National Library of Energy BETA

Sample records for thermal deposition cxs

  1. Ion beam assisted deposition of thermal barrier coatings

    DOE Patents [OSTI]

    Youchison, Dennis L.; McDonald, Jimmie M.; Lutz, Thomas J.; Gallis, Michail A.

    2010-11-23

    Methods and apparatus for depositing thermal barrier coatings on gas turbine blades and vanes using Electron Beam Physical Vapor Deposition (EBPVD) combined with Ion Beam Assisted Deposition (IBAD).

  2. Deposition of Graded Thermal Barrier Coatings for Gas Turbine...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Deposition of Graded Thermal Barrier Coatings for Gas Turbine Blades Sandia National Laboratories Contact SNL About This Technology ...

  3. Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation

    SciTech Connect (OSTI)

    Nitin Padture

    2011-12-31

    Ceramic thermal barrier coatings (TBCs) used in gas-turbine engines afford higher operating temperatures, resulting in enhanced efficiencies and performance. However, in the case of syngas-fired engines, fly ash particulate impurities that may be present in syngas can melt on the hotter TBC surfaces and form glassy deposits. These deposits can penetrate the TBCs leading to their failure. In experiments using lignite fly ash to simulate these conditions we show that conventional TBCs of composition 93wt% ZrO{sub 2} + 7wt% Y{sub 2}O{sub 3} (7YSZ) fabricated using the air plasma spray (APS) process are completely destroyed by the molten fly ash. The molten fly ash is found to penetrate the full thickness of the TBC. The mechanisms by which this occurs appear to be similar to those observed in degradation of 7YSZ TBCs by molten calcium-magnesium-aluminosilicate (CMAS) sand and by molten volcanic ash in aircraft engines. In contrast, APS TBCs of Gd{sub 2Zr{sub 2}O{sub 7} composition are highly resistant to attack by molten lignite fly ash under identical conditions, where the molten ash penetrates ~25% of TBC thickness. This damage mitigation appears to be due to the formation of an impervious, stable crystalline layer at the fly ash/Gd{sub 2}Zr{sub 2}O{sub 7} TBC interface arresting the penetrating moltenfly- ash front. Additionally, these TBCs were tested using a rig with thermal gradient and simultaneous accumulation of ash. Modeling using an established mechanics model has been performed to illustrate the modes of delamination, as well as further opportunities to optimize coating microstructure. Transfer of the technology was developed in this program to all interested parties.

  4. Thermal conductivity of nitride films of Ti, Cr, and W deposited by reactive magnetron sputtering

    SciTech Connect (OSTI)

    Jagannadham, Kasichainula

    2015-05-15

    Nitride films of Ti, Cr, and W were deposited using reactive magnetron sputtering from metal targets in argon and nitrogen plasma. TiN films with (200) orientation were achieved on silicon (100) at the substrate temperature of 500 and 600?C. The films were polycrystalline at lower temperature. An amorphous interface layer was observed between the TiN film and Si wafer deposited at 600?C. TiN film deposited at 600?C showed the nitrogen to Ti ratio to be near unity, but films deposited at lower temperature were nitrogen deficient. CrN film with (200) orientation and good stoichiometry was achieved at 600?C on Si(111) wafer but the film deposited at 500?C showed cubic CrN and hexagonal Cr{sub 2}N phases with smaller grain size and amorphous back ground in the x-ray diffraction pattern. An amorphous interface layer was not observed in the cubic CrN film on Si(111) deposited at 600?C. Nitride film of tungsten deposited at 600?C on Si(100) wafer was nitrogen deficient, contained both cubic W{sub 2}N and hexagonal WN phases with smaller grain size. Nitride films of tungsten deposited at 500?C were nonstoichiometric and contained cubic W{sub 2}N and unreacted W phases. There was no amorphous phase formed along the interface for the tungsten nitride film deposited at 600?C on the Si wafer. Thermal conductivity and interface thermal conductance of all the nitride films of Ti, Cr, and W were determined by transient thermoreflectance technique. The thermal conductivity of the films as function of deposition temperature, microstructure, nitrogen stoichiometry and amorphous interaction layer at the interface was determined. Tungsten nitride film containing both cubic and hexagonal phases was found to exhibit much higher thermal conductivity and interface thermal conductance. The amorphous interface layer was found to reduce effective thermal conductivity of TiN and CrN films.

  5. In-situ formation of multiphase deposited thermal barrier coatings

    DOE Patents [OSTI]

    Subramanian, Ramesh

    2004-01-13

    A multiphase ceramic thermal barrier coating is provided. The coating is adapted for use in high temperature applications in excess of about 1200.degree. C., for coating superalloy components of a combustion turbine engine. The coating comprises a ceramic single or two oxide base layer disposed on the substrate surface; and a ceramic oxide reaction product material disposed on the base layer, the reaction product comprising the reaction product of the base layer with a ceramic single or two oxide overlay layer.

  6. Uncooled thin film infrared imaging device with aerogel thermal isolation: Deposition and planarization techniques

    SciTech Connect (OSTI)

    Ruffner, J.A.; Clem, P.G.; Tuttle, B.A.; Brinker, C.J. [Sandia National Labs., Albuquerque, NM (United States); Sriram, C.S. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemical and Nuclear Engineering; Bullington, J.A. [AMMPEC, Inc., Albuquerque, NM (United States)

    1998-04-01

    The authors have successfully integrated a thermally insulating silica aerogel thin film into a new uncooled monolithic thin film infrared (IR) imaging device. Compared to other technologies (bulk ceramic and microbridge), use of an aerogel layer provides superior thermal isolation of the pyroelectric imaging element from the relatively massive heat sinking integrated circuit. This results in significantly higher thermal and temporal resolutions. They have calculated noise equivalent temperature differences of 0.04--0.10 C from a variety of Pb{sub x}Zr{sub y}Ti{sub 1{minus}y}O{sub 3} (PZT) and Pb{sub x}La{sub 1{minus}x}Zr{sub y}Ti{sub 1{minus}y}O{sub 3} (PLZT) pyroelectric imaging elements in monolithic structures. In addition, use of aerogels results in an easier, less expensive fabrication process and a more robust device. Fabrication of these monolithic devices entails sol-gel deposition of the aerogel, sputter deposition of the electrodes, and solution chemistry deposition of the pyroelectric imaging elements. Uniform pyroelectric response is achieved across the device by use of appropriate planarization techniques. These deposition and planarization techniques are described. Characterization of the individual layers and monolithic structure using scanning electron microscopy, atomic force microscopy and Byer-Roundy techniques also is discussed.

  7. Thermal behavior of spiral fin-and-tube heat exchanger having fly ash deposit

    SciTech Connect (OSTI)

    Nuntaphan, Atipoang; Kiatsiriroat, Tanongkiat

    2007-08-15

    This research investigates the effect of fly-ash deposit on thermal performance of a cross-flow heat exchanger having a set of spiral finned-tubes as a heat transfer surface. A stream of warm air having high content of fly-ash is exchanging heat with a cool water stream in the tubes. In this study, the temperature of the heat exchanger surface is lower than the dew point temperature of air, thus there is condensation of moisture in the air stream on the heat exchanger surface. The affecting parameters such as the fin spacing, the air mass flow rate, the fly-ash mass flow rate and the inlet temperature of warm air are varied while the volume flow rate and the inlet temperature of the cold water stream are kept constant at 10 l/min and 5 C, respectively. From the experiment, it is found that as the testing period is shorter than 8 h the thermal resistance due to the fouling increases with time. Moreover, the deposit of fly-ash on the heat transfer surface is directly proportional to the dust-air ratio and the amount of condensate on heat exchange surface. However, the deposit of fly-ash is inversely proportional to the fin spacing. The empirical model for evaluating the thermal resistance is also developed in this work and the simulated results agree well with those of the measured data. (author)

  8. Thermal chemistry of the Cu-KI5 atomic layer deposition precursor on a copper surface

    SciTech Connect (OSTI)

    Ma, Qiang; Zaera, Francisco

    2015-01-01

    The thermal chemistry of a Cu(I) ketoiminate complex, Cu-KI5, resulting from the modification of the known Air Products CupraSelect{sup } copper CVD precursor Cu(hfac)(tmvs) designed to tether the two ligands via an isopropoxide linker, was studied under ultrahigh vacuum on a Cu(110) single-crystal surface by using a combination of temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy. Adsorption at low temperatures was determined to take place via the displacement of the vinyl ligand by the surface. Molecular desorption was seen at 210?K, and the evolution of Cu(II)-KI5{sub 2} was established to take place at 280?K, presumably from a disproportionation reaction that also leads to the deposition of Cu(0). Other sets of desorption products were seen at 150, 250, and 430?K, all containing copper atoms and small organic moieties with molecular masses below 100 amu. The latter TPD peak in particular indicates significant fragmentation of the ligands, likely at the CN bond that holds the vinylsilane-isopropoxide moiety tethered to the ketoimine fragment, and possibly also at the union between the vinylsilane and the alkoxide linker. The 430?K temperature measured for this chemistry may set an upper limit for clean Cu film deposition, but since reactivity on the surface was also found to be inhibited at higher surface coverages, it may be delayed to higher temperatures under atomic layer deposition conditions.

  9. CHEMICALLY VAPOR DEPOSITED YTTRIA-STABILIZED ZIRCONIA (YSZ) FOR THERMAL AND ENVIRONMENTAL BARRIER COATING

    SciTech Connect (OSTI)

    Varanasi, V.G.; Besmann, T.M.; Lothian, J.L.; Xu, W.; Starr, T.L.

    2003-04-22

    Yttria-stabilized zirconia (YSZ) is used as a thermal barrier coating (TBC) to protect super-alloy blades such as Mar-M247 or Rene-N5 during engine operation. The current method for YSZ fabrication for TBC applications is by air-plasma spraying (APS) or electron beam physical vapor deposition (EB-PVD) (Haynes 1997). APS gives reasonable deposition rates, but has a limited life and aging effects due to its porous and lamellar structure. The EB-PVD coatings are more stable and can accommodate thermomechanical stresses due to their characteristic strain-tolerant, columnar microstructure. EB-PVD, however, is primarily line-of-sight, which often leaves ''hidden areas'' uncoated, has low throughput, and has high capital cost. The process of metal-organic chemical vapor deposition (MOCVD) is investigated here as an economical alternative to EB-PVD and APS, with the potential for better overall coverage as well as the ability to produce thick (100-250 {micro}m), strain-tolerant, columnar coatings. MOCVD of YSZ involves the use of zirconium and yttrium organometallic precursors reacting with an oxygen source. Previous researchers have used diketonate or chloride precursors and oxygen (Wahl et al. 2001a, Wahl et al. 2001b, Yamane and Harai 1989). These precursors have low transport rates due to their low carrier solvent solubility (Varanasi et al. 2003). Solvated zirconium and yttrium butoxide precursors were investigated here due to their higher vapor pressures and high solvent solubility. This work uses predictive equilibrium modeling and experiments involving butoxide precursors for tetragonal YSZ fabrication.

  10. An In-Core Power Deposition and Fuel Thermal Environmental Monitor for Long-Lived Reactor Cores

    SciTech Connect (OSTI)

    Don W. Miller

    2004-09-28

    The primary objective of this program is to develop the Constant Temperature Power Sensor (CTPS) as in-core instrumentation that will provide a detailed map of local nuclear power deposition and coolant thermal-hydraulic conditions during the entire life of the core.

  11. COMPARISON OF THERMAL PROPERTIES OF THERMAL BARRIER COATING DEPOSITED ON IN738 USING STANDARD AIR PLASMA SPRAY WITH 100HE PLASMA SPRAY SYSTEM

    SciTech Connect (OSTI)

    Uppu, N.; Mensah, P.F.; Ofori, D.

    2006-07-01

    A typical blade material is made of Nickel super alloy and can bear temperatures up to 950C. But the operating temperature of a gas turbine is above the melting point of super alloy nearly at 1500C. This could lead to hot corrosions, high temperature oxidation, creep, thermal fatigue may takes place on the blade material. Though the turbine has an internal cooling system, the cooling is not adequate to reduce the temperature of the blade substrate. Therefore to protect the blade material as well as increase the efficiency of the turbine, thermal barrier coatings (TBCs) must be used. A TBC coating of 250 ?m thick can reduce the temperature by up to 200 C. Air Plasma Spray Process (APS) and High Enthalpy Plasma Spray Process (100HE) were the processes used for coating the blades with the TBCs. Because thermal conductivity increases with increase in temperature, it is desired that these processes yield very low thermal conductivities at high temperatures in order not to damage the blade. An experiment was carried out using Flash line 5000 apparatus to compare the thermal conductivity of both processes.The apparatus could also be used to determine the thermal diffusivity and specific heat of the TBCs. 75 to 2800 K was the temperature range used in the experimentation. It was found out that though 100HE has high deposition efficiency, the thermal conductivity increases with increase in temperatures whiles APS yielded low thermal conductivities.

  12. Thermally-driven H interaction with HfO{sub 2} films deposited on Ge(100) and Si(100)

    SciTech Connect (OSTI)

    Soares, G. V. Feij, T. O.; Baumvol, I. J. R.; Aguzzoli, C.; Krug, C.; Radtke, C.

    2014-01-27

    In the present work, we investigated the thermally-driven H incorporation in HfO{sub 2} films deposited on Si and Ge substrates. Two regimes for deuterium (D) uptake were identified, attributed to D bonded near the HfO{sub 2}/substrate interface region (at 300?C) and through the whole HfO{sub 2} layer (400600?C). Films deposited on Si presented higher D amounts for all investigated temperatures, as well as, a higher resistance for D desorption. Moreover, HfO{sub 2} films underwent structural changes during annealings, influencing D incorporation. The semiconductor substrate plays a key role in this process.

  13. Thermal stability of sputter-deposited 330 austenitic stainless-steel thin films with nanoscale growth twins

    SciTech Connect (OSTI)

    Zhang, X.; Misra, A.; Wang, H.; Swadener, J.G.; Lima, A.L.; Hundley, M.F.; Hoagland, R.G.

    2005-12-05

    We have explored the thermal stability of nanoscale growth twins in sputter-deposited 330 stainless-steel (SS) films by vacuum annealing up to 500 deg. C. In spite of an average twin spacing of only 4 nm in the as-deposited films, no detectable variation in the twin spacing or orientation of twin interfaces was observed after annealing. An increase in the average columnar grain size was observed after annealing. The hardness of 330 SS films increases after annealing, from 7 GPa for as-deposited films to around 8 GPa for annealed films, while the electrical resistivity decreases slightly after annealing. The changes in mechanical and electrical properties after annealing are interpreted in terms of the corresponding changes in the residual stress and microstructure of the films.

  14. TiO{sub 2} Film Deposition by Atmospheric Thermal Plasma CVD Using Laminar and Turbulence Plasma Jets

    SciTech Connect (OSTI)

    Ando, Yasutaka; Tobe, Shogo [Ashikaga Institute of Technology, 268-1 Omae, Ashikaga, Tochigi 326-8558 (Japan); Tahara, Hirokazu [Osaka Institute of Technology, 5-16-1 Omiya, Asahi-Ku, Osaka 535-8585 (Japan)

    2008-02-21

    In this study, to provide continuous plasma atmosphere on the substrate surface in the case of atmospheric thermal plasma CVD, TiO{sub 2} film deposition by thermal plasma CVD using laminar plasma jet was carried out. For comparison, the film deposition using turbulence plasma jet was conducted as well. Consequently, transition of the plasma jet from laminar to turbulent occurred on the condition of over 3.5 1/min in Ar working gas flow rate and the plasma jet became turbulent on the condition of over 10 1/min. In the case of the turbulent plasma jet use, anatase rich titanium oxide film could be obtained though plasma jet could not contact with the surface of the substrate continuously even on the condition that feedstock material was injected into the plasma jet. On the other hand,, in the case of laminar gas flow rate, the plasma jet could contact with the substrate continuously without melt down of the substrate during film deposition. Besides, titanium oxide film could be obtained even in the case of the laminar plasma jet use. From these results, this technique was thought to have high potential for atmospheric thermal plasma CVD.

  15. Initial growth, refractive index, and crystallinity of thermal and plasma-enhanced atomic layer deposition AlN films

    SciTech Connect (OSTI)

    Van Bui, Hao Wiggers, Frank B.; Gupta, Anubha; Nguyen, Minh D.; Aarnink, Antonius A. I.; Jong, Michel P. de; Kovalgin, Alexey Y.

    2015-01-01

    The authors have studied and compared the initial growth and properties of AlN films deposited on Si(111) by thermal and plasma-enhanced atomic layer deposition (ALD) using trimethylaluminum and either ammonia or a N{sub 2}-H{sub 2} mixture as precursors. In-situ spectroscopic ellipsometry was employed to monitor the growth and measure the refractive index of the films during the deposition. The authors found that an incubation stage only occurred for thermal ALD. The linear growth for plasma-enhanced ALD (PEALD) started instantly from the beginning due to the higher nuclei density provided by the presence of plasma. The authors observed the evolution of the refractive index of AlN during the growth, which showed a rapid increase up to a thickness of about 30?nm followed by a saturation. Below this thickness, higher refractive index values were obtained for AlN films grown by PEALD, whereas above that the refractive index was slightly higher for thermal ALD films. X-ray diffraction characterization showed a wurtzite crystalline structure with a (101{sup }0) preferential orientation obtained for all the layers with a slightly better crystallinity for films grown by PEALD.

  16. Thermal and plasma enhanced atomic layer deposition of TiO{sub 2}: Comparison of spectroscopic and electric properties

    SciTech Connect (OSTI)

    Das, Chittaranjan Henkel, Karsten; Tallarida, Massimo; Schmeißer, Dieter; Gargouri, Hassan; Kärkkänen, Irina; Schneidewind, Jessica; Gruska, Bernd; Arens, Michael

    2015-01-15

    Titanium oxide (TiO{sub 2}) deposited by atomic layer deposition (ALD) is used as a protective layer in photocatalytic water splitting system as well as a dielectric in resistive memory switching. The way ALD is performed (thermally or plasma-assisted) may change the growth rate as well as the electronic properties of the deposited films. In the present work, the authors verify the influence of the ALD mode on functional parameters, by comparing the growth rate and electronic properties of TiO{sub 2} films deposited by thermal (T-) and plasma-enhanced (PE-) ALD. The authors complete the study with the electrical characterization of selected samples by means of capacitance–voltage and current–voltage measurements. In all samples, the authors found a significant presence of Ti{sup 3+} states, with the lowest content in the PE-ALD grown TiO{sub 2} films. The observation of Ti{sup 3+} states was accompanied by the presence of in-gap states above the valence band maximum. For films thinner than 10 nm, the authors found also a strong leakage current. Also in this case, the PE-ALD films showed the weakest leakage currents, showing a correlation between the presence of Ti{sup 3+} states and leakage current density.

  17. Density dependence of the room temperature thermal conductivity of atomic layer deposition-grown amorphous alumina (Al{sub 2}O{sub 3})

    SciTech Connect (OSTI)

    Gorham, Caroline S.; Gaskins, John T.; Hopkins, Patrick E.; Parsons, Gregory N.; Losego, Mark D.

    2014-06-23

    We report on the thermal conductivity of atomic layer deposition-grown amorphous alumina thin films as a function of atomic density. Using time domain thermoreflectance, we measure the thermal conductivity of the thin alumina films at room temperature. The thermal conductivities vary ?35% for a nearly 15% change in atomic density and are substrate independent. No density dependence of the longitudinal sound speeds is observed with picosecond acoustics. The density dependence of the thermal conductivity agrees well with a minimum limit to thermal conductivity model that is modified with a differential effective-medium approximation.

  18. Post-deposition control of ferroelastic stripe domains and internal electric field by thermal treatment

    SciTech Connect (OSTI)

    Feigl, L.; Iwanowska, M.; Sandu, C. S.; Setter, N.; Janolin, P.-E.; Yamada, T.

    2015-01-19

    The dependence of the formation of ferroelastic stripe domain patterns on the thermal history is investigated by detailed piezoresponse force microscopy and X-ray diffraction experiments after and during annealing of tensile strained tetragonal Pb(Ti,Zr)O{sub 3} epitaxial thin films on DyScO{sub 3} substrates. In particular, the ferroelastic pattern is reversibly interchanged between a cross-hatched and a stripe domain pattern if the films are cooled at different rates after annealing above the formation temperature of a-domains. Different types of 180 and non-180 patterns can be created, depending on the thermal treatment. The changes in the 180 domain structure and lattice parameters are attributed to a change of oxygen vacancy concentration, which results in a modification of the internal electric field and unit cell size, causing also a shift of T{sub C}. Thermal treatment is done on rhombohedral La:BiFeO{sub 3} thin films as well. It is observed that also in these films, appropriate heat treatment modifies the domain pattern and films with a stripe domain pattern can be created, confirming the general validity of the developed model.

  19. Simplified models of growth, defect formation, and thermal conductivity in diamond chemical vapor deposition

    SciTech Connect (OSTI)

    Coltrin, M.E.; Dandy, D.S.

    1996-04-01

    A simplified surface reaction mechanism is presented for the CVD of diamond thin films. The mechanism also accounts for formation of point defects in the diamond lattice, an alternate, undesirable reaction pathway. Both methyl radicals and atomic C are considered as growth precursors. While not rigorous in all details, the mechanism is useful in describing the CVD diamond process over a wide range of reaction conditions. It should find utility in reactor modeling studies, for example in optimizing diamond growth rate while minimizing defect formation. This report also presents a simple model relating the diamond point-defect density to the thermal conductivity of the material.

  20. Glass-Like Thermal Conductivity of (010)-Textured Lanthanum-Doped Strontium Niobate Synthesized with Wet Chemical Deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Foley, Brian M.; Brown-Shaklee, Harlan J.; Campion, Michael J.; Medlin, Douglas L.; Clem, Paul G.; Ihlefeld, Jon F.; Hopkins, Patrick E.

    2014-11-08

    We have measured the cross-plane thermal conductivity (κ) of (010)-textured, undoped, and lanthanum-doped strontium niobate (Sr2-xLaxNb2O7-δ) thin films via time-domain thermoreflectance. Then the thin films were deposited on (001)-oriented SrTiO3 substrates via the highly-scalable technique of chemical solution deposition. We find that both film thickness and lanthanum doping have little effect on κ, suggesting that there is a more dominant phonon scattering mechanism present in the system; namely the weak interlayer-bonding along the b-axis in the Sr2Nb2O7 parent structure. We also compare our experimental results with two variations of the minimum-limit model for κ and discuss the nature of transportmore » in material systems with weakly-bonded layers. The low cross-plane κ of these scalably-fabricated films is comparable to that of similarly layered niobate structures grown epitaxially.« less

  1. Reaction kinetics during the thermal activation of the silicon surface passivation with atomic layer deposited Al{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Richter, Armin Benick, Jan; Hermle, Martin; Glunz, Stefan W.

    2014-02-10

    The excellent surface passivation of crystalline silicon provided by Al{sub 2}O{sub 3} requires always an activation by a thermal post-deposition treatment. In this work, we present an indirect study of the reaction kinetics during such thermal activation treatments for Al{sub 2}O{sub 3} synthesized by atomic layer deposition. The study was performed for Al{sub 2}O{sub 3} deposited at varying temperatures, which results in different micro-structures of the films and, in particular, different hydrogen concentrations. The effective carrier lifetime was measured sequentially as a function of the annealing time and temperature. From these data, the reaction rate R{sub act} and the activation energy E{sub A} were extracted. The results revealed a rather constant E{sub A} in the range of 1.4 to 1.5?eV, independent of the deposition temperature. The reaction rate, however, was found to increase with decreasing deposition temperature, which correlates with an increasing amount of hydrogen being incorporated in the Al{sub 2}O{sub 3} films. This is a strong indication for an interface hydrogenation that takes place during the thermal activation, which is limited by the amount of hydrogen provided by the Al{sub 2}O{sub 3} layer.

  2. On the thermal stability of physical vapor deposited oxide-hardened nanocrystalline gold thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Argibay, Nicolas; Mogonye, J. E.; Michael, Joseph R.; Goeke, Ronald S.; Kotula, Paul G.; Scharf, T. W.; Dugger, Michael Thomas; Prasad, Somuri V.

    2015-04-08

    We describe a correlation between electrical resistivity and grain size for PVD synthesized polycrystalline oxide-hardened metal-matrix thin films in oxide-dilute (<5 vol. % oxide phase) compositions. The correlation is based on the Mayadas-Shatzkes (M-S) electron scattering model, predictive of grain size evolution as a function of composition in the oxide-dilute regime for 2 μm thick Au-ZnO films. We describe a technique to investigate grain boundary (GB) mobility and the thermal stability of GBs based on in situelectrical resistivity measurements during annealing experiments, interpreted using a combination of the M-S model and the Michels et al. model describing solute drag stabilizedmore » grain growth kinetics. Using this technique, activation energy and pre-exponential Arrhenius parameter values of Ea = 21.6 kJ/mol and Ao = 2.3 × 10-17 m2/s for Au-1 vol. % ZnO and Ea =12.7 kJ/mol and Ao = 3.1 × 10-18 m2/s for Au-2 vol.% ZnO were determined. In the oxide-dilute regime, the grain size reduction of the Au matrix yielded a maximum hardness of 2.6 GPa for 5 vol. % ZnO. A combined model including percolation behavior and grain refinement is presented that accurately describes the composition dependent change in electrical resistivity throughout the entire composition range for Au-ZnO thin films. As a result, the proposed correlations are supported by microstructural characterization using transmission electron microscopy and electron diffraction mapping for grain size determination.« less

  3. On the thermal stability of physical vapor deposited oxide-hardened nanocrystalline gold thin films

    SciTech Connect (OSTI)

    Argibay, Nicolas; Mogonye, J. E.; Michael, Joseph R.; Goeke, Ronald S.; Kotula, Paul G.; Scharf, T. W.; Dugger, Michael Thomas; Prasad, Somuri V.

    2015-04-08

    We describe a correlation between electrical resistivity and grain size for PVD synthesized polycrystalline oxide-hardened metal-matrix thin films in oxide-dilute (<5 vol. % oxide phase) compositions. The correlation is based on the Mayadas-Shatzkes (M-S) electron scattering model, predictive of grain size evolution as a function of composition in the oxide-dilute regime for 2 ?m thick Au-ZnO films. We describe a technique to investigate grain boundary (GB) mobility and the thermal stability of GBs based on in situelectrical resistivity measurements during annealing experiments, interpreted using a combination of the M-S model and the Michels et al. model describing solute drag stabilized grain growth kinetics. Using this technique, activation energy and pre-exponential Arrhenius parameter values of Ea = 21.6 kJ/mol and Ao = 2.3 1017 m2/s for Au-1 vol. % ZnO and Ea =12.7 kJ/mol and Ao = 3.1 1018 m2/s for Au-2 vol.% ZnO were determined. In the oxide-dilute regime, the grain size reduction of the Au matrix yielded a maximum hardness of 2.6 GPa for 5 vol. % ZnO. A combined model including percolation behavior and grain refinement is presented that accurately describes the composition dependent change in electrical resistivity throughout the entire composition range for Au-ZnO thin films. As a result, the proposed correlations are supported by microstructural characterization using transmission electron microscopy and electron diffraction mapping for grain size determination.

  4. Microstructural Evolution of EGR Cooler Deposits

    Broader source: Energy.gov [DOE]

    Characterize the thermo-physical properties of the deposit under different operating conditions on model EGR cooler tube and determine the long-term changes in deposit properties due to thermal cycling and water/HC condensation

  5. DEGRADATION OF SM2ZR2O7 THERMAL BARRIER COATING CAUSED BY CALCIUM-MAGNESIUM-ALUMINUM-SILICON OXIDE (CMAS) DEPOSITION

    SciTech Connect (OSTI)

    Wang, Honglong; Sheng, Zhizhi; Tarwater, Emily; Zhang, Xingxing; Dasgupta, Sudip; Fergus, Jeffrey

    2015-03-16

    Rare earth zirconates are promising materials for use as thermal barrier coatings in gas turbine engines. Among the lanthanide zirconate materials, Sm2Zr2O7 with the pyrochlore structure has lower thermal conductivity and better corrosion resistance against calcium-magnesium-aluminum-silicon oxide (CMAS). In this work, after reaction with CMAS, the pyrochlore structure transforms to the cubic fluorite structure and Ca2Sm8(SiO4)6O2 forms in elongated grain.

  6. Momentum Deposition in Curvilinear Coordinates

    SciTech Connect (OSTI)

    Cleveland, Mathew Allen; Lowrie, Robert Byron; Rockefeller, Gabriel M.; Thompson, Kelly Glen; Wollaber, Allan Benton

    2015-08-03

    The momentum imparted into a material by thermal radiation deposition is an important physical process in astrophysics and inertial confinement fusion (ICF) simulations. In recent work we presented a new method of evaluating momentum deposition that relies on the combination of a time-averaged approximation and a numerical integration scheme. This approach robustly and efficiently evaluates the momentum deposition in spherical geometry. Future work will look to extend this approach to 2D cylindrical geometries.

  7. Correlations between 1/f noise and thermal treatment of Al-doped ZnO thin films deposited by direct current sputtering

    SciTech Connect (OSTI)

    Barhoumi, A. Guermazi, S.; Leroy, G.; Gest, J.; Carru, J. C.; Yang, L.; Boughzala, H.; Duponchel, B.

    2014-05-28

    Al-doped ZnO thin films (AZO) have been deposited on amorphous glass substrates by DC sputtering at different substrate temperatures T{sub s}. X-Ray diffraction results reveal that AZO thin films have a hexagonal wurtzite structure with (002) preferred orientation. (002) peaks indicate that the crystalline structure of the films is oriented with c-axis perpendicular to the substrate. Three-dimensional (3D) atomic force microscopy images of AZO thin films deposited on glass substrate at 200?C, 300?C, and 400?C, respectively, shows the improvement of the crystallinity and the homogeneity of AZO thin films with T{sub s} which is in agreement with the noise measurements. The noise was characterized between 1?Hz and 100?kHz and we have obtained 1/f spectra. The noise is very sensitive to the crystal structure especially to the orientation of the crystallites which is perpendicular to the substrate and to the grain boundaries which generate a high current flow and a sharp increase in noise. Through time, R{sub sh} and [??]{sub eff} increase with the modification of the crystallinity of AZO thin films. Study of noise aging shows that the noise is more sensitive than resistivity for all AZO thin films.

  8. Investigation of the deposition and thermal behavior of striped phases of unsymmetric disulfide self-assembled monolayers on Au(111): The case of 11-hydroxyundecyl decyl disulfide

    SciTech Connect (OSTI)

    Albayrak, Erol; Karabuga, Semistan; Bracco, Gianangelo; Dan??man, M. Fatih

    2015-01-07

    Self-assembled monolayers (SAMs) of unsymmetric disulfides on Au(111) are used to form mixed SAMs that can be utilized in many applications. Here, we have studied 11-hydroxyundecyl decyl disulfide (CH{sub 3}(CH{sub 2}){sub 9}SS(CH{sub 2}){sub 11}OH, HDD) SAMs produced by supersonic molecular beam deposition and characterized by He diffraction. The film growth was monitored at different temperatures up to a coverage which corresponds to a full lying down phase and the diffraction analysis shows that below 250 K the phase is different from the phase measured above 300 K. During the annealing of the film, two phase transitions were observed, at 250 K and 350 K. The overall data suggest that the former is related to an irreversible phase separation of HDD above 250 K to decanethiolate (S(CH{sub 2}){sub 9}CH{sub 3}, DTT) and hydroxyundecylthiolate (S(CH{sub 2}){sub 11}OH, MUDT), while the latter to a reversible melting of the film. Above 450 K, the specular intensity shows an increase related to film desorption and different chemisorbed states were observed with energies in the same range as observed for decanethiol (HS(CH{sub 2}){sub 9}CH{sub 3}, DT) and mercaptoundecanol (HS(CH{sub 2}){sub 11}OH, MUD) SAMs.

  9. Analysis Of Hot Springs And Associated Deposits In Yellowstone...

    Open Energy Info (EERE)

    Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and the Airborne VisibleIR Image Spectrometer (AVIRIS) data were used to characterize hot spring deposits in the...

  10. Deposited films with improved microstructures

    DOE Patents [OSTI]

    Patten, James W.; Moss, Ronald W.; McClanahan, Edwin D.

    1984-01-01

    Methods for improving microstructures of line-of-sight deposited films are described. Columnar growth defects ordinarily produced by geometrical shadowing during deposition of such films are eliminated without resorting to post-deposition thermal or mechanical treatments. The native, as-deposited coating qualities, including homogeneity, fine grain size, and high coating-to-substrate adherence, can thus be retained. The preferred method includes the steps of emitting material from a source toward a substrate to deposit a coating non-uniformly on the substrate surface, removing a portion of the coating uniformly over the surface, again depositing material onto the surface, but from a different direction, and repeating the foregoing steps. The quality of line-of-sight deposited films such as those produced by sputtering, progressively deteriorates as the angle of incidence between the flux and the surface becomes increasingly acute. Depositing non-uniformly, so that the coating becomes progressively thinner as quality deteriorates, followed by uniformly removing some of the coating, such as by resputtering, eliminates the poor quality portions, leaving only high quality portions of the coating. Subsequently sputtering from a different direction applies a high quality coating to other regions of the surface. Such steps can be performed either simultaneously or sequentially to apply coatings of a uniformly high quality, closed microstructure to three-dimensional or large planar surfaces.

  11. mhtml:file://H:\CATX\APPROVED-CXS\EERE FOA 1201 - Rankine Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . ., . . BNL-68599 PRODUCTION OF RADIOACTIVE IODINE David J. Schlyer Iodine-123 Probably the most 'widely used cyclotron produced radiohalogen is 1-123. It has gradually replaced I-13 1 as the isotope of choice for diagnostic radiopharmaceuticals containing radioiodine. It gives a much lower radiation dose to the patient and the gamma ray energy of 159 keV is ideally suited for use in a gamma camera. The gamma ray will penetrate tissue very effectively without excessive radiation dose. For this

  12. Ceramic thermal barrier coating for rapid thermal cycling applications

    DOE Patents [OSTI]

    Scharman, Alan J.; Yonushonis, Thomas M.

    1994-01-01

    A thermal barrier coating for metal articles subjected to rapid thermal cycling includes a metallic bond coat deposited on the metal article, at least one MCrAlY/ceramic layer deposited on the bond coat, and a ceramic top layer deposited on the MCrAlY/ceramic layer. The M in the MCrAlY material is Fe, Ni, Co, or a mixture of Ni and Co. The ceramic in the MCrAlY/ceramic layer is mullite or Al.sub.2 O.sub.3. The ceramic top layer includes a ceramic with a coefficient of thermal expansion less than about 5.4.times.10.sup.-6 .degree.C.sup.-1 and a thermal conductivity between about 1 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1 and about 1.7 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1.

  13. Formation of amorphous metal alloys by chemical vapor deposition

    DOE Patents [OSTI]

    Mullendore, A.W.

    1988-03-18

    Amorphous alloys are deposited by a process of thermal dissociation of mixtures of organometallic compounds and metalloid hydrides,e.g., transition metal carbonyl, such as nickel carbonyl and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit. 1 fig.

  14. Formation of amorphous metal alloys by chemical vapor deposition

    DOE Patents [OSTI]

    Mullendore, Arthur W.

    1990-01-01

    Amorphous alloys are deposited by a process of thermal dissociation of mixtures or organometallic compounds and metalloid hydrides, e.g., transition metal carbonyl such as nickel carbonyl, and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit.

  15. NREL: Process Development and Integration Laboratory - Materials Deposition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Device Fabrication in the Atmospheric Processing Platform Materials Deposition and Device Fabrication in the Atmospheric Processing Platform This page provides details on materials deposition and device fabrication in the Atmospheric Processing platform. The four techniques highlighted are robotic inkjet printing, large-area ultrasonic spray deposition, sputtering, and thermal evaporator deposition. Photo of the shiny back of the glove box behind a close-up of an unenclosed inkjet

  16. Hydrocarbon and Deposit Morphology Effects on EGR Cooler Deposit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Deposit Morphology Effects on EGR Cooler Deposit Stability and Removal Hydrocarbon and Deposit Morphology Effects on EGR Cooler Deposit Stability and Removal This paper reports ...

  17. Deposition head for laser

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    1999-01-01

    A deposition head for use as a part of apparatus for forming articles from materials in particulate form in which the materials are melted by a laser beam and deposited at points along a tool path to form an article of the desired shape and dimensions. The deposition head delivers the laser beam and powder to a deposition zone, which is formed at the tip of the deposition head. A controller comprised of a digital computer directs movement of the deposition zone along the tool path and provides control signals to adjust apparatus functions, such as the speed at which the deposition head moves along the tool path.

  18. Advanced Thermally Stable Jet Fuels

    SciTech Connect (OSTI)

    A. Boehman; C. Song; H. H. Schobert; M. M. Coleman; P. G. Hatcher; S. Eser

    1998-01-01

    The Penn State program in advanced thermally stable jet fuels has five components: 1) development of mechanisms of degradation and solids formation; 2) quantitative measurement of growth of sub-micrometer and micrometer-sized particles during thermal stressing; 3) characterization of carbonaceous deposits by various instrumental and microscopic methods; 4) elucidation of the role of additives in retarding the formation of carbonaceous solids; and 5) assessment of the potential of producing high yields of cycloalkanes and hydroaromatics from coal.

  19. direct_deposit_111609

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PROTECT YOUR BANKING INFORMATION: DO NOT complete this form until you are ready to submit it to the Payroll Department. DIRECT DEPOSIT REQUEST Directions: 1. Provide required information neatly, legibly; 2. If Checking Account Direct Deposit, include a voided check. a. DO NOT submit a deposit slip! 3. If Savings Account Direct Deposit, include a copy of savings card. 4. Sign this form; 5. Inter-office mail it to Craft Payroll at "P238." DIRECT DEPOSITION AUTHORIZATION I hereby

  20. Thermal Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Sciences NETL's Thermal Sciences competency provides the scientific, engineering, and technology development community with innovative and efficient approaches to measure, harness, and convert thermal energy. Research includes sensors, advanced energy concepts, and thermodynamic optimization, specifically: Sensors and Diagnostics Advanced sensor and diagnostic technology to develop and evaluate advanced methods for non-intrusive measurement and measurement in extreme environments.

  1. Molybdenum enhanced low-temperature deposition of crystalline silicon nitride

    DOE Patents [OSTI]

    Lowden, Richard A.

    1994-01-01

    A process for chemical vapor deposition of crystalline silicon nitride which comprises the steps of: introducing a mixture of a silicon source, a molybdenum source, a nitrogen source, and a hydrogen source into a vessel containing a suitable substrate; and thermally decomposing the mixture to deposit onto the substrate a coating comprising crystalline silicon nitride containing a dispersion of molybdenum silicide.

  2. Process for depositing Cr-bearing layer

    DOE Patents [OSTI]

    Ellis, Timothy W.; Lograsso, Thomas A.; Eshelman, Mark A.

    1995-05-09

    A method of applying a Cr-bearing layer to a substrate, comprises introducing an organometallic compound, in vapor or solid powder form entrained in a carrier gas to a plasma of an inductively coupled plasma torch or device to thermally decompose the organometallic compound and contacting the plasma and the substrate to be coated so as to deposit the Cr-bearing layer on the substrate. A metallic Cr, Cr alloy or Cr compound such as chromium oxide, nitride and carbide can be provided on the substrate. Typically, the organometallic compound is introduced to an inductively coupled plasma torch that is disposed in ambient air so to thermally decompose the organometallic compound in the plasma. The plasma is directed at the substrate to deposit the Cr-bearing layer or coating on the substrate.

  3. Process for depositing Cr-bearing layer

    DOE Patents [OSTI]

    Ellis, T.W.; Lograsso, T.A.; Eshelman, M.A.

    1995-05-09

    A method of applying a Cr-bearing layer to a substrate, comprises introducing an organometallic compound, in vapor or solid powder form entrained in a carrier gas to a plasma of an inductively coupled plasma torch or device to thermally decompose the organometallic compound and contacting the plasma and the substrate to be coated so as to deposit the Cr-bearing layer on the substrate. A metallic Cr, Cr alloy or Cr compound such as chromium oxide, nitride and carbide can be provided on the substrate. Typically, the organometallic compound is introduced to an inductively coupled plasma torch that is disposed in ambient air so to thermally decompose the organometallic compound in the plasma. The plasma is directed at the substrate to deposit the Cr-bearing layer or coating on the substrate. 7 figs.

  4. Supplemental heating of deposition tooling shields

    DOE Patents [OSTI]

    Ohlhausen, James A. (Albuquerque, NM); Peebles, Diane E. (Albuquerque, NM); Hunter, John A. (Albuquerque, NM); Eckelmeyer, Kenneth H. (Albuquerque, NM)

    2000-01-01

    A method of reducing particle generation from the thin coating deposited on the internal surfaces of a deposition chamber which undergoes temperature variation greater than 100.degree. C. comprising maintaining the temperature variation of the internal surfaces low enough during the process cycle to keep thermal expansion stresses between the coating and the surfaces under 500 MPa. For titanium nitride deposited on stainless steel, this means keeping temperature variations under approximately 70.degree. C. in a chamber that may be heated to over 350.degree. C. during a typical processing operation. Preferably, a supplemental heater is mounted behind the upper shield and controlled by a temperature sensitive element which provides feedback control based on the temperature of the upper shield.

  5. Radionuclide deposition control

    DOE Patents [OSTI]

    Brehm, William F.; McGuire, Joseph C.

