of granitic sand: an experimental investigation in a hydrothermal flow-through system 

    E-Print Network [OSTI]

    Reed, Christy Lynn

    1990-01-01

    THE ROLE OF OXALIC ACID ON THE DISSOLUTION OF GRANITIC SAND: AN EXPERIMENTAL INVESTIGATION IN A HYDROTHERMAL FLOW-THROUGH SYSTEM A Thesis by CHRISTY LYNN REED Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1990 Major Subject: Geology THE ROLE OF OXALIC ACID ON THE DISSOLUTION OF GRANITIC SAND: AN EXPERIMENTAL INVESTIGATION IN A HYDROTHERMAL FLOW-THROUGH SYSTEM A Thesis...

  20. Development of a high-throughput microfluidic integrated microarray for the detection of chimeric bioweapons.

    SciTech Connect (OSTI)

    Sheppod, Timothy; Satterfield, Brent; Hukari, Kyle W.; West, Jason A. A.; Hux, Gary A.

    2006-10-01

    The advancement of DNA cloning has significantly augmented the potential threat of a focused bioweapon assault, such as a terrorist attack. With current DNA cloning techniques, toxin genes from the most dangerous (but environmentally labile) bacterial or viral organism can now be selected and inserted into robust organism to produce an infinite number of deadly chimeric bioweapons. In order to neutralize such a threat, accurate detection of the expressed toxin genes, rather than classification on strain or genealogical decent of these organisms, is critical. The development of a high-throughput microarray approach will enable the detection of unknowns chimeric bioweapons. The development of a high-throughput microarray approach will enable the detection of unknown bioweapons. We have developed a unique microfluidic approach to capture and concentrate these threat genes (mRNA's) upto a 30 fold concentration. These captured oligonucleotides can then be used to synthesize in situ oligonucleotide copies (cDNA probes) of the captured genes. An integrated microfluidic architecture will enable us to control flows of reagents, perform clean-up steps and finally elute nanoliter volumes of synthesized oligonucleotides probes. The integrated approach has enabled a process where chimeric or conventional bioweapons can rapidly be identified based on their toxic function, rather than being restricted to information that may not identify the critical nature of the threat.

  1. Impact of sensitivity and throughput on optimum selection of a low-background alpha/beta gross counting system

    SciTech Connect (OSTI)

    Seymour, R.; Sergent, F.; Knight, K.; Kyker, B.

    1992-12-31

    Selection of the appropriate low-background counting system is determined by the laboratory`s measurement requirements including the radionuclide activities being measured, required sensitivity, sample volume, sample throughput, operator skill, automation, reporting requirements, budget, reliability, service, and upgrade capability. These requirements are ranked differently by each user. Nevertheless, any selection requires that the sensitivity and sample throughput be evaluated first because these parameters are instrument-specific, cannot be changed after the equipment is purchased and are easily quantified beforehand. Many of the other criteria are also related to sensitivity and affect the choice of instrument. Mathematical expressions, useful in evaluating sensitivity and throughput, are reviewed, extended, and applied to selecting a low-background alpha/beta counting system.

  2. Hydrothermal synthesis of nanocubes of sillenite type compounds for photovoltaic applications and solar energy conversion of carbon dioxide to fuels

    DOE Patents [OSTI]

    Subramanian, Vaidyanathan; Murugesan, Sankaran

    2014-04-29

    The present invention relates to formation of nanocubes of sillenite type compounds, such as bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, via a hydrothermal synthesis process, with the resulting compound(s) having multifunctional properties such as being useful in solar energy conversion, environmental remediation, and/or energy storage, for example. In one embodiment, a hydrothermal method is disclosed that transforms nanoparticles of TiO.sub.2 to bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, optionally loaded with palladium nanoparticles. The method includes reacting titanium dioxide nanotubes with a bismuth salt in an acidic bath at a temperature sufficient and for a time sufficient to form bismuth titanate crystals, which are subsequently annealed to form bismuth titanate nanocubes. After annealing, the bismuth titanate nanocubes may be optionally loaded with nano-sized metal particles, e.g., nanosized palladium particles.

  3. Hydrothermal synthesis of flowerlike SnO{sub 2} nanorod bundles and their application for lithium ion battery

    SciTech Connect (OSTI)

    Wen, Zhigang, E-mail: xh168688@126.com [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China); Department of Chemistry and Chemical Engineering, Qiannan Normal College for Nationalities, Duyun 558000 (China); Zheng, Feng, E-mail: fzheng@mail.csu.edu.cn [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China); Yu, Hongchun; Jiang, Ziran [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Liu, Kanglian [Department of Chemistry and Chemical Engineering, Qiannan Normal College for Nationalities, Duyun 558000 (China)

    2013-02-15

    SnO{sub 2} nanorod bundles were synthesized by hydrothermal method. Field-emission scanning electron microscopy and transmission electron microscopy images showed that the as-prepared flowerlike SnO{sub 2} nanorod bundles consist of tetragonal nanorods with size readily tunable. Their electrochemical properties and application as anode for lithium-ion battery were evaluated by galvanostatic discharge–charge testing and cycle voltammetry. SnO{sub 2} nanorod flowers possess improved discharge capacity of 694 mA h g{sup ?1} up to 40th cycle at 0.1 C. - Highlights: ? The flowerlike SnO{sub 2} nanorod bundles were synthesized by hydrothermal method. ? SnO{sub 2} nanorod bundles with tunable size by controlling concentration of SnCl{sub 4}. ? A probable formation mechanism of SnO{sub 2} nanorod bundles has been proposed.

  4. Luminescent nanocrystals in the rare-earth niobate–zirconia system formed via hydrothermal method

    SciTech Connect (OSTI)

    Hirano, Masanori Dozono, Hayato

    2013-08-15

    Luminescent nanocrystals based on the rare-earth niobates (Ln{sub 3}NbO{sub 7}, Ln=Y, Eu) and zirconia (ZrO{sub 2}) that were composed of 50 mol% Ln{sub 3}NbO{sub 7} and 50 mol% ZrO{sub 2}, were hydrothermally formed as cubic phase under weakly basic conditions at 240 °C. The lattice parameter of the as-prepared nanoparticles corresponding to the composition of Y{sub 3?x}Eu{sub x}NbO{sub 7}–4ZrO{sub 2} that was estimated as a single phase of cubic gradually increased as the content of europium x increased. The existence of small absorbance peaks at 395 and 466 nm corresponding to the Eu{sup 3+7}F{sub 0}?{sup 5}L{sub 6}, and {sup 7}F{sub 0}?{sup 5}D{sub 2} excitation transition, respectively, was clearly observed in the diffuse reflectance spectra of the as-prepared samples containing europium. The optical band gap of the as-prepared samples was in the range from 3.5 to 3.7 eV. The photoluminescence spectra of the as-prepared nanocrystals containing europium showed orange and red luminescences with main peaks at 590 and 610 nm, corresponding to {sup 5}D{sub 0}?{sup 7}F{sub 1} and {sup 5}D{sub 0}?{sup 7}F{sub 2} transitions of Eu{sup 3+}, respectively, under excitation at 395 nm Xe lamp. The emission intensity corresponding to {sup 5}D{sub 0}?{sup 7}F{sub 2} transition increased as heat-treatment temperature rose from 800 to 1200 °C. - Graphical abstract: This graphical abstract shows the excitation and emission spectra and a transmission electron microscopy image of nanocrystals (with composition based on the rare-earth niobates (Ln{sub 3}NbO{sub 7}, Ln=Y, Eu) and zirconia (ZrO{sub 2}) that were composed of 50 mol% Ln{sub 3}NbO{sub 7} and 50 mol% ZrO{sub 2}) formed via hydrothermal route. Display Omitted - Highlights: • Nanocrystals composed of 50 mol% Y{sub 3?x}Eu{sub x}NbO{sub 7} and 50 mol% ZrO{sub 2} was directly formed. • The nanocrystals were hydrothermally formed under weakly basic conditions at 240 °C. • The Y{sub 3}NbO{sub 7} showed an UV-blue and broad-band emission under excitation at 240 nm. • The emission is originated from the niobate octahedral group [NbO{sub 6}]{sup 7?}. • The nanocrystals showed orange and red luminescences ({sup 5}D{sub 0}?{sup 7}F{sub 1} and {sup 5}D{sub 0}?{sup 7}F{sub 2} , Eu{sup 3+})

  5. Behavior of nuclear waste elements during hydrothermal alteration of glassy rhyolite in an active geothermal system: Yellowstone National Park, Wyoming

    SciTech Connect (OSTI)

    Sturchio, N.C.; Seitz, M.G.

    1984-12-31

    The behavior of a group of nuclear waste elements (U, Th, Sr, Zr, Sb, Cs, Ba, and Sm) during hydrothermal alteration of glassy rhyolite is investigated through detailed geochemical analyses of whole rocks, glass and mineral separates, and thermal waters. Significant mobility of U, Sr, Sb, Cs, and Ba is found, and the role of sorption processes in their observed behavior is identified. Th, Zr, and Sm are relatively immobile, except on a microscopic scale. 9 references, 2 figures, 2 tables.

  6. Ion dynamics in nanocrystalline LiMnPO{sub 4} synthesised by novel template free hydrothermal approach

    SciTech Connect (OSTI)

    Vijayan, Lakshmi, E-mail: lakshmivijayan@gmail.com [St. Aloysius' College, Edathua, Alappuzha-689 573, Kerala (India); Cheruku, Rajesh; Govindaraj, G. [Department of Physics, School of Physical, Chemical and Applied Sciences, Pondicherry University, R.V. Nagar, Kalapet, Pondicherry -605 014 (India)

    2014-04-24

    A dense core rectangular shaped nanocrystalline LiMnPO{sub 4} material was synthesized by template free sucrose assisted hydrothermal synthesis. The material possess orthorhombic crystal structure with Pnma, space group having four formula units. The structural characterization was accomplished through X-ray diffraction, thermo gravimetry/differential thermal analysis. Morphology was identified by the SEM, VSM was used to verify the magnetic behavior of the material and electrical characterization was done through impedance spectroscopy and the results were reported.

  7. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-05-15

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles [1-2], among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials [3] and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique [4], including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  8. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-10-12

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles, among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique, including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  9. Radium-thorium disequilibrium and zeolite-water ion exchange in a Yellowstone hydrothermal environment

    SciTech Connect (OSTI)

    Sturchio, N.C.; Bohlke, J.K. (Argonne National Laboratory, IL (USA)); Binz, C.M. (Loras College, Dubuque, IA (USA))

    1989-05-01

    Whole rock samples of hydrothermally altered Biscuit Basin rhyolite from Yellowstone drill cores Y-7 and Y-8 were analyzed for {sup 226}Ra and {sup 230}Th to determine the extent of radioactive disequilibrium and its relation to the rates and mechanisms of element transport in the shallow portion of an active hydrothermal system. The ({sup 226}Ra/{sup 230}Th) activity ratios range from 0.73 to 1.46 and are generally correlated with Th-normalized Ba concentrations (Ba{sub N}). Compositions of clinoptilolite and mordenite in these samples are consistent with ion exchange equilibrium between zeolites and coexisting thermal waters. Average K{sup Ba}{sub d mineral-water} values are 1.0 {center dot} 10{sup 5} mL/g for clinoptilolite and 1.4 {center dot} 10{sup 4} mL/g for mordenite. Apparent diffusivities through matrix porosity estimated for R and Ba range from {approximately}10{sup {minus}12} to {approximately}10{sup {minus}10} cm{sup 2} s{sup {minus}1} in thoroughly zeolitic rhyolite; these rates of diffusion are too low to account for the observed distance scale of ({sup 226}Ra/{sup 230}Th) disequilibrium. The correlated values of ({sup 226}Ra/{sup 230}Th) disequilibrium and Ba{sub N} represent zeolite-water ion exchange equilibrium that is caused by porous flow of water through the rock matrix and by the relatively rapid diffusion of cations within the zeolite lattices. A water flux of at least {approximately}2.5 (cm{sup 3}{sub water}/cm{sup 3}{sub rock}) yr{sup {minus}1} is required to produce measurable ({sup 226}Ra/{sup 230}Th) disequilibrium, whereas at least {approximately}23 (cm{sup 3}{sub water}/cm{sup 3}{sub rock}) yr{sup {minus}1} is required for the sample exhibiting the most extreme ({sup 226}Ra/{sup 230}Th) disequilibrium; these fluxes are much higher than those that can be inferred from net mass transfers of stable species.

