National Library of Energy BETA

Sample records for thermoelectric devices cxs

  1. Composite Thermoelectric Devices

    Broader source: Energy.gov [DOE]

    Composite thermoelectric devices incorporating common conductors laminated between P- and N-type thermoelectric plates demonstrate internal ohmic loss reduction and enhanced performance

  2. Thermoelectric Materials, Devices and Systems:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DRAFT - PRE-DECISIONAL -DRAFT - FOR OFFICIAL USE ONLY - DRAFT Thermoelectric Materials, Devices and Systems: 1 Technology Assessment 2 Contents 3 1. Thermoelectric Generation ................................................................................................................... 2 4 2. Technology Assessment and Potential ................................................................................................. 3 5 2.1 Performance Advances

  3. Enhancing Heat Recovery for Thermoelectric Devices | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat Recovery for Thermoelectric Devices Enhancing Heat Recovery for Thermoelectric Devices Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research ...

  4. High performance thermoelectric nanocomposite device

    DOE Patents [OSTI]

    Yang, Jihui; Snyder, Dexter D.

    2011-10-25

    A thermoelectric device includes a nanocomposite material with nanowires of at least one thermoelectric material having a predetermined figure of merit, the nanowires being formed in a porous substrate having a low thermal conductivity and having an average pore diameter ranging from about 4 nm to about 300 nm.

  5. Improved Thermoelectric Devices: Advanced Semiconductor Materials for Thermoelectric Devices

    SciTech Connect (OSTI)

    2009-12-11

    Broad Funding Opportunity Announcement Project: Phononic Devices is working to recapture waste heat and convert it into usable electric power. To do this, the company is using thermoelectric devices, which are made from advanced semiconductor materials that convert heat into electricity or actively remove heat for refrigeration and cooling purposes. Thermoelectric devices resemble computer chips, and they manage heat by manipulating the direction of electrons at the nanoscale. These devices aren’t new, but they are currently too inefficient and expensive for widespread use. Phononic Devices is using a high-performance, cost-effective thermoelectric design that will improve the device’s efficiency and enable electronics manufacturers to more easily integrate them into their products.

  6. Electronic cooling using thermoelectric devices

    SciTech Connect (OSTI)

    Zebarjadi, M.

    2015-05-18

    Thermoelectric coolers or Peltier coolers are used to pump heat in the opposite direction of the natural heat flux. These coolers have also been proposed for electronic cooling, wherein the aim is to pump heat in the natural heat flux direction and from hot spots to the colder ambient temperature. In this manuscript, we show that for such applications, one needs to use thermoelectric materials with large thermal conductivity and large power factor, instead of the traditionally used high ZT thermoelectric materials. We further show that with the known thermoelectric materials, the active cooling cannot compete with passive cooling, and one needs to explore a new set of materials to provide a cooling solution better than a regular copper heat sink. We propose a set of materials and directions for exploring possible materials candidates suitable for electronic cooling. Finally, to achieve maximum cooling, we propose to use thermoelectric elements as fins attached to copper blocks.

  7. Thermoelectric Materials, Devices and Systems:

    Energy Savers [EERE]

    ... However the use of thermoelectric modules as solid state heat pumps for 42 heating and cooling applications using the opposite Peltier effect is far more common than their use as ...

  8. Thermoelectric devices and applications for the same

    DOE Patents [OSTI]

    Olsen, Larry C.; DeSteese, John G.; Martin, Peter M.; Johnston, John W.; Peters, Timothy J.

    2016-03-08

    High performance thin film thermoelectric couples and methods of making the same are disclosed. Such couples allow fabrication of at least microwatt to watt-level power supply devices operating at voltages greater than one volt even when activated by only small temperature differences.

  9. Thermoelectric devices and applications for the same

    DOE Patents [OSTI]

    DeSteese, John G [Kennewick, WA; Olsen, Larry C [Richland, WA; Martin, Peter M [Kennewick, WA

    2010-12-14

    High performance thin film thermoelectric couples and methods of making the same are disclosed. Such couples allow fabrication of at least microwatt to watt-level power supply devices operating at voltages greater than one volt even when activated by only small temperature differences.

  10. Analytical Modeling and Simulation of Thermoelectric Devices...

    Broader source: Energy.gov (indexed) [DOE]

    and Technologies Micro- & Nano-Technologies Enabling More Compact, Lightweight Thermoelectric Power Generation & Cooling Systems Automotive Thermoelectric Generators and HVAC

  11. Development of thermoelectric fibers for miniature thermoelectric devices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ren, Fei; Menchhofer, Paul A.; Kiggans, Jr., James O.; Wang, Hsin

    2016-09-23

    Miniature thermoelectric (TE) devices may be used in a variety of applications such as power sources of small sensors, temperature regulation of precision electronics, etc. Reducing the size of TE elements may also enable design of novel devices with unique form factor and higher device efficiency. Current industrial practice of fabricating TE devices usually involves mechanical removal processes that not only lead to material loss but also limit the geometry of the TE elements. In this project, we explored a powder-processing method for the fabrication of TE fibers with large length-to-area ratio, which could be potentially used for miniature TEmore » devices. Powders were milled from Bi2Te3-based bulk materials and then mixed with a thermoplastic resin dissolved in an organic solvent. Through an extrusion process, flexible, continuous fibers with sub-millimeter diameters were formed. The polymer phase was then removed by sintering. Sintered fibers exhibited similar Seebeck coefficients to the bulk materials. Moreover, their electrical resistivity was much higher, which might be related to the residual porosity and grain boundary contamination. Prototype miniature uni-couples fabricated from these fibers showed a linear I-V behavior and could generate millivolt voltages and output power in the nano-watt range. Further development of these TE fibers requires improvement in their electrical conductivities, which needs a better understanding of the causes that lead to the low conductivity in the sintered fibers.« less

  12. Characterization of thermoelectric elements and devices by impedance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    describes a new measurement technique that utilizes impedance spectroscopy for the characterization of thermoelectric materials and devices. Two circuit models were...

  13. Development of a Thermoelectric Device for an Automotive Zonal...

    Broader source: Energy.gov (indexed) [DOE]

    thermoelectric device using liquid working fluid on the waste side and air as working fluid on the main side to enable zonal or distributed heatingcooling systems within ...

  14. High-Performance Thermoelectric Devices Based on Abundant Silicide

    Broader source: Energy.gov (indexed) [DOE]

    Materials for Vehicle Waste Heat Recovery | Department of Energy Development of high-performance thermoelectric devices for vehicle waste heat recovery will include fundamental research to use abundant promising low-cost thermoelectric materials, thermal management and interfaces design, and metrology shi.pdf (4.76

  15. Performance, Market and Manufacturing Constraints relevant to the Industrialization of Thermoelectric Devices

    Office of Energy Efficiency and Renewable Energy (EERE)

    Market pricing of thermoelectric raw materials and processing, cost of manufacture of devices and systems constraints on the viability of a mass market thermoelectric product are discussed

  16. An integrated approach towards efficient, scalable, and low cost thermoelectric waste heat recovery devices for vehicles

    Broader source: Energy.gov [DOE]

    Efficient, scalable, and low cost vehicular thermoelectric generators development will include rapid synthesis of thermoelectric materials, different device geometries, heat sink designs, and durability and long-term performance tests

  17. High-Performance Thermoelectric Devices Based on Abundant Silicide Materials for Vehicle Waste Heat Recovery

    Broader source: Energy.gov [DOE]

    Development of high-performance thermoelectric devices for vehicle waste heat recovery will include fundamental research to use abundant promising low-cost thermoelectric materials, thermal management and interfaces design, and metrology

  18. Overview of Research on Thermoelectric Materials and Devices in China |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy An overview presentation of R&D projects on thermoelectric power generation technology in China. zhang.pdf (3.85 MB) More Documents & Publications Recent Progress in the Development of N-type Skutterudites Vehicular Thermoelectric Applications Session DEER 2009 The Bottom-Up Approach forThermoelectric Nanocomposites, plusƒ

  19. Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI

    Broader source: Energy.gov [DOE]

    Reviews work in engineered thin-film nanoscale thermoelectric materials and nano-bulk materials with high ZT undertaken by RTI in collaboration with its research partners

  20. High-Performance Thermoelectric Devices Based on Abundant Silicide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    vehicle waste heat recovery will include fundamental research to use abundant promising low-cost thermoelectric materials, thermal management and interfaces design, and metrology

  1. Overview of Research on Thermoelectric Materials and Devices...

    Broader source: Energy.gov (indexed) [DOE]

    An overview presentation of R&D projects on thermoelectric power generation technology in China. zhang.pdf (3.85 MB) More Documents & Publications Recent Progress in the ...

  2. Development and Testing of an Integrated Sandia Cooler Thermoelectric Device (SCTD).

    SciTech Connect (OSTI)

    Johnson, Terry A.; Staats, Wayne Lawrence,; Leick, Michael Thomas; Zimmerman, Mark D.; Radermacher, Reinhard; Martin, Cara; Nasuta, Dennis; Kalinowski, Paul; Hoffman, William

    2014-12-01

    This report describes a FY14 effort to develop an integrated Sandia Cooler T hermoelectric D evice (SCTD) . The project included a review of feasible thermoelectric (TE) cooling applications, baseline performance testing of an existing TE device, analysis and design development of an integrated SCTD assembly, and performance measurement and validation of the integrated SCTD prototype.

  3. Development of a Thermoelectric Device for an Automotive Zonal HVAC System

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presents development of a thermoelectric device using liquid working fluid on the wasteŽ side and air as working fluid on the mainŽ side to enable zonal or distributed heating/cooling systems within a vehicle

  4. Thermoelectric Alloys and Devices for Radioisotope Space Power Systems: State of the Art and Current Developments

    SciTech Connect (OSTI)

    Barnett, W.; Dick, P.; Beaudry, B.; Gorsuch, P.; Skrabek, E.

    1989-01-01

    Lead telluride and silicon germanium type alloys have served over the past several decades as the preferred thermoelectric conversion materials for U. S. radioisotope thermoelectric generator (RTG) power systems for planetary deep space exploration missions. The Pioneer missions to Jupiter and Jupiter/Saturn and the Viking Mars Lander missions employed TAGS-2N (lead and germanium telluride derivatives) power conversion devices. Since 1976, silicon germanium (SiGe) alloys, incorporated into the unicouple device, have evolved as the thermoelectric materials of choice for U. S. RTG powered space missions. These include the U. S. Air Force Lincoln Experimental Satellites 8 & 9 for communications, in 1976, followed in 1977 by the National Aeronautics and Space Administration Voyager 1 and 2 planetary missions. In 1989, advanced SiGe RTGs were used to power the Galileo exploration of Jupiter and, in 1990, will be used to power the Ulysses investigation of the Sun. In addition, SiGe technology has been chosen to provide RTG power for the 1995 Comet Rendezvous and Asteroid Flyby mission and the 1996 Cassini Saturn orbiter mission. Summaries of the flight performance data for these systems are presented.; Current U. S. Department of Energy thermoelectric development activities include (1) the development of conversion devices based on hi-density, close packed couple arrays and (2) the development of improved performance silicon germanium type thermoelectric materials. The silicon germanium type "multicouple", being developed in conjunction with the Modular RTG program, is discussed in a companion paper. A lead telluride type close-packed module, discussed herein, offers the promise of withstanding high velocity impacts and, thus, is a candidate for a Mars Penetrator application.; Recent projects sponsored by the U. S. Department of Energy, including the Improved Thermoelectric Materials and Modular Radioisotope Thermoelectric Generator programs, have shown that improvements

  5. High temperature thermoelectrics

    DOE Patents [OSTI]

    Moczygemba, Joshua E.; Biershcenk, James L.; Sharp, Jeffrey W.

    2014-09-23

    In accordance with one embodiment of the present disclosure, a thermoelectric device includes a plurality of thermoelectric elements that each include a diffusion barrier. The diffusion barrier includes a refractory metal. The thermoelectric device also includes a plurality of conductors coupled to the plurality of thermoelectric elements. The plurality of conductors include aluminum. In addition, the thermoelectric device includes at least one plate coupled to the plurality of thermoelectric elements using a braze. The braze includes aluminum.

  6. Thermoelectric system

    SciTech Connect (OSTI)

    Reiners, Eric A.; Taher, Mahmoud A.; Fei, Dong; McGilvray, Andrew N.

    2007-10-30

    In one particular embodiment, an internal combustion engine is provided. The engine comprises a block, a head, a piston, a combustion chamber defined by the block, the piston, and the head, and at least one thermoelectric device positioned between the combustion chamber and the head. In this particular embodiment, the thermoelectric device is in direct contact with the combustion chamber. In another particular embodiment, a cylinder head configured to sit atop a cylinder bank of an internal combustion engine is provided. The cylinder head comprises a cooling channel configured to receive cooling fluid, valve seats configured for receiving intake and exhaust valves, and thermoelectric devices positioned around the valve seats.

  7. WASTE HEAT RECOVERY USING THERMOELECTRIC DEVICES IN THE LIGHT METALS INDUSTRY

    SciTech Connect (OSTI)

    Choate, William T.; Hendricks, Terry J.; Majumdar, Rajita

    2007-05-01

    Recently discovered thermoelectric materials and associated manufacturing techniques (nanostructures, thin-film super lattice, quantum wells...) have been characterized with thermal to electric energy conversion efficiencies of 12-25+%. These advances allow the manufacture of small-area, high-energy flux (350 W/cm2 input) thermoelectric generating (TEG) devices that operate at high temperatures (~750C). TEG technology offers the potential for large-scale conversion of waste heat from the exhaust gases of electrolytic cells (e.g., Hall-Hroult cells) and from aluminum, magnesium, metal and glass melting furnaces. This paper provides an analysis of the potential energy recovery and of the engineering issues that are expected when integrating TEG systems into existing manufacturing processes. The TEG module must be engineered for low-cost, easy insertion and simple operation in order to be incorporated into existing manufacturing operations. Heat transfer on both the hot and cold-side of these devices will require new materials, surface treatments and design concepts for their efficient operation.

  8. Device for use in a furnace exhaust stream for thermoelectric generation

    DOE Patents [OSTI]

    Polcyn, Adam D.

    2013-06-11

    A device for generating voltage or electrical current includes an inner elongated member mounted in an outer elongated member, and a plurality of thermoelectric modules mounted in the space between the inner and the outer members. The outer and/or inner elongated members each include a plurality of passages to move a temperature altering medium through the members so that the device can be used in high temperature environments, e.g. the exhaust system of an oxygen fired glass melting furnace. The modules are designed to include a biasing member and/or other arrangements to compensate for differences in thermal expansion between the first and the second members. In this manner, the modules remain in contact with the first and second members. The voltage generated by the modules can be used to power electrical loads.

  9. The Industrialization of Thermoelectric Power Generation Technology...

    Broader source: Energy.gov (indexed) [DOE]

    Devices An integrated approach towards efficient, scalable, and low cost thermoelectric waste heat recovery devices for vehicles Automotive Thermoelectric Generators and HVAC

  10. Manufacture of thermoelectric generator structures by fiber drawing

    DOE Patents [OSTI]

    McIntyre, Timothy J; Simpson, John T; West, David L

    2014-11-18

    Methods of manufacturing a thermoelectric generator via fiber drawing and corresponding or associated thermoelectric generator devices are provided.

  11. Synthetic thermoelectric materials comprising phononic crystals

    DOE Patents [OSTI]

    El-Kady, Ihab F; Olsson, Roy H; Hopkins, Patrick; Reinke, Charles; Kim, Bongsang

    2013-08-13

    Synthetic thermoelectric materials comprising phononic crystals can simultaneously have a large Seebeck coefficient, high electrical conductivity, and low thermal conductivity. Such synthetic thermoelectric materials can enable improved thermoelectric devices, such as thermoelectric generators and coolers, with improved performance. Such synthetic thermoelectric materials and devices can be fabricated using techniques that are compatible with standard microelectronics.

  12. Thermoelectrics Partnership: Automotive Thermoelectric Modules...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solution for Automotive Thermoelectric Modules Application Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces

  13. High-Efficiency Solid State Cooling Technologies: Non-Equilibrium Asymmetic Thermoelectrics (NEAT) Devices

    SciTech Connect (OSTI)

    2010-09-01

    BEETIT Project: Sheetak is developing a thermoelectric-based solid state cooling system to replace typical air conditioners that use vapor compression to cool air. With noisy mechanical components, vapor compression systems use a liquid refrigerant to circulate within the air conditioner, absorb heat, and pump the heat out into the external environment. With no noisy moving parts or polluting refrigerants, thermoelectric systems rely on an electrical current being passed through the junction of the two different conducting materials to change temperature. Using advanced semiconductor technology, Sheetak is improving solid state cooling systems by using proprietary thermoelectric materials along with other innovations to achieve significant energy efficiency. Sheetak’s new design displaces compressor-based technology; improves reliability; and decreases energy usage. Sheetak’s use of semiconductor manufacturing methods leads to less material use—facilitating cheaper production.

  14. Semiconductor nanowire thermoelectric materials and devices, and processes for producing same

    DOE Patents [OSTI]

    Lagally, Max G.; Evans, Paul G.; Ritz, Clark S.

    2011-02-15

    The present invention provides nanowires and nanoribbons that are well suited for use in thermoelectric applications. The nanowires and nanoribbons are characterized by a periodic longitudinal modulation, which may be a compositional modulation or a strain-induced modulation. The nanowires are constructed using lithographic techniques from thin semiconductor membranes, or "nanomembranes."

  15. Semiconductor nanowire thermoelectric materials and devices, and processes for producing same

    DOE Patents [OSTI]

    Lagally, Max G; Evans, Paul G; Ritz, Clark S

    2013-09-17

    The present invention provides nanowires and nanoribbons that are well suited for use in thermoelectric applications. The nanowires and nanoribbons are characterized by a periodic compositional longitudinal modulation. The nanowires are constructed using lithographic techniques from thin semiconductor membranes, or "nanomembranes."

  16. Semiconductor nanowire thermoelectric materials and devices, and processes for producing same

    DOE Patents [OSTI]

    Lagally, Max G.; Evans, Paul G.; Ritz, Clark S.

    2015-11-17

    The present invention provides nanowires and nanoribbons that are well suited for use in thermoelectric applications. The nanowires and nanoribbons are characterized by a periodic compositional longitudinal modulation. The nanowires are constructed using lithographic techniques from thin semiconductor membranes, or "nanomembranes."

  17. Thermoelectrics Partnership: Automotive Thermoelectric Modules...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces Novel Nanostructured Interface Solution for Automotive ...

  18. Sandia Researchers Are First to Measure Thermoelectric Behavior...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Thermoelectric devices convert heat to electricity and have no moving parts, making them extremely attractive for cooling and energy harvesting applications. Thermoelectric ...

  19. NSF/DOE Thermoelectric Partnership: High-Performance Thermoelectric...

    Broader source: Energy.gov (indexed) [DOE]

    An integrated approach towards efficient, scalable, and low cost thermoelectric waste heat recovery devices for vehicles An integrated approach towards efficient, scalable, and low ...

  20. A compact broadband ion beam focusing device based on laser-driven megagauss thermoelectric magnetic fields

    SciTech Connect (OSTI)

    Albertazzi, B.; D'Humières, E.; Lancia, L.; Antici, P.; Dervieux, V.; Nakatsutsumi, M.; Romagnani, L.; Fuchs, J.; Böcker, J.; Swantusch, M.; Willi, O.; Bonlie, J.; Cauble, B.; Shepherd, R.; Breil, J.; Feugeas, J. L.; Nicolaï, P.; Tikhonchuk, V. T.; Chen, S. N.; Sentoku, Y.; and others

    2015-04-15

    Ultra-intense lasers can nowadays routinely accelerate kiloampere ion beams. These unique sources of particle beams could impact many societal (e.g., proton-therapy or fuel recycling) and fundamental (e.g., neutron probing) domains. However, this requires overcoming the beam angular divergence at the source. This has been attempted, either with large-scale conventional setups or with compact plasma techniques that however have the restriction of short (<1 mm) focusing distances or a chromatic behavior. Here, we show that exploiting laser-triggered, long-lasting (>50 ps), thermoelectric multi-megagauss surface magnetic (B)-fields, compact capturing, and focusing of a diverging laser-driven multi-MeV ion beam can be achieved over a wide range of ion energies in the limit of a 5° acceptance angle.

  1. Thermoelectric Activities of European Community within Framework...

    Broader source: Energy.gov (indexed) [DOE]

    Bulk Materials and Device Development Overview of Fraunhofer IPM Activities in High Temperature Bulk Materials and Device Development Automotive Thermoelectric Generators and HVAC

  2. Thermoelectrics Partnership: High Performance Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Embedded Nanoparticles Thermoelectrics Partnership: High Performance Thermoelectric Waste Heat Recovery System Based on Zintl Phase Materials with Embedded Nanoparticles 2011 DOE ...

  3. Thermoelectric Mechanical Reliability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    DRAFT - PRE-DECISIONAL -DRAFT - FOR OFFICIAL USE ONLY - DRAFT Thermoelectric Materials, Devices and Systems: 1 Technology Assessment 2 Contents 3 1. Thermoelectric Generation ................................................................................................................... 2 4 2. Technology Assessment and Potential ................................................................................................. 3 5 2.1 Performance Advances

  4. Fabrication of stable electrode/diffusion barrier layers for thermoelectric filled skutterudite devices

    DOE Patents [OSTI]

    Jie, Qing; Ren, Zhifeng; Chen, Gang

    2015-12-08

    Disclosed are methods for the manufacture of n-type and p-type filled skutterudite thermoelectric legs of an electrical contact. A first material of CoSi.sub.2 and a dopant are ball-milled to form a first powder which is thermo-mechanically processed with a second powder of n-type skutterudite to form a n-type skutterudite layer disposed between a first layer and a third layer of the doped-CoSi.sub.2. In addition, a plurality of components such as iron, and nickel, and at least one of cobalt or chromium are ball-milled form a first powder that is thermo-mechanically processed with a p-type skutterudite layer to form a p-type skutterudite layer "second layer" disposed between a first and a third layer of the first powder. The specific contact resistance between the first layer and the skutterudite layer for both the n-type and the p-type skutterudites subsequent to hot-pressing is less than about 10.0 .mu..OMEGA.cm.sup.2.

  5. Thermoelectric device including an alloy of GeTe and AgSbTe as the P-type element

    DOE Patents [OSTI]

    Skrabek, Emanuel Andrew; Trimmer, Donald Smith

    1976-01-01

    Improved alloys suitable for thermoelectric applications and having the general formula: (AgSbTe.sub.2).sub.1.sub.-x + (GeTe).sub.x wherein x has a value of about 0.80 and 0.85, have been found to possess unexpectedly high thermoelectric properties such as efficiency index, as well as other improved physical properties.

  6. Thermoelectric converter

    DOE Patents [OSTI]

    Kim, C.K.

    1974-02-26

    This invention relates in general to thermoelectric units and more particularly to a tubular thermoelectric unit which includes an array of tandemly arranged radially tapered annular thermoelectric pellets having insulation material of a lower density than the thermoelectric pellets positioned between each pellet. (Official Gazette)

  7. Thermoelectric system for an engine

    DOE Patents [OSTI]

    Mcgilvray, Andrew N.; Vachon, John T.; Moser, William E.

    2010-06-22

    An internal combustion engine that includes a block, a cylinder head having an intake valve port and exhaust valve port formed therein, a piston, and a combustion chamber defined by the block, the piston, and the head. At least one thermoelectric device is positioned within either or both the intake valve port and the exhaust valve port. Each of the valves is configured to move within a respective intake and exhaust valve port thereby causing said valves to engage the thermoelectric devices resulting in heat transfer from the valves to the thermoelectric devices. The intake valve port and exhaust valve port are configured to fluidly direct intake air and exhaust gas, respectively, into the combustion chamber and the thermoelectric device is positioned within the intake valve port, and exhaust valve port, such that the thermoelectric device is in contact with the intake air and exhaust gas.

  8. High-Efficiency, Cost-effective Thermoelectric Materials/Devices for Industrial Process Refrigeration and Waste Heat Recovery, STTR Phase II Final Report

    SciTech Connect (OSTI)

    Lin, Timothy

    2011-01-07

    This is the final report of DoE STTR Phase II project, “High-efficiency, Cost-effective Thermoelectric Materials/Devices for Industrial Process Refrigeration and Waste Heat Recovery”. The objective of this STTR project is to develop a cost-effective processing approach to produce bulk high-performance thermoelectric (TE) nanocomposites, which will enable the development of high-power, high-power-density TE modulus for waste heat recovery and industrial refrigeration. The use of this nanocomposite into TE modules are expected to bring about significant technical benefits in TE systems (e.g. enhanced energy efficiency, smaller sizes and light weight). The successful development and applications of such nanocomposite and the resultant TE modules can lead to reducing energy consumption and environmental impacts, and creating new economic development opportunities.

  9. Tuning the thermoelectric power factor in carbon nanotube films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Tuning the thermoelectric power factor in carbon nanotube films Ben Zhou 1 , Azure Avery 2 , Andrew Ferguson 2 , Jeff Blackburn 2 Schematic of a thermoelectric device. (wikipedia) Heat Thermoelectric Device Electricity Thermoelectrics Carbon Nanotubes Introduction * Single walled carbon nanotubes (SWCNTs) are promising thermoelectrics because of their good conductivity and one dimensional density of states. Materials and Methods * Ink Preparation: (7,5) nanotubes were dispersed by

  10. Thermoelectric Mechanical Reliability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation pm012_wereszczak_2011_o.pdf (498.73 KB) More Documents & Publications Thermoelectrics Theory and Structure Transport Properties, Thermal Response, and Mechanical Reliability of Thermoelectric Materials and Devices for Automotive Waste Heat Recovery Thermoelectric Mechanical Reliability

  11. Thermoelectrics Theory and Structure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation pm012_wereszczak_2011_o.pdf (498.73 KB) More Documents & Publications Thermoelectric Mechanical Reliability Transport Properties, Thermal Response, and Mechanical Reliability of Thermoelectric Materials and Devices for Automotive Waste Heat Recovery Thermoelectric Mechanical Reliability

  12. Nano-structures Thermoelectric Materals - Part 1 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Nano-structures Thermoelectric Materals - Part 1 2002 DEER Conference Presentation: RTI International 2002_deer_venkatasubramanian1.pdf (1.13 MB) More Documents & Publications Nano-structures Thermoelectric Materals - Part 2 Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI Thermoelectric Developments for Vehicular Applications

  13. Engineering and Materials for Automotive Thermoelectric Applications...

    Broader source: Energy.gov (indexed) [DOE]

    cooling and heating with TE devices; discovery and development of highly efficient TE materials. yang.pdf (4.47 MB) More Documents & Publications Develop Thermoelectric ...

  14. Thermoelectrics and Photovoltaics - Center for Solar and Thermal Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion Thermoelectrics and Photovoltaics Thermoelectrics A significant amount of heat is wasted from industrial processes, home heating and vehicle exhausts that could otherwise be converted to electricity through the use of thermoelectric devices. The interconversion between heat and electricity, through the use of thermoelectrics, is environmentally friendly and highly reliable. With improved efficiency, thermoelectrics could have a significant impact on the energy consumption

  15. Thermoelectric module

    DOE Patents [OSTI]

    Kortier, William E.; Mueller, John J.; Eggers, Philip E.

    1980-07-08

    A thermoelectric module containing lead telluride as the thermoelectric mrial is encapsulated as tightly as possible in a stainless steel canister to provide minimum void volume in the canister. The lead telluride thermoelectric elements are pressure-contacted to a tungsten hot strap and metallurgically bonded at the cold junction to iron shoes with a barrier layer of tin telluride between the iron shoe and the p-type lead telluride element.

  16. Probabilistic Mechanical Reliability Prediction of Thermoelectric Legs

    SciTech Connect (OSTI)

    Jadaan, Osama M.; Wereszczak, Andrew A

    2009-05-01

    The probability of failure, Pf, for various square-arrayed thermoelectric device designs using bismuth telluride, lead telluride, or skutterudite thermoelectric materials were estimated. Only volume- or bulk-based Pf analysis was considered in this study. The effects of the choice of the thermoelectric material, the size of the leg array, the height of the thermoelectric legs, and the boundary conditions on the Pf of thermoelectric devices were investigated. Yielding of the solder contacts and mounting layer was taken into account. The modeling results showed that the use of longer legs, using skutterudites, allowing the thermoelectric device to freely deform while under a thermal gradient, and using smaller arrays promoted higher probabilities of survival.

  17. Thermoelectrically cooled water trap

    DOE Patents [OSTI]

    Micheels, Ronald H.

    2006-02-21

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  18. Semimetal/Semiconductor Nanocomposites for Thermoelectrics

    SciTech Connect (OSTI)

    Lu, Hong; Burke, Peter G.; Gossard, Arthur C.; Zeng, Gehong; Ramu, Ashok T.; Bahk, Je-Hyeong; Bowers, John E.

    2011-04-15

    In this work, we present research on semimetal-semiconductor nanocomposites grown by molecular beam epitaxy (MBE) for thermoelectric applications. We study several different III-V semiconductors embedded with semimetallic rare earth-group V (RE-V) compounds, but focus is given here to ErSb:InxGa1-xSb as a promising p-type thermoelectric material. Nanostructures of RE-V compounds are formed and embedded within the III-V semiconductor matrix. By codoping the nanocomposites with the appropriate dopants, both n-type and p-type materials have been made for thermoelectric applications. The thermoelectric properties have been engineered for enhanced thermoelectric device performance. Segmented thermoelectric power generator modules using 50 ?m thick Er-containing nanocomposites have been fabricated and measured. Research on different rare earth elements for thermoelectrics is discussed.

  19. Silicon-Based Thermoelectrics: Harvesting Low Quality Heat Using Economically Printed Flexible Nanostructured Stacked Thermoelectric Junctions

    SciTech Connect (OSTI)

    2010-03-01

    Broad Funding Opportunity Announcement Project: UIUC is experimenting with silicon-based materials to develop flexible thermoelectric devices—which convert heat into energy—that can be mass-produced at low cost. A thermoelectric device, which resembles a computer chip, creates electricity when a different temperature is applied to each of its sides. Existing commercial thermoelectric devices contain the element tellurium, which limits production levels because tellurium has become increasingly rare. UIUC is replacing this material with microscopic silicon wires that are considerably cheaper and could be equally effective. Improvements in thermoelectric device production could return enough wasted heat to add up to 23% to our current annual electricity production.

  20. NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics for Automotive Waste Heat Recovery Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces

  1. Thermoelectrics | Solid State Solar Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermoelectrics One of the central themes of S3TEC is to develop more efficient thermoelectric materials to directly convert heat into electricity via the Seebeck effect, or provide cooling via the Peltier effect. Their ability to harvest waste heat and deliver cooling power through solid-state devices without moving parts makes them important candidates of sustainable energy technologies in the future. Despite the benefits, the current bottleneck of thermoelectric technology is its relatively

  2. Nano-structures Thermoelectric Materals - Part 2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Nano-structures Thermoelectric Materals - Part 2 2002 DEER Conference Presentation: RTI International 2002_deer_venkatasubramanian2.pdf (3.14 MB) More Documents & Publications Nano-structures Thermoelectric Materals - Part 1 Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI The 60% Efficient Diesel Engine: Probably, Possible, Or Just a Fantasy?

  3. Commercialization of Bulk Thermoelectric Materials for Power Generation

    Broader source: Energy.gov [DOE]

    Critical aspects of technology commercialization of preproduction high performance thermoelectric materials available for device developers, data analysis, and future plans are discussed

  4. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, J.D.; El-Genk, M.S.

    1996-01-01

    An apparatus and method for producing electricity from heat. The present invention is a thermoelectric generator that uses materials with substantially no electrical resistance, often called superconductors, to efficiently convert heat into electrical energy without resistive losses. Preferably, an array of superconducting elements is encased within a second material with a high thermal conductivity. The second material is preferably a semiconductor. Alternatively, the superconducting material can be doped on a base semiconducting material, or the superconducting material and the semiconducting material can exist as alternating, interleaved layers of waferlike materials. A temperature gradient imposed across the boundary of the two materials establishes an electrical potential related to the magnitude of the temperature gradient. The superconducting material carries the resulting electrical current at zero resistivity, thereby eliminating resistive losses. The elimination of resistive losses significantly increases the conversion efficiency of the thermoelectric device.

  5. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, J.D.; El-Genk, M.S.

    1998-05-05

    An apparatus and method for producing electricity from heat is disclosed. The present invention is a thermoelectric generator that uses materials with substantially no electrical resistance, often called superconductors, to efficiently convert heat into electrical energy without resistive losses. Preferably, an array of superconducting elements is encased within a second material with a high thermal conductivity. The second material is preferably a semiconductor. Alternatively, the superconducting material can be doped on a base semiconducting material, or the superconducting material and the semiconducting material can exist as alternating, interleaved layers of waferlike materials. A temperature gradient imposed across the boundary of the two materials establishes an electrical potential related to the magnitude of the temperature gradient. The superconducting material carries the resulting electrical current at zero resistivity, thereby eliminating resistive losses. The elimination of resistive losses significantly increases the conversion efficiency of the thermoelectric device. 4 figs.

  6. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, John D.; El-Genk, Mohamed S.

    1998-01-01

    An apparatus and method for producing electricity from heat. The present invention is a thermoelectric generator that uses materials with substantially no electrical resistance, often called superconductors, to efficiently convert heat into electrical energy without resistive losses. Preferably, an array of superconducting elements is encased within a second material with a high thermal conductivity. The second material is preferably a semiconductor. Alternatively, the superconducting material can be doped on a base semiconducting material, or the superconducting material and the semiconducting material can exist as alternating, interleaved layers of waferlike materials. A temperature gradient imposed across the boundary of the two materials establishes an electrical potential related to the magnitude of the temperature gradient. The superconducting material carries the resulting electrical current at zero resistivity, thereby eliminating resistive losses. The elimination of resistive losses significantly increases the conversion efficiency of the thermoelectric device.

  7. Thermoelectric generator

    DOE Patents [OSTI]

    Pryslak, N.E.

