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Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
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1

Thermal Barrier Coatings  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Barrier Coatings Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States...

2

Catalytic thermal barrier coatings  

Science Conference Proceedings (OSTI)

A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

Kulkarni, Anand A. (Orlando, FL); Campbell, Christian X. (Orlando, FL); Subramanian, Ramesh (Oviedo, FL)

2009-06-02T23:59:59.000Z

3

Thermal barrier coating  

SciTech Connect

A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

Bowker, Jeffrey Charles (Gibsonia, PA); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL)

2001-01-01T23:59:59.000Z

4

Multilayer thermal barrier coating systems  

DOE Patents (OSTI)

The present invention generally describes multilayer thermal barrier coating systems and methods of making the multilayer thermal barrier coating systems. The thermal barrier coating systems comprise a first ceramic layer, a second ceramic layer, a thermally grown oxide layer, a metallic bond coating layer and a substrate. The thermal barrier coating systems have improved high temperature thermal and chemical stability for use in gas turbine applications.

Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

2000-01-01T23:59:59.000Z

5

Thermal barrier coatings  

DOE Patents (OSTI)

This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.

Alvin, Mary Anne (Pittsburg, PA)

2010-06-22T23:59:59.000Z

6

Multilayer Nanoscale Thermal Barrier Coatings  

Science Conference Proceedings (OSTI)

Advanced high-efficiency gas turbines require thermal barrier coatings (TBCs) with low thermal conductivity and excellent thermal-cycling resistance. The multilayer TBC developed in this project has a thermal conductivity about half that of conventional TBCs and also rejects up to 70 percent of incoming radiant energy.

1999-05-26T23:59:59.000Z

7

Thermal barrier coating for alloy systems  

DOE Patents (OSTI)

An alloy substrate is protected by a thermal barrier coating formed from a layer of metallic bond coat and a top coat formed from generally hollow ceramic particles dispersed in a matrix bonded to the bond coat.

Seals, Roland D. (Oak Ridge, TN); White, Rickey L. (Harriman, TN); Dinwiddie, Ralph B. (Knoxville, TN)

2000-01-01T23:59:59.000Z

8

Combustion chemical vapor deposited coatings for thermal barrier coating systems  

DOE Green Energy (OSTI)

The new deposition process, combustion chemical vapor deposition, shows a great deal of promise in the area of thermal barrier coating systems. This technique produces dense, adherent coatings, and does not require a reaction chamber. Coatings can therefore be applied in the open atmosphere. The process is potentially suitable for producing high quality CVD coatings for use as interlayers between the bond coat and thermal barrier coating, and/or as overlayers, on top of thermal barrier coatings. In this report, the evaluation of alumina and ceria coatings on a nickel-chromium alloy is described.

Hampikian, J.M.; Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States). School of Materials Science and Engineering

1995-12-31T23:59:59.000Z

9

Damage Evolution in Thermal Barrier Coatings with Thermal Cycling  

Science Conference Proceedings (OSTI)

Abstract Scope, Thermal barrier coatings typically fail on cooling after prolonged thermal cycling by the growth of sub-critical interface separations. Observations ...

10

Multilayer Thermal Barrier Coatings: Interplay Among Coating ...  

Science Conference Proceedings (OSTI)

Cold Sprayed Aluminum Based Glassy Coatings for Improved Corrosion and Wear ... Effect of Thermal Cycling and Sliding on the Structure of Cu-Nb Nanolaminates ... Based on Oscillatory Voltage Wave Forms for Insulating Film Depositions.

11

Advanced Thermal Barrier Coating System Development  

DOE Green Energy (OSTI)

The objectives of the program are to provide an improved Thermal Barrier Coating (TBC) system with increased temperature capability and improved reliability relative to current state of the art TBC systems. The development of such a coating system is essential to the ATS engine meeting its objectives. The base program consists of three phases: Phase I: Program Planning - Complete; Phase II: Development; and Phase III: Selected Specimen - Bench Test Work is being performed in Phase II and III of the program.

NONE

1999-03-31T23:59:59.000Z

12

Deposition of Graded Thermal Barrier Coatings for Gas Turbine ...  

Wind Energy Industrial Technologies Advanced Materials Deposition of Graded Thermal Barrier Coatings for Gas Turbine Blades Sandia National ...

13

Ion beam assisted deposition of thermal barrier coatings ...  

... Energy Innovation Portal on Google; Bookmark Ion beam assisted deposition of thermal barrier coatings - Energy Innovation Portal on Delicious ...

14

Thermal Barrier Coating Systems II  

Science Conference Proceedings (OSTI)

Oct 26, 2009... on the application requirements and not on substrate physical properties such as thermal expansion rate Esp. within the same class of alloys.

15

Thermal barrier coating having high phase stability  

DOE Patents (OSTI)

A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating characterized by a microstructure having gaps (28) where the thermal barrier coating comprises a first thermal barrier layer (40), and a second thermal barrier layer (30) with a pyrochlore crystal structure having a chemical formula of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof, where B is selected from the group of elements consisting of Zr, Hf, Ti and mixtures thereof, where n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

Subramanian, Ramesh (Oviedo, FL)

2002-01-01T23:59:59.000Z

16

Pratt and Whitney thermal barrier coatings  

DOE Green Energy (OSTI)

Thermal barrier coatings (TBCs) will be used to achieve the objectives of the Advanced Turbine Systems (ATS) program. They are used in aircraft engines and have accumulated millions upon millions of reliable hours. Differences in the duty cycles of the aircraft and industrial gas turbines are recognized as is the marked differences in environmental operational envelope. At the completion of this program the TBCs best suited to meet the needs of the ATS program will have been identified, tested, and confirmed.

Bornstein, N. [United Technologies Research Center, East Hartford, CT (United States); Marcin, J. [Pratt and Whitney Aircraft, East Hartford, CT (United States)

1995-12-31T23:59:59.000Z

17

Multilayer Thermal Barrier Coatings: Interplay Among Coating ...  

Science Conference Proceedings (OSTI)

... and resistant to environmental damage from ingested sand particles ( categorized ... A Study on the Hot Corrosion Resistance of Metal-cemet-glass Coating on ...

18

Thermal barrier coating resistant to sintering  

DOE Patents (OSTI)

A device (10) having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10) and is not soluble with the underlying ceramic layer (16). For a YSZ ceramic layer (16) the sintering resistant layer (22) may preferably be aluminum oxide or yttrium aluminum oxide, deposited as a continuous layer or as nodules.

Subramanian, Ramesh (Orlando, FL); Sabol, Stephen M. (Orlando, FL)

2001-01-01T23:59:59.000Z

19

Degradation of Thermal Barrier Coatings from Deposits and Its...  

NLE Websites -- All DOE Office Websites (Extended Search)

Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation-The Ohio State University Background When coal derived synthesis gas (syngas) is used in place of natural...

20

Thermal Barrier Coatings for Resistance Against Attack by Molten ...  

Science Conference Proceedings (OSTI)

Presentation Title, Thermal Barrier Coatings for Resistance Against Attack by Molten Silicate Deposits from CMAS Sand, Volcanic Ash, or Coal Fly Ash Ingested ...

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Thermal barrier coatings for turbine components  

DOE Patents (OSTI)

A turbine component, such as a turbine blade having a metal substrate (22) is coated with a metal MCrAlY alloy layer (24) and then a thermal barrier layer (20) selected from LaAlO.sub.3, NdAlO.sub.3, La.sub.2 Hf.sub.2 O.sub.7, Dy.sub.3 Al.sub.5 O.sub.12, HO.sub.3 Al.sub.3 O.sub.12, ErAlO.sub.3, GdAlO.sub.3, Yb.sub.2 Ti.sub.2 O.sub.7, LaYbO.sub.3, Gd.sub.2 Hf.sub.2 O.sub.7 or Y.sub.3 Al.sub.5 O.sub.12.

Subramanian, Ramesh (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sloan, Kelly M. (Bethesda, MD); Vance, Steven J. (Orlando, FL)

2002-01-01T23:59:59.000Z

22

Ceramic thermal barrier coating for rapid thermal cycling applications  

DOE Patents (OSTI)

A thermal barrier coating for metal articles subjected to rapid thermal cycling includes a metallic bond coat deposited on the metal article, at least one MCrAlY/ceramic layer deposited on the bond coat, and a ceramic top layer deposited on the MCrAlY/ceramic layer. The M in the MCrAlY material is Fe, Ni, Co, or a mixture of Ni and Co. The ceramic in the MCrAlY/ceramic layer is mullite or Al.sub.2 O.sub.3. The ceramic top layer includes a ceramic with a coefficient of thermal expansion less than about 5.4.times.10.sup.-6 .degree.C.sup.-1 and a thermal conductivity between about 1 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1 and about 1.7 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1.

Scharman, Alan J. (Hebron, CT); Yonushonis, Thomas M. (Columbus, IN)

1994-01-01T23:59:59.000Z

23

Advanced thermal barrier coating system development. Technical progress report  

Science Conference Proceedings (OSTI)

This report describes work to develop new thermal barrier coating systems, which will be essential to the operation of the ATS engine which is under development. Work is at the stage of process improvement and bond coat improvement, along with proof testing of the coatings under thermal conditions typical of what can be expected in the ATS engine.

NONE

1998-03-16T23:59:59.000Z

24

Superior Thermal Barrier Coatings for Industrial Gas-Turbine...  

NLE Websites -- All DOE Office Websites (Extended Search)

070103 (36 Months Duration) 546,000 Total Contract Value (546,000 DOE) Superior Thermal Barrier Coatings for Industrial Gas-Turbine Engines Using a Novel Solution-Precursor...

25

Thermomechanical behavior of plasma-sprayed zirconia thermal barrier coatings.  

SciTech Connect

The effect of coating porosity and thickness on the resistance to damage of yttria stabilized zirconia thermal barrier coatings in an oxidizing environment by thermal cycling was evaluated. Hardness and elastic modulus of an as-processed porous coating were lower than those of a dense coating and the porous coating failed after fewer thermal cycles. Similarly, specimen with a thicker coating failed after fewer thermal cycles than specimen with a thinner coating. The earlier failure of the porous coating is due to lower fracture toughness and enhanced oxidation of the coating/substrate interface, whereas, the earlier failure of the thick coating is due to higher thermal transient stresses that developed in the coating during thermal cycling. Generally, an increase in coating density led to initial increase in both hardness and elastic modulus with increasing thermal cycles. However, hardness and density gradually decreased as the number of thermal cycles increase because of microcracks formation and growth. Microscopic observations indicated that the formation of multiple microcracks and their subsequent growth and coalescence led to final coating failure.

Singh, J. P.

1998-04-01T23:59:59.000Z

26

Interface Science of Thermal Barrier Coatings  

SciTech Connect

The drive for greater efficiency in propulsion and industrial/power production machinery has pushed metallurgy to develop ever better alloys and taken existing metallic components to their reliability threshold. Nowhere is that better illustrated than in turbine engine materials. The nickel-based superalloys currently in use for the most demanding areas of the engines melt at 1230-1315 aC and yet see combustion environments >1600 aC. The result is that these components require thermal protection to avoid failure from phenomena such as melting, creep, oxidation, thermal fatigue, and so on [1]. The stakes are high as the equipment must remain reliable for thousands of take-offs and landings for aircraft turbine engines, and up to 40,000 hours of operation in power generating land-based gas turbines [2, 3]. One of the most critical items that see both the greatest temperatures and experience the highest stresses is the hot-section turbine blades. Two strategies have been adopted to help the superalloy turbine blades survive the demanding environment: Active air cooling and ceramic thermal protection coatings, which together can reduce metal surface temperatures by >300 aC.[2]. The combination of turbine blade external film cooling and internal air cooling requires an exceptionally complex structure with flow passages and sets of small holes in the blades where air bled from a matching stage of the compressor is directed over the surface. Stecura [4] was among the first to describe a successful coating system, and today s the ceramic insulating layer alone is credited with reducing metal temperatures as much as 165 aC [1, 5].

Besmann, Theodore M [ORNL

2009-01-01T23:59:59.000Z

27

Bond strength and stress measurements in thermal barrier coatings  

DOE Green Energy (OSTI)

Thermal barrier coatings have been used extensively in aircraft gas turbines for more than 15 years to insulate combustors and turbine vanes from the hot gas stream. Plasma sprayed thermal barrier coatings (TBCs) provide metal temperature reductions as much as 300{degrees}F, with improvements in durability of two times or more being achieved. The introduction of TBCs deposited by electron beam physical vapor deposition (EB-PVD) processes in the last five years has provided a major improvement in durability and also enabled TBCs to be applied to turbine blades for improved engine performance. This program evaluates the bond strength of yttria stabilized zirconia coatings with MCrAlY and Pt-Al bond coats utilizing diffraction and fluorescence methods.

Gell, M.; Jordan, E.

1995-12-31T23:59:59.000Z

28

In Situ Temporary Repair of Thermal Barrier Coatings  

Science Conference Proceedings (OSTI)

The durability of thermal barrier coatings (TBCs) on combustion turbine blades and vanes is a critical issue in the power generation industry. Degradation of TBCs occur by the spallation of the ceramic layer — partially stabilized zirconia (PSZ) — that resides on the Al2O3-covered MCrAlY bondcoat. In the event of such local failures of the TBC, a quick in-situ technique to repair the coating would be desirable.

2005-03-31T23:59:59.000Z

29

Thermal Barrier Coatings Resistant to Attack by Molten Fly Ash in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Thermal Barrier Coatings Resistant to Attack by Molten Fly Ash in Integrated Gas Combined Cycle Turbine Engines. Author(s), Andrew D.

30

FARADAYIC ElectroPhoretic Deposition of YSZ for Use in Thermal Barrier Coatings - Faraday Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

FARADAYIC ElectroPhoretic Deposition FARADAYIC ElectroPhoretic Deposition of YSZ for Use in Thermal Barrier Coatings-Faraday Technology Background Thermal barrier coatings (TBCs) are employed to protect gas turbine engine components. These coating systems provide thermal, oxidation, and mechanical protection; reduce thermal gradients; and lower the metal substrate surface temperature, extending the life of the engine components. Faraday Technology, Inc. (Faraday) is developing a new manufacturing process, the

31

Advanced thermal barrier coating system development. Technical progress report, September 1, 1997--November 30, 1997  

SciTech Connect

The objectives of this project were to provide an improved thermal barrier coating system with increased temperature capability and reliability. This report describes bond coat development, manufacturing, nondestructive evaluation, maintenance, and repair, and bench testing.

1997-12-12T23:59:59.000Z

32

The effect of thermal aging on the thermal conductivity of plasma sprayed and EB-PVD thermal barrier coatings  

DOE Green Energy (OSTI)

Thermal barrier coatings (TBCs) applied to the hot gas components of turbine engines lead to enhanced fuel efficiency and component reliability. Understanding the mechanisms which control the thermal transport behavior of the TBCs is of primary importance. Electron beam-physical vapor deposition (EV-PVD) and air plasma spraying (APS) are the two most commonly used coating techniques. These techniques produce coatings with unique microstructures which control their performance and stability. The density of the APS coatings was controlled by varying the spray parameters. The low density APS yttria-partially stabilized zirconia (yttria-PSZ) coatings yielded a thermal conductivity that is lower than both the high density APS coatings and the EB-PVD coatings. The thermal aging of both fully and partially stabilized zirconia are compared. The thermal conductivity of the coatings permanently increases upon exposure to high temperatures. These increases are attributed to microstructural changes within the coatings. This increase in thermal conductivity can be modeled using a relationship which depends on both the temperature and time of exposure. Although the EB-PVD coatings are less susceptible to thermal aging effects, results suggest that they typically have a higher thermal conductivity than APS coatings before thermal aging. The increases in thermal conductivity due to thermal aging for plasma sprayed partially stabilized zirconia have been found to be less than for plasma sprayed fully stabilized zirconia coatings.

Dinwiddie, R.B.; Beecher, S.C.; Porter, W.D. [Oak Ridge National Lab., TN (United States); Nagaraj, B.A. [General Electric Co., Cincinnati, OH (United States). Aircraft Engine Group

1996-05-01T23:59:59.000Z

33

Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation  

SciTech Connect

Ceramic thermal barrier coatings (TBCs) used in gas-turbine engines afford higher operating temperatures, resulting in enhanced efficiencies and performance. However, in the case of syngas-fired engines, fly ash particulate impurities that may be present in syngas can melt on the hotter TBC surfaces and form glassy deposits. These deposits can penetrate the TBCs leading to their failure. In experiments using lignite fly ash to simulate these conditions we show that conventional TBCs of composition 93wt% ZrO{sub 2} + 7wt% Y{sub 2}O{sub 3} (7YSZ) fabricated using the air plasma spray (APS) process are completely destroyed by the molten fly ash. The molten fly ash is found to penetrate the full thickness of the TBC. The mechanisms by which this occurs appear to be similar to those observed in degradation of 7YSZ TBCs by molten calcium-magnesium-aluminosilicate (CMAS) sand and by molten volcanic ash in aircraft engines. In contrast, APS TBCs of Gd{sub 2}Zr{sub 2}O{sub 7} composition are highly resistant to attack by molten lignite fly ash under identical conditions, where the molten ash penetrates ~25% of TBC thickness. This damage mitigation appears to be due to the formation of an impervious, stable crystalline layer at the fly ash/Gd{sub 2}Zr{sub 2}O{sub 7} TBC interface arresting the penetrating moltenfly- ash front. Additionally, these TBCs were tested using a rig with thermal gradient and simultaneous accumulation of ash. Modeling using an established mechanics model has been performed to illustrate the modes of delamination, as well as further opportunities to optimize coating microstructure. Transfer of the technology was developed in this program to all interested parties.

