National Library of Energy BETA

Sample records for thermoelectric generators thermal

  1. Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presents progress in cost-effective thermoelectric generator fabrication by thermal spraying of thermoelectric materials and other functional layers directly onto automotive exhaust pipes with enhanced performance, durability, and heat transfer

  2. Thermal Strategies for High Efficiency Thermoelectric Power Generation...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Proactive Strategies for Designing Thermoelectric Materials for Power Generation Proactive Strategies for Designing Thermoelectric Materials for Power ...

  3. Thermoelectric power generator for variable thermal power source

    SciTech Connect (OSTI)

    Bell, Lon E; Crane, Douglas Todd

    2015-04-14

    Traditional power generation systems using thermoelectric power generators are designed to operate most efficiently for a single operating condition. The present invention provides a power generation system in which the characteristics of the thermoelectrics, the flow of the thermal power, and the operational characteristics of the power generator are monitored and controlled such that higher operation efficiencies and/or higher output powers can be maintained with variably thermal power input. Such a system is particularly beneficial in variable thermal power source systems, such as recovering power from the waste heat generated in the exhaust of combustion engines.

  4. Thermoelectric generator

    DOE Patents [OSTI]

    Pryslak, N.E.

    1974-02-26

    A thermoelectric generator having a rigid coupling or stack'' between the heat source and the hot strap joining the thermoelements is described. The stack includes a member of an insulating material, such as ceramic, for electrically isolating the thermoelements from the heat source, and a pair of members of a ductile material, such as gold, one each on each side of the insulating member, to absorb thermal differential expansion stresses in the stack. (Official Gazette)

  5. Analytical thermal model validation for Cassini radioisotope thermoelectric generator

    SciTech Connect (OSTI)

    Lin, E.I.

    1997-12-31

    The Saturn-bound Cassini spacecraft is designed to rely, without precedent, on the waste heat from its three radioisotope thermoelectric generators (RTGs) to warm the propulsion module subsystem, and the RTG end dome temperature is a key determining factor of the amount of waste heat delivered. A previously validated SINDA thermal model of the RTG was the sole guide to understanding its complex thermal behavior, but displayed large discrepancies against some initial thermal development test data. A careful revalidation effort led to significant modifications and adjustments of the model, which result in a doubling of the radiative heat transfer from the heat source support assemblies to the end domes and bring up the end dome and flange temperature predictions to within 2 C of the pertinent test data. The increased inboard end dome temperature has a considerable impact on thermal control of the spacecraft central body. The validation process offers an example of physically-driven analytical model calibration with test data from not only an electrical simulator but also a nuclear-fueled flight unit, and has established the end dome temperatures of a flight RTG where no in-flight or ground-test data existed before.

  6. Integrated Design and Manufacturing of Thermoelectric Generator...

    Broader source: Energy.gov (indexed) [DOE]

    Presents progress in cost-effective thermoelectric generator fabrication by thermal spraying of thermoelectric materials and other functional layers directly onto automotive ...

  7. In situ nanostructure generation and evolution within a bulk thermoelectric material to reduce lattice thermal conductivity.

    SciTech Connect (OSTI)

    Girard, S. N.; He, J.; Li, C.; Moses, S.; Wang, G.; Uher, C.; Dravid, V. P.; Kanatzidis, M. G.

    2010-07-26

    We show experimentally the direct reduction in lattice thermal conductivity as a result of in situ nanostructure generation within a thermoelectric material. Solid solution alloys of the high-performance thermoelectric PbTe-PbS 8% can be synthesized through rapid cooling and subsequent high-temperature activation that induces a spontaneous nucleation and growth of PbS nanocrystals. The emergence of coherent PbS nanostructures reduces the lattice thermal conductivity from {approx}1 to {approx}0.4 W/mK between 400 and 500 K.

  8. Thermal vacuum life test facility for radioisotope thermoelectric generators

    SciTech Connect (OSTI)

    Deaton, R.L.; Goebel, C.J.; Amos, W.R.

    1990-01-01

    In the late 1970's, the Department of Energy (DOE) assigned Monsanto Research Corporation, Mound Facility, now operated by EG G Mound Applied Technologies, the responsibility for assembling and testing General Purpose Heat Source (GPHS) radioisotope thermoelectric generators (RTGs). Assembled and tested were five RTGs, which included four flight units and one non-flight qualification unit. Figure 1 shows the RTG, which was designed by General Electric AstroSpace Division (GE/ASD) to produce 285 W of electrical power. A detailed description of the processes for RTG assembly and testing is presented by Amos and Goebel (1989). The RTG performance data are described by Bennett, et al. (1986). The flight units will provide electrical power for the National Aeronautics and Space Administration's (NASA) Galileo mission to Jupiter (two RTGs) and the joint NASA/European Space Agency (ESA) Ulysses mission to study the polar regions of the sun (one RTG). The remaining flight unit will serve as the spare for both missions, and a non-flight qualification unit was assembled and tested to ensure that performance criteria were adequately met. 4 refs., 3 figs.

  9. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, J.D.; El-Genk, M.S.

    1994-01-01

    Thermoelectricity is produced by applying a temperature differential to dissimilar electrically conducting or semiconducting materials, thereby producing a voltage that is proportional to the temperature difference. Thermoelectric generators use this effect to directly convert heat into electricity; however, presently-known generators have low efficiencies due to the production of high currents which in turn cause large resistive heating losses. Some thermoelectric generators operate at efficiencies between 4% and 7% in the 800{degrees} to 1200{degrees}C range. According to its major aspects and bradly stated, the present invention is an apparatus and method for producing electricity from heat. In particular, the invention is a thermoelectric generator that juxtaposes a superconducting material and a semiconducting material - so that the superconducting and the semiconducting materials touch - to convert heat energy into electrical energy without resistive losses in the temperature range below the critical temperature of the superconducting material. Preferably, an array of superconducting material is encased in one of several possible configurations within a second material having a high thermal conductivity, preferably a semiconductor, to form a thermoelectric generator.

  10. Component for thermoelectric generator

    DOE Patents [OSTI]

    Purdy, David L.

    1977-01-01

    In a thermoelectric generator, a component comprises a ceramic insulator, having over limited areas thereof, each area corresponding to a terminal end of thermoelectric wires, a coating of a first metal which adheres to the insulator, and an electrical thermoelectric junction including a second metal which wets said first metal and adheres to said terminal ends but does not wet said insulator, and a cloth composed of electrically insulating threads interlaced with thermoelectric wires.

  11. Waste Heat Recovery Opportunities for Thermoelectric Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat Recovery Opportunities for Thermoelectric Generators Waste Heat Recovery Opportunities for Thermoelectric Generators Thermoelectrics have unique advantages for ...

  12. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, J.D.; El-Genk, M.S.

    1996-01-01

    An apparatus and method for producing electricity from heat. The present invention is a thermoelectric generator that uses materials with substantially no electrical resistance, often called superconductors, to efficiently convert heat into electrical energy without resistive losses. Preferably, an array of superconducting elements is encased within a second material with a high thermal conductivity. The second material is preferably a semiconductor. Alternatively, the superconducting material can be doped on a base semiconducting material, or the superconducting material and the semiconducting material can exist as alternating, interleaved layers of waferlike materials. A temperature gradient imposed across the boundary of the two materials establishes an electrical potential related to the magnitude of the temperature gradient. The superconducting material carries the resulting electrical current at zero resistivity, thereby eliminating resistive losses. The elimination of resistive losses significantly increases the conversion efficiency of the thermoelectric device.

  13. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, J.D.; El-Genk, M.S.

    1998-05-05

    An apparatus and method for producing electricity from heat is disclosed. The present invention is a thermoelectric generator that uses materials with substantially no electrical resistance, often called superconductors, to efficiently convert heat into electrical energy without resistive losses. Preferably, an array of superconducting elements is encased within a second material with a high thermal conductivity. The second material is preferably a semiconductor. Alternatively, the superconducting material can be doped on a base semiconducting material, or the superconducting material and the semiconducting material can exist as alternating, interleaved layers of waferlike materials. A temperature gradient imposed across the boundary of the two materials establishes an electrical potential related to the magnitude of the temperature gradient. The superconducting material carries the resulting electrical current at zero resistivity, thereby eliminating resistive losses. The elimination of resistive losses significantly increases the conversion efficiency of the thermoelectric device. 4 figs.

  14. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, John D.; El-Genk, Mohamed S.

    1998-01-01

    An apparatus and method for producing electricity from heat. The present invention is a thermoelectric generator that uses materials with substantially no electrical resistance, often called superconductors, to efficiently convert heat into electrical energy without resistive losses. Preferably, an array of superconducting elements is encased within a second material with a high thermal conductivity. The second material is preferably a semiconductor. Alternatively, the superconducting material can be doped on a base semiconducting material, or the superconducting material and the semiconducting material can exist as alternating, interleaved layers of waferlike materials. A temperature gradient imposed across the boundary of the two materials establishes an electrical potential related to the magnitude of the temperature gradient. The superconducting material carries the resulting electrical current at zero resistivity, thereby eliminating resistive losses. The elimination of resistive losses significantly increases the conversion efficiency of the thermoelectric device.

  15. Modular Isotopic Thermoelectric Generator

    SciTech Connect (OSTI)

    Schock, Alfred

    1981-04-03

    Advanced RTG concepts utilizing improved thermoelectric materials and converter concepts are under study at Fairchild for DOE. The design described here is based on DOE's newly developed radioisotope heat source, and on an improved silicon-germanium material and a multicouple converter module under development at Syncal. Fairchild's assignment was to combine the above into an attractive power system for use in space, and to assess the specific power and other attributes of that design. The resultant design is highly modular, consisting of standard RTG slices, each producing ~24 watts at the desired output voltage of 28 volt. Thus, the design could be adapted to various space missions over a wide range of power levels, with little or no redesign. Each RTG slice consists of a 250-watt heat source module, eight multicouple thermoelectric modules, and standard sections of insulator, housing, radiator fins, and electrical circuit. The design makes it possible to check each thermoelectric module for electrical performance, thermal contact, leaktightness, and performance stability, after the generator is fully assembled; and to replace any deficient modules without disassembling the generator or perturbing the others. The RTG end sections provide the spring-loaded supports required to hold the free-standing heat source stack together during launch vibration. Details analysis indicates that the design offers a substantial improvement in specific power over the present generator of RTGs, using the same heat source modules. There are three copies in the file.

  16. Solar thermoelectric generator

    DOE Patents [OSTI]

    Toberer, Eric S.; Baranowski, Lauryn L.; Warren, Emily L.

    2016-05-03

    Solar thermoelectric generators (STEGs) are solid state heat engines that generate electricity from concentrated sunlight. A novel detailed balance model for STEGs is provided and applied to both state-of-the-art and idealized materials. STEGs can produce electricity by using sunlight to heat one side of a thermoelectric generator. While concentrated sunlight can be used to achieve extremely high temperatures (and thus improved generator efficiency), the solar absorber also emits a significant amount of black body radiation. This emitted light is the dominant loss mechanism in these generators. In this invention, we propose a solution to this problem that eliminates virtually all of the emitted black body radiation. This enables solar thermoelectric generators to operate at higher efficiency and achieve said efficient with lower levels of optical concentration. The solution is suitable for both single and dual axis solar thermoelectric generators.

  17. Automotive Thermoelectric Generators and HVAC

    Broader source: Energy.gov [DOE]

    Provides overview of DOE-supported projects in automotive thermoelectric generators and heaters/air conditioners

  18. In-situ nanostructure generation and evolution within a bulk thermoelectric material to reduce lattice thermal conductivity

    SciTech Connect (OSTI)

    Girard, Steven; He, Jiaqing; Li, Chang-Peng; Moses, Steven; Wang, Guoyu Y.; Uher, Ctirad; Dravid, Vinayak; Kanatzidis, Mercouri G.

    2010-07-26

    We show experimentally the direct reduction in lattice thermal conductivity as a result of in situ nanostructure generation within a thermoelectric material. Solid solution alloys of the high-performance thermoelectric PbTe-PbS 8% can be synthesized through rapid cooling and subsequent high-temperature activation that induces a spontaneous nucleation and growth of PbS nanocrystals. The emergence of coherent PbS nanostructures reduces the lattice thermal conductivity from ~1 to ~0.4 W/mK between 400 and 500 K.

  19. Overview of Thermoelectric Power Generation Technologies in Japan

    Broader source: Energy.gov [DOE]

    Discusses thermoelectric power generation technologies as applied to waste heat recovery, renewable thermal energy sources, and energy harvesting

  20. Overview of Thermoelectric Power Generation Technologies in Japan |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Discusses thermoelectric power generation technologies as applied to waste heat recovery, renewable thermal energy sources, and energy harvesting kajikawa.pdf (4.47 MB) More Documents & Publications Overview of Thermoelectric Power Generation Technologies in Japan Overview of Progress in Thermoelectric Power Generation Technologies in Japan Overview of Japanese Activities in Thermoelectrics

  1. Thermoelectric Generator Development for Automotive Waste Heat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generator Development for Automotive Waste Heat Recovery Thermoelectric Generator ... More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat ...

  2. Effective thermal conductivity in thermoelectric materials

    SciTech Connect (OSTI)

    Baranowski, LL; Snyder, GJ; Toberer, ES

    2013-05-28

    Thermoelectric generators (TEGs) are solid state heat engines that generate electricity from a temperature gradient. Optimizing these devices for maximum power production can be difficult due to the many heat transport mechanisms occurring simultaneously within the TEG. In this paper, we develop a model for heat transport in thermoelectric materials in which an "effective thermal conductivity" (kappa(eff)) encompasses both the one dimensional steady-state Fourier conduction and the heat generation/consumption due to secondary thermoelectric effects. This model is especially powerful in that the value of kappa(eff) does not depend upon the operating conditions of the TEG but rather on the transport properties of the TE materials themselves. We analyze a variety of thermoelectric materials and generator designs using this concept and demonstrate that kappa(eff) predicts the heat fluxes within these devices to 5% of the exact value. (C) 2013 AIP Publishing LLC.

  3. Automotive Thermoelectric Generator (TEG) Controls

    Office of Energy Efficiency and Renewable Energy (EERE)

    Addresses functions to be controlled that make the difference between a barely functional and an efficient, cost-effective thermoelectric generator(TEG)

  4. Thermoelectric Generator Development at Renault Trucks-Volvo...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    systems PDF icon aixala.pdf More Documents & Publications RENOTER Project RENOTER Project Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

  5. Overview of Thermoelectric Power Generation Technologies in Japan...

    Broader source: Energy.gov (indexed) [DOE]

    Discusses thermoelectric power generation technologies as applied to waste heat recovery, renewable thermal energy sources, and energy harvesting kajikawa.pdf (4.47 MB) More ...

  6. Thermoelectric Power Generation System with Loop Thermosyphon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Power Generation System with Loop Thermosyphon in Future High Efficiency ... More Documents & Publications Low and high Temperature Dual Thermoelectric Generation ...

  7. The Industrialization of Thermoelectric Power Generation Technology...

    Broader source: Energy.gov (indexed) [DOE]

    Devices An integrated approach towards efficient, scalable, and low cost thermoelectric waste heat recovery devices for vehicles Automotive Thermoelectric Generators and HVAC

  8. Thermoelectric generator for motor vehicle

    DOE Patents [OSTI]

    Bass, John C.

    1997-04-29

    A thermoelectric generator for producing electric power for a motor vehicle from the heat of the exhaust gasses produced by the engine of the motor vehicle. The exhaust gasses pass through a finned heat transfer support structure which has seat positions on its outside surface for the positioning of thermoelectric modules. A good contact cylinder provides a framework from which a spring force can be applied to the thermoelectric modules to hold them in good contact on their seats on the surface of the heat transfer support structure.

  9. Development of a 100-Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 100-Watt High Temperature Thermoelectric Generator Development of a 100-Watt High Temperature Thermoelectric Generator Test results for low and high temperature thermoelectric ...

  10. Manufacture of thermoelectric generator structures by fiber drawing

    DOE Patents [OSTI]

    McIntyre, Timothy J; Simpson, John T; West, David L

    2014-11-18

    Methods of manufacturing a thermoelectric generator via fiber drawing and corresponding or associated thermoelectric generator devices are provided.

  11. Modular Isotopic Thermoelectric Generator

    SciTech Connect (OSTI)

    Schock, Alfred

    1981-01-01

    Advanced RTG concepts utilizing improved thermoelectric materials and converter concepts are under study at Fairchild for DOE. The design described here is based on DOE's newly developed radioisotope heat source, and on an improved silicon-germanium material and multicouple converter module under development at Syncal. Fairchild's assignment was to combine the above into an attractive power system for use in space, and to assess the specific power and other attributes of that design.

  12. Thermoelectric Generator Development at Renault Trucks-Volvo Group |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Reviews project to study the potential of thermoelectricity for diesel engines of trucks and passenger cars, where relatively low exhaust temperature is challenging for waste heat recovery systems aixala.pdf (2.28 MB) More Documents & Publications RENOTER Project RENOTER Project Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

  13. Glass-like thermal conductivity in high efficiency thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermal conductivity in high efficiency thermoelectric materials Glass-like thermal conductivity in high efficiency thermoelectric materials Discusses strategies to design ...

  14. Skutterudite Thermoelectric Generator For Automotive Waste Heat...

    Broader source: Energy.gov (indexed) [DOE]

    of Exhaust Gas Waste Heat into Usable Electricity Development of Cost-Competitive Advanced Thermoelectric Generators for Direct Conversion of Vehicle Waste Heat into Useful ...

  15. A Thermoelectric Generator with an Intermediate Heat Exchanger...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System for Light-Duty Vehicles Thermoelectric Power Generation System with Loop Thermosyphon in Future High Efficiency Hybrid Vehicles Automotive Thermoelectric Generators and HVAC

  16. Overview of Progress in Thermoelectric Power Generation Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overview of Thermoelectric Power Generation Technologies in Japan Overview of Thermoelectric Power Generation Technologies in Japan Overview of Japanese Activities in ...

  17. Feasibility of OnBoard Thermoelectric Generation for Improved...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OnBoard Thermoelectric Generation for Improved Vehicle Fuel Economy Feasibility of OnBoard Thermoelectric Generation for Improved Vehicle Fuel Economy Poster presentation at the ...

  18. Development of a 500 Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 500 Watt High Temperature Thermoelectric Generator Development of a 500 Watt High Temperature Thermoelectric Generator A low temperature TEG has been built and tested providing ...

  19. Low and high Temperature Dual Thermoelectric Generation Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System ...

  20. Development of Cost-Competitive Advanced Thermoelectric Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost-Competitive Advanced Thermoelectric Generators for Direct Conversion of Vehicle Waste Heat into Useful Electrical Power Development of Cost-Competitive Advanced Thermoelectric...

  1. OSTIblog Articles in the Radioisotope Thermoelectric Generator Topic |

    Office of Scientific and Technical Information (OSTI)

    OSTI, US Dept of Energy Office of Scientific and Technical Information Radioisotope Thermoelectric Generator

  2. High-Temperature High-Efficiency Solar Thermoelectric Generators

    SciTech Connect (OSTI)

    Baranowski, LL; Warren, EL; Toberer, ES

    2014-03-01

    Inspired by recent high-efficiency thermoelectric modules, we consider thermoelectrics for terrestrial applications in concentrated solar thermoelectric generators (STEGs). The STEG is modeled as two subsystems: a TEG, and a solar absorber that efficiently captures the concentrated sunlight and limits radiative losses from the system. The TEG subsystem is modeled using thermoelectric compatibility theory; this model does not constrain the material properties to be constant with temperature. Considering a three-stage TEG based on current record modules, this model suggests that 18% efficiency could be experimentally expected with a temperature gradient of 1000A degrees C to 100A degrees C. Achieving 15% overall STEG efficiency thus requires an absorber efficiency above 85%, and we consider two methods to achieve this: solar-selective absorbers and thermally insulating cavities. When the TEG and absorber subsystem models are combined, we expect that the STEG modeled here could achieve 15% efficiency with optical concentration between 250 and 300 suns.

  3. Thermoelectric Generator (TEG) Fuel Displacement Potential using...

    Broader source: Energy.gov (indexed) [DOE]

    Assessment of fuel savings with thermoelectric generators (TEGs) using detailed model of GM-developed TEG as part of the engine connected to a dynamometer that emulates the rest of ...

  4. System and method to improve the power output and longetivity of a radioisotope thermoelectric generator

    DOE Patents [OSTI]

    Mowery, Jr., Alfred L.

    1993-01-01

    By using the helium generated by the alpha emissions of a thermoelectric generator during space travel for cooling, the thermal degradation of the thermoelectric generator can be slowed. Slowing degradation allows missions to be longer with little additional expense or payload.

  5. Thermoelectric Generator (TEG) Fuel Displacement Potential using

    Broader source: Energy.gov (indexed) [DOE]

    Energy Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_fairbanks.pdf (7.06 MB) More Documents & Publications High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation Quantum Well Thermoelectrics and Waste Heat Recovery High Temperature Thermoelectric Materials Engine-in-the-Loop and Simulation | Department of Energy

    Assessment of

  6. Thermoelectric generator cooling system and method of control

    SciTech Connect (OSTI)

    Prior, Gregory P; Meisner, Gregory P; Glassford, Daniel B

    2012-10-16

    An apparatus is provided that includes a thermoelectric generator and an exhaust gas system operatively connected to the thermoelectric generator to heat a portion of the thermoelectric generator with exhaust gas flow through the thermoelectric generator. A coolant system is operatively connected to the thermoelectric generator to cool another portion of the thermoelectric generator with coolant flow through the thermoelectric generator. At least one valve is controllable to cause the coolant flow through the thermoelectric generator in a direction that opposes a direction of the exhaust gas flow under a first set of operating conditions and to cause the coolant flow through the thermoelectric generator in the direction of exhaust gas flow under a second set of operating conditions.

  7. Thermoelectric power generator with intermediate loop

    SciTech Connect (OSTI)

    Bell, Lon E; Crane, Douglas Todd

    2013-05-21

    A thermoelectric power generator is disclosed for use to generate electrical power from heat, typically waste heat. An intermediate heat transfer loop forms a part of the system to permit added control and adjustability in the system. This allows the thermoelectric power generator to more effectively and efficiently generate power in the face of dynamically varying temperatures and heat flux conditions, such as where the heat source is the exhaust of an automobile, or any other heat source with dynamic temperature and heat flux conditions.

  8. Thermoelectric power generator with intermediate loop

    DOE Patents [OSTI]

    Bel,; Lon E.; Crane, Douglas Todd

    2009-10-27

    A thermoelectric power generator is disclosed for use to generate electrical power from heat, typically waste heat. An intermediate heat transfer loop forms a part of the system to permit added control and adjustability in the system. This allows the thermoelectric power generator to more effectively and efficiently generate power in the face of dynamically varying temperatures and heat flux conditions, such as where the heat source is the exhaust of an automobile, or any other heat source with dynamic temperature and heat flux conditions.

  9. Advanced Thermoelectric Materials and Generator Technology for Automotive

    Broader source: Energy.gov (indexed) [DOE]

    Waste Heat at GM | Department of Energy Overview of design, fabrication, integration, and test of working prototype TEG for engine waste heat recovery on Suburban test vehicle, and continuing investigation of skutterudite materials systems meisner.pdf (1.94 MB) More Documents & Publications Advanced Thermoelectric Materials and Generator Technology for Automotive Waste Heat at GM Electrical and Thermal Transport Optimization of High Efficient n-type Skutterudites Electrical and Thermal

  10. Method of operating a thermoelectric generator

    DOE Patents [OSTI]

    Reynolds, Michael G; Cowgill, Joshua D

    2013-11-05

    A method for operating a thermoelectric generator supplying a variable-load component includes commanding the variable-load component to operate at a first output and determining a first load current and a first load voltage to the variable-load component while operating at the commanded first output. The method also includes commanding the variable-load component to operate at a second output and determining a second load current and a second load voltage to the variable-load component while operating at the commanded second output. The method includes calculating a maximum power output of the thermoelectric generator from the determined first load current and voltage and the determined second load current and voltage, and commanding the variable-load component to operate at a third output. The commanded third output is configured to draw the calculated maximum power output from the thermoelectric generator.

  11. Thermoelectric energy converter for generation of electricity from low-grade heat

    DOE Patents [OSTI]

    Jayadev, T.S.; Benson, D.K.

    1980-05-27

    A thermoelectric energy conversion device which includes a plurality of thermoelectric elements is described. A hot liquid is supplied to one side of each element and a cold liquid is supplied to the other side of each element. The thermoelectric generator may be utilized to produce power from low-grade heat sources such as ocean thermal gradients, solar ponds, and low-grade geothermal resources. (WHK)

  12. Thermoelectric generator having a resiliently mounted removable thermoelectric module

    DOE Patents [OSTI]

    Purdy, David L.; Shapiro, Zalman M.; Hursen, Thomas F.; Maurer, Gerould W.

    1976-11-02

    An electrical generator having an Isotopic Heat Capsule including radioactive fuel rod 21 as a primary heat source and Thermoelectric Modules 41 and 43 as converters. The Biological Shield for the Capsule is suspended from Spiders at each end each consisting of pretensioned rods 237 and 239 defining planes at right angles to each other. The Modules are mounted in cups 171 of transition members 173 of a heat rejection Fin Assembly whose fins 195 and 197 extend from both sides of the transition member 173 for effective cooling.

  13. PACCAR/Hi-Z Thermoelectric Generator Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PACCAR/Hi-Z Thermoelectric Generator Project PACCAR/Hi-Z Thermoelectric Generator Project 2002 DEER Conference Presentation: Hi-Z Technology, Inc. 2002_deer_bergstrand.pdf (5.53 MB) More Documents & Publications Self-powered Hydrogen + Oxygen Injection System The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Recent Progress in the Development of High Efficiency Thermoelectrics

  14. Titanium nitride electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Novak, Robert F.; Schmatz, Duane J.; Hunt, Thomas K.

    1987-12-22

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film of titanium nitride as an electrode deposited onto solid electrolyte. The invention is also directed to the method of making same.

  15. Molybdenum oxide electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Schmatz, Duane J.

    1989-01-01

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film comprising molybdenum oxide as an electrode deposited by physical deposition techniques onto solid electrolyte. The invention is also directed to the method of making same.

  16. Glass-like thermal conductivity in high efficiency thermoelectric materials

    Broader source: Energy.gov [DOE]

    Discusses strategies to design thermoelectric materials with extremely low lattice thermal conductivity through modifications of the phonon band structure and phonon relaxation time.

  17. Modular Low Cost High Energy Exhaust Heat Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modular Low Cost High Energy Exhaust Heat Thermoelectric Generator with Closed-Loop ... Solid State Vehicular Generators and HVAC Development An Innovative Pressure Sensor ...

  18. Automotive Thermoelectric Generator Design Issues

    Office of Energy Efficiency and Renewable Energy (EERE)

    Mechanical, electrical, thermal engineering, and durability issues related to use of TEGs in the challenging automotive environment need to be resolved as they affect warranty cost and customer acceptance.

  19. Design and development of thermoelectric generator

    SciTech Connect (OSTI)

    Prem Kumar, D. S. Mahajan, Ishan Vardhan Anbalagan, R. Mallik, Ramesh Chandra

    2014-04-24

    In this paper we discuss the fabrication, working and characteristics of a thermoelectric generator made up of p and n type semiconductor materials. The device consists of Fe{sub 0.2}Co{sub 3.8}Sb{sub 11.5}Te{sub 0.5} (zT = 1.04 at 818 K) as the n-type and Zn4Sb3 (zT=0.8 at 550 K) as the p-type material synthesized by vacuum hot press method. Carbon paste has been used to join the semiconductor legs to metal (Molybdenum) electrodes to reduce the contact resistance. The multi-couple (4 legs) generator results a maximum output power of 1.083 mW at a temperature difference of 240 K between the hot and cold sides. In this investigation, an I-V characteristic, maximum output power of the thermoelectric module is presented. The efficiency of thermoelectric module is obtained as ? = 0.273 %.

  20. Radioisotope thermoelectric generator reliability and safety

    SciTech Connect (OSTI)

    Campbell, R.; Klein, J.

    1989-01-01

    There are numerous occasions when a planetary mission requires energy in remote areas of the solar system. Anytime power is required much beyond Mars or the Asteroid Belts, solar power is not an option. The radioisotope thermoelectric generator (RTG) was developed for such a mission requirement. It is a relatively small and lightweight power source that can produce power under adverse conditions. Just this type of source has become the backbone of the power system for far outer plant exploration. Voyagers I and II are utilizing RTGs, which will soon power the Galileo spacecraft to Jupiter and the Ulysses spacecraft to study the solar poles. The paper discusses RTG operation including thermoelectric design, converter design, general-purpose heat source; RTG reliability including design, testing, experience, and launch approval; and RTG safety issues and methods of ensuring safety.

  1. Powering Curiosity: Multi-Mission Radioisotope Thermoelectric Generators |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Powering Curiosity: Multi-Mission Radioisotope Thermoelectric Generators Powering Curiosity: Multi-Mission Radioisotope Thermoelectric Generators January 29, 2008 - 7:06pm Addthis Mars Science Laboratory, aka Curiosity, is part of NASA's Mars Exploration Program, a long-term program of robotic exploration of the Red Planet. It's powered by the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG). Photo courtesy of NASA/JPL-Caltech. Mars Science Laboratory, aka

  2. Multi-physics modeling of thermoelectric generators for waste...

    Broader source: Energy.gov (indexed) [DOE]

    Model developed provides effective guidelines to designing thermoelectric generation systems for automotive waste heat recovery applications deer12zhang2.pdf (2.06 MB) More ...

  3. Status of Segmented Element Thermoelectric Generator for Vehicle...

    Broader source: Energy.gov (indexed) [DOE]

    Discusses progress of thermoelectric generator development at BSST and assessment of potential to enter commercial operation in vehicles crane.pdf (2.32 MB) More Documents & ...

  4. A miniaturized mW thermoelectric generator for nw objectives...

    Office of Scientific and Technical Information (OSTI)

    reliable power for decades. Citation Details In-Document Search Title: A miniaturized mW thermoelectric generator for nw objectives: continuous, autonomous, reliable power for ...

  5. Thermoelectric Generator Performance for Passenger Vehicles | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10_meisner.pdf (2.38 MB) More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat Recovery Advanced Thermoelectric Materials and Generator Technology for Automotive Waste Heat at GM Advanced Thermoelectric Materials and Generator Technology for Automotive Waste Heat at GM Energy

  6. Radioisotope thermoelectric generator transport trailer system

    SciTech Connect (OSTI)

    Ard, K.E.; King, D.A.; Leigh, H.; Satoh, J.A.

    1995-01-20

    The Radioisotope Thermoelectric Generator (RTG) Transportation System, designated as System 100, comprises four major systems. The four major systems are designated as the Packaging System (System 120), Trailer System (System 140), Operations and Ancillary Equipment System (System 160), and Shipping and Receiving Facility Transport System (System 180). Packaging System (System 120), including the RTG packaging is licensed (regulatory) hardware; it is certified by the U.S. Department of Energy to be in accordance with Title 10, {ital Code} {ital of} {ital Federal} {ital Regulations}, Part 71 (10 CFR 71). System 140, System 160, and System 180 are nonlicensed (nonregulatory) hardware. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}

  7. Microscreen radiation shield for thermoelectric generator

    DOE Patents [OSTI]

    Hunt, Thomas K.; Novak, Robert F.; McBride, James R.

    1990-01-01

    The present invention provides a microscreen radiation shield which reduces radiative heat losses in thermoelectric generators such as sodium heat engines without reducing the efficiency of operation of such devices. The radiation shield is adapted to be interposed between a reaction zone and a means for condensing an alkali metal vapor in a thermoelectric generator for converting heat energy directly to electrical energy. The radiation shield acts to reflect infrared radiation emanating from the reaction zone back toward the reaction zone while permitting the passage of the alkali metal vapor to the condensing means. The radiation shield includes a woven wire mesh screen or a metal foil having a plurality of orifices formed therein. The orifices in the foil and the spacing between the wires in the mesh is such that radiant heat is reflected back toward the reaction zone in the interior of the generator, while the much smaller diameter alkali metal atoms such as sodium pass directly through the orifices or along the metal surfaces of the shield and through the orifices with little or no impedance.

  8. The Effects of an Exhaust Thermoelectric Generator of a GM Sierra...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck 2004 Diesel Engine Emissions ...

  9. Thermoelectric generators incorporating phase-change materials for waste heat recovery from engine exhaust

    DOE Patents [OSTI]

    Meisner, Gregory P; Yang, Jihui

    2014-02-11

    Thermoelectric devices, intended for placement in the exhaust of a hydrocarbon fuelled combustion device and particularly suited for use in the exhaust gas stream of an internal combustion engine propelling a vehicle, are described. Exhaust gas passing through the device is in thermal communication with one side of a thermoelectric module while the other side of the thermoelectric module is in thermal communication with a lower temperature environment. The heat extracted from the exhaust gasses is converted to electrical energy by the thermoelectric module. The performance of the generator is enhanced by thermally coupling the hot and cold junctions of the thermoelectric modules to phase-change materials which transform at a temperature compatible with the preferred operating temperatures of the thermoelectric modules. In a second embodiment, a plurality of thermoelectric modules, each with a preferred operating temperature and each with a uniquely-matched phase-change material may be used to compensate for the progressive lowering of the exhaust gas temperature as it traverses the length of the exhaust pipe.

  10. Thermoelectrics | Solid State Solar Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermoelectrics One of the central themes of S3TEC is to develop more efficient thermoelectric materials to directly convert heat into electricity via the Seebeck effect, or provide cooling via the Peltier effect. Their ability to harvest waste heat and deliver cooling power through solid-state devices without moving parts makes them important candidates of sustainable energy technologies in the future. Despite the benefits, the current bottleneck of thermoelectric technology is its relatively

  11. Synthetic thermoelectric materials comprising phononic crystals

    DOE Patents [OSTI]

    El-Kady, Ihab F; Olsson, Roy H; Hopkins, Patrick; Reinke, Charles; Kim, Bongsang

    2013-08-13

    Synthetic thermoelectric materials comprising phononic crystals can simultaneously have a large Seebeck coefficient, high electrical conductivity, and low thermal conductivity. Such synthetic thermoelectric materials can enable improved thermoelectric devices, such as thermoelectric generators and coolers, with improved performance. Such synthetic thermoelectric materials and devices can be fabricated using techniques that are compatible with standard microelectronics.

  12. Multi-physics modeling of thermoelectric generators for waste heat recovery applications

    Office of Energy Efficiency and Renewable Energy (EERE)

    Model developed provides effective guidelines to designing thermoelectric generation systems for automotive waste heat recovery applications

  13. Nanostructured Thermoelectric Materials and High Efficiency Power...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanostructured Thermoelectric Materials and High Efficiency Power Generation Modules Home ... electrical conductivity and thermopower and, simultaneously, low thermal conductivity. ...

  14. Nanostructured Bulk Thermoelectric Generator for Efficient Power Harvesting for Self-powered Sensor Networks

    SciTech Connect (OSTI)

    Zhang, Yanliang; Butt, Darryl; Agarwal, Vivek

    2015-07-01

    The objective of this Nuclear Energy Enabling Technology research project is to develop high-efficiency and reliable thermoelectric generators for self-powered wireless sensors nodes utilizing thermal energy from nuclear plant or fuel cycle. The power harvesting technology has crosscutting significance to address critical technology gaps in monitoring nuclear plants and fuel cycle. The outcomes of the project will lead to significant advancement in sensors and instrumentation technology, reducing cost, improving monitoring reliability and therefore enhancing safety. The self-powered wireless sensor networks could support the long-term safe and economical operation of all the reactor designs and fuel cycle concepts, as well as spent fuel storage and many other nuclear science and engineering applications. The research is based on recent breakthroughs in high-performance nanostructured bulk (nanobulk) thermoelectric materials that enable high-efficiency direct heat-to-electricity conversion over a wide temperature range. The nanobulk thermoelectric materials that the research team at Boise State University and University of Houston has developed yield up to a 50% increase in the thermoelectric figure of merit, ZT, compared with state-of-the-art bulk counterparts. This report focuses on the selection of optimal thermoelectric materials for this project. The team has performed extensive study on two thermoelectric materials systems, i.e. the half-Heusler materials, and the Bismuth-Telluride materials. The report contains our recent research results on the fabrication, characterization and thermoelectric property measurements of these two materials.

  15. System level modeling of thermoelectric generators for automotive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Uses a model to predict and analyze the system-level performance of a thermoelectric generator in terms of the power output and the power density at the element, module and ...

  16. Development of a 100-Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov [DOE]

    Test results for low and high temperature thermoelectric generators (TEG) those for a 530-watt BiTe TEG; design and construction of a 100-watt high temperature TEG currently in fabrication.

  17. Fiber optic signal amplifier using thermoelectric power generation

    DOE Patents [OSTI]

    Hart, M.M.

    1993-01-01

    A remote fiber optic signal amplifier for use as a repeater/amplifier, such as in transoceanic communication, powered by a Pu{sub 238} or Sr{sub 90} thermoelectric generator. The amplifier comprises a unit with connections on the receiving and sending sides of the communications system, and an erbium-doped fiber amplifier connecting each sending fiber to each receiving fiber. The thermoelectric generator, preferably a Pu{sub 238} or Sr{sub 90} thermoelectric generator delivers power to the amplifiers through a regulator. The heat exchange surfaces of the thermoelectric generator are made of material resistant to corrosion and biological growth and are directly exposed to the outside, such as the ocean water in transoceanic communications.

  18. Fiber optic signal amplifier using thermoelectric power generation

    DOE Patents [OSTI]

    Hart, M.M.

    1995-04-18

    A remote fiber optic signal amplifier for use as a repeater/amplifier, such as in transoceanic communications, powered by a Pu{sub 238} or Sr{sub 90} thermoelectric generator. The amplifier comprises a unit with connections on the receiving and sending sides of the communications system, and an erbium-doped fiber amplifier connecting each sending fiber to each receiving fiber. The thermoelectric generator, preferably a Pu{sub 238} or Sr{sub 90} thermoelectric generator delivers power to the amplifiers through a regulator. The heat exchange surfaces of the thermoelectric generator are made of materials resistant to corrosion and biological growth and are directly exposed to the outside, such as the ocean water in transoceanic communications. 2 figs.

  19. Fiber optic signal amplifier using thermoelectric power generation

    DOE Patents [OSTI]

    Hart, Mark M.

    1995-01-01

    A remote fiber optic signal amplifier for use as a repeater/amplifier, such as in transoceanic communications, powered by a Pu.sub.238 or Sr.sub.90 thermoelectric generator. The amplifier comprises a unit with connections on the receiving and sending sides of the communications system, and an erbium-doped fiber amplifier connecting each sending fiber to each receiving fiber. The thermoelectric generator, preferably a Pu.sub.238 or Sr.sub.90 thermoelectric generator delivers power to the amplifiers through a regulator. The heat exchange surfaces of the thermoelectric generator are made of materials resistant to corrosion and biological growth and are directly exposed to the outside, such as the ocean water in transoceanic communications.

  20. Thermoelectric generator and method for the fabrication thereof

    DOE Patents [OSTI]

    Benson, D.K.; Tracy, C.E.

    1984-08-01

    A thermoelectric generator using semiconductor elements for responding to a temperature gradient to produce electrical energy with all of the semiconductor elements being of the same type is disclosed. A continuous process for forming substrates on which the semiconductor elements and superstrates are deposited and a process for forming the semiconductor elements on the substrates are also disclosed. The substrates with the semiconductor elements thereon are combined with superstrates to form modules for use as thermoelectric generators.

