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Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Thermal barrier coating  

DOE Patents [OSTI]

A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

Bowker, Jeffrey Charles (Gibsonia, PA); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL)

2001-01-01T23:59:59.000Z

2

Multilayer thermal barrier coating systems  

DOE Patents [OSTI]

The present invention generally describes multilayer thermal barrier coating systems and methods of making the multilayer thermal barrier coating systems. The thermal barrier coating systems comprise a first ceramic layer, a second ceramic layer, a thermally grown oxide layer, a metallic bond coating layer and a substrate. The thermal barrier coating systems have improved high temperature thermal and chemical stability for use in gas turbine applications.

Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

2000-01-01T23:59:59.000Z

3

Thermal barrier coatings  

DOE Patents [OSTI]

This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.

Alvin, Mary Anne (Pittsburg, PA)

2010-06-22T23:59:59.000Z

4

Low Conductivity Thermal Barrier Coatings  

E-Print Network [OSTI]

Low Conductivity Thermal Barrier Coatings A Dissertation Presented to The Faculty of the School conductivity of the coatings. The minimum thermal conductivity occurs at a low rotation rate and is 0.8 W intrinsic thermal conductivity, good phase stability and greater resistance to sintering and CMAS attack

Wadley, Haydn

5

Westinghouse thermal barrier coatings development  

SciTech Connect (OSTI)

Westinghouse, in conjunction with the Department of Energy and Oak Ridge National Laboratory, has embarked upon a program for the development of advanced thermal barrier coatings for industrial gas turbines. Development of thermal barrier coatings (TBC`s) for industrial gas turbines has relied heavily on the transfer of technology from the aerospace industry. Significant differences in the time/temperature/stress duty cycles exist between these two coating applications. Coating systems which perform well in aerospace applications may not been optimized to meet power generation performance requirements. This program will focus on development of TBC`s to meet the specific needs of power generation applications. The program is directed at developing a state-of-the-art coating system with a minimum coating life of 25,000 hours at service temperatures required to meet increasing operating efficiency goals. Westinghouse has assembled a team of university and industry leaders to accomplish this goal. Westinghouse will coordinate the efforts of all program participants. Chromalloy Turbine Technologies, Inc. and Sermatech International, Inc. will be responsible for bond coat and TBC deposition technology. Praxair Specialty Powders, Inc. will be responsible for the fabrication of all bond coat and ceramic powders for the program. Southwest Research Institute will head the life prediction modelling effort; they will also be involved in coordinating nondestructive evaluation (NDE) efforts. Process modelling will be provided by the University of Arizona.

Goedjen, J.G.; Wagner, G. [Westinghouse Electric Corp., Orlando, FL (United States)

1995-10-01T23:59:59.000Z

6

Thermal barrier coating for alloy systems  

DOE Patents [OSTI]

An alloy substrate is protected by a thermal barrier coating formed from a layer of metallic bond coat and a top coat formed from generally hollow ceramic particles dispersed in a matrix bonded to the bond coat.

Seals, Roland D. (Oak Ridge, TN); White, Rickey L. (Harriman, TN); Dinwiddie, Ralph B. (Knoxville, TN)

2000-01-01T23:59:59.000Z

7

Combustion chemical vapor deposited coatings for thermal barrier coating systems  

SciTech Connect (OSTI)

The new deposition process, combustion chemical vapor deposition, shows a great deal of promise in the area of thermal barrier coating systems. This technique produces dense, adherent coatings, and does not require a reaction chamber. Coatings can therefore be applied in the open atmosphere. The process is potentially suitable for producing high quality CVD coatings for use as interlayers between the bond coat and thermal barrier coating, and/or as overlayers, on top of thermal barrier coatings. In this report, the evaluation of alumina and ceria coatings on a nickel-chromium alloy is described.

Hampikian, J.M.; Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States). School of Materials Science and Engineering

1995-12-31T23:59:59.000Z

8

Model Studies of Pore Stability and Evolution in Thermal Barrier Coatings (TBCs)  

E-Print Network [OSTI]

N. Katz, “Advanced Ceramics: Thermal Barrier Coatings BeatConductivity of Advanced Ceramic Thermal Barrier CoatingsFatigue Testing of Ceramic Thermal Barrier Coatings,” NASA/

Glaeser, A M

2008-01-01T23:59:59.000Z

9

Delamination resistance of thermal barrier coatings containing embedded ductile layers  

E-Print Network [OSTI]

-tempera- ture exposure to oxygen, and an outer low thermal conduc- tivity ceramic coating, such as ytrriaDelamination resistance of thermal barrier coatings containing embedded ductile layers Matthew R layers upon thermal cycling delamination failure of thermal barrier coatings (TBCs) driven by thickening

Wadley, Haydn

10

Vapor deposited samarium zirconate thermal barrier coatings Hengbei Zhao a,  

E-Print Network [OSTI]

Thermal barrier coatings The rare earth zirconates (M2Zr2O7, M=LaGd) have a low intrinsic thermal conductivity and high temperature phase stability making them attractive candidates for thermal barrier coating conditions and the coating composition, structure, texture, pore morphology, and thermal conductivity

Wadley, Haydn

11

Thermal barrier coating having high phase stability  

DOE Patents [OSTI]

A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating characterized by a microstructure having gaps (28) where the thermal barrier coating comprises a first thermal barrier layer (40), and a second thermal barrier layer (30) with a pyrochlore crystal structure having a chemical formula of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof, where B is selected from the group of elements consisting of Zr, Hf, Ti and mixtures thereof, where n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

Subramanian, Ramesh (Oviedo, FL)

2002-01-01T23:59:59.000Z

12

Thermal barrier coating resistant to sintering  

DOE Patents [OSTI]

A device (10) is made, having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10), is not soluble with the underlying ceramic layer (16) and is applied by a process that is not an electron beam physical vapor deposition process.

Subramanian, Ramesh; Seth, Brij B.

2004-06-29T23:59:59.000Z

13

Thermal barrier coating resistant to sintering  

DOE Patents [OSTI]

A device (10) having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10) and is not soluble with the underlying ceramic layer (16). For a YSZ ceramic layer (16) the sintering resistant layer (22) may preferably be aluminum oxide or yttrium aluminum oxide, deposited as a continuous layer or as nodules.

Subramanian, Ramesh (Orlando, FL); Sabol, Stephen M. (Orlando, FL)

2001-01-01T23:59:59.000Z

14

Ion beam assisted deposition of thermal barrier coatings  

DOE Patents [OSTI]

Methods and apparatus for depositing thermal barrier coatings on gas turbine blades and vanes using Electron Beam Physical Vapor Deposition (EBPVD) combined with Ion Beam Assisted Deposition (IBAD).

Youchison, Dennis L. (Albuquerque, NM); McDonald, Jimmie M. (Albuquerque, NM); Lutz, Thomas J. (Albuquerque, NM); Gallis, Michail A. (Albuquerque, NM)

2010-11-23T23:59:59.000Z

15

Thermal barrier coating having high phase stability  

DOE Patents [OSTI]

A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating layer (20) characterized by a microstructure having gaps (28) where the thermal barrier coating (20) consists essentially of a pyrochlore crystal structure having a chemical formula consisting essentially of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements selected from La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof; where B is selected from the group of elements selected from Zr, Hf, Ti and mixtures thereof; n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

Subramanian, Ramesh (Oviedo, FL)

2001-01-01T23:59:59.000Z

16

Thermal barrier coatings for turbine components  

DOE Patents [OSTI]

A turbine component, such as a turbine blade having a metal substrate (22) is coated with a metal MCrAlY alloy layer (24) and then a thermal barrier layer (20) selected from LaAlO.sub.3, NdAlO.sub.3, La.sub.2 Hf.sub.2 O.sub.7, Dy.sub.3 Al.sub.5 O.sub.12, HO.sub.3 Al.sub.3 O.sub.12, ErAlO.sub.3, GdAlO.sub.3, Yb.sub.2 Ti.sub.2 O.sub.7, LaYbO.sub.3, Gd.sub.2 Hf.sub.2 O.sub.7 or Y.sub.3 Al.sub.5 O.sub.12.

Subramanian, Ramesh (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sloan, Kelly M. (Bethesda, MD); Vance, Steven J. (Orlando, FL)

2002-01-01T23:59:59.000Z

17

Thermal barrier coating resistant to sintering  

DOE Patents [OSTI]

A device (10) is made, having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10), is not soluble with the underlying ceramic layer (16) and is applied by a process that is not an electron beam physical vapor deposition process. The sintering inhibiting material (22) has a morphology adapted to improve the functionality of the sintering inhibiting material (22), characterized as continuous, nodule, rivulet, grain, crack, flake and combinations thereof and being disposed within at least some of the vertical and horizontal gaps.

Subramanian, Ramesh; Seth, Brig B.

2005-08-23T23:59:59.000Z

18

Ceramic thermal barrier coating for rapid thermal cycling applications  

DOE Patents [OSTI]

A thermal barrier coating for metal articles subjected to rapid thermal cycling includes a metallic bond coat deposited on the metal article, at least one MCrAlY/ceramic layer deposited on the bond coat, and a ceramic top layer deposited on the MCrAlY/ceramic layer. The M in the MCrAlY material is Fe, Ni, Co, or a mixture of Ni and Co. The ceramic in the MCrAlY/ceramic layer is mullite or Al.sub.2 O.sub.3. The ceramic top layer includes a ceramic with a coefficient of thermal expansion less than about 5.4.times.10.sup.-6 .degree.C.sup.-1 and a thermal conductivity between about 1 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1 and about 1.7 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1.

Scharman, Alan J. (Hebron, CT); Yonushonis, Thomas M. (Columbus, IN)

1994-01-01T23:59:59.000Z

19

Molten silicate interactions with thermal barrier coatings Hengbei Zhao a,  

E-Print Network [OSTI]

Molten silicate interactions with thermal barrier coatings Hengbei Zhao a, , Carlos G. Levi b is enhanced by incorporation of through-thickness pores within the coating. However, molten calcium­magnesium­alumino­silicate in dissolution of the coat- ing in the silicate melt, precipitation of new phases, and the elimination

Wadley, Haydn

20

In-situ formation of multiphase deposited thermal barrier coatings  

DOE Patents [OSTI]

A multiphase ceramic thermal barrier coating is provided. The coating is adapted for use in high temperature applications in excess of about 1200.degree. C., for coating superalloy components of a combustion turbine engine. The coating comprises a ceramic single or two oxide base layer disposed on the substrate surface; and a ceramic oxide reaction product material disposed on the base layer, the reaction product comprising the reaction product of the base layer with a ceramic single or two oxide overlay layer.

Subramanian, Ramesh

2004-01-13T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Thermal Barrier Coatings Chemically and Mechanically Resistant to High Temperature Attack by Molten Ashes.  

E-Print Network [OSTI]

?? Thermal barrier coatings (TBCs) are ceramic coatings used on component in the hottest sections of gas turbine engines, used for power generation and aviation.… (more)

Gledhill, Andrew Dean

2011-01-01T23:59:59.000Z

22

Research: A typical thermal barrier coating consists of two layers over the substrate: 1) a ceramic top coat to  

E-Print Network [OSTI]

Research: A typical thermal barrier coating consists of two layers over the substrate: 1) a ceramic-level understanding of the metal-ceramic and ceramic-ceramic interfaces present in thermal barrier coatings. We have interfaces weaken as the ceramic thickens. This provides atomic-level insight as to why thermal barrier

Carter, Emily A.

23

Simulation of the high temperature impression of thermal barrier coatings with columnar microstructure  

E-Print Network [OSTI]

the deformation resistance of actual EB-PVD layers and its application to a range of thermal barrier materials [9Simulation of the high temperature impression of thermal barrier coatings with columnar of thermal barrier coatings (TBCs) are affected by their high temperature mechanical properties: especially

Hutchinson, John W.

24

Lifetime Assessment for Thermal Barrier Coatings: Tests for Measuring Mixed Mode Delamination Toughness  

E-Print Network [OSTI]

the thermally grown oxide (TGO), and a porous ceramic topcoat which serves as the thermal insulation. DetailsLifetime Assessment for Thermal Barrier Coatings: Tests for Measuring Mixed Mode Delamination Mechanisms leading to degradation of the adherence of thermal barrier coatings (TBC) used in aircraft

Hutchinson, John W.

25

Title: Improving Jet Engine Turbine Thermal Barrier Coatings via Reactive Element Addition to the Bond Coat Alloy  

E-Print Network [OSTI]

Title: Improving Jet Engine Turbine Thermal Barrier Coatings via Reactive Element Addition engine turbine blades can shield the temperature to which the underlying superalloy is exposed modifications that should inhibit the failure of these jet engine turbine thermal barrier coatings. Research

Carter, Emily A.

26

Grain-Boundary Grooving of Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings  

E-Print Network [OSTI]

Grain-Boundary Grooving of Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings Engineering, West Lafayette, Indiana 47907 The focus of this study was to determine the mechanisms re- sponsible for the microstructural changes of plasma-sprayed 7 wt% Y2O3­ZrO2 thermal barrier coatings

Trice, Rodney W.

27

Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation  

SciTech Connect (OSTI)

Ceramic thermal barrier coatings (TBCs) used in gas-turbine engines afford higher operating temperatures, resulting in enhanced efficiencies and performance. However, in the case of syngas-fired engines, fly ash particulate impurities that may be present in syngas can melt on the hotter TBC surfaces and form glassy deposits. These deposits can penetrate the TBCs leading to their failure. In experiments using lignite fly ash to simulate these conditions we show that conventional TBCs of composition 93wt% ZrO{sub 2} + 7wt% Y{sub 2}O{sub 3} (7YSZ) fabricated using the air plasma spray (APS) process are completely destroyed by the molten fly ash. The molten fly ash is found to penetrate the full thickness of the TBC. The mechanisms by which this occurs appear to be similar to those observed in degradation of 7YSZ TBCs by molten calcium-magnesium-aluminosilicate (CMAS) sand and by molten volcanic ash in aircraft engines. In contrast, APS TBCs of Gd{sub 2Zr{sub 2}O{sub 7} composition are highly resistant to attack by molten lignite fly ash under identical conditions, where the molten ash penetrates ~25% of TBC thickness. This damage mitigation appears to be due to the formation of an impervious, stable crystalline layer at the fly ash/Gd{sub 2}Zr{sub 2}O{sub 7} TBC interface arresting the penetrating moltenfly- ash front. Additionally, these TBCs were tested using a rig with thermal gradient and simultaneous accumulation of ash. Modeling using an established mechanics model has been performed to illustrate the modes of delamination, as well as further opportunities to optimize coating microstructure. Transfer of the technology was developed in this program to all interested parties.

Nitin Padture

2011-12-31T23:59:59.000Z

28

Europium-doped Pyrochlores for Use as Thermographic Phosphors in Thermal Barrier Coatings  

E-Print Network [OSTI]

temperatures and better efficiency · Two primary characteristics for coating: low thermal conductivity and high conductivities and high thermal expansion coefficients making them attractive as materials in thermal barrier · Selected compounds have low thermal conductivity, high melting points, and adequate thermal expansion

Walker, D. Greg

29

The influence of coating compliance on the delamination of thermal barrier coatings Hengbei Zhao , Zhuo Yu, Haydn N.G. Wadley  

E-Print Network [OSTI]

zirconia (YSZ) thermal barrier coatings have been deposited on NiCoCrAlY over-lay bond-coated Hastelloy-X

Wadley, Haydn

30

Method And Apparatus For Determining Health Of Thermal Barrier Coatings  

DOE Patents [OSTI]

A method for determining past-service conditions and/or remaining useful life of a component of a combustion engine and/or a thermal barrier coating ("TBC") of the component comprises providing a photoluminescent ("PL") material in the TBC, directing an exciting radiation at the TBC, measuring the intensity of a characteristic peak in the emission spectrum of the PL material, and correlating the intensity of the characteristic peak or another quantity derived therefrom to an amount of a new phase that has been formed as a result of the exposure of the component to extreme temperatures. An apparatus for carrying out the method comprises a radiation source that provides the exciting radiation to the TBC, a radiation detector for detecting radiation emitted by the PL material, and means for relating a characteristic of the emission spectrum of the PL material to the amount of the new phase in the TBC, thereby inferring the past-service conditions or the remaining useful life of the component.

Srivastava, Alok Mani (Niskayuna, NY); Setlur, Anant Achyut (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Devitt, John William (Clifton Park, NY); Ruud, James Anthony (Delmar, NY); Brewer, Luke Nathaniel (Clifton Park, NY)

2005-09-13T23:59:59.000Z

31

Experiments and modeling of multilayered coatings and membranes : application to thermal barrier coatings and reverse osmosis membranes  

E-Print Network [OSTI]

In this thesis, I developed a novel methodology for characterizing interfacial delamination of thermal barrier coatings. The proposed methodology involves novel experiments-plus numerical simulations in order to determine ...

Luk-Cyr, Jacques

2014-01-01T23:59:59.000Z

32

Method of applying a bond coating and a thermal barrier coating on a metal substrate, and related articles  

DOE Patents [OSTI]

A method for applying at least one bond coating on a surface of a metal-based substrate is described. A foil of the bond coating material is first attached to the substrate surface and then fused thereto, e.g., by brazing. The foil is often initially prepared by thermally spraying the bond coating material onto a removable support sheet, and then detaching the support sheet. Optionally, the foil may also include a thermal barrier coating applied over the bond coating. The substrate can be a turbine engine component.

Hasz, Wayne Charles (Pownal, VT); Borom, Marcus Preston (Tucson, AZ)

2002-01-01T23:59:59.000Z

33

On the oxidation of high-temperature alloys, and its role in failure of thermal barrier coatings  

E-Print Network [OSTI]

Thermal barrier coating (TBC) systems are applied to superalloy turbine blades to provide thermal insulation and oxidation protection. A TBC system consists of (a) an outer oxide layer that imparts thermal insulation, and ...

Loeffel, Kaspar Andreas

2013-01-01T23:59:59.000Z

34

Factors affecting the microstructural stability and durability of thermal barrier coatings fabricated by air plasma spraying  

SciTech Connect (OSTI)

The high-temperature behavior of high-purity, low-density (HP-LD) air plasma sprayed (APS) thermal barrier coatings (TBCs) with NiCoCrAlY bond coats deposited by argon-shrouded plasma spraying is described. The high purity yttria-stabilized zirconia resulted in top coats which are highly resistant to sintering and transformation from the metastable tetragonal phase to the equilibrium mixture of monoclinic and cubic phases. The thermal conductivity of the as-processed TBC is low but increases during high temperature exposure even before densification occurs. The porous topcoat microstructure also resulted in good spallation resistance during thermal cycling. The actual failure mechanisms of the APS coatings were found to depend on topcoat thickness, topcoat density, and the thermal cycle frequency. The failure mechanisms are described and the durability of the HP-LD coatings is compared with that of state-of-the-art electron beam physical vapor deposition TBCs.

Helminiak, M. A. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States); Yanar, N. M. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States); Pettit, F. S. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States); Taylor, T. A. [Praxair Surface Technologies, Inc., Indianapolis, IN (United States); Meier, G. H. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States)

2012-10-01T23:59:59.000Z

35

Reaction, transformation and delamination of samarium zirconate thermal barrier coatings  

E-Print Network [OSTI]

cycling between 100 and 1100 °C. This cycling eventually led to delamination of the coatings, with failure thick (50­100 m) metallic "bond coat" applied to the turbine airfoil alloy to slow the kinetics of oxidation and promote TGO adherence. The bond coat has a high aluminum concentration to promote slow

Wadley, Haydn

36

NONDESTRUCTIVE DETECTION OF DELAMINATION IN THERMAL BARRIER COATINGS USING ULTRASONIC TECHNIQUE  

SciTech Connect (OSTI)

Nondestructive testing using an acousto-ultrasonic technique has been utilized to detect the change of material properties and provide early warning of failure of thermal barrier coating (TBC) systems. Testing was performed on René N5 and Haynes 230 coupons with an applied NETL-bond coat, as well as on coupons containing both an applied MCrAlY bond coat and 7-YSZ top coat. The coupons were subjected to either cyclic or isothermal testing at 1100ºC. Ultrasonic testing was performed before and after thermal testing using piezoelectric sensors with dry contact on the surface of the coatings. Proof-of-concept test results indicated that changes in the properties of the ?40 ?m bond coat can be detected using the proposed technique. Waveforms generated via Pitch/Catch indicated minor changes within the bond coat applied to René N5 substrate after 400?500 hours of cyclic oxidation at 1100°C. In contrast, marked differences in waveforms and travel time reflected significant crack formation and spallation of the bond coat from the Haynes 230 substrate. Finite element analysis (FEA) simulation of the wave propagation on a simplified TBC system with nonlinear effects was conducted. FEA results clearly show detection of a small embedded void incorporated to simulate delamination. Comparisons between experimental measurements and finite element simulations were used to estimate the material properties of the coatings and the substrate.

Roger H. L. Chen; Binwei Zhang; Mary Anne Alvin

2009-06-12T23:59:59.000Z

37

Ultrasonic Detection of Delamination and Material Characterization of Thermal Barrier Coatings  

SciTech Connect (OSTI)

This article describes ultrasonic nondestructive evaluation (NDE) to detect the changes of material properties and provide early warning of delamination in thermal barrier coating (TBC) systems. NDE tests were performed on single-crystal René N5 superalloy coupons that were coated with a commercially available MCrAlY bond coat and an air plasma sprayed 7% yttria-stabilized zirconia (YSZ) top coat deposited by Air Plasma Spray method, as well as Haynes 230 superalloy coupons coated with MCrA1Y bond coat, and an electron beam physical vapor deposit of 7% YSZ top coat. The TBC coupons were subjected to either cyclic or isothermal exposure for various lengths of time at temperatures ranging from 900 to 1100 °C. The ultrasonic measurements performed on the coupons had provided an early warning of delamination along the top coat/TGO interface before exposure time, when delamination occurred. The material's property (Young’s modulus) of the top coat was estimated using the measured wave speeds. Finite element analysis (FEA) of the ultrasonic wave propagation was conducted on a simplified TBC system to verify experimental observations. The technique developed was also demonstrated on an as-manufactured turbine blade to estimate normalized top coat thickness measurements.

Chen, Hung-Liang Roger; Zhang, Binwei; Alvin, Mary Anne; Lin, Yun

2012-12-01T23:59:59.000Z

38

Thick Thermal Barrier Coatings (TTBCs) for Low Emission, High Efficiency Diesel Engine Components  

SciTech Connect (OSTI)

The objective of this program was to advance the fundamental understanding of thick thermal barrier coating (TTBC) systems for application to low heat rejection diesel engine combustion chambers. Previous reviews of thermal barrier coating technology concluded that the current level of understanding of coating system behavior is inadequate and the lack of fundamental understanding may impede the application of thermal barrier coating to diesel engines.(1) Areas of TTBC technology examined in this program include powder characteristics and chemistry; bond coating composition, coating design, microstructure and thickness as they affect properties, durability, and reliability; and TTBC "aging" effects (microstructural and property changes) under diesel engine operating conditions. Fifteen TTBC ceramic powders were evaluated. These powders were selected to investigate the effects of different chemistries, different manufacturing methods, lot-to-lot variations, different suppliers and varying impurity levels. Each of the fifteen materials has been sprayed using 36 parameters selected by a design of experiments (DOE) to determine the effects of primary gas (Ar and N2), primary gas flow rate, voltage, arc current, powder feed rate, carrier gas flow rate, and spraying distance. The deposition efficiency, density, and thermal conductivity of the resulting coatings were measured. A coating with a high deposition efficiency and low thermal conductivity is desired from an economic standpoint. An optimum combination of thermal conductivity and disposition efficiency was found for each lot of powder in follow-on experiments and disposition parameters were chosen for full characterization.(2) Strengths of the optimized coatings were determined using 4-point bending specimens. The tensile strength was determined using free-standing coatings made by spraying onto mild steel substrates which were subsequently removed by chemical etching. The compressive strengths of the coatings were determined using composite specimens of ceramic coated onto stainless steel substrates, tested with the coating in compression and the steel in tension. The strength of the coating was determined from an elastic bi-material analysis of the resulting failure of the coating in compression.(3) Altough initial comparisons of the materials would appear to be straight forward from these results, the results of the aging tests of the materials are necessary to insure that trends in properties remain after long term exposure to a diesel environment. Some comparisons can be made, such as the comparison between for lot-to-lot variation. An axial fatigue test to determine the high cycle fatigue behavior of TTBCs was developed at the University of Illinois under funding from this program.(4) A fatigue test apparatus has been designed and initial work performed which demonstrates the ability to provide a routine method of axial testing of coating. The test fixture replaces the normal load frame and fixtures used to transmit the hydraulic oil loading to the sample with the TTBC specimen itself. The TTBC specimen is a composite metal/coating with stainless steel ends. The coating is sprayed onto a mild steel center tube section onto which the stainless steel ends are press fit. The specimen is then machined. After machining, the specimen is placed in an acid bath which etches the mild steel away leaving the TTBC attached to the the stainless steel ends. Plugs are then installed in the ends and the composite specimen loaded in the test fixture where the hydraulic oil pressurizes each end to apply the load. Since oil transmits the load, bending loads are minimized. This test fixture has been modified to allow piston ends to be attached to the specimen which allows tensile loading as well as compressive loading of the specimen. In addition to the room temperature data, specimens have been tested at 800 Degrees C with the surprising result that at high temperature, the TTBC exhibits much higher fatigue strength. Testing of the TTBC using tension/compression cycling has been con

M. Brad Beardsley, Caterpillar Inc.; Dr. Darrell Socie, University of Illinois; Dr. Ed Redja, University of Illinois; Dr. Christopher Berndt, State University of New York at Stony Brook

2006-03-02T23:59:59.000Z

39

Hafnia-Based Nanostructured Thermal Barrier Coatings for Advanced Hydrogen Turbine Technology  

SciTech Connect (OSTI)

Thermal barrier coatings (TBCs) are critical technologies for future gas turbine engines of advanced coal based power generation systems. TBCs protect engine components and allow further increase in engine temperatures for higher efficiency. In this work, nanostructured HfO{sub 2}-based coatings, namely Y{sub 2}O{sub 3}-stabilized HfO{sub 2} (YSH), Gd{sub 2}O{sub 3}-stabilized HfO{sub 2} (GSH) and Y{sub 2}O{sub 3}-stabilized ZrO{sub 2}-HfO{sub 2} (YSZH) were investigated for potential TBC applications in hydrogen turbines. Experimental efforts are aimed at creating a fundamental understanding of these TBC materials. Nanostructured ceramic coatings of YSH, GSH and YSZH were grown by physical vapor deposition methods. The effects of processing parameters and ceramic composition on the microstructural evolution of YSH, GSH and YSZH nanostructured coatings was studied using combined X-ray diffraction (XRD) and Electron microscopy analyses. Efforts were directed to derive a detailed understanding of crystal-structure, morphology, and stability of the coatings. In addition, thermal conductivity as a function of composition in YSH, YSZH and GSH coatings was determined. Laboratory experiments using accelerated test environments were used to investigate the relative importance of various thermo-mechanical and thermo-chemical failure modes of TBCs. Effects of thermal cycling, oxidation and their complex interactions were evaluated using a syngas combustor rig.

Ramana, Chintalapalle; Choudhuri, Ahsan

2013-01-31T23:59:59.000Z

40

Combustion Control and Diagnostics Sensor Testing in a Thermal Barrier Coated Combustor  

SciTech Connect (OSTI)

The combustion control and diagnostics sensor (CCADS) continues to be developed as an in-situ combustion sensor, with immediate application to natural gas fired turbines. In-situ combustion monitoring is also expected to benefit advanced power plants of the future, fueled by coal-derived syngas, liquified natural gas (LNG), hydrogen, or hydrogen blend fuels. The in-situ monitoring that CCADS provides can enable the optimal operation of advanced, fuel-flexible turbines for minimal pollutant emissions and maximum efficiency over the full operating range of an advanced turbine. Previous work has demonstrated CCADS as a useful sensor for in-situ monitoring of natural gas combustion, including detection of important combustion events such as flashback and lean blowoff, in experimental combustors without thermal barrier coatings (TBC). Since typical TBC materials are electrical insulators at room temperature, and CCADS operation requires conduction of electrical current to the walls of the combustor, a TBC on the combustion liner was identified as a potential barrier to CCADS operation in commercial application. This paper reports on CCADS experiments in a turbulent lean premixed combustor with a yttria-stabilized zirconia (YSZ) thermal barrier coating on the combustor wall. The tests were conducted at 0.1 MPa (1 atm), with a 15V excitation voltage on the CCADS electrodes. The results confirm that for a typical thermal barrier coating, CCADS operates properly, and the total measured average resistance is close to that of an uncoated combustor. This result is consistent with previous materials studies that found the electrical resistance of typical TBC materials considerably decreases at combustor operating temperatures.

Chorpening, B.T.; Dukes, M.G.; Robey, E.H.; Thornton, J.D.

2007-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers  

DOE Patents [OSTI]

The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

2001-01-01T23:59:59.000Z

42

Apparatus for determining past-service conditions and remaining life of thermal barrier coatings and components having such coatings  

DOE Patents [OSTI]

An apparatus for determining past-service conditions and/or remaining useful life of a component of a combustion engine and/or a thermal barrier coating ("TBC") of the component comprises a radiation source that provides the exciting radiation to the TBC to excite a photoluminescent ("PL") material contained therein, a radiation detector for detecting radiation emitted by the PL material, and means for relating a characteristic of an emission spectrum of the PL material to the amount of a crystalline phase in the TBC, thereby inferring the past-service conditions or the remaining useful life of the component or the TBC.

Srivastava, Alok Mani (Niskayuna, NY); Setlur, Anant Achyut (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Devitt, John William (Clifton Park, NY); Ruud, James Anthony (Delmar, NY); Brewer, Luke Nathaniel (Rexford, NY)

2004-05-04T23:59:59.000Z

43

Influence of EB-PVD TBC Microstructure on Thermal Barrier Coating System Performance Under Cyclic Conditions  

SciTech Connect (OSTI)

The lifetimes of electron beam physical vapor deposited (EB-PVD) thermal barrier coating systems (TBCs) with three different microstructures of the Y2O3-stabilized ZrO, YSZ) ceramic top layer were investigated in lh thermal cycles at 1100 and 1150°C in flowing oxygen. Single crystal alloys CMSX-4 and Rene N5 that had been coated with an EB-PVD NiCoCrAlY bond coat were chosen as substrate materials. At 1150°C all samples failed after 80-100, lh cycles, predominantly at the bond coat/alumina interface after cooling down from test temperature. The alumina scale remained adherent to the YSZ after spallation. Despite the different YSZ microstructures no clear tendency regarding differences in spallation behavior were observed at 1150°C. At 1100°C the minimum lifetime was 750 , lh cycles for CMSX-4, whereas the first Rene N5 specimen failed after 1750, lh cycles. The longest TBC lifetime on CMSX-4 substrates was 1250, lh cycles, whereas the respective Rene N5 specimens have not yet failed after 2300, lh cycles. The failure mode at 1100°C was identical to that at 115O?C, i.e. the TBC spalled off the surface exposing bare metal after cooling. Even though not all specimens have failed to date, the available results at 1100°C suggested that both, the substrate alloy chemistry and the YSZ microstructure significantly affect the spallation resistance of the TBC.

Leyens, C.; Pint, B.A.; Schulz, U.; Wright, I.G.

1999-04-12T23:59:59.000Z

44

Method for improving the oxidation-resistance of metal substrates coated with thermal barrier coatings  

DOE Patents [OSTI]

A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.

Thompson, Anthony Mark (Niskayuna, NY); Gray, Dennis Michael (Delanson, NY); Jackson, Melvin Robert (Niskayuna, NY)

2002-01-01T23:59:59.000Z

45

Method For Improving The Oxidation Resistance Of Metal Substrates Coated With Thermal Barrier Coatings  

DOE Patents [OSTI]

A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described. A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.

Thompson, Anthony Mark (Niskayuna, NY); Gray, Dennis Michael (Delanson, NY); Jackson, Melvin Robert (Niskayuna, NY)

2003-05-13T23:59:59.000Z

46

Microwave Drilling of Ceramic Thermal-Barrier Coatings Faculty of Engineering, Tel Aviv University, Ramat Aviv 69978, Israel  

E-Print Network [OSTI]

Microwave Drilling of Ceramic Thermal-Barrier Coatings Eli Jerby Faculty of Engineering, Tel Aviv, Schenectady, New York 12301 The microwave drill is a novel process for creating shaped holes in nonconductive materials. Its inherent material selec- tivity makes the microwave drill ideally suited for the con- trolled

Jerby, Eli

47

Use of Covalently-Bonded Ceramics in Jet Engine Thermal BarrierCoatings Emily A. Jarvis and Emily A. Carter  

E-Print Network [OSTI]

Use of Covalently-Bonded Ceramics in Jet Engine Thermal BarrierCoatings Emily A. Jarvis and Emily A-shell repulsions with the nickel metal alloy. We demonstrated how doping the ceramic-metal interface with early with a more covalently bonded ceramic, silica. We found the ideal ceramic/metal and ceramiclceramic TBC

Carter, Emily A.

48

Spectral Modeling of Residual Stress and Stored Elastic Strain Energy in Thermal Barrier Coatings  

SciTech Connect (OSTI)

Solutions to the thermoelastic problem are important for characterizing the response under temperature change of refractory systems. This work extends a spectral fast Fourier transform (FFT) technique to analyze the thermoelastic behavior of thermal barrier coatings (TBCs), with the intent of probing the local origins of failure in TBCs. The thermoelastic FFT (teFFT) approach allows for the characterization of local thermal residual stress and strain fields, which constitute the origins of failure in TBC systems. A technique based on statistical extreme value theory known as peaks-over-threshold (POT) is developed to quantify the extreme values ("hot spots") of stored elastic strain energy (i.e., elastic energy density, or EED). The resolution dependence of the teFFT method is assessed through a sensitivity study of the extreme values in EED. The sensitivity study is performed both for the local (point-by-point) #12;eld distributions as well as the grain scale #12;eld distributions. A convergence behavior to a particular distribution shape is demonstrated for the local #12;elds. The grain scale fields are shown to exhibit a possible convergence to a maximum level of EED. To apply the teFFT method to TBC systems, 3D synthetic microstructures are created to approximate actual TBC microstructures. The morphology of the grains in each constituent layer as well as the texture is controlled. A variety of TBC materials, including industry standard materials and potential future materials, are analyzed using the teFFT. The resulting hot spots are quantified using the POT approach. A correlation between hot spots in EED and interface rumpling between constituent layers is demonstrated, particularly for the interface between the bond coat (BC) and the thermally grown oxide (TGO) layer.

Donegan, Sean; Rolett, Anthony

2013-12-31T23:59:59.000Z

49

Finite element study of multi-modal vibration damping for thermal barrier coating applications  

E-Print Network [OSTI]

barriers for gas turbine blades, there is a growing interest in devel- oping multifunctional coatings methods is critical in many tech- nologies and especially so for gas turbine engines since many the spinning up of the turbine to avoid resonances. One of the advances made in gas turbine technologies, has

50

ON-LINE THERMAL BARRIER COATING MONITORING FOR REAL-TIME FAILURE PROTECTION AND LIFE MAXIMIZATION  

SciTech Connect (OSTI)

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization,'' to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2002-04-01T23:59:59.000Z

51

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure Protection and Life Maximization  

SciTech Connect (OSTI)

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Power Generation, Inc proposed a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization'', to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Power Generation, Inc. has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2005-10-01T23:59:59.000Z

52

ON-LINE THERMAL BARRIER COATING MONITORING FOR REAL-TIME FAILURE PROTECTION AND LIFE MAXIMIZATION  

SciTech Connect (OSTI)

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization,'' to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability, availability, and maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can, therefore, accelerate the degradation of substrate component materials and eventually lead to a premature failure of critical components and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2003-07-01T23:59:59.000Z

53

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure Protection and Life Maximization  

SciTech Connect (OSTI)

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization'', to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2005-04-01T23:59:59.000Z

54

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure Protection and Life Maximization  

SciTech Connect (OSTI)

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization'', to develop, build and install the first generation of an on-line TBC monitoring system for use on land -based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems; a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization.

Dennis H. LeMieux

2004-10-01T23:59:59.000Z

55

ON-LINE THERMAL BARRIER COATING MONITORING FOR REAL-TIME FAILURE PROTECTION AND LIFE MAXIMIZATION  

SciTech Connect (OSTI)

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization,'' to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability, availability, and maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can, therefore, accelerate the degradation of substrate component materials and eventually lead to a premature failure of critical components and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2003-10-01T23:59:59.000Z

56

A sintering model for thermal barrier coatings R.G. Hutchinson a  

E-Print Network [OSTI]

Turbine blades in the high-pressure, high-temperature stages of gas turbines are manufactured from creep-resistant nickel or cobalt alloys. The blades are internally air-cooled and are commonly thermally insulated-PVD coatings comprise a 100­200 lm thick layer of columnar yttria-stabilised zirconia (typically, 7YSZ

Fleck, Norman A.

57

Hydrogen Permeation Barrier Coatings  

SciTech Connect (OSTI)

Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

Henager, Charles H.

2008-01-01T23:59:59.000Z

58

Non-destructive evaluation of degradation in EB-PVD thermal barrier coatings by infrared reflectance spectroscopy  

SciTech Connect (OSTI)

At room temperature and atmospheric conditions infrared reflectance spectroscopy and X-ray diffraction were employed for the detection of the phase transformation and residual stress within thermal barrier coatings (TBC). The TBC's samples initially consisted of the porous ceramic topcoat deposited by electron beam plasma vapor deposition, a bond coat and a superalloy substrate. Reflectance spectroscopy scans were performed from 7497 cm{sup -1} to 68 cm{sup -1} to analysis the fingerprint region as well as the chemical bonding region. These regions should indicate if a detectable change within the TBC response is a result of thermal degradation of the microstructure and the changes in yttrium dispersion throughout the yttrium stabilized zirconium. The thermal degradation was induced by thermal cycling the samples to 1100 Degree-Sign C and then cooling them in an atmospheric environment. X-ray diffraction was also used to detect the phase composition within the TBC samples and see if either would clearly identify failure prior to actual spallation. The eventual measurability and quantify-ability of the phase changes within the TBC's may be used as an effective non-destructive evaluation (NDE) technique that would allow personnel in the field to know when servicing of the turbine blade was necessary.

Flattum, Richard Y.; Cooney, Adam T. [Air Force Research Laboratory, Materials and Manufacturing Directorate, NonDestructive Evaluation Branch, Wright-Patterson AFB, OH (United States)

2013-01-25T23:59:59.000Z

59

Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content (HHC) - Fueled Turbines  

SciTech Connect (OSTI)

The overarching goal of this research program has been to evaluate the potential impacts of coal-derived syngas and high-hydrogen content fuels on the degradation of turbine hot-section components through attack of protective oxides and thermal barrier coatings. The primary focus of this research program has been to explore mechanisms underpinning the observed degradation processes, and connections to the combustion environments and characteristic non-combustible constituents. Based on the mechanistic understanding of how these emerging fuel streams affect materials degradation, the ultimate goal of the program is to advance the goals of the Advanced Turbine Program by developing materials design protocols leading to turbine hot-section components with improved resistance to service lifetime degradation under advanced fuels exposures. This research program has been focused on studying how: (1) differing combustion environments – relative to traditional natural gas fired systems – affect both the growth rate of thermally grown oxide (TGO) layers and the stability of these oxides and of protective thermal barrier coatings (TBCs); and (2) how low levels of fuel impurities and characteristic non-combustibles interact with surface oxides, for instance through the development of molten deposits that lead to hot corrosion of protective TBC coatings. The overall program has been comprised of six inter-related themes, each comprising a research thrust over the program period, including: (i) evaluating the role of syngas and high hydrogen content (HHC) combustion environments in modifying component surface temperatures, heat transfer to the TBC coatings, and thermal gradients within these coatings; (ii) understanding the instability of TBC coatings in the syngas and high hydrogen environment with regards to decomposition, phase changes and sintering; (iii) characterizing ash deposition, molten phase development and infiltration, and associated corrosive/thermo-chemical attack mechanisms; (iv) developing a mechanics-based analysis of the driving forces for crack growth and delamination, based on molten phase infiltration, misfit upon cooling, and loss of compliance; (v) understanding changes in TGO growth mechanisms associated with these emerging combustion product streams; and (vi) identifying degradation resistant alternative materials (including new compositions or bi-layer concepts) for use in mitigating the observed degradation modes. To address the materials stability concerns, this program integrated research thrusts aimed at: (1) Conducting tests in simulated syngas and HHC environments to evaluate materials evolution and degradation mechanisms; assessing thermally grown oxide development unique to HHC environmental exposures; carrying out high-resolution imaging and microanalysis to elucidate the evolution of surface deposits (molten phase formation and infiltration); exploring thermo-chemical instabilities; assessing thermo-mechanical drivers and thermal gradient effects on degradation; and quantitatively measuring stress evolution due to enhanced sintering and thermo-chemical instabilities induced in the coating. (2) Executing experiments to study the melting and infiltration of simulated ash deposits, and identifying reaction products and evolving phases associated with molten phase corrosion mechanisms; utilizing thermal spray techniques to fabricate test coupons with controlled microstructures to study mechanisms of instability and degradation; facilitating thermal gradient testing; and developing new materials systems for laboratory testing; (3) Correlating information on the resulting combustion environments to properly assess materials exposure conditions and guide the development of lab-scale simulations of material exposures; specification of representative syngas and high-hydrogen fuels with realistic levels of impurities and contaminants, to explore differences in heat transfer, surface degradation, and deposit formation; and facilitating combustion rig testing of materials test coupons.

Mumm, Daniel

2013-08-31T23:59:59.000Z

60

A Load-based Depth-sensing Indentation Technique for NDE and Life Assessment of Thermal Barrier Coatings  

SciTech Connect (OSTI)

In this paper, we present a load-based micro-indentation technique for evaluating material mechanical properties as well as degradation evaluation and debonding/spallation detection of thermal barrier coating (TBC) materials. Instead of using contact area as a necessary parameter, the new technique is based on the indentation load. Coupled with a multiple-partial unloading procedure during the indentation process, this technique results in a load-depth sensing indentation system capable of determining Young’s modulus of metals, superalloys, and single crystal matrices, and stiffness of coated material systems with flat, tubular, or curved architectures. This micro-indentation technique can be viewed as a viable non-destructive evaluation (NDE) technique for determining as-manufactured and process-exposed metal, superalloy, single crystal, and TBC-coated material properties. This technique also shows promise for the development of a portable instrument for on-line, in-situ NDE and mechanical properties measurement of structural components.

B. S.-J. Kang; C. Feng; J. M. Tannenbaum; M.A. Alvin

2009-06-12T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Method and apparatus for measuring on-line failure of turbine thermal barrier coatings  

SciTech Connect (OSTI)

A method of remotely monitoring the radiant energy (6) emitted from a turbine component such as a turbine blade (1) having a low-reflective surface coating (3) which may be undergoing potential degradation is used to determine whether erosion, spallation, delamination, or the like, of the coating (3) is occurring.

Zombo, Paul J.; Lemieux, Dennis; Diatzikis, Evangelos

2010-04-06T23:59:59.000Z

62

Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings  

E-Print Network [OSTI]

blades and vanes of gas turbine engines, turbine shrouds and combus- tor cans. These coatings increase (TBCs) by gas tunnel-type plasma spraying exhibited ceramic-composite features consisting of a host measurements across the coating thickness. A one-dimensional series heat transfer model was developed

Ghoniem, Nasr M.