Padture, Nitin

2011-12-31T23:59:59.000Z

34

Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation  

Science Conference Proceedings (OSTI)

Ceramic thermal barrier coatings (TBCs) used in gas-turbine engines afford higher operating temperatures, resulting in enhanced efficiencies and performance. However, in the case of syngas-fired engines, fly ash particulate impurities that may be present in syngas can melt on the hotter TBC surfaces and form glassy deposits. These deposits can penetrate the TBCs leading to their failure. In experiments using lignite fly ash to simulate these conditions we show that conventional TBCs of composition 93wt% ZrO{sub 2} + 7wt% Y{sub 2}O{sub 3} (7YSZ) fabricated using the air plasma spray (APS) process are completely destroyed by the molten fly ash. The molten fly ash is found to penetrate the full thickness of the TBC. The mechanisms by which this occurs appear to be similar to those observed in degradation of 7YSZ TBCs by molten calcium-magnesium-aluminosilicate (CMAS) sand and by molten volcanic ash in aircraft engines. In contrast, APS TBCs of Gd{sub 2Zr{sub 2}O{sub 7} composition are highly resistant to attack by molten lignite fly ash under identical conditions, where the molten ash penetrates ~25% of TBC thickness. This damage mitigation appears to be due to the formation of an impervious, stable crystalline layer at the fly ash/Gd{sub 2}Zr{sub 2}O{sub 7} TBC interface arresting the penetrating moltenfly- ash front. Additionally, these TBCs were tested using a rig with thermal gradient and simultaneous accumulation of ash. Modeling using an established mechanics model has been performed to illustrate the modes of delamination, as well as further opportunities to optimize coating microstructure. Transfer of the technology was developed in this program to all interested parties.

Nitin Padture

2011-12-31T23:59:59.000Z

35

Low-Conductivity Thermal Barrier Coating for Gas Turbines: Material Testing Status  

Science Conference Proceedings (OSTI)

Advanced gas turbines rely on air-cooled components protected by ceramic thermal barrier coatings to survive increasingly high operating temperatures. A new generation of coatings offers lower thermal conductivity, potentially further reducing component heat loading, which can improve durability, lower life cycle cost, and enable longer range efficiency gains. Testing improved coatings is a necessary step towards field demonstration.BackgroundAs gas turbine ...

2012-12-31T23:59:59.000Z

36

Functionally gradient materials for thermal barrier coatings in advanced gas turbine systems  

DOE Green Energy (OSTI)

New designs for advanced gas turbine engines for power production are required to have higher operating temperatures in order to increase efficiency. However, elevated temperatures will increase the magnitude and severity of environmental degradation of critical turbine components (e.g. combustor parts, turbine blades, etc.). To offset this problem, the usage of thermal barrier coatings (TBCs) has become popular by allowing an increase in maximum inlet temperatures for an operating engine. Although thermal barrier technology is over thirty years old, the principle failure mechanism is the spallation of the ceramic coating at or near the ceramic/bond coat interface. Therefore, it is desirable to develop a coating that combines the thermal barrier qualities of the ceramic layer and the corrosion protection by the metallic bond coat without the detrimental effects associated with the localization of the ceramic/metal interface to a single plane.

Banovic, S.W.; Chan, H.M.; Marder, A.R. [Lehigh Univ., Bethlehem, PA (United States)] [and others

1995-12-31T23:59:59.000Z

37

A model for residual stress evolution in air-plasma-sprayed zirconia thermal barrier coatings  

Science Conference Proceedings (OSTI)

Ruby fluorescence spectroscopy indicates that residual stress in air-plasma-sprayed zirconia thermal barrier coatings is a function of the local interface geometry. The stress profile of a simulated rough interface characterized by ``peaks'' and ``valleys'' was modeled with a finite-element approach that accounted for thermal mismatch, oxide scale growth, and top coat sintering. Dependence of the stress profile on interface geometry and microstructure was investigated, and the results were compared with measured stresses.

Nair, B. G.; Singh, J. P.; Grimsditch, M.

2000-02-28T23:59:59.000Z

38

The effect of sintering and CMAS on the stability of plasma-sprayed zirconia thermal barrier coatings  

E-Print Network (OSTI)

State of the art thermal barrier coatings (TBCs) for gas turbine applications comprise (7 wt.%) yttria partially stabilized zirconia (7YSZ). 7YSZ offers a range of attractive functional properties – low thermal conductivity, high thermal expansion...

Shinozaki, Maya

2013-07-09T23:59:59.000Z

39

On the oxidation of high-temperature alloys, and its role in failure of thermal barrier coatings  

E-Print Network (OSTI)

Thermal barrier coating (TBC) systems are applied to superalloy turbine blades to provide thermal insulation and oxidation protection. A TBC system consists of (a) an outer oxide layer that imparts thermal insulation, and ...

Loeffel, Kaspar Andreas

2013-01-01T23:59:59.000Z

40

Thermal Barrier Coatings for Low Emission, High Efficiency Diesel Engine Applications  

DOE Green Energy (OSTI)

Thermal efficiencies of 54% have been demonstrated by single cylinder engine testing of advanced diesel engine concepts developed under Department of Energy funding. In order for these concept engines to be commercially viable, cost effective and durable systems for insulating the piston, head, ports and exhaust manifolds will be required. The application and development of new materials such as thick thermal barrier coating systems will be key to insulating these components. Development of test methods to rapidly evaluate the durability of coating systems without expensive engine testing is a major objective of current work. In addition, a novel, low cost method for producing thermal barrier coated pistons without final machining of the coating has been developed.

M. B. Beardsley; P. G. Happoldt; K.C. Kelley; E. F. Rejda; D. F. Socie

1999-04-26T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Some effects of metallic substrate composition on degradation of thermal barrier coatings  

SciTech Connect

Comparisons have been made in laboratory isothermal and cyclic oxidation tests of the degradation of oxide scales grown on single crystal superalloy substrates and bond coating alloys intended for use in thermal barrier coatings systems. The influence of desulfurization of the superalloy and bond coating, of reactive element addition to the bond coating alloy, and of oxidation temperature on the spallation behavior of the alumina scales formed was assessed from oxidation kinetics and from SEM observations of the microstructure and composition of the oxide scales. Desulfurization of nickel-base superalloy (in the absence of a Y addition) resulted in an increase in the lifetime of a state-of-the-art thermal barrier coating applied to it compared to a Y-free, non-desulfurized version of the alloy. The lifetime of the same ceramic coating applied without a bond coating to a non-desulfurized model alloy that formed an ideal alumina scale was also found to be at least four times longer than on the Y-doped superalloy plus state-of-the-art bond coating combination. Some explanations are offered of the factors controlling the degradation of such coatings.

Wright, I.G.; Pint, B.A.; Lee, W.Y.; Alexander, K.B.; Pruessner, K.

1997-12-31T23:59:59.000Z

42

Advanced thermal barrier coating system development: Technical progress report  

DOE Green Energy (OSTI)

Objectives are to provide an improved TBC system with increased temperature capability and improved reliability. Such coating systems are essential to the ATS engine (gas turbine) meeting its objectives.

NONE

1996-12-11T23:59:59.000Z

43

Assessment of Failure Mechanisms for Thermal Barrier Coatings by Photoluminescence, Electrochemical Impedance and Focused Ion Beam  

NLE Websites -- All DOE Office Websites (Extended Search)

H. Sohn, B. Jayaraj and V.H. Desai H. Sohn, B. Jayaraj and V.H. Desai SCIES Project 02- 01- SR103 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (May 1, 2002, 36 Month Duration) $249,766 Total Contract Value ($208,228 DOE UTSR) Assessment of Failure Mechanisms for Thermal Barrier Coatings by Photoluminescence, Electrochemical Impedance and Focused Ion Beam YHS@UCF,10/17/05 Gas Turbine Needs: Reliable and Durable Thermal Barrier Coatings (TBCs) TBCs Provide Thermal Protection of Hot Components in Advanced Gas Turbine Engines Increase in Performance, Efficiency, Reliability and Maintainability. Reduction Life Cycle Costs. Reliable and Durable TBCs Needed as An Integral Part of Component Design.

44

Advanced Thermal Barrier Coating System Development. Technical progress report  

Science Conference Proceedings (OSTI)

The objectives of the program are to provide an improved TBC system with increased temperature capability and improved reliability relative to current state of the art TBC systems. The development of such a coating system is essential to the ATS engine meeting its objectives. The base program consists of three phases: Phase I: Program Planning - Complete; Phase II: Development; and Phase III: Selected Specimen - Bench Test. Work is being performed in Phase II and III of the program.

None

1999-10-15T23:59:59.000Z

45

Advanced Thermal Barrier Coating System Development. Technical progress report  

Science Conference Proceedings (OSTI)

The objectives of the program are to provide an improved TBC system with increased temperature capability and improved reliability relative to current state of the art TBC systems. The development of such a coating system is essential to the ATS engine meeting its objectives. The base program consists of three phases: Phase I: Program Planning - Complete; Phase II: Development - Complete; and Phase III: Selected Specimen - Bench Test. Work was performed in Phase II and III of the program during the reporting period.

None

2000-01-13T23:59:59.000Z

46

Advanced Thermal Barrier Coating System Development. Technical progress report  

Science Conference Proceedings (OSTI)

The objectives of the program are to provide an improved TBC system with increased temperature capability and improved reliability relative to current state of the art TBC systems. The development of such a coating system is essential to the ATS engine meeting its objectives. The base program consists of three phases: Phase I: Program Planning - Complete; Phase II: Development; and Phase III: Selected Specimen - Bench Test. Work is being performed in Phase II and III of the program.

None

1998-09-21T23:59:59.000Z

47

Thick Thermal Barrier Coatings (TTBCs) for Low Emission, High Efficiency Diesel Engine Components  

SciTech Connect

The objective of this program was to advance the fundamental understanding of thick thermal barrier coating (TTBC) systems for application to low heat rejection diesel engine combustion chambers. Previous reviews of thermal barrier coating technology concluded that the current level of understanding of coating system behavior is inadequate and the lack of fundamental understanding may impede the application of thermal barrier coating to diesel engines.(1) Areas of TTBC technology examined in this program include powder characteristics and chemistry; bond coating composition, coating design, microstructure and thickness as they affect properties, durability, and reliability; and TTBC "aging" effects (microstructural and property changes) under diesel engine operating conditions. Fifteen TTBC ceramic powders were evaluated. These powders were selected to investigate the effects of different chemistries, different manufacturing methods, lot-to-lot variations, different suppliers and varying impurity levels. Each of the fifteen materials has been sprayed using 36 parameters selected by a design of experiments (DOE) to determine the effects of primary gas (Ar and N2), primary gas flow rate, voltage, arc current, powder feed rate, carrier gas flow rate, and spraying distance. The deposition efficiency, density, and thermal conductivity of the resulting coatings were measured. A coating with a high deposition efficiency and low thermal conductivity is desired from an economic standpoint. An optimum combination of thermal conductivity and disposition efficiency was found for each lot of powder in follow-on experiments and disposition parameters were chosen for full characterization.(2) Strengths of the optimized coatings were determined using 4-point bending specimens. The tensile strength was determined using free-standing coatings made by spraying onto mild steel substrates which were subsequently removed by chemical etching. The compressive strengths of the coatings were determined using composite specimens of ceramic coated onto stainless steel substrates, tested with the coating in compression and the steel in tension. The strength of the coating was determined from an elastic bi-material analysis of the resulting failure of the coating in compression.(3) Altough initial comparisons of the materials would appear to be straight forward from these results, the results of the aging tests of the materials are necessary to insure that trends in properties remain after long term exposure to a diesel environment. Some comparisons can be made, such as the comparison between for lot-to-lot variation. An axial fatigue test to determine the high cycle fatigue behavior of TTBCs was developed at the University of Illinois under funding from this program.(4) A fatigue test apparatus has been designed and initial work performed which demonstrates the ability to provide a routine method of axial testing of coating. The test fixture replaces the normal load frame and fixtures used to transmit the hydraulic oil loading to the sample with the TTBC specimen itself. The TTBC specimen is a composite metal/coating with stainless steel ends. The coating is sprayed onto a mild steel center tube section onto which the stainless steel ends are press fit. The specimen is then machined. After machining, the specimen is placed in an acid bath which etches the mild steel away leaving the TTBC attached to the the stainless steel ends. Plugs are then installed in the ends and the composite specimen loaded in the test fixture where the hydraulic oil pressurizes each end to apply the load. Since oil transmits the load, bending loads are minimized. This test fixture has been modified to allow piston ends to be attached to the specimen which allows tensile loading as well as compressive loading of the specimen. In addition to the room temperature data, specimens have been tested at 800 Degrees C with the surprising result that at high temperature, the TTBC exhibits much higher fatigue strength. Testing of the TTBC using tension/compression cycling has been con

M. Brad Beardsley, Caterpillar Inc.; Dr. Darrell Socie, University of Illinois; Dr. Ed Redja, University of Illinois; Dr. Christopher Berndt, State University of New York at Stony Brook

2006-03-02T23:59:59.000Z

48

Combustion Control and Diagnostics Sensor Testing in a Thermal Barrier Coated Combustor  

Science Conference Proceedings (OSTI)

The combustion control and diagnostics sensor (CCADS) continues to be developed as an in-situ combustion sensor, with immediate application to natural gas fired turbines. In-situ combustion monitoring is also expected to benefit advanced power plants of the future, fueled by coal-derived syngas, liquified natural gas (LNG), hydrogen, or hydrogen blend fuels. The in-situ monitoring that CCADS provides can enable the optimal operation of advanced, fuel-flexible turbines for minimal pollutant emissions and maximum efficiency over the full operating range of an advanced turbine. Previous work has demonstrated CCADS as a useful sensor for in-situ monitoring of natural gas combustion, including detection of important combustion events such as flashback and lean blowoff, in experimental combustors without thermal barrier coatings (TBC). Since typical TBC materials are electrical insulators at room temperature, and CCADS operation requires conduction of electrical current to the walls of the combustor, a TBC on the combustion liner was identified as a potential barrier to CCADS operation in commercial application. This paper reports on CCADS experiments in a turbulent lean premixed combustor with a yttria-stabilized zirconia (YSZ) thermal barrier coating on the combustor wall. The tests were conducted at 0.1 MPa (1 atm), with a 15V excitation voltage on the CCADS electrodes. The results confirm that for a typical thermal barrier coating, CCADS operates properly, and the total measured average resistance is close to that of an uncoated combustor. This result is consistent with previous materials studies that found the electrical resistance of typical TBC materials considerably decreases at combustor operating temperatures.

Chorpening, B.T.; Dukes, M.G.; Robey, E.H.; Thornton, J.D.

2007-05-01T23:59:59.000Z

49

Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers  

DOE Patents (OSTI)

The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

2001-01-01T23:59:59.000Z

50

Apparatus for determining past-service conditions and remaining life of thermal barrier coatings and components having such coatings  

DOE Patents (OSTI)

An apparatus for determining past-service conditions and/or remaining useful life of a component of a combustion engine and/or a thermal barrier coating ("TBC") of the component comprises a radiation source that provides the exciting radiation to the TBC to excite a photoluminescent ("PL") material contained therein, a radiation detector for detecting radiation emitted by the PL material, and means for relating a characteristic of an emission spectrum of the PL material to the amount of a crystalline phase in the TBC, thereby inferring the past-service conditions or the remaining useful life of the component or the TBC.

Srivastava, Alok Mani (Niskayuna, NY); Setlur, Anant Achyut (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Devitt, John William (Clifton Park, NY); Ruud, James Anthony (Delmar, NY); Brewer, Luke Nathaniel (Rexford, NY)

2004-05-04T23:59:59.000Z

51

Thermal barrier coatings issues in advanced land-based gas turbines  

Science Conference Proceedings (OSTI)

The Department of Energy`s Advanced Turbine Systems (ATS) program is aimed at fostering the development of a new generation of land-based gas turbine systems with overall efficiencies significantly beyond those of current state-of-the-art machines, as well as greatly increased times between inspection and refurbishment, improved environmental impact, and decreased cost. The proposed duty cycle of ATS machines will emphasize different criteria in the selection of materials for the critical components. In particular, thermal barrier coatings (TBCS) will be an essential feature of the hot gas path components in these machines. In fact, the goals of the ATS will require significant improvements in TBC technology, since these turbines will be totally reliant on TBCs, which will be required to function on critical components such as the first stage vanes and blades for times considerably in excess of those experienced in current applications. Issues that assume increased importance are the mechanical and chemical stability of the ceramic layer and of the metallic bond coat; the thermal expansion characteristics and compliance of the ceramic layer; and the thermal conductivity across the thickness of the ceramic layer. Obviously, the ATS program provides a very challenging opportunity for TBCs, and involves some significant opportunities to extend this technology. A significant TBC development effort is planned in the ATS program which will address these key issues.