  1. Thermoelectric generator and method for the fabrication thereof

    DOE Patents [OSTI]

    Benson, David K.; Tracy, C. Edwin

    1987-01-01

    A thermoelectric generator using semiconductor elements for responding to a temperature gradient to produce electrical energy with all of the semiconductor elements being of the same type is disclosed. A continuous process for forming substrates on which the semiconductor elements and superstrates are deposited and a process for forming the semiconductor elements on the substrates are also disclosed. The substrates with the semiconductor elements thereon are combined with superstrates to form modules for use thermoelectric generators.

  2. Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE)

    Developing a low and high temperature dual thermoelectric generation waste heat recovery system for light-duty vehicles.

  3. Thermoelectric Materials Development for Low Temperature Geothermal Power Generation

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Tim Hansen

    2016-01-29

    Data includes characterization results for novel thermoelectric materials developed specifically for power generation from low temperature geothermal brines. Materials characterization data includes material density, thickness, resistance, Seebeck coefficient. This research was carried out by Novus Energy Partners in Cooperation with Southern Research Institute for a Department of Energy Sponsored Project.

  4. Molybdenum-platinum-oxide electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Schmatz, Duane J.

    1990-01-01

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a solid electrolyte carrying a thin film comprising molybdenum-platinum-oxide as an electrode deposited by physical deposition techniques. The invention is also directed to the method of making same.

  5. Radioisotope thermoelectric generator transportation system subsystem 143 software development plan

    SciTech Connect (OSTI)

    King, D.A.

    1994-11-10

    This plan describes the activities to be performed and the controls to be applied to the process of specifying, developing, and qualifying the data acquisition software for the Radioisotope Thermoelectric Generator (RTG) Transportation System Subsystem 143 Instrumentation and Data Acquisition System (IDAS). This plan will serve as a software quality assurance plan, a verification and validation (V and V) plan, and a configuration management plan.

  6. An Affordable Advanced Biomass Cookstove with Thermoelectric Generator (TEG)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Bioenergy Technologies Office 2015 Peer Review Biomass Cookstove Technology Review March 26, 2015 Lawrence Berkeley National Laboratory An Affordable Advanced Biomass Cookstove with Thermoelectric Generator (TEG) This presentation does not contain any proprietary, confidential, or otherwise restricted information Ashok Gadgil eere.energy.gov 1 Goal Statement Develop an affordable tier-4 cookstove desirable for purchase Design novel air injection configurations for flame manipulation powered

  7. THERMOELECTRIC GENERATION OF CHARGE IMBALANCE AT A SUPERCONDUCTOR-NORMAL METAL INTERFACE

    SciTech Connect (OSTI)

    Van Harlingen, D. J.

    1981-01-01

    The thermoelectric voltage produced across a superconductor-normal metal-superconductor (SNS) sandwich by an applied heat current has been measured in Pb-Cu-PbBi and In-Al-Sn as a function of temperature. The observed divergence of the thermoelectric voltage near T{sub c} is attributed to a charge imbalance region decaying into the superconductor from the NS interface over the quasiparticle diffusion length {lambda}{sub Q*}. The charge imbalance is generated by thermoelectrically driven quasiparticle currents in the superconductor. It contributes a voltage per unit heat power given by V{sub s}/P = {lambda}{sub Q*}S/{kappa}A, where A is the sample cross-sectional area, and S and {kappa} are the thermopower and the thermal conductivity of quasiparticles in the superconductor. For Pb and In, we find the measured thermopower in the superconducting state to be slowly-varying with temperature near T{sub c} and consistent in magnitude with normal state values. This result is in agreement with theoretical predictions of thermoelectric effects in superconductors but contrary to previous experimental results obtained by other methods.

  8. Thermoelectrics and Photovoltaics - Center for Solar and Thermal Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion Thermoelectrics and Photovoltaics Thermoelectrics A significant amount of heat is wasted from industrial processes, home heating and vehicle exhausts that could otherwise be converted to electricity through the use of thermoelectric devices. The interconversion between heat and electricity, through the use of thermoelectrics, is environmentally friendly and highly reliable. With improved efficiency, thermoelectrics could have a significant impact on the energy consumption

  9. Real-time monitoring during transportation of a radioisotope thermoelectric generator (RTG) using the radioisotope thermoelectric generator transportation system (RTGTS)

    SciTech Connect (OSTI)

    Pugh, B.K.

    1997-01-01

    The Radioisotopic Thermoelectric Generators (RTGs) that will be used to support the Cassini mission will be transported in the Radioisotope Thermoelectric Generator Transportation System (RTGTS). To ensure that the RTGs will not be affected during transportation, all parameters that could adversely affect RTG{close_quote}s performance must be monitored. The Instrumentation and Data Acquisition System (IDAS) for the RTGTS displays, monitors, and records all critical packaging and trailer system parameters. The IDAS also monitors the package temperature control system, RTG package shock and vibration data, and diesel fuel levels for the diesel fuel tanks. The IDAS alarms if any of these parameters reach an out-of-limit condition. This paper discusses the real-time monitoring during transportation of the Cassini RTGs using the RTGTS IDAS. {copyright} {ital 1997 American Institute of Physics.}

  10. Real-time monitoring during transportation of a radioisotope thermoelectric generator (RTG) using the radioisotope thermoelectric generator transportation system (RTGTS)

    SciTech Connect (OSTI)

    Pugh, Barry K.

    1997-01-10

    The Radioisotopic Thermoelectric Generators (RTGs) that will be used to support the Cassini mission will be transported in the Radioisotope Thermoelectric Generator Transportation System (RTGTS). To ensure that the RTGs will not be affected during transportation, all parameters that could adversely affect RTG's performance must be monitored. The Instrumentation and Data Acquisition System (IDAS) for the RTGTS displays, monitors, and records all critical packaging and trailer system parameters. The IDAS also monitors the package temperature control system, RTG package shock and vibration data, and diesel fuel levels for the diesel fuel tanks. The IDAS alarms if any of these parameters reach an out-of-limit condition. This paper discusses the real-time monitoring during transportation of the Cassini RTGs using the RTGTS IDAS.

  11. End-on radioisotope thermoelectric generator impact tests

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Hhinckley, J.E.

    1997-01-01

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of [sup 238]Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). The modular GPHS design was developed to address both survivability during launch abort and return from orbit. The first two RTG Impact Tests were designed to provide information on the response of a fully loaded RTG to end-on impact against a concrete target. The results of these tests indicated that at impact velocities up to 57 m/s the converter shell and internal components protect the GPHS capsules from excessive deformation. At higher velocities, some of the internal components of the RTG interact with the GPHS capsules to cause excessive localized deformation and failure.

  12. End-on radioisotope thermoelectric generator impact tests

    SciTech Connect (OSTI)

    Reimus, M.A.; Hinckley, J.E.

    1997-01-01

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). The modular GPHS design was developed to address both survivability during launch abort and return from orbit. The first two RTG Impact Tests were designed to provide information on the response of a fully loaded RTG to end-on impact against a concrete target. The results of these tests indicated that at impact velocities up to 57 m/s the converter shell and internal components protect the GPHS capsules from excessive deformation. At higher velocities, some of the internal components of the RTG interact with the GPHS capsules to cause excessive localized deformation and failure. {copyright} {ital 1997 American Institute of Physics.}

  13. Radioisotope thermoelectric generator/thin fragment impact test

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Hinckley, J.E.

    1998-12-31

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. This test was designed to provide information on the response of a loaded RTG to impact by a fragment similar to the type of fragment produced by breakup of the spacecraft propulsion module system (PMS). The results of this test indicated that impact of the RTG by a thin aluminum fragment traveling at 306 m/s may result in significant damage to the convertor housing, failure of one fueled clad, and release of a small quantity of fuel.

  14. Radioisotope thermoelectric generator/thin fragment impact test

    SciTech Connect (OSTI)

    Reimus, M.A.; Hinckley, J.E.

    1998-01-01

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. This test was designed to provide information on the response of a loaded RTG to impact by a fragment similar to the type of fragment produced by breakup of the spacecraft propulsion module system (PMS). The results of this test indicated that impact of the RTG by a thin aluminum fragment traveling at 306 m/s may result in significant damage to the converter housing, failure of one fueled clad, and release of a small quantity of fuel. {copyright} {ital 1998 American Institute of Physics.}

  15. Radioisotope thermoelectric generator/thin fragment impact test

    SciTech Connect (OSTI)

    Reimus, M. A. H.; Hinckley, J. E.

    1998-01-15

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. This test was designed to provide information on the response of a loaded RTG to impact by a fragment similar to the type of fragment produced by breakup of the spacecraft propulsion module system (PMS). The results of this test indicated that impact of the RTG by a thin aluminum fragment traveling at 306 m/s may result in significant damage to the converter housing, failure of one fueled clad, and release of a small quantity of fuel.

  16. Progress towards an Optimization Methodology for Combustion-Driven Portable Thermoelectric Power Generation Systems

    SciTech Connect (OSTI)

    Krishnan, Shankar; Karri, Naveen K.; Gogna, Pawan K.; Chase, Jordan R.; Fleurial, Jean-Pierre; Hendricks, Terry J.

    2012-03-13

    Enormous military and commercial interests exist in developing quiet, lightweight, and compact thermoelectric (TE) power generation systems. This paper investigates design integration and analysis of an advanced TE power generation system implementing JP-8 fueled combustion and thermal recuperation. Design and development of a portable TE power system using a JP-8 combustor as a high temperature heat source and optimal process flows depend on efficient heat generation, transfer, and recovery within the system are explored. Design optimization of the system required considering the combustion system efficiency and TE conversion efficiency simultaneously. The combustor performance and TE sub-system performance were coupled directly through exhaust temperatures, fuel and air mass flow rates, heat exchanger performance, subsequent hot-side temperatures, and cold-side cooling techniques and temperatures. Systematic investigation of this system relied on accurate thermodynamic modeling of complex, high-temperature combustion processes concomitantly with detailed thermoelectric converter thermal/mechanical modeling. To this end, this work reports on design integration of systemlevel process flow simulations using commercial software CHEMCADTM with in-house thermoelectric converter and module optimization, and heat exchanger analyses using COMSOLTM software. High-performance, high-temperature TE materials and segmented TE element designs are incorporated in coupled design analyses to achieve predicted TE subsystem level conversion efficiencies exceeding 10%. These TE advances are integrated with a high performance microtechnology combustion reactor based on recent advances at the Pacific Northwest National Laboratory (PNNL). Predictions from this coupled simulation established a basis for optimal selection of fuel and air flow rates, thermoelectric module design and operating conditions, and microtechnology heat-exchanger design criteria. This paper will discuss this

  17. Development of an Underamor 1-kW Thermoelectric Generator Waste Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recovery System for Military Vehicles | Department of Energy an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles Development of an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Hi-Z Technology, Inc. 2004_deer_bass.pdf (484.67 KB) More Documents & Publications High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation

  18. High Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies

    Broader source: Energy.gov [DOE]

    Key technologies and system approaches to excellent record of thermoelectric power sources in deep space missions and development of higher performance TE materials for the next generation systems

  19. Nonequilibrium Thermoelectrics: Low-Cost, High-Performance Materials for Cooling and Power Generation

    SciTech Connect (OSTI)

    Li, Q.

    2011-05-18

    Thermoelectric materials can be made into coolers (TECs) that use electricity to develop a temperature difference, cooling something, or generators (TEGs) that convert heat directly to electricity. One application of TEGs is to place them in a waste heat stream to recuperate some of the power being lost and putting it to use more profitably. To be effective thermoelectrics, however, materials must have both high electrical conductivity and low thermal conductivity, a combination rarely found in nature. Materials selection and processing has led to the development of several systems with a figure of merit, ZT, of nearly unity. By using non-equilibrium techniques, we have fabricated higher efficiency thermoelectric materials. The process involves creating an amorphous material through melt spinning and then sintering it with either spark plasma or a hot press for as little as two minutes. This results in a 100% dense material with an extremely fine grain structure. The grain boundaries appear to retard phonons resulting in a reduced thermal conductivity while the electrons move through the material relatively unchecked. The techniques used are low-cost and scaleable to support industrial manufacturing.

  20. Novel Nanostructured Thermoelectrics | Center for Energy Efficient...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials with improved thermoelectric power generation capabilities, the path to that goal ... electrical conductivity, and reduce the electronic and lattice thermal conductivities. ...

  1. Procurement of a fully licensed radioisotope thermoelectric generator transportation system

    SciTech Connect (OSTI)

    Adkins, H.E.; Bearden, T.E.

    1990-10-01

    A fully licensed transportation system for Radioisotope Thermoelectric Generators and Light-Weight Radioisotope Heater Units is currently being designed and built. The system will comply with all applicable US Department of Transportation regulations without the use of a DOE Alternative.'' The US Department of Transportation has special double containment'' requirements for plutonium. The system packaging uses a doubly contained bell jar'' concept. A refrigerated trailer is used for cooling the high-heat payloads. The same packaging is used for both high- and low-heat payloads. The system is scheduled to be available for use by mid-1992. 4 refs., 4 figs., 2 tabs.

  2. An overview of the Radioisotope Thermoelectric Generator Transporation System Program

    SciTech Connect (OSTI)

    McCoy, J.C.

    1995-10-01

    Radioisotope Thermoelectric Generators (RTG) convert the heat generated by radioactive decay to electricity using thermocouples. RTGs have a long operating life, are reasonably lightweight, and require little or no maintenance once assembled and tested. These factors make RTGs particularly attractive for use in spacecraft However, because RTGs contain significant quantities of radioactive materials, normally plutonium-238 and its decay products, they must be transported in packages built in accordance with Title 10, Code of Federal Regulations, Part 71. The US Department of Energy assigned the Radioisotope Thermoelectric Generator Transportation System (RTGTS) Program to Westinghouse Hanford Company in 1988 to develop a system meeting the regulatory requirements. The program objective was to develop a transportation system that would fully comply with 10 CFR 71 while protecting RTGs from adverse environmental conditions during normal conditions of transport (e.g., shock and heat). The RTGTS is scheduled for completion in December 1996 and will be available to support the National Aeronautics and Space Administrations Cassini mission to Saturn in October 1997. This paper provides an overview of the RTGTS and discusses the hardware being produced. Additionally, various program management innovations mandated by recent ma or changes in the US Department of Energy structure and resources will be outlined.

  3. Thermal Conductivity Measurements of Bulk Thermoelectric Materials (Prop. 2004-067)

    SciTech Connect (OSTI)

    Wang, Hsin; Porter, Wallace D; Sharp, J

    2006-01-01

    Thermal conductivity is an important material property of the bulk thermoelectrics. To improve ZT a reduced thermal conductivity is always desired. However, there is no standard material for thermoelectrics and the test results, even on the same material, often show significant scatter. The scatter in thermal conductivity made reported ZT values uncertain and sometime unrepeatable. One of the reasons for the uncertainty is due to the microstructure differences resulting from sintering, heat treatment and other processing parameters. They selected commonly used bulk thermoelectric materials and conducted thermal conductivity measurements using the laser flash diffusivity and differential scanning calorimeter (DSC) systems. Thermal conductivity was measured as a function of temperature of temperature from room temperature to 500 K and back to room temperature. The effect of thermal cycling on the bulk thermoelectric was studied. Comnbined with measurements on electrical resistivity and Seebeck coefficient, they show the use of a ZT map in selecting thermoelectrics. The commercial bulk material showed very good consistency and reliability compared to other bulk materials. The goal is to develop a thermal transport properties database for the bulk thermoelectrics and make the information available to the research community and industry.

  4. Thermoelectric HVAC and Thermal Comfort Enablers for Light-Duty...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Thermoelectric HVAC for Light-Duty Vehicle Applications Improving efficiency of a vehicle HVAC system with comfort modeling, zonal design, and ...

  5. A facility to remotely assemble radioisotope thermoelectric generators

    SciTech Connect (OSTI)

    Engstrom, J.W.; Goldmann, L.H.; Truitt, R.W.

    1992-07-01

    Radioisotope Thermoelectric Generators (RTGs) are electrical power sources that use heat from decaying radioisotopes to directly generate electrical power. The RTG assembly process is performed in an inert atmosphere inside a large glovebox, which is surrounded by radiation shielding to reduce exposure to neutron and gamma radiation from the radioisotope heat source. In the past, allowable dose rate limits have allowed direct, manual assembly methods; however, current dose rate limits require a thicker radiation shielding that makes direct, manual assembly infeasible. To minimize RTG assembly process modifications, telerobotic systems are being investigated to perform remote assembly tasks. Telerobotic systems duplicate human arm motion and incorporate force feedback sensitivity to handle objects and tools in a human-like manner. A telerobotic system with two arms and a three-dimensional (3-D) vision system can be used to perform remote RTG assembly tasks inside gloveboxes and cells using unmodified, normal hand tools.

  6. A facility to remotely assemble radioisotope thermoelectric generators

    SciTech Connect (OSTI)

    Engstrom, J.W.; Goldmann, L.H.; Truitt, R.W. )

    1993-01-15

    Radioisotope Thermoelectric Generators (RTGs) are electrical power sources that use heat from decaying radioisotopes to directly generate electrical power. The RTG assembly process is performed in an inert atmosphere inside a large glovebox, which is surrounded by radiation shielding to reduce exposure to neutron and gamma radiation from the radioisotope heat source. In the past, allowable dose rate limits have allowed direct, manual assembly methods; however, current dose rate limits require a thicker radiation shielding that makes direct, manual assembly infeasible. To minimize RTG assembly process modifications, telerobotic systems are being investigated to perform remote assembly tasks. Telerobotic systems duplicate human arm motion and incorporate force feedback sensitivity to handle objects and tools in a human-like manner. A telerobotic system with two arms and a three-dimensional (3-D) vision system can be used to perform remote RTG assembly tasks inside gloveboxes and cells using unmodified, normal hand tools.

  7. Clean Diesel Engine Component Improvement Program Diesel Truck Thermoelectric Generator

    SciTech Connect (OSTI)

    Elsner, N. B.; Bass, J. C.; Ghamaty, S.; Krommenhoek, D.; Kushch, A.; Snowden, D.; Marchetti, S.

    2005-03-16

    Hi-Z Technology, Inc. (Hi-Z) is currently developing four different auxiliary generator designs that are used to convert a portion (5 to 20%) of the waste heat from vehicle engines exhaust directly to electricity. The four designs range from 200 Watts to 10 kW. The furthest along is the 1 kW Diesel Truck Thermoelectric Generator (DTTEG) for heavy duty Class 8 Diesel trucks, which, under this program, has been subjected to 543,000 equivalent miles of bouncing and jarring on PACCAR's test track. Test experience on an earlier version of the DTTEG on the same track showed the need for design modifications incorporated in DTTEG Mod 2, such as a heavy duty shock mounting system and reinforcement of the electrical leads mounting system, the thermocouple mounting system and the thermoelectric module restraints. The conclusion of the 543,000 mile test also pointed the way for an upgrading to heavy duty hose or flex connections for the internal coolant connections for the TEG, and consideration of a separate lower temperature cooling loop with its own radiator. Fuel savings of up to $750 per year and a three to five year payback are believed to be possible with the 5 % efficiency modules. The economics are expected to improve considerably to approach a two year payback when the 5 kW to 10 kW generators make it to the market in a few years with a higher efficiency (20%) thermoelectric module system called Quantum Wells, which are currently under development by Hi-Z. Ultimately, as automation takes over to reduce material and labor costs in the high volume production of QW modules, a one year payback for the 5 kW to10 kW generator appears possible. This was one of the stated goals at the beginning of the project. At some future point in time, with the DTTEG becoming standard equipment on all trucks and automobiles, fuel savings from the 25% conversion of exhaust heat to useable electricity nationwide equates to a 10% reduction in the 12 to 15 million barrels per day of

  8. Specification for strontium-90 500-watt(e) radioisotopic thermoelectric generator. Final report

    SciTech Connect (OSTI)

    Hammel, T.; Himes, J.; Lieberman, A.; McGrew, J.; Owings, D.; Schumann, F.

    1983-04-01

    A conceptual design for a demonstration 500-watt(e) radioisotopic thermoelectric generator has been created for the Department of Energy. The design effort was divided into two tasks, viz., create a design specification for a capsule strength member that utilizes a standard Strontium-90 fluoride-filled WESF inner liner, and create a conceptual design for a 500-watt(e) RTG. Both tasks have been accomplished. The strength-member specification was designed to survive an external pressure of 24,500 psi and meet the requirements of special-form radioisotope heat sources. Therefore the capsule can, if desired, be licensed for domestic and international transport. The design for the RTG features a radioisotopic heat source, an array of nine capsules in a tungsten biological shield, four current-technology series-connected thermoelectric-conversion modules, low-conductivity thermal insulation, and a passive finned-housing radiator for waste-heat dissipation. The preliminary RTG specification formulated previous to contract award has been met or exceeded. The power source will generate the required power for the required service period at 28 volts dc with a conversion efficiency of 8%, provided the existing in-pool capsules at WESF meet the assumed thermal-inventory requirements.

  9. Commercialization of Bulk Thermoelectric Materials for Power Generation

    Broader source: Energy.gov [DOE]

    Critical aspects of technology commercialization of preproduction high performance thermoelectric materials available for device developers, data analysis, and future plans are discussed

  10. High Reliability, High TemperatureThermoelectric Power Generation...

    Broader source: Energy.gov (indexed) [DOE]

    Key technologies and system approaches to excellent record of thermoelectric power sources in deep space missions and development of higher performance TE materials for the next ...

  11. Device for use in a furnace exhaust stream for thermoelectric generation

    DOE Patents [OSTI]

    Polcyn, Adam D.

    2013-06-11

    A device for generating voltage or electrical current includes an inner elongated member mounted in an outer elongated member, and a plurality of thermoelectric modules mounted in the space between the inner and the outer members. The outer and/or inner elongated members each include a plurality of passages to move a temperature altering medium through the members so that the device can be used in high temperature environments, e.g. the exhaust system of an oxygen fired glass melting furnace. The modules are designed to include a biasing member and/or other arrangements to compensate for differences in thermal expansion between the first and the second members. In this manner, the modules remain in contact with the first and second members. The voltage generated by the modules can be used to power electrical loads.

  12. Exploring packaging strategies of nano-embedded thermoelectric generators

    SciTech Connect (OSTI)

    Singha, Aniket; Muralidharan, Bhaskaran; Mahanti, Subhendra D.

    2015-10-15

    Embedding nanostructures within a bulk matrix is an important practical approach towards the electronic engineering of high performance thermoelectric systems. For power generation applications, it ideally combines the efficiency benefit offered by low dimensional systems along with the high power output advantage offered by bulk systems. In this work, we uncover a few crucial details about how to embed nanowires and nanoflakes in a bulk matrix so that an overall advantage over pure bulk may be achieved. First and foremost, we point out that a performance degradation with respect to bulk is inevitable as the nanostructure transitions to a multi moded one. It is then shown that a nano embedded system of suitable cross-section offers a power density advantage over a wide range of efficiencies at higher packing fractions, and this range gradually narrows down to the high efficiency regime, as the packing fraction is reduced. Finally, we introduce a metric - the advantage factor, to elucidate quantitatively, the enhancement in the power density offered via nano-embedding at a given efficiency. In the end, we explore the maximum effective width of nano-embedding which serves as a reference in designing generators in the efficiency range of interest.

  13. Electron-beam activated thermal sputtering of thermoelectric materials

    SciTech Connect (OSTI)

    Wu Jinsong; Dravid, Vinayak P.; He Jiaqing; Han, Mi-Kyung; Sootsman, Joseph R.; Girard, Steven; Arachchige, Indika U.; Kanatzidis, Mercouri G.

    2011-08-15

    Thermoelectricity and Seebeck effect have long been observed and validated in bulk materials. With the development of advanced tools of materials characterization, here we report the first observation of such an effect in the nanometer scale: in situ directional sputtering of several thermoelectric materials inside electron microscopes. The temperature gradient introduced by the electron beam creates a voltage-drop across the samples, which enhances spontaneous sputtering of specimen ions. The sputtering occurs along a preferential direction determined by the direction of the temperature gradient. A large number of nanoparticles form and accumulate away from the beam location as a result. The sputtering and re-crystallization are found to occur at temperatures far below the melting points of bulk materials. The sputtering occurs even when a liquid nitrogen cooling holder is used to keep the overall temperature at -170 deg. C. This unique phenomenon that occurred in the nanometer scale may provide useful clues to understanding the mechanism of thermoelectric effect.

  14. Electron-beam activated thermal sputtering of thermoelectric materials.

    SciTech Connect (OSTI)

    Wu, J.; He, J.; Han, M-K.; Sootsman, J. R.; Girard, S.; Arachchige, I. U.; Kanatzidis, M. G.; Dravid, V. P.

    2011-08-01

    Thermoelectricity and Seebeck effect have long been observed and validated in bulk materials. With the development of advanced tools of materials characterization, here we report the first observation of such an effect in the nanometer scale: in situ directional sputtering of several thermoelectric materials inside electron microscopes. The temperature gradient introduced by the electron beam creates a voltage-drop across the samples, which enhances spontaneous sputtering of specimen ions. The sputtering occurs along a preferential direction determined by the direction of the temperature gradient. A large number of nanoparticles form and accumulate away from the beam location as a result. The sputtering and re-crystallization are found to occur at temperatures far below the melting points of bulk materials. The sputtering occurs even when a liquid nitrogen cooling holder is used to keep the overall temperature at -170 C. This unique phenomenon that occurred in the nanometer scale may provide useful clues to understanding the mechanism of thermoelectric effect.

  15. High Temperature Thermal Array for Next Generation Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This ...

  16. High Energy Density Thermal Batteries: Thermoelectric Reactors for Efficient Automotive Thermal Storage

    SciTech Connect (OSTI)

    2011-11-15

    HEATS Project: Sheetak is developing a new HVAC system to store the energy required for heating and cooling in EVs. This system will replace the traditional refrigerant-based vapor compressors and inefficient heaters used in today’s EVs with efficient, light, and rechargeable hot-and-cold thermal batteries. The high energy density thermal battery—which does not use any hazardous substances—can be recharged by an integrated solid-state thermoelectric energy converter while the vehicle is parked and its electrical battery is being charged. Sheetak’s converters can also run on the electric battery if needed and provide the required cooling and heating to the passengers—eliminating the space constraint and reducing the weight of EVs that use more traditional compressors and heaters.

  17. Spin-on-doping for output power improvement of silicon nanowire array based thermoelectric power generators

    SciTech Connect (OSTI)

    Xu, B. Fobelets, K.

    2014-06-07

    The output power of a silicon nanowire array (NWA)-bulk thermoelectric power generator (TEG) with Cu contacts is improved by spin-on-doping (SOD). The Si NWAs used in this work are fabricated via metal assisted chemical etching (MACE) of 0.010.02 ? cm resistivity n- and p-type bulk, converting ~4% of the bulk thickness into NWs. The MACE process is adapted to ensure crystalline NWs. Current-voltage and Seebeck voltage-temperature measurements show that while SOD mainly influences the contact resistance in bulk, it influences both contact resistance and power factor in NWA-bulk based TEGs. According to our experiments, using Si NWAs in combination with SOD increases the output power by an order of 3 under the same heating power due to an increased power factor, decreased thermal conductivity of the NWA and reduced Si-Cu contact resistance.

  18. Certification testing of the Los Alamos National Laboratory Heat Source/Radioisotopic Thermoelectric Generator shipping container

    SciTech Connect (OSTI)

    Bronowski, D.R.; Madsen, M.M.

    1991-09-01

    The Heat Source/Radioisotopic Thermoelectric Generator shipping counter is a Type B packaging currently under development by Los Alamos National Laboratory. Type B packaging for transporting radioactive material is required to maintain containment and shielding after being exposed to normal and hypothetical accident environments defined in Title 10 of the Code of Federal Regulations Part 71. A combination of testing and analysis is used to verify the adequacy of this packaging design. This report documents the testing portion of the design verification. Six tests were conducted on a prototype package: a water spray test, a 4-foot normal conditions drop test, a 30-foot drop test, a 40-inch puncture test, a 30-minute thermal test, and an 8-hour immersion test.

  19. Calculated transport properties of CdO: thermal conductivity and thermoelectric power factor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lindsay, Lucas R.; Parker, David S.

    2015-10-01

    We present first principles calculations of the thermal and electronic transport properties of the oxide semiconductor CdO. In particular, we find from theory that the accepted thermal conductivity κ value of 0.7 Wm-1K-1 is approximately one order of magnitude too small; our calculations of κ of CdO are in good agreement with recent measurements. We also find that alloying of MgO with CdO is an effective means to reduce the lattice contribution to κ, despite MgO having a much larger thermal conductivity. We further consider the electronic structure of CdO in relation to thermoelectric performance, finding that large thermoelectric powermore » factors may occur if the material can be heavily doped p-type. This work develops insight into the nature of thermal and electronic transport in an important oxide semiconductor.« less

  20. Calculated transport properties of CdO: thermal conductivity and thermoelectric power factor

    SciTech Connect (OSTI)

    Lindsay, Lucas R.; Parker, David S.

    2015-10-01

    We present first principles calculations of the thermal and electronic transport properties of the oxide semiconductor CdO. In particular, we find from theory that the accepted thermal conductivity κ value of 0.7 Wm-1K-1 is approximately one order of magnitude too small; our calculations of κ of CdO are in good agreement with recent measurements. We also find that alloying of MgO with CdO is an effective means to reduce the lattice contribution to κ, despite MgO having a much larger thermal conductivity. We further consider the electronic structure of CdO in relation to thermoelectric performance, finding that large thermoelectric power factors may occur if the material can be heavily doped p-type. This work develops insight into the nature of thermal and electronic transport in an important oxide semiconductor.

  1. Advanced Soldier Thermoelectric Power System for Power Generation from Battlefield Heat Sources

    SciTech Connect (OSTI)

    Hendricks, Terry J.; Hogan, Tim; Case, Eldon D.; Cauchy, Charles J.

    2010-09-01

    The U.S. military uses large amounts of fuel during deployments and battlefield operations. This project sought to develop a lightweight, small form-factor, soldier-portable advanced thermoelectric (TE) system prototype to recover and convert waste heat from various deployed military equipment (i.e., diesel generators/engines, incinerators, vehicles, and potentially mobile kitchens), with the ultimate purpose of producing power for soldier battery charging, advanced capacitor charging, and other battlefield power applications. The technical approach employed microchannel technology, a unique “power panel” approach to heat exchange/TE system integration, and newly-characterized LAST (lead-antimony-silver-telluride) and LASTT (lead-antimony-silver-tin-telluride) TE materials segmented with bismuth telluride TE materials in designing a segmented-element TE power module and system. This project researched never-before-addressed system integration challenges (thermal expansion, thermal diffusion, electrical interconnection, thermal and electrical interfaces) of designing thin “power panels” consisting of alternating layers of thin, microchannel heat exchangers (hot and cold) sandwiching thin, segmented-element TE power generators. The TE properties, structurally properties, and thermal fatigue behavior of LAST and LASTT materials were developed and characterized such that the first segmented-element TE modules using LAST / LASTT materials were fabricated and tested at hot-side temperatures = 400 °C and cold-side temperatures = 40 °C. LAST / LASTT materials were successfully segmented with bismuth telluride and electrically interconnected with diffusion barrier materials and copper strapping within the module electrical circuit. A TE system design was developed to produce 1.5-1.6 kW of electrical energy using these new TE modules from the exhaust waste heat of 60-kW Tactical Quiet Generators as demonstration vehicles.

  2. Analytical Modeling and Simulation of Thermoelectric Devices...

    Broader source: Energy.gov (indexed) [DOE]

    and Technologies Micro- & Nano-Technologies Enabling More Compact, Lightweight Thermoelectric Power Generation & Cooling Systems Automotive Thermoelectric Generators and HVAC

  3. Commercialization of Bulk Thermoelectric Materials for Power...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercialization of Bulk Thermoelectric Materials for Power Generation Commercialization of Bulk Thermoelectric Materials for Power Generation Critical aspects of technology ...

  4. Exhaust gas bypass valve control for thermoelectric generator

    DOE Patents [OSTI]

    Reynolds, Michael G; Yang, Jihui; Meisner, Greogry P.; Stabler, Francis R.; De Bock, Hendrik Pieter Jacobus; Anderson, Todd Alan

    2012-09-04

    A method of controlling engine exhaust flow through at least one of an exhaust bypass and a thermoelectric device via a bypass valve is provided. The method includes: determining a mass flow of exhaust exiting an engine; determining a desired exhaust pressure based on the mass flow of exhaust; comparing the desired exhaust pressure to a determined exhaust pressure; and determining a bypass valve control value based on the comparing, wherein the bypass valve control value is used to control the bypass valve.

  5. Proof-of-principle test for thermoelectric generator for diesel engines; Final report

    SciTech Connect (OSTI)

    1991-07-26

    In September of 1987, the principals of what is now Hi-Z TECHNOLOGY, INC. applied to the National Bureau of Standards (now National Institute of Standards and Technology, NIST) under the Energy Related Inventions Program. The invention was entitled ``Thermoelectric Generator for Diesel Engines.`` The National Institute of Standards and Technology evaluated the invention and on January 12, 1989 forwarded Recommendation Number 455 to the Department of Energy (DOE). This recommendation informed the DOE that the invention had been selected for recommendation by the NIST for possible funding by the DOE. Following the recommendation of the NIST, the DOE contacted Hi-Z to work out a development program for the generator. A contract for a grant to design, fabricate, and test a Proof-of-Principle exhaust powered thermoelectric generator for Diesel engines was signed October 19, 1989. Hi-Z provided the thermoelectric modules used in the generator as their contribution to the project. The purpose of this Grant Program was to design, build, and test a small-scale, Proof-of-Principle thermoelectric generator for a Diesel engine. 15 figs., 1 tab.

  6. Thermoelectrics: The New Green Automotive Technology | Department...

    Broader source: Energy.gov (indexed) [DOE]

    (5.35 MB) More Documents & Publications Automotive Thermoelectric Generators and HVAC Vehicular Thermoelectrics: A New Green Technology Thermoelectrics: The New Green Automotive

  7. Thermoelectric Nanocarbon Ensembles | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2_gruen.pdf (1.55 MB) More Documents & Publications Diamond Based TE Materials DOE Vehicle Technologies Program 2009 Merit Review Report - Propulsion Materials Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

  8. Rare Earth Atoms Make the Best Thermoelectrics Better | U.S....

    Office of Science (SC) Website

    ... interplay between electronic and thermal transport in the material that is ... the goal of ZT 2.0 needed for the commercialization of thermoelectric power generation. ...

  9. Proactive Strategies for Designing Thermoelectric Materials for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Proactive Strategies for Designing Thermoelectric Materials for Power Generation Proactive Strategies for Designing Thermoelectric Materials for Power ...

  10. Reduced thermal conductivity in niobium-doped calcium-manganate compounds for thermoelectric applications

    SciTech Connect (OSTI)

    Graff, Ayelet; Amouyal, Yaron

    2014-11-03

    Reduction of thermal conductivity is essential for obtaining high energy conversion efficiency in thermoelectric materials. We report on significant reduction of thermal conductivity in niobium-doped CaO(CaMnO{sub 3}){sub m} compounds for thermoelectric energy harvesting due to introduction of extra CaO-planes in the CaMnO{sub 3}-base material. We measure the thermal conductivities of the different compounds applying the laser flash analysis at temperatures between 300 and 1000 K, and observe a remarkable reduction in thermal conductivity with increasing CaO-planar density, from a value of 3.7 W·m{sup −1}K{sup −1} for m = ∞ down to 1.5 W·m{sup −1}K{sup −1} for m = 1 at 400 K. This apparent correlation between thermal conductivity and CaO-planar density is elucidated in terms of boundary phonon scattering, providing us with a practical way to manipulate lattice thermal conductivity via microstructural modifications.

  11. Thermal to Electrical Energy Conversion of Skutterudite-Based Thermoelectric Modules

    SciTech Connect (OSTI)

    Salvador, James R.; Cho, Jung Y; Ye, Zuxin; Moczygemba, Joshua E.; Thompson, Alan; Sharp, Jeff W.; Konig, Jan; Maloney, Ryan; Thompson, Travis; Sakamoto, Jeff; Wang, Hsin; Wereszczak, Andrew A; Meisner, G P

    2013-01-01

    The performance of thermoelectric (TE) materials has improved tremendously over the past decade. The intrinsic thermal and electrical properties of state-of-the-art TE materials demonstrate that the potential for widespread practical TE applications is very large and includes TE generators (TEGs) for automotive waste heat recovery. TE materials for automotive TEG applications must have good intrinsic performance, be thermomechanically compatible, and be chemically stable in the 400 K to 850 K temperature range. Both n-type and p-type varieties must be available at low cost, easily fabricated, and durable. They must also form robust junctions and develop good interfaces with other materials to permit efficient flows of electrical and thermal energy. Among the TE materials of interest for automotive waste heat recovery systems are the skutterudite compounds, which are the antimony-based transition-metal compounds RTE4Sb12, where R can be an alkali metal (e.g., Na, K), alkaline earth (e.g., Ba), or rare earth (e.g., La, Ce, Yb), and TE can be a transition metal (e.g., Co, Fe). We synthesized a considerable quantity of n-type and p-type skutterudites, fabricated TE modules, incorporated these modules into a prototype TEG, and tested the TEG on a production General Motors (GM) vehicle. We discuss our progress on skutterudite TE module fabrication and present module performance data for electrical power output under simulated operating conditions for automotive waste heat recovery systems. We also present preliminary durability results on our skutterudite modules.

  12. EIS-0302: Transfer of the Heat Source/Radioisotope Thermoelectric Generator Assembly and Test Operations From the Mound Site

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposed transfer of the Heat Source/Radioisotope Thermoelectric Generator (HS/RTG) operations at the Mound Site near Miamisburg, Ohio, to an alternative DOE site.

  13. Progress in Thermoelectrical Energy Recovery from a Light Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Thermoelectrical Energy Recovery From the Exhaust of a Light Truck Automotive Thermoelectric Generators and HVAC

  14. Complex oxides useful for thermoelectric energy conversion

    SciTech Connect (OSTI)

    Majumdar, Arunava; Ramesh, Ramamoorthy; Yu, Choongho; Scullin, Matthew L.; Huijben, Mark

    2012-07-17

    The invention provides for a thermoelectric system comprising a substrate comprising a first complex oxide, wherein the substrate is optionally embedded with a second complex oxide. The thermoelectric system can be used for thermoelectric power generation or thermoelectric cooling.

  15. Freshwater Availability and Constraints on Thermoelectric Power Generation in the Southeast U.S.

    SciTech Connect (OSTI)

    David Feldman; Amanda Slough; Gary Garrett

    2008-06-01

    There is a myriad of uses to which our country's freshwater supply is currently committed. Together with increasing quantities of consumption, there are growing constraints on water availability. In our future there will be two elements of consumption at the forefront of concern: availability and efficiency. Availability of freshwater is the most important of these and is the subject of this report. To use water efficiently, we must first have it. Efficiency is key to ensuring availability for future needs. As population grows and economic and technology demands increase - especially for thermoelectric power - needs for freshwater will also increase. Thus, using our limited supplies of freshwater must be done as efficiently as possible. Thermoelectric generating industry is the largest user of our nation's water resources, including fresh, surface, ground, and saline water. Saline water use accounts for approximately 30% of thermoelectric use, while the remaining 70% is from freshwater sources. The U.S. Geological Survey (USGS) estimates that thermoelectric generation accounts for roughly 136,000 million gallons per day (MGD), or 39% of freshwater withdrawals. This ranks slightly behind agricultural irrigation as the top source of freshwater withdrawals in the U.S. in 2000. For Americans to preserve their standard of living and maintain a thriving economy it is essential that greater attention be paid to freshwater availability in efforts to meet energy demands - particularly for electric power. According to projections by the Energy Information Administration's (EIA) Annual Energy Outlook 2006 (AEO 2006) anticipated growth of thermoelectric generating capacity will be 22% between 2005 and 2030. In the 2007 Report, EIA estimates that capacity to grow from approximately 709 GW in 2005 to 862 GW in 20303. These large increases in generating capacity will result in increased water demands by thermoelectric power plants and greater competition over water between the

  16. Modular Isotopic Thermoelectric Generator (MITG) Design and Development, Part A-E. Original was presented at 1983 Intersociety Energy Conversion Engineering Conference (IECEC)

    SciTech Connect (OSTI)

    Schock, A.