  10. A review on biomass classification and composition, cofiring issues and pretreatment methods

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; Shahab Sokhansanj; Christopher T. Wright; Richard D. Boardman

    2011-08-01

    Presently around the globe there is a significant interest in using biomass for power generation as power generation from coal continues to raise environmental concerns. Biomass alone can be used for generation of power which can bring lot of environmental benefits. However the constraints of using biomass alone can include high investments costs for biomass feed systems and also uncertainty in the security of the feedstock supply due to seasonal variations and in most of the countries biomass is dispersed and the infrastructure for biomass supply is not well established. Alternatively cofiring biomass along with coal offer advantages like (a) reducing the issues related to biomass quality and buffers the system when there is insufficient feedstock quantity and (b) costs of adapting the existing coal power plants will be lower than building new systems dedicated only to biomass. However with the above said advantages there exists some technical constrains including low heating and energy density values, low bulk density, lower grindability index, higher moisture and ash content to successfully cofire biomass with coal. In order to successfully cofire biomass with coal, biomass feedstock specifications need to be established to direct pretreatment options that may include increasing the energy density, bulk density, stability during storage and grindability. Impacts on particle transport systems, flame stability, pollutant formation and boiler tube fouling/corrosion must also be minimized by setting feedstock specifications including composition and blend ratios if necessary. Some of these limitations can be overcome by using pretreatment methods. This paper discusses the impact of feedstock pretreatment methods like sizing, baling, pelletizing, briquetting, washing/leaching, torrefaction, torrefaction and pelletization and steam explosion in attainment of optimum feedstock characteristics to successfully cofire biomass with coal.

  11. Mesophilic and thermophilic anaerobic biodegradability of water hyacinth pre-treated at 80 {sup o}C

    SciTech Connect (OSTI)

    Ferrer, Ivet, E-mail: ivet.ferrer@upc.ed [Environmental Engineering Division, Department of Hydraulic, Maritime and Environmental Engineering. Technical University of Catalonia, C/ Jordi Girona 1-3, E-08034 Barcelona (Spain); Palatsi, Jordi [GIRO Technological Centre, Rambla Pompeu Fabra 1, E-08100 Mollet del Valles, Barcelona (Spain); Campos, Elena [Laboratory of Environmental Engineering, Centre UdL-IRTA, Rovira Roure 191, E-25198 Lleida (Spain); Flotats, Xavier [GIRO Technological Centre, Rambla Pompeu Fabra 1, E-08100 Mollet del Valles, Barcelona (Spain); Department of Agrifood Engineering and Biotechnology, Technical University of Catalonia, Parc Mediterrani de la Tecnologia Edifici D-4, E-08860 Castelldefels, Barcelona (Spain)

    2010-10-15

    Water hyacinth (Eichornia crassipes) is a fast growing aquatic plant which causes environmental problems in continental water bodies. Harvesting and handling this plant becomes an issue, and focus has been put on the research of treatment alternatives. Amongst others, energy production through biomethanation has been proposed. The aim of this study was to assess the anaerobic biodegradability of water hyacinth under mesophilic and thermophilic conditions. The effect of a thermal sludge pre-treatment at 80 {sup o}C was also evaluated. To this end, anaerobic biodegradability tests were carried out at 35 {sup o}C and 55 {sup o}C, with raw and pre-treated water hyacinth. According to the results, the thermal pre-treatment enhanced the solubilisation of water hyacinth (i.e. increase in the soluble to total chemical oxygen demand (COD)) from 4% to 12% after 30 min. However, no significant effect was observed on the methane yields (150-190 L CH{sub 4}/kg volatile solids). Initial methane production rates for thermophilic treatments were two fold those of mesophilic ones (6-6.5 L vs. 3-3.5 L CH{sub 4}/kg COD.day). Thus, higher methane production rates might be expected from thermophilic reactors working at short retention times. The study of longer low temperature pre-treatments or pre-treatments at elevated temperatures coupled to thermophilic reactors should be considered in the future.

  12. Nguyen, Son, Capacity and Throughput Optimization in Multi-cell 3G WCDMA Networks Master of Science (Computer Science and Engineering), August 2005, 82 pp., 16 tables, 25

    E-Print Network [OSTI]

    Akl, Robert

    L. Terrell, Dean of the Robert B. Toulouse School of Graduate Studies #12;ACKNOWLEDGMENTS FirstNguyen, Son, Capacity and Throughput Optimization in Multi-cell 3G WCDMA Networks Master of Science;CAPACITY AND THROUGHPUT OPTIMIZATION IN MULTI-CELL 3G WCDMA NETWORKS Son Nguyen, B.S. Thesis Prepared

  13. Sulfur geochemistry of hydrothermal waters in Yellowstone National Park. 1: The origin of thiosulfate in hot spring waters

    SciTech Connect (OSTI)

    Xu, Y.; Schoonen, M.A.A. [SUNY, Stony Brook, NY (United States). Dept. of Geosciences] [SUNY, Stony Brook, NY (United States). Dept. of Geosciences; Nordstrom, D.K.; Cunningham, K.M.; Ball, J.W. [Geological Survey, Boulder, CO (United States). Water Resources Div.] [Geological Survey, Boulder, CO (United States). Water Resources Div.

    1998-12-01

    Thiosulfate (S{sub 2}O{sub 3}{sup 2{minus}}), polythionate (S{sub x}O{sub 6}{sup 2{minus}}), dissolved sulfide (H{sub 2}S), and sulfate (SO{sub 4}{sup 2{minus}}) concentrations in thirty-nine alkaline and acidic springs in Yellowstone National Park (YNP) were determined. The analyses were conducted on site, using ion chromatography for thiosulfate, polythionate, and sulfate, and using colorimetry for dissolved sulfide. Thiosulfate was detected at concentrations typically less than 2 {micro}mol/L in neutral and alkaline chloride springs with low sulfate concentrations (Cl{sup {minus}}/SO{sub 4}{sup 2{minus}} > 25). The thiosulfate concentration levels are about one to two orders of magnitude lower than the concentration of dissolved sulfide in these springs. In most acid sulfate and acid sulfate-chloride springs (Cl{sup {minus}}/SO{sub 4}{sup 2{minus}} < 10), thiosulfate concentrations were also typically lower than 2 {micro}mol/L. However, in some chloride springs enriched with sulfate (Cl{sup {minus}}/SO{sub 4}{sup 2{minus}} between 10 and 25), thiosulfate was found at concentrations ranging from 9 to 95 {micro}mol/L, higher than the concentrations of dissolved sulfide in these waters. Polythionate was detected only in Cinder Pool, Norris Geyser basin, at concentrations up to 8 {micro}mol/L, with an average S-chain-length from 4.1 to 4.9 sulfur atoms. The results indicate that no thiosulfate occurs in the deeper parts of the hydrothermal system. Thiosulfate may form, however, from (1) hydrolysis of native sulfur by hydrothermal solutions in the shallower parts (<50 m) of the system, (2) oxidation of dissolved sulfide upon mixing of a deep hydrothermal water with aerated shallow groundwater, and (3) the oxidation of dissolved sulfide by dissolved oxygen upon discharge of the hot spring. Upon discharge of a sulfide-containing hydrothermal water, oxidation proceeds rapidly as atmospheric oxygen enters the water. The transfer of oxygen is particularly effective if the hydrothermal discharge is turbulent and has a large surface area.

  14. Petrology and geochemistry of Alto Peak, a vapor-cored hydrothermal system, Leyte Province, Philippines

    SciTech Connect (OSTI)

    Reyes, A.G.; Giggenbach, W.F.; Saleras, J.R.M.; Salonga, N.D.; Vergara, M.C.

    1993-10-01

    Based on detailed petrological information on secondary mineral assemblages and the composition of fluids trapped in inclusions and discharged from five wells, the Alto Peak geothermal field was found to represent a combined vapor and liquid-dominated system. A central core or chimney, with a diameter of about 1 km, a height of some 3 km and occupied by a high gas vapor (1.1 to 5.6 molal CO{sub 2}), is surrounded by an envelope of intermediate salinity water (7,000 mg/kg Cl) with temperatures between 250 and 350 C. The transition from purely vapor-dominated to liquid-dominated zones takes place via two-phase zones occupied by fluid mixtures of highly variable compositions. Much of the lower temperature, mature neutral pH Cl water is likely to have formed during an earlier stage in the evolution of the system. High temperatures of > 300 C, and associated alteration, are limited to wells AP-1D and the lower parts of AP-2D and are ascribed to re-heating by recent magmatic intrusions. The isotopic composition of the well discharges suggests that they contain some 40 to 50% of magmatic water. Alto Peak is considered a typical example of hydrothermal systems associated with many dormant volcanoes.

  15. Hydrothermal growth and morphology evolution of CePO{sub 4} aggregates by a complexing method

    SciTech Connect (OSTI)

    Ma Lin [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Chen Weixiang [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)], E-mail: weixiangchen@css.zju.edu.cn; Zheng Yifan [Institute of Industrial Catalysis, Zhejiang University of Technology, Hangzhou 310014 (China); Xu Zhude [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)

    2008-11-03

    A facile hydrothermal route assisted by Na{sub 2}H{sub 2}EDTA (ethylenediaminetetraacetic acid disodium) has been successfully developed to prepare uniform cerium phosphate (CePO{sub 4}) aggregates with different morphologies, such as peanut-like and spindle-like. It was found that the as-prepared uniform CePO{sub 4} aggregates were constructed with many nearly parallel aligned nanorods. The molar ratio of EDTA/Ce{sup 3+}, solution pH and reaction time had great influences on the morphologies and sizes of the CePO{sub 4} samples. In our process of synthesis, Na{sub 2}H{sub 2}EDTA played important roles as complexing reagent and inducing agent on the formation of CePO{sub 4} aggregates. The possible growth mechanism for CePO{sub 4} aggregates was presented. Ce{sub 0.9}Tb{sub 0.1}PO{sub 4} aggregates with different morphologies were also prepared and their photoluminescence properties were characterized.