    1974-02-26

    A thermoelectric generator having a rigid coupling or stack'' between the heat source and the hot strap joining the thermoelements is described. The stack includes a member of an insulating material, such as ceramic, for electrically isolating the thermoelements from the heat source, and a pair of members of a ductile material, such as gold, one each on each side of the insulating member, to absorb thermal differential expansion stresses in the stack. (Official Gazette)

  8. 2009 Thermoelectrics Applications Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics Applications Workshop 2009 Thermoelectrics Applications Workshop September 29 - October 1, 2009 San Diego, CA Tuesday, September 29, 2009 Opening Plenary Session Wednesday, September 30, 2009 Overview of Worldwide Activities in Thermoelectrics Thermoelectric Applications I Thermoelectric Materials I Thermoelectric Manufacturing Thursday, October 1, 2009 Thermoelectric Materials II Thermoelectric Applications II Thermoelectric Materials III Thermoelectric Applications III Tuesday,

  9. Electroforming of Bi(1-x)Sb(x) nanowires for high-efficiency micro-thermoelectric cooling devices on a chip.

    SciTech Connect (OSTI)

    Overmyer, Donald L.; Webb, Edmund Blackburn, III; Siegal, Michael P.; Yelton, William Graham

    2006-11-01

    Active cooling of electronic systems for space-based and terrestrial National Security missions has demanded use of Stirling, reverse-Brayton, closed Joule-Thompson, pulse tube and more elaborate refrigeration cycles. Such cryocoolers are large systems that are expensive, demand large powers, often contain moving parts and are difficult to integrate with electronic systems. On-chip, solid-state, active cooling would greatly enhance the capabilities of future systems by reducing the size, cost and inefficiencies compared to existing solutions. We proposed to develop the technology for a thermoelectric cooler capable of reaching 77K by replacing bulk thermoelectric materials with arrays of Bi{sub 1-x}Sb{sub x} nanowires. Furthermore, the Sandia-developed technique we will use to produce the oriented nanowires occurs at room temperature and can be applied directly to a silicon substrate. Key obstacles include (1) optimizing the Bi{sub 1-x}Sb{sub x} alloy composition for thermoelectric properties; (2) increasing wire aspect ratios to 3000:1; and (3) increasing the array density to {ge} 10{sup 9} wires/cm{sup 2}. The primary objective of this LDRD was to fabricate and test the thermoelectric properties of arrays of Bi{sub 1-x}Sb{sub x} nanowires. With this proof-of-concept data under our belts we are positioned to engage National Security systems customers to invest in the integration of on-chip thermoelectric coolers for future missions.

  10. Effective thermal conductivity in thermoelectric materials

    SciTech Connect (OSTI)

    Baranowski, LL; Snyder, GJ; Toberer, ES

    2013-05-28

    Thermoelectric generators (TEGs) are solid state heat engines that generate electricity from a temperature gradient. Optimizing these devices for maximum power production can be difficult due to the many heat transport mechanisms occurring simultaneously within the TEG. In this paper, we develop a model for heat transport in thermoelectric materials in which an "effective thermal conductivity" (kappa(eff)) encompasses both the one dimensional steady-state Fourier conduction and the heat generation/consumption due to secondary thermoelectric effects. This model is especially powerful in that the value of kappa(eff) does not depend upon the operating conditions of the TEG but rather on the transport properties of the TE materials themselves. We analyze a variety of thermoelectric materials and generator designs using this concept and demonstrate that kappa(eff) predicts the heat fluxes within these devices to 5% of the exact value. (C) 2013 AIP Publishing LLC.

  11. Challenges and Opportunities in Thermoelectric Energy Conversion |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Conversion Challenges and Opportunities in Thermoelectric Energy Conversion 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Lawrence Berkeley Laboratory 2004_deer_majumdar.pdf (1.3 MB) More Documents & Publications High performance Zintl phase TE materials with embedded nanoparticles High performance Zintl phase TE materials with embedded nanoparticles Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI

  12. Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat

    Broader source: Energy.gov (indexed) [DOE]

    Recovery Applications | Department of Energy Progress in reliable high temperature segmented thermoelectric devices and potential for producing electricity from waste heat from energy intensive industrial processes and transportation vehicles exhaust are discussed fluerial.pdf (3.11 MB) More Documents & Publications Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat Recovery Applications High Reliability, High TemperatureThermoelectric Power Generation Materials and

  13. Waste Heat Recovery Opportunities for Thermoelectric Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat Recovery Opportunities for Thermoelectric Generators Waste Heat Recovery Opportunities for Thermoelectric Generators Thermoelectrics have unique advantages for ...

  14. Thermoelectrics Partnership: Automotive Thermoelectric Modules with

    Broader source: Energy.gov (indexed) [DOE]

    Scalable Thermo- and Electro-Mechanical Interfaces | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ace067_goodson_2012_o.pdf (5.6 MB) More Documents & Publications Novel Nanostructured Interface Solution for Automotive Thermoelectric Modules Application Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces

  15. Thermoelectrics Partnership: Automotive Thermoelectric Modules with

    Broader source: Energy.gov (indexed) [DOE]

    Scalable Thermo- and Electro-Mechanical Interfaces | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace067_goodson_2011_o.pdf (1.89 MB) More Documents & Publications Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces Novel Nanostructured Interface Solution for Automotive Thermoelectric Modules Application

  16. Determination of Thermoelectric Module Efficiency A Survey

    SciTech Connect (OSTI)

    Wang, Hsin; McCarty, Robin; Salvador, James R.; Yamamoto, Atsushi; Konig, Jan

    2014-01-01

    The development of thermoelectrics (TE) for energy conversion is in the transition phase from laboratory research to device development. There is an increasing demand to accurately determine the module efficiency, especially for the power generation mode. For many thermoelectrics, the figure of merit, ZT, of the material sometimes cannot be fully realized at the device level. Reliable efficiency testing of thermoelectric modules is important to assess the device ZT and provide the end-users with realistic values on how much power can be generated under specific conditions. We conducted a general survey of efficiency testing devices and their performance. The results indicated the lack of industry standards and test procedures. This study included a commercial test system and several laboratory systems. Most systems are based on the heat flow meter method and some are based on the Harman method. They are usually reproducible in evaluating thermoelectric modules. However, cross-checking among different systems often showed large errors that are likely caused by unaccounted heat loss and thermal resistance. Efficiency testing is an important area for the thermoelectric community to focus on. A follow-up international standardization effort is planned.

  17. Component for thermoelectric generator

    DOE Patents [OSTI]

    Purdy, David L.

    1977-01-01

    In a thermoelectric generator, a component comprises a ceramic insulator, having over limited areas thereof, each area corresponding to a terminal end of thermoelectric wires, a coating of a first metal which adheres to the insulator, and an electrical thermoelectric junction including a second metal which wets said first metal and adheres to said terminal ends but does not wet said insulator, and a cloth composed of electrically insulating threads interlaced with thermoelectric wires.

  18. Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat Recovery Applications

    Broader source: Energy.gov [DOE]

    Progress in reliable high temperature segmented thermoelectric devices and potential for producing electricity from waste heat from energy intensive industrial processes and transportation vehicles exhaust are discussed

  19. Advanced Thin Film Thermoelectric Systems forEfficient Air-Conditioner...

    Broader source: Energy.gov (indexed) [DOE]

    Presents recent advances in thermoelectric device fabrication and the design of novel coolingheating engines exploiting thermal storage for efficient air-conditioners in ...

  20. Micro- & Nano-Technologies Enabling More Compact, Lightweight Thermoelectric Power Generation & Cooling Systems

    Broader source: Energy.gov [DOE]

    Advanced thermoelectric energy recovery and cooling system weight and volume improvements with low-cost microtechnology heat and mass transfer devices are presented

  1. Advanced Thin Film Thermoelectric Systems forEfficient Air-Conditioners

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presents recent advances in thermoelectric device fabrication and the design of novel cooling/heating engines exploiting thermal storage for efficient air-conditioners in automobiles

  2. Thermoelectric materials having porosity

    DOE Patents [OSTI]

    Heremans, Joseph P.; Jaworski, Christopher M.; Jovovic, Vladimir; Harris, Fred

    2014-08-05

    A thermoelectric material and a method of making a thermoelectric material are provided. In certain embodiments, the thermoelectric material comprises at least 10 volume percent porosity. In some embodiments, the thermoelectric material has a zT greater than about 1.2 at a temperature of about 375 K. In some embodiments, the thermoelectric material comprises a topological thermoelectric material. In some embodiments, the thermoelectric material comprises a general composition of (Bi.sub.1-xSb.sub.x).sub.u(Te.sub.1-ySe.sub.y).sub.w, wherein 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.1, 1.8.ltoreq.u.ltoreq.2.2, 2.8.ltoreq.w.ltoreq.3.2. In further embodiments, the thermoelectric material includes a compound having at least one group IV element and at least one group VI element. In certain embodiments, the method includes providing a powder comprising a thermoelectric composition, pressing the powder, and sintering the powder to form the thermoelectric material.

  3. New Composite Thermoelectric Materials for Macro-size Applications

    ScienceCinema (OSTI)

    Dresselhaus, Mildred [MIT, Cambridge, Massachusetts, United States

    2010-01-08

    A review will be given of several important recent advances in both thermoelectrics research and industrial thermoelectric applications, which have attracted much attention, increasing incentives for developing advanced materials appropriate for large-scale applications of thermoelectric devices. One promising strategy is the development of materials with a dense packing of random nanostructures as a route for the sacle-up of thermoelectrics applications. The concepts involved in designing composite materials containing nanostructures for thermoelectric applications will be discussed in general terms. Specific application is made to the Bi{sub 2}Te{sub 3} nanocomposite system for use in power generation. Also emphasized are the scientific advantages of the nanocomposite approach for the simultaneous increase in the power factor and decrease of the thermal conductivity, along with the practical advantages of having bulk samples for property measurements and device applications. A straightforward path is identified for the scale-up of thermoelectric materials synthesis containing nanostructured constituents for use in thermoelectric applications. We end with some vision of where the field of thermoelectrics is now heading.

  4. Nanostructured Thermoelectrics. The New Paradigm

    Broader source: Energy.gov [DOE]

    Highlights advances and future strategies for enhancing the thermoelectric figure of merit of bulk nanostructured thermoelectric and materials using low cost earth abundant elements

  5. Thermoelectric heat exchange element

    DOE Patents [OSTI]

    Callas, James J.; Taher, Mahmoud A.

    2007-08-14

    A thermoelectric heat exchange module includes a first substrate including a heat receptive side and a heat donative side and a series of undulatory pleats. The module may also include a thermoelectric material layer having a ZT value of 1.0 or more disposed on at least one of the heat receptive side and the heat donative side, and an electrical contact may be in electrical communication with the thermoelectric material layer.

  6. Solar Thermoelectric Energy Conversion

    Office of Energy Efficiency and Renewable Energy (EERE)

    Efficiencies of different types of solar thermoelectric generators were predicted using theoretical modeling and validated with measurements using constructed prototypes under different solar intensities

  7. Mechanical Response of Thermoelectric Materials

    SciTech Connect (OSTI)

    Wereszczak, Andrew A.; Case, Eldon D.

    2015-05-01

    A sufficient mechanical response of thermoelectric materials (TEMats) to structural loadings is a prerequisite to the exploitation of any candidate TEMat's thermoelectric efficiency. If a TEMat is mechanically damaged or cracks from service-induced stresses, then its thermal and electrical functions can be compromised or even cease. Semiconductor TEMats tend to be quite brittle and have a high coefficient of thermal expansion; therefore, they can be quite susceptible to mechanical failure when subjected to operational thermal gradients. Because of this, sufficient mechanical response (vis-a-vis, mechanical properties) of any candidate TEMat must be achieved and sustained in the context of the service-induced stress state to which it is subjected. This report provides an overview of the mechanical responses of state-of-the-art TEMats; discusses the relevant properties that are associated with those responses and their measurement; and describes important, nonequilibrium phenomena that further complicate their use in thermoelectric devices. For reference purposes, the report also includes several appendixes that list published data on elastic properties and strengths of a variety of TEMats.

  8. Holey Silicon as an Efficient Thermoelectric Material

    SciTech Connect (OSTI)

    Tang, Jinyao; Wang, Hung-Ta; Hyun Lee, Dong; Fardy, Melissa; Huo, Ziyang; Russell, Thomas P.; Yang, Peidong

    2010-09-30

    This work investigated the thermoelectric properties of thin silicon membranes that have been decorated with high density of nanoscopic holes. These ?holey silicon? (HS) structures were fabricated by either nanosphere or block-copolymer lithography, both of which are scalable for practical device application. By reducing the pitch of the hexagonal holey pattern down to 55 nm with 35percent porosity, the thermal conductivity of HS is consistently reduced by 2 orders of magnitude and approaches the amorphous limit. With a ZT value of 0.4 at room temperature, the thermoelectric performance of HS is comparable with the best value recorded in silicon nanowire system.

  9. Synthesis and Evaluation of Single Layer, Bilayer, and Multilayer Thermoelectric Thin Films

    DOE R&D Accomplishments [OSTI]

    Farmer, J. C.; Barbee, T. W. Jr.; Chapline, G. C. Jr.; Olsen, M. L.; Foreman, R. J.; Summers, L. J.; Dresselhaus, M. S.; Hicks, L. D.

    1995-01-20

    The relative efficiency of a thermoelectric material is measured in terms of a dimensionless figure of merit, ZT. Though all known thermoelectric materials are believed to have ZT{le}1, recent theoretical results predict that thermoelectric devices fabricated as two-dimensional quantum wells (2D QWs) or one-dimensional (ID) quantum wires could have ZT{ge}3. Multilayers with the dimensions of 2D QWs have been synthesized by alternately sputtering thermoelectric and barrier materials onto a moving single-crystal sapphire substrate from dual magnetrons. These materials have been used to test the thermoelectric quantum well concept and gain insight into relevant transport mechanisms. If successful, research could lead to thermoelectric devices that have efficiencies close to that of an ideal Carnot engine. Ultimately, such devices could be used to replace conventional heat engines and mechanical refrigeration systems.

  10. Thermoelectric Mechanical Reliability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    0_wereszczak.pdf (1.52 MB) More Documents & Publications Thermoelectric Mechanical Reliability Thermoelectric Mechanical Reliability Thermoelectrics Theory and Structure

  11. Vehicular Thermoelectric Applications Session DEER 2009 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Applications Session DEER 2009 Vehicular Thermoelectric Applications Session DEER 2009 This presentation is an overview of the DOE thermoelectric program. ...

  12. Challenges and Opportunities in Thermoelectric Materials Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Challenges and Opportunities in Thermoelectric Materials Research for Automotive ... The Bottom-Up Approach forThermoelectric Nanocomposites, plus NSFDOE Thermoelectric ...

  13. Thermoelectrics: The New Green Automotive Technology | Department...

    Broader source: Energy.gov (indexed) [DOE]

    (2.09 MB) More Documents & Publications Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: The New Green

  14. Thermoelectrics: The New Green Automotive Technology | Department...

    Broader source: Energy.gov (indexed) [DOE]

    (5.35 MB) More Documents & Publications Automotive Thermoelectric Generators and HVAC Vehicular Thermoelectrics: A New Green Technology Thermoelectrics: The New Green Automotive

  15. Vehicular Thermoelectrics: A New Green Technology | Department...

    Broader source: Energy.gov (indexed) [DOE]

    (3.68 MB) More Documents & Publications Thermoelectrics: The New Green Automotive Technology Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: The

  16. Automotive Thermoelectric Generators and HVAC

    Broader source: Energy.gov [DOE]

    Provides overview of DOE-supported projects in automotive thermoelectric generators and heaters/air conditioners

  17. Complex oxides useful for thermoelectric energy conversion

    SciTech Connect (OSTI)

    Majumdar, Arunava; Ramesh, Ramamoorthy; Yu, Choongho; Scullin, Matthew L.; Huijben, Mark

    2012-07-17

    The invention provides for a thermoelectric system comprising a substrate comprising a first complex oxide, wherein the substrate is optionally embedded with a second complex oxide. The thermoelectric system can be used for thermoelectric power generation or thermoelectric cooling.

  18. Proactive Strategies for Designing Thermoelectric Materials for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Proactive Strategies for Designing Thermoelectric Materials for Power Generation Proactive Strategies for Designing Thermoelectric Materials for Power ...

  19. Encapsulation of High Temperature Thermoelectric Modules | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Encapsulation of High Temperature Thermoelectric Modules Encapsulation of High Temperature Thermoelectric Modules Presents concept for hermetic encapsulation of TE modules ...

  20. Thermoelectric Generator Development for Automotive Waste Heat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generator Development for Automotive Waste Heat Recovery Thermoelectric Generator ... More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat ...

  1. Novel Nanostructured Interface Solution for Automotive Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Electro-Mechanical Interfaces Thermoelectrics Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces Automotive ...

  2. Commercialization of Bulk Thermoelectric Materials for Power...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercialization of Bulk Thermoelectric Materials for Power Generation Commercialization of Bulk Thermoelectric Materials for Power Generation Critical aspects of technology ...

  3. Concentrated Solar Thermoelectric Power

    SciTech Connect (OSTI)

    Chen, Gang; Ren, Zhifeng

    2015-07-09

    The goal of this project is to demonstrate in the lab that solar thermoelectric generators (STEGs) can exceed 10% solar-to-electricity efficiency, and STEGs can be integrated with phase-change materials (PCM) for thermal storage, providing operation beyond daylight hours. This project achieved significant progress in many tasks necessary to achieving the overall project goals. An accurate Themoelectric Generator (TEG) model was developed, which included realistic treatment of contact materials, contact resistances and radiative losses. In terms of fabricating physical TEGs, high performance contact materials for skutterudite TE segments were developed, along with brazing and soldering methods to assemble segmented TEGs. Accurate measurement systems for determining device performance (in addition to just TE material performance) were built for this project and used to characterize our TEGs. From the optical components’ side, a spectrally selective cermet surface was developed with high solar absorptance and low thermal emittance, with thermal stability at high temperature. A measurement technique was also developed to determine absorptance and total hemispherical emittance at high temperature, and was used to characterize the fabricated spectrally selective surfaces. In addition, a novel reflective cavity was designed to reduce radiative absorber losses and achieve high receiver efficiency at low concentration ratios. A prototype cavity demonstrated that large reductions in radiative losses were possible through this technique. For the overall concentrating STEG system, a number of devices were fabricated and tested in a custom built test platform to characterize their efficiency performance. Additionally, testing was performed with integration of PCM thermal storage, and the storage time of the lab scale system was evaluated. Our latest testing results showed a STEG efficiency of 9.6%, indicating promising potential for high performance concentrated STEGs.

  4. Thermoelectric energy converter for generation of electricity from low-grade heat

    DOE Patents [OSTI]

    Jayadev, T.S.; Benson, D.K.

    1980-05-27

    A thermoelectric energy conversion device which includes a plurality of thermoelectric elements is described. A hot liquid is supplied to one side of each element and a cold liquid is supplied to the other side of each element. The thermoelectric generator may be utilized to produce power from low-grade heat sources such as ocean thermal gradients, solar ponds, and low-grade geothermal resources. (WHK)

  5. Quantum interference in thermoelectric molecular junctions: A toy model perspective

    SciTech Connect (OSTI)

    Nozaki, Daijiro E-mail: research@nano.tu-dresden.de; Avdoshenko, Stas M.; Sevinçli, Hâldun; Cuniberti, Gianaurelio

    2014-08-21

    Quantum interference (QI) phenomena between electronic states in molecular circuits offer a new opportunity to design new types of molecular devices such as molecular sensors, interferometers, and thermoelectric devices. Controlling the QI effect is a key challenge for such applications. For the development of single molecular devices employing QI effects, a systematic study of the relationship between electronic structure and the quantum interference is needed. In order to uncover the essential topological requirements for the appearance of QI effects and the relationship between the QI-affected line shape of the transmission spectra and the electronic structures, we consider a homogeneous toy model where all on-site energies are identical and model four types of molecular junctions due to their topological connectivities. We systematically analyze their transmission spectra, density of states, and thermoelectric properties. Even without the degree of freedom for on-site energies an asymmetric Fano peak could be realized in the homogeneous systems with the cyclic configuration. We also calculate the thermoelectric properties of the model systems with and without fluctuation of on-site energies. Even under the fluctuation of the on-site energies, the finite thermoelectrics are preserved for the Fano resonance, thus cyclic configuration is promising for thermoelectric applications. This result also suggests the possibility to detect the cyclic configuration in the homogeneous systems and the presence of the QI features from thermoelectric measurements.

  6. Solar thermoelectric generator

    DOE Patents [OSTI]

    Toberer, Eric S.; Baranowski, Lauryn L.; Warren, Emily L.

    2016-05-03

    Solar thermoelectric generators (STEGs) are solid state heat engines that generate electricity from concentrated sunlight. A novel detailed balance model for STEGs is provided and applied to both state-of-the-art and idealized materials. STEGs can produce electricity by using sunlight to heat one side of a thermoelectric generator. While concentrated sunlight can be used to achieve extremely high temperatures (and thus improved generator efficiency), the solar absorber also emits a significant amount of black body radiation. This emitted light is the dominant loss mechanism in these generators. In this invention, we propose a solution to this problem that eliminates virtually all of the emitted black body radiation. This enables solar thermoelectric generators to operate at higher efficiency and achieve said efficient with lower levels of optical concentration. The solution is suitable for both single and dual axis solar thermoelectric generators.

  7. Thermoelectric HVAC and Thermal Comfort Enablers for Light-Duty Vehicle

    Broader source: Energy.gov (indexed) [DOE]

    Applications | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ace047_maranville_2012_o.pdf (1.03 MB) More Documents & Publications Thermoelectric HVAC for Light-Duty Vehicle Applications Improving efficiency of a vehicle HVAC system with comfort modeling, zonal design, and thermoelectric devices

  8. Amplification and reversal of Knudsen force by thermoelectric heating

    SciTech Connect (OSTI)

    O'Neill, William J.; Wada, Mizuki; Strongrich, Andrew D.; Cofer, Anthony; Alexeenko, Alina A.

    2014-12-09

    We show that the Knudsen thermal force generated by a thermally-induced flow over a heated beam near a colder wall could be amplified significantly by thermoelectric heating. Bidirectional actuation is achieved by switching the polarity of the thermoelectric device bias voltage. The measurements of the resulting thermal forces at different rarefaction regimes, realized by changing geometry and gas pressure, are done using torsional microbalance. The repulsive or attractive forces between a thermoelectrically heated or cooled plate and a substrate are shown to be up to an order of magnitude larger than for previously studied configurations and heating methods due to favorable coupling of two thermal gradients. The amplification and reversal of the Knudsen force is confirmed by numerical solution of the Boltzmann-ESBGK kinetic model equation. Because of the favorable scaling with decreasing system size, the Knudsen force with thermoelectric heating offers a novel actuation and sensing mechanism for nano/microsystems.

  9. Superconducting thermoelectric generator

    DOE Patents [OSTI]

    Metzger, J.D.; El-Genk, M.S.

    1994-01-01

    Thermoelectricity is produced by applying a temperature differential to dissimilar electrically conducting or semiconducting materials, thereby producing a voltage that is proportional to the temperature difference. Thermoelectric generators use this effect to directly convert heat into electricity; however, presently-known generators have low efficiencies due to the production of high currents which in turn cause large resistive heating losses. Some thermoelectric generators operate at efficiencies between 4% and 7% in the 800{degrees} to 1200{degrees}C range. According to its major aspects and bradly stated, the present invention is an apparatus and method for producing electricity from heat. In particular, the invention is a thermoelectric generator that juxtaposes a superconducting material and a semiconducting material - so that the superconducting and the semiconducting materials touch - to convert heat energy into electrical energy without resistive losses in the temperature range below the critical temperature of the superconducting material. Preferably, an array of superconducting material is encased in one of several possible configurations within a second material having a high thermal conductivity, preferably a semiconductor, to form a thermoelectric generator.

  10. Advanced Thermoelectric Materials for Efficient Waste Heat Recovery in Process Industries

    SciTech Connect (OSTI)

    Adam Polcyn; Moe Khaleel

    2009-01-06

    The overall objective of the project was to integrate advanced thermoelectric materials into a power generation device that could convert waste heat from an industrial process to electricity with an efficiency approaching 20%. Advanced thermoelectric materials were developed with figure-of-merit ZT of 1.5 at 275 degrees C. These materials were not successfully integrated into a power generation device. However, waste heat recovery was demonstrated from an industrial process (the combustion exhaust gas stream of an oxyfuel-fired flat glass melting furnace) using a commercially available (5% efficiency) thermoelectric generator coupled to a heat pipe. It was concluded that significant improvements both in thermoelectric material figure-of-merit and in cost-effective methods for capturing heat would be required to make thermoelectric waste heat recovery viable for widespread industrial application.

  11. Proactive Strategies for Designing Thermoelectric Materials for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Proactive Strategies for Designing Thermoelectric Materials for Power Generation Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite ...

  12. Integrated Design and Manufacturing of Thermoelectric Generator...

    Broader source: Energy.gov (indexed) [DOE]

    Presents progress in cost-effective thermoelectric generator fabrication by thermal spraying of thermoelectric materials and other functional layers directly onto automotive ...

  13. Heilongjiang Mudanjiang Nongken Xinneng Thermoelectric Co Ltd...

    Open Energy Info (EERE)

    Heilongjiang Mudanjiang Nongken Xinneng Thermoelectric Co Ltd Jump to: navigation, search Name: Heilongjiang Mudanjiang Nongken Xinneng Thermoelectric Co., Ltd. Place: Mishan,...

  14. Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste Heat Recovery Nanostructured High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste ...

  15. Vehicular Applications of Thermoelectrics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overivew of DOE projects developing thermoelectric generators for engine waste heat utilization and vehiclular thermoelectric heatingcooling. deer08fairbanks.pdf (5.58 MB) More ...

  16. Concentrated Solar Thermoelectric Power | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrated Solar Thermoelectric Power Concentrated Solar Thermoelectric Power This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, ...

  17. Development of Thermoelectric Technology for Automotive Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Technology for Automotive Waste Heat Recovery Development of Thermoelectric Technology for Automotive Waste Heat Recovery Overview and status of project to develop ...

  18. Thermoelectric Power Generation System with Loop Thermosyphon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Power Generation System with Loop Thermosyphon in Future High Efficiency ... More Documents & Publications Low and high Temperature Dual Thermoelectric Generation ...

  19. Investigations of Interfacial Structure in Thermoelectric Tellurides...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigations of Interfacial Structure in Thermoelectric Tellurides Discusses examples of work on the investigation of atomic structure of interfaces in thermoelectric tellurides ...

  20. Vehicular Thermoelectrics: A New Green Technology | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (8.06 MB) More Documents & Publications Thermoelectrics: The New Green Automotive Technology Automotive Thermoelectric Generators and HVAC Solid-State Energy Conversion Overview

  1. Automotive Thermoelectric Generator (TEG) Controls

    Office of Energy Efficiency and Renewable Energy (EERE)

    Addresses functions to be controlled that make the difference between a barely functional and an efficient, cost-effective thermoelectric generator(TEG)

  2. Design and development of thermoelectric generator

    SciTech Connect (OSTI)

    Prem Kumar, D. S. Mahajan, Ishan Vardhan Anbalagan, R. Mallik, Ramesh Chandra

    2014-04-24

    In this paper we discuss the fabrication, working and characteristics of a thermoelectric generator made up of p and n type semiconductor materials. The device consists of Fe{sub 0.2}Co{sub 3.8}Sb{sub 11.5}Te{sub 0.5} (zT = 1.04 at 818 K) as the n-type and Zn4Sb3 (zT=0.8 at 550 K) as the p-type material synthesized by vacuum hot press method. Carbon paste has been used to join the semiconductor legs to metal (Molybdenum) electrodes to reduce the contact resistance. The multi-couple (4 legs) generator results a maximum output power of 1.083 mW at a temperature difference of 240 K between the hot and cold sides. In this investigation, an I-V characteristic, maximum output power of the thermoelectric module is presented. The efficiency of thermoelectric module is obtained as ? = 0.273 %.

  3. Thermoelectric generators incorporating phase-change materials for waste heat recovery from engine exhaust

    DOE Patents [OSTI]

    Meisner, Gregory P; Yang, Jihui

    2014-02-11

    Thermoelectric devices, intended for placement in the exhaust of a hydrocarbon fuelled combustion device and particularly suited for use in the exhaust gas stream of an internal combustion engine propelling a vehicle, are described. Exhaust gas passing through the device is in thermal communication with one side of a thermoelectric module while the other side of the thermoelectric module is in thermal communication with a lower temperature environment. The heat extracted from the exhaust gasses is converted to electrical energy by the thermoelectric module. The performance of the generator is enhanced by thermally coupling the hot and cold junctions of the thermoelectric modules to phase-change materials which transform at a temperature compatible with the preferred operating temperatures of the thermoelectric modules. In a second embodiment, a plurality of thermoelectric modules, each with a preferred operating temperature and each with a uniquely-matched phase-change material may be used to compensate for the progressive lowering of the exhaust gas temperature as it traverses the length of the exhaust pipe.

  4. Modular Isotopic Thermoelectric Generator

    SciTech Connect (OSTI)

    Schock, Alfred

    1981-01-01

    Advanced RTG concepts utilizing improved thermoelectric materials and converter concepts are under study at Fairchild for DOE. The design described here is based on DOE's newly developed radioisotope heat source, and on an improved silicon-germanium material and multicouple converter module under development at Syncal. Fairchild's assignment was to combine the above into an attractive power system for use in space, and to assess the specific power and other attributes of that design.

  5. Modular Isotopic Thermoelectric Generator

    SciTech Connect (OSTI)

    Schock, Alfred

    1981-04-03

    Advanced RTG concepts utilizing improved thermoelectric materials and converter concepts are under study at Fairchild for DOE. The design described here is based on DOE's newly developed radioisotope heat source, and on an improved silicon-germanium material and a multicouple converter module under development at Syncal. Fairchild's assignment was to combine the above into an attractive power system for use in space, and to assess the specific power and other attributes of that design. The resultant design is highly modular, consisting of standard RTG slices, each producing ~24 watts at the desired output voltage of 28 volt. Thus, the design could be adapted to various space missions over a wide range of power levels, with little or no redesign. Each RTG slice consists of a 250-watt heat source module, eight multicouple thermoelectric modules, and standard sections of insulator, housing, radiator fins, and electrical circuit. The design makes it possible to check each thermoelectric module for electrical performance, thermal contact, leaktightness, and performance stability, after the generator is fully assembled; and to replace any deficient modules without disassembling the generator or perturbing the others. The RTG end sections provide the spring-loaded supports required to hold the free-standing heat source stack together during launch vibration. Details analysis indicates that the design offers a substantial improvement in specific power over the present generator of RTGs, using the same heat source modules. There are three copies in the file.

  6. Recent Device Developments with Advanced Bulk Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and nano-bulk materials with high ZT undertaken by RTI in collaboration with its research partners venkatasubramanian.pdf (1.82 MB) More Documents & Publications Nano-structur...

  7. Progress in Thermoelectrical Energy Recovery from a Light Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Thermoelectrical Energy Recovery From the Exhaust of a Light Truck Automotive Thermoelectric Generators and HVAC

  8. NSF/DOE Thermoelectric Partnership: Inorganic-Organic Hybrid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inorganic-Organic Hybrid Thermoelectrics NSFDOE Thermoelectric Partnership: Inorganic-Organic Hybrid Thermoelectrics 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle ...

  9. Role of Thermoelectrics in Vehicle Efficiency Increase | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Status of the Application of Thermoelectric Technology in Vehicles Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle Applications Thermoelectric ...

  10. Development of a 100-Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 100-Watt High Temperature Thermoelectric Generator Development of a 100-Watt High Temperature Thermoelectric Generator Test results for low and high temperature thermoelectric ...

  11. Quantum Well Thermoelectrics and Waste Heat Recovery | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation Recent Progress in the Development of High Efficiency Thermoelectrics High Temperature Thermoelectric ...

  12. Semiconductor-based, large-area, flexible, electronic devices

    DOE Patents [OSTI]

    Goyal, Amit

    2011-03-15

    Novel articles and methods to fabricate the same resulting in flexible, large-area, triaxially textured, single-crystal or single-crystal-like, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  13. Methods of synthesizing thermoelectric materials

    DOE Patents [OSTI]

    Ren, Zhifeng; Chen, Shuo; Liu, Wei-Shu; Wang, Hengzhi; Wang, Hui; Yu, Bo; Chen, Gang

    2016-04-05

    Methods for synthesis of thermoelectric materials are disclosed. In some embodiments, a method of fabricating a thermoelectric material includes generating a plurality of nanoparticles from a starting material comprising one or more chalcogens and one or more transition metals; and consolidating the nanoparticles under elevated pressure and temperature, wherein the nanoparticles are heated and cooled at a controlled rate.

  14. 3rd Thermoelectrics Applications Workshop 2012

    Broader source: Energy.gov [DOE]

    Tuesday, March 20, 2012Opening Plenary SessionThermoelectric Applications IThermoelectric Applications IIThermoelectric Technologies

  15. Investigations of Interfacial Structure in Thermoelectric Tellurides

    Office of Energy Efficiency and Renewable Energy (EERE)

    Discusses examples of work on the investigation of atomic structure of interfaces in thermoelectric tellurides

  16. Concentrated Thermoelectric Power

    Broader source: Energy.gov [DOE]

    This fact sheet describes a concentrated solar hydroelectric power project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by MIT, is working to demonstrate concentrating solar thermoelectric generators with >10% solar-to-electrical energy conversion efficiency while limiting optical concentration to less than a factor of 10 and potentially less than 4. When combined with thermal storage, CSTEGs have the potential to provide electricity day and night using no moving parts at both the utility and distributed scale.

  17. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat Recovery Engineering and Materials for Automotive Thermoelectric Applications Electrical ...

  18. NSF/DOE Thermoelectics Partnership: Thermoelectrics for Automotive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectics Partnership: Thermoelectrics for Automotive Waste Heat Recovery NSFDOE Thermoelectics Partnership: Thermoelectrics for Automotive Waste Heat Recovery 2011 DOE ...

  19. Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Caterpillar Diesel Racing: Yesterday & Today Thermoelectric Conversion of ...

  20. NSF/DOE Thermoelectrics Partnership: Purdue … GM Partnership...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces NSFDOE Thermoelectics Partnership: Thermoelectrics for Automotive Waste Heat ...

  1. Thermal Strategies for High Efficiency Thermoelectric Power Generation...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Proactive Strategies for Designing Thermoelectric Materials for Power Generation Proactive Strategies for Designing Thermoelectric Materials for Power ...

  2. Thermoelectric generator for motor vehicle

    DOE Patents [OSTI]

    Bass, John C.

    1997-04-29

    A thermoelectric generator for producing electric power for a motor vehicle from the heat of the exhaust gasses produced by the engine of the motor vehicle. The exhaust gasses pass through a finned heat transfer support structure which has seat positions on its outside surface for the positioning of thermoelectric modules. A good contact cylinder provides a framework from which a spring force can be applied to the thermoelectric modules to hold them in good contact on their seats on the surface of the heat transfer support structure.

  3. NSF/DOE Thermoelectics Partnership: Thermoelectrics for Automotive Waste

    Broader source: Energy.gov (indexed) [DOE]

    Heat Recovery | Department of Energy 4_xu_2011_p.pdf (2.97 MB) More Documents & Publications NSF/DOE Thermoelectrics Partnership: Purdue … GM Partnership on Thermoelectrics for Automotive Waste Heat Recovery NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive Waste Heat Recovery NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive Waste Heat Recovery

  4. Thermoelectric power source utilizing ambient energy harvesting for remote sensing and transmitting

    DOE Patents [OSTI]

    DeSteese, John G

    2010-11-16

    A method and apparatus for providing electrical energy to an electrical device wherein the electrical energy is originally generated from temperature differences in an environment having a first and a second temperature region. A thermoelectric device having a first side and a second side wherein the first side is in communication with a means for transmitting ambient thermal energy collected or rejected in the first temperature region and the second side is in communication with the second temperature region thereby producing a temperature gradient across the thermoelectric device and in turn generating an electrical current.