    1983-04-29

    Advanced RTG concepts utilizing improved thermoelectric materials and converter concepts are under study at Fairchild for DOE. The design described here is based on DOE's newly developed radioisotope heat source, and on an improved silicon-germanium material and a multicouple converter module under development at Syncal. Fairchild's assignment was to combine the above into an attractive power system for use in space, and to assess the specific power and other attributes of that design. The resultant design is highly modular, consisting of standard RTG slices, each producing 24 watts at the desired output voltage of 28 volt. Thus, the design could be adapted to various space missions over a wide range of power levels, with little or no redesign. Each RTG slice consists of a 250-watt heat source module, eight multicouple thermoelectric modules, and standard sections of insulator, housing, radiator fins, and electrical circuit. The design makes it possible to check each thermoelectric module for electrical performance, thermal contact, leaktightness, and performance stability, after the generator is fully assembled; and to replace any deficient modules without disassembling the generator or perturbing the others. The RTG end sections provide the spring-loaded supports required to hold the free-standing heat source stack together during launch vibration. Detailed analysis indicates that the present generation of RTGs, using the same heat source modules. There is a duplicate copy of this document. OSTI has a copy of this paper.

  17. Thermoelectrics Partnership: Automotive Thermoelectric Modules...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solution for Automotive Thermoelectric Modules Application Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces

  18. Quantum Well Thermoelectrics and Waste Heat Recovery | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation Recent Progress in the Development of High Efficiency Thermoelectrics High Temperature Thermoelectric ...

  19. Thermoelectric power generator module of 16x16 Bi{sub 2}Te{sub 3} and 0.6%ErAs:(InGaAs){sub 1-x}(InAlAs){sub x} segmented elements

    SciTech Connect (OSTI)

    Zeng Gehong; Bahk, Je-Hyeong; Bowers, John E.; Lu Hong; Gossard, Arthur C.; Singer, Suzanne L.; Majumdar, Arun; Bian, Zhixi; Zebarjadi, Mona; Shakouri, Ali

    2009-08-24

    We report the fabrication and characterization of thermoelectric power generator modules of 16x16 segmented elements consisting of 0.8 mm thick Bi{sub 2}Te{sub 3} and 50 {mu}m thick ErAs:(InGaAs){sub 1-x}(InAlAs){sub x} with 0.6% ErAs by volume. An output power up to 6.3 W was measured when the heat source temperature was at 610 K. The thermoelectric properties of (InGaAs){sub 1-x}(InAlAs){sub x} were characterized from 300 up to 830 K. The finite element modeling shows that the performance of the generator modules can further be enhanced by improving the thermoelectric properties of the element materials, and reducing the electrical and thermal parasitic losses.

  20. Impact of parasitic thermal effects on thermoelectric property measurements by Harman method

    SciTech Connect (OSTI)

    Kwon, Beomjin Baek, Seung-Hyub; Keun Kim, Seong; Kim, Jin-Sang

    2014-04-15

    Harman method is a rapid and simple technique to measure thermoelectric properties. However, its validity has been often questioned due to the over-simplified assumptions that this method relies on. Here, we quantitatively investigate the influence of the previously ignored parasitic thermal effects on the Harman method and develop a method to determine an intrinsic ZT. We expand the original Harman relation with three extra terms: heat losses via both the lead wires and radiation, and Joule heating within the sample. Based on the expanded Harman relation, we use differential measurement of the sample geometry to measure the intrinsic ZT. To separately evaluate the parasitic terms, the measured ZTs with systematically varied sample geometries and the lead wire types are fitted to the expanded relation. A huge discrepancy (∼28%) of the measured ZTs depending on the measurement configuration is observed. We are able to separately evaluate those parasitic terms. This work will help to evaluate the intrinsic thermoelectric property with Harman method by eliminating ambiguities coming from extrinsic effects.

  1. Mass Properties Testing and Evaluation for the Multi-Mission Radioisotope Thermoelectric Generator

    SciTech Connect (OSTI)

    Felicione, Frank S.

    2009-12-01

    Mass properties (MP) measurements were performed for the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG), serial number (S/N) 0X730401, the power system designated for the Mars Science Laboratory (MSL) mission. Measurements were made using new mounting fixtures at the mass properties testing station in the Idaho National Laboratory (INL) Space and Security Power Systems Facility (SSPSF). The objective of making mass properties measurements was to determine the generators flight configured mass and center of mass or center of gravity (CG). Using an extremely accurate platform scale, the mass of the as-tested generator was determined to be 100.117 0.007 lb. Weight accuracy was determined by checking the platform scale with calibrated weights immediately prior to weighing the MMRTG.a CG measurement accuracy was assessed by surrogate testing using an inert mass standard for which the CG could be readily determined analytically. Repeated testing using the mass standard enabled the basic measurement precision of the system to be quantified in terms of a physical confidence interval about the measured CG position. However, repetitious testing with the MMRTG itself was not performed in deference to the gamma and neutron radiation dose to operators and the damage potential to the flight unit from extra handling operations. Since the mass standard had been specially designed to have a total weight and CG location that closely matched the MMRTG, the uncertainties determined from its testing were assigned to the MMRTG as well. On this basis, and at the 99% confidence level, a statistical analysis found the direct, as-measured MMRTG-MSL CG to be located at 10.816 0.0011 in. measured perpendicular from the plane of the lower surface of the generators mounting lugs (Z direction), and offset from the generators long axis centerline in the X and Y directions by 0.0968 0.0040 in. and 0.0276 0.0026 in., respectively. These uncertainties are based simply on the

  2. Engineering Scoping Study of Thermoelectric Generator Systems for Industrial Waste Heat Recovery

    SciTech Connect (OSTI)

    Hendricks, Terry; Choate, William T.

    2006-11-01

    This report evaluates thermoelectric generator (TEG) systems with the intent to: 1) examine industrial processes in order to identify and quantify industrial waste heat sources that could potentially use TEGs; 2) describe the operating environment that a TEG would encounter in selected industrial processes and quantify the anticipated TEG system performance; 3) identify cost, design and/or engineering performance requirements that will be needed for TEGs to operate in the selected industrial processes; and 4) identify the research, development and deployment needed to overcome the limitations that discourage the development and use of TEGs for recovery of industrial waste heat.

  3. Work plan for the fabrication of the radioisotope thermoelectric generator transportation system package mounting

    SciTech Connect (OSTI)

    Satoh, J.A.

    1994-11-09

    The Radioisotope Thermoelectric Generator (RTG) has available a dedicated system for the transportation of RTG payloads. The RTG Transportation System (System 100) is comprised of four systems; the Package (System 120), the Semi-trailer (System 140), the Gas Management (System 160), and the Facility Transport (System 180). This document provides guidelines on the fabrication, technical requirements, and quality assurance of the Package Mounting (Subsystem 145), part of System 140. The description follows the Development Control Requirements of WHC-CM-6-1, EP 2.4, Rev. 3.

  4. Environmental assessment of decommissioning radioisotope thermoelectric generators (RTG) in northwest Russia

    SciTech Connect (OSTI)

    Hosseini, A.; Standring, W.J.F.; Brown, J.E.; Dowdall, M.; Amundsen, I.B.

    2007-07-01

    This article presents some results from assessment work conducted as part of a joint Norwegian-Russian project to decommission radioisotope thermoelectric generators (RTG) in Northwest Russia. Potential worst case accident scenarios, based on the decommissioning procedures for RTGs, were assessed to study possible radiation effects to the environment. Close contact with exposed RTG sources will result in detrimental health effects. However, doses to marine biota from ingestion of radioactivity under the worst-case marine scenario studied were lower than threshold limits given in IAEA literature. (authors)

  5. Development and Demonstration of a Modeling Framework for Assessing the Efficacy of Using Mine Water for Thermoelectric Power Generation

    SciTech Connect (OSTI)

    2010-03-01

    studies of mine water and power plant cooling. Visual basic software was used to create general information/evaluation modules for a range of power plant water needs that were tested/verified against the Beech Hollow project. The program allows for consideration of blending mine water as needed as well as considering potential thermal and environmental benefits that can be derived from using constant temperature mine water. Users input mine water flow, quality, distance to source, elevations to determine collection, transport and treatment system design criteria. The program also evaluates low flow volumes and sustainable yields for various sources. All modules have been integrated into a seamless user friendly computer design aid and user's manual for evaluating the capital and operating costs of mine water use. The framework will facilitate the use of mine water for thermoelectric generation, reduce demand on freshwater resources and result in environmental benefits from reduced emissions and abated mine discharges.

  6. Thermal Strategies for High Efficiency Thermoelectric Power Generation |

    Broader source: Energy.gov (indexed) [DOE]

    Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). deer07_crane.pdf (64.03 KB) More Documents & Publications Phase 1 of the Advanced Collaborative Emissions Study (ACES): Highlights of Project Finding Engine Tests of an Active PM Filter Regeneration System Integrated Engine and Aftertreatment

  7. Superior thermoelectric performance in PbTe-PbS pseudo-binary. Extremely low thermal conductivity and modulated carrier concentration

    SciTech Connect (OSTI)

    Wu, D.; Zhao, L. -D.; Tong, X.; Li, W.; Wu, L.; Tan, Q.; Pei, Y.; Huang, L.; Li, J. -F.; Zhu, Y.; Kanatzidis, M. G.; He, J.

    2015-05-19

    Lead chalcogenides have exhibited their irreplaceable role as thermoelectric materials at the medium temperature range, owing to highly degenerate electronic bands and intrinsically low thermal conductivities. PbTe-PbS pseudo-binary has been paid extensive attentions due to the even lower thermal conductivity which originates largely from the coexistence of both alloying and phase-separated precipitations. To investigate the competition between alloying and phase separation and its pronounced effect on the thermoelectric performance in PbTe-PbS, we systematically studied Spark Plasma Sintered (SPSed), 3 at% Na- doped (PbTe)1-x(PbS)x samples with x=10%, 15%, 20%, 25%, 30% and 35% by means of transmission electron microscopy (TEM) observations and theoretical calculations. Corresponding to the lowest lattice thermal conductivity as a result of the balance between point defect- and precipitates- scattering, the highest figure of merit ZT~2.3 was obtained at 923 K when PbS phase fraction x is at 20%. The consistently lower lattice thermal conductivities in SPSed samples compared with corresponding ingots, resulting from the powdering and follow-up consolidation processes, also contribute to the observed superior ZT. Notably, the onset of carrier concentration modulation ~600 K due to excessive Na’s diffusion and re-dissolution leads to the observed saturations of electrical transport properties, which is believed equally crucial to the outstanding thermoelectric performance of SPSed PbTe-PbS samples.

  8. Superior thermoelectric performance in PbTe-PbS pseudo-binary. Extremely low thermal conductivity and modulated carrier concentration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, D.; Zhao, L. -D.; Tong, X.; Li, W.; Wu, L.; Tan, Q.; Pei, Y.; Huang, L.; Li, J. -F.; Zhu, Y.; et al

    2015-05-19

    Lead chalcogenides have exhibited their irreplaceable role as thermoelectric materials at the medium temperature range, owing to highly degenerate electronic bands and intrinsically low thermal conductivities. PbTe-PbS pseudo-binary has been paid extensive attentions due to the even lower thermal conductivity which originates largely from the coexistence of both alloying and phase-separated precipitations. To investigate the competition between alloying and phase separation and its pronounced effect on the thermoelectric performance in PbTe-PbS, we systematically studied Spark Plasma Sintered (SPSed), 3 at% Na- doped (PbTe)1-x(PbS)x samples with x=10%, 15%, 20%, 25%, 30% and 35% by means of transmission electron microscopy (TEM) observationsmore » and theoretical calculations. Corresponding to the lowest lattice thermal conductivity as a result of the balance between point defect- and precipitates- scattering, the highest figure of merit ZT~2.3 was obtained at 923 K when PbS phase fraction x is at 20%. The consistently lower lattice thermal conductivities in SPSed samples compared with corresponding ingots, resulting from the powdering and follow-up consolidation processes, also contribute to the observed superior ZT. Notably, the onset of carrier concentration modulation ~600 K due to excessive Na’s diffusion and re-dissolution leads to the observed saturations of electrical transport properties, which is believed equally crucial to the outstanding thermoelectric performance of SPSed PbTe-PbS samples.« less

  9. Superior thermoelectric performance in PbTe-PbS pseudo-binary. Extremely low thermal conductivity and modulated carrier concentration

    SciTech Connect (OSTI)

    Wu, D.; Zhao, L. -D.; Tong, X.; Li, W.; Wu, L.; Tan, Q.; Pei, Y.; Huang, L.; Li, J. -F.; Zhu, Y.; Kanatzidis, M. G.; He, J.

    2015-05-19

    Lead chalcogenides have exhibited their irreplaceable role as thermoelectric materials at the medium temperature range, owing to highly degenerate electronic bands and intrinsically low thermal conductivities. PbTe-PbS pseudo-binary has been paid extensive attentions due to the even lower thermal conductivity which originates largely from the coexistence of both alloying and phase-separated precipitations. To investigate the competition between alloying and phase separation and its pronounced effect on the thermoelectric performance in PbTe-PbS, we systematically studied Spark Plasma Sintered (SPSed), 3 at% Na- doped (PbTe)1-x(PbS)x samples with x=10%, 15%, 20%, 25%, 30% and 35% by means of transmission electron microscopy (TEM) observations and theoretical calculations. Corresponding to the lowest lattice thermal conductivity as a result of the balance between point defect- and precipitates- scattering, the highest figure of merit ZT~2.3 was obtained at 923 K when PbS phase fraction x is at 20%. The consistently lower lattice thermal conductivities in SPSed samples compared with corresponding ingots, resulting from the powdering and follow-up consolidation processes, also contribute to the observed superior ZT. Notably, the onset of carrier concentration modulation ~600 K due to excessive Nas diffusion and re-dissolution leads to the observed saturations of electrical transport properties, which is believed equally crucial to the outstanding thermoelectric performance of SPSed PbTe-PbS samples.

  10. Infrared and thermoelectric power generation in thin atomic layer deposited Nb-doped TiO{sub 2} films

    SciTech Connect (OSTI)

    Mann, Harkirat S.; Lang, Brian N.; Schwab, Yosyp; Scarel, Giovanna; Niemelä, Janne-Petteri; Karppinen, Maarit

    2015-01-15

    Infrared radiation is used to radiatively transfer heat to a nanometric power generator (NPG) device with a thermoelectric Nb-doped TiO{sub 2} film deposited by atomic layer deposition (ALD) as the active element, onto a borosilicate glass substrate. The linear rise of the produced voltage with respect to the temperature difference between the “hot” and “cold” junctions, typical of the Seebeck effect, is missing. The discovery of the violation of the Seebeck effect in NPG devices combined with the ability of ALD to tune thermoelectric thin film properties could be exploited to increase the efficiency of these devices for energy harvesting purposes.

  11. Multiple-Filled Skutterudites: High Thermoelectric Figure of Merit through Separately Optimizing Electrical and Thermal Transports

    SciTech Connect (OSTI)

    Zhang, Weiqing; Yang, Jiong; Yang, Jihui; Wang, Hsin; Salvador, James R.; Shi, Xun; Chi, Miaofang; Cho, Jung Y; Bai, Shengqiang; Chen, Lidong

    2011-01-01

    Skutterudites CoSb{sub 3} with multiple cofillers Ba, La, and Yb were synthesized and very high thermoelectric figure of merit ZT = 1.7 at 850 K was realized. X-ray diffraction of the densified multiple-filled bulk samples reveals all samples are phase pure. High-resolution scanning transmission electron microscopy (STEM) and energy dispersive X-ray spectroscopy (EDS) analysis confirm that multiple guest fillers occupy the nanoscale-cages in the skutterudites. The fillers are further shown to be uniformly distributed and the Co-Sb skutterudite framework is virtually unperturbed from atomic scale to a few micrometers. Our results firmly show that high power factors can be realized by adjusting the total filling fraction of fillers with different charge states to reach the optimum carrier density, at the same time, lattice thermal conductivity can also be significantly reduced, to values near the glass limit of these materials, through combining filler species of different rattling frequencies to achieve broad-frequency phonon scattering. Therefore, partially filled skutterudites with multiple fillers of different chemical nature render unique structural characteristics for optimizing electrical and thermal transports in a relatively independent way, leading to continually enhanced ZT values from single- to double-, and finally to multiple-filled skutterudites. The idea of combining multiple fillers with different charge states and rattling frequencies for performance optimization is also expected to be valid for other caged TE compounds.

  12. Proactive Strategies for Designing Thermoelectric Materials for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Proactive Strategies for Designing Thermoelectric Materials for Power Generation Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite ...

  13. Vehicular Applications of Thermoelectrics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overivew of DOE projects developing thermoelectric generators for engine waste heat utilization and vehiclular thermoelectric heatingcooling. deer08fairbanks.pdf (5.58 MB) More ...

  14. Vehicular Thermoelectrics: A New Green Technology | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (8.06 MB) More Documents & Publications Thermoelectrics: The New Green Automotive Technology Automotive Thermoelectric Generators and HVAC Solid-State Energy Conversion Overview

  15. Tailored semiconducting carbon nanotube networks with enhanced thermoelectric properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Avery, Azure D.; Zhou, Ben H.; Lee, Jounghee; Lee, Eui -Sup; Miller, Elisa M.; Ihly, Rachelle; Wesenberg, Devin; Mistry, Kevin S.; Guillot, Sarah L.; Zink, Barry L.; et al

    2016-04-04

    Thermoelectric power generation, allowing recovery of part of the energy wasted as heat, is emerging as an important component of renewable energy and energy efficiency portfolios. Although inorganic semiconductors have traditionally been employed in thermoelectric applications, organic semiconductors garner increasing attention as versatile thermoelectric materials. Here we present a combined theoretical and experimental study suggesting that semiconducting single-walled carbon nanotubes with carefully controlled chirality distribution and carrier density are capable of large thermoelectric power factors, higher than 340 μW m-1 K-2, comparable to the best-performing conducting polymers and larger than previously observed for carbon nanotube films. Furthermore, we demonstrate thatmore » phonons are the dominant source of thermal conductivity in the networks, and that our carrier doping process significantly reduces the thermal conductivity relative to undoped networks. As a result, these findings provide the scientific underpinning for improved functional organic thermoelectric composites with carbon nanotube inclusions.« less

  16. Thermoelectric HVAC and Thermal Comfort Enablers for Light-Duty Vehicle

    Broader source: Energy.gov (indexed) [DOE]

    Applications | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ace047_maranville_2012_o.pdf (1.03 MB) More Documents & Publications Thermoelectric HVAC for Light-Duty Vehicle Applications Improving efficiency of a vehicle HVAC system with comfort modeling, zonal design, and thermoelectric devices

  17. A compendium of the radioisotope thermoelectric generator transportation system and recent programmatic changes

    SciTech Connect (OSTI)

    Becker, D.L.; McCoy, J.C.

    1996-03-01

    Because RTGs contain significant quantities of radioactive materials, usually plutonium-238 and its decay products, they must be transported in packages built in accordance with 10 CFR 71 (1994). To meet these regulatory requirements, US DOE commissioned Westinghouse Hanford Co. in 1988 to develop a Radioisotope Thermoelectric Generator Transportation System (RTGTS) that would fully comply while protecting RTGs from adverse environmental conditions during normal transport conditions (eg, mainly shock and heat). RTGTS is scheduled for completion Dec. 1996 and will be available to support NASA`s Cassini mission to Saturn in Oct. 1997. This paper provides an overview of the RTGTS project, discusses the hardware being produced, and summarizes various programmatic and management innovations required by recent changes at DOE.

  18. Variable cooling circuit for thermoelectric generator and engine and method of control

    SciTech Connect (OSTI)

    Prior, Gregory P

    2012-10-30

    An apparatus is provided that includes an engine, an exhaust system, and a thermoelectric generator (TEG) operatively connected to the exhaust system and configured to allow exhaust gas flow therethrough. A first radiator is operatively connected to the engine. An openable and closable engine valve is configured to open to permit coolant to circulate through the engine and the first radiator when coolant temperature is greater than a predetermined minimum coolant temperature. A first and a second valve are controllable to route cooling fluid from the TEG to the engine through coolant passages under a first set of operating conditions to establish a first cooling circuit, and from the TEG to a second radiator through at least some other coolant passages under a second set of operating conditions to establish a second cooling circuit. A method of controlling a cooling circuit is also provided.

  19. Quality Assurance Plan for Heat Source/Radioisotope Thermoelectric Generator Programs

    SciTech Connect (OSTI)

    Gabriel, D. M.; Miller, G. D.; Bohne, W. A.

    1995-03-16

    The purpose of this document is to serve as the Quality Assurance Plan for Heat Source/Radioisotope Thermoelectric Generator (HS/RTG) programs performed at EG&G Mound Applied Technologies. As such, it identifies and describes the systems and activities in place to support the requirements contained in DOE Order 5700.6C as reflected in MD-10334, Mound Quality Policy and Responsibilities and the DOE/RPSD supplement, OSA/PQAR-1, Programmatic Quality Assurance Requirements for Space and Terrestrial Nuclear Power Systems. Unique program requirements, including additions, modifications, and exceptions to these quality requirements, are contained in the appendices of this plan. Additional appendices will be added as new programs and activities are added to Mound's HS/RTG mission assignment.

  20. Method of controlling temperature of a thermoelectric generator in an exhaust system

    DOE Patents [OSTI]

    Prior, Gregory P; Reynolds, Michael G; Cowgill, Joshua D

    2013-05-21

    A method of controlling the temperature of a thermoelectric generator (TEG) in an exhaust system of an engine is provided. The method includes determining the temperature of the heated side of the TEG, determining exhaust gas flow rate through the TEG, and determining the exhaust gas temperature through the TEG. A rate of change in temperature of the heated side of the TEG is predicted based on the determined temperature, the determined exhaust gas flow rate, and the determined exhaust gas temperature through the TEG. Using the predicted rate of change of temperature of the heated side, exhaust gas flow rate through the TEG is calculated that will result in a maximum temperature of the heated side of the TEG less than a predetermined critical temperature given the predicted rate of change in temperature of the heated side of the TEG. A corresponding apparatus is provided.

  1. Thermoelectric Power Generation System with Loop Thermosyphon in Future High Efficiency Hybrid Vehicles

    Broader source: Energy.gov [DOE]

    This project discusses preliminary experimental results to find how thermoelectrics can be applied ot future hybrid vehicles and the optimum design of such equipment using heat pipes

  2. Micro- & Nano-Technologies Enabling More Compact, Lightweight Thermoelectric Power Generation & Cooling Systems

    Broader source: Energy.gov [DOE]

    Advanced thermoelectric energy recovery and cooling system weight and volume improvements with low-cost microtechnology heat and mass transfer devices are presented

  3. Solar Thermoelectric Energy Conversion

    Office of Energy Efficiency and Renewable Energy (EERE)

    Efficiencies of different types of solar thermoelectric generators were predicted using theoretical modeling and validated with measurements using constructed prototypes under different solar intensities

  4. Amplification and reversal of Knudsen force by thermoelectric heating

    SciTech Connect (OSTI)

    O'Neill, William J.; Wada, Mizuki; Strongrich, Andrew D.; Cofer, Anthony; Alexeenko, Alina A.

    2014-12-09

    We show that the Knudsen thermal force generated by a thermally-induced flow over a heated beam near a colder wall could be amplified significantly by thermoelectric heating. Bidirectional actuation is achieved by switching the polarity of the thermoelectric device bias voltage. The measurements of the resulting thermal forces at different rarefaction regimes, realized by changing geometry and gas pressure, are done using torsional microbalance. The repulsive or attractive forces between a thermoelectrically heated or cooled plate and a substrate are shown to be up to an order of magnitude larger than for previously studied configurations and heating methods due to favorable coupling of two thermal gradients. The amplification and reversal of the Knudsen force is confirmed by numerical solution of the Boltzmann-ESBGK kinetic model equation. Because of the favorable scaling with decreasing system size, the Knudsen force with thermoelectric heating offers a novel actuation and sensing mechanism for nano/microsystems.

  5. Disposition of Radioisotope Thermoelectric Generators Currently Located at the Oak Ridge National Laboratory - 12232

    SciTech Connect (OSTI)

    Glenn, J.; Patterson, J.; DeRoos, K.; Patterson, J.E.; Mitchell, K.G.

    2012-07-01

    Under the American Recovery and Reinvestment Act (ARRA), the U.S. Department of Energy (DOE) awarded SEC Federal Services Corporation (SEC) a 34-building demolition and disposal (D and D) project at the Oak Ridge National Laboratory (ORNL) that included the disposition of six Strontium (Sr-90) powered Radioisotope Thermoelectric Generators (RTGs) stored outside of ORNL Building 3517. Disposition of the RTGs is very complex both in terms of complying with disposal facility waste acceptance criteria (WAC) and U.S. Department of Transportation (DOT) requirements for packaging and transportation in commerce. Two of the RTGs contain elemental mercury which requires them to be Land Disposal Restrictions (LDR) compliant prior to disposal. In addition, all of the RTGs exceed the Class C waste concentration limits under Nuclear Regulatory Commission (NRC) Waste Classification Guidelines. In order to meet the LDR requirements and Nevada National Security Site (NNSS) WAC, a site specific treatability variance for mercury was submitted to the U.S. Environmental Protection Agency (EPA) to allow macro-encapsulation to be an acceptable treatment standard for elemental mercury. By identifying and confirming the design configuration of the mercury containing RTGs, the SEC team proved that the current configuration met the macro-encapsulation standard of 40 Code of Federal Regulations (CFR) 268.45. The SEC Team also worked with NNSS to demonstrate that all radioisotope considerations are compliant with the NNSS low-level waste (LLW) disposal facility performance assessment and WAC. Lastly, the SEC team determined that the GE2000 Type B cask met the necessary size, weight, and thermal loading requirements for five of the six RTGs. The sixth RTG (BUP-500) required a one-time DOT shipment exemption request due to the RTG's large size. The DOT exemption justification for the BUP-500 relies on the inherent robust construction and material make-up of the BUP- 500 RTG. DOE-ORO, SEC, and

  6. Thermoelectrics Partnership: Automotive Thermoelectric Modules...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces Novel Nanostructured Interface Solution for Automotive ...

  7. Overview of Fords Thermoelectric Programs: Waste Heat Recovery...

    Broader source: Energy.gov (indexed) [DOE]

    Overview of Fords Thermoelectric Programs: Waste Heat Recovery and Climate Control Thermoelectric HVAC for Light-Duty Vehicle Applications Automotive Thermoelectric Generators ...

  8. Over-the-road shock and vibration testing of the radioisotope thermoelectric generator transportation system

    SciTech Connect (OSTI)

    Becker, D.L.

    1997-05-01

    Radioisotope Thermoelectric Generators (RTG) convert heat generated by radioactive decay into electricity through the use of thermocouples. The RTGs have a long operating life, are reasonably lightweight, and require little or no maintenance, which make them particularly attractive for use in spacecraft. However, because RTGs contain significant quantities of radioactive materials, normally plutonium-238 and its decay products, they must be transported in packages built in accordance with Title 10, Code of Federal Regulations, Part 71 (10 CFR 71). To meet these regulations, a RTG Transportation System (RTGTS) that fully complies with 10 CFR 71 has been developed, which protects RTGs from adverse environmental conditions during normal conditions of transport (e.g., shock, vibration, and heat). To ensure the protection of RTGs from shock and vibration loadings during transport, extensive over-the-road testing was conducted on the RTG`S to obtain real-time recordings of accelerations of the air-ride suspension system trailer floor, packaging, and support structure. This paper provides an overview of the RTG`S, a discussion of the shock and vibration testing, and a comparison of the test results to the specified shock response spectra and power spectral density acceleration criteria.

  9. Magnesium and Manganese Silicides For Efficient And Low Cost Thermo-Electric Power Generation

    SciTech Connect (OSTI)

    Trivedi, Sudhir B.; Kutcher, Susan W.; Rosemeier, Cory A.; Mayers, David; Singh, Jogender

    2013-12-02

    Thermoelectric Power Generation (TEPG) is the most efficient and commercially deployable power generation technology for harvesting wasted heat from such things as automobile exhausts, industrial furnaces, and incinerators, and converting it into usable electrical power. We investigated the materials magnesium silicide (Mg2Si) and manganese silicide (MnSi) for TEG. MgSi2 and MnSi are environmentally friendly, have constituent elements that are abundant in the earth's crust, non-toxic, lighter and cheaper. In Phase I, we successfully produced Mg2Si and MnSi material with good TE properties. We developed a novel technique to synthesize Mg2Si with good crystalline quality, which is normally very difficult due to high Mg vapor pressure and its corrosive nature. We produced n-type Mg2Si and p-type MnSi nanocomposite pellets using FAST. Measurements of resistivity and voltage under a temperature gradient indicated a Seebeck coefficient of roughly 120 V/K on average per leg, which is quite respectable. Results indicated however, that issues related to bonding resulted in high resistivity contacts. Determining a bonding process and bonding material that can provide ohmic contact from room temperature to the operating temperature is an essential part of successful device fabrication. Work continues in the development of a process for reproducibly obtaining low resistance electrical contacts.

  10. Thermoelectric Materials, Devices and Systems:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DRAFT - PRE-DECISIONAL -DRAFT - FOR OFFICIAL USE ONLY - DRAFT Thermoelectric Materials, Devices and Systems: 1 Technology Assessment 2 Contents 3 1. Thermoelectric Generation ................................................................................................................... 2 4 2. Technology Assessment and Potential ................................................................................................. 3 5 2.1 Performance Advances

  11. Concentrated Thermoelectric Power

    Broader source: Energy.gov [DOE]

    This fact sheet describes a concentrated solar hydroelectric power project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by MIT, is working to demonstrate concentrating solar thermoelectric generators with >10% solar-to-electrical energy conversion efficiency while limiting optical concentration to less than a factor of 10 and potentially less than 4. When combined with thermal storage, CSTEGs have the potential to provide electricity day and night using no moving parts at both the utility and distributed scale.

  12. Apparatus and method for thermal power generation

    DOE Patents [OSTI]

    Cohen, Paul; Redding, Arnold H.

    1978-01-01

    An improved thermal power plant and method of power generation which minimizes thermal stress and chemical impurity buildup in the vaporizing component, particularly beneficial under loss of normal feed fluid and startup conditions. The invention is particularly applicable to a liquid metal fast breeder reactor plant.

  13. General-purpose heat source: Research and development program. Radioisotope thermoelectric generator impact tests: RTG-1 and RTG-2

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Hinckley, J.E.; George, T.G.

    1996-07-01

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. The first two RTG Impact Tests were designed to provide information on the response of a fully loaded RTG to end-on impact against a concrete target. The results of these tests indicated that at impact velocities up to 57 m/s the converter shell and internal components protect the GPHS capsules from excessive deformation. At higher velocities, some of the internal components of the RTG interact with the GPHS capsules to cause excessive localized deformation and failure.

  14. General-purpose heat source: Research and development program, radioisotope thermoelectric generator/thin fragment impact test

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Hinckley, J.E.

    1996-11-01

    The general-purpose heat source provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. This test was designed to provide information on the response of a loaded RTG to impact by a fragment similar to the type of fragment produced by breakup of the spacecraft propulsion module system. The results of this test indicated that impact by a thin aluminum fragment traveling at 306 m/s may result in significant damage to the converter housing, failure of one fueled clad, and release of a small quantity of fuel.

  15. Radiation Environments and Exposure Considerations for the Multi-Mission Radioisotope Thermoelectric Generator

    SciTech Connect (OSTI)

    Kelly, William M.; Low, Nora M.; Zillmer, Andrew; Johnson, Gregory A.; Normand, Eugene

    2006-01-20

    The Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) is the next generation (RTG) being developed by DOE to provide reliable, long-life electric power for NASA's planetary exploration programs. The MMRTG is being developed by Pratt and Whitney Rocketdyne and Teledyne Energy Systems Incorporated (TESI) for use on currently planned and projected flyby, orbital and planet landing missions. This is a significant departure from the design philosophy of the past which was to match specific mission requirements to RTG design capabilities. Undefined mission requirements provide a challenge to system designers by forcing them to put a design envelope around 'all possible missions'. These multi-mission requirements include internal and external radiation sources. Internal sources include the particles ejected by decaying Pu-238 and its daughters plus particles resulting from the interaction of these particles with other MMRTG materials. External sources include the full spectrum of charged particle radiation surrounding planets with magnetic fields and the surfaces of extraterrestrial objects not shielded by magnetic fields. The paper presents the results of investigations into the environments outlined above and the impact of radiation exposure on potential materials to be used on MMRTG and ground support personnel. Mission requirements were also reviewed to evaluate total integrated dose and to project potential shielding requirements for materials. Much of the information on mission shielding requirements was provided by NASA's Jet Propulsion Laboratory. The primary result is an ionizing radiation design curve which indicates the limits to which a particular mission can take the MMRTG in terms of ionizing radiation exposure. Estimates of personnel radiation exposure during ground handling are also provided.

  16. New Composite Thermoelectric Materials for Macro-size Applications

    ScienceCinema (OSTI)

    Dresselhaus, Mildred [MIT, Cambridge, Massachusetts, United States

    2010-01-08

    A review will be given of several important recent advances in both thermoelectrics research and industrial thermoelectric applications, which have attracted much attention, increasing incentives for developing advanced materials appropriate for large-scale applications of thermoelectric devices. One promising strategy is the development of materials with a dense packing of random nanostructures as a route for the sacle-up of thermoelectrics applications. The concepts involved in designing composite materials containing nanostructures for thermoelectric applications will be discussed in general terms. Specific application is made to the Bi{sub 2}Te{sub 3} nanocomposite system for use in power generation. Also emphasized are the scientific advantages of the nanocomposite approach for the simultaneous increase in the power factor and decrease of the thermal conductivity, along with the practical advantages of having bulk samples for property measurements and device applications. A straightforward path is identified for the scale-up of thermoelectric materials synthesis containing nanostructured constituents for use in thermoelectric applications. We end with some vision of where the field of thermoelectrics is now heading.

  17. Thermoelectrics Partnership: High Performance Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Embedded Nanoparticles Thermoelectrics Partnership: High Performance Thermoelectric Waste Heat Recovery System Based on Zintl Phase Materials with Embedded Nanoparticles 2011 DOE ...

  18. Method and apparatus for thermal power generation

    DOE Patents [OSTI]

    Mangus, James D.

    1979-01-01

    A method and apparatus for power generation from a recirculating superheat-reheat circuit with multiple expansion stages which alleviates complex control systems and minimizes thermal cycling of system components, particularly the reheater. The invention includes preheating cold reheat fluid from the first expansion stage prior to its entering the reheater with fluid from the evaporator or drum component.

  19. Vibration Testing of the Pluto/New Horizons Radioisotope Thermoelectric Generator

    SciTech Connect (OSTI)

    Charles D. Griffin

    2006-06-01

    The Radioisotopic Thermal Generator (RTG) for the Pluto/New Horizons spacecraft was subjected to a flight dynamic acceptance test to demonstrate that it would perform successfully following launch. Seven RTGs of this type had been assembled and tested at Mound, Ohio from 1984 to 1997. This paper chronicles major events in establishing a new vibration test laboratory at the Idaho National Laboratory and the nineteen days of dynamic testing.

  20. Thermal stability and thermoelectric properties of Cu{sub x}As{sub 40−x}Te{sub 60−y}Se{sub y} semiconducting glasses

    SciTech Connect (OSTI)

    Vaney, J.B.; Piarristeguy, A.; Pradel, A.; Alleno, E.; Lenoir, B.; Candolfi, C.; Dauscher, A.; Gonçalves, A.P.; Lopes, E.B.; Monnier, J.; Ribes, M.; Godart, C.

    2013-07-15

    We report on the thermal behavior and thermoelectric properties of bulk chalcogenide glasses in the systems Cu{sub x}As{sub 40−x}Te{sub 60} (20≤x≤32.5) and Cu{sub x}As{sub 40−x}Te{sub 60−y}Se{sub y}, (0≤y≤9) synthesized by conventional melt-quenching techniques. The thermal stability of these glasses was probed by differential scanning calorimetry to determine the characteristic T{sub g} and ΔT temperatures, both of which increasing noticeably with y. Thermoelectric properties were found to be mainly influenced by the Cu concentration with respect to the Se content. The thermal conductivity is practically composition-independent throughout the compositional range covered. A maximum ZT value of 0.02 at 300 K increasing to 0.06 at 375 K was achieved for the composition Cu{sub 30}As{sub 10}Te{sub 54}Se{sub 6}. - Graphical abstract: Effect of substitution of Te by Se and As by Cu on thermal stability and thermoelectric properties of Cu{sub x}As{sub 40−x}Te{sub 60−y}Se{sub y} semiconducting glasses. - Highlights: • We studied substitution of Te by Se in Cu–As–Te thermoelectric chalcogenide glasses. • Cu–As–Te–Se glasses were prepared by conventional melt-quenching method. • Se inclusion increases thermal stability in Cu–As–Te glasses. • Increasing copper concentration enhances thermoelectric properties. • ZT of 0.02 was achieved at 300 K and 0.06 at 375 K.

  1. Thermoelectric converter

    DOE Patents [OSTI]

    Kim, C.K.

    1974-02-26

    This invention relates in general to thermoelectric units and more particularly to a tubular thermoelectric unit which includes an array of tandemly arranged radially tapered annular thermoelectric pellets having insulation material of a lower density than the thermoelectric pellets positioned between each pellet. (Official Gazette)

  2. Determination of Thermoelectric Module Efficiency A Survey

    SciTech Connect (OSTI)

    Wang, Hsin; McCarty, Robin; Salvador, James R.; Yamamoto, Atsushi; Konig, Jan

    2014-01-01

    The development of thermoelectrics (TE) for energy conversion is in the transition phase from laboratory research to device development. There is an increasing demand to accurately determine the module efficiency, especially for the power generation mode. For many thermoelectrics, the figure of merit, ZT, of the material sometimes cannot be fully realized at the device level. Reliable efficiency testing of thermoelectric modules is important to assess the device ZT and provide the end-users with realistic values on how much power can be generated under specific conditions. We conducted a general survey of efficiency testing devices and their performance. The results indicated the lack of industry standards and test procedures. This study included a commercial test system and several laboratory systems. Most systems are based on the heat flow meter method and some are based on the Harman method. They are usually reproducible in evaluating thermoelectric modules. However, cross-checking among different systems often showed large errors that are likely caused by unaccounted heat loss and thermal resistance. Efficiency testing is an important area for the thermoelectric community to focus on. A follow-up international standardization effort is planned.

  3. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Broader source: Energy.gov (indexed) [DOE]

    Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Development of Cost-Competitive ...

  4. Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Gas Waste Heat into Usable Electricity Thermoelectric Conversion of Exhaust Gas ... More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste ...

  5. Thermoelectrical Energy Recovery From the Exhaust of a Light...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Progress in Thermoelectrical Energy Recovery from a Light Truck Exhaust ...