63

Functionally graded materials for thermal barrier coatings in advanced gas turbine systems research. Semi-annual report, May 1--December 31, 1996  

SciTech Connect (OSTI)

A combination of two new production methods, reaction-bonded metal oxide (RBMO) and electrochemical processing, have been utilized to create a functionally graded thermal barrier coating. Electrochemical processing, which includes both electrodeposition (EDEP) and electrophoretic deposition (EPD), has been used to deposit both the metallic and ceramic layers of the coating. EPD has been used to deposit the RBMO precursor powders, which exhibit the dual properties of both a metal and ceramic due to its composite nature. A summary of the FGM production methods and resulting characterization of the produced coatings for the eleventh and twelfth quarters (5/96--12/96), as well as a project summary, are outlined in this final report.

NONE

1997-08-01T23:59:59.000Z

64

Microstructures and properties of laser-glazed plasma-sprayed ZrO{sub 2}-YO{sub 1.5}/Ni-22Cr-10Al-1Y thermal barrier coatings  

SciTech Connect (OSTI)

Thermal barrier coatings (TBCs) consisting of two layers with various yttria contents (ZrO{sub 2}-YO{sub 1.5}/Ni-22Cr-10Al-1Y) were plasma sprayed, and parts of the various specimens were glazed by using a pulsed CO{sub 2} laser. All the specimens were then subjected to furnace thermal cycling tests at 1,100 C; the effect of laser glazing on the durability and failure mechanism of the TBCs was then evaluated. From these results, two models were developed to show the failure mechanism of as-sprayed and laser-glazed TBCs: model A, which is thermal-stress dominant, and model V, which is oxidation-stress dominant. For top coats containing cubic phase, cubic and monoclinic phases, or tetragonal and a relatively larger amount of monoclinic phases, whose degradation is thermal-stress dominant, laser glazing improved the durability of TBCs by a factor of about 2 to 6. Segmented cracks that occurred during glazing proved beneficial for accommodating thermal stress and raising the tolerance to oxidation, which resulted in a higher durability. Thermal barrier coatings with top coats containing tetragonal phase had the highest durability. Degradation of such TBCs resulted mainly from oxidation of the bond coats. For top coats with a greater amount of monoclinic phase, thermal mismatch stress occurred during cooling and detrimentally affected durability.

Tsai, H.L.; Tsai, P.C. [National Taiwan Inst. of Tech., Taipei (Taiwan, Province of China). Dept. of Mechanical Engineering and Technology

1995-12-01T23:59:59.000Z

65

Thermal barrier coating deposition by rarefied gas jet assisted processes: Simulations of deposition on a stationary airfoil  

E-Print Network [OSTI]

of a disk by inter- action with a set of turbine blades (airfoils) attached to the periphery of the disk­150 lm thick layer of zirconia stabilized with 7 wt. % yttria. Such coatings reduce the bond coat surface

Wadley, Haydn

66

ADVANCED ELECTRON BEAM TECHNIQUES FOR METALLIC AND CERAMIC PROTECTIVE COATING SYSTEMS  

E-Print Network [OSTI]

cobalt and chromium. Ceramic or thermal barrier coatings canin fuel usage. Also, ceramic or thermal barrier coatings~n Oslo developed ceramic or thermal barrier coatings that

Boone, Donald H.

2013-01-01T23:59:59.000Z

67

In-situ formation of multiphase air plasma sprayed barrier coatings for turbine components  

DOE Patents [OSTI]

A turbine component (10), such as a turbine blade, is provided which is made of a metal alloy (22) and a base, planar-grained thermal barrier layer (28) applied by air plasma spraying on the alloy surface, where a heat resistant ceramic oxide overlay material (32') covers the bottom thermal barrier coating (28), and the overlay material is the reaction product of the precursor ceramic oxide overlay material (32) and the base thermal barrier coating material (28).

Subramanian, Ramesh (Oviedo, FL)

2001-01-01T23:59:59.000Z

68

Front surface thermal property measurements of air plasma spray coatings  

SciTech Connect (OSTI)

A front-surface measurement for determining the thermal properties of thermal barrier coatings has been applied to air plasma spray coatings. The measurement is used to determine all independent thermal properties of the coating simultaneously. Furthermore, with minimal requirements placed on the sample and zero sample preparation, measurements can be made under previously impossible conditions, such as on serviceable engine parts. Previous application of this technique was limited to relatively thin coatings, where a one-dimensional heat transfer model is applied. In this paper, the influence of heat spreading on the measurement of thicker coatings is investigated with the development of a two-dimensional heat transfer model.

Bennett, Ted; Kakuda, Tyler [University of California, Santa Barbara, California 93106-5070 (United States); Kulkarni, Anand [Siemens Energy, Orlando, Florida 32826-2399 (United States)

2009-04-15T23:59:59.000Z

69

Barrier Coatings for Refractory Metals and Superalloys  

SciTech Connect (OSTI)

In the closed working fluid loop of the proposed Prometheus space nuclear power plant (SNPP), there is the potential for reaction of core and plant structural materials with gas phase impurities and gas phase transport of interstitial elements between superalloy and refractory metal alloy components during service. Primary concerns are surface oxidation, interstitial embrittlement of refractory metals and decarburization of superalloys. In parallel with kinetic investigations, this letter evaluates the ability of potential coatings to prevent or impede communication between reactor and plant components. Key coating requirements are identified and current technology coating materials are reviewed relative to these requirements. Candidate coatings are identified for future evaluation based on current knowledge of design parameters and anticipated environment. Coatings were identified for superalloys and refractory metals to provide diffusion barriers to interstitial transport and act as reactive barriers to potential oxidation. Due to their high stability at low oxygen potential, alumina formers are most promising for oxidation protection given the anticipated coolant gas chemistry. A sublayer of iridium is recommended to provide inherent diffusion resistance to interstitials. Based on specific base metal selection, a thin film substrate--coating interdiffusion barrier layer may be necessary to meet mission life.

SM Sabol; BT Randall; JD Edington; CJ Larkin; BJ Close

2006-02-23T23:59:59.000Z

70

In-situ formation of multiphase electron beam physical vapor deposited barrier coatings for turbine components  

DOE Patents [OSTI]

A turbine component (10), such as a turbine blade, is provided which is made of a metal alloy (22) and a base columnar thermal barrier coating (20) on the alloy surface, where a heat resistant ceramic oxide sheath material (32' or 34') covers the columns (28), and the sheath material is the reaction product of a precursor ceramic oxide sheath material and the base thermal barrier coating material.

Subramanian, Ramesh (Oviedo, FL)

2001-01-01T23:59:59.000Z

71

ATOMIC-LEVEL PROPERTIES OF THERMAL BARRIER CHARACTERIZATION OF METAL-CERAMIC INTERFRACES  

E-Print Network [OSTI]

engines. These TBC's are comprised of ceramics, with favorably low thermal conductivity, deposited years ago.2 Hence, engineers looked to ceramic materials as a means of providing a thermal barrierChapter 1 ATOMIC-LEVEL PROPERTIES OF THERMAL BARRIER COATINGS : CHARACTERIZATION OF METAL

Carter, Emily A.

72

Thermal Bypass Air Barriers in the 2009 International Energy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermal Bypass Air Barriers in the 2009 International Energy Conservation Code - Building America Top Innovation Thermal Bypass Air Barriers in the 2009 International Energy...

73

Comparative Experimental Investigation of Combustion, Performance and Emission in a Single Cylinder Thermal Barrier Coated Diesel Engine using Diesel and Neem Biodiesel  

E-Print Network [OSTI]

Abstract- The use of methyl esters of vegetable oil known as biodiesel are increasingly popular because of their low impact on environment, green alternate fuel and most interestingly it's use in engines does not require major modification in the engine hardware. Use of biodiesel as sole fuel in conventional direct injection diesel engine results in combustion problems, hence it is proposed to use the biodiesel in low heat rejection (LHR) diesel engines with its significance characteristics of higher operating temperature, maximum heat release, higher brake thermal efficiency (BTE) and ability to handle the lower calorific value (CV) fuel. In this work biodiesel from Neem oil called as Neem oil methyl ester (NOME) was used as sole fuel in conventional diesel engine and LHR direct injection (Dl) diesel engine. The low heat rejection engine was developed with uniform ceramic coating of combustion chamber (includes piston crown, cylinder head, valves and cylinder liner) by partially stabilized /zirconia (PSZ) of 0.5 mm thickness. The experimental investigation was carried out in a single cylinder water-cooled LHR direct injection diesel engine. In this investigation, the combustion, performance and emission analysis were carried out in a diesel and biodiesel fueled conventional and LHR engine under identical operating conditions. The test result of biodiesel fueled LHR engine was quite identical to that of the conventional diesel engine. The brake thermal efficiency (BTE) of LHR engine with biodiesel is decreased marginally than LHR engine operated with diesel. Carbon monoxide (CO) and Hydrocarbon (HC) emission levels are decreased. The results of this comparative experimental investigation reveals that, some of the drawbacks of

M C Navindgi; Dr. Maheswar Dutta; Dr. B. Sudheer Prem Kumar

74

Nondestructive evaluation of environmental barrier coatings in CFCC combustor liners.  

SciTech Connect (OSTI)

Advanced combustor liners fabricated of SiC/SiC continuous fiber-reinforced ceramic composite (CFCC) and covered with environmental barrier coatings (EBCs) have been successfully tested in Solar Turbines Inc. field engines. The primary goal for the CFCC/EBC liners is to reach a 30,000-h lifetime. Because the EBCs, when applied on the hot surfaces of liners, protect the underlying CFCC from oxidation damage, their performance is critical in achieving the lifetime goal. To determine CFCC/EBC liner condition and assess operating damage, the liners were subjected to nondestructive evaluation (NDE) during various processing stages, as well as before and after the engine test. The NDE techniques included pulsed infrared thermal imaging, air-coupled ultrasonic scanning, and X-ray computerized tomography. It was found that EBC damage and spallation depend on the condition of the CFCC material. The NDE results and correlations with destructive examination are discussed.

Sun, J. G.; Benz, J.; Ellingson, W. A.; Kimmel, J. B.; Price, J. R.; Energy Technology; Solar Turbines, Inc

2007-01-01T23:59:59.000Z

75

Computational Design and Experimental Validation of New Thermal Barrier Systems  

SciTech Connect (OSTI)

This project (10/01/2010-9/30/2014), “Computational Design and Experimental Validation of New Thermal Barrier Systems”, originates from Louisiana State University (LSU) Mechanical Engineering Department and Southern University (SU) Department of Computer Science. This project will directly support the technical goals specified in DE-FOA-0000248, Topic Area 3: Turbine Materials, by addressing key technologies needed to enable the development of advanced turbines and turbine-based systems that will operate safely and efficiently using coal-derived synthesis gases. In this project, the focus is to develop and implement novel molecular dynamics method to improve the efficiency of simulation on novel TBC materials; perform high performance computing (HPC) on complex TBC structures to screen the most promising TBC compositions; perform material characterizations and oxidation/corrosion tests; and demonstrate our new thermal barrier coating (TBC) systems experimentally under integrated gasification combined cycle (IGCC) environments.

Guo, Shengmin; Yang, Shizhong; Khosravi, Ebrahim

2014-04-01T23:59:59.000Z

76

Thermal sensor with an improved coating  

DOE Patents [OSTI]

The disclosure is directed to an apparatus for detecting radiation having wavelengths from about 0.4 .mu.m to about 5.6 .mu.m. An optical coating is applied to a thermal sensor that is normally transparent to radiation with such wavelengths. The optical coating is thin and light and includes a modifier and an absorber. The thermal sensor can be a pyroelectric detector such as strontium barium niobate.

LaDelfe, Peter C. (Los Alamos, NM); Stotlar, Suzanne C. (Los Alamos, NM)

1986-01-01T23:59:59.000Z

77

Nuclear reactor vessel fuel thermal insulating barrier  

DOE Patents [OSTI]

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel that has a hemispherical lower section that increases in volume from the center line of the reactor to the outer extent of the diameter of the thermal insulating barrier and smoothly transitions up the side walls of the vessel. The space between the thermal insulating harrier and the reactor vessel forms a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive inlet valve for the cooling water includes a buoyant door that is normally maintained sealed under its own weight and floats open when the cavity is Hooded. Passively opening steam vents are also provided.

Keegan, C. Patrick; Scobel, James H.; Wright, Richard F.

2013-03-19T23:59:59.000Z

78

Coating thermal noise for arbitrary shaped beams  

E-Print Network [OSTI]

Advanced LIGO's sensitivity will be limited by coating noise. Though this noise depends on beam shape, and though nongaussian beams are being seriously considered for advanced LIGO, no published analysis exists to compare the quantitative thermal noise improvement alternate beams offer. In this paper, we derive and discuss a simple integral which completely characterizes the dependence of coating thermal noise on shape. The derivation used applies equally well, with minor modifications, to all other forms of thermal noise in the low-frequency limit.

Richard O'Shaughnessy

2006-10-13T23:59:59.000Z

79

Computational Design and Experimental Validation of New Thermal Barrier Systems  

SciTech Connect (OSTI)

This project (10/01/2010-9/30/2013), “Computational Design and Experimental Validation of New Thermal Barrier Systems”, originates from Louisiana State University (LSU) Mechanical Engineering Department and Southern University (SU) Department of Computer Science. This proposal will directly support the technical goals specified in DE-FOA-0000248, Topic Area 3: Turbine Materials, by addressing key technologies needed to enable the development of advanced turbines and turbine-based systems that will operate safely and efficiently using coal-derived synthesis gases. We will develop novel molecular dynamics method to improve the efficiency of simulation on novel TBC materials; we will perform high performance computing (HPC) on complex TBC structures to screen the most promising TBC compositions; we will perform material characterizations and oxidation/corrosion tests; and we will demonstrate our new Thermal barrier coating (TBC) systems experimentally under Integrated gasification combined cycle (IGCC) environments. The durability of the coating will be examined using the proposed High Temperature/High Pressure Durability Test Rig under real syngas product compositions.

Guo, Shengmin; Yang, Shizhong; Khosravi, Ebrahim

2011-12-31T23:59:59.000Z

80

Thermal coatings for titanium-aluminum alloys  

SciTech Connect (OSTI)

Titanium aluminides and titanium alloys are candidate materials for use in hot structure and heat-shield components of hypersonic vehicles because of their good strength-to-weight characteristics at elevated temperature. However, in order to utilize their maximum temperature capability, they must be coated to resist oxidation and to have a high total remittance. Also, surface catalysis for recombination of dissociated species in the aerodynamic boundary layer must be minimized. Very thin chemical vapor deposition (CVD) coatings are attractive candidates for this application because of durability and very light weight. To demonstrate this concept, coatings of boron-silicon and aluminum-boron-silicon compositions were applied to the titanium-aluminides alpha2 (Ti-14Al-21Nb), super-alpha2 (Ti-14Al-23-Nb-2V), and gamma (Ti-33Al-6Nb-1Ta) and to the titanium alloy beta-21S (Ti-15Mo-3Al-3Nb-0.2Si). Coated specimens of each alloy were subjected to a set of simulated hypersonic vehicle environmental tests to determine their properties of oxidation resistance, surface catalysis, radiative emittance, and thermal shock resistance. Surface catalysis results should be viewed as relative performance only of the several coating-alloy combinations tested under the specific environmental conditions of the LaRC Hypersonic Materials Environmental Test System (HYMETS) arc-plasma-heated hypersonic wind tunnel. Tests were also conducted to evaluate the hydrogen transport properties of the coatings and any effects of the coating processing itself on fatigue life of the base alloys. Results are presented for three types of coatings, which are as follows: (1) a single layer boron silicon coating, (2) a single layer aluminum-boron-silicon coating, and (3) a multilayer coating consisting of an aluminum-boron-silicon sublayer with a boron-silicon outer layer.

Cunnington, G.R.; Clark, R.K.; Robinson, J.C.

1993-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Thermal Barrier Coatings Resistant to Glassy Deposits.  

E-Print Network [OSTI]

?? Engineering of alloys has for years allowed aircraft turbine engines to become more efficient and operate at higher temperatures. As advancements in these alloy… (more)

Drexler, Julie

2011-01-01T23:59:59.000Z

82

Development of Diffusion barrier coatings and Deposition Technologies for Mitigating Fuel Cladding Chemical Interactions (FCCI)  

SciTech Connect (OSTI)

The goal of this project is to develop diffusion barrier coatings on the inner cladding surface to mitigate fuel-cladding chemical interaction (FCCI). FCCI occurs due to thermal and radiation enhanced inter-diffusion between the cladding and fuel materials, and can have the detrimental effects of reducing the effective cladding wall thickness and lowering the melting points of the fuel and cladding. The research is aimed at the Advanced Burner Reactor (ABR), a sodium-cooled fast reactor, in which higher burn-ups will exacerbate the FCCI problem. This project will study both diffusion barrier coating materials and deposition technologies. Researchers will investigate pure vanadium, zirconium, and titanium metals, along with their respective oxides, on substrates of HT-9, T91, and oxide dispersion-strengthened (ODS) steels; these materials are leading candidates for ABR fuel cladding. To test the efficacy of the coating materials, the research team will perform high-temperature diffusion couple studies using both a prototypic metallic uranium fuel and a surrogate�¢����the rare-earth element lanthanum. Ion irradiation experiments will test the stability of the coating and the coating-cladding interface. A critical technological challenge is the ability to deposit uniform coatings on the inner surface of cladding. The team will develop a promising non-line-of-sight approach that uses nanofluids . Recent research has shown the feasibility of this simple yet novel approach to deposit coatings on test flats and inside small sections of claddings. Two approaches will be investigated: 1) modified electrophoretic deposition (MEPD) and 2) boiling nanofluids. The coatings will be evaluated in the as-deposited condition and after sintering.

Sridharan, Kumar; Allen, Todd; Cole, James

2013-02-27T23:59:59.000Z

83

Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings  

E-Print Network [OSTI]

SAW Amorphous metal and ceramic thermal spray coatings havefor Thermal Spray Amorphous Metal and Ceramic Coatings J.

Blink, J.; Farmer, J.; Choi, J.; Saw, C.

2009-01-01T23:59:59.000Z

84

Method of producing thermally sprayed metallic coating  

DOE Patents [OSTI]

The cylinder walls of light metal engine blocks are thermally spray coated with a ferrous-based coating using an HVOF device. A ferrous-based wire is fed to the HVOF device to locate a tip end of the wire in a high temperature zone of the device. Jet flows of oxygen and gaseous fuel are fed to the high temperature zone and are combusted to generate heat to melt the tip end. The oxygen is oversupplied in relation to the gaseous fuel. The excess oxygen reacts with and burns a fraction of the ferrous-based feed wire in an exothermic reaction to generate substantial supplemental heat to the HVOF device. The molten/combusted metal is sprayed by the device onto the walls of the cylinder by the jet flow of gases.

Byrnes, Larry Edward (Rochester Hills, MI); Kramer, Martin Stephen (Clarkston, MI); Neiser, Richard A. (Albuquerque, NM)

2003-08-26T23:59:59.000Z

85

Morphology and thermal conductivity of yttria-stabilized zirconia coatings  

E-Print Network [OSTI]

yttria-stabilized zir- conia (YSZ) is then applied to provide thermal insulation [1]. This ceramic layer]. The thermal conductivity of the ceramic layer has been found to depend on the pore morphology within a coatingMorphology and thermal conductivity of yttria-stabilized zirconia coatings Hengbei Zhao a

Wadley, Haydn

86

In situ thermal performance of APP modified bitumen roof membranes coated with reflective coatings  

SciTech Connect (OSTI)

A multi-faceted field research program regarding seven atactic polypropylene (APP) modified bitumen membrane roof systems and four reflective coatings began in 1991. This long-term project is evaluating the performance of various APP modified bitumen membranes (both coated and uncoated), the comparative performance of coating application soon after membrane installation versus preweathering, coating performance, and aspects of recoating. This paper is a progress report on the in situ thermal performance of the various types of coatings compared to the thermal performance of the exposed membrane. The thermal performance of an adjacent ballasted ethylene propylene diene terpolymer (EPDM) roofing system is also described.

Carlson, J.D.; Smith, T.L. (National Roofing Contractors Association, Rosemont, IL (United States)); Christian, J.E. (Oak Ridge National Lab., TN (United States))

1992-01-01T23:59:59.000Z

87

In situ thermal performance of APP modified bitumen roof membranes coated with reflective coatings  

SciTech Connect (OSTI)

A multi-faceted field research program regarding seven atactic polypropylene (APP) modified bitumen membrane roof systems and four reflective coatings began in 1991. This long-term project is evaluating the performance of various APP modified bitumen membranes (both coated and uncoated), the comparative performance of coating application soon after membrane installation versus preweathering, coating performance, and aspects of recoating. This paper is a progress report on the in situ thermal performance of the various types of coatings compared to the thermal performance of the exposed membrane. The thermal performance of an adjacent ballasted ethylene propylene diene terpolymer (EPDM) roofing system is also described.

Carlson, J.D.; Smith, T.L. [National Roofing Contractors Association, Rosemont, IL (United States); Christian, J.E. [Oak Ridge National Lab., TN (United States)

1992-10-01T23:59:59.000Z

88

Reduced Thermal Conductivity of Compacted Silicon Nanowires  

E-Print Network [OSTI]

Thermal-Barrier-Coating Applications,” Journa of American Ceramicthermal conductivity materials are typically found among ceramicsThermal Conductivity of Porous Materials: Application to Thick Barrier Coatings,” Journal of the European Ceramic

Yuen, Taylor S.

89

Barrier Coatings for Thin Film Solar Cells: Final Subcontract Report, September 1, 2002 -- January 30, 2008  

SciTech Connect (OSTI)

This program has involved investigations of the stability of CdTe and copper-indium-gallium-diselenide (CIGS) solar cells under damp heat conditions and effects of barrier coatings.

Olsen, L. C.

2010-03-01T23:59:59.000Z

90

Thermal model of attic systems with radiant barriers  

SciTech Connect (OSTI)

This report summarizes the first phase of a project to model the thermal performance of radiant barriers. The objective of this phase of the project was to develop a refined model for the thermal performance of residential house attics, with and without radiant barriers, and to verify the model by comparing its predictions against selected existing experimental thermal performance data. Models for the thermal performance of attics with and without radiant barriers have been developed and implemented on an IBM PC/AT computer. The validity of the models has been tested by comparing their predictions with ceiling heat fluxes measured in a number of laboratory and field experiments on attics with and without radiant barriers. Cumulative heat flows predicted by the models were usually within about 5 to 10 percent of measured values. In future phases of the project, the models for attic/radiant barrier performance will be coupled with a whole-house model and further comparisons with experimental data will be made. Following this, the models will be utilized to provide an initial assessment of the energy savings potential of radiant barriers in various configurations and under various climatic conditions. 38 refs., 14 figs., 22 tabs.

Wilkes, K.E.

1991-07-01T23:59:59.000Z

91

Advances in PSII Deposited Diamond-Like Carbon Coatings for Use as a Corrosion Barrier  

E-Print Network [OSTI]

Advances in PSII Deposited Diamond-Like Carbon Coatings for Use as a Corrosion Barrier R. S to improve corrosion resistance, however, the necessary organometallics needed to implant these materials to produce an adherent, hard, wear and, corrosion-resistant coating plays a vital role. These applications

92

Failure Modes of Vacuum Plasma Spray Tungsten Coating Created on Carbon Fibre Composites under Thermal Loads  

E-Print Network [OSTI]

Failure Modes of Vacuum Plasma Spray Tungsten Coating Created on Carbon Fibre Composites under Thermal Loads

93

Studies of switching field and thermal energy barrier distributions in a FePt nanoparticle system  

E-Print Network [OSTI]

Studies of switching field and thermal energy barrier distributions in a FePt nanoparticle system X dependence of the thermal stability factor, the width of the thermal energy barrier distribution- ropy energy distribution and the interaction and the thermal energy barrier distribution determined

Laughlin, David E.

94

Metallic coatings for enhancement of thermal contact conductance  

SciTech Connect (OSTI)

The reliability of standard electronic modules may be improved by decreasing overall module temperature. This may be accomplished by enhancing the thermal contact conductance at the interface between the module frame guide rib and the card rail to which the module is clamped. Some metallic coatings, when applied to the card rail, would deform under load, increasing the contact area and associated conductance. This investigation evaluates the enhancements in thermal conductance afforded by vapor deposited silver and gold coatings. Experimental thermal conductance measurements were made for anodized aluminum 6101-T6 and electroless nickel-plated copper C11000-H03 card materials to the aluminum A356-T61 rail material. Conductance values for the electroless nickel-plated copper junction ranged from 600 to 2800 W/m(exp 2)K and those for the anodized aluminum junction ranged from 25 to 91 W/m(exp 2)K for contact pressures of 0.172-0.862 MPa and mean junction temperatures of 20-100 C. Experimental thermal conductance values of vapor deposited silver- and gold-coated aluminum A356-T61 rail surfaces indicate thermal enhancements of 1.25-2.19 for the electroless nickel-plated copper junctions and 1.79-3.41 for the anodized aluminum junctions. The silver and gold coatings provide significant thermal enhancement; however, these coating-substrate combinations are susceptible to galvanic corrosion under some conditions. 25 refs.

Lambert, M.A.; Fletcher, L.S. (Texas A M Univ., College Station, TX (United States))

1994-04-01T23:59:59.000Z

95

Initial Assessment of Environmental Barrier Coatings for the Prometheus Project  

SciTech Connect (OSTI)

Depending upon final design and materials selections, a variety of engineering solutions may need to be considered to avoid chemical degradation of components in a notional space nuclear power plant (SNPP). Coatings are one engineered approach that was considered. A comprehensive review of protective coating technology for various space-reactor structural materials is presented, including refractory metal alloys [molybdenum (Mo), tungsten (W), rhenium (Re), tantalum (Ta), and niobium (Nb)], nickel (Ni)-base superalloys, and silicon carbide (Sic). A summary description of some common deposition techniques is included. A literature survey identified coatings based on silicides or iridium/rhenium as the primary methods for environmental protection of refractory metal alloys. Modified aluminide coatings have been identified for superalloys and multilayer ceramic coatings for protection of Sic. All reviewed research focused on protecting structural materials from extreme temperatures in highly oxidizing conditions. Thermodynamic analyses indicate that some of these coatings may not be protective in the high-temperature, impure-He environment expected in a Prometheus reactor system. Further research is proposed to determine extensibility of these coating materials to less-oxidizing or neutral environments.

M. Frederick

2005-12-15T23:59:59.000Z

96

Distributed Porosity as a Control Parameter for Oxide Thermal Barriers Made by Physical Vapor Deposition  

E-Print Network [OSTI]

Anthony G. Evans* Materials Institute, Princeton University, Princeton, New Jersey 08544 Thermal barrier and generating new thermal resistance solutions, as appropri- ate. A continuum heat flow analysis is usedDistributed Porosity as a Control Parameter for Oxide Thermal Barriers Made by Physical Vapor

Wadley, Haydn

97

Engineered Barrier Systems Thermal-Hydraulic-Chemical Column Test Report  

SciTech Connect (OSTI)

The Engineered Barrier System (EBS) Thermal-Hydraulic-Chemical (THC) Column Tests provide data needed for model validation. The EBS Degradation, Flow, and Transport Process Modeling Report (PMR) will be based on supporting models for in-drift THC coupled processes, and the in-drift physical and chemical environment. These models describe the complex chemical interaction of EBS materials, including granular materials, with the thermal and hydrologic conditions that will be present in the repository emplacement drifts. Of particular interest are the coupled processes that result in mineral and salt dissolution/precipitation in the EBS environment. Test data are needed for thermal, hydrologic, and geochemical model validation and to support selection of introduced materials (CRWMS M&O 1999c). These column tests evaluated granular crushed tuff as potential invert ballast or backfill material, under accelerated thermal and hydrologic environments. The objectives of the THC column testing are to: (1) Characterize THC coupled processes that could affect performance of EBS components, particularly the magnitude of permeability reduction (increases or decreases), the nature of minerals produced, and chemical fractionation (i.e., concentrative separation of salts and minerals due to boiling-point elevation). (2) Generate data for validating THC predictive models that will support the EBS Degradation, Flow, and Transport PMR, Rev. 01.

W.E. Lowry

2001-12-13T23:59:59.000Z

98

Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings  

SciTech Connect (OSTI)

Amorphous metal and ceramic thermal spray coatings have been developed that can be used to enhance the corrosion resistance of containers for the transportation, aging and disposal of spent nuclear fuel and high-level radioactive wastes. Iron-based amorphous metal formulations with chromium, molybdenum and tungsten have shown the corrosion resistance believed to be necessary for such applications. Rare earth additions enable very low critical cooling rates to be achieved. The boron content of these materials, and their stability at high neutron doses, enable them to serve as high efficiency neutron absorbers for criticality control. Ceramic coatings may provide even greater corrosion resistance for container applications, though the boron-containing amorphous metals are still favored for criticality control applications. These amorphous metal and ceramic materials have been produced as gas atomized powders and applied as near full density, non-porous coatings with the high-velocity oxy-fuel process. This paper summarizes the performance of these coatings as corrosion-resistant barriers, and as neutron absorbers. Relevant corrosion models are also discussed, as well as a cost model to quantify the economic benefits possible with these new materials.

Blink, J; Choi, J; Farmer, J

2007-07-09T23:59:59.000Z

99

Deposition of Graded Thermal Barrier Coatings for Gas Turbine Blades -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesData Files DataADVANCESDepartmentDepartmentalDeployment of a

100

MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM  

SciTech Connect (OSTI)

In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

V.K. Mathur

2003-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Corrosion-resistant coating prepared by the thermal decomposition of lithium permanganate  

SciTech Connect (OSTI)

A ceramic, metal, or metal alloy surface is covered with lithium permanganate which is then thermally decomposed to produce a corrosion resistant coating on the surface. This coating serves as a primer coating which is preferably covered with an overcoat of a sealing paint.

Ferrando, W.A.

1999-09-01T23:59:59.000Z

102

E-Print Network 3.0 - advanced thermal barrier Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: either kinetic or thermal effects, viz., from pumping of electrons from the wells to the barriers... . Tischler, B. A. Weinstein1 ), and B. D. McCombe Department of...

103

Thermal Performance Evaluation of Attic Radiant Barrier Systems Using the Large Scale Climate Simulator (LSCS)  

SciTech Connect (OSTI)

Application of radiant barriers and low-emittance surface coatings in residential building attics can significantly reduce conditioning loads from heat flow through attic floors. The roofing industry has been developing and using various radiant barrier systems and low-emittance surface coatings to increase energy efficiency in buildings; however, minimal data are available that quantifies the effectiveness of these technologies. This study evaluates performance of various attic radiant barrier systems under simulated summer daytime conditions and nighttime or low solar gain daytime winter conditions using the large scale climate simulator (LSCS). The four attic configurations that were evaluated are 1) no radiant barrier (control), 2) perforated low-e foil laminated oriented strand board (OSB) deck, 3) low-e foil stapled on rafters, and 4) liquid applied low-emittance coating on roof deck and rafters. All test attics used nominal RUS 13 h-ft2- F/Btu (RSI 2.29 m2-K/W) fiberglass batt insulation on attic floor. Results indicate that the three systems with radiant barriers had heat flows through the attic floor during summer daytime condition that were 33%, 50%, and 19% lower than the control, respectively.

Shrestha, Som S [ORNL] [ORNL; Miller, William A [ORNL] [ORNL; Desjarlais, Andre Omer [ORNL] [ORNL

2013-01-01T23:59:59.000Z

104

Methods for coating conduit interior surfaces utilizing a thermal spray gun with extension arm  

DOE Patents [OSTI]

Systems and methods for applying a coating to an interior surface of a conduit. In one embodiment, a spray gun configured to apply a coating is attached to an extension arm which may be inserted into the bore of a pipe. The spray gun may be a thermal spray gun adapted to apply a powder coating. An evacuation system may be used to provide a volume area of reduced air pressure for drawing overspray out of the pipe interior during coating. The extension arm as well as the spray gun may be cooled to maintain a consistent temperature in the system, allowing for more consistent coating.

Moore, Karen A. (Idaho Falls, ID); Zatorski, Raymond A. (East Hampton, CT)

2007-10-02T23:59:59.000Z

105

Systems and methods for coating conduit interior surfaces utilizing a thermal spray gun with extension arm  

DOE Patents [OSTI]

Systems and methods for applying a coating to an interior surface of a conduit. In one embodiment, a spray gun configured to apply a coating is attached to an extension arm which may be inserted into the bore of a pipe. The spray gun may be a thermal spray gun adapted to apply a powder coating. An evacuation system may be used to provide a volume area of reduced air pressure for drawing overspray out of the pipe interior during coating. The extension arm as well as the spray gun may be cooled to maintain a consistent temperature in the system, allowing for more consistent coating.

Moore, Karen A.; Zatorski, Raymond A.

2005-07-12T23:59:59.000Z

106

Observability of thermal effects in the Casimir interaction from graphene-coated substrates  

E-Print Network [OSTI]

Using the recently proposed theory, we calculate thermal effect in the Casimir interaction from graphene-coated metallic and dielectric substrates. The cases when only one or both of the two parallel plates are coated with graphene are considered. It is shown that the graphene coating does not influence the Casimir interaction between metals, but produces large impact for dielectrics. This impact increases with decreasing static dielectric permittivity of the plate material. The thermal correction to the gradient of the Casimir force between an Au sphere and graphene coated fused silica plate is calculated. It is shown to be significanlty greater than the total experimental error in the recently performed experiment, which is demonstrated to be only one step away from observation of the thermal effect from a graphene-coated substrate at short separation distances. To achieve this goal, one should increase the thickness of the fused silica film from 300 nm to 2000 nm.

G. L. Klimchitskaya; V. M. Mostepanenko

2014-05-11T23:59:59.000Z

107

Thermal contact conductance of metallic coated superconductor/copper interfaces at cryogenic temperatures  

E-Print Network [OSTI]

of the vapor deposition process when using soft metallic coatings so that the maximum allowable enhancement for a specific coating thickness can be obtained. Also, the temperature dependence for the microhardness of copper was ex- perimentally determined...- sate for the difFerence in layer and substrate thermal conductivities. When applied, the model agreed well with the data obtained in this investigation at low coating thick- ness but overpredicted the data, as the thickness increased. In addition...

Ochterbeck, Jay Matthew

1990-01-01T23:59:59.000Z

108

Thermal stability and oxidation resistance of TiCrAlYO coatings...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications. Thermal stability and oxidation resistance of TiCrAlYO...

109

Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel  

DOE Patents [OSTI]

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor.

Schreiber, Roger B. (Penn Twp., PA); Fero, Arnold H. (New Kensington, PA); Sejvar, James (Murrysville, PA)

1997-01-01T23:59:59.000Z

110

Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel  

DOE Patents [OSTI]

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor. 8 figs.

Schreiber, R.B.; Fero, A.H.; Sejvar, J.

1997-12-16T23:59:59.000Z

111

Chemical and mechanical consequences of environmental barrier coating exposure to calcium-magnesium-aluminosilicate.  

SciTech Connect (OSTI)

The success of Si-based ceramics as high-temperature structural materials for gas turbine applications relies on the use of environmental barrier coatings (EBCs) with low silica activity, such as Ba{sub 1-x}Sr{sub x}Al{sub 2}Si{sub 2}O{sub 8} (BSAS), which protect the underlying components from oxidation and corrosion in combustion environments containing water vapor. One of the current challenges concerning EBC lifetime is the effect of sandy deposits of calcium-magnesium-aluminosilicate (CMAS) glass that melt during engine operation and react with the EBC, changing both its composition and stress state. In this work, we study the effect of CMAS exposure at 1300 C on the residual stress state and composition in BSAS-mullite-Si-SiC multilayers. Residual stresses were measured in BSAS multilayers exposed to CMAS for different times using high-energy X-ray diffraction. Their microstructure was studied using a combination of scanning electron microscopy and transmission electron microscopy techniques. Our results show that CMAS dissolves the BSAS topcoat preferentially through the grain boundaries, dislodging the grains and changing the residual stress state in the topcoat to a nonuniform and increasingly compressive stress state with increasing exposure time. The presence of CMAS accelerates the hexacelsian-to-celsian phase transformation kinetics in BSAS, which reacts with the glass by a solution-reprecipitation mechanism. Precipitates have crystallographic structures consistent with Ca-doped celsian and Ba-doped anorthite.

Harder, B.; Ramirez-Rico, J.; Almer, J. D.; Kang, L.; Faber, K. (X-Ray Science Division); (NASA Glenn Research Center); (Univ. of Seville); (Rolls-Royce Corp.); (Northwestern Univ.)

2011-06-01T23:59:59.000Z

112

P-28 / D. R. Cairns P-28: The Effect of Thermal Shrinkage on Indium Tin Oxide Coated  

E-Print Network [OSTI]

P-28 / D. R. Cairns P-28: The Effect of Thermal Shrinkage on Indium Tin Oxide Coated Polyethylene Tin Oxide (ITO) coated Polyethylene Terephthalate (PET) for flexible display applications

Cairns, Darran

113

Iron-Based Amorphous Coatings Produced by HVOF Thermal Spray Processing-Coating Structure and Properties  

SciTech Connect (OSTI)

The feasibility to coat large SNF/HLW containers with a structurally amorphous material (SAM) was demonstrated on sub-scale models fabricated from Type 316L stainless steel. The sub-scale model were coated with SAM 1651 material using kerosene high velocity oxygen fuel (HVOF) torch to thicknesses ranging from 1 mm to 2 mm. The process parameters such as standoff distance, oxygen flow, and kerosene flow, were optimized in order to improve the corrosion properties of the coatings. Testing in an electrochemical cell and long-term exposure to a salt spray environment were used to guide the selection of process parameters.

Beardsley, M B

2008-03-26T23:59:59.000Z

114

Improvement of Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn2O4  

E-Print Network [OSTI]

thermal stability of the Li-ion battery. CONCLUSIONS CoatingPDDA. EC- AFM studies on Li-ion battery electrodes offered

Stroeve, Pieter; Vidu, Ruxandra

2004-01-01T23:59:59.000Z

115

Gaseous modification of MCrAlY coatings  

DOE Patents [OSTI]

The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

2000-01-01T23:59:59.000Z

116

Coating of a stainless steel tube-wall catalytic reactor with thermally treated polysiloxane thick films  

E-Print Network [OSTI]

Coating of a stainless steel tube-wall catalytic reactor with thermally treated polysiloxane thick stainless steel by plasma assisted chemical vapour deposition process. Thicknesses up to 10µm were developed glass-like silicon oxide but cannot be related to an amorphous silica structure. At 1273K the steel

Paris-Sud XI, Université de

117

Influence of Microstructure on Residual Thermal Stresses in TiCxN1-x and -Al2O3 Coatings on WC-Co Tool Inserts  

E-Print Network [OSTI]

Influence of Microstructure on Residual Thermal Stresses in TiCxN1-x and -Al2O3 Coatings on WC deposited coatings on four tool inserts have been comprehensively characterized using electron backscatter the residual thermal strains in the coatings. The results indicate that the thermal strains and stored elastic

Rohrer, Gregory S.

118

Stability of nickel-coated sand as gravel-pack material for thermal wells  

SciTech Connect (OSTI)

Laboratory flow tests have been carried out to study the stability of various nickel-coated sands under aqueous steam temperature and pH conditions that may exist in thermal recovery operations. Other gravel-pack materials tested include Ottawa sand, sintered bauxite, cement clinker, zirconium oxide, and nickel pellets. A comparison was made between the performances of these materials after exposure to identical thermal and hydrolytic conditions. Test results indicate that nickel-coated sands are highly resistant to dissolution at temperatures as high as 300/sup 0/C (570/sup 0/F) and to solution pH's from 4.75 to 11. Weight losses measured after a 72-hour period were less than 1%. In contrast, weight losses from sintered bauxite, zirconium oxide, and Ottawa sand dissolution tests were 30 to 70 times higher under the same conditions. Cement clinker losses were in the intermediate range under alkaline conditions. API standard crushing and acid-solubility tests for proppants also were performed on nickel-coated sands. These results were favorable in that they exceeded the recommended standards. This study of nickel-coated sand stability and mechanical strength has demonstrated its high potential for application as either a gravel-pack material or proppant in thermal recovery operations.

Sacuta, A.; Nguyen, D.M.; Kissel, G.A. (Alberta Research Council (CA))

1988-11-01T23:59:59.000Z

119

Preparation of high temperature superconducting coated wires by dipping and post annealing  

SciTech Connect (OSTI)

This patent describes a process for coating a film on a wire substrate, it comprises: melting a superconducting metal oxide mixture in a crucible to form a melt; coating the substrate with a diffusion barrier; dipping the coated wire substrate into the melt; cooling the coated wire substrate at a rate sufficiently slow to avoid thermal shock and hot cracking; and post-annealing the cooled, coated wire substrate to relieve thermal stresses in the coating, whereupon the superconducting metal-oxide mixture forms a perovskite coating upon the wire substrate.

Provenzano, V.; Singh, A.K.; Imam, M.A.; Tritt, T.M.

1992-04-14T23:59:59.000Z

120

Thermal stability and adhesion of low-emissivity electroplated Au coatings.  

SciTech Connect (OSTI)

We are developing a low-emissivity thermal management coating system to minimize radiative heat losses under a high-vacuum environment. Good adhesion, low outgassing, and good thermal stability of the coating material are essential elements for a long-life, reliable thermal management device. The system of electroplated Au coating on the adhesion-enhancing Wood's Ni strike and 304L substrate was selected due to its low emissivity and low surface chemical reactivity. The physical and chemical properties, interface bonding, thermal aging, and compatibility of the above Au/Ni/304L system were examined extensively. The study shows that the as-plated electroplated Au and Ni samples contain submicron columnar grains, stringers of nanopores, and/or H{sub 2} gas bubbles, as expected. The grain structure of Au and Ni are thermally stable up to 250 C for 63 days. The interface bonding is strong, which can be attributed to good mechanical locking among the Au, the 304L, and the porous Ni strike. However, thermal instability of the nanopore structure (i.e., pore coalescence and coarsening due to vacancy and/or entrapped gaseous phase diffusion) and Ni diffusion were observed. In addition, the study also found that prebaking 304L in the furnace at {ge} 1 x 10{sup -4} Torr promotes surface Cr-oxides on the 304L surface, which reduces the effectiveness of the intended H-removal. The extent of the pore coalescence and coarsening and their effect on the long-term system integrity and outgassing are yet to be understood. Mitigating system outgassing and improving Au adhesion require a further understanding of the process-structure-system performance relationships within the electroplated Au/Ni/304L system.

Jorenby, Jeff W.; Hachman, John T., Jr.; Yang, Nancy Y. C.; Chames, Jeffrey M.; Clift, W. Miles

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Thermal heat radiation, near-field energy density and near-field radiative heat transfer of coated materials  

E-Print Network [OSTI]

We investigate the thermal radiation and thermal near-field energy density of a metal-coated semi-infinite body for different substrates. We show that the surface polariton coupling within the metal coating leads to an enhancement of the TM-mode part of the thermal near-field energy density when a polar substrate is used. In this case the result obtained for a free standing metal film is retrieved. In contrast, in the case of a metal substrate there is no enhancement in the TM-mode part, as can also be explained within the framework of surface plasmon coupling within the coating. Finally, we discuss the influence of the enhanced thermal energy density on the near-field radiative heat transfer between a simple semi-infinite and a coated semi-infinite body for different material combinations.