  5. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle

    SciTech Connect (OSTI)

    2012-01-31

    The thermoelectric generator shorting system provides the capability to monitor and short-out individual thermoelectric couples in the event of failure. This makes the series configured thermoelectric generator robust to individual thermoelectric couple failure. Open circuit detection of the thermoelectric couples and the associated short control is a key technique to ensure normal functionality of the TE generator under failure of individual TE couples. This report describes a five-year effort whose goal was the understanding the issues related to the development of a thermoelectric energy recovery device for a Class-8 truck. Likely materials and important issues related to the utility of this generator were identified. Several prototype generators were constructed and demonstrated. The generators developed demonstrated several new concepts including advanced insulation, couple bypass technology and the first implementation of skutterudite thermoelectric material in a generator design. Additional work will be required to bring this system to fruition. However, such generators offer the possibility of converting energy that is otherwise wasted to useful electric power. Uur studies indicate that this can be accomplished in a cost-effective manner for this application.

  6. Materials strategies for improving the overall device ZT | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy Discusses two strategies for increasing device ZT … Ag-doped PbTe/Ag2Te composites and Na doped MgxPb(1-x) Te alloys snyder.pdf (3.84 MB) More Documents & Publications Strategies for High Thermoelectric zT in Bulk Materials Strategies for High Thermoelectric zT in Bulk Materials Glass-like thermal conductivity in high efficiency thermoelectric materials

  7. Thermoelectric Applications to Truck Essential Power

    SciTech Connect (OSTI)

    John C. Bass; Norbert B. Elsner

    2001-12-12

    The subjects covered in this report are: thermoelectrics, 1-kW generator for diesel engine; self-powered heater; power for wireless data transmission; and quantum-well thermoelectrics.

  8. Benefits of Thermoelectric Technology for the Automobile

    Broader source: Energy.gov [DOE]

    Discusses improved fuel efficiency and other benefits of automotive application of thermoelectric (power generation and heating/cooling) and the need for production quantities of high-efficiency thermoelectric modules

  9. Phase Stability, Crystal Structure, and Thermoelectric Properties...

    Office of Scientific and Technical Information (OSTI)

    and Thermoelectric Properties of Cu12Sb4S13xSex Solid Solutions Citation Details In-Document Search Title: Phase Stability, Crystal Structure, and Thermoelectric Properties ...

  10. Exhaust gas bypass valve control for thermoelectric generator

    DOE Patents [OSTI]

    Reynolds, Michael G; Yang, Jihui; Meisner, Greogry P.; Stabler, Francis R.; De Bock, Hendrik Pieter Jacobus; Anderson, Todd Alan

    2012-09-04

    A method of controlling engine exhaust flow through at least one of an exhaust bypass and a thermoelectric device via a bypass valve is provided. The method includes: determining a mass flow of exhaust exiting an engine; determining a desired exhaust pressure based on the mass flow of exhaust; comparing the desired exhaust pressure to a determined exhaust pressure; and determining a bypass valve control value based on the comparing, wherein the bypass valve control value is used to control the bypass valve.

  11. Microscreen radiation shield for thermoelectric generator

    DOE Patents [OSTI]

    Hunt, Thomas K.; Novak, Robert F.; McBride, James R.

    1990-01-01

    The present invention provides a microscreen radiation shield which reduces radiative heat losses in thermoelectric generators such as sodium heat engines without reducing the efficiency of operation of such devices. The radiation shield is adapted to be interposed between a reaction zone and a means for condensing an alkali metal vapor in a thermoelectric generator for converting heat energy directly to electrical energy. The radiation shield acts to reflect infrared radiation emanating from the reaction zone back toward the reaction zone while permitting the passage of the alkali metal vapor to the condensing means. The radiation shield includes a woven wire mesh screen or a metal foil having a plurality of orifices formed therein. The orifices in the foil and the spacing between the wires in the mesh is such that radiant heat is reflected back toward the reaction zone in the interior of the generator, while the much smaller diameter alkali metal atoms such as sodium pass directly through the orifices or along the metal surfaces of the shield and through the orifices with little or no impedance.

  12. Thermoelectric Bulk Materials from the Explosive Consolidation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Bulk Materials from the Explosive Consolidation of Nanopowders Describes technique of explosively consolidating nanopowders to yield fully dense, consolidated, ...

  13. Development of Marine Thermoelectric Heat Recovery Systems

    Broader source: Energy.gov [DOE]

    Discusses benefits of integration of thermoelectrics into the marine industry, research program milestones, and prototype TEG design and integration

  14. Nanostructured Thermoelectric Materials and High Efficiency Power...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanostructured Thermoelectric Materials and High Efficiency Power Generation Modules Home ... electrical conductivity and thermopower and, simultaneously, low thermal conductivity. ...

  15. Reliability of Transport Properties for Bulk Thermoelectrics

    Broader source: Energy.gov [DOE]

    Presents international round-robin study to ensure quality of transport data and figure of merit of thermoelectric materials

  16. Thermoelectrics Theory and Structure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting pm013_singh_2012_o.pdf (1.45 MB) More Documents & Publications Thermoelectrics Theory and Structure Thermoelectric Materials for Automotive Applications Recent Theoretical Results for Advanced Thermoelectric Materials

  17. Semiconductor-based, large-area, flexible, electronic devices on {110}<100> oriented substrates

    SciTech Connect (OSTI)

    Goyal, Amit

    2014-08-05

    Novel articles and methods to fabricate the same resulting in flexible, oriented, semiconductor-based, electronic devices on {110}<100> textured substrates are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  18. [100] or [110] aligned, semiconductor-based, large-area, flexible, electronic devices

    SciTech Connect (OSTI)

    Goyal, Amit

    2015-03-24

    Novel articles and methods to fabricate the same resulting in flexible, large-area, [100] or [110] textured, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  19. Thermoelectric refrigerator having improved temperature stabilization means

    DOE Patents [OSTI]

    Falco, Charles M.

    1982-01-01

    A control system for thermoelectric refrigerators is disclosed. The thermoelectric refrigerator includes at least one thermoelectric element that undergoes a first order change at a predetermined critical temperature. The element functions as a thermoelectric refrigerator element above the critical temperature, but discontinuously ceases to function as a thermoelectric refrigerator element below the critical temperature. One example of such an arrangement includes thermoelectric refrigerator elements which are superconductors. The transition temperature of one of the superconductor elements is selected as the temperature control point of the refrigerator. When the refrigerator attempts to cool below the point, the metals become superconductors losing their ability to perform as a thermoelectric refrigerator. An extremely accurate, first-order control is realized.

  20. Potential Thermoelectric Applications in Diesel Vehicles | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Thermoelectric Applications in Diesel Vehicles Potential Thermoelectric Applications in Diesel Vehicles 2003 DEER Conference Presentation: BSST, LLC 2003_deer_crane.pdf (618.11 KB) More Documents & Publications Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Thermoelectrics: The New Green Automotive Technology Challenges and Opportunities in Thermoelectric Materials Research for Automotive Applications

  1. High Performance Bulk Thermoelectric Materials

    SciTech Connect (OSTI)

    Ren, Zhifeng

    2013-03-31

    Over 13 plus years, we have carried out research on electron pairing symmetry of superconductors, growth and their field emission property studies on carbon nanotubes and semiconducting nanowires, high performance thermoelectric materials and other interesting materials. As a result of the research, we have published 104 papers, have educated six undergraduate students, twenty graduate students, nine postdocs, nine visitors, and one technician.

  2. NSF/DOE Thermoelectrics Partnership: Purdue … GM Partnership on Thermoelectrics for Automotive Waste Heat Recovery

    Broader source: Energy.gov [DOE]

    Reviews results in developing commercially viable thermoelectric generators for efficient conversion of automotive exhaust waste heat to electricity

  3. Infrared and thermoelectric power generation in thin atomic layer deposited Nb-doped TiO{sub 2} films

    SciTech Connect (OSTI)

    Mann, Harkirat S.; Lang, Brian N.; Schwab, Yosyp; Scarel, Giovanna; Niemelä, Janne-Petteri; Karppinen, Maarit

    2015-01-15

    Infrared radiation is used to radiatively transfer heat to a nanometric power generator (NPG) device with a thermoelectric Nb-doped TiO{sub 2} film deposited by atomic layer deposition (ALD) as the active element, onto a borosilicate glass substrate. The linear rise of the produced voltage with respect to the temperature difference between the “hot” and “cold” junctions, typical of the Seebeck effect, is missing. The discovery of the violation of the Seebeck effect in NPG devices combined with the ability of ALD to tune thermoelectric thin film properties could be exploited to increase the efficiency of these devices for energy harvesting purposes.

  4. Inorganic-Organic Hybrid Thermoelectrics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inorganic-Organic Hybrid Thermoelectrics Inorganic-Organic Hybrid Thermoelectrics Large-scale synthesis of inorganic and organic nanomaterials (single-crystalline nanowires and ...

  5. A Thermoelectric Generator with an Intermediate Heat Exchanger...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System for Light-Duty Vehicles Thermoelectric Power Generation System with Loop Thermosyphon in Future High Efficiency Hybrid Vehicles Automotive Thermoelectric Generators and HVAC

  6. Progress toward Development of a High-Efficiency Zonal Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    toward Development of a High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Progress toward Development of a High-Efficiency Zonal Thermoelectric HVAC ...

  7. Glass-like thermal conductivity in high efficiency thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermal conductivity in high efficiency thermoelectric materials Glass-like thermal conductivity in high efficiency thermoelectric materials Discusses strategies to design ...

  8. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermoelectrics on a OTR truck PDF icon schock.pdf More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle...

  9. Overview of Progress in Thermoelectric Power Generation Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overview of Thermoelectric Power Generation Technologies in Japan Overview of Thermoelectric Power Generation Technologies in Japan Overview of Japanese Activities in ...

  10. Innovative Nano-structuring Routes for Novel ThermoelectricMaterials...

    Broader source: Energy.gov (indexed) [DOE]

    Presents new concepts for high performance nanostructured bulk thermoelectric materials lee.pdf (1.98 MB) More Documents & Publications Thermoelectric Materials for Automotive ...

  11. An Overview of Thermoelectric Waste Heat Recovery Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An Overview of Thermoelectric Waste Heat Recovery Activities in Europe An Overview of Thermoelectric Waste Heat Recovery Activities in Europe An overview presentation of R&D ...

  12. Probing strong Kondo disorder with measurements of thermoelectric...

    Office of Scientific and Technical Information (OSTI)

    Probing strong Kondo disorder with measurements of thermoelectric power Title: Probing strong Kondo disorder with measurements of thermoelectric power Authors: White, B. D. ; ...

  13. Thermoelectrics: From Space Power Systems to Terrestrial Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat Recovery Applications Thermoelectrics: From Space Power Systems to Terrestrial Waste Heat Recovery Applications ...

  14. Nanostructures boost the thermoelectric performance of PbS (Journal...

    Office of Scientific and Technical Information (OSTI)

    Nanostructures boost the thermoelectric performance of PbS Citation Details In-Document Search Title: Nanostructures boost the thermoelectric performance of PbS In situ ...

  15. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Broader source: Energy.gov (indexed) [DOE]

    Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Development of Cost-Competitive ...

  16. A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel Process Employing Heterometallic Alkoxides A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel ...

  17. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Develop thermoelectric technology for waste heat recovery with a 10% fuel economy ... Engineering and Materials for Automotive Thermoelectric Applications Electrical and ...

  18. Thermoelectric FabricsŽ based on carbon nanotube composites...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Fabrics based on carbon nanotube composites Composite films of ... multiple element modules, results in thermoelectric fabrics with increased power output ...

  19. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities and Challenges of Thermoelectrlic Waste Heat Recovery in the Automotive Industry On Thermoelectric Properties of p-Type Skutterudites Development of Thermoelectric ...

  20. Feasibility of OnBoard Thermoelectric Generation for Improved...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OnBoard Thermoelectric Generation for Improved Vehicle Fuel Economy Feasibility of OnBoard Thermoelectric Generation for Improved Vehicle Fuel Economy Poster presentation at the ...

  1. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MB) More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Waste Heat to Electricity ...

  2. Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Gas Heat to Power Using Thermoelectric Engines Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines Discusses a novel TEG which utilizes a proprietary stack ...

  3. Development of a 500 Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 500 Watt High Temperature Thermoelectric Generator Development of a 500 Watt High Temperature Thermoelectric Generator A low temperature TEG has been built and tested providing ...

  4. Thermoelectric Conversion of Wate Heat to Electricity in an IC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wate Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Wate ... MB) More Documents & Publications Thermoelectric Conversion of Waste Heat to ...

  5. Atomic-Scale Mapping of Thermoelectric Power on Graphene: Role...

    Office of Scientific and Technical Information (OSTI)

    Mapping of Thermoelectric Power on Graphene: Role of Defects and Boundaries Citation Details In-Document Search Title: Atomic-Scale Mapping of Thermoelectric Power on ...

  6. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Improvement in an Over the Road Diesel Powered Engine System by the Application of Advanced Thermoelectric Systems Implemented in a Hybrid Configuration Thermoelectric ...

  7. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat to Electricity in an IC Engine-Powered Vehicle Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Wate

  8. Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Gas Waste Heat into Usable Electricity Thermoelectric Conversion of Exhaust Gas ... More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste ...

  9. Low and high Temperature Dual Thermoelectric Generation Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System ...

  10. Multilayer Thin-Film Thermoelectric Materials for Vehicle Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multilayer Thin-Film Thermoelectric Materials for Vehicle Applications Multilayer Thin-Film Thermoelectric Materials for Vehicle Applications 2004 Diesel Engine Emissions Reduction ...

  11. Thermoelectrical Energy Recovery From the Exhaust of a Light...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Progress in Thermoelectrical Energy Recovery from a Light Truck Exhaust ...

  12. Development of Cost-Competitive Advanced Thermoelectric Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost-Competitive Advanced Thermoelectric Generators for Direct Conversion of Vehicle Waste Heat into Useful Electrical Power Development of Cost-Competitive Advanced Thermoelectric...

  13. {100}<100> or 45.degree.-rotated {100}<100>, semiconductor-based, large-area, flexible, electronic devices

    DOE Patents [OSTI]

    Goyal, Amit

    2012-05-15

    Novel articles and methods to fabricate the same resulting in flexible, {100}<100> or 45.degree.-rotated {100}<100> oriented, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  14. Thermoelectric Materials by Design, Computational Theory and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    by Design, Computational Theory and Structure Thermoelectric Materials by Design, Computational Theory and Structure 2009 DOE Hydrogen Program and Vehicle Technologies Program...

  15. Correlation Between Structure and Thermoelectric Properties of...

    Broader source: Energy.gov (indexed) [DOE]

    Rapid solidified precursor converted into crystalline bulks under pressure produced thermoelectric materials of nano-sized grains with strongly coupled grain boundaries, achieving ...

  16. Skutterudite Thermoelectric Generator For Automotive Waste Heat...

    Broader source: Energy.gov (indexed) [DOE]

    of Exhaust Gas Waste Heat into Usable Electricity Development of Cost-Competitive Advanced Thermoelectric Generators for Direct Conversion of Vehicle Waste Heat into Useful ...

  17. Development of Marine Thermoelectric Heat Recovery Systems

    Broader source: Energy.gov [DOE]

    Thermoelectric generator prototypes are evaluated in a dedicated hybrid vessel test platform fabricated from an encapsulated lifeboat to optimize performance and reliability for marine industry applications

  18. Vehicle Fuel Economy Improvement through Thermoelectric Waste...

    Broader source: Energy.gov (indexed) [DOE]

    Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deercrane.pdf (549.96 KB) More Documents & Publications Potential of Thermoelectrics forOccupant ...

  19. Connecting Thermoelectric Performance and Topological-Insulator...

    Office of Scientific and Technical Information (OSTI)

    Publisher's Accepted Manuscript: Connecting Thermoelectric Performance and Topological-Insulator Behavior: BiTe and BiTeSe from First Principles Prev Next Title: ...

  20. High-Temperature Thermoelectric Materials Characterization for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  1. Proactive Strategies for Designing Thermoelectric Materials for...

    Broader source: Energy.gov (indexed) [DOE]

    New p-type and n-type multiple-rattler skutterudite thermoelectric materials design, synthesis, fabrication, and characterization for power generation using vehicle exhaust waste ...

  2. Vehicular Thermoelectrics: The New Green Technology | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The New Green Technology Vehicular Thermoelectrics: The New Green Technology Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference ...

  3. Novel Nanostructured Thermoelectrics | Center for Energy Efficient...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials with improved thermoelectric power generation capabilities, the path to that goal ... electrical conductivity, and reduce the electronic and lattice thermal conductivities. ...

  4. Thermoelectric materials ternary penta telluride and selenide compounds

    DOE Patents [OSTI]

    Sharp, Jeffrey W.

    2001-01-01

    Ternary tellurium compounds and ternary selenium compounds may be used in fabricating thermoelectric devices with a thermoelectric figure of merit (ZT) of 1.5 or greater. Examples of such compounds include Tl.sub.2 SnTe.sub.5, Tl.sub.2 GeTe.sub.5, K.sub.2 SnTe.sub.5 and Rb.sub.2 SnTe.sub.5. These compounds have similar types of crystal lattice structures which include a first substructure with a (Sn, Ge) Te.sub.5 composition and a second substructure with chains of selected cation atoms. The second substructure includes selected cation atoms which interact with selected anion atoms to maintain a desired separation between the chains of the first substructure. The cation atoms which maintain the desired separation between the chains occupy relatively large electropositive sites in the resulting crystal lattice structure which results in a relatively low value for the lattice component of thermal conductivity (.kappa..sub.g). The first substructure of anion chains indicates significant anisotropy in the thermoelectric characteristics of the resulting semiconductor materials.

  5. Thermoelectric materials: ternary penta telluride and selenide compounds

    DOE Patents [OSTI]

    Sharp, Jeffrey W.

    2002-06-04

    Ternary tellurium compounds and ternary selenium compounds may be used in fabricating thermoelectric devices with a thermoelectric figure of merit (ZT) of 1.5 or greater. Examples of such compounds include Tl.sub.2 SnTe.sub.5, Tl.sub.2 GeTe.sub.5, K.sub.2 SnTe.sub.5 and Rb.sub.2 SnTe.sub.5. These compounds have similar types of crystal lattice structures which include a first substructure with a (Sn, Ge) Te.sub.5 composition and a second substructure with chains of selected cation atoms. The second substructure includes selected cation atoms which interact with selected anion atoms to maintain a desired separation between the chains of the first substructure. The cation atoms which maintain the desired separation between the chains occupy relatively large electropositive sites in the resulting crystal lattice structure which results in a relatively low value for the lattice component of thermal conductivity (.kappa..sub.g). The first substructure of anion chains indicates significant anisotropy in the thermoelectric characteristics of the resulting semiconductor materials.

  6. THERMO-ELECTRIC GENERATOR

    DOE Patents [OSTI]

    Jordan, K.C.

    1958-07-22

    The conversion of heat energy into electrical energy by a small compact device is descrtbed. Where the heat energy is supplied by a radioactive material and thermopIIes convert the heat to electrical energy. The particular battery construction includes two insulating discs with conductive rods disposed between them to form a circular cage. In the center of the cage is disposed a cup in which the sealed radioactive source is located. Each thermopile is formed by connecting wires from two adjacent rods to a potnt on an annular ring fastened to the outside of the cup, the ring having insulation on its surface to prevent electrica1 contact with the thermopiles. One advantage of this battery construction is that the radioactive source may be inserted after the device is fabricated, reducing the radiation hazard to personnel assembling the battery.

  7. Overview of Fords Thermoelectric Programs: Waste Heat Recovery...

    Broader source: Energy.gov (indexed) [DOE]

    Overview of Fords Thermoelectric Programs: Waste Heat Recovery and Climate Control Thermoelectric HVAC for Light-Duty Vehicle Applications Automotive Thermoelectric Generators ...

  8. Phononic crystal devices

    SciTech Connect (OSTI)

    El-Kady, Ihab F.; Olsson, Roy H.

    2012-01-10

    Phononic crystals that have the ability to modify and control the thermal black body phonon distribution and the phonon component of heat transport in a solid. In particular, the thermal conductivity and heat capacity can be modified by altering the phonon density of states in a phononic crystal. The present invention is directed to phononic crystal devices and materials such as radio frequency (RF) tags powered from ambient heat, dielectrics with extremely low thermal conductivity, thermoelectric materials with a higher ratio of electrical-to-thermal conductivity, materials with phononically engineered heat capacity, phononic crystal waveguides that enable accelerated cooling, and a variety of low temperature application devices.

  9. Thermoelectric Development at Hi-Z Technology

    SciTech Connect (OSTI)

    Kushch, Aleksandr S.; Bass, John C.; Ghamaty, Saeid; Elsner, Norbert B.; Bergstrand, Richard A.; Furrow, David; Melvin, Mike

    2002-08-25

    An improved Thermoelectric Generator (TEG) for the Heavy Duty Class Eight Diesel Trucks is under development at Hi-Z Technology. The current TEG is equipped with the improved HZ-14 Thermoelectric module, which features better mechanical properties as well as higher electric power output. Also, the modules are held in place more securely.

  10. Nanostructures having high performance thermoelectric properties

    SciTech Connect (OSTI)

    Yang, Peidong; Majumdar, Arunava; Hochbaum, Allon I; Chen, Renkun; Delgado, Raul Diaz

    2014-05-20

    The invention provides for a nanostructure, or an array of such nanostructures, each comprising a rough surface, and a doped or undoped semiconductor. The nanostructure is an one-dimensional (1-D) nanostructure, such a nanowire, or a two-dimensional (2-D) nanostructure. The nanostructure can be placed between two electrodes and used for thermoelectric power generation or thermoelectric cooling.

  11. Heat reflecting tape for thermoelectric converter

    DOE Patents [OSTI]

    Purdy, David L.

    1977-01-01

    Threads are interlaced with thermoelectric wires to provide a woven cloth in tape form, there being an intermediate layer of heat radiation reflecting material (e.g., aluminum foil) insulated electrically from said wires, which are of opposite thermoelectric polarity and connected as a plurality of thermocouples.

  12. Nanostructures having high performance thermoelectric properties

    DOE Patents [OSTI]

    Yang, Peidong; Majumdar, Arunava; Hochbaum, Allon I.; Chen, Renkun; Delgado, Raul Diaz

    2015-12-22

    The invention provides for a nanostructure, or an array of such nanostructures, each comprising a rough surface, and a doped or undoped semiconductor. The nanostructure is an one-dimensional (1-D) nanostructure, such a nanowire, or a two-dimensional (2-D) nanostructure. The nanostructure can be placed between two electrodes and used for thermoelectric power generation or thermoelectric cooling.

  13. OSTIblog Articles in the Radioisotope Thermoelectric Generator Topic |

    Office of Scientific and Technical Information (OSTI)

    OSTI, US Dept of Energy Office of Scientific and Technical Information Radioisotope Thermoelectric Generator

  14. Develop Thermoelectric Technology for Automotive Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE)

    Develop thermoelectric technology for waste heat recovery with a 10% fuel economy improvement without increasing emissions.

  15. Innovative Nano-structuring Routes for Novel Thermoelectric

    Broader source: Energy.gov (indexed) [DOE]

    Materials;Phonon Blocking & DOS Engineering | Department of Energy Presents new concepts for high performance nanostructured bulk thermoelectric materials lee.pdf (1.98 MB) More Documents & Publications Thermoelectric Materials for Automotive Applications The Bottom-Up Approach forThermoelectric Nanocomposites, plusƒ Glass-like thermal conductivity in high efficiency thermoelectric materials

  16. Overview of Thermoelectric Power Generation Technologies in Japan |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Discusses thermoelectric power generation technologies as applied to waste heat recovery, renewable thermal energy sources, and energy harvesting kajikawa.pdf (4.47 MB) More Documents & Publications Overview of Thermoelectric Power Generation Technologies in Japan Overview of Progress in Thermoelectric Power Generation Technologies in Japan Overview of Japanese Activities in Thermoelectrics

  17. Thermoelectric Opportunities for Light-Duty Vehicles | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    thermoelectrics for automotive applications and role of automakers in setting guidelines and technology attributes needed for the global product, regulatory, and market environment maranville.pdf (3 MB) More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Thermoelectric Activities of European Community within Framework Programme 7 and additional activities in Germany Automotive Thermoelectric Generator

  18. Fluidic nanotubes and devices

    DOE Patents [OSTI]

    Yang, Peidong; He, Rongrui; Goldberger, Joshua; Fan, Rong; Wu, Yiying; Li, Deyu; Majumdar, Arun

    2008-04-08

    Fluidic nanotube devices are described in which a hydrophilic, non-carbon nanotube, has its ends fluidly coupled to reservoirs. Source and drain contacts are connected to opposing ends of the nanotube, or within each reservoir near the opening of the nanotube. The passage of molecular species can be sensed by measuring current flow (source-drain, ionic, or combination). The tube interior can be functionalized by joining binding molecules so that different molecular species can be sensed by detecting current changes. The nanotube may be a semiconductor, wherein a tubular transistor is formed. A gate electrode can be attached between source and drain to control current flow and ionic flow. By way of example an electrophoretic array embodiment is described, integrating MEMs switches. A variety of applications are described, such as: nanopores, nanocapillary devices, nanoelectrophoretic, DNA sequence detectors, immunosensors, thermoelectric devices, photonic devices, nanoscale fluidic bioseparators, imaging devices, and so forth.

  19. Fluidic nanotubes and devices

    DOE Patents [OSTI]

    Yang, Peidong; He, Rongrui; Goldberger, Joshua; Fan, Rong; Wu, Yiying; Li, Deyu; Majumdar, Arun

    2010-01-10

    Fluidic nanotube devices are described in which a hydrophilic, non-carbon nanotube, has its ends fluidly coupled to reservoirs. Source and drain contacts are connected to opposing ends of the nanotube, or within each reservoir near the opening of the nanotube. The passage of molecular species can be sensed by measuring current flow (source-drain, ionic, or combination). The tube interior can be functionalized by joining binding molecules so that different molecular species can be sensed by detecting current changes. The nanotube may be a semiconductor, wherein a tubular transistor is formed. A gate electrode can be attached between source and drain to control current flow and ionic flow. By way of example an electrophoretic array embodiment is described, integrating MEMs switches. A variety of applications are described, such as: nanopores, nanocapillary devices, nanoelectrophoretic, DNA sequence detectors, immunosensors, thermoelectric devices, photonic devices, nanoscale fluidic bioseparators, imaging devices, and so forth.

  20. Thermoelectric generator having a resiliently mounted removable thermoelectric module

    DOE Patents [OSTI]

    Purdy, David L.; Shapiro, Zalman M.; Hursen, Thomas F.; Maurer, Gerould W.

    1976-11-02

    An electrical generator having an Isotopic Heat Capsule including radioactive fuel rod 21 as a primary heat source and Thermoelectric Modules 41 and 43 as converters. The Biological Shield for the Capsule is suspended from Spiders at each end each consisting of pretensioned rods 237 and 239 defining planes at right angles to each other. The Modules are mounted in cups 171 of transition members 173 of a heat rejection Fin Assembly whose fins 195 and 197 extend from both sides of the transition member 173 for effective cooling.

  1. Status of the Application of Thermoelectric Technology in Vehicles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Application of Thermoelectric Technology in Vehicles Status of the Application of Thermoelectric Technology in Vehicles 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: BSST LLC 2004_deer_bell.pdf (428.1 KB) More Documents & Publications Role of Thermoelectrics in Vehicle Efficiency Increase Potential Thermoelectric Applications in Diesel Vehicles Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle

  2. Thermoelectric Generator (TEG) Fuel Displacement Potential using

    Broader source: Energy.gov (indexed) [DOE]

    Energy Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_fairbanks.pdf (7.06 MB) More Documents & Publications High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation Quantum Well Thermoelectrics and Waste Heat Recovery High Temperature Thermoelectric Materials Engine-in-the-Loop and Simulation | Department of Energy

    Assessment of

  3. Bulk dimensional nanocomposites for thermoelectric applications

    DOE Patents [OSTI]

    Nolas, George S

    2014-06-24

    Thermoelectric elements may be used for heat sensors, heat pumps, and thermoelectric generators. A quantum-dot or nano-scale grain size polycrystalline material the effects of size-quantization are present inside the nanocrystals. A thermoelectric element composed of densified Groups IV-VI material, such as calcogenide-based materials are doped with metal or chalcogenide to form interference barriers form along grains. The dopant used is either silver or sodium. These chalcogenide materials form nanoparticles of highly crystal grains, and may specifically be between 1- and 100 nm. The compound is densified by spark plasma sintering.

  4. In-Line Thermoelectric Module

    SciTech Connect (OSTI)

    Pento, Robert; Marks, James E.; Staffanson, Clifford D.

    1998-07-28

    A thermoelectric module with a plurality of electricity generating units each having a first end and a second end, the units being arranged first end to second end along an-in-line axis. Each unit includes first and second elements each made of a thermoelectric material, an electrically conductive hot member arranged to heat one side of the first element, and an electrically conductive cold member arranged to cool another side of the first element and to cool one side of the second element. The hot member, the first element, the cold member and the second element are supported in a fixture, are electrically connected respectively to provide an electricity generating unit, and are arranged respectively in positions along the in-line axis. The individual components of each generating unit and the respective generating units are clamped in their in-line positions by a loading bolt at one end of the fixture and a stop wall at the other end of the fixture. The hot members may have a T-shape and the cold members an hourglass shape to facilitate heat transfer. The direction of heat transfer through the hot members may be perpendicular to the direction of heat transfer through the cold members, and both of these heat transfer directions maybe perpendicular to the direction-of current flow through the module.

  5. In-line thermoelectric module

    DOE Patents [OSTI]

    Pento, Robert; Marks, James E.; Staffanson, Clifford D.

    2000-01-01

    A thermoelectric module with a plurality of electricity generating units each having a first end and a second end, the units being arranged first end to second end along an in-line axis. Each unit includes first and second elements each made of a thermoelectric material, an electrically conductive hot member arranged to heat one side of the first element, and an electrically conductive cold member arranged to cool another side of the first element and to cool one side of the second element. The hot member, the first element, the cold member and the second element are supported in a fixture, are electrically connected respectively to provide an electricity generating unit, and are arranged respectively in positions along the in-line axis. The individual components of each generating unit and the respective generating units are clamped in their in-line positions by a loading bolt at one end of the fixture and a stop wall at the other end of the fixture. The hot members may have a T-shape and the cold members an hourglass shape to facilitate heat transfer. The direction of heat transfer through the hot members may be perpendicular to the direction of heat transfer through the cold members, and both of these heat transfer directions may be perpendicular to the direction of current flow through the module.

  6. Thermoelectric generator cooling system and method of control

    SciTech Connect (OSTI)

    Prior, Gregory P; Meisner, Gregory P; Glassford, Daniel B

    2012-10-16

    An apparatus is provided that includes a thermoelectric generator and an exhaust gas system operatively connected to the thermoelectric generator to heat a portion of the thermoelectric generator with exhaust gas flow through the thermoelectric generator. A coolant system is operatively connected to the thermoelectric generator to cool another portion of the thermoelectric generator with coolant flow through the thermoelectric generator. At least one valve is controllable to cause the coolant flow through the thermoelectric generator in a direction that opposes a direction of the exhaust gas flow under a first set of operating conditions and to cause the coolant flow through the thermoelectric generator in the direction of exhaust gas flow under a second set of operating conditions.

  7. New Perspectives in Thermoelectric Energy Recovery System Design Optimization

    SciTech Connect (OSTI)

    Hendricks, Terry J.; Karri, Naveen K.; Hogan, Tim; Cauchy, Charles J.

    2013-02-12

    Abstract: Large amounts of waste heat are generated worldwide in industrial processes, automotive transportation, diesel engine exhaust, military generators, and incinerators because 60-70% of the fuel energy is typically lost in these processes. There is a strong need to develop technologies that recover this waste heat to increase fuel efficiency and minimize fuel requirements in these industrial processes, automotive and heavy vehicle engines, diesel generators, and incinerators. There are additional requirements to reduce CO2 production and environmental footprints in many of these applications. Recent work with the Strategic Environmental Research and Development Program office has investigated new thermoelectric (TE) materials and systems that can operate at higher performance levels and show a viable pathway to lightweight, small form-factor, advanced thermoelectric generator (TEG) systems to recover waste heat in many of these applications. New TE materials include nano-composite materials such as lead-antimony-silver-telluride (LAST) and lead-antimony-silver-tin-telluride (LASTT) compounds. These new materials have created opportunities for high-performance, segmented-element TE devices. New higher-performance TE devices segmenting LAST/LASTT materials with bismuth telluride have been designed and fabricated. Sectioned TEG systems using these new TE devices and materials have been designed. Integrated heat exchanger/TE device system analyses of sectioned TE system designs have been performed creating unique efficiency-power maps that provide better understandings and comparisons of design tradeoffs and nominal and off-nominal system performance conditions. New design perspectives in optimization of sectioned TE design approaches are discussed that provide insight on how to optimize such sectioned TE systems. System performance analyses using ANSYS TE modeling capabilities have integrated heat exchanger performance models with ANSYS TE models to extend

  8. Thermoelectric Generator (TEG) Fuel Displacement Potential using...

    Broader source: Energy.gov (indexed) [DOE]

    Assessment of fuel savings with thermoelectric generators (TEGs) using detailed model of GM-developed TEG as part of the engine connected to a dynamometer that emulates the rest of ...

  9. Thermoelectric Nanocarbon Ensembles | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2_gruen.pdf (1.55 MB) More Documents & Publications Diamond Based TE Materials DOE Vehicle Technologies Program 2009 Merit Review Report - Propulsion Materials Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

  10. Thermoelectric materials and methods for synthesis thereof

    DOE Patents [OSTI]

    Ren, Zhifeng; Zhang, Qinyong; Zhang, Qian; Chen, Gang

    2015-08-04

    Materials having improved thermoelectric properties are disclosed. In some embodiments, lead telluride/selenide based materials with improved figure of merit and mechanical properties are disclosed. In some embodiments, the lead telluride/selenide based materials of the present disclosure are p-type thermoelectric materials formed by adding sodium (Na), silicon (Si) or both to thallium doped lead telluride materials. In some embodiments, the lead telluride/selenide based materials are formed by doping lead telluride/selenides with potassium.

  11. POTENTIAL THERMOELECTRIC APPLICATIONS IN DIESEL VEHICLES

    SciTech Connect (OSTI)

    Crane, D

    2003-08-24

    Novel thermodynamic cycles developed by BSST provide improvements by factors of approximately 2 in cooling, heating and power generation efficiency of solid-state thermoelectric systems. The currently available BSST technology is being evaluated in automotive development programs for important new applications. Thermoelectric materials are likely to become available that further increase performance by a comparable factor. These major advancements should allow the use of thermoelectric systems in new applications that have the prospect of contributing to emissions reduction, fuel economy, and improved user comfort. Potential applications of thermoelectrics in diesel vehicles are identified and discussed. As a case in point, the history and status of the Climate Controlled Seat (CCS) system from Amerigon, the parent of BSST, is presented. CCS is the most successful and highest production volume thermoelectric system in vehicles today. As a second example, the results of recent analyses on electric power generation from vehicle waste heat are discussed. Conclusions are drawn as to the practicality of waste power generation systems that incorporate BSST's thermodynamic cycle and advanced thermoelectric materials.