  16. Textural properties of synthetic nano-calcite produced by hydrothermal carbonation of calcium hydroxide

    E-Print Network [OSTI]

    Montes-Hernandez, German; Charlet, L; Tisserand, Delphine; Renard, F

    2008-01-01

    The hydrothermal carbonation of calcium hydroxide (Ca(OH)2) at high pressure of CO2 (initial PCO2 1/4 55 bar) and moderate to high temperature (30 and 90 1C) was used to synthesize fine particles of calcite. This method allows a high carbonation efficiency (about 95% of Ca(OH)2-CaCO3 conversion), a significant production rate (48 kg/m3 h) and high purity of product (about 96%). However, the various initial physicochemical conditions have a strong influence on the crystal size and surface area of the synthesized calcite crystals. The present study is focused on the estimation of the textural properties of synthesized calcite (morphology, specific surface area, average particle size, particle size distribution and particle size evolution with reaction time), using Rietveld refinements of X-ray diffraction (XRD) spectra, Brunauer-Emmett-Teller (BET) measurements, and scanning electron microscope (SEM) and transmission electron microscope (TEM) observations. This study demonstrate that the pressure, the temperatu...

  17. Integrated crystal mounting and alignment system for high-throughput biological crystallography

    DOE Patents [OSTI]

    Nordmeyer, Robert A.; Snell, Gyorgy P.; Cornell, Earl W.; Kolbe, William; Yegian, Derek; Earnest, Thomas N.; Jaklevic, Joseph M.; Cork, Carl W.; Santarsiero, Bernard D.; Stevens, Raymond C.

    2005-07-19

    A method and apparatus for the transportation, remote and unattended mounting, and visual alignment and monitoring of protein crystals for synchrotron generated x-ray diffraction analysis. The protein samples are maintained at liquid nitrogen temperatures at all times: during shipment, before mounting, mounting, alignment, data acquisition and following removal. The samples must additionally be stably aligned to within a few microns at a point in space. The ability to accurately perform these tasks remotely and automatically leads to a significant increase in sample throughput and reliability for high-volume protein characterization efforts. Since the protein samples are placed in a shipping-compatible layered stack of sample cassettes each holding many samples, a large number of samples can be shipped in a single cryogenic shipping container.

  18. Thicker, more efficient superconducting strip-line detectors for high throughput macromolecules analysis

    SciTech Connect (OSTI)

    Casaburi, A.; Ejrnaes, M.; Cristiano, R.; Zen, N.; Ohkubo, M.; Pagano, S.

    2011-01-10

    Fast detectors with large area are required in time-of-flight mass spectrometers for high throughput analysis of biological molecules. We fabricated and characterized subnanosecond 1x1 mm{sup 2} NbN superconducting strip-line detectors. The influence of the strip-line thickness on the temporal characteristics and efficiency of the detector for the impacts of keV accelerated molecules is investigated. We find that the increase of thickness improves both efficiency and response time. In the thicker sample we achieved a rise time of 380 ps, a fall time of 1.38 ns, and a higher count rate. The physics involved in this behavior is investigated.

  19. Development and operation of a high-throughput accurate-wavelength lens-based spectrometera

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bell, Ronald E.

    2014-11-01

    A high-throughput spectrometer for the 400-820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm-1 grating is matched with fast f /1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy ? 0.075 arc seconds. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount behind the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, andmore »wavelength calibration.« less

  20. Enabling a High Throughput Real Time Data Pipeline for a Large Radio Telescope Array with GPUs

    E-Print Network [OSTI]

    Edgar, R G; Dale, K; Mitchell, D A; Ord, S M; Wayth, R B; Pfister, H; Greenhill, L J

    2010-01-01

    The Murchison Widefield Array (MWA) is a next-generation radio telescope currently under construction in the remote Western Australia Outback. Raw data will be generated continuously at 5GiB/sec. This high throughput motivates the development of on-site, real time processing and reduction in preference to archiving, transport and off-line processing. Maintaining real time operation will require a sustained performance of around 2.5TFLOP/sec (including convolutions, FFTs, interpolations and matrix multiplications). We describe a scalable heterogeneous computing pipeline implementation, exploiting both the high computing density and FLOP-per-Watt ratio of modern GPUs. The architecture is highly parallel within and across nodes, with all major processing elements performed by GPUs. Necessary scatter-gather operations along the pipeline are loosely synchronized and implemented in MPI. The MWA will be a frontier scientific instrument and a pathfinder for planned peta- and exascale facilities.

  1. High-throughput, dual probe biological assays based on single molecule detection

    DOE Patents [OSTI]

    Hollars, Christopher W. (Brentwood, CA); Huser, Thomas R. (Livermore, CA); Lane, Stephen M. (Oakland, CA); Balhorn, Rodney L. (Livermore, CA); Bakajin, Olgica (San Leandro, CA); Darrow, Christopher (Pleasanton, CA); Satcher, Jr., Joe H. (Patterson, CA)

    2006-07-11

    A method and apparatus with the sensitivity to detect and identify single target molecules through the localization of dual, fluorescently labeled probe molecules. This can be accomplished through specific attachment of the taget to a surface or in a two-dimensional (2D) flowing fluid sheet having approximate dimensions of 0.5 .mu.m.times.100 .mu.m.times.100 .mu.m. A device using these methods would have 10.sup.3 10.sup.4 greater throughput than previous one-dimensional (1D) micro-stream devices having 1 .mu.m.sup.3 interrogation volumes and would for the first time allow immuno- and DNA assays at ultra-low (femtomolar) concentrations to be performed in short time periods (.about.10 minutes). The use of novel labels (such as metal or semiconductor nanoparticles) may be incorporated to further extend the sensitivity possibly into the attomolar range.

  2. Development and operation of a high-throughput accurate-wavelength lens-based spectrometera

    SciTech Connect (OSTI)

    Bell, Ronald E.

    2014-11-01

    A high-throughput spectrometer for the 400-820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm-1 grating is matched with fast f /1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy ? 0.075 arc seconds. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount behind the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, and wavelength calibration.

  3. Development and Operation of High-throughput Accurate-wavelength Lens-based Spectrometer

    SciTech Connect (OSTI)

    Bell, Ronald E

    2014-07-01

    A high-throughput spectrometer for the 400-820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm-1 grating is matched with fast f /1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy < 0.075 arc seconds. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount behind the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, and wavelength calibration.

  4. Development and operation of a high-throughput accurate-wavelength lens-based spectrometer

    SciTech Connect (OSTI)

    Bell, Ronald E.

    2014-11-15

    A high-throughput spectrometer for the 400–820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm{sup ?1} grating is matched with fast f/1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy ?0.075 arc sec. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount at the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, and wavelength calibration.

  5. Heterogeneous High Throughput Scientific Computing with APM X-Gene and Intel Xeon Phi

    E-Print Network [OSTI]

    David Abdurachmanov; Brian Bockelman; Peter Elmer; Giulio Eulisse; Robert Knight; Shahzad Muzaffar

    2014-10-10

    Electrical power requirements will be a constraint on the future growth of Distributed High Throughput Computing (DHTC) as used by High Energy Physics. Performance-per-watt is a critical metric for the evaluation of computer architectures for cost- efficient computing. Additionally, future performance growth will come from heterogeneous, many-core, and high computing density platforms with specialized processors. In this paper, we examine the Intel Xeon Phi Many Integrated Cores (MIC) co-processor and Applied Micro X-Gene ARMv8 64-bit low-power server system-on-a-chip (SoC) solutions for scientific computing applications. We report our experience on software porting, performance and energy efficiency and evaluate the potential for use of such technologies in the context of distributed computing systems such as the Worldwide LHC Computing Grid (WLCG).

  6. Development and operation of a high-throughput accurate-wavelength lens-based spectrometera)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bell, Ronald E. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543, USA

    2014-11-01

    A high-throughput spectrometer for the 400-820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm-1 grating is matched with fast f /1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy < 0.075 arc seconds. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount behind the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, and wavelength calibration.

  7. Cross Calibration of Telescope Optical Throughput Efficiencies using Reconstructed Shower Energies for the Cherenkov Telescope Array

    E-Print Network [OSTI]

    Mitchell, A M W; Hofmann, W; Bernloehr, K

    2015-01-01

    For reliable event reconstruction of Imaging Atmospheric Cherenkov Telescopes (IACTs), calibration of the optical throughput efficiency is required. Within current facilities, this is achieved through the use of ring shaped images generated by muons. Here, a complementary approach is explored, achieving cross calibration of elements of IACT arrays through pairwise comparisons between telescopes, focussing on its applicability to the upcoming Cherenkov Telescope Array (CTA). Intercalibration of telescopes of a particular type using eventwise comparisons of shower image amplitudes has previously been demonstrated to recover the relative telescope optical responses. A method utilising the reconstructed energy as an alternative to image amplitude is presented, enabling cross calibration between telescopes of varying types within an IACT array. Monte Carlo studies for two plausible CTA layouts have shown that this calibration procedure recovers the relative telescope response efficiencies at the few percent level.

  8. Integrated crystal mounting and alignment system for high-throughput biological crystallography

    DOE Patents [OSTI]

    Nordmeyer, Robert A. (San Leandro, CA); Snell, Gyorgy P. (Richmond, CA); Cornell, Earl W. (Antioch, CA); Kolbe, William F. (Moraga, CA); Yegian, Derek T. (Oakland, CA); Earnest, Thomas N. (Berkeley, CA); Jaklevich, Joseph M. (Lafayette, CA); Cork, Carl W. (Walnut Creek, CA); Santarsiero, Bernard D. (Chicago, IL); Stevens, Raymond C. (La Jolla, CA)

    2007-09-25

    A method and apparatus for the transportation, remote and unattended mounting, and visual alignment and monitoring of protein crystals for synchrotron generated x-ray diffraction analysis. The protein samples are maintained at liquid nitrogen temperatures at all times: during shipment, before mounting, mounting, alignment, data acquisition and following removal. The samples must additionally be stably aligned to within a few microns at a point in space. The ability to accurately perform these tasks remotely and automatically leads to a significant increase in sample throughput and reliability for high-volume protein characterization efforts. Since the protein samples are placed in a shipping-compatible layered stack of sample cassettes each holding many samples, a large number of samples can be shipped in a single cryogenic shipping container.

  9. Metalloproteomics: High-Throughput Structural and Functional Annotation of Proteins in Structural Genomics

    SciTech Connect (OSTI)

    Shi,W.; Zhan, C.; Lgnatov, A.; Manjasetty, B.; Marinkovic, N.; Sullivan, M.; Huang, R.; Chance, M.; Li, H.; et al.

    2005-01-01

    A high-throughput method for measuring transition metal content based on quantitation of X-ray fluorescence signals was used to analyze 654 proteins selected as targets by the New York Structural GenomiX Research Consortium. Over 10% showed the presence of transition metal atoms in stoichiometric amounts; these totals as well as the abundance distribution are similar to those of the Protein Data Bank. Bioinformatics analysis of the identified metalloproteins in most cases supported the metalloprotein annotation; identification of the conserved metal binding motif was also shown to be useful in verifying structural models of the proteins. Metalloproteomics provides a rapid structural and functional annotation for these sequences and is shown to be {approx}95% accurate in predicting the presence or absence of stoichiometric metal content. The project's goal is to assay at least 1 member from each Pfam family; approximately 500 Pfam families have been characterized with respect to transition metal content so far.

  10. High-throughput generation, optimization and analysis of genome-scale metabolic models.

    SciTech Connect (OSTI)

    Henry, C. S.; DeJongh, M.; Best, A. A.; Frybarger, P. M.; Linsay, B.; Stevens, R. L.