Parks, W.P. [USDOE Office of Industrial Technologies, Washington, DC (United States); Lee, W.Y.; Wright, I.G. [Oak Ridge National Lab., TN (United States)

1995-06-01T23:59:59.000Z

52

Method for improving the oxidation-resistance of metal substrates coated with thermal barrier coatings  

DOE Patents (OSTI)

A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.

Thompson, Anthony Mark (Niskayuna, NY); Gray, Dennis Michael (Delanson, NY); Jackson, Melvin Robert (Niskayuna, NY)

2002-01-01T23:59:59.000Z

53

Method For Improving The Oxidation Resistance Of Metal Substrates Coated With Thermal Barrier Coatings  

DOE Patents (OSTI)

A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described. A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.

Thompson, Anthony Mark (Niskayuna, NY); Gray, Dennis Michael (Delanson, NY); Jackson, Melvin Robert (Niskayuna, NY)

2003-05-13T23:59:59.000Z

54

Advanced turbine systems - research and development of thermal barrier coatings technology: 2nd bimonthly report, February 1996  

Science Conference Proceedings (OSTI)

Objective of the ATS program is the development of ultra-highly efficient, environmentally superior, and cost-competitive gas turbine systems, with long, less cyclic operating profiles than aircraft gas turbine engines. Durability and performance demands of ATS can be achieved by means of thermal barrier coatings. Phase I (program plan) is complete. Phase II is in progress.

NONE

1996-02-01T23:59:59.000Z

55

NON-DESTRUCTIVE TECHNIQUES FOR THE EVALUATION OF OVERLAY AND THERMAL BARRIER COATINGS ON GAS TURBINE COMPONENTS  

DOE Green Energy (OSTI)

There is currently no satisfactory method for the non-destructive examination (NDE) of coatings on gas turbine parts and determination of coating thickness, for example, has to be carried out by sectioning of the component and subsequent metallographic analysis. This method, which is both time-consuming and expensive, has nevertheless been used extensively for aero-engine parts to monitor coating quality and to gather statistical information for process control. For large components from utility size gas turbines costs are high and compared with aero-engines, only a limited number of parts can be examined so that the destructive method becomes less attractive both as an inspection technique and for obtaining process control data to measure part to part variations in coating thickness, for example. During engine service protective coatings slowly degrade and this degradation process effectively controls the life of the part, particularly in situations where a thermal barrier coating (TBC) is used to protect against excessive metal temperatures. In this case growth of the oxide at the interface between the bond coat and the TBC leads to a build-up of stress in the TBC which can be relieved by a spalling of the ceramic layer and loss of the protection from the thermal barrier. In situations where the integrity of the TBC system is critical to the survival of the part, some non-destructive method of determining the degradation condition of the bond coat would clearly be advantageous. In this report the results are described of recent progress in a program to develop non-destructive methods to measure coating quality and to monitor the condition of coatings in service. The work which has formed part of the Advanced Turbine Systems (ATS) Project funded by DOE, has involved the use of eddy-current (ET) and ultrasonic (US) methods developed by SouthWest Research Institute (SwRI) who have been responsible for development of the technique.

Michael Cybulsky

1998-03-10T23:59:59.000Z

56

ON-LINE THERMAL BARRIER COATING MONITORING FOR REAL-TIME FAILURE PROTECTION AND LIFE MAXIMIZATION  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization,'' to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2002-04-01T23:59:59.000Z

57

ON-LINE THERMAL BARRIER COATING MONITORING FOR REAL-TIME FAILURE PROTECTION AND LIFE MAXIMIZATION  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization,'' to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability, availability, and maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can, therefore, accelerate the degradation of substrate component materials and eventually lead to a premature failure of critical components and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2003-07-01T23:59:59.000Z

58

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure Protection and Life Maximization  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization'', to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2005-04-01T23:59:59.000Z

59

ON-LINE THERMAL BARRIER COATING MONITORING FOR REAL-TIME FAILURE PROTECTION AND LIFE MAXIMIZATION  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization,'' to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability, availability, and maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can, therefore, accelerate the degradation of substrate component materials and eventually lead to a premature failure of critical components and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2003-10-01T23:59:59.000Z

60

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure Protection and Life Maximization  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Power Generation, Inc proposed a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization'', to develop, build and install the first generation of an on-line TBC monitoring system for use on land-based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Power Generation, Inc. has teamed with Indigo Systems, a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization in the field of infrared non-destructive examination (NDE), to complete the program.

Dennis H. LeMieux

2005-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure Protection and Life Maximization  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Laboratory, Siemens Westinghouse Power Corporation proposes a four year program titled, ''On-Line Thermal Barrier Coating (TBC) Monitor for Real-Time Failure Protection and Life Maximization'', to develop, build and install the first generation of an on-line TBC monitoring system for use on land -based advanced gas turbines (AGT). Federal deregulation in electric power generation has accelerated power plant owner's demand for improved reliability availability maintainability (RAM) of the land-based advanced gas turbines. As a result, firing temperatures have been increased substantially in the advanced turbine engines, and the TBCs have been developed for maximum protection and life of all critical engine components operating at these higher temperatures. Losing TBC protection can therefore accelerate the degradation of substrate components materials and eventually lead to a premature failure of critical component and costly unscheduled power outages. This program seeks to substantially improve the operating life of high cost gas turbine components using TBC; thereby, lowering the cost of maintenance leading to lower cost of electricity. Siemens Westinghouse Power Corporation has teamed with Indigo Systems; a supplier of state-of-the-art infrared camera systems, and Wayne State University, a leading research organization.

Dennis H. LeMieux

2004-10-01T23:59:59.000Z

62

Measurement of Three Critical Parameters as a Basis for a Simple Thermal Barrier Coating Life Prediction Methodology  

NLE Websites -- All DOE Office Websites (Extended Search)

Three Critical Parameters Three Critical Parameters As A Basis for A Simple Thermal Barrier Coating Life Prediction Methodology University of Connecticut Eric Jordan and Maurice Gell SCIES Project 02- 01- SR 097 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (05/01/02, 36 Month Duration) $ 478,495 Total Contract Value ($ 478,495 DOE) Gas Turbine Need * Industrial Gas Turbine Performance & Durability Depend Strongly On Use Of Thermal Barrier Coatings * Aggressive Application of TBCs Limited By Lack of NDI And Lifing Methods University of Connecticut Gas Turbine Need Non-Destructive Assessment of Remaining Life Strongly Impacts Operating Cost * Reduce occurrence of unplanned shut down * Reduce wasteful precautionary part replacement

63

Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content-Fueled Turbines - University of California, Irvine  

NLE Websites -- All DOE Office Websites (Extended Search)

Mechanisms Underpinning Degradation Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content-Fueled Turbines-University of California, Irvine Background Thermal barrier coatings (TBCs) and components in the hot section of gas turbines are degraded by coal-derived high hydrogen content (HHC) synthesis gas (syngas). In this project the University of California, Irvine (UCI) will provide an improved mechanistic understanding of the degradation of critical turbine system materials in HHC-fueled

64

COMPARISON OF THERMAL PROPERTIES OF THERMAL BARRIER COATING DEPOSITED ON IN738 USING STANDARD AIR PLASMA SPRAY WITH 100HE PLASMA SPRAY SYSTEM  

SciTech Connect

A typical blade material is made of Nickel super alloy and can bear temperatures up to 950°C. But the operating temperature of a gas turbine is above the melting point of super alloy nearly at 1500°C. This could lead to hot corrosions, high temperature oxidation, creep, thermal fatigue may takes place on the blade material. Though the turbine has an internal cooling system, the cooling is not adequate to reduce the temperature of the blade substrate. Therefore to protect the blade material as well as increase the efficiency of the turbine, thermal barrier coatings (TBCs) must be used. A TBC coating of 250 ?m thick can reduce the temperature by up to 200° C. Air Plasma Spray Process (APS) and High Enthalpy Plasma Spray Process (100HE) were the processes used for coating the blades with the TBCs. Because thermal conductivity increases with increase in temperature, it is desired that these processes yield very low thermal conductivities at high temperatures in order not to damage the blade. An experiment was carried out using Flash line 5000 apparatus to compare the thermal conductivity of both processes.The apparatus could also be used to determine the thermal diffusivity and specific heat of the TBCs. 75 to 2800 K was the temperature range used in the experimentation. It was found out that though 100HE has high deposition efficiency, the thermal conductivity increases with increase in temperatures whiles APS yielded low thermal conductivities.

Uppu, N.; Mensah, P.F.; Ofori, D.

2006-07-01T23:59:59.000Z

65

Non-destructive evaluation of degradation in EB-PVD thermal barrier coatings by infrared reflectance spectroscopy  

Science Conference Proceedings (OSTI)

At room temperature and atmospheric conditions infrared reflectance spectroscopy and X-ray diffraction were employed for the detection of the phase transformation and residual stress within thermal barrier coatings (TBC). The TBC's samples initially consisted of the porous ceramic topcoat deposited by electron beam plasma vapor deposition, a bond coat and a superalloy substrate. Reflectance spectroscopy scans were performed from 7497 cm{sup -1} to 68 cm{sup -1} to analysis the fingerprint region as well as the chemical bonding region. These regions should indicate if a detectable change within the TBC response is a result of thermal degradation of the microstructure and the changes in yttrium dispersion throughout the yttrium stabilized zirconium. The thermal degradation was induced by thermal cycling the samples to 1100 Degree-Sign C and then cooling them in an atmospheric environment. X-ray diffraction was also used to detect the phase composition within the TBC samples and see if either would clearly identify failure prior to actual spallation. The eventual measurability and quantify-ability of the phase changes within the TBC's may be used as an effective non-destructive evaluation (NDE) technique that would allow personnel in the field to know when servicing of the turbine blade was necessary.

Flattum, Richard Y.; Cooney, Adam T. [Air Force Research Laboratory, Materials and Manufacturing Directorate, NonDestructive Evaluation Branch, Wright-Patterson AFB, OH (United States)

2013-01-25T23:59:59.000Z

66

Effect of thermal barrier coatings on the performance of steam- and water-cooled gas turbine: steam turbine combined cycle systems  

SciTech Connect

An analytical study was made of the performance of air-, steam-, and water-cooled gas-turbine/steam-turbine combined-cycle systems with and without thermal-barrier coatings. For steam cooling, thermal-barrier coatings permit an increase in the turbine inlet temperature from 1205/sup 0/C to 1370/sup 0/C, resulting in an efficiency improvement of 1.9 percentage points. The maximum specific power improvement with thermal barriers is 32.4% when the turbine inlet temperature is increased from 1425/sup 0/C to 1675/sup 0/C and the airfoil temperature is kept the same. For water cooling, the maximum efficiency improvement is 2.2 percentage points at a turbine inlet temperature of 1683/sup 0/C and the maximum specific power improvement is 36.6% by increasing the turbine inlet temperature from 1425/sup 0/C to 1730/sup 0/C and keeping the airfoil temperatures the same. These improvements are greater than that obtained with combined cycles using air-cooling at a turbine inlet temperature of 1205/sup 0/C. The large temperature differences across the thermal barriers at these high temperatures, however, indicate that thermal stresses may present obstacles to the use of coatings at high turbine inlet temperatures.

Nainiger, J.J.

1978-12-01T23:59:59.000Z

67

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure...  

NLE Websites -- All DOE Office Websites (Extended Search)

...32 9.0 List of Figures and Tables Figure 1.3a - Thermal Snapshot of 2' Diameter Flywheel with Target Features "White Light Still Frame" in...

68

Thermal Spray Coatings  

Science Conference Proceedings (OSTI)

Table 35   Thermal spray coatings used for hardfacing applications...piston ring (internal combustion);

69

Nanocomposite Thermal Spray Coatings.  

Science Conference Proceedings (OSTI)

Long-Term Surface Restoration Effect Introduced by Advanced Lubricant Additive · Nanocomposite Thermal Spray Coatings. New Hardfacing Overlay Claddings ...

70

Thermal Barrier Coatings  

Science Conference Proceedings (OSTI)

Oct 18, 2011... by Gas-Turbine Engines: Nitin Padture1; 1The Ohio State University ... in gas- turbine engines used in aircraft propulsion and electricity ...

71

An Equal Opportunity and Affirmative Action InstitutionDegradation of Thermal Barrier Coatings with Syngas Combustion: Testing by Hyperbaric Advanced Development Environmental Simulator and Characterization by Advanced Electron Microscopy  

E-Print Network (OSTI)

Please accept my apology in delayed delivery. Enclosed is the final technical report entitled “Degradation of Thermal Barrier Coatings with Syngas Combustion: Testing by Hyperbaric Advanced Development Environmental Simulator and Characterization by Advanced Electron Microscopy, ” by Sohn. If you have any questions, please do not hesitate to contact me at 407-882-1181 or ysohn@mail.ucf.edu.

Dr. Richard Wenglarz; Yongho Sohn

2005-01-01T23:59:59.000Z

72

In-situ formation of multiphase air plasma sprayed barrier coatings for turbine components  

DOE Patents (OSTI)

A turbine component (10), such as a turbine blade, is provided which is made of a metal alloy (22) and a base, planar-grained thermal barrier layer (28) applied by air plasma spraying on the alloy surface, where a heat resistant ceramic oxide overlay material (32') covers the bottom thermal barrier coating (28), and the overlay material is the reaction product of the precursor ceramic oxide overlay material (32) and the base thermal barrier coating material (28).

Subramanian, Ramesh (Oviedo, FL)

2001-01-01T23:59:59.000Z

73

Barrier Coatings for Refractory Metals and Superalloys  

SciTech Connect

In the closed working fluid loop of the proposed Prometheus space nuclear power plant (SNPP), there is the potential for reaction of core and plant structural materials with gas phase impurities and gas phase transport of interstitial elements between superalloy and refractory metal alloy components during service. Primary concerns are surface oxidation, interstitial embrittlement of refractory metals and decarburization of superalloys. In parallel with kinetic investigations, this letter evaluates the ability of potential coatings to prevent or impede communication between reactor and plant components. Key coating requirements are identified and current technology coating materials are reviewed relative to these requirements. Candidate coatings are identified for future evaluation based on current knowledge of design parameters and anticipated environment. Coatings were identified for superalloys and refractory metals to provide diffusion barriers to interstitial transport and act as reactive barriers to potential oxidation. Due to their high stability at low oxygen potential, alumina formers are most promising for oxidation protection given the anticipated coolant gas chemistry. A sublayer of iridium is recommended to provide inherent diffusion resistance to interstitials. Based on specific base metal selection, a thin film substrate--coating interdiffusion barrier layer may be necessary to meet mission life.

SM Sabol; BT Randall; JD Edington; CJ Larkin; BJ Close

2006-02-23T23:59:59.000Z

74

In-situ formation of multiphase electron beam physical vapor deposited barrier coatings for turbine components  

DOE Patents (OSTI)

A turbine component (10), such as a turbine blade, is provided which is made of a metal alloy (22) and a base columnar thermal barrier coating (20) on the alloy surface, where a heat resistant ceramic oxide sheath material (32' or 34') covers the columns (28), and the sheath material is the reaction product of a precursor ceramic oxide sheath material and the base thermal barrier coating material.

Subramanian, Ramesh (Oviedo, FL)

2001-01-01T23:59:59.000Z

75

Thermal and Environmental Barrier Coatings  

Science Conference Proceedings (OSTI)

Surface Protection for Enhanced Materials Performance: Science, Technology, and ... In this talk, we highlight results from microstructural and spectroscopic ...

76

Thermal Barrier Coatings for Superalloys  

Science Conference Proceedings (OSTI)

near-term means to dramatica?yl-y increase gas turbine inZet temperatures beyond those .... in rapid response furnaces, natural gas torch rigs, and Mach 1 burner rigs (5). Figure 3, adapted from .... under which liquid deposits are stable are.

77

Residual stress analysis of multilayer environmental barrier coatings.  