  12. High Temperature Integrated Thermoelectric Ststem and Materials

    SciTech Connect (OSTI)

    Mike S. H. Chu

    2011-06-06

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits

  13. Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presents progress in cost-effective thermoelectric generator fabrication by thermal spraying of thermoelectric materials and other functional layers directly onto automotive exhaust pipes with enhanced performance, durability, and heat transfer

  14. CX-009905: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    25A1001 - Advanced Semiconductor Materials for High Efficiency Thermoelectric Devices CX(s) Applied: B3.6 Date: 12/01/2009 Location(s): California, North Carolina, Oklahoma Offices(s): Advanced Research Projects Agency-Energy

  15. Thermoelectric properties of IV–VI-based heterostructures and superlattices

    SciTech Connect (OSTI)

    Borges, P.D.; Petersen, J.E.; Scolfaro, L.; Leite Alves, H.W.; Myers, T.H.

    2015-07-15

    VI-based heterostructures and superlattices. • High figure of merit is predicted for the PbTe/SnTe/PbTe heterostructure. • Nanotechnology has an important role for the development of thermoelectric devices.

  16. Recent Progress in the Development of High Efficiency Thermoelectrics |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy in the Development of High Efficiency Thermoelectrics Recent Progress in the Development of High Efficiency Thermoelectrics 2003_deer_bass.pdf (992.67 KB) More Documents & Publications High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation Quantum Well Thermoelectrics and Waste Heat Recovery Scale Up of Si/Si0.8GE0.2 and B4C/B9C Superlattices for Harvesting of Waste Heat in Diesel Engines

  17. Development of Thermoelectric Technology for Automotive Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Thermoelectric Technology for Automotive Waste Heat Recovery Development of Thermoelectric Technology for Automotive Waste Heat Recovery Overview and status of project to develop thermoelectric generator for automotive waste heat recovery and achieve at least 10% fuel economy improvement. deer08_gundlach.pdf (1 MB) More Documents & Publications Opportunities and Challenges of Thermoelectrlic Waste Heat Recovery in the Automotive Industry Develop Thermoelectric

  18. PACCAR/Hi-Z Thermoelectric Generator Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PACCAR/Hi-Z Thermoelectric Generator Project PACCAR/Hi-Z Thermoelectric Generator Project 2002 DEER Conference Presentation: Hi-Z Technology, Inc. 2002_deer_bergstrand.pdf (5.53 MB) More Documents & Publications Self-powered Hydrogen + Oxygen Injection System The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Recent Progress in the Development of High Efficiency Thermoelectrics

  19. Compositional ordering and stability in nanostructured, bulk thermoelectric alloys.

    SciTech Connect (OSTI)

    Hekmaty, Michelle A.; Faleev, S.; Medlin, Douglas L.; Leonard, F.; Lensch-Falk, J.; Sharma, Peter Anand; Sugar, J. D.

    2009-09-01

    Thermoelectric materials have many applications in the conversion of thermal energy to electrical power and in solid-state cooling. One route to improving thermoelectric energy conversion efficiency in bulk material is to embed nanoscale inclusions. This report summarize key results from a recently completed LDRD project exploring the science underpinning the formation and stability of nanostructures in bulk thermoelectric and the quantitative relationships between such structures and thermoelectric properties.

  20. Overview of Thermoelectric Power Generation Technologies in Japan

    Broader source: Energy.gov [DOE]

    Discusses thermoelectric power generation technologies as applied to waste heat recovery, renewable thermal energy sources, and energy harvesting

  1. Thermoelectric Materials for Automotive Applications | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Discusses the background information on what makes a good thermoelectric material, then the findings of three recent ORNL field report studies focused at PbSe, Bi2Se3, CrSi2, respectively parker.pdf (1.4 MB) More Documents & Publications Thermoelectrics Theory and Structure Thermoelectrics Theory and Structure

  2. Thermoelectric Opportunities in Light-Duty Vehicles | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    thermoelectric (TE) vehicle exhaust heat recovery, TE HVAC systems, and OEM role in establishing guidelines for cost, power density, systems integration, and durability. maranville.pdf (480.27 KB) More Documents & Publications Vehicular Thermoelectrics: A New Green Technology Vehicular Thermoelectrics: A New Green Technology Cost Effectiveness of Technology Solutions for Future Vehicle Systems

  3. High-Performance Thermoelectric Devices Based on Abundant Silicide...

    Broader source: Energy.gov (indexed) [DOE]

    Reports of methods to synthesize single-crystal and poly or nano- crystalline p- and n-type higher manganese silicides to reduce lattice thermal conductivity shi.pdf (6.72

  4. Review of Interests and Activities in Thermoelectric Materials and Devices

    Broader source: Energy.gov (indexed) [DOE]

    INQUIRY REPORT Review of Allegations Regarding Continued Retaliation Against a Bonneville Power Administration Whistleblower DOE/IG-0910 May 2014 U.S. Department of Energy Office of Inspector General Office of Audits and Inspections Department of Energy Washington, DC 20585 May 15, 2014 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman Inspector General SUBJECT: INFORMATION: Special Inquiry: "Review of Allegations Regarding Continued Retaliation Against a Bonneville Power

  5. Feasibility of Thermoelectrics for Waste Heat Recovery in Conventional Vehicles

    SciTech Connect (OSTI)

    Smith, K.; Thornton, M.

    2009-04-01

    Thermoelectric (TE) generators convert heat directly into electricity when a temperature gradient is applied across junctions of two dissimilar metals. The devices could increase the fuel economy of conventional vehicles by recapturing part of the waste heat from engine exhaust and generating electricity to power accessory loads. A simple vehicle and engine waste heat model showed that a Class 8 truck presents the least challenging requirements for TE system efficiency, mass, and cost; these trucks have a fairly high amount of exhaust waste heat, have low mass sensitivity, and travel many miles per year. These factors help maximize fuel savings and economic benefits. A driving/duty cycle analysis shows strong sensitivity of waste heat, and thus TE system electrical output, to vehicle speed and driving cycle. With a typical alternator, a TE system could allow electrification of 8%-15% of a Class 8 truck's accessories for 2%-3% fuel savings. More research should reduce system cost and improve economics.

  6. Method of operating a thermoelectric generator

    DOE Patents [OSTI]

    Reynolds, Michael G; Cowgill, Joshua D

    2013-11-05

    A method for operating a thermoelectric generator supplying a variable-load component includes commanding the variable-load component to operate at a first output and determining a first load current and a first load voltage to the variable-load component while operating at the commanded first output. The method also includes commanding the variable-load component to operate at a second output and determining a second load current and a second load voltage to the variable-load component while operating at the commanded second output. The method includes calculating a maximum power output of the thermoelectric generator from the determined first load current and voltage and the determined second load current and voltage, and commanding the variable-load component to operate at a third output. The commanded third output is configured to draw the calculated maximum power output from the thermoelectric generator.

  7. Thermoelectric power generator with intermediate loop

    SciTech Connect (OSTI)

    Bell, Lon E; Crane, Douglas Todd

    2013-05-21

    A thermoelectric power generator is disclosed for use to generate electrical power from heat, typically waste heat. An intermediate heat transfer loop forms a part of the system to permit added control and adjustability in the system. This allows the thermoelectric power generator to more effectively and efficiently generate power in the face of dynamically varying temperatures and heat flux conditions, such as where the heat source is the exhaust of an automobile, or any other heat source with dynamic temperature and heat flux conditions.

  8. Thermoelectric power generator with intermediate loop

    DOE Patents [OSTI]

    Bel,; Lon E.; Crane, Douglas Todd

    2009-10-27

    A thermoelectric power generator is disclosed for use to generate electrical power from heat, typically waste heat. An intermediate heat transfer loop forms a part of the system to permit added control and adjustability in the system. This allows the thermoelectric power generator to more effectively and efficiently generate power in the face of dynamically varying temperatures and heat flux conditions, such as where the heat source is the exhaust of an automobile, or any other heat source with dynamic temperature and heat flux conditions.

  9. Alkaline earth filled nickel skutterudite antimonide thermoelectrics

    DOE Patents [OSTI]

    Singh, David Joseph

    2013-07-16

    A thermoelectric material including a body centered cubic filled skutterudite having the formula A.sub.xFe.sub.yNi.sub.zSb.sub.12, where A is an alkaline earth element, x is no more than approximately 1.0, and the sum of y and z is approximately equal to 4.0. The alkaline earth element includes guest atoms selected from the group consisting of Be, Mb, Ca, Sr, Ba, Ra and combinations thereof. The filled skutterudite is shown to have properties suitable for a wide variety of thermoelectric applications.

  10. NSF/DOE Thermoelectrics Partnership: Thermoelectrics for Automotive Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE)

    Development for commercialization of automotive thermoelectric generators from high-ZT TE materials with using low-cost, widely available materials, system design and modeling to maximize temperature differential across TE modules and maximize power output

  11. Titanium nitride electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Novak, Robert F.; Schmatz, Duane J.; Hunt, Thomas K.

    1987-12-22

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film of titanium nitride as an electrode deposited onto solid electrolyte. The invention is also directed to the method of making same.

  12. Molybdenum oxide electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Schmatz, Duane J.

    1989-01-01

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film comprising molybdenum oxide as an electrode deposited by physical deposition techniques onto solid electrolyte. The invention is also directed to the method of making same.

  13. High ZT bismuth-doped perovskite thermoelectrics

    DOE Patents [OSTI]

    Brown-Shaklee, Harlan James

    2016-02-23

    A bismuth-doped perovskite thermoelectric, comprising (Bi.sub.x, La.sub.0.1-x)SrTiO.sub.3, wherein x is between 0.01 and 0.1, can have a high figure-of-merit, ZT.

  14. Personal cooling air filtering device

    DOE Patents [OSTI]

    Klett, James [Knoxville, TN; Conway, Bret [Denver, NC

    2002-08-13

    A temperature modification system for modifying the temperature of fluids includes at least one thermally conductive carbon foam element, the carbon foam element having at least one flow channel for the passage of fluids. At least one temperature modification device is provided, the temperature modification device thermally connected to the carbon foam element and adapted to modify the temperature of the carbon foam to modify the temperature of fluids flowing through the flow channels. Thermoelectric and/or thermoionic elements can preferably be used as the temperature modification device. A method for the reversible temperature modification of fluids includes the steps of providing a temperature modification system including at least one thermally conductive carbon foam element having flow channels and at least one temperature modification device, and flowing a fluid through the flow channels.

  15. High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power...

    Broader source: Energy.gov (indexed) [DOE]

    Development of an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles Recent Progress in the Development of High Efficiency Thermoelectrics ...

  16. Thermoelectric-Enhanced Cookstove Add-on (TECA) for Clean Biomass...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (BETO) 2015 Project Peer Review Thermoelectric-Enhanced Cookstove Add-on (TECA) for ... performance through the use of RTI's Thermoelectric Enhanced Cookstove Add-on (TECA) ...

  17. The Effects of an Exhaust Thermoelectric Generator of a GM Sierra...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck 2004 Diesel Engine Emissions ...

  18. Project Profile: Concentrated Solar Thermoelectric Power | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Concentrated Solar Thermoelectric Power Project Profile: Concentrated Solar Thermoelectric Power MIT logo -- This project is inactive -- The Rohsenow-Kendall Heat Transfer Lab at Massachusetts Institute of Technology(MIT), under the 2012 SunShot Concentrating Solar Power (CSP) R&D FOA, is developing concentrated solar thermoelectric generators (CSTEGs) for CSP systems. This innovative distributed solution contains no moving parts and converts heat directly into electricity.

  19. Thermoelectric Bulk Materials from the Explosive Consolidation of

    Broader source: Energy.gov (indexed) [DOE]

    Nanopowders | Department of Energy Describes technique of explosively consolidating nanopowders to yield fully dense, consolidated, nanostructured thermoelectric material nemir.pdf (3.11 MB) More Documents & Publications The Bottom-Up Approach forThermoelectric Nanocomposites, plusƒ Enhancing the Figure-of-Merit in Half-Heuslers for Vehicle Waste Heat Recovery Correlation Between Structure and Thermoelectric Properties of Bulk High Performance Materials for Energy Conversion

  20. Thermoelectric Generator Performance for Passenger Vehicles | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10_meisner.pdf (2.38 MB) More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat Recovery Advanced Thermoelectric Materials and Generator Technology for Automotive Waste Heat at GM Advanced Thermoelectric Materials and Generator Technology for Automotive Waste Heat at GM Energy

  1. Thermoelectric Waste Heat Recovery Program for Passenger Vehicles |

    Broader source: Energy.gov (indexed) [DOE]

    High Efficiency Hybrid Vehicles | Department of Energy This project discusses preliminary experimental results to find how thermoelectrics can be applied ot future hybrid vehicles and the optimum design of such equipment using heat pipes deer09_kim.pdf (628.26 KB) More Documents & Publications Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles A Thermoelectric Generator with an Intermediate Heat Exchanger for Automotive Waste Heat

  2. Molecular and Hybrid Solution Processable Thermoelectrics | MIT-Harvard

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Excitonics and Hybrid Solution Processable Thermoelectrics February 15, 2011 at 3pm/36-428 Rachel Segalman University of California, Berkeley segalman_001 abstract: Thermoelectric materials for energy generation have several advantages over conventional power cycles including lack of moving parts, silent operation, miniaturizability, and CO2 free conversion of heat to electricity. Excellent thermoelectric efficiency requires a combination of high thermopower (S, V/K), high

  3. Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Exhaust Gas Waste Heat into Usable Electricity Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Presents successful incorporation of one of the most promising classes of the new materials, the skutterudites, into a working automotive TEG prototype and test results on its performance deer11_meisner.pdf (1.17 MB) More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Develop Thermoelectric

  4. Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Fuel Economy Improvement through Thermoelectric Waste Heat Recovery Vehicle Fuel Economy Improvement through Thermoelectric Waste Heat Recovery 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_crane.pdf (549.96 KB) More Documents & Publications Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle Applications Automotive Waste Heat Conversion to Electric Power using Skutterudites, TAGS,

  5. Powering Curiosity: Multi-Mission Radioisotope Thermoelectric Generators |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Powering Curiosity: Multi-Mission Radioisotope Thermoelectric Generators Powering Curiosity: Multi-Mission Radioisotope Thermoelectric Generators January 29, 2008 - 7:06pm Addthis Mars Science Laboratory, aka Curiosity, is part of NASA's Mars Exploration Program, a long-term program of robotic exploration of the Red Planet. It's powered by the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG). Photo courtesy of NASA/JPL-Caltech. Mars Science Laboratory, aka

  6. Modular Low Cost High Energy Exhaust Heat Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modular Low Cost High Energy Exhaust Heat Thermoelectric Generator with Closed-Loop ... Solid State Vehicular Generators and HVAC Development An Innovative Pressure Sensor ...

  7. BTO Partners Develop Novel, Energy-efficient Thermoelectric Clothes...

    Energy Savers [EERE]

    The cooled air is then heated by passing over the hot side of the thermoelectric modules ... Design Competition Small Businesses Receive 2 Million to Advance HVAC Technologies

  8. Thermoelectric HVAC and Thermal Comfort Enablers for Light-Duty...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Thermoelectric HVAC for Light-Duty Vehicle Applications Improving efficiency of a vehicle HVAC system with comfort modeling, zonal design, and ...

  9. Design of Bulk Nanocomposites as High Efficiency Thermoelectric...

    Office of Science (SC) Website

    Design of Bulk Nanocomposites as High Efficiency Thermoelectric Materials Energy Frontier ... News & Events Publications History Contact BES Home 04.27.12 Design of Bulk Nanocomposites ...

  10. Thermoelectric Generator Development at Renault Trucks-Volvo...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    systems PDF icon aixala.pdf More Documents & Publications RENOTER Project RENOTER Project Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

  11. Multi-physics modeling of thermoelectric generators for waste...

    Broader source: Energy.gov (indexed) [DOE]

    Model developed provides effective guidelines to designing thermoelectric generation systems for automotive waste heat recovery applications deer12zhang2.pdf (2.06 MB) More ...

  12. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Evaluation PDF icon ace049schock2011o.pdf More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle...

  13. Glass-like thermal conductivity in high efficiency thermoelectric materials

    Broader source: Energy.gov [DOE]

    Discusses strategies to design thermoelectric materials with extremely low lattice thermal conductivity through modifications of the phonon band structure and phonon relaxation time.

  14. DOE/NSF Thermoelectric Partnership Project SEEBECK Saving Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    research and sharing Knowledge DOENSF Thermoelectric Partnership Project SEEBECK Saving Energy Effectively By Engaging in Collaborative research and sharing Knowledge 2011 DOE ...

  15. DOE/NSF Thermoelectric Partnership Project SEEBECK Saving Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research and Sharing Knowledge DOENSF Thermoelectric Partnership Project SEEBECK Saving Energy Effectively By Engaging in Collaborative Research and Sharing Knowledge 2012 DOE ...

  16. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Describes TEG systems built at MSU to mitigate couple failures and a cost-benefit analysis ... More Documents & Publications Thermoelectric Conversion of Wate Heat to Electricity in an ...

  17. Progress in Thermoelectrical Energy Recovery from a Light Truck Exhaust |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy in Thermoelectrical Energy Recovery from a Light Truck Exhaust Progress in Thermoelectrical Energy Recovery from a Light Truck Exhaust Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_thacher.pdf (780.57 KB) More Documents & Publications The Effects of an Exhaust Thermoelectric Generator of a GM Sierra Pickup Truck Thermoelectrical Energy

  18. Thermoelectric Properties of Rare-Earth-Ruthenium-Germanium Compounds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cobalt substitution for ruthenium enhances the semiconductor character but does not improve the thermoelectric properties. URL: Link to article - Journal of Applied Physics...

  19. Development of a High-Efficiency Zonal Thermoelectric HVAC System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Improving Energy Efficiency by Developing Components for Distributed Cooling and Heating Based on ...

  20. Benefits of Thermoelectric Technology for the Automobile | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Discusses improved fuel efficiency and other benefits of automotive application of thermoelectric (power generation and heatingcooling) and the need for production quantities of ...

  1. Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines

    Office of Energy Efficiency and Renewable Energy (EERE)

    Discusses a novel TEG which utilizes a proprietary stack designed thermoelectric engine to achieve high power density and reduced system weight and volume

  2. 2nd Thermoelectrics Applications Workshop 2011 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Micro- and Nano-Technologies Enabling More Compact, Lightweight Thermoelectric Power Generation and Cooling Systems Terry Hendricks PNNL, Corvallis, OR Proactive Design of n-Type ...

  3. High Heat Flux Thermoelectric Module Using Standard Bulk Material

    Broader source: Energy.gov [DOE]

    Presents high heat flux thermoelectric module design for cooling using a novel V-shaped shunt configuration with bulk TE elements achieving high area packing fractions

  4. Thermoelectric Waste Heat Recovery Program for Passenger Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat Recovery Program for Passenger Vehicles Thermoelectric Waste Heat Recovery Program for Passenger Vehicles 2012 DOE Hydrogen and Fuel Cells Program and Vehicle ...

  5. Status of Segmented Element Thermoelectric Generator for Vehicle...

    Broader source: Energy.gov (indexed) [DOE]

    Discusses progress of thermoelectric generator development at BSST and assessment of potential to enter commercial operation in vehicles crane.pdf (2.32 MB) More Documents & ...

  6. Enhancement of automotive exhaust heat recovery by thermoelectric...

    Office of Scientific and Technical Information (OSTI)

    exists between the gas and solid surface temperature due ... practice in thermoelectric waste energy harvesting ... Energy Conversion and Management; Journal Volume: 224; ...

  7. A miniaturized mW thermoelectric generator for nw objectives...

    Office of Scientific and Technical Information (OSTI)

    reliable power for decades. Citation Details In-Document Search Title: A miniaturized mW thermoelectric generator for nw objectives: continuous, autonomous, reliable power for ...

  8. Strategies for High Thermoelectric zT in Bulk Materials

    Office of Energy Efficiency and Renewable Energy (EERE)

    Zintl principle in chemistry, complex electronic band structures, and incorporation of nanometer sized particles were used to explore, optimize and improve bulk thermoelectric materials

  9. High Reliability, High TemperatureThermoelectric Power Generation...

    Broader source: Energy.gov (indexed) [DOE]

    Key technologies and system approaches to excellent record of thermoelectric power sources in deep space missions and development of higher performance TE materials for the next ...

  10. Sandia Energy - The Quest for Efficiency in Thermoelectric Nanowires

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency in Thermoelectric Nanowires Sandia researchers say better materials and manufacturing techniques for nanowires could allow car makers to harvest power from the heat...

  11. Automotive Thermoelectric Moduleswith Scalable Thermo- andElectro...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Moduleswith Scalable Thermo- and Electro-Mechanical Interfaces Automotive Thermoelectric Moduleswith Scalable Thermo- and Electro-Mechanical Interfaces Interface materials based on ...

  12. The potential impact of ZT=4 thermoelectric materials on solar...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: The potential impact of ZT4 thermoelectric materials on solar thermal energy conversion ... B; Journal Volume: 114; Journal Issue: Mar. 2, 2010 Research Org: ...

  13. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Broader source: Energy.gov (indexed) [DOE]

    Energy Conversion for Efficient Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery ...

  14. Overview of Thermoelectric Power Generation Technologies in Japan...

    Broader source: Energy.gov (indexed) [DOE]

    Discusses thermoelectric power generation technologies as applied to waste heat recovery, renewable thermal energy sources, and energy harvesting kajikawa.pdf (4.47 MB) More ...

  15. Calcium manganate: A promising candidate as buffer layer for hybrid halide perovskite photovoltaic-thermoelectric systems

    SciTech Connect (OSTI)

    Zhao, Pengjun; Wang, Hongguang; Kong, Wenwen; Xu, Jinbao Wang, Lei; Ren, Wei; Bian, Liang; Chang, Aimin

    2014-11-21

    We have systematically studied the feasibility of CaMnO{sub 3} thin film, an n-type perovskite, to be utilized as the buffer layer for hybrid halide perovskite photovoltaic-thermoelectric device. Locations of the conduction band and the valence band, spontaneous polarization performance, and optical properties were investigated. Results indicate the energy band of CaMnO{sub 3} can match up well with that of CH{sub 3}NH{sub 3}PbI{sub 3} on separating electron-hole pairs. In addition, the consistent polarization angle helps enlarge the open circuit voltage of the composite system. Besides, CaMnO{sub 3} film shows large absorption coefficient and low extinction coefficient under visible irradiation, demonstrating high carrier concentration, which is beneficial to the current density. More importantly, benign thermoelectric properties enable CaMnO{sub 3} film to assimilate phonon vibration from CH{sub 3}NH3PbI{sub 3}. All the above features lead to a bright future of CaMnO{sub 3} film, which can be a promising candidate as a buffer layer for hybrid halide perovskite photovoltaic-thermoelectric systems.

  16. Radioisotope thermoelectric generator reliability and safety

    SciTech Connect (OSTI)

    Campbell, R.; Klein, J.

    1989-01-01

    There are numerous occasions when a planetary mission requires energy in remote areas of the solar system. Anytime power is required much beyond Mars or the Asteroid Belts, solar power is not an option. The radioisotope thermoelectric generator (RTG) was developed for such a mission requirement. It is a relatively small and lightweight power source that can produce power under adverse conditions. Just this type of source has become the backbone of the power system for far outer plant exploration. Voyagers I and II are utilizing RTGs, which will soon power the Galileo spacecraft to Jupiter and the Ulysses spacecraft to study the solar poles. The paper discusses RTG operation including thermoelectric design, converter design, general-purpose heat source; RTG reliability including design, testing, experience, and launch approval; and RTG safety issues and methods of ensuring safety.

  17. Progress towards an Optimization Methodology for Combustion-Driven Portable Thermoelectric Power Generation Systems

    SciTech Connect (OSTI)

    Krishnan, Shankar; Karri, Naveen K.; Gogna, Pawan K.; Chase, Jordan R.; Fleurial, Jean-Pierre; Hendricks, Terry J.

    2012-03-13

    Enormous military and commercial interests exist in developing quiet, lightweight, and compact thermoelectric (TE) power generation systems. This paper investigates design integration and analysis of an advanced TE power generation system implementing JP-8 fueled combustion and thermal recuperation. Design and development of a portable TE power system using a JP-8 combustor as a high temperature heat source and optimal process flows depend on efficient heat generation, transfer, and recovery within the system are explored. Design optimization of the system required considering the combustion system efficiency and TE conversion efficiency simultaneously. The combustor performance and TE sub-system performance were coupled directly through exhaust temperatures, fuel and air mass flow rates, heat exchanger performance, subsequent hot-side temperatures, and cold-side cooling techniques and temperatures. Systematic investigation of this system relied on accurate thermodynamic modeling of complex, high-temperature combustion processes concomitantly with detailed thermoelectric converter thermal/mechanical modeling. To this end, this work reports on design integration of systemlevel process flow simulations using commercial software CHEMCADTM with in-house thermoelectric converter and module optimization, and heat exchanger analyses using COMSOLTM software. High-performance, high-temperature TE materials and segmented TE element designs are incorporated in coupled design analyses to achieve predicted TE subsystem level conversion efficiencies exceeding 10%. These TE advances are integrated with a high performance microtechnology combustion reactor based on recent advances at the Pacific Northwest National Laboratory (PNNL). Predictions from this coupled simulation established a basis for optimal selection of fuel and air flow rates, thermoelectric module design and operating conditions, and microtechnology heat-exchanger design criteria. This paper will discuss this

  18. Calculation of Nonlinear Thermoelectric Coefficients of InAs1-xSbx Using Monte Carlo Method

    SciTech Connect (OSTI)

    Sadeghian, RB; Bahk, JH; Bian, ZX; Shakouri, A

    2011-12-28

    It was found that the nonlinear Peltier effect could take place and increase the cooling power density when a lightly doped thermoelectric material is under a large electrical field. This effect is due to the Seebeck coefficient enhancement from an electron distribution far from equilibrium. In the nonequilibrium transport regime, the solution of the Boltzmann transport equation in the relaxation-time approximation ceases to apply. The Monte Carlo method, on the other hand, proves to be a capable tool for simulation of semiconductor devices at small scales as well as thermoelectric effects with local nonequilibrium charge distribution. InAs1-xSb is a favorable thermoelectric material for nonlinear operation owing to its high mobility inherited from the binary compounds InSb and InAs. In this work we report simulation results on the nonlinear Peltier power of InAs1-xSb at low doping levels, at room temperature and at low temperatures. The thermoelectric power factor in nonlinear operation is compared with the maximum value that can be achieved with optimal doping in the linear transport regime.

  19. thermo-electric power conversion technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thermo-electric power conversion technology - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management

  20. Develop Thermoelectric Technology for Automotive Waste Heat Recovery |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ace_45_yang.pdf (1.15 MB) More Documents & Publications Develop Thermoelectric Technology for Automotive Waste Heat Recovery Engineering and Materials for Automotive Thermoelectric Applications Solid-State Energy Conversion Overview

  1. Thermoelectric Generator Development at Renault Trucks-Volvo Group |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Reviews project to study the potential of thermoelectricity for diesel engines of trucks and passenger cars, where relatively low exhaust temperature is challenging for waste heat recovery systems aixala.pdf (2.28 MB) More Documents & Publications RENOTER Project RENOTER Project Integrated Design and Manufacturing of Thermoelectric Generator Using Thermal Spray

  2. Thermoelectric HVAC for Light-Duty Vehicle Applications | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace047_maranville_2011_o.pdf (1.08 MB) More Documents & Publications Thermoelectric HVAC for Light-Duty Vehicle Applications Thermoelectric HVAC and Thermal Comfort Enablers for Light-Duty Vehicle Applications

  3. Multi-physics modeling of thermoelectric generators for waste heat recovery applications

    Office of Energy Efficiency and Renewable Energy (EERE)

    Model developed provides effective guidelines to designing thermoelectric generation systems for automotive waste heat recovery applications

  4. Tailored semiconducting carbon nanotube networks with enhanced thermoelectric properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Avery, Azure D.; Zhou, Ben H.; Lee, Jounghee; Lee, Eui -Sup; Miller, Elisa M.; Ihly, Rachelle; Wesenberg, Devin; Mistry, Kevin S.; Guillot, Sarah L.; Zink, Barry L.; et al

    2016-04-04

    Thermoelectric power generation, allowing recovery of part of the energy wasted as heat, is emerging as an important component of renewable energy and energy efficiency portfolios. Although inorganic semiconductors have traditionally been employed in thermoelectric applications, organic semiconductors garner increasing attention as versatile thermoelectric materials. Here we present a combined theoretical and experimental study suggesting that semiconducting single-walled carbon nanotubes with carefully controlled chirality distribution and carrier density are capable of large thermoelectric power factors, higher than 340 μW m-1 K-2, comparable to the best-performing conducting polymers and larger than previously observed for carbon nanotube films. Furthermore, we demonstrate thatmore » phonons are the dominant source of thermal conductivity in the networks, and that our carrier doping process significantly reduces the thermal conductivity relative to undoped networks. As a result, these findings provide the scientific underpinning for improved functional organic thermoelectric composites with carbon nanotube inclusions.« less

  5. Radioisotope thermoelectric generator transport trailer system

    SciTech Connect (OSTI)

    Ard, K.E.; King, D.A.; Leigh, H.; Satoh, J.A.

    1995-01-20

    The Radioisotope Thermoelectric Generator (RTG) Transportation System, designated as System 100, comprises four major systems. The four major systems are designated as the Packaging System (System 120), Trailer System (System 140), Operations and Ancillary Equipment System (System 160), and Shipping and Receiving Facility Transport System (System 180). Packaging System (System 120), including the RTG packaging is licensed (regulatory) hardware; it is certified by the U.S. Department of Energy to be in accordance with Title 10, {ital Code} {ital of} {ital Federal} {ital Regulations}, Part 71 (10 CFR 71). System 140, System 160, and System 180 are nonlicensed (nonregulatory) hardware. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}

  6. Energy harvesting using a thermoelectric material

    DOE Patents [OSTI]

    Nersessian, Nersesse; Carman, Gregory P.; Radousky, Harry B.

    2008-07-08

    A novel energy harvesting system and method utilizing a thermoelectric having a material exhibiting a large thermally induced strain (TIS) due to a phase transformation and a material exhibiting a stress induced electric field is introduced. A material that exhibits such a phase transformation exhibits a large increase in the coefficient of thermal expansion over an incremental temperature range (typically several degrees Kelvin). When such a material is arranged in a geometric configuration, such as, for a example, a laminate with a material that exhibits a stress induced electric field (e.g. a piezoelectric material) the thermally induced strain is converted to an electric field.

  7. Solid state transport-based thermoelectric converter

    DOE Patents [OSTI]

    Hu, Zhiyu

    2010-04-13

    A solid state thermoelectric converter includes a thermally insulating separator layer, a semiconducting collector and an electron emitter. The electron emitter comprises a metal nanoparticle layer or plurality of metal nanocatalyst particles disposed on one side of said separator layer. A first electrically conductive lead is electrically coupled to the electron emitter. The collector layer is disposed on the other side of the separator layer, wherein the thickness of the separator layer is less than 1 .mu.m. A second conductive lead is electrically coupled to the collector layer.

  8. Aerogel Derived Nanostructured Thermoelectric Materials

    SciTech Connect (OSTI)

    Wendell E Rhine, PI; Dong, Wenting; Greg Caggiano, PM

    2010-10-08

    Americas dependence on foreign sources for fuel represents a economic and security threat for the country. These non renewable resources are depleting, and the effects of pollutants from fuels such as oil are reaching a problematic that affects the global community. Solar concentration power (SCP) production systems offer the opportunity to harness one of the United States most under utilized natural resources; sunlight. While commercialization of this technology is increasing, in order to become a significant source of electricity production in the United States the costs of deploying and operating SCP plants must be further reduced. Parabolic Trough SCP technologies are close to meeting energy production cost levels that would raise interest in the technology and help accelerate its adoption as a method to produce a significant portion of the Countrys electric power needs. During this program, Aspen Aerogels will develop a transparent aerogel insulation that can replace the costly vacuum insulation systems that are currently used in parabolic trough designs. During the Phase I program, Aspen Aerogels will optimize the optical and thermal properties of aerogel to meet the needs of this application. These properties will be tested, and the results will be used to model the performance of a parabolic trough HCE system which uses this novel material in place of vacuum. During the Phase II program, Aspen Aerogels will scale up this technology. Together with industry partners, Aspen Aerogels will build and test a prototype Heat Collection Element that is insulated with the novel transparent aerogel material. This new device will find use in parabolic trough SCP applications.

  9. System level modeling of thermoelectric generators for automotive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Uses a model to predict and analyze the system-level performance of a thermoelectric generator in terms of the power output and the power density at the element, module and ...

  10. Recent Progress in the Development of High Efficiency Thermoelectrics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Heat Power Generation Quantum Well Thermoelectrics and Waste Heat Recovery Scale Up of SiSi0.8GE0.2 and B4CB9C Superlattices for Harvesting of Waste Heat in Diesel Engines

  11. High temperature thermoelectric properties of the solid-solution...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: High temperature thermoelectric properties of the solid-solution zintl phase EuCd6-xZnxSb Citation Details In-Document Search Title: High temperature ...

  12. Automotive Thermoelectric Moduleswith Scalable Thermo- and Electro-Mechanical Interfaces

    Broader source: Energy.gov [DOE]

    Interface materials based on carbon nanotubes and metallic alloys, scalable p- and n-type thermoelectrics, materials compatibility for improved reliability, and performance targets for automotive applications are discussed

  13. Development of a 100-Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov [DOE]

    Test results for low and high temperature thermoelectric generators (TEG) those for a 530-watt BiTe TEG; design and construction of a 100-watt high temperature TEG currently in fabrication.

  14. Proactive Strategies for Designing Thermoelectric Materials for Power

    Broader source: Energy.gov (indexed) [DOE]

    Generation | Department of Energy New p-type and n-type multiple-rattler skutterudite thermoelectric materials design, synthesis, fabrication, and characterization for power generation using vehicle exhaust waste heat. subramanian.pdf (1.79

  15. Large-dimension, high-ZT Thermoelectric Nanocomposites for High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BiTe and Pb-based nanocomposites produced with a low-cost scalable process were used for development and testing of ... research and sharing Knowledge DOENSF Thermoelectric ...

  16. High Heat Flux Thermoelectric Module Using Standard Bulk Material...

    Broader source: Energy.gov (indexed) [DOE]

    Presents high heat flux thermoelectric module design for cooling using a novel V-shaped shunt configuration with bulk TE elements achieving high area packing fractions crane.pdf ...