    2010-09-01

    Genome-scale metabolic models have proven to be valuable for predicting organism phenotypes from genotypes. Yet efforts to develop new models are failing to keep pace with genome sequencing. To address this problem, we introduce the Model SEED, a web-based resource for high-throughput generation, optimization and analysis of genome-scale metabolic models. The Model SEED integrates existing methods and introduces techniques to automate nearly every step of this process, taking {approx}48 h to reconstruct a metabolic model from an assembled genome sequence. We apply this resource to generate 130 genome-scale metabolic models representing a taxonomically diverse set of bacteria. Twenty-two of the models were validated against available gene essentiality and Biolog data, with the average model accuracy determined to be 66% before optimization and 87% after optimization.

  11. Acoustic transfer of protein crystals from agarose pedestals to micromeshes for high-throughput screening

    SciTech Connect (OSTI)

    Cuttitta, Christina M.; Ericson, Daniel L.; Scalia, Alexander; Roessler, Christian G.; Teplitsky, Ella; Joshi, Karan; Campos, Olven; Agarwal, Rakhi; Allaire, Marc; Orville, Allen M.; Sweet, Robert M.; Soares, Alexei S.

    2015-01-01

    An acoustic high-throughput screening method is described for harvesting protein crystals and combining the protein crystals with chemicals such as a fragment library. Acoustic droplet ejection (ADE) is an emerging technology with broad applications in serial crystallography such as growing, improving and manipulating protein crystals. One application of this technology is to gently transfer crystals onto MiTeGen micromeshes with minimal solvent. Once mounted on a micromesh, each crystal can be combined with different chemicals such as crystal-improving additives or a fragment library. Acoustic crystal mounting is fast (2.33 transfers s{sup ?1}) and all transfers occur in a sealed environment that is in vapor equilibrium with the mother liquor. Here, a system is presented to retain crystals near the ejection point and away from the inaccessible dead volume at the bottom of the well by placing the crystals on a concave agarose pedestal (CAP) with the same chemical composition as the crystal mother liquor. The bowl-shaped CAP is impenetrable to crystals. Consequently, gravity will gently move the crystals into the optimal location for acoustic ejection. It is demonstrated that an agarose pedestal of this type is compatible with most commercially available crystallization conditions and that protein crystals are readily transferred from the agarose pedestal onto micromeshes with no loss in diffraction quality. It is also shown that crystals can be grown directly on CAPs, which avoids the need to transfer the crystals from the hanging drop to a CAP. This technology has been used to combine thermolysin and lysozyme crystals with an assortment of anomalously scattering heavy atoms. The results point towards a fast nanolitre method for crystal mounting and high-throughput screening.

  12. been the key to their success is the use of high-throughput experiments to assess various zeo-

    E-Print Network [OSTI]

    Silver, Whendee

    it and the resulting pore structure. It could be that the hexamethonium molecules pack in such a way as to providebeen the key to their success is the use of high- throughput experiments to assess various zeo and shape of the resulting pores cor- responds to the size and shape of the organic molecule. ITQ-33

  13. Implementation of a High-Throughput Screen for Identifying Small Molecules to Activate the Keap1-Nrf2-ARE Pathway

    E-Print Network [OSTI]

    Wu, Kai Connie; McDonald, Peter R.; Liu, Jie Jerry; Chaguturu, Rathnam; Klaassen, Curtis D.

    2012-10-08

    of these genes. To identify Nrf2 activators for the treatment of oxidative/electrophilic stress-induced diseases, the present study developed a high-throughput assay to evaluate Nrf2 activation using AREc32 cells that contain a luciferase gene under the control...

  14. Storage Performance Virtualization via Throughput and Latency Control Jianyong Zhang Alma Riska Anand Sivasubramaniam Qian Wang Erik Riedel

    E-Print Network [OSTI]

    Riska, Alma

    Storage Performance Virtualization via Throughput and Latency Control Jianyong Zhang Alma Riska and managing storage systems. A consequence of this trend is the need to serve multiple users that can be built on top of an existing storage utility. This frame- work uses a low-level feedback

  15. 4350 IEEE TRANSACTIONS ON WIRELESS COMMUNICATIONS, VOL. 8, NO. 8, AUGUST 2009 Outage, Local Throughput, and Capacity of

    E-Print Network [OSTI]

    Haenggi, Martin

    4350 IEEE TRANSACTIONS ON WIRELESS COMMUNICATIONS, VOL. 8, NO. 8, AUGUST 2009 Outage, Local Throughput, and Capacity of Random Wireless Networks Martin Haenggi, Senior Member, IEEE Abstract--Outage parameter, the so- called spatial contention, is defined. It measures the slope of the outage probability

  16. PIPELINED PARALLEL ARCHITECTURE FOR HIGH THROUGHPUT MAP DETECTORS Ruwan Ratnayake, Gu-Yeon Wei and Aleksandar Kavcic

    E-Print Network [OSTI]

    Kavcic, Aleksandar

    PIPELINED PARALLEL ARCHITECTURE FOR HIGH THROUGHPUT MAP DETECTORS Ruwan Ratnayake, Gu-Yeon Wei performance close to the channel capacity limits. Deep pipelined architecture for the forward only method, where as FB-BCJR only allow sequential state metric computations. Parallelism facilitates pipelining, re

  17. A GPU-INSPIRED SOFT PROCESSOR FOR HIGH-THROUGHPUT ACCELERATION Jeffrey Kingyens and J. Gregory Steffan

    E-Print Network [OSTI]

    Steffan, J. Gregory

    ) is realizable on an XtremeData XD1000 FPGA-based accelerator system, we demonstrate that our soft processor can in the scientific, financial, and other data-driven arenas that will use them. Developing an accelerator designA GPU-INSPIRED SOFT PROCESSOR FOR HIGH-THROUGHPUT ACCELERATION Jeffrey Kingyens and J. Gregory

  18. Utility Maximization for Resolving Throughput/Reliability Trade-offs in an Unreliable Network with Multipath Routing

    E-Print Network [OSTI]

    Utility Maximization for Resolving Throughput/Reliability Trade-offs in an Unreliable Network can be characterized by some utility function, the goal of balancing competing requirements for each user as well as across different users is to maximize the aggregate utility. The framework assumes

  19. Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio computations

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio (>700 Wh/kg) cathode materials for lithium-ion batteries. 1 Introduction The widespread use of lithium compounds. Testing previously known lithium-containing compounds for battery properties can lead

  20. A Cell-Based High-Throughput Screen for Novel Chemical Inducers of Fetal Hemoglobin for Treatment of Hemoglobinopathies

    E-Print Network [OSTI]

    Peterson, Kenneth R.; Costa, Flá via C.; Fedosyuk, Halyna; Neades, Renee Y.; Chazelle, Allen M.; Zelenchuk, Lesya; Fonteles, Andrea H.; Dalal, Parmita; Roy, Anuradha; Chaguturu, Rathnam; Li, Biaoru; Pace, Betty S.

    2014-09-16

    , with minimal off-target effects, continues to be an elusive goal. One hurdle has been an assay amenable to a high-throughput screen (HTS) of chemicals that displays a robust c-globin off-on switch to identify potential lead compounds. Assay systems developed...

  1. Modelling the Impact of User Mobility on the Throughput in Networks of Wireless 802.11 LANs

    E-Print Network [OSTI]

    van der Mei, Rob

    Modelling the Impact of User Mobility on the Throughput in Networks of Wireless 802.11 LANs Sandjai@feweb.vu.nl Abstract-- The wireless LAN technology 802.11, also called Wi-Fi, offers high speed wireless Internet by simulation results. I. INTRODUCTION The wireless LAN (WLAN) industry is one of the fastest growing segments

  2. PIPA: A High-Throughput Pipeline for Protein Function Annotation Chenggang Yu, Valmik Desai, Nela Zavaljevski, and Jaques Reifman

    E-Print Network [OSTI]

    PIPA: A High-Throughput Pipeline for Protein Function Annotation Chenggang Yu, Valmik Desai, Nela of multisource predictions. We developed Pipeline for Protein Annotation (PIPA), a genome-wide protein function annotation pipeline that runs in a high-performance computing environment. PIPA integrates different tools

  3. Modification of Bi:YIG film properties by substrate surface ion pre-treatment

    SciTech Connect (OSTI)

    Shaposhnikov, A.N.; Prokopov, A.R.; Karavainikov, A.V.; Berzhansky, V.N.; Mikhailova, T.V.; Kotov, V.A.; Balabanov, D.E.; Sharay, I.V.; Salyuk, O.Y.; Vasiliev, M.; Golub, V.O.

    2014-07-01

    Highlights: • Effects of substrates ion beam treatment on magnetoptical properties Bi:YIG films. • Substrate surface damage results in sign inversion of the magneto-optical effects. • Atomically smooth films growth takes place on low energy ions treated substrates. • High energy ions treatment results in selective nucleation mechanism of the growth. - Abstract: The effect of a controlled ion beam pre-treatment of (1 1 1)-oriented Gd{sub 3}Ga{sub 5}O{sub 12} substrates on the magneto-optical properties and surface morphology of the ultrathin bismuth-substituted yttrium–iron garnet films with a composition Bi{sub 2.8}Y{sub 0.2}Fe{sub 5}O{sub 12} was studied. It has been shown that the observed sign inversion of magneto-optical effects (Faraday rotation and magnetic circular dichroism) observed in films that were deposited on the GGG substrate pre-treated by 1 keV and 4 keV Ar{sup +} ion beams is a result of the substrate surface amorphization caused by the ion bombardment.

  4. Fermentation of dilute acid pretreated Populus by Clostridium thermocellum, Caldicellulosiruptor bescii, and Caldicellulosiruptor obsidiansis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yee, Kelsey L.; Rodriguez, Jr., Miguel; Hamilton, Choo Yieng; Hamilton-Brehm, Scott D.; Thompson, Olivia A.; Elkins, James G.; Davison, Brian H.; Mielenz, Jonathan R.

    2015-07-25

    Consolidated bioprocessing (CBP), which merges enzyme production, biomass hydrolysis, and fermentation into a single step, has the potential to become an efficient and economic strategy for the bioconversion of lignocellulosic feedstocks to transportation fuels or chemicals. In this study, we evaluated Clostridium thermocellum, Caldicellulosiruptor bescii, and Caldicellulosiruptor obsidiansis, three , thermophilic,cellulolytic, mixed-acid fermenting candidate CBP microorganisms, for their fermentation capabilities using dilute acid pretreated Populus as a model biomass feedstock. Under pH controlled, anaerobic fermentation conditions, each candidate successfully digested a minimum of 75% of the cellulose from dilute acid pretreated Populus, as indicated by an increase in planktonic cellsmore »and end-product metabolites and a concurrent decrease in glucan content. C. thermocellum, which employs a cellulosomal approach to biomass degradation, required 120 hours to achieve 75% cellulose utilization. In contrast, the non-cellulosomal, secreted hydrolytic enzyme system of the Caldicellulosiruptor sp. required 300 hours to achieve similar results. End-point fermentation conversions for C. thermocellum, C. bescii, and C. obsidiansis were determined to be 0.29, 0.34, and 0.38 grams of total metabolites per gram of loaded glucan, respectively. This data provide a starting point for future strain engineering efforts that can serve to improve the biomass fermentation capabilities of these three promising candidate CBP platforms.« less

  5. In-tank pretreatment of high-level tank wastes: The SIPS system

    SciTech Connect (OSTI)

    Reich, M.; Powell, J.; Barletta, R.