Svend-Age Biehs

2011-03-15T23:59:59.000Z

122

Aluminide coatings  

DOE Patents [OSTI]

Disclosed herein are aluminide coatings. In one embodiment coatings are used as a barrier coating to protect a metal substrate, such as a steel or a superalloy, from various chemical environments, including oxidizing, reducing and/or sulfidizing conditions. In addition, the disclosed coatings can be used, for example, to prevent the substantial diffusion of various elements, such as chromium, at elevated service temperatures. Related methods for preparing protective coatings on metal substrates are also described.

Henager, Jr; Charles, H [Kennewick, WA; Shin, Yongsoon [Richland, WA; Samuels, William D [Richland, WA

2009-08-18T23:59:59.000Z

123

Analysis of the Window Side Thermal Environment Formed by Air Barrier Technique in Winter Conditions and Its Economy  

E-Print Network [OSTI]

the energy-saving potential and thermal comfort of the air barrier technique used in office buildings. It also analyzes the surface temperature of the window by using the simulation software Airpak. According to the results, we can obtain the key control...

Huang, C.; Jia, Y.; Liu, L.; Wang, X.

2006-01-01T23:59:59.000Z

124

Continental Scientific Drilling (CSD): Technology Barriers to Deep Drilling Studies in Thermal Regimes  

SciTech Connect (OSTI)

This report is the proceedings of a workshop. The primary thrust of these discussion was to identify the major key technology barriers to the Department of Energy (DOE) supported Thermal Regimes CSD projects and to set priorities for research and development. The major technological challenge is the high temperature to be encountered at depth. Specific problems derived from this issue were widely recognized among the participants and are reflected in this summary. A major concern for the projected Thermal Regimes CSD boreholes was the technology required for continuous coring, in contrast to that required for drilling without core or spot coring. Current commercial technology bases for these two techniques are quite different. The DOE has successfully fielded projects that used both technologies, i.e, shallow continuous coring (Inyo Domes and Valles Caldera) and deeper drilling with spot cores (Imperial Valley-SSSDP). It was concluded that future scientific objectives may still require both approaches, but continuous coring is the most likely requirement in the near term. (DJE-2005)

Kolstad, George A.; Rowley, John C.

1987-01-16T23:59:59.000Z

125

Thermally Induced Stresses in Functionally Graded Thick Tubes  

E-Print Network [OSTI]

thermal barrier coating for high temperature applications, a discrete layer of ceramic material is bondedThermally Induced Stresses in Functionally Graded Thick Tubes Senthil S. Vel and Rajeev Baskiyar method to obtain the temperature, displacements and thermal stresses. In addition to the thermal

Vel, Senthil

126

Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof  

DOE Patents [OSTI]

An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications is disclosed. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al[sub x]N[sub y]O[sub z] layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al[sub x]N[sub y]O[sub z] layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

Sarin, V.K.

1990-08-21T23:59:59.000Z

127

Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof  

DOE Patents [OSTI]

An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al.sub.x N.sub.y O.sub.z layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al.sub.x N.sub.y O.sub.z layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

Sarin, Vinod K. (Lexington, MA)

1990-01-01T23:59:59.000Z

128

Salt spray testing of sacrificial and barrier type coatings for the purpose of finding a corrosion resistant and environmentally acceptable replacement for cadmium plate  

SciTech Connect (OSTI)

Cadmium plate is used to protect various components of offshore oil and gas production equipment from surface marine environments such as salt spray. This research project was performed to find an environmentally acceptable coating which provides equivalent or superior resistance to surface marine corrosion when compared to cadmium plate. In order to find a replacement for cadmium plate, a large number of sacrificial and barrier type coatings were exposed to an accelerated salt spray test in accordance with ASTM B117-94. The only sacrificial coating which resisted 1,000 hours of accelerated salt spray testing without any indication of failure was the 0.0006-in. thick zinc-nickel plate with an olive drab chromate treatment. Based on these test results, zinc-nickel plate is recommended as a corrosion resistant and environmentally acceptable replacement for cadmium plate for use in surface marine environments. Electroless nickel coatings with a minimum applied thickness of 0.002-in. also resisted 1,000 hours of accelerated salt spray testing without indication of failure. Electroless nickel is not recommended for corrosion resistance in salt spray environments for two reasons. Electroless nickel is susceptible to microcracking when heat treated at moderate to high temperatures. Heat treatment improves the hardness and resultant wear resistance of the coating. Microcracking will compromise the integrity of the coating resulting in pitting, cracking or crevice corrosion of the substrate in corrosive environments. Secondly, any significant mechanical damage to the coating or disbonding of the coating substrate interface will also result in corrosive attack of the substrate.

Schultz, E.J.; Haeberle, T.

1996-12-31T23:59:59.000Z

129

In situ control of lubricant properties for reduction of power cylinder friction through thermal barrier coating  

E-Print Network [OSTI]

Lowering lubricant viscosity to reduce friction generally carries a side effect of increased metal-metal contact in mixed or boundary lubrication, for example near top ring reversal along the engine cylinder liner. A ...

Molewyk, Mark Allen

2014-01-01T23:59:59.000Z

130

Model Studies of Pore Stability and Evolution in Thermal Barrier Coatings (TBCs)  

E-Print Network [OSTI]

cavities. Solid- state diffusion bonding conditions werewere internalized by diffusion bonding the etched faces toion beam etching and diffusion bonding. Figure 9 shows a

Glaeser, A M

2008-01-01T23:59:59.000Z

131

Corrosion and wear resistance of tungsten carbide-cobalt and tungsten carbide-cobalt-chromium thermal spray coatings  

SciTech Connect (OSTI)

Tungsten carbide thermal spray coatings provide wear surfaces to new and overhauled components for various industries. Their wear resistance is obtained by incorporating small tungsten carbide particles into a metal matrix. This presentation will show what parameters influence their corrosion resistance in the ASTM B-117 Salt Spray Corrosion Test,

Quets, J.; Alford, J.R.

1999-07-01T23:59:59.000Z

132

Environmental barrier coating  

SciTech Connect (OSTI)

The present invention relates generally to a multi-layered article suitable for service in severe environments. The article may be formed of a substrate, such as silicon carbide and/or silicon nitride. The substrate may have a first layer of a mixture of a rare earth silicate and Cordierite. The substrate may also have a second layer of a rare earth silicate or a mixture of a rare earth silicate and cordierite.

Pujari, Vimal K.; Vartabedian, Ara; Collins, William T.; Woolley, David; Bateman, Charles

2012-12-18T23:59:59.000Z

133

Stress-Relaxation and Creep Behavior of Heat-Treated Stand-Alone Plasma-Sprayed 7 wt.% Y2O3-ZrO2 Coatings  

E-Print Network [OSTI]

Thermal barrier coatings have significantly increased the working efficiency of turbine engine and diesel the stock powder into high velocity arc plasma, which melts the powder while propelling it toward

Trice, Rodney W.

134

Gas seal for an in situ oil shale retort and method of forming thermal barrier  

DOE Patents [OSTI]

A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

Burton, III, Robert S. (Mesa, CO)

1982-01-01T23:59:59.000Z

135

Modification of petroleum-bitumen anticorrosion coatings aimed at improvement of their thermal resistance  

SciTech Connect (OSTI)

We develop petroleum-bitumen coatings modified by mineral fillers and epoxy resins, give experimental demonstration of the improvement of mechanical, thermophysical, and anticorrosion properties of mastics and reinforced coatings obtained on their basis, and outline the areas of possible use of these coatings.

Nironovych, I.O.; Suprun, V.V.; Tselyukh, O.I. [Karpenko Physicomechanical Institute, L`viv (Ukraine)] [and others

1994-11-01T23:59:59.000Z

136

High efficiency turbine blade coatings.  

SciTech Connect (OSTI)

The development of advanced thermal barrier coatings (TBCs) of yttria stabilized zirconia (YSZ) that exhibit lower thermal conductivity through better control of electron beam - physical vapor deposition (EB-PVD) processing is of prime interest to both the aerospace and power industries. This report summarizes the work performed under a two-year Lab-Directed Research and Development (LDRD) project (38664) to produce lower thermal conductivity, graded-layer thermal barrier coatings for turbine blades in an effort to increase the efficiency of high temperature gas turbines. This project was sponsored by the Nuclear Fuel Cycle Investment Area. Therefore, particular importance was given to the processing of the large blades required for industrial gas turbines proposed for use in the Brayton cycle of nuclear plants powered by high temperature gas-cooled reactors (HTGRs). During this modest (~1 full-time equivalent (FTE)) project, the processing technology was developed to create graded TBCs by coupling ion beam-assisted deposition (IBAD) with substrate pivoting in the alumina-YSZ system. The Electron Beam - 1200 kW (EB-1200) PVD system was used to deposit a variety of TBC coatings with micron layered microstructures and reduced thermal conductivity below 1.5 W/m.K. The use of IBAD produced fully stoichiometric coatings at a reduced substrate temperature of 600 oC and a reduced oxygen background pressure of 0.1 Pa. IBAD was also used to successfully demonstrate the transitioning of amorphous PVD-deposited alumina to the -phase alumina required as an oxygen diffusion barrier and for good adhesion to the substrate Ni2Al3 bondcoat. This process replaces the time consuming thermally grown oxide formation required before the YSZ deposition. In addition to the process technology, Direct Simulation Monte Carlo plume modeling and spectroscopic characterization of the PVD plumes were performed. The project consisted of five tasks. These included the production of layered periodic microstructures in the coating, the Direct Simulation Monte Carlo (DSMC) modeling of particle transport in the PVD plume, functional graded layer development, the deposition of all layers to form a complete coating, and materials characterization including thermal testing. Ion beam-assisted deposition, beam sharing through advanced digital rastering, substrate pivoting, hearth calorimetry, infrared imaging, fiber optic-enabled optical emission spectroscopy and careful thermal management were used to achieve all the milestones outlined in the FY02 LDRD proposal.

Youchison, Dennis L.; Gallis, Michail A.

2014-06-01T23:59:59.000Z

137

Ceramic plasma-sprayed coating of melting crucibles for casting metal fuel slugs  

SciTech Connect (OSTI)

Thermal cycling and melt reaction studies of ceramic coatings plasma-sprayed on Nb substrates were carried out to evaluate the performance of barrier coatings for metallic fuel casting applications. Thermal cycling tests of the ceramic plasma-sprayed coatings to 1450 degrees C showed that HfN, TiC, ZrC, and Y2O3 coating had good cycling characteristics with few interconnected cracks even after 20 cycles. Interaction studies by 1550 degrees C melt dipping tests of the plasma-sprayed coatings also indicated that HfN and Y2O3 do not form significant reaction layer between U–20 wt.% Zr melt and the coating layer. Plasma-sprayed Y2O3 coating exhibited the most promising characteristics among HfN, TiC, ZrC, and Y2O3 coating.

K.H. Kim; C.T. Lee; C.B. Lee; R.S. Fielding; J.R. Kennedy

2013-10-01T23:59:59.000Z

138

Thermal Degradation Of Ceramic Interfaces Emily A. Asche, Emily A. Carter  

E-Print Network [OSTI]

Thermal Degradation Of Ceramic Interfaces Emily A. Asche, Emily A. Carter I n order to achieve between this ceramic and the underlying engine superalloy. Unfortunately, with repeated thermal cycling the melting temperature of the engine metal alloy. To realize this goal, a Thermal Barrier Coating (TBC

Carter, Emily A.

139

Thermal input control and enhancement for laser based residual stress measurements using liquid temperature indicating coatings  

DOE Patents [OSTI]

An improved method for measuring residual stress in a material is disclosed comprising the steps of applying a spot of temperature indicating coating to the surface to be studied, establishing a speckle pattern surrounds the spot of coating with a first laser then heating the spot of coating with a far infrared laser until the surface plastically deforms. Comparing the speckle patterns before and after deformation by subtracting one pattern from the other will produce a fringe pattern that serves as a visual and quantitative indication of the degree to which the plasticized surface responded to the stress during heating and enables calculation of the stress. 3 figs.

Pechersky, M.J.

1999-07-06T23:59:59.000Z

140

Thermal input control and enhancement for laser based residual stress measurements using liquid temperature indicating coatings  

DOE Patents [OSTI]

An improved method for measuring residual stress in a material comprising the steps of applying a spot of temperature indicating coating to the surface to be studied, establishing a speckle pattern surrounds the spot of coating with a first laser then heating the spot of coating with a far infrared laser until the surface plastically deforms. Comparing the speckle patterns before and after deformation by subtracting one pattern from the other will produce a fringe pattern that serves as a visual and quantitative indication of the degree to which the plasticized surface responded to the stress during heating and enables calculation of the stress.

Pechersky, Martin J. (Aiken, SC)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Materials Science and Engineering A369 (2004) 124137 Studies of the microstructure and properties of dense ceramic coatings  

E-Print Network [OSTI]

for wear resistance and zirconia-based materials for ther- mal barrier coatings [1­4]. The high temperature (enthalpy) availability within the thermal plasma enables melting, relatively high-velocity delivery applications. The advent of high velocity oxygen-fuel (HVOF) thermal spray has made a significant impact

New York at Stoney Brook, State University of

142

Final Technical Report - Recovery Act: Organic Coatings as Encapsulants for Low Cost, High Performance PV Modules  

SciTech Connect (OSTI)

The objective of this project was to evaluate the feasibility of utilizing PPG's commercial organic coatings systems as efficient, modernized encapsulants for low cost, high performance, thin film photovoltaic modules. Our hypothesis was that the combination of an anticorrosive coating with a more traditional barrier topcoat would mitigate many electrochemical processes that are now responsible for the significant portion of photovoltaic (PV) failures, thereby nullifying the extremely high moisture barrier requirements of currently used encapsulation technology. Nine commercially available metal primer coatings and six commercially available top coatings were selected for screening. Twenty-one different primer/top coat combinations were evaluated. The primer coatings were shown to be the major contributor to corrosion inhibition, adhesion, and barrier properties. Two primer coatings and one top coating were downselected for testing on specially-fabricated test modules. The coated test modules passed initial current leakage and insulation testing. Damp Heat testing of control modules showed visible corrosion to the bus bar metal, whereas the coated modules showed none. One of the primer/top coat combinations retained solar power performance after Damp Heat testing despite showing some delamination at the EVA/solar cell interface. Thermal Cycling and Humidity Freeze testing resulted in only one test module retaining its power performance. Failure modes depended on the particular primer/top coating combination used. Overall, this study demonstrated that a relatively thin primer/top coating has the potential to replace the potting film and backsheet in crystalline silicon-based photovoltaic modules. Positive signals were received from commercially available coatings developed for applications having performance requirements different from those required for photovoltaic modules. It is likely that future work to redesign and customize these coatings would result in a coating system meeting the requirements for photovoltaic module encapsulation.

Stuart Hellring; Jiping Shao; James Poole

2011-12-05T23:59:59.000Z

143

Oxidation of Metals, Vol. 61, Nos. 3/4, April 2004 ( 2004) Thermal Conductivity, Phase Stability, and Oxidation  

E-Print Network [OSTI]

, and Oxidation Resistance of Y3Al5O12 (YAG)/Y2O3­ZrO2 (YSZ) Thermal-Barrier Coatings Y. J. Su, R. W. Trice,# K oxidation resistance while maintaining low thermal conductivity and good phase stability. Padture) is proposed. The objective of this work is to quantify the effect of YAG on thermal resistance, long

Trice, Rodney W.

144

Effect of metallic coatings on the thermal contact conductance of turned surfaces  

E-Print Network [OSTI]

area. . IInfortunately this is not always possible, due to design or load restrictions In situations where the applied load is limited. the thermal contact resistance can be reduced by introducing a material at the interface that is relatively sof... materials on thermal contact resistance both analytically and experimen- tally for a. fixed geometry and material. In the analytical portion, the approximate relative reduction of the thermal contact resistance due to plating was described as ~plating (u...

Kang, Tik Kwie

2012-06-07T23:59:59.000Z

145

E-Print Network 3.0 - amorphous-metal thermal-spray coatings...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The thermophysical parameters of thermal... to determine the thickness of tungsten carbide and ... Source: Mandelis, Andreas - Department of Electrical and Computer...

146

Measurement of Thermal Conductivity of PbTe Nanocrystal Coated Glass Fibers by the 3 Method  

E-Print Network [OSTI]

and high aspect ratio result in a significant thermal radiation effect. We simulate the experiment using such as automobile exhaust pipes, power plant steam pipes, manufacturing industry cooling pipes, and so forth. Our the radiation effect and extract the thermal conductivity at the single fiber level. Our simulation method

Ruan, Xiulin

147

Thermal Stability and Aging Characteristics of Chromate Conversion Coatings on Aluminum Alloy 2024-T3  

SciTech Connect (OSTI)

XANES and electrochemical impedance spectroscopes were used in parallel to correlate the amount of Cr(VI) in chromate conversion coatings (CCC) on Al 2024 and their corrosion resistance in order to understand the degradation mechanisms upon aging or heating. Cr(VI) species appear to be immobilized for temperatures higher than 80 C due to dehydration. CCC are shown to be dynamic in the first month of aging with no significant dehydration. Another degradation mechanism involving chemical changes is to be considered.

Laget, V.; Jeffcoate, C.; Isaacs, H. S.; Buchheit, R. G.

1999-10-17T23:59:59.000Z

148

Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical report, January 14, 1997--August 14, 1997  

SciTech Connect (OSTI)

Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. Bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. Also, to deposit model Ni-Al{sub 2}O{sub 3} coatings, an electrodeposition technique was developed and coatings with various volume fractions (0-35%) of Al{sub 2}O{sub 3} were produced. The powder and electrodeposition processing of Ni-Al{sub 2}O{sub 3} Composites provide the ability to produce two phase microstructure without changing the microstructure of the matrix material. Therefore, the effect of hard second phase particles size and volume fraction on erosion resistance could be analyzed.

Schorr, B.S.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

1997-08-31T23:59:59.000Z

149

Compositions of corrosion-resistant Fe-based amorphous metals suitable for producing thermal spray coatings  

DOE Patents [OSTI]

A method of coating a surface comprising providing a source of amorphous metal that contains manganese (1 to 3 atomic %), yttrium (0.1 to 10 atomic %), and silicon (0.3 to 3.1 atomic %) in the range of composition given in parentheses; and that contains the following elements in the specified range of composition given in parentheses: chromium (15 to 20 atomic %), molybdenum (2 to 15 atomic %), tungsten (1 to 3 atomic %), boron (5 to 16 atomic %), carbon (3 to 16 atomic %), and the balance iron; and applying said amorphous metal to the surface by a spray.

Farmer, Joseph C.; Wong, Frank M. G.; Haslam, Jeffery J.; Ji, Xiaoyan (Jane); Day, Sumner D.; Blue, Craig A.; Rivard, John D. K.; Aprigliano, Louis F.; Kohler, Leslie K.; Bayles, Robert; Lemieux, Edward J.; Yang, Nancy; Perepezko, John H.; Kaufman, Larry; Heuer, Arthur; Lavernia, Enrique J.

2013-07-09T23:59:59.000Z

150

Compositions of corrosion-resistant Fe-based amorphous metals suitable for producing thermal spray coatings  

DOE Patents [OSTI]

A method of coating a surface comprising providing a source of amorphous metal that contains manganese (1 to 3 atomic %), yttrium (0.1 to 10 atomic %), and silicon (0.3 to 3.1 atomic %) in the range of composition given in parentheses; and that contains the following elements in the specified range of composition given in parentheses: chromium (15 to 20 atomic %), molybdenum (2 to 15 atomic %), tungsten (1 to 3 atomic %), boron (5 to 16 atomic %), carbon (3 to 16 atomic %), and the balance iron; and applying said amorphous metal to the surface by a spray.

Farmer, Joseph C; Wong, Frank M.G.; Haslam, Jeffery J; Ji, Xiaoyan; Day, Sumner D; Blue, Craig A; Rivard, John D.K.; Aprigliano, Louis F; Kohler, Leslie K; Bayles, Robert; Lemieux, Edward J; Yang, Nancy; Perepezko, John H; Kaufman, Larry; Heuer, Arthur; Lavernia, Enrique J

2013-09-03T23:59:59.000Z

151

Determination of the recombination efficiency of thermal control coatings for hypersonic vehicles  

SciTech Connect (OSTI)

A method is presented for determining the recombination efficiency of coatings for hypersonic vehicle applications. The approach uses experimental results from arc-jet tests with an analysis to determine the efficiency for the recombination of atomic species present in the boundary layer. The analysis employs analytical solutions to the laminar boundary-layer heat-transfer equations with experimental heating-rate, temperature, and pressure measurements. The authors discuss experimental difficulties in achieving reliable materials-performance data. The utility of the method is that it provides a rapid and efficient tool for use in qualitative screening and development of materials. The effects of second-order heat-transfer terms may be as high as 50% for low-catalysis surfaces. With the second-order terms included, the maximum uncertainty in recombination-efficiency data for low-catalysis surfaces is 45%. The discussions are based on experimental data and calculations for arc-jet tests of the titanium alloy Ti-14Al-21Nb with a borosilicate-like glass coating that has a recombination efficiency of about 0.006 to 0.01. 20 refs.

Clark, R.K.; Cunnington, G.R. Jr.; Wiedemann, K.E. [National Aeronautics and Space Administration, Langley Research Center, Hampton, VA (United States)

1995-01-01T23:59:59.000Z

152

MATERIALS AND MOLECULAR RESEARCH DIVISION. ANNUAL REPORT 1981  

E-Print Network [OSTI]

types and forms of ceramic thermal barrier coatings andfatigue resist­ ance of ceramic thermal barrier coatings byoverlay coatings, and ceramic or thermal barrier coatings.

Authors, Various

2010-01-01T23:59:59.000Z

153

Stability of Self-Assembled Monolayer Surfactant Coating in Thermal Nanoimprint  

E-Print Network [OSTI]

Figure 1.3 10nm PMMA pits ................................................................................... 11 Figure 2.1 Thermal nanoimprint ............................................................................. 13 Figure 2... Figure 4.4 Binding energy spectra of OTS before (blue) and after (red) anneal for O1s ....................................................................... 21 Figure 4.5 XPS spectra of C1s for OTS after PMMA nanoimprint for 30...

Lunsford, Patrick

2012-02-14T23:59:59.000Z

154

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2003-10-14T23:59:59.000Z

155

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2004-08-31T23:59:59.000Z

156

High Temperature Thermal Stability and Oxidation Resistance of Magnetron-sputtered Homogeneous CrAlON Coatings on 430 Steel  

SciTech Connect (OSTI)

The requirements of low cost and high-temperature corrosion resistance for bipolar interconnect plates in solid oxide fuel cell stacks has directed attention to the use of metal plates with oxidation resistant coatings. We have investigated the performance of steel plates with homogenous coatings of CrAlON (oxynitrides). The coatings were deposited using RF magnetron sputtering, with Ar as a sputtering gas. Oxygen in these coatings was not intentionally added. Oxygen might have come through contaminated nitrogen gas bottle, leak in the chamber or from the partial pressure of water vapors. Nitrogen was added during the growth process to get oxynitride coating. The Cr/Al composition ratio in the coatings was varied in a combinatorial approach. The coatings were subsequently annealed in air for up to 25 hours at 800 deg. C. The composition of the coated plates and the rate of oxidation were characterized using Rutherford backscattering (RBS) and nuclear reaction analysis (NRA). From our results, we conclude that Al rich coatings are more susceptible to oxidation than Cr rich coatings.

Kayani, A.; Wickey, K. J.; Nandasiri, M. I.; Moore, A.; Garratt, E.; AlFaify, S.; Gao, X. [Western Michigan University-Kalamazoo, MI 49008 (United States); Smith, R. J.; Buchanan, T. L.; Priyantha, W.; Kopczyk, M.; Gannon, P. E. [Montana State University-Bozeman, MT 59717 (United States); Gorokhovsky, V. I. [Arcomac Surface Engineering, LLC-Bozeman, MT 59715 (United States)

2009-03-10T23:59:59.000Z

157

The Radial Loss of Ions Trapped in the Thermal Barrier Potential and the Design of Divertor Magnetic Field in GAMMA10  

SciTech Connect (OSTI)

The ion radial loss exists in the presence of a non-axisymmetric electrostatic potential in the end-mirror cells of GAMMA10, which leads to a formation of the thermal barrier potential. The non-axisymmetric electrostatic potential can also exist in the central cell. A design for divertor magnetic field of GAMMA10 is performed, the purpose of which is first to reduce an ion radial transport in the central cell by making electrostatic potential circular and second to assure the macroscopic plasma stability of GAMMA10 without help of non-axisymmetric anchor cells which enhances a neoclassical radial transport.

Katanuma, I. [Plasma Research Center, University of Tsukuba (Japan); Ito, T. [Plasma Research Center, University of Tsukuba (Japan); Saimaru, H. [Plasma Research Center, University of Tsukuba (Japan); Sasagawa, Y. [Plasma Research Center, University of Tsukuba (Japan); Pastukhov, V.P. [I.V.Kuruchatov Atomic Energy Institute (Russian Federation); Ishii, K. [Plasma Research Center, University of Tsukuba (Japan); Tatematsu, Y. [Plasma Research Center, University of Tsukuba (Japan); Saito, T. [Plasma Research Center, University of Tsukuba (Japan); Islam, Md.K. [Plasma Research Center, University of Tsukuba (Japan); Nakashima, Y. [Plasma Research Center, University of Tsukuba (Japan); Cho, T. [Plasma Research Center, University of Tsukuba (Japan)

2005-01-15T23:59:59.000Z

158

DEVELOPMENT AND ASSESSMENT OF COATINGS FOR FUTURE POWER GENERATION TURBINES  

SciTech Connect (OSTI)

The NETL-Regional University Alliance (RUA) continues to advance technology development critical to turbine manufacturer efforts for achieving DOE Fossil Energy (FE's) Advanced Turbine Program Goals. In conjunction with NETL, Coatings for Industry (CFI), the University of Pittsburgh, NASA GRC, and Corrosion Control Inc., efforts have been focused on development of composite thermal barrier coating (TBC) architectures that consist of an extreme temperature coating, a commercially applied 7-8 YSZ TBC, a reduced cost bond coat, and a diffusion barrier coating that are applied to nickel-based superalloys or single crystal airfoil substrate materials for use at temperatures >1450 C (> 2640 F). Additionally, construction of a unique, high temperature ({approx}1100 C; {approx}2010 F), bench-scale, micro-indentation, nondestructive (NDE) test facility at West Virginia University (WVU) was completed to experimentally address in-situ changes in TBC stiffness during extended cyclic oxidation exposure of coated single crystal coupons in air or steam containing environments. The efforts and technical accomplishments in these areas are presented in the following sections of this paper.

Alvin, Maryanne; Klotz, K.; McMordie, B.; Gleeson, B.; Zhu, D.; Warnes, B.; Kang, B.; Tannenbaum, J.

2012-01-01T23:59:59.000Z

159

MATERIALS AND MOLECULAR RESEARCH DIVISION. ANNUAL REPORT 1980  

E-Print Network [OSTI]

Characterization of Thermal Barrier Ceramic Coatings . . .stabilized zirconia thermal barrier ceramic coat­ ing wasfor the application of ceramic thermal barrier coatings.

Searcy, Alan W.

2010-01-01T23:59:59.000Z

160

Evaluation of the Thermal Performance for a Wire Mesh/Hollow Glass Microsphere Composite Structure as a Conduction Barrier  

E-Print Network [OSTI]

An experimental investigation exploring the use of wire mesh/hollow glass microsphere combination for use as thermal insulation was conducted with the aim to conclude whether or not it represents a superior insulation technology to those...

Mckenna, Sean

2010-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Evaluate Thermal Spray Coatings  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Develop a pressure seal alternative to conventional elastomerand metal C-rings.

162

Proceedings of the 1987 coatings for advanced heat engines workshop  

SciTech Connect (OSTI)

This Workshop was conducted to enhance communication among those involved in coating development for improved heat engine performance and durability. We were fortunate to have Bill Goward review the steady progress and problems encountered along the way in the use of thermal barrier coatings (TBC) in aircraft gas turbine engines. Navy contractors discussed their work toward the elusive goal of qualifying TBC for turbine airfoil applications. In the diesel community, Caterpillar and Cummins are developing TBC for combustion chamber components as part of the low heat rejection diesel engine concept. The diesel engine TBC work is based on gas turbine technology with a goal of more than twice the thickness used on gas turbine engine components. Adoption of TBC in production for diesel engines could justify a new generation of plasma spray coating equipment. Increasing interests in tribology were evident in this Workshop. Coatings have a significant role in reducing friction and wear under greater mechanical loadings at higher temperatures. The emergence of a high temperature synthetic lubricant could have an enormous impact on diesel engine design and operating conditions. The proven coating processes such as plasma spray, electron-beam physical vapor deposition, sputtering, and chemical vapor deposition have shown enhanced capabilities, particularly with microprocessor controls. Also, the newer coating schemes such as ion implantation and cathodic arc are demonstrating intriguing potential for engine applications. Coatings will play an expanding role in higher efficiency, more durable heat engines.

Not Available

1987-01-01T23:59:59.000Z

163

Coated ceramic breeder materials  

DOE Patents [OSTI]

A breeder material for use in a breeder blanket of a nuclear reactor is disclosed. The breeder material comprises a core material of lithium containing ceramic particles which has been coated with a neutron multiplier such as Be or BeO, which coating has a higher thermal conductivity than the core material.

Tam, Shiu-Wing (Downers Grove, IL); Johnson, Carl E. (Elk Grove, IL)

1987-01-01T23:59:59.000Z

164

Zinc phosphate conversion coatings  

DOE Patents [OSTI]

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

Sugama, Toshifumi (Wading River, NY)

1997-01-01T23:59:59.000Z

165

Zinc phosphate conversion coatings  

DOE Patents [OSTI]

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

Sugama, T.

1997-02-18T23:59:59.000Z

166

Liquid Salts as Media for Process Heat Transfer from VHTR's: Forced Convective Channel Flow Thermal Hydraulics, Materials, and Coating  

SciTech Connect (OSTI)

The goal of this NERI project was to perform research on high temperature fluoride and chloride molten salts towards the long-term goal of using these salts for transferring process heat from high temperature nuclear reactor to operation of hydrogen production and chemical plants. Specifically, the research focuses on corrosion of materials in molten salts, which continues to be one of the most significant challenges in molten salts systems. Based on the earlier work performed at ORNL on salt properties for heat transfer applications, a eutectic fluoride salt FLiNaK (46.5% LiF-11.5%NaF-42.0%KF, mol.%) and a eutectic chloride salt (32%MgCl2-68%KCl, mole %) were selected for this study. Several high temperature candidate Fe-Ni-Cr and Ni-Cr alloys: Hastelloy-N, Hastelloy-X, Haynes-230, Inconel-617, and Incoloy-800H, were exposed to molten FLiNaK with the goal of understanding corrosion mechanisms and ranking these alloys for their suitability for molten fluoride salt heat exchanger and thermal storage applications. The tests were performed at 850��������C for 500 h in sealed graphite crucibles under an argon cover gas. Corrosion was noted to occur predominantly from dealloying of Cr from the alloys, an effect that was particularly pronounced at the grain boundaries Alloy weight-loss due to molten fluoride salt exposure correlated with the initial Cr-content of the alloys, and was consistent with the Cr-content measured in the salts after corrosion tests. The alloys���¢�������� weight-loss was also found to correlate to the concentration of carbon present for the nominally 20% Cr containing alloys, due to the formation of chromium carbide phases at the grain boundaries. Experiments involving molten salt exposures of Incoloy-800H in Incoloy-800H crucibles under an argon cover gas showed a significantly lower corrosion for this alloy than when tested in a graphite crucible. Graphite significantly accelerated alloy corrosion due to the reduction of Cr from solution by graphite and formation on Cr-carbide on the graphite surface. Ni-electroplating dramatically reduced corrosion of alloys, although some diffusion of Fe and Cr were observed occur through the Ni plating. A pyrolytic carbon and SiC (PyC/SiC) CVD coating was also investigated and found to be effective in mitigating corrosion. The KCl-MgCl2 molten salt was less corrosive than FLiNaK fluoride salts for corrosion tests performed at 850oC. Cr dissolution in the molten chloride salt was still observed and consequently Ni-201 and Hastelloy N exhibited the least depth of attack. Grain-boundary engineering (GBE) of Incoloy 800H improved the corrosion resistance (as measured by weight loss and maximum depth of attack) by nearly 50% as compared to the as-received Incoloy 800H sample. Because Cr dissolution is an important mechanism of corrosion, molten salt electrochemistry experiments were initiated. These experiments were performed using anodic stripping voltammetry (ASV). Using this technique, the reduction potential of Cr was determined against a Pt quasi-reference electrode as well as against a Ni(II)-Ni reference electrode in molten FLiNaK at 650 oC. The integrated current increased linearly with Cr-content in the salt, providing for a direct assessment of the Cr concentration in a given salt of unknown Cr concentration. To study heat transfer mechanisms in these molten salts over the forced and mixed convection regimes, a forced convective loop was constructed to measure heat transfer coefficients, friction factors and corrosion rates in different diameter tubes in a vertical up flow configuration in the laminar flow regime. Equipment and instrumentation for the forced convective loop was designed, constructed, and tested. These include a high temperature centrifugal pump, mass flow meter, and differential pressure sensing capabilities to an uncertainty of < 2 Pa. The heat transfer coefficient for the KCl-MgCl2 salt was measured in t

Kumar Sridharan; Mark Anderson; Todd Allen; Michael Corradini

2012-01-30T23:59:59.000Z

167

Ceramic-metallic coatings by electron beam physical vapor deposition (EB-PVD) process  

SciTech Connect (OSTI)

Electron Beam Physical Vapor Deposition (EB-PVD) process is considered to be a technology that has overcome some of the difficulties or problems associated with the chemical vapor deposition (CVD), physical vapor deposition (PVD) and metal spray processes. The EB-PVD process offers many desirable characteristics such as relatively high deposition rates (up to 100-150 {mu}m/minute with an evaporation rate {approx}10-15 Kg/hour,) dense coatings, precise compositional control, columnar and poly-crystalline microstructure, low contamination, and high thermal efficiency. Various metallic and ceramic coatings (oxides, carbides, nitrides) can be deposited at relatively low temperatures. Even elements with low vapor pressure such as molybdenum, tungsten, and carbon are readily evaporated by this process. In addition, EB-PVD is capable of producing multi-layered laminated metallic/ceramic coatings on large components by changing the EB-PVD processing conditions such as ingot composition, part manipulation, and electron beam energy. Attachment of an ion assisted beam source to the EB-PVD offers additional benefits such as dense coatings with improved adhesion. In addition, textured coatings can be obtained that are desirable in many applications such as cutting tools. This laboratory has started a new thrust in the coating area by the EB-PVD process. The microstructure of thermal barrier ceramic coatings (i.e., yttria stabilized zirconia) developed by the EB-PVD process will be presented.

Wolfe, D.E.; Singh, J. [Pennsylvania State Univ., State College, PA (United States)

1995-12-31T23:59:59.000Z

168

Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environment. Semi-annual report, August 14, 1996--January 14, 1997  

SciTech Connect (OSTI)

Research is being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The cermet composites will be produced using powder metallurgy and electrodeposition. Model Ni-Al{sub 2}O{sub 3} cermet coatings with varying alumina fractions were produced. During this period, powder processed and electrodeposited composites were tested in the erosion simulator (Al{sub 2}O{sub 3} erodent, 40 m/s velocity, 90{degree} impact angle) and their relative erosion resistances were determined. It was found that electrodeposited Ni-Al{sub 2}O{sub 3} composites containing small Al{sub 2}O{sub 3} particles (1{mu}m)s showed better erosion resistance than powder processed composites with large Al{sub 2}O{sub 3} particles (12{mu}m). Also, an increase in volume fraction of Al{sub 2}O{sub 3} particles in powder processed alloys led to decreased erosion resistance. For both powder processed and electrodeposited Ni-Al{sub 2}O{sub 3} composites, addition of hard Al{sub 2}O{sub 3} particles did not improve erosion resistance compared with pure Ni.

Levin, B.F.; DuPont, J.N.; Marder, A.R.

1997-02-01T23:59:59.000Z

169

Effects of thermal annealing on the microstructure of sputtered Al{sub 2}O{sub 3} coatings  

SciTech Connect (OSTI)

The morphology and microstructure of Al{sub 2}O{sub 3} thin films deposited by pulsed direct current magnetron sputtering were studied in the as-grown state and after vacuum annealing at 1000 deg. C for 12 h using transmission electron microscopy. For the coating deposited under low ion bombardment conditions, the film consists of small {gamma}- and/or {delta}-Al{sub 2}O{sub 3} grains embedded in an amorphous matrix. The grain size at the region close to the interface to the substrate was much larger than that of the remaining layer. Growth of the {gamma}-Al{sub 2}O{sub 3} phase is promoted during annealing but no transformation to {alpha}-Al{sub 2}O{sub 3} was detected. For high-energetic growth conditions, clear evidence for {gamma}-Al{sub 2}O{sub 3} formation was found in the upper part of the coating with grain size much larger than for low-energetic growth, but the film was predominately amorphous at the interface region. Annealing resulted in the transformation of {gamma}-Al{sub 2}O{sub 3} to {alpha}-Al{sub 2}O{sub 3}, while the mainly amorphous part crystallized to {gamma}-Al{sub 2}O{sub 3}.

Edlmayr, V.; Harzer, T. P.; Hoffmann, R.; Kiener, D.; Scheu, C.; Mitterer, C. [Department of Physical Metallurgy and Materials Testing, University of Leoben, A-8700 Leoben (Austria); Department of Chemistry, Ludwig-Maximilians-University of Munich, D-81377 Munich (Germany); Department of Physical Metallurgy and Materials Testing, University of Leoben, A-8700 Leoben (Austria)

2011-07-15T23:59:59.000Z

170

Isothermal and thermal cycling oxidation of hot-dip aluminide coating on flake/spheroidal graphite cast iron  

E-Print Network [OSTI]

as engineering materials in high temperature applications, such as furnace parts, turbocharger housings and exhaust manifolds that require high-temperature oxidation resistance and mechanical strength [1 been aluminized by hot-dipping, and then their oxidation and thermal fatigue resistance were evaluated

Volinsky, Alex A.

171

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: Combined stability in isothermal ageing and thermal cycling with YSZ coated ferritic stainless steels  

SciTech Connect (OSTI)

An alkali-containing silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel cell (SOFC) applications. The glass contains about 17 mole% alkalis (K+Na) and has low glass transition and softening temperatures. It remains vitreous and compliant around 750-800oC after sealing without substantial crystallization, as contrary to conventional glass-ceramic sealants, which experience rapid crystallization after the sealing process. The glassy nature and low characteristic temperatures can reduce residual stresses and result in the potential for crack healing. In a previous study, the glass was found to have good thermal cycle stability and was chemically compatible with YSZ coating during short term testing. In the current study, the compliant glass was further evaluated in a more realistic way in that the sealed glass couples were first isothermally aged for 1000h followed by thermal cycling. High temperature leakage was measured. The chemical compatibility was also investigated with powder mixtures at 700 and 800oC to enhance potential interfacial reaction. In addition, interfacial microstructure was examined with scanning electron microscopy and evaluated with regard to the leakage and chemical compatibility results.

Chou, Y. S.; Thomsen, Edwin C.; Choi, Jung-Pyung; Stevenson, Jeffry W.

2012-01-01T23:59:59.000Z

172

Micro heat barrier  

DOE Patents [OSTI]

A highly effective, micron-scale micro heat barrier structure and process for manufacturing a micro heat barrier based on semiconductor and/or MEMS fabrication techniques. The micro heat barrier has an array of non-metallic, freestanding microsupports with a height less than 100 microns, attached to a substrate. An infrared reflective membrane (e.g., 1 micron gold) can be supported by the array of microsupports to provide radiation shielding. The micro heat barrier can be evacuated to eliminate gas phase heat conduction and convection. Semi-isotropic, reactive ion plasma etching can be used to create a microspike having a cusp-like shape with a sharp, pointed tip (<0.1 micron), to minimize the tip's contact area. A heat source can be placed directly on the microspikes. The micro heat barrier can have an apparent thermal conductivity in the range of 10.sup.-6 to 10.sup.-7 W/m-K. Multiple layers of reflective membranes can be used to increase thermal resistance.

Marshall, Albert C.; Kravitz, Stanley H.; Tigges, Chris P.; Vawter, Gregory A.

2003-08-12T23:59:59.000Z

173

Development of nondestructive evaluation methods for ceramic coatings.  

SciTech Connect (OSTI)

Various nondestructive evaluation (NDE) technologies are being developed to study the use of ceramic coatings on components in the hot-gas path of advanced low-emission gas-fired turbines. The types of ceramic coatings include thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs). TBCs are under development for vanes, blades, and combustor liners to allow hotter gas-path temperatures, and EBCs are under development to reduce environmental damage to high-temperature components made of ceramic matrix composites. The NDE methods will be used to (a) provide data to assess the reliability of new coating application processes, (b) identify defective components that could cause unscheduled outages, (c) track growth rates of defects during component use in engines, and (d) allow rational judgment for replace/repair/re-use decisions regarding components. Advances in TBC application, both electron beam-physical vapor deposition (EB-PVD) and air plasma spraying (APS), are allowing higher temperatures in the hot-gas path. However, as TBCs become ''prime reliant,'' their condition at scheduled or unscheduled outages must be known. NDE methods are under development to assess the condition of the TBC for pre-spall conditions. EB-PVD test samples with up to 70 thermal cycles have been studied by a newly developed method involving polarized laser back-scatter NDE. Results suggest a correlation between the NDE laser data and the TBC/bond-coat topography. This finding is important because several theories directed toward understanding the pre-spall condition suggest that the topography in the thermally grown oxide layer changes significantly as a function of the number of thermal cycles. Tests have also been conducted with this NDE method on APS TBCs. Results suggest that the pre-spall condition is detected for these coatings. One-sided, high-speed thermal imaging also has shown promise for NDE of APS coatings. Testing of SiC/SiC composites for combustor liners has demonstrated that environmental EBCs are required to reduce oxidation-induced recession rates. NDE technologies, primarily one-sided and through-thickness thermal imaging, are under development to detect delaminations and degradation of EBCs. Recent results have demonstrated that NDE thermal image data correctly detected pre-spall regions of a barium-strontium-alumino-silicate coating on melt-infiltrated SiC/SiC. The NDE data were verified with field test data from a combustor liner in a 4.5 MW(e) natural-gas-fired turbine. The shape of the spalled EBC region and the growth of the spalled EBC region after various engine run times were correlated with boroscope image data from field tests. An effort has recently been started to address NDE development for oxide/oxide ceramic composites with an EBC. We will discuss the NDE methods under development for TBCs, recent NDE test results from thermally cycled TBCs, NDE results from EBCs on SiC/SiC, and the new effort directed toward oxide/oxide materials.

Ellingson, W. A.; Deemer, C.; Sun, J. G.; Erdman, S.; Muliere, D.; Wheeler, B.

2002-04-29T23:59:59.000Z

174

Progression in non-destructive spallation prediction and elevated temperature mechanical property evaluation of thermal barrier coating systems by use of a spherical micro-indentation method.  

E-Print Network [OSTI]

??The accumulation of carbon dioxide in the atmosphere continues to be an important ecological issue associated with global warming. The demand for improved efficiencies in… (more)

Tannenbaum, Jared Michael.