    1980-01-01

    The deposition of radionuclides manganese-54, cobalt-58 and cobalt-60 from liquid sodium coolant is controlled by providing surfaces of nickel or high nickel alloys to extract the radionuclides from the liquid sodium, and by providing surfaces of tungsten, molybdenum or tantalum to prevent or retard radionuclide deposition.

  6. Nanostructure templating using low temperature atomic layer deposition

    DOE Patents [OSTI]

    Grubbs, Robert K.; Bogart, Gregory R.; Rogers, John A.

    2011-12-20

    Methods are described for making nanostructures that are mechanically, chemically and thermally stable at desired elevated temperatures, from nanostructure templates having a stability temperature that is less than the desired elevated temperature. The methods comprise depositing by atomic layer deposition (ALD) structural layers that are stable at the desired elevated temperatures, onto a template employing a graded temperature deposition scheme. At least one structural layer is deposited at an initial temperature that is less than or equal to the stability temperature of the template, and subsequent depositions made at incrementally increased deposition temperatures until the desired elevated temperature stability is achieved. Nanostructure templates include three dimensional (3D) polymeric templates having features on the order of 100 nm fabricated by proximity field nanopatterning (PnP) methods.

  7. Solution deposition assembly

    DOE Patents [OSTI]

    Roussillon, Yann; Scholz, Jeremy H; Shelton, Addison; Green, Geoff T; Utthachoo, Piyaphant

    2014-01-21

    Methods and devices are provided for improved deposition systems. In one embodiment of the present invention, a deposition system is provided for use with a solution and a substrate. The system comprises of a solution deposition apparatus; at least one heating chamber, at least one assembly for holding a solution over the substrate; and a substrate curling apparatus for curling at least one edge of the substrate to define a zone capable of containing a volume of the solution over the substrate. In another embodiment of the present invention, a deposition system for use with a substrate, the system comprising a solution deposition apparatus; at heating chamber; and at least assembly for holding solution over the substrate to allow for a depth of at least about 0.5 microns to 10 mm.

  8. Advanced thermally stable jet fuels

    SciTech Connect (OSTI)

    Schobert, H.H.

    1999-01-31

    The Pennsylvania State University program in advanced thermally stable coal-based jet fuels has five broad objectives: (1) Development of mechanisms of degradation and solids formation; (2) Quantitative measurement of growth of sub-micrometer and micrometer-sized particles suspended in fuels during thermal stressing; (3) Characterization of carbonaceous deposits by various instrumental and microscopic methods; (4) Elucidation of the role of additives in retarding the formation of carbonaceous solids; (5) Assessment of the potential of production of high yields of cycloalkanes by direct liquefaction of coal. Future high-Mach aircraft will place severe thermal demands on jet fuels, requiring the development of novel, hybrid fuel mixtures capable of withstanding temperatures in the range of 400--500 C. In the new aircraft, jet fuel will serve as both an energy source and a heat sink for cooling the airframe, engine, and system components. The ultimate development of such advanced fuels requires a thorough understanding of the thermal decomposition behavior of jet fuels under supercritical conditions. Considering that jet fuels consist of hundreds of compounds, this task must begin with a study of the thermal degradation behavior of select model compounds under supercritical conditions. The research performed by The Pennsylvania State University was focused on five major tasks that reflect the objectives stated above: Task 1: Investigation of the Quantitative Degradation of Fuels; Task 2: Investigation of Incipient Deposition; Task 3: Characterization of Solid Gums, Sediments, and Carbonaceous Deposits; Task 4: Coal-Based Fuel Stabilization Studies; and Task 5: Exploratory Studies on the Direct Conversion of Coal to High Quality Jet Fuels. The major findings of each of these tasks are presented in this executive summary. A description of the sub-tasks performed under each of these tasks and the findings of those studies are provided in the remainder of this volume (Sections 1 through 5).

  9. Molybdenum enhanced low-temperature deposition of crystalline silicon nitride

    DOE Patents [OSTI]

    Lowden, R.A.

    1994-04-05

    A process for chemical vapor deposition of crystalline silicon nitride is described which comprises the steps of: introducing a mixture of a silicon source, a molybdenum source, a nitrogen source, and a hydrogen source into a vessel containing a suitable substrate; and thermally decomposing the mixture to deposit onto the substrate a coating comprising crystalline silicon nitride containing a dispersion of molybdenum silicide. 5 figures.

  10. Process for thin film deposition of cadmium sulfide

    DOE Patents [OSTI]

    Muruska, H. Paul; Sansregret, Joseph L.; Young, Archie R.

    1982-01-01

    The present invention teaches a process for depositing layers of cadmium sulfide. The process includes depositing a layer of cadmium oxide by spray pyrolysis of a cadmium salt in an aqueous or organic solvent. The oxide film is then converted into cadmium sulfide by thermal ion exchange of the O.sup.-2 for S.sup.-2 by annealing the oxide layer in gaseous sulfur at elevated temperatures.

  11. Perspectives on Deposition Velocity

    Office of Environmental Management (EM)

    Deposition Velocity ... Going down the rabbit hole to explain that sinking feeling Brian DiNunno, Ph.D. Project Enhancement Corporation June 6 th , 2012 Discussion Framework  Development of the HSS Deposition Velocity Safety Bulletin  Broader discussion of appropriate conservatism within dispersion modeling and DOE-STD-3009 DOE-STD-3009 Dose Comparison "General discussion is provided for source term calculation and dose estimation, as well as prescriptive guidance for the latter. The

  12. The effect of thermal aging on the thermal conductivity of plasma sprayed and EB-PVD thermal barrier coatings

    SciTech Connect (OSTI)

    Dinwiddie, R.B.; Beecher, S.C.; Porter, W.D.; Nagaraj, B.A.

    1996-05-01

    Thermal barrier coatings (TBCs) applied to the hot gas components of turbine engines lead to enhanced fuel efficiency and component reliability. Understanding the mechanisms which control the thermal transport behavior of the TBCs is of primary importance. Electron beam-physical vapor deposition (EV-PVD) and air plasma spraying (APS) are the two most commonly used coating techniques. These techniques produce coatings with unique microstructures which control their performance and stability. The density of the APS coatings was controlled by varying the spray parameters. The low density APS yttria-partially stabilized zirconia (yttria-PSZ) coatings yielded a thermal conductivity that is lower than both the high density APS coatings and the EB-PVD coatings. The thermal aging of both fully and partially stabilized zirconia are compared. The thermal conductivity of the coatings permanently increases upon exposure to high temperatures. These increases are attributed to microstructural changes within the coatings. This increase in thermal conductivity can be modeled using a relationship which depends on both the temperature and time of exposure. Although the EB-PVD coatings are less susceptible to thermal aging effects, results suggest that they typically have a higher thermal conductivity than APS coatings before thermal aging. The increases in thermal conductivity due to thermal aging for plasma sprayed partially stabilized zirconia have been found to be less than for plasma sprayed fully stabilized zirconia coatings.

  13. Process maps for plasma spray. Part II: Deposition and properties

    SciTech Connect (OSTI)

    XIANGYANG,JIANG; MATEJICEK,JIRI; KULKARNI,ANAND; HERMAN,HERBERT; SAMPATH,SANJAY; GILMORE,DELWYN L.; NEISER JR.,RICHARD A

    2000-03-28

    This is the second paper of a two part series based on an integrated study carried out at the State University of New York at Stony Brook and Sandia National Laboratories. The goal of the study is the fundamental understanding of the plasma-particle interaction, droplet/substrate interaction, deposit formation dynamics and microstructure development as well as the deposit property. The outcome is science-based relationships, which can be used to link processing to performance. Molybdenum splats and coatings produced at 3 plasma conditions and three substrate temperatures were characterized. It was found that there is a strong mechanical/thermal interaction between droplet and substrate, which builds up the coatings/substrate adhesion. Hardness, thermal conductivity, and modulus increase, while oxygen content and porosity decrease with increasing particle velocity. Increasing deposition temperature resulted in dramatic improvement in coating thermal conductivity and hardness as well as increase in coating oxygen content. Indentation reveals improved fracture resistance for the coatings prepared at higher deposition temperature. Residual stress was significantly affected by deposition temperature, although not significant by particle energy within the investigated parameter range. Coatings prepared at high deposition temperature with high-energy particles suffered considerably less damage in wear tests. Possible mechanisms behind these changes are discussed within the context of relational maps which are under development.

  14. Substrate heater for thin film deposition

    DOE Patents [OSTI]

    Foltyn, Steve R. (111 Beryl St., Los Alamos, NM 87544)

    1996-01-01

    A substrate heater for thin film deposition of metallic oxides upon a target substrate configured as a disk including means for supporting in a predetermined location a target substrate configured as a disk, means for rotating the target substrate within the support means, means for heating the target substrate within the support means, the heating means about the support means and including a pair of heating elements with one heater element situated on each side of the predetermined location for the target substrate, with one heater element defining an opening through which desired coating material can enter for thin film deposition and with the heating means including an opening slot through which the target substrate can be entered into the support means, and, optionally a means for thermal shielding of the heating means from surrounding environment is disclosed.

  15. Improved process for the preparation of fiber-reinforced ceramic composites by chemical vapor deposition

    DOE Patents [OSTI]

    Lackey, W.J. Jr.; Caputo, A.J.

    1984-09-07

    A specially designed apparatus provides a steep thermal gradient across the thickness of fibrous preform. A flow of gaseous ceramic matrix material is directed into the fibrous preform at the cold surface. The deposition of the matrix occurs progressively from the hot surface of the fibrous preform toward the cold surface. Such deposition prevents the surface of the fibrous preform from becoming plugged. As a result thereof, the flow of reactant matrix gases into the uninfiltrated (undeposited) portion of the fibrous preform occurs throughout the deposition process. The progressive and continuous deposition of ceramic matrix within the fibrous preform provides for a significant reduction in process time over known chemical vapor deposition processes.

  16. Method of deposition of silicon carbide layers on substrates

    DOE Patents [OSTI]

    Angelini, P.; DeVore, C.E.; Lackey, W.J.; Blanco, R.E.; Stinton, D.P.

    1982-03-19

    A method for direct chemical vapor deposition of silicon carbide to substrates, especially nuclear waste particles, is provided by the thermal decomposition of methylsilane at 800 to 1050/sup 0/C when the substrates have been confined within a suitable coating environment.

  17. Methods for making deposited films with improved microstructures

    DOE Patents [OSTI]

    Patten, James W.; Moss, Ronald W.; McClanahan, Edwin D.

    1982-01-01

    Methods for improving microstructures of line-of-sight deposited films are described. Columnar growth defects ordinarily produced by geometrical shadowing during deposition of such films are eliminated without resorting to post-deposition thermal or mechanical treatments. The native, as-deposited coating qualities, including homogeneity, fine grain size, and high coating-to-substrate adherence, can thus be retained. The preferred method includes the steps of emitting material from a source toward a substrate to deposit a coating non-uniformly on the substrate surface, removing a portion of the coating uniformly over the surface, again depositing material onto the surface, but from a different direction, and repeating the foregoing steps. The quality of line-of-sight deposited films such as those produced by sputtering, progressively deteriorates as the angle of incidence between the flux and the surface becomes increasingly acute. Depositing non-uniformly, so that the coating becomes progressively thinner as quality deteriorates, followed by uniformly removing some of the coating, such as by resputtering, eliminates the poor quality portions, leaving only high quality portions of the coating. Subsequently sputtering from a different direction applies a high quality coating to other regions of the surface. Such steps can be performed either simultaneously or sequentially to apply coatings of a uniformly high quality, closed microstructure to three-dimensional or larger planar surfaces.

  18. Multi-chamber deposition system

    DOE Patents [OSTI]

    Jacobson, Richard L.; Jeffrey, Frank R.; Westerberg, Roger K.

    1989-06-27

    A system for the simultaneous deposition of different coatings onto a thin web within a large volume vacuum chamber is disclosed which chamber is provided with a plurality of deposition chambers in which the different layers are deposited onto the film as its moves from a supply roll to a finished take-up roll of coated web. The deposition chambers provided within the large vacuum chamber are provided with separate seals which minimize back diffusion of any dopant gas from adjacent deposition chambers.

  19. Multi-chamber deposition system

    DOE Patents [OSTI]

    Jacobson, Richard L.; Jeffrey, Frank R.; Westerberg, Roger K.

    1989-10-17

    A system for the simultaneous deposition of different coatings onto a thin web within a large volume vacuum chamber is disclosed which chamber is provided with a plurality of deposition chambers in which the different layers are deposited onto the film as its moves from a supply roll to a finished take-up roll of coated web. The deposition chambers provided within the large vacuum chamber are provided with separate seals which minimize back diffusion of any dopant gas from adjacent deposition chambers.

  20. Effects of thermal fluctuations on thermal inflation

    SciTech Connect (OSTI)

    Hiramatsu, Takashi; Miyamoto, Yuhei; Yokoyama, Jun’ichi

    2015-03-12

    The mechanism of thermal inflation, a relatively short period of accelerated expansion after primordial inflation, is a desirable ingredient for a certain class of particle physics models if they are not to be in contention with the cosmology of the early Universe. Though thermal inflation is most simply described in terms of a thermal effective potential, a thermal environment also gives rise to thermal fluctuations that must be taken into account. We numerically study the effects of these thermal fluctuations using lattice simulations. We conclude that though they do not ruin the thermal inflation scenario, the phase transition at the end of thermal inflation proceeds through phase mixing and is therefore not accompanied by the formations of bubbles nor appreciable amplitude of gravitational waves.

  1. High Temperature Thermal Array for Next Generation Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This ...

  2. Deposition System Controller

    Energy Science and Technology Software Center (OSTI)

    2005-10-01

    This software is a complete thin film deposition controller. The software takes as its input a script file that dictates enablinig/disabling of sputtering power supplies, pause times, velocities and distances to move a substrate. An emulator has been created and built into the software package that can debug in advance any deposition script and decide if there is an overrun condition, accidental infinite look, and can estimate a time for completion. All necessary process variablesmore » are data logged and recorded for later inspection. This emulator currently interfaces to a Parker-Compumotor SX6 stepper moror indexer, but the software is written in such a way that it is easily modifiable for interface to othe brand and models of motor drivers. Other process I/O variables may be easily added. The software uses any multifunction DAQ card from National Instruments via their free NIDAQ API package, but again, the software is written such that othe brand DAQ cards may be used.« less

  3. Thermal Control & System Integration

    Broader source: Energy.gov [DOE]

    The thermal control and system integration activity focuses on issues such as the integration of motor and power control technologies and the development of advanced thermal control technologies....

  4. Biocompatible Coating (Parylene) Deposition System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Containing Diamond-Like Carbon Deposition System Varshni Singh and Jost Goettert Center for Advanced Microstructures & Devices, Louisiana State University, 6980 Jefferson Hwy., Baton Rouge, LA-70806 Summary CAMD/LSU received funds from the Board of Regents' Enhancement Program for modifying and upgrading of a diamond like carbon (DLC) deposition system. This included a magnetron with shield, DC power supply and pulsing unit, mass flow controllers and in-situ thin film deposition

  5. Carbonate Deposition | Open Energy Information

    Open Energy Info (EERE)

    Alteration Products Carbonate deposits come in many forms and sometimes develop into spectacular colorful terraces such as these at Mammoth Hot Springs in Yellowstone National...

  6. Thermal barrier coating resistant to sintering

    DOE Patents [OSTI]

    Subramanian, Ramesh; Seth, Brij B.

    2004-06-29

    A device (10) is made, having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10), is not soluble with the underlying ceramic layer (16) and is applied by a process that is not an electron beam physical vapor deposition process.

  7. Low Speed Carbon Deposition Process for Hermetic Optical Fibers

    SciTech Connect (OSTI)

    ABRAMCZYK,JAROSLAW; ARTHUR,SARA E. TALLANT,DAVID R.; HIKANSSON,ADAM S.; LINDHOLM,ERIC A.; LO,JIE

    1999-09-29

    For optical fibers used in adverse environments, a carbon coating is frequently deposited on the fiber surface to prevent water and hydrogen ingression that lead respectively to strength degradation through fatigue and hydrogen-induced attenuation. The deposition of a hermetic carbon coating onto an optical fiber during the draw process holds a particular challenge when thermally-cured specialty coatings are subsequently applied because of the slower drawing rate. In this paper, we report on our efforts to improve the low-speed carbon deposition process by altering the composition and concentration of hydrocarbon precursor gases. The resulting carbon layers have been analyzed for electrical resistance, Raman spectra, coating thickness, and surface roughness, then compared to strength data and dynamic fatigue behavior.

  8. Variable temperature semiconductor film deposition

    DOE Patents [OSTI]

    Li, Xiaonan; Sheldon, Peter

    1998-01-01

    A method of depositing a semiconductor material on a substrate. The method sequentially comprises (a) providing the semiconductor material in a depositable state such as a vapor for deposition on the substrate; (b) depositing the semiconductor material on the substrate while heating the substrate to a first temperature sufficient to cause the semiconductor material to form a first film layer having a first grain size; (c) continually depositing the semiconductor material on the substrate while cooling the substrate to a second temperature sufficient to cause the semiconductor material to form a second film layer deposited on the first film layer and having a second grain size smaller than the first grain size; and (d) raising the substrate temperature, while either continuing or not continuing to deposit semiconductor material to form a third film layer, to thereby anneal the film layers into a single layer having favorable efficiency characteristics in photovoltaic applications. A preferred semiconductor material is cadmium telluride deposited on a glass/tin oxide substrate already having thereon a film layer of cadmium sulfide.

  9. Variable temperature semiconductor film deposition

    DOE Patents [OSTI]

    Li, X.; Sheldon, P.

    1998-01-27

    A method of depositing a semiconductor material on a substrate is disclosed. The method sequentially comprises (a) providing the semiconductor material in a depositable state such as a vapor for deposition on the substrate; (b) depositing the semiconductor material on the substrate while heating the substrate to a first temperature sufficient to cause the semiconductor material to form a first film layer having a first grain size; (c) continually depositing the semiconductor material on the substrate while cooling the substrate to a second temperature sufficient to cause the semiconductor material to form a second film layer deposited on the first film layer and having a second grain size smaller than the first grain size; and (d) raising the substrate temperature, while either continuing or not continuing to deposit semiconductor material to form a third film layer, to thereby anneal the film layers into a single layer having favorable efficiency characteristics in photovoltaic applications. A preferred semiconductor material is cadmium telluride deposited on a glass/tin oxide substrate already having thereon a film layer of cadmium sulfide.

  10. Process for the preparation of fiber-reinforced ceramic composites by chemical vapor deposition

    DOE Patents [OSTI]

    Lackey, Jr., Walter J.; Caputo, Anthony J.

    1986-01-01

    A chemical vapor deposition (CVD) process for preparing fiber-reinforced ceramic composites. A specially designed apparatus provides a steep thermal gradient across the thickness of a fibrous preform. A flow of gaseous ceramic matrix material is directed into the fibrous preform at the cold surface. The deposition of the matrix occurs progressively from the hot surface of the fibrous preform toward the cold surface. Such deposition prevents the surface of the fibrous preform from becoming plugged. As a result thereof, the flow of reactant matrix gases into the uninfiltrated (undeposited) portion of the fibrous preform occurs throughout the deposition process. The progressive and continuous deposition of ceramic matrix within the fibrous preform provides for a significant reduction in process time over known chemical vapor deposition processes.

  11. Advanced thermal barrier coating system development. Technical progress report, April 1, 1996--May 31, 1996

    SciTech Connect (OSTI)

    1996-06-10

    Objectives of this program are to provide an improved thermal barrier system with increased temperature capability and reliability relative to current systems. This report describes the bond coat development and deposition, manufacturing, and repair.

  12. Thermal decomposition of silane to form hydrogenated amorphous Si film

    DOE Patents [OSTI]

    Strongin, Myron; Ghosh, Arup K.; Wiesmann, Harold J.; Rock, Edward B.; Lutz, III, Harry A.

    1980-01-01

    This invention relates to hydrogenated amorphous silicon produced by thermally decomposing silano (SiH.sub.4) or other gases comprising H and Si, at elevated temperatures of about 1700.degree.-2300.degree. C., and preferably in a vacuum of about 10.sup.-8 to 10.sup.-4 torr, to form a gaseous mixture of atomic hydrogen and atomic silicon, and depositing said gaseous mixture onto a substrate outside said source of thermal decomposition to form hydrogenated amorphous silicon.

  13. Analysis of Zinc 65 Contamination after Vacuum Thermal Process

    SciTech Connect (OSTI)

    Korinko, Paul S.; Tosten, Michael H.

    2013-01-01

    Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

  14. HEATS: Thermal Energy Storage

    SciTech Connect (OSTI)

    2012-01-01

    HEATS Project: The 15 projects that make up ARPA-Es HEATS program, short for High Energy Advanced Thermal Storage, seek to develop revolutionary, cost-effective ways to store thermal energy. HEATS focuses on 3 specific areas: 1) developing high-temperature solar thermal energy storage capable of cost-effectively delivering electricity around the clock and thermal energy storage for nuclear power plants capable of cost-effectively meeting peak demand, 2) creating synthetic fuel efficiently from sunlight by converting sunlight into heat, and 3) using thermal energy storage to improve the driving range of electric vehicles (EVs) and also enable thermal management of internal combustion engine vehicles.

  15. Direct Deposit Form | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Direct Deposit Form Direct Deposit Form PDF icon Direct Deposit Form More Documents & Publications Employee In-Processing Forms Agreement for Minority Financial Institutions Participation in the Bank Deposit Financial Assistance Program Agreement for Minority Financial Institutions Participation in the Bank Deposit Financial Assistance Program

  16. Thin film deposition behavior of lubricants as a function of temperature - Lubricant stability maps

    SciTech Connect (OSTI)

    Klaus, E.E.; Wang, J.C.; Duda, J.L. )

    1992-07-01

    The relative rates of evaporation and oxidative or thermal decomposition in lubricants are investigated experimentally at elevated temperatures. Thin films of lubricant are exposed to air at high temperatures, and attention is given to the amount of solid deposit rendered and the amount of evaporated material. The effects of volatility, oxidative stability, and thermal stability are assessed with the help of stability maps for liquid lubricants. The concept of fluid-stability maps based on deposit formation as a function of temperature is shown to be effective. At 200-425 C lubricant deposit formation in the presence of air is a function of lubricant volatility, oxidation rate, the rate of thermal degradation, and the effect of the bearing surface. Some materials are listed that can mitigate the effects of oxidation on lubricant performance which can be used for a range of aerospace applications. 16 refs.

  17. Particle deposition in ventilation ducts

    SciTech Connect (OSTI)

    Sippola, Mark R.

    2002-09-01

    Exposure to airborne particles is detrimental to human health and indoor exposures dominate total exposures for most people. The accidental or intentional release of aerosolized chemical and biological agents within or near a building can lead to exposures of building occupants to hazardous agents and costly building remediation. Particle deposition in heating, ventilation and air-conditioning (HVAC) systems may significantly influence exposures to particles indoors, diminish HVAC performance and lead to secondary pollutant release within buildings. This dissertation advances the understanding of particle behavior in HVAC systems and the fates of indoor particles by means of experiments and modeling. Laboratory experiments were conducted to quantify particle deposition rates in horizontal ventilation ducts using real HVAC materials. Particle deposition experiments were conducted in steel and internally insulated ducts at air speeds typically found in ventilation ducts, 2-9 m/s. Behaviors of monodisperse particles with diameters in the size range 1-16 {micro}m were investigated. Deposition rates were measured in straight ducts with a fully developed turbulent flow profile, straight ducts with a developing turbulent flow profile, in duct bends and at S-connector pieces located at duct junctions. In straight ducts with fully developed turbulence, experiments showed deposition rates to be highest at duct floors, intermediate at duct walls, and lowest at duct ceilings. Deposition rates to a given surface increased with an increase in particle size or air speed. Deposition was much higher in internally insulated ducts than in uninsulated steel ducts. In most cases, deposition in straight ducts with developing turbulence, in duct bends and at S-connectors at duct junctions was higher than in straight ducts with fully developed turbulence. Measured deposition rates were generally higher than predicted by published models. A model incorporating empirical equations based on the experimental measurements was applied to evaluate particle losses in supply and return duct runs. Model results suggest that duct losses are negligible for particle sizes less than 1 {micro}m and complete for particle sizes greater than 50 {micro}m. Deposition to insulated ducts, horizontal duct floors and bends are predicted to control losses in duct systems. When combined with models for HVAC filtration and deposition to indoor surfaces to predict the ultimate fates of particles within buildings, these results suggest that ventilation ducts play only a small role in determining indoor particle concentrations, especially when HVAC filtration is present. However, the measured and modeled particle deposition rates are expected to be important for ventilation system contamination.

  18. Fabrication of Conductive Paths on a Fused Deposition Modeling Substrate using Inkjet Deposition

    SciTech Connect (OSTI)

    Zhou, Wenchao; List, III, Frederick Alyious; Duty, Chad E.; Babu, Sudarsanam Suresh

    2015-01-15

    Inkjet deposition is one of the most attractive fabrication techniques for producing cost efficient and lightweight electronic devices on various substrates with low environmental impact. Fused Deposition Modeling (FDM) is one of the most used and reliable additive manufacturing processes by extrusion of wire-shaped thermoplastic materials, which provides an opportunity for embedding printed electronics into mechanical structures during the building process and enables the design of compact smart structures that can sense and adapt to their own state and the environment. This paper represents one of the first explorations of integrating inkjet deposition of silver nanoparticle inks with the FDM process for making compact electro-mechanical structures. Three challenges have been identified and investigated, including the discontinuity of the printed lines resulting from the irregular surface of the FDM substrate, the non-conductivity of the printed lines due to the particle segregation during the droplet drying process, and the slow drying process caused by the skinning effect . Two different techniques are developed in this paper to address the issue of continuity of the printed lines, including surface ironing and a novel thermal plow technique that plows a channel in the FDM substrate to seal off the pores in the substrate and contain the deposited inks. Two solutions are also found for obtaining conductivity from the continuous printed lines, including porous surface coating and using a more viscous ink with larger nanoparticle size. Then the effects of the printing and post-processing parameters on the conductivity are examined. It is found that post-processing is a dominant factor in determining the conductivity of the printed lines.

  19. Fabrication of Conductive Paths on a Fused Deposition Modeling Substrate using Inkjet Deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Wenchao; List, III, Frederick Alyious; Duty, Chad E.; Babu, Sudarsanam Suresh

    2015-01-15

    Inkjet deposition is one of the most attractive fabrication techniques for producing cost efficient and lightweight electronic devices on various substrates with low environmental impact. Fused Deposition Modeling (FDM) is one of the most used and reliable additive manufacturing processes by extrusion of wire-shaped thermoplastic materials, which provides an opportunity for embedding printed electronics into mechanical structures during the building process and enables the design of compact smart structures that can sense and adapt to their own state and the environment. This paper represents one of the first explorations of integrating inkjet deposition of silver nanoparticle inks with the FDMmore » process for making compact electro-mechanical structures. Three challenges have been identified and investigated, including the discontinuity of the printed lines resulting from the irregular surface of the FDM substrate, the non-conductivity of the printed lines due to the particle segregation during the droplet drying process, and the slow drying process caused by the skinning effect . Two different techniques are developed in this paper to address the issue of continuity of the printed lines, including surface ironing and a novel thermal plow technique that plows a channel in the FDM substrate to seal off the pores in the substrate and contain the deposited inks. Two solutions are also found for obtaining conductivity from the continuous printed lines, including porous surface coating and using a more viscous ink with larger nanoparticle size. Then the effects of the printing and post-processing parameters on the conductivity are examined. It is found that post-processing is a dominant factor in determining the conductivity of the printed lines.« less

  20. MODELING OF THERMOPHORETIC SOOT DEPOSITION ANDHYDROCARBON CONDENSATION IN EGR COOLERS

    SciTech Connect (OSTI)

    Abarham, Mehdi; Hoard, John W.; Assanis, Dennis; Styles, Dan; Curtis, Eric W.; Ramesh, Nitia; Sluder, Scott; Storey, John Morse

    2009-01-01

    EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40-90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature. Thermal properties of fouled layer are calculated based on mass fraction of deposited soot and hydrocarbons. The experiments with the same conditions ran to validate the model. Hot EGR gases flow through the inner pipe and the coolant circulates around it in the outer pipe to keep a constant wall temperature. Effectiveness, deposited soot mass, condensed hydrocarbon mass, and pressure drop across the cooler are the parameters that have been compared. The results of the model are in a reasonably good agreement with the experimental results although there are some fields that need to be studied in future to improve the model.

  1. Thermal Energy Storage

    SciTech Connect (OSTI)

    Rutberg, Michael; Hastbacka, Mildred; Cooperman, Alissa; Bouza, Antonio

    2013-06-05

    The article discusses thermal energy storage technologies. This article addresses benefits of TES at both the building site and the electricity generation source. The energy savings and market potential of thermal energy store are reviewed as well.

  2. thermal energy power conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Solar Thermal Test Facility Nuclear ... Climate & Earth Systems Climate Measurement & Modeling ... Tribal Energy Program Intellectual Property Current EC ...

  3. MACCS2/Deposition Velocity Workshop

    Broader source: Energy.gov [DOE]

    The Department of Energy’s Chief of Nuclear Safety hosted a MACCS2/Deposition Velocity Workshop on June 5-6, 2012, in Germantown, Maryland. Approximately 70 participants attended. The purpose of...

  4. Thermal neutron detection system

    DOE Patents [OSTI]

    Peurrung, Anthony J. (Richland, WA); Stromswold, David C. (West Richland, WA)

    2000-01-01

    According to the present invention, a system for measuring a thermal neutron emission from a neutron source, has a reflector/moderator proximate the neutron source that reflects and moderates neutrons from the neutron source. The reflector/moderator further directs thermal neutrons toward an unmoderated thermal neutron detector.

  5. Thermal Performance Benchmarking (Presentation)

    SciTech Connect (OSTI)

    Moreno, G.

    2014-11-01

    This project will benchmark the thermal characteristics of automotive power electronics and electric motor thermal management systems. Recent vehicle systems will be benchmarked to establish baseline metrics, evaluate advantages and disadvantages of different thermal management systems, and identify areas of improvement to advance the state-of-the-art.

  6. Chemical enhancement of surface deposition

    DOE Patents [OSTI]

    Patch, Keith D.; Morgan, Dean T.

    1997-07-29

    A method and apparatus for increasing the deposition of ions onto a surface, such as the adsorption of uranium ions on the detecting surface of a radionuclide detector. The method includes the step of exposing the surface to a complexing agent, such as a phosphate ion solution, which has an affinity for the dissolved species to be deposited on the surface. This provides, for example, enhanced sensitivity of the radionuclide detector.

  7. Vapor deposition of hardened niobium

    DOE Patents [OSTI]

    Blocher, Jr., John M.; Veigel, Neil D.; Landrigan, Richard B.

    1983-04-19

    A method of coating ceramic nuclear fuel particles containing a major amount of an actinide ceramic in which the particles are placed in a fluidized bed maintained at ca. 800.degree. to ca. 900.degree. C., and niobium pentachloride vapor and carbon tetrachloride vapor are led into the bed, whereby niobium metal is deposited on the particles and carbon is deposited interstitially within the niobium. Coating apparatus used in the method is also disclosed.

  8. Chemical enhancement of surface deposition

    DOE Patents [OSTI]

    Patch, K.D.; Morgan, D.T.

    1997-07-29

    A method and apparatus are disclosed for increasing the deposition of ions onto a surface, such as the adsorption of uranium ions on the detecting surface of a radionuclide detector. The method includes the step of exposing the surface to a complexing agent, such as a phosphate ion solution, which has an affinity for the dissolved species to be deposited on the surface. This provides, for example, enhanced sensitivity of the radionuclide detector. 16 figs.

  9. Deposition > Complex Oxides > Research > The Energy Materials...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis Nanoparticles Nanostructured Systems Deposition Deposition Veeco GEN10 MBE system dedicated to the growth of oxide heterostructures being installed in Duffield Lab at...

  10. Methods of electrophoretic deposition for functionally graded...

    Office of Scientific and Technical Information (OSTI)

    Methods of electrophoretic deposition for functionally graded porous nanostructures and ... and depositing the material onto surfaces of the particles of the impurity to form ...

  11. Westinghouse thermal barrier coatings development

    SciTech Connect (OSTI)

    Goedjen, J.G.; Wagner, G.

    1995-10-01

    Westinghouse, in conjunction with the Department of Energy and Oak Ridge National Laboratory, has embarked upon a program for the development of advanced thermal barrier coatings for industrial gas turbines. Development of thermal barrier coatings (TBC`s) for industrial gas turbines has relied heavily on the transfer of technology from the aerospace industry. Significant differences in the time/temperature/stress duty cycles exist between these two coating applications. Coating systems which perform well in aerospace applications may not been optimized to meet power generation performance requirements. This program will focus on development of TBC`s to meet the specific needs of power generation applications. The program is directed at developing a state-of-the-art coating system with a minimum coating life of 25,000 hours at service temperatures required to meet increasing operating efficiency goals. Westinghouse has assembled a team of university and industry leaders to accomplish this goal. Westinghouse will coordinate the efforts of all program participants. Chromalloy Turbine Technologies, Inc. and Sermatech International, Inc. will be responsible for bond coat and TBC deposition technology. Praxair Specialty Powders, Inc. will be responsible for the fabrication of all bond coat and ceramic powders for the program. Southwest Research Institute will head the life prediction modelling effort; they will also be involved in coordinating nondestructive evaluation (NDE) efforts. Process modelling will be provided by the University of Arizona.

  12. Thermal Effusivity Tomography from Pulsed Thermal Imaging

    Energy Science and Technology Software Center (OSTI)

    2006-12-01

    The software program generates 3D volume distribution of thermal effusivity within a test material from one-sided pulsed thermal imaging data. Thsi is the first software capable of accurate, fast and automated thermal tomographic imaging of inhomogeneous materials to produce 3D images similar to those obtained from 3D X-ray CT (all previous thermal-imaging software can only produce 2D results). Because thermal effusivity is an intrisic material property that is related to material constituent, density, conductivity, etc.,more » quantitative imaging of effusivity allowed direct visualization of material's internal constituent/structure and damage distributions, thereby potentially leading to quantitative prediction of other material properties such as strength. I can be therefre be used for 3D imaging of material structure in fundamental material studies, nondestructive characterization of defects/flaws in structural engineering components, health monitoring of material damage and degradation during service, and medical imaging and diagnostics. This technology is one-sided, non contact and sensitive to material's thermal property and discontinuity. One major advantage of this tomographic technology over x-ray CT and ultrasounds is its natural efficiency for 3D imaging of the volume under a large surface area. This software is implemented with a method for thermal computed tomography of thermal effusivity from one-sided pulsed thermal imaging (or thermography) data. The method is based on several solutions of the governing heat transfer equation under pulsed thermography test condition. In particular, it consists of three components. 1) It utilized the thermal effusivity as the imaging parameter to construct the 3D image. 2) It established a relationship between the space (depth) and the time, because thermography data are in the time domain. 3) It incorporated a deconvolution algorithm to solve the depth porfile of the material thermal effusivity from the measured (temporal) surface temperature data. The predicted effusivity is a direct function of depth, not an average or convolved parameter, so it is an accurate (and more sensitive) representation of local property along depth.« less

  13. Reexamination of Basal Plane Thermal Conductivity of Suspended Graphene Samples Measured by Electro-Thermal Micro-Bridge Methods

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jo, Insun; Pettes, Michael; Lindsay, Lucas R; Ou, Eric; Weathers, Annie; Moore, Arden; Yao, Zhen; Shi, Li

    2015-01-01

    Thermal transport in suspended graphene samples has been measured in prior works and this work with the use of a suspended electro-thermal micro-bridge method. These measurement results are analyzed here to evaluate and eliminate the errors caused by the extrinsic thermal contact resistance. It is noted that the thermal resistance measured in a recent work increases linearly with the suspended length of the single-layer graphene samples synthesized by chemical vapor deposition (CVD), and that such a feature does not reveal the failure of Fourier s law despite the increase in the apparent thermal conductivity with length. The re-analyzed thermal conductivitymore » of a single-layer CVD graphene sample reaches about ( 1680 180 )Wm-1K-1 at room temperature, which is close to the highest value reported for highly oriented pyrolytic graphite. In comparison, the thermal conductivity values measured for two suspended exfoliated bi-layer graphene samples are about ( 880 60 ) and ( 730 60 ) Wm-1K-1 at room temperature, and approach that of the natural graphite source above room temperature. However, the low-temperature thermal conductivities of these suspended graphene samples are still considerably lower than the graphite values, with the peak thermal conductivities shifted to much higher temperatures. Analysis of the thermal conductivity data reveals that the low temperature behavior is dominated by phonon scattering by polymer residue instead of by the lateral boundary.« less

  14. Reexamination of Basal Plane Thermal Conductivity of Suspended Graphene Samples Measured by Electro-Thermal Micro-Bridge Methods

    SciTech Connect (OSTI)

    Jo, Insun; Pettes, Michael; Lindsay, Lucas R; Ou, Eric; Weathers, Annie; Moore, Arden; Yao, Zhen; Shi, Li

    2015-01-01

    Thermal transport in suspended graphene samples has been measured in prior works and this work with the use of a suspended electro-thermal micro-bridge method. These measurement results are analyzed here to evaluate and eliminate the errors caused by the extrinsic thermal contact resistance. It is noted that the thermal resistance measured in a recent work increases linearly with the suspended length of the single-layer graphene samples synthesized by chemical vapor deposition (CVD), and that such a feature does not reveal the failure of Fourier s law despite the increase in the apparent thermal conductivity with length. The re-analyzed thermal conductivity of a single-layer CVD graphene sample reaches about ( 1680 180 )Wm-1K-1 at room temperature, which is close to the highest value reported for highly oriented pyrolytic graphite. In comparison, the thermal conductivity values measured for two suspended exfoliated bi-layer graphene samples are about ( 880 60 ) and ( 730 60 ) Wm-1K-1 at room temperature, and approach that of the natural graphite source above room temperature. However, the low-temperature thermal conductivities of these suspended graphene samples are still considerably lower than the graphite values, with the peak thermal conductivities shifted to much higher temperatures. Analysis of the thermal conductivity data reveals that the low temperature behavior is dominated by phonon scattering by polymer residue instead of by the lateral boundary.

  15. Thermal Effusivity Tomography from Pulsed Thermal Imaging

    Energy Science and Technology Software Center (OSTI)

    2008-11-05

    The software program generates 3D volume distribution of thermal effusivity within a test material from one—sided pulsed thermal imaging data. Thsi is the first software capable of accurate, fast and automated thermal tomographic imaging of inhomogeneoirs materials to produce 3D images similar to those obtained from 3D X—ray CT (all previous thepnal—imaging software can only produce 20 results) . Because thermal effusivity is an Intrisic material property that is related to material constituent, density, conductivity,more » etc., quantitative imaging of eftusivity allowed direct visualization of material’s internal constituent/structure and damage distributions, thereby potentially leading to quantitative prediction of other material properties such as strength. I can be therefre be used for 3D imaging of material structure in fundamental material studies, nondestructive characterization of defects/flaws in structural engineering components, health monitoring of material damage and degradation during service, and medical imaging and diagnostics. This technology is one—sided, non contact and sensitive to material’s thermal property and discontinuity. One major advantage of this tomographic technology over x-ray CT and ultrasounds is its natural efficiency for 3D imaging of the volume under a large surface area. This software is implemented with a method for thermal computed tomography of thermal effusivity from one—sided pulsed thermal imaging (or thermography) data. The method is based on several solutions of the governing heat transfer equation under pulsed thermography test condition. In particular, it consists of three components. 1) It utilized the thermal effusivity as the imaging parameter to construct the 3D image. 2) It established a relationship between the space (depth) and the time, because thermography data are in the time domain. 3) It incorporated a deconvolution algorithm to solve the depth porfile of the material thermal effusivity from the measured (temporal) surface temperature data. The predicted effusivity is a direct function of depth, not an average or convolved parameter, so it is an accurate (and more sensitive) representation of local property along depth.« less

  16. TULSA UNIVERSITY PARAFFIN DEPOSITION PROJECTS

    SciTech Connect (OSTI)

    Cem Sarica; Michael Volk

    2004-06-01

    As oil and gas production moves to deeper and colder water, subsea multiphase production systems become critical for economic feasibility. It will also become increasingly imperative to adequately identify the conditions for paraffin precipitation and predict paraffin deposition rates to optimize the design and operation of these multi-phase production systems. Although several oil companies have paraffin deposition predictive capabilities for single-phase oil flow, these predictive capabilities are not suitable for the multiphase flow conditions encountered in most flowlines and wellbores. For deepwater applications in the Gulf of Mexico, it is likely that multiphase production streams consisting of crude oil, produced water and gas will be transported in a single multiphase pipeline to minimize capital cost and complexity at the mudline. Existing single-phase (crude oil) paraffin deposition predictive tools are clearly inadequate to accurately design these pipelines, because they do not account for the second and third phases, namely, produced water and gas. The objective of this program is to utilize the current test facilities at The University of Tulsa, as well as member company expertise, to accomplish the following: enhance our understanding of paraffin deposition in single and two-phase (gas-oil) flows; conduct focused experiments to better understand various aspects of deposition physics; and, utilize knowledge gained from experimental modeling studies to enhance the computer programs developed in the previous JIP for predicting paraffin deposition in single and two-phase flow environments. These refined computer models will then be tested against field data from member company pipelines.