    1996-03-01

    A new approach, termed SIPS (Small In-Tank Processing System), that enables the in-tank processing and separation of high-level tank wastes into high-level waste (HLW) and low-level waste (LLW) streams that are suitable for vitrification, is described. Presently proposed pretreatment systems, such as enhanced sludge washing (ESW) and TRUEX, require that the high-level tank wastes be retrieved and pumped to a large, centralized processing facility, where the various waste components are separated into a relatively small, radioactively concentrated stream (HLW), and a relatively large, predominantly non-radioactive stream (LLW). In SIPS, a small process module, typically on the order of 1 meter in diameter and 4 meters in length, is inserted into a tank. During a period of approximately six months, it processes the solid/liquid materials in the tank, separating them into liquid HLW and liquid LLW output streams that are pumped away in two small diameter (typically 3 cm o.d.) pipes. The SIPS concept appears attractive for pretreating high level wastes, since it would: (1) process waste in-situ in the tanks, (2) be cheaper and more reliable than a larger centralized facility, (3) be quickly demonstrable at full scale, (4) have less technical risk, (5) avoid having to transfer unstable slurries for long distances, and (6) be simple to decommission and dispose of. Further investigation of the SIPS concept appears desirable, including experimental testing and development of subscale demonstration units.

  6. Suppression of alkylating agent induced cell transformation and gastric ulceration by low-dose alkylating agent pretreatment

    SciTech Connect (OSTI)

    Onodera, Akira; Department of Pharmaceutical Sciences, Kobegakuin University, 1-1-3 Minatojima, Chuo-ku, Kobe 650-8586 ; Kawai, Yuichi; Kashimura, Asako; Ogita, Fumiya; Tsutsumi, Yasuo; Itoh, Norio

    2013-06-14

    Highlights: •Low-dose MNNG pretreatment suppresses high-dose MNNG induced in vitro transformation. •Gastric ulcers induced by high-dose MNNG decreased after low-dose MNNG pretreatment. •Efficacy of low-dose MNNG related to resistance of mutation and oxidative stress. -- Abstract: Exposure to mild stress by chemicals and radiation causes DNA damage and leads to acquired stress resistance. Although the linear no-threshold (LNT) model of safety assessment assumes risk from any dose, evidence from radiological research demonstrates a conflicting hormetic phenomenon known as the hormesis effect. However, the mechanisms underlying radiation hormesis have not yet been clarified, and little is known about the effects of low doses of chemical carcinogens. We analyzed the efficacy of pretreatment with low doses of the alkylating agent N-methyl-N?-nitro-N-nitrosoguanidine (MNNG) on the subsequent induction of cell transformation and gastric ulceration by high-dose MNNG. We used an in vitro Balb/3T3 A31-1-1 cell transformation test and monitored the formation of gastric ulcers in 5-week-old male ICR mice that were administered MNNG in drinking water. The treatment concentrations of MNNG were determined by the cell survival rate and past reports. For low-dose in vitro and in vivo experiments, MNNG was used at 0.028 ?M, and 2.8 ?g/mL, respectively. The frequency of cell transformation induced by 10 ?m MNNG was decreased by low-dose MNNG pretreatment to levels similar to that of spontaneous transformation. In addition, reactive oxygen species (ROS) and mutation frequencies induced by 10 ?m MNNG were decreased by low-dose MNNG pretreatment. Importantly, low-dose MNNG pretreatment had no effect on cell proliferation. In vivo studies showed that the number of gastric ulcers induced by 1 mg/mL MNNG decreased after low-dose MNNG pretreatment. These data indicate that low-dose pretreatment with carcinogens may play a beneficial role in the prevention of chemical toxicity under specified conditions.

  7. Chemical and isotopic kinetics of sulfate reduction by organic matter under hydrothermal conditions

    SciTech Connect (OSTI)

    Kaiser, C.J.

    1988-01-01

    This study investigated the feasibility of nonbacterial sulfate reduction by organic matter in geologic environments. Sulfate is reduced by dextrose under acidic conditions at temperatures of 230-270 C. Reaction products include sulfide and organic-sulfur compounds; sulfite, thiosulfate and elemental sulfur were not detected. The rate law for the initial one- or two-electron reduction of sulfate at 250C is first-order in bisulfate and about one-half-order in initial dextrose concentration, and shows a very strong dependence on pH. The kinetics of sulfate reduction by fructose at 250C are virtually the same. The lack of sulfate reduction by formaldehyde, methanol, ethanol and acetic acid at 250 C indicates that the reducing power of dextrose and fructose cannot be attributed to carbonyl, carboxyl or hydroxyl functional groups. The form of the rate law for sulfate reduction by dextrose and the presence of an induction period rather suggest that the initial reduction of sulfate occurs with free radicals derived from the thermal decomposition of the hexoses or their alteration products. The inferred sulfate-reduction reaction mechanism suggest that aqueous sulfate may be reduced to sulfide in geologic environments such as deep sedimentary basins. The observed acid-catalysis of the reaction in the laboratory may be supplanted by clay-mineral catalysis in geologic environments. Sulfur isotopes are fractionated during the reduction of sulfate by dextrose under hydrothermal conditions. Computer simulations of the isotopic evolution of the experiments suggest that sulfate-sulfide isotopic exchange largely controls the isotopic composition of sulfate and sulfide. The extent of isotopic fractionation due solely to sulfate reduction thus cannot be determined from the experiments

  8. Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources

    E-Print Network [OSTI]

    California at Riverside, University of

    , a powerful greenhouse gas that feeds global climate change. Biomass is the only sustainable resource that canComparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar States b Center for Environmental Research and Technology, University of California, Riverside, CA 92506

  9. Pretreatment anti-Mullerian hormone predicts for loss of ovarian function after chemotherapy for early breast cancer

    E-Print Network [OSTI]

    St Andrews, University of

    AMH Ovarian reserve Chemotherapy Amenorrhoea Fertility Breast cancer Abstract Aim: Improving survivalPretreatment anti-Mu¨llerian hormone predicts for loss of ovarian function after chemotherapy for early breast cancer Richard A. Anderson a, , Mikkel Rosendahl b , Thomas W. Kelsey c , David A. Cameron

  10. Anaerobic oxidation of short-chain alkanes in hydrothermal sediments: potential influences on sulfur cycling and microbial diversity

    SciTech Connect (OSTI)

    Adams, MM; Hoarfrost, AL; Bose, A; Joye, SB; Girguis, PR

    2013-05-14

    Short-chain alkanes play a substantial role in carbon and sulfur cycling at hydrocarbon-rich environments globally, yet few studies have examined the metabolism of ethane (C-2), propane (C-3), and butane (C-4) in anoxic sediments in contrast to methane (C-1). In hydrothermal vent systems, short-chain alkanes are formed over relatively short geological time scales via thermogenic processes and often exist at high concentrations. The sediment-covered hydrothermal vent systems at Middle Valley (MV Juan de Fuca Ridge) are an ideal site for investigating the anaerobic oxidation of C-1-C-4 alkanes, given the elevated temperatures and dissolved hydrocarbon species characteristic of these metalliferous sediments. We examined whether MV microbial communities oxidized C-1-C-4 alkanes under mesophilic to thermophilic sulfate-reducing conditions. Here we present data from discrete temperature (25, 55, and 75 degrees C) anaerobic batch reactor incubations of MV sediments supplemented with individual alkanes. Co-registered alkane consumption and sulfate reduction (SR) measurements provide clear evidence for C-1-C-4 alkane oxidation linked to SR over time and across temperatures. In these anaerobic batch reactor sediments, 16S ribosomal RNA pyrosequencing revealed that Deltaproteobacteria, particularly a novel sulfate-reducing lineage, were the likely phylotypes mediating the oxidation of C-2-C-4 alkanes. Maximum C-1-C-4 alkane oxidation rates occurred at 55 degrees C, which reflects the mid-core sediment temperature profile and corroborates previous studies of rate maxima for the anaerobic oxidation of methane (AOM). Of the alkanes investigated, C-3 was oxidized at the highest rate over time, then C-4, C-2, and C-1, respectively. The implications of these results are discussed with respect to the potential competition between the anaerobic oxidation of C-2-C(4)alkanes with AOM for available oxidants and the influence on the fate of C-1 derived from these hydrothermal systems.

  11. Evaluation of a New Remote Handling Design for High Throughput Annular Centrifugal Contactors

    SciTech Connect (OSTI)

    David H. Meikrantz; Troy G. Garn; Jack D. Law; Lawrence L. Macaluso

    2009-09-01

    Advanced designs of nuclear fuel recycling plants are expected to include more ambitious goals for aqueous based separations including; higher separations efficiency, high-level waste minimization, and a greater focus on continuous processes to minimize cost and footprint. Therefore, Annular Centrifugal Contactors (ACCs) are destined to play a more important role for such future processing schemes. Previous efforts defined and characterized the performance of commercial 5 cm and 12.5 cm single-stage ACCs in a “cold” environment. The next logical step, the design and evaluation of remote capable pilot scale ACCs in a “hot” or radioactive environment was reported earlier. This report includes the development of remote designs for ACCs that can process the large throughput rates needed in future nuclear fuel recycling plants. Novel designs were developed for the remote interconnection of contactor units, clean-in-place and drain connections, and a new solids removal collection chamber. A three stage, 12.5 cm diameter rotor module has been constructed and evaluated for operational function and remote handling in highly radioactive environments. This design is scalable to commercial CINC ACC models from V-05 to V-20 with total throughput rates ranging from 20 to 650 liters per minute. The V-05R three stage prototype was manufactured by the commercial vendor for ACCs in the U.S., CINC mfg. It employs three standard V-05 clean-in-place (CIP) units modified for remote service and replacement via new methods of connection for solution inlets, outlets, drain and CIP. Hydraulic testing and functional checks were successfully conducted and then the prototype was evaluated for remote handling and maintenance suitability. Removal and replacement of the center position V-05R ACC unit in the three stage prototype was demonstrated using an overhead rail mounted PaR manipulator. This evaluation confirmed the efficacy of this innovative design for interconnecting and cleaning individual stages while retaining the benefits of commercially reliable ACC equipment for remote applications in the nuclear industry. Minor modifications and suggestions for improved manual remote servicing by the remote handling specialists were provided but successful removal and replacement was demonstrated in the first prototype.

  12. Realization of single-termination SrTiO{sub 3} (100) surfaces by a microwave-induced hydrothermal process

    SciTech Connect (OSTI)

    Velasco-Davalos, Ivan; Thomas, Reji; Ruediger, Andreas, E-mail: ruediger@emt.inrs.ca [Centre Énergie, Matériaux et Télécommunications, INRS, 1650 Lionel-Boulet, Varennes, Québec J3X1S2 (Canada)] [Centre Énergie, Matériaux et Télécommunications, INRS, 1650 Lionel-Boulet, Varennes, Québec J3X1S2 (Canada)

    2013-11-11

    A microwave-induced hydrothermal etching of SrTiO{sub 3} (100) single crystal surfaces in deionized water and subsequent annealing in oxygen atmosphere results in single-terminated and atomically flat terraces for pure and niobium-doped substrates as confirmed through one unit-cell step height and uniform phase by atomic force microscopy. This process that requires 3?min of moderate microwave radiation completely avoids the use of hydrofluoric acid (HF) and related point defects due to fluorine in the crystal surface. The advantages of a safe, inexpensive, and environmentally neutral process hold promise to replace the existing standard protocol for substrate preparation based on buffered HF.