2011-01-01T23:59:59.000Z

175

Coatings on reflective mask substrates  

DOE Patents [OSTI]

A process for creating a mask substrate involving depositing: 1) a coating on one or both sides of a low thermal expansion material EUVL mask substrate to improve defect inspection, surface finishing, and defect levels; and 2) a high dielectric coating, on the backside to facilitate electrostatic chucking and to correct for any bowing caused by the stress imbalance imparted by either other deposited coatings or the multilayer coating of the mask substrate. An film, such as TaSi, may be deposited on the front side and/or back of the low thermal expansion material before the material coating to balance the stress. The low thermal expansion material with a silicon overlayer and a silicon and/or other conductive underlayer enables improved defect inspection and stress balancing.

Tong, William Man-Wai (Oakland, CA); Taylor, John S. (Livermore, CA); Hector, Scott D. (Oakland, CA); Mangat, Pawitter J. S. (Gilbert, AZ); Stivers, Alan R. (San Jose, CA); Kofron, Patrick G. (San Jose, CA); Thompson, Matthew A. (Austin, TX)

2002-01-01T23:59:59.000Z

176

Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical progress report, August 14, 1996--January 14, 1997  

SciTech Connect (OSTI)

Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. In the first six months of this project, bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The results of microstructural characterization of these alloys were presented in the first semiannual report. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. An increase in the volume fraction of alumina in the nickel matrix from 0 to 45% led to a significant increase in hardness of these composites.

Levin, B.F.; DuPont, J.N.; Marder, A.R.

1997-02-01T23:59:59.000Z

177

The Effect of Oxygen Contamination on the Amorphous Structure of Thermally Sprayed Coatings of Cu47Ti33Zr11Ni8Si1  

SciTech Connect (OSTI)

this research has shown that it is possible to deposit coatings of gas atomized Cu{sub 47}Ti{sub 33}Zr{sub 11}Ni{sub 8}Si{sub 1} powders containing various levels of oxygen contamination using plasma arc spray methods. The structure of the coating was found to depend primarily on the spray environment, with an argon atmosphere producing the most amorphous samples for a given starting powder. The oxygen content of the coatings reflected the relative levels of the oxygen contamination in the starting powders. The analysis of the starting powders displayed oxygen contents ranging from 0.125-0.79 wt.%. It was shown that higher oxygen levels lead to more crystalline structure in the starting powders as determined by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). This trend was found to be true for both the starting powders and for the plasma sprayed coatings. Chemical composition for all starting powders was very close to the nominal alloy composition. Chemical changes in the coatings involved the loss of Cu in coatings where high levels of oxidation were found. Cavitation erosion testing of selected coatings showed a weak trend that coatings prepared by vacuum plasma spray (VPS) had lower damage rates, but there was no clear data to indicate which coating parameters were superior. The range of data produced from testing duplicate coating was too wide to provide a good statistical measure of cavitation erosion resistance. of interest was the fact that when coatings began to show damage from cracking, all samples of a group showed similar damage and usually the damage pattern was somewhat unique to that group of samples. Failure of the coatings was due to features inherent to plasma arc spray (PAS) coating (i.e., pores, splat boundaries, oxide inclusions) rather than the mechanical characteristics of the amorphous alloy.

Matthew Frank Besser

2002-05-27T23:59:59.000Z

178

Corrosion resistant coatings suitable for elevated temperature application  

DOE Patents [OSTI]

The present invention relates to corrosion resistance coatings suitable for elevated temperature applications, which employ compositions of iron (Fe), chromium (Cr), nickel (Ni) and/or aluminum (Al). The compositions may be configured to regulate the diffusion of metals between a coating and a substrate, which may then influence coating performance, via the formation of an inter-diffusion barrier layer. The inter-diffusion barrier layer may comprise a face-centered cubic phase.

Chan, Kwai S. (San Antonio, TX); Cheruvu, Narayana Sastry (San Antonio, TX); Liang, Wuwei (Austin, TX)

2012-07-31T23:59:59.000Z

179

Vehicle barrier with access delay  

DOE Patents [OSTI]

An access delay vehicle barrier for stopping unauthorized entry into secure areas by a vehicle ramming attack includes access delay features for preventing and/or delaying an adversary from defeating or compromising the barrier. A horizontally deployed barrier member can include an exterior steel casing, an interior steel reinforcing member and access delay members disposed within the casing and between the casing and the interior reinforcing member. Access delay members can include wooden structural lumber, concrete and/or polymeric members that in combination with the exterior casing and interior reinforcing member act cooperatively to impair an adversarial attach by thermal, mechanical and/or explosive tools.

Swahlan, David J; Wilke, Jason

2013-09-03T23:59:59.000Z

180

DEVELOPMENT OF PROTECTIVE COATINGS FOR SINGLE CRYSTAL TURBINE BLADES  

SciTech Connect (OSTI)

Turbine blades in coal derived syngas systems are subject to oxidation and corrosion due to high steam temperature and pressure. Thermal barrier coatings (TBCs) are developed to address these problems. The emphasis is on prime-reliant design and a better coating architecture, having high temperature and corrosion resistance properties for turbine blades. In Phase I, UES Inc. proposed to develop, characterize and optimize a prime reliant TBC system, having smooth and defect-free NiCoCrAlY bond layer and a defect free oxide sublayer, using a filtered arc technology. Phase I work demonstrated the deposition of highly dense, smooth and defect free NiCoCrAlY bond coat on a single crystal CMSX-4 substrate and the deposition of alpha-alumina and yttrium aluminum garnet (YAG) sublayer on top of the bond coat. Isothermal and cyclic oxidation test and pre- and post-characterization of these layers, in Phase I work, (with and without top TBC layer of commercial EB PVD YSZ) revealed significant performance enhancement.

Amarendra K. Rai

2006-12-04T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Thermo-optic noise in coated mirrors for high-precision optical measurements  

E-Print Network [OSTI]

Thermal fluctuations in the coatings used to make high-reflectors are becoming significant noise sources in precision optical measurements and are particularly relevant to advanced gravitational wave detectors. There are two recognized sources of coating thermal noise, mechanical loss and thermal dissipation. Thermal dissipation causes thermal fluctuations in the coating which produce noise via the thermo-elastic and thermo-refractive mechanisms. We treat these mechanisms coherently, give a correction for finite coating thickness, and evaluate the implications for Advanced LIGO.

M. Evans; S. Ballmer; M. Fejer; P. Fritschel; G. Harry; G. Ogin

2008-07-30T23:59:59.000Z

182

Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semi-annual technical progress report, February 1996--July 1996  

SciTech Connect (OSTI)

Present coal-fired boiler environments remain hostile to the materials of choice since corrosion and erosion can be a serious problem in certain regions of the boiler. Recently, the Clean Air Act Amendment is requiring electric power plants to reduce NO{sub x}, emissions to the environment. To reduce NO{sub x}, emissions, new low NO{sub x}, combustors are utilized which burn fuel with a substoichiometric amount of oxygen (i.e., low oxygen partial pressure). In these low NO{sub x} environments, H{sub 2}S gas is a major source of sulfur. Due to the sulfidation process, corrosion rates in reducing parts of boilers have increased significantly and existing boiler tube materials do not always provide adequate corrosion resistance. Combined attack due to corrosion and erosion is a concern because of the significantly increased operating costs which result in material failures. One method to combat corrosion and erosion in coal-fired boilers is to apply coatings to the components subjected to aggressive environments. Thermal spray coatings, a cermet composite comprised of hard ceramic phases of oxide and/or carbide in a metal binder, have been used with some success as a solution to the corrosion and erosion problems in boilers. However, little is known on the effect of the volume fraction, size, and shape of the hard ceramic phase on the erosion and corrosion resistance of the thermally sprayed coatings. It is the objective of this research to investigate metal matrix composite (cermet) coatings in order to determine the optimum ceramic/metal combination that will give the best erosion and corrosion resistance in new advanced coal-fired boilers.

Banovic, S.W.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

1996-08-01T23:59:59.000Z

183

Active barrier films of PET for solar cell application: Processing and characterization  

SciTech Connect (OSTI)

A preliminary investigation was carried out on the possibility to improve the protective action offered by the standard multilayer structures used to encapsulate photovoltaic devices. With this aim, a commercial active barrier PET-based material, able to absorb oxygen when activated by liquid water, was used to produce flexible and transparent active barrier films, by means of a lab-scale film production plant. The obtained film, tested in terms of thermal, optical and oxygen absorption properties, shows a slow oxygen absorption kinetics, an acceptable transparency and an easy roll-to-roll processability, so proving itself as a good candidate for the development of protective coating for solar cells against the atmospheric degradation agents like the rain.

Rossi, Gabriella; Scarfato, Paola; Incarnato, Loredana [Department of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132 - 84084 Fisciano (Italy)

2014-05-15T23:59:59.000Z

184

High-Performance Corrosion-Resistant Materials: Iron-Based Amorphous-Metal Thermal-Spray Coatings: SAM HPCRM Program ? FY04 Annual Report ? Rev. 0 - DARPA DSO & DOE OCRWM Co-Sponsored Advanced Materials Program  

SciTech Connect (OSTI)

The multi-institutional High Performance Corrosion Resistant Materials (HPCRM) Team is cosponsored by the Defense Advanced Projects Agency (DARPA) Defense Science Office (DSO) and the Department of Energy (DOE) Office of Civilian Radioactive Waste Management (OCRWM), and has developed new corrosion-resistant, iron-based amorphous metals that can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The Fe-based corrosion-resistant, amorphous-metal coatings under development may prove of importance for applications on ships. Such coatings could be used as an 'integral drip shield' on spent fuel containers, as well as protective coatings that could be applied over welds, thereby preventing exposure to environments that might cause stress corrosion cracking. In the future, such new high-performance iron-based materials could be substituted for more-expensive nickel-based alloys, thereby enabling a reduction in the $58-billion life cycle cost for the long-term storage of the Nation's spent nuclear fuel by tens of percent.

Farmer, J; Haslam, J; Wong, F; Ji, S; Day, S; Branagan, D; Marshall, M; Meacham, B; Buffa, E; Blue, C; Rivard, J; Beardsley, M; Buffa, E; Blue, C; Rivard, J; Beardsley, M; Weaver, D; Aprigliano, L; Kohler, L; Bayles, R; Lemieux, E; Wolejsza, T; Martin, F; Yang, N; Lucadamo, G; Perepezko, J; Hildal, K; Kaufman, L; Heuer, A; Ernst, F; Michal, G; Kahn, H; Lavernia, E

2007-09-19T23:59:59.000Z

185

Progress to Develop an Advanced Solar-Selective Coating  

SciTech Connect (OSTI)

The progress to develop a durable advanced solar-selective coating will be described. Experimental work has focused on modeling high-temperature, solar-selective coatings; depositing the individual layers and modeled coatings; measuring the optical, thermal, morphology, and compositional properties and using the data to validate the modeled and deposited properties; re-optimizing the coating; and testing the coating performance and durability.

Kennedy, C. E.

2008-03-01T23:59:59.000Z

186

High-Temperature Solar Selective Coating Development for Power...  

Broader source: Energy.gov (indexed) [DOE]

are low risk Goal: Develop solar selective coatings for next- generation concentrated solar power towers that exhibit high absorptance with low thermal emittance, that can...

187

A Study of Advanced Materials for Gas Turbine Coatings at Elevated Temperatures Using Selected Microstructures and Characteristic Environments for Syngas Combustion  

SciTech Connect (OSTI)

Thermal barrier coatings (TBCs) that can be suitable for use in industrial gas turbine engines have been processed and compared with electron beam physical vapor deposition (EBPVD) microstructures for applications in advanced gas turbines that use coal-derived synthesis gas. Thermo-physical properties have been evaluated of the processed air plasma sprayed TBCs with standard APS-STD and vertically cracked APS-VC coatings samples up to 1300 C. Porosity of these selected coatings with related microstructural effects have been analyzed in this study. Wet and dry thermal cycling studies at 1125 C and spalling resistance thermal cycling studies to 1200 C have also been carried out. Type I and Type II hot corrosion tests were carried out to investigate the effects of microstructure variations and additions of alumina in YSZ top coats in multi-layered TBC structures. The thermal modeling of turbine blade has also been carried out that gives the capability to predict in-service performance temperature gradients. In addition to isothermal high temperature oxidation kinetics analysis in YSZ thermal barrier coatings of NiCoCrAlY bond coats with 0.25% Hf. This can affect the failure behavior depending on the control of the thermally grown oxide (TGO) growth at the interface. The TGO growth kinetics is seen to be parabolic and the activation energies correspond to interfacial growth kinetics that is controlled by the diffusion of O{sub 2} in Al{sub 2}O{sub 3}. The difference between oxidation behavior of the VC and STD structures are attributed to the effects of microstructure morphology and porosity on oxygen ingression into the zirconia and TGO layers. The isothermal oxidation resistance of the STD and VC microstructures is similar at temperatures up to 1200 C. However, the generally thicker TGO layer thicknesses and the slightly faster oxidation rates in the VC microstructures are attributed to the increased ingression of oxygen through the grain boundaries of the vertically cracked microstructures. The plasma sprayed TBC microstructure (VC and STD) with NiCoCrAlY-Hf bond coat are stable up to 1100 C. However, as with other TBC structures, a considerable amount of interdiffusion was observed in the different layers, although the TBC growth was self-limiting and parabolic. The addition of Hf to the VC microstructure appears to have some potential for the future development of robust TBCs with improved isothermal and service temperatures in advanced gas turbines.

Ravinder Diwan; Patrick Mensah; Guoqiang Li; Nalini Uppu; Strphen Akwaboa; Monica Silva; Ebubekir Beyazoglu; Ogad Agu; Naresh Polasa; Lawrence Bazille; Douglas Wolfe; Purush Sahoo

2011-02-10T23:59:59.000Z

188

Assessment of ceramic coatings for metal fuel melting crucible  

SciTech Connect (OSTI)

The objective of this study is to develop a coating method and material for crucibles to prevent material interactions with the U-Zr/U-TRU-Zr fuels during the manufacturing of SFR fuels. Refractory coatings were applied to niobium substrates by vacuum plasma-spray coating method. Melt dipping tests conducted were the coated rods lowered into the fuel melt at 1600 C. degrees, and withdrawn and cooled outside the crucible in the inert atmosphere of the induction furnace. Melt dipping tests of the coated Nb rods indicated that plasma-sprayed Y{sub 2}O{sub 3} coating doesn't form significant reaction layer between fuel melt and coating layer. Melt dipping tests of the coated Nb rods showed that TiC, TaC, and Y{sub 2}O{sub 3} coatings exhibited the promising performance among other ceramic coatings. These materials could be promising candidate materials for the reusable melt crucible of metal fuel for SFR. In addition, in order to develop the vacuum plasma-spray coating method for re-usable crucible of metal fuel slugs to be overcome the issue of thermal expansion mismatch between coating material and crucible, various combinations of coating conditions were investigated to find the bonding effect on the substrate in pursuit of more effective ways to withstand the thermal stresses. It is observed that most coating methods maintained sound coating state in U-Zr melt. (authors)

Kim, Ki-Hwan; Song, Hoon; Kim, Jong-Hwan; Oh, Seok-Jin; Kim, Hyung-Tae; Lee, Chan-Bock [Korea Atomic Energy Research Institute, Yuseong, Daejeon 305-600 (Korea, Republic of)

2013-07-01T23:59:59.000Z

189

Metal matrix coated fiber composites and the methods of manufacturing such composites  

DOE Patents [OSTI]

A fiber coating which allows ceramic or metal fibers to be wetted by molten metals is disclosed. The coating inhibits degradation of the physical properties caused by chemical reaction between the fiber and the coating itself or between the fiber and the metal matrix. The fiber coating preferably includes at least a wetting layer, and in some applications, a wetting layer and a barrier layer between the fiber and the wetting layer. The wetting layer promotes fiber wetting by the metal matrix. The barrier layer inhibits fiber degradation. The fiber coating permits the fibers to be infiltrated with the metal matrix resulting in composites having unique properties not obtainable in pure materials.

Weeks, Jr., Joseph K. (Salt Lake City, UT); Gensse, Chantal (Salt Lake City, UT)

1993-01-01T23:59:59.000Z

190

Composite ceria-coated aerogels and methods of making the same  

DOE Patents [OSTI]

Ceria-coated aerogels can include an aerogel support material having a stabilized ceria coating thereon. The ceria coating can be formed by solution or vapor deposition of alcogels or aerogels. Additional catalytic metal species can also be incorporated into the coating to form multi-metallic compounds having improved catalytic activity. Further, the ceria coated aerogels retain high surface areas at elevated temperatures. Thus, improvements in catalytic activity and thermal stability can be achieved using these ceria-coated composite aerogels.

Eyring, Edward M; Ernst, Richard D; Turpin, Gregory C; Dunn, Brian C

2013-05-07T23:59:59.000Z

191

Constructing Hydraulic Barriers in Deep Geologic Formations  

SciTech Connect (OSTI)

Many construction methods have been developed to create hydraulic barriers to depths of 30 to 50 meters, but few have been proposed for depths on the order of 500 meters. For these deep hydraulic barriers, most methods are potentially feasible for soil but not for hard rock. In the course of researching methods of isolating large subterranean blocks of oil shale, the authors have developed a wax thermal permeation method for constructing hydraulic barriers in rock to depths of over 500 meters in competent or even fractured rock as well as soil. The technology is similar to freeze wall methods, but produces a permanent barrier; and is potentially applicable in both dry and water saturated formations. Like freeze wall barriers, the wax thermal permeation method utilizes a large number of vertical or horizontal boreholes around the perimeter to be contained. However, instead of cooling the boreholes, they are heated. After heating these boreholes, a specially formulated molten wax based grout is pumped into the boreholes where it seals fractures and also permeates radially outward to form a series of columns of wax-impregnated rock. Rows of overlapping columns can then form a durable hydraulic barrier. These barriers can also be angled above a geologic repository to help prevent influx of water due to atypical rainfall events. Applications of the technique to constructing containment structures around existing shallow waste burial sites and water shutoff for mining are also described. (authors)

Carter, E.E.; Carter, P.E. [Technologies Co, Texas (United States); Cooper, D.C. [Ph.D. Idaho National Laboratory, Idaho Falls, ID (United States)

2008-07-01T23:59:59.000Z

192

Nanoscale Reinforced, Polymer Derived Ceramic Matrix Coatings  

SciTech Connect (OSTI)

The goal of this project was to explore and develop a novel class of nanoscale reinforced ceramic coatings for high temperature (600-1000 C) corrosion protection of metallic components in a coal-fired environment. It was focused on developing coatings that are easy to process and low cost. The approach was to use high-yield preceramic polymers loaded with nano-size fillers. The complex interplay of the particles in the polymer, their role in controlling shrinkage and phase evolution during thermal treatment, resulting densification and microstructural evolution, mechanical properties and effectiveness as corrosion protection coatings were investigated. Fe-and Ni-based alloys currently used in coal-fired environments do not possess the requisite corrosion and oxidation resistance for next generation of advanced power systems. One example of this is the power plants that use ultra supercritical steam as the working fluid. The increase in thermal efficiency of the plant and decrease in pollutant emissions are only possible by changing the properties of steam from supercritical to ultra supercritical. However, the conditions, 650 C and 34.5 MPa, are too severe and result in higher rate of corrosion due to higher metal temperatures. Coating the metallic components with ceramics that are resistant to corrosion, oxidation and erosion, is an economical and immediate solution to this problem. Good high temperature corrosion protection ceramic coatings for metallic structures must have a set of properties that are difficult to achieve using established processing techniques. The required properties include ease of coating complex shapes, low processing temperatures, thermal expansion match with metallic structures and good mechanical and chemical properties. Nanoscale reinforced composite coatings in which the matrix is derived from preceramic polymers have the potential to meet these requirements. The research was focused on developing suitable material systems and processing techniques for these coatings. In addition, we investigated the effect of microstructure on the mechanical properties and oxidation protection ability of the coatings. Coatings were developed to provide oxidation protection to both ferritic and austentic alloys and Ni-based alloys. The coatings that we developed are based on low viscosity pre-ceramic polymers. Thus they can be easily applied to any shape by using a variety of techniques including dip-coating, spray-coating and painting. The polymers are loaded with a variety of nanoparticles. The nanoparticles have two primary roles: control of the final composition and phases (and hence the properties); and control of the shrinkage during thermal decomposition of the polymer. Thus the selection of the nanoparticles was the most critical aspect of this project. Based on the results of the processing studies, the performance of selected coatings in oxidizing conditions (both static and cyclic) was investigated.

Rajendra Bordia

2009-07-31T23:59:59.000Z

193

Boron nitride nanosheets as oxygen-atom corrosion protective coatings  

SciTech Connect (OSTI)

The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

Yi, Min [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Shen, Zhigang, E-mail: shenzhg@buaa.edu.cn [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Zhao, Xiaohu [Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liang, Shuaishuai [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liu, Lei [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China)

2014-04-07T23:59:59.000Z

194

Methods and systems to thermally protect fuel nozzles in combustion systems  

DOE Patents [OSTI]

A method of assembling a gas turbine engine is provided. The method includes coupling a combustor in flow communication with a compressor such that the combustor receives at least some of the air discharged by the compressor. A fuel nozzle assembly is coupled to the combustor and includes at least one fuel nozzle that includes a plurality of interior surfaces, wherein a thermal barrier coating is applied across at least one of the plurality of interior surfaces to facilitate shielding the interior surfaces from combustion gases.

Helmick, David Andrew; Johnson, Thomas Edward; York, William David; Lacy, Benjamin Paul

2013-12-17T23:59:59.000Z

195

Puncture detecting barrier materials  

DOE Patents [OSTI]

A method and apparatus for continuous real-time monitoring of the integrity of protective barrier materials, particularly protective barriers against toxic, radioactive and biologically hazardous materials has been developed. Conductivity, resistivity or capacitance between conductive layers in the multilayer protective materials is measured by using leads connected to electrically conductive layers in the protective barrier material. The measured conductivity, resistivity or capacitance significantly changes upon a physical breach of the protective barrier material. 4 figs.

Hermes, R.E.; Ramsey, D.R.; Stampfer, J.F.; Macdonald, J.M.

1998-03-31T23:59:59.000Z

196

Mickey Leland Energy Fellowship Report: Development of Advanced Window Coatings  

SciTech Connect (OSTI)

Advanced fenestration technologies for light and thermal management in building applications are of great recent research interest for improvements in energy efficiency. Of these technologies, there is specific interest in advanced window coating technologies that have tailored control over the visible and infrared (IR) scattering into a room for both static and dynamic applications. Recently, PNNL has investigated novel subwavelength nanostructured coatings for both daylighting, and IR thermal management applications. Such coatings rese still in the early stages and additional research is needed in terms of scalable manufacturing. This project investigates aspects of a potential new methodology for low-cost scalable manufacture of said subwavelength coatings.

Bolton, Ladena A.; Alvine, Kyle J.; Schemer-Kohrn, Alan L.

2014-08-05T23:59:59.000Z

197

Corrosion resistant coating  

DOE Patents [OSTI]

A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

Wrobleski, Debra A. (Los Alamos, NM); Benicewicz, Brian C. (Los Alamos, NM); Thompson, Karen G. (Orlando, FL); Bryan, Coleman J. (Merritt Island, FL)

1997-01-01T23:59:59.000Z

198

Corrosion resistant coating  

DOE Patents [OSTI]

A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

Wrobleski, D.A.; Benicewicz, B.C.; Thompson, K.G.; Bryan, C.J.

1997-08-19T23:59:59.000Z

199

Methods for fabricating a micro heat barrier  

DOE Patents [OSTI]

Methods for fabricating a highly effective, micron-scale micro heat barrier structure and process for manufacturing a micro heat barrier based on semiconductor and/or MEMS fabrication techniques. The micro heat barrier has an array of non-metallic, freestanding microsupports with a height less than 100 microns, attached to a substrate. An infrared reflective membrane (e.g., 1 micron gold) can be supported by the array of microsupports to provide radiation shielding. The micro heat barrier can be evacuated to eliminate gas phase heat conduction and convection. Semi-isotropic, reactive ion plasma etching can be used to create a microspike having a cusp-like shape with a sharp, pointed tip (<0.1 micron), to minimize the tip's contact area. A heat source can be placed directly on the microspikes. The micro heat barrier can have an apparent thermal conductivity in the range of 10.sup.-6 to 10.sup.-7 W/m-K. Multiple layers of reflective membranes can be used to increase thermal resistance.

Marshall, Albert C.; Kravitz, Stanley H.; Tigges, Chris P.; Vawter, Gregory A.

2004-01-06T23:59:59.000Z

200

High Temperature Oxidation Performance of Aluminide Coatings  

SciTech Connect (OSTI)

Aluminide coatings are of interest for many high temperature applications because of the possibility of improving the oxidation resistance of structural alloys by forming a protective external alumina scale. Steam and exhaust gas environments are of particular interest because alumina is less susceptible to the accelerated attack due to hydroxide formation observed for chromia- and silica-forming alloys and ceramics. For water vapor testing, one ferritic (Fe-9Cr-1Mo) and one austenitic alloy (304L) have been selected as substrate materials and CVD coatings have been used in order to have a well-controlled, high purity coating. It is anticipated that similar aluminide coatings could be made by a higher-volume, commercial process such as pack cementation. Previous work on this program has examined as-deposited coatings made by high and low Al activity CVD processes and the short-term performance of these coatings. The current work is focusing on the long term behavior in both diffusion tests16 and oxidation tests of the thicker, high Al activity coatings. For long-term coating durability, one area of concern has been the coefficient of thermal expansion (CTE) mismatch between coating and substrate. This difference could cause cracking or deformation that could reduce coating life. Corrosion testing using thermal cycling is of particular interest because of this potential problem and results are presented where a short exposure cycle (1h) severely degraded aluminide coatings on both types of substrates. To further study the potential role of aluminide coatings in fossil energy applications, several high creep strength Ni-base alloys were coated by CVD for testing in a high pressure (20atm) steam-CO{sub 2} environment for the ZEST (zero-emission steam turbine) program. Such alloys would be needed as structural and turbine materials in this concept. For Ni-base alloys, CVD produces a {approx}50{mu}m {beta}-NiAl outer layer with an underlying interdiffusion zone. Specimens of HR160, alloy 601 and alloy 230 were tested with and without coatings at 900 C and preliminary post-test characterization is reported.

Pint, Bruce A [ORNL; Zhang, Ying [Tennessee Technological University; Haynes, James A [ORNL; Wright, Ian G [ORNL

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Hydrogen permeation resistant barrier  

DOE Patents [OSTI]

A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

McGuire, Joseph C. (Richland, WA); Brehm, William F. (Richland, WA)

1982-01-01T23:59:59.000Z

202

Passivation coating for flexible substrate mirrors  

DOE Patents [OSTI]

A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate before metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors. Also, the silver or other reflective metal layer on mirrors comprising thin, lightweight, flexible substrates of metal or polymer sheets coated with glassy layers can be protected with silicon nitride according to this invention.

Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

1990-01-01T23:59:59.000Z

203

Photovoltaic-thermal collectors  

DOE Patents [OSTI]

A photovoltaic-thermal solar cell including a semiconductor body having antireflective top and bottom surfaces and coated on each said surface with a patterned electrode covering less than 10% of the surface area. A thermal-absorbing surface is spaced apart from the bottom surface of the semiconductor and a heat-exchange fluid is passed between the bottom surface and the heat-absorbing surface.

Cox, III, Charles H. (Carlisle, MA)

1984-04-24T23:59:59.000Z

204

Flow coating apparatus and method of coating  

DOE Patents [OSTI]

Disclosed is a flow coating apparatus, comprising a slot that can dispense a coating material in an approximately uniform manner along a distribution blade that increases uniformity by means of surface tension and transfers the uniform flow of coating material onto an inclined substrate such as for example glass, solar panels, windows or part of an electronic display. Also disclosed is a method of flow coating a substrate using the apparatus such that the substrate is positioned correctly relative to the distribution blade, a pre-wetting step is completed where both the blade and substrate are completed wetted with a pre-wet solution prior to dispensing of the coating material onto the distribution blade from the slot and hence onto the substrate. Thereafter the substrate is removed from the distribution blade and allowed to dry, thereby forming a coating.

Hanumanthu, Ramasubrahmaniam; Neyman, Patrick; MacDonald, Niles; Brophy, Brenor; Kopczynski, Kevin; Nair, Wood

2014-03-11T23:59:59.000Z

205

A mathematical model for blade coating of a nematic liquid crystal  

E-Print Network [OSTI]

because they are thin, light, and have a low power consumption. LCD technology exploits a simple electro substrate (usually treated with appropriate barrier layers to prevent the passage of water and oxygen) using a blade-coating technique. This coating technique is relatively standard in other areas of technology [3

Mottram, Nigel

206

EERE Desal using Superhydrophobic Coatings  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

coating's surface; preventing salt creep, and thus virtually eliminates salt induced corrosion on any surface coated. 2. These coatings consist primarily of diatomaceous earth as...

207

Coated graphite articles useful in metallurgical processes and method for making same  

DOE Patents [OSTI]

Graphite articles including crucibles and molds used in metallurgical processes involving the melting and the handling of molten metals and alloys that are reactive with carbon when in a molten state and at process temperatures up to about 2000.degree. C. are provided with a multiple-layer coating for inhibiting carbon diffusion from the graphite into the molten metal or alloys. The coating is provided by a first coating increment of a carbide-forming metal on selected surfaces of the graphite, a second coating increment of a carbide forming metal and a refractory metal oxide, and a third coating increment of a refractory metal oxide. The second coating increment provides thermal shock absorbing characteristics to prevent delamination of the coating during temperature cycling. A wash coat of unstabilized zirconia or titanium nitride can be applied onto the third coating increment to facilitate release of melts from the coating.

Holcombe, Cressie E. (Knoxville, TN); Bird, Eugene L. (Knoxville, TN)

1995-01-01T23:59:59.000Z

208

Mercury Oxidation via Catalytic Barrier Filters Phase II  

SciTech Connect (OSTI)

In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

2007-09-30T23:59:59.000Z

209

Retractable barrier strip  

DOE Patents [OSTI]

A portable barrier strip having retractable tire-puncture spikes for puncturing a vehicle tire. The tire-puncture spikes have an armed position for puncturing a tire and a retracted position for not puncturing a tire. The strip comprises a plurality of barrier blocks having the tire-puncture spikes removably disposed in a shaft that is rotatably disposed in each barrier block. The plurality of barrier blocks hare hingedly interconnected by complementary hinges integrally formed into the side of each barrier block which allow the strip to be rolled for easy storage and retrieval, but which prevent irregular or back bending of the strip. The shafts of adjacent barrier blocks are pivotally interconnected via a double hinged universal joint to accommodate irregularities in a roadway surface and to transmit torsional motion of the shaft from block to block. A single flexshaft cable is connected to the shaft of an end block to allow a user to selectively cause the shafts of a plurality of adjacently connected barrier blocks to rotate the tire-puncture spikes to the armed position for puncturing a vehicle tire, and to the retracted position for not puncturing the tire. The flexshaft is provided with a resiliently biased retracting mechanism, and a release latch for allowing the spikes to be quickly retracted after the intended vehicle tire is punctured.

Marts, Donna J. (Idaho Falls, ID); Barker, Stacey G. (Idaho Falls, ID); Wowczuk, Andrew (Wheeling, WV); Vellenoweth, Thomas E. (Wheeling, WV)

2002-01-01T23:59:59.000Z

210

Recycler barrier RF buckets  

SciTech Connect (OSTI)

The Recycler Ring at Fermilab uses a barrier rf systems for all of its rf manipulations. In this paper, I will give an overview of historical perspective on barrier rf system, the longitudinal beam dynamics issues, aspects of rf linearization to produce long flat bunches and methods used for emittance measurements of the beam in the RR barrier rf buckets. Current rf manipulation schemes used for antiproton beam stacking and longitudinal momentum mining of the RR beam for the Tevatron collider operation are explained along with their importance in spectacular success of the Tevatron luminosity performance.

Bhat, C.M.; /Fermilab

2011-03-01T23:59:59.000Z

211

Corrosion protection mechanism of polyaniline blended organic coating on steel  

SciTech Connect (OSTI)

Epoxy-coal tar coatings are widely used to protect steel structures exposed to marine atmosphere due to their good barrier property. However, the presence of micropores and microcracks formed during the coating formation leads to failure of the coating due to permeation of corrosive ions. In recent years, it has been established that the coatings containing polyaniline (PANI) is able to protect pinholes and defects due to its passivating ability. Hence, a study has been made on the effect of polyaniline content (1 and 3%) in epoxy-coal tar coating on the corrosion protection of steel in 3% NaCl solution by electrochemical impedance spectroscopy (EIS) studies. Both phosphate- and chloride-doped polyanilines were prepared by a chemical oxidative polymerization method. From EIS studies, it has been found that the resistance value of the coatings containing 1 and 3% phosphate-doped polyaniline and 3% chloride-doped polyaniline pigmented coatings are similar to 10{sup 9} {Omega} cm{sup 2} even after 90 days exposure to NaCl solution, which are two orders high in comparison to that of conventional coal tar epoxy coatings. Besides, the conducting state of polyaniline has been found to be decreased after exposure to NaCl solution due to redox property of PANI. X-ray photoelectron spectroscopy studies have shown that polyaniline forms a complex layer with iron beneath the coating along with iron oxide.

Sathiyanarayanan, S.; Jeyaram, R.; Muthukrishnan, S.; Venkatachari, G. [Central Electrochemical Research Institute, Karaikkudi (India)

2009-07-01T23:59:59.000Z

212

Ultra-thin moisture barrier coatings for passive components  

E-Print Network [OSTI]

Polymer Multi-Layer (PML) capacitors have demonstrated excellent performance for numerous power electronics applications, particularly where high temperature stability is required. These capacitors are sensitive to high ...

Jensen, Robert A. (Robert Allen), 1980-

2004-01-01T23:59:59.000Z

213

Development of spray coated cathodes for RITS-6.  

SciTech Connect (OSTI)

This report documents work conducted in FY13 to conduct a feasibility study on thermal spray coated cathodes to be used in the RITS-6 accelerator in an attempt to improve surface uniformity and repeatability. Currently, the cathodes are coated with colloidal silver by means of painting by hand. It is believed that improving the cathode coating process could simplify experimental setup and improve flash x-ray radiographic performance. This report documents the experimental setup and summarizes the results of our feasibility study. Lastly, it describes the path forward and potential challenges that must be overcome in order to improve the process for creating uniform and repeatable silver coatings for cathodes.

Simpson, Sean; Leckbee, Joshua J.; Miller, Stephen Samuel

2013-09-01T23:59:59.000Z

214

Method of fabricating silicon carbide coatings on graphite surfaces  

DOE Patents [OSTI]

The vacuum plasma spray process produces well-bonded, dense, stress-free coatings for a variety of materials on a wide range of substrates. The process is used in many industries to provide for the excellent wear, corrosion resistance, and high temperature behavior of the fabricated coatings. In this application, silicon metal is deposited on graphite. This invention discloses the optimum processing parameters for as-sprayed coating qualities. The method also discloses the effect of thermal cycling on silicon samples in an inert helium atmosphere at about 1600.degree.C. which transforms the coating to silicon carbide.

Varacalle, Jr., Dominic J. (Idaho Falls, ID); Herman, Herbert (Port Jefferson, NY); Burchell, Timothy D. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

215

Method of fabricating silicon carbide coatings on graphite surfaces  

DOE Patents [OSTI]

The vacuum plasma spray process produces well-bonded, dense, stress-free coatings for a variety of materials on a wide range of substrates. The process is used in many industries to provide for the excellent wear, corrosion resistance, and high temperature behavior of the fabricated coatings. In this application, silicon metal is deposited on graphite. This invention discloses the optimum processing parameters for as-sprayed coating qualities. The method also discloses the effect of thermal cycling on silicon samples in an inert helium atmosphere at about 1,600 C which transforms the coating to silicon carbide. 3 figs.

Varacalle, D.J. Jr.; Herman, H.; Burchell, T.D.

1994-07-26T23:59:59.000Z

216

Materials Science and Engineering A297 (2001) 235243 Plasma-sprayed ceramic coatings: anisotropic elastic and  

E-Print Network [OSTI]

anisotropic elastic stiffnesses and thermal conductivities of the plasma sprayed ceramic coatingMaterials Science and Engineering A297 (2001) 235­243 Plasma-sprayed ceramic coatings: anisotropic are derived. © 2001 Elsevier Science S.A. All rights reserved. Keywords: Thermal spray; Elastic properties

Sevostianov, Igor

217

Retractable barrier strip  

DOE Patents [OSTI]

A portable barrier strip is described having retractable tire-puncture means for puncturing a vehicle tire. The tire-puncture means, such as spikes, have an armed position for puncturing a tire and a retracted position for not puncturing a tire. The strip comprises a plurality of barrier blocks having the tire-puncture means removably disposed in a shaft that is rotatably disposed in each barrier block. The shaft removably and pivotally interconnects the plurality of barrier blocks. Actuation cables cause the shaft to rotate the tire-puncture means to the armed position for puncturing a vehicle tire and to the retracted position for not puncturing the tire. Each tire-puncture means is received in a hollow-bed portion of its respective barrier block when in the retracted position. The barrier strip rests in its deployed position and substantially motionless as a tire rolls thereon and over. The strip is rolled up for retrieval, portability, and storage purposes, and extended and unrolled in its deployed position for use. 13 figs.

Marts, D.J.; Barker, S.G.; McQueen, M.A.

1996-04-16T23:59:59.000Z

218

Multiphase Nano-Composite Coatings for Achieving Energy Optimization  

SciTech Connect (OSTI)

UES Inc. and ANL teamed in this work to develop novel coating systems for the protection of surfaces from thermal degradation mainly in two applications; Machining and Die casting. These coatings were specifically designed for the purpose by incorporating required material phases and the overall architecture, which led to reduce the energy usage and increase efficiency of the operations. Following the UES/ANL'Â?s feasibility work, the coatings were developed utilizing High power impulse magnetron sputtering (HiPMS) and Large area filtered arc deposition (LAFAD) techniques. Toughness, hardness and oxidation resistance: contrasting qualities have been mixed in the right proportion to attain the suitable material characteristic for the cause. Hafnium diboride (HfB2) based materials provided such a system and its properties were tamed to attain the right combination of toughness and hardness by working on the microstructure and architecture of coatings. An effective interfacing material (graded concentrations of topcoat) was also achieved in this work to provide the required adhesion between the substrate and the coating. Combination of an appropriate bond coat and a functional top coat provided the present thermal degradation resistant coating for cutting tools and die-casting applications. Laboratory level performance tests and industrial level application tests by partner companies (Beta Site Testing) were used for the development of these coatings.

Dr. Jose Nainaparampil

2012-03-26T23:59:59.000Z

219

Spin coating of electrolytes  

DOE Patents [OSTI]

Methods for spin coating electrolytic materials onto substrates are disclosed. More particularly, methods for depositing solid coatings of ion-conducting material onto planar substrates and onto electrodes are disclosed. These spin coating methods are employed to fabricate electrochemical sensors for use in measuring, detecting and quantifying gases and liquids.

Stetter, Joseph R. (Naperville, IL); Maclay, G. Jordan (Maywood, IL)

1989-01-01T23:59:59.000Z

220

Thermal insulated glazing unit  

SciTech Connect (OSTI)

An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas.

Selkowitz, Stephen E. (Piedmont, CA); Arasteh, Dariush K. (Oakland, CA); Hartmann, John L. (Seattle, WA)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Thermal insulated glazing unit  

SciTech Connect (OSTI)

An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas. 2 figs.

Selkowitz, S.E.; Arasteh, D.K.; Hartmann, J.L.

1988-04-05T23:59:59.000Z

222

Vacuum barrier for excimer lasers  

DOE Patents [OSTI]

A barrier for separating the vacuum area of a diode from the pressurized gas area of an excimer laser. The barrier is a composite material comprising layers of a metal such as copper, along with layers of polyimide, and a matrix of graphite fiber yarns impregnated with epoxy. The barrier is stronger than conventional foil barriers, and allows greater electron throughput. 3 figs.

Shurter, R.P.

1992-09-15T23:59:59.000Z

223

Effectiveness of Cool Roof Coatings with Ceramic Particles  

SciTech Connect (OSTI)

Liquid applied coatings promoted as cool roof coatings, including several with ceramic particles, were tested at Oak Ridge National Laboratory (ORNL), Oak Ridge, Tenn., for the purpose of quantifying their thermal performances. Solar reflectance measurements were made for new samples and aged samples using a portable reflectometer (ASTM C1549, Standard Test Method for Determination of Solar Reflectance Near Ambient Temperature Using a Portable Solar Reflectometer) and for new samples using the integrating spheres method (ASTM E903, Standard Test Method for Solar Absorptance, Reflectance, and Transmittance of Materials Using Integrating Spheres). Thermal emittance was measured for the new samples using a portable emissometer (ASTM C1371, Standard Test Method for Determination of Emittance of Materials Near Room 1 Proceedings of the 2011 International Roofing Symposium Temperature Using Portable Emissometers). Thermal conductivity of the coatings was measured using a FOX 304 heat flow meter (ASTM C518, Standard Test Method for Steady-State Thermal Transmission Properties by Means of the Heat Flow Meter Apparatus). The surface properties of the cool roof coatings had higher solar reflectance than the reference black and white material, but there were no significant differences among coatings with and without ceramics. The coatings were applied to EPDM (ethylene propylene diene monomer) membranes and installed on the Roof Thermal Research Apparatus (RTRA), an instrumented facility at ORNL for testing roofs. Roof temperatures and heat flux through the roof were obtained for a year of exposure in east Tennessee. The field tests showed significant reduction in cooling required compared with the black reference roof (~80 percent) and a modest reduction in cooling compared with the white reference roof (~33 percent). The coating material with the highest solar reflectivity (no ceramic particles) demonstrated the best overall thermal performance (combination of reducing the cooling load cost and not incurring a large heating penalty cost) and suggests solar reflectivity is the significant characteristic for selecting cool roof coatings.

Brehob, Ellen G [ORNL] [ORNL; Desjarlais, Andre Omer [ORNL] [ORNL; Atchley, Jerald Allen [ORNL] [ORNL

2011-01-01T23:59:59.000Z

224

Metallic coating of microspheres  

SciTech Connect (OSTI)

Extremely smooth, uniform metal coatings of micrometer thicknesses on microscopic glass spheres (microspheres) are often needed as targets for inertial confinement fusion (ICF) experiments. The first part of this paper reviews those methods used successfully to provide metal coated microspheres for ICF targets, including magnetron sputtering, electro- and electroless plating, and chemical vapor pyrolysis. The second part of this paper discusses some of the critical aspects of magnetron sputter coating of microspheres, including substrate requirements, the sticking of microspheres during coating (preventing a uniform coating), and the difficulties in growing the desired dense, smooth, uniform microstructure on continuously moving spherical substrates.

Meyer, S.F.

1980-08-15T23:59:59.000Z

225

Thermal Properties of Metal-Coated Vertically-Aligned Single Wall Nanotube Films M. Panzer, G. Zhang, D. Mann, X. Hu, E. Pop, H. Dai, and K. E. Goodson  

E-Print Network [OSTI]

materials. Keywords: Vertically-aligned Carbon Nanotubes, Thermal Interface Resistance, Thermoreflectance interface materials (TIMs). While there has been much previous research on carbon nanotube thermal properties including their interface resistances. The data show the total thermal resistance of the TIM is R

Zhang, Guangyu

226

Method of installing subsurface barrier  

DOE Patents [OSTI]

Systems, components, and methods relating to subterranean containment barriers. Laterally adjacent tubular casings having male interlock structures and multiple female interlock structures defining recesses for receiving a male interlock structure are used to create subterranean barriers for containing and treating buried waste and its effluents. The multiple female interlock structures enable the barriers to be varied around subsurface objects and to form barrier sidewalls. The barrier may be used for treating and monitoring a zone of interest.