  17. Review of Interests and Activities in Thermoelectric Materials...

    Broader source: Energy.gov (indexed) [DOE]

    waste-heat recovery on vehicles, heat-powered mobile units, and for thermoelectric cooling of high-performance infrared systems for surveillance taylor.pdf (1.18 MB) More ...

  18. High-Temperature High-Efficiency Solar Thermoelectric Generators

    SciTech Connect (OSTI)

    Baranowski, LL; Warren, EL; Toberer, ES

    2014-03-01

    Inspired by recent high-efficiency thermoelectric modules, we consider thermoelectrics for terrestrial applications in concentrated solar thermoelectric generators (STEGs). The STEG is modeled as two subsystems: a TEG, and a solar absorber that efficiently captures the concentrated sunlight and limits radiative losses from the system. The TEG subsystem is modeled using thermoelectric compatibility theory; this model does not constrain the material properties to be constant with temperature. Considering a three-stage TEG based on current record modules, this model suggests that 18% efficiency could be experimentally expected with a temperature gradient of 1000A degrees C to 100A degrees C. Achieving 15% overall STEG efficiency thus requires an absorber efficiency above 85%, and we consider two methods to achieve this: solar-selective absorbers and thermally insulating cavities. When the TEG and absorber subsystem models are combined, we expect that the STEG modeled here could achieve 15% efficiency with optical concentration between 250 and 300 suns.

  19. Fiber optic signal amplifier using thermoelectric power generation

    DOE Patents [OSTI]

    Hart, M.M.

    1993-01-01

    A remote fiber optic signal amplifier for use as a repeater/amplifier, such as in transoceanic communication, powered by a Pu{sub 238} or Sr{sub 90} thermoelectric generator. The amplifier comprises a unit with connections on the receiving and sending sides of the communications system, and an erbium-doped fiber amplifier connecting each sending fiber to each receiving fiber. The thermoelectric generator, preferably a Pu{sub 238} or Sr{sub 90} thermoelectric generator delivers power to the amplifiers through a regulator. The heat exchange surfaces of the thermoelectric generator are made of material resistant to corrosion and biological growth and are directly exposed to the outside, such as the ocean water in transoceanic communications.

  20. Thermoelectric skutterudite compositions and methods for producing the same

    DOE Patents [OSTI]

    Ren, Zhifeng; Yang, Jian; Yan, Xiao; He, Qinyu; Chen, Gang; Hao, Qing

    2014-11-11

    Compositions related to skutterudite-based thermoelectric materials are disclosed. Such compositions can result in materials that have enhanced ZT values relative to one or more bulk materials from which the compositions are derived. Thermoelectric materials such as n-type and p-type skutterudites with high thermoelectric figures-of-merit can include materials with filler atoms and/or materials formed by compacting particles (e.g., nanoparticles) into a material with a plurality of grains each having a portion having a skutterudite-based structure. Methods of forming thermoelectric skutterudites, which can include the use of hot press processes to consolidate particles, are also disclosed. The particles to be consolidated can be derived from (e.g., grinded from), skutterudite-based bulk materials, elemental materials, other non-Skutterudite-based materials, or combinations of such materials.

  1. Fiber optic signal amplifier using thermoelectric power generation

    DOE Patents [OSTI]

    Hart, M.M.

    1995-04-18

    A remote fiber optic signal amplifier for use as a repeater/amplifier, such as in transoceanic communications, powered by a Pu{sub 238} or Sr{sub 90} thermoelectric generator. The amplifier comprises a unit with connections on the receiving and sending sides of the communications system, and an erbium-doped fiber amplifier connecting each sending fiber to each receiving fiber. The thermoelectric generator, preferably a Pu{sub 238} or Sr{sub 90} thermoelectric generator delivers power to the amplifiers through a regulator. The heat exchange surfaces of the thermoelectric generator are made of materials resistant to corrosion and biological growth and are directly exposed to the outside, such as the ocean water in transoceanic communications. 2 figs.

  2. Fiber optic signal amplifier using thermoelectric power generation

    DOE Patents [OSTI]

    Hart, Mark M.

    1995-01-01

    A remote fiber optic signal amplifier for use as a repeater/amplifier, such as in transoceanic communications, powered by a Pu.sub.238 or Sr.sub.90 thermoelectric generator. The amplifier comprises a unit with connections on the receiving and sending sides of the communications system, and an erbium-doped fiber amplifier connecting each sending fiber to each receiving fiber. The thermoelectric generator, preferably a Pu.sub.238 or Sr.sub.90 thermoelectric generator delivers power to the amplifiers through a regulator. The heat exchange surfaces of the thermoelectric generator are made of materials resistant to corrosion and biological growth and are directly exposed to the outside, such as the ocean water in transoceanic communications.

  3. Electronic, phononic, and thermoelectric properties of graphyne sheets

    SciTech Connect (OSTI)

    Sevinli, Hldun; Sevik, Cem

    2014-12-01

    Electron, phonon, and thermoelectric transport properties of ?-, ?-, ?-, and 6,6,12-graphyne sheets are compared and contrasted with those of graphene. ?-, ?-, and 6,6,12-graphynes, with direction dependent Dirac dispersions, have higher electronic transmittance than graphene. ?-graphyne also attains better electrical conduction than graphene except at its band gap. Vibrationally, graphene conducts heat much more efficiently than graphynes, a behavior beyond an atomic density differences explanation. Seebeck coefficients of the considered Dirac materials are similar but thermoelectric power factors decrease with increasing effective speeds of light. ?-graphyne yields the highest thermoelectric efficiency with a thermoelectric figure of merit as high as ZT?=?0.45, almost an order of magnitude higher than that of graphene.

  4. Thermoelectrics Interests and Research: ARL and TARDEC | Department of

    Broader source: Energy.gov (indexed) [DOE]

    of Energy Composite films of multi-walled carbon nanotubes/polyvinylidene fluoride layered into multiple element modules, results in thermoelectric fabrics with increased power output carroll.pdf (1.61 MB) More Documents & Publications Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts High Performance Zintl Phase TE Materials with Embedded Particles Novel Nanostructured Interface Solution for Automotive Thermoelectric Modules Application

    International is a trade

  5. Thermoelectric generator and method for the fabrication thereof

    DOE Patents [OSTI]

    Benson, D.K.; Tracy, C.E.

    1984-08-01

    A thermoelectric generator using semiconductor elements for responding to a temperature gradient to produce electrical energy with all of the semiconductor elements being of the same type is disclosed. A continuous process for forming substrates on which the semiconductor elements and superstrates are deposited and a process for forming the semiconductor elements on the substrates are also disclosed. The substrates with the semiconductor elements thereon are combined with superstrates to form modules for use as thermoelectric generators.

  6. Thermoelectric generator and method for the fabrication thereof

    DOE Patents [OSTI]

    Benson, David K.; Tracy, C. Edwin

    1987-01-01

    A thermoelectric generator using semiconductor elements for responding to a temperature gradient to produce electrical energy with all of the semiconductor elements being of the same type is disclosed. A continuous process for forming substrates on which the semiconductor elements and superstrates are deposited and a process for forming the semiconductor elements on the substrates are also disclosed. The substrates with the semiconductor elements thereon are combined with superstrates to form modules for use thermoelectric generators.

  7. Resonant Level Enhancement of the Thermoelectric Power of Bi2Te3...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resonant Level Enhancement of the Thermoelectric Power of Bi2Te3 with Tin Resonant Level Enhancement of the Thermoelectric Power of Bi2Te3 with Tin Application to practical p-type...

  8. A new n-type half-Heusler thermoelectric material NbCoSb (Journal...

    Office of Scientific and Technical Information (OSTI)

    A new n-type half-Heusler thermoelectric material NbCoSb Citation Details In-Document Search Title: A new n-type half-Heusler thermoelectric material NbCoSb Highlights: * ...

  9. High-Temperature Thermoelectric Properties of p-Type Yb-filled...

    Office of Scientific and Technical Information (OSTI)

    High-Temperature Thermoelectric Properties of p-Type Yb-filled Skutterudites with FeSb2 Nanoinclusions Citation Details In-Document Search Title: High-Temperature Thermoelectric ...

  10. Thermoelectric properties of rocksalt ZnO from first-principles calculations

    SciTech Connect (OSTI)

    Alvarado, Andrew; Attapattu, Jeevake; Zhang, Yi; Chen, Changfeng

    2015-10-28

    Zinc oxide (ZnO) undergoes a pressure-induced structural transition from its normal ambient-pressure wurtzite (WZ) phase to a rocksalt (RS) phase around 10 GPa. A recent experiment shows that the high-pressure RS ZnO phase can be recovered and stabilized at ambient conditions, which raises exciting prospects of expanding the range of properties of ZnO. For a fundamental understanding of the RS ZnO phase, we have performed first-principles calculations to determine its electronic, phonon, and thermodynamic properties at high (20 GPa) and ambient (0 GPa) pressure. Furthermore, we have calculated its electrical and thermal transport properties, which allow an evaluation of its thermoelectric figure of merit ZT at different temperature and doping levels. Our calculations show that the ambient-pressure RS ZnO phase can reach ZT values of 0.25 to 0.3 under both n-type and p-type doping in a large temperature range of 400 K to 800 K, which is considerably lower than the temperature range of 1400 K to 1600 K where WZ ZnO reaches similar ZT values. These results establish RS ZnO as a promising material for thermoelectric devices designed to operate at temperatures desirable for many heat recovery applications.

  11. Toward Nanostructured Thermoelectrics. Synthesis and Characterization of Lead Telluride Gels and Aerogels

    SciTech Connect (OSTI)

    Ganguly, Shreyashi [Wayne State Univ., Detroit, MI (United States); Brock, Stephanie L. [Wayne State Univ., Detroit, MI (United States)

    2011-05-12

    The synthesis and characterization of lead telluride (PbTe) gels and aerogels with nanostructured features of potential benefit for enhanced thermoelectrics is reported. In this approach, discrete thiolate-capped PbTe nanoparticles were synthesized by a solution-based approach followed by oxidation-induced nanoparticle assembly with tetranitromethane or hydrogen peroxide to form wet gels. Drying of the wet gels by supercritical CO? extraction yielded aerogels, whereas xerogels were produced by ambient pressure bench top drying. The gels consist of an interconnected network of colloidal nanoparticles and pores with surface areas up to 74 m g-1. The thermal stability of the nanostructures relative to nanoparticles was probed with the help of in situ transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The aerogels were observed to sublime at a higher temperature and over a larger range (425500 C) relative to the precursor nanoparticles. TGA-DSC suggests that organic capping groups can be removed in the region 250450 C, and melting of PbTe nanoparticles occurs near the temperature for bulk materials (ca. 920 C). The good thermal stability combined with the presence of nanoscale interfaces suggests PbTe gels may show promise in thermoelectric devices.

  12. Exploration of Melt Spinning as a Route to Large Volume Production of Skutterudite Thermoelectric Materials

    Broader source: Energy.gov [DOE]

    Melt spinning combined with Spark Plasma Sintering provides a potential route to the mass production of Skutterudite based thermoelectric materials

  13. Pb7Bi4Se13: A Lillianite Homologue with Promising Thermoelectric...

    Office of Scientific and Technical Information (OSTI)

    Subject: solar (photovoltaic), solar (thermal), phonons, thermal conductivity, thermoelectric, electrodes - solar, defects, charge transport, materials and chemistry by design, ...

  14. DOE Office of Basic Sciences: An Overview of Basic Research Activities on Thermoelectrics

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presents overview of BES Physical Behavior of Materials Program including examples of research related to thermoelectric technologies

  15. Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE)

    Developing a low and high temperature dual thermoelectric generation waste heat recovery system for light-duty vehicles.

  16. NSF/DOE Thermoelectric Partnership: High-Performance Thermoelectric Devices Based on Abundant Silicide Materials for Vehicle Waste Heat Recovery

    Office of Energy Efficiency and Renewable Energy (EERE)

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  17. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine

    Broader source: Energy.gov (indexed) [DOE]

    Powered Vehicle | Department of Energy Determining if a 10% fuel economy improvement is possible using thermoelectrics on a OTR truck schock.pdf (2.38 MB) More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Wate

  18. Thermoelectric material including conformal oxide layers and method of making the same using atomic layer deposition

    DOE Patents [OSTI]

    Cho, Jung Young; Ahn, Dongjoon; Salvador, James R.; Meisner, Gregory P.

    2016-06-07

    A thermoelectric material includes a substrate particle and a plurality of conformal oxide layers formed on the substrate particle. The plurality of conformal oxide layers has a total oxide layer thickness ranging from about 2 nm to about 20 nm. The thermoelectric material excludes oxide nanoparticles. A method of making the thermoelectric material is also disclosed herein.

  19. Thermoelectric powered wireless sensors for spent fuel monitoring

    SciTech Connect (OSTI)

    Carstens, T.; Corradini, M.; Blanchard, J.; Ma, Z.

    2011-07-01

    This paper describes using thermoelectric generators to power wireless sensors to monitor spent nuclear fuel during dry-cask storage. OrigenArp was used to determine the decay heat of the spent fuel at different times during the service life of the dry-cask. The Engineering Equation Solver computer program modeled the temperatures inside the spent fuel storage facility during its service life. The temperature distribution in a thermoelectric generator and heat sink was calculated using the computer program Finite Element Heat Transfer. From these temperature distributions the power produced by the thermoelectric generator was determined as a function of the service life of the dry-cask. In addition, an estimation of the path loss experienced by the wireless signal can be made based on materials and thickness of the structure. Once the path loss is known, the transmission power and thermoelectric generator power requirements can be determined. This analysis estimates that a thermoelectric generator can produce enough power for a sensor to function and transmit data from inside the dry-cask throughout its service life. (authors)

  20. Engineering and Materials for Automotive Thermoelectric Applications

    Office of Energy Efficiency and Renewable Energy (EERE)

    Design and optimization of TE exhaust generator, vehicle integration, and thermal management; distributed cooling and heating with TE devices; discovery and development of highly efficient TE materials.

  1. Challenges and Opportunities in Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High performance Zintl phase TE materials with embedded nanoparticles High performance Zintl phase TE materials with embedded nanoparticles Recent Device Developments with Advanced ...

  2. Miniature thermo-electric cooled cryogenic pump

    DOE Patents [OSTI]

    Keville, R.F.

    1997-11-18

    A miniature thermo-electric cooled cryogenic pump is described for removing residual water molecules from an inlet sample prior to sample analysis in a mass spectroscopy system, such as ion cyclotron resonance (ICR) mass spectroscopy. The cryogenic pump is a battery operated, low power (<1.6 watts) pump with a {Delta}T=100 C characteristic. The pump operates under vacuum pressures of 5{times}10{sup {minus}4} Torr to ultra high vacuum (UHV) conditions in the range of 1{times}10{sup {minus}7} to 3{times}10{sup {minus}9} Torr and will typically remove partial pressure, 2{times}10{sup {minus}7} Torr, residual water vapor. The cryogenic pump basically consists of an inlet flange piece, a copper heat sink with a square internal bore, four two tier Peltier (TEC) chips, a copper low temperature square cross sectional tubulation, an electronic receptacle, and an exit flange piece, with the low temperature tubulation being retained in the heat sink at a bias angle of 5{degree}, and with the TECs being positioned in parallel to each other with a positive potential being applied to the top tier thereof. 2 figs.

  3. Thermoelectric Properties of Indium-Filled Skutterudites

    SciTech Connect (OSTI)

    He, Tao; Chen, Jiazhong; Rosenfeld, H. David; Subramanian, M.A.

    2008-09-18

    Structural, electrical, and thermal transport properties of CoSb{sub 3} partially filled with indium are reported. Polycrystalline samples of In{sub x}Co{sub 4}Sb{sub 12} (0 {le} x {le} 0.3) were prepared by solid-state reaction under a gas mixture of 5% H{sub 2} and 95% Ar. The solubility limit of the indium filling voids in CoSb{sub 3} was found to be close to 0.22. Synchrotron X-ray diffraction refinement of the x = 0.2 sample showed that the indium is located in the classic rattler site and has a substantially larger thermal factor than those of Co and Sb. The electrical resistivity, Seebeck coefficients, and thermal conductivity of the In{sub x}Co{sub 4}Sb{sub 12} samples were measured in the temperature range of 300-600 K. All samples showed metal-like behavior, and the large negative Seebeck coefficients indicated n-type conduction. The thermal conductivity decreased with increasing temperature for all samples. A thermoelectric figure-of-merit (ZT) {ge} 1 (n-type) has been achieved when x {ge} 0.2 in In{sub x}Co{sub 4}Sb{sub 12} at 575 K.

  4. Miniature thermo-electric cooled cryogenic pump

    DOE Patents [OSTI]

    Keville, Robert F.

    1997-01-01

    A miniature thermo-electric cooled cryogenic pump for removing residual water molecules from an inlet sample prior to sample analysis in a mass spectroscopy system, such as ion cyclotron resonance (ICR) mass spectroscopy. The cryogenic pump is a battery operated, low power (<1.6 watts) pump with a .DELTA.T=100.degree. C. characteristic. The pump operates under vacuum pressures of 5.times.10.sup.-4 Torr to ultra high vacuum (UHV) conditions in the range of 1.times.10.sup.-7 to 3.times.10.sup.-9 Torr and will typically remove partial pressure, 2.times.10.sup.-7 Torr, residual water vapor. The cryogenic pump basically consists of an inlet flange piece, a copper heat sink with a square internal bore, four two tier Peltier (TEC) chips, a copper low temperature square cross sectional tubulation, an electronic receptacle, and an exit flange piece, with the low temperature tubulation being retained in the heat sink at a bias angle of 5.degree., and with the TECs being positioned in parallel to each other with a positive potential being applied to the top tier thereof.

  5. Electron-beam activated thermal sputtering of thermoelectric materials

    SciTech Connect (OSTI)

    Wu Jinsong; Dravid, Vinayak P.; He Jiaqing; Han, Mi-Kyung; Sootsman, Joseph R.; Girard, Steven; Arachchige, Indika U.; Kanatzidis, Mercouri G.

    2011-08-15

    Thermoelectricity and Seebeck effect have long been observed and validated in bulk materials. With the development of advanced tools of materials characterization, here we report the first observation of such an effect in the nanometer scale: in situ directional sputtering of several thermoelectric materials inside electron microscopes. The temperature gradient introduced by the electron beam creates a voltage-drop across the samples, which enhances spontaneous sputtering of specimen ions. The sputtering occurs along a preferential direction determined by the direction of the temperature gradient. A large number of nanoparticles form and accumulate away from the beam location as a result. The sputtering and re-crystallization are found to occur at temperatures far below the melting points of bulk materials. The sputtering occurs even when a liquid nitrogen cooling holder is used to keep the overall temperature at -170 deg. C. This unique phenomenon that occurred in the nanometer scale may provide useful clues to understanding the mechanism of thermoelectric effect.

  6. Electron-beam activated thermal sputtering of thermoelectric materials.

    SciTech Connect (OSTI)

    Wu, J.; He, J.; Han, M-K.; Sootsman, J. R.; Girard, S.; Arachchige, I. U.; Kanatzidis, M. G.; Dravid, V. P.

    2011-08-01

    Thermoelectricity and Seebeck effect have long been observed and validated in bulk materials. With the development of advanced tools of materials characterization, here we report the first observation of such an effect in the nanometer scale: in situ directional sputtering of several thermoelectric materials inside electron microscopes. The temperature gradient introduced by the electron beam creates a voltage-drop across the samples, which enhances spontaneous sputtering of specimen ions. The sputtering occurs along a preferential direction determined by the direction of the temperature gradient. A large number of nanoparticles form and accumulate away from the beam location as a result. The sputtering and re-crystallization are found to occur at temperatures far below the melting points of bulk materials. The sputtering occurs even when a liquid nitrogen cooling holder is used to keep the overall temperature at -170 C. This unique phenomenon that occurred in the nanometer scale may provide useful clues to understanding the mechanism of thermoelectric effect.

  7. Microscopic theory of thermoelectric properties of silicon nanowires

    SciTech Connect (OSTI)

    Vo, T; Williamson, A; Lordi, V; Galli, G

    2007-06-14

    We present predictions of the thermoelectric figure of merit (ZT) of Si nanowires, as obtained using Boltzman transport equation and ab-initio electronic structure calculations. We find that ZT is strongly dependent on the nanowire growth direction and surface reconstruction and we discuss general rules to select silicon based nanostructures with combined n-type and p-type optimal ZT. In particular, our calculations indicate that 1 nm wires grown in the [001] and [011] directions can attain ZT values which are about twice as high as those of ordinary thermoelectric materials.

  8. Thermoelectric power generator for variable thermal power source

    SciTech Connect (OSTI)

    Bell, Lon E; Crane, Douglas Todd

    2015-04-14

    Traditional power generation systems using thermoelectric power generators are designed to operate most efficiently for a single operating condition. The present invention provides a power generation system in which the characteristics of the thermoelectrics, the flow of the thermal power, and the operational characteristics of the power generator are monitored and controlled such that higher operation efficiencies and/or higher output powers can be maintained with variably thermal power input. Such a system is particularly beneficial in variable thermal power source systems, such as recovering power from the waste heat generated in the exhaust of combustion engines.

  9. Photovoltaic device

    DOE Patents [OSTI]

    Reese, Jason A.; Keenihan, James R.; Gaston, Ryan S.; Kauffmann, Keith L.; Langmaid, Joseph A.; Lopez, Leonardo C.; Maak, Kevin D.; Mills, Michael E.; Ramesh, Narayan; Teli, Samar R.

    2015-06-02

    The present invention is premised upon an improved photovoltaic device ("PV device"), more particularly to an improved photovoltaic device with a multilayered photovoltaic cell assembly and a body portion joined at an interface region and including an intermediate layer, at least one interconnecting structural member, relieving feature, unique component geometry, or any combination thereof.

  10. Photovoltaic device

    SciTech Connect (OSTI)

    Reese, Jason A.; Keenihan, James R.; Gaston, Ryan S.; Kauffmann, Keith L.; Langmaid, Joseph A.; Lopez, Leonardo C.; Maak, Kevin D.; Mills, Michael E.; Ramesh, Narayan; Teli, Samar R.

    2015-09-01

    The present invention is premised upon an improved photovoltaic device ("PV device"), more particularly to an improved photovoltaic device (10) with a multilayered photovoltaic cell assembly (100) and a body portion (200) joined at an interface region (410) and including an intermediate layer (500), at least one interconnecting structural member (1500), relieving feature (2500), unique component geometry, or any combination thereof.

  11. High Thermoelectric Performance in Copper Telluride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Ying; Zhang, Tiansong; Shi, Xun; Wei, Su-Huai; Chen, Lidong

    2015-06-21

    Recently, Cu 2-δ S and Cu 2-δ Se were reported to have an ultralow thermal conductivity and high thermoelectric figure of merit zT. Thus, as a member of the copper chalcogenide group, Cu 2-δ Te is expected to possess superior zTs because Te is less ionic and heavy. However, the zT value is low in the Cu2Te sintered using spark plasma sintering, which is typically used to fabricate high-density bulk samples. In addition, the extra sintering processes may change the samples’ compositions as well as their physical properties, especially for Cu2Te, which has many stable and meta-stable phasesmore » as well as weaker ionic bonding between Cu and Te as compared with Cu2S and Cu2Se. In this study, high-density Cu2Te samples were obtained using direct annealing without a sintering process. In the absence of sintering processes, the samples’ compositions could be well controlled, leading to substantially reduced carrier concentrations that are close to the optimal value. The electrical transports were optimized, and the thermal conductivity was considerably reduced. The zT values were significantly improved—to 1.1 at 1000 K—which is nearly 100% improvement. Furthermore, this method saves substantial time and cost during the sample’s growth. The study demonstrates that Cu 2-δ X (X=S, Se and Te) is the only existing system to show high zTs in the series of compounds composed of three sequential primary group elements.« less

  12. High Thermoelectric Performance in Copper Telluride

    SciTech Connect (OSTI)

    He, Ying; Zhang, Tiansong; Shi, Xun; Wei, Su-Huai; Chen, Lidong

    2015-06-21

    Recently, Cu 2-δ S and Cu 2-δ Se were reported to have an ultralow thermal conductivity and high thermoelectric figure of merit zT. Thus, as a member of the copper chalcogenide group, Cu 2-δ Te is expected to possess superior zTs because Te is less ionic and heavy. However, the zT value is low in the Cu2Te sintered using spark plasma sintering, which is typically used to fabricate high-density bulk samples. In addition, the extra sintering processes may change the samples’ compositions as well as their physical properties, especially for Cu2Te, which has many stable and meta-stable phases as well as weaker ionic bonding between Cu and Te as compared with Cu2S and Cu2Se. In this study, high-density Cu2Te samples were obtained using direct annealing without a sintering process. In the absence of sintering processes, the samples’ compositions could be well controlled, leading to substantially reduced carrier concentrations that are close to the optimal value. The electrical transports were optimized, and the thermal conductivity was considerably reduced. The zT values were significantly improved—to 1.1 at 1000 K—which is nearly 100% improvement. Furthermore, this method saves substantial time and cost during the sample’s growth. The study demonstrates that Cu 2-δ X (X=S, Se and Te) is the only existing system to show high zTs in the series of compounds composed of three sequential primary group elements.

  13. QUANTUM WELL THERMOELECTRICS FOR CONVERTING WASTE HEAT TO ELECTRICITY

    SciTech Connect (OSTI)

    Saeid Ghamaty

    2006-02-01

    New thermoelectric materials using Quantum Well (QW) technology are expected to increase the energy conversion efficiency to more than 25% from the present 5%, which will allow for the low cost conversion of waste heat into electricity. Hi-Z Technology, Inc. has been developing QW technology over the past six years. It will use Caterpillar, Inc., a leader in the manufacture of large scale industrial equipment, for verification and life testing of the QW films and modules. Other members of the team are Pacific Northwest National Laboratory, who will sputter large area QW films. The Scope of Work is to develop QW materials from their present proof-of-principle technology status to a pre-production level over a proposed three year period. This work will entail fabricating the QW films through a sputtering process of 50 {micro}m thick multi layered films and depositing them on 12 inch diameter, 5 {micro}m thick Si substrates. The goal in this project is to produce the technology for fabricating a basic 10-20 watt module that can be used to build up any size generator such as: a 5-10 kW Auxiliary Power Unit (APU), a multi kW Waste Heat Recovery Generator (WHRG) for a class 8 truck or as small as a 10-20 watt unit that would fit on a daily used wood fired stove and allow some of the estimated 2-3 billion people on earth, who have no electricity, to recharge batteries (such as a cell phone) or directly power radios, TVs, computers and other low powered devices. In this quarter Hi-Z has continued fabrication of the QW films and also continued development of joining techniques for fabricating the N and P legs into a couple. The upper operating temperature limit for these films is unknown and will be determined via the isothermal aging studies that are in progress. We are reporting on these studies in this report. The properties of the QW films that are being evaluated are Seebeck, thermal conductivity and thermal-to-electricity conversion efficiency.

  14. QUANTUM WELL THERMOELECTRICS FOR CONVERTING WASTE HEAT TO ELECTRICITY

    SciTech Connect (OSTI)

    Saeid Ghamaty

    2006-03-31

    New thermoelectric materials using Quantum Well (QW) technology are expected to increase the energy conversion efficiency to more than 25% from the present 5%, which will allow for the low cost conversion of waste heat into electricity. Hi-Z Technology, Inc. has been developing QW technology over the past six years. It will use Caterpillar, Inc., a leader in the manufacture of large scale industrial equipment, for verification and life testing of the QW films and modules. Other members of the team are Pacific Northwest National Laboratory, who will sputter large area QW films. The Scope of Work is to develop QW materials from their present proof-of-principle technology status to a pre-production level over a proposed three year period. This work will entail fabricating the QW films through a sputtering process of 50 {micro}m thick multi layered films and depositing them on 12 inch diameter, 5 {micro}m thick Si substrates. The goal in this project is to produce the technology for fabricating a basic 10-20 watt module that can be used to build up any size generator such as: a 5-10 kW Auxiliary Power Unit (APU), a multi kW Waste Heat Recovery Generator (WHRG) for a class 8 truck or as small as a 10-20 watt unit that would fit on a daily used wood fired stove and allow some of the estimated 2-3 billion people on earth, who have no electricity, to recharge batteries (such as a cell phone) or directly power radios, TVs, computers and other low powered devices. In this quarter Hi-Z has continued fabrication of the QW films and also continued development of joining techniques for fabricating the N and P legs into a couple. The upper operating temperature limit for these films is unknown and will be determined via the isothermal aging studies that are in progress. We are reporting on these studies in this report. The properties of the QW films that are being evaluated are Seebeck, thermal conductivity and thermal-to-electricity conversion efficiency.

  15. New approaches to thermoelectric cooling effects in magnetic fields

    SciTech Connect (OSTI)

    Migliori, A.; Darling, T.W.; Freibert, F.; Trugman, S.A.; Moshopoulou, E.; Sarrao, J.L.

    1997-08-01

    The authors review thermoelectric effects in a magnetic field at a phenomenological level. Discussions of the limiting performance and problems with its computation for both Peltier and Ettingshausen coolers are presented. New principles are discussed to guide the materials scientist in the search for better Ettingshausen materials, and a brief review of the subtle measurement problems is presented.

  16. Thermoelectric Materials Development for Low Temperature Geothermal Power Generation

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Tim Hansen

    2016-01-29

    Data includes characterization results for novel thermoelectric materials developed specifically for power generation from low temperature geothermal brines. Materials characterization data includes material density, thickness, resistance, Seebeck coefficient. This research was carried out by Novus Energy Partners in Cooperation with Southern Research Institute for a Department of Energy Sponsored Project.

  17. Measurement and simulation of thermoelectric efficiency for single leg

    SciTech Connect (OSTI)

    Hu, Xiaokai; Yamamoto, Atsushi Ohta, Michihiro; Nishiate, Hirotaka

    2015-04-15

    Thermoelectric efficiency measurements were carried out on n-type bismuth telluride legs with the hot-side temperature at 100 and 150°C. The electric power and heat flow were measured individually. Water coolant was utilized to maintain the cold-side temperature and to measure heat flow out of the cold side. Leg length and vacuum pressure were studied in terms of temperature difference across the leg, open-circuit voltage, internal resistance, and heat flow. Finite-element simulation on thermoelectric generation was performed in COMSOL Multiphysics, by inputting two-side temperatures and thermoelectric material properties. The open-circuit voltage and resistance were in good agreement between the measurement and simulation. Much larger heat flows were found in measurements, since they were comprised of conductive, convective, and radiative contributions. Parasitic heat flow was measured in the absence of bismuth telluride leg, and the conductive heat flow was then available. Finally, the maximum thermoelectric efficiency was derived in accordance with the electric power and the conductive heat flow.

  18. Thermoelectric Materials by Design, Computational Theory and Structure |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. pm_11_singh.pdf (2.16 MB) More Documents & Publications Thermoelectrics Theory and Structure Vehicle Technologies Office: 2008 Oak Ridge Transportation Technology Program Annual Report

  19. Thermo-electric modular structure and method of making same

    DOE Patents [OSTI]

    Freedman, N.S.; Horsting, C.W.; Lawrence, W.F.; Carrona, J.J.

    1974-01-29

    A method is presented for making a thermoelectric module wtth the aid of an insulating wafer having opposite metallized surfaces, a pair of similar equalizing sheets of metal, a hot-junction strap of metal, a thermoelectric element having hot- and cold-junction surfaces, and a radiator sheet of metal. The method comprises the following steps: brazing said equalizer sheets to said opposite metallized surfaces, respectively, of said insulating wafer with pure copper in a non-oxidizing ambient; brazing one surface of said hot-junction strap to one of the surfaces of said equalizing sheet with a nickel-gold alloy in a non- oxidizing ambient; and diffusion bonding said hot-junction surface of said thermoelectric element to the other surface of said hot-junction strap and said radiator sheet to said cold-junction surface of said thermoelectric element, said diffusion bonding being carried out in a non-oxidizing ambient, under compressive loading, at a temperature of about 550 deg C., and for about one-half hour. (Official Gazette)

  20. Molybdenum-platinum-oxide electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Schmatz, Duane J.

    1990-01-01

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a solid electrolyte carrying a thin film comprising molybdenum-platinum-oxide as an electrode deposited by physical deposition techniques. The invention is also directed to the method of making same.

  1. Electrocaloric devices based on thini-film heat switches

    SciTech Connect (OSTI)

    Epstein, Richard I; Malloy, Kevin J

    2009-01-01

    We describe a new approach to refrigeration and electrical generation that exploits the attractive properties of thin films of electrocaloric materials. Layers of electrocaloric material coupled with thin-film heat switches can work as either refrigerators or electrical generators, depending on the phasing of the applied voltages and heat switching. With heat switches based on thin layers of liquid crystals, the efficiency of these thin-film heat engines can be at least as high as that of current thermoelectric devices. Advanced heat switches would enable thin-film heat engines to outperform conventional vaporcompression devices.

  2. Semiconducting glasses: A new class of thermoelectric materials?

    SciTech Connect (OSTI)

    Goncalves, A.P.; Vaney, J.B.; Lenoir, B.; Piarristeguy, A.; Pradel, A.; Monnier, J.; Ochin, P.; Godart, C.

    2012-09-15

    The deeper understanding of the factors that affect the dimensionless figure of merit, ZT, and the use of new synthetic methods has recently led to the development of novel systems with improved thermoelectric performances. Albeit up to now with ZT values lower than the conventional bulk materials, semiconducting glasses have also emerged as a new family of potential thermoelectric materials. This paper reviews the latest advances on semiconducting glasses for thermoelectric applications. Key examples of tellurium-based glasses, with high Seebeck coefficients, very low thermal conductivities and tunable electrical conductivities, are presented. ZT values as high as 0.2 were obtained at room temperature for several tellurium-based glasses with high copper concentrations, confirming chalcogenide semiconducting glasses as good candidates for high-performance thermoelectric materials. However, the temperature stability and electrical conductivity of the reported glasses are still not good enough for practical applications and further studies are still needed to enhance them. - Graphical abstract: Power factor as a function of the temperature for the Cu{sub 27.5}Ge{sub 2.5}Te{sub 70} and Cu{sub 30}As{sub 15}Te{sub 55} seniconducting glasses. Highlights: Black-Right-Pointing-Pointer A review of semiconducting glasses for thermoelectrics applications is presented. Black-Right-Pointing-Pointer The studied semiconducting glasses present very low thermal conductivities. Black-Right-Pointing-Pointer Composition can tune electrical conductivity and Seebeck coefficient. Black-Right-Pointing-Pointer ZT=0.2 is obtained at 300 K for different semiconducting glasses.

  3. Sealing device

    DOE Patents [OSTI]

    Garcia-Crespo, Andres Jose

    2013-12-10

    A sealing device for sealing a gap between a dovetail of a bucket assembly and a rotor wheel is disclosed. The sealing device includes a cover plate configured to cover the gap and a retention member protruding from the cover plate and configured to engage the dovetail. The sealing device provides a seal against the gap when the bucket assemply is subjected to a centrifugal force.