  6. Thermoelectric Mechanical Reliability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation pm012_wereszczak_2011_o.pdf (498.73 KB) More Documents & Publications Thermoelectrics Theory and Structure Transport Properties, Thermal Response, and Mechanical Reliability of Thermoelectric Materials and Devices for Automotive Waste Heat Recovery Thermoelectric Mechanical Reliability

  7. Thermoelectrics Theory and Structure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation pm012_wereszczak_2011_o.pdf (498.73 KB) More Documents & Publications Thermoelectric Mechanical Reliability Transport Properties, Thermal Response, and Mechanical Reliability of Thermoelectric Materials and Devices for Automotive Waste Heat Recovery Thermoelectric Mechanical Reliability

  8. Thermoelectric Applications to Truck Essential Power

    SciTech Connect (OSTI)

    John C. Bass; Norbert B. Elsner

    2001-12-12

    The subjects covered in this report are: thermoelectrics, 1-kW generator for diesel engine; self-powered heater; power for wireless data transmission; and quantum-well thermoelectrics.

  9. Benefits of Thermoelectric Technology for the Automobile

    Broader source: Energy.gov [DOE]

    Discusses improved fuel efficiency and other benefits of automotive application of thermoelectric (power generation and heating/cooling) and the need for production quantities of high-efficiency thermoelectric modules

  10. Thermoelectric Mechanical Reliability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    DRAFT - PRE-DECISIONAL -DRAFT - FOR OFFICIAL USE ONLY - DRAFT Thermoelectric Materials, Devices and Systems: 1 Technology Assessment 2 Contents 3 1. Thermoelectric Generation ................................................................................................................... 2 4 2. Technology Assessment and Potential ................................................................................................. 3 5 2.1 Performance Advances

  11. Electron-phonon coupling and thermal transport in the thermoelectric compound Mo3Sb7–xTex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bansal, Dipanshu; Li, Chen W.; Said, Ayman H.; Abernathy, Douglas L.; Yan, Jiaqiang; Delaire, Olivier A.

    2015-12-07

    Phonon properties of Mo3Sb7–xTex (x = 0, 1.5, 1.7), a potential high-temperature thermoelectric material, have been studied with inelastic neutron and x-ray scattering, and with first-principles simulations. The substitution of Te for Sb leads to pronounced changes in the electronic struc- ture, local bonding, phonon density of states (DOS), dispersions, and phonon lifetimes. Alloying with tellurium shifts the Fermi level upward, near the top of the valence band, resulting in a strong suppression of electron-phonon screening, and a large overall stiffening of interatomic force- constants. The suppression in electron-phonon coupling concomitantly increases group velocities and suppresses phonon scattering rates, surpassingmore » the effects of alloy-disorder scattering, and re- sulting in a surprising increased lattice thermal conductivity in the alloy. We also identify that the local bonding environment changes non-uniformly around different atoms, leading to variable perturbation strengths for different optical phonon branches. The respective roles of changes in phonon group velocities and phonon lifetimes on the lattice thermal conductivity are quantified. Lastly, our results highlight the importance of the electron-phonon coupling on phonon mean-free-paths in this compound, and also estimates the contributions from boundary scattering, umklapp scattering, and point-defect scattering.« less

  12. NSF/DOE Thermoelectrics Partnership: Purdue … GM Partnership on Thermoelectrics for Automotive Waste Heat Recovery

    Broader source: Energy.gov [DOE]

    Reviews results in developing commercially viable thermoelectric generators for efficient conversion of automotive exhaust waste heat to electricity

  13. High performance thermoelectric nanocomposite device

    DOE Patents [OSTI]

    Yang, Jihui; Snyder, Dexter D.

    2011-10-25

    A thermoelectric device includes a nanocomposite material with nanowires of at least one thermoelectric material having a predetermined figure of merit, the nanowires being formed in a porous substrate having a low thermal conductivity and having an average pore diameter ranging from about 4 nm to about 300 nm.

  14. Innovative Nano-structuring Routes for Novel Thermoelectric

    Broader source: Energy.gov (indexed) [DOE]

    Materials;Phonon Blocking & DOS Engineering | Department of Energy Presents new concepts for high performance nanostructured bulk thermoelectric materials lee.pdf (1.98 MB) More Documents & Publications Thermoelectric Materials for Automotive Applications The Bottom-Up Approach forThermoelectric Nanocomposites, plusƒ Glass-like thermal conductivity in high efficiency thermoelectric materials

  15. Thermoelectric Opportunities for Light-Duty Vehicles | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    thermoelectrics for automotive applications and role of automakers in setting guidelines and technology attributes needed for the global product, regulatory, and market environment maranville.pdf (3 MB) More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Thermoelectric Activities of European Community within Framework Programme 7 and additional activities in Germany Automotive Thermoelectric Generator

  16. Pb7Bi4Se13: A Lillianite Homologue with Promising Thermoelectric...

    Office of Scientific and Technical Information (OSTI)

    Subject: solar (photovoltaic), solar (thermal), phonons, thermal conductivity, thermoelectric, electrodes - solar, defects, charge transport, materials and chemistry by design, ...

  17. Project Profile: High-Temperature Thermal Array for Next-Generation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Array for Next-Generation Solar Thermal Power Production Project Profile: High-Temperature Thermal Array for Next-Generation Solar Thermal Power Production Los Alamos ...

  18. Device for thermal transfer and power generation

    DOE Patents [OSTI]

    Weaver, Stanton Earl; Arik, Mehmet

    2011-04-19

    A system is provided. The system includes a device that includes top and bottom thermally conductive substrates positioned opposite to one another, wherein a top surface of the bottom thermally conductive substrate is substantially atomically flat and a thermal blocking layer disposed between the top and bottom thermally conductive substrates. The device also includes top and bottom electrodes separated from one another between the top and bottom thermally conductive substrates to define a tunneling path, wherein the top electrode is disposed on the thermal blocking layer and the bottom electrode is disposed on the bottom thermally conductive substrate.

  19. Methods of synthesizing thermoelectric materials

    DOE Patents [OSTI]

    Ren, Zhifeng; Chen, Shuo; Liu, Wei-Shu; Wang, Hengzhi; Wang, Hui; Yu, Bo; Chen, Gang

    2016-04-05

    Methods for synthesis of thermoelectric materials are disclosed. In some embodiments, a method of fabricating a thermoelectric material includes generating a plurality of nanoparticles from a starting material comprising one or more chalcogens and one or more transition metals; and consolidating the nanoparticles under elevated pressure and temperature, wherein the nanoparticles are heated and cooled at a controlled rate.

  20. Thermoelectric module

    DOE Patents [OSTI]

    Kortier, William E.; Mueller, John J.; Eggers, Philip E.

    1980-07-08

    A thermoelectric module containing lead telluride as the thermoelectric mrial is encapsulated as tightly as possible in a stainless steel canister to provide minimum void volume in the canister. The lead telluride thermoelectric elements are pressure-contacted to a tungsten hot strap and metallurgically bonded at the cold junction to iron shoes with a barrier layer of tin telluride between the iron shoe and the p-type lead telluride element.

  1. Electrical and thermal properties of polycrystalline Si thin films with phononic crystal nanopatterning for thermoelectric applications

    SciTech Connect (OSTI)

    Nomura, Masahiro; Kage, Yuta; Mller, David; Moser, Dominik; Paul, Oliver

    2015-06-01

    Electrical and thermal properties of polycrystalline Si thin films with two-dimensional phononic patterning were investigated at room temperature. Electrical and thermal conductivities for the phononic crystal nanostructures with a variety of radii of the circular holes were measured to systematically investigate the impact of the nanopatterning. The concept of phonon-glass and electron-crystal is valid in the investigated electron and phonon transport systems with the neck size of 80?nm. The thermal conductivity is more sensitive than the electrical conductivity to the nanopatterning due to the longer mean free path of the thermal phonons than that of the charge carriers. The values of the figure of merit ZT were 0.065 and 0.035, and the enhancement factors were 2 and 4 for the p-doped and n-doped phononic crystals compared to the unpatterned thin films, respectively, when the characteristic size of the phononic crystal nanostructure is below 100?nm. The greater enhancement factor of ZT for the n-doped sample seems to result from the strong phonon scattering by heavy phosphorus atoms at the grain boundaries.

  2. Techno-Economic Feasibility of Highly Efficient Cost-Effective Thermoelectric-SOFC Hybrid Power Generation Systems

    SciTech Connect (OSTI)

    Jifeng Zhang; Jean Yamanis

    2007-09-30

    Solid oxide fuel cell (SOFC) systems have the potential to generate exhaust gas streams of high temperature, ranging from 400 to 800 C. These high temperature gas streams can be used for additional power generation with bottoming cycle technologies to achieve higher system power efficiency. One of the potential candidate bottoming cycles is power generation by means of thermoelectric (TE) devices, which have the inherent advantages of low noise, low maintenance and long life. This study was to analyze the feasibility of combining coal gas based SOFC and TE through system performance and cost techno-economic modeling in the context of multi-MW power plants, with 200 kW SOFC-TE module as building blocks. System and component concepts were generated for combining SOFC and TE covering electro-thermo-chemical system integration, power conditioning system (PCS) and component designs. SOFC cost and performance models previously developed at United Technologies Research Center were modified and used in overall system analysis. The TE model was validated and provided by BSST. The optimum system in terms of energy conversion efficiency was found to be a pressurized SOFC-TE, with system efficiency of 65.3% and cost of $390/kW of manufacturing cost. The pressurization ratio was approximately 4 and the assumed ZT of the TE was 2.5. System and component specifications were generated based on the modeling study. The major technology and cost barriers for maturing the system include pressurized SOFC stack using coal gas, the high temperature recycle blowers, and system control design. Finally, a 4-step development roadmap is proposed for future technology development, the first step being a 1 kW proof-of-concept demonstration unit.

  3. Next-Generation LED Package Architectures Enabled by Thermally...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This project will develop next-generation LED package architectures enabled by thermally conductive composite encapsulant materials utilizing boron nitride (BN). Nanoscale boron ...

  4. Electronic cooling using thermoelectric devices

    SciTech Connect (OSTI)

    Zebarjadi, M.

    2015-05-18

    Thermoelectric coolers or Peltier coolers are used to pump heat in the opposite direction of the natural heat flux. These coolers have also been proposed for electronic cooling, wherein the aim is to pump heat in the natural heat flux direction and from hot spots to the colder ambient temperature. In this manuscript, we show that for such applications, one needs to use thermoelectric materials with large thermal conductivity and large power factor, instead of the traditionally used high ZT thermoelectric materials. We further show that with the known thermoelectric materials, the active cooling cannot compete with passive cooling, and one needs to explore a new set of materials to provide a cooling solution better than a regular copper heat sink. We propose a set of materials and directions for exploring possible materials candidates suitable for electronic cooling. Finally, to achieve maximum cooling, we propose to use thermoelectric elements as fins attached to copper blocks.

  5. Concentrated Solar Thermoelectric Power

    SciTech Connect (OSTI)

    Chen, Gang; Ren, Zhifeng

    2015-07-09

    The goal of this project is to demonstrate in the lab that solar thermoelectric generators (STEGs) can exceed 10% solar-to-electricity efficiency, and STEGs can be integrated with phase-change materials (PCM) for thermal storage, providing operation beyond daylight hours. This project achieved significant progress in many tasks necessary to achieving the overall project goals. An accurate Themoelectric Generator (TEG) model was developed, which included realistic treatment of contact materials, contact resistances and radiative losses. In terms of fabricating physical TEGs, high performance contact materials for skutterudite TE segments were developed, along with brazing and soldering methods to assemble segmented TEGs. Accurate measurement systems for determining device performance (in addition to just TE material performance) were built for this project and used to characterize our TEGs. From the optical components’ side, a spectrally selective cermet surface was developed with high solar absorptance and low thermal emittance, with thermal stability at high temperature. A measurement technique was also developed to determine absorptance and total hemispherical emittance at high temperature, and was used to characterize the fabricated spectrally selective surfaces. In addition, a novel reflective cavity was designed to reduce radiative absorber losses and achieve high receiver efficiency at low concentration ratios. A prototype cavity demonstrated that large reductions in radiative losses were possible through this technique. For the overall concentrating STEG system, a number of devices were fabricated and tested in a custom built test platform to characterize their efficiency performance. Additionally, testing was performed with integration of PCM thermal storage, and the storage time of the lab scale system was evaluated. Our latest testing results showed a STEG efficiency of 9.6%, indicating promising potential for high performance concentrated STEGs.

  6. Generators for Small Electrical and Thermal Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    build and test improved electric-power generators for use in residential Combined Heat and Power (CHP) systems, which capture the generator's heat output for space and water...

  7. High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power...

    Broader source: Energy.gov (indexed) [DOE]

    Development of an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles Recent Progress in the Development of High Efficiency Thermoelectrics ...

  8. GPHS-RTG system explosion test direct course experiment 5000. [General Purpose Heat Source-Radioisotope Thermoelectric Generator

    SciTech Connect (OSTI)

    Not Available

    1984-03-01

    The General Purpose Heat Source-Radioisotope Thermoelectric Generator (GPHS-RTG) has been designed and is being built to provide electrical power for spacecrafts to be launched on the Space Shuttle. The objective of the RTG System Explosion Test was to expose a mock-up of the GPHS-RTG with a simulated heat source to the overpressure and impulse representative of a potential upper magnitude explosion of the Space Shuttle. The test was designed so that the heat source module would experience an overpressure at which the survival of the fuel element cladding would be expected to be marginal. Thus, the mock-up was placed where the predicted incident overpressure would be 1300 psi. The mock-up was mounted in an orientation representative of the launch configuration on the spacecraft to be used on the NASA Galileo Mission. The incident overpressure measured was in the range of 1400 to 2100 psi. The mock-up and simulated heat source were destroyed and only very small fragments were recovered. This damage is believed to have resulted from a combination of the overpressure and impact by very high velocity fragments from the ANFO sphere. Post-test analysis indicated that extreme working of the iridium clad material occurred, indicative of intensive impulsive loading on the metal.

  9. Thermoelectric Activities of European Community within Framework...

    Broader source: Energy.gov (indexed) [DOE]

    Bulk Materials and Device Development Overview of Fraunhofer IPM Activities in High Temperature Bulk Materials and Device Development Automotive Thermoelectric Generators and HVAC

  10. Development of Marine Thermoelectric Heat Recovery Systems

    Broader source: Energy.gov [DOE]

    Thermoelectric generator prototypes are evaluated in a dedicated hybrid vessel test platform fabricated from an encapsulated lifeboat to optimize performance and reliability for marine industry applications

  11. Proactive Strategies for Designing Thermoelectric Materials for...

    Broader source: Energy.gov (indexed) [DOE]

    New p-type and n-type multiple-rattler skutterudite thermoelectric materials design, synthesis, fabrication, and characterization for power generation using vehicle exhaust waste ...

  12. NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics for Automotive Waste Heat Recovery Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces

  13. Efficient and Dynamic ? The BMW Group Roadmap for the Application of Thermoelectric Generators

    Broader source: Energy.gov [DOE]

    The diesel engine EGR system is a logical application of TE generators because the necessary system components are already available; transfer of module concepts is possible to other applications in the exhaust system with higher waste heat recovery potential

  14. Efficient and Dynamic … The BMW Group Roadmap for the Application of Thermoelectric Generators

    Broader source: Energy.gov [DOE]

    The diesel engine EGR system is a logical application of TE generators because the necessary system components are already available; transfer of module concepts is possible to other applications in the exhaust system with higher waste heat recovery potential

  15. Thermoelectric system

    SciTech Connect (OSTI)

    Reiners, Eric A.; Taher, Mahmoud A.; Fei, Dong; McGilvray, Andrew N.

    2007-10-30

    In one particular embodiment, an internal combustion engine is provided. The engine comprises a block, a head, a piston, a combustion chamber defined by the block, the piston, and the head, and at least one thermoelectric device positioned between the combustion chamber and the head. In this particular embodiment, the thermoelectric device is in direct contact with the combustion chamber. In another particular embodiment, a cylinder head configured to sit atop a cylinder bank of an internal combustion engine is provided. The cylinder head comprises a cooling channel configured to receive cooling fluid, valve seats configured for receiving intake and exhaust valves, and thermoelectric devices positioned around the valve seats.

  16. Semimetal/Semiconductor Nanocomposites for Thermoelectrics

    SciTech Connect (OSTI)

    Lu, Hong; Burke, Peter G.; Gossard, Arthur C.; Zeng, Gehong; Ramu, Ashok T.; Bahk, Je-Hyeong; Bowers, John E.

    2011-04-15

    In this work, we present research on semimetal-semiconductor nanocomposites grown by molecular beam epitaxy (MBE) for thermoelectric applications. We study several different III-V semiconductors embedded with semimetallic rare earth-group V (RE-V) compounds, but focus is given here to ErSb:InxGa1-xSb as a promising p-type thermoelectric material. Nanostructures of RE-V compounds are formed and embedded within the III-V semiconductor matrix. By codoping the nanocomposites with the appropriate dopants, both n-type and p-type materials have been made for thermoelectric applications. The thermoelectric properties have been engineered for enhanced thermoelectric device performance. Segmented thermoelectric power generator modules using 50 ?m thick Er-containing nanocomposites have been fabricated and measured. Research on different rare earth elements for thermoelectrics is discussed.

  17. Radioisotope Thermoelectric Generator Transporation System licensed hardware second certification test series and package shock mount system test

    SciTech Connect (OSTI)

    Ferrell, P.C.; Moody, D.A.

    1995-10-01

    This paper presents a summary of two separate drop test a e performed in support of the Radioisotope Thermoelectric Generator (RTG) Transportation System (RTGTS). The first portion of this paper presents the second series of drop testing required to demonstrate that the RTG package design meets the requirements of Title 10, Code of Federal Regulations, ``Part 71`` (10 CFR 71). Results of the first test series, performed in July 1994, demonstrated that some design changes were necessary. The package design was modified to improve test performance and the design changes were incorporated into the Safety Analysis Report for Packaging (SARP). The second full-size certification test article (CTA-2) incorporated the modified design and was tested at the US Department of Energy`s (DOE) Hanford Site near Richland, Washington. With the successful completion of the test series, and pending DOE Office of Facility Safety Analysis approval of the SARP, a certificate of compliance will be issued for the RTG package allowing its use. The second portion of this paper presents the design and testing of the RTG Package Mount System. The RTG package mount was designed to protect the RTG from excessive vibration during transport, provide shock protection during on/off loading, and provide a mechanism for moving the RTG package with a forklift. Military Standard (MIL-STD) 810E, Transit Drop Procedure (DOE 1989), was used to verify that the shock limiting system limited accelerations in excess of 15 G`s at frequencies below 150 Hz. Results of the package mount drop tests indicate that an impact force of 15 G`s was not exceeded in any test from a free drop height of 457 mm (18 in.).

  18. Radioisotope Thermoelectric Generator Transportation System licensed hardware second certification test series and package shock mount system test

    SciTech Connect (OSTI)

    Ferrell, P.C.; Moody, D.A.

    1996-03-01

    This paper presents a summary of two separate drop test activities that were performed in support of the Radioisotope Thermoelectric Generator (RTG) Transportation System (RTGTS). The first portion of this paper presents the second series of drop testing required to demonstrate that the RTG package design meets the requirements of {ital Title} 10, {ital Code} {ital of} {ital Federal} {ital Regulations}, {open_quote}{open_quote}Part 71{close_quote}{close_quote} (10 CFR 71). Results of the first test series, performed in July 1994, demonstrated that some design changes were necessary. The package design was modified to improve test performance and the design changes were incorporated into the Safety Analysis Report for Packaging (SARP). The second full-size certification test article (CTA-2) incorporated the modified design and was tested at the U.S. Department of Energy{close_quote}s (DOE) Hanford Site near Richland, Washington. With the successful completion of the test series, and pending DOE Office of Facility Safety Analysis approval of the SARP, a certificate of compliance will be issued for the RTG package allowing its use. The second portion of this paper presents the design and testing of the RTG Package Mount System. The RTG package mount was designed to protect the RTG from excessive vibration during transport, provide shock protection during on/off loading, and provide a mechanism for moving the RTG package with a forklift. Military Standard (MIL-STD) 810E, {ital Transit} {ital Drop} {ital Procedure} (DOE 1989), was used to verify that the shock limiting system limited accelerations in excess of 15 G{close_quote}s at frequencies below 150 Hz. Results of the package mount drop tests indicate that an impact force of 15 G{close_quote}s was not exceeded in any test from a free drop height of 457 mm (18 in.). {copyright} {ital 1996 American Institute of Physics.}

  19. Atomic-level cotrol of the thermoelectric properties in polytypoid nanowires

    SciTech Connect (OSTI)

    Andrews, Sean C.; Fardy, Melissa A.; Moore, Michael C.; Aloni, Shaoul; Zhang, Minjuan; Radmilovic, Velimir; Yang, Peidong

    2010-10-23

    Thermoelectric materials have generated interest as a means of increasing the efficiency of power generation through the scavenging of waste heat. Materials containing nanometer-sized structural and compositional features can exhibit enhanced thermoelectric performance due to the decoupling of certain electrical and thermal properties, but the extent to which these features can be controlled is often limited. Here we report a simple synthesis of M{sub 2}O{sub 3}(ZnO){sub n} (M = In, Ga, Fe) nanowires with controllable polytypoid structures, where the nanostructured features are tuned by adjusting the amount of metal precursor. After the introduction of nanometer-scale features (individual atomic layers and alloying), thermal and electrical measurements on single In{sub 2-x}Ga{sub x}O3(ZnO){sub n} nanowires reveal a simultaneous improvement in all contributing factors to the thermoelectric figure of merit, indicating successful modification of the nanowire transport properties.

  20. Compositional ordering and stability in nanostructured, bulk thermoelectric alloys.

    SciTech Connect (OSTI)

    Hekmaty, Michelle A.; Faleev, S.; Medlin, Douglas L.; Leonard, F.; Lensch-Falk, J.; Sharma, Peter Anand; Sugar, J. D.

    2009-09-01

    Thermoelectric materials have many applications in the conversion of thermal energy to electrical power and in solid-state cooling. One route to improving thermoelectric energy conversion efficiency in bulk material is to embed nanoscale inclusions. This report summarize key results from a recently completed LDRD project exploring the science underpinning the formation and stability of nanostructures in bulk thermoelectric and the quantitative relationships between such structures and thermoelectric properties.

  1. Probabilistic Mechanical Reliability Prediction of Thermoelectric Legs

    SciTech Connect (OSTI)

    Jadaan, Osama M.; Wereszczak, Andrew A

    2009-05-01

    The probability of failure, Pf, for various square-arrayed thermoelectric device designs using bismuth telluride, lead telluride, or skutterudite thermoelectric materials were estimated. Only volume- or bulk-based Pf analysis was considered in this study. The effects of the choice of the thermoelectric material, the size of the leg array, the height of the thermoelectric legs, and the boundary conditions on the Pf of thermoelectric devices were investigated. Yielding of the solder contacts and mounting layer was taken into account. The modeling results showed that the use of longer legs, using skutterudites, allowing the thermoelectric device to freely deform while under a thermal gradient, and using smaller arrays promoted higher probabilities of survival.

  2. Thermoelectric power source utilizing ambient energy harvesting for remote sensing and transmitting

    DOE Patents [OSTI]

    DeSteese, John G

    2010-11-16

    A method and apparatus for providing electrical energy to an electrical device wherein the electrical energy is originally generated from temperature differences in an environment having a first and a second temperature region. A thermoelectric device having a first side and a second side wherein the first side is in communication with a means for transmitting ambient thermal energy collected or rejected in the first temperature region and the second side is in communication with the second temperature region thereby producing a temperature gradient across the thermoelectric device and in turn generating an electrical current.

  3. High-Performance Thermoelectric Devices Based on Abundant Silicide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    vehicle waste heat recovery will include fundamental research to use abundant promising low-cost thermoelectric materials, thermal management and interfaces design, and metrology

  4. The potential impact of ZT=4 thermoelectric materials on solar...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: The potential impact of ZT4 thermoelectric materials on solar thermal energy conversion ... B; Journal Volume: 114; Journal Issue: Mar. 2, 2010 Research Org: ...

  5. Optimum composition of a Bi{sub 2}Te{sub 3-x}Se{sub x} alloy for the n-type leg of a thermoelectric generator

    SciTech Connect (OSTI)

    Prokofieva, L. V. Pshenay-Severin, D. A.; Konstantinov, P. P.; Shabaldin, A. A.

    2009-08-15

    The reliability of determination of model parameters for the Bi{sub 2}Te{sub 3-x}Se{sub x} alloys is improved by extending the concentration and temperature ranges in experimental studies and, correspondingly, in calculations of kinetic coefficients based on the two-band model of the electronic spectrum. The obtained results served as a motivation for a study of the thermoelectric figure of merit for the above-mentioned alloys with x = 0.3, 0.45, and 0.6 and with the electron concentration varied in the range (1-50) x 10{sup 18} cm{sup -3} at temperatures 300-550 K. Comparison of the results showed that the highest efficiency is exhibited by the Bi{sub 2}Te{sub 2.7}Se{sub 0.3} alloy with the absolute value of the thermoelectric power of about 165 {mu}VK{sup -1} at 300 K, and the dimensionless efficiency is equal to 1.2 at 410 K. An appreciable decrease in thermal conductivity in alloys with x = 0.6 at 410 K is related to a larger band gap and could beneficially affect the figure of merit. However, the magnitude of this effect is found to be too small to compensate a decrease in electrical conductivity due to a large fraction of heavy electrons in the concentration and to a high content of selenium.

  6. THERMO-ELECTRIC GENERATOR

    DOE Patents [OSTI]

    Jordan, K.C.

    1958-07-22

    The conversion of heat energy into electrical energy by a small compact device is descrtbed. Where the heat energy is supplied by a radioactive material and thermopIIes convert the heat to electrical energy. The particular battery construction includes two insulating discs with conductive rods disposed between them to form a circular cage. In the center of the cage is disposed a cup in which the sealed radioactive source is located. Each thermopile is formed by connecting wires from two adjacent rods to a potnt on an annular ring fastened to the outside of the cup, the ring having insulation on its surface to prevent electrica1 contact with the thermopiles. One advantage of this battery construction is that the radioactive source may be inserted after the device is fabricated, reducing the radiation hazard to personnel assembling the battery.

  7. On the Design of High Efficiency Thermoelectric Type I Clathrates through Transition Metal Doping

    SciTech Connect (OSTI)

    Shi, Xun; Yang, Jiong; Yang, Jihui; Salvador, James R.; Bai, Shengqiang; Zhang, Weiqing; Chen, Lidong; Wong-Ng, W.; Wang, Hsin

    2010-01-01

    The lack of high efficiency thermoelectric materials hinders their deployment into wide ranging applications such as power generation from waste heat and solid state heating and cooling, which could lead to significant energy savings. Type I clathrates have recently been identified as prospective thermoelectric materials for power generation purposes due to their very low lattice thermal conductivity values. The maximum thermoelectric figure of merit of almost all type I clathrates is, however, less than 1; and occurs at, or above, 1000 K making them unfavorable especially for intermediate temperature applications. In this report, we demonstrate that transition metal doping introduces charge distortion and lattice defects into these materials which increases the ionized impurity scattering of carriers and point defect scattering of lattice phonons, respectively; leading to an enhanced power factor, reduced lattice thermal conductivity, and therefore improved thermoelectric figure of merit. Most importantly, the band gap of these materials can be tuned between 0.1 eV and 0.5 eV by adjusting the transition metal content, making it possible to design type I clathrates with excellent thermoelectric properties between 500 K and 1000 K.

  8. Overview of Research on Thermoelectric Materials and Devices in China |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy An overview presentation of R&D projects on thermoelectric power generation technology in China. zhang.pdf (3.85 MB) More Documents & Publications Recent Progress in the Development of N-type Skutterudites Vehicular Thermoelectric Applications Session DEER 2009 The Bottom-Up Approach forThermoelectric Nanocomposites, plusƒ

  9. High temperature thermoelectrics

    DOE Patents [OSTI]

    Moczygemba, Joshua E.; Biershcenk, James L.; Sharp, Jeffrey W.

    2014-09-23

    In accordance with one embodiment of the present disclosure, a thermoelectric device includes a plurality of thermoelectric elements that each include a diffusion barrier. The diffusion barrier includes a refractory metal. The thermoelectric device also includes a plurality of conductors coupled to the plurality of thermoelectric elements. The plurality of conductors include aluminum. In addition, the thermoelectric device includes at least one plate coupled to the plurality of thermoelectric elements using a braze. The braze includes aluminum.

  10. Recent Progress in the Development of High Efficiency Thermoelectrics |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy in the Development of High Efficiency Thermoelectrics Recent Progress in the Development of High Efficiency Thermoelectrics 2003_deer_bass.pdf (992.67 KB) More Documents & Publications High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation Quantum Well Thermoelectrics and Waste Heat Recovery Scale Up of Si/Si0.8GE0.2 and B4C/B9C Superlattices for Harvesting of Waste Heat in Diesel Engines

  11. Development of Thermoelectric Technology for Automotive Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Thermoelectric Technology for Automotive Waste Heat Recovery Development of Thermoelectric Technology for Automotive Waste Heat Recovery Overview and status of project to develop thermoelectric generator for automotive waste heat recovery and achieve at least 10% fuel economy improvement. deer08_gundlach.pdf (1 MB) More Documents & Publications Opportunities and Challenges of Thermoelectrlic Waste Heat Recovery in the Automotive Industry Develop Thermoelectric

  12. Composite Thermoelectric Devices

    Broader source: Energy.gov [DOE]

    Composite thermoelectric devices incorporating common conductors laminated between P- and N-type thermoelectric plates demonstrate internal ohmic loss reduction and enhanced performance

  13. Thermoelectric Development at Hi-Z Technology

    SciTech Connect (OSTI)

    Kushch, Aleksandr S.; Bass, John C.; Ghamaty, Saeid; Elsner, Norbert B.; Bergstrand, Richard A.; Furrow, David; Melvin, Mike

    2002-08-25

    An improved Thermoelectric Generator (TEG) for the Heavy Duty Class Eight Diesel Trucks is under development at Hi-Z Technology. The current TEG is equipped with the improved HZ-14 Thermoelectric module, which features better mechanical properties as well as higher electric power output. Also, the modules are held in place more securely.

  14. Nanostructures having high performance thermoelectric properties

    SciTech Connect (OSTI)

    Yang, Peidong; Majumdar, Arunava; Hochbaum, Allon I; Chen, Renkun; Delgado, Raul Diaz

    2014-05-20

    The invention provides for a nanostructure, or an array of such nanostructures, each comprising a rough surface, and a doped or undoped semiconductor. The nanostructure is an one-dimensional (1-D) nanostructure, such a nanowire, or a two-dimensional (2-D) nanostructure. The nanostructure can be placed between two electrodes and used for thermoelectric power generation or thermoelectric cooling.

  15. Nanostructures having high performance thermoelectric properties

    DOE Patents [OSTI]

    Yang, Peidong; Majumdar, Arunava; Hochbaum, Allon I.; Chen, Renkun; Delgado, Raul Diaz

    2015-12-22

    The invention provides for a nanostructure, or an array of such nanostructures, each comprising a rough surface, and a doped or undoped semiconductor. The nanostructure is an one-dimensional (1-D) nanostructure, such a nanowire, or a two-dimensional (2-D) nanostructure. The nanostructure can be placed between two electrodes and used for thermoelectric power generation or thermoelectric cooling.

  16. Accelerator Generation and Thermal Separation (AGATS) of Technetium-99m

    ScienceCinema (OSTI)

    None

    2013-05-28

    Accelerator Generation and Thermal Separation (AGATS) of Technetium-99m is a linear electron accelerator-based technology for producing medical imaging radioisotopes from a separation process that heats, vaporizes and condenses the desired radioisotope. You can learn more about INL's education programs at http://www.facebook.com/idahonationallaboratory.

  17. Nanocrystalline silicon: Lattice dynamics and enhanced thermoelectric properties

    SciTech Connect (OSTI)

    Claudio, Tania; Stein, Niklas; Stroppa, Daniel G.; Klobes, Benedikt; Koza, Michael Marek; Kudejova, Petra; Petermann, Nils; Wiggers, Hartmut; Schierning, Gabi; Hermann, Raphaël P.

    2014-12-21

    In this study, silicon has several advantages when compared to other thermoelectric materials, but until recently it was not used for thermoelectric applications due to its high thermal conductivity, 156 W K-1 m-1 at room temperature. Nanostructuration as means to decrease thermal transport through enhanced phonon scattering has been a subject of many studies. In this work we have evaluated the effects of nanostructuration on the lattice dynamics of bulk nanocrystalline doped silicon. The samples were prepared by gas phase synthesis, followed by current and pressure assisted sintering. The heat capacity, density of phonons states, and elastic constants were measured, which all reveal a significant, ≈25%, reduction in the speed of sound. The samples present a significantly decreased lattice thermal conductivity, ≈25 W K-1 m-1, which, combined with a very high carrier mobility, results in a dimensionless figure of merit with a competitive value that peaks at ZT ≈ 0.57 at 973 °C. Due to its easily scalable and extremely low-cost production process, nanocrystalline Si prepared by gas phase synthesis followed by sintering could become the material of choice for high temperature thermoelectric generators.

  18. Nanocrystalline silicon: Lattice dynamics and enhanced thermoelectric properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Claudio, Tania; Stein, Niklas; Stroppa, Daniel G.; Klobes, Benedikt; Koza, Michael Marek; Kudejova, Petra; Petermann, Nils; Wiggers, Hartmut; Schierning, Gabi; Hermann, Raphaël P.

    2014-12-21

    In this study, silicon has several advantages when compared to other thermoelectric materials, but until recently it was not used for thermoelectric applications due to its high thermal conductivity, 156 W K-1 m-1 at room temperature. Nanostructuration as means to decrease thermal transport through enhanced phonon scattering has been a subject of many studies. In this work we have evaluated the effects of nanostructuration on the lattice dynamics of bulk nanocrystalline doped silicon. The samples were prepared by gas phase synthesis, followed by current and pressure assisted sintering. The heat capacity, density of phonons states, and elastic constants were measured,more » which all reveal a significant, ≈25%, reduction in the speed of sound. The samples present a significantly decreased lattice thermal conductivity, ≈25 W K-1 m-1, which, combined with a very high carrier mobility, results in a dimensionless figure of merit with a competitive value that peaks at ZT ≈ 0.57 at 973 °C. Due to its easily scalable and extremely low-cost production process, nanocrystalline Si prepared by gas phase synthesis followed by sintering could become the material of choice for high temperature thermoelectric generators.« less

  19. Electron-phonon coupling and thermal transport in the thermoelectric compound Mo3Sb7–xTex

    SciTech Connect (OSTI)

    Bansal, Dipanshu; Li, Chen W.; Said, Ayman H.; Abernathy, Douglas L.; Yan, Jiaqiang; Delaire, Olivier A.

    2015-12-07

    Phonon properties of Mo3Sb7–xTex (x = 0, 1.5, 1.7), a potential high-temperature thermoelectric material, have been studied with inelastic neutron and x-ray scattering, and with first-principles simulations. The substitution of Te for Sb leads to pronounced changes in the electronic struc- ture, local bonding, phonon density of states (DOS), dispersions, and phonon lifetimes. Alloying with tellurium shifts the Fermi level upward, near the top of the valence band, resulting in a strong suppression of electron-phonon screening, and a large overall stiffening of interatomic force- constants. The suppression in electron-phonon coupling concomitantly increases group velocities and suppresses phonon scattering rates, surpassing the effects of alloy-disorder scattering, and re- sulting in a surprising increased lattice thermal conductivity in the alloy. We also identify that the local bonding environment changes non-uniformly around different atoms, leading to variable perturbation strengths for different optical phonon branches. The respective roles of changes in phonon group velocities and phonon lifetimes on the lattice thermal conductivity are quantified. Lastly, our results highlight the importance of the electron-phonon coupling on phonon mean-free-paths in this compound, and also estimates the contributions from boundary scattering, umklapp scattering, and point-defect scattering.

  20. High-Performance Thermoelectric Devices Based on Abundant Silicide Materials for Vehicle Waste Heat Recovery

    Broader source: Energy.gov [DOE]

    Development of high-performance thermoelectric devices for vehicle waste heat recovery will include fundamental research to use abundant promising low-cost thermoelectric materials, thermal management and interfaces design, and metrology

  1. Evaluation of Thermal to Electrical Energy Conversion of High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Skutterudite-Based Thermoelectric Modules Evaluation of Thermal to Electrical Energy Conversion of High Temperature Skutterudite-Based Thermoelectric Modules Discusses ...

  2. An Innovative System for the Efficient and Effective Treatment of Non-Traditional Waters for Reuse in Thermoelectric Power Generation

    SciTech Connect (OSTI)

    John Rodgers; James Castle

    2008-08-31

    This study assessed opportunities for improving water quality associated with coal-fired power generation including the use of non-traditional waters for cooling, innovative technology for recovering and reusing water within power plants, novel approaches for the removal of trace inorganic compounds from ash pond effluents, and novel approaches for removing biocides from cooling tower blowdown. This research evaluated specifically designed pilot-scale constructed wetland systems for treatment of targeted constituents in non-traditional waters for reuse in thermoelectric power generation and other purposes. The overall objective of this project was to decrease targeted constituents in non-traditional waters to achieve reuse criteria or discharge limitations established by the National Pollutant Discharge Elimination System (NPDES) and Clean Water Act (CWA). The six original project objectives were completed, and results are presented in this final technical report. These objectives included identification of targeted constituents for treatment in four non-traditional water sources, determination of reuse or discharge criteria for treatment, design of constructed wetland treatment systems for these non-traditional waters, and measurement of treatment of targeted constituents in non-traditional waters, as well as determination of the suitability of the treated non-traditional waters for reuse or discharge to receiving aquatic systems. The four non-traditional waters used to accomplish these objectives were ash basin water, cooling water, flue gas desulfurization (FGD) water, and produced water. The contaminants of concern identified in ash basin waters were arsenic, chromium, copper, mercury, selenium, and zinc. Contaminants of concern in cooling waters included free oxidants (chlorine, bromine, and peroxides), copper, lead, zinc, pH, and total dissolved solids. FGD waters contained contaminants of concern including arsenic, boron, chlorides, selenium, mercury

  3. 2009 Thermoelectrics Applications Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics Applications Workshop 2009 Thermoelectrics Applications Workshop September 29 - October 1, 2009 San Diego, CA Tuesday, September 29, 2009 Opening Plenary Session Wednesday, September 30, 2009 Overview of Worldwide Activities in Thermoelectrics Thermoelectric Applications I Thermoelectric Materials I Thermoelectric Manufacturing Thursday, October 1, 2009 Thermoelectric Materials II Thermoelectric Applications II Thermoelectric Materials III Thermoelectric Applications III Tuesday,

  4. Efficiency Improvement in an Over the Road Diesel Powered Engine System by the Application of Advanced Thermoelectric Systems Implemented in a Hybrid Configuration

    Broader source: Energy.gov [DOE]

    Hybridization of heavy-duty truck propulsion with thermoelectric generator and potential efficiency enhancement

  5. Investigation of thermal storage and steam generator issues

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    A review and evaluation of steam generator and thermal storage tank designs for commercial nitrate salt technology showed that the potential exists to procure both on a competitive basis from a number of qualified vendors. The report outlines the criteria for review and the results of the review, which was intended only to assess the feasibility of each design, not to make a comparison or select the best concept.

  6. Benefits of Thermoelectric Technology for the Automobile | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Discusses improved fuel efficiency and other benefits of automotive application of thermoelectric (power generation and heatingcooling) and the need for production quantities of ...

  7. 2nd Thermoelectrics Applications Workshop 2011 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Micro- and Nano-Technologies Enabling More Compact, Lightweight Thermoelectric Power Generation and Cooling Systems Terry Hendricks PNNL, Corvallis, OR Proactive Design of n-Type ...

  8. Improving Energy Efficiency by Developing Components for Distributed Cooling and Heating Based on Thermal Comfort Modeling[Thermoelectric (TE) HVAC

    Broader source: Energy.gov [DOE]

    Discusses results from TE HVAC project to add detail to a human thermal comfort model and further allow load reduction in the climate control energy through a distributed TE network

  9. Thermal energy storage for coal-fired power generation

    SciTech Connect (OSTI)

    Drost, M.K.; Somasundaram, S.; Brown, D.R.; Antoniak, Z.I.