DOE Green Energy (OSTI)

Silicon-based ceramics (SiC, Si{sub 3}N{sub 4}) are promising materials systems for high-temperature structural applications in gas turbine engines. However, the silica layer that forms on these materials is susceptible to attack from water vapor present in combustion environments. To protect against this degradation, environmental barrier coatings (EBCs) have been developed to shield the underlying substrate and prevent degradation. Here we report on elastic and thermal properties, as well as internal stresses of candidate multilayer coatings, as measured in situ using microfocused high-energy X-rays in a transmission diffraction geometry. Doped aluminosilicate coatings were investigated for their stability on a SiC/SiC melt-infiltrated substrate. The coatings consisted of a Ba{sub 1-x}Sr{sub x}Al{sub 2}Si{sub 2}O{sub 8} topcoat with a mullite or mullite+SrAl{sub 2}Si{sub 2}O{sub 8} interlayer, and a silicon bond coat. A numerical model was used to compare the stress results with an ideal coating system. Experiments were carried out on as-sprayed and heat-treated samples in order to analyze the strain and phase evolution as a function of multilayer depth and temperature. The phase transformation of the topcoat promoted healing of cracks in the EBC and reduced stresses in the underlying layers and the addition of SAS to the interlayer reduced stresses in thermally cycled coatings, but did not stop cracks from forming.

Harder, B.; Almer, J.; Weyant, C.; Lee, K.; Faber, K.; Northwestern Univ.; Rolls-Royce Corp.

2009-02-01T23:59:59.000Z

78

Thermal spray coatings on Yankee dryers  

SciTech Connect

Several failure investigations and recent research on thermal spray coatings on Yankee dryer surfaces show at least three modes of environmentally induced degradation. Corrosion may occur with the ingress of certain chemicals into coating pores. Erosion or corrosion is manifested by streaks at local sites of high doctor blade loading. Erosion and cracking occur due to coating parameters, thermal stress, and differential expansion. While most of the results described in this paper are from investigations of molybdenum, stainless steel coatings also are discussed.

Bowers, D.F. (Packer Engineering, Inc., Naperville, IL (United States))

1994-08-01T23:59:59.000Z

79

Nondestructive evaluation of environmental barrier coatings in CFCC combustor liners.  

SciTech Connect

Advanced combustor liners fabricated of SiC/SiC continuous fiber-reinforced ceramic composite (CFCC) and covered with environmental barrier coatings (EBCs) have been successfully tested in Solar Turbines Inc. field engines. The primary goal for the CFCC/EBC liners is to reach a 30,000-h lifetime. Because the EBCs, when applied on the hot surfaces of liners, protect the underlying CFCC from oxidation damage, their performance is critical in achieving the lifetime goal. To determine CFCC/EBC liner condition and assess operating damage, the liners were subjected to nondestructive evaluation (NDE) during various processing stages, as well as before and after the engine test. The NDE techniques included pulsed infrared thermal imaging, air-coupled ultrasonic scanning, and X-ray computerized tomography. It was found that EBC damage and spallation depend on the condition of the CFCC material. The NDE results and correlations with destructive examination are discussed.

Sun, J. G.; Benz, J.; Ellingson, W. A.; Kimmel, J. B.; Price, J. R.; Energy Technology; Solar Turbines, Inc

2007-01-01T23:59:59.000Z

80

Thermal Spraying Coatings Assisted by Laser Treatment  

Science Conference Proceedings (OSTI)

Coatings produced by air plasma spraying (APS) are widely used to protect components against abrasive wear and corrosion. However, APS coatings contain porosities and the properties of these coatings may thereby be reduced. To improve these properties, various methods could be proposed, including post-laser irradiation [1-4]. Firstly, PROTAL process (thermal spraying assisted by laser) has been developed as a palliative technique to degreasing and grit-blasting prior to thermal spraying. Secondly, thermal spray coatings are densified and remelted using Laser treatment. In this study, a review of microstructure coatings prepared by laser-assisted air plasma spraying will be presented. Mechanical and magnetic properties will be evaluated in relation to changes in the coating microstructure and the properties of such coatings will be compared with those of as-sprayed APS coatings.

Fenineche, N. E.; Cherigui, M. [LERMPS-UTBM (Site de Sevenans), 90010 Belfort Cedex (France)

2008-09-23T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Thermal Spray Coatings for Coastal Infrastructure  

Science Conference Proceedings (OSTI)

Several protection strategies for coastal infrastructure using thermal-spray technology are presented from research at the Albany Research Center. Thermal-sprayed zinc coatings for anodes in impressed current cathodic protection systems are used to extend the service lives of reinforced concrete bridges along the Oregon coast. Thermal-sprayed Ti is examined as an alternative to the consumable zinc anode. Sealed thermal-sprayed Al is examined as an alternative coating to zinc dust filled polyurethane paint for steel structures.

Holcomb, G.R.; Covino, BernardS. Jr.; Cramer, S.D.; Bullard, S.J.

1997-11-01T23:59:59.000Z

82

Study on machined thermal sprayed coatings adherence  

Science Conference Proceedings (OSTI)

Thermal sprayed coatings represent a modern way of solving real important problems, like repairing worn parts working under severe wearing conditions or, ensuring efficient corrosion protection of parts used in sea, as platform, bridges, or obtaining ... Keywords: adherence, cylindrical turning, metallizing process, sample, thermal sprayed coatings, transducer

Mihaiela Iliescu; Mihnea Costoiu; Sergiu Tonoiu

2008-11-01T23:59:59.000Z

83

Nuclear reactor vessel fuel thermal insulating barrier  

DOE Patents (OSTI)

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel that has a hemispherical lower section that increases in volume from the center line of the reactor to the outer extent of the diameter of the thermal insulating barrier and smoothly transitions up the side walls of the vessel. The space between the thermal insulating harrier and the reactor vessel forms a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive inlet valve for the cooling water includes a buoyant door that is normally maintained sealed under its own weight and floats open when the cavity is Hooded. Passively opening steam vents are also provided.

Keegan, C. Patrick; Scobel, James H.; Wright, Richard F.

2013-03-19T23:59:59.000Z

84

Thermal sensor with an improved coating  

DOE Patents (OSTI)

The disclosure is directed to an apparatus for detecting radiation having wavelengths from about 0.4 .mu.m to about 5.6 .mu.m. An optical coating is applied to a thermal sensor that is normally transparent to radiation with such wavelengths. The optical coating is thin and light and includes a modifier and an absorber. The thermal sensor can be a pyroelectric detector such as strontium barium niobate.

LaDelfe, Peter C. (Los Alamos, NM); Stotlar, Suzanne C. (Los Alamos, NM)

1986-01-01T23:59:59.000Z

85

Thermal and Cold Sprayed Coatings  

Science Conference Proceedings (OSTI)

Mar 5, 2013... Coating Evaluated by Micro and Nano Indentation: Meysam Keshavarz1; Mohd Hasbullah bin Hj.Idris1; 1UTM,Universiti Teknologi Malaysia

86

Coating thermal noise for arbitrary shaped beams  

E-Print Network (OSTI)

Advanced LIGO's sensitivity will be limited by coating noise. Though this noise depends on beam shape, and though nongaussian beams are being seriously considered for advanced LIGO, no published analysis exists to compare the quantitative thermal noise improvement alternate beams offer. In this paper, we derive and discuss a simple integral which completely characterizes the dependence of coating thermal noise on shape. The derivation used applies equally well, with minor modifications, to all other forms of thermal noise in the low-frequency limit.

Richard O'Shaughnessy

2006-07-10T23:59:59.000Z

87

New Barrier Coating Materials for PV Module Backsheets: Preprint  

DOE Green Energy (OSTI)

This conference paper describes the high moisture barrier high resistivity coatings on polyethylene terepthalate (PET) have been fabricated and characterized for use in PV module back sheet applications. These thin film barriers exhibit water vapor transmission rates (WVTR) as low as 0.1 g/m2-day at 37.8 C and have shown excellent adhesion (> 10 N/mm) to both ethylene vinyl acetate (EVA) and PET even after filtered xenon arc lamp UV exposure. The WVTR and adhesion values for this construction are compared to and shown to be superior to candidate polymeric backsheet materials.

Barber, G. D.; Jorgensen, G. J.; Terwilliger, K.; Glick, S. H.; Pern, J.; McMahon, T. J.

2002-05-01T23:59:59.000Z

88

Thermal-Mechanical Fatigue Life Model for Coated Superalloy ...  

Science Conference Proceedings (OSTI)

in an aggressive combustion gas environment. Coating ..... M.I. Wood and G.F. Harrison, "Modeling The Deformation Of Coated. Superalloys Under Thermal ...

89

Thermal Barrier Coatings, Oxidation and Corrosion - Programmaster ...  

Science Conference Proceedings (OSTI)

Aug 5, 2013 ... In this study, 21%Cr SS and TYPE304 were exposed for 5 years at seashore area in Okinawa, and corrosion resistance of these steels was ...

90

Thermal Sprays and Ceramic Coatings Assessments: Laboratory and Field Evaluations of Ceramic and Thermal Sprays Coatings  

Science Conference Proceedings (OSTI)

This report includes assessments of Ceramic and Thermal Spray coatings both by laboratory evaluation and analysis of field samples. The field samples are presented as case studies describing the condition of the material solution applied. Several thermal sprays and ceramic coatings were tested and analyzed for their ability to mitigate fireside corrosion, reduce slagging and it's propensity to have circumferential cracking occur due to cyclic temperature variations. In addition, the case studies provide ...

2010-12-31T23:59:59.000Z

91

Method of producing thermally sprayed metallic coating  

DOE Patents (OSTI)

The cylinder walls of light metal engine blocks are thermally spray coated with a ferrous-based coating using an HVOF device. A ferrous-based wire is fed to the HVOF device to locate a tip end of the wire in a high temperature zone of the device. Jet flows of oxygen and gaseous fuel are fed to the high temperature zone and are combusted to generate heat to melt the tip end. The oxygen is oversupplied in relation to the gaseous fuel. The excess oxygen reacts with and burns a fraction of the ferrous-based feed wire in an exothermic reaction to generate substantial supplemental heat to the HVOF device. The molten/combusted metal is sprayed by the device onto the walls of the cylinder by the jet flow of gases.

Byrnes, Larry Edward (Rochester Hills, MI); Kramer, Martin Stephen (Clarkston, MI); Neiser, Richard A. (Albuquerque, NM)

2003-08-26T23:59:59.000Z

92

Characterization of thermally sprayed coatings for high-temperature wear-protection applications  

SciTech Connect

Under normal high-temperature gas-cooled reactor (HTGR) operating conditions, faying surfaces of metallic components under high contact pressure are prone to friction, wear, and self-welding damage. Component design calls for coatings for the protection of the mating surfaces. Anticipated operating temperatures up to 850 to 950/sup 0/C (1562 to 1742/sup 0/F) and a 40-y design life require coatings with excellent thermal stability and adequate wear and spallation resistance, and they must be compatible with the HTGR coolant helium environment. Plasma and detonation-gun (D-gun) deposited chromium carbide-base and stabilized zirconia coatings are under consideration for wear protection of reactor components such as the thermal barrier, heat exchangers, control rods, and turbomachinery. Programs are under way to address the structural integrity, helium compatibility, and tribological behavior of relevant sprayed coatings. In this paper, the need for protection of critical metallic components and the criteria for selection of coatings are discussed. The technical background to coating development and the experience with the steam cycle HTGR (HTGR-SC) are commented upon. Coating characterization techniques employed at General Atomic Company (GA) are presented, and the progress of the experimental programs is briefly reviewed. In characterizing the coatings for HTGR applications, it is concluded that a systems approach to establish correlation between coating process parameters and coating microstructural and tribological properties for design consideration is required.

Li, C.C.

1980-03-01T23:59:59.000Z

93

Barrier Coatings for Thin Film Solar Cells: Final Subcontract Report, September 1, 2002 -- January 30, 2008  

DOE Green Energy (OSTI)

This program has involved investigations of the stability of CdTe and copper-indium-gallium-diselenide (CIGS) solar cells under damp heat conditions and effects of barrier coatings.

Olsen, L. C.

2010-03-01T23:59:59.000Z

94

Studies of switching field and thermal energy barrier distributions in a FePt nanoparticle system  

E-Print Network (OSTI)

Studies of switching field and thermal energy barrier distributions in a FePt nanoparticle system X dependence of the thermal stability factor, the width of the thermal energy barrier distribution- ropy energy distribution and the interaction and the thermal energy barrier distribution determined

Laughlin, David E.

95

Oxide Multilayer Thermal Radiation Energy Reflection EBCs: Effect ...  

Science Conference Proceedings (OSTI)

Environmental barrier coatings (EBCs) with thermal radiation energy reflection have been developed recently. The EBCs utilize interaction between ...

96

Engineered Barrier Systems Thermal-Hydraulic-Chemical Column Test Report  

SciTech Connect

The Engineered Barrier System (EBS) Thermal-Hydraulic-Chemical (THC) Column Tests provide data needed for model validation. The EBS Degradation, Flow, and Transport Process Modeling Report (PMR) will be based on supporting models for in-drift THC coupled processes, and the in-drift physical and chemical environment. These models describe the complex chemical interaction of EBS materials, including granular materials, with the thermal and hydrologic conditions that will be present in the repository emplacement drifts. Of particular interest are the coupled processes that result in mineral and salt dissolution/precipitation in the EBS environment. Test data are needed for thermal, hydrologic, and geochemical model validation and to support selection of introduced materials (CRWMS M&O 1999c). These column tests evaluated granular crushed tuff as potential invert ballast or backfill material, under accelerated thermal and hydrologic environments. The objectives of the THC column testing are to: (1) Characterize THC coupled processes that could affect performance of EBS components, particularly the magnitude of permeability reduction (increases or decreases), the nature of minerals produced, and chemical fractionation (i.e., concentrative separation of salts and minerals due to boiling-point elevation). (2) Generate data for validating THC predictive models that will support the EBS Degradation, Flow, and Transport PMR, Rev. 01.

W.E. Lowry

2001-12-13T23:59:59.000Z

97

Diffusion Barrier Properties of Nitride-Based Coatings on Fuel Cladding  

SciTech Connect

In this work titanium nitride (TiN) and zirconium nitride (ZrN) coatings are proposed as diffusion barriers between stainless steel nuclear fuel cladding and lanthanide fission products. TiN and ZrN have been coated as barrier materials between pure Fe and Ce, i.e. diffusion couples of Fe/TiN/Ce and Fe/ZrN/Ce, annealed up to a temperature of 600 degrees C, and compared to the diffusion behavior of uncoated Fe/Ce. Backscattered electron images and electron dispersive X-ray spectroscopy measurements confirm that, with a 500 nm TiN or ZrN layer, no obvious diffusion is observed between Fe and Ce. Basic diffusion characteristics of the Fe/Ce couple have also been measured and compared with the TiN and ZrN coated ones. The results strongly advocate that TiN and ZrN coatings provide reliable diffusion barrier characteristics against Ce and possibly other lanthanide fission products.

Fauzia Khatkhatay; Jie Jian; Liang Jiao; Qing Su; Jian Gan; James I. Cole; Haiyan Wang

2013-12-01T23:59:59.000Z

98

Measurement of thermal noise in multilayer coatings with optimized layer thickness  

Science Conference Proceedings (OSTI)

A standard quarter-wavelength multilayer optical coating will produce the highest reflectivity for a given number of coating layers, but in general it will not yield the lowest thermal noise for a prescribed reflectivity. Coatings with the layer thicknesses optimized to minimize thermal noise could be useful in future generation interferometric gravitational wave detectors where coating thermal noise is expected to limit the sensitivity of the instrument. We present the results of direct measurements of the thermal noise of a standard quarter-wavelength coating and a low noise optimized coating. The measurements indicate a reduction in thermal noise in line with modeling predictions.

Villar, Akira E.; Black, Eric D.; DeSalvo, Riccardo; Libbrecht, Kenneth G.; Michel, Christophe; Morgado, Nazario; Pinard, Laurent; Pinto, Innocenzo M.; Pierro, Vincenzo; Galdi, Vincenzo; Principe, Maria; Taurasi, Ilaria [LIGO Laboratory, California Institute of Technology, Mail Code 264-33, Pasadena, California 91125 (United States); Laboratoire des Materiaux Avances, Universite Claude Bernard Lyon 1, CNRS/IN2P3, Villeurbaune (France); Waves Group, University of Sannio at Benevento, Benevento, Italy, INFN and LSC (Italy)

2010-06-15T23:59:59.000Z

99

Coating thermal noise of a finite-size cylindrical mirror  

E-Print Network (OSTI)

Thermal noise of a mirror is one of the limiting noise sources in the high precision measurement such as gravitational-wave detection, and the modeling of thermal noise has been developed and refined over a decade. In this paper, we present a derivation of coating thermal noise of a finite-size cylindrical mirror based on the fluctuation-dissipation theorem. The result agrees to a previous result with an infinite-size mirror in the limit of large thickness, and also agrees to an independent result based on the mode expansion with a thin-mirror approximation. Our study will play an important role not only to accurately estimate the thermal-noise level of gravitational-wave detectors but also to help analyzing thermal noise in quantum-measurement experiments with lighter mirrors.