  4. Micro- & Nano-Technology: A Critical Design Key in Advanced Thermoelectric Cooling Systems

    SciTech Connect (OSTI)

    Hendricks, Terry J.; Karri, Naveen K.

    2009-07-01

    Advanced, thermoelectric cooling technologies now are receiving more research attention to provide cooling in advanced vehicles and residential systems to assist in increasing overall system energy efficiency and reduce greenhouse gas impacts from leakage by current R-134a systems. This work explores the systems-related impacts, barriers, and challenges of using micro-technology solutions integrated with advances in nano-scale thermoelectric materials in advanced TE cooling systems. Integrated system-level analyses that simultaneously account for thermal energy transport into / dissipation out of the TE device, environmental effects, temperature-dependent TE and thermo-physical properties, thermal losses, and thermal and electrical contact resistances are presented to establish accurate optimum system designs using both BixSb2-xTe3 / Bi2Te3 TE systems and Bi2Te3 TE systems. This work established the design trends and identified optimum design regimes and metrics for these types of systems that will minimize system mass, volume and cost to maximize their commercialization potential in vehicular and residential applications. The relationships between important design metrics, like coefficient of performance, specific cooling capacity and cooling heat flux requirements, upper limits, and critical differences in these metrics in BixSb2-xTe3 / Bi2Te3 TE systems and Bi2Te3 TE systems are explored and quantified. Finally, the work discusses the critical role that micro-technologies and nano-technologies can play in enabling miniature TE cooling systems in advanced vehicle and residential applications and gives some key relevant examples.

  5. Interpretation of thermoelectric properties of Cu substituted LaCoO{sub 3} ceramics

    SciTech Connect (OSTI)

    Choudhary, K. K.; Kaurav, N.; Sharma, U.; Ghosh, S. K.

    2014-04-24

    The thermoelectric properties of LaCo{sub 1?x}Cu{sub x}O{sub 3??} is theoretically analyzed, it is observed that thermoelectric figure of merit ZT (=S{sup 2}?T/?) is maximized by Cu substitution in LaCoO{sub 3} Ceramics at x=0.15. The lattice thermal conductivity and thermoelectric power were estimated by the scattering of phonons with defects, grain boundaries, electrons and phonons to evaluate the thermoelectric properties. We found that Cu substitution increase the phonon scattering with grain boundaries and defects which significantly increase the thermoelectric power and decrease the thermal conductivity. The present numerical analysis will help in designing more efficient thermoelectric materials.

  6. BRAKE DEVICE

    DOE Patents [OSTI]

    O'Donnell, T.J.

    1959-03-10

    A brake device is described for utilization in connection with a control rod. The device comprises a pair of parallelogram link mechanisms, a control rod moveable rectilinearly therebetween in opposite directions, and shoes resiliently supported by the mechanism for frictional engagement with the control rod.

  7. Electrochromic devices

    DOE Patents [OSTI]

    Allemand, Pierre M.; Grimes, Randall F.; Ingle, Andrew R.; Cronin, John P.; Kennedy, Steve R.; Agrawal, Anoop; Boulton, Jonathan M.

    2001-01-01

    An electrochromic device is disclosed having a selective ion transport layer which separates an electrochemically active material from an electrolyte containing a redox active material. The devices are particularly useful as large area architectural and automotive glazings due to there reduced back reaction.

  8. PLASMA DEVICE

    DOE Patents [OSTI]

    Gow, J.D.; Wilcox, J.M.

    1961-12-26

    A device is designed for producing and confining highenergy plasma from which neutrons are generated in copious quantities. A rotating sheath of electrons is established in a radial electric field and axial magnetic field produced within the device. The electron sheath serves as a strong ionizing medium to gas introdueed thereto and also functions as an extremely effective heating mechanism to the resulting plasma. In addition, improved confinement of the plasma is obtained by ring magnetic mirror fields produced at the ends of the device. Such ring mirror fields are defined by the magnetic field lines at the ends of the device diverging radially outward from the axis of the device and thereafter converging at spatial annular surfaces disposed concentrically thereabout. (AFC)

  9. Development of an Underamor 1-kW Thermoelectric Generator Waste Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recovery System for Military Vehicles | Department of Energy an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles Development of an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Hi-Z Technology, Inc. 2004_deer_bass.pdf (484.67 KB) More Documents & Publications High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation

  10. Progress toward Development of a High-Efficiency Zonal Thermoelectric HVAC

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System for Automotive Applications | Department of Energy toward Development of a High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Progress toward Development of a High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10_maranville.pdf (598.71 KB) More Documents & Publications Thermoelectric

  11. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy Presents successful incorporation of one of the most promising classes of the new materials, the skutterudites, into a working automotive TEG prototype and test results on its performance deer11_meisner.pdf (1.17 MB) More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Develop Thermoelectric Technology for Automotive Waste Heat Recovery Development of Cost-Competitive Advanced Thermoelectric Generators for Direct

  12. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Powered Vehicle | Department of Energy MSU has developed and demonstrated a 5-couple module which produced 5.4 watts at an average ∆T estimated to be ~500 oC deer09_schock.pdf (1.89 MB) More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Wate

  13. High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generation | Department of Energy High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_krommenhoek.pdf (761.33 KB) More Documents & Publications Development of an Underamor 1-kW Thermoelectric Generator Waste Heat Recovery System for Military Vehicles Recent Progress in the Development of High

  14. Thermoelectric Power Generation System with Loop Thermosyphon in Future High Efficiency Hybrid Vehicles

    Broader source: Energy.gov [DOE]

    This project discusses preliminary experimental results to find how thermoelectrics can be applied ot future hybrid vehicles and the optimum design of such equipment using heat pipes

  15. Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic Hybrid Thermoelectrics

    Broader source: Energy.gov [DOE]

    Demonstrates self-catalytic schemes for large-scale synthesis of compound semiconductor nanowire powders for inorganic-organic hybrid thermoelectric cells

  16. Tuning thermoelectricity in a Bi2Se3 topological insulator via varied film thickness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Minghua; Wang, Zhenyu; Xu, Yong; Huang, Huaqing; Zang, Yunyi; Liu, Chang; Duan, Wenhui; Gan, Zhongxue; Zhang, Shou-Cheng; He, Ke; et al

    2016-01-12

    We report thermoelectric transport studies on Bi2Se3 topological insulator thin films with varied thickness grown by molecular beam epitaxy. We find that the Seebeck coefficient and thermoelectric power factor decrease systematically with the reduction of film thickness. These experimental observations can be explained quantitatively by theoretical calculations based on realistic electronic band structure of the Bi2Se3 thin films. Lastly, this work illustrates the crucial role played by the topological surface states on the thermoelectric transport of topological insulators, and sheds new light on further improvement of their thermoelectric performance.

  17. Standardization of Transport Properties Measurements: Internal Energy Agency (IEA-AMT) Annex on Thermoelectric

    Office of Energy Efficiency and Renewable Energy (EERE)

    Thermoelectric materials transport properties measurements improvement and standardization is undertaken by new IEA annex under the Advanced Materials for Transportation implementing agreement

  18. Rare Earth Atoms Make the Best Thermoelectrics Better | U.S....

    Office of Science (SC) Website

    ... interplay between electronic and thermal transport in the material that is ... the goal of ZT 2.0 needed for the commercialization of thermoelectric power generation. ...

  19. High Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies

    Broader source: Energy.gov [DOE]

    Key technologies and system approaches to excellent record of thermoelectric power sources in deep space missions and development of higher performance TE materials for the next generation systems

  20. End-on radioisotope thermoelectric generator impact tests

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Hhinckley, J.E.

    1997-01-01

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of [sup 238]Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). The modular GPHS design was developed to address both survivability during launch abort and return from orbit. The first two RTG Impact Tests were designed to provide information on the response of a fully loaded RTG to end-on impact against a concrete target. The results of these tests indicated that at impact velocities up to 57 m/s the converter shell and internal components protect the GPHS capsules from excessive deformation. At higher velocities, some of the internal components of the RTG interact with the GPHS capsules to cause excessive localized deformation and failure.

  1. End-on radioisotope thermoelectric generator impact tests

    SciTech Connect (OSTI)

    Reimus, M.A.; Hinckley, J.E.

    1997-01-01

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). The modular GPHS design was developed to address both survivability during launch abort and return from orbit. The first two RTG Impact Tests were designed to provide information on the response of a fully loaded RTG to end-on impact against a concrete target. The results of these tests indicated that at impact velocities up to 57 m/s the converter shell and internal components protect the GPHS capsules from excessive deformation. At higher velocities, some of the internal components of the RTG interact with the GPHS capsules to cause excessive localized deformation and failure. {copyright} {ital 1997 American Institute of Physics.}

  2. Special Applications RTG Technology Program: Thermoelectric module development summary report

    SciTech Connect (OSTI)

    Brittain, W.M.

    1988-09-01

    The primary objective of the Special Applications thermoelectric module development program is to design, develop and demonstrate the performance of a module which provides a significant thermoelectric conversion efficiency improvement over available technology for low power, relatively high voltage RTGS intended for terrestrial applications. ``Low power`` can be construed as an RTG power output of 10 watts or less, and ``high voltage`` can be considered as a load voltage of 5 volts or greater. In particular, the effort is to improve the system efficiency characteristic of the state-of-the-art bismuth telluride-based RTG system (e.g., Five-Watt RTG and Half-Watt RTG), typically 3 to 4%, to the range of 6% or better. This increase in efficiency will also permit reductions in the weight and size of RTGs in the low power range.

  3. Radioisotope thermoelectric generator/thin fragment impact test

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Hinckley, J.E.

    1998-12-31

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. This test was designed to provide information on the response of a loaded RTG to impact by a fragment similar to the type of fragment produced by breakup of the spacecraft propulsion module system (PMS). The results of this test indicated that impact of the RTG by a thin aluminum fragment traveling at 306 m/s may result in significant damage to the convertor housing, failure of one fueled clad, and release of a small quantity of fuel.

  4. Radioisotope thermoelectric generator/thin fragment impact test

    SciTech Connect (OSTI)

    Reimus, M.A.; Hinckley, J.E.

    1998-01-01

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. This test was designed to provide information on the response of a loaded RTG to impact by a fragment similar to the type of fragment produced by breakup of the spacecraft propulsion module system (PMS). The results of this test indicated that impact of the RTG by a thin aluminum fragment traveling at 306 m/s may result in significant damage to the converter housing, failure of one fueled clad, and release of a small quantity of fuel. {copyright} {ital 1998 American Institute of Physics.}

  5. Radioisotope thermoelectric generator/thin fragment impact test

    SciTech Connect (OSTI)

    Reimus, M. A. H.; Hinckley, J. E.

    1998-01-15

    The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of {sup 238}Pu decay to an array of thermoelectric elements in a radioisotope thermoelectric generator (RTG). Because the potential for a launch abort or return from orbit exists for any space mission, the heat source response to credible accident scenarios is being evaluated. This test was designed to provide information on the response of a loaded RTG to impact by a fragment similar to the type of fragment produced by breakup of the spacecraft propulsion module system (PMS). The results of this test indicated that impact of the RTG by a thin aluminum fragment traveling at 306 m/s may result in significant damage to the converter housing, failure of one fueled clad, and release of a small quantity of fuel.

  6. An apparatus for concurrent measurement of thermoelectric material parameters

    SciTech Connect (OSTI)

    Kallaher, R. L.; Latham, C. A.; Sharifi, F.

    2013-01-15

    We describe an apparatus which concurrently and independently measures the parameters determining thermoelectric material conversion efficiency: the Seebeck coefficient, thermal conductivity, and electrical resistivity. The apparatus is designed to characterize thermoelectric materials which are technologically relevant for waste heat energy conversion, and may operate from room temperature to 400 Degree-Sign C. It is configured so the heat flux is axially confined along two boron nitride rods of known thermal conductance. The Seebeck coefficient and thermal conductivity are obtained in steady-state using a differential technique, while the electrical resistivity is obtained using a four-point lock-in amplification method. Measurements on the newly developed NIST Seebeck standard reference material are presented in the temperature range from 50 Degree-Sign C to 250 Degree-Sign C.

  7. Noncontacting thermoelectric detection of material imperfections in metals

    SciTech Connect (OSTI)

    Peter B. Nagy; Adnan H. Nayfeh; Waseem I. Faidi; Hector Carreon; Balachander Lakshminaraya; Feng Yu; Bassam Abu-Nabah

    2005-06-17

    This project was aimed at developing a new noncontacting thermoelectric method for nondestructive detection of material imperfections in metals. The method is based on magnetic sensing of local thermoelectric currents around imperfections when a temperature gradient is established throughout a conducting specimen by external heating and cooling. The surrounding intact material serves as the reference electrode therefore the detection sensitivity could be very high if a sufficiently sensitive magnetometer is used in the measurements. This self-referencing, noncontacting, nondestructive inspection technique offers the following distinct advantages over conventional methods: high sensitivity to subtle variations in material properties, unique insensitivity to the size, shape, and other geometrical features of the specimen, noncontacting nature with a substantial stand-off distance, and the ability to probe relatively deep into the material. The potential applications of this method cover a very wide range from detection metallic inclusions and segregations, inhomogeneities, and tight cracks to characterization of hardening, embrittlement, fatigue, texture, and residual stresses.

  8. Advanced Thermoelectric Materials and Generator Technology for Automotive

    Broader source: Energy.gov (indexed) [DOE]

    Waste Heat at GM | Department of Energy Overview of design, fabrication, integration, and test of working prototype TEG for engine waste heat recovery on Suburban test vehicle, and continuing investigation of skutterudite materials systems meisner.pdf (1.94 MB) More Documents & Publications Advanced Thermoelectric Materials and Generator Technology for Automotive Waste Heat at GM Electrical and Thermal Transport Optimization of High Efficient n-type Skutterudites Electrical and Thermal

  9. Develop Thermoelectric Technology for Automotive Waste Heat Recovery |

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review emrgtech06_reedy_040213.pdf (403.24 KB) More Documents & Publications Working Fluids Low Global Warming Potential Refrigerants - 2013 Peer Review Multi-Function Fuel-Fired Heat Pump - 2013 Peer Review Buildings Performance Database - 2013 BTO Peer Review Department of Energy

    Develop thermoelectric technology for waste heat recovery with a 10% fuel economy

  10. Radioisotope thermoelectric generator transportation system subsystem 143 software development plan

    SciTech Connect (OSTI)

    King, D.A.

    1994-11-10

    This plan describes the activities to be performed and the controls to be applied to the process of specifying, developing, and qualifying the data acquisition software for the Radioisotope Thermoelectric Generator (RTG) Transportation System Subsystem 143 Instrumentation and Data Acquisition System (IDAS). This plan will serve as a software quality assurance plan, a verification and validation (V and V) plan, and a configuration management plan.

  11. Electronic Transport in Old and New Thermoelectric Materials

    SciTech Connect (OSTI)

    Singh, David J

    2011-01-01

    There is no known fundamental limit to the performance of thermoelectric materials as characterized by the dimensionless figure of merit, ZT, and in fact there has been significant recent progress in improving the performance of practical materials. Here we discuss some of the issues involved in improving ZT starting from transport theory, with particular emphasis on recent results on IV-VI chalcogenides and filled skutterudites.

  12. Sandia Researchers Are First to Measure Thermoelectric Behavior of a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoporous Metal-Organic Framework Are First to Measure Thermoelectric Behavior of a Nanoporous Metal-Organic Framework - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power &

  13. Thermoelectric Activities of European Community within Framework Programme

    Broader source: Energy.gov (indexed) [DOE]

    Energy Discusses engine technology enablers that help achieve overall system integration effectively deer12_suresh.pdf (986.08 KB) More Documents & Publications Cummins Next Generation Tier 2, Bin 2 Light Truck Diesel engine Cummins/DOE Light Truck Diesel Engine Progress Report Cummins' Next Generation Tier 2, Bin 2 Light Truck Diesel Engine 7 and additional activities in Germany | Department of Energy

    Provides survey of basic and applied thermoelectric activities in Germany

  14. Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite

    Broader source: Energy.gov (indexed) [DOE]

    Powered Vehicle | Department of Energy Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10_schock.pdf (2.44 MB) More Documents & Publications Thermoelectric Conversion of Waste Materials for Automotive Energy Recovery | Department of Energy

    Presents recent accomplishments and couple test results with these (In, Ce)-based skutterudite TE materials and potential impacts TE power system

  15. Assessing How Renewables Affect Water Used for Thermoelectric Cooling |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. DOE Office of Science (SC) Assessing How Renewables Affect Water Used for Thermoelectric Cooling Biological and Environmental Research (BER) BER Home About Research Facilities Science Highlights Searchable Archive of BER Highlights External link Benefits of BER Funding Opportunities Biological & Environmental Research Advisory Committee (BERAC) Community Resources Contact Information Biological and Environmental Research U.S. Department of Energy SC-23/Germantown Building 1000

  16. An Affordable Advanced Biomass Cookstove with Thermoelectric Generator (TEG)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Bioenergy Technologies Office 2015 Peer Review Biomass Cookstove Technology Review March 26, 2015 Lawrence Berkeley National Laboratory An Affordable Advanced Biomass Cookstove with Thermoelectric Generator (TEG) This presentation does not contain any proprietary, confidential, or otherwise restricted information Ashok Gadgil eere.energy.gov 1 Goal Statement Develop an affordable tier-4 cookstove desirable for purchase Design novel air injection configurations for flame manipulation powered

  17. Thermoelectric effects in organic conductors in a strong magnetic field

    SciTech Connect (OSTI)

    Kirichenko, O. V.; Peschanskii, V. G. Hasan, R. A.

    2007-07-15

    The linear response of the electron system of a layered conductor to the temperature gradient in this system in a strong magnetic field is investigated theoretically. Thermoelectric emf is studied as a function of the magnitude and orientation of a strong external magnetic field; the experimental investigation of this function, combined with the study of the electric and thermal resistance, allows one to completely determine the structure of the energy spectrum of charge carriers.

  18. Misfit layer compounds and ferecrystals: Model systems for thermoelectric nanocomposites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Merrill, Devin R.; Moore, Daniel B.; Bauers, Sage R.; Falmbigl, Matthias; Johnson, David C.

    2015-04-22

    A basic summary of thermoelectric principles is presented in a historical context, following the evolution of the field from initial discovery to modern day high-zT materials. A specific focus is placed on nanocomposite materials as a means to solve the challenges presented by the contradictory material requirements necessary for efficient thermal energy harvest. Misfit layer compounds are highlighted as an example of a highly ordered anisotropic nanocomposite system. Their layered structure provides the opportunity to use multiple constituents for improved thermoelectric performance, through both enhanced phonon scattering at interfaces and through electronic interactions between the constituents. Recently, a class ofmore » metastable, turbostratically-disordered misfit layer compounds has been synthesized using a kinetically controlled approach with low reaction temperatures. The kinetically stabilized structures can be prepared with a variety of constituent ratios and layering schemes, providing an avenue to systematically understand structure-function relationships not possible in the thermodynamic compounds. We summarize the work that has been done to date on these materials. The observed turbostratic disorder has been shown to result in extremely low cross plane thermal conductivity and in plane thermal conductivities that are also very small, suggesting the structural motif could be attractive as thermoelectric materials if the power factor could be improved. The first 10 compounds in the [(PbSe)1+δ]m(TiSe₂)n family (m, n ≤ 3) are reported as a case study. As n increases, the magnitude of the Seebeck coefficient is significantly increased without a simultaneous decrease in the in-plane electrical conductivity, resulting in an improved thermoelectric power factor.« less

  19. Rare earth chalcogenides for use as high temperature thermoelectric materials

    SciTech Connect (OSTI)

    Michiels, J.

    1996-01-02

    In the first part of the thesis, the electric resistivity, Seebeck coefficient, and Hall effect were measured in X{sub y}(Y{sub 2}S{sub 3}){sub 1-y} (X = Cu, B, or Al), for y = 0.05 (Cu, B) or 0.025-0.075 for Al, in order to determine their potential as high- temperature (HT)(300-1000 C) thermoelectrics. Results indicate that Cu, B, Al- doped Y{sub 2}S{sub 3} are not useful as HT thermoelectrics. In the second part, phase stability of {gamma}-cubic LaSe{sub 1.47-1.48} and NdSe{sub 1.47} was measured periodically during annealing at 800 or 1000 C for the same purpose. In the Nd selenide, {beta} phase increased with time, while the Nd selenide showed no sign of this second phase. It is concluded that the La selenide is not promising for use as HT thermoelectric due to the {gamma}-to-{beta} transformation, whereas the Nd selenide is promising.

  20. Close-packed-array (CPA) thermoelectric module development status

    SciTech Connect (OSTI)

    Brittain, W.M. )

    1991-01-05

    Prior effort on the U.S. Department of Energy-sponsored Special Applications Radioisotope Thermoelectric Generator (RTG) Technology Program and Two-Watt RTG Program has focused on terrestrial applications where the RTG will be exposed to relatively low temperature thermal environments (subsea). Thus, effort has been oriented towards design optimization at cold junction temperatures in the 10 to 93 {degree}C (50 to 200 {degree}F) range. However, for other more severe design environments (such as space applications where a high heat rejection radiator temperature in the 177 to 204 {degree}C (350 to 400 {degree}F) range is required to minimize RTG size and weight, and high g shock/vibration capability is necessary) a modified thermoelectric module design is dictated. In order to minimize the RTG system size and weight, and to increase the mechanical strength of the thermoelectric module to withstand increased dynamic loads, a close-packed-array (CPA) module configuration is desirable. The monolithic nature of such a module generally results in greater shear and compression load capability than free-standing individual couples. A CPA module is especially attractive for terrestrial and space applications where severe structural loads will be imposed such as airborne deployment or planetary landers and penetrators.

  1. Economic analysis of municipal wastewater utilization for thermoelectric power production

    SciTech Connect (OSTI)

    Safari, I.; Walker, M.; Abbasian, J.; Arastoopour, H.; Hsieh, M-K.; Theregowda, R.; Dzombak, D.; Miller, D.

    2011-01-01

    The thermoelectric power industry in the U.S. uses a large amount of freshwater. The large water demand is increasingly a problem, especially for new power plant development, as availability of freshwater for new uses diminishes in the United States. Reusing non-traditional water sources, such as treated municipal wastewater, provides one option to mitigate freshwater usage in the thermoelectric power industry. The amount of freshwater withdrawal that can be displaced with non-traditional water sources at a particular location requires evaluation of the water management and treatment requirements, considering the quality and abundance of the non-traditional water sources. This paper presents the development of an integrated costing model to assess the impact of degraded water treatment, as well as the implications of increased tube scaling in the main condenser. The model developed herein is used to perform case studies of various treatment, condenser cleaning and condenser configurations to provide insight into the ramifications of degraded water use in the cooling loops of thermoelectric power plants. Further, this paper lays the groundwork for the integration of relationships between degraded water quality, scaling characteristics and volatile emission within a recirculating cooling loop model.

  2. Nanocrystalline silicon: Lattice dynamics and enhanced thermoelectric properties

    SciTech Connect (OSTI)

    Claudio, Tania; Stein, Niklas; Stroppa, Daniel G.; Klobes, Benedikt; Koza, Michael Marek; Kudejova, Petra; Petermann, Nils; Wiggers, Hartmut; Schierning, Gabi; Hermann, Raphaël P.

    2014-12-21

    In this study, silicon has several advantages when compared to other thermoelectric materials, but until recently it was not used for thermoelectric applications due to its high thermal conductivity, 156 W K-1 m-1 at room temperature. Nanostructuration as means to decrease thermal transport through enhanced phonon scattering has been a subject of many studies. In this work we have evaluated the effects of nanostructuration on the lattice dynamics of bulk nanocrystalline doped silicon. The samples were prepared by gas phase synthesis, followed by current and pressure assisted sintering. The heat capacity, density of phonons states, and elastic constants were measured, which all reveal a significant, ≈25%, reduction in the speed of sound. The samples present a significantly decreased lattice thermal conductivity, ≈25 W K-1 m-1, which, combined with a very high carrier mobility, results in a dimensionless figure of merit with a competitive value that peaks at ZT ≈ 0.57 at 973 °C. Due to its easily scalable and extremely low-cost production process, nanocrystalline Si prepared by gas phase synthesis followed by sintering could become the material of choice for high temperature thermoelectric generators.

  3. Nanocrystalline silicon: Lattice dynamics and enhanced thermoelectric properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Claudio, Tania; Stein, Niklas; Stroppa, Daniel G.; Klobes, Benedikt; Koza, Michael Marek; Kudejova, Petra; Petermann, Nils; Wiggers, Hartmut; Schierning, Gabi; Hermann, Raphaël P.

    2014-12-21

    In this study, silicon has several advantages when compared to other thermoelectric materials, but until recently it was not used for thermoelectric applications due to its high thermal conductivity, 156 W K-1 m-1 at room temperature. Nanostructuration as means to decrease thermal transport through enhanced phonon scattering has been a subject of many studies. In this work we have evaluated the effects of nanostructuration on the lattice dynamics of bulk nanocrystalline doped silicon. The samples were prepared by gas phase synthesis, followed by current and pressure assisted sintering. The heat capacity, density of phonons states, and elastic constants were measured,more » which all reveal a significant, ≈25%, reduction in the speed of sound. The samples present a significantly decreased lattice thermal conductivity, ≈25 W K-1 m-1, which, combined with a very high carrier mobility, results in a dimensionless figure of merit with a competitive value that peaks at ZT ≈ 0.57 at 973 °C. Due to its easily scalable and extremely low-cost production process, nanocrystalline Si prepared by gas phase synthesis followed by sintering could become the material of choice for high temperature thermoelectric generators.« less

  4. Electrochemically deposited BiTe-based nanowires for thermoelectric applications

    SciTech Connect (OSTI)

    Ng, Inn-Khuan; Kok, Kuan-Ying; Rahman, Che Zuraini Che Ab; Saidin, Nur Ubaidah; Ilias, Suhaila Hani; Choo, Thye-Foo

    2014-02-12

    Nanostructured materials systems such as thin-films and nanowires (NWs) are promising for thermoelectric power generation and refrigeration compared to traditional counterparts in bulk, due to their enhanced thermoelectric figures-of-merit. BiTe and its derivative compounds, in particular, are well-known for their near-room temperature thermoelectric performance. In this work, both the binary and ternary BiTe-based nanowires namely, BiTe and BiSbTe, were synthesized using template-assisted electrodeposition. Diameters of the nanowires were controlled by the pore sizes of the anodised alumina (AAO) templates used. Systematic study on the compositional change as a function of applied potential was carried out via Linear Sweep Voltanmetry (LSV). Chemical compositions of the nanowires were studied using Energy Dispersive X-ray Spectrometry (EDXS) and their microstructures evaluated using diffraction and imaging techniques. Results from chemical analysis on the nanowires indicated that while the Sb content in BiSbTe nanowires increased with more negative deposition potentials, the formation of Te{sup 0} and Bi{sub 2}Te{sub 3} were favorable at more positive potentials.

  5. Real-time monitoring during transportation of a radioisotope thermoelectric generator (RTG) using the radioisotope thermoelectric generator transportation system (RTGTS)

    SciTech Connect (OSTI)

    Pugh, B.K.

    1997-01-01

    The Radioisotopic Thermoelectric Generators (RTGs) that will be used to support the Cassini mission will be transported in the Radioisotope Thermoelectric Generator Transportation System (RTGTS). To ensure that the RTGs will not be affected during transportation, all parameters that could adversely affect RTG{close_quote}s performance must be monitored. The Instrumentation and Data Acquisition System (IDAS) for the RTGTS displays, monitors, and records all critical packaging and trailer system parameters. The IDAS also monitors the package temperature control system, RTG package shock and vibration data, and diesel fuel levels for the diesel fuel tanks. The IDAS alarms if any of these parameters reach an out-of-limit condition. This paper discusses the real-time monitoring during transportation of the Cassini RTGs using the RTGTS IDAS. {copyright} {ital 1997 American Institute of Physics.}

  6. Real-time monitoring during transportation of a radioisotope thermoelectric generator (RTG) using the radioisotope thermoelectric generator transportation system (RTGTS)

    SciTech Connect (OSTI)

    Pugh, Barry K.

    1997-01-10

    The Radioisotopic Thermoelectric Generators (RTGs) that will be used to support the Cassini mission will be transported in the Radioisotope Thermoelectric Generator Transportation System (RTGTS). To ensure that the RTGs will not be affected during transportation, all parameters that could adversely affect RTG's performance must be monitored. The Instrumentation and Data Acquisition System (IDAS) for the RTGTS displays, monitors, and records all critical packaging and trailer system parameters. The IDAS also monitors the package temperature control system, RTG package shock and vibration data, and diesel fuel levels for the diesel fuel tanks. The IDAS alarms if any of these parameters reach an out-of-limit condition. This paper discusses the real-time monitoring during transportation of the Cassini RTGs using the RTGTS IDAS.

  7. Photo-controllable thermoelectric properties with reversibility and photo-thermoelectric effects of tungsten trioxide accompanied by its photochromic phenomenon

    SciTech Connect (OSTI)

    Azuma, Chiori; Kawano, Takuto; Kakemoto, Hirofumi; Irie, Hiroshi

    2014-11-07

    The addition of photo-controllable properties to tungsten trioxide (WO{sub 3}) is of interest for developing practical applications of WO{sub 3} as well as for interpreting such phenomena from scientific viewpoints. Here, a sputtered crystalline WO{sub 3} thin film generated thermoelectric power due to ultraviolet (UV) light-induced band-gap excitation and was accompanied by a photochromic reaction resulting from generating W{sup 5+} ions. The thermoelectric properties (electrical conductivity (?) and Seebeck coefficient (S)) and coloration of WO{sub 3} could be reversibly switched by alternating the external stimulus between UV light irradiation and dark storage. After irradiating the film with UV light, ? increased, whereas the absolute value of S decreased, and the photochromic (coloration) reaction was detected. Notably, the opposite behavior was exhibited by WO{sub 3} after dark storage, and this reversible cycle could be repeated at least three times. Moreover, photo-thermoelectric effects (photo-conductive effect (photo-conductivity, ?{sub photo}) and photo-Seebeck effect (photo-Seebeck coefficient, S{sub photo})) were also detected in response to visible-light irradiation of the colored WO{sub 3} thin films. Under visible-light irradiation, ?{sub photo} and the absolute value of S{sub photo} increased and decreased, respectively. These effects are likely attributable to the excitation of electrons from the mid-gap visible light absorption band (W{sup 5+} state) to the conduction band of WO{sub 3}. Our findings demonstrate that the simultaneous, reversible switching of multiple properties of WO{sub 3} thin film is achieved by the application of an external stimulus and that this material exhibits photo-thermoelectric effects when irradiated with visible-light.

  8. Cooling effect of nanoscale Bi2Te3/Sb2Te3 multilayered thermoelectric thin films

    SciTech Connect (OSTI)

    Hines, Mardecial; Lenhardt, Joshua; Lu, Ming; Jiang, Li; Xiao, Zhigang

    2012-01-01

    Managing high heat flux is one of the greatest technical challenges the integrated circuit (IC) industry is facing because the rising temperature limits device minimization and decreases its lifetime. In this paper, we report the characterization of the cooling effect of nanoscale Bi2Te3/Sb2Te3 multilayered thin films. The multilayerthin film was prepared with e-beam evaporation, and had 21 layers (5-nm-thick each layer and 105-nm-thick total). A thermoelectric device of the multilayerfilm, which is sandwiched between a diode temperature sensor and a platinum temperature sensor, was fabricated to measure the cooling effect. A maximum cooling temperature difference of about 3K was obtained from the film at an applied dc electrical current of 5 mA. The nanoscale multilayerfilm could be integrated in the IC devices for the application of high-efficiency thermoelectric solid-state cooling.

  9. Feasibility of Thermoelectrics for Waste Heat Recovery in Hybrid Vehicles: Preprint

    SciTech Connect (OSTI)

    Smith, K.; Thornton, M.

    2007-12-01

    Using advanced materials, thermoelectric conversion of efficiencies on the order of 20% may be possible in the near future. Thermoelectric generators offer potential to increase vehicle fuel economy by recapturing a portion of the waste heat from the engine exhaust and generating electricity to power vehicle accessory or traction loads.

  10. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine

    Broader source: Energy.gov (indexed) [DOE]

    Powered Vehicle | Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ace_46_schock.pdf (1.94 MB) More Documents & Publications Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Waste

  11. System and method to improve the power output and longetivity of a radioisotope thermoelectric generator

    DOE Patents [OSTI]

    Mowery, Jr., Alfred L.

    1993-01-01

    By using the helium generated by the alpha emissions of a thermoelectric generator during space travel for cooling, the thermal degradation of the thermoelectric generator can be slowed. Slowing degradation allows missions to be longer with little additional expense or payload.

  12. Efficiency Improvement in an Over the Road Diesel Powered Engine System by the Application of Advanced Thermoelectric Systems Implemented in a Hybrid Configuration

    Broader source: Energy.gov [DOE]

    Hybridization of heavy-duty truck propulsion with thermoelectric generator and potential efficiency enhancement

  13. PLASMA DEVICE

    DOE Patents [OSTI]

    Baker, W.R.; Brathenahl, A.; Furth, H.P.

    1962-04-10

    A device for producing a confined high temperature plasma is described. In the device the concave inner surface of an outer annular electrode is disposed concentrically about and facing the convex outer face of an inner annular electrode across which electrodes a high potential is applied to produce an electric field there between. Means is provided to create a magnetic field perpendicular to the electric field and a gas is supplied at reduced pressure in the area therebetween. Upon application of the high potential, the gas between the electrodes is ionized, heated, and under the influence of the electric and magnetic fields there is produced a rotating annular plasma disk. The ionized plasma has high dielectric constant properties. The device is useful as a fast discharge rate capacitor, in controlled thermonuclear research, and other high temperature gas applications. (AEC)

  14. Nanoscale Studies of Pyroelectric and Thermoelectric Phenomena

    SciTech Connect (OSTI)

    Gruverman, Alexei; Ducharme, Stephen

    2014-07-31

    This research project is focused on (1) development of novel scanning probe microscopy techniques for investigation of the thermally and electrically induced changes in the physical properties of organic polymer ferroelectrics; (2) fabrication of ferroelectric nanostructures and investigation of their functional behavior; (3) fabrication and testing of the organic photovoltaic devices with enhanced energy conversion efficiency. Research activities throughout this project resulted in novel effects and exciting physics reported in 10 papers published in high-profile journals, including Nature Materials, Nano Letters, Advanced Materials, Energy and Environmental Science and Applied Physics Letters. These findings have been presented at a number of domestic and international conferences such as MRS Spring and Fall meetings, International Symposium on Integrated Functionalities, International Symposium on Applications of Ferroelectrics (in total 9 presentations). Below we summarize the most important findings of this project.

  15. Electrochemical device

    DOE Patents [OSTI]

    Grimes, Patrick G.; Einstein, Harry; Bellows, Richard J.

    1988-01-12

    A tunnel protected electrochemical device features channels fluidically communicating between manifold, tunnels and cells. The channels are designed to provide the most efficient use of auxiliary power. The channels have a greater hydraulic pressure drop and electrical resistance than the manifold. This will provide a design with the optimum auxiliary energy requirements.