    1990-11-01

    This paper presents an engineering and economic evaluation of using thermal energy storage (TES) with coal-fired conventional and combined cycle power plants. In the first case, conventional pulverized coal combustion equipment was assumed to continuously operate to heat molten nitrate salt which was then stored in a tank. During intermediate-load demand periods, hot salt was withdrawn from storage and used to generate steam for a Rankine steam power cycle. This allowed the coal-fired salt heater to be approximately one-third the size of a coal-fired boiler in a conventional cycling plant. The use of nitrate salt TES also reduced the levelized cost of power by between 5% and 24% depends on the operating schedule. The second case evaluate the use of thermal energy storage with an integrated gasification combined cycle (IGCC) power plant. In this concept, the nitrate salt was heated by a combination of the gas turbine exhaust and the hot fuel gas. The IGCC plant also contained a low-temperature storage unit that uses a mixture of oil and rock as the thermal storage medium. Thermal energy stored in the low-temperature TES was used to preheat the feedwater after it leaves the condenser and to produce process steam for other applications in the IGCC plant. This concept study also predicted a 5% to 20% reduction in levelized cost of power compared to other coal-fired alternatives. If significant escalation rates in the price of fuel were assumed, the concept could be competitive with natural-gas-fired intermediate-load power generation. A sensitivity analysis of using a direct-contact heat exchanger instead of the conventional finned-tube design showed a significant reduction in the installed capital cost. 3 refs., 2 figs., 6 tabs.

  10. Thermoelectric Waste Heat Recovery Program for Passenger Vehicles |

    Broader source: Energy.gov (indexed) [DOE]

    High Efficiency Hybrid Vehicles | Department of Energy This project discusses preliminary experimental results to find how thermoelectrics can be applied ot future hybrid vehicles and the optimum design of such equipment using heat pipes deer09_kim.pdf (628.26 KB) More Documents & Publications Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles A Thermoelectric Generator with an Intermediate Heat Exchanger for Automotive Waste Heat

  11. Thermoelectrics Partnership: Automotive Thermoelectric Modules with

    Broader source: Energy.gov (indexed) [DOE]

    Scalable Thermo- and Electro-Mechanical Interfaces | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ace067_goodson_2012_o.pdf (5.6 MB) More Documents & Publications Novel Nanostructured Interface Solution for Automotive Thermoelectric Modules Application Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces

  12. Thermoelectrics Partnership: Automotive Thermoelectric Modules with

    Broader source: Energy.gov (indexed) [DOE]

    Scalable Thermo- and Electro-Mechanical Interfaces | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace067_goodson_2011_o.pdf (1.89 MB) More Documents & Publications Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces Novel Nanostructured Interface Solution for Automotive Thermoelectric Modules Application

  13. Bulk dimensional nanocomposites for thermoelectric applications

    DOE Patents [OSTI]

    Nolas, George S

    2014-06-24

    Thermoelectric elements may be used for heat sensors, heat pumps, and thermoelectric generators. A quantum-dot or nano-scale grain size polycrystalline material the effects of size-quantization are present inside the nanocrystals. A thermoelectric element composed of densified Groups IV-VI material, such as calcogenide-based materials are doped with metal or chalcogenide to form interference barriers form along grains. The dopant used is either silver or sodium. These chalcogenide materials form nanoparticles of highly crystal grains, and may specifically be between 1- and 100 nm. The compound is densified by spark plasma sintering.

  14. An integrated approach towards efficient, scalable, and low cost thermoelectric waste heat recovery devices for vehicles

    Broader source: Energy.gov [DOE]

    Efficient, scalable, and low cost vehicular thermoelectric generators development will include rapid synthesis of thermoelectric materials, different device geometries, heat sink designs, and durability and long-term performance tests

  15. High-Performance Thermoelectric Devices Based on Abundant Silicide

    Broader source: Energy.gov (indexed) [DOE]

    Materials for Vehicle Waste Heat Recovery | Department of Energy Development of high-performance thermoelectric devices for vehicle waste heat recovery will include fundamental research to use abundant promising low-cost thermoelectric materials, thermal management and interfaces design, and metrology shi.pdf (4.76

  16. Thermoelectric HVAC for Light-Duty Vehicle Applications | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace047_maranville_2011_o.pdf (1.08 MB) More Documents & Publications Thermoelectric HVAC for Light-Duty Vehicle Applications Thermoelectric HVAC and Thermal Comfort Enablers for Light-Duty Vehicle Applications

  17. Mechanical Response of Thermoelectric Materials

    SciTech Connect (OSTI)

    Wereszczak, Andrew A.; Case, Eldon D.

    2015-05-01

    A sufficient mechanical response of thermoelectric materials (TEMats) to structural loadings is a prerequisite to the exploitation of any candidate TEMat's thermoelectric efficiency. If a TEMat is mechanically damaged or cracks from service-induced stresses, then its thermal and electrical functions can be compromised or even cease. Semiconductor TEMats tend to be quite brittle and have a high coefficient of thermal expansion; therefore, they can be quite susceptible to mechanical failure when subjected to operational thermal gradients. Because of this, sufficient mechanical response (vis-a-vis, mechanical properties) of any candidate TEMat must be achieved and sustained in the context of the service-induced stress state to which it is subjected. This report provides an overview of the mechanical responses of state-of-the-art TEMats; discusses the relevant properties that are associated with those responses and their measurement; and describes important, nonequilibrium phenomena that further complicate their use in thermoelectric devices. For reference purposes, the report also includes several appendixes that list published data on elastic properties and strengths of a variety of TEMats.

  18. Project Profile: High-Temperature Thermal Array for Next-Generation Solar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Power Production | Department of Energy Thermal Array for Next-Generation Solar Thermal Power Production Project Profile: High-Temperature Thermal Array for Next-Generation Solar Thermal Power Production Los Alamos National Laboratory logo The Los Alamos National Laboratory (LANL), under the National Laboratory R&D competitive funding opportunity, is developing a megawatt-scale heat pipe-based technology designed to bridge the heliostat reflector field and the power cycle by

  19. Radioisotope Power System Delivery, Ground Support and Nuclear Safety Implementation: Use of the Multi-Mission Radioisotope Thermoelectric Generator for the NASA's Mars Science Laboratory

    SciTech Connect (OSTI)

    S.G. Johnson; K.L. Lively; C.C. Dwight

    2014-07-01

    Radioisotope power systems have been used for over 50 years to enable missions in remote or hostile environments. They are a convenient means of supplying a few milliwatts up to a few hundred watts of useable, long-term electrical power. With regard to use of a radioisotope power system, the transportation, ground support and implementation of nuclear safety protocols in the field is a complex process that requires clear identification of needed technical and regulatory requirements. The appropriate care must be taken to provide high quality treatment of the item to be moved so it arrives in a condition to fulfill its missions in space. Similarly it must be transported and managed in a manner compliant with requirements for shipment and handling of special nuclear material. This presentation describes transportation, ground support operations and implementation of nuclear safety and security protocols for a radioisotope power system using recent experience involving the Multi-Mission Radioisotope Thermoelectric Generator for National Aeronautics and Space Administration’s Mars Science Laboratory, which launched in November of 2011.

  20. NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE)

    Development for commercialization of automotive thermoelectric generators from high-ZT TE materials with using low-cost, widely available materials, system design and modeling to maximize temperature differential across TE modules and maximize power output

  1. Close-packed-array (CPA) thermoelectric module development status

    SciTech Connect (OSTI)

    Brittain, W.M. )

    1991-01-05

    Prior effort on the U.S. Department of Energy-sponsored Special Applications Radioisotope Thermoelectric Generator (RTG) Technology Program and Two-Watt RTG Program has focused on terrestrial applications where the RTG will be exposed to relatively low temperature thermal environments (subsea). Thus, effort has been oriented towards design optimization at cold junction temperatures in the 10 to 93 {degree}C (50 to 200 {degree}F) range. However, for other more severe design environments (such as space applications where a high heat rejection radiator temperature in the 177 to 204 {degree}C (350 to 400 {degree}F) range is required to minimize RTG size and weight, and high g shock/vibration capability is necessary) a modified thermoelectric module design is dictated. In order to minimize the RTG system size and weight, and to increase the mechanical strength of the thermoelectric module to withstand increased dynamic loads, a close-packed-array (CPA) module configuration is desirable. The monolithic nature of such a module generally results in greater shear and compression load capability than free-standing individual couples. A CPA module is especially attractive for terrestrial and space applications where severe structural loads will be imposed such as airborne deployment or planetary landers and penetrators.

  2. POTENTIAL THERMOELECTRIC APPLICATIONS IN DIESEL VEHICLES

    SciTech Connect (OSTI)

    Crane, D

    2003-08-24

    Novel thermodynamic cycles developed by BSST provide improvements by factors of approximately 2 in cooling, heating and power generation efficiency of solid-state thermoelectric systems. The currently available BSST technology is being evaluated in automotive development programs for important new applications. Thermoelectric materials are likely to become available that further increase performance by a comparable factor. These major advancements should allow the use of thermoelectric systems in new applications that have the prospect of contributing to emissions reduction, fuel economy, and improved user comfort. Potential applications of thermoelectrics in diesel vehicles are identified and discussed. As a case in point, the history and status of the Climate Controlled Seat (CCS) system from Amerigon, the parent of BSST, is presented. CCS is the most successful and highest production volume thermoelectric system in vehicles today. As a second example, the results of recent analyses on electric power generation from vehicle waste heat are discussed. Conclusions are drawn as to the practicality of waste power generation systems that incorporate BSST's thermodynamic cycle and advanced thermoelectric materials.

  3. Project Profile: Concentrated Solar Thermoelectric Power | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Concentrated Solar Thermoelectric Power Project Profile: Concentrated Solar Thermoelectric Power MIT logo -- This project is inactive -- The Rohsenow-Kendall Heat Transfer Lab at Massachusetts Institute of Technology(MIT), under the 2012 SunShot Concentrating Solar Power (CSP) R&D FOA, is developing concentrated solar thermoelectric generators (CSTEGs) for CSP systems. This innovative distributed solution contains no moving parts and converts heat directly into electricity.

  4. Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat

    Broader source: Energy.gov (indexed) [DOE]

    Recovery Applications | Department of Energy Progress in reliable high temperature segmented thermoelectric devices and potential for producing electricity from waste heat from energy intensive industrial processes and transportation vehicles exhaust are discussed fluerial.pdf (3.11 MB) More Documents & Publications Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat Recovery Applications High Reliability, High TemperatureThermoelectric Power Generation Materials and

  5. Molecular and Hybrid Solution Processable Thermoelectrics | MIT-Harvard

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Excitonics and Hybrid Solution Processable Thermoelectrics February 15, 2011 at 3pm/36-428 Rachel Segalman University of California, Berkeley segalman_001 abstract: Thermoelectric materials for energy generation have several advantages over conventional power cycles including lack of moving parts, silent operation, miniaturizability, and CO2 free conversion of heat to electricity. Excellent thermoelectric efficiency requires a combination of high thermopower (S, V/K), high

  6. Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Exhaust Gas Waste Heat into Usable Electricity Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Presents successful incorporation of one of the most promising classes of the new materials, the skutterudites, into a working automotive TEG prototype and test results on its performance deer11_meisner.pdf (1.17 MB) More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Develop Thermoelectric

  7. Radiolytic and thermal generation of gases from Hanford grout samples

    SciTech Connect (OSTI)

    Meisel, D.; Jonah, C.D.; Kapoor, S.; Matheson, M.S.; Mulac, W.A.

    1993-10-01

    Gamma irradiation of WHC-supplied samples of grouted Tank 102-AP simulated nonradioactive waste has been carried out at three dose rates, 0.25, 0.63, and 130 krad/hr. The low dose rate corresponds to that in the actual grout vaults; with the high dose rate, doses equivalent to more than 40 years in the grout vault were achieved. An average G(H{sub 2}) = 0.047 molecules/100 eV was found, independent of dose rate. The rate of H2 production decreases above 80 Mrad. For other gases, G(N{sub 2}) = 0.12, G(O{sub 2}) = 0.026, G(N{sub 2}O) = 0.011 and G(CO) = 0.0042 at 130 krad/hr were determined. At lower dose rates, N{sub 2} and O{sub 2} could not be measured because of interference by trapped air. The value of G(H{sub 2}) is higher than expected, suggesting segregation of water from nitrate and nitrite salts in the grout. The total pressure generated by the radiolysis at 130 krad/h has been independently measured, and total amounts of gases generated were calculated from this measurement. Good agreement between this measurement and the sum of all the gases that were independently determined was obtained. Therefore, the individual gas measurements account for most of the major components that are generated by the radiolysis. At 90 {degree}C, H{sub 2}, N{sub 2}, and N{sub 2}O were generated at a rate that could be described by exponential formation of each of the gases. Gases measured at the lower temperatures were probably residual trapped gases. An as yet unknown product interfered with oxygen determinations at temperatures above ambient. The thermal results do not affect the radiolytic findings.

  8. Advanced Thin Film Thermoelectric Systems forEfficient Air-Conditioner...

    Broader source: Energy.gov (indexed) [DOE]

    Presents recent advances in thermoelectric device fabrication and the design of novel coolingheating engines exploiting thermal storage for efficient air-conditioners in ...

  9. Advanced Thin Film Thermoelectric Systems forEfficient Air-Conditioners

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presents recent advances in thermoelectric device fabrication and the design of novel cooling/heating engines exploiting thermal storage for efficient air-conditioners in automobiles

  10. Thermoelectric materials having porosity

    DOE Patents [OSTI]

    Heremans, Joseph P.; Jaworski, Christopher M.; Jovovic, Vladimir; Harris, Fred

    2014-08-05

    A thermoelectric material and a method of making a thermoelectric material are provided. In certain embodiments, the thermoelectric material comprises at least 10 volume percent porosity. In some embodiments, the thermoelectric material has a zT greater than about 1.2 at a temperature of about 375 K. In some embodiments, the thermoelectric material comprises a topological thermoelectric material. In some embodiments, the thermoelectric material comprises a general composition of (Bi.sub.1-xSb.sub.x).sub.u(Te.sub.1-ySe.sub.y).sub.w, wherein 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.1, 1.8.ltoreq.u.ltoreq.2.2, 2.8.ltoreq.w.ltoreq.3.2. In further embodiments, the thermoelectric material includes a compound having at least one group IV element and at least one group VI element. In certain embodiments, the method includes providing a powder comprising a thermoelectric composition, pressing the powder, and sintering the powder to form the thermoelectric material.

  11. Progress in Thermoelectrical Energy Recovery from a Light Truck Exhaust |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy in Thermoelectrical Energy Recovery from a Light Truck Exhaust Progress in Thermoelectrical Energy Recovery from a Light Truck Exhaust Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_thacher.pdf (780.57 KB) More Documents & Publications The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Thermoelectrical Energy

  12. Modeling Energy Recovery Using Thermoelectric Conversion Integrated with an Organic Rankine Bottoming Cycle

    SciTech Connect (OSTI)

    Miller, Erik W.; Hendricks, Terry J.; Peterson, Richard B.

    2009-07-01

    Hot engine exhaust represents a resource that is often rejected to the environment without further utilization. This resource is most prevalent in the transportation sector, but stationary engine-generator systems also typically do not utilize this resource. Engine exhaust is a source of high grade thermal energy that can potentially be utilized by various approaches to produce electricity or to drive heating and cooling systems. This paper describes a model system that employs thermoelectric conversion as a topping cycle integrated with an organic Rankine bottoming cycle for waste heat utilization. This approach is being developed to fully utilize the thermal energy contained in hot exhaust streams. The model is composed of a high temperature heat exchanger which extracts thermal energy for driving the thermoelectric conversion elements. However, substantial sensible heat remains in the exhaust stream after emerging from the heat exchanger. The model incorporates a closely integrated bottoming cycle to utilize this remaining thermal energy in the exhaust stream. The model has many interacting parameters that define combined system quantities such as overall output power, efficiency, and total energy utilization factors. In addition, the model identifies a maximum power operating point for the system. That is, the model can identify the optimal amount of heat to remove from the exhaust flow to run through the thermoelectric elements. Removing too much or too little heat from the exhaust stream in this stage will reduce overall cycle performance. The model has been developed such that heat exchanger UAh values, thermal resistances, ZT values, and multiple thermoelectric elements can be investigated in the context of system operation. The model also has the ability to simultaneously determine the effect of each cycle design parameter on the performance of the overall system, thus giving the ability to utilize as much waste heat as possible. Key analysis results are

  13. Proactive Strategies for Designing Thermoelectric Materials for Power

    Broader source: Energy.gov (indexed) [DOE]

    Generation | Department of Energy New p-type and n-type multiple-rattler skutterudite thermoelectric materials design, synthesis, fabrication, and characterization for power generation using vehicle exhaust waste heat. subramanian.pdf (1.79

  14. Nanostructured Thermoelectrics. The New Paradigm

    Broader source: Energy.gov [DOE]

    Highlights advances and future strategies for enhancing the thermoelectric figure of merit of bulk nanostructured thermoelectric and materials using low cost earth abundant elements

  15. Thermoelectric heat exchange element

    DOE Patents [OSTI]

    Callas, James J.; Taher, Mahmoud A.

    2007-08-14

    A thermoelectric heat exchange module includes a first substrate including a heat receptive side and a heat donative side and a series of undulatory pleats. The module may also include a thermoelectric material layer having a ZT value of 1.0 or more disposed on at least one of the heat receptive side and the heat donative side, and an electrical contact may be in electrical communication with the thermoelectric material layer.

  16. High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generation | Department of Energy High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_krommenhoek.pdf (761.33 KB) More Documents & Publications Development of an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles Recent Progress in the Development of High

  17. Sustainable solar thermal power generation (STPG) technologies in Indian context

    SciTech Connect (OSTI)

    Sharma, R.S.

    1996-12-31

    India is a fast developing country. Some of the factors like population growth, industrialization, liberalization in economic policies, green revolution and awareness toward the environment, are increasing the electricity demand rapidly. As per the 14th Power Survey Report, an energy deficit of (+) 9% and peak demand deficit of (+) 18% have been estimated. Keeping in view the liberalization in economic policies, this deficit may be higher by the year 2000 AD. An estimation indicates that India is blessed with solar energy to the tune of 5 x 10{sup 15} kWh/yr. Being clean and inexhaustible source of energy, it can be used for large-scale power generation in the country. Keeping in view the present state-of-art technologies for STPG in MW range, best possible efforts are required to be made by all the concerned, to develop sustainable STPG technology of the future, specially for tropical regions. Standardization of vital equipment is an important aspect. There are a few required criteria like simple and robust technology, its transfer and adaptation in tropical climate conditions; high plant load factor without fossil-fired backup; availability of plant during evening peak and night hours; least use of fragile components, and capacity optimization for MW plants as per solar irradiance and environmental factors. In this paper, efforts have been made to compare the different STPG technologies. On the basis, of literature surveyed and studies carried out by the author, it may be stated that Central Receiver System technologies using molten salt and volumetric air receiver, along with molten salt and ceramic thermal storage respectively seems to be suitable and comparable in Indian context. Performance of SOLAR-TWO and PHOEBUS plants may be decisive.

  18. Holey Silicon as an Efficient Thermoelectric Material

    SciTech Connect (OSTI)

    Tang, Jinyao; Wang, Hung-Ta; Hyun Lee, Dong; Fardy, Melissa; Huo, Ziyang; Russell, Thomas P.; Yang, Peidong

    2010-09-30

    This work investigated the thermoelectric properties of thin silicon membranes that have been decorated with high density of nanoscopic holes. These ?holey silicon? (HS) structures were fabricated by either nanosphere or block-copolymer lithography, both of which are scalable for practical device application. By reducing the pitch of the hexagonal holey pattern down to 55 nm with 35percent porosity, the thermal conductivity of HS is consistently reduced by 2 orders of magnitude and approaches the amorphous limit. With a ZT value of 0.4 at room temperature, the thermoelectric performance of HS is comparable with the best value recorded in silicon nanowire system.

  19. High Temperature Integrated Thermoelectric Ststem and Materials

    SciTech Connect (OSTI)

    Mike S. H. Chu

    2011-06-06

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits

  20. Thermal equation of state and spin transition of magnesiosiderite...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Thermal equation of ... Subject: catalysis (heterogeneous), solar (photovoltaic), phonons, thermoelectric, energy storage (including ...

  1. Thermoelectric Mechanical Reliability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    0_wereszczak.pdf (1.52 MB) More Documents & Publications Thermoelectric Mechanical Reliability Thermoelectric Mechanical Reliability Thermoelectrics Theory and Structure

  2. Vehicular Thermoelectric Applications Session DEER 2009 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Applications Session DEER 2009 Vehicular Thermoelectric Applications Session DEER 2009 This presentation is an overview of the DOE thermoelectric program. ...

  3. Challenges and Opportunities in Thermoelectric Materials Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Challenges and Opportunities in Thermoelectric Materials Research for Automotive ... The Bottom-Up Approach forThermoelectric Nanocomposites, plus NSFDOE Thermoelectric ...

  4. Thermoelectrics: The New Green Automotive Technology | Department...

    Broader source: Energy.gov (indexed) [DOE]

    (2.09 MB) More Documents & Publications Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: The New Green

  5. Vehicular Thermoelectrics: A New Green Technology | Department...

    Broader source: Energy.gov (indexed) [DOE]

    (3.68 MB) More Documents & Publications Thermoelectrics: The New Green Automotive Technology Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: The

  6. Automotive Thermoelectric Generators and HVAC

    Office of Energy Efficiency and Renewable Energy (EERE)

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  7. Novel Thermal Storage Technologies for Concentrating Solar Power Generation

    SciTech Connect (OSTI)

    Neti, Sudhakar; Oztekin, Alparslan; Chen, John; Tuzla, Kemal; Misiolek, Wojciech

    2013-06-20

    The technologies that are to be developed in this work will enable storage of thermal energy in 100 MWe solar energy plants for 6-24 hours at temperatures around 300oC and 850oC using encapsulated phase change materials (EPCM). Several encapsulated phase change materials have been identified, fabricated and proven with calorimetry. Two of these materials have been tested in an airflow experiment. A cost analysis for these thermal energy storage systems has also been conducted that met the targets established at the initiation of the project.

  8. Thermal and Electrical Analysis of Mars Rover RTGs

    SciTech Connect (OSTI)

    Schock, Alfred; Or, Chuen T; Skrabek, Emanuel A

    2012-01-19

    The RTG designs described in the preceding paper in these proceedings were analyzed for their thermal and electrical performance. Each analysis consisted of coupled thermal, thermoelectric, and electrical analyses, using Fairchild-generated specialized computer codes. These were supplemented with preliminary structural and mass analyses. For each design, various cases representing different operating conditions (water-cooled/radiation-cooled, BOM/EOM, summer/winter, day/night) and different thermoelectric performance assumptions (from conservative to optimistic) were analyzed; and for every case, the heat flow rates, temperatures and electrical performance of each layer of thermoelectric elements and of the overall RTG were determined. The analyses were performed in great detail, to obtain accurate answers permitting meaningful comparisons between different designs. The results presented show the RTG performance achievable with current technology, and the performance improvements that would be achievable with various technology developments.

  9. Synthesis and characterization of Bi-doped Mg{sub 2}Si thermoelectric materials

    SciTech Connect (OSTI)

    Fiameni, S.; Battiston, S.; Boldrini, S.; Famengo, A.; Agresti, F.; Barison, S.; Fabrizio, M.

    2012-09-15

    The Mg{sub 2}Si-based alloys are promising candidates for thermoelectric energy conversion for the middle high range of temperature. They are very attractive as they could replace lead-based compounds due to their low cost and non toxicity. They could also result in thermoelectric generator weight reduction (a key feature for the automotive application field). The high value of thermal conductivity of the silicide-based materials could be reduced by increasing the phonon scattering in the presence of nanosized crystalline grains without heavily interfering with the electrical conductivity of the thermoelectric material. Nanostructured materials were obtained under inert atmosphere through ball milling, thermal treatment and spark plasma sintering processes. In particular, the role of several bismuth doping amounts in Mg{sub 2}Si were investigated (Mg{sub 2}Si:Bi=1:x for x=0.01, 0.02 and 0.04 M ratio). The morphology, the composition and the structure of the samples were characterized by FE-SEM, EDS and XRD analyses after each process step. Moreover, the Seebeck coefficient analyses at high temperature and the electrical and thermal conductivity of the samples are presented in this work. The nanostructuring processes were affect by the MgO amount increase which influenced the thermoelectric properties of the samples mainly by reducing the electrical conductivity. With the aim of further increasing the scattering phenomena by interface or boundary effect, carbon nanostructures named Single Wall Carbon Nanohorns were added to the Mg{sub 2}Si in order to produce a nanocomposite material. The influence of the nanostructured filler on the thermoelectric material properties is also discussed. - Graphical abstract: Figure of merit (ZT) of Bi-doped samples and undoped Mg{sub 2}Si. A maximum ZT value of 0.39 at 600 Degree-Sign C was obtained for the nanocomposite material obtained adding Single Wall Carbon Nanohorns to the Bi 0.02 at% doped silicide. Highlights: Black

  10. Interpretation of thermoelectric properties of Cu substituted LaCoO{sub 3} ceramics

    SciTech Connect (OSTI)

    Choudhary, K. K.; Kaurav, N.; Sharma, U.; Ghosh, S. K.

    2014-04-24

    The thermoelectric properties of LaCo{sub 1?x}Cu{sub x}O{sub 3??} is theoretically analyzed, it is observed that thermoelectric figure of merit ZT (=S{sup 2}?T/?) is maximized by Cu substitution in LaCoO{sub 3} Ceramics at x=0.15. The lattice thermal conductivity and thermoelectric power were estimated by the scattering of phonons with defects, grain boundaries, electrons and phonons to evaluate the thermoelectric properties. We found that Cu substitution increase the phonon scattering with grain boundaries and defects which significantly increase the thermoelectric power and decrease the thermal conductivity. The present numerical analysis will help in designing more efficient thermoelectric materials.

  11. Recent Progress in the Development of High Efficiency Thermoelectrics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat Power Generation Quantum Well Thermoelectrics and Waste Heat Recovery Scale Up of SiSi0.8GE0.2 and B4CB9C Superlattices for Harvesting of Waste Heat in Diesel Engines

  12. Overview of Research on Thermoelectric Materials and Devices...

    Broader source: Energy.gov (indexed) [DOE]

    An overview presentation of R&D projects on thermoelectric power generation technology in China. zhang.pdf (3.85 MB) More Documents & Publications Recent Progress in the ...

  13. Encapsulation of High Temperature Thermoelectric Modules | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Encapsulation of High Temperature Thermoelectric Modules Encapsulation of High Temperature Thermoelectric Modules Presents concept for hermetic encapsulation of TE modules ...

  14. Novel Nanostructured Interface Solution for Automotive Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Electro-Mechanical Interfaces Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces Automotive ...

  15. In-Line Thermoelectric Module

    SciTech Connect (OSTI)

    Pento, Robert; Marks, James E.; Staffanson, Clifford D.

    1998-07-28

    A thermoelectric module with a plurality of electricity generating units each having a first end and a second end, the units being arranged first end to second end along an-in-line axis. Each unit includes first and second elements each made of a thermoelectric material, an electrically conductive hot member arranged to heat one side of the first element, and an electrically conductive cold member arranged to cool another side of the first element and to cool one side of the second element. The hot member, the first element, the cold member and the second element are supported in a fixture, are electrically connected respectively to provide an electricity generating unit, and are arranged respectively in positions along the in-line axis. The individual components of each generating unit and the respective generating units are clamped in their in-line positions by a loading bolt at one end of the fixture and a stop wall at the other end of the fixture. The hot members may have a T-shape and the cold members an hourglass shape to facilitate heat transfer. The direction of heat transfer through the hot members may be perpendicular to the direction of heat transfer through the cold members, and both of these heat transfer directions maybe perpendicular to the direction-of current flow through the module.

  16. In-line thermoelectric module

    DOE Patents [OSTI]

    Pento, Robert; Marks, James E.; Staffanson, Clifford D.

    2000-01-01

    A thermoelectric module with a plurality of electricity generating units each having a first end and a second end, the units being arranged first end to second end along an in-line axis. Each unit includes first and second elements each made of a thermoelectric material, an electrically conductive hot member arranged to heat one side of the first element, and an electrically conductive cold member arranged to cool another side of the first element and to cool one side of the second element. The hot member, the first element, the cold member and the second element are supported in a fixture, are electrically connected respectively to provide an electricity generating unit, and are arranged respectively in positions along the in-line axis. The individual components of each generating unit and the respective generating units are clamped in their in-line positions by a loading bolt at one end of the fixture and a stop wall at the other end of the fixture. The hot members may have a T-shape and the cold members an hourglass shape to facilitate heat transfer. The direction of heat transfer through the hot members may be perpendicular to the direction of heat transfer through the cold members, and both of these heat transfer directions may be perpendicular to the direction of current flow through the module.

  17. Enhanced thermoelectric performance driven by high-temperature phase transition in the phase change material Ge4SbTe5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Williams, Jared B.; Lara-Curzio, Edgar; Cakmak, Ercan; Watkins, Thomas R.; Morelli, Donald T.

    2015-05-15

    Phase change materials are identified for their ability to rapidly alternate between amorphous and crystalline phases and have large contrast in the optical/electrical properties of the respective phases. The materials are primarily used in memory storage applications, but recently they have also been identified as potential thermoelectric materials. Many of the phase change materials researched today can be found on the pseudo-binary (GeTe)1-x(Sb2Te3)x tie-line. While many compounds on this tie-line have been recognized as thermoelectric materials, here we focus on Ge4SbTe5, a single phase compound just off of the (GeTe)1-x(Sb2Te3)x tie-line, that forms in a stable rocksalt crystal structure atmore » room temperature. We find that stoichiometric and undoped Ge4SbTe5 exhibits a thermal conductivity of ~1.2 W/m-K at high temperature and a large Seebeck coefficient of ~250 μV/K. The resistivity decreases dramatically at 623 K due to a structural phase transition which lends to a large enhancement in both thermoelectric power factor and thermoelectric figure of merit at 823 K. In a more general sense the research presents evidence that phase change materials can potentially provide a new route to highly efficient thermoelectric materials for power generation at high temperature.« less

  18. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy Presents successful incorporation of one of the most promising classes of the new materials, the skutterudites, into a working automotive TEG prototype and test results on its performance deer11_meisner.pdf (1.17 MB) More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Develop Thermoelectric Technology for Automotive Waste Heat Recovery Development of Cost-Competitive Advanced Thermoelectric Generators for Direct

  19. Advanced Heat Transfer Fluids and Novel Thermal Storage Concepts for CSP Generation

    Office of Energy Efficiency and Renewable Energy (EERE)

    In 2008, DOE issued the Advanced Heat Transfer Fluids and Novel Thermal Storage Concepts for Concentrating Solar Power (CSP) Generation funding opportunity announcement (FOA) managed by the SunShot Initiative. The following projects were selected under this competitive solicitation.

  20. Energy harvesting using a thermoelectric material

    DOE Patents [OSTI]

    Nersessian, Nersesse; Carman, Gregory P.; Radousky, Harry B.

    2008-07-08

    A novel energy harvesting system and method utilizing a thermoelectric having a material exhibiting a large thermally induced strain (TIS) due to a phase transformation and a material exhibiting a stress induced electric field is introduced. A material that exhibits such a phase transformation exhibits a large increase in the coefficient of thermal expansion over an incremental temperature range (typically several degrees Kelvin). When such a material is arranged in a geometric configuration, such as, for a example, a laminate with a material that exhibits a stress induced electric field (e.g. a piezoelectric material) the thermally induced strain is converted to an electric field.

  1. Progress from DOE EF RC: Solid-State Solar-Thermal Energy Conversion Center

    Broader source: Energy.gov (indexed) [DOE]

    (S3TEC ) | Department of Energy Introduction to the solid-state solar-thermal energy conversion center plus discussion on phonon transport and solar thermoelectric energy conversion chen.pdf (2.01 MB) More Documents & Publications Solar Thermoelectric Energy Conversion Solar Thermoelectric Energy Conversion DOE Office of Basic Sciences: An Overview of Basic Research Activities on Thermoelectrics

  2. Feasibility of Thermoelectrics for Waste Heat Recovery in Hybrid Vehicles: Preprint

    SciTech Connect (OSTI)

    Smith, K.; Thornton, M.

    2007-12-01

    Using advanced materials, thermoelectric conversion of efficiencies on the order of 20% may be possible in the near future. Thermoelectric generators offer potential to increase vehicle fuel economy by recapturing a portion of the waste heat from the engine exhaust and generating electricity to power vehicle accessory or traction loads.

  3. Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems

    SciTech Connect (OSTI)

    2011-12-05

    HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at nightwhen the sun is not outto drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNLs metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800C). A high-temperature tank in PNNLs storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNLs thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

  4. Thermoelectrically cooled water trap

    DOE Patents [OSTI]

    Micheels, Ronald H.

    2006-02-21

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  5. Development of New Generation of Thermally-Enhanced Fiber Glass Insulation

    SciTech Connect (OSTI)

    Kosny, Jan; Yarbrough, David W; Childs, Phillip W; Miller, William A; Atchley, Jerald Allen; Shrestha, Som S

    2010-03-01

    This report presents experimental and numerical results from thermal performance studies. The purpose of this Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and John s Manville was to design a basic concept of a new generation of thermally-enhanced fiber glass insulation. Different types of Phase Change Materials (PCMs) have been tested as dynamic components in buildings during the last 4 decades. Most historical studies have found that PCMs enhance building energy performance. Some PCM-enhanced building materials, like PCM-gypsum boards or PCM-impregnated concretes have already found their limited applications in different countries. Today, continued improvements in building envelope technologies suggest that throughout Southern and Central U.S. climates, residences may soon be routinely constructed with PCM in order to maximize insulation effectiveness and maintain low heating and cooling loads. The proposed thermally-enhanced fiber glass insulation will maximize this integration by utilizing a highly-efficient building envelope with high-R thermal insulation, active thermal mass and superior air-tightness. Improved thermal resistance will come from modifications in infrared internal characteristics of the fiber glass insulation. Thermal mass effect can be provided by proprietary thermally-active microencapsulated phase change material (PCM). Work carried out at the Oak Ridge National Laboratory (ORNL) on the CRADA is described in this report.

  6. Thermoelectric and Structural Characterization of Ba2Ho(Cu3-xCox)O6+y

    SciTech Connect (OSTI)

    Wong-Ng, W.; Li, Q.; Yang, Z.; Hu, Y.F.; Huang, Q.; Lowhorn, N.; Otani, M.; Kaduk, J.A.

    2009-03-18

    The search for thermoelectric materials for power generation and for solid-state cooling has led to increased interest of layered cobalt-containing oxides because of their thermal stability at high temperature and their desirable thermoelectric properties. This paper examines the effect of substitution of Co in the layered pervoskite Ba{sub 2}Ho(Cu{sub 3-x}Co{sub x})O{sub 6+y} (x = 0.3, 0.4, 0.5, 0.6, and 1.0). Structural analysis using the neutron Rietveld refinement technique reveals that when x {le} 0.4, Co substitutes mainly for Cu in the 'chain sites' of the Ba{sub 2}Ho(Cu{sub 3-x}Co{sub x})O{sub 6+y} structure. As x > 0.4, Co also enters in the Cu-O 'plane sites' as well. The thermoelectric properties of polycrystalline Ba{sub 2}Ho(Cu{sub 3-x}Co{sub x})O{sub 6+y} samples were studied in the temperature range of 10-390 K. In general, as the cobalt content x increases, the resistivity and Seebeck coefficient of these samples increase while the thermal conductivity decreases. Among the five Ba{sub 2}Ho(Cu{sub 3-x}Co{sub x})O{sub 6+y} compositions, the x = 0.4 member gives the highest figure of merit ZT of {approx} 0.02 at approximately 270 K.

  7. Correlation Between Structure and Thermoelectric Properties of Bulk High Performance Materials for Energy Conversion

    Broader source: Energy.gov [DOE]

    Rapid solidified precursor converted into crystalline bulks under pressure produced thermoelectric materials of nano-sized grains with strongly coupled grain boundaries, achieving reduced lattice thermal conductivity and increased power factor

  8. Thermoelectric powered wireless sensors for spent fuel monitoring

    SciTech Connect (OSTI)

    Carstens, T.; Corradini, M.; Blanchard, J.; Ma, Z.

    2011-07-01

    This paper describes using thermoelectric generators to power wireless sensors to monitor spent nuclear fuel during dry-cask storage. OrigenArp was used to determine the decay heat of the spent fuel at different times during the service life of the dry-cask. The Engineering Equation Solver computer program modeled the temperatures inside the spent fuel storage facility during its service life. The temperature distribution in a thermoelectric generator and heat sink was calculated using the computer program Finite Element Heat Transfer. From these temperature distributions the power produced by the thermoelectric generator was determined as a function of the service life of the dry-cask. In addition, an estimation of the path loss experienced by the wireless signal can be made based on materials and thickness of the structure. Once the path loss is known, the transmission power and thermoelectric generator power requirements can be determined. This analysis estimates that a thermoelectric generator can produce enough power for a sensor to function and transmit data from inside the dry-cask throughout its service life. (authors)

  9. Industry sector analysis, Ecuador: Thermal power generating equipment. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1993-04-01

    The article is derived from a report titled: The Thermal Power Generation Equipment Market in Ecuador, dated April 1993, prepared by P. Zaldumbide, A. Moreno, and N. Ordonez, American Embassy - Quito. The article consists of 10 pages and contains the following subtopics: Overview; Statistical Data; Market Assessment; Best Sales Prospects; Competitive Situation; Market Access; and Trade Promotion Opportunities.

  10. Geek-Up[04.01.2011]: Charting Wind, Thermal, Hydro Generation

    Office of Energy Efficiency and Renewable Energy (EERE)

    Check out Bonneville Power Administration’s new near real-time energy monitoring – it displays the output of all wind, thermal and hydro generation in the agency’s balancing authority against its load. Updated every five minutes, it’s a great resource for universities, research laboratories and other utilities.

  11. NSF/DOE Thermoelectric Partnership: High-Performance Thermoelectric...

    Broader source: Energy.gov (indexed) [DOE]

    An integrated approach towards efficient, scalable, and low cost thermoelectric waste heat recovery devices for vehicles An integrated approach towards efficient, scalable, and low ...

  12. Heilongjiang Mudanjiang Nongken Xinneng Thermoelectric Co Ltd...

    Open Energy Info (EERE)

    Heilongjiang Mudanjiang Nongken Xinneng Thermoelectric Co Ltd Jump to: navigation, search Name: Heilongjiang Mudanjiang Nongken Xinneng Thermoelectric Co., Ltd. Place: Mishan,...

  13. Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste Heat Recovery Nanostructured High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste ...

  14. Concentrated Solar Thermoelectric Power | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrated Solar Thermoelectric Power Concentrated Solar Thermoelectric Power This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, ...

  15. Development of Thermoelectric Technology for Automotive Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Technology for Automotive Waste Heat Recovery Development of Thermoelectric Technology for Automotive Waste Heat Recovery Overview and status of project to develop ...

  16. Enhancing Heat Recovery for Thermoelectric Devices | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat Recovery for Thermoelectric Devices Enhancing Heat Recovery for Thermoelectric Devices Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research ...

  17. Investigations of Interfacial Structure in Thermoelectric Tellurides...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigations of Interfacial Structure in Thermoelectric Tellurides Discusses examples of work on the investigation of atomic structure of interfaces in thermoelectric tellurides ...