Kentaro Somiya; Kazuhiro Yamamoto

2009-03-17T23:59:59.000Z

100

Characterization of Thermal Barrier Coatings Resistant to Corrosion ...  

Science Conference Proceedings (OSTI)

Mechanisms of TBC failure after sealing have not been adequately explored. ... Bi-layer TBCs, comprising an air plasma sprayed yttria-stabilized zirconia inner ...

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Advanced thermal barrier coating system development: Technical progress report  

Science Conference Proceedings (OSTI)

Objectives are to provide an improved TBC system with increased temperature capability and improved reliability, for the Advanced Turbine Systems program (gas turbine). The base program consists of three phases: Phase I, program planning (complete); Phase II, development; and Phase III (selected specimen-bench test). Work is currently being performed in Phase II.

NONE

1996-08-07T23:59:59.000Z

102

Analysis of Annual Thermal and Moisture Performance of Radiant Barrier Systems  

Science Conference Proceedings (OSTI)

A detailed thermal energy analysis model helps identify locations where radiant barriers are cost-effective while analyzing moisture performance to predict potential problem areas. The model described in this report estimates annual energy savings and moisture accumulation rates from horizontal radiant barrier applications in a variety of climates.

1991-09-03T23:59:59.000Z

103

Analysis of annual thermal and moisture performance of radiant barrier systems  

Science Conference Proceedings (OSTI)

This report summarizes a project to model the annual thermal and moisture performance of radiant barrier systems installed in residential attics. A previously developed model for the thermal performance of attics with radiant barriers was modified to allow estimates of moisture condensation on the underside of radiant barriers that are laid directly on top of existing attic insulation. The model was partially validated by comparing its predictions of ceiling heat flows and moisture condensation with data and visual observations made during a field experiment with full-size houses near Knoxville, Tennessee. Since the model predictions were found to be in reasonable agreement with the experimental data, the models were used to estimate annual energy savings and moisture accumulation rates for a wide variety of climatic conditions. The models results have been used to identify locations where radiant barriers are cost effective and also where radiant barriers have potential for causing moisture problems. 58 refs., 20 figs., 32 tabs.

Wilkes, K.E.

1991-04-01T23:59:59.000Z

104

Thermal performance of clean horizontal radiant barriers under winter conditions: Laboratory measurements and mathematical modeling  

Science Conference Proceedings (OSTI)

Several field experiments have been performed on attic radiant barriers under winter conditions; however, most of them have been confined to the fairly mild climates of Florida, Oklahoma, and Tennessee. Only one field experiment in a very cold climate (Canada) has been performed. In addition, no previous laboratory experiments under winter conditions have been performed on an attic both with and without a radiant barrier. This paper presents the results of laboratory measurements of the thermal performance of clean horizontal radiant barriers in a simulated residential attic module under nighttime or low solar gain daytime winter conditions. Comparing tests under the same conditions with and without a radiant barrier shows that the addition of a clean horizontal radiant barrier to insulation at the R-22 to R-25 level decreases the ceiling heat flow by 6 to 8%. The experimental results were found to be in very good agreement with predictions made with a mathematical model for the thermal performance of attics.

Wilkes, K.E.; Childs, P.W.

1992-01-01T23:59:59.000Z

105

Analysis of annual thermal and moisture performance of radiant barrier systems  

Science Conference Proceedings (OSTI)

This report summarizes a project to model the annual thermal and moisture performance of radiant barrier systems installed in residential attics. A previously developed model for the thermal performance of attics with radiant barriers was modified to allow estimates of moisture condensation on the underside of radiant barriers that are laid directly on top of existing attic insulation. The model was partially validated by comparing its predictions of ceiling heat flows and moisture condensation with data and visual observations made during a field experiment with full-size houses near Knoxville, Tennessee. Since the model predictions were found to be in reasonable agreement with the experimental data, the models were used to estimate annual energy savings and moisture accumulation rates for a wide variety of climatic conditions. The model results have been used to identify locations where radiant barriers are cost effective and also where radiant barriers have potential for causing moisture problems. 58 refs., 20 figs., 32 tabs.

Wilkes, K.E. (Oak Ridge National Lab., TN (United States))

1991-08-01T23:59:59.000Z

106

Thermal performance of clean horizontal radiant barriers under winter conditions: Laboratory measurements and mathematical modeling  

Science Conference Proceedings (OSTI)

Several field experiments have been performed on attic radiant barriers under winter conditions; however, most of them have been confined to the fairly mild climates of Florida, Oklahoma, and Tennessee. Only one field experiment in a very cold climate (Canada) has been performed. In addition, no previous laboratory experiments under winter conditions have been performed on an attic both with and without a radiant barrier. This paper presents the results of laboratory measurements of the thermal performance of clean horizontal radiant barriers in a simulated residential attic module under nighttime or low solar gain daytime winter conditions. Comparing tests under the same conditions with and without a radiant barrier shows that the addition of a clean horizontal radiant barrier to insulation at the R-22 to R-25 level decreases the ceiling heat flow by 6 to 8%. The experimental results were found to be in very good agreement with predictions made with a mathematical model for the thermal performance of attics.

Wilkes, K.E.; Childs, P.W.

1992-08-01T23:59:59.000Z

107

Thermal Performance Evaluation of Attic Radiant Barrier Systems Using the Large Scale Climate Simulator (LSCS)  

SciTech Connect

Application of radiant barriers and low-emittance surface coatings in residential building attics can significantly reduce conditioning loads from heat flow through attic floors. The roofing industry has been developing and using various radiant barrier systems and low-emittance surface coatings to increase energy efficiency in buildings; however, minimal data are available that quantifies the effectiveness of these technologies. This study evaluates performance of various attic radiant barrier systems under simulated summer daytime conditions and nighttime or low solar gain daytime winter conditions using the large scale climate simulator (LSCS). The four attic configurations that were evaluated are 1) no radiant barrier (control), 2) perforated low-e foil laminated oriented strand board (OSB) deck, 3) low-e foil stapled on rafters, and 4) liquid applied low-emittance coating on roof deck and rafters. All test attics used nominal RUS 13 h-ft2- F/Btu (RSI 2.29 m2-K/W) fiberglass batt insulation on attic floor. Results indicate that the three systems with radiant barriers had heat flows through the attic floor during summer daytime condition that were 33%, 50%, and 19% lower than the control, respectively.

Shrestha, Som S [ORNL] [ORNL; Miller, William A [ORNL] [ORNL; Desjarlais, Andre Omer [ORNL] [ORNL

2013-01-01T23:59:59.000Z

108

METAL-MATRIX COMPOSITES AND THERMAL SPRAY COATINGS FOR EARTH MOVING MACHINES  

SciTech Connect

In the 11th quarter, further testing was performed on thermal spray coatings. A component coated and fused in the 9th quarter underwent high-stress abrasive wear testing. The test successfully showed this coating could survive in a high stress, sliding wear environment as the base layer in an FGM design coating. Work on the ferrous metal-matrix composites was completed in previous quarter and therefore no update is provided.

D. Trent Weaver; Matthew T. Kiser

2003-10-01T23:59:59.000Z

109

Improved 3-omega measurement of thermal conductivity in liquid, gases, and powders using a metal-coated optical fiber  

Science Conference Proceedings (OSTI)

A novel 3?thermal conductivitymeasurement technique called metal-coated 3? is introduced for use with liquids

Scott N. Schiffres; Jonathan A. Malen

2011-01-01T23:59:59.000Z

110

Computational Design and Experimental Validation of New Thermal...  

NLE Websites -- All DOE Office Websites (Extended Search)

State University Background Thermal barrier coating (TBC) systems safeguard modern gas turbine engines against significant temperature extremes and degradation. In order to...

111

Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel  

DOE Patents (OSTI)

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor.

Schreiber, Roger B. (Penn Twp., PA); Fero, Arnold H. (New Kensington, PA); Sejvar, James (Murrysville, PA)

1997-01-01T23:59:59.000Z

112

Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel  

DOE Patents (OSTI)

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor. 8 figs.

Schreiber, R.B.; Fero, A.H.; Sejvar, J.

1997-12-16T23:59:59.000Z

113

Methods for coating conduit interior surfaces utilizing a thermal spray gun with extension arm  

SciTech Connect

Systems and methods for applying a coating to an interior surface of a conduit. In one embodiment, a spray gun configured to apply a coating is attached to an extension arm which may be inserted into the bore of a pipe. The spray gun may be a thermal spray gun adapted to apply a powder coating. An evacuation system may be used to provide a volume area of reduced air pressure for drawing overspray out of the pipe interior during coating. The extension arm as well as the spray gun may be cooled to maintain a consistent temperature in the system, allowing for more consistent coating.

Moore, Karen A. (Idaho Falls, ID); Zatorski, Raymond A. (East Hampton, CT)

2007-10-02T23:59:59.000Z

114

Chemical and mechanical consequences of environmental barrier coating exposure to calcium-magnesium-aluminosilicate.  

Science Conference Proceedings (OSTI)

The success of Si-based ceramics as high-temperature structural materials for gas turbine applications relies on the use of environmental barrier coatings (EBCs) with low silica activity, such as Ba{sub 1-x}Sr{sub x}Al{sub 2}Si{sub 2}O{sub 8} (BSAS), which protect the underlying components from oxidation and corrosion in combustion environments containing water vapor. One of the current challenges concerning EBC lifetime is the effect of sandy deposits of calcium-magnesium-aluminosilicate (CMAS) glass that melt during engine operation and react with the EBC, changing both its composition and stress state. In this work, we study the effect of CMAS exposure at 1300 C on the residual stress state and composition in BSAS-mullite-Si-SiC multilayers. Residual stresses were measured in BSAS multilayers exposed to CMAS for different times using high-energy X-ray diffraction. Their microstructure was studied using a combination of scanning electron microscopy and transmission electron microscopy techniques. Our results show that CMAS dissolves the BSAS topcoat preferentially through the grain boundaries, dislodging the grains and changing the residual stress state in the topcoat to a nonuniform and increasingly compressive stress state with increasing exposure time. The presence of CMAS accelerates the hexacelsian-to-celsian phase transformation kinetics in BSAS, which reacts with the glass by a solution-reprecipitation mechanism. Precipitates have crystallographic structures consistent with Ca-doped celsian and Ba-doped anorthite.

Harder, B.; Ramirez-Rico, J.; Almer, J. D.; Kang, L.; Faber, K. (X-Ray Science Division); (NASA Glenn Research Center); (Univ. of Seville); (Rolls-Royce Corp.); (Northwestern Univ.)

2011-06-01T23:59:59.000Z

115

Thermal Sprayed Coatings for Heat Exchangers in Heat Storage ...  

Science Conference Proceedings (OSTI)

Inorganic salt hydrate PCMs have a number of advantages in comparison to ... Al -Si-Fe coatings on 6061 Aluminium Alloy using Cold Metal Transfer Technique.

116

Recent experimental progress in the TMX-U thermal barrier tandem mirror experiment  

Science Conference Proceedings (OSTI)

Recent experiments on the TMX-U thermal barrier device at LLNL have achieved the end plugging of axial ion losses up to a central cell density of n/sub c/ = 2 x 10/sup 12/ cm. During these tests, the axial potential profile characteristic of a thermal barrier has been measured experimentally, indicating an ion-confining potential greater than 1.5 kV and a potential depression of 0.45 kV in the barrier region. The average beta of hot electrons in the thermal barrier has been increased to 15% and appears limited only by classical scattering and ECRH pulse duration. Furthermore, deuterium ions in the central cell have been heated with ICRF to an average energy of 1.5 keV, with a heating efficiency of 40%. During strong end plugging, the axial ion confinement time reached 50 to 100 ms while the nonambipolar radial ion confinement time was 5 to 15 ms - independent of end plugging. Radial ion confinement time exceeding 100 ms has been attained on shots without end plugging. Plates, floated electrically on the end walls, have increased the radial ion confinement time by a factor of 1.8. Further improvement in the central cell density during end plugging can be expected by increasing the ICRF, improving the central cell vacuum conditions and beam heating efficiency, and increasing the radial extent of the potential control plates on the end walls.

Turner, W.C.; Allen, S.L.; Casper, T.A.; Clauser, J.F.; Coensgen, F.H.; Correll, D.L.; Cummins, W.F.; Damm, C.C.; Foote, J.H.; Goodman, R.K.

1984-06-22T23:59:59.000Z

117

Non-Destructive Evaluation of Thermal Spray Coating Interface Quality By Eddy Current Method  

SciTech Connect

Thermal spray coating is usually applied through directing molten or softened particles at very high velocities onto a substrate. An eddy current non-destructive inspection technique is presented here for thermal spray coating interface quality characterization. Several high-velocity-oxy-fuel (HVOF) coated steel plates were produced with various surface preparation conditions or spray process parameters. A quad-frequency eddy current probe was used to manually scan over the coating surface to evaluate the bonding quality. Experimental results show that different surface preparation conditions and varied process parameters can be successfully differentiated by the impedance value observed from the eddy current probe. The measurement is fairly robust and consistent. This non-contact, nondestructive, easy-to-use technique has the potential for evaluating the coating quality immediately after its application so that any defects can be corrected immediately.

B. Mi; G. Zhao; R. Bayles

2006-08-10T23:59:59.000Z

118

Thermal oxidation of tungsten-based sputtered coatings  

SciTech Connect

The effect of the addition of nickel, titanium, and nitrogen on the air oxidation behavior of W-based sputtered coatings in the temperature range 600 to 800 C was studied. In some cases these additions significantly improved the oxidation resistance of the tungsten coatings. As reported for bulk tungsten, all the coatings studied were oxidized by layers following a parabolic law. Besides WO{sub 3} and WO{sub x} phases detected in all the oxidized coatings, TiO{sub 2} and NiWO{sub 4} were also detected for W-Ti and W-Ni films, respectively. WO{sub x} was present as an inner protective compact layer covered by the porous WO{sub 3} oxide. The best oxidation resistance was found for W-Ti and W-N-Ni coatings which also presented the highest activation energies (E{sub a} = 234 and 218 kJ/mol, respectively, as opposed to E{sub a} {approx} 188 kJ/mol for the other coatings). These lower oxidation weight gains were attributed to the greater difficulty of the inward diffusion of oxygen ions for W-Ti films, owing to the formation of fine particles of TiO{sub 2}, and the formation of the external, more protective layer of NiWO{sub 4} for W-N-Ni coatings.

Louro, C.; Cavaleiro, A. [Dept. de Engenharia Mecanica-Polo II, Coimbra (Portugal)

1997-01-01T23:59:59.000Z

119

FeAl and Mo-Si-B Intermetallic Coatings Prepared by Thermal Spraying  

SciTech Connect

FeAl and Mo-Si-B intermetallic coatings for elevated temperature environmental resistance were prepared using high-velocity oxy-fuel (HVOF) and air plasma spray (APS) techniques. For both coating types, the effect of coating parameters (spray particle velocity and temperature) on the microstructure and physical properties of the coatings was assessed. Fe-24Al (wt.%) coatings were prepared using HVOF thermal spraying at spray particle velocities varying from 540 m/s to 700 m/s. Mo-13.4Si-2.6B coatings were prepared using APS at particle velocities of 180 and 350 m/s. Residual stresses in the HVOF FeAl coatings were compressive, while stresses in the APS Mo-Si-B coatings were tensile. In both cases, residual stresses became more compressive with increasing spray particle velocity due to increased peening imparted by the spray particles. The hardness and elastic moduli of FeAl coatings also increased with increasing particle velocity, again due to an increased peening effect. For Mo-Si-B coatings, plasma spraying at 180 m/s resulted in significant oxidation of the spray particles and conversion of the T1 phase into amorphous silica and {alpha}-Mo. The T1 phase was retained after spraying at 350 m/s.

Totemeier, T.C.; Wright, R.N.; Swank, W.D.

2003-04-22T23:59:59.000Z

120

Simulation of surface roughness during the formation of thermal spray coatings  

SciTech Connect

The formation of a thermal spray coating was analyzed to identify methods to reduce the surface roughness of the coating. A new methodology was developed which uses a string of equally spaced node points to define the shape of the coating surface and to track the shape change as the thermal spray mass is deposited. This allows the calculation of arbitrary shapes for the coating surface which may be very complex. The model simulates the stochastic deposition of a large number of thermal spray droplets, where experimental data is used for the mass flux distribution on the target surface. This data shows that when the thermal spray mass impinges on the target surface, a large fraction of it (over-spray) splashes off the target and is re-deposited with a small spray angle, resulting in a large coating roughness. This analysis was used in a parameter study to identify methods for reducing the coating roughness. Effect of the shape of the profile for the pre-roughened substrate was found to be small. Decreasing the droplet size by a factor of 2 decreased the roughness by 13%. Increasing the spray angle for the over-spray by a factor of 2 decreased the roughness by 50%, and decreasing the amount of over- spray by a factor of 2 decreased the roughness by 51%.

Kanouff, M.P.