Nickelson, Reva A. (Shelley, ID); Richardson, John G. (Idaho Falls, ID); Kostelnik, Kevin M. (Idaho Falls, ID); Sloan, Paul A. (Rigby, ID)

2007-10-09T23:59:59.000Z

227

Metal matrix coated fiber composites and the methods of manufacturing such composites  

DOE Patents [OSTI]

A fiber coating which allows ceramic or metal fibers to be wetted by molten metals is disclosed. The coating inhibits degradation of the physical properties caused by chemical reaction between the fiber and the coating itself or between the fiber and the metal matrix. The fiber coating preferably includes at least a wetting layer, and in some applications, a wetting layer and a barrier layer between the fiber and the wetting layer. The wetting layer promotes fiber wetting by the metal matrix. The barrier layer inhibits fiber degradation. The fiber coating permits the fibers to be infiltrated with the metal matrix resulting in composites having unique properties not obtainable in pure materials. 8 figures.

Weeks, J.K. Jr.; Gensse, C.

1993-09-14T23:59:59.000Z

228

Plasma Surface Modification of Polymer Backsheets: Origins of Future Interfacial Barrier/Backsheet Failure  

SciTech Connect (OSTI)

Flexible polymer substrates coated with inorganic oxide moisture barriers are a potential replacement for glass backsheets in thin film PV modules. Silicon oxynitride (SiOxNy) deposited by PECVD on polyethylene terephthalate (PET) represents one potential new backsheet candidate. Barrier deposition runs at NREL have typically included a nitrogen-rich plasma pretreatment prior to actual barrier deposition with the intention of cleaning the PET surface as well as enhancing adhesion of the SiOxNy barrier film to PET; however, test coupons of PET/barrier/EVA/TPE failed after damp heat exposure. PET substrates exposed to plasma conditions similar to those used in pre-treatment were examined by X-ray photoelectron spectroscopy (XPS) to reveal new low molecular weight PET fragments are created which are volatile upon heating and water soluble. Failure analysis of the coupons determined that the moisture barrier is, in fact, transferred to the encapsulant side.

Pankow, J. W.; Glick, S. H.

2005-11-01T23:59:59.000Z

229

Microsecond switchable thermal antenna  

SciTech Connect (OSTI)

We propose a thermal antenna that can be actively switched on and off at the microsecond scale by means of a phase transition of a metal-insulator material, the vanadium dioxide (VO{sub 2}). This thermal source is made of a periodically patterned tunable VO{sub 2} nanolayer, which support a surface phonon-polariton in the infrared range in their crystalline phase. Using electrodes properly registered with respect to the pattern, the VO{sub 2} phase transition can be locally triggered by ohmic heating so that the surface phonon-polariton can be diffracted by the induced grating, producing a highly directional thermal emission. Conversely, when heating less, the VO{sub 2} layers cool down below the transition temperature, the surface phonon-polariton cannot be diffracted anymore so that thermal emission is inhibited. This switchable antenna could find broad applications in the domain of active thermal coatings or in those of infrared spectroscopy and sensing.

Ben-Abdallah, Philippe, E-mail: pba@institutoptique.fr; Benisty, Henri; Besbes, Mondher [Laboratoire Charles Fabry, UMR 8501, Institut d'Optique, CNRS, Université Paris-Sud 11, 2, Avenue Augustin Fresnel, 91127 Palaiseau Cedex (France)

2014-07-21T23:59:59.000Z

230

Quantification of corrosion resistance of a new-class of criticality control materials: thermal-spray coatings of high-boron iron-based amorphous metals - Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4  

SciTech Connect (OSTI)

An iron-based amorphous metal, Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} (SAM2X5), with very good corrosion resistance was developed. This material was produced as a melt-spun ribbon, as well as gas atomized powder and a thermal-spray coating. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. Earlier studies have shown that ingots and melt-spun ribbons of these materials have good passive film stability in these environments. Thermal spray coatings of these materials have now been produced, and have undergone a variety of corrosion testing, including both atmospheric and long-term immersion testing. The modes and rates of corrosion have been determined in the various environments, and are reported here.

Farmer, J C; Choi, J S; Shaw, C K; Rebak, R; Day, S D; Lian, T; Hailey, P; Payer, J H; Branagan, D J; Aprigliano, L F

2007-03-28T23:59:59.000Z

231

Engineered Barrier System: Physical and Chemical Environment  

SciTech Connect (OSTI)

The conceptual and predictive models documented in this Engineered Barrier System: Physical and Chemical Environment Model report describe the evolution of the physical and chemical conditions within the waste emplacement drifts of the repository. The modeling approaches and model output data will be used in the total system performance assessment (TSPA-LA) to assess the performance of the engineered barrier system and the waste form. These models evaluate the range of potential water compositions within the emplacement drifts, resulting from the interaction of introduced materials and minerals in dust with water seeping into the drifts and with aqueous solutions forming by deliquescence of dust (as influenced by atmospheric conditions), and from thermal-hydrological-chemical (THC) processes in the drift. These models also consider the uncertainty and variability in water chemistry inside the drift and the compositions of introduced materials within the drift. This report develops and documents a set of process- and abstraction-level models that constitute the engineered barrier system: physical and chemical environment model. Where possible, these models use information directly from other process model reports as input, which promotes integration among process models used for total system performance assessment. Specific tasks and activities of modeling the physical and chemical environment are included in the technical work plan ''Technical Work Plan for: In-Drift Geochemistry Modeling'' (BSC 2004 [DIRS 166519]). As described in the technical work plan, the development of this report is coordinated with the development of other engineered barrier system analysis model reports.

P. Dixon

2004-04-26T23:59:59.000Z

232

Bioactive glass coatings for orthopedic metallic implants  

SciTech Connect (OSTI)

The objective of this work is to develop bioactive glass coatings for metallic orthopedic implants. A new family of glasses in the SiO2-Na2O-K2O-CaO-MgO-P2O5 system has been synthesized and characterized. The glass properties (thermal expansion, softening and transformation temperatures, density and hardness) are in line with the predictions of established empirical models. The optimized firing conditions to fabricate coatings on Ti-based and Co-Cr alloys have been determined and related to the glass properties and the interfacial reactions. Excellent adhesion to alloys has been achieved through the formation of 100-200 nm thick interfacial layers (Ti5Si3 on Ti-based alloys and CrOx on Co-Cr). Finally, glass coatings, approximately 100 mu m thick, have been fabricated onto commercial Ti alloy-based dental implants.

Lopez-Esteban, Sonia; Saiz, Eduardo; Fujino, Sigheru; Oku, Takeo; Suganuma, Katsuaki; Tomsia, Antoni P.

2003-06-30T23:59:59.000Z

233

Glass/ceramic coatings for implants  

SciTech Connect (OSTI)

Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

Tomsia, Antoni P. (Pinole, CA); Saiz, Eduardo (Berkeley, CA); Gomez-Vega, Jose M. (Nagoya, JP); Marshall, Sally J. (Larkspur, CA); Marshall, Grayson W. (Larkspur, CA)

2011-09-06T23:59:59.000Z

234

Geophysical characterization of subsurface barriers  

SciTech Connect (OSTI)

An option for controlling contaminant migration from plumes and buried waste sites is to construct a subsurface barrier of a low-permeability material. The successful application of subsurface barriers requires processes to verify the emplacement and effectiveness of barrier and to monitor the performance of a barrier after emplacement. Non destructive and remote sensing techniques, such as geophysical methods, are possible technologies to address these needs. The changes in mechanical, hydrologic and chemical properties associated with the emplacement of an engineered barrier will affect geophysical properties such a seismic velocity, electrical conductivity, and dielectric constant. Also, the barrier, once emplaced and interacting with the in situ geologic system, may affect the paths along which electrical current flows in the subsurface. These changes in properties and processes facilitate the detection and monitoring of the barrier. The approaches to characterizing and monitoring engineered barriers can be divided between (1) methods that directly image the barrier using the contrasts in physical properties between the barrier and the host soil or rock and (2) methods that reflect flow processes around or through the barrier. For example, seismic methods that delineate the changes in density and stiffness associated with the barrier represents a direct imaging method. Electrical self potential methods and flow probes based on heat flow methods represent techniques that can delineate the flow path or flow processes around and through a barrier.

Borns, D.J.

1995-08-01T23:59:59.000Z

235

New capabilities and applications for electrophoretically deposited coatings  

SciTech Connect (OSTI)

Our primary purpose in this test is to provide a brief general description of a few applications of various electrophoretic systems which have been investigated and have found use in various coating applications at Sandia National Laboratories. Both organic and inorganic suspensions in aqueous and non-aqueous media have been considered in these studies. Applications include high voltage insulating dielectrics, thermally conductive/electrically insulating films, adherent lubricating films, uniform photoresist films, glass coatings, and fissile uranium oxide/carbon composite films for studies of nuclear powered lasers. More recently, we have become interested in the beneficial environmental aspects of being able to provide protective polymer coatings which reduce or minimize the use of organic solvents required by traditional spray coat processes. Important practical factors which relate to film uniformity, adhesion, and composition are related to unique coating or plating capabilities and applications. 6 refs., 2 figs., 1 tab.

Sharp, D.J.

1991-01-01T23:59:59.000Z

236

Underground waste barrier structure  

DOE Patents [OSTI]

Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.

Saha, Anuj J. (Hamburg, NY); Grant, David C. (Gibsonia, PA)

1988-01-01T23:59:59.000Z

237

Silicon nitride protective coatings for silvered glass mirrors  

DOE Patents [OSTI]

A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate before metal deposition to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors.

Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

1988-01-01T23:59:59.000Z

238

Silicon nitride protective coatings for silvered glass mirrors  

DOE Patents [OSTI]

A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate prior to metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors.

Tracy, C.E.; Benson, D.K.

1984-07-20T23:59:59.000Z

239

Barrier breaching device  

DOE Patents [OSTI]

A barrier breaching device that is designed primarily for opening holes in interior walls of buildings uses detonating fuse for explosive force. The fuse acts as the ribs or spokes of an umbrella-like device that may be opened up to form a cone. The cone is placed against the wall so that detonating fuse that rings the base of the device and which is ignited by the spoke-like fuses serves to cut a circular hole in the wall.

Honodel, Charles A. (Tracy, CA)

1985-01-01T23:59:59.000Z

240

Barrier breaching device  

DOE Patents [OSTI]

A barrier breaching device that is designed primarily for opening holes in interior walls of buildings uses detonating fuse for explosive force. The fuse acts as the ribs or spokes of an umbrella-like device that may be opened up to form a cone. The cone is placed against the wall so that detonating fuse that rings the base of the device and which is ignited by the spoke-like fuses serves to cut a circular hole in the wall.

Honodel, C.A.

1983-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders  

SciTech Connect (OSTI)

This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

Asit Biswas Andrew J. Sherman

2006-09-25T23:59:59.000Z

242

Power Electronics Thermal Control (Presentation)  

SciTech Connect (OSTI)

Thermal management plays an important part in the cost of electric drives in terms of power electronics packaging. Very promising results have been obtained by using microporous coatings and skived surfaces in conjunction with single-phase and two-phase flows. Sintered materials and thermoplastics with embedded fibers show significant promise as thermal interface materials, or TIMs. Appropriate cooling technologies depend on the power electronics package application and reliability.

Narumanchi, S.

2010-05-05T23:59:59.000Z

243

Thermal Fluids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermal Fluids The Thermal Fluids and Heat Transfer program works on thermal hydraulic reactor safety code development and experimental heat transferthermal hydraulics. The...

244

Corrosion-resistant multilayer coatings for the 28-75 nm wavelength region  

SciTech Connect (OSTI)

Corrosion has prevented use of SiC/Mg multilayers in applications requiring good lifetime stability. We have developed Al-based barrier layers that dramatically reduce corrosion, while preserving high reflectance and low stress. The aforementioned advances may enable the implementation of corrosion-resistant, high-performance SiC/Mg coatings in the 28-75 nm region in applications such as tabletop EUV/soft x-ray laser sources and solar physics telescopes. Further study and optimization of corrosion barrier structures and coating designs is underway.

Soufli, R; Fernandez-Perea, M; Al, E T

2011-11-08T23:59:59.000Z

245

Performing a local barrier operation  

DOE Patents [OSTI]

Performing a local barrier operation with parallel tasks executing on a compute node including, for each task: retrieving a present value of a counter; calculating, in dependence upon the present value of the counter and a total number of tasks performing the local barrier operation, a base value of the counter, the base value representing the counter's value prior to any task joining the local barrier; calculating, in dependence upon the base value and the total number of tasks performing the local barrier operation, a target value, the target value representing the counter's value when all tasks have joined the local barrier; joining the local barrier, including atomically incrementing the value of the counter; and repetitively, until the present value of the counter is no less than the target value of the counter: retrieving the present value of the counter and determining whether the present value equals the target value.

Archer, Charles J; Blocksome, Michael A; Ratterman, Joseph D; Smith, Brian E

2014-03-04T23:59:59.000Z

246

Performing a local barrier operation  

DOE Patents [OSTI]

Performing a local barrier operation with parallel tasks executing on a compute node including, for each task: retrieving a present value of a counter; calculating, in dependence upon the present value of the counter and a total number of tasks performing the local barrier operation, a base value, the base value representing the counter's value prior to any task joining the local barrier; calculating, in dependence upon the base value and the total number of tasks performing the local barrier operation, a target value of the counter, the target value representing the counter's value when all tasks have joined the local barrier; joining the local barrier, including atomically incrementing the value of the counter; and repetitively, until the present value of the counter is no less than the target value of the counter: retrieving the present value of the counter and determining whether the present value equals the target value.

Archer, Charles J; Blocksome, Michael A; Ratterman, Joseph D; Smith, Brian E

2014-03-04T23:59:59.000Z

247

Protective Coatings for Turbomachinery  

E-Print Network [OSTI]

for power plant efficiency and reliability, the need to prevent corrosion and erosion is growing. Operators, overhaulers, and manufacturers have been using protective coatings for over twenty-five years to prevent erosion and corrosion. The evolution...

McCune, B.; Hilty, L.

248

Friction surfaced Stellite6 coatings  

SciTech Connect (OSTI)

Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material for friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.

Rao, K. Prasad; Damodaram, R. [Department of Metallurgical and Materials Engineering - Indian Institute of Technology Madras, Chennai 600 036 (India); Rafi, H. Khalid, E-mail: khalidrafi@gmail.com [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai 600 036 (India); Ram, G.D. Janaki [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai 600 036 (India); Reddy, G. Madhusudhan [Metal Joining Group, Defence Metallurgical Research Laboratory (DMRL) Kanchanbagh, Hyderabad 500 058 (India); Nagalakshmi, R. [Welding Research Institute, Bharat Heavy Electricals Limited, Tiruchirappalli 620 014 (India)

2012-08-15T23:59:59.000Z

249

Thermal characterization of submicron polyacrylonitrile fibers based on optical heating and electrical thermal sensing  

SciTech Connect (OSTI)

In this work, the thermal diffusivity of single submicron ({approx}800 nm) polyacrylonitrile (PAN) fibers is characterized using the recently developed optical heating and electrical thermal sensing technique. In the experiment, a thin Au film (approximately in the nanometer range) is coated on the surface of nonconductive PAN fibers. A periodically modulated laser beam is used to irradiate suspended individual fibers to achieve noncontact periodical heating. The periodical temperature response of the sample is monitored by measuring the electrical resistance variation of the thin Au coating. The experimental results for three different synthesized PAN fibers with varying Au coating thickness are presented and discussed.

Hou Jinbo; Wang Xinwei; Zhang Lijun [Department of Mechanical Engineering, N104 Walter Scott Engineering Center, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0656 (United States)

2006-10-09T23:59:59.000Z

250

Developing TiAIN Coatings for Intermediate Temperature-Solid Oxide Fuel Cell Interconnect Applications  

SciTech Connect (OSTI)

TiN-type coatings have potential to be used as SOFC interconnect coatings SOFC because of their low resistance and high temperature stability. In this research, various (Ti,Al)N coatings were deposited on stainless steels by filtered-arc method. ASR and XRD tests were conducted on these coatings, and SEM/EDAX analysis were conducted after ASR and XRD tests. SEM/EDAX analyses show that (Ti,Al)N remains stable at temperature up to 700°C. It is also indicated that Al has beneficial effect on the stability of TiN type coatings. At 900°C, (Ti-30Al)N is fully oxidized and some of (Ti-50Al)N coating still remains as nitride. The analyses on cross-sectional samples show that these coatings are effective barrier to the Cr migration. In summary, (Ti.Al)N coatings are good candidates for the SOFC interconnect applications at 700°C. The future directions of this research are to improve the stability of these coatings by alloy-doping and to develop multi-layer coatings.

Liu, X. (West Virginia University); Johnson, C.D.; Li, C. (West Virginia University); Xu, J. (West Virginia University); Cross, C.

2007-02-01T23:59:59.000Z

251

Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Use of Laser Engineered Net Shaping for Rapid Manufacturing of Dies with Protective Coatings and Improved Thermal Management  

SciTech Connect (OSTI)

In the high pressure die casting process, molten metal is introduced into a die cavity at high pressure and velocity, enabling castings of thin wall section and complex geometry to be obtained. Traditional die materials have been hot work die steels, commonly H13. Manufacture of the dies involves machining the desired geometry from monolithic blocks of annealed tool steel, heat treating to desired hardness and toughness, and final machining, grinding and polishing. The die is fabricated with internal water cooling passages created by drilling. These materials and fabrication methods have been used for many years, however, there are limitations. Tool steels have relatively low thermal conductivity, and as a result, it takes time to remove the heat from the tool steel via the drilled internal water cooling passages. Furthermore, the low thermal conductivity generates large thermal gradients at the die cavity surfaces, which ultimately leads to thermal fatigue cracking on the surfaces of the die steel. The high die surface temperatures also promote the metallurgical bonding of the aluminum casting alloy to the surface of the die steel (soldering). In terms of process efficiency, these tooling limitations reduce the number of die castings that can be made per unit time by increasing cycle time required for cooling, and increasing downtime and cost to replace tooling which has failed either by soldering or by thermal fatigue cracking (heat checking). The objective of this research was to evaluate the feasibility of designing, fabricating, and testing high pressure die casting tooling having properties equivalent to H13 on the surface in contact with molten casting alloy - for high temperature and high velocity molten metal erosion resistance – but with the ability to conduct heat rapidly to interior water cooling passages. A layered bimetallic tool design was selected, and the design evaluated for thermal and mechanical performance via finite element analysis. H13 was retained as the exterior layer of the tooling, while commercially pure copper was chosen for the interior structure of the tooling. The tooling was fabricated by traditional machining of the copper substrate, and H13 powder was deposited on the copper via the Laser Engineered Net Shape (LENSTM) process. The H13 deposition layer was then final machined by traditional methods. Two tooling components were designed and fabricated; a thermal fatigue test specimen, and a core for a commercial aluminum high pressure die casting tool. The bimetallic thermal fatigue specimen demonstrated promising performance during testing, and the test results were used to improve the design and LENS TM deposition methods for subsequent manufacture of the commercial core. Results of the thermal finite element analysis for the thermal fatigue test specimen indicate that it has the ability to lose heat to the internal water cooling passages, and to external spray cooling, significantly faster than a monolithic H13 thermal fatigue sample. The commercial core is currently in the final stages of fabrication, and will be evaluated in an actual production environment at Shiloh Die casting. In this research, the feasibility of designing and fabricating copper/H13 bimetallic die casting tooling via LENS TM processing, for the purpose of improving die casting process efficiency, is demonstrated.

Brevick, Jerald R. [Ohio State University

2014-06-13T23:59:59.000Z

252

Method of producing a carbon coated ceramic membrane and associated product  

DOE Patents [OSTI]

A method is described for producing a carbon coated ceramic membrane including passing a selected hydrocarbon vapor through a ceramic membrane and controlling ceramic membrane exposure temperature and ceramic membrane exposure time. The method produces a carbon coated ceramic membrane of reduced pore size and modified surface properties having increased chemical, thermal and hydrothermal stability over an uncoated ceramic membrane. 12 figures.

Liu, P.K.T.; Gallaher, G.R.; Wu, J.C.S.

1993-11-16T23:59:59.000Z

253

Method of producing a carbon coated ceramic membrane and associated product  

DOE Patents [OSTI]

A method of producing a carbon coated ceramic membrane including passing a selected hydrocarbon vapor through a ceramic membrane and controlling ceramic membrane exposure temperature and ceramic membrane exposure time. The method produces a carbon coated ceramic membrane of reduced pore size and modified surface properties having increased chemical, thermal and hydrothermal stability over an uncoated ceramic membrane.

Liu, Paul K. T. (O'Hara Township, Allegheny County, PA); Gallaher, George R. (Oakmont Borough, PA); Wu, Jeffrey C. S. (Pittsburgh, PA)

1993-01-01T23:59:59.000Z

254

Delamination of Ceramic Coatings with Embedded Metal Layers Matthew R. Begleyw  

E-Print Network [OSTI]

sili- con-based ceramic matrix composites from oxidation and evap- orative hydrolysis at elevatedDelamination of Ceramic Coatings with Embedded Metal Layers Matthew R. Begleyw Mechanical ce- ramic coating. I. Introduction LOW-thermal-conductivity ceramic layers are now widely used

Wadley, Haydn

255

E-Print Network 3.0 - applied coating system Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

facility for the HEFT hard X-ray telescope Carsten P. Jensena , Finn E... ) for the production coating of depth graded multilayers on the thermally slumped glass segments which...

256

Ocean Barrier Layers’ Effect on Tropical Cyclone Intensification  

SciTech Connect (OSTI)

Improving a tropical cyclone's forecast and mitigating its destructive potential requires knowledge of various environmental factors that influence the cyclone's path and intensity. Herein, using a combination of observations and model simulations, we systematically demonstrate that tropical cyclone intensification is significantly affected by salinity-induced barrier layers, which are 'quasi-permanent' features in the upper tropical oceans. When tropical cyclones pass over regions with barrier layers, the increased stratification and stability within the layer reduce storm-induced vertical mixing and sea surface temperature cooling. This causes an increase in enthalpy flux from the ocean to the atmosphere and, consequently, an intensification of tropical cyclones. On average, the tropical cyclone intensification rate is nearly 50% higher over regions with barrier layers, compared to regions without. Our finding, which underscores the importance of observing not only the upper-ocean thermal structure but also the salinity structure in deep tropical barrier layer regions, may be a key to more skillful predictions of tropical cyclone intensities through improved ocean state estimates and simulations of barrier layer processes. As the hydrological cycle responds to global warming, any associated changes in the barrier layer distribution must be considered in projecting future tropical cyclone activity.

Balaguru, Karthik; Chang, P.; Saravanan, R.; Leung, Lai-Yung R.; Xu, Zhao; Li, M.; Hsieh, J.

2012-09-04T23:59:59.000Z

257

Characterization of Ceramic Plasma-Sprayed Coatings, and Interaction Studies Between U-Zr Fuel and Ceramic Coated Interface at an Elevated Temperature  

SciTech Connect (OSTI)

Candidate coating materials for re-usable metallic nuclear fuel crucibles, HfN, TiC, ZrC, and Y2O3, were plasma-sprayed onto niobium substrates. The coating microstructure and the thermal cycling behavior were characterized, and U-Zr melt interaction studies carried out. The Y2O3 coating layer had a uniform thickness and was well consolidated with a few small pores scattered throughout. While the HfN coating was not well consolidated with a considerable amount of porosity, but showed somewhat uniform thickness. Thermal cycling tests on the HfN, TiC, ZrC, and Y2O3 coatings showed good cycling characteristics with no interconnected cracks forming even after 20 cycles. Interaction studies done on the coated samples by dipping into a U-20wt.%Zr melt indicated that HfN and Y2O3 did not form significant reaction layers between the melt and the coating while the TiC and the ZrC coatings were significantly degraded. Y2O3 exhibited the most promising performance among HfN, TiC, ZrC, and Y2O3 coatings.

Ki Hwan Kim; Chong Tak Lee; R. S. Fielding; J. R. Kennedy

2011-08-01T23:59:59.000Z

258

JOURNALDE PHYSIQUE IV Colloque C7, supplkmentau Journal de Physique 111,Volume 3, novembre 1993  

E-Print Network [OSTI]

heat resistant materials or more efficient cooling techniques. In combination with advanced Plasma sprayed thermal barrier coatings for industrial gas turbines: morphology, processing ABSTRACT Thermal barrier coatings out of fully or partially stabilized zirconia offer a unique chance

Boyer, Edmond

259

Composites Part B: Engineering, 2011, 42(4): p. 916-925 Analysis of active cooling through nickel coated carbon fibers in the solidification  

E-Print Network [OSTI]

nickel coated carbon fibers in the solidification processing of aluminum matrix composites Nikhil Gupta1 , Nguyen Q. Nguyen2 , and Pradeep K. Rohatgi2 1 Composite Materials and Mechanics Laboratory, Mechanical In carbon fiber reinforced aluminum or aluminum alloy matrix composites a barrier coating is applied

Gupta, Nikhil

260

Oxidation-resistant interfacial coatings for continuous fiber ceramic composites  

SciTech Connect (OSTI)

Developing an oxidation-resistant interfacial coating for continuous fiber ceramic composites (CFCCs) continues to be a major challenge. CFCCs` mechanical behavior are influenced by the interfacial bonding characteristics between the fiber and the matrix. Finite element modeling studies suggest that a low-modulus interfacial coating material will be effective in reducing the residual thermal stresses that are generated upon cooling from processing temperatures. Nicalon/SiC composites with carbon, alumina and mullite interfacial coatings were fabricated with the SiC matrix deposited using a forced-flow chemical vapor infiltration process. Composites with mullite interfacial coatings exhibited considerable fiber pull-out even after oxidation and have potential as a composite system.

Shanmugham, S.; Liaw, P.K. [Tennessee Univ., Knoxville, TN (United States); Stinton, D.P.; Bleier, A.; Besmann, T.M.; Lara-Curzio, E. [Oak Ridge National Lab., TN (United States); Rebillat, F. [LCTS, Pessac (France)

1995-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Metallic coatings: autocatalytic (electroless) nickel-phosphorus alloy coatings: specification and test methods  

E-Print Network [OSTI]

Metallic coatings: autocatalytic (electroless) nickel-phosphorus alloy coatings: specification and test methods

International Organization for Standardization. Geneva

2003-01-01T23:59:59.000Z

262

Revêtements métalliques : Dépôts électrolytiques de nickel Metallic coatings : Electrodeposited coatings of nickel  

E-Print Network [OSTI]

Revêtements métalliques : Dépôts électrolytiques de nickel Metallic coatings : Electrodeposited coatings of nickel

International Organization for Standardization. Geneva

2002-01-01T23:59:59.000Z

263

Levelized cost of coating (LCOC) for selective absorber materials.  

SciTech Connect (OSTI)

A new metric has been developed to evaluate and compare selective absorber coatings for concentrating solar power applications. Previous metrics have typically considered the performance of the selective coating (i.e., solar absorptance and thermal emittance), but cost and durability were not considered. This report describes the development of the levelized cost of coating (LCOC), which is similar to the levelized cost of energy (LCOE) commonly used to evaluate alternative energy technologies. The LCOC is defined as the ratio of the annualized cost of the coating (and associated costs such as labor and number of heliostats required) to the average annual thermal energy produced by the receiver. The baseline LCOC using Pyromark 2500 paint was found to be %240.055/MWht, and the distribution of LCOC values relative to this baseline were determined in a probabilistic analysis to range from -%241.6/MWht to %247.3/MWht, accounting for the cost of additional (or fewer) heliostats required to yield the same baseline average annual thermal energy produced by the receiver. A stepwise multiple rank regression analysis showed that the initial solar absorptance was the most significant parameter impacting the LCOC, followed by thermal emittance, degradation rate, reapplication interval, and downtime during reapplication.

Ho, Clifford Kuofei; Pacheco, James Edward

2013-09-01T23:59:59.000Z

264

Oxidation-resistant interfacial coatings for fiber-reinforced ceramic composites  

SciTech Connect (OSTI)

A ceramic-matrix composite having a multilayered interfacial coating adapted to protect the reinforcing fibers from long-term oxidation, while allowing these to bridge the wake of advancing cracks in the matrix, is provided by selectively mismatching materials within adjacent layers of the interfacial coating, the materials having different coefficients of thermal expansion so that a low toughness interface region is created to promote crack deflection either within an interior layer of the mismatched interfacial coating or between adjacent layers of the mismatched interfacial coating.

Lara-Curzio, Edgar; More, Karren L.; Lee, Woo Y.

1999-04-22T23:59:59.000Z

265

Fiber coating method  

DOE Patents [OSTI]

A coating is applied to reinforcing fibers arranged into a tow by coaxially aligning the tow with an adjacent separation layer and winding or wrapping the tow and separation layer onto a support structure in an interleaved manner so that the separation layer separates a wrap of the tow from an adjacent wrap of the tow. A coating can then be uniformly applied to the reinforcing fibers without defects caused by fiber tow to fiber tow contact. The separation layer can be a carbon fiber veil.

Corman, Gregory Scot (Ballston Lake, NY)

2003-04-15T23:59:59.000Z

266

Fiber coating method  

DOE Patents [OSTI]

A coating is applied to reinforcing fibers arranged into a tow by coaxially aligning the tow with an adjacent separation layer and winding or wrapping the tow and separation layer onto a support structure in an interleaved manner so that the separation layer separates a wrap of the tow from an adjacent wrap of the tow. A coating can then be uniformly applied to the reinforcing fibers without defects caused by fiber tow to fiber tow contact. The separation layer can be a carbon fiber veil.

Corman, Gregory Scot (Ballston Lake, NY)

2001-01-01T23:59:59.000Z

267

Tribology and coatings  

SciTech Connect (OSTI)

The future use of fuel-efficient, low-emission, advanced transportation systems (for example, those using low-heat-rejection diesel engines or advanced gas turbines) presents new challenges to tribologists and materials scientists. High service temperatures, corrosive environments, and extreme contact pressures are among the concerns that make necessary new tribological designs, novel materials, and effective lubrication concepts. Argonne is working on methods to reduce friction, wear and corrosion, such as soft metal coatings on ceramics, layered compounds, diamond coatings, and hard surfaces.

NONE

1995-06-01T23:59:59.000Z

268

Graphene Coating Coupled Emission  

E-Print Network [OSTI]

Graphene Coating Coupled Emission A COMSET, A single sheet of sp2-hybridized carbon atoms, called of graphene and its unique properties, I will present amplification of surface graphene-Ag hybrid films which when graphene is used as the spacer layer in a conventional Ag- harnessed the nonlinear properties

Shyamasundar, R.K.

269

Electrical insulator assembly with oxygen permeation barrier  

DOE Patents [OSTI]

A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

Van Der Beck, R.R.; Bond, J.A.

1994-03-29T23:59:59.000Z

270

Low friction and galling resistant coatings and processes for coating  

DOE Patents [OSTI]

The present invention describes coating processes and the resultant coated articles for use in high temperature sodium environments, such as those found in liquid metal fast breeder reactors and their associated systems. The substrate to which the coating is applied may be either an iron base or nickel base alloy. The coating itself is applied to the substrate by electro-spark deposition techniques which result in metallurgical bonding between the coating and the substrate. One coating according to the present invention involves electro-spark depositing material from a cemented chromium carbide electrode and an aluminum electrode. Another coating according to the present invention involves electro-spark depositing material from a cemented chromium carbide electrode and a nickel-base hardfacing alloy electrode.

Johnson, Roger N. (Richland, WA)

1987-01-01T23:59:59.000Z

271

In situ fabrication of blue ceramic coatings on wrought Al Alloy 2024 by plasma electrolytic oxidation  

SciTech Connect (OSTI)

In situ formation of ceramic coatings on 2024 Al alloy with a blue color was successfully achieved using a plasma electrolytic oxidation process working at atmospheric pressure. This novel blue ceramic coating overcomes the shortcomings of surface treatments resulting from conventional dyeing processes by depositing organic dyes into the porous structure of anodic film, which has poor resistance to abrasion and rapid fading when exposed to sunlight. X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy were employed to characterize the microstructure of the blue ceramic coating. The fabricated ceramic coating was composed of CoAl{sub 2}O{sub 4}, {alpha}-Al{sub 2}O{sub 3}, and {gamma}-Al{sub 2}O{sub 3.} By controlling the working parameters, the distribution of the CoAl{sub 2}O{sub 4} phase on the surface can be adjusted, and plays a key role in the appearance of the coating. Electrochemical testing, thermal cycling method, and pin-on-disk sliding wear testing were employed to evaluate corrosion, thermal cycling, and wear resistance of the ceramic coatings. The results indicate that the blue ceramic coating has a similar polarization resistance to that of conventional anodic film and can significantly enhance the corrosion resistance of aluminum alloy. There are no destructive horizontal cracks observed within the blue ceramic coating when subjected to 120 times of thermal cycling, which heats the samples up to 573 K and followed by submersion in water at room temperature for 10 min. Compared with the aluminum substrate as well as a conventional anodic film coated aluminum sample, the wear resistance of the blue ceramic coating coated sample was significantly increased while the coefficient of friction was decreased from 0.34 to 0.14.

Wang Zhijiang; Nie Xueyuan; Hu, Henry; Hussein, Riyad O. [Department of Mechanical, Automotive and Materials Engineering, University of Windsor, Windsor, Ontario N9B 3P4 (Canada)

2012-03-15T23:59:59.000Z

272

The Cementitious Barriers Partnership (CBP) Software Toolbox Capabilities In Assessing The Degradation Of Cementitious Barriers  

SciTech Connect (OSTI)

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy (US DOE) Office of Tank Waste and Nuclear Materials Management. The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that help improve understanding and predictions of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program have been used to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to 100 years and longer for operating facilities and longer than 1000 years for waste disposal. The CBP Software Toolbox has produced tangible benefits to the DOE Performance Assessment (PA) community. A review of prior DOE PAs has provided a list of potential opportunities for improving cementitious barrier performance predictions through the use of the CBP software tools. These opportunities include: 1) impact of atmospheric exposure to concrete and grout before closure, such as accelerated slag and Tc-99 oxidation, 2) prediction of changes in Kd/mobility as a function of time that result from changing pH and redox conditions, 3) concrete degradation from rebar corrosion due to carbonation, 4) early age cracking from drying and/or thermal shrinkage and 5) degradation due to sulfate attack. The CBP has already had opportunity to provide near-term, tangible support to ongoing DOE-EM PAs such as the Savannah River Saltstone Disposal Facility (SDF) by providing a sulfate attack analysis that predicts the extent and damage that sulfate ingress will have on the concrete vaults over extended time (i.e., > 1000 years). This analysis is one of the many technical opportunities in cementitious barrier performance that can be addressed by the DOE-EM sponsored CBP software tools. Modification of the existing tools can provide many opportunities to bring defense in depth in prediction of the performance of cementitious barriers over time.

Flach, G. P. [Savannah River Site (SRS), Aiken, SC (United States); Burns, H. H. [Savannah River Site (SRS), Aiken, SC (United States); Langton, C. [Savannah River Site (SRS), Aiken, SC (United States); Smith, F. G. III [Savannah River Site (SRS), Aiken, SC (United States); Brown, K. G. [Vanderbilt University, Nashville, TN (United States); Kosson, D. S. [Vanderbilt University, Nashville, TN (United States); Garrabrants, A. C. [Vanderbilt University, Nashville, TN (United States); Sarkar, S. [Vanderbilt University, Nashville, TN (United States); van der Sloot, H. [Hans van der Sloot Consultancy (The Netherlands); Meeussen, J. C.L. [Nuclear Research and Consultancy Group, Petten (The Netherlands); Samson, E. [SIMCO Technologies Inc. , 1400, boul. du Parc - Technologique , Suite 203, Quebec (Canada); Mallick, P. [United States Department of Energy, 1000 Independence Ave. SW , Washington, DC (United States); Suttora, L. [United States Department of Energy, 1000 Independence Ave. SW , Washington, DC (United States); Esh, D. W. [U .S. Nuclear Regulatory Commission , Washington, DC (United States); Fuhrmann, M. J. [U .S. Nuclear Regulatory Commission , Washington, DC (United States); Philip, J. [U .S. Nuclear Regulatory Commission , Washington, DC (United States)

2013-01-11T23:59:59.000Z

273

The Cementitious Barriers Partnership (CBP) Software Toolbox Capabilities in Assessing the Degradation of Cementitious Barriers - 13487  

SciTech Connect (OSTI)

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy (US DOE) Office of Tank Waste and Nuclear Materials Management. The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that help improve understanding and predictions of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program have been used to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to 100 years and longer for operating facilities and longer than 1000 years for waste disposal. The CBP Software Toolbox has produced tangible benefits to the DOE Performance Assessment (PA) community. A review of prior DOE PAs has provided a list of potential opportunities for improving cementitious barrier performance predictions through the use of the CBP software tools. These opportunities include: 1) impact of atmospheric exposure to concrete and grout before closure, such as accelerated slag and Tc-99 oxidation, 2) prediction of changes in K{sub d}/mobility as a function of time that result from changing pH and redox conditions, 3) concrete degradation from rebar corrosion due to carbonation, 4) early age cracking from drying and/or thermal shrinkage and 5) degradation due to sulfate attack. The CBP has already had opportunity to provide near-term, tangible support to ongoing DOE-EM PAs such as the Savannah River Saltstone Disposal Facility (SDF) by providing a sulfate attack analysis that predicts the extent and damage that sulfate ingress will have on the concrete vaults over extended time (i.e., > 1000 years). This analysis is one of the many technical opportunities in cementitious barrier performance that can be addressed by the DOE-EM sponsored CBP software tools. Modification of the existing tools can provide many opportunities to bring defense in depth in prediction of the performance of cementitious barriers over time. (authors)

Flach, G.P.; Burns, H.H.; Langton, C.; Smith, F.G. III [Savannah River National Laboratory, Savannah River Site, Aiken SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken SC 29808 (United States); Brown, K.G.; Kosson, D.S.; Garrabrants, A.C.; Sarkar, S. [Vanderbilt University, Nashville, TN (United States)] [Vanderbilt University, Nashville, TN (United States); Van der Sloot, H. [Hans Van der Sloot Consultancy (Netherlands)] [Hans Van der Sloot Consultancy (Netherlands); Meeussen, J.C.L. [Nuclear Research and Consultancy Group, Petten (Netherlands)] [Nuclear Research and Consultancy Group, Petten (Netherlands); Samson, E. [SIMCO Technologies Inc., 1400, boul. du Parc-Technologique, Suite 203, Quebec (Canada)] [SIMCO Technologies Inc., 1400, boul. du Parc-Technologique, Suite 203, Quebec (Canada); Mallick, P.; Suttora, L. [United States Department of Energy, 1000 Independence Ave. SW, Washington, DC (United States)] [United States Department of Energy, 1000 Independence Ave. SW, Washington, DC (United States); Esh, D.W.; Fuhrmann, M.J.; Philip, J. [U.S. Nuclear Regulatory Commission, Washington, DC (United States)] [U.S. Nuclear Regulatory Commission, Washington, DC (United States)

2013-07-01T23:59:59.000Z

274

Multi-barrier borehole canister designs for a tuff repository  

SciTech Connect (OSTI)

Initial dimensions are presented for proposed multi-barrier spent fuel borehole canisters using coated shells combined with sacrificial anodes and alkaline, oxide barriers to adjust potential and pH of the exterior shell into thermodynamically passive or immune regions of the Pourbaix diagram. Configuration of the 3 PWR canister is similar to the 1983 Site Characterization Project (SCP) borehole design. Canister dimensions were determined by using material performance data to calculate wall thickness, criticality, and sacrificial anode life. For the 3-PWR canister. Incoloy 825 is the preferred exterior canister shell material; copper-nickel alloy CDA 715 is the preferred interior canister shell material. High-lime concrete or alumina is preferred for the alkaline filler. Magnesium alloy is the preferred sacrificial anode material. Coating the canister exterior would be necessary to reduce corrosion current density to the point where a 10,000 year design life is possible. A 1 PWR canister has lower mass, thinner walls and lower criticality than the 3 PWR design. Equilibrium calculations for the historical average composition of J-13 water using the aquatic chemical speciation program WQ4F show positive saturation indices for several minerals, indicating potential for deposition on the canister exterior over long time periods. Uniform deposition could reduce corrosion rate by hindering transport of corrosion products from the canister surface. If deposition is non-uniform, local corrosion could increase through development of differential oxygen concentration cells.

James, D.E.; Skaggs, R.L.; Mohansingh, S.

1994-05-01T23:59:59.000Z

275

Plasma Surface Modification of Polymer Backsheets: Origins of Future Interfacial Barrier/Backsheet Failure (Poster)  

SciTech Connect (OSTI)

Flexible polymer substrates coated with inorganic oxide moisture barriers are a potential replacement for glass backsheets in thin-film PV (photovoltaic) modules. Silicon oxynitride (SiO{sub x}N{sub y}) deposited by plasma enhanced chemical vapor deposition (PECVD) on polyethylene terephthalate (PET) represents one potential new backsheet candidate. Barrier deposition runs at NREL have included a nitrogen-rich plasma pretreatment prior to barrier deposition with the intention of cleaning the PET surface and enhancing adhesion of the SiO{sub x}N{sub y} barrier film to PET; however, test coupons of PET/barrier/EVA/TPE failed after damp-heat exposure. (EVA is ethylene vinyl acetate and TPE is Tedlar{reg_sign}-PET-EVA). PET substrates exposed to plasma conditions similar to those used in pretreatment were examined by X-ray photoelectron spectroscopy (XPS) to reveal that new low molecular weight PET fragments were created at the PET surface. These fragments are responsible for barrier/PET interfacial failure and barrier transfer to the EVA encapsulant side following damp heat exposure.

Pankow, J. W.; Glick, S. H.

2006-05-01T23:59:59.000Z

276

Global interrupt and barrier networks  

DOE Patents [OSTI]

A system and method for generating global asynchronous signals in a computing structure. Particularly, a global interrupt and barrier network is implemented that implements logic for generating global interrupt and barrier signals for controlling global asynchronous operations performed by processing elements at selected processing nodes of a computing structure in accordance with a processing algorithm; and includes the physical interconnecting of the processing nodes for communicating the global interrupt and barrier signals to the elements via low-latency paths. The global asynchronous signals respectively initiate interrupt and barrier operations at the processing nodes at times selected for optimizing performance of the processing algorithms. In one embodiment, the global interrupt and barrier network is implemented in a scalable, massively parallel supercomputing device structure comprising a plurality of processing nodes interconnected by multiple independent networks, with each node including one or more processing elements for performing computation or communication activity as required when performing parallel algorithm operations. One multiple independent network includes a global tree network for enabling high-speed global tree communications among global tree network nodes or sub-trees thereof. The global interrupt and barrier network may operate in parallel with the global tree network for providing global asynchronous sideband signals.

Blumrich, Matthias A. (Ridgefield, CT); Chen, Dong (Croton-On-Hudson, NY); Coteus, Paul W. (Yorktown Heights, NY); Gara, Alan G. (Mount Kisco, NY); Giampapa, Mark E (Irvington, NY); Heidelberger, Philip (Cortlandt Manor, NY); Kopcsay, Gerard V. (Yorktown Heights, NY); Steinmacher-Burow, Burkhard D. (Mount Kisco, NY); Takken, Todd E. (Mount Kisco, NY)

2008-10-28T23:59:59.000Z

277

Effects of volatile coatings on the morphology and optical detection of combustion-generated black carbon particles.  