  18. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle

    SciTech Connect (OSTI)

    2012-01-31

    The thermoelectric generator shorting system provides the capability to monitor and short-out individual thermoelectric couples in the event of failure. This makes the series configured thermoelectric generator robust to individual thermoelectric couple failure. Open circuit detection of the thermoelectric couples and the associated short control is a key technique to ensure normal functionality of the TE generator under failure of individual TE couples. This report describes a five-year effort whose goal was the understanding the issues related to the development of a thermoelectric energy recovery device for a Class-8 truck. Likely materials and important issues related to the utility of this generator were identified. Several prototype generators were constructed and demonstrated. The generators developed demonstrated several new concepts including advanced insulation, couple bypass technology and the first implementation of skutterudite thermoelectric material in a generator design. Additional work will be required to bring this system to fruition. However, such generators offer the possibility of converting energy that is otherwise wasted to useful electric power. Uur studies indicate that this can be accomplished in a cost-effective manner for this application.

  19. Advanced Thermoelectric Materials for Efficient Waste Heat Recovery in Process Industries

    SciTech Connect (OSTI)

    Adam Polcyn; Moe Khaleel

    2009-01-06

    The overall objective of the project was to integrate advanced thermoelectric materials into a power generation device that could convert waste heat from an industrial process to electricity with an efficiency approaching 20%. Advanced thermoelectric materials were developed with figure-of-merit ZT of 1.5 at 275 degrees C. These materials were not successfully integrated into a power generation device. However, waste heat recovery was demonstrated from an industrial process (the combustion exhaust gas stream of an oxyfuel-fired flat glass melting furnace) using a commercially available (5% efficiency) thermoelectric generator coupled to a heat pipe. It was concluded that significant improvements both in thermoelectric material figure-of-merit and in cost-effective methods for capturing heat would be required to make thermoelectric waste heat recovery viable for widespread industrial application.

  20. Enhanced interfacial thermal transport in pnictogen tellurides metallized with a lead-free solder alloy

    SciTech Connect (OSTI)

    Devender,; Ramanath, Ganpati; Lofgreen, Kelly; Devasenathipathy, Shankar; Swan, Johanna; Mahajan, Ravi; Borca-Tasciuc, Theodorian

    2015-11-15

    Controlling thermal transport across metal–thermoelectric interfaces is essential for realizing high efficiency solid-state refrigeration and waste-heat harvesting power generation devices. Here, the authors report that pnictogen chalcogenides metallized with bilayers of Sn{sub 96.5}Ag{sub 3}Cu{sub 0.5} solder and Ni barrier exhibit tenfold higher interfacial thermal conductance Γ{sub c} than that obtained with In/Ni bilayer metallization. X-ray diffraction and x-ray spectroscopy indicate that reduced interdiffusion and diminution of interfacial SnTe formation due to Ni layer correlates with the higher Γ{sub c}. Finite element modeling of thermoelectric coolers metallized with Sn{sub 96.5}Ag{sub 3}Cu{sub 0.5}/Ni bilayers presages a temperature drop ΔT ∼ 22 K that is 40% higher than that obtained with In/Ni metallization. Our results underscore the importance of controlling chemical intermixing at solder–metal–thermoelectric interfaces to increase the effective figure of merit, and hence, the thermoelectric cooling efficiency. These findings should facilitate the design and development of lead-free metallization for pnictogen chalcogenide-based thermoelectrics.

  1. NSF/DOE Thermoelectric Partnership: Inorganic-Organic Hybrid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inorganic-Organic Hybrid Thermoelectrics NSFDOE Thermoelectric Partnership: Inorganic-Organic Hybrid Thermoelectrics 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle ...

  2. Role of Thermoelectrics in Vehicle Efficiency Increase | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Status of the Application of Thermoelectric Technology in Vehicles Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle Applications Thermoelectric ...

  3. Solid state transport-based thermoelectric converter

    DOE Patents [OSTI]

    Hu, Zhiyu

    2010-04-13

    A solid state thermoelectric converter includes a thermally insulating separator layer, a semiconducting collector and an electron emitter. The electron emitter comprises a metal nanoparticle layer or plurality of metal nanocatalyst particles disposed on one side of said separator layer. A first electrically conductive lead is electrically coupled to the electron emitter. The collector layer is disposed on the other side of the separator layer, wherein the thickness of the separator layer is less than 1 .mu.m. A second conductive lead is electrically coupled to the collector layer.

  4. 3rd Thermoelectrics Applications Workshop 2012

    Broader source: Energy.gov [DOE]

    Tuesday, March 20, 2012Opening Plenary SessionThermoelectric Applications IThermoelectric Applications IIThermoelectric Technologies

  5. Investigations of Interfacial Structure in Thermoelectric Tellurides

    Office of Energy Efficiency and Renewable Energy (EERE)

    Discusses examples of work on the investigation of atomic structure of interfaces in thermoelectric tellurides

  6. Thermoelectric system for an engine

    DOE Patents [OSTI]

    Mcgilvray, Andrew N.; Vachon, John T.; Moser, William E.

    2010-06-22

    An internal combustion engine that includes a block, a cylinder head having an intake valve port and exhaust valve port formed therein, a piston, and a combustion chamber defined by the block, the piston, and the head. At least one thermoelectric device is positioned within either or both the intake valve port and the exhaust valve port. Each of the valves is configured to move within a respective intake and exhaust valve port thereby causing said valves to engage the thermoelectric devices resulting in heat transfer from the valves to the thermoelectric devices. The intake valve port and exhaust valve port are configured to fluidly direct intake air and exhaust gas, respectively, into the combustion chamber and the thermoelectric device is positioned within the intake valve port, and exhaust valve port, such that the thermoelectric device is in contact with the intake air and exhaust gas.

  7. Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux

    DOE Patents [OSTI]

    Bowman, Charles D.

    1992-01-01

    Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux. High thermal neutron fluxes generated from the action of a high power proton accelerator on a spallation target allows the efficient burn-up of higher actinide nuclear waste by a two-step process. Additionally, rapid burn-up of fission product waste for nuclides having small thermal neutron cross sections, and the practicality of small material inventories while achieving significant throughput derive from employment of such high fluxes. Several nuclear technology problems are addressed including 1. nuclear energy production without a waste stream requiring storage on a geological timescale, 2. the burn-up of defense and commercial nuclear waste, and 3. the production of defense nuclear material. The apparatus includes an accelerator, a target for neutron production surrounded by a blanket region for transmutation, a turbine for electric power production, and a chemical processing facility. In all applications, the accelerator power may be generated internally from fission and the waste produced thereby is transmuted internally so that waste management might not be required beyond the human lifespan.

  8. Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux

    DOE Patents [OSTI]

    Bowman, C.D.

    1992-11-03

    Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux. High thermal neutron fluxes generated from the action of a high power proton accelerator on a spallation target allows the efficient burn-up of higher actinide nuclear waste by a two-step process. Additionally, rapid burn-up of fission product waste for nuclides having small thermal neutron cross sections, and the practicality of small material inventories while achieving significant throughput derive from employment of such high fluxes. Several nuclear technology problems are addressed including 1. nuclear energy production without a waste stream requiring storage on a geological timescale, 2. the burn-up of defense and commercial nuclear waste, and 3. the production of defense nuclear material. The apparatus includes an accelerator, a target for neutron production surrounded by a blanket region for transmutation, a turbine for electric power production, and a chemical processing facility. In all applications, the accelerator power may be generated internally from fission and the waste produced thereby is transmuted internally so that waste management might not be required beyond the human lifespan.

  9. Quantity, quality, and availability of waste heat from United States thermal power generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gingerich, Daniel B; Mauter, Meagan S

    2015-06-10

    Secondary application of unconverted heat produced during electric power generation has the potential to improve the life-cycle fuel efficiency of the electric power industry and the sectors it serves. This work quantifies the residual heat (also known as waste heat) generated by U.S. thermal power plants and assesses the intermittency and transport issues that must be considered when planning to utilize this heat. Combining Energy Information Administration plant-level data with literature-reported process efficiency data, we develop estimates of the unconverted heat flux from individual U.S. thermal power plants in 2012. Together these power plants discharged an estimated 18.9 billion GJthmoreof residual heat in 2012, 4% of which was discharged at temperatures greater than 90 C. We also characterize the temperature, spatial distribution, and temporal availability of this residual heat at the plant level and model the implications for the technical and economic feasibility of its end use. Increased implementation of flue gas desulfurization technologies at coal-fired facilities and the higher quality heat generated in the exhaust of natural gas fuel cycles are expected to increase the availability of residual heat generated by 10.6% in 2040.less

  10. Enhanced thermoelectric performance driven by high-temperature phase transition in the phase change material Ge4SbTe5

    SciTech Connect (OSTI)

    Williams, Jared B.; Lara-Curzio, Edgar; Cakmak, Ercan; Watkins, Thomas R.; Morelli, Donald T.

    2015-05-15

    Phase change materials are identified for their ability to rapidly alternate between amorphous and crystalline phases and have large contrast in the optical/electrical properties of the respective phases. The materials are primarily used in memory storage applications, but recently they have also been identified as potential thermoelectric materials. Many of the phase change materials researched today can be found on the pseudo-binary (GeTe)1-x(Sb2Te3)x tie-line. While many compounds on this tie-line have been recognized as thermoelectric materials, here we focus on Ge4SbTe5, a single phase compound just off of the (GeTe)1-x(Sb2Te3)x tie-line, that forms in a stable rocksalt crystal structure at room temperature. We find that stoichiometric and undoped Ge4SbTe5 exhibits a thermal conductivity of ~1.2 W/m-K at high temperature and a large Seebeck coefficient of ~250 μV/K. The resistivity decreases dramatically at 623 K due to a structural phase transition which lends to a large enhancement in both thermoelectric power factor and thermoelectric figure of merit at 823 K. In a more general sense the research presents evidence that phase change materials can potentially provide a new route to highly efficient thermoelectric materials for power generation at high temperature.

  11. An apparatus for concurrent measurement of thermoelectric material parameters

    SciTech Connect (OSTI)

    Kallaher, R. L.; Latham, C. A.; Sharifi, F.

    2013-01-15

    We describe an apparatus which concurrently and independently measures the parameters determining thermoelectric material conversion efficiency: the Seebeck coefficient, thermal conductivity, and electrical resistivity. The apparatus is designed to characterize thermoelectric materials which are technologically relevant for waste heat energy conversion, and may operate from room temperature to 400 Degree-Sign C. It is configured so the heat flux is axially confined along two boron nitride rods of known thermal conductance. The Seebeck coefficient and thermal conductivity are obtained in steady-state using a differential technique, while the electrical resistivity is obtained using a four-point lock-in amplification method. Measurements on the newly developed NIST Seebeck standard reference material are presented in the temperature range from 50 Degree-Sign C to 250 Degree-Sign C.

  12. Geek-Up[6.10.2011]: Thermoelectrics' Great Power, Key Ingredient in Bone's Nanostructure

    Broader source: Energy.gov [DOE]

    Advanced thermoelectric materials could be used to develop vehicle exhaust systems that convert exhaust heat into electricity, concentrate solar energy for power generation and recover waste heat from industrial processes.

  13. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat Recovery Engineering and Materials for Automotive Thermoelectric Applications Electrical ...

  14. NSF/DOE Thermoelectics Partnership: Thermoelectrics for Automotive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectics Partnership: Thermoelectrics for Automotive Waste Heat Recovery NSFDOE Thermoelectics Partnership: Thermoelectrics for Automotive Waste Heat Recovery 2011 DOE ...

  15. Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Caterpillar Diesel Racing: Yesterday & Today Thermoelectric Conversion of ...

  16. NSF/DOE Thermoelectrics Partnership: Purdue … GM Partnership...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces NSFDOE Thermoelectics Partnership: Thermoelectrics for Automotive Waste Heat ...

  17. The effect of Coulomb interactions on thermoelectric properties of quantum dots

    SciTech Connect (OSTI)

    Zimbovskaya, Natalya A.

    2014-03-14

    Thermoelectric effects in a quantum dot coupled to the source and drain charge reservoirs are explored using a nonequilibrium Green's functions formalism beyond the Hartree-Fock approximation. Thermal transport is analyzed within a linear response regime. A transition from Coulomb blockade regime to Kondo regime in thermoelectric transport through a single-level quantum dot is traced using unified approximations for the relevant Green's functions.

  18. Thermal generation of spin current in epitaxial CoFe2O4 thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Er -Jia; Herklotz, Andreas; Kehlberger, Andreas; Cramer, Joel; Jakob, Gerhard; Klaeui, Mathias

    2016-01-12

    The longitudinal spin Seebeck effect (LSSE) has been investigated in high-quality epitaxial CoFe2O4 (CFO) thin films. The thermally excited spin currents in the CFO films are electrically detected in adjacent Pt layers due to the inverse spin Hall effect (ISHE). The LSSE signal exhibits a linear increase with increasing temperature gradient, yielding a LSSE coefficient of –100 nV/K at room temperature. The temperature dependence of the LSSE is investigated from room temperature down to 30 K, showing a significant reduction at low temperatures, revealing that the total amount of thermally generated magnons decreases. Moreover, we demonstrate that the spin Seebeckmore » effect is an effective tool to study the magnetic anisotropy induced by epitaxial strain, especially in ultrathin films with low magnetic moments.« less

  19. Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation

    SciTech Connect (OSTI)

    Reddy, Ramana G.

    2013-10-23

    The explicit UA program objective is to develop low melting point (LMP) molten salt thermal energy storage media with high thermal energy storage density for sensible heat storage systems. The novel Low Melting Point (LMP) molten salts are targeted to have the following characteristics: 1. Lower melting point (MP) compared to current salts (<222ºC) 2. Higher energy density compared to current salts (>300 MJ/m3) 3. Lower power generation cost compared to current salt In terms of lower power costs, the program target the DOE's Solar Energy Technologies Program year 2020 goal to create systems that have the potential to reduce the cost of Thermal Energy Storage (TES) to less than $15/kWh-th and achieve round trip efficiencies greater than 93%. The project has completed the experimental investigations to determine the thermo-physical, long term thermal stability properties of the LMP molten salts and also corrosion studies of stainless steel in the candidate LMP molten salts. Heat transfer and fluid dynamics modeling have been conducted to identify heat transfer geometry and relative costs for TES systems that would utilize the primary LMP molten salt candidates. The project also proposes heat transfer geometry with relevant modifications to suit the usage of our molten salts as thermal energy storage and heat transfer fluids. The essential properties of the down-selected novel LMP molten salts to be considered for thermal storage in solar energy applications were experimentally determined, including melting point, heat capacity, thermal stability, density, viscosity, thermal conductivity, vapor pressure, and corrosion resistance of SS 316. The thermodynamic modeling was conducted to determine potential high temperature stable molten salt mixtures that have thermal stability up to 1000 °C. The thermo-physical properties of select potential high temperature stable (HMP) molten salt mixtures were also experimentally determined. All the salt mixtures align with the go

  20. NSF/DOE Thermoelectics Partnership: Thermoelectrics for Automotive Waste

    Broader source: Energy.gov (indexed) [DOE]

    Heat Recovery | Department of Energy 4_xu_2011_p.pdf (2.97 MB) More Documents & Publications NSF/DOE Thermoelectrics Partnership: Purdue … GM Partnership on Thermoelectrics for Automotive Waste Heat Recovery NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive Waste Heat Recovery NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive Waste Heat Recovery

  1. Development of thermoelectric fibers for miniature thermoelectric devices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ren, Fei; Menchhofer, Paul A.; Kiggans, Jr., James O.; Wang, Hsin

    2016-09-23

    Miniature thermoelectric (TE) devices may be used in a variety of applications such as power sources of small sensors, temperature regulation of precision electronics, etc. Reducing the size of TE elements may also enable design of novel devices with unique form factor and higher device efficiency. Current industrial practice of fabricating TE devices usually involves mechanical removal processes that not only lead to material loss but also limit the geometry of the TE elements. In this project, we explored a powder-processing method for the fabrication of TE fibers with large length-to-area ratio, which could be potentially used for miniature TEmore » devices. Powders were milled from Bi2Te3-based bulk materials and then mixed with a thermoplastic resin dissolved in an organic solvent. Through an extrusion process, flexible, continuous fibers with sub-millimeter diameters were formed. The polymer phase was then removed by sintering. Sintered fibers exhibited similar Seebeck coefficients to the bulk materials. Moreover, their electrical resistivity was much higher, which might be related to the residual porosity and grain boundary contamination. Prototype miniature uni-couples fabricated from these fibers showed a linear I-V behavior and could generate millivolt voltages and output power in the nano-watt range. Further development of these TE fibers requires improvement in their electrical conductivities, which needs a better understanding of the causes that lead to the low conductivity in the sintered fibers.« less

  2. Thermoelectric Materials, Devices and Systems:

    Energy Savers [EERE]

    ... However the use of thermoelectric modules as solid state heat pumps for 42 heating and cooling applications using the opposite Peltier effect is far more common than their use as ...

  3. An improved absorption generator for solar-thermal powered heat pumps. Part 2: Energy and economics

    SciTech Connect (OSTI)

    Fineblum, S.

    1997-12-31

    Solar heated absorption chiller installations have been very expensive for their rating. To enhance collector thermal efficiency the liquid flowing within the collectors must be kept as cool as possible. However, there is also a need to operate the absorption reported earlier. The compromise usually results in poor collector efficiency as well as a relatively poor specific chiller effect. The proposed vortex generator permits a heat pump to operate efficiently with relatively low temperature solar heated fluid (70--80 C). As a result, the collectors are cooler and more efficient. As noted in Part 1, the specific heat pumping capacity is about 27% greater than conventional systems operating at the same reduced generator temperatures. Therefore, a smaller, less expensive chiller is required. The reduced investment in solar arrays and absorption chillers is estimated along with a range of paybacks.

  4. An improved absorption generator for solar-thermal powered heat pumps. Part 1: Feasibility

    SciTech Connect (OSTI)

    Fineblum, S.

    1997-12-31

    Solar heated absorption chiller installations have been, typically, very expensive for their rating. The need to keep the liquid flowing within the collectors as cool as possible to enhance collector thermal efficiency, conflicts with the need to operate the absorption chiller at a higher temperature. The compromise usually results in poor collector efficiency as well as a relatively poor specific chiller effect. The proposed vortex generator permits a heat pump to operate efficiently with relatively low temperature solar heated fluid (70--80 C). As a result, the collectors are cooler and much more efficient. In addition, the specific heat pumping capacity is about 27% greater than conventional systems operating at the same reduced generator temperatures and, therefore, a smaller chiller is required. The economic consequences of these benefits will be presented in Part 2.

  5. Improvement in thermal barriers to intense terahertz generation from photoconductive antennas

    SciTech Connect (OSTI)

    Ropagnol, X.; Bouvier, Marcel; Reid, M.; Ozaki, T.

    2014-07-28

    We study the generation of free-space terahertz (THz) pulses at low THz frequencies using 6H-SiC and 4H-SiC photoconductive antennas. We investigate the dependence of the THz electric field radiated from the biased SiC emitters on the applied bias field and on the incident optical fluence. In this work, bias fields as high as 32?kV/cm, and optical fluences up to 2.5?mJ/cm{sup 2} (for the 400?nm laser), and 7.5?mJ/cm{sup 2} (for the 800?nm laser) were used. THz generation with back- and front-side illumination of the antennas is also examined. It is found that the SiC antenna, when illuminated from the backside, generates higher THz electric fields. The performance of 6H-SiC and ZnSe photoconductive antennas are compared. We show that, taking advantage of the superior thermal properties of SiC compare with ZnSe, the THz output power generated with the 6H-SiC photoconductive antenna under optimum conditions is 2.3 times larger that with a ZnSe photoconductive antenna.

  6. Evaluation of Thermal to Electrical Energy Conversion of High Temperature

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Skutterudite-Based Thermoelectric Modules | Department of Energy Thermal to Electrical Energy Conversion of High Temperature Skutterudite-Based Thermoelectric Modules Evaluation of Thermal to Electrical Energy Conversion of High Temperature Skutterudite-Based Thermoelectric Modules Discusses progress toward the fabrication of a skutterudite-based TE module and provides module performance data under operating conditions similar to those for automotive applications deer11_salvador.pdf (2.68

  7. WASTE HEAT RECOVERY USING THERMOELECTRIC DEVICES IN THE LIGHT METALS INDUSTRY

    SciTech Connect (OSTI)

    Choate, William T.; Hendricks, Terry J.; Majumdar, Rajita

    2007-05-01

    Recently discovered thermoelectric materials and associated manufacturing techniques (nanostructures, thin-film super lattice, quantum wells...) have been characterized with thermal to electric energy conversion efficiencies of 12-25+%. These advances allow the manufacture of small-area, high-energy flux (350 W/cm2 input) thermoelectric generating (TEG) devices that operate at high temperatures (~750C). TEG technology offers the potential for large-scale conversion of waste heat from the exhaust gases of electrolytic cells (e.g., Hall-Hroult cells) and from aluminum, magnesium, metal and glass melting furnaces. This paper provides an analysis of the potential energy recovery and of the engineering issues that are expected when integrating TEG systems into existing manufacturing processes. The TEG module must be engineered for low-cost, easy insertion and simple operation in order to be incorporated into existing manufacturing operations. Heat transfer on both the hot and cold-side of these devices will require new materials, surface treatments and design concepts for their efficient operation.

  8. A high-pressure route to thermoelectrics with low thermal conductivity: The solid solution series AgIn{sub x}Sb{sub 1?x}Te{sub 2} (x=0.10.6)

    SciTech Connect (OSTI)

    Schrder, Thorsten; Rosenthal, Tobias; Souchay, Daniel; Petermayer, Christian; Grott, Sebastian; Scheidt, Ernst-Wilhelm; Gold, Christian; Scherer, Wolfgang; Oeckler, Oliver

    2013-10-15

    Metastable rocksalt-type phases of the solid solution series AgIn{sub x}Sb{sub 1?x}Te{sub 2} (x=0.1, 0.2, 0.4, 0.5 and 0.6) were prepared by high-pressure synthesis at 2.5 GPa and 400 C. In these structures, the coordination number of In{sup 3+} is six, in contrast to chalcopyrite ambient-pressure AgInTe{sub 2} with fourfold In{sup 3+} coordination. Transmission electron microscopy shows that real-structure phenomena and a certain degree of short-range order are present, yet not very pronounced. All three cations are statistically disordered. The high degree of disorder is probably the reason why AgIn{sub x}Sb{sub 1?x}Te{sub 2} samples with 0.4thermal conductivities with a total ?<0.5 W/K m and a lattice contribution of ?{sub ph} ?0.3 W/K m at room temperature. These are lower than those of other rocksalt-type tellurides at room temperature; e.g. the well-known thermoelectric AgSbTe{sub 2} (? ?0.6 W/K m). The highest ZT value (0.15 at 300 K) is observed for AgIn{sub 0.5}Sb{sub 0.5}Te{sub 2}, mainly due to its high Seebeck coefficient of 160 V/K. Temperature-dependent X-ray powder patterns indicate that the solid solutions are metastable at ambient pressure. At 150 C, the quaternary compounds decompose into chalcopyrite-type AgInTe{sub 2} and rocksalt-type AgSbTe{sub 2}. - Graphical abstract: Reaction scheme, temperature characteristics of the ZT value and a selected-area electron diffraction pattern (background) of AgIn{sub 0.5}Sb{sub 0.5}Te{sub 2}, which crystallizes in a rocksalt-type structure with statistical cation disorder. Display Omitted - Highlights: High-pressure synthesis yields the novel solid solution series AgIn{sub x}Sb{sub 1?x}Te{sub 2}. In contrast to AgInTe{sub 2}, the compounds are inert at ambient pressure. HRTEM shows no pronounced short-range order in the disordered NaCl-type structure. The metastable phases exhibit very low total thermal conductivities <0.5 W/K m. ZT values of 0.15 at room temperature were

  9. Semiconducting glasses: A new class of thermoelectric materials?

    SciTech Connect (OSTI)

    Goncalves, A.P.; Vaney, J.B.; Lenoir, B.; Piarristeguy, A.; Pradel, A.; Monnier, J.; Ochin, P.; Godart, C.

    2012-09-15

    The deeper understanding of the factors that affect the dimensionless figure of merit, ZT, and the use of new synthetic methods has recently led to the development of novel systems with improved thermoelectric performances. Albeit up to now with ZT values lower than the conventional bulk materials, semiconducting glasses have also emerged as a new family of potential thermoelectric materials. This paper reviews the latest advances on semiconducting glasses for thermoelectric applications. Key examples of tellurium-based glasses, with high Seebeck coefficients, very low thermal conductivities and tunable electrical conductivities, are presented. ZT values as high as 0.2 were obtained at room temperature for several tellurium-based glasses with high copper concentrations, confirming chalcogenide semiconducting glasses as good candidates for high-performance thermoelectric materials. However, the temperature stability and electrical conductivity of the reported glasses are still not good enough for practical applications and further studies are still needed to enhance them. - Graphical abstract: Power factor as a function of the temperature for the Cu{sub 27.5}Ge{sub 2.5}Te{sub 70} and Cu{sub 30}As{sub 15}Te{sub 55} seniconducting glasses. Highlights: Black-Right-Pointing-Pointer A review of semiconducting glasses for thermoelectrics applications is presented. Black-Right-Pointing-Pointer The studied semiconducting glasses present very low thermal conductivities. Black-Right-Pointing-Pointer Composition can tune electrical conductivity and Seebeck coefficient. Black-Right-Pointing-Pointer ZT=0.2 is obtained at 300 K for different semiconducting glasses.

  10. Thermal and Electrical Analysis of MARS Rover RTG, and Performance Comparison of Alternative Design Options.

    SciTech Connect (OSTI)

    Schock, Alfred; Or, Chuen T; Skrabek, Emanuel A

    1989-09-29

    The paper describes the thermal, thermoelectric and electrical analysis of Radioisotope Thermoelectric Generators (RTGs) for powering the MARS Rover vehicle, which is a critical element of the unmanned Mars Rover and Sample Return mission (MRSR). The work described was part of an RTG design study conducted by Fairchild Space Company for the U.S. Department of Energy, in support of the Jet Propulsion Laboratory's MRSR Project.; A companion paper presented at this conference described a reference mission scenario, al illustrative Rover design and activity pattern on Mars, its power system requirements and environmental constraints, a design approach enabling RTG operation in the Martian atmosphere, and the design and the structural and mass analysis of a conservative baseline RTG employing safety-qualified heat source modules and reliability-proven thermoelectric converter elements.; The present paper presents a detailed description of the baseline RTG's thermal, thermoelectric, and electrical analysis. It examines the effect of different operating conditions (beginning versus end of mission, water-cooled versus radiation-cooled, summer day versus winter night) on the RTG's performance. Finally, the paper describes and analyzes a number of alternative RTG designs, to determine the effect of different power levels (250W versus 125W), different thermoelectric element designs (standard versus short unicouples versus multicouples) and different thermoelectric figures of merit (0.00058K(superscript -1) to 0.000140K (superscript -1) on the RTG's specific power.; The results presented show the RTG performance achievable with current technology, and the performance improvements that would be achievable with various technology developments. It provides a basis for selecting the optimum strategy for meeting the Mars Rover design goals with minimal programmatic risk and cost.; There is a duplicate copy and also a duplicate copy in the ESD files.

  11. Phase Stability, Crystal Structure, and Thermoelectric Properties...

    Office of Scientific and Technical Information (OSTI)

    and Thermoelectric Properties of Cu12Sb4S13xSex Solid Solutions Citation Details In-Document Search Title: Phase Stability, Crystal Structure, and Thermoelectric Properties ...

  12. Thermoelectric Bulk Materials from the Explosive Consolidation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Bulk Materials from the Explosive Consolidation of Nanopowders Describes technique of explosively consolidating nanopowders to yield fully dense, consolidated, ...

  13. Development of Marine Thermoelectric Heat Recovery Systems

    Broader source: Energy.gov [DOE]

    Discusses benefits of integration of thermoelectrics into the marine industry, research program milestones, and prototype TEG design and integration

  14. Reliability of Transport Properties for Bulk Thermoelectrics

    Broader source: Energy.gov [DOE]

    Presents international round-robin study to ensure quality of transport data and figure of merit of thermoelectric materials

  15. Thermoelectric effects in organic conductors in a strong magnetic field

    SciTech Connect (OSTI)

    Kirichenko, O. V.; Peschanskii, V. G. Hasan, R. A.

    2007-07-15

    The linear response of the electron system of a layered conductor to the temperature gradient in this system in a strong magnetic field is investigated theoretically. Thermoelectric emf is studied as a function of the magnitude and orientation of a strong external magnetic field; the experimental investigation of this function, combined with the study of the electric and thermal resistance, allows one to completely determine the structure of the energy spectrum of charge carriers.

  16. Enhancing efficiency and power of quantum-dots resonant tunneling thermoelectrics in three-terminal geometry by cooperative effects

    SciTech Connect (OSTI)

    Jiang, Jian-Hua

    2014-11-21

    We propose a scheme of multilayer thermoelectric engine where one electric current is coupled to two temperature gradients in three-terminal geometry. This is realized by resonant tunneling through quantum dots embedded in two thermal and electrical resisting polymer matrix layers between highly conducting semiconductor layers. There are two thermoelectric effects, one of which is pertaining to inelastic transport processes (if energies of quantum dots in the two layers are different), while the other exists also for elastic transport processes. These two correspond to the transverse and longitudinal thermoelectric effects, respectively, and are associated with different temperature gradients. We show that cooperation between the two thermoelectric effects leads to markedly improved figure of merit and power factor, which is confirmed by numerical calculation using material parameters. Such enhancement is robust against phonon heat conduction and energy level broadening. Therefore, we demonstrated cooperative effect as an additional way to effectively improve performance of thermoelectrics in three-terminal geometry.

  17. Enhanced Thermoelectric Properties of Cu2ZnSnSe4 with Ga-doping

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Kaya; Beauchemin, Laura; Wang, Hsin; Porter, Wallace D.; Martin, Joshua; Nolas, George S.

    2015-08-10

    Gallium doped Cu2ZnSnSe4 quaternary chalcogenides with and without excess Cu were synthesized by elemental reaction and densified using hot pressing in order to investigate their high temperature thermoelectric properties. The resistivity, , and Seebeck coefficient, S, for these materials decrease with increased Ga-doping while both mobility and effective mass increase with Ga doping. The power factor (S2/ρ) therefore increases with Ga-doping. The highest thermoelectric figure of merit (ZT = 0.39 at 700 K) was obtained for the composition that had the lowest thermal conductivity. Our results suggest an approach to achieving optimized thermoelectric properties and are part of the continuingmore » effort to explore different quaternary chalcogenide compositions and structure types, as this class of materials continues to be of interest for thermoelectrics applications.« less

  18. An assessment of ocean thermal energy conversion as an advanced electric generation methodology

    SciTech Connect (OSTI)

    Heydt, G.T. . School of Electrical Engineering)

    1993-03-01

    Ocean thermal energy conversion (OTEC) is a process that employs the temperature difference between surface and deep ocean water to alternately evaporate and condense a working fluid. In the open-cycle OTEC configuration, the working fluid is seawater. In the closed-cycle configuration, a working fluid such as propane is used. In this paper, OTEC is assessed for its practical merits for electric power generation. The process is not new--and its history is reviewed. Because the OTEC principle operates under a small net temperature difference regime, rather large amounts of seawater and working fluid are required. The energy requirements for pumping these fluids may be greater than the energy recovered from the OTEC engine itself. The concept of net power production is discussed. The components of a typical OTEC plant are discussed with emphasis on the evaporator heat exchanger. Operation of an OTEC electric generating station is discussed, including transient operation. Perhaps the most encouraging aspect of OTEC is the recent experiments and efforts at the Natural Energy Laboratory--Hawaii (NELH). The NELH work is summarized in the paper. Remarks are made on bottlenecks and the future of OTEC as an advanced electric generation methodology.

  19. Thermoelectrics Theory and Structure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting pm013_singh_2012_o.pdf (1.45 MB) More Documents & Publications Thermoelectrics Theory and Structure Thermoelectric Materials for Automotive Applications Recent Theoretical Results for Advanced Thermoelectric Materials

  20. Thermoelectric Activities of European Community within Framework Programme

    Broader source: Energy.gov (indexed) [DOE]

    Energy Discusses engine technology enablers that help achieve overall system integration effectively deer12_suresh.pdf (986.08 KB) More Documents & Publications Cummins Next Generation Tier 2, Bin 2 Light Truck Diesel engine Cummins/DOE Light Truck Diesel Engine Progress Report Cummins' Next Generation Tier 2, Bin 2 Light Truck Diesel Engine 7 and additional activities in Germany | Department of Energy

    Provides survey of basic and applied thermoelectric activities in Germany

  1. Improved Thermoelectric Devices: Advanced Semiconductor Materials for Thermoelectric Devices

    SciTech Connect (OSTI)

    2009-12-11

    Broad Funding Opportunity Announcement Project: Phononic Devices is working to recapture waste heat and convert it into usable electric power. To do this, the company is using thermoelectric devices, which are made from advanced semiconductor materials that convert heat into electricity or actively remove heat for refrigeration and cooling purposes. Thermoelectric devices resemble computer chips, and they manage heat by manipulating the direction of electrons at the nanoscale. These devices aren’t new, but they are currently too inefficient and expensive for widespread use. Phononic Devices is using a high-performance, cost-effective thermoelectric design that will improve the device’s efficiency and enable electronics manufacturers to more easily integrate them into their products.

  2. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  3. Engineering and Materials for Automotive Thermoelectric Applications

    Office of Energy Efficiency and Renewable Energy (EERE)

    Design and optimization of TE exhaust generator, vehicle integration, and thermal management; distributed cooling and heating with TE devices; discovery and development of highly efficient TE materials.

  4. Misfit layer compounds and ferecrystals: Model systems for thermoelectric nanocomposites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Merrill, Devin R.; Moore, Daniel B.; Bauers, Sage R.; Falmbigl, Matthias; Johnson, David C.

    2015-04-22

    A basic summary of thermoelectric principles is presented in a historical context, following the evolution of the field from initial discovery to modern day high-zT materials. A specific focus is placed on nanocomposite materials as a means to solve the challenges presented by the contradictory material requirements necessary for efficient thermal energy harvest. Misfit layer compounds are highlighted as an example of a highly ordered anisotropic nanocomposite system. Their layered structure provides the opportunity to use multiple constituents for improved thermoelectric performance, through both enhanced phonon scattering at interfaces and through electronic interactions between the constituents. Recently, a class ofmore » metastable, turbostratically-disordered misfit layer compounds has been synthesized using a kinetically controlled approach with low reaction temperatures. The kinetically stabilized structures can be prepared with a variety of constituent ratios and layering schemes, providing an avenue to systematically understand structure-function relationships not possible in the thermodynamic compounds. We summarize the work that has been done to date on these materials. The observed turbostratic disorder has been shown to result in extremely low cross plane thermal conductivity and in plane thermal conductivities that are also very small, suggesting the structural motif could be attractive as thermoelectric materials if the power factor could be improved. The first 10 compounds in the [(PbSe)1+δ]m(TiSe₂)n family (m, n ≤ 3) are reported as a case study. As n increases, the magnitude of the Seebeck coefficient is significantly increased without a simultaneous decrease in the in-plane electrical conductivity, resulting in an improved thermoelectric power factor.« less

  5. Thermoelectric Properties of Indium-Filled Skutterudites

    SciTech Connect (OSTI)

    He, Tao; Chen, Jiazhong; Rosenfeld, H. David; Subramanian, M.A.

    2008-09-18

    Structural, electrical, and thermal transport properties of CoSb{sub 3} partially filled with indium are reported. Polycrystalline samples of In{sub x}Co{sub 4}Sb{sub 12} (0 {le} x {le} 0.3) were prepared by solid-state reaction under a gas mixture of 5% H{sub 2} and 95% Ar. The solubility limit of the indium filling voids in CoSb{sub 3} was found to be close to 0.22. Synchrotron X-ray diffraction refinement of the x = 0.2 sample showed that the indium is located in the classic rattler site and has a substantially larger thermal factor than those of Co and Sb. The electrical resistivity, Seebeck coefficients, and thermal conductivity of the In{sub x}Co{sub 4}Sb{sub 12} samples were measured in the temperature range of 300-600 K. All samples showed metal-like behavior, and the large negative Seebeck coefficients indicated n-type conduction. The thermal conductivity decreased with increasing temperature for all samples. A thermoelectric figure-of-merit (ZT) {ge} 1 (n-type) has been achieved when x {ge} 0.2 in In{sub x}Co{sub 4}Sb{sub 12} at 575 K.

  6. Program Final Report - Develop Thermoelectric Technology for Automotive Waste Heat Recovery

    SciTech Connect (OSTI)

    Gregory Meisner

    2011-08-31

    We conducted a vehicle analysis to assess the feasibility of thermoelectric technology for waste heat recovery and conversion to useful electrical power and found that eliminating the 500 W of electrical power generated by the alternator corresponded to about a 7% increase in fuel economy (FE) for a small car and about 6% for a full size truck. Electric power targets of 300 W were established for city and highway driving cycles for this project. We obtained critical vehicle level information for these driving cycles that enabled a high-level design and performance analysis of radiator and exhaust gas thermoelectric subsystems for several potential vehicle platforms, and we identified the location and geometric envelopes of the radiator and exhaust gas thermoelectric subsystems. Based on this analysis, we selected the Chevrolet Suburban as the most suitable demonstration vehicle for this project. Our modeling and thermal analysis assessment of a radiator-based thermoelectric generator (TEG), however, revealed severe practical limitations. Specifically the small temperature difference of 100°C or less between the engine coolant and ambient air results in a low Carnot conversion efficiency, and thermal resistance associated with air convection would reduce this conversion efficiency even further. We therefore decided not to pursue a radiator-based waste heat recovery system and focused only on the exhaust gas. Our overall approach was to combine science and engineering: (1) existing and newly developed TE materials were carefully selected and characterized by the material researcher members of our team, and most of the material property results were validated by our research partners, and (2) system engineers worked closely with vehicle engineers to ensure that accurate vehicle-level information was used for developing subsystem models and designs, and the subsystem output was analyzed for potential fuel economy gains. We incorporated material, module, subsystem, and

  7. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  8. Thermoelectric refrigerator having improved temperature stabilization means

    DOE Patents [OSTI]

    Falco, Charles M.

    1982-01-01

    A control system for thermoelectric refrigerators is disclosed. The thermoelectric refrigerator includes at least one thermoelectric element that undergoes a first order change at a predetermined critical temperature. The element functions as a thermoelectric refrigerator element above the critical temperature, but discontinuously ceases to function as a thermoelectric refrigerator element below the critical temperature. One example of such an arrangement includes thermoelectric refrigerator elements which are superconductors. The transition temperature of one of the superconductor elements is selected as the temperature control point of the refrigerator. When the refrigerator attempts to cool below the point, the metals become superconductors losing their ability to perform as a thermoelectric refrigerator. An extremely accurate, first-order control is realized.

  9. Thermoelectric generator with hinged assembly for fins

    DOE Patents [OSTI]

    Purdy, David L.; Shapiro, Zalman M.; Hursen, Thomas F.; Maurer, Gerould W.

    1976-11-02

    A cylindrical casing has a central shielded capsule of radioisotope fuel. A plurality of thermonuclear modules are axially arranged with their hot junctions resiliently pressed toward the shield and with their cold junctions adjacent a transition member having fins radiating heat to the environment. For each module, the assembly of transition member and fins is hinged to the casing for swinging to permit access to and removal of such module. A ceramic plate having gold layers on opposite faces prevents diffusion bonding of the hot junction to the shield.

  10. Advanced Thermoelectric Materials and Generator Technology for...

    Broader source: Energy.gov (indexed) [DOE]

    Overview of design, fabrication, integration, and test of working prototype TEG for engine waste heat recovery on Suburban test vehicle, and continuing investigation of ...