  13. SPONTANEOUS CATALYTIC WET AIR OXIDATION DURING PRE-TREATMENT OF HIGH-LEVEL RADIOACTIVE WASTE SLUDGE

    SciTech Connect (OSTI)

    Koopman, D.; Herman, C.; Pareizs, J.; Bannochie, C.; Best, D.; Bibler, N.; Fellinger, T.

    2009-10-01

    Savannah River Remediation, LLC (SRR) operates the Defense Waste Processing Facility for the U.S. Department of Energy at the Savannah River Site. This facility immobilizes high-level radioactive waste through vitrification following chemical pretreatment. Catalytic destruction of formate and oxalate ions to carbon dioxide has been observed during qualification testing of non-radioactive analog systems. Carbon dioxide production greatly exceeded hydrogen production, indicating the occurrence of a process other than the catalytic decomposition of formic acid. Statistical modeling was used to relate the new reaction chemistry to partial catalytic wet air oxidation of both formate and oxalate ions driven by the low concentrations of palladium, rhodium, and/or ruthenium in the waste. Variations in process conditions led to increases or decreases in the total oxidative destruction, as well as partially shifting the preferred species undergoing destruction from oxalate ion to formate ion.

  14. A NEW PROCESS DEVELOPED FOR SEPARATION OF LIGNIN FROM AMMONIUM HYDROXIDE PRETREATMENT SOLUTIONS

    SciTech Connect (OSTI)

    Sherman, S.; Gorensek, M.; Milliken, C.

    2010-12-14

    A method is described for separating lignin from liquid solutions resulting from the pretreatment of lignocellulosic materials such as switchgrass with ammonium hydroxide. The method involves a sequence of steps including acidification, evaporation, and precipitation or centrifugation that are performed under defined conditions, and results in a relatively pure, solid lignin product. The method is tested on ammonium hydroxide solutions containing lignin extracted from switchgrass. Experimental results show that the method is capable of recovering between 66-95% of dissolved lignin as a precipitated solid. Cost estimates of pilot-scale and industrial-scale expressions of the process indicate that breakeven lignin prices of $2.36/kg and $0.78/kg, respectively, may be obtainable with this recovery method.

  15. Evaluation of solid-based separation materials for the pretreatment of radioactive wastes

    SciTech Connect (OSTI)

    Lumetta, G.J.; Wagner, M.J.; Wester, D.W.; Morrey, J.R.

    1993-05-01

    Separation science will play an important role in pretreating nuclear wastes stored at various US Department of Energy Sites. The application of separation processes offers potential economic and environmental benefits with regards to remediating these sites. For example, at the Hanford Site, the sizeable volume of radioactive wastes stored in underground tanks could be partitioned into a small volume of high-level waste (HLW) and a relatively large volume of low-level waste (LLW). After waste separation, only the smaller volume of HLW would require costly vitrification and geologic disposal. Furthermore, the quality of the remaining LLW form (e.g., grout) would be improved due to the lower inventory of radionuclides present in the LLW stream. This report investigates extraction chromatography as a possible separation process for Hanford wastes.

  16. Recovery of Plutonium from Refractory Residues Using a Sodium Peroxide Pretreatment Process

    SciTech Connect (OSTI)

    Rudisill, T.S.

    2003-10-23

    The recycle of plutonium from refractory residues is a necessary activity for the nuclear weapon production complex. Traditionally, high-fired plutonium oxide (PuO2) was leached from the residue matrix using a nitric acid/fluoride dissolving flowsheet. The recovery operations were time consuming and often required multiple contacts with fresh dissolving solution to reduce the plutonium concentration to levels where residual solids could be discarded. Due to these drawbacks, the development of an efficient process for the recovery of plutonium from refractory materials is desirable. To address this need, a pretreatment process was developed. The development program utilized a series of small-scale experiments to optimize processing conditions for the fusion process and demonstrate the plutonium recovery efficiency using ceramic materials developed as potential long-term storage forms for PuO2 and an incinerator ash from the Rocky Flats Environmental Technology Site (Rocky Flats) as te st materials.

  17. Impact of Mixed Feedstocks and Feedstock Densification on Ionic Liquid Pretreatment Efficiency

    SciTech Connect (OSTI)

    Jian Shi; Vicki S. Thompson; Neal A. Yancey; Vitalie Stavila; Blake A. Simmons; Seema Singh

    2013-01-01

    Background: Lignocellulosic biorefineries must be able to efficiently process the regional feedstocks that are available at cost-competitive prices year round. These feedstocks typically have low energy densities and vary significantly in composition. One potential solution to these issues is blending and/or densifying the feedstocks in order to create a uniform feedstock. Results/discussion: We have mixed four feedstocks - switchgrass, lodgepole pine, corn stover, and eucalyptus - in flour and pellet form and processed them using the ionic liquid 1-ethyl-3-methylimidazolium acetate. Sugar yields from both the mixed flour and pelletized feedstocks reach 90% within 24 hours of saccharification. Conclusions: Mixed feedstocks, in either flour or pellet form, are efficiently processed using this pretreatment process, and demonstrate that this approach has significant potential.

  18. Preliminary design requirements document (DRD) for Project W-236B, ``Initial Pretreatment Module``

    SciTech Connect (OSTI)

    Swanson, L.M.

    1995-02-15

    The scope of this Design Requirements Document (DRD) is to identify and define the functions, with associated requirements, which must be performed to separate Hanford Site tank waste supernatants into low-level and high-level fractions. This documents sets forth function requirements, performance requirements, and design constraints necessary to begin conceptual design for the Initial Pretreatment Module (IPM). System and physical interfaces between the IPM project and the Tank Waste Remediation System (TWRS) are identified. The constraints, performance requirements, and transfer of information and data across a technical interface will be documented in an Interface Control Document. Supplemental DRDs will be prepared to provide more detailed requirements specific to systems described in the DRD.

  19. Evaluating the biogas potential of the dry fraction from pretreatment of food waste from households

    SciTech Connect (OSTI)

    Murto, Marika; Björnsson, Lovisa; Rosqvist, Håkan; Bohn, Irene

    2013-05-15

    Highlights: ? A novel approach for biogas production from a waste fraction that today is incinerated. ? Biogas production is possible in spite of the impurities of the waste. ? Tracer studies are applied in a novel way. ? Structural material is needed to improve the flow pattern of the waste. ? We provide a solution to biological treatment for the complex waste fraction. - Abstract: At the waste handling company NSR, Helsingborg, Sweden, the food waste fraction of source separated municipal solid waste is pretreated to obtain a liquid fraction, which is used for biogas production, and a dry fraction, which is at present incinerated. This pretreatment and separation is performed to remove impurities, however also some of the organic material is removed. The possibility of realising the methane potential of the dry fraction through batch-wise dry anaerobic digestion was investigated. The anaerobic digestion technique used was a two-stage process consisting of a static leach bed reactor and a methane reactor. Treatment of the dry fraction alone and in a mixture with structural material was tested to investigate the effect on the porosity of the leach bed. A tracer experiment was carried out to investigate the liquid flow through the leach beds, and this method proved useful in demonstrating a more homogenous flow through the leach bed when structural material was added. Addition of structural material to the dry fraction was needed to achieve a functional digestion process. A methane yield of 98 m{sup 3}/ton was obtained from the dry fraction mixed with structural material after 76 days of digestion. This was in the same range as obtained in the laboratory scale biochemical methane potential test, showing that it was possible to extract the organic content in the dry fraction in this type of dry digestion system for the production of methane.

  20. FELIX: a High-Throughput Network Approach for Interfacing to Front End Electronics for ATLAS Upgrades

    E-Print Network [OSTI]

    Anderson, John Thomas; The ATLAS collaboration; Boterenbrood, Hendrik; Chen, Hucheng; Chen, Kai; Drake, Gary; Francis, David; Gorini, Benedetto; Lanni, Francesco; Lehmann Miotto, Giovanna; Levinson, Lorne; Narevicius, Julia; Plessl, Christian; Roich, Alexander; Ryu, Soo; Schreuder, Frans Philip; Schumacher, Jorn; Vandelli, Wainer; Vermeulen, Jos; Zhang, Jinlong

    2015-01-01

    The ATLAS experiment at CERN is planning full deployment of a new unified optical link technology for connecting detector front end electronics on the timescale of the LHC Run 4 (2025). It is estimated that roughly 8000 GBT (GigaBit Transceiver) links, with transfer rates up to 10.24~Gbps, will replace existing links used for readout, detector control and distribution of timing and trigger information. A new class of devices will be needed to interface many GBT links to the rest of the trigger, data-acquisition and detector control systems. In this paper FELIX (Front End LInk eXchange) is presented, a PC-based device to route data from and to multiple GBT links via a high-performance general purpose network capable of a total throughput up to O(20 Tbps). FELIX implies architectural changes to the ATLAS data acquisition system, such as the use of industry standard COTS components early in the DAQ chain. Additionally the design and implementation of a FELIX demonstration platform is presented, and hardware and ...

  1. A search model for topological insulators with high-throughput robustness descriptors

    SciTech Connect (OSTI)

    Yang, Kesong; Setyawan, Wahyu; Wang, Shidong; Nardelli, Marco B.; Curtarolo, Stephano

    2012-05-13

    Topological insulators (TI) are becoming one of the most studied classes of novel materials because of their great potential for applications ranging from spintronics to quantum computers. To fully integrate TI materials in electronic devices, high-quality epitaxial single-crystalline phases with sufficiently large bulk bandgaps are necessary. Current efforts have relied mostly on costly and time-consuming trial-and-error procedures. Here we show that by defining a reliable and accessible descriptor {cflx X}TI, which represents the topological robustness or feasibility of the candidate, and by searching the quantum materials repository aflowlib.org, we have automatically discovered 28 TIs (some of them already known) in five different symmetry families. These include peculiar ternary halides, Cs{l_brace}Sn,Pb,Ge{r_brace}{l_brace}Cl,Br,I{r_brace}{sub 3}, which could have been hardly anticipated without high-throughput means. Our search model, by relying on the significance of repositories in materials development, opens new avenues for the discovery of more TIs in different and unexplored classes of systems.

  2. FBI Fingerprint Image Capture System High-Speed-Front-End throughput modeling

    SciTech Connect (OSTI)

    Rathke, P.M.

    1993-09-01

    The Federal Bureau of Investigation (FBI) has undertaken a major modernization effort called the Integrated Automated Fingerprint Identification System (IAFISS). This system will provide centralized identification services using automated fingerprint, subject descriptor, mugshot, and document processing. A high-speed Fingerprint Image Capture System (FICS) is under development as part of the IAFIS program. The FICS will capture digital and microfilm images of FBI fingerprint cards for input into a central database. One FICS design supports two front-end scanning subsystems, known as the High-Speed-Front-End (HSFE) and Low-Speed-Front-End, to supply image data to a common data processing subsystem. The production rate of the HSFE is critical to meeting the FBI`s fingerprint card processing schedule. A model of the HSFE has been developed to help identify the issues driving the production rate, assist in the development of component specifications, and guide the evolution of an operations plan. A description of the model development is given, the assumptions are presented, and some HSFE throughput analysis is performed.