  17. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A.; Campbell, Christian X.; Subramanian, Ramesh

    2009-06-02

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  18. Vapor deposition of thin films

    SciTech Connect (OSTI)

    Smith, D.C.; Pattillo, S.G.; Laia, J.R. Jr.; Sattelberger, A.P.

    1990-10-05

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl){sub 3}, iridium(allyl){sub 3}, molybdenum(allyl){sub 4}, tungsten(allyl){sub 4}, rhenium (allyl){sub 4}, platinum(allyl){sub 2}, or palladium(allyl){sub 2} are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  19. Fluidized bed deposition of diamond

    DOE Patents [OSTI]

    Laia, Jr., Joseph R.; Carroll, David W.; Trkula, Mitchell; Anderson, Wallace E.; Valone, Steven M.

    1998-01-01

    A process for coating a substrate with diamond or diamond-like material including maintaining a substrate within a bed of particles capable of being fluidized, the particles having substantially uniform dimensions and the substrate characterized as having different dimensions than the bed particles, fluidizing the bed of particles, and depositing a coating of diamond or diamond-like material upon the substrate by chemical vapor deposition of a carbon-containing precursor gas mixture, the precursor gas mixture introduced into the fluidized bed under conditions resulting in excitation mechanisms sufficient to form the diamond coating.

  20. Vapor deposition of thin films

    DOE Patents [OSTI]

    Smith, David C. (Los Alamos, NM); Pattillo, Stevan G. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Sattelberger, Alfred P. (Los Alamos, NM)

    1992-01-01

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl).sub.3, iridium(allyl).sub.3, molybdenum(allyl).sub.4, tungsten(allyl).sub.4, rhenium(allyl).sub.4, platinum(allyl).sub.2, or palladium(allyl).sub.2 are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  1. Effect of interfacial interactions on the thermal conductivity and interfacial thermal conductance in tungstengraphene layered structure

    SciTech Connect (OSTI)

    Jagannadham, K.

    2014-09-01

    Graphene film was deposited by microwave plasma assisted deposition on polished oxygen free high conductivity copper foils. Tungstengraphene layered film was formed by deposition of tungsten film by magnetron sputtering on the graphene covered copper foils. Tungsten film was also deposited directly on copper foil without graphene as the intermediate film. The tungstengraphenecopper samples were heated at different temperatures up to 900?C in argon atmosphere to form an interfacial tungsten carbide film. Tungsten film deposited on thicker graphene platelets dispersed on silicon wafer was also heated at 900?C to identify the formation of tungsten carbide film by reaction of tungsten with graphene platelets. The films were characterized by scanning electron microscopy, Raman spectroscopy, and x-ray diffraction. It was found that tungsten carbide film formed at the interface upon heating only above 650?C. Transient thermoreflectance signal from the tungsten film surface on the samples was collected and modeled using one-dimensional heat equation. The experimental and modeled results showed that the presence of graphene at the interface reduced the cross-plane effective thermal conductivity and the interfacial thermal conductance of the layer structure. Heating at 650 and 900?C in argon further reduced the cross-plane thermal conductivity and interface thermal conductance as a result of formation nanocrystalline tungsten carbide at the interface leading to separation and formation of voids. The present results emphasize that interfacial interactions between graphene and carbide forming bcc and hcp elements will reduce the cross-plane effective thermal conductivity in composites.

  2. Thermal conductance of metallic interface in vacuum

    SciTech Connect (OSTI)

    Mortazavi, P.; Shu, D.

    1985-01-01

    In most heat transfer applications, the deposited heat is transferred by any of the following classical methods: conduction, convection, radiation, or any combinations of these three. Depending on how critical the nature is of the designed equipment, the response time must be short enough in order to safeguard the proper performance of the devices. For instance, currently at the National Synchrotron Light Source (NSLS), various hardware equipment are being designed to intercept or to stop intense radiation beams induced by insertion devices such as wiggler and undulators. Due to the nature of some of these designs, the deposited high flux thermal load must be transferred across unbonded contact surfaces. Since any miscalculation would result in the disintegration of exposed material and therefore cause substantial problems, a true actual conductance measurement of the material in question is highly desirable. In the following three sections, background summary, the method of measurement, and the obtained results are discussed.

  3. Scattering Solar Thermal Concentrators

    Office of Environmental Management (EM)

    sunshot DOEGO-102012-3669 * September 2012 MOTIVATION All thermal concentrating solar power (CSP) systems use solar tracking, which involves moving large mirror surfaces...

  4. Sandia Thermal Program

    Energy Science and Technology Software Center (OSTI)

    2005-11-23

    Thermal analysis in 1-D planar, cylindrical and spherical geometries using control volume finite element spatial discretization with 1st and 2nd order implicit time integrators.

  5. Battery Thermal Characterization

    SciTech Connect (OSTI)

    Saxon, Aron; Powell, Mitchell; Shi, Ying

    2015-06-09

    This presentation provides an update of NREL's battery thermal characterization efforts for the 2015 U.S. Department of Energy Annual Merit Reviews.

  6. Turbine Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Key Contacts Turbine Thermal Management The gas turbine is the workhorse of power generation, and technology ... could result in a 4 - 6 percent gain in overall system efficiency. ...

  7. Review of computational thermal-hydraulic modeling

    SciTech Connect (OSTI)

    Keefer, R.H.; Keeton, L.W.

    1995-12-31

    Corrosion of heat transfer tubing in nuclear steam generators has been a persistent problem in the power generation industry, assuming many different forms over the years depending on chemistry and operating conditions. Whatever the corrosion mechanism, a fundamental understanding of the process is essential to establish effective management strategies. To gain this fundamental understanding requires an integrated investigative approach that merges technology from many diverse scientific disciplines. An important aspect of an integrated approach is characterization of the corrosive environment at high temperature. This begins with a thorough understanding of local thermal-hydraulic conditions, since they affect deposit formation, chemical concentration, and ultimately corrosion. Computational Fluid Dynamics (CFD) can and should play an important role in characterizing the thermal-hydraulic environment and in predicting the consequences of that environment,. The evolution of CFD technology now allows accurate calculation of steam generator thermal-hydraulic conditions and the resulting sludge deposit profiles. Similar calculations are also possible for model boilers, so that tests can be designed to be prototypic of the heat exchanger environment they are supposed to simulate. This paper illustrates the utility of CFD technology by way of examples in each of these two areas. This technology can be further extended to produce more detailed local calculations of the chemical environment in support plate crevices, beneath thick deposits on tubes, and deep in tubesheet sludge piles. Knowledge of this local chemical environment will provide the foundation for development of mechanistic corrosion models, which can be used to optimize inspection and cleaning schedules and focus the search for a viable fix.

  8. Method of chemical vapor deposition of boron nitride using polymeric cyanoborane

    DOE Patents [OSTI]

    Maya, Leon

    1994-01-01

    Polymeric cyanoborane is volatilized, decomposed by thermal or microwave plasma energy, and deposited on a substrate as an amorphous film containing boron, nitrogen and carbon. Residual carbon present in the film is removed by ammonia treatment at an increased temperature, producing an adherent, essentially stoichiometric boron nitride film.

  9. Method of chemical vapor deposition of boron nitride using polymeric cyanoborane

    DOE Patents [OSTI]

    Maya, L.

    1994-06-14

    Polymeric cyanoborane is volatilized, decomposed by thermal or microwave plasma energy, and deposited on a substrate as an amorphous film containing boron, nitrogen and carbon. Residual carbon present in the film is removed by ammonia treatment at an increased temperature, producing an adherent, essentially stoichiometric boron nitride film. 11 figs.

  10. Method of deposition of silicon carbide layers on substrates and product

    DOE Patents [OSTI]

    Angelini, Peter; DeVore, Charles E.; Lackey, Walter J.; Blanco, Raymond E.; Stinton, David P.

    1984-01-01

    A method for direct chemical vapor deposition of silicon carbide to substrates, especially nuclear waste particles, is provided by the thermal decomposition of methylsilane at about 800.degree. C. to 1050.degree. C. when the substrates have been confined within a suitable coating environment.

  11. Thermal barrier coating resistant to sintering

    DOE Patents [OSTI]

    Subramanian, Ramesh; Sabol, Stephen M.

    2001-01-01

    A device (10) having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10) and is not soluble with the underlying ceramic layer (16). For a YSZ ceramic layer (16) the sintering resistant layer (22) may preferably be aluminum oxide or yttrium aluminum oxide, deposited as a continuous layer or as nodules.

  12. Vacuum vapor deposition gun assembly

    DOE Patents [OSTI]

    Zeren, Joseph D.

    1985-01-01

    A vapor deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, a hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

  13. Variable pressure thermal insulating jacket

    DOE Patents [OSTI]

    Nelson, Paul A. (Wheaton, IL); Malecha, Richard F. (Naperville, IL); Chilenskas, Albert A. (Chicago, IL)

    1994-01-01

    A device for controlled insulation of a thermal device. The device includes a thermal jacket with a closed volume able to be evacuated to form an insulating jacket around the thermal source. A getter material is in communcation with the closed volume of the thermal jacket. The getter material can absorb and desorb a control gas to control gas pressure in the volume of the thermal jacket to control thermal conductivity in the thermal jacket.

  14. Variable pressure thermal insulating jacket

    DOE Patents [OSTI]

    Nelson, P.A.; Malecha, R.F.; Chilenskas, A.A.

    1994-09-20

    A device for controlled insulation of a thermal device is disclosed. The device includes a thermal jacket with a closed volume able to be evacuated to form an insulating jacket around the thermal source. A getter material is in communication with the closed volume of the thermal jacket. The getter material can absorb and desorb a control gas to control gas pressure in the volume of the thermal jacket to control thermal conductivity in the thermal jacket. 10 figs.

  15. Thermally actuated wedge block

    DOE Patents [OSTI]

    Queen, Jr., Charles C.

    1980-01-01

    This invention relates to an automatically-operating wedge block for maintaining intimate structural contact over wide temperature ranges, including cryogenic use. The wedging action depends on the relative thermal expansion of two materials having very different coefficients of thermal expansion. The wedge block expands in thickness when cooled to cryogenic temperatures and contracts in thickness when returned to room temperature.

  16. Thermal protection apparatus

    DOE Patents [OSTI]

    Bennett, G.A.; Elder, M.G.; Kemme, J.E.

    1984-03-20

    The disclosure is directed to an apparatus for thermally protecting sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components such as electronics to a heat sink such as ice.

  17. Thermal protection apparatus

    DOE Patents [OSTI]

    Bennett, Gloria A.; Elder, Michael G.; Kemme, Joseph E.

    1985-01-01

    An apparatus which thermally protects sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components to a heat sink such as ice.

  18. Tunable thermal link

    DOE Patents [OSTI]

    Chang, Chih-Wei; Majumdar, Arunava; Zettl, Alexander K.

    2014-07-15

    Disclosed is a device whereby the thermal conductance of a multiwalled nanostructure such as a multiwalled carbon nanotube (MWCNT) can be controllably and reversibly tuned by sliding one or more outer shells with respect to the inner core. As one example, the thermal conductance of an MWCNT dropped to 15% of the original value after extending the length of the MWCNT by 190 nm. The thermal conductivity returned when the tube was contracted. The device may comprise numbers of multiwalled nanotubes or other graphitic layers connected to a heat source and a heat drain and various means for tuning the overall thermal conductance for applications in structure heat management, heat flow in nanoscale or microscale devices and thermal logic devices.

  19. Solar thermal aircraft

    DOE Patents [OSTI]

    Bennett, Charles L.

    2007-09-18

    A solar thermal powered aircraft powered by heat energy from the sun. A heat engine, such as a Stirling engine, is carried by the aircraft body for producing power for a propulsion mechanism, such as a propeller. The heat engine has a thermal battery in thermal contact with it so that heat is supplied from the thermal battery. A solar concentrator, such as reflective parabolic trough, is movably connected to an optically transparent section of the aircraft body for receiving and concentrating solar energy from within the aircraft. Concentrated solar energy is collected by a heat collection and transport conduit, and heat transported to the thermal battery. A solar tracker includes a heliostat for determining optimal alignment with the sun, and a drive motor actuating the solar concentrator into optimal alignment with the sun based on a determination by the heliostat.

  20. Thermal treatment wall

    DOE Patents [OSTI]

    Aines, Roger D.; Newmark, Robin L.; Knauss, Kevin G.

    2000-01-01

    A thermal treatment wall emplaced to perform in-situ destruction of contaminants in groundwater. Thermal destruction of specific contaminants occurs by hydrous pyrolysis/oxidation at temperatures achievable by existing thermal remediation techniques (electrical heating or steam injection) in the presence of oxygen or soil mineral oxidants, such as MnO.sub.2. The thermal treatment wall can be installed in a variety of configurations depending on the specific objectives, and can be used for groundwater cleanup, wherein in-situ destruction of contaminants is carried out rather than extracting contaminated fluids to the surface, where they are to be cleaned. In addition, the thermal treatment wall can be used for both plume interdiction and near-wellhead in-situ groundwater treatment. Thus, this technique can be utilized for a variety of groundwater contamination problems.

  1. Thermal barrier coating having high phase stability

    DOE Patents [OSTI]

    Subramanian, Ramesh

    2002-01-01

    A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating characterized by a microstructure having gaps (28) where the thermal barrier coating comprises a first thermal barrier layer (40), and a second thermal barrier layer (30) with a pyrochlore crystal structure having a chemical formula of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof, where B is selected from the group of elements consisting of Zr, Hf, Ti and mixtures thereof, where n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

  2. Deposition

    National Nuclear Security Administration (NNSA)

    Reporting Company 866.488.DEPO www.CapitalReportingCompany.com 1 DEPARTMENT OF ENERGY 1 2 PROPOSED CHANGES FOR DOE PART 810 3 ASSISTANCE TO FOREIGN NUCLEAR ACTIVITIES 4 5 NNSA - SNOPR ROLLOUT MEETING 6 7 Department of Energy 8 1000 Independence Avenue, S.W. 9 Forrestal Building 10 Washington, D.C. 11 12 13 Monday, August 5, 2013 14 1:00 p.m. 15 16 17 18 19 Reported by: Natalia Thomas, 20 Capital Reporting Company 21 22 Capital Reporting Company 866.488.DEPO www.CapitalReportingCompany.com 2 A P

  3. Deposition

    National Nuclear Security Administration (NNSA)

    ... 9 take a look at a rule that really no longer reflected 10 how proliferation was being conducted or how we saw 11 proliferation and, yet, also how industry was moving 12 forward. ...

  4. Thermal Shock Structural Analyses of a Positron Target

    SciTech Connect (OSTI)

    Stein, W; Sunwoo, A; Schultz, D C; Sheppard, J C

    2001-06-07

    In the positron source of the Stanford Linear Collider (SLC), the electron beam collides with a tungsten-rhenium target. As the beam passes into the material, thermal energy is created that heats the material to several hundred degrees centigrade on a time scale of nanoseconds. The heating of the material results in thermal stresses that may be large enough to cause material failure. The analyses calculate the thermal shock pressure and stress pulses as they move throughout the material due to the rapid energy deposition. Failure of the target occurred after three years of operation with an elevated power deposition toward the end of the three years. The calculations were made with the LLNL coupled heat transfer and dynamic solid mechanics analysis codes, TOPAZ3D and DYNA3D, and the thermal energy deposition was calculated with the SLAC Electron Gamma Shower (EGS) code simulating the electron-induced cascade. Material fatigue strength, experimentally measured properties for the non-irradiated and irradiated material, as well as the calculated stress state are evaluated in assessing the cause for the target failure.

  5. Thermal Shock Structural Analyses of a Positron Target

    SciTech Connect (OSTI)

    Bharadwaj, Vinod

    2002-08-20

    In the positron source of the Stanford Linear Collider (SLC), the electron beam collides with a tungsten-rhenium target. As the beam passes into the material, thermal energy is created that heats the material to several hundred degrees centigrade on a time scale of nanoseconds. The heating of the material results in thermal stresses that may be large enough to cause material failure. The analyses calculate the thermal shock pressure and stress pulses as they move throughout the material due to the rapid energy deposition. Failure of the target occurred after three years of operation with an elevated power deposition toward the end of the three years. The calculations were made with the LLNL coupled heat transfer and dynamic solid mechanics analysis codes, TOPAZ3D and DYNA3D, and the thermal energy deposition was calculated with the SLAC Electron Gamma Shower (EGS) code simulating the electron-induced cascade. Material fatigue strength, experimentally measured properties for the non-irradiated and irradiated material, as well as the calculated stress state are evaluated in assessing the cause for the target failure.

  6. Thermally-related safety issues associated with thermal batteries.

    SciTech Connect (OSTI)

    Guidotti, Ronald Armand

    2006-06-01

    Thermal batteries can experience thermal runaway under certain usage conditions. This can lead to safety issues for personnel and cause damage to associated test equipment if the battery thermally self destructs. This report discusses a number of thermal and design related issues that can lead to catastrophic destruction of thermal batteries under certain conditions. Contributing factors are identified and mitigating actions are presented to minimize or prevent undesirable thermal runaway.

  7. Chemical vapor deposition of sialon

    DOE Patents [OSTI]

    Landingham, R.L.; Casey, A.W.

    A laminated composite and a method for forming the composite by chemical vapor deposition are described. The composite includes a layer of sialon and a material to which the layer is bonded. The method includes the steps of exposing a surface of the material to an ammonia containing atmosphere; heating the surface to at least about 1200/sup 0/C; and impinging a gas containing N/sub 2/, SiCl/sub 4/, and AlCl/sub 3/ on the surface.

  8. Zinc deposition in acid electrolytes

    SciTech Connect (OSTI)

    McBreen, J.; Gannon, E.

    1981-01-01

    In the past decade, two aqueous zinc/halogen batteries, the zinc/chlorine, and the zinc/bromine systems, have been considered for load-leveling and vehicular applications. Even though considerable progress has been made in engineering these batteries, several problems related to the zinc electrode have yet to be solved. These are related to the growth of dendritic zinc and a maldistribution of the zinc deposit that can occur during cycling. Both problems are exacerbated by recharge of the battery after partial discharge of the zinc deposit. A survey of the literature indicates that a more desireable zinc morphology can be achieved by use of inorganic additives, fluorinated surfactants, and A-C modulation of the charging current. In this investigation, the deposition of zinc from zinc bromide and zinc chloride electrolytes was investigated under conditions that precluded dendrite growth. The techniques used were cyclic voltammetry, the potential step technique and scanning electron microscopy. The variables investigated were the substrate (zinc and dense graphite), electrolyte pH, inorganic additives (Pb/sup + +/ and Bi/sup 3 +/) and A-V modulation of the charging potential by superimposed square waves.

  9. Thermal transport in tantalum oxide films for memristive applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Landon, Colin Donald; Wilke, Rudeger H. T.; Brumbach, Michael T.; Brennecka, Geoffrey L.; Blea-Kirby, Mia Angelica; Ihlefeld, Jon; Marinella, Matthew; Thomas Edwin Beechem

    2015-07-15

    The thermal conductivity of amorphous TaOx memristive films having variable oxygen content is measured using time domain thermoreflectance. Furthermore, the thermal transport is described by a two-partmodel where the electrical contribution is quantified via the Wiedemann-Franz relation and the vibrational contribution by the minimum thermal conductivity limit for amorphous solids. Additionally, the vibrational contribution remains constant near 0.9 W/mK regardless of oxygen concentration, while the electrical contribution varies from 0 to 3.3 W/mK. Thus, the dominant thermal carrier in TaOx switches between vibrations and charge carriers and is controllable either by oxygen content during deposition, or dynamically by field-induced chargemore » state migration.« less

  10. Thermal transport in tantalum oxide films for memristive applications

    SciTech Connect (OSTI)

    Landon, Colin Donald; Wilke, Rudeger H. T.; Brumbach, Michael T.; Brennecka, Geoffrey L.; Blea-Kirby, Mia Angelica; Ihlefeld, Jon; Marinella, Matthew; Thomas Edwin Beechem

    2015-07-15

    The thermal conductivity of amorphous TaOx memristive films having variable oxygen content is measured using time domain thermoreflectance. Furthermore, the thermal transport is described by a two-partmodel where the electrical contribution is quantified via the Wiedemann-Franz relation and the vibrational contribution by the minimum thermal conductivity limit for amorphous solids. Additionally, the vibrational contribution remains constant near 0.9 W/mK regardless of oxygen concentration, while the electrical contribution varies from 0 to 3.3 W/mK. Thus, the dominant thermal carrier in TaOx switches between vibrations and charge carriers and is controllable either by oxygen content during deposition, or dynamically by field-induced charge state migration.

  11. Crediting Tritium Deposition in Accident Analysis

    SciTech Connect (OSTI)

    Murphy, C.E. Jr.

    2001-06-20

    This paper describes the major aspects of tritium dispersion phenomenology, summarizes deposition attributes of the computer models used in the DOE Complex for tritium dispersion, and recommends an approach to account for deposition in accident analysis.

  12. Multilayer thermal barrier coating systems

    DOE Patents [OSTI]

    Vance, Steven J.; Goedjen, John G.; Sabol, Stephen M.; Sloan, Kelly M.

    2000-01-01

    The present invention generally describes multilayer thermal barrier coating systems and methods of making the multilayer thermal barrier coating systems. The thermal barrier coating systems comprise a first ceramic layer, a second ceramic layer, a thermally grown oxide layer, a metallic bond coating layer and a substrate. The thermal barrier coating systems have improved high temperature thermal and chemical stability for use in gas turbine applications.

  13. Thermal Properties Measurement Report

    SciTech Connect (OSTI)

    Carmack, Jon; Braase, Lori; Papesch, Cynthia; Hurley, David; Tonks, Michael; Zhang, Yongfeng; Gofryk, Krzysztof; Harp, Jason; Fielding, Randy; Knight, Collin; Meyer, Mitch

    2015-08-01

    The Thermal Properties Measurement Report summarizes the research, development, installation, and initial use of significant experimental thermal property characterization capabilities at the INL in FY 2015. These new capabilities were used to characterize a U3Si2 (candidate Accident Tolerant) fuel sample fabricated at the INL. The ability to perform measurements at various length scales is important and provides additional data that is not currently in the literature. However, the real value of the data will be in accomplishing a phenomenological understanding of the thermal conductivity in fuels and the ties to predictive modeling. Thus, the MARMOT advanced modeling and simulation capability was utilized to illustrate how the microstructural data can be modeled and compared with bulk characterization data. A scientific method was established for thermal property measurement capability on irradiated nuclear fuel samples, which will be installed in the Irradiated Material Characterization Laboratory (IMCL).

  14. Thermal insulations using vacuum panels

    DOE Patents [OSTI]

    Glicksman, Leon R.; Burke, Melissa S.

    1991-07-16

    Thermal insulation vacuum panels are formed of an inner core of compressed low thermal conductivity powders enclosed by a ceramic/glass envelope evaluated to a low pressure.

  15. Underhood Thermal Performance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Underhood Thermal Performance This email address is being protected from spambots. You need JavaScript enabled to view it. - Computational Fluid Dynamics Project Leader Background As vehicle technology advances, automakers need a better understanding of underhood heat loads, especially as they relate to emissions and fuel efficiency. Manufacturers of heavy-duty vehicles and off-road machines have similar concerns. Ineffective underhood thermal management can lead to higher emissions, reduced

  16. Turbine Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbine Thermal Management Fact Sheets Research Team Members Key Contacts Turbine Thermal Management The gas turbine is the workhorse of power generation, and technology advances to current land-based turbines are directly linked to our country's economic and energy security. Technical advancement for any type of gas turbine generally implies better performance, greater efficiency, and extended component life. From the standpoint of cycle efficiency and durability, this suggests that a continual

  17. Photovoltaic-thermal collectors

    DOE Patents [OSTI]

    Cox, III, Charles H. (Carlisle, MA)

    1984-04-24

    A photovoltaic-thermal solar cell including a semiconductor body having antireflective top and bottom surfaces and coated on each said surface with a patterned electrode covering less than 10% of the surface area. A thermal-absorbing surface is spaced apart from the bottom surface of the semiconductor and a heat-exchange fluid is passed between the bottom surface and the heat-absorbing surface.

  18. Thermal sprayed composite melt containment tubular component and method of making same

    DOE Patents [OSTI]

    Besser, Matthew F. (Urbandale, IA); Terpstra, Robert L. (Ames, IA); Sordelet, Daniel J. (Ames, IA); Anderson, Iver E. (Ames, IA)

    2002-03-19

    A tubular thermal sprayed melt containment component for transient containment of molten metal or alloy wherein the tubular member includes a thermal sprayed inner melt-contacting layer for contacting molten metal or alloy to be processed, a thermal sprayed heat-generating layer deposited on the inner layer, and an optional thermal sprayed outer thermal insulating layer. The thermal sprayed heat-generating layer is inductively heated as a susceptor of an induction field or electrical resistively heated by passing electrical current therethrough. The tubular thermal sprayed melt containment component can comprise an elongated melt pour tube of a gas atomization apparatus where the melt pour tube supplies molten material from a crucible to an underlying melt atomization nozzle.

  19. Uncooled thin film pyroelectric IR detector with aerogel thermal isolation

    DOE Patents [OSTI]

    Ruffner, Judith A.; Bullington, Jeff A.; Clem, Paul G.; Warren, William L.; Brinker, C. Jeffrey; Tuttle, Bruce A.; Schwartz, Robert W.

    1999-01-01

    A monolithic infrared detector structure which allows integration of pyroelectric thin films atop low thermal conductivity aerogel thin films. The structure comprises, from bottom to top, a substrate, an aerogel insulating layer, a lower electrode, a pyroelectric layer, and an upper electrode layer capped by a blacking layer. The aerogel can offer thermal conductivity less than that of air, while providing a much stronger monolithic alternative to cantilevered or suspended air-gap structures for pyroelectric thin film pixel arrays. Pb(Zr.sub.0.4 Ti.sub.0.6)O.sub.3 thin films deposited on these structures displayed viable pyroelectric properties, while processed at 550.degree. C.

  20. Thick adherent dielectric films on plastic substrates and method for depositing same

    DOE Patents [OSTI]

    Wickboldt, Paul; Ellingboe, Albert R.; Theiss, Steven D.; Smith, Patrick M.

    2002-01-01

    Thick adherent dielectric films deposited on plastic substrates for use as a thermal barrier layer to protect the plastic substrates from high temperatures which, for example, occur during laser annealing of layers subsequently deposited on the dielectric films. It is desirable that the barrier layer has properties including: a thickness of 1 .mu.m or greater, adheres to a plastic substrate, does not lift-off when cycled in temperature, has few or no cracks and does not crack when subjected to bending, resistant to lift-off when submersed in fluids, electrically insulating and preferably transparent. The thick barrier layer may be composed, for example, of a variety of dielectrics and certain metal oxides, and may be deposited on a variety of plastic substrates by various known deposition techniques. The key to the method of forming the thick barrier layer on the plastic substrate is maintaining the substrate cool during deposition of the barrier layer. Cooling of the substrate maybe accomplished by the use of a cooling chuck on which the plastic substrate is positioned, and by directing cooling gas, such as He, Ar and N.sub.2, between the plastic substrate and the cooling chucks. Thick adherent dielectric films up to about 5 .mu.m have been deposited on plastic substrates which include the above-referenced properties, and which enable the plastic substrates to withstand laser processing temperatures applied to materials deposited on the dielectric films.

  1. Vacuum deposited polymer films: Past, present, and future applications

    SciTech Connect (OSTI)

    Affinito, J.; Martin, P.; Gross, M.; Bennett, W.

    1994-11-01

    Two extremely high rate processes have been developed for the vacuum deposition of polymer thin films. Dubbed the PML (for Polymer Multi-Layer) and LML (for Liquid Multi-Layer) processes, the PML technique was originally developed for the manufacture of polymer/aluminum surface mount capacitors while the LML method arose from a need to fabricate lithium polymer batteries. These processes have since been found to be compatible with most other vacuum deposition techniques in, integrated, in-line coating processes. Battelle has developed an extensive program, and a great deal of hardware, to pursue a wide variety of PML and LML applications which integrate these two process technologies with other, conventional, vacuum deposition methods. The historical development of the technologies is reviewed and the Battelle PML/LML facilities are described. Current Battelle work involving solar thermal control films, PML QWOTs, and polymer/metal high reflectors are also discussed. Battelle PML work that is just starting, involving non-linear optical materials/devices, lithium polymer battery fabrication, electrochromic devices, and polymer/oxide multilayers, is discussed as well.

  2. Success Story: Chrome Deposit Corporation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Success Story: Chrome Deposit Corporation Success Story: Chrome Deposit Corporation This case study describes how Chrome Deposit Corporation was able to reduce plant-wide energy ...

  3. Chemical vapor deposition of epitaxial silicon

    DOE Patents [OSTI]

    Berkman, Samuel

    1984-01-01

    A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

  4. Metal deposition using seed layers

    DOE Patents [OSTI]

    Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

    2013-11-12

    Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

  5. Chemical vapor deposition of sialon

    DOE Patents [OSTI]

    Landingham, Richard L.; Casey, Alton W.

    1982-01-01

    A laminated composite and a method for forming the composite by chemical vapor deposition. The composite includes a layer of sialon and a material to which the layer is bonded. The method includes the steps of exposing a surface of the material to an ammonia containing atmosphere; heating the surface to at least about 1200.degree. C.; and impinging a gas containing in a flowing atmosphere of air N.sub.2, SiCl.sub.4, and AlCl.sub.3 on the surface.

  6. Bond strength and stress measurements in thermal barrier coatings

    SciTech Connect (OSTI)

    Gell, M.; Jordan, E.

    1995-12-31

    Thermal barrier coatings have been used extensively in aircraft gas turbines for more than 15 years to insulate combustors and turbine vanes from the hot gas stream. Plasma sprayed thermal barrier coatings (TBCs) provide metal temperature reductions as much as 300{degrees}F, with improvements in durability of two times or more being achieved. The introduction of TBCs deposited by electron beam physical vapor deposition (EB-PVD) processes in the last five years has provided a major improvement in durability and also enabled TBCs to be applied to turbine blades for improved engine performance. This program evaluates the bond strength of yttria stabilized zirconia coatings with MCrAlY and Pt-Al bond coats utilizing diffraction and fluorescence methods.

  7. Thermal decomposition of silane to form hydrogenated amorphous Si

    DOE Patents [OSTI]

    Strongin, M.; Ghosh, A.K.; Wiesmann, H.J.; Rock, E.B.; Lutz, H.A. III

    Hydrogenated amorphous silicon is produced by thermally decomposing silane (SiH/sub 4/) or other gases comprising H and Si, at elevated temperatures of about 1700 to 2300/sup 0/C, in a vacuum of about 10/sup -8/ to 10/sup -4/ torr. A gaseous mixture is formed of atomic hydrogen and atomic silicon. The gaseous mixture is deposited onto a substrate to form hydrogenated amorphous silicon.

  8. Vacuum thermal evaporation of polyaniline doped with camphor sulfonic acid

    SciTech Connect (OSTI)

    Boyne, Devon; Menegazzo, Nicola; Pupillo, Rachel C.; Rosenthal, Joel; Booksh, Karl S.

    2015-05-15

    Intrinsically conducting polymers belong to a class of organic polymers with intriguing electronic and physical properties specifically for electro-optical applications. Significant interest into doped polyaniline (PAni) can be attributed to its high conductivity and environmental stability. Poor dissolution in most solvents has thus far hindered the successful integration of PAni into commercial applications, which in turn, has led to the investigations of various deposition and acidic doping methods. Physical vapor deposition methods, including D.C. magnetron sputtering and vacuum thermal evaporation, have shown exceptional control over physical film properties (thickness and morphology). However, resulting films are less conductive than films deposited by conventional methods (i.e., spin and drop casting) due to interruption of the hyperconjugation of polymer chains. Specifically, vacuum thermal evaporation requires a postdoping process, which results in incorporation of impurities and oxidation of surface moieties. In this contribution, thermally evaporated films, sequentially doped by vacuum evaporation of an organic acid (camphorsulfonic acid, CSA) is explored. Spectroscopic evidence confirms the successful doping of PAni with CSA while physical characterization (atomic force microscopy) suggests films retain good morphology and are not damaged by the doping process. The procedure presented herein also combines other postpreparation methods in an attempt to improve conductivity and/or substrate adhesion.

  9. Highly directional thermal emitter

    DOE Patents [OSTI]

    Ribaudo, Troy; Shaner, Eric A; Davids, Paul; Peters, David W

    2015-03-24

    A highly directional thermal emitter device comprises a two-dimensional periodic array of heavily doped semiconductor structures on a surface of a substrate. The array provides a highly directional thermal emission at a peak wavelength between 3 and 15 microns when the array is heated. For example, highly doped silicon (HDSi) with a plasma frequency in the mid-wave infrared was used to fabricate nearly perfect absorbing two-dimensional gratings structures that function as highly directional thermal radiators. The absorption and emission characteristics of the HDSi devices possessed a high degree of angular dependence for infrared absorption in the 10-12 micron range, while maintaining high reflectivity of solar radiation (.about.64%) at large incidence angles.

  10. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, S.E.; Arasteh, D.K.; Hartmann, J.L.

    1988-04-05

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas. 2 figs.

  11. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, Stephen E. (Piedmont, CA); Arasteh, Dariush K. (Oakland, CA); Hartmann, John L. (Seattle, WA)

    1991-01-01

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas.

  12. Thermal trim for luminaire

    DOE Patents [OSTI]

    Bazydola, Sarah; Ghiu, Camil-Daniel; Harrison, Robert; Jeswani, Anil

    2013-11-19

    A luminaire with a thermal pathway to reduce the junction temperature of the luminaire's light source, and methods for so doing, are disclosed. The luminaire includes a can, a light engine, and a trim, that define a substantially continuous thermal pathway from the light engine to a surrounding environment. The can defines a can cavity and includes a can end region. The light engine is within the can cavity and includes a light source and a heat sink, including a heat sink end region, coupled thereto. The trim is at least partially disposed within the can cavity and includes a first trim end region coupled to the heat sink end region and a second trim end region coupled to the can end region. Thermal interface material may be located between: the heat sink and the trim, the trim and the can, and/or the heat sink and the light source.

  13. Article for thermal energy storage

    DOE Patents [OSTI]

    Salyer, Ival O.

    2000-06-27

    A thermal energy storage composition is provided which is in the form of a gel. The composition includes a phase change material and silica particles, where the phase change material may comprise a linear alkyl hydrocarbon, water/urea, or water. The thermal energy storage composition has a high thermal conductivity, high thermal energy storage, and may be used in a variety of applications such as in thermal shipping containers and gel packs.

  14. Local deposition of high-purity Pt nanostructures by combining electron beam induced deposition and atomic layer deposition

    SciTech Connect (OSTI)

    Mackus, A. J. M.; Sanden, M. C. M. van de; Kessels, W. M. M.; Mulders, J. J. L.

    2010-06-15

    An approach for direct-write fabrication of high-purity platinum nanostructures has been developed by combining nanoscale lateral patterning by electron beam induced deposition (EBID) with area-selective deposition of high quality material by atomic layer deposition (ALD). Because virtually pure, polycrystalline Pt nanostructures are obtained, the method extends the application possibilities of EBID, whereas compared to other area-selective ALD approaches, a much higher resolution is attainable; potentially down to sub-10 nm lateral dimensions.

  15. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, Roy; Kakwani, Ramesh M.; Valdmanis, Edgars; Woods, Melvins E.

    1988-01-01

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m.degree. C. and a specific heat greater than 480 J/kg.degree. C. with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber.

  16. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

    1988-04-19

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

  17. Factors affecting the microstructural stability and durability of thermal barrier coatings fabricated by air plasma spraying

    SciTech Connect (OSTI)

    Helminiak, M. A.; Yanar, N. M.; Pettit, F. S.; Taylor, T. A.; Meier, G. H.

    2012-10-01

    The high-temperature behavior of high-purity, low-density (HP-LD) air plasma sprayed (APS) thermal barrier coatings (TBCs) with NiCoCrAlY bond coats deposited by argon-shrouded plasma spraying is described. The high purity yttria-stabilized zirconia resulted in top coats which are highly resistant to sintering and transformation from the metastable tetragonal phase to the equilibrium mixture of monoclinic and cubic phases. The thermal conductivity of the as-processed TBC is low but increases during high temperature exposure even before densification occurs. The porous topcoat microstructure also resulted in good spallation resistance during thermal cycling. The actual failure mechanisms of the APS coatings were found to depend on topcoat thickness, topcoat density, and the thermal cycle frequency. The failure mechanisms are described and the durability of the HP-LD coatings is compared with that of state-of-the-art electron beam physical vapor deposition TBCs.

  18. Thermally conductive alumina/organic composites for photovoltaic concentrator cell isolation

    SciTech Connect (OSTI)

    Beavis, L.C.; Panitz, J.K.G.; Sharp, D.J.

    1988-01-01

    Electrophoretically deposited styrene-acrylate films were studied. These yield marginally useful thermal conductivities of 0.1--0.2 watts/meter-Kelvin, but have useful dielectric strengths over 2500 volts for 40 micrometer thick coatings. Thin, 25 micrometer, coatings of anodically grown Al/sub 2/O/sub 3/ films were also investigated. These films have thermal conductivities of approximately 6--8 watts/meter-Kelvin. Although these Al/sub 2/O/sub 3/ films have greater thermal conductivity than the polymer films, they exhibit porosity which typically limits their dielectric strength to less than 1000 volts. In the current study we have determined that styrene-acrylate can be electrophoretically deposited in porous anodic aluminum oxide films to form an alumina-organic composite with improved electrical breakdown strengths as well as higher thermal conductivity than styrene-acrylate films. 7 refs., 2 tabs.

  19. Modeling particle deposition on HVAC heat exchangers

    SciTech Connect (OSTI)

    Siegel, J.A.; Nazaroff, W.W.

    2002-01-01

    Fouling of fin-and-tube heat exchangers by particle deposition leads to diminished effectiveness in supplying ventilation and air conditioning. This paper explores mechanisms that cause particle deposition on heat exchanger surfaces. We present a model that accounts for impaction, diffusion, gravitational settling, and turbulence. Simulation results suggest that some submicron particles deposit in the heat exchanger core, but do not cause significant performance impacts. Particles between 1 and 10 {micro}m deposit with probabilities ranging from 1-20% with fin edge impaction representing the dominant mechanism. Particles larger than 10 {micro}m deposit by impaction on refrigerant tubes, gravitational settling on fin corrugations, and mechanisms associated with turbulent airflow. The model results agree reasonably well with experimental data, but the deposition of larger particles at high velocities is underpredicted. Geometric factors, such as discontinuities in the fins, are hypothesized to be responsible for the discrepancy.

  20. Ocean thermal energy conversion

    SciTech Connect (OSTI)

    Avery, W.H.

    1983-03-17

    A brief explanation of the Ocean Thermal Energy Conversion (OTEC) concept and an estimate of the amount of energy that can be produced from the ocean resource without introducing environmental concerns are presented. Use of the OTEC system to generate electric power and products which can replace fossil fuels is shown. The OTEC program status and its prospects for the future are discussed.

  1. Thermal Reactor Safety

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Information is presented concerning fire risk and protection; transient thermal-hydraulic analysis and experiments; class 9 accidents and containment; diagnostics and in-service inspection; risk and cost comparison of alternative electric energy sources; fuel behavior and experiments on core cooling in LOCAs; reactor event reporting analysis; equipment qualification; post facts analysis of the TMI-2 accident; and computational methods.

  2. Thermal barrier coating

    DOE Patents [OSTI]

    Bowker, Jeffrey Charles; Sabol, Stephen M.; Goedjen, John G.

    2001-01-01

    A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

  3. Giant landslide deposits in northwest Argentina

    SciTech Connect (OSTI)

    Fauque, L.; Strecker, M.R.; Bloom, A.L.

    1985-01-01

    Giant Quaternary landslide deposits occur along mountain fronts in the structural transition zone between the high-angle reverse-fault-bounded Sierras Pampeanas and the low-angle thrust belt of the Sierras Subandinas. There are two modes of occurrence: (1) chaotic masses without distinct geometry, and (2) masses with distinct lobate geometry similar to glacial moraines. Type (1) deposits occur where the moving rock mass followed a narrow valley and blocked the drainage. Many of these caused subsequent formation of lakes and changed the sedimentation processes on pediments at the mountain fronts. In type (2) deposits, lateral and frontal ridges are up to 10 m higher than the interior parts; in some places pressure ridges within the lobes are well preserved. Type (2) deposits show reverse grading and were deposited on relatively smooth pediments or alluvial fans. The lobate geometry strongly suggests that type (2) deposits are a product of flowage and are debris stream or sturzstrom deposits (sense of Heim, 1932 and Hsu, 1975). All investigated deposits occur in areas of demonstrated Quaternary faulting and are interpreted as the result of tectonic movements, although structural inhomogeneities in the source area may have been a significant factor for some of the landslides. No datable materials have yet been found associated with the deposits.

  4. Selective deposition of nanostructured ruthenium oxide using...

    Office of Scientific and Technical Information (OSTI)

    Title: Selective deposition of nanostructured ruthenium oxide using Tobacco mosaic virus for micro-supercapacitors in solid Nafion electrolyte Authors: Gnerlich, Markus ; Ben-Yoav, ...

  5. Hydrothermally Deposited Rock | Open Energy Information

    Open Energy Info (EERE)

    at Paleochori, Milos, Greece. http:www.photovolcanica.comVolcanoInfoMilosMilos.html Hydrothermally deposited rock includes rocks and minerals that have precipitated from...