SciTech Connect (OSTI)

We have measured time-resolved laser-induced incandescence (LII) from combustion-generated mature soot extracted from a burner and (1) coated with oleic acid or (2) coated with oleic acid and then thermally denuded using a thermodenuder. The soot samples were size selected using a differential mobility analyser and characterized with a scanning mobility particle sizer, centrifugal particle mass analyser, and transmission electron microscope. The results demonstrate a strong influence of coatings particle morphology and on the magnitude and temporal evolution of the LII signal. For coated particles higher laser fluences are required to reach LII signal levels comparable to those of uncoated particles. This effect is predominantly attributable to the additional energy needed to vaporize the coating while heating the particle. LII signals are higher and signal decay rates are significantly slower for thermally denuded particles relative to coated or uncoated particles, particularly at low and intermediate laser fluences.

Bambha, Ray P.; Dansson, Mark Alex; Schrader, Paul E.; Michelsen, Hope A.

2013-09-01T23:59:59.000Z

278

Ceramic wash-coat for catalyst support  

SciTech Connect (OSTI)

A wash-coat (16) for use as a support for an active catalyst species (18) and a catalytic combustor component (10) incorporating such wash-coat. The wash-coat is a solid solution of alumina or alumina-based material (Al2O3-0-3 wt % La2O3) and a further oxide exhibiting a coefficient of thermal expansion that is lower than that exhibited by alumina. The further oxide may be silicon dioxide (2-30 wt % SiO2), zirconia silicate (2-30 wt % ZrSiO4), neodymium oxide (0-4 wt %), titania (Al2O3-3-40% TiO2) or alumina-based magnesium aluminate spinel (Al2O3-25 wt % MgO) in various embodiments. The active catalyst species may be palladium and a second metal in a concentration of 10-50% of the concentration of the palladium.

Kulkarni, Anand A.; Subramanian, Ramesh; Sabol, Stephen M.

2012-08-14T23:59:59.000Z

279

Ultra-Low Thermal Conductivity in W/Al2O3 Nanolaminates  

E-Print Network [OSTI]

conversion (3). Conversely, the thermal resistance of interfaces degrades the performance of materials dissimilar materials may provide a route for the production of thermal barriers with ultra-low thermal and improve the performance of thermal bar- riers (2) and of materials used in thermoelec- tric energy

George, Steven M.

280

Thermal Bypass Air Barriers in the 2009 International Energy Conservation  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyThe EnergyDepartment of Energy The U.S.DepartmentStorage

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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281

Antithrombogenic Polymer Coating.  

DOE Patents [OSTI]

An article having a non-thrombogenic surface and a process for making the article are disclosed. The article is formed by (i) coating a polymeric substrate with a crosslinked chemical combination of a polymer having at least two amino substituted side chains, a crosslinking agent containing at least two crosslinking functional groups which react with amino groups on the polymer, and a linking agent containing a first functional group which reacts with a third functional group of the crosslinking agent, and (ii) contacting the coating on the substrate with an antithrombogenic agent which covalently bonds to a second functional group of the linking agent. In one example embodiment, the polymer is a polyamide having amino substituted alkyl chains on one side of the polyamide backbone, the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl, the linking agent is a polyhydrazide and the antithrombogenic agent is heparin.

Huang, Zhi Heng (San Ramon, CA); McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

2003-01-21T23:59:59.000Z

282

1-nm-thick graphene tri-layer as the ultimate copper diffusion barrier  

SciTech Connect (OSTI)

We demonstrate the thinnest ever reported Cu diffusion barrier, a 1-nm-thick graphene tri-layer. X-ray diffraction patterns and Raman spectra show that the graphene is thermally stable at up to 750?°C against Cu diffusion. Transmission electron microscopy images show that there was no inter-diffusion in the Cu/graphene/Si structure. Raman analyses indicate that the graphene may have degraded into a nanocrystalline structure at 750?°C. At 800?°C, the perfect carbon structure was damaged, and thus the barrier failed. The results of this study suggest that graphene could be the ultimate Cu interconnect diffusion barrier.

Nguyen, Ba-Son [Department of Mechanical Engineering, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Lin, Jen-Fin [Department of Mechanical Engineering, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Center for Micro/Nano Science and Technology, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Perng, Dung-Ching, E-mail: dcperng@ee.ncku.edu.tw [Institute of Microelectronics and Electrical Engineering Department, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Center for Micro/Nano Science and Technology, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China)

2014-02-24T23:59:59.000Z

283

Effect of combined nanoparticle and polymeric dispersions on critical heat flux, nucleate boiling heat transfer coefficient, and coating adhesion  

E-Print Network [OSTI]

An experimental study was performed to determine thermal performance and adhesion effects of a combined nanoparticle and polymeric dispersion coating. The critical heat flux (CHF) values and nucleate boiling heat transfer ...

Edwards, Bronwyn K

2009-01-01T23:59:59.000Z

284

To link to this article: DOI: 10.1007/s11085-011-9241-y http://dx.doi.org/10.1007/s11085-011-9241-y  

E-Print Network [OSTI]

) are ``multi-layered'' structures. They are composed of an insulating ceramic top coat (the thermal barrier A-Coating for Thermal Barrier Coating Systems. (2011) Oxidation of Metals, vol. 75 (n° 5-6). pp. 247-279. ISSN 0030-770X-Coating for Thermal Barrier Coating Systems Aure´lie Vande Put · Djar Oquab · Eve Pe´re´ · Aymeric Raffaitin · Daniel

Mailhes, Corinne

285

Active cooling-based surface confinement system for thermal soil treatment  

DOE Patents [OSTI]

A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders. 1 fig.

Aines, R.D.; Newmark, R.L.

1997-10-28T23:59:59.000Z

286

Active cooling-based surface confinement system for thermal soil treatment  

DOE Patents [OSTI]

A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders.

Aines, Roger D. (Livermore, CA); Newmark, Robin L. (Pleasanton, CA)

1997-01-01T23:59:59.000Z

287

COMBUSTION TURBINE (CT) HOT SECTION COATING LIFE MANAGEMENT  

SciTech Connect (OSTI)

The integrity of coatings used in hot section components of combustion turbines is crucial to the reliability of the buckets. This project was initiated in recognition of the need for predicting the life of coatings analytically, and non-destructively; correspondingly, four principal tasks were established. Task 1, with the objective of analytically developing stress, strain and temperature distributions in the bucket and thereby predicting thermal fatigue (TMF) damage for various operating conditions; Task 2 with the objective of developing eddy current techniques to measure both TMF damage and general degradation of coatings and, Task 3 with the objective of developing mechanism based algorithms. Task 4 is aimed at verifying analytical predictions from Task 1 and the NDE predictions from Task 3 against field observations.

D. Gandy; R. Viswanathan; S. Cheruvu; K. Krzywosz

2006-03-31T23:59:59.000Z

288

COMBUSTION TURBINE (CT) HOT SECTION COATING LIFE MANAGEMENT  

SciTech Connect (OSTI)

The integrity of coatings used in hot section components of combustion turbine is crucial to the reliability of the buckets. This project was initiated in recognition of the need for predicting the life of coatings analytically, and non destructively; correspondingly, three principal tasks were established. Task 1, with the objective of analytically developing stress, strain and temperature distributions in the bucket and thereby predicting thermal fatigue (TMF) damage for various operating conditions; Task 2 with the objective of developing eddy current techniques to measure both TMF damage and general degradation of coatings and, Task 3, with the objective of developing mechanism based algorithms. This report is a record of the progress to date on these 3 key tasks. Two supporting tasks relating to field validation (Task 4) and economic analysis (Task 5) have not yet been initiated.

R. Viswanathan; D. Gandy; K. Krzywosz; S. Cheruvu; E. Wan

2002-12-02T23:59:59.000Z

289

HIGHWAY INFRASTRUCTURE FOCUS AREA NEXT-GENERATION INFRASTRUCTURE MATERIALS VOLUME I - TECHNICAL PROPOSAL & MANAGEMENTENHANCEMENT OF TRANSPORTATION INFRASTRUCTURE WITH IRON-BASED AMORPHOUS-METAL AND CERAMIC COATINGS  

SciTech Connect (OSTI)

The infrastructure for transportation in the United States allows for a high level of mobility and freight activity for the current population of 300 million residents, and several million business establishments. According to a Department of Transportation study, more than 230 million motor vehicles, ships, airplanes, and railroads cars were used on 6.4 million kilometers (4 million miles) of highways, railroads, airports, and waterways in 1998. Pipelines and storage tanks were considered to be part of this deteriorating infrastructure. The annual direct cost of corrosion in the infrastructure category was estimated to be approximately $22.6 billion in 1998. There were 583,000 bridges in the United States in 1998. Of this total, 200,000 bridges were steel, 235,000 were conventional reinforced concrete, 108,000 bridges were constructed using pre-stressed concrete, and the balance was made using other materials of construction. Approximately 15 percent of the bridges accounted for at this point in time were structurally deficient, primarily due to corrosion of steel and steel reinforcement. Iron-based amorphous metals, including SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe{sub 48}Mo{sub 14}Cr{sub 15}Y{sub 2}C{sub 15}B{sub 6}) have been developed, and have very good corrosion resistance. These materials have been prepared as a melt-spun ribbons, as well as gas atomized powders and thermal-spray coatings. During electrochemical testing in several environments, including seawater at 90 C, the passive film stabilities of these materials were found to be comparable to that of more expensive high-performance alloys, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates. These materials also performed very well in standard salt fog tests. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. These amorphous alloys appear to maintain their corrosion resistance up to the glass transition temperature. Visionary research is proposed to extend the application of corrosion-resistant iron-based amorphous metal coatings, and variants of these coatings, to protection of the Nation's transportation infrastructure. Specific objectives of the proposed work are: (1) fabrication of appropriate test samples for evaluation of concept; (2) collection of production and test data for coated steel reinforcement bars, enabling systematic comparison of various coating options, based upon performance and economic considerations; and (3) construction and testing of concrete structures with coated steel reinforcement bars, thereby demonstrating the value of amorphous-metal coatings. The benefits of ceramic coatings as thermal barriers will also be addressed.

Farmer, J C

2007-12-04T23:59:59.000Z

290

Observations of Ferroelastic Switching by Raman Spectroscopy  

E-Print Network [OSTI]

Thermal barrier coatings (TBCs) have become an important part of turbine technology by providing thermal protection to the underlying metallic components. These coatings are typically made from a zirconia-based ceramics which have a low thermal...

Bolon, Amy Marie

2012-02-14T23:59:59.000Z

291

Ceramic electrolyte coating and methods  

DOE Patents [OSTI]

Aqueous coating slurries useful in depositing a dense coating of a ceramic electrolyte material (e.g., yttrium-stabilized zirconia) onto a porous substrate of a ceramic electrode material (e.g., lanthanum strontium manganite or nickel/zirconia) and processes for preparing an aqueous suspension of a ceramic electrolyte material and an aqueous spray coating slurry including a ceramic electrolyte material. The invention also includes processes for depositing an aqueous spray coating slurry including a ceramic electrolyte material onto pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.

Seabaugh, Matthew M. (Columbus, OH); Swartz, Scott L. (Columbus, OH); Dawson, William J. (Dublin, OH); McCormick, Buddy E. (Dublin, OH)

2007-08-28T23:59:59.000Z

292

High-Performance Nanostructured Coating  

Broader source: Energy.gov (indexed) [DOE]

design utilizing a nanoparticle in dielectric matrix approach is used to achieve high optical performance. New refractory materials are used to either make or coat the...

293

Engineered Barrier System: Physical and Chemical Environment Model  

SciTech Connect (OSTI)

The conceptual and predictive models documented in this Engineered Barrier System: Physical and Chemical Environment Model report describe the evolution of the physical and chemical conditions within the waste emplacement drifts of the repository. The modeling approaches and model output data will be used in the total system performance assessment (TSPA-LA) to assess the performance of the engineered barrier system and the waste form. These models evaluate the range of potential water compositions within the emplacement drifts, resulting from the interaction of introduced materials and minerals in dust with water seeping into the drifts and with aqueous solutions forming by deliquescence of dust (as influenced by atmospheric conditions), and from thermal-hydrological-chemical (THC) processes in the drift. These models also consider the uncertainty and variability in water chemistry inside the drift and the compositions of introduced materials within the drift. This report develops and documents a set of process- and abstraction-level models that constitute the engineered barrier system: physical and chemical environment model. Where possible, these models use information directly from other process model reports as input, which promotes integration among process models used for total system performance assessment. Specific tasks and activities of modeling the physical and chemical environment are included in the technical work plan ''Technical Work Plan for: In-Drift Geochemistry Modeling'' (BSC 2004 [DIRS 166519]). As described in the technical work plan, the development of this report is coordinated with the development of other engineered barrier system analysis model reports.

D. M. Jolley; R. Jarek; P. Mariner

2004-02-09T23:59:59.000Z

294

Systems study on engineered barriers: barrier performance analysis  

SciTech Connect (OSTI)

A performance assessment model for multiple barrier packages containing unreprocessed spent fuel has been modified and applied to several package designs. The objective of the study was to develop information to be used in programmatic decision making concerning engineered barrier package design and development. The assessment model, BARIER, was developed in previous tasks of the System Study on Engineered Barriers (SSEB). The new version discussed in this report contains a refined and expanded corrosion rate data base which includes pitting, crack growth, and graphitization as well as bulk corrosion. Corrosion rates for oxic and anoxic conditions at each of the two temperature ranges are supplied. Other improvements include a rigorous treatment of radionuclide release after package failure which includes resistance of damaged barriers and backfill, refined temperature calculations that account for convection and radiation, a subroutine to calculate nuclear gamma radiation field at each barrier surface, refined stress calculations with reduced conservatism and various coding improvements to improve running time and core usage. This report also contains discussion of alternative scenarios to the assumed flooded repository as well as the impact of water exclusion backfills. The model was used to assess post repository closure performance for several designs which were all variation of basic designs from the Spent Unreprocessed Fuel (SURF) program. Many designs were found to delay the onset of leaching by at least a few hundreds of years in all geologic media. Long delay times for radionuclide release were found for packages with a few inches of sorption backfill. Release of uranium, plutonium, and americium was assessed.

Stula, R.T.; Albert, T.E.; Kirstein, B.E.; Lester, D.H.

1980-09-01T23:59:59.000Z

295

Electron-stimulated desorption from polished and vacuum fired 316LN stainless steel coated with Ti-Zr-Hf-V  

SciTech Connect (OSTI)

In this study, two identical 316LN stainless steel tubular samples, which had previously been polished and vacuum-fired and then used for the electron-stimulated desorption (ESD) experiments, were coated with Ti-Zr-Hf-V with different morphologies: columnar and dense. ESD measurement results after nonevaporable getter (NEG) activation to 150, 180, 250, and 350?°C indicated that the values for the ESD yields are significantly (2–20 times) lower than the data from our previous study with similar coatings on nonvacuum-fired samples. Based on these results, the lowest pressure and best long-term performance in particle accelerators will be achieved with a vacuum-fired vacuum chamber coated with dense Ti-Zr-Hf-V coating activated at 180?°C. This is likely due to the following facts: after NEG activation, the hydrogen concentration inside the NEG was lower than in the bulk stainless steel substrate; the NEG coating created a barrier for gas diffusion from the sample bulk to vacuum; the dense NEG coating performed better as a barrier than the columnar NEG coating.

Malyshev, Oleg B., E-mail: oleg.malyshev@stfc.ac.uk; Valizadeh, Reza; Hogan, Benjamin T.; Hannah, Adrian N. [ASTeC, STFC Daresbury Laboratory, Daresbury, Warrington, WA4 4AD Cheshire (United Kingdom)

2014-11-01T23:59:59.000Z

296

Vented Cavity Radiant Barrier Assembly And Method  

DOE Patents [OSTI]

A vented cavity radiant barrier assembly (2) includes a barrier (12), typically a PV module, having inner and outer surfaces (18, 22). A support assembly (14) is secured to the barrier and extends inwardly from the inner surface of the barrier to a building surface (14) creating a vented cavity (24) between the building surface and the barrier inner surface. A low emissivity element (20) is mounted at or between the building surface and the barrier inner surface. At least part of the cavity exit (30) is higher than the cavity entrance (28) to promote cooling air flow through the cavity.

Dinwoodie, Thomas L. (Piedmont, CA); Jackaway, Adam D. (Berkeley, CA)

2000-05-16T23:59:59.000Z

297

Carbonaceous film coating  

DOE Patents [OSTI]

A method of making a carbonaceous film comprising heating tris(1,3,2-benzodiazaborolo)borazine or dodecahydro tris(1,3,2)diazaborine(1,2-a:1'2'-c:1''2''-e)borazine in an inert atmosphere in the presence of a substrate to a temperature at which the borazine compound decomposes, and the decomposition products deposit onto the substrate to form a thin, tenacious, highly reflective conductive coating having a narrow band gap which is susceptible of modification and a relatively low coefficient of friction.

Maya, L.

1988-04-27T23:59:59.000Z

298

Thermal Analysis of Novel Underfill Materials with Optimum Processing Characteristics  

E-Print Network [OSTI]

Thermal Analysis of Novel Underfill Materials with Optimum Processing Characteristics Yang Liu,1 Yi evolution. Boron nitride, silica-coated alu- minum nitride, and alumina ceramic powders were used as fillers poly- merization. The effects of the filler type and composition on the thermal and mechanical

Harmon, Julie P.

299

Plastic Schottky barrier solar cells  

DOE Patents [OSTI]

A photovoltaic cell structure is fabricated from an active medium including an undoped, intrinsically p-type organic semiconductor comprising polyacetylene. When a film of such material is in rectifying contact with a magnesium electrode, a Schottky-barrier junction is obtained within the body of the cell structure. Also, a gold overlayer passivates the magnesium layer on the undoped polyacetylene film.

Waldrop, James R. (Thousand Oaks, CA); Cohen, Marshall J. (Thousand Oaks, CA)

1984-01-24T23:59:59.000Z

300

A View of Compatible Heat-Resistant Alloy and Coating Systems at High-Temperatures  

SciTech Connect (OSTI)

Conventional and advanced coatings were reviewed, and it was pointed out that the coated Ni-base superalloys decreased their creep rupture life significantly at higher temperatures, and the advanced high strength superalloy became more remarkably. Concept of diffusion barrier coating system (DBC system) and their formation process was introduced, and the results obtained for several heat-resistant alloys, stainless steel (SUS310S), Ni-Mo base alloy (Hastelloy-X), and 4{sup th} generation single crystal superalloy (TMS-138) were given. It was noted that creep-rupture life of the SUS310S and Hastelloy-X with the DBC system became longer than those of the bare alloys with or without conventional {beta}-NiAl coatings. This is due to slow creep-deformation of the Re-base alloy layer as the diffusion barrier. A novel concept based on combination of superalloys and coatings was proposed, by taking both the materials science and corrosion science into consideration.

Narita, Toshio [Specially Promoted Research Laboratory of Advanced Coatings, Hokkaido University, Kite-13 Nishi-8, Kita-Ku, Sapporo 060-8628 (Japan)

2009-09-14T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Sol-Gel Deposited Electrochromic Coatings  

E-Print Network [OSTI]

R A T O R Y Sol-Gel Deposited Electrochromic Coatings NilgunUC-1600 Sol-Gel Deposited Electrochromic Coatings NilgunPaper Sol-gel Deposited Electrochromic Coatings Nilgun Ozer

Ozer, N.

2010-01-01T23:59:59.000Z

302

NANOSCALE BOEHMITE FILLER FOR CORROSION AND WEAR RESISTANT POLYPHENYLENESULFIDE COATINGS.  

SciTech Connect (OSTI)

The authors evaluated the usefulness of nanoscale boehmite crystals as a filler for anti-wear and anti-corrosion polyphenylenesulfide (PPS) coatings exposed to a very harsh, 300 C corrosive geothermal environment. The boehmite fillers dispersed uniformly into the PPS coating, conferring two advanced properties: First, they reduced markedly the rate of blasting wear; second, they increased the PPS's glass transition temperature and thermal decomposition temperature. The wear rate of PPS surfaces was reduced three times when 5wt% boehmite was incorporated into the PPS. During exposure for 15 days at 300 C, the PPS underwent hydrothermal oxidation, leading to the substitution of sulfide linkages by the sulfite linkages. However, such molecular alteration did not significantly diminish the ability of the coating to protect carbon steel against corrosion. In fact, PPS coating filled with boehmite of {le} 5wt% adequately mitigated its corrosion in brine at 300 C. One concern in using this filler was that it absorbs brine. Thus, adding an excess amount of boehmite was detrimental to achieving the maximum protection afforded by the coatings.

SUGAMA,T.

2003-06-26T23:59:59.000Z

303

E-Print Network 3.0 - aluminas sinterizadas visando Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering 45 Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings Summary: to estimate upper and lower bounds of the transverse thermal resistance...

304

E-Print Network 3.0 - alumina untuk bahan Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization 50 Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings Summary: to estimate upper and lower bounds of the transverse thermal resistance...

305

E-Print Network 3.0 - alumina determinacion espectrografica Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization 40 Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings Summary: to estimate upper and lower bounds of the transverse thermal resistance...

306

Performance of composite coatings in a coal-fired boiler environment  

SciTech Connect (OSTI)

Four samples of thermal spray coatings, each made from different core wire consumables by twin wire arc spray, were exposed for 18 months in a coal-fired boiler environment. The tests are described and the performance of each coating is evaluated. Results indicated that the four consumable wire alloys showed remarkable resistance to fly ash erosion and corrosion over the period of the test.

Nava, J.C. [ME Technical Services, Bridgeton, MO (United States)

2009-09-15T23:59:59.000Z

307

Novel Non Chrome Processes for the Protection of Metal For commercial applications, specially formulated conversion coating treatments based  

E-Print Network [OSTI]

industries. Chromate coatings are favored due to their barrier and corrosion resistance properties. Chromium deposition is obtained from hexavalent Cr salt baths, which are subject to stringent regulations. Due is a temporary solution and it also toxic. Silica is a white, crystalline solid with a tetrahedral crystalline

Popov, Branko N.

308

Thin film ion conducting coating  

DOE Patents [OSTI]

Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

Goldner, Ronald B. (Lexington, MA); Haas, Terry (Sudbury, MA); Wong, Kwok-Keung (Watertown, MA); Seward, George (Arlington, MA)

1989-01-01T23:59:59.000Z

309

Overcoming Multifamily Sector Barriers in Austin, Texas  

Broader source: Energy.gov [DOE]

Presents techniques on overcoming the barriers of multifamily energy efficiency projects, including how to market to property managers.

310

Heat barrier for use in a nuclear reactor facility  

DOE Patents [OSTI]

A thermal barrier for use in a nuclear reactor facility is disclosed herein. Generally, the thermal barrier comprises a flexible, heat-resistant web mounted over the annular space between the reactor vessel and the guard vessel in order to prevent convection currents generated in the nitrogen atmosphere in this space from entering the relatively cooler atmosphere of the reactor cavity which surrounds these vessels. Preferably, the flexible web includes a blanket of heat-insulating material formed from fibers of a refractory material, such as alumina and silica, sandwiched between a heat-resistant, metallic cloth made from stainless steel wire. In use, the web is mounted between the upper edges of the guard vessel and the flange of a sealing ring which surrounds the reactor vessel with a sufficient enough slack to avoid being pulled taut as a result of thermal differential expansion between the two vessels. The flexible web replaces the rigid and relatively complicated structures employed in the prior art for insulating the reactor cavity from the convection currents generated between the reactor vessel and the guard vessel.

Keegan, Charles P. (South Huntingdon Twp., Westmoreland County, PA)

1988-01-01T23:59:59.000Z

311

Sol-Gel Deposited Electrochromic Coatings  

E-Print Network [OSTI]

Handbook of Inorganic Electrochromic Materials, Elsevier, .O R Y Sol-Gel Deposited Electrochromic Coatings Nilgun Ozer1600 Sol-Gel Deposited Electrochromic Coatings Nilgun Ozer

Ozer, N.

2010-01-01T23:59:59.000Z

312

Shirley Coates Brostmeyer: Changing the (Engineering) Game |...  

Broader source: Energy.gov (indexed) [DOE]

Coates Brostmeyer holds FTTs twin-spool turbofan, the most efficient micro-turbine of its size | credit Frank Serio Shirley Coates Brostmeyer holds FTT's twin-spool...

313

Numerical Valuation of Discrete Barrier Options with  

E-Print Network [OSTI]

Numerical Valuation of Discrete Barrier Options with the Adaptive Mesh Model and Other Competing for discrete barrier options such that many methods have been suggested and declared to price discrete barrier options fast and accurately but no one can tell exactly that what method is the best. We also make

Chu, Hao-hua

314

Ceramic composite coating  

DOE Patents [OSTI]

A thin, room-temperature-curing, ceramic composite for coating and patching etal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

Wicks, George G. (Aiken, SC)

1997-01-01T23:59:59.000Z

315

Ceramic composite coating  

DOE Patents [OSTI]

A thin, room-temperature-curing, ceramic composite for coating and patching metal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

Wicks, G.G.

1997-01-21T23:59:59.000Z

316

REVUE DE PHYSIQUE APPLIQUE A complex investigation of structure and properties of thermally sprayed  

E-Print Network [OSTI]

performed on the bonding mechanism between the sprayed coating and the substrate [2, 3]. The thermal diffusivity and thermal effusivity coefficients as well as the thermal conductivity and the specific heat° to Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/rphysap

Paris-Sud XI, Université de

317

Thermal-wave nondestructive evaluation of cylindrical composite structures using frequency-domain photothermal radiometry  

E-Print Network [OSTI]

.e., a cylindrical material with a surface coating and a cylindrical tube filled with a low thermal-conductivity the thermal-wave field of a cylindrical composite material, the Green function corresponding to the composite development of photo- thermal techniques has allowed the evaluation not only of homogeneous materials5

Mandelis, Andreas

318

Ceramic coating system or water oxidation environments  

DOE Patents [OSTI]

A process for water oxidation of combustible materials in which during at least a part of the oxidation corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises titanium dioxide coated onto a titanium metal substrate. Such ceramic composites have been found to be highly resistant to environments encountered in the process of supercritical water oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases, and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 700.degree. C. The ceramic composites are also resistant to degradation mechanisms caused by thermal stresses.

Hong, Glenn T. (Tewksbury, MA)

1996-01-01T23:59:59.000Z

319

Cryogenic Barrier Demonstration Project. Final report  

SciTech Connect (OSTI)

A long-term frozen soil barrier was implemented at the HRE (Homogeneous Reactor Experiment) Pond facility at the Oak Ridge National Laboratory in 1997. This was performed to verify the technical feasibility and costs of deploying a frozen barrier at a radiologically contaminated site. Work began in September 1996 and progressed through to December 1999. The frozen barrier has been operational since November 1997. Verification of the barrier integrity was performed independently by the EPA's SITE Program. This project showed frozen barriers offer a proven technology to retain below grade hazardous substances at relatively low costs with minimal effect on the environment.

Johnson, L.A.; Yarmak, E.; Long, E.L.

2000-03-01T23:59:59.000Z

320

Energy Efficiency Projects: Overcoming Internal Barriers to Implementa...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Energy Efficiency Projects: Overcoming Internal Barriers to Implementation Energy Efficiency Projects: Overcoming Internal Barriers to Implementation This presentation discusses...

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Environmental Technology Verification Coatings and Coating Equipment Program (ETV CCEP)  

E-Print Network [OSTI]

.2 Quality Assurance for the ETV CCEP.....................................................................1.................................................................11 2.2.12 Determination of Total Volatile Content of the UV-Curable Coating.......14 2.3 Schedule.0 QUALITY ASSURANCE OBJECTIVES.......................................

322

barrier  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste andAnniversary, partReview64,783 56,478Tidd Optical Depthbarrier

323

Development of Recycling Compatible Pressure-Sensitive Adhesives and Coatings  

SciTech Connect (OSTI)

The objective of this project was the design of new water-based pressure-sensitive adhesive (PSA) products and coatings engineered for enhanced removal during the processing of recycled fiber. Research included the formulation, characterization, and performance measurements of new screenable coatings, testing of modified paper and board substrates and the design of test methods to characterize the inhibition of adhesive and coating fragmentation and relative removal efficiencies of developed formulations. This project was operated under the requirements that included commercially viable approaches be the focus, that findings be published in the open literature and that new strategies could not require changes in the methods and equipment used to produce PSA and PS labels or in the recycling process. The industrial partners benefited through the building of expertise in their company that they would not, and likely could not, have pursued if it had not been for the partnership. Results of research on water-based PSAs clearly identifies which PSA and paper facestock properties govern the fragmentation of the adhesive and provide multiple strategies for making (pressure-sensitive) PS labels for which the PSA is removed at very high efficiencies from recycling operations. The application of these results has led to the identification of several commercial products in Franklin International’s (industrial partner) product line that are recycling compatible. Several new formulations were also designed and are currently being scaled-up. Work on recycling compatible barrier coatings for corrugated containers examined the reinforcement of coatings using a small amount of exfoliated organically modified montmorillonite (OMMT). These OMMT/paraffin wax nanocomposites demonstrated significantly improved mechanical properties. Paraffin waxes containing clay were found to have significantly higher Young’s moduli and yield stress relative to the wax matrix, but the most impressive finding was the impact of the clay on the elongation at break; a nearly 400% increase was observed for a clay concentration of 0.5 wt.%. These coatings also demonstrate a number of other property enhancements, which make them a good candidate for continued research. Another approach explored in this research was the use of structured and self-cleaning surfaces. If the amount of coating utilized can be significantly reduced, the environmental impact is diminished.

Steven J. Severtson

2010-02-15T23:59:59.000Z

324

Method of measuring metal coating adhesion  

DOE Patents [OSTI]

A method for measuring metal coating adhesion to a substrate material comprising the steps of preparing a test coupon of substrate material having the metal coating applied to one surface thereof, applying a second metal coating of gold or silver to opposite surfaces of the test coupon by hot hollow cathode process, applying a coating to one end of each of two pulling rod members, joining the coated ends of the pulling rod members to said opposite coated surfaces of the test coupon by a solid state bonding technique and finally applying instrumented static tensile loading to the pulling rod members until fracture of the metal coating adhesion to the substrate material occurs.

Roper, John R. (Northglenn, CO)

1985-01-01T23:59:59.000Z

325

Prime coats materials and methods  

E-Print Network [OSTI]

A prime coat is the application of a suitable bituminous binder applied to a nonbituminous granular base as a preliminary treatment before the application of a bituminous surfacing. The purpose of this research is to establish practical applications...

Mantilla, Christian Augusto

1994-01-01T23:59:59.000Z

326

Corrosion resistant neutron absorbing coatings  

DOE Patents [OSTI]

A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

Choi, Jor-Shan; Farmer, Joseph C; Lee, Chuck K; Walker, Jeffrey; Russell, Paige; Kirkwood, Jon; Yang, Nancy; Champagne, Victor

2013-11-12T23:59:59.000Z

327

Corrosion resistant neutron absorbing coatings  

DOE Patents [OSTI]

A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

Choi, Jor-Shan (El Cerrito, CA); Farmer, Joseph C. (Tracy, CA); Lee, Chuck K. (Hayward, CA); Walker, Jeffrey (Gaithersburg, MD); Russell, Paige (Las Vegas, NV); Kirkwood, Jon (Saint Leonard, MD); Yang, Nancy (Lafayette, CA); Champagne, Victor (Oxford, PA)

2012-05-29T23:59:59.000Z

328

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

Fontana, J.J.; Elling, D.; Reams, W.

1988-05-26T23:59:59.000Z

329

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

1990-01-01T23:59:59.000Z

330

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

Fontana, J.J.; Elling, D.; Reams, W.

1990-03-13T23:59:59.000Z

331

Structurally Integrated Coatings for Wear and Corrosion  

SciTech Connect (OSTI)

Wear and corrosion of structures cuts across industries and continues to challenge materials scientists and engineers to develop cost effective solutions. Industries typically seek mature technologies that can be implemented for production with rapid or minimal development and have little appetite for the longer-term materials research and development required to solve complex problems. The collaborative work performed in this project addressed the complexity of this problem in a multi-year program that industries would be reluctant to undertake without government partnership. This effort built upon the prior development of Advanced Abrasion Resistant Materials conduct by Caterpillar Inc. under DOE Cooperative Agreement No. DE-FC26-01NT41054. In this referenced work, coatings were developed that exhibited significant wear life improvements over standard carburized heat treated steel in abrasive wear applications. The technology used in this referenced work, arc lamp fusing of thermal spray coatings, was one of the primary technical paths in this work effort. In addition to extending the capability of the coating technology to address corrosion issues, additional competitive coating technologies were evaluated to insure that the best technology was developed to meet the goals of the program. From this, plasma transferred arc (PTA) welding was selected as the second primary technology that was investigated. Specifically, this project developed improved, cost effective surfacing materials and processes for wear and corrosion resistance in both sliding and abrasive wear applications. Materials with wear and corrosion performance improvements that are 4 to 5 times greater than heat treated steels were developed. The materials developed were based on low cost material systems utilizing ferrous substrates and stainless steel type matrix with hard particulates formed from borides and carbides. Affordability was assessed against other competing hard surfacing or coating techniques, balanced with overall materials performance. State-of-the-art design and simulation capabilities were used to guide materials and process refinement. Caterpillar was the lead of the multi-partner collaborative project. Specific tasks were performed by the partners base on their unique capabilities. The project team was selected to include leaders in the field of material development, processing, modeling, and material characterization. Specifically, industrial members include the suppliers Deloro Stellite and Powder Alloy Corporation., who provided the experimental alloys and who aided in the development of the costs for the alloys, the Missouri University of Science and Technology and Iowa State University, who provided help in the alloy development and material characterization, QuesTek Innovations, a small company specializing the microstructural modeling of materials, and the DOE laboratories, Oak Ridge National Laboratory and National Energy Technology Laboratory (Albany), who provided unique coating process capability and wear characterization testing. The technologies developed in this program are expected to yield energy savings of about 50% over existing technologies, or 110 trillion BTUs per year by 2020 when fully implemented. Primary applications by Caterpillar are to replace the surface of machine components which are currently carburized and heat treated with new cladding materials with double the wear life. The new cladding technologies will consume less energy than carburizing. Thus, nearly 50% energy savings can be expected as a result from elimination of the heat treat process and the reduce wear of the materials. Additionally, when technologies from this project are applied on titanium or other non-ferrous substrates to make lighter weight, more wear resistant, and more efficient structures, significant fuel savings can be realized. With the anticipated drastic reduction in cost for refining titanium-containing ores, the usage of titanium alloys in earthmoving and related machinery is expected to increase multiple folds in the next d

Beardsley, M. Brad; Sebright, Jason L.

2008-11-18T23:59:59.000Z

332

Reaction synthesis of Ni-Al based particle composite coatings  

SciTech Connect (OSTI)

Electrodeposited metal matrix/metal particle composite (EMMC) coatings were produced with a nickel matrix and aluminum particles. By optimizing the process parameters, coatings were deposited with 20 volume percent aluminum particles. Coating morphology and composition were characterized using light optical microscopy (LOM), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). Differential thermal analysis (DTA) was employed to study reactive phase formation. The effect of heat treatment on coating phase formation was studied in the temperature range 415 to 1,000 C. Long-time exposure at low temperature results in the formation of several intermetallic phases at the Ni matrix/Al particle interfaces and concentrically around the original Al particles. Upon heating to the 500--600 C range, the aluminum particles react with the nickel matrix to form NiAl islands within the Ni matrix. When exposed to higher temperatures (600--1,000 C), diffusional reaction between NiAl and nickel produces ({gamma})Ni{sub 3}Al. The final equilibrium microstructure consists of blocks of ({gamma}{prime})Ni{sub 3}Al in a {gamma}(Ni) solid solution matrix, with small pores also present. Pore formation is explained based on local density changes during intermetallic phase formation and microstructural development is discussed with reference to reaction synthesis of bulk nickel aluminides.

SUSAN,DONALD F.; MISIOLEK,WOICECK Z.; MARDER,ARNOLD R.

2000-02-11T23:59:59.000Z

333

High Temperature Corrosion Behavior of Iron Aluminide Alloys and Coatings  

SciTech Connect (OSTI)

A multi-year effort has been focused on optimizing the long-term oxidation performance of ingot-processed (IP) and oxide-dispersion strengthened (ODS) Fe{sub 3}Al and iron aluminide-based coatings. Based on results from several composition iterations, a Hf-doped alloy (Fe-28Al-2Cr-0.05at.%Hf) has been developed with significantly better high temperature oxidation resistance than other iron aluminides. The scale adhesion is not significantly better; however, the {alpha}-Al{sub 2}O{sub 3} scale grows at a slower rate, approximately a factor of 10 less than undoped iron aluminide. The benefit of Hf is greatest at 1100-1200 C. Long-term oxidation resistance of commercially fabricated ODS Fe{sub 3}Al has been determined and compared to commercially available ODS FeCrAl. Scale spallation rates for ODS Fe{sub 3}Al are higher than for ODS FeCrAl. To complement studies of iron-aluminide weld-overlay coatings, carbon steel was coated with Fe-Al-Cr by thermal spraying. These specimens were then exposed in air at 900 and 1000 C and in air-1%SO{sub 2} at 800 C. Most likely due to an inadequate aluminum concentration in the coatings, continuous protective Al{sub 2}O{sub 3} could not be maintained and, consequently, the corrosion performance was significantly worse than what is normally observed for Fe{sub 3}Al.

Pint, B.A.

2001-10-22T23:59:59.000Z

334

Nanoscale thermal transport. II. 2003–2012  

SciTech Connect (OSTI)

A diverse spectrum of technology drivers such as improved thermal barriers, higher efficiency thermoelectric energy conversion, phase-change memory, heat-assisted magnetic recording, thermal management of nanoscale electronics, and nanoparticles for thermal medical therapies are motivating studies of the applied physics of thermal transport at the nanoscale. This review emphasizes developments in experiment, theory, and computation in the past ten years and summarizes the present status of the field. Interfaces become increasingly important on small length scales. Research during the past decade has extended studies of interfaces between simple metals and inorganic crystals to interfaces with molecular materials and liquids with systematic control of interface chemistry and physics. At separations on the order of ?1?nm, the science of radiative transport through nanoscale gaps overlaps with thermal conduction by the coupling of electronic and vibrational excitations across weakly bonded or rough interfaces between materials. Major advances in the physics of phonons include first principles calculation of the phonon lifetimes of simple crystals and application of the predicted scattering rates in parameter-free calculations of the thermal conductivity. Progress in the control of thermal transport at the nanoscale is critical to continued advances in the density of information that can be stored in phase change memory devices and new generations of magnetic storage that will use highly localized heat sources to reduce the coercivity of magnetic media. Ultralow thermal conductivity—thermal conductivity below the conventionally predicted minimum thermal conductivity—has been observed in nanolaminates and disordered crystals with strong anisotropy. Advances in metrology by time-domain thermoreflectance have made measurements of the thermal conductivity of a thin layer with micron-scale spatial resolution relatively routine. Scanning thermal microscopy and thermal analysis using proximal probes has achieved spatial resolution of 10?nm, temperature precision of 50 mK, sensitivity to heat flows of 10 pW, and the capability for thermal analysis of sub-femtogram samples.

Cahill, David G., E-mail: d-cahill@illinois.edu; Braun, Paul V. [Department of Materials Science and Engineering and the Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801 (United States); Chen, Gang [Department of Mechanical Engineering, MIT, Cambridge, Massachusetts 02139 (United States); Clarke, David R. [School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States); Fan, Shanhui [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States); Goodson, Kenneth E. [Department of Mechanical Engineering, Stanford University, Stanford, California 94305 (United States); Keblinski, Pawel [Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); King, William P. [Department of Mechanical Sciences and Engineering, University of Illinois, Urbana, Illinois 61801 (United States); Mahan, Gerald D. [Department of Physics, Penn State University, University Park, Pennsylvania 16802 (United States); Majumdar, Arun [Department of Mechanical Engineering, University of California, Berkeley, California 94720 (United States); Maris, Humphrey J. [Department of Physics, Brown University, Providence, Rhode Island 02912 (United States); Phillpot, Simon R. [Department of Materials Science and Engineering, University of Florida, Gainseville, Florida 32611 (United States); Pop, Eric [Department of Electrical and Computer Engineering, University of Illinois, Urbana, Illinois 61801 (United States); Shi, Li [Department of Mechanical Engineering, University of Texas, Autin, Texas 78712 (United States)

2014-03-15T23:59:59.000Z

335

International Collaborations on Engineered Barrier Systems: Experiment...  

Broader source: Energy.gov (indexed) [DOE]

interaction to evaluate sealing and clay barrier performance; 2) EBS Experiment -thermo-hydro-mechanical-chemical (THMC) behavior of the EBS under heating conditions and...

336

Rejuvenating Permeable Reactive Barriers by Chemical Flushing  

Broader source: Energy.gov [DOE]

Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

337

Manufacturing Barriers to High Temperature PEM Commercialization...  

Broader source: Energy.gov (indexed) [DOE]

Barriers to High Temperature PEM Commercialization Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop in Washington, DC, August 11-12, 2011....

338

BIBLIOGRAPHY ON INSTITUTIONAL BARRIERS TO ENERGY CONSERVATION  

E-Print Network [OSTI]

Institutional Barriers to Energy Conservation C. M. York, C.P.R. , 1973. "Energy Conservation in Buildings: ItsS. (eds. ), 1973. Energy Conservation: Implica­ tions for

York, C.M.

2011-01-01T23:59:59.000Z

339

Low thermal distortion extreme-UV lithography reticle  

DOE Patents [OSTI]

Thermal distortion of reticles or masks can be significantly reduced by emissivity engineering, i.e., the selective placement or omission of coatings on the reticle. Reflective reticles so fabricated exhibit enhanced heat transfer thereby reducing the level of thermal distortion and ultimately improving the quality of the transcription of the reticle pattern onto the wafer. Reflective reticles include a substrate having an active region that defines the mask pattern and non-active region(s) that are characterized by a surface that has a higher emissivity than that of the active region. The non-active regions are not coated with the radiation reflective material.

Gianoulakis, Steven E. (Albuquerque, NM); Ray-Chaudhuri, Avijit K. (Livermore, CA)

2001-01-01T23:59:59.000Z

340

Low thermal distortion extreme-UV lithography reticle  

DOE Patents [OSTI]

Thermal distortion of reticles or masks can be significantly reduced by emissivity engineering, i.e., the selective placement or omission of coatings on the reticle. Reflective reticles so fabricated exhibit enhanced heat transfer thereby reducing the level of thermal distortion and ultimately improving the quality of the transcription of the reticle pattern onto the wafer. Reflective reticles include a substrate having an active region that defines the mask pattern and non-active region(s) that are characterized by a surface that has a higher emissivity than that of the active region. The non-active regions are not coated with the radiation reflective material.

Gianoulakis, Steven E. (Albuquerque, NM); Ray-Chaudhuri, Avijit K. (Livermore, CA)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Low thermal distortion Extreme-UV lithography reticle and method  

DOE Patents [OSTI]

Thermal distortion of reticles or masks can be significantly reduced by emissivity engineering, i.e., the selective placement or omission of coatings on the reticle. Reflective reticles so fabricated exhibit enhanced heat transfer thereby reducing the level of thermal distortion and ultimately improving the quality of the transcription of the reticle pattern onto the wafer. Reflective reticles include a substrate having an active region that defines the mask pattern and non-active region(s) that are characterized by a surface that has a higher emissivity than that of the active region. The non-active regions are not coated with the radiation reflective material.