1996-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Peculiarities of parabolic-barrier penetrability and thermal decay rate with the quantum diffusion approach  

SciTech Connect

With the quantum diffusion approach, the passing probability through the parabolic barrier is examined in the limit of linear coupling in the momentum between the collective subsystem and environment. The dependencies of the penetrability on time, energy, and the coupling strength between the interacting subsystems are studied. The quasistationary thermal decay rate from a metastable state is considered in the cases of linear couplings both in the momentum and in the coordinate.

Kuzyakin, R. A. [Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Omsk State Transport University, 644046 Omsk (Russian Federation); Sargsyan, V. V.; Adamian, G. G.; Antonenko, N. V. [Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation)

2011-06-15T23:59:59.000Z

122

Thermal spray coatings: New materials, processes and applications; Proceedings of the Second National Conference on Thermal Spray, Long Beach, CA, October 31-November 2, 1984  

SciTech Connect

Thermal-spray-coating techniques and their applications are discussed in reviews and reports of laboratory experiments and industrial experience. Topics explored include the future of thermal spraying, plasma-sprayed bonding coats for plastic substrates, plasma-spray deposition of hollow-particle ceramic powders, volumetric-feed-back powder-feed controllers, metal sprayed coating systems onboard U.S. Navy ships, high-performance plasma-sprayed coatings, and arc-coating technology and equipment. Consideration is given to cavitation-erosion of plasma-sprayed alloys, statistical methods of plasma-spray parameter testing, NDE of surface coatings by photothermal imaging, NDE of thermal-spray-coating bonds, and diamond-wheel grinding of thermal-spray materials.

Longo, F.N.

1985-01-01T23:59:59.000Z

123

Effect of incorporating cellulose nanocrystals from corncob on the tensile, thermal and barrier properties of poly(vinyl alcohol) nanocomposites  

Science Conference Proceedings (OSTI)

The effect of incorporating cellulose nanocrystals fromcorncob (CNC) on the tensile, thermal, and barrier properties of poly(vinyl alcohol) (PVA) nanocomposites was evaluated. The CNC were prepared by sulfuric acid hydrolysis at 45°C for 60 minutes, ...

Hudson Alves Silvério, Wilson Pires Flauzino Neto, Daniel Pasquini

2013-01-01T23:59:59.000Z

124

Non-Destructive Evaluation of Thermal Spray Coating Interface Quality by Eddy Current Method  

SciTech Connect

Thermal spray coating is usually applied through directing molten or softened particles at very high velocities onto a substrate. An eddy current non-destructive inspection technique is presented here for thermal spray coating interface quality characterization. Several high-velocity-oxy-fuel (HVOF) coated steel plates were produced with different surface preparation conditions before applying the coating, e.g., grit-blasted surface, wire-brush cleaned surface, and a dirty surface. A quad-frequency eddy current probe was used to manually scan over the coating surface to evaluate the bonding quality. Experimental results show that the three surface preparation conditions can be successfully differentiated by looking into the impedance difference observed from the eddy current probe. The measurement is fairly robust and consistent. More specimens are also prepared with variations of process parameters, such as spray angle, stand-off distance, and application of corrosion protective sealant, etc. They are blindly tested to evaluate the reliability of the eddy current system. Quantitative relations between the coating bond strength and the eddy current response are also established with the support of destructive testing. This non-contact, non-destructive, easy to use technique has the potential for evaluating the coating quality immediately after its application so that any defects can be corrected immediately.

B.Mi; X. Zhao; R. Bayles

2006-05-26T23:59:59.000Z

125

Gaseous modification of MCrAlY coatings  

SciTech Connect

The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

2000-01-01T23:59:59.000Z

126

Materials Science and Engineering A369 (2004) 124137 Studies of the microstructure and properties of dense ceramic coatings  

E-Print Network (OSTI)

. Kulkarni). stress relaxation cracks [5­7]. Although, this porosity is beneficial for thermal barrier applications because it reduces the coating thermal conductivity, it is deleterious for wear and corrosion

New York at Stoney Brook, State University of

127

A finite element analysis technique for predicting as-sprayed residual stresses generated by the plasma spray coating process  

Science Conference Proceedings (OSTI)

It is essential to analyze the residual stresses during the deposition of plasma sprayed coatings since they adversely affect the coatings' performance during their service. In this article, finite element coupled heat transfer and elastic-plastic thermal ... Keywords: Finite element analysis, Heat transfer, Plasma spraying, Residual stresses, Thermal barrier coatings

H. W. Ng; Z. Gan

2005-07-01T23:59:59.000Z

128

Thin-film metal coated insulation barrier in a Josephson tunnel junction. [Patent application  

DOE Patents (OSTI)

A highly stable, durable, and reproducible Josephson tunnel junction consists of a thin-film electrode of a hard superconductor, a thin oxide insulation layer over the electrode constituting a Josephson tunnel junction barrier, a thin-film layer of stabilizing metal over the barrier, and a second thin-film hard superconductive electrode over the stabilizing film. The thin stabilizing metal film is made only thick enough to limit penetration of the electrode material through the insulation layer so as to prevent a superconductive short.

Hawkins, G.A.; Clarke, J.

1975-10-31T23:59:59.000Z

129

METAL-MATRIX COMPOSITES AND THERMAL SPRAY COATINGS FOR EARTH MOVING MACHINES  

SciTech Connect

In the 10th quarter no further work was conducted on the steel matrix composite element of this project. For this element work is effectively complete and all that remains is the composition of the final report. For the thermal spray coating effort, components coated and fused in the previous quarter were subject to high stress abrasive wear testing. Some complications were encountered with the wear testing, but the tests which were completed successfully showed that the coatings provided wear resistance 5x that of the baseline material. Further wear testing is planned for the 11th and final quarter. An overview of the progress during the 10th quarter of this project is given below. Additional research details are provided in the limited rights appendix to this report.

D. Trent Weaver; Matthew T. Kiser

2003-07-01T23:59:59.000Z

130

Thermal stability and adhesion of low-emissivity electroplated Au coatings.  

Science Conference Proceedings (OSTI)

We are developing a low-emissivity thermal management coating system to minimize radiative heat losses under a high-vacuum environment. Good adhesion, low outgassing, and good thermal stability of the coating material are essential elements for a long-life, reliable thermal management device. The system of electroplated Au coating on the adhesion-enhancing Wood's Ni strike and 304L substrate was selected due to its low emissivity and low surface chemical reactivity. The physical and chemical properties, interface bonding, thermal aging, and compatibility of the above Au/Ni/304L system were examined extensively. The study shows that the as-plated electroplated Au and Ni samples contain submicron columnar grains, stringers of nanopores, and/or H{sub 2} gas bubbles, as expected. The grain structure of Au and Ni are thermally stable up to 250 C for 63 days. The interface bonding is strong, which can be attributed to good mechanical locking among the Au, the 304L, and the porous Ni strike. However, thermal instability of the nanopore structure (i.e., pore coalescence and coarsening due to vacancy and/or entrapped gaseous phase diffusion) and Ni diffusion were observed. In addition, the study also found that prebaking 304L in the furnace at {ge} 1 x 10{sup -4} Torr promotes surface Cr-oxides on the 304L surface, which reduces the effectiveness of the intended H-removal. The extent of the pore coalescence and coarsening and their effect on the long-term system integrity and outgassing are yet to be understood. Mitigating system outgassing and improving Au adhesion require a further understanding of the process-structure-system performance relationships within the electroplated Au/Ni/304L system.

Jorenby, Jeff W.; Hachman, John T., Jr.; Yang, Nancy Y. C.; Chames, Jeffrey M.; Clift, W. Miles

2010-12-01T23:59:59.000Z

131

Elastoplastic analysis of process induced residual stresses in thermally sprayed coatings  

SciTech Connect

The residual stresses induced from thermal spraying process have been extensively investigated in previous studies. However, most of such works were focused on the elastic deformation range. In this paper, an elastoplastic model for predicting the residual stresses in thermally sprayed coatings was developed, in which two main contributions were considered, namely the deposition induced stress and that due to differential thermal contraction between the substrate and coating during cooling. The deposition induced stress was analyzed based on the assumption that the coating is formed layer-by-layer, and then a misfit strain is accommodated within the multilayer structure after the addition of each layer (plastic deformation is induced consequently). From a knowledge of specimen dimensions, processing temperatures, and material properties, residual stress distributions within the structure can be determined by implementing the model with a simple computer program. A case study for the plasma sprayed NiCoCrAlY on Inconel 718 system was performed finally. Besides some similar phenomena observed from the present study as compared with previous elastic model reported in literature, the elastoplastic model also provides some interesting features for prediction of the residual stresses.

Chen Yongxiong; Liang Xiubing; Liu Yan; Xu Binshi [National Key Laboratory for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072 (China)

2010-07-15T23:59:59.000Z

132

Thermal heat radiation, near-field energy density and near-field radiative heat transfer of coated materials  

E-Print Network (OSTI)

We investigate the thermal radiation and thermal near-field energy density of a metal-coated semi-infinite body for different substrates. We show that the surface polariton coupling within the metal coating leads to an enhancement of the TM-mode part of the thermal near-field energy density when a polar substrate is used. In this case the result obtained for a free standing metal film is retrieved. In contrast, in the case of a metal substrate there is no enhancement in the TM-mode part, as can also be explained within the framework of surface plasmon coupling within the coating. Finally, we discuss the influence of the enhanced thermal energy density on the near-field radiative heat transfer between a simple semi-infinite and a coated semi-infinite body for different material combinations.

Biehs, Svend-Age

2011-01-01T23:59:59.000Z

133

Thermal heat radiation, near-field energy density and near-field radiative heat transfer of coated materials  

E-Print Network (OSTI)

We investigate the thermal radiation and thermal near-field energy density of a metal-coated semi-infinite body for different substrates. We show that the surface polariton coupling within the metal coating leads to an enhancement of the TM-mode part of the thermal near-field energy density when a polar substrate is used. In this case the result obtained for a free standing metal film is retrieved. In contrast, in the case of a metal substrate there is no enhancement in the TM-mode part, as can also be explained within the framework of surface plasmon coupling within the coating. Finally, we discuss the influence of the enhanced thermal energy density on the near-field radiative heat transfer between a simple semi-infinite and a coated semi-infinite body for different material combinations.

Svend-Age Biehs

2011-03-15T23:59:59.000Z

134

DEAD ZONES AS THERMAL BARRIERS TO RAPID PLANETARY MIGRATION IN PROTOPLANETARY DISKS  

Science Conference Proceedings (OSTI)

Planetary migration in standard models of gaseous protoplanetary disks is known to be very rapid ({approx}10{sup 5} years), jeopardizing the existence of planetary systems. We present a new mechanism for significantly slowing rapid planetary migration, discovered by means of radiative transfer calculations of the thermal structure of protoplanetary disks irradiated by their central stars. Rapid dust settling in a disk's dead zone-a region with very little turbulence-leaves a dusty wall at its outer edge. We show that the back-heating of the dead zone by this irradiated wall produces a positive gradient of the disk temperature, which acts as a thermal barrier to planetary migration which persists for the disk lifetime. Although we analyze in detail the migration of a super-Earth in a low-mass disk around an M star, our findings can apply to a wide variety of young planetary systems. We compare our findings with other potentially important stopping mechanisms and show that there are large parameter spaces for which dead zones are likely to play the most important role for reproducing the observed mass-period relation in longer planetary periods.

Hasegawa, Yasuhiro [Department of Physics and Astronomy, McMaster University, Hamilton, ON L8S 4M1 (Canada); Pudritz, Ralph E. [Origins Institute, McMaster University, Hamilton, ON L8S 4M1 (Canada)], E-mail: hasegay@physics.mcmaster.ca, E-mail: pudritz@physics.mcmaster.ca

2010-02-20T23:59:59.000Z

135

Building America Top Innovations Hall of Fame Profile Â… Thermal Bypass Air Barriers in the 2009 International Energy Conservation Code  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Imagine Homes of San Antonio, Texas, worked Imagine Homes of San Antonio, Texas, worked with Building America team partner IBACOS to improve the continuity of the air barrier along the thermal enclosure by using spray foam insulation in the walls and attic. Building America research teams effectively demonstrated the importance of thermal bypass air barriers, which led to their inclusion in ENERGY STAR for Homes Version 3 specifications in 2006 and then to inclusion in the 2009 IECC. This is a great example of effective research driving a complete market transformation process for a critical high-performance home innovation. Air sealing of the home's thermal enclosure has been required by the energy code for many years. However, in years past, the provisions were somewhat vague and only required that critical areas of potential air leakage (e.g., joints,

136

Analysis of the Window Side Thermal Environment Formed by Air Barrier Technique in Winter Conditions and Its Economy  

E-Print Network (OSTI)

The air barrier technique applies airflow through a window fan to decrease the heat load of a window surface and avoid dewfall in winter and decrease heat radiation from the window surface in summer. This paper uses numerical simulation to predict the energy-saving potential and thermal comfort of the air barrier technique used in office buildings. It also analyzes the surface temperature of the window by using the simulation software Airpak. According to the results, we can obtain the key control strategy of this technology. It can be found that the air barrier technique, instead of the heating-supply around outside-zone for office building, can avoid dewfall in winter and decrease the cold radiation, which has a great effect on thermal environment around the window. Characteristics such as outer air temperature, indoor load, thermal characteristics of structure, and air-supply parameters through window fans are analyzed in detail to measure their effects on energy consumption, window side environment and PMV values. The paper provides theoretical reference and technical guidance for applying air barrier technology correctly, improving the window side environment and reducing energy consumption.

Huang, C.; Jia, Y.; Liu, L.; Wang, X.

2006-01-01T23:59:59.000Z

137

On-Line Thermal Barrier Coating Monitoring for Real-Time Failure Protection and Life Maximization  

NLE Websites -- All DOE Office Websites (Extended Search)

Final Technical Report For the period October 2002 to October 2005 Prepared for: U.S Department of Energy National Energy Technology Laboratory P.O. Box 10940 Pittsburgh, PA 15236-0940 Cooperative Agreement No. DE-FC26-01NT41232 Prepared by: Dennis H. LeMieux Siemens Power Generation, Inc 4400 Alafaya Trail Orlando, Florida 32826 October 2005 Disclaimer This report as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, make any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or legal fullness of any information, apparatus, product, or process disclosed, or represents that its use would

138

METAL-ORGANIC CHEMICALLY VAPOR DEPOSITED YTTRIA-STABILIZED ZIRCONIA (YSZ) FOR THERMAL BARRIER COATINGS  

E-Print Network (OSTI)

or Rene-N5 during engine operation. The current method for YSZ fabrication for TBC applications is by air. The solution was delivered continuously by a syringe pump through a poppet-seal relief valve

139

Influence of EB-PVD TBC Microstructure on Thermal Barrier Coating System Performance Under Cyclic Conditions  

DOE Green Energy (OSTI)

lifetime on CMSX-4 substrates was 1250, lh cycles, whereas the respective Rene N5 specimens have not yet failed after 2300, lh cycles. The failure mode at 1100°C was identical to that at 115O?C, i.e. the TBC spalled off the surface exposing bare metal after cooling. Even though not all specimens have failed to date, the available results at 1100°C suggested that both, the substrate alloy chemistry and the YSZ microstructure significantly affect the spallation resistance of the TBC.

Leyens, C.; Pint, B.A.; Schulz, U.; Wright, I.G.

1999-04-12T23:59:59.000Z

140

Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof  

DOE Patents (OSTI)

An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications is disclosed. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al[sub x]N[sub y]O[sub z] layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al[sub x]N[sub y]O[sub z] layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

Sarin, V.K.

1990-08-21T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Structure determination of thermal-spray materials using synchrotron x-ray microtomography. [Cr[sub 3]C[sub 2]/NiCr thermal-spray coating  

SciTech Connect

The structure of materials prepared using thermal spray methods is difficult to determine using conventional microscopy of porosimetry methods. The difficulties inherent in these approaches can be circumvented using synchrotron computed microtomography(CMT). An example of the use of CMT to produce a high resolution non- destructive image of a thermal-spray coating is Cr[sub 3]C[sub 2]/NiCr is described here to illustrate the power of this technique.

Spanne, P.; Jones, K.W. (Brookhaven National Lab., Upton, NY (United States)); Herman, H. (State Univ. of New York, Stony Brook, NY (United States)); Riggs, W.L. (General Electric Co., Cincinnati, OH (United States). Aircraft Engines)

1991-01-01T23:59:59.000Z

142

Gas seal for an in situ oil shale retort and method of forming thermal barrier  

DOE Patents (OSTI)

A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

Burton, III, Robert S. (Mesa, CO)

1982-01-01T23:59:59.000Z

143

Thermal effects on the Fission Barrier of neutron-rich nuclei  

E-Print Network (OSTI)

We discuss the fission barrier height of neutron-rich nuclei in a r-process site at highly excited state, which is resulted from the beta-decay or the neutron-capture processes. We particularly investigate the sensitivity of the fission barrier height to the temperature, including the effect of pairing phase transition from superfluid to normal fluid phases. To this end, we use the finite-temperature Skyrme-Hartree-Fock-Bogolubov method with a zero-range pairing interaction. We also discuss the temperature dependence of the fission decay rate.