  6. Other Hydrothermal Deposits | Open Energy Information

    Open Energy Info (EERE)

    Capping Other Hydrothermal Alteration Products Colorful hydrothermal deposits dot the landscape at the Hverir Geothermal Area, Iceland. Photo by Darren Atkins User-specified field...

  7. Advanced thermally stable jet fuels. Technical progress report, April 1996--June 1996

    SciTech Connect (OSTI)

    Schobert, H.H.; Eser, S.; Song, C.

    1996-11-01

    The Penn State program in advanced thermally stable jet fuels has five components: (1) development of mechanisms of degradation and solids formation: (2) quantitative measurement of growth of sub-micrometer and micrometer-sized particles during thermal stressing; (3) characterization of carbonaceous deposits by various instrumental and microscopic methods: (4) elucidation of the role of additives in retarding the formation of carbonaceous solids; and (5) assessment of the potential of producing high yields of cycloalkanes and hydroaromatics from coal.

  8. Advanced thermally stable jet fuels. Technical progress report, July 1995--September 1995

    SciTech Connect (OSTI)

    Schobert, H.H.; Eser, S.; Song, C.

    1995-10-01

    The Penn State program in advanced thermally stable jet engine fuels has five components: development of mechanisms of degradation and solids formation; quantitative measurement of growth of sub-micrometer-sized and micrometer particles suspended in fuels during thermal stresses; characterization of carbonaceous deposits by various instrumental and microscopic methods; elucidation of the role of additives in retarding the formation of carbonaceous solids; and assessment of the potential of producing high yields of cycloalkanes and hydroaromatics by direct coal liquefaction. Progress is described.

  9. THERMAL PROCESSES GOVERNING HOT-JUPITER RADII (Journal Article) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect THERMAL PROCESSES GOVERNING HOT-JUPITER RADII Citation Details In-Document Search Title: THERMAL PROCESSES GOVERNING HOT-JUPITER RADII There have been many proposed explanations for the larger-than-expected radii of some transiting hot Jupiters, including either stellar or orbital energy deposition deep in the atmosphere or deep in the interior. In this paper, we explore the important influences on hot-Jupiter radius evolution of (1) additional heat sources in the high atmosphere,

  10. Fabrication of thermal microphotonic sensors and sensor arrays

    DOE Patents [OSTI]

    Shaw, Michael J. (Tijeras, NM); Watts, Michael R. (Albuquerque, NM); Nielson, Gregory N. (Albuquerque, NM)

    2010-10-26

    A thermal microphotonic sensor is fabricated on a silicon substrate by etching an opening and a trench into the substrate, and then filling in the opening and trench with silicon oxide which can be deposited or formed by thermally oxidizing a portion of the silicon substrate surrounding the opening and trench. The silicon oxide forms a support post for an optical resonator which is subsequently formed from a layer of silicon nitride, and also forms a base for an optical waveguide formed from the silicon nitride layer. Part of the silicon substrate can be selectively etched away to elevate the waveguide and resonator. The thermal microphotonic sensor, which is useful to detect infrared radiation via a change in the evanescent coupling of light between the waveguide and resonator, can be formed as a single device or as an array.

  11. EMBEDDED OPTICAL SENSORS FOR THERMAL BARRIER COATINGS

    SciTech Connect (OSTI)

    David R. Clarke

    2004-12-16

    In this first year of the program we have focused on the selection of rare-earth dopants for luminescent sensing in thermal barrier coating materials, the effect of dopant concentration on several of the luminescence characteristics and initial fabrication of one type of embedded sensor, the ''red-line'' sensor. We have initially focused on erbium as the lanthanide dopant for luminescence doping of yttria-stabilized zirconia and europium as the lanthanide for luminescence doping of gadolinium zirconate. The latter exhibits a temperature-dependent luminescence lifetime up to at least 1100 C. A buried layer, ''red-line'' sensor in an electron-beam deposited yttria-stabilized zirconia coating with erbium has been demonstrated and exhibits a temperature-dependent luminescence lifetime up to at least 400 C.

  12. Thermal barrier coating resistant to sintering

    DOE Patents [OSTI]

    Subramanian, Ramesh; Seth, Brig B.

    2005-08-23

    A device (10) is made, having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10), is not soluble with the underlying ceramic layer (16) and is applied by a process that is not an electron beam physical vapor deposition process. The sintering inhibiting material (22) has a morphology adapted to improve the functionality of the sintering inhibiting material (22), characterized as continuous, nodule, rivulet, grain, crack, flake and combinations thereof and being disposed within at least some of the vertical and horizontal gaps.

  13. Optical Properties of Zn(O,S) Thin Films Deposited by RF Sputtering, Atomic Layer Deposition, and Chemical Bath Deposition: Preprint

    SciTech Connect (OSTI)

    Li, J.; Glynn, S.; Christensen, S.; Mann, J.; To, B.; Ramanathan, K.; Noufi, R.; Furtak, T. E.; Levi, D.

    2012-06-01

    Zn(O,S) thin films 27 - 100 nm thick were deposited on glass or Cu(InxGa1-x)Se2/Molybdenum/glass with RF sputtering, atomic layer deposition, and chemical bath deposition.

  14. Liquid-phase-deposited siloxane-based capping layers for silicon solar cells

    SciTech Connect (OSTI)

    Veith-Wolf, Boris; Wang, Jianhui; Hannu-Kuure, Milja; Chen, Ning; Hadzic, Admir; Williams, Paul; Leivo, Jarkko; Karkkainen, Ari; Schmidt, Jan

    2015-02-02

    We apply non-vacuum processing to deposit dielectric capping layers on top of ultrathin atomic-layer-deposited aluminum oxide (AlO{sub x}) films, used for the rear surface passivation of high-efficiency crystalline silicon solar cells. We examine various siloxane-based liquid-phase-deposited (LPD) materials. Our optimized AlO{sub x}/LPD stacks show an excellent thermal and chemical stability against aluminum metal paste, as demonstrated by measured surface recombination velocities below 10 cm/s on 1.3 Ωcm p-type silicon wafers after firing in a belt-line furnace with screen-printed aluminum paste on top. Implementation of the optimized LPD layers into an industrial-type screen-printing solar cell process results in energy conversion efficiencies of up to 19.8% on p-type Czochralski silicon.

  15. Effect of substrate pretreatments on the atomic layer deposited Al{sub 2}O{sub 3} passivation quality

    SciTech Connect (OSTI)

    Bao, Yameng; Li, Shuo Gastrow, Guillaume von; Repo, Pivikki; Savin, Hele; Putkonen, Matti

    2015-01-15

    The authors show here that the passivation quality of Al{sub 2}O{sub 3} is highly sensitive to the surface condition prior to the atomic layer deposition, affecting especially the thermal stability of the film. Pretreatments like diluted HCl bath or preheating at 200?C both improved significantly the passivation quality and thermal stability of the films. In addition, the authors observed that a thin chemical SiO{sub 2} layer resulting from diluted HCl solves the blistering problem often encountered in H{sub 2}O based atomic layer deposited process. Finally, the authors show that the chemical oxide protects the surface from contaminants, enabling long storage times in a dirty ambient between the cleaning and the film deposition.

  16. Ammonia release method for depositing metal oxides

    DOE Patents [OSTI]

    Silver, G.L.; Martin, F.S.

    1994-12-13

    A method is described for depositing metal oxides on substrates which is indifferent to the electrochemical properties of the substrates and which comprises forming ammine complexes containing metal ions and thereafter effecting removal of ammonia from the ammine complexes so as to permit slow precipitation and deposition of metal oxide on the substrates. 1 figure.

  17. Ammonia release method for depositing metal oxides

    DOE Patents [OSTI]

    Silver, Gary L.; Martin, Frank S.

    1994-12-13

    A method of depositing metal oxides on substrates which is indifferent to the electrochemical properties of the substrates and which comprises forming ammine complexes containing metal ions and thereafter effecting removal of ammonia from the ammine complexes so as to permit slow precipitation and deposition of metal oxide on the substrates.

  18. Atomic Layer Deposition | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic Layer Deposition New nanophase thin film materials with properties tailored to specifically meet the needs of industry New software simulates ALD over multiple length scale, saving industry time and money on developing specialized tools PDF icon Atomic_Layer_Deposition

  19. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  20. EGR Cooler Deposit Analysis | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Analysis of fouling and performance of exhaust gas recirculation (EGR) coolers as a function of EGR flow rate, inlet gas and coolant temperatures, soot level, and hydrocarbon concentration PDF icon deer11_lance.pdf More Documents & Publications Materials Issues Associated with EGR Systems (Agreement ID:18571) Microstructural Evolution of EGR Cooler Deposits Characterization of Field-Aged Exhaust Gas Recirculation Cooler Deposits

  1. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    Smith, P.; Deo, M.; Eddings, E.; Sarofim, A.; Gueishen, K.; Hradisky, M.; Kelly, K.; Mandalaparty, P.; Zhang, H.

    2012-01-11

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coal's carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO2 sequestration.

  2. Thermal synthesis apparatus

    DOE Patents [OSTI]

    Fincke, James R. [Idaho Falls, ID; Detering, Brent A. [Idaho Falls, ID

    2009-08-18

    An apparatus for thermal conversion of one or more reactants to desired end products includes an insulated reactor chamber having a high temperature heater such as a plasma torch at its inlet end and, optionally, a restrictive convergent-divergent nozzle at its outlet end. In a thermal conversion method, reactants are injected upstream from the reactor chamber and thoroughly mixed with the plasma stream before entering the reactor chamber. The reactor chamber has a reaction zone that is maintained at a substantially uniform temperature. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle, which "freezes" the desired end product(s) in the heated equilibrium reaction stage, or is discharged through an outlet pipe without the convergent-divergent nozzle. The desired end products are then separated from the gaseous stream.

  3. Thermally stable diamond brazing

    DOE Patents [OSTI]

    Radtke, Robert P. (Kingwood, TX)

    2009-02-10

    A cutting element and a method for forming a cutting element is described and shown. The cutting element includes a substrate, a TSP diamond layer, a metal interlayer between the substrate and the diamond layer, and a braze joint securing the diamond layer to the substrate. The thickness of the metal interlayer is determined according to a formula. The formula takes into account the thickness and modulus of elasticity of the metal interlayer and the thickness of the TSP diamond. This prevents the use of a too thin or too thick metal interlayer. A metal interlayer that is too thin is not capable of absorbing enough energy to prevent the TSP diamond from fracturing. A metal interlayer that is too thick may allow the TSP diamond to fracture by reason of bending stress. A coating may be provided between the TSP diamond layer and the metal interlayer. This coating serves as a thermal barrier and to control residual thermal stress.

  4. Thermal reactor safety

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Information is presented concerning new trends in licensing; seismic considerations and system structural behavior; TMI-2 risk assessment and thermal hydraulics; statistical assessment of potential accidents and verification of computational methods; issues with respect to improved safety; human factors in nuclear power plant operation; diagnostics and activities in support of recovery; LOCA transient analysis; unresolved safety issues and other safety considerations; and fission product transport.

  5. Thermally actuated thermionic switch

    DOE Patents [OSTI]

    Barrus, Donald M.; Shires, Charles D.

    1988-01-01

    A thermally actuated thermionic switch which responds to an increase of temperature by changing from a high impedance to a low impedance at a predictable temperature set point. The switch has a bistable operation mode switching only on temperature increases. The thermionic material may be a metal which is liquid at the desired operation temperature and held in matrix in a graphite block reservoir, and which changes state (ionizes, for example) so as to be electrically conductive at a desired temperature.

  6. Thermally actuated thermionic switch

    DOE Patents [OSTI]

    Barrus, D.M.; Shires, C.D.

    1982-09-30

    A thermally actuated thermionic switch which responds to an increase of temperature by changing from a high impedance to a low impedance at a predictable temperature set point. The switch has a bistable operation mode switching only on temperature increases. The thermionic material may be a metal which is liquid at the desired operation temperature and held in matrix in a graphite block reservoir, and which changes state (ionizes, for example) so as to be electrically conductive at a desired temperature.

  7. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  8. Solar Thermal Electric | Open Energy Information

    Open Energy Info (EERE)

    Thermal Electric Jump to: navigation, search TODO: Add description List of Solar Thermal Electric Incentives Retrieved from "http:en.openei.orgwindex.php?titleSolarThermalEl...

  9. Power Electronic Thermal System Performance and Integration ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Motor Thermal Control Thermal Stress and Reliability for Advanced Power Electronics and Electric Machines Integrated Vehicle Thermal Management

  10. Ocean Thermal Extractable Energy Visualization: Final Technical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ocean Thermal Extractable Energy Visualization: Final Technical Report Ocean Thermal Extractable Energy Visualization: Final Technical Report Report about the Ocean Thermal ...

  11. Methods of forming thermal management systems and thermal management methods

    DOE Patents [OSTI]

    Gering, Kevin L.; Haefner, Daryl R.

    2012-06-05

    A thermal management system for a vehicle includes a heat exchanger having a thermal energy storage material provided therein, a first coolant loop thermally coupled to an electrochemical storage device located within the first coolant loop and to the heat exchanger, and a second coolant loop thermally coupled to the heat exchanger. The first and second coolant loops are configured to carry distinct thermal energy transfer media. The thermal management system also includes an interface configured to facilitate transfer of heat generated by an internal combustion engine to the heat exchanger via the second coolant loop in order to selectively deliver the heat to the electrochemical storage device. Thermal management methods are also provided.

  12. Thermal and Non-thermal Physiochemical Processes in Nanoscale Films of Amorphous Solid Water

    SciTech Connect (OSTI)

    Smith, R. Scott; Petrik, Nikolay G.; Kimmel, Gregory A.; Kay, Bruce D.

    2012-01-17

    Amorphous solid water (ASW) is a metastable form of water created by vapor deposition onto a cold substrate (typically less than 130 K). Since this unusual form of water only exists on earth in laboratories with highly specialized equipment, it is fair to ask why there is any interest in studying this esoteric material. Much of the scientific interest involves using ASW as a model system to explore the physical and reactive properties of liquid water and aqueous solutions. Other researchers are interested in ASW because it is believed to be the predominate form of water in the extreme cold temperatures found in many astrophysical and planetary environments. In addition, ASW is a convenient model system for studying the stability of metastable systems (glasses) and the properties of highly porous materials. A fundamental understanding of such properties has applications in a diverse range of disciplines including cryobiology, food science, pharmaceuticals, astrophysics and nuclear waste storage among others.There exist several excellent reviews on the properties of ASW and supercooled liquid water and a new comprehensive review is beyond the scope of this Account. Instead, we focus on our research over the past 15 years using molecular beams and surface science techniques to probe the thermal and non thermal properties of nanoscale films of ASW. We use molecular beams to precisely control the deposition conditions (flux, incident, energy, incident angle) to create compositionally-tailored, nanoscale films of ASW at low temperatures. To study the transport properties (viscosity, diffusivity), the amorphous films can be heated above their glass transition temperatures, Tg, at which time they transform into deeply supercooled liquids prior to crystallization. The advantage of this approach is that at temperatures near Tg the viscosity is approximately 15 orders of magnitude larger than a normal liquid, and therefore the crystallization kinetics are dramatically slowed, increasing the time available for experiments. For example, near Tg, on a typical laboratory time scale (e.g. {approx}1000 s), a water molecule moves less than a molecular distance. For this reason, nanoscale films help to probe the behavior and reactions of supercooled liquid at these low temperatures. ASW films can be used for investigating the non-thermal reactions relevant to radiolysis. In this account we will present a survey of our research on the thermal and non thermal properties of ASW using this approach.

  13. Thermal conductivity of vertically aligned carbon nanotube arrays: Growth conditions and tube inhomogeneity

    SciTech Connect (OSTI)

    Bauer, Matthew L.; Pham, Quang N.; Saltonstall, Christopher B.; Norris, Pamela M.

    2014-10-13

    The thermal conductivity of vertically aligned carbon nanotube arrays (VACNTAs) grown on silicon dioxide substrates via chemical vapor deposition is measured using a 3ω technique. For each sample, the VACNTA layer and substrate are pressed to a heating line at varying pressures to extract the sample's thermophysical properties. The nanotubes' structure is observed via transmission electron microscopy and Raman spectroscopy. The presence of hydrogen and water vapor in the fabrication process is tuned to observe the effect on measured thermal properties. The presence of iron catalyst particles within the individual nanotubes prevents the array from achieving the overall thermal conductivity anticipated based on reported measurements of individual nanotubes and the packing density.

  14. Thermal barrier coating having high phase stability

    DOE Patents [OSTI]

    Subramanian, Ramesh

    2001-01-01

    A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating layer (20) characterized by a microstructure having gaps (28) where the thermal barrier coating (20) consists essentially of a pyrochlore crystal structure having a chemical formula consisting essentially of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements selected from La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof; where B is selected from the group of elements selected from Zr, Hf, Ti and mixtures thereof; n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

  15. Modelling the microstructure of thermal barrier coatings

    SciTech Connect (OSTI)

    Cirolini, S.; Marchese, M.; Jacucci, G.; Harding, J.H.; Mulheran, P.A.

    1994-12-31

    Thermal barrier coatings produced by plasma spraying have a characteristic microstructure of lamellae, pores and cracks. The lamellae are produced by the splashing of particles onto the substrate. As the coating grows, the lamellae pile on top of each other, producing an interlocking structure. In most cases the growth is rapid and chaotic. The result is a microstructure characterized by pores and cracks. The authors present an improved model for the deposition process of thermal barrier coatings. The task of modeling the coating growth is split into two parts: first the authors consider a description of the particle on arrival at the film, based on the available theoretical, numerical and experimental findings. Second they define and discuss a set of physically-based rules for combining these events to obtain the film. The splats run along the surface and are permitted to curl up (producing pores) or interlock. The computer model uses a mesh to combine these processes and build the coating. They discuss the use of the proposed model in predicting microstructures and hence in correlating the properties of these coatings with the parameters of the process used to make them.

  16. Thermal control structure and garment

    DOE Patents [OSTI]

    Klett, James W.; Cameron, Christopher Stan

    2012-03-13

    A flexible thermally conductive structure. The structure generally includes a plurality of thermally conductive yarns, at least some of which are at least partially disposed adjacent to an elastomeric material. Typically, at least a portion of the plurality of thermally conductive yarns is configured as a sheet. The yarns may be constructed from graphite, metal, or similar materials. The elastomeric material may be formed from urethane or silicone foam that is at least partially collapsed, or from a similar material. A thermal management garment is provided, the garment incorporating a flexible thermally conductive structure.

  17. Reducing dislocations in semiconductors utilizing repeated thermal cycling during multistage epitaxial growth

    DOE Patents [OSTI]

    Fan, John C. C.; Tsaur, Bor-Yeu; Gale, Ronald P.; Davis, Frances M.

    1992-02-25

    Dislocation densities are reduced in growing semiconductors from the vapor phase by employing a technique of interrupting growth, cooling the layer so far deposited, and then repeating the process until a high quality active top layer is achieved. The method of interrupted growth, coupled with thermal cycling, permits dislocations to be trapped in the initial stages of epitaxial growth.

  18. Reducing dislocations in semiconductors utilizing repeated thermal cycling during multistage epitaxial growth

    DOE Patents [OSTI]

    Fan, John C. C.; Tsaur, Bor-Yeu; Gale, Ronald P.; Davis, Frances M.

    1986-12-30

    Dislocation densities are reduced in growing semiconductors from the vapor phase by employing a technique of interrupting growth, cooling the layer so far deposited, and then repeating the process until a high quality active top layer is achieved. The method of interrupted growth, coupled with thermal cycling, permits dislocations to be trapped in the initial stages of epitaxial growth.

  19. Apparatus for gas-metal arc deposition

    DOE Patents [OSTI]

    Buhrmaster, Carol L.; Clark, Denis E.; Smartt, Herschel B.

    1991-01-01

    Apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspenion of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

  20. Method for gas-metal arc deposition

    DOE Patents [OSTI]

    Buhrmaster, Carol L.; Clark, Denis E.; Smartt, Herschel B.

    1990-01-01

    Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment wiht the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

  1. Method for gas-metal arc deposition

    DOE Patents [OSTI]

    Buhrmaster, C.L.; Clark, D.E.; Smartt, H.B.

    1990-11-13

    Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites are disclosed. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite. 1 fig.

  2. Thermal management systems and methods

    DOE Patents [OSTI]

    Gering, Kevin L.; Haefner, Daryl R.

    2006-12-12

    A thermal management system for a vehicle includes a heat exchanger having a thermal energy storage material provided therein, a first coolant loop thermally coupled to an electrochemical storage device located within the first coolant loop and to the heat exchanger, and a second coolant loop thermally coupled to the heat exchanger. The first and second coolant loops are configured to carry distinct thermal energy transfer media. The thermal management system also includes an interface configured to facilitate transfer of heat generated by an internal combustion engine to the heat exchanger via the second coolant loop in order to selectively deliver the heat to the electrochemical storage device. Thermal management methods are also provided.

  3. Photobiomolecular deposition of metallic particles and films

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2005-02-08

    The method of the invention is based on the unique electron-carrying function of a photocatalytic unit such as the photosynthesis system I (PSI) reaction center of the protein-chlorophyll complex isolated from chloroplasts. The method employs a photo-biomolecular metal deposition technique for precisely controlled nucleation and growth of metallic clusters/particles, e.g., platinum, palladium, and their alloys, etc., as well as for thin-film formation above the surface of a solid substrate. The photochemically mediated technique offers numerous advantages over traditional deposition methods including quantitative atom deposition control, high energy efficiency, and mild operating condition requirements.

  4. Geothermal regime and thermal history of the Llanos Basin, Columbia

    SciTech Connect (OSTI)

    Bachu, S.; Underschultz, J.R.; Ramon, J.C.; Villegas, M.E.

    1995-01-01

    The Llanos basin is a siliciclastic foreland sub-Andean sedimentary basin located in Columbia between the Cordillera Oriental and the Guyana Precambrian shield. Data on bottom-hole temperature, lithology, porosity, and vitrinite reflectance from all 318 wells drilled in the central and southern parts of the basin were used to analyze its geothermal regime and thermal history. Average geothermal gradients in the Llanos basin decrease generally with depth and westward toward the fold and thrust belt. The geothermal regime is controlled by a moderate, generally westward-decreasing basement heat flow, by depositional and compaction factors, and, in places, by advection by formation waters. Compaction leads to increased thermal conductivity with depth, whereas westward downdip flow in deep sandstone formations may exert a cooling effect in the central-western part of the basin. Vitrinite reflectance variation with depth shows a major discontinuity at the pre-Cretaceous unconformity. Areally, vitrinite reflectance increases southwestward in Paleozoic strata and northwestward in post-Paleozoic strata. These patterns indicate that the thermal history of the basin probably includes three thermal events that led to peaks in oil generation: a Paleozoic event in the southwest, a failed Cretaceous rifting event in the west, and an early Tertiary back-arc event in the west. Rapid cooling since the last thermal event is possibly caused by subhorizontal subduction of cold oceanic lithospheric plate.

  5. Thermally cleavable surfactants

    DOE Patents [OSTI]

    McElhanon, James R.; Simmons, Blake A.; Zifer, Thomas; Jamison, Gregory M.; Loy, Douglas A.; Rahimian, Kamyar; Long, Timothy M.; Wheeler, David R.; Staiger, Chad L.

    2006-04-04

    Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments and the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.

  6. Thermally cleavable surfactants

    DOE Patents [OSTI]

    McElhanon, James R.; Simmons, Blake A.; Zifer, Thomas; Jamison, Gregory M.; Loy, Douglas A.; Rahimian, Kamyar; Long, Timothy M.; Wheeler, David R.; Staiger, Chad L.

    2009-09-29

    Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.

  7. Thermally cleavable surfactants

    DOE Patents [OSTI]

    McElhanon, James R.; Simmons, Blake A.; Zifer, Thomas; Jamison, Gregory M.; Loy, Douglas A.; Rahimian, Kamyar; Long, Timothy M.; Wheeler, David R.; Staiger, Chad L.

    2009-11-24

    Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.

  8. Thermal indicator for wells

    DOE Patents [OSTI]

    Gaven, Jr., Joseph V.; Bak, Chan S.

    1983-01-01

    Minute durable plate-like thermal indicators are employed for precision measuring static and dynamic temperatures of well drilling fluids. The indicators are small enough and sufficiently durable to be circulated in the well with drilling fluids during the drilling operation. The indicators include a heat resistant indicating layer, a coacting meltable solid component and a retainer body which serves to unitize each indicator and which may carry permanent indicator identifying indicia. The indicators are recovered from the drilling fluid at ground level by known techniques.

  9. Thermal network reduction

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1983-01-01

    A method is presented for reducing the number of elements required in a thermal network representation of a building. The method is based on matching the actual building response at two frequencies, the diurnal response and 3-day response. The procedure provides a straightforward methodology for combining all the various materials inside a discrete building zone into a few nodes while retaining a high degree of accuracy in the dynamic response. An example is given showing a comparison between a large network and the reduced network.

  10. Thermal network reduction

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1983-06-01

    A method is presented for reducing the number of elements required in a thermal network representation of a building. The method is based on matching the actual building response at two frequencies, the diurnal response and 3-day response. The procedure provides a straightforward methodology for combining all the various materials inside a discrete building zone into a few nodes while retaining a high degree of accuracy in the dynamic response. An example is given showing a comparison between a large network and the reduced network.

  11. Thermal transient anemometer

    DOE Patents [OSTI]

    Bailey, J.L.; Vresk, J.

    1989-07-18

    A thermal transient anemometer is disclosed having a thermocouple probe which is utilized to measure the change in temperature over a period of time to provide a measure of fluid flow velocity. The thermocouple probe is located in the fluid flow path and pulsed to heat or cool the probe. The cooling of the heated probe or the heating of the cooled probe from the fluid flow over a period of time is measured to determine the fluid flow velocity. The probe is desired to be locally heated near the tip to increase the efficiency of devices incorporating the probe. 12 figs.

  12. Response microcantilever thermal detector

    DOE Patents [OSTI]

    Cunningham, Joseph P.; Rajic, Slobodan; Datskos, Panagiotis G.; Evans III, Boyd M.

    2004-10-19

    A "folded leg" thermal detector microcantilever constructed of a substrate with at least one leg interposed between a fixed end and a deflective end, each leg having at least three essentially parallel leg segments interconnected on alternate opposing ends and aligned in a serpentine pattern with only the first leg segment attached to the fixed end and only the last leg segment attached to the deflective end. Alternate leg segment are coated on the pentalever with coating applied to the top of the first, third, and fifth leg segments of each leg and to the bottom of the second and fourth leg segments of each leg.

  13. Thermal transient anemometer

    DOE Patents [OSTI]

    Bailey, James L.; Vresk, Josip

    1989-01-01

    A thermal transient anemometer having a thermocouple probe which is utilized to measure the change in temperature over a period of time to provide a measure of fluid flow velocity. The thermocouple probe is located in the fluid flow path and pulsed to heat or cool the probe. The cooling of the heated probe or the heating of the cooled probe from the fluid flow over a period of time is measured to determine the fluid flow velocity. The probe is desired to be locally heated near the tip to increase the efficiency of devices incorporating the probe.

  14. Thermally switchable dielectrics

    DOE Patents [OSTI]

    Dirk, Shawn M.; Johnson, Ross S.

    2013-04-30

    Precursor polymers to conjugated polymers, such as poly(phenylene vinylene), poly(poly(thiophene vinylene), poly(aniline vinylene), and poly(pyrrole vinylene), can be used as thermally switchable capacitor dielectrics that fail at a specific temperature due to the non-conjugated precursor polymer irreversibly switching from an insulator to the conjugated polymer, which serves as a bleed resistor. The precursor polymer is a good dielectric until it reaches a specific temperature determined by the stability of the leaving groups. Conjugation of the polymer backbone at high temperature effectively disables the capacitor, providing a `built-in` safety mechanism for electronic devices.

  15. Ultratough, Thermally Stable Polycrystalline Diamond/Silicon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultratough, Thermally Stable Polycrystalline DiamondSilicon Carbide Nanocomposites for Drill Bits Ultratough, Thermally Stable Polycrystalline DiamondSilicon Carbide ...

  16. Thermomechanical measurements on thermal microactuators. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Thermal and mechanical measurements for the bent-beam polycrystalline silicon thermal ... SANDIA NATIONAL LABORATORIES; SILICON; VALIDATION Microactuators.; Ceramic ...

  17. Integrated Vehicle Thermal Management Systems (VTMS) Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Integrated Vehicle Thermal Management Power Electronic Thermal System Performance and Integration Characterization and Development of Advanced...

  18. Uncooled thin film pyroelectric IR detector with aerogel thermal isolation

    SciTech Connect (OSTI)

    Ruffner, J.A.; Clem, P.G.; Tuttle, B.A. [and others

    1998-01-01

    Uncooled pyroelectric IR imaging systems, such as night vision goggles, offer important strategic advantages in battlefield scenarios and reconnaissance surveys. Until now, the current technology for fabricating these devices has been limited by low throughput and high cost which ultimately limit the availability of these sensor devices. We have developed and fabricated an alternative design for pyroelectric IR imaging sensors that utilizes a multilayered thin film deposition scheme to create a monolithic thin film imaging element on an active silicon substrate for the first time. This approach combines a thin film pyroelectric imaging element with a thermally insulating SiO{sub 2} aerogel thin film to produce a new type of uncooled IR sensor that offers significantly higher thermal, spatial, and temporal resolutions at a substantially lower cost per unit. This report describes the deposition, characterization and optimization of the aerogel thermal isolation layer and an appropriate pyroelectric imaging element. It also describes the overall integration of these components along with the appropriate planarization, etch stop, adhesion, electrode, and blacking agent thin film layers into a monolithic structure. 19 refs., 8 figs., 6 tabs.

  19. Solar thermal power system

    DOE Patents [OSTI]

    Bennett, Charles L.

    2010-06-15

    A solar thermal power generator includes an inclined elongated boiler tube positioned in the focus of a solar concentrator for generating steam from water. The boiler tube is connected at one end to receive water from a pressure vessel as well as connected at an opposite end to return steam back to the vessel in a fluidic circuit arrangement that stores energy in the form of heated water in the pressure vessel. An expander, condenser, and reservoir are also connected in series to respectively produce work using the steam passed either directly (above a water line in the vessel) or indirectly (below a water line in the vessel) through the pressure vessel, condense the expanded steam, and collect the condensed water. The reservoir also supplies the collected water back to the pressure vessel at the end of a diurnal cycle when the vessel is sufficiently depressurized, so that the system is reset to repeat the cycle the following day. The circuital arrangement of the boiler tube and the pressure vessel operates to dampen flow instabilities in the boiler tube, damp out the effects of solar transients, and provide thermal energy storage which enables time shifting of power generation to better align with the higher demand for energy during peak energy usage periods.

  20. Polymer-assisted aqueous deposition of metal oxide films (Patent...

    Office of Scientific and Technical Information (OSTI)

    Polymer-assisted aqueous deposition of metal oxide films Title: Polymer-assisted aqueous deposition of metal oxide films An organic solvent-free process for deposition of metal ...

  1. Source replenishment device for vacuum deposition

    DOE Patents [OSTI]

    Hill, Ronald A. (Albuquerque, NM)

    1988-01-01

    A material source replenishment device for use with a vacuum deposition apparatus. The source replenishment device comprises an intermittent motion producing gear arrangement disposed within the vacuum deposition chamber. An elongated rod having one end operably connected to the gearing arrangement is provided with a multiarmed head at the opposite end disposed adjacent the heating element of the vacuum deposition apparatus. An inverted U-shaped source material element is releasably attached to the outer end of each arm member whereby said multiarmed head is moved to locate a first of said material elements above said heating element, whereupon said multiarmed head is lowered to engage said material element with the heating element and further lowered to release said material element on the heating element. After vaporization of said material element, second and subsequent material elements may be provided to the heating element without the need for opening the vacuum deposition apparatus to the atmosphere.

  2. Source replenishment device for vacuum deposition

    DOE Patents [OSTI]

    Hill, R.A.

    1986-05-15

    A material source replenishment device for use with a vacuum deposition apparatus is described. The source replenishment device comprises an intermittent motion producing gear arrangement disposed within the vacuum deposition chamber. An elongated rod having one end operably connected to the gearing arrangement is provided with a multiarmed head at the opposite end disposed adjacent the heating element of the vacuum deposition apparatus. An inverted U-shaped source material element is releasably attached to the outer end of each arm member whereby said multiarmed head is moved to locate a first of said material elements above said heating element, whereupon said multiarmed head is lowered to engage said material element with the heating element and further lowered to release said material element on the heating element. After vaporization of said material element, second and subsequent material elements may be provided to the heating element without the need for opening the vacuum deposition apparatus to the atmosphere.

  3. Electric Vehicle Battery Thermal Issues and Thermal Management Techniques (Presentation)

    SciTech Connect (OSTI)

    Rugh, J. P.; Pesaran, A.; Smith, K.

    2013-07-01

    This presentation examines the issues concerning thermal management in electric drive vehicles and management techniques for improving the life of a Li-ion battery in an EDV.

  4. Polymer-assisted deposition of films

    DOE Patents [OSTI]

    McCleskey, Thomas M.; Burrell; Anthony K.; Jia; Quanxi; Lin; Yuan

    2009-10-20

    A polymer assisted deposition process for deposition of metal oxide films and the like is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures to yield metal oxide films and the like. Such films can be epitaxial in structure and can be of optical quality. The process can be organic solvent-free.

  5. Polymer-assisted deposition of films

    DOE Patents [OSTI]

    McCleskey, Thomas M.; Burrell, Anthony K.; Jia, Quanxi; Lin, Yuan

    2008-04-29

    A polymer assisted deposition process for deposition of metal oxide films is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures to yield metal oxide films. Such films can be epitaxial in structure and can be of optical quality. The process can be organic solvent-free.

  6. Method of deposition by molecular beam epitaxy

    DOE Patents [OSTI]

    Chalmers, Scott A.; Killeen, Kevin P.; Lear, Kevin L.

    1995-01-01

    A method is described for reproducibly controlling layer thickness and varying layer composition in an MBE deposition process. In particular, the present invention includes epitaxially depositing a plurality of layers of material on a substrate with a plurality of growth cycles whereby the average of the instantaneous growth rates for each growth cycle and from one growth cycle to the next remains substantially constant as a function of time.

  7. Energy deposition in STARFIRE reactor components

    SciTech Connect (OSTI)

    Gohar, Y.; Brooks, J.N.

    1985-04-01

    The energy deposition in the STARFIRE commercial tokamak reactor was calculated based on detailed models for the different reactor components. The heat deposition and the 14 MeV neutron flux poloidal distributions in the first wall were obtained. The poloidal surface heat load distribution in the first wall was calculated from the plasma radiation. The Monte Carlo method was used for the calculation to allow an accurate modeling for the reactor geometry.

  8. Semiconductor assisted metal deposition for nanolithography applications

    DOE Patents [OSTI]

    Rajh, Tijana; Meshkov, Natalia; Nedelijkovic, Jovan M.; Skubal, Laura R.; Tiede, David M.; Thurnauer, Marion

    2001-01-01

    An article of manufacture and method of forming nanoparticle sized material components. A semiconductor oxide substrate includes nanoparticles of semiconductor oxide. A modifier is deposited onto the nanoparticles, and a source of metal ions are deposited in association with the semiconductor and the modifier, the modifier enabling electronic hole scavenging and chelation of the metal ions. The metal ions and modifier are illuminated to cause reduction of the metal ions to metal onto the semiconductor nanoparticles.

  9. Semiconductor assisted metal deposition for nanolithography applications

    DOE Patents [OSTI]

    Rajh, Tijana; Meshkov, Natalia; Nedelijkovic, Jovan M.; Skubal, Laura R.; Tiede, David M.; Thurnauer, Marion

    2002-01-01

    An article of manufacture and method of forming nanoparticle sized material components. A semiconductor oxide substrate includes nanoparticles of semiconductor oxide. A modifier is deposited onto the nanoparticles, and a source of metal ions are deposited in association with the semiconductor and the modifier, the modifier enabling electronic hole scavenging and chelation of the metal ions. The metal ions and modifier are illuminated to cause reduction of the metal ions to metal onto the semiconductor nanoparticles.

  10. Method of deposition by molecular beam epitaxy

    DOE Patents [OSTI]

    Chalmers, S.A.; Killeen, K.P.; Lear, K.L.

    1995-01-10

    A method is described for reproducibly controlling layer thickness and varying layer composition in an MBE deposition process. In particular, the present invention includes epitaxially depositing a plurality of layers of material on a substrate with a plurality of growth cycles whereby the average of the instantaneous growth rates for each growth cycle and from one growth cycle to the next remains substantially constant as a function of time. 9 figures.

  11. Geology and Mineral Deposits of Churchill County, Nevada | Open...

    Open Energy Info (EERE)

    Mineral Deposits of Churchill County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geology and Mineral Deposits of Churchill County, Nevada...

  12. Precursors for the polymer-assisted deposition of films (Patent...

    Office of Scientific and Technical Information (OSTI)

    A polymer assisted deposition process for deposition of metal oxide films is presented. The process includes solutions of one or more metal precursor and soluble polymers having ...

  13. Low-temperature plasma-deposited silicon epitaxial films: Growth...

    Office of Scientific and Technical Information (OSTI)

    Low-temperature plasma-deposited silicon epitaxial films: Growth and properties Citation Details In-Document Search Title: Low-temperature plasma-deposited silicon epitaxial films:...

  14. Development and Characterization of a Spray Deposited CNT/PVDF...

    Office of Scientific and Technical Information (OSTI)

    of a Spray Deposited CNTPVDF Thin Film. Citation Details In-Document Search Title: Development and Characterization of a Spray Deposited CNTPVDF Thin Film. Abstract not provided. ...

  15. Chrome Deposit Corporation and the University of Delaware IAC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chrome Deposit Corporation and the University of Delaware IAC: Another Energy Efficiency Success Story Chrome Deposit Corporation and the University of Delaware IAC: Another Energy ...

  16. Precursors for the polymer-assisted deposition of films (Patent...

    Office of Scientific and Technical Information (OSTI)

    Precursors for the polymer-assisted deposition of films Citation Details In-Document Search Title: Precursors for the polymer-assisted deposition of films A polymer assisted ...

  17. Detection and Control of Deposition on Pendant Tubes in Kraft...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detection and Control of Deposition on Pendant Tubes in Kraft Chemical Recovery Boilers Detection and Control of Deposition on Pendant Tubes in Kraft Chemical Recovery Boilers ...

  18. Solvothermal Thin Film Deposition of Electron Blocking Layers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers...

  19. Spatial atomic layer deposition on flexible substrates using...

    Office of Scientific and Technical Information (OSTI)

    Spatial atomic layer deposition on flexible substrates using a modular rotating cylinder reactor Citation Details In-Document Search Title: Spatial atomic layer deposition on...

  20. Atomic Layer Deposition for Stabilization of Amorphous Silicon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Atomic Layer Deposition for Stabilization of Amorphous Silicon Anodes Atomic Layer Deposition for Stabilization of Amorphous Silicon Anodes 2012 DOE Hydrogen and Fuel Cells Program ...

  1. Eulerian CFD Models to Predict Thermophoretic Deposition of Soot...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Eulerian CFD Models to Predict Thermophoretic Deposition of Soot Particles in EGR Coolers Eulerian CFD Models to Predict Thermophoretic Deposition of Soot Particles in EGR Coolers ...

  2. CFD Analysis of Particle Deposition During DPF Filtration Processes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis of Particle Deposition During DPF Filtration Processes CFD Analysis of Particle Deposition During DPF Filtration Processes A 3-D DPF model is developed to predict ...

  3. Atomic Layer Deposition of Metal Sulfide Materials | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic Layer Deposition of Metal Sulfide Materials Title Atomic Layer Deposition of Metal Sulfide Materials Publication Type Journal Article Year of Publication 2015 Authors...

  4. On the physical and chemical details of alumina atomic layer deposition: A combined experimental and numerical approach

    SciTech Connect (OSTI)

    Pan, Dongqing; Ma, Lulu; Xie, Yuanyuan; Yuan, Chris; Jen, Tien Chien

    2015-03-15

    Alumina thin film is typically studied as a model atomic layer deposition (ALD) process due to its high dielectric constant, high thermal stability, and good adhesion on various wafer surfaces. Despite extensive applications of alumina ALD in microelectronics industries, details on the physical and chemical processes are not yet well understood. ALD experiments are not able to shed adequate light on the detailed information regarding the transient ALD process. Most of current numerical approaches lack detailed surface reaction mechanisms, and their results are not well correlated with experimental observations. In this paper, the authors present a combined experimental and numerical study on the details of flow and surface reactions in alumina ALD using trimethylaluminum and water as precursors. Results obtained from experiments and simulations are compared and correlated. By experiments, growth rate on five samples under different deposition conditions is characterized. The deposition rate from numerical simulation agrees well with the experimental results. Details of precursor distributions in a full cycle of ALD are studied numerically to bridge between experimental observations and simulations. The 3D transient numerical model adopts surface reaction kinetics and mechanisms based on atomic-level studies to investigate the surface deposition process. Surface deposition is shown as a strictly self-limited process in our numerical studies. ALD is a complex strong-coupled fluid, thermal and chemical process, which is not only heavily dependent on the chemical kinetics and surface conditions but also on the flow and material distributions.