Gianoulakis, Steven E. (Albuquerque, NM); Ray-Chaudhuri, Avijit K. (Livermore, CA)

2002-01-01T23:59:59.000Z

342

Tungsten Coating on Low Activation Vanadium Alloy by Plasma Spray Process  

SciTech Connect (OSTI)

Tungsten (W) coating on fusion candidate V-4Cr-4Ti (NIFS-HEAT-2) substrate was demonstrated with plasma spray process for the purpose of applying to protection of the plasma facing surface of a fusion blanket. Increase in plasma input power and temperature of the substrate was effective to reduce porosity of the coating, but resulted in hardening of the substrate and degradation of impact property at 77 K. The hardening seemed to be due to contamination with gaseous impurities and deformation by thermal stress during the coating process. Since all the samples showed good ductility at room temperature, further heating seems to be acceptable for the vanadium substrate. The fracture stress of the W coating was estimated from bending tests as at least 313 MPa, which well exceeds the design stress for the vanadium structure in fusion blanket.

Nagasaka, Takuya [National Institute for Fusion Science (Japan); Muroga, Takeo [National Institute for Fusion Science (Japan); Noda, Nobuaki [National Institute for Fusion Science (Japan); Kawamura, Masashi [Kawasaki Heavy Industries, LTD (Japan); Ise, Hideo [Kawasaki Heavy Industries, LTD (Japan); Kurishita, Hiroaki [Tohoku University (Japan)

2005-05-15T23:59:59.000Z

343

Advanced Hot Section Materials and Coatings Test Rig  

SciTech Connect (OSTI)

Phase I of the Hyperbaric Advanced Hot Section Materials & Coating Test Rig Program has been successfully completed. Florida Turbine Technologies has designed and planned the implementation of a laboratory rig capable of simulating the hot gas path conditions of coal gas fired industrial gas turbine engines. Potential uses of this rig include investigations into environmental attack of turbine materials and coatings exposed to syngas, erosion, and thermal-mechanical fatigue. The principle activities during Phase 1 of this project included providing several conceptual designs for the test section, evaluating various syngas-fueled rig combustor concepts, comparing the various test section concepts and then selecting a configuration for detail design. Conceptual definition and requirements of auxiliary systems and facilities were also prepared. Implementation planning also progressed, with schedules prepared and future project milestones defined. The results of these tasks continue to show rig feasibility, both technically and economically.

Dan Davis

2006-09-30T23:59:59.000Z

344

Nanoindentation and adhesion of sol-gel-derived hard coatings on polyester  

E-Print Network [OSTI]

. Fong, and M. Sarikaya Department of Materials Science and Engineering, University of Washington component and adding transition metal oxides. These modifications resulted in tailored thermal, optical on the plastic surface. Nanoindentation analysis revealed that the coatings have a surface hardness up to 2.5 ± 0

Cao, Guozhong

345

PERFORMANCE OF A POLYMER SEALANT COATING IN AN ARCTIC MARINE ENVIRONMENT  

SciTech Connect (OSTI)

The feasibility of using a polymer-based coating, Polibrid 705, to seal concrete and steel surfaces from permanent radioactive contamination in an Arctic marine environment has been successfully demonstrated using a combination of field and laboratory testing. A mobile, self-sufficient spraying device was developed to specifications provided by the Russian Northern Navy and deployed at the RTP Atomflot site, Murmansk, Russia. Demonstration coatings were applied to concrete surfaces exposed to conditions ranging from indoor pedestrian usage to heavy vehicle passage and container handling in a loading dock. A large steel container was also coated with the polymer, filled with solid radwaste, sealed, and left out of doors, exposed to the full annual Arctic weather cycle. The 12 months of field testing gave rise to little degradation of the sealant coating, except for a few chips and gouge marks on the loading bay surface that were readily repaired. Contamination resulting from radwaste handling was easily removed and the surface was not degraded by contact with the decontamination agents. The field tests were accompanied by a series of laboratory qualification tests carried out at a research laboratory in St. Petersburg. The laboratory tests examined a variety of properties, including bond strength between the coating and the substrate, thermal cycling resistance, wear resistance, flammability, and ease of decontamination. The Polibrid 705 coating met all the Russian Navy qualification requirements with the exception of flammability. In this last instance, it was decided to restrict application of the coating to land-based facilities.

MOSKOWITZ,P.; COWGILL,M.; GRIFFITH,A.; CHERNAENKO,L.; DIASHEV,A.; NAZARIAN,A.

2001-02-25T23:59:59.000Z

346

PERFORMANCE OF A POLYMER SEALANT COATING IN AN ARCTIC MARINE ENVIRONMENT.  

SciTech Connect (OSTI)

The feasibility of using a polymer-based coating, Polibrid 705, to seal concrete and steel surfaces from permanent radioactive contamination in an Arctic marine environment has been successfully demonstrated using a combination of field and laboratory testing. A mobile, self-sufficient spraying device was developed to specifications provided by the Russian Northern Navy and deployed at the RTP Atomflot site, Murmansk, Russia. Demonstration coatings were applied to concrete surfaces exposed to conditions ranging from indoor pedestrian usage to heavy vehicle passage and container handling in a loading dock. A large steel container was also coated with the polymer, filled with solid radwaste, sealed, and left out of doors, exposed to the full annual Arctic weather cycle. The 12 months of field testing gave rise to little degradation of the sealant coating, except for a few chips and gouge marks on the loading bay surface that were readily repaired. Contamination resulting from radwaste handling was easily removed and the surface was not degraded by contact with the decontamination agents. The field tests were accompanied by a series of laboratory qualification tests carried out at a research laboratory in St. Petersburg. The laboratory tests examined a variety of properties, including bond strength between the coating and the substrate, thermal cycling resistance, wear resistance, flammability, and ease of decontamination. The Polibrid 705 coating met all the Russian Navy qualification requirements with the exception of flammability. In this last instance, it was decided to restrict application of the coating to land-based facilities.

MOSKOWITZ,P.; COWGILL,M.; GRIFFITH,A.; CHERNAENKO,L.; DIASHEV,A.; NAZARIAN,A.

2001-02-25T23:59:59.000Z

347

OVERLAY COATINGS FOR GAS TURBINE AIRFOILS  

E-Print Network [OSTI]

of the ceramics surface stability and thermal barrierimproved thermal fatigue resistance. The use of a ceramic

Boone, Donald H.

2013-01-01T23:59:59.000Z

348

VEHICLE-BARRIER TRACKING OF ASCALED CRASH TEST FOR ROADSIDE BARRIER DESIGN  

E-Print Network [OSTI]

reality of the vehicle-barrier impact. Scaled testing may thus be a cost effective method to evaluateVEHICLE-BARRIER TRACKING OF ASCALED CRASH TEST FOR ROADSIDE BARRIER DESIGN Giuseppina Amato1 Engineering, David Keir Building, Stranmillis Road, Belfast, BT9 5AG, UK 2 Trinity College Dublin, Dept

Paris-Sud XI, Université de

349

HVOF coatings of Diamalloy 2002 and Diamalloy 4010 onto steel: Tensile and bending response of coatings  

SciTech Connect (OSTI)

HVOF coating of Diamalloy 2002 powders and Diamalloy 4010 powders as well as two-layered coatings consisting of these powders is carried out. In the two-layered structure, Diamalloy 4010 is sprayed at the substrate surface while Diamalloy 2002 is sprayed on the top of Diamalloy 4010 coating. The mechanical properties of the coatings are examined through tensile and three-point bending tests. The coating microstructure and morphology are examined using the Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) and X-ray diffraction (XRD). It is found that the coating produced is free from defects including voids and cracks. The failure mechanism of coating during tensile and three-point bending tests is mainly crack formation and propagation in the coating. The elastic modulus of coating produced from Diamalloy 2002 is higher than that of Diamalloy 4010 coating, which is due to the presence of 12% WC in the coating.

Al-Shehri, Y. A.; Hashmi, M. S. J. [School of Mechanical and Manufacturing Eng., DCU, Dublin (Ireland); Yilbas, B. S. [Mech. Eng. Department, King Fahd University of Petroleum and Minerals, Dhahran (Saudi Arabia)

2011-01-17T23:59:59.000Z

350

Material compatibility and thermal aging of thermoelectric materials.  

SciTech Connect (OSTI)

In order to design a thermoelectric (TE) module suitable for long-term elevated temperature use, the Department 8651 has conducted parametric experiments to study material compatibility and thermal aging of TE materials. In addition, a comprehensive material characterization has been preformed to examine thermal stability of P- and N-based alloys and their interaction with interconnect diffusion barrier(s) and solder. At present, we have completed the 7-days aging experiments for 36 tiles, from ambient to 250 C. The thermal behavior of P- and N-based alloys and their thermal interaction with both Ni and Co diffusion barriers and Au-Sn solder were examined. The preliminary results show the microstructure, texture, alloy composition, and hardness of P-(Bi,Sb){sub 2}Te{sub 3} and N-Bi{sub 2}(Te,Se){sub 3} alloys are thermally stable up to 7 days annealing at 250 C. However, metallurgical reactions between the Ni-phosphor barriers and P-type base alloy were evident at temperatures {ge} 175 C. At 250 C, the depth (or distance) of the metallurgical reaction and/or Ni diffusion into P-(Bi,Sb){sub 2}Te{sub 3} is approximately 10-15 {micro}m. This thermal instability makes the Ni-phosphor barrier unsuitable for use at temperatures {ge} 175 C. The Co barrier appeared to be thermally stable and compatible with P(Bi,Sb){sub 2}Te{sub 3} at all annealing temperatures, with the exception of a minor Co diffusion into Au-Sn solder at {ge} 175 C. The effects of Co diffusion on long-term system reliability and/or the thermal stability of the Co barrier are yet to be determined. Te evaporation and its subsequent reaction with Au-Sn solder and Ni and Co barriers on the ends of the tiles at temperatures {ge} 175 C were evident. The Te loss and its effect on the long-term required stoichiometry of P-(Bi, Sb){sub 2}Te{sub 3} are yet to be understood. The aging experiments of 90 days and 180 days are ongoing and scheduled to be completed in 30 days and 150 days, respectively. Material characterization activities are continuing for the remaining tiles.

Gardea, Andrew D.; Nishimoto, Ryan; Yang, Nancy Y. C.; Morales, Alfredo Martin; Whalen, Scott A.; Chames, Jeffrey M.; Clift, W. Miles

2009-09-01T23:59:59.000Z

351

Ultraviolet-B radiation enhancement in dielectric barrier discharge based xenon chloride exciplex source by air  

SciTech Connect (OSTI)

A single barrier dielectric barrier discharge tube of quartz with multi-strip Titanium-Gold (Ti-Au) coatings have been developed and utilized for ultraviolet-B (UV-B) radiation production peaking at wavelength 308?nm. The observed radiation at this wavelength has been examined for the mixtures of the Xenon together with chlorine and air admixtures. The gas mixture composition, chlorine gas content, total gas pressure, and air pressure dependency of the UV intensity, has been analyzed. It is found that the larger concentration of Cl{sub 2} deteriorates the performance of the developed source and around 2% Cl{sub 2} in this source produced optimum results. Furthermore, an addition of air in the xenon and chlorine working gas environment leads to achieve same intensity of UV-B light but at lower working gas pressure where significant amount of gas is air.

Gulati, P., E-mail: pgulati1512@gmail.com [CSIR-Central Electronics Engineering Research Institute (CSIR-CEERI), Pilani, Rajasthan-333031 (India); Department of Physics, Banasthali University, P.O. Banasthali Vidyapith, Rajasthan 304022 (India); Prakash, R.; Pal, U. N.; Kumar, M. [CSIR-Central Electronics Engineering Research Institute (CSIR-CEERI), Pilani, Rajasthan-333031 (India); Vyas, V. [Department of Physics, Banasthali University, P.O. Banasthali Vidyapith, Rajasthan 304022 (India)

2014-07-07T23:59:59.000Z

352

Standards for Barrier-Free Campus  

E-Print Network [OSTI]

Standards for Barrier-Free Campus Office for Students with Disabilities University Planning Office June 2004 F:\\PROJECTS\\Disabled\\ACCESS04.doc #12;INTRODUCTION The McGill standards for barrier-free and universal design (hereafter referred to as the McGill Standards) are the minimum requirements

Kambhampati, Patanjali

353

BUILDING CODES: BARRIERS TO GREEN INNOVATION  

E-Print Network [OSTI]

BUILDING CODES: BARRIERS TO GREEN INNOVATION JENNIFER GARMAN DR. JIM BOWYER DR. STEVE BRATKOVICH/18/2011 DOVETAIL PARTNERS, INC. www.dovetailinc.org Building Codes: Barriers to Green Innovation Introduction Many architects and contractors want to pursue green building design, technologies and construction. Green

354

High-Performance Nanostructured Coating  

Broader source: Energy.gov [DOE]

The High-Performance Nanostructured Coating fact sheet details a SunShot project led by a University of California, San Diego research team working to develop a new high-temperature spectrally selective coating for receiver surfaces. These receiver surfaces, used in concentrating solar power systems, rely on high-temperature SSCs to effectively absorb solar energy without emitting much blackbody radiation.The optical properties of the SSC directly determine the efficiency and maximum attainable temperature of solar receivers, which in turn influence the power-conversion efficiency and overall system cost.

355

Coated carbon nanotube array electrodes  

DOE Patents [OSTI]

The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

Ren, Zhifeng; Wen, Jian; Chen, Jinghua; Huang, Zhongping; Wang, Dezhi

2006-12-12T23:59:59.000Z

356

Coated carbon nanotube array electrodes  

DOE Patents [OSTI]

The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

Ren, Zhifeng (Newton, MA); Wen, Jian (Newton, MA); Chen, Jinghua (Chestnut Hill, MA); Huang, Zhongping (Belmont, MA); Wang, Dezhi (Wellesley, MA)

2008-10-28T23:59:59.000Z

357

Measurements of thermal accommodation coefficients.  

SciTech Connect (OSTI)

A previously-developed experimental facility has been used to determine gas-surface thermal accommodation coefficients from the pressure dependence of the heat flux between parallel plates of similar material but different surface finish. Heat flux between the plates is inferred from measurements of temperature drop between the plate surface and an adjacent temperature-controlled water bath. Thermal accommodation measurements were determined from the pressure dependence of the heat flux for a fixed plate separation. Measurements of argon and nitrogen in contact with standard machined (lathed) or polished 304 stainless steel plates are indistinguishable within experimental uncertainty. Thus, the accommodation coefficient of 304 stainless steel with nitrogen and argon is estimated to be 0.80 {+-} 0.02 and 0.87 {+-} 0.02, respectively, independent of the surface roughness within the range likely to be encountered in engineering practice. Measurements of the accommodation of helium showed a slight variation with 304 stainless steel surface roughness: 0.36 {+-} 0.02 for a standard machine finish and 0.40 {+-} 0.02 for a polished finish. Planned tests with carbon-nanotube-coated plates will be performed when 304 stainless-steel blanks have been successfully coated.

Rader, Daniel John; Castaneda, Jaime N.; Torczynski, John Robert; Grasser, Thomas W.; Trott, Wayne Merle

2005-10-01T23:59:59.000Z

358

Ultrahard Multilayer Coatings  

SciTech Connect (OSTI)

We have developed a new multilayer a-tC material that is thick stress-free, adherent, low friction, and with hardness and stiffness near that of diamond. The new a-tC material is deposited by J pulsed-laser deposition (PLD) at room temperature, and fully stress-relieved by a short thermal anneal at 600°C. A thick multilayer is built up by repeated deposition and annealing steps. We measured 88 GPa hardness, 1100 GPa Young's modulus, and 0.1 friction coefficient (under high load). Significantly, these results are all well within the range reported for crystalline diamond. In fact, this material, if considered separate from crystalline diamond, is the 2nd hardest material known to man. Stress-free a-tC also has important advantages over thin film diamond; namely, it is smooth, processed at lower temperature, and can be grown on a much broader range of substrates. This breakthrough will enable a host of applications that we are actively pursuing in MEMs, sensors, LIGA, etc.

Chrzan, D.C.; Dugger, M.; Follstaedt, D.M.; Friedman, Lawrence H.; Friedmann, T.A.; Knapp, J.A.; McCarty, K.F.; Medlin, D.L.; Mirkarimi, P.B.; Missert, N.; Newcomer, P.P.; Sullivan, J.P.; Tallant, D.R.

1999-05-01T23:59:59.000Z

359

Subterranean barriers including at least one weld  

DOE Patents [OSTI]

A subterranean barrier and method for forming same are disclosed, the barrier including a plurality of casing strings wherein at least one casing string of the plurality of casing strings may be affixed to at least another adjacent casing string of the plurality of casing strings through at least one weld, at least one adhesive joint, or both. A method and system for nondestructively inspecting a subterranean barrier is disclosed. For instance, a radiographic signal may be emitted from within a casing string toward an adjacent casing string and the radiographic signal may be detected from within the adjacent casing string. A method of repairing a barrier including removing at least a portion of a casing string and welding a repair element within the casing string is disclosed. A method of selectively heating at least one casing string forming at least a portion of a subterranean barrier is disclosed.

Nickelson, Reva A.; Sloan, Paul A.; Richardson, John G.; Walsh, Stephanie; Kostelnik, Kevin M.

2007-01-09T23:59:59.000Z

360

Multi-layer waste containment barrier  

DOE Patents [OSTI]

An apparatus for constructing an underground containment barrier for containing an in-situ portion of earth. The apparatus includes an excavating device for simultaneously (i) excavating earthen material from beside the in-situ portion of earth without removing the in-situ portion and thereby forming an open side trench defined by opposing earthen sidewalls, and (ii) excavating earthen material from beneath the in-situ portion of earth without removing the in-situ portion and thereby forming a generally horizontal underground trench beneath the in-situ portion defined by opposing earthen sidewalls. The apparatus further includes a barrier-forming device attached to the excavating device for simultaneously forming a side barrier within the open trench and a generally horizontal, multi-layer barrier within the generally horizontal trench. The multi-layer barrier includes at least a first layer and a second layer.

Smith, Ann Marie (Pocatello, ID); Gardner, Bradley M. (Idaho Falls, ID); Nickelson, David F. (Idaho Falls, ID)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Overcoming Barriers to Solar Use  

E-Print Network [OSTI]

system costs and improving thermal outputs to the point that solar energy is cost effective. Petro-Sun International recognized, several years ago, the need for lowering costs and has subsequently dedicated its Research and Development program... the beginning of a strong North American Solar Industry. The opportunities provided through Government assistance programs have enabled the Industry to develop products, standards and the research capability to the edge of commercially realisable solar...

Halme, D. S.; Sicotte, J. R.

362

Coated foams, preparation, uses and articles  

DOE Patents [OSTI]

Hydrophobic cellular material is coated with a thin hydrophilic polymer skin which stretches tightly over the foam but which does not fill the cells of the foam, thus resulting in a polymer-coated foam structure having a smoothness which was not possible in the prior art. In particular, when the hydrophobic cellular material is a specially chosen hydrophobic polymer foam and is formed into arbitrarily chosen shapes prior to the coating with hydrophilic polymer, inertial confinement fusion (ICF) targets of arbitrary shapes can be produced by subsequently coating the shapes with metal or with any other suitable material. New articles of manufacture are produced, including improved ICF targets, improved integrated circuits, and improved solar reflectors and solar collectors. In the coating method, the cell size of the hydrophobic cellular material, the viscosity of the polymer solution used to coat, and the surface tension of the polymer solution used to coat are all very important to the coating.

Duchane, D.V.; Barthell, B.L.

1982-10-21T23:59:59.000Z

363

High Performance Nanostructured Spectrally Selective Coating  

Broader source: Energy.gov (indexed) [DOE]

powders for SSC layer paste 'Multi-scale' particles clearly show much better light absorption Multi-scale vs. Mono-scale Structures Coating Process Development Coating of SSC...

364

Investigation of several commercial aluminide coatings for carburization protection of a nickel-base alloy  

SciTech Connect (OSTI)

Four commercial aluminide coatings applied to Hastelloy Alloy X were investigated with respect to their carburization resistance in a carburizing impure helium environment. The test gas was helium with 500 ..mu..atm H/sub 2/, 50 ..mu..atm CO, 50 ..mu..atm CH/sub 4/, and < 1.0 ..mu..atm H/sub 2/O. The uncoated specimens exposed to this test environment at 900/sup 0/C (1650/sup 0/F) for 1000 and 2000 h exhibited significant carburization. All four coatings provided good protection against carburization of the substrate Hastelloy Alloy X, presumably due to the formation of an Al/sub 2/O/sub 3/ oxide scale on the coating surface during the high-temperature corrosion exposure. The Al/sub 2/O/sub 3/ oxide is believed to be an effective barrier to carbon transport. Aluminide coatings applied to Hastelloy Alloy X exhibited a tendency for forming Kirkendall diffusion voids (or pores) in the diffusion zone during long-term high-temperature exposures (e.g., 900/sup 0/C (1650/sup 0/F) for 1000 h). Chromium addition during aluminizing, which resulted in a high chromium content in the coating, appears to be effective in preventing the pore formation during subsequent long-term high-temperature exposures.

Lai, G.Y.

1980-06-01T23:59:59.000Z

365

Friction- and wear-reducing coating  

DOE Patents [OSTI]

A coating includes a first layer of a ceramic alloy and a second layer disposed on the first layer and including carbon. The coating has a hardness of from 10 to 20 GPa and a coefficient of friction of less than or equal to 0.12. A method of coating a substrate includes cleaning the substrate, forming the first layer on the substrate, and depositing the second layer onto the first layer to thereby coat the substrate.

Zhu, Dong (Farmington Hills, MI); Milner, Robert (Warren, MI); Elmoursi, Alaa AbdelAzim (Troy, MI)

2011-10-18T23:59:59.000Z

366

Processing and Gas Barrier Behavior of Multilayer Thin Nanocomposite Films  

E-Print Network [OSTI]

barrier for goods requiring long shelf life. Current gas barrier technologies like plasma-enhanced vapor deposition (PECVD) often create high barrier metal oxide films, which are prone to cracking when flexed. Bulk composites composed of polymer...

Yang, You-Hao

2012-10-19T23:59:59.000Z

367

CORROSION-RESISTANT COATING FOR CARBONATE  

E-Print Network [OSTI]

CORROSION-RESISTANT COATING FOR CARBONATE FUEL CELL COMPONENTS Prepared For: California Energy ANALYSIS REPORT (FAR) CORROSION RESISTANT COATING FOR CARBONATE FUEL CELL COMPONENTS EISG AWARDEE Chemat://www.energy.ca.gov/research/index.html. #12;Page 1 Corrosion Resistant Coating for Carbonate Fuel Cell Components EISG Grant # 00-05 Awardee

368

Chemical vapor deposition of mullite coatings  

DOE Patents [OSTI]

This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

1998-01-01T23:59:59.000Z

369

Terahertz antireflection coatings using metamaterials  

SciTech Connect (OSTI)

We demonstrate terahertz metamaterial antireflection coatings (ARCs) that significantly reduce the reflection and enhance the transmission at an interface of dielectric media. They are able to operate over a wide range of incidence angles for both TM and TE polarizations. Experiments and finite-element simulations will be presented and discussed.

Chen, Hou-tong [Los Alamos National Laboratory; Zhou, Jiangfeng [Los Alamos National Laboratory; O' Hara, John F [Los Alamos National Laboratory; Azad, Abul K [Los Alamos National Laboratory; Chen, Frank [Los Alamos National Laboratory; Taylor, Antoinette J [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

370

RAPID-CURE COATINGS SYSTEM  

Energy Innovation Portal (Marketing Summaries) [EERE]

The Naval Research Laboratory has developed a durable, rapid cure coatings system that is designed for harsh environments. Developed for the maritime industry, it is suit-able for the interior & exterior of shipboard structures and tanks as well as other appli-cations where performance counts...

2011-06-01T23:59:59.000Z

371

Thermal insulation for high temperature microwave sintering operations and method thereof  

DOE Patents [OSTI]

Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering. 1 fig.

Holcombe, C.E.; Dykes, N.L.; Morrow, M.S.

1995-09-12T23:59:59.000Z

372

Method of preparing thermal insulation for high temperature microwave sintering operations  

DOE Patents [OSTI]

Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering. 1 fig.

Holcombe, C.E.; Dykes, N.L.; Morrow, M.S.

1996-07-16T23:59:59.000Z

373

Method of preparing thermal insulation for high temperature microwave sintering operations  

DOE Patents [OSTI]

Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering.

Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN); Morrow, Marvin S. (Kingston, TN)

1996-01-01T23:59:59.000Z

374

Thermal insulation for high temperature microwave sintering operations and method thereof  

DOE Patents [OSTI]

Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering.

Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN); Morrow, Marvin S. (Kingston, TN)

1995-01-01T23:59:59.000Z

375

Thermal spin-transfer torque in magnetic tunnel junctions (invited)  

SciTech Connect (OSTI)

The thermal spin-transfer torque (TSTT) is an effect to switch the magnetic free layer in a magnetic tunnel junction by a temperature gradient only. We present ab initio calculations of the TSTT. In particular, we discuss the influence of magnetic layer composition by considering Fe{sub x}Co{sub 1–x} alloys. Further, we compare the TSTT to the bias voltage driven STT and discuss the requirements for a possible thermal switching. For example, only for very thin barriers of 3 monolayers MgO, a thermal switching is imaginable. However, even for such a thin barrier, the TSTT is still too small for switching at the moment and further optimization is needed. In particular, the TSTT strongly depends on the composition of the ferromagnetic layer. In our current study, it turns out that at the chosen thickness of the ferromagnetic layer, pure Fe gives the highest thermal spin-transfer torque.

Heiliger, Christian, E-mail: christian.heiliger@physik.uni-giessen.de; Franz, C.; Czerner, Michael [I. Physikalisches Institut, Justus Liebig University, Giessen (Germany)

2014-05-07T23:59:59.000Z

376

Modeling the thermal conductivity of fiber-reinforced ceramic composites  

SciTech Connect (OSTI)

A review of models for the prediction of the thermal conductivity of uni-directional fiber-reinforced composites will be presented. The ability of these models to give an accurate prediction of the composite thermal conductivity depends on the amount of information known about the constituent phase properties under the assumption that these properties do not change as a result of processing. Also presented are models that take into account the effects of fiber coatings.

Beecher, S.C.; Dinwiddie, R.B.

1993-06-01T23:59:59.000Z

377

DOE to Address Small Businesses Barriers in Government Contracting...  

Broader source: Energy.gov (indexed) [DOE]

to Address Small Businesses Barriers in Government Contracting at Waste Management Conference DOE to Address Small Businesses Barriers in Government Contracting at Waste Management...

378

Drivers and Barriers in the Current Concentrated Solar Power...  

Open Energy Info (EERE)

Drivers and Barriers in the Current Concentrated Solar Power (CSP) Market (Webinar) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Drivers and Barriers in the Current...

379

Deployment Barriers to Distributed Wind Energy: Workshop Report...  

Energy Savers [EERE]

Deployment Barriers to Distributed Wind Energy: Workshop Report, October 28, 2010 Deployment Barriers to Distributed Wind Energy: Workshop Report, October 28, 2010 This report...

380

Geothermal Heat Pumps: Market Status, Barriers to Adoption, and...  

Open Energy Info (EERE)

Barriers to Adoption, and Actions to Overcome Barriers AgencyCompany Organization: Oak Ridge National Laboratory Sector: Energy Focus Area: Renewable Energy, Geothermal...

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

February 20, 2014 Webinar - Performance of Engineered Barriers...  

Office of Environmental Management (EM)

20, 2014 Webinar - Performance of Engineered Barriers: Lessons Learned February 20, 2014 Webinar - Performance of Engineered Barriers: Lessons Learned February 20, 2014 Webinar -...

382

Vehicle Technologies Office Merit Review 2014: Removing Barriers...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Review 2014: Removing Barriers, Implementing Policies and Advancing Alternative Fuels Markets in New England Vehicle Technologies Office Merit Review 2014: Removing Barriers,...

383

Recent Research to Address Technical Barriers to Increased Use...  

Broader source: Energy.gov (indexed) [DOE]

Recent Research to Address Technical Barriers to Increased Use of Biodiesel Recent Research to Address Technical Barriers to Increased Use of Biodiesel 2005 Diesel Engine Emissions...

384

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network [OSTI]

using aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"ings of Aquifer Thermal Energy Storage Workshop, Lawrence

Tsang, C.-F.

2011-01-01T23:59:59.000Z

385

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network [OSTI]

aquifers for thermal energy storage. Problems outlined aboveModeling of Thermal Energy Storage in Aquifers," Proceed-ings of Aquifer Thermal Energy Storage Workshop, Lawrence

Tsang, C.-F.

2011-01-01T23:59:59.000Z

386

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network [OSTI]

using aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"Proceed- ings of Aquifer Thermal Energy Storage Workshop,

Tsang, C.-F.

2011-01-01T23:59:59.000Z

387

Method for forming a barrier layer  

SciTech Connect (OSTI)

Cubic or metastable cubic refractory metal carbides act as barrier layers to isolate, adhere, and passivate copper in semiconductor fabrication. One or more barrier layers of the metal carbide are deposited in conjunction with copper metallizations to form a multilayer characterized by a cubic crystal structure with a strong (100) texture. Suitable barrier layer materials include refractory transition metal carbides such as vanadium carbide (VC), niobium carbide (NbC), tantalum carbide (TaC), chromium carbide (Cr.sub.3 C.sub.2), tungsten carbide (WC), and molybdenum carbide (MoC).

Weihs, Timothy P. (Baltimore, MD); Barbee, Jr., Troy W. (Palo Alto, CA)

2002-01-01T23:59:59.000Z

388

Method for making nanoporous hydrophobic coatings  

DOE Patents [OSTI]

A simple coating method is used to form nanoporous hydrophobic films that can be used as optical coatings. The method uses evaporation-induced self-assembly of materials. The coating method starts with a homogeneous solution comprising a hydrophobic polymer and a surfactant polymer in a selective solvent. The solution is coated onto a substrate. The surfactant polymer forms micelles with the hydrophobic polymer residing in the particle core when the coating is dried. The surfactant polymer can be dissolved and selectively removed from the separated phases by washing with a polar solvent to form the nanoporous hydrophobic film.

Fan, Hongyou

2013-04-23T23:59:59.000Z

389

Corrosion protection of SiC-based ceramics with CVDMullite coatings  

SciTech Connect (OSTI)

Silicon carbide ceramics are the leading candidate materials for use as heat exchangers in advanced combined cycle power plants because of their unique combination of high temperature strength, high thermal conductivity, excellent thermal shock resistance, and good high temperature stability and oxidation resistance. Ceramic coatings are being considered for diesel engine cylinder liners, piston caps, valve faces and seats, piston rings, and for turbine components such as combustors, blades, stators, seals, and bearings. Under such conditions ceramics are better suited to high temperature environments than metals. For the first time, adherent crystalline mullite coatings have been chemically vapor deposited onto SiC substrates to enhance its corrosion/oxidation resistance. Thermodynamic and kinetic considerations have been utilized to produce mullite coatings with a variety of growth rates, compositions, and morphologies. The flexibility of processing can be exploited to produce coated ceramics with properties tailored to specific applications and varied corrosive environments. These corrosive environments include thermal, Na{sub 2}SO{sub 4}, O{sub 2} and coal slag.

Sarin, V.; Auger, M. [Boston Univ., MA (United States)

1997-05-01T23:59:59.000Z

390

Channel cracks in atomic-layer and molecular-layer deposited multilayer thin film coatings  

SciTech Connect (OSTI)

Metal oxide thin film coatings produced by atomic layer deposition have been shown to be an effective permeation barrier. The primary failure mode of such coatings under tensile loads is the propagation of channel cracks that penetrate vertically into the coating films. Recently, multi-layer structures that combine the metal oxide material with relatively soft polymeric layers produced by molecular layer deposition have been proposed to create composite thin films with desired properties, including potentially enhanced resistance to fracture. In this paper, we study the effects of layer geometry and material properties on the critical strain for channel crack propagation in the multi-layer composite films. Using finite element simulations and a thin-film fracture mechanics formalism, we show that if the fracture energy of the polymeric layer is lower than that of the metal oxide layer, the channel crack tends to penetrate through the entire composite film, and dividing the metal oxide and polymeric materials into thinner layers leads to a smaller critical strain. However, if the fracture energy of the polymeric material is high so that cracks only run through the metal oxide layers, more layers can result in a larger critical strain. For intermediate fracture energy of the polymer material, we developed a design map that identifies the optimal structure for given fracture energies and thicknesses of the metal oxide and polymeric layers. These results can facilitate the design of mechanically robust permeation barriers, an important component for the development of flexible electronics.

Long, Rong, E-mail: rlongmech@gmail.com [Department of Mechanical Engineering, University of Alberta, Edmonton, Alberta T6G 2G8 (Canada); Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309 (United States); Dunn, Martin L. [Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309 (United States); Singapore University of Technology and Design, Singapore 138682 (Singapore)

2014-06-21T23:59:59.000Z

391

Electrical contact arrangement for a coating process  

DOE Patents [OSTI]

A protective coating is applied to the electrically conductive surface of a reflective coating of a solar mirror by biasing a conductive member having a layer of a malleable electrically conductive material, e.g. a paste, against a portion of the conductive surface while moving an electrodepositable coating composition over the conductive surface. The moving of the electrodepositable coating composition over the conductive surface includes moving the solar mirror through a flow curtain of the electrodepositable coating composition and submerging the solar mirror in a pool of the electrodepositable coating composition. The use of the layer of a malleable electrically conductive material between the conductive member and the conductive surface compensates for irregularities in the conductive surface being contacted during the coating process thereby reducing the current density at the electrical contact area.

Kabagambe, Benjamin; McCamy, James W; Boyd, Donald W

2013-09-17T23:59:59.000Z

392

Armor systems including coated core materials  

DOE Patents [OSTI]

An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

Chu, Henry S. (Idaho Falls, ID); Lillo, Thomas M. (Idaho Falls, ID); McHugh, Kevin M. (Idaho Falls, ID)

2012-07-31T23:59:59.000Z

393

Armor systems including coated core materials  

DOE Patents [OSTI]

An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

2013-10-08T23:59:59.000Z

394

Effects of Thermal Exposure and Test Temperature on Structure Evolution and Hardness/Viscosity  

E-Print Network [OSTI]

Effects of Thermal Exposure and Test Temperature on Structure Evolution and Hardness/Viscosity the physical and mechanical properties (i.e., viscosity, flow, and fracture). In some cases, the thermal coating techniques (e.g., high velocity oxygen fuel (HVOF), plasma spray, cold spray, etc.) have been used

Rollins, Andrew M.

395

Hygrothermal performance of an engineered clay barrier during sustained heating  

SciTech Connect (OSTI)

Bentonitic clay buffers, with a potential for swelling, form an integral part of the natural (geological formation)/engineered multi-barrier concepts being proposed for the disposal of heat-generating radioactive nuclear fuel wastes. The integrity of such barriers during thermal loadings is of primary interest to the assessment of their reliability. This paper discusses the results of a series of experiments performed to assess the performance of buffer material under sustained heating. These experiments were conducted in a large-scale granite block facility. The laboratory modeling approximately simulates the local environment that can be encountered in a disposal vault in a granitic rock mass. Experiments in which the power supply to an embedded heater was held constant are described. The temperature distributions within the buffer and the granite block together with the residual moisture content distributions are documented. Also discussed is the application of a computational model of coupled heat and moisture flows. Moisture and heat transfer in the buffer under coupled gradients is described by the Philip-de Vries-type model in which the hygrothermal parameters are determined separately.

Selvadurai, A.P.S. [Carleton Univ., Ottawa, Ontario (Canada). Dept. of Civil and Environmental Engineering; Onofrei, C. [AECL Research, Pinawa, Manitoba (Canada). Whiteshell Labs.

1993-12-31T23:59:59.000Z

396

High Density Infrared (HDI) Transient Liquid Coatings for Improved Wear and Corrosion Resistance  

SciTech Connect (OSTI)

This report documents a collaborative effort between Oak Ridge National Laboratory (ORNL), Materials Resources International and an industry team of participants to develop, evaluate and understand how high density infrared heating technology could be used to improve infiltrated carbide wear coatings and/or to densify sprayed coatings. The research included HDI fusion evaluations of infiltrated carbide suspensions such (BrazeCoat® S), composite suspensions with tool steel powders, thermally sprayed Ni-Cr- B-Si (self fluxing alloy) and nickel powder layers. The applied work developed practical HDI / transient liquid coating (TLC) procedures on test plates that demonstrated the ability to fuse carbide coatings for industrial applications such as agricultural blades, construction and mining vehicles. Fundamental studies helped create process models that led to improved process understanding and control. The coating of agricultural blades was demonstrated and showed the HDI process to have the ability to fuse industrial scale components. Sliding and brasive wear tests showed that high degree of wear resistance could be achieved with the addition of tool steel powders to carbide particulate composites.

Ronald W. Smith

2007-07-05T23:59:59.000Z

397

Solid-gel precursor solutions and methods for the fabrication of polymetallicsiloxane coating films  

DOE Patents [OSTI]

Solutions and preparation methods necessary for the fabrication of metal oxide cross-linked polysiloxane coating films are disclosed. The films are useful in provide heat resistance against oxidation, wear resistance, thermal insulation, and corrosion resistance of substrates. The sol-gel precursor solution comprises a mixture of a monomeric organoalkoxysilane, a metal alkoxide M(OR)[sub n] (wherein M is Ti, Zr, Ge or Al; R is CH[sub 3], C[sub 2]H[sub 5] or C[sub 3]H[sub 7]; and n is 3 or 4), methanol, water, HCl and NaOH. The invention provides a sol-gel solution, and a method of use thereof, which can be applied and processed at low temperatures (i.e., < 1,000 C.). The substrate can be coated by immersing it in the above mentioned solution at ambient temperature. The substrate is then withdrawn from the solution. Next, the coated substrate is heated for a time sufficient and at a temperature sufficient to yield a solid coating. The coated substrate is then heated for a time sufficient, and temperature sufficient to produce a polymetallicsiloxane coating.

Toshifumi Sugama.

1993-04-06T23:59:59.000Z

398

ALD Produced B{sub 2}O{sub 3}, Al{sub 2}O{sub 3} and TiO{sub 2} Coatings on Gd{sub 2}O{sub 3} Burnable Poison Nanoparticles and Carbonaceous TRISO Coating Layers  

SciTech Connect (OSTI)

This project will demonstrate the feasibility of using atomic layer deposition (ALD) to apply ultrathin neutron-absorbing, corrosion-resistant layers consisting of ceramics, metals, or combinations thereof, on particles for enhanced nuclear fuel pellets. Current pellet coating technology utilizes chemical vapor deposition (CVD) in a fluidized bed reactor to deposit thick, porous layers of C (or PyC) and SiC. These graphitic/carbide materials degrade over time owing to fission product bombardment, active oxidation, thermal management issues, and long-term irradiation effects. ALD can be used to deposit potential ceramic barrier materials of interest, including ZrO{sub 2}, Y{sub 2}O{sub 3}:ZrO{sub 2} (YSZ), Al{sub 2}O{sub 3}, and TiO{sub 2}, or neutron-absorbing materials, namely B (in BN or B{sub 2}O{sub 3}) and Gd (in Gd{sub 2}O{sub 3}). This project consists of a two-pronged approach to integrate ALD into the next-generation nuclear plant (NGNP) fuel pellet manufacturing process:

Alan Weimer

2012-11-26T23:59:59.000Z

399

ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS  

SciTech Connect (OSTI)

This slide-show presents 3M photovoltaic-related products, particularly flexible components. Emphasis is on the 3M Ultra Barrier Solar Films. Topics covered include reliability and qualification testing and flexible photovoltaic encapsulation costs.

DeScioli, Derek

2013-06-01T23:59:59.000Z

400

Communicating across barriers at home and abroad  

SciTech Connect (OSTI)

This paper intends to catalyze the exchange of experience among technical communicators in meeting the challenge of communicating across a multitude of barriers: linguistic, disciplinary, cultural, political, intellectual, and emotional.

McDonald, J.W.

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Breaking the Fuel Cell Cost Barrier  

Broader source: Energy.gov (indexed) [DOE]

the Fuel Cell Cost Barrier AMFC Workshop May 8 th , 2011, Arlington, VA Shimshon Gottesfeld, CTO The Fuel Cell Cost Challenge 2 CellEra's goal - achieve price parity with...

402

Sunk Costs and Antitrust Barriers to Entry  

E-Print Network [OSTI]

US antitrust policy takes as its objective consumer welfare, not total economic welfare. With that objective, Joe Bain's definition of entry barriers is more useful than George Stigler's or definitions ...

Schmalensee, Richard

2004-12-10T23:59:59.000Z

403

Sunk Costs and Antitrust Barriers to Entry  

E-Print Network [OSTI]

US antitrust policy takes as its objective consumer welfare, not total economic welfare. With that objective, Joe Bain's definition of entry barriers is more useful than George Stigler's or definitions based on economic ...

Schmalensee, Richard

2004-04-02T23:59:59.000Z

404

Modeling of Residential Attics with Radiant Barriers  

E-Print Network [OSTI]

This paper gives a summary of the efforts at ORNL in modeling residential attics with radiant barriers. Analytical models based on a system of macroscopic heat balances have been developed. Separate models have been developed for horizontal radiant...

Wilkes, K. E.

1988-01-01T23:59:59.000Z

405

ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS  

SciTech Connect (OSTI)

This poster describes the 3M Ultra-Barrier Solar Film and its application; production scale-up and data; reliability and qualification testing; and improvements in the next generation.

Alan, Nachtigal; Berniard, Tracie; Murray, Bill; Roehrig, Mark; Schubert, Charlene; Spagnola, Joseph; Weigel, Mark

2013-01-01T23:59:59.000Z

406

Surface barriers: Problems, solutions, and future needs  

SciTech Connect (OSTI)

The problem of designing a surface barrier for a remediation project can be an enormously challenging task. There is a widely held misconception that surface barrier technology is well developed and works as expected. In fact, the technology is largely unproved and experimental, particularly in terms of long-term performance. The most difficult problem with surface barriers is to provide a long-term barrier to infiltration of water. The materials that have traditionally been considered for the hydraulic barrier within surface barrier systems are low-permeability compacted soil, geomembranes, and the geosynthetic clay liner (GCL). Data are presented to suggest that low-permeability compacted soil is often a poor choice of materials. Unless the compacted soil liner is buried under a very thick layer of protective soil or covered by a geomembrane, the low-permeability, clay-rich, compacted soil is likely to desiccate and lose its low hydraulic conductivity. Differential settlement of a compacted soil liner from uneven compression of underlying waste or other causes is almost certain to produce cracks within the soil liner. Geomembranes do not suffer as much from these problems, but their design life is, at best, a few centuries, The GCL, which contains a thin layer of bentonite, is much better able to resist damage from freezing/thawing, desiccation, and differential settlement than compacted soil liners. The technology of the GCL, which is particularly well suited for arid sites, is reviewed in some detail in this paper because of its technical attributes in surface-barrier applications. Published case histories of the performance of surface barriers are summarized.