Futoshi Minato; Kouichi Hagino

2008-07-23T23:59:59.000Z

144

Thermally Evaporated Iron (Oxide) on an Alumina Barrier Layer, by XPS  

SciTech Connect

We report the XPS characterization of a thermally evaporated iron thin film (6 nm) deposited on an Si/SiO_2/Al_2O_3 substrate using Al Ka X-rays. An XPS survey spectrum, narrow Fe 2p scan, narrow O 1s, and valence band scan are shown.

Madaan, Nitesh; Kanyal, Supriya S.; Jensen, David S.; Vail, Michael A.; Dadson, Andrew; Engelhard, Mark H.; Linford, Matthew R.

2013-09-06T23:59:59.000Z

145

Thermal-Hydrologic Sensitivity Analysis of Engineered Barrier System Design Options  

Science Conference Proceedings (OSTI)

This sensitivity study presents the effects that changing the ventilation time and initial linear power loading can have on specific thermal-hydrologic response parameters, such as waste package peak temperatures. Results show that an approximate 55 C drop in waste package peak temperature can be expected from the reference case design if the initial line loading is reduced to 0.90 kW/m or if the ventilation time is increased to 125 years. Increasing the waste package to waste package spacing in order to reduce the linear load to 0.90 kW/m requires additional emplacement drifts and an expansion of the area that the repository occupies. Increasing the ventilation duration requires that the repository remains open and is maintained for long periods of time. The effectiveness and expense of each design alternative must be weighed in determining the best way to achieve a particular thermal goal. Also, this sensitivity study shows that certain thermal goals may not be reached if only using ventilation, sometimes only the reduction of the linear load or a combination of linear loading and ventilation can reduce the thermal response to lower temperature specifications, if considered. As an example, Figure 1 shows that waste package peak temperatures below 96 C would require both a reduction in the linear load and an increase in ventilation duration.

B. Dunlap

2000-11-01T23:59:59.000Z

146

Development of nondestructive evaluation methods for ceramic coatings.  

SciTech Connect

Various nondestructive evaluation (NDE) technologies are being developed to advance the knowledge of ceramic coatings for components in the hot gas-path of advanced, low-emission gas-fired turbine engines. The ceramic coating systems being studied by NDE include thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs). TBCs are under development for vanes, blades and combustor liners to allow hotter gas path temperatures and EBCs are under development to reduce environmental damage to high temperature components made of ceramic matrix composites (CMCs). Data provided by NDE methods will be used to: (a) provide data to assess reliability of new coating application processes, (b) identify defective components that could cause unscheduled outages (c) track growth rates of defects during use in engines and (d) allow rational judgement for replace/repair/re-use decisions of components.

Sun, J. G. (Nuclear Engineering Division)

2007-01-01T23:59:59.000Z

147

Probability of passing through a parabolic barrier and thermal decay rate: Case of linear coupling both in momentum and in coordinate  

SciTech Connect

With the quantum diffusion approach, the probability of passing through the parabolic barrier and the quasistationary thermal decay rate from a metastable state are examined in the limit of linear coupling both in momentum and in coordinate between a collective subsystem and the environment. An increase of passing probability with friction coefficient is demonstrated to occur at subbarrier energies.

Kuzyakin, R. A. [Joint Institute for Nuclear Research, RU-141980 Dubna (Russian Federation); Omsk State Transport University, RU-644046 Omsk (Russian Federation); Sargsyan, V. V. [Joint Institute for Nuclear Research, RU-141980 Dubna (Russian Federation); Yerevan State University, International Center for Advanced Studies, Yerevan (Armenia); Adamian, G. G.; Antonenko, N. V. [Joint Institute for Nuclear Research, RU-141980 Dubna (Russian Federation)

2011-09-15T23:59:59.000Z

148

Alternate Coating Methods  

Science Conference Proceedings (OSTI)

Oct 28, 2009 ... The cold spray process can prepare thick coatings (> 1 cm) with many ... protection, thermal insulation, thermal dissipation, wear resistance, ...

149

Understanding Compatibilities between Advanced Coatings and ...  

Science Conference Proceedings (OSTI)

Oxidation Studies of HVAS-sprayed Nanostructured Coatings at Elevated Temperature · Oxide Based Thermal Sprayed Coatings for Metal Dusting Applications.

150

HVOF Thermal Spray TiC/TiB2 Coatings of AUSC Boiler/Turbine ...  

Science Conference Proceedings (OSTI)

The paper presents the research endeavors to synthesize TiC and TiB2 coatings on existing boiler materials for applications at high temperatures (500 -750 oC) ...

151

Environmental Coatings  

Science Conference Proceedings (OSTI)

Oct 28, 2009... thermal cycle lifetime when compared to conventional EB-PVD coatings. ... widely used on turbine engine blades/vanes as stand-alone overlayers. .... thin film provides a flexible, low-cost platform for surface engineering.

152

Final Technical Report - Recovery Act: Organic Coatings as Encapsulants for Low Cost, High Performance PV Modules  

DOE Green Energy (OSTI)

The objective of this project was to evaluate the feasibility of utilizing PPG's commercial organic coatings systems as efficient, modernized encapsulants for low cost, high performance, thin film photovoltaic modules. Our hypothesis was that the combination of an anticorrosive coating with a more traditional barrier topcoat would mitigate many electrochemical processes that are now responsible for the significant portion of photovoltaic (PV) failures, thereby nullifying the extremely high moisture barrier requirements of currently used encapsulation technology. Nine commercially available metal primer coatings and six commercially available top coatings were selected for screening. Twenty-one different primer/top coat combinations were evaluated. The primer coatings were shown to be the major contributor to corrosion inhibition, adhesion, and barrier properties. Two primer coatings and one top coating were downselected for testing on specially-fabricated test modules. The coated test modules passed initial current leakage and insulation testing. Damp Heat testing of control modules showed visible corrosion to the bus bar metal, whereas the coated modules showed none. One of the primer/top coat combinations retained solar power performance after Damp Heat testing despite showing some delamination at the EVA/solar cell interface. Thermal Cycling and Humidity Freeze testing resulted in only one test module retaining its power performance. Failure modes depended on the particular primer/top coating combination used. Overall, this study demonstrated that a relatively thin primer/top coating has the potential to replace the potting film and backsheet in crystalline silicon-based photovoltaic modules. Positive signals were received from commercially available coatings developed for applications having performance requirements different from those required for photovoltaic modules. It is likely that future work to redesign and customize these coatings would result in a coating system meeting the requirements for photovoltaic module encapsulation.

Stuart Hellring; Jiping Shao; James Poole

2011-12-05T23:59:59.000Z

153

Filler Materials for Polyphenylenesulphide Composite Coatings: Preprint  

DOE Green Energy (OSTI)

Researchers at Brookhaven National Laboratory and the National Renewable Energy Laboratory have tested polymer-based coating systems to reduce the capital equipment and maintenance costs of heat exchangers in corrosive and fouling geothermal environments. These coating systems act as barriers to corrosion to protect low-cost carbon steel tubing; they are formulated to resist wear from hydroblasting and to have high thermal conductivity. Recently, new filler materials have been developed for coating systems that use polyphenylenesulphide as a matrix. These materials include boehmite crystals (orthorhombic aluminum hydroxide, which is grown in situ as a product of reaction with the geothermal fluid), which enhance wear and corrosion resistance, and carbon fibers, which improve mechanical, thermal, and corrosion-resistance properties of the composite.

Sugama, T.; Gawlik, K.

2001-07-17T23:59:59.000Z

154

Degradation of yttria-stabilized zirconia thermal barrier coatings by vanadium pentoxide, phosphorous pentoxide, and sodium sulfate  

Science Conference Proceedings (OSTI)

The presence of vanadium, phosphorus, and sodium impurities in petcoke and coal/petcoke blends used in integrated gasification combined cycle (IGCC) plants warrants a clear understanding of high-temperature material degradation for the development of fuel-flexible gas turbines. In this study, degradation reactions of free-standing air plasma-sprayed (APS) yttria-stabilized zirconia (YSZ) in contact with V{sub 2}O{sub 5}, P{sub 2}O{sub 5}, and Na{sub 2}SO{sub 4} were investigated at temperatures up to 1200{sup o}C. Phase transformations and microstructural development were examined using X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Molten V{sub 2}O{sub 5} reacted with solid YSZ to form ZrV{sub 2}O{sub 7} at temperatures below 747{sup o}C. However, at temperatures above 747{sup o}C, molten V{sub 2}O{sub 5} reacted with YSZ to form yttrium vanadate (YVO{sub 4}). The formation of YVO{sub 4} led to the depletion of the Y2O{sub 3} stabilizer and deleterious transformation to the monoclinic ZrO{sub 2} phase. In addition, studies on YSZ degradation by Na{sub 2}SO{sub 4} and a Na{sub 2}SO{sub 4}+V{sub 2}O{sub 5} mixture (50-50 mol%) showed that Na{sub 2}SO{sub 4} itself had no effect on the degradation of YSZ. However, in the presence of V{sub 2}O{sub 5} at high temperatures, Na{sub 2}SO{sub 4} forms vanadate compounds having a lower melting point such as sodium metavanadate (610{sup o}C), which was found to degrade YSZ by the formation of YVO{sub 4} at a relatively lower temperature of 700{sup o}C. P{sub 2}O{sub 5} was found to react with APS YSZ by the formation of ZrP{sub 2}O{sub 7} at all the temperatures studied. At temperatures as low as 200{sup o}C and as high as 1200{sup o}C, molten P{sub 2}O{sub 5} was observed to react with solid YSZ to yield ZrP{sub 2}O{sub 7}, which led to the depletion of ZrO{sub 2} in YSZ that promoted the formation of the fluorite-cubic ZrO{sub 2} phase.

Mohan, P.; Yuan, B.; Patterson, T.; Desai, V.H.; Sohn, Y.H. [University of Central Florida, Orlando, FL (United States)

2007-11-15T23:59:59.000Z

155

Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical report, January 14, 1997--August 14, 1997  

SciTech Connect

Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. Bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. Also, to deposit model Ni-Al{sub 2}O{sub 3} coatings, an electrodeposition technique was developed and coatings with various volume fractions (0-35%) of Al{sub 2}O{sub 3} were produced. The powder and electrodeposition processing of Ni-Al{sub 2}O{sub 3} Composites provide the ability to produce two phase microstructure without changing the microstructure of the matrix material. Therefore, the effect of hard second phase particles size and volume fraction on erosion resistance could be analyzed.

Schorr, B.S.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

1997-08-31T23:59:59.000Z

156

Compositions of corrosion-resistant Fe-based amorphous metals suitable for producing thermal spray coatings  

SciTech Connect

A method of coating a surface comprising providing a source of amorphous metal that contains manganese (1 to 3 atomic %), yttrium (0.1 to 10 atomic %), and silicon (0.3 to 3.1 atomic %) in the range of composition given in parentheses; and that contains the following elements in the specified range of composition given in parentheses: chromium (15 to 20 atomic %), molybdenum (2 to 15 atomic %), tungsten (1 to 3 atomic %), boron (5 to 16 atomic %), carbon (3 to 16 atomic %), and the balance iron; and applying said amorphous metal to the surface by a spray.

Farmer, Joseph C; Wong, Frank M.G.; Haslam, Jeffery J; Ji, Xiaoyan; Day, Sumner D; Blue, Craig A; Rivard, John D.K.; Aprigliano, Louis F; Kohler, Leslie K; Bayles, Robert; Lemieux, Edward J; Yang, Nancy; Perepezko, John H; Kaufman, Larry; Heuer, Arthur; Lavernia, Enrique J

2013-09-03T23:59:59.000Z

157

Compositions of corrosion-resistant Fe-based amorphous metals suitable for producing thermal spray coatings  

SciTech Connect

A method of coating a surface comprising providing a source of amorphous metal that contains manganese (1 to 3 atomic %), yttrium (0.1 to 10 atomic %), and silicon (0.3 to 3.1 atomic %) in the range of composition given in parentheses; and that contains the following elements in the specified range of composition given in parentheses: chromium (15 to 20 atomic %), molybdenum (2 to 15 atomic %), tungsten (1 to 3 atomic %), boron (5 to 16 atomic %), carbon (3 to 16 atomic %), and the balance iron; and applying said amorphous metal to the surface by a spray.

Farmer, Joseph C.; Wong, Frank M. G.; Haslam, Jeffery J.; Ji, Xiaoyan (Jane); Day, Sumner D.; Blue, Craig A.; Rivard, John D. K.; Aprigliano, Louis F.; Kohler, Leslie K.; Bayles, Robert; Lemieux, Edward J.; Yang, Nancy; Perepezko, John H.; Kaufman, Larry; Heuer, Arthur; Lavernia, Enrique J.

2013-07-09T23:59:59.000Z

158

Evaluation of the thermal resistance of a roof-mounted multi-reflective radiant barrier for tropical and humid conditions: Experimental study from field measurements  

E-Print Network (OSTI)

This paper deals with the experimental evaluation of a roof-mounted multi-reflective radiant barrier (MRRB), installed according to the state of the art, on a dedicated test cell. An existing experimental device was completed with a specific system for the regulation of the airflow rate in the upper air layer included in a typical roof from Reunion Island. Several experimental sequences were conducted to determine the thermal resistance of the roof according to several parameters and following a specific method. The mean method, well known in international standards (ISO 9869 - 1994) for the determination of the thermal resistance using dynamic data, was used. The method was implemented in a building simulation code in order to allow the determination of the thermal indicator automatically. Experimental results are proposed according to different seasonal periods and for different values of the airflow rate in the upper air layer.

Frédéric Miranville; Ali Hamada Fakra; Stéphane Guichard; Harry Boyer; Jean Philippe Praene; Dimitri Bigot

2012-12-19T23:59:59.000Z

159

Evaluation of the thermal resistance of a roof-mounted multi-reflective radiant barrier for tropical and humid conditions: Experimental study from field measurements  

E-Print Network (OSTI)

This paper deals with the experimental evaluation of a roof-mounted multi-reflective radiant barrier (MRRB), installed according to the state of the art, on a dedicated test cell. An existing experimental device was completed with a specific system for the regulation of the airflow rate in the upper air layer included in a typical roof from Reunion Island. Several experimental sequences were conducted to determine the thermal resistance of the roof according to several parameters and following a specific method. The mean method, well known in international standards (ISO 9869 - 1994) for the determination of the thermal resistance using dynamic data, was used. The method was implemented in a building simulation code in order to allow the determination of the thermal indicator automatically. Experimental results are proposed according to different seasonal periods and for different values of the airflow rate in the upper air layer

Miranville, Frédéric; Guichard, Stéphane; Boyer, Harry; Praene, Jean Philippe; Bigot, Dimitri

2012-01-01T23:59:59.000Z

160

The Radial Loss of Ions Trapped in the Thermal Barrier Potential and the Design of Divertor Magnetic Field in GAMMA10  

Science Conference Proceedings (OSTI)

The ion radial loss exists in the presence of a non-axisymmetric electrostatic potential in the end-mirror cells of GAMMA10, which leads to a formation of the thermal barrier potential. The non-axisymmetric electrostatic potential can also exist in the central cell. A design for divertor magnetic field of GAMMA10 is performed, the purpose of which is first to reduce an ion radial transport in the central cell by making electrostatic potential circular and second to assure the macroscopic plasma stability of GAMMA10 without help of non-axisymmetric anchor cells which enhances a neoclassical radial transport.

Katanuma, I. [Plasma Research Center, University of Tsukuba (Japan); Ito, T. [Plasma Research Center, University of Tsukuba (Japan); Saimaru, H. [Plasma Research Center, University of Tsukuba (Japan); Sasagawa, Y. [Plasma Research Center, University of Tsukuba (Japan); Pastukhov, V.P. [I.V.Kuruchatov Atomic Energy Institute (Russian Federation); Ishii, K. [Plasma Research Center, University of Tsukuba (Japan); Tatematsu, Y. [Plasma Research Center, University of Tsukuba (Japan); Saito, T. [Plasma Research Center, University of Tsukuba (Japan); Islam, Md.K. [Plasma Research Center, University of Tsukuba (Japan); Nakashima, Y. [Plasma Research Center, University of Tsukuba (Japan); Cho, T. [Plasma Research Center, University of Tsukuba (Japan)

2005-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Comparision of Stellite Coatings on Valve Steel Material Prepared ...  

Science Conference Proceedings (OSTI)

Oxidation Studies of HVAS-sprayed Nanostructured Coatings at Elevated Temperature · Oxide Based Thermal Sprayed Coatings for Metal Dusting Applications.

162

Preparing of High Silicon Coating by Composite Electrodeposition in ...  