  3. Throughput Optimal Policies for Energy Harvesting Wireless Transmitters with Non-Ideal Circuit Power

    E-Print Network [OSTI]

    Xu, Jie

    2012-01-01

    Characterizing the fundamental tradeoffs for maximizing energy efficiency (EE) versus spectrum efficiency (SE) is a key problem in wireless communication. In this paper, we address this problem for a point-to-point additive white Gaussian noise (AWGN) channel with the transmitter powered solely via energy harvesting from the environment. In addition, we assume a practical on-off transmitter model with non-ideal circuit power, i.e., when the transmitter is on, its consumed power is the sum of the transmit power and a constant circuit power. Under this setup, we study the optimal transmit power allocation to maximize the average throughput over a finite horizon, subject to the time-varying energy constraint and the non-ideal circuit power consumption. First, we consider the off-line optimization under the assumption that the energy arrival time and amount are a priori known at the transmitter. Although this problem is non-convex due to the non-ideal circuit power, we show an efficient optimal solution that in g...

  4. Gasification of refuse derived fuel in the Battelle high throughput gasification system

    SciTech Connect (OSTI)

    Paisley, M.A.; Creamer, K.S.; Tweksbury, T.L.; Taylor, D.R. )

    1989-07-01

    This report presents the results of an experimental program to demonstrate the suitability of the Battelle High Throughput Gasification Process to non-wood biomass fuels. An extensive data base on wood gasification was generated during a multi-year experimental program. This data base and subsequent design and economic analysis activities led to the discussion to study the gasification character of other fuels. The specific fuel studied was refuse derived fuel (RDF) which is a prepared municipal solid waste (MSW). The use of RDF, while providing a valuable fuel, can also provide a solution to MSW disposal problems. Gasification of MSW provides advantages over land fill or mass burn technology since a more usable form of energy, medium Btu gas, is produced. Land filling of wastes produces no usable products and mass burning while greatly reducing the volume of wastes for disposal can produce only steam. This steam must be used on site or very nearby this limiting the potential locations for mass burn facilities. Such a gas, if produced from currently available supplies of MSW, can contribute 2 quads to the US energy supply. 3 refs., 12 figs., 7 tabs.

  5. A microreactor array for spatially resolved measurement of catalytic activity for high-throughput catalysis science

    SciTech Connect (OSTI)

    Kondratyuk, Petro; Gumuslu, Gamze; Shukla, Shantanu; Miller, James B.; Morreale, Bryan D.; Gellman, Andrew J.

    2013-04-01

    We describe a 100 channel microreactor array capable of spatially resolved measurement of catalytic activity across the surface of a flat substrate. When used in conjunction with a composition spread alloy film (CSAF, e.g. Pd{sub x}Cu{sub y}Au{sub 1-x-y}) across which component concentrations vary smoothly, such measurements permit high-throughput analysis of catalytic activity and selectivity as a function of catalyst composition. In the reported implementation, the system achieves spatial resolution of 1 mm{sup 2} over a 10×10 mm{sup 2} area. During operation, the reactant gases are delivered at constant flow rate to 100 points of differing composition on the CSAF surface by means of a 100-channel microfluidic device. After coming into contact with the CSAF catalyst surface, the product gas mixture from each of the 100 points is withdrawn separately through a set of 100 isolated channels for analysis using a mass spectrometer. We demonstrate the operation of the device on a Pd{sub x}Cu{sub y}Au{sub 1-x-y} CSAF catalyzing the H{sub 2}-D{sub 2} exchange reaction at 333 K. In essentially a single experiment, we measured the catalytic activity over a broad swathe of concentrations from the ternary composition space of the Pd{sub x}Cu{sub y}Au{sub 1-x-y} alloy.

  6. High-throughput liquid-absorption air-sampling apparatus and methods

    DOE Patents [OSTI]

    Zaromb, Solomon (95706 William Dr., Hinsdale, IL 60521)

    2000-01-01

    A portable high-throughput liquid-absorption air sampler [PHTLAAS] has an asymmetric air inlet through which air is drawn upward by a small and light-weight centrifugal fan driven by a direct current motor that can be powered by a battery. The air inlet is so configured as to impart both rotational and downward components of motion to the sampled air near said inlet. The PHTLAAS comprises a glass tube of relatively small size through which air passes at a high rate in a swirling, highly turbulent motion, which facilitates rapid transfer of vapors and particulates to a liquid film covering the inner walls of the tube. The pressure drop through the glass tube is <10 cm of water, usually <5 cm of water. The sampler's collection efficiency is usually >20% for vapors or airborne particulates in the 2-3.mu. range and >50% for particles larger than 4.mu.. In conjunction with various analyzers, the PHTLAAS can serve to monitor a variety of hazardous or illicit airborne substances, such as lead-containing particulates, tritiated water vapor, biological aerosols, or traces of concealed drugs or explosives.

  7. Metal Organic Framework Research: High Throughput Discovery of Robust Metal Organic Framework for CO2 Capture

    SciTech Connect (OSTI)

    None

    2010-08-01

    IMPACCT Project: LBNL is developing a method for identifying the best metal organic frameworks for use in capturing CO2 from the flue gas of coal-fired power plants. Metal organic frameworks are porous, crystalline compounds that, based on their chemical structure, vary considerably in terms of their capacity to grab hold of passing CO2 molecules and their ability to withstand the harsh conditions found in the gas exhaust of coal-fired power plants. Owing primarily to their high tunability, metal organic frameworks can have an incredibly wide range of different chemical and physical properties, so identifying the best to use for CO2 capture and storage can be a difficult task. LBNL uses high-throughput instrumentation to analyze nearly 100 materials at a time, screening them for the characteristics that optimize their ability to selectively adsorb CO2 from coal exhaust. Their work will identify the most promising frameworks and accelerate their large-scale commercial development to benefit further research into reducing the cost of CO2 capture and storage.

  8. Ultrahigh throughput plasma processing of free standing silicon nanocrystals with lognormal size distribution

    SciTech Connect (OSTI)

    Dogan, Ilker; Kramer, Nicolaas J.; Westermann, Rene H. J.; Verheijen, Marcel A. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Dohnalova, Katerina; Gregorkiewicz, Tom [Van der Waals-Zeeman Institute, University of Amsterdam, Science Park 904, 1098 XH Amsterdam (Netherlands); Smets, Arno H. M. [Photovoltaic Materials and Devices Laboratory, Delft University of Technology, P.O. Box 5031, 2600 GA Delft (Netherlands); Sanden, Mauritius C. M. van de [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands)

    2013-04-07

    We demonstrate a method for synthesizing free standing silicon nanocrystals in an argon/silane gas mixture by using a remote expanding thermal plasma. Transmission electron microscopy and Raman spectroscopy measurements reveal that the distribution has a bimodal shape consisting of two distinct groups of small and large silicon nanocrystals with sizes in the range 2-10 nm and 50-120 nm, respectively. We also observe that both size distributions are lognormal which is linked with the growth time and transport of nanocrystals in the plasma. Average size control is achieved by tuning the silane flow injected into the vessel. Analyses on morphological features show that nanocrystals are monocrystalline and spherically shaped. These results imply that formation of silicon nanocrystals is based on nucleation, i.e., these large nanocrystals are not the result of coalescence of small nanocrystals. Photoluminescence measurements show that silicon nanocrystals exhibit a broad emission in the visible region peaked at 725 nm. Nanocrystals are produced with ultrahigh throughput of about 100 mg/min and have state of the art properties, such as controlled size distribution, easy handling, and room temperature visible photoluminescence.

  9. 'Sifting the significance from the data' - the impact of high-throughput genomic technologies on human genetics and health care

    E-Print Network [OSTI]

    Clarke, Angus J.; Cooper, David N.; Krawczak, Michael; Tyler-Smith, Chris; Wallace, Helen M.; Wilkie, Andrew O. M.; Raymond, Frances L.; Chadwick, Ruth; Craddock, Nick; John, Ros; Gallacher, John; Chiano, Mathias

    2012-08-02

    and ageing), and in response to environmental challenges (diet, stress). To this end, a number of ingenious genome-wide, high- throughput technologies have been developed. Some are based on the ability to selectively capture methylated fragments of the genome... consumes too much energy or mis- conceived arguments lead to the inappropriate applica- tion of theory in policy and practise across various walks of life, most especially psychiatry, education and the law. Second, and despite a full acceptance...

  10. Hydrothermal Synthesis and Structural Characterization of Novel Zn-Triazole-Benzenedicarboxylate Frameworks

    SciTech Connect (OSTI)

    Park, Hyunsoo; Moureau, David M.; Parise, John B.

    2008-10-03

    Three new metal-organic coordination polymers were synthesized hydrothermally using Zn2+ ion, 1,2,4-triazole, and 1,4-benzenedicarboxylic acid (BDC): Zn5(H2O)2(C2H2N3)4(C8H4O4)3 {center_dot} 3.9H2O (1), Zn2(C2H2N3)2(C2H3N3)(C8H4O4) {center_dot} 2.5H2O (2), and Zn4(H2O)2(C2H2N3)4(C8H4O4)2 {center_dot} 14H2O (3). Their crystal structures were determined by single-crystal X-ray diffraction. Their thermal properties were examined by thermogravimetric analysis. Structure 1 crystallizes in the monoclinic P21/n space group with a = 10.192(2) {angstrom}, b = 17.764(4) {angstrom}, c = 24.437(5) {angstrom}, {beta} = 91.19(3){sup o}, and V = 4423.3(15) {angstrom}3. Structure 2 crystallizes in the triclinic P space group with a = 7.797(2) {angstrom}, b = 10.047(2) {angstrom}, c = 13.577(3) {angstrom}, {alpha} = 110.18(3){sup o}, {beta} = 105.46(3){sup o}, {gamma} = 93.90(3){sup o}, and V = 947.0(3) {angstrom}3. Structure 3 crystallizes in monoclinic P21/n space group with a = 13.475(3) {angstrom}, b = 26.949(5) {angstrom}, c = 13.509(3) {angstrom}, {beta} = 95.18(3){sup o}, and V = 4885.7(17) {angstrom}3. In structure 1, the units of the triazole-Zn polyhedra are linked by BDC in a zigzag fashion to create the stacking of phenyl groups along the a axis. In structure 2, both triazole and BDC bridge Zn polyhedra in the (011) plane, resulting in the eight-membered channels along the a axis. In the case of structure 3, the BDC links the Zn polyhedra along the b axis to form a pillared open framework. This structure is the most porous of the compounds presented in this work.