  5. Hydrocarbon and Deposit Morphology Effects on EGR Cooler Deposit Stability and Removal

    Broader source: Energy.gov [DOE]

    This paper reports on studies carried out at ORNL to examine the shear force required to remove particles from a well-developed EGR cooler deposit.

  6. Thermal protection apparatus

    DOE Patents [OSTI]

    Bennett, Gloria A.; Moore, Troy K.

    1988-01-01

    An apparatus for thermally protecting heat sensitive components of tools. The apparatus comprises a Dewar for holding the heat sensitive components. The Dewar has spaced-apart inside and outside walls, an open top end and a bottom end. An insulating plug is located in the top end. The inside wall has portions defining an inside wall aperture located at the bottom of the Dewar and the outside wall has portions defining an outside wall aperture located at the bottom of the Dewar. A bottom connector has inside and outside components. The inside component sealably engages the inside wall aperture and the outside component sealably engages the outside wall aperture. The inside component is operatively connected to the heat sensitive components and to the outside component. The connections can be made with optical fibers or with electrically conducting wires.

  7. THERMALLY OPERATED VAPOR VALVE

    DOE Patents [OSTI]

    Dorward, J.G. Jr.

    1959-02-10

    A valve is presented for use in a calutron to supply and control the vapor to be ionized. The invention provides a means readily operable from the exterior of the vacuum tank of the apparatuss without mechanical transmission of forces for the quick and accurate control of the ionizing arc by a corresponding control of gas flow theretos thereby producing an effective way of carefully regulating the operation of the calutron. The invention consists essentially of a tube member extending into the charge bottle of a calutron devices having a poppet type valve closing the lower end of the tube. An electrical heating means is provided in the valve stem to thermally vary the length of the stem to regulate the valve opening to control the flow of material from the charge bottle.

  8. SUPERFAST THERMALIZATION OF PLASMA

    DOE Patents [OSTI]

    Chang, C.C.

    1962-06-12

    A method is given for the superfast thermalization of plasma by shock conversion of the kinetic energy stored in rotating plasma rings or plasmoids colliding at near supersonic speeds in a containment field to heat energy in the resultant confined plasma mass. The method includes means for generating rotating plasmoids at the opposite ends of a Pyrotron or Astron containment field. The plasmoids are magnetically accelerated towards each other into the opposite ends of time containment field. During acceleration of the plasmoids toward the center of the containment field, the intensity of the field is sequentially increased to adiabatically compress the plasmoids and increase the plasma energy. The plasmoids hence collide with a violent shock at the eenter of the containment field, causing the substantial kinetic energy stored in the plasmoids to be converted to heat in the resultant plasma mass. (AEC)

  9. Thermally stabilized heliostat

    DOE Patents [OSTI]

    Anderson, Alfred J.

    1983-01-01

    An improvement in a heliostat having a main support structure and pivoting and tilting motors and gears and a mirror module for reflecting solar energy onto a collector, the improvement being characterized by an internal support structure within each mirror module and front and back sheets attached to the internal support structure, the front and back sheets having the same coefficient of thermal expansion such that no curvature is induced by temperature change, and a layer of adhesive adhering the mirror to the front sheet. The adhesive is water repellent and has adequate set strength to support the mirror but has sufficient shear tolerance to permit the differential expansion of the mirror and the front sheet without inducing stresses or currature effect. The adhesive also serves to dampen fluttering of the mirror and to protect the mirror backside against the adverse effects of weather. Also disclosed are specific details of the preferred embodiment.

  10. Thermal barrier coatings

    DOE Patents [OSTI]

    Alvin, Mary Anne

    2010-06-22

    This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.

  11. Actively driven thermal radiation shield

    DOE Patents [OSTI]

    Madden, Norman W. (Livermore, CA); Cork, Christopher P. (Pleasant Hill, CA); Becker, John A. (Alameda, CA); Knapp, David A. (Livermore, CA)

    2002-01-01

    A thermal radiation shield for cooled portable gamma-ray spectrometers. The thermal radiation shield is located intermediate the vacuum enclosure and detector enclosure, is actively driven, and is useful in reducing the heat load to mechanical cooler and additionally extends the lifetime of the mechanical cooler. The thermal shield is electrically-powered and is particularly useful for portable solid-state gamma-ray detectors or spectrometers that dramatically reduces the cooling power requirements. For example, the operating shield at 260K (40K below room temperature) will decrease the thermal radiation load to the detector by 50%, which makes possible portable battery operation for a mechanically cooled Ge spectrometer.

  12. Overview of solar thermal technologies

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    The solar-thermal overview section of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  13. Firearm suppressor having enhanced thermal management for rapid heat dissipation

    DOE Patents [OSTI]

    Moss, William C.; Anderson, Andrew T.

    2014-08-19

    A suppressor is disclosed for use with a weapon having a barrel through which a bullet is fired. The suppressor has an inner portion having a bore extending coaxially therethrough. The inner portion is adapted to be secured to a distal end of the barrel. A plurality of axial flow segments project radially from the inner portion and form axial flow paths through which expanding propellant gasses discharged from the barrel flow through. The axial flow segments have radially extending wall portions that define sections which may be filled with thermally conductive material, which in one example is a thermally conductive foam. The conductive foam helps to dissipate heat deposited within the suppressor during firing of the weapon.

  14. Apparatus for laser assisted thin film deposition

    DOE Patents [OSTI]

    Warner, Bruce E.; McLean, II, William

    1996-01-01

    A pulsed laser deposition apparatus uses fiber optics to deliver visible output beams. One or more optical fibers are coupled to one or more laser sources, and delivers visible output beams to a single chamber, to multiple targets in the chamber or to multiple chambers. The laser can run uninterrupted if one of the deposition chambers ceases to operate because other chambers can continue their laser deposition processes. The laser source can be positioned at a remote location relative to the deposition chamber. The use of fiber optics permits multi-plexing. A pulsed visible laser beam is directed at a generally non-perpendicular angle upon the target in the chamber, generating a plume of ions and energetic neutral species. A portion of the plume is deposited on a substrate as a thin film. A pulsed visible output beam with a high pulse repetition frequency is used. The high pulse repetition frequency is greater than 500 Hz, and more preferably, greater than about 1000 Hz. Diamond-like-carbon (DLC) is one of the thin films produced using the apparatus.

  15. Patterns of permeability in eolian deposits

    SciTech Connect (OSTI)

    Goggin, D.J.; Chandler, M.A.; Kocurek, G.; Lake, L.W.

    1988-06-01

    The eolian, Jurassic Page sandstone of northeastern Arizona is marked by a highly ordered heterogeneity. The heterogeneity is expressed by the intricate association of stratification types, which are a direct result of the depositional processes. The dominant stratification types in eolian reservoirs are grainflow, grainfall, and wind-ripple deposits, which form on the lee faces of migrating dunes; interdune deposits, which form between migrating dunes; and extra-erg deposits, which occur sporadically when other depositional environments encroach upon an eolian system. These stratification types each have a unique permeability range, which implies that the fluid migration routes in eolian reservoirs will be dictated by the geometry and types of stratification present. One of the most important aspects of this study is the correlation of qualitative geologic descriptions with quantitative variables such as permeability. About 2,000 measurements were made with a field minipermeameter on an outcrop of the Page sandstone. These data show that three distinct permeability modes directly relate to the different stratification types.

  16. Apparatus for laser assisted thin film deposition

    DOE Patents [OSTI]

    Warner, B.E.; McLean, W. II

    1996-02-13

    A pulsed laser deposition apparatus uses fiber optics to deliver visible output beams. One or more optical fibers are coupled to one or more laser sources, and delivers visible output beams to a single chamber, to multiple targets in the chamber or to multiple chambers. The laser can run uninterrupted if one of the deposition chambers ceases to operate because other chambers can continue their laser deposition processes. The laser source can be positioned at a remote location relative to the deposition chamber. The use of fiber optics permits multi-plexing. A pulsed visible laser beam is directed at a generally non-perpendicular angle upon the target in the chamber, generating a plume of ions and energetic neutral species. A portion of the plume is deposited on a substrate as a thin film. A pulsed visible output beam with a high pulse repetition frequency is used. The high pulse repetition frequency is greater than 500 Hz, and more preferably, greater than about 1000 Hz. Diamond-like-carbon (DLC) is one of the thin films produced using the apparatus. 9 figs.

  17. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    6 Number of companies expecting to introduce new solar new solar thermal collector products in 2010 Low-Temperature Collectors 4 Medium-Temperature Collectors 16 High-Temperature Collectors 11 Noncollector Components 12 Form EIA-63A, "Annual Solar Thermal Collector Manufacturers Survey." New Product Type Number of Companies Source: U.S. Energy Information Administration,

  18. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    8 Employment in the solar thermal collector industry, 2000 - 2009 2000 284 2001 256 2002 356 2003 287 2004 317 2005 353 2006 1,069 2007 686 2008 1,083 2009 1,321 Year Person-Years Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal

  19. Peg supported thermal insulation panel

    DOE Patents [OSTI]

    Nowobilski, J.J.; Owens, W.J.

    1985-04-30

    A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprises high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure. 2 figs.

  20. Peg supported thermal insulation panel

    DOE Patents [OSTI]

    Nowobilski, Jeffert J.; Owens, William J.

    1985-01-01

    A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprising high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure.

  1. Review of US Nanocorp - SNL Joint Development of Thermal-Sprayed Thin-Film Cathodes for Thermal Batteries

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.; DAI,JINXIANG; XIAO,T. DANNY; REISNER,DAVID E.

    2000-11-14

    The use of plasma spray to deposit thin metal-sulfide cathode films is described in this paper. Conventional electroactive stack components in thermal batteries are constructed from pressed-powder parts that are difficult to fabricate in large diameters in thicknesses <0.010. Plasma-sprayed electrodes do not steer from this difficulty, allowing greater energy densities and specific energies to be realized. Various co-spraying agents have been found suitable for improving the mechanical as well as electrochemical properties of plasma-sprayed cathodes for thermal batteries. These electrodes generally show equal or improved performance over conventional pressed-powder electrodes. A number of areas for future growth and development of plasma-spray technology is discussed.

  2. Microsoft Word - Deposition Request Form Rev10-12.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Substrate Description ( substrate provided by user) Total Number of Substrates: Deposition Specifications Film FunctionApplication:**...

  3. Method and apparatus for conducting variable thickness vapor deposition

    DOE Patents [OSTI]

    Nesslage, G.V.

    1984-08-03

    A method of vapor depositing metal on a substrate in variable thickness comprises conducting the deposition continuously without interruption to avoid formation of grain boundaries. To achieve reduced deposition in specific regions a thin wire or ribbon blocking body is placed between source and substrate to partially block vapors from depositing in the region immediately below.

  4. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, Ahmet

    1989-01-01

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula (I) ##STR1## where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula I is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula I and a heat decomposable tellurium compound under nonoxidizing conditions.

  5. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, A.

    1989-11-21

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

  6. Forming aspheric optics by controlled deposition

    DOE Patents [OSTI]

    Hawryluk, Andrew M.

    1998-01-01

    An aspheric optical element formed by depositing material onto a spherical surface of an optical element by controlled deposition to form an aspheric surface of desired shape. A reflecting surface, single or multi-layer, can then be formed on the aspheric surface by evaporative or sputtering techniques. Aspheric optical elements are suitable for deep ultra-violet (UV) and x-ray wavelengths. The reflecting surface may, for example, be a thin (.about.100 nm) layer of aluminum, or in some cases the deposited modifying layer may function as the reflecting surface. For certain applications, multi-layer reflective surfaces may be utilized, such as chromium-carbon or tungsten-carbon multi-layer, with the number of layers and thickness being determined by the intended application.

  7. Forming aspheric optics by controlled deposition

    DOE Patents [OSTI]

    Hawryluk, A.M.

    1998-04-28

    An aspheric optical element is disclosed formed by depositing material onto a spherical surface of an optical element by controlled deposition to form an aspheric surface of desired shape. A reflecting surface, single or multi-layer, can then be formed on the aspheric surface by evaporative or sputtering techniques. Aspheric optical elements are suitable for deep ultra-violet (UV) and x-ray wavelengths. The reflecting surface may, for example, be a thin ({approx}100 nm) layer of aluminum, or in some cases the deposited modifying layer may function as the reflecting surface. For certain applications, multi-layer reflective surfaces may be utilized, such as chromium-carbon or tungsten-carbon multi-layer, with the number of layers and thickness being determined by the intended application. 4 figs.

  8. Line-of-sight deposition method

    DOE Patents [OSTI]

    Patten, James W.; McClanahan, Edwin D.; Bayne, Michael A.

    1981-01-01

    A line-of-sight method of depositing a film having substantially 100% of theoretical density on a substrate. A pressure vessel contains a target source having a surface thereof capable of emitting particles therefrom and a substrate with the source surface and the substrate surface positioned such that the source surface is substantially parallel to the direction of the particles impinging upon the substrate surface, the distance between the most remote portion of the substrate surface receiving the particles and the source surface emitting the particles in a direction parallel to the substrate surface being relatively small. The pressure in the vessel is maintained less than about 5 microns to prevent scattering and permit line-of-sight deposition. By this method the angles of incidence of the particles impinging upon the substrate surface are in the range of from about 45.degree. to 90.degree. even when the target surface area is greatly expanded to increase the deposition rate.

  9. Line-of-sight deposition method

    DOE Patents [OSTI]

    Patten, J.W.; McClanahan, E.D.; Bayne, M.A.

    1980-04-16

    A line-of-sight method of depositing a film having substantially 100% of theoretical density on a substrate. A pressure vessel contains a target source having a surface thereof capable of emitting particles therefrom and a substrate with the source surface and the substrate surface positioned such that the source surface is substantially parallel to the direction of the particles impinging upon the substrate surface, the distance between the most remote portion of the substrate surface receiving the particles and the source surface emitting the particles in a direction parallel to the substrate surface being relatively small. The pressure in the vessel is maintained less than about 5 microns to prevent scattering and permit line-of-sight deposition. By this method the angles of incidence of the particles impinging upon the substrate surface are in the range of from about 45/sup 0/ to 90/sup 0/ even when the target surface area is greatly expanded to increase the deposition rate.

  10. Glow discharge plasma deposition of thin films

    DOE Patents [OSTI]

    Weakliem, Herbert A. (Pennington, NJ); Vossen, Jr., John L. (Bridgewater, NJ)

    1984-05-29

    A glow discharge plasma reactor for deposition of thin films from a reactive RF glow discharge is provided with a screen positioned between the walls of the chamber and the cathode to confine the glow discharge region to within the region defined by the screen and the cathode. A substrate for receiving deposition material from a reactive gas is positioned outside the screened region. The screen is electrically connected to the system ground to thereby serve as the anode of the system. The energy of the reactive gas species is reduced as they diffuse through the screen to the substrate. Reactive gas is conducted directly into the glow discharge region through a centrally positioned distribution head to reduce contamination effects otherwise caused by secondary reaction products and impurities deposited on the reactor walls.

  11. Liquid injection plasma deposition method and apparatus

    DOE Patents [OSTI]

    Kong, Peter C.; Watkins, Arthur D.

    1999-01-01

    A liquid injection plasma torch deposition apparatus for depositing material onto a surface of a substrate may comprise a plasma torch for producing a jet of plasma from an outlet nozzle. A plasma confinement tube having an inlet end and an outlet end and a central bore therethrough is aligned with the outlet nozzle of the plasma torch so that the plasma jet is directed into the inlet end of the plasma confinement tube and emerges from the outlet end of the plasma confinement tube. The plasma confinement tube also includes an injection port transverse to the central bore. A liquid injection device connected to the injection port of the plasma confinement tube injects a liquid reactant mixture containing the material to be deposited onto the surface of the substrate through the injection port and into the central bore of the plasma confinement tube.

  12. Liquid injection plasma deposition method and apparatus

    DOE Patents [OSTI]

    Kong, P.C.; Watkins, A.D.

    1999-05-25

    A liquid injection plasma torch deposition apparatus for depositing material onto a surface of a substrate may comprise a plasma torch for producing a jet of plasma from an outlet nozzle. A plasma confinement tube having an inlet end and an outlet end and a central bore therethrough is aligned with the outlet nozzle of the plasma torch so that the plasma jet is directed into the inlet end of the plasma confinement tube and emerges from the outlet end of the plasma confinement tube. The plasma confinement tube also includes an injection port transverse to the central bore. A liquid injection device connected to the injection port of the plasma confinement tube injects a liquid reactant mixture containing the material to be deposited onto the surface of the substrate through the injection port and into the central bore of the plasma confinement tube. 8 figs.

  13. Thermal energy storage apparatus

    SciTech Connect (OSTI)

    Thoma, P.E.

    1980-04-22

    A thermal energy storage apparatus and method employs a container formed of soda lime glass and having a smooth, defectfree inner wall. The container is filled substantially with a material that can be supercooled to a temperature greater than 5* F., such as ethylene carbonate, benzophenone, phenyl sulfoxide, di-2-pyridyl ketone, phenyl ether, diphenylmethane, ethylene trithiocarbonate, diphenyl carbonate, diphenylamine, 2benzoylpyridine, 3-benzoylpyridine, 4-benzoylpyridine, 4methylbenzophenone, 4-bromobenzophenone, phenyl salicylate, diphenylcyclopropenone, benzyl sulfoxide, 4-methoxy-4prmethylbenzophenone, n-benzoylpiperidine, 3,3pr,4,4pr,5 pentamethoxybenzophenone, 4,4'-bis-(Dimethylamino)-benzophenone, diphenylboron bromide, benzalphthalide, benzophenone oxime, azobenzene. A nucleating means such as a seed crystal, a cold finger or pointed member is movable into the supercoolable material. A heating element heats the supercoolable material above the melting temperature to store heat. The material is then allowed to cool to a supercooled temperature below the melting temperature, but above the natural, spontaneous nucleating temperature. The liquid in each container is selectively initiated into nucleation to release the heat of fusion. The heat may be transferred directly or through a heat exchange unit within the material.

  14. Microelectromechanical (MEM) thermal actuator

    DOE Patents [OSTI]

    Garcia, Ernest J.; Fulcher, Clay W. G.

    2012-07-31

    Microelectromechanical (MEM) buckling beam thermal actuators are disclosed wherein the buckling direction of a beam is constrained to a desired direction of actuation, which can be in-plane or out-of-plane with respect to a support substrate. The actuators comprise as-fabricated, linear beams of uniform cross section supported above the substrate by supports which rigidly attach a beam to the substrate. The beams can be heated by methods including the passage of an electrical current through them. The buckling direction of an initially straight beam upon heating and expansion is controlled by incorporating one or more directional constraints attached to the substrate and proximal to the mid-point of the beam. In the event that the beam initially buckles in an undesired direction, deformation of the beam induced by contact with a directional constraint generates an opposing force to re-direct the buckling beam into the desired direction. The displacement and force generated by the movement of the buckling beam can be harnessed to perform useful work, such as closing contacts in an electrical switch.

  15. Solar Thermal Demonstration Project

    SciTech Connect (OSTI)

    Biesinger, K.; Cuppett, D.; Dyer, D.

    2012-01-30

    HVAC Retrofit and Energy Efficiency Upgrades at Clark High School, Las Vegas, Nevada The overall objectives of this project are to increase usage of alternative/renewable fuels, create a better and more reliable learning environment for the students, and reduce energy costs. Utilizing the grant resources and local bond revenues, the District proposes to reduce electricity consumption by installing within the existing limited space, one principal energy efficient 100 ton adsorption chiller working in concert with two 500 ton electric chillers. The main heating source will be primarily from low nitrogen oxide (NOX), high efficiency natural gas fired boilers. With the use of this type of chiller, the electric power and cost requirements will be greatly reduced. To provide cooling to the information technology centers and equipment rooms of the school during off-peak hours, the District will install water source heat pumps. In another measure to reduce the cooling requirements at Clark High School, the District will replace single pane glass and metal panels with ‘Kalwall’ building panels. An added feature of the “Kalwall” system is that it will allow for natural day lighting in the student center. This system will significantly reduce thermal heat/cooling loss and control solar heat gain, thus delivering significant savings in heating ventilation and air conditioning (HVAC) costs.

  16. Method for deposition of a conductor in integrated circuits

    DOE Patents [OSTI]

    Creighton, J.R.; Dominguez, F.; Johnson, A.W.; Omstead, T.R.

    1997-09-02

    A method is described for fabricating integrated semiconductor circuits and, more particularly, for the selective deposition of a conductor onto a substrate employing a chemical vapor deposition process. By way of example, tungsten can be selectively deposited onto a silicon substrate. At the onset of loss of selectivity of deposition of tungsten onto the silicon substrate, the deposition process is interrupted and unwanted tungsten which has deposited on a mask layer with the silicon substrate can be removed employing a halogen etchant. Thereafter, a plurality of deposition/etch back cycles can be carried out to achieve a predetermined thickness of tungsten. 2 figs.

  17. Method for deposition of a conductor in integrated circuits

    DOE Patents [OSTI]

    Creighton, J. Randall; Dominguez, Frank; Johnson, A. Wayne; Omstead, Thomas R.

    1997-01-01

    A method is described for fabricating integrated semiconductor circuits and, more particularly, for the selective deposition of a conductor onto a substrate employing a chemical vapor deposition process. By way of example, tungsten can be selectively deposited onto a silicon substrate. At the onset of loss of selectivity of deposition of tungsten onto the silicon substrate, the deposition process is interrupted and unwanted tungsten which has deposited on a mask layer with the silicon substrate can be removed employing a halogen etchant. Thereafter, a plurality of deposition/etch back cycles can be carried out to achieve a predetermined thickness of tungsten.

  18. Advanced thermally stable jet fuels. Technical progress report, July 1993--September 1993

    SciTech Connect (OSTI)

    Schobert, H.H.; Eser, S.; Song, C.; Hatcher, P.G.; Walsh, P.M.; Coleman, M.M.

    1993-12-01

    The Penn State program in advanced thermally stable coal-based jet fuels has five broad objectives: (1) development of mechanisms of degradation and solids formation; (2) quantitative measurement of growth of sub-micrometer and micrometer-sized particles suspended in fuels during thermal stressing; (3) characterization of carbonaceous deposits by various instrumental and microscopic methods; (4) elucidation of the role of additives in retarding the formation of carbonaceous solids; (5) assessment of the potential of production of high yields of cycloalkanes by direct liquefaction of coal. An exploratory study was conducted to investigate the pyrolysis of n-butylbenzene in a flow reactor at atmospheric pressure. A number of similarities to trends previously observed in high-pressure static reactions were identified. The product distribution from pyrolysis of n-tetradecane at 400{degrees}C and 425{degrees}C was investigated. The critical temperatures of a suite of petroleum- and coal-derived jet fuels were measured by a rapidly heating sealed tube method. Work has continued on refining the measurements of deposit growth for stressing mixtures of coal-derived JP-8C with tetradecane. Current work has given emphasis to the initial stages of fuel decomposition and the onset of deposition. Pretreatment of JPTS fuel with PX-21 activated carbon (50 mg of PX-21 in 15 mL JPTS) delayed degradation and prevented carbon deposition during thermal stressing at 425{degrees}C for 5 h in nitrogen and air atmospheres. Clear indications of initial and subsequent deposit formation on different metal surfaces have been identified for thermal stressing of dodecane. Seven additives were tested for their ability to retard decomposition of dodecane at 450{degrees}C under nitrogen. Nuclear magnetic resonance data for Dammar resin indicates that structures proposed in the literature are not entirely correct.

  19. Thermal to electricity conversion using thermal magnetic properties

    DOE Patents [OSTI]

    West, Phillip B [Idaho Falls, ID; Svoboda, John [Idaho Falls, ID

    2010-04-27

    A system for the generation of Electricity from Thermal Energy using the thermal magnetic properties of a Ferromagnetic, Electrically Conductive Material (FECM) in one or more Magnetic Fields. A FECM is exposed to one or more Magnetic Fields. Thermal Energy is applied to a portion of the FECM heating the FECM above its Curie Point. The FECM, now partially paramagnetic, moves under the force of the one or more Magnetic Fields. The movement of the FECM induces an electrical current through the FECM, generating Electricity.

  20. Low Thermal Conductivity, High Durability Thermal Barrier Coatings for IGCC Environments

    SciTech Connect (OSTI)

    Jordan, Eric; Gell, Maurice

    2015-01-15

    Advanced thermal barrier coatings (TBC) are crucial to improved energy efficiency in next generation gas turbine engines. The use of traditional topcoat materials, e.g. yttria-stabilized zirconia (YSZ), is limited at elevated temperatures due to (1) the accelerated undesirable phase transformations and (2) corrosive attacks by calcium-magnesium-aluminum-silicate (CMAS) deposits and moisture. The first goal of this project is to use the Solution Precursor Plasma Spray (SPPS) process to further reduce the thermal conductivity of YSZ TBCs by introducing a unique microstructural feature of layered porosity, called inter-pass boundaries (IPBs). Extensive process optimization accompanied with hundreds of spray trials as well as associated SEM cross-section and laser-flash measurements, yielded a thermal conductivity as low as 0.62 Wm⁻¹K⁻¹ in SPPS YSZ TBCs, approximately 50% reduction of APS TBCs; while other engine critical properties, such as cyclic durability, erosion resistance and sintering resistance, were characterized to be equivalent or better than APS baselines. In addition, modifications were introduced to SPPS TBCs so as to enhance their resistance to CMAS under harsh IGCC environments. Several mitigation approaches were explored, including doping the coatings with Al₂O₃ and TiO₂, applying a CMAS infiltration-inhibiting surface layer, and filling topcoat cracks with blocking substances. The efficacy of all these modifications was assessed with a set of novel CMAS-TBC interaction tests, and the moisture resistance was tested in a custom-built high-temperature moisture rig. In the end, the optimal low thermal conductivity TBC system was selected based on all evaluation tests and its processing conditions were documented. The optimal coating consisted on a thick inner layer of YSZ coating made by the SPPS process having a thermal conductivity 50% lower than standard YSZ coatings topped with a high temperature tolerant CMAS resistant gadolinium zirconate Coating made by the SPPS process. Noteworthy was the fact that the YSZ to GZO interface made by the SPPS process was not the failure location as had been observed in APS coatings.

  1. Polymer-assisted deposition of films

    DOE Patents [OSTI]

    McCleskey,Thomas M.; Burrell,Anthony K.; Jia,Quanxi; Lin,Yuan

    2012-02-28

    A polymer assisted deposition process for deposition of metal nitride films and the like is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures under a suitable atmosphere to yield metal nitride films and the like. Such films can be conformal on a variety of substrates including non-planar substrates. In some instances, the films can be epitaxial in structure and can be of optical quality. The process can be organic solvent-free.

  2. Ruthenium / aerogel nanocomposits via Atomic Layer Deposition

    SciTech Connect (OSTI)

    Biener, J; Baumann, T F; Wang, Y; Nelson, E J; Kucheyev, S O; Hamza, A V; Kemell, M; Ritala, M; Leskela, M

    2006-08-28

    We present a general approach to prepare metal/aerogel nanocomposites via template directed atomic layer deposition (ALD). In particular, we used a Ru ALD process consisting of alternating exposures to bis(cyclopentadienyl)ruthenium (RuCp{sub 2}) and air at 350 C to deposit metallic Ru nanoparticles on the internal surfaces of carbon and silica aerogels. The process does not affect the morphology of the aerogel template and offers excellent control over metal loading by simply adjusting the number of ALD cycles. We also discuss the limitations of our ALD approach, and suggest ways to overcome these.

  3. Simulation of surface roughness during the formation of thermal spray coatings

    SciTech Connect (OSTI)

    Kanouff, M.P.

    1996-07-01

    The formation of a thermal spray coating was analyzed to identify methods to reduce the surface roughness of the coating. A new methodology was developed which uses a string of equally spaced node points to define the shape of the coating surface and to track the shape change as the thermal spray mass is deposited. This allows the calculation of arbitrary shapes for the coating surface which may be very complex. The model simulates the stochastic deposition of a large number of thermal spray droplets, where experimental data is used for the mass flux distribution on the target surface. This data shows that when the thermal spray mass impinges on the target surface, a large fraction of it (over-spray) splashes off the target and is re-deposited with a small spray angle, resulting in a large coating roughness. This analysis was used in a parameter study to identify methods for reducing the coating roughness. Effect of the shape of the profile for the pre-roughened substrate was found to be small. Decreasing the droplet size by a factor of 2 decreased the roughness by 13%. Increasing the spray angle for the over-spray by a factor of 2 decreased the roughness by 50%, and decreasing the amount of over- spray by a factor of 2 decreased the roughness by 51%.

  4. Dual ion beam assisted deposition of biaxially textured template layers

    DOE Patents [OSTI]

    Groves, James R.; Arendt, Paul N.; Hammond, Robert H.

    2005-05-31

    The present invention is directed towards a process and apparatus for epitaxial deposition of a material, e.g., a layer of MgO, onto a substrate such as a flexible metal substrate, using dual ion beams for the ion beam assisted deposition whereby thick layers can be deposited without degradation of the desired properties by the material. The ability to deposit thicker layers without loss of properties provides a significantly broader deposition window for the process.

  5. Third-order nonlinear optical response of colloidal gold nanoparticles prepared by sputtering deposition

    SciTech Connect (OSTI)

    Castro, Hemerson P. S.; Alencar, Márcio A. R. C.; Hickmann, Jandir M.; Wender, Heberton; Department of Physics, Universidade Federal do Mato Grosso do Sul, 79070-900, Campo Grande ; Teixeira, Sergio R.; Dupont, Jairton

    2013-11-14

    The nonlinear optical responses of gold nanoparticles dispersed in castor oil produced by sputtering deposition were investigated, using the thermally managed Z-scan technique. Particles with spherical shape and 2.6 nm of average diameter were obtained and characterized by transmission electron microscopy and small angle X-ray scattering. This colloid was highly stable, without the presence of chemical impurities, neither stabilizers. It was observed that this system presents a large refractive third-order nonlinear response and a negligible nonlinear absorption. Moreover, the evaluation of the all-optical switching figures of merit demonstrated that the colloidal nanoparticles prepared by sputtering deposition have a good potential for the development of ultrafast photonic devices.

  6. Ultra-low loading Pt nanocatalysts prepared by atomic layer deposition on carbon aerogels

    SciTech Connect (OSTI)

    King, J S; Wittstock, A; Biener, J; Kucheyev, S O; Wang, Y M; Baumann, T F; Giri, S; Hamza, A V; Baeumer, M; Bent, S F

    2008-04-21

    Using atomic layer deposition (ALD), we show that Pt nanoparticles can be deposited on the inner surfaces of carbon aerogels (CA). The resultant Pt-loaded materials exhibit high catalytic activity for the oxidation of CO even at loading levels as low as {approx}0.05 mg Pt/cm{sup 2}. We observe a conversion efficiency of nearly 100% in the temperatures range 150-250 C, and the total conversion rate seems to be only limited by the thermal stability of our CA support in ambient oxygen. Our ALD approach described here is universal in nature, and can be applied to the design of new catalytic materials for a variety of applications, including fuel cells, hydrogen storage, pollution control, green chemistry, and liquid fuel production.

  7. Scattering Solar Thermal Concentrators

    SciTech Connect (OSTI)

    Giebink, Noel C.

    2015-01-31

    This program set out to explore a scattering-based approach to concentrate sunlight with the aim of improving collector field reliability and of eliminating wind loading and gross mechanical movement through the use of a stationary collection optic. The approach is based on scattering sunlight from the focal point of a fixed collection optic into the confined modes of a sliding planar waveguide, where it is transported to stationary tubular heat transfer elements located at the edges. Optical design for the first stage of solar concentration, which entails focusing sunlight within a plane over a wide range of incidence angles (>120 degree full field of view) at fixed tilt, led to the development of a new, folded-path collection optic that dramatically out-performs the current state-of-the-art in scattering concentration. Rigorous optical simulation and experimental testing of this collection optic have validated its performance. In the course of this work, we also identified an opportunity for concentrating photovoltaics involving the use of high efficiency microcells made in collaboration with partners at the University of Illinois. This opportunity exploited the same collection optic design as used for the scattering solar thermal concentrator and was therefore pursued in parallel. This system was experimentally demonstrated to achieve >200x optical concentration with >70% optical efficiency over a full day by tracking with <1 cm of lateral movement at fixed latitude tilt. The entire scattering concentrator waveguide optical system has been simulated, tested, and assembled at small scale to verify ray tracing models. These models were subsequently used to predict the full system optical performance at larger, deployment scale ranging up to >1 meter aperture width. Simulations at an aperture widths less than approximately 0.5 m with geometric gains ~100x predict an overall optical efficiency in the range 60-70% for angles up to 50 degrees from normal. However, the concentrator optical efficiency was found to decrease significantly with increasing aperture width beyond 0.5 m due to parasitic waveguide out-coupling loss and low-level absorption that become dominant at larger scale. A heat transfer model was subsequently implemented to predict collector fluid heat gain and outlet temperature as a function of flow rate using the optical model as a flux input. It was found that the aperture width size limitation imposed by the optical efficiency characteristics of the waveguide limits the absolute optical power delivered to the heat transfer element per unit length. As compared to state-of-the-art parabolic trough CPV system aperture widths approaching 5 m, this limitation leads to an approximate factor of order of magnitude increase in heat transfer tube length to achieve the same heat transfer fluid outlet temperature. The conclusion of this work is that scattering solar thermal concentration cannot be implemented at the scale and efficiency required to compete with the performance of current parabolic trough CSP systems. Applied within the alternate context of CPV, however, the results of this work have likely opened up a transformative new path that enables quasi-static, high efficiency CPV to be implemented on rooftops in the form factor of traditional fixed-panel photovoltaics.

  8. Advanced Wellbore Thermal Simulator

    Energy Science and Technology Software Center (OSTI)

    1992-03-04

    GEOTEMP2, which is based on the earlier GEOTEMP program, is a wellbore thermal simulator designed for geothermal well drilling and production applications. The code treats natural and forced convection and conduction within the wellbore and heat conduction within the surrounding rock matrix. A variety of well operations can be modeled including injection, production, forward and reverse circulation with gas or liquid, gas or liquid drilling, and two-phase steam injection and production. Well completion with severalmore » different casing sizes and cement intervals can be modeled. The code allows variables, such as flow rate, to change with time enabling a realistic treatment of well operations. Provision is made in the flow equations to allow the flow areas of the tubing to vary with depth in the wellbore. Multiple liquids can exist in GEOTEMP2 simulations. Liquid interfaces are tracked through the tubing and annulus as one liquid displaces another. GEOTEMP2, however, does not attempt to simulate displacement of liquids with a gas or two-phase steam or vice versa. This means that it is not possible to simulate an operation where the type of drilling fluid changes, e.g. mud going to air. GEOTEMP2 was designed primarily for use in predicting the behavior of geothermal wells, but it is flexible enough to handle many typical drilling, production, and injection problems in the oil industry as well. However, GEOTEMP2 does not allow the modeling of gas-filled annuli in production or injection problems. In gas or mist drilling, no radiation losses are included in the energy balance. No attempt is made to model flow in the formation. Average execution time is 50 CP seconds on a CDC CYBER170. This edition of GEOTEMP2 is designated as Version 2.0 by the contributors.« less

  9. REACTOR GROUT THERMAL PROPERTIES

    SciTech Connect (OSTI)

    Steimke, J.; Qureshi, Z.; Restivo, M.; Guerrero, H.

    2011-01-28

    Savannah River Site has five dormant nuclear production reactors. Long term disposition will require filling some reactor buildings with grout up to ground level. Portland cement based grout will be used to fill the buildings with the exception of some reactor tanks. Some reactor tanks contain significant quantities of aluminum which could react with Portland cement based grout to form hydrogen. Hydrogen production is a safety concern and gas generation could also compromise the structural integrity of the grout pour. Therefore, it was necessary to develop a non-Portland cement grout to fill reactors that contain significant quantities of aluminum. Grouts generate heat when they set, so the potential exists for large temperature increases in a large pour, which could compromise the integrity of the pour. The primary purpose of the testing reported here was to measure heat of hydration, specific heat, thermal conductivity and density of various reactor grouts under consideration so that these properties could be used to model transient heat transfer for different pouring strategies. A secondary purpose was to make qualitative judgments of grout pourability and hardened strength. Some reactor grout formulations were unacceptable because they generated too much heat, or started setting too fast, or required too long to harden or were too weak. The formulation called 102H had the best combination of characteristics. It is a Calcium Alumino-Sulfate grout that contains Ciment Fondu (calcium aluminate cement), Plaster of Paris (calcium sulfate hemihydrate), sand, Class F fly ash, boric acid and small quantities of additives. This composition afforded about ten hours of working time. Heat release began at 12 hours and was complete by 24 hours. The adiabatic temperature rise was 54 C which was within specification. The final product was hard and displayed no visible segregation. The density and maximum particle size were within specification.

  10. Size effects on the thermal conductivity of amorphous silicon thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thomas Edwin Beechem; Braun, Jeffrey L.; Baker, Christopher H.; Elahi, Miraz; Artyushkova, Kateryna; Norris, Pamela M.; Leseman, Zayd Chad; Gaskins, John T.; Hopkins, Patrick E.; Giri, Ashutosh

    2016-04-01

    In this study, we investigate thickness-limited size effects on the thermal conductivity of amorphous silicon thin films ranging from 3 to 1636 nm grown via sputter deposition. While exhibiting a constant value up to ~100 nm, the thermal conductivity increases with film thickness thereafter. The thickness dependence we demonstrate is ascribed to boundary scattering of long wavelength vibrations and an interplay between the energy transfer associated with propagating modes (propagons) and nonpropagating modes (diffusons). A crossover from propagon to diffuson modes is deduced to occur at a frequency of ~1.8 THz via simple analytical arguments. These results provide empirical evidencemore » of size effects on the thermal conductivity of amorphous silicon and systematic experimental insight into the nature of vibrational thermal transport in amorphous solids.« less

  11. Fabrication of high thermal conductivity arrays of carbon nanotubes and their composites

    DOE Patents [OSTI]

    Geohegan, David B. (Knoxville, TN) [Knoxville, TN; Ivanov, Ilya N. (Knoxville, TN) [Knoxville, TN; Puretzky, Alexander A [Knoxville, TN

    2010-07-27

    Methods and apparatus are described for fabrication of high thermal conductivity arrays of carbon nanotubes and their composites. A composition includes a vertically aligned nanotube array including a plurality of nanotubes characterized by a property across substantially all of the vertically aligned nanotube array. A method includes depositing a vertically aligned nanotube array that includes a plurality of nanotubes; and controlling a deposition rate of the vertically aligned nanotubes array as a function of an in situ monitored property of the plurality of nanotubes.

  12. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    4 Average thermal performance rating of solar thermal collectors by type shipped in 2009 (Btu per square foot per day) Low- High Temperature Temperature Liquid/air Parabolic Year Metallic and Nonmetallic Air ICS/Thermosi phon Flat-Plate (Pumped) Evaculated Tube Concentrator Paraboloic Dish/Trough 2009 1,139 971 913 981 973 2,196 1,262 Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal Collector Manufacturers Survey." Medium-Temperature Type Liquid

  13. Rapid thermal processing by stamping

    DOE Patents [OSTI]

    Stradins, Pauls; Wang, Qi

    2013-03-05

    A rapid thermal processing device and methods are provided for thermal processing of samples such as semiconductor wafers. The device has components including a stamp (35) having a stamping surface and a heater or cooler (40) to bring it to a selected processing temperature, a sample holder (20) for holding a sample (10) in position for intimate contact with the stamping surface; and positioning components (25) for moving the stamping surface and the stamp (35) in and away from intimate, substantially non-pressured contact. Methods for using and making such devices are also provided. These devices and methods allow inexpensive, efficient, easily controllable thermal processing.

  14. Ocean Thermal Extractable Energy Visualization

    SciTech Connect (OSTI)

    Ascari, Matthew

    2012-10-28

    The Ocean Thermal Extractable Energy Visualization (OTEEV) project focuses on assessing the Maximum Practicably Extractable Energy (MPEE) from the world’s ocean thermal resources. MPEE is defined as being sustainable and technically feasible, given today’s state-of-the-art ocean energy technology. Under this project the OTEEV team developed a comprehensive Geospatial Information System (GIS) dataset and software tool, and used the tool to provide a meaningful assessment of MPEE from the global and domestic U.S. ocean thermal resources.

  15. Thermal properties of soils and soils testing

    SciTech Connect (OSTI)

    Not Available

    1981-02-17

    The thermal properties of soils are reviewed with reference to the use of soils as heat sources, heat sinks, or thermal storage. Specific heat and thermal conductivity are discussed. (ACR)

  16. Electric Motor Thermal Management | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    ape030_bennion_2012_o.pdf More Documents & Publications Electric Motor Thermal Management Electric Motor Thermal Management Vehicle Technologies Office Merit Review 2015: Electric Motor Thermal Management R&D

  17. Chemical vapor deposition of aluminum oxide

    DOE Patents [OSTI]

    Gordon, Roy; Kramer, Keith; Liu, Xinye

    2000-01-01

    An aluminum oxide film is deposited on a heated substrate by CVD from one or more alkylaluminum alkoxide compounds having composition R.sub.n Al.sub.2 (OR').sub.6-n, wherein R and R' are alkyl groups and n is in the range of 1 to 5.