  11. The Industrialization of Thermoelectric Power Generation Technology |

    Broader source: Energy.gov (indexed) [DOE]

    Research and Training Reactors | Department of Energy Nuclear engineering programs and departments with an initial emphasis in fission were formed in the late 1950's and 1960's from interdisciplinary efforts in many of the top research universities, providing the manpower for this technical discipline. In the same time period, for many of these programs, university nuclear reactors were constructed and began their operation, providing some of the facilities needed for research and training

  12. Waste Heat Recovery Opportunities for Thermoelectric Generators |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Archived 02/10/16, Superseded by WPN 16-3 To provide Grantees with the 2015 Poverty Income Guidelines and Definition of Income for use in the low-income Weatherization Assistance Program (WAP). WPN 15-3: 2015 Poverty Income Guidelines and Definition of Income (293.58 KB) More Documents & Publications WPN 14-3: 2014 Poverty Income Guidance and Definition of Income WPN 12-8: 2012 Poverty Income Guidelines and Definition of Income WPN 16-3: 2016 Poverty Income

  13. High-Temperature Solar Thermoelectric Generators (STEG)

    Broader source: Energy.gov [DOE]

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  14. Potential Thermoelectric Applications in Diesel Vehicles | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Thermoelectric Applications in Diesel Vehicles Potential Thermoelectric Applications in Diesel Vehicles 2003 DEER Conference Presentation: BSST, LLC 2003_deer_crane.pdf (618.11 KB) More Documents & Publications Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Thermoelectrics: The New Green Automotive Technology Challenges and Opportunities in Thermoelectric Materials Research for Automotive Applications

  15. Progress from DOE EF RC: Solid-State Solar-Thermal Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Introduction to the solid-state solar-thermal energy conversion center plus discussion on phonon transport and solar thermoelectric energy conversion PDF icon chen.pdf More ...

  16. Measurement and simulation of thermoelectric efficiency for single leg

    SciTech Connect (OSTI)

    Hu, Xiaokai; Yamamoto, Atsushi Ohta, Michihiro; Nishiate, Hirotaka

    2015-04-15

    Thermoelectric efficiency measurements were carried out on n-type bismuth telluride legs with the hot-side temperature at 100 and 150°C. The electric power and heat flow were measured individually. Water coolant was utilized to maintain the cold-side temperature and to measure heat flow out of the cold side. Leg length and vacuum pressure were studied in terms of temperature difference across the leg, open-circuit voltage, internal resistance, and heat flow. Finite-element simulation on thermoelectric generation was performed in COMSOL Multiphysics, by inputting two-side temperatures and thermoelectric material properties. The open-circuit voltage and resistance were in good agreement between the measurement and simulation. Much larger heat flows were found in measurements, since they were comprised of conductive, convective, and radiative contributions. Parasitic heat flow was measured in the absence of bismuth telluride leg, and the conductive heat flow was then available. Finally, the maximum thermoelectric efficiency was derived in accordance with the electric power and the conductive heat flow.

  17. High Performance Bulk Thermoelectric Materials

    SciTech Connect (OSTI)

    Ren, Zhifeng

    2013-03-31

    Over 13 plus years, we have carried out research on electron pairing symmetry of superconductors, growth and their field emission property studies on carbon nanotubes and semiconducting nanowires, high performance thermoelectric materials and other interesting materials. As a result of the research, we have published 104 papers, have educated six undergraduate students, twenty graduate students, nine postdocs, nine visitors, and one technician.

  18. Coupled Thermal and Electrical Analysis of Obstructed RTGs

    SciTech Connect (OSTI)

    Schock, Alfred; Noravian, Heros; Or, Chuen T.

    1990-01-01

    A Radioisotope Thermoelectric Generator (RTG) with an unsymmetrically obstructed heat rejection path can have significant axial and circumferential variations in the temperatures, currents, and voltages of its thermoelectric couple network. The present paper describes a methodology for analyzing the thermal and electrical performance of such an RTG, and the development of a computer code for implementing that emthodology. The code derives coupled solutions of the RTG's thermal, thermoelectric, and electrical equations. It accounts for the Peltier effect, Ohmic heating, and the Thomson effect, and treats the electrical power produced in each couple as an effective heat sink. It satisfies the condition that all parallel couples produce the same voltage, and that all series-connected couple groups produce the same current. Finally, the paper illustrates the use of the code by applying it to the detailed analysis of the RTGs for the CRAF and Cassini missions. In each of these, there are two adjacent RTGs which are obstructed by each other and by the nearby spacecraft. The results of the analysis will be used by the spacecraft designers in selecting the location, orientation, and spacing of the two RTGs. There are two copies in the file.

  19. Deep levels generated by thermal oxidation in p-type 4H-SiC

    SciTech Connect (OSTI)

    Kawahara, Koutarou; Suda, Jun; Kimoto, Tsunenobu

    2013-01-21

    Thermal oxidation is an effective method to reduce deep levels, especially the Z{sub 1/2}-center (E{sub C}-0.67 eV), which strongly suppresses carrier lifetimes in n-type 4H-SiC epilayers. The oxidation, however, simultaneously generates other deep levels, HK0 (E{sub V}+0.79 eV) and HK2 (E{sub V}+0.98 eV) centers, within the lower half of the bandgap of SiC, where the HK0 center is a dominant deep level with a concentration of about 1 Multiplication-Sign 10{sup 13} cm{sup -3} after oxidation. By comparing deep levels observed in three sets of p-type 4H-SiC: oxidized, electron-irradiated, and C{sup +}- or Si{sup +}-implanted samples, we find that the HK0 and HK2 centers are complexes including carbon interstitials such as the di-carbon interstitial or di-carbon antisite. Other defects observed in p-type 4H-SiC after electron irradiation or after C{sup +}/Si{sup +} implantation are also studied.

  20. Full-scale computation for all the thermoelectric property parameters of half-Heusler compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hong, A. J.; Li, L.; He, R.; Gong, J. J.; Yan, Z. B.; Wang, K. F.; Liu, J. -M.; Ren, Z. F.

    2016-03-07

    The thermoelectric performance of materials relies substantially on the band structures that determine the electronic and phononic transports, while the transport behaviors compete and counter-act for the power factor PF and figure-of-merit ZT. These issues make a full-scale computation of the whole set of thermoelectric parameters particularly attractive, while a calculation scheme of the electronic and phononic contributions to thermal conductivity remains yet challenging. In this work, we present a full-scale computation scheme based on the first-principles calculations by choosing a set of doped half- Heusler compounds as examples for illustration. The electronic structure is computed using the WIEN2k codemore » and the carrier relaxation times for electrons and holes are calculated using the Bardeen and Shockley’s deformation potential (DP) theory. The finite-temperature electronic transport is evaluated within the framework of Boltzmann transport theory. In sequence, the density functional perturbation combined with the quasi-harmonic approximation and the Klemens’ equation is implemented for calculating the lattice thermal conductivity of carrier-doped thermoelectric materials such as Tidoped NbFeSb compounds without losing a generality. The calculated results show good agreement with experimental data. Lastly, the present methodology represents an effective and powerful approach to calculate the whole set of thermoelectric properties for thermoelectric materials.« less

  1. Inorganic-Organic Hybrid Thermoelectrics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inorganic-Organic Hybrid Thermoelectrics Inorganic-Organic Hybrid Thermoelectrics Large-scale synthesis of inorganic and organic nanomaterials (single-crystalline nanowires and ...

  2. Progress toward Development of a High-Efficiency Zonal Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    toward Development of a High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Progress toward Development of a High-Efficiency Zonal Thermoelectric HVAC ...

  3. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermoelectrics on a OTR truck PDF icon schock.pdf More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle...

  4. Innovative Nano-structuring Routes for Novel ThermoelectricMaterials...

    Broader source: Energy.gov (indexed) [DOE]

    Presents new concepts for high performance nanostructured bulk thermoelectric materials lee.pdf (1.98 MB) More Documents & Publications Thermoelectric Materials for Automotive ...

  5. An Overview of Thermoelectric Waste Heat Recovery Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An Overview of Thermoelectric Waste Heat Recovery Activities in Europe An Overview of Thermoelectric Waste Heat Recovery Activities in Europe An overview presentation of R&D ...

  6. Probing strong Kondo disorder with measurements of thermoelectric...

    Office of Scientific and Technical Information (OSTI)

    Probing strong Kondo disorder with measurements of thermoelectric power Title: Probing strong Kondo disorder with measurements of thermoelectric power Authors: White, B. D. ; ...

  7. Thermoelectrics: From Space Power Systems to Terrestrial Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat Recovery Applications Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat Recovery Applications ...

  8. Nanostructures boost the thermoelectric performance of PbS (Journal...

    Office of Scientific and Technical Information (OSTI)

    Nanostructures boost the thermoelectric performance of PbS Citation Details In-Document Search Title: Nanostructures boost the thermoelectric performance of PbS In situ ...

  9. Sandia Researchers Are First to Measure Thermoelectric Behavior...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Thermoelectric devices convert heat to electricity and have no moving parts, making them extremely attractive for cooling and energy harvesting applications. Thermoelectric ...

  10. A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel Process Employing Heterometallic Alkoxides A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel ...

  11. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Develop thermoelectric technology for waste heat recovery with a 10% fuel economy ... Engineering and Materials for Automotive Thermoelectric Applications Electrical and ...

  12. Thermoelectric FabricsŽ based on carbon nanotube composites...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Fabrics based on carbon nanotube composites Composite films of ... multiple element modules, results in thermoelectric fabrics with increased power output ...

  13. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities and Challenges of Thermoelectrlic Waste Heat Recovery in the Automotive Industry On Thermoelectric Properties of p-Type Skutterudites Development of Thermoelectric ...

  14. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MB) More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Waste Heat to Electricity ...

  15. Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Gas Heat to Power Using Thermoelectric Engines Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines Discusses a novel TEG which utilizes a proprietary stack ...

  16. Thermoelectric Conversion of Wate Heat to Electricity in an IC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wate Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Wate ... MB) More Documents & Publications Thermoelectric Conversion of Waste Heat to ...

  17. Atomic-Scale Mapping of Thermoelectric Power on Graphene: Role...

    Office of Scientific and Technical Information (OSTI)

    Mapping of Thermoelectric Power on Graphene: Role of Defects and Boundaries Citation Details In-Document Search Title: Atomic-Scale Mapping of Thermoelectric Power on ...

  18. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Improvement in an Over the Road Diesel Powered Engine System by the Application of Advanced Thermoelectric Systems Implemented in a Hybrid Configuration Thermoelectric ...

  19. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat to Electricity in an IC Engine-Powered Vehicle Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Wate

  20. Multilayer Thin-Film Thermoelectric Materials for Vehicle Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multilayer Thin-Film Thermoelectric Materials for Vehicle Applications Multilayer Thin-Film Thermoelectric Materials for Vehicle Applications 2004 Diesel Engine Emissions Reduction ...

  1. Thermoelectric Materials by Design, Computational Theory and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    by Design, Computational Theory and Structure Thermoelectric Materials by Design, Computational Theory and Structure 2009 DOE Hydrogen Program and Vehicle Technologies Program...

  2. Correlation Between Structure and Thermoelectric Properties of...

    Broader source: Energy.gov (indexed) [DOE]

    Rapid solidified precursor converted into crystalline bulks under pressure produced thermoelectric materials of nano-sized grains with strongly coupled grain boundaries, achieving ...

  3. Engineering and Materials for Automotive Thermoelectric Applications...

    Broader source: Energy.gov (indexed) [DOE]

    cooling and heating with TE devices; discovery and development of highly efficient TE materials. yang.pdf (4.47 MB) More Documents & Publications Develop Thermoelectric ...

  4. Vehicle Fuel Economy Improvement through Thermoelectric Waste...

    Broader source: Energy.gov (indexed) [DOE]

    Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deercrane.pdf (549.96 KB) More Documents & Publications Potential of Thermoelectrics forOccupant ...

  5. Connecting Thermoelectric Performance and Topological-Insulator...

    Office of Scientific and Technical Information (OSTI)

    Publisher's Accepted Manuscript: Connecting Thermoelectric Performance and Topological-Insulator Behavior: BiTe and BiTeSe from First Principles Prev Next Title: ...

  6. High-Temperature Thermoelectric Materials Characterization for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  7. Vehicular Thermoelectrics: The New Green Technology | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The New Green Technology Vehicular Thermoelectrics: The New Green Technology Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference ...

  8. Enhanced thermoelectric performance and novel nanopores in AgSbTe{sub 2} prepared by melt spinning

    SciTech Connect (OSTI)

    Du, Baoli; Li, Han; Xu, Jingjing; Tang, Xinfeng; Uher, Ctirad

    2011-01-15

    We report a melt-spinning spark-plasma-sintering synthesis process of the polycrystalline p-type material composed of AgSbTe{sub 2} coarse grains and evenly formed 5-10 nm pores that occur primarily on the surface of matrix grains. The formation mechanism of nanopores and their influences on the thermoelectric properties have been studied and correlated. Microstructure analysis shows that the as-prepared sample can be regarded as a nanocomposite of matrix and in situ generated nanopores evenly coated on matrix grains. For the single-phase component and the possible energy-filter effect caused by the nanopores, the electrical transport properties are improved. Moreover, the thermal conductivity is significantly reduced by strong phonon scattering effect resulted from the nanopores. The thermoelectric performance of the as prepared sample enhances greatly and a ZT of 1.65 at 570 K is achieved, increasing{approx}200% compared with the sample prepared by traditional melt and slow-cooling method. -- Graphical abstract: Representative nanostructure of AgSbTe{sub 2} sample (a) ribbons obtained after melt spinning (b) bulk AgSbTe{sub 2} material obtained after spark plasma sintering. Display Omitted

  9. Development and Validation of Temperature Dependent Thermal Neutron Scattering Laws for Applications and Safety Implications in Generation IV Reactor Designs

    SciTech Connect (OSTI)

    Ayman Hawari

    2008-06-20

    The overall obljectives of this project are to critically review the currently used thermal neutron scattering laws for various moderators as a function of temperature, select as well documented and representative set of experimental data sensitive to the neutron spectra to generate a data base of benchmarks, update models and models parameters by introducing new developments in thermalization theory and condensed matter physics into various computational approaches in establishing the scattering laws, benchmark the results against the experimentatl set. In the case of graphite, a validation experiment is performed by observing nutron slowing down as a function of temperatures equal to or greater than room temperature.

  10. Thermoelectric materials ternary penta telluride and selenide compounds

    DOE Patents [OSTI]

    Sharp, Jeffrey W.

    2001-01-01

    Ternary tellurium compounds and ternary selenium compounds may be used in fabricating thermoelectric devices with a thermoelectric figure of merit (ZT) of 1.5 or greater. Examples of such compounds include Tl.sub.2 SnTe.sub.5, Tl.sub.2 GeTe.sub.5, K.sub.2 SnTe.sub.5 and Rb.sub.2 SnTe.sub.5. These compounds have similar types of crystal lattice structures which include a first substructure with a (Sn, Ge) Te.sub.5 composition and a second substructure with chains of selected cation atoms. The second substructure includes selected cation atoms which interact with selected anion atoms to maintain a desired separation between the chains of the first substructure. The cation atoms which maintain the desired separation between the chains occupy relatively large electropositive sites in the resulting crystal lattice structure which results in a relatively low value for the lattice component of thermal conductivity (.kappa..sub.g). The first substructure of anion chains indicates significant anisotropy in the thermoelectric characteristics of the resulting semiconductor materials.

  11. Thermoelectric materials: ternary penta telluride and selenide compounds

    DOE Patents [OSTI]

    Sharp, Jeffrey W.

    2002-06-04

    Ternary tellurium compounds and ternary selenium compounds may be used in fabricating thermoelectric devices with a thermoelectric figure of merit (ZT) of 1.5 or greater. Examples of such compounds include Tl.sub.2 SnTe.sub.5, Tl.sub.2 GeTe.sub.5, K.sub.2 SnTe.sub.5 and Rb.sub.2 SnTe.sub.5. These compounds have similar types of crystal lattice structures which include a first substructure with a (Sn, Ge) Te.sub.5 composition and a second substructure with chains of selected cation atoms. The second substructure includes selected cation atoms which interact with selected anion atoms to maintain a desired separation between the chains of the first substructure. The cation atoms which maintain the desired separation between the chains occupy relatively large electropositive sites in the resulting crystal lattice structure which results in a relatively low value for the lattice component of thermal conductivity (.kappa..sub.g). The first substructure of anion chains indicates significant anisotropy in the thermoelectric characteristics of the resulting semiconductor materials.

  12. Generation of electrical power

    DOE Patents [OSTI]

    Hursen, Thomas F.; Kolenik, Steven A.; Purdy, David L.

    1976-01-01

    A heat-to-electricity converter is disclosed which includes a radioactive heat source and a thermoelectric element of relatively short overall length capable of delivering a low voltage of the order of a few tenths of a volt. Such a thermoelectric element operates at a higher efficiency than longer higher-voltage elements; for example, elements producing 6 volts. In the generation of required power, thermoelectric element drives a solid-state converter which is controlled by input current rather than input voltage and operates efficiently for a high signal-plus-noise to signal ratio of current. The solid-state converter has the voltage gain necessary to deliver the required voltage at the low input of the thermoelectric element.

  13. Enhanced Thermoelectric Properties of Cu2ZnSnSe4 with Ga-doping

    SciTech Connect (OSTI)

    Wei, Kaya; Beauchemin, Laura; Wang, Hsin; Porter, Wallace D.; Martin, Joshua; Nolas, George S.

    2015-08-10

    Gallium doped Cu2ZnSnSe4 quaternary chalcogenides with and without excess Cu were synthesized by elemental reaction and densified using hot pressing in order to investigate their high temperature thermoelectric properties. The resistivity, , and Seebeck coefficient, S, for these materials decrease with increased Ga-doping while both mobility and effective mass increase with Ga doping. The power factor (S2/ρ) therefore increases with Ga-doping. The highest thermoelectric figure of merit (ZT = 0.39 at 700 K) was obtained for the composition that had the lowest thermal conductivity. Our results suggest an approach to achieving optimized thermoelectric properties and are part of the continuing effort to explore different quaternary chalcogenide compositions and structure types, as this class of materials continues to be of interest for thermoelectrics applications.

  14. Potential thermoelectric performance from optimization of hole-doped Bi2Se3

    SciTech Connect (OSTI)

    Parker, David S; Singh, David J

    2011-01-01

    We present an analysis of the potential thermoelectric performance of hole-doped Bi2Se3, which is commonly considered to show inferior room temperature performance when compared to Bi2Te3. We find that if the lattice thermal conductivity can be reduced by nanostructuring techniques (as have been applied to Bi2Te3) the material may show optimized ZT values of unity or more in the 300 - 500 K temperature range and thus be suitable for cooling and moderate temperature waste heat recovery and thermoelectric solar cell applications. Central to this conclusion are the larger band gap and the relatively heavier valence bands of Bi2Se3.

  15. Development and Demonstration of an Innovative Thermal Energy Storage System for Baseload Power Generation

    SciTech Connect (OSTI)

    D. Y. Goswami

    2012-09-04

    The objective of this project is to research and develop a thermal energy storage system (operating range 3000C ???¢???????? 450 0C ) based on encapsulated phase change materials (PCM) that can meet the utility-scale base-load concentrated solar power plant requirements at much lower system costs compared to the existing thermal energy storage (TES) concepts. The major focus of this program is to develop suitable encapsulation methods for existing low-cost phase change materials that would provide a cost effective and reliable solution for thermal energy storage to be integrated in solar thermal power plants. This project proposes a TES system concept that will allow for an increase of the capacity factor of the present CSP technologies to 75% or greater and reduce the cost to less than $20/kWht.

  16. QUANTUM WELL THERMOELECTRICS FOR CONVERTING WASTE HEAT TO ELECTRICITY

    SciTech Connect (OSTI)

    Saeid Ghamaty

    2006-02-01

    New thermoelectric materials using Quantum Well (QW) technology are expected to increase the energy conversion efficiency to more than 25% from the present 5%, which will allow for the low cost conversion of waste heat into electricity. Hi-Z Technology, Inc. has been developing QW technology over the past six years. It will use Caterpillar, Inc., a leader in the manufacture of large scale industrial equipment, for verification and life testing of the QW films and modules. Other members of the team are Pacific Northwest National Laboratory, who will sputter large area QW films. The Scope of Work is to develop QW materials from their present proof-of-principle technology status to a pre-production level over a proposed three year period. This work will entail fabricating the QW films through a sputtering process of 50 {micro}m thick multi layered films and depositing them on 12 inch diameter, 5 {micro}m thick Si substrates. The goal in this project is to produce the technology for fabricating a basic 10-20 watt module that can be used to build up any size generator such as: a 5-10 kW Auxiliary Power Unit (APU), a multi kW Waste Heat Recovery Generator (WHRG) for a class 8 truck or as small as a 10-20 watt unit that would fit on a daily used wood fired stove and allow some of the estimated 2-3 billion people on earth, who have no electricity, to recharge batteries (such as a cell phone) or directly power radios, TVs, computers and other low powered devices. In this quarter Hi-Z has continued fabrication of the QW films and also continued development of joining techniques for fabricating the N and P legs into a couple. The upper operating temperature limit for these films is unknown and will be determined via the isothermal aging studies that are in progress. We are reporting on these studies in this report. The properties of the QW films that are being evaluated are Seebeck, thermal conductivity and thermal-to-electricity conversion efficiency.

  17. QUANTUM WELL THERMOELECTRICS FOR CONVERTING WASTE HEAT TO ELECTRICITY

    SciTech Connect (OSTI)

    Saeid Ghamaty

    2006-03-31

    New thermoelectric materials using Quantum Well (QW) technology are expected to increase the energy conversion efficiency to more than 25% from the present 5%, which will allow for the low cost conversion of waste heat into electricity. Hi-Z Technology, Inc. has been developing QW technology over the past six years. It will use Caterpillar, Inc., a leader in the manufacture of large scale industrial equipment, for verification and life testing of the QW films and modules. Other members of the team are Pacific Northwest National Laboratory, who will sputter large area QW films. The Scope of Work is to develop QW materials from their present proof-of-principle technology status to a pre-production level over a proposed three year period. This work will entail fabricating the QW films through a sputtering process of 50 {micro}m thick multi layered films and depositing them on 12 inch diameter, 5 {micro}m thick Si substrates. The goal in this project is to produce the technology for fabricating a basic 10-20 watt module that can be used to build up any size generator such as: a 5-10 kW Auxiliary Power Unit (APU), a multi kW Waste Heat Recovery Generator (WHRG) for a class 8 truck or as small as a 10-20 watt unit that would fit on a daily used wood fired stove and allow some of the estimated 2-3 billion people on earth, who have no electricity, to recharge batteries (such as a cell phone) or directly power radios, TVs, computers and other low powered devices. In this quarter Hi-Z has continued fabrication of the QW films and also continued development of joining techniques for fabricating the N and P legs into a couple. The upper operating temperature limit for these films is unknown and will be determined via the isothermal aging studies that are in progress. We are reporting on these studies in this report. The properties of the QW films that are being evaluated are Seebeck, thermal conductivity and thermal-to-electricity conversion efficiency.

  18. Heat reflecting tape for thermoelectric converter

    DOE Patents [OSTI]

    Purdy, David L.

    1977-01-01

    Threads are interlaced with thermoelectric wires to provide a woven cloth in tape form, there being an intermediate layer of heat radiation reflecting material (e.g., aluminum foil) insulated electrically from said wires, which are of opposite thermoelectric polarity and connected as a plurality of thermocouples.

  19. Nano-structures Thermoelectric Materals - Part 1 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Nano-structures Thermoelectric Materals - Part 1 2002 DEER Conference Presentation: RTI International 2002_deer_venkatasubramanian1.pdf (1.13 MB) More Documents & Publications Nano-structures Thermoelectric Materals - Part 2 Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI Thermoelectric Developments for Vehicular Applications

  20. Develop Thermoelectric Technology for Automotive Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE)

    Develop thermoelectric technology for waste heat recovery with a 10% fuel economy improvement without increasing emissions.

  1. Photo-controllable thermoelectric properties with reversibility and photo-thermoelectric effects of tungsten trioxide accompanied by its photochromic phenomenon

    SciTech Connect (OSTI)

    Azuma, Chiori; Kawano, Takuto; Kakemoto, Hirofumi; Irie, Hiroshi

    2014-11-07

    The addition of photo-controllable properties to tungsten trioxide (WO{sub 3}) is of interest for developing practical applications of WO{sub 3} as well as for interpreting such phenomena from scientific viewpoints. Here, a sputtered crystalline WO{sub 3} thin film generated thermoelectric power due to ultraviolet (UV) light-induced band-gap excitation and was accompanied by a photochromic reaction resulting from generating W{sup 5+} ions. The thermoelectric properties (electrical conductivity (?) and Seebeck coefficient (S)) and coloration of WO{sub 3} could be reversibly switched by alternating the external stimulus between UV light irradiation and dark storage. After irradiating the film with UV light, ? increased, whereas the absolute value of S decreased, and the photochromic (coloration) reaction was detected. Notably, the opposite behavior was exhibited by WO{sub 3} after dark storage, and this reversible cycle could be repeated at least three times. Moreover, photo-thermoelectric effects (photo-conductive effect (photo-conductivity, ?{sub photo}) and photo-Seebeck effect (photo-Seebeck coefficient, S{sub photo})) were also detected in response to visible-light irradiation of the colored WO{sub 3} thin films. Under visible-light irradiation, ?{sub photo} and the absolute value of S{sub photo} increased and decreased, respectively. These effects are likely attributable to the excitation of electrons from the mid-gap visible light absorption band (W{sup 5+} state) to the conduction band of WO{sub 3}. Our findings demonstrate that the simultaneous, reversible switching of multiple properties of WO{sub 3} thin film is achieved by the application of an external stimulus and that this material exhibits photo-thermoelectric effects when irradiated with visible-light.

  2. Large theoretical thermoelectric power factor of suspended single-layer MoS{sub 2}

    SciTech Connect (OSTI)

    Babaei, Hasan E-mail: babaei@auburn.edu; Khodadadi, J. M.; Sinha, Sanjiv

    2014-11-10

    We have calculated the semi-classical thermoelectric power factor of suspended single-layer (SL)- MoS{sub 2} utilizing electron relaxation times derived from ab initio calculations. Measurements of the thermoelectric power factor of SL-MoS{sub 2} on substrates reveal poor power factors. In contrast, we find the thermoelectric power factor of suspended SL-MoS{sub 2} to peak at ∼2.8 × 10{sup 4} μW/m K{sup 2} at 300 K, at an electron concentration of 10{sup 12} cm{sup −2}. This figure is higher than that in bulk Bi{sub 2}Te{sub 3}, for example. Given its relatively high thermal conductivity, suspended SL-MoS{sub 2} may hold promise for in-plane thin-film Peltier coolers, provided reasonable mobilities can be realized.

  3. Electrochemically deposited BiTe-based nanowires for thermoelectric applications

    SciTech Connect (OSTI)

    Ng, Inn-Khuan; Kok, Kuan-Ying; Rahman, Che Zuraini Che Ab; Saidin, Nur Ubaidah; Ilias, Suhaila Hani; Choo, Thye-Foo

    2014-02-12

    Nanostructured materials systems such as thin-films and nanowires (NWs) are promising for thermoelectric power generation and refrigeration compared to traditional counterparts in bulk, due to their enhanced thermoelectric figures-of-merit. BiTe and its derivative compounds, in particular, are well-known for their near-room temperature thermoelectric performance. In this work, both the binary and ternary BiTe-based nanowires namely, BiTe and BiSbTe, were synthesized using template-assisted electrodeposition. Diameters of the nanowires were controlled by the pore sizes of the anodised alumina (AAO) templates used. Systematic study on the compositional change as a function of applied potential was carried out via Linear Sweep Voltanmetry (LSV). Chemical compositions of the nanowires were studied using Energy Dispersive X-ray Spectrometry (EDXS) and their microstructures evaluated using diffraction and imaging techniques. Results from chemical analysis on the nanowires indicated that while the Sb content in BiSbTe nanowires increased with more negative deposition potentials, the formation of Te{sup 0} and Bi{sub 2}Te{sub 3} were favorable at more positive potentials.

  4. Tuning the thermoelectric power factor in carbon nanotube films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Tuning the thermoelectric power factor in carbon nanotube films Ben Zhou 1 , Azure Avery 2 , Andrew Ferguson 2 , Jeff Blackburn 2 Schematic of a thermoelectric device. (wikipedia) Heat Thermoelectric Device Electricity Thermoelectrics Carbon Nanotubes Introduction * Single walled carbon nanotubes (SWCNTs) are promising thermoelectrics because of their good conductivity and one dimensional density of states. Materials and Methods * Ink Preparation: (7,5) nanotubes were dispersed by

  5. Status of the Application of Thermoelectric Technology in Vehicles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Application of Thermoelectric Technology in Vehicles Status of the Application of Thermoelectric Technology in Vehicles 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: BSST LLC 2004_deer_bell.pdf (428.1 KB) More Documents & Publications Role of Thermoelectrics in Vehicle Efficiency Increase Potential Thermoelectric Applications in Diesel Vehicles Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle

  6. Development and Performance Evaluation of High Temperature Concrete for Thermal Energy Storage for Solar Power Generation

    SciTech Connect (OSTI)

    R. Panneer Selvam; Hale, Micah; Strasser, Matt

    2013-03-31

    Thermal energy can be stored by the mechanism of sensible or latent heat or heat from chemical reactions. Sensible heat is the means of storing energy by increasing the temperature of the solid or liquid. Since the concrete as media cost per kWhthermal is $1, this seems to be a very economical material to be used as a TES. This research is focused on extending the concrete TES system for higher temperatures (500 °C to 600 °C) and increasing the heat transfer performance using novel construction techniques. To store heat at high temperature special concretes are developed and tested for its performance. The storage capacity costs of the developed concrete is in the range of $0.91-$3.02/kWhthermal. Two different storage methods are investigated. In the first one heat is transported using molten slat through a stainless steel tube and heat is transported into concrete block through diffusion. The cost of the system is higher than the targeted DOE goal of $15/kWhthermal. The increase in cost of the system is due to stainless steel tube to transfer the heat from molten salt to the concrete blocks.The other method is a one-tank thermocline system in which both the hot and cold fluid occupy the same tank resulting in reduced storage tank volume. In this model, heated molten salt enters the top of the tank which contains a packed bed of quartzite rock and silica sand as the thermal energy storage (TES) medium. The single-tank storage system uses about half the salt that is required by the two-tank system for a required storage capacity. This amounts to a significant reduction in the cost of the storage system. The single tank alternative has also been proven to be cheaper than the option which uses large concrete modules with embedded heat exchangers. Using computer models optimum dimensions are determined to have an round trip efficiency of 84%. Additionally, the cost of the structured concrete thermocline configuration provides the TES

  7. Thermoelectric properties of polycrystalline In4Se3 and In4Te3

    SciTech Connect (OSTI)

    Shi, Xun; Cho, Jung Y; Salvador, James R.; Yang, Jihui; Wang, Hsin

    2010-01-01

    High thermoelectric performance of a single crystal layered compound In{sub 4}Se{sub 3} was reported recently. We present here an electrical and thermal transport property study over a wide temperature range for polycrystalline samples of In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3}. Our data demonstrate that these materials are lightly doped semiconductors, leading to large thermopower and resistivity. Very low thermal conductivity, below 1 W/m K, is observed. The power factors for In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3} are much smaller when compared with state-of-the-art thermoelectric materials. This combined with the very low thermal conductivity results in the maximum ZT value of less than 0.6 at 700 K for In{sub 4}Se{sub 3}.

  8. Diameter dependent thermoelectric properties of individual SnTe nanowires

    SciTech Connect (OSTI)

    Xu, E. Z.; Li, Z.; Martinez, J. A.; Sinitsyn, N.; Htoon, H.; Li, Nan; Swartzentruber, B.; Hollingsworth, J. A.; Wang, Jian; Zhang, S. X.

    2015-01-15

    The lead-free compound tin telluride (SnTe) has recently been suggested to be a potentially promising thermoelectric material because of its similar electronic band structure as the well-known lead telluride. Here we report on the first thermoelectric study of individual single crystalline SnTe nanowires (NWs) with different diameters ranging from ~200 to ~1000 nm. Measurements of thermopower S, electrical conductivity σ, and thermal conductivity κ were carried out on the same nanowires over a temperature range of 25 - 300 K. While σ does not show a strong diameter dependence, the thermopower increases by a factor of 2 when the nanowire diameter is decreased from 1000 nm to 200 nm. The thermal conductivities of the measured NWs are only about half of that of the bulk SnTe, which may arise from the enhanced phonon-grain boundary and phonon-defect scatterings. Temperature dependent figure-of-merit ZT was determined and the maximum value at room temperature is ~3 times higher than what was obtained in bulk samples of comparable carrier density.

  9. Diameter dependent thermoelectric properties of individual SnTe nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, E. Z.; Li, Z.; Martinez, J. A.; Sinitsyn, N.; Htoon, H.; Li, Nan; Swartzentruber, B.; Hollingsworth, J. A.; Wang, Jian; Zhang, S. X.

    2015-01-15

    The lead-free compound tin telluride (SnTe) has recently been suggested to be a potentially promising thermoelectric material because of its similar electronic band structure as the well-known lead telluride. Here we report on the first thermoelectric study of individual single crystalline SnTe nanowires (NWs) with different diameters ranging from ~200 to ~1000 nm. Measurements of thermopower S, electrical conductivity σ, and thermal conductivity κ were carried out on the same nanowires over a temperature range of 25 - 300 K. While σ does not show a strong diameter dependence, the thermopower increases by a factor of 2 when the nanowiremore » diameter is decreased from 1000 nm to 200 nm. The thermal conductivities of the measured NWs are only about half of that of the bulk SnTe, which may arise from the enhanced phonon-grain boundary and phonon-defect scatterings. Temperature dependent figure-of-merit ZT was determined and the maximum value at room temperature is ~3 times higher than what was obtained in bulk samples of comparable carrier density.« less

  10. Silicon-Based Thermoelectrics: Harvesting Low Quality Heat Using Economically Printed Flexible Nanostructured Stacked Thermoelectric Junctions

    SciTech Connect (OSTI)

    2010-03-01

    Broad Funding Opportunity Announcement Project: UIUC is experimenting with silicon-based materials to develop flexible thermoelectric devices—which convert heat into energy—that can be mass-produced at low cost. A thermoelectric device, which resembles a computer chip, creates electricity when a different temperature is applied to each of its sides. Existing commercial thermoelectric devices contain the element tellurium, which limits production levels because tellurium has become increasingly rare. UIUC is replacing this material with microscopic silicon wires that are considerably cheaper and could be equally effective. Improvements in thermoelectric device production could return enough wasted heat to add up to 23% to our current annual electricity production.

  11. Phase transition enhanced thermoelectric figure-of-merit in copper chalcogenides

    SciTech Connect (OSTI)

    Brown, David R.; Day, Tristan; Snyder, G. Jeffrey; Borup, Kasper A.; Christensen, Sebastian; Iversen, Bo B.

    2013-11-01

    While thermoelectric materials can be used for solid state cooling, waste heat recovery, and solar electricity generation, low values of the thermoelectric figure of merit, zT, have led to an efficiency too low for widespread use. Thermoelectric effects are characterized by the Seebeck coefficient or thermopower, which is related to the entropy associated with charge transport. For example, coupling spin entropy with the presence of charge carriers has enabled the enhancement of zT in cobalt oxides. We demonstrate that the coupling of a continuous phase transition to carrier transport in Cu{sub 2}Se over a broad (360–410 K) temperature range results in a dramatic peak in thermopower, an increase in phonon and electron scattering, and a corresponding doubling of zT (to 0.7 at 406 K), and a similar but larger increase over a wider temperature range in the zT of Cu{sub 1.97}Ag{sub .03}Se (almost 1.0 at 400 K). The use of structural entropy for enhanced thermopower could lead to new engineering approaches for thermoelectric materials with high zT and new green applications for thermoelectrics.

  12. Drought Risk Modeling for Thermoelectric Power Plants Siting using an Excess Over Threshold Approach

    SciTech Connect (OSTI)

    Bekera, Behailu B; Francis, Royce A; Omitaomu, Olufemi A

    2014-01-01

    Water availability is among the most important elements of thermoelectric power plant site selection and evaluation criteria. With increased variability and changes in hydrologic statistical stationarity, one concern is the increased occurrence of extreme drought events that may be attributable to climatic changes. As hydrological systems are altered, operators of thermoelectric power plants need to ensure a reliable supply of water for cooling and generation requirements. The effects of climate change are expected to influence hydrological systems at multiple scales, possibly leading to reduced efficiency of thermoelectric power plants. In this paper, we model drought characteristics from a thermoelectric systems operational and regulation perspective. A systematic approach to characterise a stream environment in relation to extreme drought occurrence, duration and deficit-volume is proposed and demonstrated. This approach can potentially enhance early stage decisions in identifying candidate sites for a thermoelectric power plant application and allow investigation and assessment of varying degrees of drought risk during more advanced stages of the siting process.

  13. High Thermoelectric Performance in Copper Telluride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Ying; Zhang, Tiansong; Shi, Xun; Wei, Su-Huai; Chen, Lidong

    2015-06-21

    Recently, Cu 2-δ S and Cu 2-δ Se were reported to have an ultralow thermal conductivity and high thermoelectric figure of merit zT. Thus, as a member of the copper chalcogenide group, Cu 2-δ Te is expected to possess superior zTs because Te is less ionic and heavy. However, the zT value is low in the Cu2Te sintered using spark plasma sintering, which is typically used to fabricate high-density bulk samples. In addition, the extra sintering processes may change the samples’ compositions as well as their physical properties, especially for Cu2Te, which has many stable and meta-stable phasesmore » as well as weaker ionic bonding between Cu and Te as compared with Cu2S and Cu2Se. In this study, high-density Cu2Te samples were obtained using direct annealing without a sintering process. In the absence of sintering processes, the samples’ compositions could be well controlled, leading to substantially reduced carrier concentrations that are close to the optimal value. The electrical transports were optimized, and the thermal conductivity was considerably reduced. The zT values were significantly improved—to 1.1 at 1000 K—which is nearly 100% improvement. Furthermore, this method saves substantial time and cost during the sample’s growth. The study demonstrates that Cu 2-δ X (X=S, Se and Te) is the only existing system to show high zTs in the series of compounds composed of three sequential primary group elements.« less

  14. High Thermoelectric Performance in Copper Telluride

    SciTech Connect (OSTI)

    He, Ying; Zhang, Tiansong; Shi, Xun; Wei, Su-Huai; Chen, Lidong

    2015-06-21

    Recently, Cu 2-δ S and Cu 2-δ Se were reported to have an ultralow thermal conductivity and high thermoelectric figure of merit zT. Thus, as a member of the copper chalcogenide group, Cu 2-δ Te is expected to possess superior zTs because Te is less ionic and heavy. However, the zT value is low in the Cu2Te sintered using spark plasma sintering, which is typically used to fabricate high-density bulk samples. In addition, the extra sintering processes may change the samples’ compositions as well as their physical properties, especially for Cu2Te, which has many stable and meta-stable phases as well as weaker ionic bonding between Cu and Te as compared with Cu2S and Cu2Se. In this study, high-density Cu2Te samples were obtained using direct annealing without a sintering process. In the absence of sintering processes, the samples’ compositions could be well controlled, leading to substantially reduced carrier concentrations that are close to the optimal value. The electrical transports were optimized, and the thermal conductivity was considerably reduced. The zT values were significantly improved—to 1.1 at 1000 K—which is nearly 100% improvement. Furthermore, this method saves substantial time and cost during the sample’s growth. The study demonstrates that Cu 2-δ X (X=S, Se and Te) is the only existing system to show high zTs in the series of compounds composed of three sequential primary group elements.