  16. Detection device

    DOE Patents [OSTI]

    Smith, J.E.

    1981-02-27

    The present invention is directed to a detection device comprising: (1) an entrance chamber; (2) a central chamber; and (3) an exit chamber. The central chamber includes an ionizing gas, anode, and means for connecting the anode with an external power supply and pulse counter.

  17. Detection device

    DOE Patents [OSTI]

    Smith, Jay E.

    1984-01-01

    The present invention is directed to a detection device comprising: (1) an entrance chamber, (2) a central chamber, and (3) an exit chamber. The central chamber includes an ionizing gas, anode, and means for connecting the anode with an external power supply and pulse counter.

  18. New experimental methodology, setup and LabView program for accurate absolute thermoelectric power and electrical resistivity measurements between 25 and 1600 K: Application to pure copper, platinum, tungsten, and nickel at very high temperatures

    SciTech Connect (OSTI)

    Abadlia, L.; Mayoufi, M.; Gasser, F.; Khalouk, K.; Gasser, J. G.

    2014-09-15

    In this paper we describe an experimental setup designed to measure simultaneously and very accurately the resistivity and the absolute thermoelectric power, also called absolute thermopower or absolute Seebeck coefficient, of solid and liquid conductors/semiconductors over a wide range of temperatures (room temperature to 1600 K in present work). A careful analysis of the existing experimental data allowed us to extend the absolute thermoelectric power scale of platinum to the range 0-1800 K with two new polynomial expressions. The experimental device is controlled by a LabView program. A detailed description of the accurate dynamic measurement methodology is given in this paper. We measure the absolute thermoelectric power and the electrical resistivity and deduce with a good accuracy the thermal conductivity using the relations between the three electronic transport coefficients, going beyond the classical Wiedemann-Franz law. We use this experimental setup and methodology to give new very accurate results for pure copper, platinum, and nickel especially at very high temperatures. But resistivity and absolute thermopower measurement can be more than an objective in itself. Resistivity characterizes the bulk of a material while absolute thermoelectric power characterizes the material at the point where the electrical contact is established with a couple of metallic elements (forming a thermocouple). In a forthcoming paper we will show that the measurement of resistivity and absolute thermoelectric power characterizes advantageously the (change of) phase, probably as well as DSC (if not better), since the change of phases can be easily followed during several hours/days at constant temperature.

  19. High-Performance Thermoelectric Devices Based on Abundant Silicide Materials for Vehicle Waste Heat Recovery

    Broader source: Energy.gov [DOE]

    Reports of methods to synthesize single-crystal and poly or nano- crystalline p- and n-type higher manganese silicides to reduce lattice thermal conductivity

  20. An integrated approach towards efficient, scalable, and low cost thermoelectric waste heat recovery devices for vehicles

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  1. Energy Efficient HVAC System for Distributed Cooling/Heating with Thermoelectric Devices

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  2. Improving efficiency of a vehicle HVAC system with comfort modeling, zonal design, and thermoelectric devices

    Office of Energy Efficiency and Renewable Energy (EERE)

    Discusses progress on thermal comfort modeling and detailed design, fabrication, and component/system-level testing of TE architecture

  3. Energy Efficient HVAC System for Distributed Cooling/Heating with Thermoelectric Devices

    Office of Energy Efficiency and Renewable Energy (EERE)

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  4. Integration of Advanced Materials and Interfaces for Durable Thermoelectric Automobile Exhaust Waste Heat Harvesting Devices

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  5. Laser device

    DOE Patents [OSTI]

    Scott, Jill R.; Tremblay, Paul L.

    2008-08-19

    A laser device includes a virtual source configured to aim laser energy that originates from a true source. The virtual source has a vertical rotational axis during vertical motion of the virtual source and the vertical axis passes through an exit point from which the laser energy emanates independent of virtual source position. The emanating laser energy is collinear with an orientation line. The laser device includes a virtual source manipulation mechanism that positions the virtual source. The manipulation mechanism has a center of lateral pivot approximately coincident with a lateral index and a center of vertical pivot approximately coincident with a vertical index. The vertical index and lateral index intersect at an index origin. The virtual source and manipulation mechanism auto align the orientation line through the index origin during virtual source motion.

  6. LOADING DEVICE

    DOE Patents [OSTI]

    Ohlinger, L.A.

    1958-10-01

    A device is presented for loading or charging bodies of fissionable material into a reactor. This device consists of a car, mounted on tracks, into which the fissionable materials may be placed at a remote area, transported to the reactor, and inserted without danger to the operating personnel. The car has mounted on it a heavily shielded magazine for holding a number of the radioactive bodies. The magazine is of a U-shaped configuration and is inclined to the horizontal plane, with a cap covering the elevated open end, and a remotely operated plunger at the lower, closed end. After the fissionable bodies are loaded in the magazine and transported to the reactor, the plunger inserts the body at the lower end of the magazine into the reactor, then is withdrawn, thereby allowing gravity to roll the remaining bodies into position for successive loading in a similar manner.

  7. Magnesium and Manganese Silicides For Efficient And Low Cost Thermo-Electric Power Generation

    SciTech Connect (OSTI)

    Trivedi, Sudhir B.; Kutcher, Susan W.; Rosemeier, Cory A.; Mayers, David; Singh, Jogender

    2013-12-02

    Thermoelectric Power Generation (TEPG) is the most efficient and commercially deployable power generation technology for harvesting wasted heat from such things as automobile exhausts, industrial furnaces, and incinerators, and converting it into usable electrical power. We investigated the materials magnesium silicide (Mg2Si) and manganese silicide (MnSi) for TEG. MgSi2 and MnSi are environmentally friendly, have constituent elements that are abundant in the earth's crust, non-toxic, lighter and cheaper. In Phase I, we successfully produced Mg2Si and MnSi material with good TE properties. We developed a novel technique to synthesize Mg2Si with good crystalline quality, which is normally very difficult due to high Mg vapor pressure and its corrosive nature. We produced n-type Mg2Si and p-type MnSi nanocomposite pellets using FAST. Measurements of resistivity and voltage under a temperature gradient indicated a Seebeck coefficient of roughly 120 V/K on average per leg, which is quite respectable. Results indicated however, that issues related to bonding resulted in high resistivity contacts. Determining a bonding process and bonding material that can provide ohmic contact from room temperature to the operating temperature is an essential part of successful device fabrication. Work continues in the development of a process for reproducibly obtaining low resistance electrical contacts.

  8. Thermoelectric-induced unitary Cooper pair splitting efficiency

    SciTech Connect (OSTI)

    Cao, Zhan; Fang, Tie-Feng; Li, Lin; Luo, Hong-Gang

    2015-11-23

    Thermoelectric effect is exploited to optimize the Cooper pair splitting efficiency in a Y-shaped junction, which consists of two normal leads coupled to an s-wave superconductor via double noninteracting quantum dots. Here, utilizing temperature difference rather than bias voltage between the two normal leads, and tuning the two dot levels such that the transmittance of elastic cotunneling process is particle-hole symmetric, we find current flowing through the normal leads are totally contributed from the splitting of Cooper pairs emitted from the superconductor. Such a unitary splitting efficiency is significantly better than the efficiencies obtained in experiments so far.

  9. Procurement of a fully licensed radioisotope thermoelectric generator transportation system

    SciTech Connect (OSTI)

    Adkins, H.E.; Bearden, T.E.

    1990-10-01

    A fully licensed transportation system for Radioisotope Thermoelectric Generators and Light-Weight Radioisotope Heater Units is currently being designed and built. The system will comply with all applicable US Department of Transportation regulations without the use of a DOE Alternative.'' The US Department of Transportation has special double containment'' requirements for plutonium. The system packaging uses a doubly contained bell jar'' concept. A refrigerated trailer is used for cooling the high-heat payloads. The same packaging is used for both high- and low-heat payloads. The system is scheduled to be available for use by mid-1992. 4 refs., 4 figs., 2 tabs.

  10. Methods for synthesis of semiconductor nanocrystals and thermoelectric compositions

    DOE Patents [OSTI]

    Ren, Zhifeng; Chen, Gang; Poudel, Bed; Kumar, Shankar; Wang, Wenzhong; Dresselhaus, Mildred

    2007-08-14

    The present invention provides methods for synthesis of IV VI nanostructures, and thermoelectric compositions formed of such structures. In one aspect, the method includes forming a solution of a Group IV reagent, a Group VI reagent and a surfactant. A reducing agent can be added to the solution, and the resultant solution can be maintained at an elevated temperature, e.g., in a range of about 20.degree. C. to about 360.degree. C., for a duration sufficient for generating nanoparticles as binary alloys of the IV VI elements.

  11. Nanostructured Bulk Thermoelectric Generator for Efficient Power Harvesting for Self-powered Sensor Networks

    SciTech Connect (OSTI)

    Zhang, Yanliang; Butt, Darryl; Agarwal, Vivek

    2015-07-01

    The objective of this Nuclear Energy Enabling Technology research project is to develop high-efficiency and reliable thermoelectric generators for self-powered wireless sensors nodes utilizing thermal energy from nuclear plant or fuel cycle. The power harvesting technology has crosscutting significance to address critical technology gaps in monitoring nuclear plants and fuel cycle. The outcomes of the project will lead to significant advancement in sensors and instrumentation technology, reducing cost, improving monitoring reliability and therefore enhancing safety. The self-powered wireless sensor networks could support the long-term safe and economical operation of all the reactor designs and fuel cycle concepts, as well as spent fuel storage and many other nuclear science and engineering applications. The research is based on recent breakthroughs in high-performance nanostructured bulk (nanobulk) thermoelectric materials that enable high-efficiency direct heat-to-electricity conversion over a wide temperature range. The nanobulk thermoelectric materials that the research team at Boise State University and University of Houston has developed yield up to a 50% increase in the thermoelectric figure of merit, ZT, compared with state-of-the-art bulk counterparts. This report focuses on the selection of optimal thermoelectric materials for this project. The team has performed extensive study on two thermoelectric materials systems, i.e. the half-Heusler materials, and the Bismuth-Telluride materials. The report contains our recent research results on the fabrication, characterization and thermoelectric property measurements of these two materials.

  12. Diversionary device

    DOE Patents [OSTI]

    Grubelich, Mark C.

    2001-01-01

    A diversionary device has a housing having at least one opening and containing a non-explosive propellant and a quantity of fine powder packed within the housing, with the powder being located between the propellant and the opening. When the propellant is activated, it has sufficient energy to propel the powder through the opening to produce a cloud of powder outside the housing. An igniter is also provided for igniting the cloud of powder to create a diversionary flash and bang, but at a low enough pressure to avoid injuring nearby people.

  13. Electrochromic device

    DOE Patents [OSTI]

    Schwendemanm, Irina G.; Polcyn, Adam D.; Finley, James J.; Boykin, Cheri M.; Knowles, Julianna M.

    2011-03-15

    An electrochromic device includes a first substrate spaced from a second substrate. A first conductive member is formed over at least a portion of the first substrate. A first electrochromic material is formed over at least a portion of the first conductive member. The first electrochromic material includes an organic material. A second conductive member is formed over at least a portion of the second substrate. A second electrochromic material is formed over at least a portion of the second conductive member. The second electrochromic material includes an inorganic material. An ionic liquid is positioned between the first electrochromic material and the second electrochromic material.

  14. OLED devices

    DOE Patents [OSTI]

    Sapochak, Linda Susan [Arlington, VA; Burrows, Paul Edward [Kennewick, WA; Bimalchandra, Asanga [Richland, WA

    2011-02-22

    An OLED device having an emission layer formed of an ambipolar phosphine oxide host material and a dopant, a hole transport layer in electrical communication with an anode, an electron transport layer in communication with a cathode, wherein the HOMO energy of the hole transport layer is substantially the same as the HOMO energy of the ambipolar host in the emission layer, and the LUMO energy of the electron transport layer is substantially the same as the LUMO energy of the ambipolar host in the emission layer.

  15. An overview of the Radioisotope Thermoelectric Generator Transporation System Program

    SciTech Connect (OSTI)

    McCoy, J.C.

    1995-10-01

    Radioisotope Thermoelectric Generators (RTG) convert the heat generated by radioactive decay to electricity using thermocouples. RTGs have a long operating life, are reasonably lightweight, and require little or no maintenance once assembled and tested. These factors make RTGs particularly attractive for use in spacecraft However, because RTGs contain significant quantities of radioactive materials, normally plutonium-238 and its decay products, they must be transported in packages built in accordance with Title 10, Code of Federal Regulations, Part 71. The US Department of Energy assigned the Radioisotope Thermoelectric Generator Transportation System (RTGTS) Program to Westinghouse Hanford Company in 1988 to develop a system meeting the regulatory requirements. The program objective was to develop a transportation system that would fully comply with 10 CFR 71 while protecting RTGs from adverse environmental conditions during normal conditions of transport (e.g., shock and heat). The RTGTS is scheduled for completion in December 1996 and will be available to support the National Aeronautics and Space Administrations Cassini mission to Saturn in October 1997. This paper provides an overview of the RTGTS and discusses the hardware being produced. Additionally, various program management innovations mandated by recent ma or changes in the US Department of Energy structure and resources will be outlined.

  16. Simultaneous thermoelectric and optoelectronic characterization of individual nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leonard, Francois; Wang, George T.; Swartzentruber, Brian S.; Martinez, Julio A.; Song, Erdong; Li, Qiming

    2015-11-03

    Semiconducting nanowires have been explored for a number of applications in optoelectronics such as photodetectors and solar cells. Currently, there is ample interest in identifying the mechanisms that lead to photoresponse in nanowires in order to improve and optimize performance. However, distinguishing among the different mechanisms, including photovoltaic, photothermoelectric, photoemission, bolometric, and photoconductive, is often difficult using purely optoelectronic measurements. In this work, we present an approach for performing combined and simultaneous thermoelectric and optoelectronic measurements on the same individual nanowire. We apply the approach to GaN/AlGaN core/shell and GaN/AlGaN/GaN core/shell/shell nanowires and demonstrate the photothermoelectric nature of the photocurrentmore » observed at the electrical contacts at zero bias, for above- and below-bandgap illumination. Furthermore, the approach allows for the experimental determination of the temperature rise due to laser illumination, which is often obtained indirectly through modeling. We also show that under bias, both above- and below-bandgap illumination leads to a photoresponse in the channel with signatures of persistent photoconductivity due to photogating. Finally, we reveal the concomitant presence of photothermoelectric and photogating phenomena at the contacts in scanning photocurrent microscopy under bias by using their different temporal response. Furthermore, our approach is applicable to a broad range of nanomaterials to elucidate their fundamental optoelectronic and thermoelectric properties.« less

  17. Diameter dependent thermoelectric properties of individual SnTe nanowires

    SciTech Connect (OSTI)

    Xu, E. Z.; Li, Z.; Martinez, J. A.; Sinitsyn, N.; Htoon, H.; Li, Nan; Swartzentruber, B.; Hollingsworth, J. A.; Wang, Jian; Zhang, S. X.

    2015-01-15

    The lead-free compound tin telluride (SnTe) has recently been suggested to be a potentially promising thermoelectric material because of its similar electronic band structure as the well-known lead telluride. Here we report on the first thermoelectric study of individual single crystalline SnTe nanowires (NWs) with different diameters ranging from ~200 to ~1000 nm. Measurements of thermopower S, electrical conductivity σ, and thermal conductivity κ were carried out on the same nanowires over a temperature range of 25 - 300 K. While σ does not show a strong diameter dependence, the thermopower increases by a factor of 2 when the nanowire diameter is decreased from 1000 nm to 200 nm. The thermal conductivities of the measured NWs are only about half of that of the bulk SnTe, which may arise from the enhanced phonon-grain boundary and phonon-defect scatterings. Temperature dependent figure-of-merit ZT was determined and the maximum value at room temperature is ~3 times higher than what was obtained in bulk samples of comparable carrier density.

  18. Simultaneous thermoelectric and optoelectronic characterization of individual nanowires

    SciTech Connect (OSTI)

    Leonard, Francois; Wang, George T.; Swartzentruber, Brian S.; Martinez, Julio A.; Song, Erdong; Li, Qiming

    2015-11-03

    Semiconducting nanowires have been explored for a number of applications in optoelectronics such as photodetectors and solar cells. Currently, there is ample interest in identifying the mechanisms that lead to photoresponse in nanowires in order to improve and optimize performance. However, distinguishing among the different mechanisms, including photovoltaic, photothermoelectric, photoemission, bolometric, and photoconductive, is often difficult using purely optoelectronic measurements. In this work, we present an approach for performing combined and simultaneous thermoelectric and optoelectronic measurements on the same individual nanowire. We apply the approach to GaN/AlGaN core/shell and GaN/AlGaN/GaN core/shell/shell nanowires and demonstrate the photothermoelectric nature of the photocurrent observed at the electrical contacts at zero bias, for above- and below-bandgap illumination. Furthermore, the approach allows for the experimental determination of the temperature rise due to laser illumination, which is often obtained indirectly through modeling. We also show that under bias, both above- and below-bandgap illumination leads to a photoresponse in the channel with signatures of persistent photoconductivity due to photogating. Finally, we reveal the concomitant presence of photothermoelectric and photogating phenomena at the contacts in scanning photocurrent microscopy under bias by using their different temporal response. Furthermore, our approach is applicable to a broad range of nanomaterials to elucidate their fundamental optoelectronic and thermoelectric properties.

  19. Diameter dependent thermoelectric properties of individual SnTe nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, E. Z.; Li, Z.; Martinez, J. A.; Sinitsyn, N.; Htoon, H.; Li, Nan; Swartzentruber, B.; Hollingsworth, J. A.; Wang, Jian; Zhang, S. X.

    2015-01-15

    The lead-free compound tin telluride (SnTe) has recently been suggested to be a potentially promising thermoelectric material because of its similar electronic band structure as the well-known lead telluride. Here we report on the first thermoelectric study of individual single crystalline SnTe nanowires (NWs) with different diameters ranging from ~200 to ~1000 nm. Measurements of thermopower S, electrical conductivity σ, and thermal conductivity κ were carried out on the same nanowires over a temperature range of 25 - 300 K. While σ does not show a strong diameter dependence, the thermopower increases by a factor of 2 when the nanowiremore » diameter is decreased from 1000 nm to 200 nm. The thermal conductivities of the measured NWs are only about half of that of the bulk SnTe, which may arise from the enhanced phonon-grain boundary and phonon-defect scatterings. Temperature dependent figure-of-merit ZT was determined and the maximum value at room temperature is ~3 times higher than what was obtained in bulk samples of comparable carrier density.« less

  20. Thermally-induced voltage alteration for analysis of microelectromechanical devices

    DOE Patents [OSTI]

    Walraven, Jeremy A.; Cole, Jr., Edward I.

    2002-01-01

    A thermally-induced voltage alteration (TIVA) apparatus and method are disclosed for analyzing a microelectromechanical (MEM) device with or without on-board integrated circuitry. One embodiment of the TIVA apparatus uses constant-current biasing of the MEM device while scanning a focused laser beam over electrically-active members therein to produce localized heating which alters the power demand of the MEM device and thereby changes the voltage of the constant-current source. This changing voltage of the constant-current source can be measured and used in combination with the position of the focused and scanned laser beam to generate an image of any short-circuit defects in the MEM device (e.g. due to stiction or fabrication defects). In another embodiment of the TIVA apparatus, an image can be generated directly from a thermoelectric potential produced by localized laser heating at the location of any short-circuit defects in the MEM device, without any need for supplying power to the MEM device. The TIVA apparatus can be formed, in part, from a scanning optical microscope, and has applications for qualification testing or failure analysis of MEM devices.

  1. CLOSURE DEVICE

    DOE Patents [OSTI]

    Linzell, S.M.; Dorcy, D.J.

    1958-08-26

    A quick opening type of stuffing box employing two banks of rotatable shoes, each of which has a caraming action that forces a neoprene sealing surface against a pipe or rod where it passes through a wall is presented. A ring having a handle or wrench attached is placed eccentric to and between the two banks of shoes. Head bolts from the shoes fit into slots in this ring, which are so arranged that when the ring is rotated a quarter turn in one direction the shoes are thrust inwardly to cramp the neopnrene about the pipe, malting a tight seal. Moving the ring in the reverse direction moves the shoes outwardly and frees the pipe which then may be readily removed from the stuffing box. This device has particular application as a closure for the end of a coolant tube of a neutronic reactor.

  2. PLASMA DEVICE

    DOE Patents [OSTI]

    Baker, W.R.

    1961-08-22

    A device is described for establishing and maintaining a high-energy, rotational plasma for use as a fast discharge capacitor. A disc-shaped, current- conducting plasma is formed in an axinl magnetic field and a crossed electric field, thereby creating rotational kinetic enengy in the plasma. Such energy stored in the rotation of the plasma disc is substantial and is convertible tc electrical energy by generator action in an output line electrically coupled to the plasma volume. Means are then provided for discharging the electrical energy into an external circuit coupled to the output line to produce a very large pulse having an extremely rapid rise time in the waveform thereof. (AE C)

  3. Optoelectronic device

    DOE Patents [OSTI]

    Bonekamp, Jeffrey E.; Boven, Michelle L.; Gaston, Ryan S.

    2014-09-09

    The invention is an optoelectronic device comprising an active portion which converts light to electricity or converts electricity to light, the active portion having a front side for the transmittal of the light and a back side opposite from the front side, at least two electrical leads to the active portion to convey electricity to or from the active portion, an enclosure surrounding the active portion and through which the at least two electrical leads pass wherein the hermetically sealed enclosure comprises at the front side of the active portion a barrier material which allows for transmittal of light, one or more getter materials disposed so as to not impede the transmission of light to or from the active portion, and a contiguous gap pathway to the getter material which pathway is disposed between the active portion and the barrier material.

  4. Enhanced Thermoelectric Properties of Cu2ZnSnSe4 with Ga-doping

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Kaya; Beauchemin, Laura; Wang, Hsin; Porter, Wallace D.; Martin, Joshua; Nolas, George S.

    2015-08-10

    Gallium doped Cu2ZnSnSe4 quaternary chalcogenides with and without excess Cu were synthesized by elemental reaction and densified using hot pressing in order to investigate their high temperature thermoelectric properties. The resistivity, , and Seebeck coefficient, S, for these materials decrease with increased Ga-doping while both mobility and effective mass increase with Ga doping. The power factor (S2/ρ) therefore increases with Ga-doping. The highest thermoelectric figure of merit (ZT = 0.39 at 700 K) was obtained for the composition that had the lowest thermal conductivity. Our results suggest an approach to achieving optimized thermoelectric properties and are part of the continuingmore » effort to explore different quaternary chalcogenide compositions and structure types, as this class of materials continues to be of interest for thermoelectrics applications.« less

  5. Development of High-efficiency Thermoelectric Materials for Vehicle Waste Heat Utililization

    SciTech Connect (OSTI)

    Li, Qiang

    2009-04-30

    The goals of this . CRADA are: 1) Investigation of atomistic structure and nucleation of nanoprecipitates in (PbTe){sub I-x}(AgSbTe2){sub x} (LAST) system; and 2) Development of non-equilibrium synthesis of thermoelectric materials for waste heat recovery. We have made significant accomplishment in both areas. We studied the structure of LAST materials using high resolution imaging, nanoelectron diffraction, energy dispersive spectrum, arid electron energy loss spectrum, and observed a range of nanoparticles The results, published in J. of Applied Physics, provide quantitative structure information about nanoparticles, that is essential for the understanding of the origin of the high thermoelectric performance in this class of materials. We coordinated non-equilibrium synthesis and characterization of thermoelectric materials for waste heat recovery application. Our results, published in J. of Electronic Materials, show enhanced thermoelectric figure of merit and robust mechanical properties in bulk . filled skutterudites.

  6. Geek-Up[6.10.2011]: Thermoelectrics' Great Power, Key Ingredient in Bone's Nanostructure

    Broader source: Energy.gov [DOE]

    Advanced thermoelectric materials could be used to develop vehicle exhaust systems that convert exhaust heat into electricity, concentrate solar energy for power generation and recover waste heat from industrial processes.

  7. Thermoelectric Enhancement in PbTe with K or Na codoping from...

    Office of Scientific and Technical Information (OSTI)

    Thermoelectric Enhancement in PbTe with K or Na codoping from tuning the interaction of the light- and heavy-hole valence bands Citation Details In-Document Search Title: ...

  8. Vehicle Technologies Office Merit Review 2014: Thermoelectric Waste Heat Recovery Program for Passenger Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by GenTherm at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about thermoelectric waste heat recovery...

  9. A new n-type half-Heusler thermoelectric material NbCoSb (Journal...

    Office of Scientific and Technical Information (OSTI)

    new n-type half-Heusler thermoelectric material NbCoSb Citation Details In-Document Search This content will become publicly available on June 15, 2017 Title: A new n-type ...

  10. A new n-type half-Heusler thermoelectric material NbCoSb (Journal...

    Office of Scientific and Technical Information (OSTI)

    A new n-type half-Heusler thermoelectric material NbCoSb This content will become publicly available on June 15, 2017 Prev Next Title: A new n-type half-Heusler ...

  11. CsBi4Te6: A High-Performance Thermoelectric Material for Low...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thermoelectric properties of CsBi(4)Te(6) appear to match or exceed those of Bi(2-x)Sb(x)Te(3-y)Se(y) alloys. URL: Link to article - National Center for Biotechnology Information

  12. Correlation Between Structure and Thermoelectric Properties of Bulk High Performance Materials for Energy Conversion

    Broader source: Energy.gov [DOE]

    Rapid solidified precursor converted into crystalline bulks under pressure produced thermoelectric materials of nano-sized grains with strongly coupled grain boundaries, achieving reduced lattice thermal conductivity and increased power factor

  13. High performance superconducting devices enabled by three dimensionally ordered nanodots and/or nanorods

    DOE Patents [OSTI]

    Goyal, Amit

    2013-09-17

    Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.

  14. High performance devices enabled by epitaxial, preferentially oriented, nanodots and/or nanorods

    DOE Patents [OSTI]

    Goyal, Amit

    2011-10-11

    Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic, superconducting and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.

  15. High performance electrical, magnetic, electromagnetic and electrooptical devices enabled by three dimensionally ordered nanodots and nanorods

    DOE Patents [OSTI]

    Goyal, Amit , Kang; Sukill

    2012-02-21

    Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.

  16. The effect of Coulomb interactions on thermoelectric properties of quantum dots

    SciTech Connect (OSTI)

    Zimbovskaya, Natalya A.

    2014-03-14

    Thermoelectric effects in a quantum dot coupled to the source and drain charge reservoirs are explored using a nonequilibrium Green's functions formalism beyond the Hartree-Fock approximation. Thermal transport is analyzed within a linear response regime. A transition from Coulomb blockade regime to Kondo regime in thermoelectric transport through a single-level quantum dot is traced using unified approximations for the relevant Green's functions.

  17. Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Vehicle Applications | Department of Energy of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle Applications Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle Applications Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_bell.pdf (1.19 MB) More Documents & Publications Vehicle Fuel Economy

  18. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Powered Vehicle | Department of Energy DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_schock.pdf (104.66 KB) More Documents & Publications Thermoelectrici Conversion of Waste Heat to Electricity in an IC Engine-Powered Vehicle Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Wate

  19. Clean Diesel Engine Component Improvement Program Diesel Truck Thermoelectric Generator

    SciTech Connect (OSTI)

    Elsner, N. B.; Bass, J. C.; Ghamaty, S.; Krommenhoek, D.; Kushch, A.; Snowden, D.; Marchetti, S.

    2005-03-16

    Hi-Z Technology, Inc. (Hi-Z) is currently developing four different auxiliary generator designs that are used to convert a portion (5 to 20%) of the waste heat from vehicle engines exhaust directly to electricity. The four designs range from 200 Watts to 10 kW. The furthest along is the 1 kW Diesel Truck Thermoelectric Generator (DTTEG) for heavy duty Class 8 Diesel trucks, which, under this program, has been subjected to 543,000 equivalent miles of bouncing and jarring on PACCAR's test track. Test experience on an earlier version of the DTTEG on the same track showed the need for design modifications incorporated in DTTEG Mod 2, such as a heavy duty shock mounting system and reinforcement of the electrical leads mounting system, the thermocouple mounting system and the thermoelectric module restraints. The conclusion of the 543,000 mile test also pointed the way for an upgrading to heavy duty hose or flex connections for the internal coolant connections for the TEG, and consideration of a separate lower temperature cooling loop with its own radiator. Fuel savings of up to $750 per year and a three to five year payback are believed to be possible with the 5 % efficiency modules. The economics are expected to improve considerably to approach a two year payback when the 5 kW to 10 kW generators make it to the market in a few years with a higher efficiency (20%) thermoelectric module system called Quantum Wells, which are currently under development by Hi-Z. Ultimately, as automation takes over to reduce material and labor costs in the high volume production of QW modules, a one year payback for the 5 kW to10 kW generator appears possible. This was one of the stated goals at the beginning of the project. At some future point in time, with the DTTEG becoming standard equipment on all trucks and automobiles, fuel savings from the 25% conversion of exhaust heat to useable electricity nationwide equates to a 10% reduction in the 12 to 15 million barrels per day of

  20. Thermal Conductivity Measurements of Bulk Thermoelectric Materials (Prop. 2004-067)

    SciTech Connect (OSTI)

    Wang, Hsin; Porter, Wallace D; Sharp, J

    2006-01-01

    Thermal conductivity is an important material property of the bulk thermoelectrics. To improve ZT a reduced thermal conductivity is always desired. However, there is no standard material for thermoelectrics and the test results, even on the same material, often show significant scatter. The scatter in thermal conductivity made reported ZT values uncertain and sometime unrepeatable. One of the reasons for the uncertainty is due to the microstructure differences resulting from sintering, heat treatment and other processing parameters. They selected commonly used bulk thermoelectric materials and conducted thermal conductivity measurements using the laser flash diffusivity and differential scanning calorimeter (DSC) systems. Thermal conductivity was measured as a function of temperature of temperature from room temperature to 500 K and back to room temperature. The effect of thermal cycling on the bulk thermoelectric was studied. Comnbined with measurements on electrical resistivity and Seebeck coefficient, they show the use of a ZT map in selecting thermoelectrics. The commercial bulk material showed very good consistency and reliability compared to other bulk materials. The goal is to develop a thermal transport properties database for the bulk thermoelectrics and make the information available to the research community and industry.

  1. Integrated device architectures for electrochromic devices

    DOE Patents [OSTI]

    Frey, Jonathan Mack; Berland, Brian Spencer

    2015-04-21

    This disclosure describes systems and methods for creating monolithically integrated electrochromic devices which may be a flexible electrochromic device. Monolithic integration of thin film electrochromic devices may involve the electrical interconnection of multiple individual electrochromic devices through the creation of specific structures such as conductive pathway or insulating isolation trenches.

  2. Laser device

    DOE Patents [OSTI]

    Scott, Jill R.; Tremblay, Paul L.

    2007-07-10

    A laser device includes a target position, an optical component separated a distance J from the target position, and a laser energy source separated a distance H from the optical component, distance H being greater than distance J. A laser source manipulation mechanism exhibits a mechanical resolution of positioning the laser source. The mechanical resolution is less than a spatial resolution of laser energy at the target position as directed through the optical component. A vertical and a lateral index that intersect at an origin can be defined for the optical component. The manipulation mechanism can auto align laser aim through the origin during laser source motion. The laser source manipulation mechanism can include a mechanical index. The mechanical index can include a pivot point for laser source lateral motion and a reference point for laser source vertical motion. The target position can be located within an adverse environment including at least one of a high magnetic field, a vacuum system, a high pressure system, and a hazardous zone. The laser source and an electro-mechanical part of the manipulation mechanism can be located outside the adverse environment. The manipulation mechanism can include a Peaucellier linkage.

  3. Laser device

    DOE Patents [OSTI]

    Scott, Jill R.; Tremblay, Paul L.

    2004-11-23

    A laser device includes a target position, an optical component separated a distance J from the target position, and a laser energy source separated a distance H from the optical component, distance H being greater than distance J. A laser source manipulation mechanism exhibits a mechanical resolution of positioning the laser source. The mechanical resolution is less than a spatial resolution of laser energy at the target position as directed through the optical component. A vertical and a lateral index that intersect at an origin can be defined for the optical component. The manipulation mechanism can auto align laser aim through the origin during laser source motion. The laser source manipulation mechanism can include a mechanical index. The mechanical index can include a pivot point for laser source lateral motion and a reference point for laser source vertical motion. The target position can be located within an adverse environment including at least one of a high magnetic field, a vacuum system, a high pressure system, and a hazardous zone. The laser source and an electro-mechanical part of the manipulation mechanism can be located outside the adverse environment. The manipulation mechanism can include a Peaucellier linkage.

  4. A facility to remotely assemble radioisotope thermoelectric generators

    SciTech Connect (OSTI)

    Engstrom, J.W.; Goldmann, L.H.; Truitt, R.W.

    1992-07-01

    Radioisotope Thermoelectric Generators (RTGs) are electrical power sources that use heat from decaying radioisotopes to directly generate electrical power. The RTG assembly process is performed in an inert atmosphere inside a large glovebox, which is surrounded by radiation shielding to reduce exposure to neutron and gamma radiation from the radioisotope heat source. In the past, allowable dose rate limits have allowed direct, manual assembly methods; however, current dose rate limits require a thicker radiation shielding that makes direct, manual assembly infeasible. To minimize RTG assembly process modifications, telerobotic systems are being investigated to perform remote assembly tasks. Telerobotic systems duplicate human arm motion and incorporate force feedback sensitivity to handle objects and tools in a human-like manner. A telerobotic system with two arms and a three-dimensional (3-D) vision system can be used to perform remote RTG assembly tasks inside gloveboxes and cells using unmodified, normal hand tools.

  5. A facility to remotely assemble radioisotope thermoelectric generators

    SciTech Connect (OSTI)

    Engstrom, J.W.; Goldmann, L.H.; Truitt, R.W. )

    1993-01-15

    Radioisotope Thermoelectric Generators (RTGs) are electrical power sources that use heat from decaying radioisotopes to directly generate electrical power. The RTG assembly process is performed in an inert atmosphere inside a large glovebox, which is surrounded by radiation shielding to reduce exposure to neutron and gamma radiation from the radioisotope heat source. In the past, allowable dose rate limits have allowed direct, manual assembly methods; however, current dose rate limits require a thicker radiation shielding that makes direct, manual assembly infeasible. To minimize RTG assembly process modifications, telerobotic systems are being investigated to perform remote assembly tasks. Telerobotic systems duplicate human arm motion and incorporate force feedback sensitivity to handle objects and tools in a human-like manner. A telerobotic system with two arms and a three-dimensional (3-D) vision system can be used to perform remote RTG assembly tasks inside gloveboxes and cells using unmodified, normal hand tools.

  6. Enhanced thermoelectric power and electronic correlations in RuSe₂

    SciTech Connect (OSTI)

    Wang, Kefeng; Wang, Aifeng; Tomic, A.; Wang, Limin; Abeykoon, A. M. Milinda; Dooryhee, E.; Billinge, S. J.L.; Petrovic, C.