  18. Plasma deposition of amorphous metal alloys

    DOE Patents [OSTI]

    Hays, Auda K. (Albuquerque, NM)

    1986-01-01

    Amorphous metal alloy coatings are plasma-deposited by dissociation of vapors of organometallic compounds and metalloid hydrides in the presence of a reducing gas, using a glow discharge. Tetracarbonylnickel, phosphine, and hydrogen constitute a typical reaction mixture of the invention, yielding a NiPC alloy.

  19. Atomic layer deposition of nanoporous biomaterials.

    SciTech Connect (OSTI)

    Narayan, R. J.; Adiga, S. P.; Pellin, M. J.; Curtiss, L. A.; Stafslien, S.; Chisholm, B.; Monteiro-Riviere, N. A.; Brigmon, R. L.; Elam, J. W.; Univ. of North Carolina; North Carolina State Univ.; Eastman Kodak Co.; North Dakota State Univ.; SRL

    2010-03-01

    Due to its chemical stability, uniform pore size, and high pore density, nanoporous alumina is being investigated for use in biosensing, drug delivery, hemodialysis, and other medical applications. In recent work, we have examined the use of atomic layer deposition for coating the surfaces of nanoporous alumina membranes. Zinc oxide coatings were deposited on nanoporous alumina membranes using atomic layer deposition. The zinc oxide-coated nanoporous alumina membranes demonstrated antimicrobial activity against Escherichia coli and Staphylococcus aureus bacteria. These results suggest that atomic layer deposition is an attractive technique for modifying the surfaces of nanoporous alumina membranes and other nanostructured biomaterials. Nanoporous alumina, also known as anodic aluminum oxide (AAO), is a nanomaterial that exhibits several unusual properties, including high pore densities, straight pores, small pore sizes, and uniform pore sizes. In 1953, Keller et al. showed that anodizing aluminum in acid electrolytes results in a thick layer of nearly cylindrical pores, which are arranged in a close-packed hexagonal cell structure. More recently, Matsuda & Fukuda demonstrated preparation of highly ordered platinum and gold nanohole arrays using a replication process. In this study, a negative structure of nanoporous alumina was initially fabricated and a positive structure of a nanoporous metal was subsequently fabricated. Over the past fifteen years, nanoporous alumina membranes have been used as templates for growth of a variety of nanostructured materials, including nanotubes, nanowires, nanorods, and nanoporous membranes.

  20. Defect distributions in weld-deposited cladding

    SciTech Connect (OSTI)

    Li, Y.Y.; Mabe, W.R.

    1998-11-01

    Defect distributions in stainless steel and nickel-chromium alloy weld-deposited cladding over a low alloy steel base were characterized by destructive evaluation (DE). An evaluation of the observed defects was conducted to characterize the defects by type or classification. Size distributions of cladding defect types were developed from the information obtained. This paper presents the results of the cladding evaluation.

  1. Plasma deposition of amorphous metal alloys

    DOE Patents [OSTI]

    Hays, A.K.

    1979-07-18

    Amorphous metal alloy coatings are plasma-deposited by dissociation of vapors of organometallic compounds and metalloid hydrides in the presence of a reducing gas, using a glow discharge. Tetracarbonylnickel, phosphine, and hydrogen constitute a typical reaction mixture of the invention, yielding a NiPC alloy.

  2. Radiography used to image thermal explosions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October » Radiography used to image thermal explosions Radiography used to image thermal explosions Researchers have gained an understanding of the mechanism of thermal explosions and have created a model capturing the stages of the explosion. October 9, 2012 Tabletop X-ray radiography of a thermal explosion. Tabletop X-ray radiography of a thermal explosion. Researchers have gained an understanding of the mechanism of thermal explosions and have created a model capturing the stages of the

  3. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    41 388 2009 10,511 809 2,307 32 980 - No data reported. ... disclosed. Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal Collector ...

  4. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    U.S. Total 5,517,291 3,455,846 100.00 - No data reported. ... rounding. Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal Collector ...

  5. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    7 Import shipments of solar thermal collectors by type, 2000 ... 687 - 5,517 2009 1,987 715 754 3,456 - No data reported. ... Source: U.S. Energy Information Administration, Form ...

  6. Thermal-Mechanical Technologies | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of thermal-mechanical research includes: Single and two phase heat transfer Nanomaterial synthesis Heat transfer fluids Engine and power electronics cooling Thermal energy...

  7. Plasma-Thermal Synthesis - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Synthesis Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL's Plasma-Thermal Synthesis process improves the conversion process...

  8. Plutonium Hexafluoride Thermal Decomposition Rates (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Plutonium Hexafluoride Thermal Decomposition Rates Citation Details In-Document Search Title: Plutonium Hexafluoride Thermal Decomposition Rates Uranium and plutonium may be ...

  9. Amulaire Thermal Technology | Open Energy Information

    Open Energy Info (EERE)

    Amulaire Thermal Technology Jump to: navigation, search Name: Amulaire Thermal Technology Address: 11555 Sorrento Valley Road Place: San Diego, California Zip: 92121 Region:...

  10. A nanostructure thermal property measurement platform. (Conference...

    Office of Scientific and Technical Information (OSTI)

    side of the central heater), and this feature permits identification of possible changes in thermal conductance along the wire and measurement of the thermal contact resistance. ...

  11. Develop & Evaluate Materials & Additives that Enhance Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluate Materials & Additives that Enhance Thermal & Overcharge Abuse Develop & Evaluate Materials & Additives that Enhance Thermal & Overcharge Abuse 2011 DOE Hydrogen and Fuel ...

  12. Stewart Thermal Ltd | Open Energy Information

    Open Energy Info (EERE)

    Thermal Ltd Jump to: navigation, search Name: Stewart Thermal Ltd Place: United Kingdom Sector: Biomass Product: Provides specialist advice in the field of biomass energy....

  13. Alumni | Solid State Solar Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Visit Website Bo Qiu ThermalMechanical Engineer, Intel Corporation Visit Website Veronika Rinnerbauer Innovation Management, Bosch Visit Website Nitin Shukla Thermal Testing ...

  14. Nextreme Thermal Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Nextreme Thermal Solutions Inc Jump to: navigation, search Name: Nextreme Thermal Solutions Inc Place: North Carolina Zip: 27709-3981 Product: String representation "Manufactures...

  15. Power Electronic Thermal System Performance and Integration ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electronic Thermal System Performance and Integration Power Electronic Thermal System Performance and Integration 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual ...

  16. Review of Thermally Activated Technologies, July 2004

    Broader source: Energy.gov [DOE]

    Status of various thermally activated technologies (TATs); includes fuel-fired and waste-heat-fired applications of thermally driven cooling systems, heat pumps, and bottoming cycles.

  17. Thermal Design and Characterization of Heterogeneously Integrated...

    Office of Scientific and Technical Information (OSTI)

    with integrated thermal management on wide-bandgap AlN substrates followed by GaAs substrate removal are demonstrated. Without thermal management, substrate removal after ...

  18. Power Electronics Thermal Control (Presentation)

    SciTech Connect (OSTI)

    Narumanchi, S.

    2010-05-05

    Thermal management plays an important part in the cost of electric drives in terms of power electronics packaging. Very promising results have been obtained by using microporous coatings and skived surfaces in conjunction with single-phase and two-phase flows. Sintered materials and thermoplastics with embedded fibers show significant promise as thermal interface materials, or TIMs. Appropriate cooling technologies depend on the power electronics package application and reliability.

  19. Lih thermal energy storage device

    DOE Patents [OSTI]

    Olszewski, Mitchell; Morris, David G.

    1994-01-01

    A thermal energy storage device for use in a pulsed power supply to store waste heat produced in a high-power burst operation utilizes lithium hydride as the phase change thermal energy storage material. The device includes an outer container encapsulating the lithium hydride and an inner container supporting a hydrogen sorbing sponge material such as activated carbon. The inner container is in communication with the interior of the outer container to receive hydrogen dissociated from the lithium hydride at elevated temperatures.

  20. Thermally activated technologies: Technology Roadmap

    SciTech Connect (OSTI)

    None, None

    2003-05-01

    The purpose of this Technology Roadmap is to outline a set of actions for government and industry to develop thermally activated technologies for converting America’s wasted heat resources into a reservoir of pollution-free energy for electric power, heating, cooling, refrigeration, and humidity control. Fuel flexibility is important. The actions also cover thermally activated technologies that use fossil fuels, biomass, and ultimately hydrogen, along with waste heat.

  1. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    5 Shipments of complete solar thermal collector systems, 2008 and 2009 Shipment Information 2008 2009 Complete Collector Systems Shipped 63,961 75,066 Thousand Square Feet 4,058 5,995 Percent of Total Shipments 24 43 Number of Companies 46 62 Revenue of Systems (Thousand Dollars) 47,523 159,085 Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal Collector Manufacturers Survey."

  2. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    9 Companies involved in solar thermal collector related activities by type, 2008 and 2009 Type of Activity 2008 2009 Collector or System Design 45 59 Prototype Collector Development 27 27 Prototype System Development 23 23 Wholesale Distribution 58 61 Retail Distribution 29 31 Installation 21 27 Noncollector System Component Manufacture 26 32 Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal

  3. Thermal Batteries for Electric Vehicles

    SciTech Connect (OSTI)

    2011-11-21

    HEATS Project: UT Austin will demonstrate a high-energy density and low-cost thermal storage system that will provide efficient cabin heating and cooling for EVs. Compared to existing HVAC systems powered by electric batteries in EVs, the innovative hot-and-cold thermal batteries-based technology is expected to decrease the manufacturing cost and increase the driving range of next-generation EVs. These thermal batteries can be charged with off-peak electric power together with the electric batteries. Based on innovations in composite materials offering twice the energy density of ice and 10 times the thermal conductivity of water, these thermal batteries are expected to achieve a comparable energy density at 25% of the cost of electric batteries. Moreover, because UT Austins thermal energy storage systems are modular, they may be incorporated into the heating and cooling systems in buildings, providing further energy efficiencies and positively impacting the emissions of current building heating/cooling systems.

  4. Differential heating: A versatile method for thermal conductivity measurements in high-energy-density matter

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, Y.; Fernandez-Panella, A.; Sio, H.; Correa, A.; Shepherd, R.; Landen, O.; London, R. A.; Sterne, P. A.; Whitley, H. D.; Fratanduono, D.; et al

    2015-09-04

    We propose a method for thermal conductivity measurements of high energy density matter based on differential heating. A temperature gradient is created either by surface heating of one material or at an interface between two materials by different energy deposition. The subsequent heat conduction across the temperature gradient is observed by various time-resolved probing techniques. Conceptual designs of such measurements using laser heating, proton heating, and x-ray heating are presented. As a result, the sensitivity of the measurements to thermal conductivity is confirmed by simulations.

  5. Advanced thermally stable jet fuels. Technical progress report, October 1993--December 1993

    SciTech Connect (OSTI)

    Schobert, H.H.; Eser, S.; Song, C.; Hatcher, P.G.; Walsh, P.M.; Coleman, M.M.

    1994-01-01

    The Penn State program in advancd thermally stable coal-based jet fuels has five broad objectives: (1) development of mechanisms of degradation and solids formation; (2) quantitative measurement of growth of sub-micrometer and micrometer-sized particles suspended in fuels during thermal stressing; (3) characterization of carbonaceous deposits by various instrumental and microscopic methods; (4) elucidation of the role of additives in retarding them formation of vcarbonaceous solids; and, (5) assessment of the potential of production of high yields of cycloalkanes by direct liquefaction of coal.

  6. Method for depositing layers of high quality semiconductor material

    DOE Patents [OSTI]

    Guha, Subhendu; Yang, Chi C.

    2001-08-14

    Plasma deposition of substantially amorphous semiconductor materials is carried out under a set of deposition parameters which are selected so that the process operates near the amorphous/microcrystalline threshold. This threshold varies as a function of the thickness of the depositing semiconductor layer; and, deposition parameters, such as diluent gas concentrations, must be adjusted as a function of layer thickness. Also, this threshold varies as a function of the composition of the depositing layer, and in those instances where the layer composition is profiled throughout its thickness, deposition parameters must be adjusted accordingly so as to maintain the amorphous/microcrystalline threshold.

  7. Development of Diffusion barrier coatings and Deposition Technologies for Mitigating Fuel Cladding Chemical Interactions (FCCI)

    SciTech Connect (OSTI)

    Sridharan, Kumar; Allen, Todd; Cole, James

    2013-02-27

    The goal of this project is to develop diffusion barrier coatings on the inner cladding surface to mitigate fuel-cladding chemical interaction (FCCI). FCCI occurs due to thermal and radiation enhanced inter-diffusion between the cladding and fuel materials, and can have the detrimental effects of reducing the effective cladding wall thickness and lowering the melting points of the fuel and cladding. The research is aimed at the Advanced Burner Reactor (ABR), a sodium-cooled fast reactor, in which higher burn-ups will exacerbate the FCCI problem. This project will study both diffusion barrier coating materials and deposition technologies. Researchers will investigate pure vanadium, zirconium, and titanium metals, along with their respective oxides, on substrates of HT-9, T91, and oxide dispersion-strengthened (ODS) steels; these materials are leading candidates for ABR fuel cladding. To test the efficacy of the coating materials, the research team will perform high-temperature diffusion couple studies using both a prototypic metallic uranium fuel and a surrogate—the rare-earth element lanthanum. Ion irradiation experiments will test the stability of the coating and the coating-cladding interface. A critical technological challenge is the ability to deposit uniform coatings on the inner surface of cladding. The team will develop a promising non-line-of-sight approach that uses nanofluids . Recent research has shown the feasibility of this simple yet novel approach to deposit coatings on test flats and inside small sections of claddings. Two approaches will be investigated: 1) modified electrophoretic deposition (MEPD) and 2) boiling nanofluids. The coatings will be evaluated in the as-deposited condition and after sintering.

  8. Prediction and measurement of thermal transport across interfaces between isotropic solids and graphitic materials.

    SciTech Connect (OSTI)

    Hopkins, Patrick E.; Norris, Pamela M.; Smoyer, Justin L.; Duda, John C.

    2010-06-01

    Due to the high intrinsic thermal conductivity of carbon allotropes, there have been many attempts to incorporate such structures into existing thermal abatement technologies. In particular, carbon nanotubes (CNTs) and graphitic materials (i.e., graphite and graphene flakes or stacks) have garnered much interest due to the combination of both their thermal and mechanical properties. However, the introduction of these carbon-based nanostructures into thermal abatement technologies greatly increases the number of interfaces per unit length within the resulting composite systems. Consequently, thermal transport in these systems is governed as much by the interfaces between the constituent materials as it is by the materials themselves. This paper reports the behavior of phononic thermal transport across interfaces between isotropic thin films and graphite substrates. Elastic and inelastic diffusive transport models are formulated to aid in the prediction of conductance at a metal-graphite interface. The temperature dependence of the thermal conductance at Au-graphite interfaces is measured via transient thermoreflectance from 78 to 400 K. It is found that different substrate surface preparations prior to thin film deposition have a significant effect on the conductance of the interface between film and substrate.

  9. Filtered cathodic arc deposition apparatus and method

    DOE Patents [OSTI]

    Krauss, Alan R.

    1999-01-01

    A filtered cathodic arc deposition method and apparatus for the production of highly dense, wear resistant coatings which are free from macro particles. The filtered cathodic arc deposition apparatus includes a cross shaped vacuum chamber which houses a cathode target having an evaporable surface comprised of the coating material, means for generating a stream of plasma, means for generating a transverse magnetic field, and a macro particle deflector. The transverse magnetic field bends the generated stream of plasma in the direction of a substrate. Macro particles are effectively filtered from the stream of plasma by traveling, unaffected by the transverse magnetic field, along the initial path of the plasma stream to a macro particle deflector. The macro particle deflector has a preformed surface which deflects macro particles away from the substrate.

  10. Ultrashort pulse laser deposition of thin films

    DOE Patents [OSTI]

    Perry, Michael D.; Banks, Paul S.; Stuart, Brent C.

    2002-01-01

    Short pulse PLD is a viable technique of producing high quality films with properties very close to that of crystalline diamond. The plasma generated using femtosecond lasers is composed of single atom ions with no clusters producing films with high Sp.sup.3 /Sp.sup.2 ratios. Using a high average power femtosecond laser system, the present invention dramatically increases deposition rates to up to 25 .mu.m/hr (which exceeds many CVD processes) while growing particulate-free films. In the present invention, deposition rates is a function of laser wavelength, laser fluence, laser spot size, and target/substrate separation. The relevant laser parameters are shown to ensure particulate-free growth, and characterizations of the films grown are made using several diagnostic techniques including electron energy loss spectroscopy (EELS) and Raman spectroscopy.

  11. Surface acoustic wave dust deposition monitor

    DOE Patents [OSTI]

    Fasching, G.E.; Smith, N.S. Jr.

    1988-02-12

    A system is disclosed for using the attenuation of surface acoustic waves to monitor real time dust deposition rates on surfaces. The system includes a signal generator, a tone-burst generator/amplifier connected to a transmitting transducer for converting electrical signals into acoustic waves. These waves are transmitted through a path defining means adjacent to a layer of dust and then, in turn, transmitted to a receiving transducer for changing the attenuated acoustic wave to electrical signals. The signals representing the attenuated acoustic waves may be amplified and used in a means for analyzing the output signals to produce an output indicative of the dust deposition rates and/or values of dust in the layer. 8 figs.

  12. Methods for patterned deposition on a substrate

    DOE Patents [OSTI]

    Rye, Robert R. (Albuquerque, NM); Ricco, Antonio J. (Albuquerque, NM); Hampden-Smith, M. J. (Albuquerque, NM); Kodas, T. T. (Albuquerque, NM)

    1995-01-01

    A method is described for patterned depositions of a material onto a substrate. A surface of a polymeric substrate is first etched so as to form an etched layer having enhanced adhesions characteristics and then selected portions of the etched layer are removed so as to define a pattern having enhanced and diminished adhesion characteristics for the deposition of a conductor onto the remaining etched layer. In one embodiment, a surface of a PTFE substrate is chemically etched so as to improve the adhesion of copper thereto. Thereafter, selected portions of the etched surface are irradiated with a laser beam so as to remove the etched selected portions of the etched surface and form patterns of enhanced and diminished adhesion of copper thereto.

  13. Methods for patterned deposition on a substrate

    DOE Patents [OSTI]

    Rye, R.R.; Ricco, A.J.; Hampden-Smith, M.J.; Kodas, T.T.

    1995-01-10

    A method is described for patterned depositions of a material onto a substrate. A surface of a polymeric substrate is first etched so as to form an etched layer having enhanced adhesions characteristics and then selected portions of the etched layer are removed so as to define a pattern having enhanced and diminished adhesion characteristics for the deposition of a conductor onto the remaining etched layer. In one embodiment, a surface of a PTFE substrate is chemically etched so as to improve the adhesion of copper thereto. Thereafter, selected portions of the etched surface are irradiated with a laser beam so as to remove the etched selected portions of the etched surface and form patterns of enhanced and diminished adhesion of copper thereto. 5 figures.

  14. Apparatus and method for photochemical vapor deposition

    DOE Patents [OSTI]

    Jackson, Scott C.; Rocheleau, Richard E.

    1987-03-31

    A photochemical vapor deposition apparatus includes a reactor housing having a window in one wall above a reaction chamber in the housing. A transparent curtain divides the reaction chamber into a reaction zone and a flush zone. At least one substrate is mounted in the reaction zone in light communication with the window so that ultraviolet radiation may penetrate through the window into the reaction zone. The window is kept clear by a gas flowing through the flush zone.

  15. DEPOSITION OF METAL ON NONMETAL FILAMENT

    DOE Patents [OSTI]

    Magel, T.T.

    1959-02-10

    A method is described for purifying metallic uranium by passing a halogen vapor continuously over the impure uranium to form uranium halide vapor and immediately passing the halide vapor into contact with a nonmetallic refractory surface which is at a temperature above the melting point of uranium metal. The halide is decomposed at the heated surface depositing molten metal, which collects and falls into a receiver below.

  16. Electrostatic force assisted deposition of graphene

    DOE Patents [OSTI]

    Liang, Xiaogan

    2011-11-15

    An embodiment of a method of depositing graphene includes bringing a stamp into contact with a substrate over a contact area. The stamp has at least a few layers of the graphene covering the contact area. An electric field is developed over the contact area. The stamp is removed from the vicinity of the substrate which leaves at least a layer of the graphene substantially covering the contact area.

  17. Stationary phase deposition based on onium salts

    DOE Patents [OSTI]

    Wheeler, David R.; Lewis, Patrick R.; Dirk, Shawn M.; Trudell, Daniel E.

    2008-01-01

    Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

  18. Nanotube array controlled carbon plasma deposition

    SciTech Connect (OSTI)

    Qian, Shi; Cao, Huiliang; Liu, Xuanyong; Ding, Chuanxian

    2013-06-17

    Finding approaches to control the elementary processes of plasma-solid interactions and direct the fluxes of matter at nano-scales becomes an important aspect in science. This letter reports that, by taking advantages of the spacing characteristics of discrete TiO{sub 2} nanotube arrays, the flying trajectories and the subsequent implantation and deposition manner of energetic carbon ions can be directed and controlled to fabricate hollow conical arrays. The study provides an alternative method for plasma nano-manufacturing.

  19. Chemical deposition methods using supercritical fluid solutions

    DOE Patents [OSTI]

    Sievers, Robert E.; Hansen, Brian N.

    1990-01-01

    A method for depositing a film of a desired material on a substrate comprises dissolving at least one reagent in a supercritical fluid comprising at least one solvent. Either the reagent is capable of reacting with or is a precursor of a compound capable of reacting with the solvent to form the desired product, or at least one additional reagent is included in the supercritical solution and is capable of reacting with or is a precursor of a compound capable of reacting with the first reagent or with a compound derived from the first reagent to form the desired material. The supercritical solution is expanded to produce a vapor or aerosol and a chemical reaction is induced in the vapor or aerosol so that a film of the desired material resulting from the chemical reaction is deposited on the substrate surface. In an alternate embodiment, the supercritical solution containing at least one reagent is expanded to produce a vapor or aerosol which is then mixed with a gas containing at least one additional reagent. A chemical reaction is induced in the resulting mixture so that a film of the desired material is deposited.

  20. Validation of thermal models for a prototypical MEMS thermal actuator.

    SciTech Connect (OSTI)

    Gallis, Michail A.; Torczynski, John Robert; Piekos, Edward Stanley; Serrano, Justin Raymond; Gorby, Allen D.; Phinney, Leslie Mary

    2008-09-01

    This report documents technical work performed to complete the ASC Level 2 Milestone 2841: validation of thermal models for a prototypical MEMS thermal actuator. This effort requires completion of the following task: the comparison between calculated and measured temperature profiles of a heated stationary microbeam in air. Such heated microbeams are prototypical structures in virtually all electrically driven microscale thermal actuators. This task is divided into four major subtasks. (1) Perform validation experiments on prototypical heated stationary microbeams in which material properties such as thermal conductivity and electrical resistivity are measured if not known and temperature profiles along the beams are measured as a function of electrical power and gas pressure. (2) Develop a noncontinuum gas-phase heat-transfer model for typical MEMS situations including effects such as temperature discontinuities at gas-solid interfaces across which heat is flowing, and incorporate this model into the ASC FEM heat-conduction code Calore to enable it to simulate these effects with good accuracy. (3) Develop a noncontinuum solid-phase heat transfer model for typical MEMS situations including an effective thermal conductivity that depends on device geometry and grain size, and incorporate this model into the FEM heat-conduction code Calore to enable it to simulate these effects with good accuracy. (4) Perform combined gas-solid heat-transfer simulations using Calore with these models for the experimentally investigated devices, and compare simulation and experimental temperature profiles to assess model accuracy. These subtasks have been completed successfully, thereby completing the milestone task. Model and experimental temperature profiles are found to be in reasonable agreement for all cases examined. Modest systematic differences appear to be related to uncertainties in the geometric dimensions of the test structures and in the thermal conductivity of the polycrystalline silicon test structures, as well as uncontrolled nonuniform changes in this quantity over time and during operation.

  1. Battery Thermal Management System Design Modeling (Presentation)

    SciTech Connect (OSTI)

    Kim, G-H.; Pesaran, A.

    2006-10-01

    Presents the objectives and motivations for a battery thermal management vehicle system design study.

  2. Thermal storage module for solar dynamic receivers

    DOE Patents [OSTI]

    Beatty, Ronald L. (Farragut, TN); Lauf, Robert J. (Oak Ridge, TN)

    1991-01-01

    A thermal energy storage system comprising a germanium phase change material and a graphite container.

  3. Thermal spray and cold spray analysis of density, porosity, and tensile Specimens for use with LIGA applications

    SciTech Connect (OSTI)

    DECKER,MERLIN K.; SMITH,MARK F.

    2000-02-01

    This analysis provides a preliminary investigation into using Twin-Wire Arc Thermal Spray and Cold Spray as material deposition processes for LIGA applications. These spray material processes were studied to make an initial determination of their potential as alternatives to producing mechanical parts via the electroplating process. Three materials, UltraMachinable{reg_sign} Stainless Steel, BondArc{reg_sign}, and aluminum, were sprayed using Thermal Spray. Only aluminum was sprayed using the Cold Spray process. Following the spray procedure, the test specimens were released from a copper mold and then tested. Three tests, density, tensile strength, and porosity, were performed on the specimens to determine the spray effect on material properties. Twin-Wire Arc Thermal Spray did not demonstrate adequate deposition properties and does not appear to be a good process candidate for LIGA. However, Cold Spray yielded better density results and warrants further investigation to analyze the minimum feature size produced by the process.

  4. Thermal Decomposition of IMX-104: Ingredient Interactions Govern Thermal Insensitivity

    SciTech Connect (OSTI)

    Maharrey, Sean; Wiese-Smith, Deneille; Highley, Aaron M.; Steill, Jeffrey D.; Behrens, Richard; Kay, Jeffrey J.

    2015-04-01

    This report summarizes initial studies into the chemical basis of the thermal insensitivity of INMX-104. The work follows upon similar efforts investigating this behavior for another DNAN-based insensitive explosive, IMX-101. The experiments described demonstrate a clear similarity between the ingredient interactions that were shown to lead to the thermal insensitivity observed in IMX-101 and those that are active in IMX-104 at elevated temperatures. Specifically, the onset of decomposition of RDX is shifted to a lower temperature based on the interaction of the RDX with liquid DNAN. This early onset of decomposition dissipates some stored energy that is then unavailable for a delayed, more violent release.

  5. Precursors for the polymer-assisted deposition of films (Patent...

    Office of Scientific and Technical Information (OSTI)

    Precursors for the polymer-assisted deposition of films Citation Details In-Document Search Title: Precursors for the polymer-assisted deposition of films You are accessing a ...

  6. Solvothermal Thin Film Deposition of Electron Blocking Layers | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers

  7. Device for thermal transfer and power generation

    DOE Patents [OSTI]

    Weaver, Stanton Earl; Arik, Mehmet

    2011-04-19

    A system is provided. The system includes a device that includes top and bottom thermally conductive substrates positioned opposite to one another, wherein a top surface of the bottom thermally conductive substrate is substantially atomically flat and a thermal blocking layer disposed between the top and bottom thermally conductive substrates. The device also includes top and bottom electrodes separated from one another between the top and bottom thermally conductive substrates to define a tunneling path, wherein the top electrode is disposed on the thermal blocking layer and the bottom electrode is disposed on the bottom thermally conductive substrate.

  8. Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal

    Office of Scientific and Technical Information (OSTI)

    Hydride Thin Films (Technical Report) | SciTech Connect Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal Hydride Thin Films Citation Details In-Document Search Title: Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal Hydride Thin Films This document summarizes research of reactively deposited metal hydride thin films and their properties. Reactive deposition processes are of interest, because desired stoichiometric phases are created in a

  9. Advanced Evaporative Deposition System with Embedded Heater Element and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shutter - Energy Innovation Portal Advanced Evaporative Deposition System with Embedded Heater Element and Shutter Colorado State University Contact CSU About This Technology Technology Marketing Summary A device for evaporative deposition of thin films that offers more efficient heating and greater deposition control. Key features include an embedded heater element and a shutter system. Description Typical evaporative deposition systems can be used for close space sublimation (CSS) or

  10. Fabrication and characterization of silver- and copper-coated Nylon 6 forcespun nanofibers by thermal evaporation

    SciTech Connect (OSTI)

    Mihut, Dorina M., E-mail: dorinamm@yahoo.com; Lozano, Karen [Department of Mechanical Engineering, The University of Texas Pan American, 1201 W University Drive, Edinburg, Texas 78539 (United States); Foltz, Heinrich [Department of Electrical Engineering, The University of Texas Pan American, 1201 W University Drive, Edinburg, Texas 78539 (United States)

    2014-11-01

    Silver and copper nanoparticles were deposited as thin films onto substrates consisting of Nylon 6 nanofibers manufactured using forcespinning{sup } equipment. Different rotational speeds were used to obtain continuous nanofibers of various diameters arranged as nonwoven mats. The Nylon 6 nanofibers were collected as successive layers on frames, and a high-vacuum thermal evaporation method was used to deposit the silver and copper thin films on the nanofibers. The structures were investigated using scanning electron microscopyscanning transmission electron microscopy, atomic force microscopy, x-ray diffraction, and electrical resistance measurements. The results indicate that evaporated silver and copper nanoparticles were successfully deposited on Nylon 6 nanofibers as thin films that adhered well to the polymer substrate while the native morphology of the nanofibers were preserved, and electrically conductive nanostructures were achieved.

  11. Excellent c-Si surface passivation by low-temperature atomic layer deposited titanium oxide

    SciTech Connect (OSTI)

    Liao, Baochen; Hoex, Bram; Aberle, Armin G.; Bhatia, Charanjit S.; Chi, Dongzhi

    2014-06-23

    In this work, we demonstrate that thermal atomic layer deposited (ALD) titanium oxide (TiO{sub x}) films are able to provide a—up to now unprecedented—level of surface passivation on undiffused low-resistivity crystalline silicon (c-Si). The surface passivation provided by the ALD TiO{sub x} films is activated by a post-deposition anneal and subsequent light soaking treatment. Ultralow effective surface recombination velocities down to 2.8 cm/s and 8.3 cm/s, respectively, are achieved on n-type and p-type float-zone c-Si wafers. Detailed analysis confirms that the TiO{sub x} films are nearly stoichiometric, have no significant level of contaminants, and are of amorphous nature. The passivation is found to be stable after storage in the dark for eight months. These results demonstrate that TiO{sub x} films are also capable of providing excellent passivation of undiffused c-Si surfaces on a comparable level to thermal silicon oxide, silicon nitride, and aluminum oxide. In addition, it is well known that TiO{sub x} has an optimal refractive index of 2.4 in the visible range for glass encapsulated solar cells, as well as a low extinction coefficient. Thus, the results presented in this work could facilitate the re-emergence of TiO{sub x} in the field of high-efficiency silicon wafer solar cells.

  12. Thermal conductivity of semitransparent materials

    SciTech Connect (OSTI)

    Fine, H.A.; Jury, S.H.; McElroy, D.L.; Yarbrough, D.W.

    1981-01-01

    The three-region approximate solution for coupled conductive and radiative heat transfer and an exact solution for uncoupled conductive and radiative heat transfer in a grey semitransparent medium bounded by infinite parallel isothermal plates are employed to establish the dependence of the apparent thermal conductivity of semitransparent materials on other material properties and boundary conditions. An application of the analyses which uses apparent thermal conductivity versus density data to predict the dependence of apparent thermal conductivity on temperature is demonstrated. The predictions for seven sets of R-11 fiberglass and rock wool insulations agree with published measured values to within the limits of experimental error (+- 3%). Agreement for three sets of R-19 fiberglass insulations was, however, not good.

  13. Thermal trim for a luminaire

    DOE Patents [OSTI]

    Bazydola, Sarah; Ghiu, Camil-Daniel; Harrison, Robert; Jeswani, Anil

    2013-02-19

    A luminaire with a thermal pathway to reduce the junction temperature of the luminaire's light source, and methods for so doing, are disclosed. The luminaire includes a can, a light engine, and a trim, that define a substantially continuous thermal pathway from the light engine to a surrounding environment. The can defines a can cavity and includes a can end region. The light engine is within the can cavity and includes a light source and a heat sink, including a heat sink end region, coupled thereto. The trim is at least partially disposed within the can cavity and includes a first trim end region coupled to the heat sink end region and a second trim end region coupled to the can end region. Thermal interface material may be located between: the heat sink and the trim, the trim and the can, and/or the heat sink and the light source.

  14. Low-Temperature Engineering Algorithm of Deposition Risk

    Energy Science and Technology Software Center (OSTI)

    1992-12-08

    LEADER is designed to qualitatively predict the potential coal ash deposition in an utility boiler in convective pass heat exchange surfaces below 1850 F. This program concentrates on those deposits which develop their strength through sulfation and not silicate sintering. Massive deposits that form on the upstream sides of boiler tubes at higher temperatures are not considered in this model.

  15. Categorical Exclusion Determinations: Environmental Management...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... September 13, 2011 CX-006990: Categorical Exclusion Determination Synthesis and Characterization of Coatings by Chemical Solution Deposition Methods CX(s) Applied: B3.6 Date: 09...

  16. Effects of Ar plasma treatment for deposition of ruthenium film by remote plasma atomic layer deposition

    SciTech Connect (OSTI)

    Park, Taeyong; Lee, Jaesang; Park, Jingyu; Jeon, Heeyoung; Jeon, Hyeongtag; Lee, Ki-Hoon; Cho, Byung-Chul; Kim, Moo-Sung; Ahn, Heui-Bok

    2012-01-15

    Ruthenium thin films were deposited on argon plasma-treated SiO{sub 2} and untreated SiO{sub 2} substrates by remote plasma atomic layer deposition using bis(ethylcyclopentadienyl)ruthenium [Ru(EtCp){sub 2}] as a Ru precursor and ammonia plasma as a reactant. The results of in situ Auger electron spectroscopy (AES) analysis indicate that the initial transient region of Ru deposition was decreased by Ar plasma treatment at 400 deg. C, but did not change significantly at 300 deg. C The deposition rate exhibited linearity after continuous film formation and the deposition rates were about 1.7 A/cycle and 0.4 A/cycle at 400 deg. C and 300 deg. C, respectively. Changes of surface energy and polar and dispersive components were measured by the sessile drop test. The quantity of surface amine groups was measured from the surface nitrogen concentration with AES. Furthermore, the Ar plasma-treated SiO{sub 2} contained more amine groups and less hydroxyl groups on the surface than on untreated SiO{sub 2}. Auger spectra exhibited chemical shifts by Ru-O bonding, and larger shifts were observed on untreated substrates due to the strong adhesion of Ru films.

  17. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    1 Distribution of domestic solar thermal collector shipments (thousand square feet) 2008 2009 Wholesale Distributors 8,680 4,063 Retail Distributors 3,997 5,739 Exporters 368 346 Installers 948 939 End Users 723 1,134 U.S. Total 14,716 12,221 Customer Type Shipments Notes: Totals may not equal sum of components due to independent rounding. U.S. total includes territories. Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal Collector Manufacturers Survey

  18. Method to grow pure nanocrystalline diamond films at low temperatures and high deposition rates

    DOE Patents [OSTI]

    Carlisle, John A.; Gruen, Dieter M.; Auciello, Orlando; Xiao, Xingcheng

    2009-07-07

    A method of depositing nanocrystalline diamond film on a substrate at a rate of not less than about 0.2 microns/hour at a substrate temperature less than about 500.degree. C. The method includes seeding the substrate surface with nanocrystalline diamond powder to an areal density of not less than about 10.sup.10sites/cm.sup.2, and contacting the seeded substrate surface with a gas of about 99% by volume of an inert gas other than helium and about 1% by volume of methane or hydrogen and one or more of acetylene, fullerene and anthracene in the presence of a microwave induced plasma while maintaining the substrate temperature less than about 500.degree. C. to deposit nanocrystalline diamond on the seeded substrate surface at a rate not less than about 0.2 microns/hour. Coatings of nanocrystalline diamond with average particle diameters of less than about 20 nanometers can be deposited with thermal budgets of 500.degree. C.-4 hours or less onto a variety of substrates such as MEMS devices.

  19. High-rate reactive sputter deposition of zirconium dioxide (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Journal Article: High-rate reactive sputter deposition of zirconium dioxide Citation Details In-Document Search Title: High-rate reactive sputter deposition of zirconium dioxide Using an improved reactive sputter deposition technique, zirconium dioxide is deposited on cooled and uncooled substrates at low, medium, and high rates of 51.7, 95.4, and 152.4 nm/min, respectively. The films are deposited by sputtering a Zr target in an oxygen--argon plasma. The Zr target

  20. Ocean thermal energy conversion (OTEC)

    SciTech Connect (OSTI)

    Lockerby, R.W.

    1981-01-01

    Ocean thermal energy conversion (OTEC) is reviewed briefly. The two types of OTEC system (open and closed) are described and limitations are pointed out. A bibliography of 148 references on OTEC is given for the time period 1975 to 1980. Entries are arranged alphabetically according to the author's name. (MJJ)

  1. HYDROGEOLOGY OF THE THERMAL LANDSLIDE

    SciTech Connect (OSTI)

    Vantine, J.

    1985-01-22

    The large Thermal Landslide overlies the initial area of geothermal development at The Geysers. The landslide is waterbearing while the underlying Franciscan formation bedrock units are essentially non-waterbearing except where affected by hydrothermal alteration. Perched ground water moving through the landslide is heated prior to discharge as spring flow.

  2. What can recycling in thermal reactors accomplish?

    SciTech Connect (OSTI)

    Piet, Steven J.; Matthern, Gretchen E.; Jacobson, Jacob J.

    2007-07-01

    Thermal recycle provides several potential benefits when used as stop-gap, mixed, or backup recycling to recycling in fast reactors. These three roles involve a mixture of thermal and fast recycling; fast reactors are required to some degree at some time. Stop-gap uses thermal reactors only until fast reactors are adequately deployed and until any thermal-recycle-only facilities have met their economic lifetime. Mixed uses thermal and fast reactors symbiotically for an extended period of time. Backup uses thermal reactors only if problems later develop in the fast reactor portion of a recycling system. Thermal recycle can also provide benefits when used as pure thermal recycling, with no intention to use fast reactors. However, long term, the pure thermal recycling approach is inadequate to meet several objectives. (authors)

  3. Vapor-deposited porous films for energy conversion

    DOE Patents [OSTI]

    Jankowski, Alan F.; Hayes, Jeffrey P.; Morse, Jeffrey D.

    2005-07-05

    Metallic films are grown with a "spongelike" morphology in the as-deposited condition using planar magnetron sputtering. The morphology of the deposit is characterized by metallic continuity in three dimensions with continuous and open porosity on the submicron scale. The stabilization of the spongelike morphology is found over a limited range of the sputter deposition parameters, that is, of working gas pressure and substrate temperature. This spongelike morphology is an extension of the features as generally represented in the classic zone models of growth for physical vapor deposits. Nickel coatings were deposited with working gas pressures up 4 Pa and for substrate temperatures up to 1000 K. The morphology of the deposits is examined in plan and in cross section views with scanning electron microscopy (SEM). The parametric range of gas pressure and substrate temperature (relative to absolute melt point) under which the spongelike metal deposits are produced appear universal for other metals including gold, silver, and aluminum.

  4. Mechanosynthesis, deposition and characterization of CZTS and CZTSe materials for solar cell applications

    SciTech Connect (OSTI)

    Shyju, T.S.; Anandhi, S.; Suriakarthick, R.; Gopalakrishnan, R.; Kuppusami, P.

    2015-07-15

    Mechanosynthesis of nanocrystalline powders of CZTS and CZTSe by ball milling technique and the physical properties of thermally evaporated CZTS and CZTSe thin films as a function of substrate temperature are investigated. Nanocrystalline Cu–Zn–Tin–Sulphide (CZTS) and Cu–Zn–Tin–Selenide (CZTSe) powders synthesized by ball milling at different milling time using the source materials of Cu, Zn, Sn, S (or) Se in the ratio 2:1:1:4 are investigated. The above synthesized powder was thermally evaporated on glass substrate kept at room temperature and 673 K under a vacuum of 10{sup −6} mbar to prepare quaternary compound semiconducting thin films in a single step process. The synthesized powder and deposited CZTS and CZTSe thin films belong to tetragonal crystal system. Raman spectra reveal that the synthesized nanocrystals are pure without any secondary phases. A gradual reduction in optical bandgap of films was observed with increasing substrate temperature due to increased crystallinity of the films. The changes in surface morphology of the films with respect to substrate temperature were studied by scanning electron microscopy and atomic force microscopy. Electrical studies indicate that the deposited films have p-type conductivity. - Highlights: • Nanocrystalline powders of CZTS and CZTSe are synthesized by ball milling technique. • The ball milled powder was thermally evaporated on glass at room temperature and 673 K. • Raman spectroscopy reveals that the synthesized nanocrystals are pure without any secondary phases. • SEM and AFM micrographs illustrate the granular type of growth and the roughness and particle sizes obtained at the substrate temperature of 673 K are higher than those obtained in the room temperature. • Hall coefficient obtained for the film confirms the p-type conductivity. • A gradual reduction in optical bandgap was observed with increasing substrate temperature.

  5. Massively parallel computation of 3D flow and reactions in chemical vapor deposition reactors

    SciTech Connect (OSTI)

    Salinger, A.G.; Shadid, J.N.; Hutchinson, S.A.; Hennigan, G.L.; Devine, K.D.; Moffat, H.K.