Daniel, D.E. [Univ. of Texas, Austin, TX (United States). Dept. of Civil Engineering

1994-12-31T23:59:59.000Z

407

Proceedings of the XVI International Conference on Thermoelectrics, Dresden, Germany, p. 641, 1997 Thermoelectric Microcoolers for Thermal Management Applications  

E-Print Network [OSTI]

microelectronics. We are pursuing a novel thermal management approach that actively cools only the key high power solutions on a variety of metallic substrates. We also report on the development of Cu diffusion barriers for Bi2Te3 and stable metallizations and diffusion barriers for diamond and AlN substrates. Introduction

408

Model assessment of protective barriers: Part 3  

SciTech Connect (OSTI)

Radioactive waste exists at the US Department of Energy's (DOE's) Hanford Site in a variety of locations, including subsurface grout and tank farms, solid waste burial grounds, and contaminated soil sites. Some of these waste sites may need to be isolated from percolating water to minimize the potential for transport of the waste to the ground water, which eventually discharges to the Columbia River. Multilayer protective barriers have been proposed as a means of limiting the flow of water through the waste sites (DOE 1987). A multiyear research program (managed jointly by Pacific Northwest Laboratory (PNL) and Westinghouse Hanford Company for the DOE) is aimed at assessing the performance of these barriers. One aspect of this program involves the use of computer models to predict barrier performance. Three modeling studies have already been conducted and a test plan was produced. The simulation work reported here was conducted by PNL and extends the previous modeling work. The purpose of this report are to understand phenomena that have been observed in the field and to provide information that can be used to improve hydrologic modeling of the protective barrier. An improved modeling capability results in better estimates of barrier performance. Better estimates can be used to improve the design of barriers and the assessment of their long-term performance.

Fayer, M.J.; Rockhold, M.L.; Holford, D.J.

1992-02-01T23:59:59.000Z

409

Thermal loading study for FY 1995  

SciTech Connect (OSTI)

This report provides the results of sensitivity analyses designed to assist the test planners in focusing their in-situ measurements on parameters that appear to be important to waste isolation. Additionally, the study provides a preliminary assessment of the feasibility of certain thermal management options. A decision on thermal loading is a critical part of the scientific and engineering basis for evaluating regulatory compliance of the potential repository for waste isolation. To show, with reasonable assurance, that the natural and engineered barriers will perform adequately under expected repository conditions (thermally perturbed) will require an integrated approach based on thermal testing (laboratory, and in-situ), natural analog observations, and analytic modeling. The Office of Civilian Radioactive Waste Management needed input to assist in the planning of the thermal testing program. Additionally, designers required information on the viability of various thermal management concepts. An approximately 18-month Thermal Loading Study was conducted from March, 1994 until September 30, 1995 to address these issues. This report documents the findings of that study. 89 refs., 71 figs., 33 tabs.

NONE

1996-01-31T23:59:59.000Z

410

Mechanisms Associated with Rumpling of Pt-Modified Beta-NiAl Coatings  

SciTech Connect (OSTI)

The formation of surface undulations (i.e. rumpling) at the bond coat/thermally grown oxide (TGO) interface has been shown to cause failure by spallation of the ceramic top coat in aero-turbine systems. Many mechanisms have been proposed concerning the cause of these surface distortions; however, there is little agreement on what may be the dominating cause of the rumpling behavior. Of there mechanisms, the reversible phase transformation from a cubic {beta}-NiAl structure to a face centered tetragonal (FCT) martensitic phase was of particular interest because of its ability to form surface rumpling in Pt-modified {beta} bulk alloys. However, the bulk alloys used in obtaining that result were simple ternary systems and not relevant to actual coating compositions as other alloying elements enter the coating due to coating/substrate interdiffusion at high temperature. In the current study, the depletion behavior of a commercial coating was studied. Compositions from the depletion path were determined and bulk alloys representing these coating compositions were prepared. The martensitic phase transformation was then characterized using DSC and XRD. The martensitic start temperature on cooling, Ms, was consistently found to be significantly lower than previously reported values (e.g. 530 C vs 100 C). Because of the low Ms temperature, the formation of the martensitic phase was concluded to be unnecessary for the occurrence of rumpling. However, cyclic exposure treatments at low temperature ({approx} 400 C) of bulk alloys and commercial coatings did show the detrimental effects of the phase transformation in the form of crack formation and propagation leading to eventual failure of the alloys. The current work also infers that the differences in coefficient of thermal expansion (CTE) mismatch between the coating and substrate are the dominating factor leading to rumpling. Dilatometry measurements were made on bulk alloys representing depleted coatings and the superalloy substrate to determine CTE as a function of temperature. Finally, simulations were completed to help determine the role of CTE mismatch. It was found that these results compared closely to those collected during experimental cyclic exposure treatments; although, modification to the current model were found to be needed in order to truly simulate rumpling.

Joseph Peter Henderkott

2007-12-01T23:59:59.000Z

411

Findings in seal coat design  

E-Print Network [OSTI]

Africa (NITRR) and its members Dr. Claude P. Marais, Dr. Alex T. Visser and Dr. C. J. Semmelink for furnishing the relevant data and figures presented in this report. Finally this thesis and accomplishments are dedicated to my project Principal... Volume. 1. Embedment 2. Wear and Degradation. 3. Skid Resistance. 35 40 41 43 44 V SOUTH AFRICANS' RATIONAL APPROACH TO THE DESIGN OF SEAL COATS AND SURFACE TREATMENT. . 50 A. Background. B. Marais' Rational Approach. 1. Aggregate Spread Rate...

Gonzalez Palmer, Miguel Angel

1988-01-01T23:59:59.000Z

412

High temperature solar selective coatings  

DOE Patents [OSTI]

Improved solar collectors (40) comprising glass tubing (42) attached to bellows (44) by airtight seals (56) enclose solar absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are coated with improved solar selective coatings {48} which provide higher absorbance, lower emittance and resistance to atmospheric oxidation at elevated temperatures. The coatings are multilayered structures comprising solar absorbent layers (26) applied to the meta surface of the absorber tubes (50), typically stainless steel, topped with antireflective Savers (28) comprising at least two layers 30, 32) of refractory metal or metalloid oxides (such as titania and silica) with substantially differing indices of refraction in adjacent layers. Optionally, at least one layer of a noble metal such as platinum can be included between some of the layers. The absorbent layers cars include cermet materials comprising particles of metal compounds is a matrix, which can contain oxides of refractory metals or metalloids such as silicon. Reflective layers within the coating layers can comprise refractory metal silicides and related compounds characterized by the formulas TiSi. Ti.sub.3SiC.sub.2, TiAlSi, TiAN and similar compounds for Zr and Hf. The titania can be characterized by the formulas TiO.sub.2, Ti.sub.3O.sub.5. TiOx or TiO.sub.xN.sub.1-x with x 0 to 1. The silica can be at least one of SiO.sub.2, SiO.sub.2x or SiO.sub.2xN.sub.1-x with x=0 to 1.

Kennedy, Cheryl E

2014-11-25T23:59:59.000Z

413

Pedestal substrate for coated optics  

DOE Patents [OSTI]

A pedestal optical substrate that simultaneously provides high substrate dynamic stiffness, provides low surface figure sensitivity to mechanical mounting hardware inputs, and constrains surface figure changes caused by optical coatings to be primarily spherical in nature. The pedestal optical substrate includes a disk-like optic or substrate section having a top surface that is coated, a disk-like base section that provides location at which the substrate can be mounted, and a connecting cylindrical section between the base and optics or substrate sections. The connecting cylindrical section may be attached via three spaced legs or members. However, the pedestal optical substrate can be manufactured from a solid piece of material to form a monolith, thus avoiding joints between the sections, or the disk-like base can be formed separately and connected to the connecting section. By way of example, the pedestal optical substrate may be utilized in the fabrication of optics for an extreme ultraviolet (EUV) lithography imaging system, or in any optical system requiring coated optics and substrates with reduced sensitivity to mechanical mounts.

Hale, Layton C. (Livermore, CA); Malsbury, Terry N. (Tracy, CA); Patterson, Steven R. (Concord, NC)

2001-01-01T23:59:59.000Z

414

High Critical Current Coated Conductors  

SciTech Connect (OSTI)

One of the important critical needs that came out of the DOE’s coated conductor workshop was to develop a high throughput and economic deposition process for YBCO. Metal-organic chemical vapor deposition (MOCVD) technique, the most critical steps in high technical micro fabrications, has been widely employed in semiconductor industry for various thin film growth. SuperPower has demonstrated that (Y,Gd)BCO films can be deposited rapid with world record performance. In addition to high critical current density with increased film thickness, flux pinning properties of REBCO films needs to be improved to meet the DOE requirements for various electric-power equipments. We have shown that doping with Zr can result in BZO nanocolumns, but at substantially reduced deposition rate. The primary purpose of this subtask is to develop high current density MOCVD-REBCO coated conductors based on the ion-beam assisted (IBAD)-MgO deposition process. Another purpose of this subtask is to investigate HTS conductor design optimization (maximize Je) with emphasis on stability and protection issues, and ac loss for REBCO coated conductors.

Paranthaman, M. P.; Selvamanickam, V. (SuperPower, Inc.)

2011-12-27T23:59:59.000Z

415

ELECTROSTATICALLY ENHANCED BARRIER FILTER COLLECTION  

SciTech Connect (OSTI)

This work was performed through the University of North Dakota (UND) Chemical Engineering Department with assistance from UND's Energy & Environmental Research Center. This research was undertaken in response to the U.S. Department of Energy Federal Technology Center Program Solicitation No. DE-PS26-99FT40479, Support of Advanced Coal Research at U.S. Universities and Colleges. Specifically, this research was in support of the UCR Core Program and addressees Topic 1, Improved Hot-Gas Contaminant and Particulate Removal Techniques, introducing an advanced design for particulate removal. Integrated gasification combined cycle (IGCC) offers the potential for very high efficiency and clean electric generation. In IGCC, the product gas from the gasifier needs to be cleaned of particulate matter to avoid erosion and high-temperature corrosion difficulties arising with the turbine blades. Current methods involve cooling the gases to {approx}100 C to condense alkalis and remove sulfur and particulates using conventional scrubber technology. This ''cool'' gas is then directed to a turbine for electric generation. While IGCC has the potential to reach efficiencies of over 50%, the current need to cool the product gas for cleaning prior to firing it in a turbine is keeping IGCC from reaching its full potential. The objective of the current project was to develop a highly reliable particulate collector system that can meet the most stringent turbine requirements and emission standards, can operate at temperatures above 1500 F, is applicable for use with all U.S. coals, is compatible with various sorbent injection schemes for sulfur and alkali control, can be integrated into a variety of configurations for both pressurized gasification and combustion, increases allowable face velocity to reduce filter system capital cost, and is cost-competitive with existing technologies. The collector being developed is a new concept in particulate control called electrostatically enhanced barrier filter collection (EBFC). This concept combines electrostatic precipitation (ESP) with candle filters in a single unit. Similar technology has been recently proven on a commercial scale for atmospheric applications, but needed to be tested at high temperatures and pressures. The synergy obtained by combining the two control technologies into a single system should actually reduce filter system capital and operating costs and make the system more reliable. More specifically, the ESP is expected to significantly reduce candle filter load and also to limit ash reintrainment, allowing for full recovery of baseline pressure drop during backpulsing of the filters.

John Erjavec; Michael D. Mann; Ryan Z. Knutson; Michael L. Swanson; Michael E. Collings

2003-06-01T23:59:59.000Z

416

E-Print Network 3.0 - apatite-type lanthanum silicates Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine 67 Europium-doped Pyrochlores for Use as Thermographic Phosphors in Thermal Barrier Coatings Summary: even when other excitation wavelengths were used 9 12;10...

417

AM  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Systems 2:30 PM Brown University Advanced Thermal Barrier Coatings for Next Generation Gas Turbine Engines Fueled by Coal- Derived Syn University of Central Florida Wireless,...

418

Process for fabricating composite material having high thermal conductivity  

DOE Patents [OSTI]

A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

Colella, Nicholas J. (Livermore, CA); Davidson, Howard L. (San Carlos, CA); Kerns, John A. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA)

2001-01-01T23:59:59.000Z

419

Electrodeposited coatings for diamond turning applications  

SciTech Connect (OSTI)

Electrodeposited coatings are attractive for precision machining operations because thick coatings can be economically applied, with good adhesion, to a variety of substrates. Approximately 20 pure metals and a large number of alloys can be deposited from aqueous solutions. Fused salt and organic solvent electrolytes can be used to lengthen the list of metals that can be electrodeposited. However, both the choice of the metallic coating and the control of the plating process are critical for success in precision finishing of electrodeposited coatings. Some preliminary results at the National Institute of Standards and Technology and at the Lawrence Livermore National Laboratory suggest that electrodeposited nickel-phosphorus alloys are excellent coatings for single point diamond turning from the standpoint of material properties and low tool wear. Electrodeposited aluminum and aluminum alloy coatings also merit consideration for precision finishing where weight is an important factor. 10 refs., 6 figs.

Mayer, A.; Bramlett, R.D.; Day, R.D. (Los Alamos National Lab., NM (USA)); Evans, C.J.; Polvani, R.S. (National Inst. of Standards and Technology, Gaithersburg, MD (USA))

1991-01-01T23:59:59.000Z

420

Surface roughness of anodized titanium coatings.  

SciTech Connect (OSTI)

Samples of grade five 6Al4V titanium alloy were coated with two commercial fluoropolymer anodizations (Tiodize and Canadize) and compared. Neither coating demonstrates significant outgassing. The coatings show very similar elemental analysis, except for the presence of lead in the Canadize coating, which may account for its lower surface friction in humid environments. Surface roughness has been compared by SEM, contact profilometry, optical profilometry, power spectral density and bidirectional scattering distribution function (BSDF). The Tiodize film is slightly smoother by all measurement methods, but the Canadize film shows slightly less scatter at all angles of incidence. Both films exhibited initial friction coefficients of 0.2 to 0.4, increasing to 0.4 to 0.8 after 1000 cycles of sliding due to wear of the coating and ball. The coatings are very similar and should behave identically in most applications.

Dugger, Michael Thomas; Chinn, Douglas Alan

2010-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Development of MnCoO Coating with New Aluminizing Process for Planar SOFC Stacks  

SciTech Connect (OSTI)

Low-cost, chromia-forming steels find widespread use in SOFCs at operating temperatures below 800°C, because of their low thermal expansion mismatch and low cost. However, volatile Cr-containing species originating from this scale poison the cathode material in the cells and subsequently cause power degradation in the devices. To prevent this, a conductive manganese cobaltite coating has been developed. However, this coating is not compatible with forming hermetic seals between the interconnect or window frame component and ceramic cell. This coating reacts with sealing materials. Thus, a new aluminizing process has been developed for the sealing regions in these parts, as well as for other metallic stack and balance-of-plant components. From this development, the sealing performance and SOFC stack performance became very stable.

Choi, Jung-Pyung; Weil, K. Scott; Chou, Y. S.; Stevenson, Jeffry W.; Yang, Zhenguo

2011-03-22T23:59:59.000Z

422

Improved oxidation resistance of organic/inorganic composite atomic layer deposition coated cellulose nanocrystal aerogels  

SciTech Connect (OSTI)

Cellulose nanocrystal (CNC) aerogels are coated with thin conformal layers of Al{sub 2}O{sub 3} using atomic layer deposition to form hybrid organic/inorganic nanocomposites. Electron probe microanalysis and scanning electron microscopy analysis indicated the Al{sub 2}O{sub 3} penetrated more than 1500??m into the aerogel for extended precursor pulse and exposure/purge times. The measured profile of coated fiber radius versus depth from the aerogel surface agrees well with simulations of precursor penetration depth in modeled aerogel structures. Thermogravimetric analysis shows that Al{sub 2}O{sub 3} coated CNC aerogel nanocomposites do not show significant thermal degradation below 295?°C as compared with 175?°C for uncoated CNC aerogels, an improvement of over 100?°C.

Smith, Sean W.; Matthews, David J.; Conley, John F., E-mail: jconley@eecs.oregonstate.edu [School of Electrical Engineering and Computer Science, 1148 Kelley Engineering Center, Oregon State University, Corvallis, Oregon 97331 (United States); Buesch, Christian; Simonsen, John [Department of Wood Science and Engineering, Oregon State University, 119 Richardson Hall, Corvallis, Oregon 97331 (United States)

2014-07-01T23:59:59.000Z

423

On Coating Durability of Polymer Coated Sheet Metal under Plastic Deformation  

E-Print Network [OSTI]

process. Thus, the effect of plastic deformation on coating adhesion is of primary interest to many engineers and researchers. This research aims at developing a methodology to predict the adhesion of coating after metal forming processes. A pull...

Huang, Yu-Hsuan

2011-08-08T23:59:59.000Z

424

Coated metal articles and method of making  

DOE Patents [OSTI]

The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

Boller, Ernest R. (Van Buren Township, IN); Eubank, Lowell D. (Wilmington, DE)

2004-07-06T23:59:59.000Z

425

Coated Metal Articles and Method of Making  

DOE Patents [OSTI]

The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

Boller, Ernest R.; Eubank, Lowell D.

2004-07-06T23:59:59.000Z

426

Renewable energy in Brazil: opportunities, barriers, and remedies  

SciTech Connect (OSTI)

An overview of the major conclusions is presented according to the goals of the study; and contents of the various chapters of the report are outlined. All major energy planning organizations in Brazil at the federal and state level perceive an urgent need for petroleum substitution by means of energy-efficient technology, coal, hydroelectricity, biomass, solar, and wind. Technologies and applications considered of high priority for US/Brazilian cooperative efforts are the following: Energy-efficient technology, used with indigenous hydroelectricity, especially heat pumps to provide (1) low temperature hot water for industrial applications, and (2) air conditioning and hot water for residential and commercial applications; solar thermal technology for low and intermediate temperature industrial process heat, and for crop drying; and small wind turbines and photovoltaic power systems for irrigation pumping and other rural applications. Certain technologies were excluded from the scope of the study by mutual agreement because a great deal of activity in such technologies was already taking place in Brazil, or because commercialization prospects seemed remote, or because of regulatory barriers. Energy conversion systems employing biomass, small- and large-scale hydropower, ocean thermal energy gradients, and cogeneration systems are not examined.

Jhirad, D.J.; Rutter, W.

1982-03-01T23:59:59.000Z

427

Schottky barrier MOSFET systems and fabrication thereof  

DOE Patents [OSTI]

(MOS) device systems-utilizing Schottky barrier source and drain to channel region junctions are disclosed. Experimentally derived results which demonstrate operation of fabricated N-channel and P-channel Schottky barrier (MOSFET) devices, and of fabricated single devices with operational characteristics similar to (CMOS) and to a non-latching (SRC) are reported. Use of essentially non-rectifying Schottky barriers in (MOS) structures involving highly doped and the like and intrinsic semiconductor to allow non-rectifying interconnection of, and electrical accessing of device regions is also disclosed. Insulator effected low leakage current device geometries and fabrication procedures therefore are taught. Selective electrical interconnection of drain to drain, source to drain, or source to source, of N-channel and/or P-channel Schottky barrier (MOSFET) devices formed on P-type, N-type and Intrinsic semiconductor allows realization of Schottky Barrier (CMOS), (MOSFET) with (MOSFET) load, balanced differential (MOSFET) device systems and inverting and non-inverting single devices with operating characteristics similar to (CMOS), which devices can be utilized in modulation, as well as in voltage controled switching and effecting a direction of rectification.

Welch, James D. (10328 Pinehurst Ave., Omaha, NE 68124)

1997-01-01T23:59:59.000Z

428

Enhanced Densification of SDC Barrier Layers  

SciTech Connect (OSTI)

This technical report explores the Enhanced Densification of SCD Barrier Layers A samaria-doped ceria (SDC) barrier layer separates the lanthanum strontium cobalt ferrite (LSCF) cathode from the yttria-stabilized zirconia (YSZ) electrolyte in a solid oxide fuel cell (SOFC) to prevent the formation of electrically resistive interfacial SrZrO{sub 3} layers that arise from the reaction of Sr from the LSCF with Zr from the YSZ. However, the sintering temperature of this SDC layer must be limited to {approx}1200 C to avoid extensive interdiffusion between SDC and YSZ to form a resistive CeO{sub 2}-ZrO{sub 2} solid solution. Therefore, the conventional SDC layer is often porous and therefore not as impervious to Sr-diffusion as would be desired. In the pursuit of improved SOFC performance, efforts have been directed toward increasing the density of the SDC barrier layer without increasing the sintering temperature. The density of the SDC barrier layer can be greatly increased through small amounts of Cu-doping of the SDC powder together with increased solids loading and use of an appropriate binder system in the screen print ink. However, the resulting performance of cells with these barrier layers did not exhibit the expected increase in accordance with that achieved with the prototypical PLD SDC layer. It was determined by XRD that increased sinterability of the SDC also results in increased interdiffusivity between the SDC and YSZ, resulting in formation of a highly resistive solid solution.

Hardy, John S.; Templeton, Jared W.; Lu, Zigui; Stevenson, Jeffry W.

2011-09-12T23:59:59.000Z

429

Near-Surface Engineered Environmental Barrier Integrity  

SciTech Connect (OSTI)

The INEEL Environmental Systems Research and Analysis (ESRA) program has launched a new R and D project on Near-Surface Engineered Environmental Barrier Integrity to increase knowledge and capabilities for using engineering and ecological components to improve the integrity of near-surface barriers used to confine contaminants from the public and the environment. The knowledge gained and the capabilities built will help verify the adequacy of past remedial decisions and enable improved solutions for future cleanup decisions. The research is planned to (a) improve the knowledge of degradation mechanisms (weathering, biological, geological, chemical, radiological, and catastrophic) in times shorter than service life, (b) improve modeling of barrier degradation dynamics, (c) develop sensor systems to identify degradation prior to failure, and (d) provide a better basis for developing and testing of new barrier systems to increase reliability and reduce the risk of failure. Our project combine s selected exploratory studies (benchtop and field scale), coupled effects accelerated aging testing and the meso-scale, testing of new monitoring concepts, and modeling of dynamic systems. The performance of evapo-transpiration, capillary, and grout-based barriers will be examined.

Piet, S.J.; Breckenridge, R.P.

2002-05-15T23:59:59.000Z

430

Near-Surface Engineered Environmental Barrier Integrity  

SciTech Connect (OSTI)

The INEEL Environmental Systems Research and Analysis (ESRA) program has launched a new R&D project on Near-Surface Engineered Environmental Barrier Integrity to increase knowledge and capabilities for using engineering and ecological components to improve the integrity of near-surface barriers used to confine contaminants from the public and the environment. The knowledge gained and the capabilities built will help verify the adequacy of past remedial decisions and enable improved solutions for future cleanup decisions. The research is planned to (a) improve the knowledge of degradation mechanisms (weathering, biological, geological, chemical, radiological, and catastrophic) in times shorter than service life, (b) improve modeling of barrier degradation dynamics, (c) develop sensor systems to identify degradation prior to failure, and (d) provide a better basis for developing and testing of new barrier systems to increase reliability and reduce the risk of failure. Our project combines selected exploratory studies (benchtop and field scale), coupled effects accelerated aging testing and the meso-scale, testing of new monitoring concepts, and modeling of dynamic systems. The performance of evapo- transpiration, capillary, and grout-based barriers will be examined.

Piet, Steven James; Breckenridge, Robert Paul; Beller, John Michael; Geesey, Gill Gregroy; Glenn, David Frankie; Jacobson, Jacob Jordan; Martian, Pete; Matthern, Gretchen Elise; Mattson, Earl Douglas; Porro, Indrek; Southworth, Finis Hio; Steffler, Eric Darwin; Stormberg, Angelica Isabel; Stormberg, Gregory John; Versteeg, Roelof Jan; White, Gregory J

2002-08-01T23:59:59.000Z

431

Metallic Bipolar Plates with Composite Coatings  

Broader source: Energy.gov (indexed) [DOE]

sheet form For corrosion resistance, apply a coating that is a composite of two materials: - Filler to provide electrical conductivity * Candidate Materials: graphite, carbon...

432

Degradation Mechanisms and Development of Protective Coatings...  

Broader source: Energy.gov (indexed) [DOE]

analyses before degradation tests. 5 Project Tasks per Period Phase 1 (FY13) * Task 1.1: Identification and characterization of candidate protective coatings for particular molten...

433

OVERLAY COATINGS FOR GAS TURBINE AIRFOILS  

E-Print Network [OSTI]

R. Krutenat, Gas Turbine Materials Conference Proceedings,Conference on Gas Turbine Materials in a Marine Environment,in developing new turbine materials, coatings and processes,

Boone, Donald H.

2013-01-01T23:59:59.000Z

434

Precise Application of Transparent Conductive Oxide Coatings...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide...

435

Spatially localized measurement of thermal conductivity using a hybrid photothermal technique  

SciTech Connect (OSTI)

A photothermal technique capable of measuring thermal conductivity with micrometer lateral resolution is presented. This technique involves measuring separately the thermal diffusivity, D, and thermal effusivity, e, to extract the thermal conductivity, k=(e2/D)1/2. To generalize this approach, sensitivity analysis was conducted for materials having a range of thermal conductivities. Experimental validation was sought using two substrate materials, SiO2 and CaF2, both coated with thin titanium films. The measured conductivities compare favorably with literature values.

David H Hurley; Marat Khafizov; Zilong Hua; Rory Kennedy; Heng Ban

2012-05-01T23:59:59.000Z

436

Non-destructive inspection protocol for reinforced concrete barriers and bridge railings  

SciTech Connect (OSTI)

Reinforced concrete highway barriers and bridge railings serve to prevent errant vehicles from departing the travel way at grade separations. Despite the important role that they play in maintaining safety and their ubiquitous nature, barrier inspection rarely moves beyond visual inspection. In August 2008, a tractor-trailer fatally departed William Preston Lane, Jr. Memorial Bridge after it dislodged a section of the bridge barrier. Investigations following the accident identified significant corrosion of the anchor bolts attaching the bridge railing to the bridge deck. As a result of the information gathered during its investigation of the accident, the National Transportation Safety Board (NTSB) made recommendations to the Federal Highway Administration concerning Non-Destructive Evaluation (NDE) of concrete bridge railings. The Center for nondestructive evaluation (NDE) at Turner Fairbank Highway Research Center in McLean, VA is currently evaluating feasibility of using four technologies - ground penetrating radar (GPR), ultrasonic pulse-echo, digital radiography and infrared thermal imaging methods to develop bridge inspection methods that augment visual inspections, offer reliable measurement techniques, and are practical, both in terms of time and cost, for field inspection work. Controlled samples containing predefined corrosion levels in reinforcing steel were embedded at barrier connection points for laboratory testing. All four NDE techniques were used in the initial phase I testing. An inspection protocol for detecting and measuring the corrosion of reinforced steel embedded in the anchorage system will be developed as part of phase II research. The identified technologies shall be further developed for field testing utilizing a structure with a barrier in good condition and a structure with a barrier in poor condition.

Chintakunta, Satish R. [Engineering and Software Consultants, Inc., 14123 Robert Paris Ct., Chantilly, VA 20151 (United States); Boone, Shane D. [Federal Highway Administration, Turner Fairbank Highway Research Center, 6300 Georgetown Pike, McLean, VA 22101 (United States)

2014-02-18T23:59:59.000Z

437

Thermal conductivity of thermal-battery insulations  

SciTech Connect (OSTI)

The thermal conductivities of a variety of insulating materials used in thermal batteries were measured in atmospheres of argon and helium using several techniques. (Helium was used to simulate the hydrogen atmosphere that results when a Li(Si)/FeS{sub 2} thermal battery ages.) The guarded-hot-plate method was used with the Min-K insulation because of its extremely low thermal conductivity. For comparison purposes, the thermal conductivity of the Min-K insulating board was also measured using the hot-probe method. The thermal-comparator method was used for the rigid Fiberfrax board and Fiberfrax paper. The thermal conductivity of the paper was measured under several levels of compression to simulate the conditions of the insulating wrap used on the stack in a thermal battery. The results of preliminary thermal-characterization tests with several silica aerogel materials are also presented.

Guidotti, R.A.; Moss, M.

1995-08-01T23:59:59.000Z

438

Prediction of tilted capillary barrier performance  

SciTech Connect (OSTI)

Capillary barriers, consisting of tilted fine-over-coarse layers under unsaturated conditions, have been suggested as landfill covers to divert water infiltration away from sensitive underground regions, especially for arid and semi-arid regions. The Hydrological Evaluation of Landfill Performance (HELP) computer code is an evaluation tool for landfill covers used by designers and regulators. HELP is a quasi-two-dimensional model that predicts moisture movement into and through the underground soil and waste layers. Processes modeled within HELP include precipitation, runoff, evapotranspiration, unsaturated vertical drainage, saturated lateral drainage, and leakage through liners. Unfortunately, multidimensional unsaturated flow phenomena that are necessary for evaluating tilted capillary barriers are not included in HELP. Differences between the predictions of the HELP and those from a multidimensional unsaturated flow code are presented to assess the two different approaches. Comparisons are presented for the landfill covers including capillary barrier configurations at the Alternative Landfill Cover Demonstration (ALCD) being conducted at Sandia.

Webb, S.W.; McCord, J.T.; Dwyer, S.F.

1997-04-01T23:59:59.000Z

439

W-320 Project thermal modeling  

SciTech Connect (OSTI)

This report summarizes the results of thermal analysis performed to provide a technical basis in support of Project W-320 to retrieve by sluicing the sludge in Tank 241-C-106 and to transfer into Tank 241-AY-102. Prior theraml evaluations in support of Project W-320 safety analysis assumed the availability of 2000 to 3000 CFM, as provided by Tank Farm Operations, for tank floor cooling channels from the secondary ventilation system. As this flow availability has no technical basis, a detailed Tank 241-AY-102 secondary ventilation and floor coating channel flow model was developed and analysis was performed. The results of the analysis show that only about 150 cfm flow is in floor cooLing channels. Tank 241-AY-102 thermal evaluation was performed to determine the necessary cooling flow for floor cooling channels using W-030 primary ventilation system for different quantities of Tank 241-C-106 sludge transfer into Tank 241-AY-102. These sludge transfers meet different options for the project along with minimum required modification of the ventilation system. Also the results of analysis for the amount of sludge transfer using the current system is presented. The effect of sludge fluffing factor, heat generation rate and its distribution between supernatant and sludge in Tank 241-AY-102 on the amount of sludge transfer from Tank 241-C-106 were evaluated and the results are discussed. Also transient thermal analysis was performed to estimate the time to reach the steady state. For a 2 feet sludge transfer, about 3 months time will be requirad to reach steady state. Therefore, for the purpose of process control, a detailed transient thermal analysis using GOTH Computer Code will be required to determine transient response of the sludge in Tank 241-AY-102. Process control considerations are also discussed to eliminate the potential for a steam bump during retrieval and storage in Tanks 241-C-106 and 241-AY-102 respectively.

Sathyanarayana, K., Fluor Daniel Hanford

1997-03-18T23:59:59.000Z

440

Pressurized security barrier and alarm system  

DOE Patents [OSTI]

A security barrier for placement across a passageway is made up of interconnected pressurized tubing made up in a grid pattern with openings too small to allow passage. The tubing is connected to a pressure switch, located away from the barrier site, which activates an alarm upon occurrence of a pressure drop. A reinforcing bar is located inside and along the length of the tubing so as to cause the tubing to rupture and set off the alarm upon an intruder`s making an attempt to crimp and seal off a portion of the tubing by application of a hydraulic tool. Radial and rectangular grid patterns are disclosed. 7 figures.

Carver, D.W.

1995-04-11T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Pressurized security barrier and alarm system  

DOE Patents [OSTI]

A security barrier for placement across a passageway is made up of interconnected pressurized tubing made up in a grid pattern with openings too small to allow passage. The tubing is connected to a pressure switch, located away from the barrier site, which activates an alarm upon occurrence of a pressure drop. A reinforcing bar is located inside and along the length of the tubing so as to cause the tubing to rupture and set off the alarm upon an intruder's making an attempt to crimp and seal off a portion of the tubing by application of a hydraulic tool. Radial and rectangular grid patterns are disclosed.

Carver, Don W. (Knoxville, TN)

1995-01-01T23:59:59.000Z

442

High Temperature Thermal Array for Next Generation Solar Thermal...  

Broader source: Energy.gov (indexed) [DOE]

High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This...

443

Corrosion protection of SiC-based ceramics with CVD mullite coatings  

SciTech Connect (OSTI)

SiC based ceramics have been identified as the leading candidate materials for elevated temperature applications in harsh oxidation/corrosion environments. It has been established that a protective coating can be effectively used to avoid problems with excessive oxidation and hot corrosion. However, to date, no coating configuration has been developed that can withstand the rigorous requirements imposed by such applications. Chemical vapor deposited (CVD) mullite coatings due to their desirable properties of toughness, corrosion resistance, and good coefficient of thermal expansion match with SiC are being developed as a potential solution. Formation of mullite on ceramic substrates via chemical vapor deposition was investigated. Thermodynamic calculations performed on the AlCl{sub 3}- SiCl{sub 4}-CO{sub 2}-H{sub 2} system were used to construct equilibrium CVD phase diagrams. Through process optimization, crystalline CVD mullite coatings have been successfully grown on SiC and Si{sub 3}N{sub 4} substrates. Results from the thermodynamic analysis, process optimization, and effect of various process parameters on deposition rate and coating morphology are discussed.

Sarin, V.; Mulpuri, R.; Auger, M. [Boston University, Boston, MA (United States) Manufacturing Engineering

1996-04-20T23:59:59.000Z

444

Tribological performance of hybrid filtered arc-magnetron coatings - Part I: Coating deposition process and basic coating properties characterization  

SciTech Connect (OSTI)

Aircraft propulsion applications require low-friction and wear resistant surfaces that operate under high contact loads in severe environments. Recent research on supertough and low friction nanocomposite coatings produced with hybrid plasma deposition processes was demonstrated to have a high potential for such demanding applications. However, industrially scalable hybrid plasma technologies are needed for their commercial realization. The Large area Filtered Arc Deposition (LAFAD) process provides atomically smooth coatings at high deposition rates over large surface areas. The LAFAD technology allows functionally graded, multilayer, super-lattice and nanocomposite architectures of multi-elemental coatings via electro-magnetic mixing of two plasma flows composed of different metal ion vapors. Further advancement can be realized through a combinatorial process using a hybrid filtered arc-magnetron deposition system. In the present study, multilayer and nanostructured TiCrCN/TiCr +TiBC composite cermet coatings were deposited by the hybrid filtered arc-magnetron process. Filtered plasma streams from arc evaporated Ti and Cr targets, and two unbalanced magnetron sputtered B4C targets, were directed to the substrates in the presence of reactive gases. A multiphase nanocomposite coating architecture was designed to provide the optimal combination of corrosion and wear resistance of advanced steels (Pyrowear 675) used in aerospace bearing and gear applications. Coatings were characterized using SEM/EDS, XPS and RBS for morphology and chemistry, XRD and TEM for structural analyses, wafer curvature and nanoindentation for stress and mechanical properties, and Rockwell and scratch indentions for adhesion. Coating properties were evaluated for a variety of coating architectures. Thermodynamic modeling was used for estimation of phase composition of the top TiBC coating segment. Correlations between coating chemistry, structure and mechanical properties are discussed.

Gorokhovsky, Vladimir; Bowman, C.; Gannon, Paul E.; VanVorous, D.; Voevodin, A. A.; Rutkowski, A.; Muratore, C.; Smith, Richard J.; Kayani, Asghar N.; Gelles, David S.; Shutthanandan, V.; Trusov, B. G.

2006-12-04T23:59:59.000Z

445

FIRE IMPACTS ON AN ENGINEERED BARRIER’S PERFORMANCE: THE HANFORD BARRIER ONE YEAR AFTER A CONTROLLED BURN  

SciTech Connect (OSTI)

A critical unknown for long-term engineered barrier performance is the effect of wild fire during a post-institutional control environment where routine maintenance may be limited or non-existent. In September 2008, a controlled burn was conducted on one half of a vegetated, multilayered capillary barrier emplaced over a Hanford waste site. The effects on barrier performance have been monitored and documented over the past year. Soil physical, chemical, and hydrologic properties; plant floristics and density; and animal-use were characterized before and after the fire with the unburned half of the barrier serving as a control. Temperatures during the controlled burn ranged from 250 oC at 1.5 cm below the surface to over 700 oC at 1 m above the surface. Significant decreases in hydraulic conductivity and surface-soil wettability were observed immediately after the fire due primarily to hydrophobic conditions created by the fire. Major soil nutrients, pH, and electrical conductivity remain elevated post-fire. Up until June 2009, post-burn soil moisture content in the 0-1 m depth interval was significantly lower on the burned section than the unburned section and is attributed to differences in surface evaporation. Higher soil moisture contents in the 1-2 m interval on the burned section are attributed to insignificant water uptake owing to the absence of deep-rooted shrubs. Moisture profiles reversed after June to show lower water contents throughout the profile on the unburned section. Dense stands of sagebrush were destroyed from the fire allowing many more species to emerge thereby increasing species diversity. Seed sources contributing to this species diversification were from either the existing seedbank and/or wind-blown sources. Measurements are ongoing and the results are expected to help close a knowledge gap about barrier recovery after major disturbances.

Ward, Anderson L.; Link, Steven O.; Leary, Kevin D.; Berlin, Gregory T.

2010-03-31T23:59:59.000Z

446

Metallic Bipolar Plates with Composite Coatings  

E-Print Network [OSTI]

that is available in sheet form For corrosion resistance, apply a coating that is a composite of two materials: ­ Filler to provide electrical conductivity · Candidate Materials: graphite, carbon black, TiB2 and CaB6Metallic Bipolar Plates with Composite Coatings Jennifer Mawdsley Argonne National Laboratory Fuel

447

Cationic electrodepositable coating composition comprising lignin  

SciTech Connect (OSTI)

A cationic electrodepositable coating composition is disclosed. The present invention in directed to a cationic electrodepositable coating composition comprising a lignin-containing cationic salt resin, that comprises (A) the reaction product of: lignin, an amine, and a carbonyl compound; (B) the reaction product of lignin, epichlorohydrin, and an amine; or (C) combinations thereof.

Fenn, David; Bowman, Mark P; Zawacky, Steven R; Van Buskirk, Ellor J; Kamarchik, Peter

2013-07-30T23:59:59.000Z

448

Flexible Ultra Moisture Barrier Film for Thin-Film Photovoltaic Applications  

SciTech Connect (OSTI)

Flexible Thin-film photovoltaic (TFPV) is a low cost alternative to incumbent c-Si PV products as it requires less volume of costly semiconductor materials and it can potentially reduce installation cost. Among the TFPV options, copper indium gallium diselenide (CIGS) has the highest efficiency and is believed to be one of the most attractive candidates to achieve PV cost reduction. However, CIGS cells are very moisture sensitive and require module water vapor transmission rate (WVTR) of less than 1x10-4 gram of water per square meter per day (g-H2O/m2/day). Successful development and commercialization of flexible transparent ultra moisture barrier film is the key to enable flexible CIGS TFPV products, and thus enable ultimate PV cost reduction. At DuPont, we have demonstrated at lab scale that we can successfully make polymer-based flexible transparent ultra moisture barrier film by depositing alumina on polymer films using atomic layer deposition (ALD) technology. The layer by layer ALD approach results in uniform and amorphous structure which effectively reduces pinhole density of the inorganic coating on the polymer, and thus allow the fabrication of flexible barrier film with WVTR of 10-5 g-H2O/m2/day. Currently ALD is a time-consuming process suitable only for high-value, relatively small substrates. To successfully commercialize the ALD-on-plastic technology for the PV industry, there is the need to scale up this technology and improve throughput. The goal of this contract work was to build a prototype demonstrating that the ALD technology could be scaled-up for commercial use. Unfortunately, the prototype failed to produce an ultra-barrier film by the close of the project.

David M. Dean

2012-10-30T23:59:59.000Z

449

Seasonal thermal energy storage  

SciTech Connect (OSTI)

This report describes the following: (1) the US Department of Energy Seasonal Thermal Energy Storage Program, (2) aquifer thermal energy storage technology, (3) alternative STES technology, (4) foreign studies in seasonal thermal energy storage, and (5) economic assessment.

Allen, R.D.; Kannberg, L.D.; Raymond, J.R.

1984-05-01T23:59:59.000Z

450

Method of coating metal surfaces to form protective metal coating thereon  

DOE Patents [OSTI]

A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

Krikorian, O.H.; Curtis, P.G.

1992-03-31T23:59:59.000Z

451

Midtemperature Solar Systems Test Facility predictions for thermal performance based on test data: Custom Engineering trough with glass reflector surface and Sandia-designed receivers  

SciTech Connect (OSTI)

Thermal performance predictions based on test data are presented for the Custom Engineering trough and Sandia-designed receivers, with glass reflector surface, for three output temperatures at five cities in the United States. Two experimental receivers were tested, one with an antireflective coating on the glass envelope around the receiver tube and one without the antireflective coating.

Harrison, T.D.

1981-05-01T23:59:59.000Z

452

Development of Steel Fastener Nano-Ceramic Coatings for Corrosion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium Parts (AMD-704) Development of Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium...

453

High-Temperatuer Solar Selective Coating Development for Power...  

Broader source: Energy.gov (indexed) [DOE]

High-Temperatuer Solar Selective Coating Development for Power Tower Receivers High-Temperatuer Solar Selective Coating Development for Power Tower Receivers This presentation was...

454

Sacrificial Protective Coating Materials That Can Be Regenerated...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sacrificial Protective Coating Materials That Can Be Regenerated In-Situ to Enable High-Performance Membranes Sacrificial Protective Coating Materials That Can Be Regenerated...

455

Method for smoothing the surface of a protective coating  

DOE Patents [OSTI]

A method for smoothing the surface of a ceramic-based protective coating which exhibits roughness is disclosed. The method includes the steps of applying a ceramic-based slurry or gel coating to the protective coating surface; heating the slurry/gel coating to remove volatile material; and then further heating the slurry/gel coating to cure the coating and bond it to the underlying protective coating. The slurry/gel coating is often based on yttria-stabilized zirconia, and precursors of an oxide matrix. Related articles of manufacture are also described.

Sangeeta, D. (Cincinnati, OH); Johnson, Curtis Alan (Schenectady, NY); Nelson, Warren Arthur (Clifton Park, NY)

2001-01-01T23:59:59.000Z

456

Accelerated Testing of HT-9 with Zirconia Coatings Containing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of HT-9 with Zirconia Coatings Containing Gallium using Raman Spectroscopy and XPS. Accelerated Testing of HT-9 with Zirconia Coatings Containing Gallium using Raman Spectroscopy...

457

Project Profile: High-Temperature Solar Selective Coating Development...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Solar Selective Coating Development for Power Tower Receivers Project Profile: High-Temperature Solar Selective Coating Development for Power Tower Receivers Sandia National...

458

Thermal unobtainiums? The perfect thermal conductor and  

E-Print Network [OSTI]

contribute to thermal resistance · Isotopically pure diamond has highest thermal conductivity of any material materials: disordered layered crystals Conclude with some thoughts on promising, high-risk, research even in a computer model. #12;Thermal resistance is created by Umklapp scattering (U

Braun, Paul

459

Electrical Transport in Schottky Barrier MOSFETs  

E-Print Network [OSTI]

Barrier (SB) MOSFET is one such device. It consists of metallic silicide source and drain contacts' that result in a reduced local potential at the abrupt metal/semiconductor interface. At relatively high at the Metal/Semiconductor Interface 66 4.3. Current Transport Limits 69 4.4. Sub-threshold Regime 72 4

Reed, Mark

460

IDENTIFYING AND OVERCOMING BARRIERS TO CLIMATE CHANGE  

E-Print Network [OSTI]

communities need outside intervention to address "legacy" and "remote" barriers. With still very little--even in highly developed nations--for the scientific community in terms of future research priorities significant in motivating or launching the adaptation process. The study also found that communities have

Note: This page contains sample records for the topic "thermal barrier coatings" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.