    2015-03-03

    We report the electronic structure, electric and thermal transport properties of Ru₁₋xIrxSe₂ (x ≤ 0.2). RuSe₂ is a semiconductor that crystallizes in a cubic pyrite unit cell. The Seebeck coefficient of RuSe₂ exceeds -200 µV/K around 730 K. Ir substitution results in the suppression of the resistivity and the Seebeck coefficient, suggesting the removal of the peaks in density of states near the Fermi level. Ru₀.₈Ir₀.₂Se₂ shows a semiconductor-metal crossover at about 30 K. The magnetic field restores the semiconducting behavior. Our results indicate the importance of the electronic correlations in enhanced thermoelectricity of RuSb₂.

  7. Enhanced thermoelectric power and electronic correlations in RuSe₂

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Kefeng; Wang, Aifeng; Tomic, A.; Wang, Limin; Abeykoon, A. M. Milinda; Dooryhee, E.; Billinge, S. J.L.; Petrovic, C.

    2015-03-03

    We report the electronic structure, electric and thermal transport properties of Ru₁₋xIrxSe₂ (x ≤ 0.2). RuSe₂ is a semiconductor that crystallizes in a cubic pyrite unit cell. The Seebeck coefficient of RuSe₂ exceeds -200 µV/K around 730 K. Ir substitution results in the suppression of the resistivity and the Seebeck coefficient, suggesting the removal of the peaks in density of states near the Fermi level. Ru₀.₈Ir₀.₂Se₂ shows a semiconductor-metal crossover at about 30 K. The magnetic field restores the semiconducting behavior. Our results indicate the importance of the electronic correlations in enhanced thermoelectricity of RuSb₂.

  8. Thermoelectric power of supported graphene - An iterative approach

    SciTech Connect (OSTI)

    Rizwana Begum, K.; Sankeshwar, N. S.

    2015-06-24

    Thermoelectric power, S, of graphene supported on SiO{sub 2} substrate is studied for 10K < T < 400K within the framework of Boltzmann transport formalism by an iterative method. Numerical calculations of diffusion thermopower, S{sub d}, as a function of temperature, are presented assuming the electrons to be scattered by impurities, vacancies, surface roughness, acoustic phonons, inelastic optical phonons and surface polar optical phonons. For the range of temperatures considered, S{sub d} is found to be dominated by impurities for T < 40K and by acoustic phonon and vacancy scatterings for T > 40K. The optical phonons are found to influence S{sub d} for T > 300K. Our calculations, assuming the drag component to be negligible, obtain good agreement with the recent experimental data.

  9. Improvement of the thermoelectric properties of [Bi{sub 1.68}Ca{sub 2}O{sub 4-{delta}}]{sup RS}[CoO{sub 2}]{sub 1.69} cobaltite by chimie douce methods

    SciTech Connect (OSTI)

    Muguerra, Herve; Rivas-Murias, Beatriz; Traianidis, Maria; Henrist, Catherine; Vertruyen, Benedicte; Cloots, Rudi

    2010-06-15

    [Bi{sub 1.68}Ca{sub 2}O{sub 4-{delta}}]{sup RS}[CoO{sub 2}]{sub 1.69} has been obtained by different chimie douce methods and uniaxially or isostatically pressed. The influence of these parameters on the thermoelectric properties has been investigated. Contrary to the Seebeck coefficient, which remains unchanged, the electrical conductivity is greatly modified. In particular, spray-drying synthesis followed by uniaxial pressing results in an electrical conductivity two times larger than in the case of conventional solid state synthesis. Our results suggest that a narrow particle size distribution is beneficial to the thermoelectric properties of the layered compounds. The spray-drying technique seems to be promising to improve the electrical conductivity of layered materials. Moreover, this method presents other advantages (homogeneous samples and less energetic processing) which could be interesting to the future manufacturing of thermoelectric devices. - Graphical abstract: Small particles and narrow size distribution is obtained for spray-drying [Bi{sub 1.68}Ca{sub 2}O{sub 4}]{sup RS}[CoO{sub 2}]{sub 1.69} cobaltate. The power factor is boosted up two times compared with the conventional solid state method.

  10. Electronic tuning of the transport properties of off-stoichiometric Pb{sub x}Sn{sub 1−x}Te thermoelectric alloys by Bi{sub 2}Te{sub 3} doping

    SciTech Connect (OSTI)

    Guttmann, Gilad M.; Dadon, David; Gelbstein, Yaniv

    2015-08-14

    The recent energy demands affected by the dilution of conventional energy resources and the growing awareness of environmental considerations had motivated many researchers to seek for novel renewable energy conversion methods. Thermoelectric direct conversion of thermal into electrical energies is such a method, in which common compositions include IV-VI semiconducting compounds (e.g., PbTe and SnTe) and their alloys. For approaching practical thermoelectric devices, the current research is focused on electronic optimization of off-stoichiometric p-type Pb{sub x}Sn{sub 1−x}Te alloys by tuning of Bi{sub 2}Te{sub 3} doping and/or SnTe alloying levels, while avoiding the less mechanically favorable Na dopant. It was shown that upon such doping/alloying, higher ZTs, compared to those of previously reported undoped Pb{sub 0.5}Sn{sub 0.5}Te alloy, were obtained at temperatures lower than 210–340 °C, depending of the exact doping/alloying level. It was demonstrated that upon optimal grading of the carrier concentration, a maximal thermoelectric efficiency enhancement of ∼38%, compared to that of an undoped material, is expected.

  11. Thermoelectric infrared microsensors based on a periodically suspended thermopile integrating nanostructured Ge/SiGe quantum dots superlattice

    SciTech Connect (OSTI)

    Ziouche, K. E-mail: Zahia.bougrioua@iemn.univ-lille1.fr; Bougrioua, Z. E-mail: Zahia.bougrioua@iemn.univ-lille1.fr; Lejeune, P.; Lasri, T.; Leclercq, D.; Savelli, G.; Hauser, D.; Michon, P.-M.

    2014-07-28

    This paper presents an original integration of polycrystalline SiGe-based quantum dots superlattices (QDSL) into Thermoelectric (TE) planar infrared microsensors (?SIR) fabricated using a CMOS technology. The nanostructuration in QDSL results into a considerably reduced thermal conductivity by a factor up to 10 compared to the one of standard polysilicon layers that are usually used for IR sensor applications. A presentation of several TE layers, QDSL and polysilicon, is given before to describe the fabrication of the thermopile-based sensors. The theoretical values of the sensitivity to irradiance of ?SIR can be predicted thanks to an analytical model. These findings are used to interpret the experimental measurements versus the nature of the TE layer exploited in the devices. The use of nanostructured QDSL as the main material in ?SIR thermopile has brought a sensitivity improvement of about 28% consistent with theoretical predictions. The impact of QDSL low thermal conductivity is damped by the contribution of the thermal conductivity of all the other sub-layers that build up the device.

  12. Connector device for building integrated photovoltaic device

    SciTech Connect (OSTI)

    Keenihan, James R.; Langmaid, Joe A.; Eurich, Gerald K.; Lesniak, Michael J.; Mazor, Michael H.; Cleerman, Robert J.; Gaston, Ryan S.

    2015-11-10

    The present invention is premised upon a connector device and method that can more easily electrically connect a plurality of PV devices or photovoltaic system components and/or locate these devices/components upon a building structure. It also may optionally provide some additional sub-components (e.g. at least one bypass diode and/or an indicator means) and may enhance the serviceability of the device.

  13. Connector device for building integrated photovoltaic device

    DOE Patents [OSTI]

    Keenihan, James R.; Langmaid, Joseph A.; Eurich, Gerald K.; Lesniak, Michael J.; Mazor, Michael H.; Cleereman, Robert J.; Gaston, Ryan S.

    2014-06-03

    The present invention is premised upon a connector device and method that can more easily electrically connect a plurality of PV devices or photovoltaic system components and/or locate these devices/components upon a building structure. It also may optionally provide some additional sub-components (e.g. at least one bypass diode and/or an indicator means) and may enhance the serviceability of the device.

  14. Direct evidence of strong local ferroelectric ordering in a thermoelectric semiconductor

    SciTech Connect (OSTI)

    Aggarwal, Leena; Sekhon, Jagmeet S.; Arora, Ashima; Sheet, Goutam; Guin, Satya N.; Negi, Devendra S.; Datta, Ranjan; Biswas, Kanishka

    2014-09-15

    It is thought that the proposed new family of multi-functional materials, namely, the ferroelectric thermoelectrics may exhibit enhanced functionalities due to the coupling of the thermoelectric parameters with ferroelectric polarization in solids. Therefore, the ferroelectric thermoelectrics are expected to be of immense technological and fundamental significance. As a first step towards this direction, it is most important to identify the existing high performance thermoelectric materials exhibiting ferroelectricity. Herein, through the direct measurement of local polarization switching, we show that the recently discovered thermoelectric semiconductor AgSbSe{sub 2} has local ferroelectric ordering. Using piezo-response force microscopy, we demonstrate the existence of nanometer scale ferroelectric domains that can be switched by external electric field. These observations are intriguing as AgSbSe{sub 2} crystalizes in cubic rock-salt structure with centro-symmetric space group (Fm–3m), and therefore, no ferroelectricity is expected. However, from high resolution transmission electron microscopy measurement, we found the evidence of local superstructure formation which, we believe, leads to local distortion of the centro-symmetric arrangement in AgSbSe{sub 2} and gives rise to the observed ferroelectricity. Stereochemically active 5S{sup 2} lone-pair of Sb may also give rise to local structural distortion thereby creating ferroelectricity in AgSbSe{sub 2}.

  15. Phase transition enhanced thermoelectric figure-of-merit in copper chalcogenides

    SciTech Connect (OSTI)

    Brown, David R.; Day, Tristan; Snyder, G. Jeffrey; Borup, Kasper A.; Christensen, Sebastian; Iversen, Bo B.

    2013-11-01

    While thermoelectric materials can be used for solid state cooling, waste heat recovery, and solar electricity generation, low values of the thermoelectric figure of merit, zT, have led to an efficiency too low for widespread use. Thermoelectric effects are characterized by the Seebeck coefficient or thermopower, which is related to the entropy associated with charge transport. For example, coupling spin entropy with the presence of charge carriers has enabled the enhancement of zT in cobalt oxides. We demonstrate that the coupling of a continuous phase transition to carrier transport in Cu{sub 2}Se over a broad (360–410 K) temperature range results in a dramatic peak in thermopower, an increase in phonon and electron scattering, and a corresponding doubling of zT (to 0.7 at 406 K), and a similar but larger increase over a wider temperature range in the zT of Cu{sub 1.97}Ag{sub .03}Se (almost 1.0 at 400 K). The use of structural entropy for enhanced thermopower could lead to new engineering approaches for thermoelectric materials with high zT and new green applications for thermoelectrics.

  16. Drought Risk Modeling for Thermoelectric Power Plants Siting using an Excess Over Threshold Approach

    SciTech Connect (OSTI)

    Bekera, Behailu B; Francis, Royce A; Omitaomu, Olufemi A

    2014-01-01

    Water availability is among the most important elements of thermoelectric power plant site selection and evaluation criteria. With increased variability and changes in hydrologic statistical stationarity, one concern is the increased occurrence of extreme drought events that may be attributable to climatic changes. As hydrological systems are altered, operators of thermoelectric power plants need to ensure a reliable supply of water for cooling and generation requirements. The effects of climate change are expected to influence hydrological systems at multiple scales, possibly leading to reduced efficiency of thermoelectric power plants. In this paper, we model drought characteristics from a thermoelectric systems operational and regulation perspective. A systematic approach to characterise a stream environment in relation to extreme drought occurrence, duration and deficit-volume is proposed and demonstrated. This approach can potentially enhance early stage decisions in identifying candidate sites for a thermoelectric power plant application and allow investigation and assessment of varying degrees of drought risk during more advanced stages of the siting process.

  17. On the Design of High Efficiency Thermoelectric Type I Clathrates through Transition Metal Doping

    SciTech Connect (OSTI)

    Shi, Xun; Yang, Jiong; Yang, Jihui; Salvador, James R.; Bai, Shengqiang; Zhang, Weiqing; Chen, Lidong; Wong-Ng, W.; Wang, Hsin

    2010-01-01

    The lack of high efficiency thermoelectric materials hinders their deployment into wide ranging applications such as power generation from waste heat and solid state heating and cooling, which could lead to significant energy savings. Type I clathrates have recently been identified as prospective thermoelectric materials for power generation purposes due to their very low lattice thermal conductivity values. The maximum thermoelectric figure of merit of almost all type I clathrates is, however, less than 1; and occurs at, or above, 1000 K making them unfavorable especially for intermediate temperature applications. In this report, we demonstrate that transition metal doping introduces charge distortion and lattice defects into these materials which increases the ionized impurity scattering of carriers and point defect scattering of lattice phonons, respectively; leading to an enhanced power factor, reduced lattice thermal conductivity, and therefore improved thermoelectric figure of merit. Most importantly, the band gap of these materials can be tuned between 0.1 eV and 0.5 eV by adjusting the transition metal content, making it possible to design type I clathrates with excellent thermoelectric properties between 500 K and 1000 K.

  18. Full-scale computation for all the thermoelectric property parameters of half-Heusler compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hong, A. J.; Li, L.; He, R.; Gong, J. J.; Yan, Z. B.; Wang, K. F.; Liu, J. -M.; Ren, Z. F.

    2016-03-07

    The thermoelectric performance of materials relies substantially on the band structures that determine the electronic and phononic transports, while the transport behaviors compete and counter-act for the power factor PF and figure-of-merit ZT. These issues make a full-scale computation of the whole set of thermoelectric parameters particularly attractive, while a calculation scheme of the electronic and phononic contributions to thermal conductivity remains yet challenging. In this work, we present a full-scale computation scheme based on the first-principles calculations by choosing a set of doped half- Heusler compounds as examples for illustration. The electronic structure is computed using the WIEN2k codemore » and the carrier relaxation times for electrons and holes are calculated using the Bardeen and Shockley’s deformation potential (DP) theory. The finite-temperature electronic transport is evaluated within the framework of Boltzmann transport theory. In sequence, the density functional perturbation combined with the quasi-harmonic approximation and the Klemens’ equation is implemented for calculating the lattice thermal conductivity of carrier-doped thermoelectric materials such as Tidoped NbFeSb compounds without losing a generality. The calculated results show good agreement with experimental data. Lastly, the present methodology represents an effective and powerful approach to calculate the whole set of thermoelectric properties for thermoelectric materials.« less

  19. Enhancing efficiency and power of quantum-dots resonant tunneling thermoelectrics in three-terminal geometry by cooperative effects

    SciTech Connect (OSTI)

    Jiang, Jian-Hua

    2014-11-21

    We propose a scheme of multilayer thermoelectric engine where one electric current is coupled to two temperature gradients in three-terminal geometry. This is realized by resonant tunneling through quantum dots embedded in two thermal and electrical resisting polymer matrix layers between highly conducting semiconductor layers. There are two thermoelectric effects, one of which is pertaining to inelastic transport processes (if energies of quantum dots in the two layers are different), while the other exists also for elastic transport processes. These two correspond to the transverse and longitudinal thermoelectric effects, respectively, and are associated with different temperature gradients. We show that cooperation between the two thermoelectric effects leads to markedly improved figure of merit and power factor, which is confirmed by numerical calculation using material parameters. Such enhancement is robust against phonon heat conduction and energy level broadening. Therefore, we demonstrated cooperative effect as an additional way to effectively improve performance of thermoelectrics in three-terminal geometry.

  20. CONTROL LIMITER DEVICE

    DOE Patents [OSTI]

    DeShong, J.A.

    1960-03-01

    A control-limiting device for monltoring a control system is described. The system comprises a conditionsensing device, a condition-varying device exerting a control over the condition, and a control means to actuate the condition-varying device. A control-limiting device integrates the total movement or other change of the condition-varying device over any interval of time during a continuum of overlapping periods of time, and if the tothl movement or change of the condition-varying device exceeds a preset value, the control- limiting device will switch the control of the operated apparatus from automatic to manual control.

  1. Thermal vacuum life test facility for radioisotope thermoelectric generators

    SciTech Connect (OSTI)

    Deaton, R.L.; Goebel, C.J.; Amos, W.R.

    1990-01-01

    In the late 1970's, the Department of Energy (DOE) assigned Monsanto Research Corporation, Mound Facility, now operated by EG G Mound Applied Technologies, the responsibility for assembling and testing General Purpose Heat Source (GPHS) radioisotope thermoelectric generators (RTGs). Assembled and tested were five RTGs, which included four flight units and one non-flight qualification unit. Figure 1 shows the RTG, which was designed by General Electric AstroSpace Division (GE/ASD) to produce 285 W of electrical power. A detailed description of the processes for RTG assembly and testing is presented by Amos and Goebel (1989). The RTG performance data are described by Bennett, et al. (1986). The flight units will provide electrical power for the National Aeronautics and Space Administration's (NASA) Galileo mission to Jupiter (two RTGs) and the joint NASA/European Space Agency (ESA) Ulysses mission to study the polar regions of the sun (one RTG). The remaining flight unit will serve as the spare for both missions, and a non-flight qualification unit was assembled and tested to ensure that performance criteria were adequately met. 4 refs., 3 figs.

  2. Analytical thermal model validation for Cassini radioisotope thermoelectric generator

    SciTech Connect (OSTI)

    Lin, E.I.

    1997-12-31

    The Saturn-bound Cassini spacecraft is designed to rely, without precedent, on the waste heat from its three radioisotope thermoelectric generators (RTGs) to warm the propulsion module subsystem, and the RTG end dome temperature is a key determining factor of the amount of waste heat delivered. A previously validated SINDA thermal model of the RTG was the sole guide to understanding its complex thermal behavior, but displayed large discrepancies against some initial thermal development test data. A careful revalidation effort led to significant modifications and adjustments of the model, which result in a doubling of the radiative heat transfer from the heat source support assemblies to the end domes and bring up the end dome and flange temperature predictions to within 2 C of the pertinent test data. The increased inboard end dome temperature has a considerable impact on thermal control of the spacecraft central body. The validation process offers an example of physically-driven analytical model calibration with test data from not only an electrical simulator but also a nuclear-fueled flight unit, and has established the end dome temperatures of a flight RTG where no in-flight or ground-test data existed before.

  3. Exploring packaging strategies of nano-embedded thermoelectric generators

    SciTech Connect (OSTI)

    Singha, Aniket; Muralidharan, Bhaskaran; Mahanti, Subhendra D.

    2015-10-15

    Embedding nanostructures within a bulk matrix is an important practical approach towards the electronic engineering of high performance thermoelectric systems. For power generation applications, it ideally combines the efficiency benefit offered by low dimensional systems along with the high power output advantage offered by bulk systems. In this work, we uncover a few crucial details about how to embed nanowires and nanoflakes in a bulk matrix so that an overall advantage over pure bulk may be achieved. First and foremost, we point out that a performance degradation with respect to bulk is inevitable as the nanostructure transitions to a multi moded one. It is then shown that a nano embedded system of suitable cross-section offers a power density advantage over a wide range of efficiencies at higher packing fractions, and this range gradually narrows down to the high efficiency regime, as the packing fraction is reduced. Finally, we introduce a metric - the advantage factor, to elucidate quantitatively, the enhancement in the power density offered via nano-embedding at a given efficiency. In the end, we explore the maximum effective width of nano-embedding which serves as a reference in designing generators in the efficiency range of interest.

  4. International Round-Robin Testing of Bulk Thermoelectrics

    SciTech Connect (OSTI)

    Wang, Hsin; Porter, Wallace D; Bottner, Harold; Konig, Jan; Chen, Lidong; Bai, Shengqiang; Tritt, Terry M.; Mayolett, Alex; Smith, Charlene; Harris, Fred; Sharp, Jeff; Lo, Jason; Keinke, Holger; Kiss, Laszlo I.

    2011-11-01

    Two international round-robin studies were conducted on transport properties measurements of bulk thermoelectric materials. The study discovered current measurement problems. In order to get ZT of a material four separate transport measurements must be taken. The round-robin study showed that among the four properties Seebeck coefficient is the one can be measured consistently. Electrical resistivity has +4-9% scatter. Thermal diffusivity has similar +5-10% scatter. The reliability of the above three properties can be improved by standardizing test procedures and enforcing system calibrations. The worst problem was found in specific heat measurements using DSC. The probability of making measurement error is great due to the fact three separate runs must be taken to determine Cp and the baseline shift is always an issue for commercial DSC. It is suggest the Dulong Petit limit be always used as a guide line for Cp. Procedures have been developed to eliminate operator and system errors. The IEA-AMT annex is developing standard procedures for transport properties testing.

  5. Band structure engineering through orbital interaction for enhanced thermoelectric power factor

    SciTech Connect (OSTI)

    Zhu, Hong; Sun, Wenhao; Ceder, Gerbrand; Armiento, Rickard; Lazic, Predrag

    2014-02-24

    Band structure engineering for specific electronic or optical properties is essential for the further development of many important technologies including thermoelectrics, optoelectronics, and microelectronics. In this work, we report orbital interaction as a powerful tool to finetune the band structure and the transport properties of charge carriers in bulk crystalline semiconductors. The proposed mechanism of orbital interaction on band structure is demonstrated for IV-VI thermoelectric semiconductors. For IV-VI materials, we find that the convergence of multiple carrier pockets not only displays a strong correlation with the s-p and spin-orbit coupling but also coincides with the enhancement of power factor. Our results suggest a useful path to engineer the band structure and an enticing solid-solution design principle to enhance thermoelectric performance.

  6. Atomic-level cotrol of the thermoelectric properties in polytypoid nanowires

    SciTech Connect (OSTI)

    Andrews, Sean C.; Fardy, Melissa A.; Moore, Michael C.; Aloni, Shaoul; Zhang, Minjuan; Radmilovic, Velimir; Yang, Peidong

    2010-10-23

    Thermoelectric materials have generated interest as a means of increasing the efficiency of power generation through the scavenging of waste heat. Materials containing nanometer-sized structural and compositional features can exhibit enhanced thermoelectric performance due to the decoupling of certain electrical and thermal properties, but the extent to which these features can be controlled is often limited. Here we report a simple synthesis of M{sub 2}O{sub 3}(ZnO){sub n} (M = In, Ga, Fe) nanowires with controllable polytypoid structures, where the nanostructured features are tuned by adjusting the amount of metal precursor. After the introduction of nanometer-scale features (individual atomic layers and alloying), thermal and electrical measurements on single In{sub 2-x}Ga{sub x}O3(ZnO){sub n} nanowires reveal a simultaneous improvement in all contributing factors to the thermoelectric figure of merit, indicating successful modification of the nanowire transport properties.

  7. Large theoretical thermoelectric power factor of suspended single-layer MoS{sub 2}

    SciTech Connect (OSTI)

    Babaei, Hasan E-mail: babaei@auburn.edu; Khodadadi, J. M.; Sinha, Sanjiv

    2014-11-10

    We have calculated the semi-classical thermoelectric power factor of suspended single-layer (SL)- MoS{sub 2} utilizing electron relaxation times derived from ab initio calculations. Measurements of the thermoelectric power factor of SL-MoS{sub 2} on substrates reveal poor power factors. In contrast, we find the thermoelectric power factor of suspended SL-MoS{sub 2} to peak at ∼2.8 × 10{sup 4} μW/m K{sup 2} at 300 K, at an electron concentration of 10{sup 12} cm{sup −2}. This figure is higher than that in bulk Bi{sub 2}Te{sub 3}, for example. Given its relatively high thermal conductivity, suspended SL-MoS{sub 2} may hold promise for in-plane thin-film Peltier coolers, provided reasonable mobilities can be realized.

  8. High Temperature Thermoelectric Oxides Engineered At Multiple Length Scales For Energy Harvesting

    SciTech Connect (OSTI)

    Ohuchi, Fumio; Bordia, Rajendra

    2014-12-20

    Thermoelectric aspects of the processing parameters the n-type relaxors, including SrxBa1-xNb2O6 (SBN100x), Sr2Nb2O7 (SN) and SrBi2Nb2O9 (SBiN), were investigated. A solution combustion synthesis (SCS) route was devised to fabricate SBN, SN and SBiN nanoparticles with excellent phase purity. X-ray photoelectron spectroscopy (XPS) was used to deduce the local cation site occupancy, and detailed thermoelectric transport processes were investigated. Based on the identified behavior, effectiveness of pore formers on the thermoelectric performance was investigated with the goal of decreasing κ through enhanced phonon scattering while preserving the electron transport characteristics.

  9. Influence of aluminium doping on thermoelectric performance of atomic layer deposited ZnO thin films

    SciTech Connect (OSTI)

    Ruoho, Mikko Pale, Ville; Erdmanis, Mikhail; Tittonen, Ilkka

    2013-11-11

    We study the effect of Al doping on thermoelectric power factor of ZnO films grown using atomic layer deposition method. The overall doping level is tuned by either varying the precursor pulsing sequence or by varying the number of precursor pulses while keeping the sequence unchanged. We observe that commonly utilized doping approach when periodic dopant layers are densely packed results in reduced power factor. At the same time, we find that thermoelectric performance can be improved by clustering the dopants. In addition, the clustering was found to tune the preferred crystal orientation of the polycrystalline film.

  10. In situ nanostructure generation and evolution within a bulk thermoelectric material to reduce lattice thermal conductivity.

    SciTech Connect (OSTI)

    Girard, S. N.; He, J.; Li, C.; Moses, S.; Wang, G.; Uher, C.; Dravid, V. P.; Kanatzidis, M. G.

    2010-07-26

    We show experimentally the direct reduction in lattice thermal conductivity as a result of in situ nanostructure generation within a thermoelectric material. Solid solution alloys of the high-performance thermoelectric PbTe-PbS 8% can be synthesized through rapid cooling and subsequent high-temperature activation that induces a spontaneous nucleation and growth of PbS nanocrystals. The emergence of coherent PbS nanostructures reduces the lattice thermal conductivity from {approx}1 to {approx}0.4 W/mK between 400 and 500 K.

  11. Lattice dynamics and thermoelectric properties of nanocrystalline silicon-germanium alloys

    SciTech Connect (OSTI)

    Claudio, Tania; Stein, Niklas; Peterman, Nils; Stroppa, Daniel; Koza, Michael M.; Wiggers, Hartmut; Klobes, B.; Schierning, Gabi; Hermann, Raphael P.

    2015-10-26

    The lattice dynamics and thermoelectric properties of sintered phosphorus-doped nanostructured silicon- germanium alloys obtained by gas-phase synthesis were studied. Measurements of the density of phonon states by inelastic neutron scattering were combined with measurements of the elastic constants and the low- temperature heat capacity. A strong influence of nanostructuring and alloying on the lattice dynamics was observed. The thermoelectric transport properties of samples with different doping as well as samples sintered at different temperature were characterized between room temperature and 1000C. A peak figure of merit zT = 0:88 at 900C is observed and comparatively insensitive to the aforementioned param- eter variations.

  12. Potential thermoelectric performance from optimization of hole-doped Bi2Se3

    SciTech Connect (OSTI)

    Parker, David S; Singh, David J

    2011-01-01

    We present an analysis of the potential thermoelectric performance of hole-doped Bi2Se3, which is commonly considered to show inferior room temperature performance when compared to Bi2Te3. We find that if the lattice thermal conductivity can be reduced by nanostructuring techniques (as have been applied to Bi2Te3) the material may show optimized ZT values of unity or more in the 300 - 500 K temperature range and thus be suitable for cooling and moderate temperature waste heat recovery and thermoelectric solar cell applications. Central to this conclusion are the larger band gap and the relatively heavier valence bands of Bi2Se3.

  13. Anomalous temperature-dependent Young's modulus of a cast LAST (Pb-Sb-Ag-Te) thermoelectric material

    SciTech Connect (OSTI)

    Ren, Fei; Case, Eldon D; Timm, Edward J; Lara-Curzio, Edgar; Trejo, Rosa M

    2010-01-01

    Thermomechanical characterization is important to material evaluation and device design in the development of thermoelectric technology. In this study, we utilize the resonant ultrasound spectroscopy (RUS) technique to examine the elastic behavior of a cast LAST (Pb Sb Ag Te) material with a composition of Ag0.86Pb19Sb1.0Te20 between room temperature and 823 K. The temperature-dependent Young s modulus exhibits a monotonically decreasing trend with increasing temperature. However, an abnormal slope change in the Young s modulus temperature curve around 500 K is observed. In addition, hysteresis between heating and cooling data in the temperature range of 450 550 K is observed, which appears to be dependent on the heating/cooling rate during the RUS experiments such that the hysteresis disappears when the heating/cooling rate was decreased from 5 to 2 K min 1. In this study we propose an order disorder transition model for the anomalous temperature-dependent Young s modulus behavior observed in this study.

  14. Proof-of-principle test for thermoelectric generator for diesel engines; Final report

    SciTech Connect (OSTI)

    1991-07-26

    In September of 1987, the principals of what is now Hi-Z TECHNOLOGY, INC. applied to the National Bureau of Standards (now National Institute of Standards and Technology, NIST) under the Energy Related Inventions Program. The invention was entitled ``Thermoelectric Generator for Diesel Engines.`` The National Institute of Standards and Technology evaluated the invention and on January 12, 1989 forwarded Recommendation Number 455 to the Department of Energy (DOE). This recommendation informed the DOE that the invention had been selected for recommendation by the NIST for possible funding by the DOE. Following the recommendation of the NIST, the DOE contacted Hi-Z to work out a development program for the generator. A contract for a grant to design, fabricate, and test a Proof-of-Principle exhaust powered thermoelectric generator for Diesel engines was signed October 19, 1989. Hi-Z provided the thermoelectric modules used in the generator as their contribution to the project. The purpose of this Grant Program was to design, build, and test a small-scale, Proof-of-Principle thermoelectric generator for a Diesel engine. 15 figs., 1 tab.

  15. Temperature Dependent Elastic moduli of Lead-Telluride based Thermoelectric Materials

    SciTech Connect (OSTI)

    Ren, Fei; Case, Eldon D; Ni, Jennifer E.; Timm, Edward J; Lara-Curzio, Edgar; Kanatzidis, Mercouri G.; Trejo, Rosa M; Lin, Chia-Her

    2009-01-01

    In the open literature, reports of mechanical properties are limited for semiconducting thermoelectric materials, including the temperature dependence of the elastic moduli. In this study, for both cast ingots and hot pressed billets of Ag-, Sb-, Sn-, and S- doped PbTe thermoelectric materials, Resonant Ultrasound Spectroscopy (RUS) was utilized to determine the temperature dependence of elastic moduli including Young's modulus, shear modulus, and Poisson's ratio. This study is the first to determine the temperature-dependent elastic moduli for these PbTe based thermoelectrics and among the few determinations of elasticity of any thermoelectric material for temperatures above 300 K. The Young s modulus and Poisson s ratio measured from room temperature to 773 K during heating and cooling agreed well. Also, the observed Young s modulus, E, versus temperature, T, relationship E(T) = E0(1 bT) is consistent with predictions for materials in the range well above the Debye temperature. A nanoindentation study of Young s modulus on the specimen faces showed that both the cast and hot pressed specimens were approximately elastically isotropic.

  16. THERMOELECTRIC GENERATION OF CHARGE IMBALANCE AT A SUPERCONDUCTOR-NORMAL METAL INTERFACE

    SciTech Connect (OSTI)

    Van Harlingen, D. J.

    1981-01-01

    The thermoelectric voltage produced across a superconductor-normal metal-superconductor (SNS) sandwich by an applied heat current has been measured in Pb-Cu-PbBi and In-Al-Sn as a function of temperature. The observed divergence of the thermoelectric voltage near T{sub c} is attributed to a charge imbalance region decaying into the superconductor from the NS interface over the quasiparticle diffusion length {lambda}{sub Q*}. The charge imbalance is generated by thermoelectrically driven quasiparticle currents in the superconductor. It contributes a voltage per unit heat power given by V{sub s}/P = {lambda}{sub Q*}S/{kappa}A, where A is the sample cross-sectional area, and S and {kappa} are the thermopower and the thermal conductivity of quasiparticles in the superconductor. For Pb and In, we find the measured thermopower in the superconducting state to be slowly-varying with temperature near T{sub c} and consistent in magnitude with normal state values. This result is in agreement with theoretical predictions of thermoelectric effects in superconductors but contrary to previous experimental results obtained by other methods.

  17. Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine

    Broader source: Energy.gov (indexed) [DOE]

    Powered Vehicle | Department of Energy Describes TEG systems built at MSU to mitigate couple failures and a cost-benefit analysis for a system used as an energy recovery system … auxiliary power unit in an over-the-road truck system. schock.pdf (2.64 MB) More Documents & Publications Thermoelectric Conversion of Wate

  18. Influence of germanium nano-inclusions on the thermoelectric power factor of bulk bismuth telluride alloy

    SciTech Connect (OSTI)

    Satyala, Nikhil; Zamanipour, Zahra; Norouzzadeh, Payam; Krasinski, Jerzy S.; Vashaee, Daryoosh; Tahmasbi Rad, Armin; Tayebi, Lobat

    2014-05-28

    Nanocomposite thermoelectric compound of bismuth telluride (Bi{sub 2}Te{sub 3}) with 5 at. % germanium nano-inclusions was prepared via mechanically alloying and sintering techniques. The influence of Ge nano-inclusions and long duration annealing on the thermoelectric properties of nanostructured Bi{sub 2}Te{sub 3} were investigated. It was found that annealing has significant effect on the carrier concentration, Seebeck coefficient, and the power factor of the thermoelectric compound. The systematic heat treatment also reduced the density of donor type defects thereby decreasing the electron concentration. While the as-pressed nanocomposite materials showed n-type properties, it was observed that with the increase of annealing time, the nanocomposite gradually transformed to an abundantly hole-dominated (p-type) sample. The long duration annealing (∼500 h) resulted in a significantly enhanced electrical conductivity pertaining to the augmentation in the density and the structural properties of the sample. Therefore, a simultaneous enhancement in both electrical and Seebeck coefficient characteristics resulted in a remarkable increase in the thermoelectric power factor.

  19. Pulse detecting device

    DOE Patents [OSTI]

    Riggan, W.C.

    1984-01-01

    A device for measuring particle flux comprises first and second photodiode detectors for receiving flux from a source and first and second outputs for producing first and second signals representing the flux incident to the detectors. The device is capable of reducing the first output signal by a portion of the second output signal, thereby enhancing the accuracy of the device. Devices in accordance with the invention may measure distinct components of flux from a single source or fluxes from several sources.

  20. Pulse flux measuring device

    DOE Patents [OSTI]

    Riggan, William C.

    1985-01-01

    A device for measuring particle flux comprises first and second photodiode detectors for receiving flux from a source and first and second outputs for producing first and second signals representing the flux incident to the detectors. The device is capable of reducing the first output signal by a portion of the second output signal, thereby enhancing the accuracy of the device. Devices in accordance with the invention may measure distinct components of flux from a single source or fluxes from several sources.