  11. Electronic structure and magnetic properties of FeWO{sub 4} nanocrystals synthesized by the microwave-hydrothermal method

    SciTech Connect (OSTI)

    Almeida, M.A.P. [INCTMN-DQ-Universidade Federal de Sao Carlos, Sao Carlos, P.O. Box 676, 13565-905, SP (Brazil)] [INCTMN-DQ-Universidade Federal de Sao Carlos, Sao Carlos, P.O. Box 676, 13565-905, SP (Brazil); Cavalcante, L.S., E-mail: laeciosc@bol.com.br [INCTMN-Universidade Estadual, Paulista, P.O. Box 355, 14801-907, Araraquara, SP (Brazil); Morilla-Santos, C.; Filho, P.N. Lisboa [MAv-Universidade Estadual, Paulista, P.O. Box 473, 17033-360, Bauru, SP (Brazil)] [MAv-Universidade Estadual, Paulista, P.O. Box 473, 17033-360, Bauru, SP (Brazil); Beltran, A.; Andres, J.; Gracia, L. [Department de Quimica Fisica i Analitica, Universitat Jaume I, E-12071 Castello (Spain)] [Department de Quimica Fisica i Analitica, Universitat Jaume I, E-12071 Castello (Spain); Longo, E. [INCTMN-DQ-Universidade Federal de Sao Carlos, Sao Carlos, P.O. Box 676, 13565-905, SP (Brazil) [INCTMN-DQ-Universidade Federal de Sao Carlos, Sao Carlos, P.O. Box 676, 13565-905, SP (Brazil); INCTMN-Universidade Estadual, Paulista, P.O. Box 355, 14801-907, Araraquara, SP (Brazil)

    2012-11-15

    This communication reports that FeWO{sub 4} nanocrystals were successfully synthesized by the microwave-hydrothermal method at 443 K for 1 h. The structure and shape of these nanocrystals were characterized by X-ray diffraction, Rietveld refinement, and transmission electron microscopy. The experimental results and first principles calculations were combined to explain the electronic structure and magnetic properties. Experimental data were obtained by magnetization measurements for different applied magnetic fields. Theoretical calculations revealed that magnetic properties of FeWO{sub 4} nanocrystals can be assigned to two magnetic orderings with parallel or antiparallel spins in adjacent chains. These factors are crucial to understanding of competition between ferro- and antiferromagnetic behavior. Highlights: Black-Right-Pointing-Pointer Monophasic FeWO{sub 4} nanocrystals were synthesized by the microwave-hydrothermal method. Black-Right-Pointing-Pointer Rietveld refinement and clusters model for monoclinic structure Black-Right-Pointing-Pointer Magnetic properties of FeWO{sub 4} nanocrystals at different temperatures.

  12. Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue

    SciTech Connect (OSTI)

    Pei, L.Z. Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

    2013-07-15

    Graphical abstract: - Highlights: • Mn vanadate nanosheets have been synthesized by simple hydrothermal process. • The formation of Mn vanadate nanosheets can be controlled by growth conditions. • Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 2–10 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

  13. New Challenges of the Computation of Multiple Sequence Alignments in the High-Throughput Era (2010 JGI/ANL HPC Workshop)

    ScienceCinema (OSTI)

    Notredame, Cedric [Centre for Genomic Regulation

    2011-06-08

    Cedric Notredame from the Centre for Genomic Regulation gives a presentation on "New Challenges of the Computation of Multiple Sequence Alignments in the High-Throughput Era" at the JGI/Argonne HPC Workshop on January 26, 2010.

  14. Vehicle Technologies Office Merit Review 2015: High-Throughput Study of Diffusion and Phase Transformation Kinetics of Magnesium-Based Systems For Automotive Cast Magnesium Alloys

    Broader source: Energy.gov [DOE]

    Presentation given by Ohio State University at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high-throughput study...

  15. Soft inertial microfluidics for high throughput separation of bacteria from human blood cells

    SciTech Connect (OSTI)

    Wu, Zhigang; Willing, Ben; Bjerketorp, Joakim; Jansson, Janet K.; Hjort, Klas

    2009-01-05

    We developed a new approach to separate bacteria from human blood cells based on soft inertial force induced migration with flow defined curved and focused sample flow inside a microfluidic device. This approach relies on a combination of an asymmetrical sheath flow and proper channel geometry to generate a soft inertial force on the sample fluid in the curved and focused sample flow segment to deflect larger particles away while the smaller ones are kept on or near the original flow streamline. The curved and focused sample flow and inertial effect were visualized and verified using a fluorescent dye primed in the device. First the particle behavior was studied in detail using 9.9 and 1.0 {micro}m particles with a polymer-based prototype. The prototype device is compact with an active size of 3 mm{sup 2}. The soft inertial effect and deflection distance were proportional to the fluid Reynolds number (Re) and particle Reynolds number (Re{sub p}), respectively. We successfully demonstrated separation of bacteria (Escherichia coli) from human red blood cells at high cell concentrations (above 10{sup 8}/mL), using a sample flow rate of up to 18 {micro}L/min. This resulted in at least a 300-fold enrichment of bacteria at a wide range of flow rates with a controlled flow spreading. The separated cells were proven to be viable. Proteins from fractions before and after cell separation were analyzed by gel electrophoresis and staining to verify the removal of red blood cell proteins from the bacterial cell fraction. This novel microfluidic process is robust, reproducible, simple to perform, and has a high throughput compared to other cell sorting systems. Microfluidic systems based on these principles could easily be manufactured for clinical laboratory and biomedical applications.

  16. Acoustic transfer of protein crystals from agarose pedestals to micromeshes for high-throughput screening

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cuttitta, Christina M.; Ericson, Daniel L.; Scalia, Alexander; Roessler, Christian G.; Teplitsky, Ella; Joshi, Karan; Campos, Olven; Agarwal, Rakhi; Allaire, Marc; Orville, Allen M.; et al

    2014-06-01

    Acoustic droplet ejection (ADE) is an emerging technology with broad applications in serial crystallography such as growing, improving and manipulating protein crystals. One application of this technology is to gently transfer crystals onto MiTeGen micromeshes with minimal solvent. Once mounted on a micromesh, each crystal can be combined with different chemicals such as crystal-improving additives or a fragment library. Acoustic crystal mounting is fast (2.33 transfers s-1) and all transfers occur in a sealed environment that is in vapor equilibrium with the mother liquor. Here, a system is presented to retain crystals near the ejection point and away from themore »inaccessible dead volume at the bottom of the well by placing the crystals on a concave agarose pedestal (CAP) with the same chemical composition as the crystal mother liquor. The bowl-shaped CAP is impenetrable to crystals. Consequently, gravity will gently move the crystals into the optimal location for acoustic ejection. It is demonstrated that an agarose pedestal of this type is compatible with most commercially available crystallization conditions and that protein crystals are readily transferred from the agarose pedestal onto micromeshes with no loss in diffraction quality. It is also shown that crystals can be grown directly on CAPs, which avoids the need to transfer the crystals from the hanging drop to a CAP. This technology has been used to combine thermolysin and lysozyme crystals with an assortment of anomalously scattering heavy atoms. The results point towards a fast nanolitre method for crystal mounting and high-throughput screening.« less

  17. Acoustic transfer of protein crystals from agarose pedestals to micromeshes for high-throughput screening

    SciTech Connect (OSTI)

    Cuttitta, Christina M.; Ericson, Daniel L.; Scalia, Alexander; Roessler, Christian G.; Teplitsky, Ella; Joshi, Karan; Campos, Olven; Agarwal, Rakhi; Allaire, Marc; Orville, Allen M.; Sweet, Robert M.; Soares, Alexei S.

    2014-06-01

    Acoustic droplet ejection (ADE) is an emerging technology with broad applications in serial crystallography such as growing, improving and manipulating protein crystals. One application of this technology is to gently transfer crystals onto MiTeGen micromeshes with minimal solvent. Once mounted on a micromesh, each crystal can be combined with different chemicals such as crystal-improving additives or a fragment library. Acoustic crystal mounting is fast (2.33 transfers s-1) and all transfers occur in a sealed environment that is in vapor equilibrium with the mother liquor. Here, a system is presented to retain crystals near the ejection point and away from the inaccessible dead volume at the bottom of the well by placing the crystals on a concave agarose pedestal (CAP) with the same chemical composition as the crystal mother liquor. The bowl-shaped CAP is impenetrable to crystals. Consequently, gravity will gently move the crystals into the optimal location for acoustic ejection. It is demonstrated that an agarose pedestal of this type is compatible with most commercially available crystallization conditions and that protein crystals are readily transferred from the agarose pedestal onto micromeshes with no loss in diffraction quality. It is also shown that crystals can be grown directly on CAPs, which avoids the need to transfer the crystals from the hanging drop to a CAP. This technology has been used to combine thermolysin and lysozyme crystals with an assortment of anomalously scattering heavy atoms. The results point towards a fast nanolitre method for crystal mounting and high-throughput screening.

  18. Study concerning the utilization of the ocean spreading center environment for the conversion of biomass to a liquid fuel. (Includes Appendix A: hydrothermal petroleum genesis). [Supercritical water

    SciTech Connect (OSTI)

    Steverson, M.; Stormberg, G.

    1985-01-01

    This document contains a report on the feasibility of utilizing energy obtained from ocean spreading centers as process heat for the conversion of municipal solid wastes to liquid fuels. The appendix contains a paper describing hydrothermal petroleum genesis. Both have been indexed separately for inclusion in the Energy Data Base. (DMC)

  19. A New Type of Two-Dimensional Metal Coordination Systems: Hydrothermal Synthesis and Properties of the First Oxalate-bpy Mixed-Ligand Framework

    E-Print Network [OSTI]

    Li, Jing

    A New Type of Two-Dimensional Metal Coordination Systems: Hydrothermal Synthesis and Properties, 290 °C; II, 340 °C; III, 350 °C; and IV, 290 °C). Introduction Investigation of novel inorganic-organic hybrid framework assemblies represents one of the most active areas of materials science and chemical

  20. EVALUATION OF SUPPLEMENTAL PRE-TREATMENT DEVELOPMENT REQUIREMENTS TO MEET TRL 6 ROTARY MICROFILTRATION

    SciTech Connect (OSTI)

    HUBER HJ

    2011-10-03

    In spring 2011, the Technology Maturation Plan (TMP) for the Supplemental Treatment Project (RPP-PLAN-49827, Rev. 0), Technology Maturation Plan for the Treatment Project (T4S01) was developed. This plan contains all identified actions required to reach technical maturity for a field-deployable waste feed pretreatment system. The supplemental pretreatment system has a filtration and a Cs-removal component. Subsequent to issuance of the TMP, rotary microfiltration (RMF) has been identified as the prime filtration technology for this application. The prime Cs-removal technology is small column ion exchange (ScIX) using spherical resorcinol formaldehyde (sRF) as the exchange resin. During fiscal year 2011 (FY2011) some of the tasks identified in the TMP have been completed. As of September 2011, the conceptual design package has been submitted to DOE as part of the critical decision (CD-1) process. This document describes the remaining tasks identified in the TMP to reach technical maturity and evaluates the validity of the proposed tests to fill the gaps as previously identified in the TMP. The potential vulnerabilities are presented and the completed list of criteria for the DOE guide DOE G 413.3-4 different technology readiness levels are added in an attachment. This evaluation has been conducted from a technology development perspective - all programmatic and manufacturing aspects were excluded from this exercise. Compliance with the DOE G 413.3-4 programmatic and manufacturing requirements will be addressed directly by the Treatment Project during the course of engineering design. The results of this evaluation show that completion of the proposed development tasks in the TMP are sufficient to reach TRL 6 from a technological point of view. The tasks involve actual waste tests using the current baseline configuration (2nd generation disks, 40 psi differential pressure, 30 C feed temperature) and three different simulants - the PEP, an AP-Farm and an S-saltcake. Based on FY2011 dollars used in the TMP, these tests will have ROM costs of $950K and require up to 10 months to complete. Completion of the simulant testing will satisfy the TRL 5 and TRL 6 criteria that are related to system testing with materials that represent the full range of properties in a relevant environment.