  15. Publications | Solid State Solar Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Publications Publications supported by S3TEC: 339 Yang, J.; Xi, L.; Qiu, W.; Wu, L.; Shi, X.; Chen, L.; Yang, J.; Zhang, W.; Uher, C.; Singh, D.J., On the tuning of electrical and thermal transport in thermoelectrics: an integrated theory-experiment perspective, Npj Computational Materials, 2, (2016). [DOI: ] 338 Sun, J.; Singh, D.J., Thermoelectric Properties of {\$}{\{}{$\backslash$}mathrm{\{}Mg{\}}{\}}{\_}{\{}2{\}}({$\backslash$}mathrm{\{}Ge{\}},{$\backslash$}mathrm{\{}Sn{\}}){\$}: Model and

  16. High-temperature charge and thermal transport properties of the...

    Office of Scientific and Technical Information (OSTI)

    transport properties of the n -type thermoelectric material PbSe Citation Details In-Document Search Title: High-temperature charge and thermal transport properties of the n ...

  17. Thermoelectric properties of IV–VI-based heterostructures and superlattices

    SciTech Connect (OSTI)

    Borges, P.D.; Petersen, J.E.; Scolfaro, L.; Leite Alves, H.W.; Myers, T.H.

    2015-07-15

    Doping in a manner that introduces anisotropy in order to reduce thermal conductivity is a significant focus in thermoelectric research today. By solving the semiclassical Boltzmann transport equations in the constant scattering time (τ) approximation, in conjunction with ab initio electronic structure calculations, within Density Functional Theory, we compare the Seebeck coefficient (S) and figure of merit (ZT) of bulk PbTe to PbTe/SnTe/PbTe heterostructures and PbTe doping superlattices (SLs) with periodically doped planes. Bismuth and Thallium were used as the n- and p-type impurities, respectively. The effects of carrier concentration are considered via chemical potential variation in a rigid band approximation. The impurity bands near the Fermi level in the electronic structure of PbTe SLs are of Tl s- and Bi p-character, and this feature is independent of the doping concentration or the distance between impurity planes. We observe the impurity bands to have a metallic nature in the directions perpendicular to the doping planes, yet no improvement on the values of ZT is found when compared to bulk PbTe. For the PbTe/SnTe/PbTe heterostructures, the calculated S presents good agreement with recent experimental data, and an anisotropic behavior is observed for low carrier concentrations (n<10{sup 18} cm{sup −3}). A large value of ZT{sub ||} (parallel to the growth direction) of 3.0 is predicted for n=4.7×10{sup 18} cm{sup −3} and T=700 K, whereas ZT{sub p} (perpendicular to the growth direction) is found to peak at 1.5 for n=1.7×10{sup 17} cm{sup −3}. Both electrical conductivity enhancement and thermal conductivity reduction are analyzed. - Graphical abstract: Figure of merit for PbTe/SnTe/PbTe heterostructure along the [0 0 1] direction, P.D. Borges, J.E. Petersen, L. Scolfaro, H.W. Leite Alves, T.H. Myers, Improved thermoelectric properties of IV–VI-based heterostructures and superlattices. - Highlights: • Thermoelectric properties of IV

  18. Methods for synthesis of semiconductor nanocrystals and thermoelectric compositions

    DOE Patents [OSTI]

    Ren, Zhifeng; Chen, Gang; Poudel, Bed; Kumar, Shankar; Wang, Wenzhong; Dresselhaus, Mildred

    2007-08-14

    The present invention provides methods for synthesis of IV VI nanostructures, and thermoelectric compositions formed of such structures. In one aspect, the method includes forming a solution of a Group IV reagent, a Group VI reagent and a surfactant. A reducing agent can be added to the solution, and the resultant solution can be maintained at an elevated temperature, e.g., in a range of about 20.degree. C. to about 360.degree. C., for a duration sufficient for generating nanoparticles as binary alloys of the IV VI elements.

  19. ARCADIA{sup R} - A New Generation of Coupled Neutronics / Core Thermal- Hydraulics Code System at AREVA NP

    SciTech Connect (OSTI)

    Curca-Tivig, Florin; Merk, Stephan; Pautz, Andreas; Thareau, Sebastien

    2007-07-01

    Anticipating future needs of our customers and willing to concentrate synergies and competences existing in the company for the benefit of our customers, AREVA NP decided in 2002 to develop the next generation of coupled neutronics/ core thermal-hydraulic (TH) code systems for fuel assembly and core design calculations for both, PWR and BWR applications. The global CONVERGENCE project was born: after a feasibility study of one year (2002) and a conceptual phase of another year (2003), development was started at the beginning of 2004. The present paper introduces the CONVERGENCE project, presents the main feature of the new code system ARCADIA{sup R} and concludes on customer benefits. ARCADIA{sup R} is designed to meet AREVA NP market and customers' requirements worldwide. Besides state-of-the-art physical modeling, numerical performance and industrial functionality, the ARCADIA{sup R} system is featuring state-of-the-art software engineering. The new code system will bring a series of benefits for our customers: e.g. improved accuracy for heterogeneous cores (MOX/ UOX, Gd...), better description of nuclide chains, and access to local neutronics/ thermal-hydraulics and possibly thermal-mechanical information (3D pin by pin full core modeling). ARCADIA is a registered trademark of AREVA NP. (authors)

  20. Core thermal response and hydrogen generation of the N Reactor hydrogen mitigation design basis accident

    SciTech Connect (OSTI)

    White, M.D.; Lombardo, N.J.; Heard, F.J.; Ogden, D.M.; Quapp, W.J.

    1988-04-01

    Calculations were performed to determine core heatup, core damage, and subsequent hydrogen production of a hypothetical loss-of-cooling accident at the Department of Energy's N Reactor. The thermal transient response of the reactor core was solved using the TRUMP-BD computer program. Estimates of whole-core thermal damage and hydrogen production were made by weighting the results of multiple half-length pressure tube simulations at various power levels. The Baker-Just and Wilson parabolic rate equations for the metal-water chemical reactions modeled the key phenomena of chemical energy and hydrogen evolution. Unlimited steam was assumed available for continuous oxidation of exposed Zircaloy-2 surfaces and for uranium metal with fuel cladding beyond the failure temperature (1038 C). Intact fuel geometry was modeled. Maximum fuel temperatures (1181 C) in the cooled central regions of the core were predicted to occur one-half hour into the accident scenario. Maximum fuel temperatures of 1447 C occurred in the core GSCS-regions at the end of the 10-h transient. After 10-h 26% of the fuel inventory was predicted to have failed. Peak hydrogen evolution equaled 42 g/s, while 10-h integrated hydrogen evolution equaled 167 kg. 12 refs., 12 figs., 2 tabs.

  1. Innovative Application of Maintenance-Free Phase-Change Thermal Energy Storage for Dish-Engine Solar Power Generation

    SciTech Connect (OSTI)

    Qui, Songgang; Galbraith, Ross

    2013-01-23

    This final report summarizes the final results of the Phase II Innovative Application of Maintenance-Free Phase-Change Thermal Energy Storage for Dish-Engine Solar Power Generation project being performed by Infinia Corporation for the U.S. Department of Energy under contract DE-FC36-08GO18157 during the project period of September 1, 2009 - August 30, 2012. The primary objective of this project is to demonstrate the practicality of integrating thermal energy storage (TES) modules, using a suitable thermal salt phase-change material (PCM) as its medium, with a dish/Stirling engine; enabling the system to operate during cloud transients and to provide dispatchable power for 4 to 6 hours after sunset. A laboratory prototype designed to provide 3 kW-h of net electrical output was constructed and tested at Infinia's Ogden Headquarters. In the course of the testing, it was determined that the system's heat pipe network - used to transfer incoming heat from the solar receiver to both the Stirling generator heater head and to the phase change salt - did not perform to expectations. The heat pipes had limited capacity to deliver sufficient heat energy to the generator and salt mass while in a charging mode, which was highly dependent on the orientation of the device (vertical versus horizontal). In addition, the TES system was only able to extract about 30 to 40% of the expected amount of energy from the phase change salt once it was fully molten. However, the use of heat pipes to transfer heat energy to and from a thermal energy storage medium is a key technical innovation, and the project team feels that the limitations of the current device could be greatly improved with further development. A detailed study of manufacturing costs using the prototype TES module as a basis indicates that meeting DOE LCOE goals with this hardware requires significant efforts. Improvement can be made by implementing aggressive cost-down initiatives in design and materials, improving system

  2. Challenges and Opportunities in Thermoelectric Energy Conversion |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Conversion Challenges and Opportunities in Thermoelectric Energy Conversion 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Lawrence Berkeley Laboratory 2004_deer_majumdar.pdf (1.3 MB) More Documents & Publications High performance Zintl phase TE materials with embedded nanoparticles High performance Zintl phase TE materials with embedded nanoparticles Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI

  3. Thermoelectric materials and methods for synthesis thereof

    DOE Patents [OSTI]

    Ren, Zhifeng; Zhang, Qinyong; Zhang, Qian; Chen, Gang

    2015-08-04

    Materials having improved thermoelectric properties are disclosed. In some embodiments, lead telluride/selenide based materials with improved figure of merit and mechanical properties are disclosed. In some embodiments, the lead telluride/selenide based materials of the present disclosure are p-type thermoelectric materials formed by adding sodium (Na), silicon (Si) or both to thallium doped lead telluride materials. In some embodiments, the lead telluride/selenide based materials are formed by doping lead telluride/selenides with potassium.

  4. Thermoelectric Alloys and Devices for Radioisotope Space Power Systems: State of the Art and Current Developments

    SciTech Connect (OSTI)

    Barnett, W.; Dick, P.; Beaudry, B.; Gorsuch, P.; Skrabek, E.

    1989-01-01

    Lead telluride and silicon germanium type alloys have served over the past several decades as the preferred thermoelectric conversion materials for U. S. radioisotope thermoelectric generator (RTG) power systems for planetary deep space exploration missions. The Pioneer missions to Jupiter and Jupiter/Saturn and the Viking Mars Lander missions employed TAGS-2N (lead and germanium telluride derivatives) power conversion devices. Since 1976, silicon germanium (SiGe) alloys, incorporated into the unicouple device, have evolved as the thermoelectric materials of choice for U. S. RTG powered space missions. These include the U. S. Air Force Lincoln Experimental Satellites 8 & 9 for communications, in 1976, followed in 1977 by the National Aeronautics and Space Administration Voyager 1 and 2 planetary missions. In 1989, advanced SiGe RTGs were used to power the Galileo exploration of Jupiter and, in 1990, will be used to power the Ulysses investigation of the Sun. In addition, SiGe technology has been chosen to provide RTG power for the 1995 Comet Rendezvous and Asteroid Flyby mission and the 1996 Cassini Saturn orbiter mission. Summaries of the flight performance data for these systems are presented.; Current U. S. Department of Energy thermoelectric development activities include (1) the development of conversion devices based on hi-density, close packed couple arrays and (2) the development of improved performance silicon germanium type thermoelectric materials. The silicon germanium type "multicouple", being developed in conjunction with the Modular RTG program, is discussed in a companion paper. A lead telluride type close-packed module, discussed herein, offers the promise of withstanding high velocity impacts and, thus, is a candidate for a Mars Penetrator application.; Recent projects sponsored by the U. S. Department of Energy, including the Improved Thermoelectric Materials and Modular Radioisotope Thermoelectric Generator programs, have shown that improvements

  5. Electronic structure, transport, and phonons of SrAgChF (Ch = S,Se,Te): Bulk superlattice thermoelectrics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gudelli, Vijay Kumar; Kanchana, V.; Vaitheeswaran, G.; Singh, David J.; Svane, Axel; Christensen, Niels Egede; Mahanti, Subhendra D.

    2015-07-15

    Here, we report calculations of the electronic structure, vibrational properties, and transport for the p-type semiconductors, SrAgChF (Ch = S, Se, and Te). We find soft phonons with low frequency optical branches intersecting the acoustic modes below 50 cm–1, indicative of a material with low thermal conductivity. The bands at and near the valence-band maxima are highly two-dimensional, which leads to high thermopowers even at high carrier concentrations, which is a combination that suggests good thermoelectric performance. These materials may be regarded as bulk realizations of superlattice thermoelectrics.

  6. Next-generation purex flowsheets with acetohydroxamic acid as complexant for FBR and thermal-fuel reprocessing

    SciTech Connect (OSTI)

    Kumar, Shekhar; Koganti, S.B.

    2008-07-01

    Acetohydroxamic acid (AHA) is a novel complexant for recycle of nuclear-fuel materials. It can be used in ordinary centrifugal extractors, eliminating the need for electro-redox equipment or complex maintenance requirements in a remotely maintained hot cell. In this work, the effect of AHA on Pu(IV) distribution ratios in 30% TBP system was quantified, modeled, and integrated in SIMPSEX code. Two sets of batch experiments involving macro Pu concentrations (conducted at IGCAR) and one high-Pu flowsheet (literature) were simulated for AHA based U-Pu separation. Based on the simulation and validation results, AHA based next-generation reprocessing flowsheets are proposed for co-processing based FBR and thermal-fuel reprocessing as well as evaporator-less macro-level Pu concentration process required for MOX fuel fabrication. Utilization of AHA results in significant simplification in plant design and simpler technology implementations with significant cost savings. (authors)

  7. Nano-structures Thermoelectric Materals - Part 2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Nano-structures Thermoelectric Materals - Part 2 2002 DEER Conference Presentation: RTI International 2002_deer_venkatasubramanian2.pdf (3.14 MB) More Documents & Publications Nano-structures Thermoelectric Materals - Part 1 Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI The 60% Efficient Diesel Engine: Probably, Possible, Or Just a Fantasy?

  8. Thermoelectric Materials for Automotive Applications | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Discusses the background information on what makes a good thermoelectric material, then the findings of three recent ORNL field report studies focused at PbSe, Bi2Se3, CrSi2, respectively parker.pdf (1.4 MB) More Documents & Publications Thermoelectrics Theory and Structure Thermoelectrics Theory and Structure

  9. Thermoelectric Opportunities in Light-Duty Vehicles | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    thermoelectric (TE) vehicle exhaust heat recovery, TE HVAC systems, and OEM role in establishing guidelines for cost, power density, systems integration, and durability. maranville.pdf (480.27 KB) More Documents & Publications Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: A New Green Technology Cost Effectiveness of Technology Solutions for Future Vehicle Systems

  10. Enhanced thermoelectric power and electronic correlations in RuSe₂

    SciTech Connect (OSTI)

    Wang, Kefeng; Wang, Aifeng; Tomic, A.; Wang, Limin; Abeykoon, A. M. Milinda; Dooryhee, E.; Billinge, S. J.L.; Petrovic, C.

    2015-03-03

    We report the electronic structure, electric and thermal transport properties of Ru₁₋xIrxSe₂ (x ≤ 0.2). RuSe₂ is a semiconductor that crystallizes in a cubic pyrite unit cell. The Seebeck coefficient of RuSe₂ exceeds -200 µV/K around 730 K. Ir substitution results in the suppression of the resistivity and the Seebeck coefficient, suggesting the removal of the peaks in density of states near the Fermi level. Ru₀.₈Ir₀.₂Se₂ shows a semiconductor-metal crossover at about 30 K. The magnetic field restores the semiconducting behavior. Our results indicate the importance of the electronic correlations in enhanced thermoelectricity of RuSb₂.

  11. Enhanced thermoelectric power and electronic correlations in RuSe₂

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Kefeng; Wang, Aifeng; Tomic, A.; Wang, Limin; Abeykoon, A. M. Milinda; Dooryhee, E.; Billinge, S. J.L.; Petrovic, C.

    2015-03-03

    We report the electronic structure, electric and thermal transport properties of Ru₁₋xIrxSe₂ (x ≤ 0.2). RuSe₂ is a semiconductor that crystallizes in a cubic pyrite unit cell. The Seebeck coefficient of RuSe₂ exceeds -200 µV/K around 730 K. Ir substitution results in the suppression of the resistivity and the Seebeck coefficient, suggesting the removal of the peaks in density of states near the Fermi level. Ru₀.₈Ir₀.₂Se₂ shows a semiconductor-metal crossover at about 30 K. The magnetic field restores the semiconducting behavior. Our results indicate the importance of the electronic correlations in enhanced thermoelectricity of RuSb₂.

  12. Feasibility of Thermoelectrics for Waste Heat Recovery in Conventional Vehicles

    SciTech Connect (OSTI)

    Smith, K.; Thornton, M.

    2009-04-01

    Thermoelectric (TE) generators convert heat directly into electricity when a temperature gradient is applied across junctions of two dissimilar metals. The devices could increase the fuel economy of conventional vehicles by recapturing part of the waste heat from engine exhaust and generating electricity to power accessory loads. A simple vehicle and engine waste heat model showed that a Class 8 truck presents the least challenging requirements for TE system efficiency, mass, and cost; these trucks have a fairly high amount of exhaust waste heat, have low mass sensitivity, and travel many miles per year. These factors help maximize fuel savings and economic benefits. A driving/duty cycle analysis shows strong sensitivity of waste heat, and thus TE system electrical output, to vehicle speed and driving cycle. With a typical alternator, a TE system could allow electrification of 8%-15% of a Class 8 truck's accessories for 2%-3% fuel savings. More research should reduce system cost and improve economics.

  13. Alkaline earth filled nickel skutterudite antimonide thermoelectrics

    DOE Patents [OSTI]

    Singh, David Joseph

    2013-07-16

    A thermoelectric material including a body centered cubic filled skutterudite having the formula A.sub.xFe.sub.yNi.sub.zSb.sub.12, where A is an alkaline earth element, x is no more than approximately 1.0, and the sum of y and z is approximately equal to 4.0. The alkaline earth element includes guest atoms selected from the group consisting of Be, Mb, Ca, Sr, Ba, Ra and combinations thereof. The filled skutterudite is shown to have properties suitable for a wide variety of thermoelectric applications.

  14. New Perspectives in Thermoelectric Energy Recovery System Design Optimization

    SciTech Connect (OSTI)

    Hendricks, Terry J.; Karri, Naveen K.; Hogan, Tim; Cauchy, Charles J.

    2013-02-12

    Abstract: Large amounts of waste heat are generated worldwide in industrial processes, automotive transportation, diesel engine exhaust, military generators, and incinerators because 60-70% of the fuel energy is typically lost in these processes. There is a strong need to develop technologies that recover this waste heat to increase fuel efficiency and minimize fuel requirements in these industrial processes, automotive and heavy vehicle engines, diesel generators, and incinerators. There are additional requirements to reduce CO2 production and environmental footprints in many of these applications. Recent work with the Strategic Environmental Research and Development Program office has investigated new thermoelectric (TE) materials and systems that can operate at higher performance levels and show a viable pathway to lightweight, small form-factor, advanced thermoelectric generator (TEG) systems to recover waste heat in many of these applications. New TE materials include nano-composite materials such as lead-antimony-silver-telluride (LAST) and lead-antimony-silver-tin-telluride (LASTT) compounds. These new materials have created opportunities for high-performance, segmented-element TE devices. New higher-performance TE devices segmenting LAST/LASTT materials with bismuth telluride have been designed and fabricated. Sectioned TEG systems using these new TE devices and materials have been designed. Integrated heat exchanger/TE device system analyses of sectioned TE system designs have been performed creating unique efficiency-power maps that provide better understandings and comparisons of design tradeoffs and nominal and off-nominal system performance conditions. New design perspectives in optimization of sectioned TE design approaches are discussed that provide insight on how to optimize such sectioned TE systems. System performance analyses using ANSYS TE modeling capabilities have integrated heat exchanger performance models with ANSYS TE models to extend

  15. Influence of rare earth doping on thermoelectric properties of SrTiO{sub 3} ceramics

    SciTech Connect (OSTI)

    Liu, J. Wang, C. L.; Li, Y.; Su, W. B.; Zhu, Y. H.; Li, J. C.; Mei, L. M.

    2013-12-14

    Thermoelectric properties of SrTiO{sub 3} ceramics, doped with different rare earth elements, were investigated in this work. It's found that the ionic radius of doping elements plays an important role on thermoelectric properties: SrTiO{sub 3} ceramics doped with large rare earth ions (such as La, Nd, and Sm) exhibit large power factors, and those doped with small ions (such as Gd, Dy, Er, and Y) exhibit low thermal conductivities. Therefore, a simple approach for enhancing the thermoelectric performance of SrTiO{sub 3} ceramics is proposed: mainly doped with large ions to obtain a large power factor and, simultaneously, slightly co-doped with small ions to obtain a low thermal conductivity. Based on this rule, Sr{sub 0.8}La{sub 0.18}Yb{sub 0.02}TiO{sub 3} ceramics were prepared, whose ZT value at 1 023 K reaches 0.31, increasing by a factor of 19% compared with the single-doped counterpart Sr{sub 0.8}La{sub 0.2}TiO{sub 3} (ZT = 0.26)

  16. Thermoelectric devices and applications for the same

    DOE Patents [OSTI]

    Olsen, Larry C.; DeSteese, John G.; Martin, Peter M.; Johnston, John W.; Peters, Timothy J.

    2016-03-08

    High performance thin film thermoelectric couples and methods of making the same are disclosed. Such couples allow fabrication of at least microwatt to watt-level power supply devices operating at voltages greater than one volt even when activated by only small temperature differences.

  17. Thermoelectric devices and applications for the same

    DOE Patents [OSTI]

    DeSteese, John G [Kennewick, WA; Olsen, Larry C [Richland, WA; Martin, Peter M [Kennewick, WA

    2010-12-14

    High performance thin film thermoelectric couples and methods of making the same are disclosed. Such couples allow fabrication of at least microwatt to watt-level power supply devices operating at voltages greater than one volt even when activated by only small temperature differences.

  18. High ZT bismuth-doped perovskite thermoelectrics

    DOE Patents [OSTI]

    Brown-Shaklee, Harlan James

    2016-02-23

    A bismuth-doped perovskite thermoelectric, comprising (Bi.sub.x, La.sub.0.1-x)SrTiO.sub.3, wherein x is between 0.01 and 0.1, can have a high figure-of-merit, ZT.

  19. Science Highlights- Center for Solar and Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 - Abstracts and Highlight Slides Energy Level Modulation in Conjugated Polymers for Organic Photovoltaic Applications Aligning Carbon Nanotubes (CNTs) Using Ultrafast Laser Irradiation Disordered Interfaces Improve Organic Photovoltaics New Way of Reducing Thermal Conductivity in Thermoelectric Materials Phase-field Simulations of GaN/InGaN Quantum Dot Growth by Selective Area Epitaxy High Performance Thermoelectricity in Earth-Abundant Compounds Based on Natural Mineral Tetrahedrites Effect

  20. Thermoelectric Properties of Au- Containing Type-I Clathrates Ba8AuxGa16-3xGe30+2x

    SciTech Connect (OSTI)

    Ye, Zuxin; Cho, Jung Young; Tessema, Misle M.; Salvador, James R.; Waldo, Richard A.; Yang, Jihui; Wang, Hsin; Cai, Wei; Kirkham, Melanie J; Yang, Jiong; Zhang, Wenqing

    2014-01-01

    Type I clathrates, with compositions based on Ba8Ga16Ge30, are a class of promising thermoelectric materials due to their intrinsically low thermal conductivity. It has been demonstrated previously that the thermoelectric performance can be improved by transition metal substitution of the framework atoms. In this study, the effects of Au substitution for Ga/Ge on thermal and electrical transport properties of type I clathrate compounds have been investigated. Polycrystalline samples with a large range of Au content have been synthesized using conventional solid state techniques with the actual compositions of resulting materials approximately following Zintl-Klemm rules. The charge carrier type changes from electrons (n) to holes (p) as the Au content increases. The Seebeck coefficient (S) and power factor (S2/ where is the electrical resistivity) were improved by Au substitution and the resulting overall thermoelectric properties were enhanced by Au substitution with a thermoelectric figure of merit ZT ~ 0.63 at temperature T = 740 K for the composition Ba8Au5.47Ge39.96. The results presented herein show that Au-containing type I clathrates are promising p-type thermoelectric materials for high temperature applications.

  1. Performance, Market and Manufacturing Constraints relevant to the Industrialization of Thermoelectric Devices

    Office of Energy Efficiency and Renewable Energy (EERE)

    Market pricing of thermoelectric raw materials and processing, cost of manufacture of devices and systems constraints on the viability of a mass market thermoelectric product are discussed

  2. Thermoelectric-Enhanced Cookstove Add-on (TECA) for Clean Biomass...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (BETO) 2015 Project Peer Review Thermoelectric-Enhanced Cookstove Add-on (TECA) for ... performance through the use of RTI's Thermoelectric Enhanced Cookstove Add-on (TECA) ...

  3. Next Generation Nuclear Plant Phenomena Identification and Ranking Tables (PIRTs) Volume 2: Accident and Thermal Fluids Analysis PIRTs

    SciTech Connect (OSTI)

    Ball, Sydney J; Corradini, M.; Fisher, Stephen Eugene; Gauntt, R.; Geffraye, G.; Gehin, Jess C; Hassan, Y.; Moses, David Lewis; Renier, John-Paul; Schultz, R.; Wei, T.

    2008-03-01

    An accident, thermal fluids, and reactor physics phenomena identification and ranking process was conducted by a panel of experts on the next generation nuclear plant (NGNP) design (consideration given to both pebble-bed and prismatic gas-cooled reactor configurations). Safety-relevant phenomena, importance, and knowledge base were assessed for the following event classes: (1) normal operation (including some reactor physics aspects), (2) general loss of forced circulation (G-LOFC), (3) pressurized loss-of-forced circulation (P-LOFC), (4) depressurized loss-of-forced circulation (D-LOFC), (5) air ingress (following D-LOFC), (6) reactivity transients - including anticipated transients without scram (ATWS), (7) processes coupled via intermediate heat exchanger (IHX) (IHX failure with molten salt), and (8) steam/water ingress. The panel's judgment of the importance ranking of a given phenomenon (or process) was based on the effect it had on one or more figures of merit or evaluation criteria. These included public and worker dose, fuel failure, and primary (and other safety) system integrity. The major phenomena of concern that were identified and categorized as high importance combined with medium to low knowledge follow: (1) core coolant bypass flows (normal operation), (2) power/flux profiles (normal operation), (3) outlet plenum flows (normal operation), (4) reactivity-temperature feedback coefficients for high-plutonium-content cores (normal operation and accidents), (5) fission product release related to the transport of silver (normal operation), (6)emissivity aspects for the vessel and reactor cavity cooling system (G-LOFC), (7) reactor vessel cavity air circulation and heat transfer (G-LOFC), and (8)convection/radiation heating of upper vessel area (P-LOFC).

  4. Thermoelectric Bulk Materials from the Explosive Consolidation of

    Broader source: Energy.gov (indexed) [DOE]

    Nanopowders | Department of Energy Describes technique of explosively consolidating nanopowders to yield fully dense, consolidated, nanostructured thermoelectric material nemir.pdf (3.11 MB) More Documents & Publications The Bottom-Up Approach forThermoelectric Nanocomposites, plusƒ Enhancing the Figure-of-Merit in Half-Heuslers for Vehicle Waste Heat Recovery Correlation Between Structure and Thermoelectric Properties of Bulk High Performance Materials for Energy Conversion

  5. Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_crane.pdf (549.96 KB) More Documents & Publications Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle Applications Automotive Waste Heat Conversion to Electric Power using Skutterudites, TAGS,

  6. Materials, Modules, and Systems: An Atoms to Autos Approach to...

    Broader source: Energy.gov (indexed) [DOE]

    Thermoelectric Materials Evaluation of Thermal to Electrical Energy Conversion of High ... Modules Proactive Strategies for Designing Thermoelectric Materials for Power Generation

  7. BTO Partners Develop Novel, Energy-efficient Thermoelectric Clothes...

    Energy Savers [EERE]

    The cooled air is then heated by passing over the hot side of the thermoelectric modules ... Design Competition Small Businesses Receive 2 Million to Advance HVAC Technologies

  8. Design of Bulk Nanocomposites as High Efficiency Thermoelectric...

    Office of Science (SC) Website

    Design of Bulk Nanocomposites as High Efficiency Thermoelectric Materials Energy Frontier ... News & Events Publications History Contact BES Home 04.27.12 Design of Bulk Nanocomposites ...

  9. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Evaluation PDF icon ace049schock2011o.pdf More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle...

  10. DOE/NSF Thermoelectric Partnership Project SEEBECK Saving Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    research and sharing Knowledge DOENSF Thermoelectric Partnership Project SEEBECK Saving Energy Effectively By Engaging in Collaborative research and sharing Knowledge 2011 DOE ...

  11. DOE/NSF Thermoelectric Partnership Project SEEBECK Saving Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research and Sharing Knowledge DOENSF Thermoelectric Partnership Project SEEBECK Saving Energy Effectively By Engaging in Collaborative Research and Sharing Knowledge 2012 DOE ...

  12. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Describes TEG systems built at MSU to mitigate couple failures and a cost-benefit analysis ... More Documents & Publications Thermoelectric Conversion of Wate Heat to Electricity in an ...

  13. Characterization of thermoelectric elements and devices by impedance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    describes a new measurement technique that utilizes impedance spectroscopy for the characterization of thermoelectric materials and devices. Two circuit models were...

  14. Thermoelectric Properties of Rare-Earth-Ruthenium-Germanium Compounds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cobalt substitution for ruthenium enhances the semiconductor character but does not improve the thermoelectric properties. URL: Link to article - Journal of Applied Physics...

  15. Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI

    Broader source: Energy.gov [DOE]

    Reviews work in engineered thin-film nanoscale thermoelectric materials and nano-bulk materials with high ZT undertaken by RTI in collaboration with its research partners

  16. Development of a High-Efficiency Zonal Thermoelectric HVAC System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Improving Energy Efficiency by Developing Components for Distributed Cooling and Heating Based on ...

  17. Development of a Thermoelectric Device for an Automotive Zonal...

    Broader source: Energy.gov (indexed) [DOE]

    thermoelectric device using liquid working fluid on the waste side and air as working fluid on the main side to enable zonal or distributed heatingcooling systems within ...

  18. Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines

    Office of Energy Efficiency and Renewable Energy (EERE)

    Discusses a novel TEG which utilizes a proprietary stack designed thermoelectric engine to achieve high power density and reduced system weight and volume

  19. High Heat Flux Thermoelectric Module Using Standard Bulk Material

    Broader source: Energy.gov [DOE]

    Presents high heat flux thermoelectric module design for cooling using a novel V-shaped shunt configuration with bulk TE elements achieving high area packing fractions

  20. Thermoelectric Waste Heat Recovery Program for Passenger Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat Recovery Program for Passenger Vehicles Thermoelectric Waste Heat Recovery Program for Passenger Vehicles 2012 DOE Hydrogen and Fuel Cells Program and Vehicle ...

  1. Enhancement of automotive exhaust heat recovery by thermoelectric...

    Office of Scientific and Technical Information (OSTI)

    exists between the gas and solid surface temperature due ... practice in thermoelectric waste energy harvesting ... Energy Conversion and Management; Journal Volume: 224; ...

  2. Strategies for High Thermoelectric zT in Bulk Materials

    Office of Energy Efficiency and Renewable Energy (EERE)

    Zintl principle in chemistry, complex electronic band structures, and incorporation of nanometer sized particles were used to explore, optimize and improve bulk thermoelectric materials

  3. Sandia Energy - The Quest for Efficiency in Thermoelectric Nanowires

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency in Thermoelectric Nanowires Sandia researchers say better materials and manufacturing techniques for nanowires could allow car makers to harvest power from the heat...

  4. Automotive Thermoelectric Moduleswith Scalable Thermo- andElectro...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Moduleswith Scalable Thermo- and Electro-Mechanical Interfaces Automotive Thermoelectric Moduleswith Scalable Thermo- and Electro-Mechanical Interfaces Interface materials based on ...

  5. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Broader source: Energy.gov (indexed) [DOE]

    Energy Conversion for Efficient Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery ...

  6. Turbine Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbine Thermal Management Fact Sheets Research Team Members Key Contacts Turbine Thermal Management The gas turbine is the workhorse of power generation, and technology advances ...

  7. thermo-electric power conversion technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thermo-electric power conversion technology - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management

  8. Thermal, thermoelectric, and cathode poisoning effects in cold fusion experiments

    SciTech Connect (OSTI)

    Keesing, R.G.; Greenhow, R.C.; Cohler, M.D. ); McQuillan, A.J. )

    1991-03-01

    This paper reports on an unsuccessful attempt to repeat the observations by Fleischmann and Pons of cold nuclear fusion in deuterium-charged palladium; no excess heat is found, nor is any gamma or neutron activity identified. Peltier heating at the palladium/platinum junction is investigated, but no effects are seen; the possibility remains, however, that a large Peltier coefficient may arise for deuterium concentrations that render the palladium-deuterium semiconducting. Finally, the effects of poisoning the palladium with cyanide were investigated.

  9. Electronic structure, transport, and phonons of SrAgChF (Ch = S,Se,Te): Bulk superlattice thermoelectrics

    SciTech Connect (OSTI)

    Gudelli, Vijay Kumar; Kanchana, V.; Vaitheeswaran, G.; Singh, David J.; Svane, Axel; Christensen, Niels Egede; Mahanti, Subhendra D.

    2015-07-15

    Here, we report calculations of the electronic structure, vibrational properties, and transport for the p-type semiconductors, SrAgChF (Ch = S, Se, and Te). We find soft phonons with low frequency optical branches intersecting the acoustic modes below 50 cm–1, indicative of a material with low thermal conductivity. The bands at and near the valence-band maxima are highly two-dimensional, which leads to high thermopowers even at high carrier concentrations, which is a combination that suggests good thermoelectric performance. These materials may be regarded as bulk realizations of superlattice thermoelectrics.

  10. High thermoelectric figure of merit in nanocrystalline polyaniline at low temperatures

    SciTech Connect (OSTI)

    Nath, Chandrani; Kumar, Ashok E-mail: okram@csr.res.in; Kuo, Yung-Kang; Okram, Gunadhor Singh E-mail: okram@csr.res.in

    2014-09-29

    Thermoelectric coolers with figure of merit (ZT) close to unity at low temperatures are the need of the hour with new advances in high temperature superconductors, superconducting microelectronic circuits, quantum computers, and photonics. Here, we demonstrate that the conducting polymer polyaniline (Pani) doped with camphor sulfonic acid synthesized in semi-crystalline nanostructures, possesses a giant Seebeck effect at low temperatures. The resulting enormously large Seebeck coefficient (up to 0.6 V/K) combined with an intrinsically low electrical conductivity and thermal conductivity give rise to a ZT = 0.77 at 45 K and ZT = 2.17 at 17 K.

  11. Develop Thermoelectric Technology for Automotive Waste Heat Recovery |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ace_45_yang.pdf (1.15 MB) More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat Recovery Engineering and Materials for Automotive Thermoelectric Applications Solid-State Energy Conversion Overview

  12. Isovalent substitutes play in different ways: Effects of isovalent substitution on the thermoelectric properties of CoSi0.98B0.02

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Hui; Lu, Xu; Morelli, Donald T.

    2016-07-21

    Boron-added CoSi, CoSi0.98B0.02, possesses a very high thermoelectric power factor of 60 μW cm-1 K-2 at room temperature, which is among the highest power factors that have ever been reported for near-room-temperature thermoelectric applications. Since the electrical properties of this material have been tuned properly, isovalent substitution for its host atoms are intentionally employed to reduce the lattice thermal conductivity while maintaining the electronic properties unchanged. In our previous work, the effect of Rh substitution for Co atoms on the thermoelectric properties of CoSi0.98B0.02 has been studied. Here we present a study of the substitution of Ge for Si atomsmore » in this compound. Even though Ge and Rh are isovalent with their corresponding host atoms, they play different roles in determining the electrical and thermal transport properties. Through the evaluation of the lattice thermal conductivity by the Debye approximation and the comparison between the high-temperature Seebeck coefficients, we propose that Rh substitution leads to a further overlapping of the conduction and the valence bands while Ge substitution only shifts the Fermi level upward into the conduction band. Lastly, our results show that the influence of isovalent substitution on the electronic structure cannot be ignored when the alloying method is used to improve thermoelectric properties.« less

  13. Modular Radioisotope Thermoelectric Generator (RTG) Program. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1992-12-31

    Section 2.0 of this report summarizes the MOD-RTG reference flight design, and Section 3.0 discusses the Ground Demonstration System design. Multicouple technology development is discussed in Section 4.0, and Section 5.0 lists all published technical papers prepared during the course of the contract.

  14. Development of a 500 Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov [DOE]

    A low temperature TEG has been built and tested providing over 500 watts electric power at a ∆T of 2000C

  15. A miniaturized mW thermoelectric generator for nw objectives...

    Office of Scientific and Technical Information (OSTI)

    Authors: Aselage, Terrence Lee ; Siegal, Michael P. ; Whalen, Scott ; Frederick, Scott K. ; Apblett, Christopher Alan ; Moorman, Matthew Wallace Publication Date: 2006-10-01 OSTI ...

  16. Radioisotope Thermoelectric Generator F7 Flight Unit Acceptance Buy Off

    SciTech Connect (OSTI)

    1997-02-20

    These are viewgraphs from the subject presentation. The LMMS E-7 history is outlined; Qualification and use of the F-7 GPHS-RTG for the Cassini mission; and the F-7 acceptance test program and performance are described.

  17. Potential improvements in SiGe radioisotope thermoelectric generator performance

    SciTech Connect (OSTI)

    Mowery, A.L.

    1999-01-01

    In accordance with NASA{close_quote}s slogan: {open_quotes}Better, Cheaper, Faster,{close_quotes} this paper will address potential improvements to SiGe RTG technology to make them Better. RTGs are doubtless cheaper than {open_quotes}paper designs{close_quotes} which are better and cheaper until development, performance and safety test costs are considered. RTGs have the advantage of being fully developed and tested in the rigors of space for over twenty years. Further, unless a new system can be accelerated tested, as were the RTGs, they cannot be deployed reliably unless a number of systems have succeeded for test periods exceeding the mission lifetime. Two potential developments are discussed that can improve the basic RTG performance by 10 to 40{sup +}{percent} depending on the mission profile. These improvements could be demonstrated in years. Accelerated testing could also be performed in this period to preserve existing RTG reliability. Data from a qualification tested RTG will be displayed, while not definitive, to support the conclusions. Finally, it is anticipated that other investigators will be encouraged to suggest further modifications to the basic RTG design to improve its performance. {copyright} {ital 1999 American Institute of Physics.}

  18. Overview of Progress in Thermoelectric Power Generation Technologies in

    Broader source: Energy.gov (indexed) [DOE]

    ENERGY lab 18 Aug 2015 Richard Hammack, Monitoring Team Lead USDOE National Energy Technology Laboratory, Pittsburgh, PA Overview of NETL Field Studies Related to Oil and Gas Production DOE Tribal Leaders Forum Denver, Colorado Newfield Exploration, Bakken Petroleum System, North Dakota * Reduce Environmental Impacts * Demonstrate Safe/Reliable Operations * Improve Efficiency of Hydraulic Fracturing Program Objectives * Surface Monitoring - Ambient Air Quality - Air Emissions - Ground Motion -

  19. Thermoelectric Generator Development for Automotive Waste Heat Recovery

    Broader source: Energy.gov [DOE]

    Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  20. Scaling Considerations for Thermoelectric Generators | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Scale-up of Algal Biofuel Production Using Waste Nutrients Civil and Environmental Engineering California Polytechnic State University San Luis Obispo, California MicroBio Engineering, Inc. San Luis Obispo, California Phase 1 Goal Statement * Develop the capability for 2500 gal/ac-yr of biofuel intermediates via HTL from