    1997-12-01

    Computer modeling of Chemical Vapor Deposition (CVD) reactors can greatly aid in the understanding, design, and optimization of these complex systems. Modeling is particularly attractive in these systems since the costs of experimentally evaluating many design alternatives can be prohibitively expensive, time consuming, and even dangerous, when working with toxic chemicals like Arsine (AsH{sub 3}): until now, predictive modeling has not been possible for most systems since the behavior is three-dimensional and governed by complex reaction mechanisms. In addition, CVD reactors often exhibit large thermal gradients, large changes in physical properties over regions of the domain, and significant thermal diffusion for gas mixtures with widely varying molecular weights. As a result, significant simplifications in the models have been made which erode the accuracy of the models` predictions. In this paper, the authors will demonstrate how the vast computational resources of massively parallel computers can be exploited to make possible the analysis of models that include coupled fluid flow and detailed chemistry in three-dimensional domains. For the most part, models have either simplified the reaction mechanisms and concentrated on the fluid flow, or have simplified the fluid flow and concentrated on rigorous reactions. An important CVD research thrust has been in detailed modeling of fluid flow and heat transfer in the reactor vessel, treating transport and reaction of chemical species either very simply or as a totally decoupled problem. Using the analogy between heat transfer and mass transfer, and the fact that deposition is often diffusion limited, much can be learned from these calculations; however, the effects of thermal diffusion, the change in physical properties with composition, and the incorporation of surface reaction mechanisms are not included in this model, nor can transitions to three-dimensional flows be detected.

  6. Thermal transport in shock wave–compressed solids using pulsed laser heating

    SciTech Connect (OSTI)

    La Lone, B. M. Capelle, G.; Stevens, G. D.; Turley, W. D.; Veeser, L. R.

    2014-07-15

    A pulsed laser heating method was developed for determining thermal transport properties of solids under shock-wave compression. While the solid is compressed, a laser deposits a known amount of heat onto the sample surface, which is held in the shocked state by a transparent window. The heat from the laser briefly elevates the surface temperature and then diffuses into the interior via one-dimensional heat conduction. The thermal effusivity is determined from the time history of the resulting surface temperature pulse, which is recorded with optical pyrometry. Thermal effusivity is the square root of the product of thermal conductivity and volumetric heat capacity and is the key thermal transport parameter for relating the surface temperature to the interior temperature of the sample in a dynamic compression experiment. Therefore, this method provides information that is needed to determine the thermodynamic state of the interior of a compressed metal sample from a temperature measurement at the surface. The laser heat method was successfully demonstrated on tin that was shock compressed with explosives to a stress and temperature of ∼25 GPa and ∼1300 K. In this state, tin was observed to have a thermal effusivity of close to twice its ambient value. The implications on determining the interior shock wave temperature of tin are discussed.

  7. NON-DESTRUCTIVE THERMAL BARRIER COATING SPALLATION PREDICTION BY A LOADBASED MICRO-INDENTATION TECHNIQUE

    SciTech Connect (OSTI)

    J. M. Tannenbaum; K. Lee; B. S.-J. Kang; M.A. Alvin

    2010-11-18

    Currently, the durability and life cycle of thermal barrier coatings (TBC) applied to gas turbine blades and combustor components are limiting the maximum temperature and subsequent efficiency at which gas turbine engines operate. The development of new materials, coating technologies and evaluation techniques is required if enhanced efficiency is to be achieved. Of the current ceramic coating materials used in gas turbine engines, yttria stabilized zirconia (YSZ) is most prevalent, its low thermal conductivity, high thermal expansion coefficient and outstanding mechanical strength make it ideal for use in TBC systems. However, residual stresses caused by coefficients of thermal expansion mismatches within the TBC system and unstable thermally grown oxides are considered the primary causes for its premature and erratic spallation failure. Through finite element simulations, it is shown that the residual stresses generated within the thermally grown oxide (TGO), bond coat (BC), YSZ and their interfaces create slight variations in indentation unloading surface stiffness response prior to spallation failure. In this research, seven air plasma sprayed and one electron beam physical vapor deposition yttria partially stabilized zirconia TBCs were subjected to isothermal and cyclic loadings at 1100C. The associated coating degradation was evaluated using a non-destructive multiple partial unloading micro-indentation procedure. The results show that the proposed non-destructive micro-indentation evaluation technique can be an effective and specimenindependent TBC failure prediction tool capable of determining the location of initial spallation failure prior to its actual occurrence.

  8. Solar energy thermalization and storage device

    DOE Patents [OSTI]

    McClelland, J.F.

    A passive solar thermalization and thermal energy storage assembly which is visually transparent is described. The assembly consists of two substantial parallel, transparent wall members mounted in a rectangular support frame to form a liquid-tight chamber. A semitransparent thermalization plate is located in the chamber, substantially paralled to and about equidistant from the transparent wall members to thermalize solar radiation which is stored in a transparent thermal energy storage liquid which fills the chamber. A number of the devices, as modules, can be stacked together to construct a visually transparent, thermal storage wall for passive solar-heated buildings.

  9. Solar energy thermalization and storage device

    DOE Patents [OSTI]

    McClelland, John F.

    1981-09-01

    A passive solar thermalization and thermal energy storage assembly which is visually transparent. The assembly consists of two substantial parallel, transparent wall members mounted in a rectangular support frame to form a liquid-tight chamber. A semitransparent thermalization plate is located in the chamber, substantially paralled to and about equidistant from the transparent wall members to thermalize solar radiation which is stored in a transparent thermal energy storage liquid which fills the chamber. A number of the devices, as modules, can be stacked together to construct a visually transparent, thermal storage wall for passive solar-heated buildings.

  10. Hydroquinone-ZnO nano-laminate deposited by molecular-atomic layer deposition

    SciTech Connect (OSTI)

    Huang, Jie; Lucero, Antonio T.; Cheng, Lanxia; Kim, Jiyoung; Hwang, Hyeon Jun; Ha, Min-Woo

    2015-03-23

    In this study, we have deposited organic-inorganic hybrid semiconducting hydroquinone (HQ)/zinc oxide (ZnO) superlattices using molecular-atomic layer deposition, which enables accurate control of film thickness, excellent uniformity, and sharp interfaces at a low deposition temperature (150 °C). Self-limiting growth of organic layers is observed for the HQ precursor on ZnO surface. Nano-laminates were prepared by varying the number of HQ to ZnO cycles in order to investigate the physical and electrical effects of different HQ to ZnO ratios. It is indicated that the addition of HQ layer results in enhanced mobility and reduced carrier concentration. The highest Hall mobility of approximately 2.3 cm{sup 2}/V·s and the lowest n-type carrier concentration of approximately 1.0 × 10{sup 18}/cm{sup 3} were achieved with the organic-inorganic superlattice deposited with a ratio of 10 ZnO cycles to 1 HQ cycle. This study offers an approach to tune the electrical transport characteristics of ALD ZnO matrix thin films using an organic dopant. Moreover, with organic embedment, this nano-laminate material may be useful for flexible electronics.

  11. Validation of ATR Fission Power Deposition Fraction in HEU and LEU Fuel Plates

    SciTech Connect (OSTI)

    G. S. Chang

    2008-09-01

    The Advanced Test Reactor (ATR) is a high power (250 MW), high neutron flux research reactor operating in the United States. Powered with highly enriched uranium (HEU), the ATR has a maximum unperturbed thermal neutron flux rating of 1.0 x 1015 n/cm2s. Because of its high power and large test volumes located in high flux areas, the ATR is an ideal candidate for assessing the feasibility of converting an HEU driven reactor to a low-enriched core. A detailed plate-by-plate MCNP ATR full core model has been developed and validated for the low-enriched uranium (LEU) fuel conversion feasibility study. Using this model, an analysis has been performed to determine the LEU density and U-235 enrichment required in the fuel meat to yield equivalent K-eff versus effective full power days (EFPDs) between the HEU and LEU cores. This model has also been used to optimize U-235 content of the LEU core, minimizing the differences in K-eff and heat flux profile between the HEU and LEU cores at 115 MW total core power for 125 EFPDs. The LEU core conversion feasibility study evaluated foil type (U-10Mo) fuel with the LEU reference design of 19.7 wt% U-235 enrichment. The LEU reference design has a fixed fuel meat thickness of 0.330 mm and can sustain the same operating cycle length as the HEU fuel. Heat flux and fission power density are parameters that are proportional to the fraction of fission power deposited in fuel. Thus, the accurate determination of the fraction of fission power deposited in the fuel is important to ATR nuclear safety. In this work, a new approach was developed and validated, the Tally Fuel Cells Only (TFCO) method. This method calculates and compares the fission power deposition fraction between HEU and LEU fuel plates. Due to the high density of the U-10Mo LEU fuel, the fission ?-energy deposition fraction is 37.12%, which is larger than the HEUs ?-energy deposition fraction of 19.7%. As a result, the fuel decay heat cooling will need to be improved. During the power operation, the total fission energy (200 MeV per fission) deposition fraction of LEU and HEU are 90.9% and 89.1%, respectively.

  12. ARM - Evaluation Product - Multispectral Thermal Imager (MTI...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : Multispectral Thermal Imager (MTI) The Multispectral Thermal Imager is a...

  13. Conceptual Thermal Treatment Technologies Feasibility Study

    SciTech Connect (OSTI)

    Suer, A.

    1996-02-28

    This report presents a conceptual Thermal Treatment Technologies Feasibility Study (FS) for the Savannah River Site (SRS) focusing exclusively on thermal treatment technologies for contaminated soil, sediment, or sludge remediation projects.

  14. Thermal synthesis apparatus and process

    DOE Patents [OSTI]

    Fincke, James R.; Detering, Brent A.

    2004-11-23

    An apparatus for thermal conversion of one or more reactants to desired end products includes an insulated reactor chamber having a high temperature heater such as a plasma torch at its inlet end and, optionally, a restrictive convergent-divergent nozzle at its outlet end. In a thermal conversion method, reactants are injected upstream from the reactor chamber and thoroughly mixed with the plasma stream before entering the reactor chamber. The reactor chamber has a reaction zone that is maintained at a substantially uniform temperature. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle, which "freezes" the desired end product(s) in the heated equilibrium reaction stage, or is discharged through an outlet pipe without the convergent-divergent nozzle. The desired end products are then separated from the gaseous stream.

  15. Microwavable thermal energy storage material

    DOE Patents [OSTI]

    Salyer, Ival O.

    1998-09-08

    A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene-vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments.

  16. Microwavable thermal energy storage material

    DOE Patents [OSTI]

    Salyer, I.O.

    1998-09-08

    A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments. 3 figs.

  17. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    0 Soloar-related sales as a percentage of total company sales revenue, 2008 and 2009 2008 2009 90-100 49 56 50-89 9 7 10-49 7 12 Less than 10 9 13 U.S. Total 74 88 Percent of Total Sales Revenue Number of Companies Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal Collector Manufacturers Survey."

  18. Thermal well-test method

    DOE Patents [OSTI]

    Tsang, Chin-Fu; Doughty, Christine A.

    1985-01-01

    A well-test method involving injection of hot (or cold) water into a groundwater aquifer, or injecting cold water into a geothermal reservoir. By making temperature measurements at various depths in one or more observation wells, certain properties of the aquifer are determined. These properties, not obtainable from conventional well test procedures, include the permeability anisotropy, and layering in the aquifer, and in-situ thermal properties. The temperature measurements at various depths are obtained from thermistors mounted in the observation wells.

  19. Electric thermal storage demonstration program

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    In early 1989, MMWEC, a joint action agency comprised of 30 municipal light departments in Massachusetts and one affiliate in Rhode Island, responded to a Department of Energy request to proposal for the Least Cost Utility Planning program. The MMWEC submission was for the development of a program, focused on small rural electric utilities, to promote the use of electric thermal storage heating systems in residential applications. In this progress report, cost savings at Bolyston light department is discussed. (JL)

  20. Electric thermal storage demonstration program

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    In early 1989, MMWEC, a joint action agency comprised of 30 municipal light departments in Massachusetts and one affiliate in Rhode Island, responded to a Department of Energy request to proposal for the Least Cost Utility Planning program. The MMWEC submission was for the development of a program, focused on small rural electric utilities, to promote the use of electric thermal storage heating systems in residential applications. In this progress report, cost savings at Bolyston light department is discussed. (JL)

  1. Tunable Thermal Link - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tunable Thermal Link Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryThermal links are incorporated into everything from frying pans to internal combustion engine spark plugs and heat sinks on integrated circuit boards. Typically, the link's thermal resistance is fixed and cannot be tuned after manufacture. While the ability to tune electrical resistors is widespread, virtually no tunable thermal resistance link exists, which has held back the

  2. Thermal Spray Coatings for Coastal Infrastructure

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, BernardS. Jr.; Cramer, S.D.; Bullard, S.J.

    1997-11-01

    Several protection strategies for coastal infrastructure using thermal-spray technology are presented from research at the Albany Research Center. Thermal-sprayed zinc coatings for anodes in impressed current cathodic protection systems are used to extend the service lives of reinforced concrete bridges along the Oregon coast. Thermal-sprayed Ti is examined as an alternative to the consumable zinc anode. Sealed thermal-sprayed Al is examined as an alternative coating to zinc dust filled polyurethane paint for steel structures.

  3. NREL: Transportation Research - Vehicle Thermal Management Facilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicle Thermal Management Facilities Image of a building with two semi truck cabs in front of it. The VTIF is used for thermal testing of every class of on-road vehicle. Photo by Dennis Schroeder, NREL The National Renewable Energy Laboratory (NREL) uses research and testing facilities to develop advanced thermal management technologies for vehicles. Vehicle Testing and Integration Facility The Vehicle Testing and Integration Facility features a test pad to conduct vehicle thermal soak testing

  4. Battery Thermal Management System Design Modeling

    SciTech Connect (OSTI)

    Pesaran, A.; Kim, G. H.

    2006-11-01

    Looks at the impact of cooling strategies with air and both direct and indirect liquid cooling for battery thermal management.

  5. perform coupled thermal electrical electrochemical and mechanical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Solar Thermal Test Facility Nuclear ... Climate & Earth Systems Climate Measurement & Modeling ... Tribal Energy Program Intellectual Property Current EC ...

  6. Battery Thermal Modeling and Testing (Presentation)

    SciTech Connect (OSTI)

    Smith, K.

    2011-05-01

    This presentation summarizes NREL battery thermal modeling and testing work for the DOE Annual Merit Review, May 9, 2011.

  7. Thermomechanical measurements on thermal microactuators. (Technical Report)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Technical Report: Thermomechanical measurements on thermal microactuators. Citation Details In-Document Search Title: Thermomechanical measurements on thermal microactuators. Due to the coupling of thermal and mechanical behaviors at small scales, a Campaign 6 project was created to investigate thermomechanical phenomena in microsystems. This report documents experimental measurements conducted under the auspices of this project. Since thermal and mechanical measurements

  8. Thermal Stability Of Formohydroxamic Acid

    SciTech Connect (OSTI)

    Fondeur, F. F.; Rudisill, T. S.

    2011-10-21

    The thermal stability of formohydroxamic acid (FHA) was evaluated to address the potential for exothermic decomposition during storage and its use in the uranium extraction process. Accelerating rate calorimetry showed rapid decomposition at a temperature above 65 {degree}?C; although, the rate of pressure rise was greater than two orders of magnitude less than the lower bound for materials which have no explosive properties with respect to transportation. FHA solutions in water and nitric acid did not reach runaway conditions until 150 {degree}?C. Analysis by differential scanning calorimetry showed that FHA melted at 67 {degree}?C and thermally decomposed at 90 {degree}?C with an enthalpy of -1924 J/g. The energics of the FHA thermal decomposition are comparable to those measured for aqueous solutions of hydroxylamine nitrate. Solid FHA should be stored in a location where the temperature does not exceed 20-25 {degree}?C. As a best practice, the solid material should be stored in a climate-controlled environment such as a refrigerator or freezer. FHA solutions in water are not susceptible to degradation by acid hydrolysis and are the preferred way to handle FHA prior to use.

  9. Size control, quantum confinement, and oxidation kinetics of silicon nanocrystals synthesized at a high rate by expanding thermal plasma

    SciTech Connect (OSTI)

    Han, Lihao E-mail: A.H.M.Smets@tudelft.nl; Zeman, Miro; Smets, Arno H. M. E-mail: A.H.M.Smets@tudelft.nl

    2015-05-25

    The growth mechanism of silicon nanocrystals (Si NCs) synthesized at a high rate by means of expanding thermal plasma chemical vapor deposition technique are studied in this letter. A bimodal Gaussian size distribution is revealed from the high-resolution transmission electron microscopy images, and routes to reduce the unwanted large Si NCs are discussed. Photoluminescence and Raman spectroscopies are employed to study the size-dependent quantum confinement effect, from which the average diameters of the small Si NCs are determined. The surface oxidation kinetics of Si NCs are studied using Fourier transform infrared spectroscopy and the importance of post-deposition passivation treatments of hydrogenated crystalline silicon surfaces are demonstrated.

  10. Effects of high-temperature thermal annealing on the electronic properties of In-Ga-Zn oxide thin films

    SciTech Connect (OSTI)

    Li, Qin; Song, Zhong Xiao; Ma, Fei E-mail: liyhemail@gmail.com; Li, Yan Huai E-mail: liyhemail@gmail.com; Xu, Ke Wei

    2015-03-15

    Indium gallium zinc oxide (IGZO) thin films were deposited by radio-frequency magnetron sputtering at room-temperature. Then, thermal annealing was conducted to improve the structural ordering. X-ray diffraction and high-resolution transmission electron microscopy demonstrated that the as-deposited IGZO thin films were amorphous and crystallization occurred at 800 and 950 °C. As a result of crystallization at high temperature, the carrier concentration and the Hall mobility of IGZO thin films were sharply increased, which could be ascribed to the increased oxygen vacancies and improved structural ordering of the thin films.

  11. Electro-deposition of superconductor oxide films

    DOE Patents [OSTI]

    Bhattacharya, Raghu N.

    2001-01-01

    Methods for preparing high quality superconducting oxide precursors which are well suited for further oxidation and annealing to form superconducting oxide films. The method comprises forming a multilayered superconducting precursor on a substrate by providing an electrodeposition bath comprising an electrolyte medium and a substrate electrode, and providing to the bath a plurality of precursor metal salts which are capable of exhibiting superconducting properties upon subsequent treatment. The superconducting precursor is then formed by electrodepositing a first electrodeposited (ED) layer onto the substrate electrode, followed by depositing a layer of silver onto the first electrodeposited (ED) layer, and then electrodepositing a second electrodeposited (ED) layer onto the Ag layer. The multilayered superconducting precursor is suitable for oxidation at a sufficient annealing temperature in air or an oxygen-containing atmosphere to form a crystalline superconducting oxide film.

  12. Method and apparatus for electrospark deposition

    DOE Patents [OSTI]

    Bailey, Jeffrey A.; Johnson, Roger N.; Park, Walter R.; Munley, John T.

    2004-12-28

    A method and apparatus for controlling electrospark deposition (ESD) comprises using electrical variable waveforms from the ESD process as a feedback parameter. The method comprises measuring a plurality of peak amplitudes from a series of electrical energy pulses delivered to an electrode tip. The maximum peak value from among the plurality of peak amplitudes correlates to the contact force between the electrode tip and a workpiece. The method further comprises comparing the maximum peak value to a set point to determine an offset and optimizing the contact force according to the value of the offset. The apparatus comprises an electrode tip connected to an electrical energy wave generator and an electrical signal sensor, which connects to a high-speed data acquisition card. An actuator provides relative motion between the electrode tip and a workpiece by receiving a feedback drive signal from a processor that is operably connected to the actuator and the high-speed data acquisition card.

  13. Vacuum deposition and curing of liquid monomers

    DOE Patents [OSTI]

    Affinito, J.D.

    1995-03-07

    The present invention is the formation of solid polymer layers under vacuum. More specifically, the present invention is the use of ``standard`` polymer layer-making equipment that is generally used in an atmospheric environment in a vacuum, and degassing the monomer material prior to injection into the vacuum. Additional layers of polymer or metal or oxide may be vacuum deposited onto solid polymer layers. Formation of polymer layers under a vacuum improves material and surface characteristics, and subsequent quality of bonding to additional layers. Further advantages include use of less to no photoinitiator for curing, faster curing, fewer impurities in the polymer electrolyte, as well as improvement in material properties including no trapped gas resulting in greater density, and reduced monomer wetting angle that facilitates spreading of the monomer and provides a smoother finished surface.

  14. Vacuum deposition and curing of liquid monomers

    DOE Patents [OSTI]

    Affinito, John D. (Richland, WA)

    1993-01-01

    The present invention is the formation of solid polymer layers under vacuum. More specifically, the present invention is the use of "standard" polymer layer-making equipment that is generally used in an atmospheric environment in a vacuum, and degassing the monomer material prior to injection into the vacuum. Additional layers of polymer or metal may be vacuum deposited onto solid polymer layers. Formation of polymer layers under a vacuum improves material and surface characteristics, and subsequent quality of bonding to additional layers. Further advantages include use of less to no photoinitiator for curing, faster curing, fewer impurities in the polymer electrolyte, as well as improvement in material properties including no trapped gas resulting in greater density, and reduced monomer wetting angle that facilitates spreading of the monomer and provides a smoother finished surface.

  15. Vacuum deposition and curing of liquid monomers

    DOE Patents [OSTI]

    Affinito, John D. (Kennewick, WA)

    1995-01-01

    The present invention is the formation of solid polymer layers under vacuum. More specifically, the present invention is the use of "standard" polymer layer-making equipment that is generally used in an atmospheric environment in a vacuum, and degassing the monomer material prior to injection into the vacuum. Additional layers of polymer or metal or oxide may be vacuum deposited onto solid polymer layers. Formation of polymer layers under a vacuum improves material and surface characteristics, and subsequent quality of bonding to additional layers. Further advantages include use of less to no photoinitiator for curing, faster curing, fewer impurities in the polymer electrolyte, as well as improvement in material properties including no trapped gas resulting in greater density, and reduced monomer wetting angle that facilitates spreading of the monomer and provides a smoother finished surface.

  16. Vacuum deposition and curing of liquid monomers

    DOE Patents [OSTI]

    Affinito, J.D.

    1993-11-09

    The present invention is the formation of solid polymer layers under vacuum. More specifically, the present invention is the use of standard polymer layer-making equipment that is generally used in an atmospheric environment in a vacuum, and degassing the monomer material prior to injection into the vacuum. Additional layers of polymer or metal may be vacuum deposited onto solid polymer layers. Formation of polymer layers under a vacuum improves material and surface characteristics, and subsequent quality of bonding to additional layers. Further advantages include use of less to no photoinitiator for curing, faster curing, fewer impurities in the polymer electrolyte, as well as improvement in material properties including no trapped gas resulting in greater density, and reduced monomer wetting angle that facilitates spreading of the monomer and provides a smoother finished surface.

  17. Thermally stable, plastic-bonded explosives

    DOE Patents [OSTI]

    Benziger, Theodore M.

    1979-01-01

    By use of an appropriate thermoplastic rubber as the binder, the thermal stability and thermal stress characteristics of plastic-bonded explosives may be greatly improved. In particular, an HMX-based explosive composition using an oil-extended styrene-ethylenebutylene-styrene block copolymer as the binder exhibits high explosive energy and thermal stability and good handling safety and physical properties.

  18. Electric Motor Thermal Management | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ape030_bennion_2011_o.pdf More Documents & Publications Motor Thermal Control Electric Motor Thermal Management Electric Motor Thermal Management

  19. Linearly Polarized Thermal Emitter for More Efficient Thermophotovolta...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Solar Thermal Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Linearly Polarized Thermal Emitter for More Efficient Thermophotovoltaic Devices ...

  20. Thermal Stress and Reliability for Advanced Power Electronics...

    Broader source: Energy.gov (indexed) [DOE]

    Thermal Stress and Reliability for Advanced Power Electronics and Electric Machines Power Electronic Thermal System Performance and Integration Thermal Performance and Reliability ...

  1. Biomass Thermal Energy Council (BTEC) | Open Energy Information

    Open Energy Info (EERE)

    Thermal Energy Council (BTEC) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Biomass Thermal Energy Council (BTEC) AgencyCompany Organization: Biomass Thermal Energy...

  2. MEMS based pyroelectric thermal energy harvester (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    MEMS based pyroelectric thermal energy harvester Title: MEMS based pyroelectric thermal energy harvester A pyroelectric thermal energy harvesting apparatus for generating an ...

  3. MEMS based pyroelectric thermal energy harvester (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Data Explorer Search Results MEMS based pyroelectric thermal energy harvester Title: MEMS based pyroelectric thermal energy harvester A pyroelectric thermal energy harvesting ...

  4. Linearly Polarized Thermal Emitter for More Efficient Thermophotovolta...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Thermal Solar Thermal Advanced Materials Advanced Materials Find More Like This Return to Search Linearly Polarized Thermal Emitter for More Efficient Thermophotovoltaic ...

  5. Sandia Energy - Thermal Pulses for Boeing Test Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Pulses for Boeing Test Article Home Renewable Energy Energy Partnership News EC Concentrating Solar Power Solar National Solar Thermal Test Facility Thermal Pulses for...

  6. Prediction of Thermal Conductivity for Irradiated SiC/SiC Composites by Informing Continuum Models with Molecular Dynamics Data

    SciTech Connect (OSTI)

    Nguyen, Ba Nghiep; Gao, Fei; Henager, Charles H.; Kurtz, Richard J.

    2014-05-01

    This article proposes a new method to estimate the thermal conductivity of SiC/SiC composites subjected to neutron irradiation. The modeling method bridges different scales from the atomic scale to the scale of a 2D SiC/SiC composite. First, it studies the irradiation-induced point defects in perfect crystalline SiC using molecular dynamics (MD) simulations to compute the defect thermal resistance as a function of vacancy concentration and irradiation dose. The concept of defect thermal resistance is explored explicitly in the MD data using vacancy concentrations and thermal conductivity decrements due to phonon scattering. Point defect-induced swelling for chemical vapor deposited (CVD) SiC as a function of irradiation dose is approximated by scaling the corresponding MD results for perfect crystal ?-SiC to experimental data for CVD-SiC at various temperatures. The computed thermal defect resistance, thermal conductivity as a function of grain size, and definition of defect thermal resistance are used to compute the thermal conductivities of CVD-SiC, isothermal chemical vapor infiltrated (ICVI) SiC and nearly-stoichiometric SiC fibers. The computed fiber and ICVI-SiC matrix thermal conductivities are then used as input for an Eshelby-Mori-Tanaka approach to compute the thermal conductivities of 2D SiC/SiC composites subjected to neutron irradiation within the same irradiation doses. Predicted thermal conductivities for an irradiated Tyranno-SA/ICVI-SiC composite are found to be comparable to available experimental data for a similar composite ICVI-processed with these fibers.

  7. Deposition method for producing silicon carbide high-temperature semiconductors

    DOE Patents [OSTI]

    Hsu, George C.; Rohatgi, Naresh K.

    1987-01-01

    An improved deposition method for producing silicon carbide high-temperature semiconductor material comprising placing a semiconductor substrate composed of silicon carbide in a fluidized bed silicon carbide deposition reactor, fluidizing the bed particles by hydrogen gas in a mildly bubbling mode through a gas distributor and heating the substrate at temperatures around 1200.degree.-1500.degree. C. thereby depositing a layer of silicon carbide on the semiconductor substrate.

  8. Inhomogeneity smoothing using density valley formed by ion beam deposition

    Office of Scientific and Technical Information (OSTI)

    in ICF fuel pellet (Journal Article) | SciTech Connect Inhomogeneity smoothing using density valley formed by ion beam deposition in ICF fuel pellet Citation Details In-Document Search Title: Inhomogeneity smoothing using density valley formed by ion beam deposition in ICF fuel pellet We study the beam non-uniformity smoothing effect of the radiation transport in the density valley formed by an ion-beam deposition in an ion-beam inertial confinement fusion pellets by numerical simulation.

  9. Atmospheric Pressure Deposition for Electrochromic Windows | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Atmospheric Pressure Deposition for Electrochromic Windows Atmospheric Pressure Deposition for Electrochromic Windows Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech22_tenent_040413.pdf More Documents & Publications NREL senior scientist, Robert Tenent, Ph.D., with equipment for low cost processing (deposition) of window coatings materials. Dynamic Windows Low-Cost Solutions for Dynamic Window Material CX-003799:

  10. Atomic layer deposition precursor step repetition and surface plasma pretreatment influence on semiconductor–insulator–semiconductor heterojunction solar cell

    SciTech Connect (OSTI)

    Talkenberg, Florian Illhardt, Stefan; Schmidl, Gabriele; Schleusener, Alexander; Sivakov, Vladimir; Radnóczi, György Zoltán; Pécz, Béla; Dikhanbayev, Kadyrjan; Mussabek, Gauhar; Gudovskikh, Alexander

    2015-07-15

    Semiconductor–insulator–semiconductor heterojunction solar cells were prepared using atomic layer deposition (ALD) technique. The silicon surface was treated with oxygen and hydrogen plasma in different orders before dielectric layer deposition. A plasma-enhanced ALD process was applied to deposit dielectric Al{sub 2}O{sub 3} on the plasma pretreated n-type Si(100) substrate. Aluminum doped zinc oxide (Al:ZnO or AZO) was deposited by thermal ALD and serves as transparent conductive oxide. Based on transmission electron microscopy studies the presence of thin silicon oxide (SiO{sub x}) layer was detected at the Si/Al{sub 2}O{sub 3} interface. The SiO{sub x} formation depends on the initial growth behavior of Al{sub 2}O{sub 3} and has significant influence on solar cell parameters. The authors demonstrate that a hydrogen plasma pretreatment and a precursor dose step repetition of a single precursor improve the initial growth behavior of Al{sub 2}O{sub 3} and avoid the SiO{sub x} generation. Furthermore, it improves the solar cell performance, which indicates a change of the Si/Al{sub 2}O{sub 3} interface states.

  11. EGR Cooler Fouling - Visualization of Deposition and Removal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EGR Cooler Fouling - Visualization of Deposition and Removal Mechanis Presents experimental data on exhaust gas recirculation(EGR) cooler fouling using new test apparatus that...

  12. Liquid-Phase Deposition of Silicon Nanocrystal Films - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid-Phase Deposition of Silicon Nanocrystal Films University of Minnesota DOE Grant Recipients Contact GRANT About This Technology Technology Marketing Summary Silicon ...

  13. OLEDWORKS DEVELOPS INNOVATIVE HIGH-PERFORMANCE DEPOSITION TECHNOLOGY...

    Energy Savers [EERE]

    high-performance deposition technology that addresses two major aspects of this manufacturing cost: the expense of organic materials per area of useable product, and the...

  14. Quick, Efficient Film Deposition for Nanomaterials - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quick, Efficient Film Deposition for Nanomaterials Oak Ridge National Laboratory Contact ORNL About This Technology Publications: PDF Document Publication Quick, Efficient Film ...

  15. System and Method for Sealing a Vapor Deposition Source - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    costs and minimizes system downtime for cleaning Applications and Industries Thin film solar Deposition of any thin film Patents and Patent Applications ID Number Title and...

  16. Method of depositing a high-emissivity layer

    DOE Patents [OSTI]

    Wickersham, Charles E.; Foster, Ellis L.

    1983-01-01

    A method of depositing a high-emissivity layer on a substrate comprising RF sputter deposition of a carbide-containing target in an atmosphere of a hydrocarbon gas and a noble gas. As the carbide is deposited on the substrate the hydrocarbon gas decomposes to hydrogen and carbon. The carbon deposits on the target and substrate causing a carbide/carbon composition gradient to form on the substrate. At a sufficiently high partial pressure of hydrocarbon gas, a film of high-emissivity pure carbon will eventually form over the substrate.

  17. Rhyolites and Associated Deposits of the Valles-Toledo Caldera...

    Open Energy Info (EERE)

    Complex Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Rhyolites and Associated Deposits of the Valles-Toledo Caldera Complex Abstract...

  18. Electroless Atomic Layer Deposition: A Scalable Approach to Surface...

    Office of Scientific and Technical Information (OSTI)

    Title: Electroless Atomic Layer Deposition: A Scalable Approach to Surface Modified Metal Powders. Abstract not provided. Authors: Cappillino, Patrick ; Robinson, David ; El Gabaly ...

  19. Plasma sprayed and electrospark deposited zirconium metal diffusion barrier coatings

    SciTech Connect (OSTI)

    Hollis, Kendall J; Pena, Maria I

    2010-01-01

    Zirconium metal coatings applied by plasma spraying and electrospark deposition (ESD) have been investigated for use as diffusion barrier coatings on low enrichment uranium fuel for research nuclear reactors. The coatings have been applied to both stainless steel as a surrogate and to simulated nuclear fuel uranium-molybdenum alloy substrates. Deposition parameter development accompanied by coating characterization has been performed. The structure of the plasma sprayed coating was shown to vary with transferred arc current during deposition. The structure of ESD coatings was shown to vary with the capacitance of the deposition equipment.

  20. Deposition of dopant impurities and pulsed energy drive-in

    DOE Patents [OSTI]

    Wickboldt, Paul; Carey, Paul G.; Smith, Patrick M.; Ellingboe, Albert R.

    2008-01-01

    A semiconductor doping process which enhances the dopant incorporation achievable using the Gas Immersion Laser Doping (GILD) technique. The enhanced doping is achieved by first depositing a thin layer of dopant atoms on a semiconductor surface followed by exposure to one or more pulses from either a laser or an ion-beam which melt a portion of the semiconductor to a desired depth, thus causing the dopant atoms to be incorporated into the molten region. After the molten region recrystallizes the dopant atoms are electrically active. The dopant atoms are deposited by plasma enhanced chemical vapor deposition (PECVD) or other known deposition techniques.

  1. A radon progeny deposition model (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    by the long half life (22 y) of sup 210Pb on sensitive locations of a detector. ... RADIATION; CLEAN ROOMS; DEPOSITION; HALF-LIFE; PROGENY; RADIATION DETECTORS; RADON; ...

  2. Spatial correlation of energy deposition events in irradiated...

    Office of Scientific and Technical Information (OSTI)

    events in irradiated liquid water Citation Details In-Document Search Title: Spatial correlation of energy deposition events in irradiated liquid water You are accessing a ...

  3. Spatial correlation of energy deposition events in irradiated...

    Office of Scientific and Technical Information (OSTI)

    events in irradiated liquid water Citation Details In-Document Search Title: Spatial correlation of energy deposition events in irradiated liquid water Monte Carlo electron ...

  4. Deposition of dopant impurities and pulsed energy drive-in

    DOE Patents [OSTI]

    Wickboldt, P.; Carey, P.G.; Smith, P.M.; Ellingboe, A.R.

    1999-06-29

    A semiconductor doping process which enhances the dopant incorporation achievable using the Gas Immersion Laser Doping (GILD) technique is disclosed. The enhanced doping is achieved by first depositing a thin layer of dopant atoms on a semiconductor surface followed by exposure to one or more pulses from either a laser or an ion-beam which melt a portion of the semiconductor to a desired depth, thus causing the dopant atoms to be incorporated into the molten region. After the molten region recrystallizes the dopant atoms are electrically active. The dopant atoms are deposited by plasma enhanced chemical vapor deposition (PECVD) or other known deposition techniques. 2 figs.

  5. Deposition of dopant impurities and pulsed energy drive-in

    DOE Patents [OSTI]

    Wickboldt, Paul; Carey, Paul G.; Smith, Patrick M.; Ellingboe, Albert R.

    1999-01-01

    A semiconductor doping process which enhances the dopant incorporation achievable using the Gas Immersion Laser Doping (GILD) technique. The enhanced doping is achieved by first depositing a thin layer of dopant atoms on a semiconductor surface followed by exposure to one or more pulses from either a laser or an ion-beam which melt a portion of the semiconductor to a desired depth, thus causing the dopant atoms to be incorporated into the molten region. After the molten region recrystallizes the dopant atoms are electrically active. The dopant atoms are deposited by plasma enhanced chemical vapor deposition (PECVD) or other known deposition techniques.

  6. Remote Detection of Quaternary Borate Deposits with ASTER Satellite...

    Open Energy Info (EERE)

    Deposits with ASTER Satellite Imagery as a Geothermal Exploration Tool Abstract In the Great Basin of the western United States, geothermal fluids are sometimes associated with...

  7. Atomic Layer Deposition and in Situ Characterization of Ultraclean...

    Office of Scientific and Technical Information (OSTI)

    Hydroxide Citation Details In-Document Search Title: Atomic Layer Deposition and in Situ Characterization of Ultraclean Lithium Oxide and Lithium Hydroxide Authors: Kozen,...

  8. Evaluation of Wax Deposition and Its Control During Production...

    Office of Scientific and Technical Information (OSTI)

    Title: Evaluation of Wax Deposition and Its Control During Production of Alaska North Slope Oils Due to increasing oil demand, oil companies are moving into arctic environments and ...

  9. USE OF ATOMIC LAYER DEPOSITION OF FUNCTIONALIZATION OF NANOPOROUS BIOMATERIALS

    SciTech Connect (OSTI)

    Brigmon, R.; Narayan, R.; Adiga, S.; Pellin, M.; Curtiss, L.; Stafslien, S.; Chisholm, B.; Monteiro-Riviere, N.; Elam, J.

    2010-02-08

    Due to its chemical stability, uniform pore size, and high pore density, nanoporous alumina is being investigated for use in biosensing, drug delivery, hemodialysis, and other medical applications. In recent work, we have examined the use of atomic layer deposition for coating the surfaces of nanoporous alumina membranes. Zinc oxide coatings were deposited on nanoporous alumina membranes using atomic layer deposition. The zinc oxide-coated nanoporous alumina membranes demonstrated antimicrobial activity against Escherichia coli and Staphylococcus aureus bacteria. These results suggest that atomic layer deposition is an attractive technique for modifying the surfaces of nanoporous alumina membranes and other nanostructured biomaterials.

  10. Liquid Metal Heat Exchanger for Geologic Deposits - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid Metal Heat Exchanger for Geologic Deposits Oak Ridge National Laboratory Contact ... The apparatus provides more efficient heat transfer than existing technologies for ...

  11. Hydrogen Absorption Induced Metal Deposition on Palladium and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Absorption Induced Metal Deposition on Palladium and Palladium-Alloy Particles Brookhaven National Laboratory Contact BNL About This Technology

    High resolution...

  12. A radon progeny deposition model (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    However, existing models have not explored the impact of some environmental factors important for low background experiments. A test stand has been constructed to deposit radon ...

  13. Active Geothermal Systems And Associated Gold Deposits In The...

    Open Energy Info (EERE)

    Geothermal Systems And Associated Gold Deposits In The Great Basin Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Active Geothermal Systems...

  14. Thermal wake/vessel detection technique

    DOE Patents [OSTI]

    Roskovensky, John K.; Nandy, Prabal; Post, Brian N

    2012-01-10

    A computer-automated method for detecting a vessel in water based on an image of a portion of Earth includes generating a thermal anomaly mask. The thermal anomaly mask flags each pixel of the image initially deemed to be a wake pixel based on a comparison of a thermal value of each pixel against other thermal values of other pixels localized about each pixel. Contiguous pixels flagged by the thermal anomaly mask are grouped into pixel clusters. A shape of each of the pixel clusters is analyzed to determine whether each of the pixel clusters represents a possible vessel detection event. The possible vessel detection events are represented visually within the image.

  15. Mechanical and Electrical Performance of Thermally Stable Au-ZnO films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schoeppner, Rachel L.; Goeke, Ronald S.; Moody, Neville R.; Bahr, David F.

    2015-03-28

    The mechanical properties, thermal stability, and electrical performance of Au–ZnO composite thin films are determined in this work. The co-deposition of ZnO with Au via physical vapor deposition leads to grain refinement over that of pure Au; the addition of 0.1 vol.% ZnO reduces the as-grown grain size by over 30%. The hardness of the as-grown films doubles with 2% ZnO, from 1.8 to 3.6 GPa as measured by nanoindentation. Films with ZnO additions greater than 0.5% show no significant grain growth after annealing at 350 °C, while pure gold and smaller additions do exhibit grain growth and subsequent mechanicalmore » softening. Films with 1% and 2% ZnO show a decrease of approximately 50% in electrical resistivity and no change in hardness after annealing. A model accounting for both changes in the interface structure between dispersed ZnO particles and the Au matrix captures the changes in mechanical and electrical resistivity. Furthermore, the addition of 1–2% ZnO co-deposited with Au provides a method to create mechanically hard and thermally stable films with a resistivity less than 80 nΩ-m. Our results complement previous studies of other alloying systems, suggesting oxide dispersion strengthened (ODS) gold shows a desirable hardness–resistivity relationship that is relatively independent of the particular ODS chemistry.« less

  16. Mechanical and Electrical Performance of Thermally Stable Au-ZnO films

    SciTech Connect (OSTI)

    Schoeppner, Rachel L.; Goeke, Ronald S.; Moody, Neville R.; Bahr, David F.

    2015-03-28

    The mechanical properties, thermal stability, and electrical performance of AuZnO composite thin films are determined in this work. The co-deposition of ZnO with Au via physical vapor deposition leads to grain refinement over that of pure Au; the addition of 0.1 vol.% ZnO reduces the as-grown grain size by over 30%. The hardness of the as-grown films doubles with 2% ZnO, from 1.8 to 3.6 GPa as measured by nanoindentation. Films with ZnO additions greater than 0.5% show no significant grain growth after annealing at 350 C, while pure gold and smaller additions do exhibit grain growth and subsequent mechanical softening. Films with 1% and 2% ZnO show a decrease of approximately 50% in electrical resistivity and no change in hardness after annealing. A model accounting for both changes in the interface structure between dispersed ZnO particles and the Au matrix captures the changes in mechanical and electrical resistivity. Furthermore, the addition of 12% ZnO co-deposited with Au provides a method to create mechanically hard and thermally stable films with a resistivity less than 80 n?-m. Our results complement previous studies of other alloying systems, suggesting oxide dispersion strengthened (ODS) gold shows a desirable hardnessresistivity relationship that is relatively independent of the particular ODS chemistry.

  17. Thermal Shock-resistant Cement

    SciTech Connect (OSTI)

    Sugama T.; Pyatina, T.; Gill, S.

    2012-02-01

    We studied the effectiveness of sodium silicate-activated Class F fly ash in improving the thermal shock resistance and in extending the onset of hydration of Secar #80 refractory cement. When the dry mix cement, consisting of Secar #80, Class F fly ash, and sodium silicate, came in contact with water, NaOH derived from the dissolution of sodium silicate preferentially reacted with Class F fly ash, rather than the #80, to dissociate silicate anions from Class F fly ash. Then, these dissociated silicate ions delayed significantly the hydration of #80 possessing a rapid setting behavior. We undertook a multiple heating -water cooling quenching-cycle test to evaluate the cement’s resistance to thermal shock. In one cycle, we heated the 200 and #61616;C-autoclaved cement at 500 and #61616;C for 24 hours, and then the heated cement was rapidly immersed in water at 25 and #61616;C. This cycle was repeated five times. The phase composition of the autoclaved #80/Class F fly ash blend cements comprised four crystalline hydration products, boehmite, katoite, hydrogrossular, and hydroxysodalite, responsible for strengthening cement. After a test of 5-cycle heat-water quenching, we observed three crystalline phase-transformations in this autoclaved cement: boehmite and #61614; and #61543;-Al2O3, katoite and #61614; calcite, and hydroxysodalite and #61614; carbonated sodalite. Among those, the hydroxysodalite and #61614; carbonated sodalite transformation not only played a pivotal role in densifying the cementitious structure and in sustaining the original compressive strength developed after autoclaving, but also offered an improved resistance of the #80 cement to thermal shock. In contrast, autoclaved Class G well cement with and without Class F fly ash and quartz flour failed this cycle test, generating multiple cracks in the cement. The major reason for such impairment was the hydration of lime derived from the dehydroxylation of portlandite formed in the autoclaved cement, causing its volume to expand.

  18. Neutrino Physics with Thermal Detectors

    SciTech Connect (OSTI)

    Nucciotti, A. [Dipartimento di Fisica, Universita di Milano Bicocca and INFN Sezione di Milano-Bicocca Piazza della Scienza, 3, 20126 Milano (Italy)

    2009-11-09

    The investigation of fundamental neutrino properties like its mass and its nature calls for the design of a new generation of experiments. High sensitivity, high energy resolution, and versatility together with the possibility of a simple multiplexing scheme are the key features of future detectors for these experiments. Thermal detectors can combine all these features. This paper reviews the status and the perspectives for what concerns the application of this type of detectors to neutrino physics, focusing on direct neutrino mass measurements and neutrinoless double beta decay searches.

  19. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    2 Solar thermal collector shipments by type, quantity, revenue, and average price, 2008 and 2009 Quantity (thousand square feet) Revenue (thousand dollars) Average Price (dollars per square foot) Quantity (thousand square feet) Revenue (thousand dollars) Average Price (dollars per square foot) Low-Temperature Liquid and Air 14,015 26,518 1.89 10,511 20,411 1.94 Medium-Temperature 2,560 50,109 19.57 2,307 51,483 22.32 Air 28 1,256 45.46 22 883 40.31 Liquid ICS/Thermosiphon 321 6,631 20.66 147

  20. Thermal well-test method

    DOE Patents [OSTI]

    Tsang, C.F.; Doughty, C.A.

    1984-02-24

    A well-test method involving injection of hot (or cold) water into a groundwater aquifer, or injecting cold water into a geothermal reservoir is disclosed. By making temperature measurements at various depths in one or more observation wells, certain properties of the aquifer are determined. These properties, not obtainable from conventional well test procedures, include the permeability anisotropy, and layering in the aquifer, and in-situ thermal properties. The temperature measurements at various depths are obtained from thermistors mounted in the observation wells.

  1. THERMAL CONDUCTIVITY ANALYSIS OF GASES

    DOE Patents [OSTI]

    Clark, W.J.

    1949-06-01

    This patent describes apparatus for the quantitative analysis of a gaseous mixture at subatmospheric pressure by measurement of its thermal conductivity. A heated wire forms one leg of a bridge circuit, while the gas under test is passed about the wire at a constant rate. The bridge unbalance will be a measure of the change in composition of the gas, if compensation is made for the effect due to gas pressure change. The apparatus provides a voltage varying with fluctuations of pressure in series with the indicating device placed across the bridge, to counterbalance the voltage change caused by fluctuations in the pressure of the gaseous mixture.

  2. Thermal Analysis of Closed Systems

    Energy Science and Technology Software Center (OSTI)

    1987-10-01

    TAP-LOOP is a finite-difference program designed for steady-state and transient thermal analysis of recirculating fluid loops and associated heat transfer equipment; however, it is not limited to loop analysis. TAP-LOOP was developed to perform scoping and conceptual design analyses for closed test loops in the Fast Flux Test Facility (FFTF), but it can handle a variety of problems which can be described in terms of potentials, sources, sinks, and storage including, in addition to heatmore » transfer problems, studies of potential fluid flow, electrical networks, and stress analysis.« less

  3. Laser-assisted nanomaterial deposition, nanomanufacturing, in situ monitoring and associated apparatus

    DOE Patents [OSTI]

    Mao, Samuel S; Grigoropoulos, Costas P; Hwang, David J; Minor, Andrew M

    2013-11-12

    Laser-assisted apparatus and methods for performing nanoscale material processing, including nanodeposition of materials, can be controlled very precisely to yield both simple and complex structures with sizes less than 100 nm. Optical or thermal energy in the near field of a photon (laser) pulse is used to fabricate submicron and nanometer structures on a substrate. A wide variety of laser material processing techniques can be adapted for use including, subtractive (e.g., ablation, machining or chemical etching), additive (e.g., chemical vapor deposition, selective self-assembly), and modification (e.g., phase transformation, doping) processes. Additionally, the apparatus can be integrated into imaging instruments, such as SEM and TEM, to allow for real-time imaging of the material processing.

  4. Improved oxidation resistance of organic/inorganic composite atomic layer deposition coated cellulose nanocrystal aerogels

    SciTech Connect (OSTI)

    Smith, Sean W.; Matthews, David J.; Conley, John F., E-mail: jconley@eecs.oregonstate.edu [School of Electrical Engineering and Computer Science, 1148 Kelley Engineering Center, Oregon State University, Corvallis, Oregon 97331 (United States); Buesch, Christian; Simonsen, John [Department of Wood Science and Engineering, Oregon State University, 119 Richardson Hall, Corvallis, Oregon 97331 (United States)

    2014-07-01

    Cellulose nanocrystal (CNC) aerogels are coated with thin conformal layers of Al{sub 2}O{sub 3} using atomic layer deposition to form hybrid organic/inorganic nanocomposites. Electron probe microanalysis and scanning electron microscopy analysis indicated the Al{sub 2}O{sub 3} penetrated more than 1500??m into the aerogel for extended precursor pulse and exposure/purge times. The measured profile of coated fiber radius versus depth from the aerogel surface agrees well with simulations of precursor penetration depth in modeled aerogel structures. Thermogravimetric analysis shows that Al{sub 2}O{sub 3} coated CNC aerogel nanocomposites do not show significant thermal degradation below 295?C as compared with 175?C for uncoated CNC aerogels, an improvement of over 100?C.

  5. Low-temperature plasma-deposited silicon epitaxial films: Growth and properties

    SciTech Connect (OSTI)

    Demaurex, Bénédicte; Bartlome, Richard; Seif, Johannes P.; Geissbühler, Jonas; Alexander, Duncan T. L.; Jeangros, Quentin; Ballif, Christophe; De Wolf, Stefaan

    2014-08-05

    Low-temperature (≤ 180 °C) epitaxial growth yields precise thickness, doping, and thermal-budget control, which enables advanced-design semiconductor devices. In this paper, we use plasma-ehanced chemical vapor deposition to grow homo-epitaxial layers and study the different growth modes on crystalline silicon substrates. In particular, we determine the conditions leading to epitaxial growth in light of a model that depends only on the silane concentration in the plasma and the mean free path length of surface adatoms. For such growth, we show that the presence of a persistent defective interface layer between the crystalline silicon substrate and the epitaxial layer stems not only from the growth conditions but also from unintentional contamination of the reactor. As a result of our findings, we determine the plasma conditions to grow high-quality bulk epitaxial films and propose a two-step growth process to obtain device-grade material.

  6. Thermal Interface Materials for Power Electronics Applications: Preprint

    SciTech Connect (OSTI)

    Narumanchi, S.; Mihalic, M.; Kelly, K.; Eesley, G.

    2008-07-01

    The thermal resistance of the thermal interface material layer greatly affects the maximum temperature of the power electronics.

  7. Develop and Evaluate Materials and Additives that Enhance Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Develop & Evaluate Materials & Additives that Enhance Thermal & Overcharge Abuse Develop & Evaluate Materials & Additives that Enhance Thermal & Overcharge Abuse High Voltage ...

  8. Develop and Evaluate Materials and Additives that Enhance Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Develop & evaluate materials & additives that enhance thermal & overcharge abuse Develop & Evaluate Materials & Additives that Enhance Thermal & ...

  9. Next-Generation LED Package Architectures Enabled by Thermally...

    Energy Savers [EERE]

    LED Package Architectures Enabled by Thermally Conductive Transparent Encapsulants Next-Generation LED Package Architectures Enabled by Thermally Conductive Transparent ...

  10. Method and closing pores in a thermally sprayed doped lanthanum chromite interconnection layer

    DOE Patents [OSTI]

    Singh, Prabhakar; Ruka, Roswell J.

    1995-01-01

    A dense, substantially gas-tight electrically conductive interconnection layer is formed on an air electrode structure of an electrochemical cell by (A) providing an air electrode surface; (B) forming on a selected portion of the electrode surface, a layer of doped LaCrO.sub.3 particles doped with an element or elements selected from Ca, Sr, Ba, Mg, Co, Ni, Al and mixtures thereof by thermal spraying doped LaCrO.sub.3 particles, either by plasma arc spraying or flame spraying; (C) depositing a mixture of CaO and Cr.sub.2 O.sub.3 on the surface of the thermally sprayed layer; and (D) heating the doped LaCrO.sub.3 layer coated with CaO and Cr.sub.2 O.sub.3 surface deposit at from about 1000.degree. C. to 1200.degree. C. to substantially close the pores, at least at a surface, of the thermally sprayed doped LaCrO.sub.3 layer. The result is a dense, substantially gas-tight, highly doped, electrically conductive interconnection material bonded to the electrode surface. A solid electrolyte layer can be applied to the nonselected portion of the air electrode. A fuel electrode can be applied to the solid electrolyte, to form an electrochemical cell, for example for generation of electrical power.

  11. Method and closing pores in a thermally sprayed doped lanthanum chromite interconnection layer

    DOE Patents [OSTI]

    Singh, P.; Ruka, R.J.

    1995-02-14

    A dense, substantially gas-tight electrically conductive interconnection layer is formed on an air electrode structure of an electrochemical cell by (A) providing an air electrode surface; (B) forming on a selected portion of the electrode surface, a layer of doped LaCrO{sub 3} particles doped with an element or elements selected from Ca, Sr, Ba, Mg, Co, Ni, Al and mixtures thereof by thermal spraying doped LaCrO{sub 3} particles, either by plasma arc spraying or flame spraying; (C) depositing a mixture of CaO and Cr{sub 2}O{sub 3} on the surface of the thermally sprayed layer; and (D) heating the doped LaCrO{sub 3} layer coated with CaO and Cr{sub 2}O{sub 3} surface deposit at from about 1,000 C to 1,200 C to substantially close the pores, at least at a surface, of the thermally sprayed doped LaCrO{sub 3} layer. The result is a dense, substantially gas-tight, highly doped, electrically conductive interconnection material bonded to the electrode surface. A solid electrolyte layer can be applied to the nonselected portion of the air electrode. A fuel electrode can be applied to the solid electrolyte, to form an electrochemical cell, for example for generation of electrical power. 5 figs.

  12. Sputter deposition for multi-component thin films

    DOE Patents [OSTI]

    Krauss, A.R.; Auciello, O.

    1990-05-08

    Ion beam sputter-induced deposition using a single ion beam and a multicomponent target is capable of reproducibly producing thin films of arbitrary composition, including those which are close to stoichiometry. Using a quartz crystal deposition monitor and a computer controlled, well-focused ion beam, this sputter-deposition approach is capable of producing metal oxide superconductors and semiconductors of the superlattice type such as GaAs-AlGaAs as well as layered metal/oxide/semiconductor/superconductor structures. By programming the dwell time for each target according to the known sputtering yield and desired layer thickness for each material, it is possible to deposit composite films from a well-controlled sub-monolayer up to thicknesses determined only by the available deposition time. In one embodiment, an ion beam is sequentially directed via a set of X-Y electrostatic deflection plates onto three or more different element or compound targets which are constituents of the desired film. In another embodiment, the ion beam is directed through an aperture in the deposition plate and is displaced under computer control to provide a high degree of control over the deposited layer. In yet another embodiment, a single fixed ion beam is directed onto a plurality of sputter targets in a sequential manner where the targets are each moved in alignment with the beam under computer control in forming a multilayer thin film. This controlled sputter-deposition approach may also be used with laser and electron beams. 10 figs.

  13. Sputter deposition for multi-component thin films

    DOE Patents [OSTI]

    Krauss, Alan R.; Auciello, Orlando

    1990-01-01

    Ion beam sputter-induced deposition using a single ion beam and a multicomponent target is capable of reproducibly producing thin films of arbitrary composition, including those which are close to stoichiometry. Using a quartz crystal deposition monitor and a computer controlled, well-focused ion beam, this sputter-deposition approach is capable of producing metal oxide superconductors and semiconductors of the superlattice type such as GaAs-AlGaAs as well as layered metal/oxide/semiconductor/superconductor structures. By programming the dwell time for each target according to the known sputtering yield and desired layer thickness for each material, it is possible to deposit composite films from a well-controlled sub-monolayer up to thicknesses determined only by the available deposition time. In one embodiment, an ion beam is sequentially directed via a set of X-Y electrostatic deflection plates onto three or more different element or compound targets which are constituents of the desired film. In another embodiment, the ion beam is directed through an aperture in the deposition plate and is displaced under computer control to provide a high degree of control over the deposited layer. In yet another embodiment, a single fixed ion beam is directed onto a plurality of sputter targets in a sequential manner where the targets are each moved in alignment with the beam under computer control in forming a multilayer thin film. This controlled sputter-deposition approach may also be used with laser and electron beams.

  14. Electroplating method for producing ultralow-mass fissionable deposits

    DOE Patents [OSTI]

    Ruddy, Francis H.

    1989-01-01

    A method for producing ultralow-mass fissionable deposits for nuclear reactor dosimetry is described, including the steps of holding a radioactive parent until the radioactive parent reaches secular equilibrium with a daughter isotope, chemically separating the daughter from the parent, electroplating the daughter on a suitable substrate, and holding the electroplated daughter until the daughter decays to the fissionable deposit.

  15. Method of depositing epitaxial layers on a substrate

    DOE Patents [OSTI]

    Goyal, Amit

    2003-12-30

    An epitaxial article and method for forming the same includes a substrate having a textured surface, and an electrochemically deposited substantially single orientation epitaxial layer disposed on and in contact with the textured surface. The epitaxial article can include an electromagnetically active layer and an epitaxial buffer layer. The electromagnetically active layer and epitaxial buffer layer can also be deposited electrochemically.

  16. High thermal expansion, sealing glass

    DOE Patents [OSTI]

    Brow, Richard K.; Kovacic, Larry

    1993-01-01

    A glass composition for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na.sub.2 O, between about 10 and about 25 mole percent K.sub.2 O, between about 5 and about 15 mole percent Al.sub.2 O.sub.3, between about 35 and about 50 mole percent P.sub.2 O.sub.5 and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe.sub.2 O.sub.3 and between 0 and about 10 mole percent B.sub.2 O.sub.3, has a thermal expansion coefficient in a range of between about 160 and 210.times.10-7/.degree.C. and a dissolution rate in a range of between about 2.times.10.sup.- 7 and 2.times.10.sup.-9 g/cm.sup.2 -min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  17. High thermal expansion, sealing glass

    DOE Patents [OSTI]

    Brow, R.K.; Kovacic, L.

    1993-11-16

    A glass composition is described for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na[sub 2]O, between about 10 and about 25 mole percent K[sub 2]O, between about 5 and about 15 mole percent Al[sub 2]O[sub 3], between about 35 and about 50 mole percent P[sub 2]O[sub 5] and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe[sub 2]O[sub 3] and between 0 and about 10 mole percent B[sub 2]O[sub 3], has a thermal expansion coefficient in a range of between about 160 and 210[times]10[sup [minus]7]/C and a dissolution rate in a range of between about 2[times]10[sup [minus]7] and 2[times]10[sup [minus]9]g/cm[sup 2]-min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  18. Borehole thermal resistance: Laboratory and field studies

    SciTech Connect (OSTI)

    Remund, C.P.

    1999-07-01

    Vertical ground heat exchangers are a common method of linking geothermal heat pump systems to the earth, and they consist of pipe installed into a borehole that is subsequently backfilled with a material that forms the heat transfer link between the pipe and earth. In many states that material must also be a grout to form a barrier against water migration in any direction along the entire borehole length. Until recently, little attention has been given to the thermal properties of commonly used backfill and grouting materials or to the effect of the thermal conductivity of those materials on the thermal performance of the vertical ground heat exchanger. Laboratory studies were performed to determine the effect of grout thermal conductivity, borehole diameter, pipe size, and pipe configuration on the total thermal resistance in the borehole. It was found that borehole thermal resistance decreased with increasing grout thermal resistance decreased with increasing grout thermal conductivity, but increasing grout thermal conductivity above 1.0 Btu/h{center{underscore}dot}ft{center{underscore}dot}{degree}F provided very small additional reduction. The studies resulted in a set of relationships for borehole thermal resistance, depending on the pipe configuration in the borehole, that can be utilized in the calculation of design length of a vertical ground heat exchanger for a prescribed heating and cooling load. A series of independent field tests verified that the assumption of equal spacing between the pipes and the borehole wall conservatively accounted for the thermal conductivity of the backfill or grout material. The effect of increasing grout thermal conductivity from 0.43 to 0.85 Btu/h{center{underscore}dot}ft{center{underscore}dot}{degree}F resulted in overall reductions in thermal resistance between the circulating fluid and the earth by 15.3% to 19.5%.

  19. Method of and apparatus for determining deposition-point temperature

    DOE Patents [OSTI]

    Mansure, Arthur J.; Spates, James J.; Martin, Stephen J.

    1998-01-01

    Acoustic-wave sensor apparatus and method for analyzing a normally liquid petroleum-based composition for monitoring deposition-point temperature. The apparatus includes at least one acoustic-wave device such as SAW, QCM, FPM, TSM or APM type devices in contact with the petroleum-based composition for sensing or detecting the surface temperature at which deposition occurs and/or rate of deposition as a function of temperature by sensing an accompanying change in frequency, phase shift, damping voltage or damping current of an electrical oscillator to a known calibrated condition. The acoustic wave device is actively cooled to monitor the deposition of constituents such as paraffins by determining the point at which solids from the liquid composition begin to form on the acoustic wave device. The acoustic wave device can be heated to melt or boil off the deposits to reset the monitor and the process can be repeated.

  20. How to make deposition of images a reality

    SciTech Connect (OSTI)

    Guss, J. Mitchell; McMahon, Brian

    2014-10-01

    An analysis is performed of the technical and financial challenges to be overcome if deposition of primary experimental data is to become routine. The IUCr Diffraction Data Deposition Working Group is investigating the rationale and policies for routine deposition of diffraction images (and other primary experimental data sets). An information-management framework is described that should inform policy directions, and some of the technical and other issues that need to be addressed in an effort to achieve such a goal are analysed. In the near future, routine data deposition could be encouraged at one of the growing number of institutional repositories that accept data sets or at a generic data-publishing web repository service. To realise all of the potential benefits of depositing diffraction data, specialized archives would be preferable. Funding such an initiative will be challenging.

  1. Method of and apparatus for determining deposition-point temperature

    DOE Patents [OSTI]

    Mansure, A.J.; Spates, J.J.; Martin, S.J.

    1998-10-27

    Acoustic-wave sensor apparatus and method are disclosed for analyzing a normally liquid petroleum-based composition for monitoring deposition-point temperature. The apparatus includes at least one acoustic-wave device such as SAW, QCM, FPM, TSM or APM type devices in contact with the petroleum-based composition for sensing or detecting the surface temperature at which deposition occurs and/or rate of deposition as a function of temperature by sensing an accompanying change in frequency, phase shift, damping voltage or damping current of an electrical oscillator to a known calibrated condition. The acoustic wave device is actively cooled to monitor the deposition of constituents such as paraffins by determining the point at which solids from the liquid composition begin to form on the acoustic wave device. The acoustic wave device can be heated to melt or boil off the deposits to reset the monitor and the process can be repeated. 5 figs.

  2. Ultra low thermal expansion, highly thermal shock resistant ceramic

    DOE Patents [OSTI]

    Limaye, S.Y.

    1996-01-30

    Three families of ceramic compositions having the given formula: {phi}{sub 1+X}Zr{sub 4}P{sub 6{minus}2X}Si{sub 2X}O{sub 24}, {phi}{sub 1+X}Zr{sub 4{minus}2X}Y{sub 2X}P{sub 6}O{sub 24} and {phi}{sub 1+X}Zr{sub 4{minus}X}Y{sub X}P{sub 6{minus}2X}Si{sub X}O{sub 24} wherein {phi} is either strontium or barium and X has a value from about 0.2 to about 0.8 have been disclosed. Ceramics formed from these compositions exhibit very low, generally near neutral, thermal expansion over a wide range of elevated temperatures. 7 figs.

  3. Ultra low thermal expansion, highly thermal shock resistant ceramic

    DOE Patents [OSTI]

    Limaye, Santosh Y.

    1996-01-01

    Three families of ceramic compositions having the given formula: .phi..sub.1+X Zr.sub.4 P.sub.6-2X Si.sub.2X O.sub.24, .phi..sub.1+X Zr.sub.4-2X Y.sub.2X P.sub.6 O.sub.24 and .phi..sub.1+X Zr.sub.4-X Y.sub.X P.sub.6-2X Si.sub.X O.sub.24 wherein .phi. is either Strontium or Barium and X has a value from about 0.2 to about 0.8 have been disclosed. Ceramics formed from these compositions exhibit very low, generally near neutral, thermal expansion over a wide range of elevated temperatures.

  4. COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

    2001-04-01

    The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

  5. Solid oxide fuel cell processing using plasma arc spray deposition techniques. Final report

    SciTech Connect (OSTI)

    Ray, E.R.; Spengler, C.J.; Herman, H.

    1991-07-01

    The Westinghouse Electric Corporation, in conjunction with the Thermal Spray Laboratory of the State University of New York, Stony Brook, investigated the fabrication of a gas-tight interconnect layer on a tubular solid oxide fuel cell with plasma arc spray deposition. The principal objective was to determine the process variables for the plasma spray deposition of an interconnect with adequate electrical conductivity and other desired properties. Plasma arc spray deposition is a process where the coating material in powder form is heated to or above its melting temperature, while being accelerated by a carrier gas stream through a high power electric arc. The molten powder particles are directed at the substrate, and on impact, form a coating consisting of many layers of overlapping, thin, lenticular particles or splats. The variables investigated were gun power, spray distance, powder feed rate, plasma gas flow rates, number of gun passes, powder size distribution, injection angle of powder into the plasma plume, vacuum or atmospheric plasma spraying, and substrate heating. Typically, coatings produced by both systems showed bands of lanthanum rich material and cracking with the coating. Preheating the substrate reduced but did not eliminate internal coating cracking. A uniformly thick, dense, adherent interconnect of the desired chemistry was finally achieved with sufficient gas- tightness to allow fabrication of cells and samples for measurement of physical and electrical properties. A cell was tested successfully at 1000{degree}C for over 1,000 hours demonstrating the mechanical, electrical, and chemical stability of a plasma-arc sprayed interconnect layer.

  6. Solid oxide fuel cell processing using plasma arc spray deposition techniques

    SciTech Connect (OSTI)

    Ray, E.R.; Spengler, C.J.; Herman, H.

    1991-07-01

    The Westinghouse Electric Corporation, in conjunction with the Thermal Spray Laboratory of the State University of New York, Stony Brook, investigated the fabrication of a gas-tight interconnect layer on a tubular solid oxide fuel cell with plasma arc spray deposition. The principal objective was to determine the process variables for the plasma spray deposition of an interconnect with adequate electrical conductivity and other desired properties. Plasma arc spray deposition is a process where the coating material in powder form is heated to or above its melting temperature, while being accelerated by a carrier gas stream through a high power electric arc. The molten powder particles are directed at the substrate, and on impact, form a coating consisting of many layers of overlapping, thin, lenticular particles or splats. The variables investigated were gun power, spray distance, powder feed rate, plasma gas flow rates, number of gun passes, powder size distribution, injection angle of powder into the plasma plume, vacuum or atmospheric plasma spraying, and substrate heating. Typically, coatings produced by both systems showed bands of lanthanum rich material and cracking with the coating. Preheating the substrate reduced but did not eliminate internal coating cracking. A uniformly thick, dense, adherent interconnect of the desired chemistry was finally achieved with sufficient gas- tightness to allow fabrication of cells and samples for measurement of physical and electrical properties. A cell was tested successfully at 1000{degree}C for over 1,000 hours demonstrating the mechanical, electrical, and chemical stability of a plasma-arc sprayed interconnect layer.

  7. AN OBSERVED CORRELATION BETWEEN THERMAL AND NON-THERMAL EMISSION IN

    Office of Scientific and Technical Information (OSTI)

    GAMMA-RAY BURSTS (Journal Article) | SciTech Connect AN OBSERVED CORRELATION BETWEEN THERMAL AND NON-THERMAL EMISSION IN GAMMA-RAY BURSTS Citation Details In-Document Search Title: AN OBSERVED CORRELATION BETWEEN THERMAL AND NON-THERMAL EMISSION IN GAMMA-RAY BURSTS Recent observations by the Fermi Gamma-ray Space Telescope have confirmed the existence of thermal and non-thermal components in the prompt photon spectra of some gamma-ray bursts (GRBs). Through an analysis of six bright Fermi

  8. Pressurized electrolysis stack with thermal expansion capability

    DOE Patents [OSTI]

    Bourgeois, Richard Scott

    2015-07-14

    The present techniques provide systems and methods for mounting an electrolyzer stack in an outer shell so as to allow for differential thermal expansion of the electrolyzer stack and shell. Generally, an electrolyzer stack may be formed from a material with a high coefficient of thermal expansion, while the shell may be formed from a material having a lower coefficient of thermal expansion. The differences between the coefficients of thermal expansion may lead to damage to the electrolyzer stack as the shell may restrain the thermal expansion of the electrolyzer stack. To allow for the differences in thermal expansion, the electrolyzer stack may be mounted within the shell leaving a space between the electrolyzer stack and shell. The space between the electrolyzer stack and the shell may be filled with a non-conductive fluid to further equalize pressure inside and outside of the electrolyzer stack.

  9. Risk assessment based on point source deposition

    SciTech Connect (OSTI)

    Chadwick, G.F.

    1997-12-31

    The International Joint Commission (IJC) in a recently published report states that various clean-up techniques have resulted in significantly cleaner lakes than 20 years ago. Both the US EPA and Environment Canada have passed laws that require emissions controls on significant sources of contaminants. Improved emission controls have played a large part in the reduced pollution levels to the Great Lakes. Improved controls have significantly reduced the pollutants deposited to both land and water. This paper will discuss a Risk Analysis for the emissions from a Hospital in Rochester, New York. Current New York Department of Environmental Conservation (DEC) regulations require emission controls on such incinerators. This hospital has added both a scrubber and a bag house to control emissions. Twenty years ago, such incinerators, like many other emission sources would not have had control devices. New York`s Department of Environmental Conservation requires, as part of the Permitting process, that an Impact Analysis and if required, a multipathway Health Risk Assessment (HRA) be performed for all Medical Waste Incinerators before a Permit can be issued. This insures that the emissions will not create a health hazard to humans. Such an analysis was performed for a new 1,000 lb/hr Medical Waste Incinerator (MWI) installed in the North-East part of Rochester, New York. An Air Quality Impact Assessment (AQIA) based on an actual stack test indicated that this facility`s dioxin emissions would exceed the NY DEC Guideline levels. The Carcinogenic Risk (of death) for our most exposed individual (MEI) was calculated to be 8.75 E{sup {minus}06} (<1:100,000). The Hazard Index calculated for this MEI was 0.43. Hazard Index`s less then 1 are considered a reasonable risk. Health risk assessments are by design, very conservative. EPA sources have concluded that calculated death risks between one (1) and one hundred (100) per million are not excessive.

  10. Fluorine contamination in yttrium-doped barium zirconate film deposited by atomic layer deposition

    SciTech Connect (OSTI)

    An Jihwan; Beom Kim, Young; Sun Park, Joong; Hyung Shim, Joon; Guer, Turgut M.; Prinz, Fritz B.

    2012-01-15

    The authors have investigated the change of chemical composition, crystallinity, and ionic conductivity in fluorine contaminated yttrium-doped barium zirconate (BYZ) fabricated by atomic layer deposition (ALD). It has been identified that fluorine contamination can significantly affect the conductivity of the ALD BYZ. The authors have also successfully established the relationship between process temperature and contamination and the source of fluorine contamination, which was the perfluoroelastomer O-ring used for vacuum sealing. The total removal of fluorine contamination was achieved by using all-metal sealed chamber instead of O-ring seals.

  11. NREL: Transportation Research - Electric Motor Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electric Motor Thermal Management A photo of a piece of laboratory testing equipment. NREL research in electric motors is helping to improve the performance and reliability of electric-drive vehicles. Photo by Kevin Bennion, NREL NREL's electric motor thermal management research generates experimental data and simulation processes for the modeling, analysis, design, and construction of new electric motors. Electric motor thermal management involves a multifaceted interaction of motor operating

  12. NREL: Transportation Research - Power Electronics Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power Electronics Thermal Management A photo of water boiling in liquid cooling lab equipment. Power electronics thermal management research aims to help lower the cost and improve the performance of electric-drive vehicles. Photo by Dennis Schroeder, NREL NREL investigates and develops thermal management strategies for power electronics systems that use wide-bandgap technology, which enables the development of devices that are smaller than those based on other materials, demonstrating

  13. NREL: Transportation Research - Thermal Performance Benchmarking

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Performance Benchmarking A photo of the internal components of an automotive inverter. NREL thermal performance benchmarking of state-of-the-art power electronics and electric motors helps guide future R&D efforts as well as industry product-development efforts. Photo by Scot Waye, NREL NREL's thermal performance benchmarking research focuses on state-of-the-art technologies used in electric-drive vehicle (EDV) systems. Benchmarks are shared with industry so that systems can be

  14. Project Profile: National Solar Thermal Test Facility

    Broader source: Energy.gov [DOE]

    The first solar receivers ever tested in the world were tested at the National Solar Thermal Test Facility (NSTTF). The receivers were each rated up to 5 megawatts thermal (MWt). Receivers with various working fluids have been tested here over the years, including air, water-steam, molten salt, liquid sodium, and solid particles. The NSTTF has also been used for a large variety of other tests, including materials tests, simulation of thermal nuclear pulses and aerodynamic heating, and ablator testing for NASA.

  15. Thermal breeder fuel enrichment zoning

    DOE Patents [OSTI]

    Capossela, Harry J.; Dwyer, Joseph R.; Luce, Robert G.; McCoy, Daniel F.; Merriman, Floyd C.

    1992-01-01

    A method and apparatus for improving the performance of a thermal breeder reactor having regions of higher than average moderator concentration are disclosed. The fuel modules of the reactor core contain at least two different types of fuel elements, a high enrichment fuel element and a low enrichment fuel element. The two types of fuel elements are arranged in the fuel module with the low enrichment fuel elements located between the high moderator regions and the high enrichment fuel elements. Preferably, shim rods made of a fertile material are provided in selective regions for controlling the reactivity of the reactor by movement of the shim rods into and out of the reactor core. The moderation of neutrons adjacent the high enrichment fuel elements is preferably minimized as by reducing the spacing of the high enrichment fuel elements and/or using a moderator having a reduced moderating effect.

  16. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    Annual shipments of solar thermal collectors by disposition, 2000 - 2009 (thousand square feet) Exports Domestic Shipments Total 2000 26 496 7,857 8,354 2001 26 840 10,349 11,189 2002 27 659 11,004 11,663 2003 26 518 10,926 11,444 2004 24 813 13,301 14,114 2005 25 1,361 14,680 16,041 2006 44 1,211 19,532 20,744 2007 60 1,376 13,777 15,153 2008 74 2,247 14,716 16,963 2009 88 1,577 12,221 13,798 Total shipments as reported by respondents include all domestic and export shipments and may include

  17. Solar Thermal Collector Manufacturing Activities

    Gasoline and Diesel Fuel Update (EIA)

    Shipments of solar thermal collectors ranked by origin and destination, 2009 Origin Top Five States 10,031 73 California 4,402 32 New Jersey 4,019 29 Florida 1,299 9 Arizona 164 1 Virginia 148 1 Other Domestic 311 2 Imported 3,456 25 U.S. Total 13,798 100 Destination Top Five States 8,961 65 Florida 3,771 27 California 3,537 26 Arizona 745 5 Hawaii 520 4 Oregon 387 3 Other Domestic 3,260 24 Exported 1,577 11 U.S. Total 13,798 100 Source: U.S. Energy Information Administration, Form EIA-63A,

  18. Thermal hydraulics development for CASL

    SciTech Connect (OSTI)

    Lowrie, Robert B

    2010-12-07

    This talk will describe the technical direction of the Thermal-Hydraulics (T-H) Project within the Consortium for Advanced Simulation of Light Water Reactors (CASL) Department of Energy Innovation Hub. CASL is focused on developing a 'virtual reactor', that will simulate the physical processes that occur within a light-water reactor. These simulations will address several challenge problems, defined by laboratory, university, and industrial partners that make up CASL. CASL's T-H efforts are encompassed in two sub-projects: (1) Computational Fluid Dynamics (CFD), (2) Interface Treatment Methods (ITM). The CFD subproject will develop non-proprietary, scalable, verified and validated macroscale CFD simulation tools. These tools typically require closures for their turbulence and boiling models, which will be provided by the ITM sub-project, via experiments and microscale (such as DNS) simulation results. The near-term milestones and longer term plans of these two sub-projects will be discussed.

  19. Design method addresses subsea pipeline thermal stresses

    SciTech Connect (OSTI)

    Suman, J.C.; Karpathy, S.A. )

    1993-08-30

    Managing thermal stresses in subsea pipelines carrying heated petroleum requires extensive thermal-stress analysis to predict trouble spots and to ensure a design flexible enough to anticipate stresses and expansions. Explored here are various methods for resolving predicaments posed by thermal loads and resulting deformations by keeping the stresses and deformations in the pipeline system within allowable limits. The problems posed by thermal stresses are not unique; the solutions proposed here are. These methods are based on recent work performed for a major Asian subsea pipeline project currently under construction.

  20. Thermally induced mechanical and permeability changes around...

    Office of Scientific and Technical Information (OSTI)

    A numerical investigation is conducted on the impacts of the thermal loading history on the evolution of mechanical response and permeability field of a fractured rock mass ...

  1. Thermal Regenerator Testing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regenerator Testing Thermal Regenerator Testing Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, ...

  2. NRG Thermal LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Jump to: navigation, search Name: NRG Thermal LLC Place: Minneapolis, Minnesota Zip: 55402-2200 Product: A subsidiary of NRG Energy that specialises in district energy systems...

  3. Trinity Thermal Systems | Open Energy Information

    Open Energy Info (EERE)

    Systems Place: Texas Zip: 75028 Product: Trinity Thermal Systems provides power storage products aimed a shifting energy use from air conditioning systems to off-peak times....

  4. Geothermal Reconnaissance From Quantitative Analysis Of Thermal...

    Open Energy Info (EERE)

    Geothermal Exploration Activities Activities (1) Thermal And-Or Near Infrared At Raft River Geothermal Area (1974-1976) Areas (1) Raft River Geothermal Area Regions (0)...

  5. Chemical preconcentrator with integral thermal flow sensor

    DOE Patents [OSTI]

    Manginell, Ronald P.; Frye-Mason, Gregory C.

    2003-01-01

    A chemical preconcentrator with integral thermal flow sensor can be used to accurately measure fluid flow rate in a microanalytical system. The thermal flow sensor can be operated in either constant temperature or constant power mode and variants thereof. The chemical preconcentrator with integral thermal flow sensor can be fabricated with the same MEMS technology as the rest of the microanlaytical system. Because of its low heat capacity, low-loss, and small size, the chemical preconcentrator with integral thermal flow sensor is fast and efficient enough to be used in battery-powered, portable microanalytical systems.

  6. Thermal Gradient Holes | Open Energy Information

    Open Energy Info (EERE)

    Holes Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Thermal Gradient Holes Details Activities (67) Areas (48) Regions (4) NEPA(33) Exploration...

  7. Thermal Waters of Nevada | Open Energy Information

    Open Energy Info (EERE)

    to library Report: Thermal Waters of Nevada Abstract Abstract unavailable. Authors Larry J. Garside and John H. Schilling Organization Nevada Bureau of Mines and Geology Published...

  8. High intensity, pulsed thermal neutron source

    DOE Patents [OSTI]

    Carpenter, J.M.

    1973-12-11

    This invention relates to a high intensity, pulsed thermal neutron source comprising a neutron-producing source which emits pulses of fast neutrons, a moderator block adjacent to the last neutron source, a reflector block which encases the fast neutron source and the moderator block and has a thermal neutron exit port extending therethrough from the moderator block, and a neutron energy- dependent decoupling reflector liner covering the interior surfaces of the thermal neutron exit port and surrounding all surfaces of the moderator block except the surface viewed by the thermal neutron exit port. (Official Gazette)

  9. Power Electronics and Thermal Management Breakout Sessions

    Broader source: Energy.gov (indexed) [DOE]

    THERMAL MANAGEMENT EV Everywhere Workshop July 24, 2012 Breakout Session 1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the Targets *...

  10. Thermal Degradation Behavior of Siloxane Elastomer Impregnated...

    Office of Scientific and Technical Information (OSTI)

    Improved transport properties (DWNT-CA, SWNT-CA) - greater than 100% enhancement in thermal conductivity, 100-400% improvement in electrical conductivity. Rich mechanical ...

  11. Thermal boundary conductance accumulation and interfacial phonon...

    Office of Scientific and Technical Information (OSTI)

    and theory Citation Details In-Document Search Title: Thermal boundary conductance accumulation and interfacial phonon transmission: Measurements and theory Authors: ...

  12. Thermal Ion Dispersion | Open Energy Information

    Open Energy Info (EERE)

    Dispersion Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Thermal Ion Dispersion Details Activities (1) Areas (1) Regions (0) NEPA(0)...

  13. Integrated External Aerodynamic and Underhood Thermal Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Cooling Boiling in Head Region - PACCAR Integrated Underhood Thermal and External Aerodynamics- Cummins Cummins SuperTruck Program - Technology and ...

  14. Thermal Energy Systems | Open Energy Information

    Open Energy Info (EERE)

    Energy Systems Jump to: navigation, search Name: Thermal Energy Systems Place: London, United Kingdom Sector: Biomass Product: UK based company that constructs and installs boilers...

  15. Southside Thermal Services Ltd | Open Energy Information

    Open Energy Info (EERE)

    Services Ltd Jump to: navigation, search Name: Southside Thermal Services Ltd Place: London, Greater London, United Kingdom Zip: SW7 2AZ Product: String representation "Southside...

  16. Thermal tolerant avicelase from acidothermus cellulolyticus ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Visit the NREL Commercialization and Technology Transfer Website Abstract: The invention provides a thermal tolerant (thermostable) cellulase that is a member of the...

  17. Thermal tolerant mannanase from acidothermus cellulolyticus ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Visit the NREL Commercialization and Technology Transfer Website Abstract: The invention provides a thermal tolerant mannanase that is a member of the glycoside hydrolase...

  18. Thermal tolerant exoglucanase from acidothermus cellulolyticus...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Visit the NREL Commercialization and Technology Transfer Website Abstract: The invention provides a thermal tolerant cellulase that is a member of the glycoside hydrolase...

  19. Thermal tolerant cellulase from acidothermus cellulolyticus ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Visit the NREL Commercialization and Technology Transfer Website Abstract: The invention provides a thermal tolerant cellulase that is a member of the glycoside hydrolase...

  20. Thermal tolerant cellulase from Acidothermus cellulolyticus ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enzymes for the Conversion of Biomass to Biofuels and Chemicals Abstract: The invention provides a thermal tolerant cellulase that is a member of the glycoside hydrolase...