Science Conference Proceedings (OSTI)

Oxidation Studies of HVAS-sprayed Nanostructured Coatings at Elevated Temperature · Oxide Based Thermal Sprayed Coatings for Metal Dusting Applications.

163

Improved Mechanical Properties of Cermet Coatings as a Function ...  

Science Conference Proceedings (OSTI)

Oxidation Studies of HVAS-sprayed Nanostructured Coatings at Elevated Temperature · Oxide Based Thermal Sprayed Coatings for Metal Dusting Applications.

164

Liquid metal hydrogen barriers  

DOE Patents (OSTI)

Hydrogen barriers which comprise liquid metals in which the solubility of hydrogen is low and which have good thermal conductivities at operating temperatures of interest. Such barriers are useful in nuclear fuel elements containing a metal hydride moderator which has a substantial hydrogen dissociation pressure at reactor operating temperatures.

Grover, George M. (Los Alamos, NM); Frank, Thurman G. (Los Alamos, NM); Keddy, Edward S. (Los Alamos, NM)

1976-01-01T23:59:59.000Z

165

Solar selective absorption coatings  

DOE Patents (OSTI)

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2004-08-31T23:59:59.000Z

166

Solar selective absorption coatings  

DOE Patents (OSTI)

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2003-10-14T23:59:59.000Z

167

Thermally stable diamond brazing  

DOE Patents (OSTI)

A cutting element and a method for forming a cutting element is described and shown. The cutting element includes a substrate, a TSP diamond layer, a metal interlayer between the substrate and the diamond layer, and a braze joint securing the diamond layer to the substrate. The thickness of the metal interlayer is determined according to a formula. The formula takes into account the thickness and modulus of elasticity of the metal interlayer and the thickness of the TSP diamond. This prevents the use of a too thin or too thick metal interlayer. A metal interlayer that is too thin is not capable of absorbing enough energy to prevent the TSP diamond from fracturing. A metal interlayer that is too thick may allow the TSP diamond to fracture by reason of bending stress. A coating may be provided between the TSP diamond layer and the metal interlayer. This coating serves as a thermal barrier and to control residual thermal stress.

Radtke, Robert P. (Kingwood, TX)

2009-02-10T23:59:59.000Z

168

A Micro-Indentation Method for Assessment of TBC Bond Coat Systems  

Science Conference Proceedings (OSTI)

Under elevated temperatures, the presence of high thermal stresses along or within thermal barrier coatings (TBCs) can lead to the development of creep cavities and wedge cracks which can ultimately form microcracks and result in interfacial debonding in the TBC bond coat region. Defects detection on the subsurface TBC layers has shown some progress by using laser scattering and other non-destructive testing (NDT) methods. However, the difficulty of determining interfacial debonding and degradation assessment of the TBC remains a significant hurdle to overcome due to the TBC’s complex multi-layer structure, and frequently rough surface morphology. The TBC has high attenuation, high porosity, and many interfaces of different materials, which are the challenges that need to be overcome by the NDT techniques. Based on our recent research development of a Transparent Indenter Measurement (TIM) method, we have further developed a simplified micro-indentation technique for mechanical property degradation measurement and debonding/spallation detection of TBC bond coat in this research effort. NETL bond-coated coupons were subjected to cumulative rapid thermal cycling, and after every 100 high temperature thermal cycles, micro-indentation tests were conducted on bond-coat superalloy and single crystal coupons. Preliminary test results showed that the measured surface stiffness responses of the NETL bond coat decreased with exposure to continued thermal cycling. Currently these data are being correlated with microstructural analyses to address potential degradation and/or spalling of the applied NETL bond coat.

Feng, C.; Alvin, M.A.; Kang, B.S.

2007-09-01T23:59:59.000Z

169

Evaluation of the Thermal Performance for a Wire Mesh/Hollow Glass Microsphere Composite Structure as a Conduction Barrier  

E-Print Network (OSTI)

An experimental investigation exploring the use of wire mesh/hollow glass microsphere combination for use as thermal insulation was conducted with the aim to conclude whether or not it represents a superior insulation technology to those on the market. Three primary variables, including number of wire mesh layers, filler material, and temperature dependence were studied using an apparatus that was part of L.I.C.H.E.N (LabVIEW Integrated Conduction Heat Experiment Network), a setup whose basic components allow three vertically stacked samples to be thermally and mechanically controlled. Knowing the temperature profile in the upper and lower samples allows for determination of thermal conductivity of the middle material through the use of Fourier?s law. The numbers of layers investigated were two, four, six, and eight, with each separated by a metallic liner. The filler materials included air, s15, s35 and s60HS 3MTM hollow glass microspheres. The experiments were conducted at four temperatures of 300, 330, 366, and 400K with an interface pressure of 20 Psi. The experimental results indicated the ?number of layers? used was the primary factor in determining the effective thermal conductivity value. The addition of hollow glass microspheres as filler material resulted in statistically insignificant changes in effective thermal conductivity. Increasing the number of wire mesh layers resulted in a corresponding increase in effective thermal conductivity of the insulation. Changes in temperature had little to no effect on thermal conductivity. The effective thermal conductivity values for the proposed insulation structure ranged from 0.22 to 0.65 W/m-K, the lowest of which came from the two layer case having air as filler material. The uncertainties associated with the experimental results fell between 10 to 20 percent in all but a few cases. In the best performing cases, when compared with existing insulation technologies, thermal conductivity was approximately 3 to 10 times higher than these methods of insulation. Thus, the proposed insulation scheme with hollow glass-sphere filler material does not represent superior technology, and would be deemed uncompetitive with those readily available in the insulation market.

Mckenna, Sean

2008-12-01T23:59:59.000Z

170

DEVELOPMENT AND ASSESSMENT OF COATINGS FOR FUTURE POWER GENERATION TURBINES  

SciTech Connect

The NETL-Regional University Alliance (RUA) continues to advance technology development critical to turbine manufacturer efforts for achieving DOE Fossil Energy (FE's) Advanced Turbine Program Goals. In conjunction with NETL, Coatings for Industry (CFI), the University of Pittsburgh, NASA GRC, and Corrosion Control Inc., efforts have been focused on development of composite thermal barrier coating (TBC) architectures that consist of an extreme temperature coating, a commercially applied 7-8 YSZ TBC, a reduced cost bond coat, and a diffusion barrier coating that are applied to nickel-based superalloys or single crystal airfoil substrate materials for use at temperatures >1450 C (> 2640 F). Additionally, construction of a unique, high temperature ({approx}1100 C; {approx}2010 F), bench-scale, micro-indentation, nondestructive (NDE) test facility at West Virginia University (WVU) was completed to experimentally address in-situ changes in TBC stiffness during extended cyclic oxidation exposure of coated single crystal coupons in air or steam containing environments. The efforts and technical accomplishments in these areas are presented in the following sections of this paper.

Alvin, Maryanne; Klotz, K.; McMordie, B.; Gleeson, B.; Zhu, D.; Warnes, B.; Kang, B.; Tannenbaum, J.

2012-01-01T23:59:59.000Z

171

Radiant Barriers | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Barriers Barriers Radiant Barriers May 30, 2012 - 2:07pm Addthis What does this mean for me? Properly installed radiant barriers can reduce your cooling costs. Radiant barriers are easiest to install in new construction, but can be installed in your existing house, especially if it has an open attic. How does it work? Radiant barriers work by reflecting radiant heat away from living spaces. Radiant barriers are installed in homes -- usually in attics -- primarily to reduce summer heat gain and reduce cooling costs. The barriers consist of a highly reflective material that reflects radiant heat rather than absorbing it. They don't, however, reduce heat conduction like thermal insulation materials. How They Work Heat travels from a warm area to a cool area by a combination of

172

Radiant Barriers | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Radiant Barriers Radiant Barriers Radiant Barriers May 30, 2012 - 2:07pm Addthis What does this mean for me? Properly installed radiant barriers can reduce your cooling costs. Radiant barriers are easiest to install in new construction, but can be installed in your existing house, especially if it has an open attic. How does it work? Radiant barriers work by reflecting radiant heat away from living spaces. Radiant barriers are installed in homes -- usually in attics -- primarily to reduce summer heat gain and reduce cooling costs. The barriers consist of a highly reflective material that reflects radiant heat rather than absorbing it. They don't, however, reduce heat conduction like thermal insulation materials. How They Work Heat travels from a warm area to a cool area by a combination of

173

Coatings for Corrosion and Wear Resistance Applications  

Science Conference Proceedings (OSTI)

Apr 2, 2012 ... Long-Term Surface Restoration Effect Introduced by Advanced Lubricant Additive · Nanocomposite Thermal Spray Coatings. New Hardfacing ...

174

Polysilazane Based Corrosion Coatings for Magnesium  

Science Conference Proceedings (OSTI)

Long-Term Surface Restoration Effect Introduced by Advanced Lubricant Additive · Nanocomposite Thermal Spray Coatings. New Hardfacing Overlay Claddings ...

175

Proceedings of the 1987 coatings for advanced heat engines workshop  

DOE Green Energy (OSTI)

This Workshop was conducted to enhance communication among those involved in coating development for improved heat engine performance and durability. We were fortunate to have Bill Goward review the steady progress and problems encountered along the way in the use of thermal barrier coatings (TBC) in aircraft gas turbine engines. Navy contractors discussed their work toward the elusive goal of qualifying TBC for turbine airfoil applications. In the diesel community, Caterpillar and Cummins are developing TBC for combustion chamber components as part of the low heat rejection diesel engine concept. The diesel engine TBC work is based on gas turbine technology with a goal of more than twice the thickness used on gas turbine engine components. Adoption of TBC in production for diesel engines could justify a new generation of plasma spray coating equipment. Increasing interests in tribology were evident in this Workshop. Coatings have a significant role in reducing friction and wear under greater mechanical loadings at higher temperatures. The emergence of a high temperature synthetic lubricant could have an enormous impact on diesel engine design and operating conditions. The proven coating processes such as plasma spray, electron-beam physical vapor deposition, sputtering, and chemical vapor deposition have shown enhanced capabilities, particularly with microprocessor controls. Also, the newer coating schemes such as ion implantation and cathodic arc are demonstrating intriguing potential for engine applications. Coatings will play an expanding role in higher efficiency, more durable heat engines.

Not Available

1987-01-01T23:59:59.000Z

176

PLASMA SPRAYED Ni-Al COATINGS FOR SAFE ENDING HEAT EXCHANGER TUBES  

DOE Green Energy (OSTI)

Brookhaven National Laboratory (BNL) has developed thermally conductive composite liners for corrosion and scale protection in heat exchanger tubes exposed to geothermal brine. The liners cannot withstand roller expansion to connect the tubes to the tubesheet. It is not possible to line the ends of the tubes with the same material after roller expansion due to the nature of the current liner application process. It was requested that BNL evaluate plasma sprayed Ni-Al coatings for safe ending heat exchanger tubes exposed to geothermal brine. The tubes of interest had an internal diameter of 0.875 inches. It is not typical to thermal spray small diameter components or use such small standoff distances. In this project a nozzle extension was developed by Zatorski Coating Company to spray the tube ends as well as flat coupons for testing. Four different Ni-Al coatings were investigated. One of these was a ductilized Ni-AIB material developed at Oak Ridge National Laboratory. The coatings were examined by optical and scanning electron microscopy. In addition, the coatings were analyzed by X-ray diffraction and subjected to corrosion, tensile adhesion, microhardness and field tests in a volcanic pool in New Zealand. It was determined that the Ni-Al coatings could be applied to a depth of two inches on the tube ends. When sprayed on flat coupons the coatings exhibited relatively high adhesion strength and microhardness. Polarization curves showed that the coating performance was variable. Measured corrosion potentials indicated that the Ni-Al coatings are active towards steel coated with thermally conductive polymers, thereby suggesting preferential corrosion. Corrosion also occurred on the coated coupons tested in the volcanic pool. This may have been exacerbated by the difficulty in applying a uniform coating to the coupon edges. The Ni-Al coatings applied to the tubes had significant porosity and did not provide adequate corrosion protection. This is associated with the short standoff distance and is not a reflection of the normal quality of plasma sprayed coatings. Even if coating porosity could be reduced, the coupling of an alloy coating to a polymer-based barrier coating in the same electrolyte is not recommended. Therefore, polymer coatings that can be field applied to the tube ends after roller expansion should be sought.

ALLAN,M.L.; OTTERSON,D.; BERNDT,C.C.

1998-11-01T23:59:59.000Z

177

Protective Coatings Assessment  

Science Conference Proceedings (OSTI)

This report describes assessments of ceramic and thermal spray coatings that have advanced significantly or recently been marketed for use in the utility boiler industry to reduce slagging, mitigate fireside corrosion and potentially, circumferential cracking due to cyclic temperature variations. These innovations promise to enhance coating quality as well as reduce time and labor required to protect large areas of the boiler waterwalls. Coatings may also enable plants to improve production rates; thereb...

2011-12-22T23:59:59.000Z

178

Thermal performance measurements of sealed insulating glass units with low-E coatings using the MoWiTT (Mobile Window Thermal Test) field-test facility  

SciTech Connect

Using data obtained in a mobile field-test facility, measured performance of clear and low-emissivity double-glazing units is presented for south-facing and north-facing orientations. The changes in U-value and shading coefficient resulting from addition of the low-E coating are found to agree with theoretical expectations for the cold spring test conditions. Accurate nighttime U-values were derived from the data and found to agree with calculations. Expected correlation between U-value and wind speed was not observed in the data; a plausible experimental reason for this is advanced.

Klems, J.; Keller, H.

1986-12-01T23:59:59.000Z

179

Ultra-High Temperature Ceramic Composite Coatings for Oxidation ...  

Science Conference Proceedings (OSTI)

Our protective coatings were evaluated for thermal-shock performance at the ... that our coatings provide oxidation protection of C-C composites at temperature.

180

Advances in Zinc-Coated Steel Sheet: Processing and Properties  

Science Conference Proceedings (OSTI)

Influences of Ni-Pretreatments on Galvanized Coatings · Surface Performance of Environment-Friendly Galvanized Sheet for Appliance · Thermal Spray Coating ...

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Vehicle barrier  

DOE Patents (OSTI)

A vehicle security barrier which can be conveniently placed across a gate opening as well as readily removed from the gate opening to allow for easy passage. The security barrier includes a barrier gate in the form of a cable/gate member in combination with laterally attached pipe sections fixed by way of the cable to the gate member and lateral, security fixed vertical pipe posts. The security barrier of the present invention provides for the use of cable restraints across gate openings to provide necessary security while at the same time allowing for quick opening and closing of the gate areas without compromising security.

Hirsh, Robert A. (Bethel Park, PA)

1991-01-01T23:59:59.000Z

182

X-231A demonstration of in-situ remediation of DNAPL compounds in low permeability media by soil fracturing with thermally enhanced mass recovery or reactive barrier destruction  

Science Conference Proceedings (OSTI)

The overall goal of the program of activities is to demonstrate robust and cost-effective technologies for in situ remediation of DNAPL compounds in low permeability media (LPM), including adaptations and enhancements of conventional technologies to achieve improved performance for DNAPLs in LPM. The technologies sought should be potential for application at simple, small sites (e.g., gasoline underground storage tanks) as well as at complex, larger sites (e.g., DOE land treatment units). The technologies involved in the X-231A demonstration at Portsmouth Gaseous Diffusion Plant (PORTS) utilized subsurface manipulation of the LPM through soil fracturing with thermally enhanced mass recovery or horizontal barrier in place destruction. To enable field evaluation of these approaches, a set of four test cells was established at the X-231A land treatment unit at the DOE PORTS plant in August 1996 and a series of demonstration field activities occurred through December 1997. The principal objectives of the PORTS X-231A demonstration were to: determine and compare the operational features of hydraulic fractures as an enabling technology for steam and hot air enhanced soil vapor extraction and mass recovery, in situ interception and reductive destruction by zero valent iron, and in situ interception and oxidative destruction by potassium permanganate; determine the interaction of the delivered agents with the LPM matrix adjacent to the fracture and within the fractured zone and assess the beneficial modifications to the transport and/or reaction properties of the LPM deposit; and determine the remediation efficiency achieved by each of the technology strategies.

Siegrist, R.L. [Oak Ridge National Lab., TN (United States)] [Oak Ridge National Lab., TN (United States); [Colorado School of Mines, Golden, CO (United States). Environmental Science and Engineering Div.; Lowe, K.S. [Oak Ridge National Lab., Grand Junction, CO (United States). Life Sciences Div.] [Oak Ridge National Lab., Grand Junction, CO (United States). Life Sciences Div.; Murdoch, L.D. [FRx, Inc., Cincinnati, OH (United States)] [FRx, Inc., Cincinnati, OH (United States); [Clemson Univ., SC (United States); Slack, W.W. [FRx, Inc., Cincinnati, OH (United States)] [FRx, Inc., Cincinnati, OH (United States); Houk, T.C. [Lockheed Martin Energy Systems, Piketon, OH (United States)] [Lockheed Martin Energy Systems, Piketon, OH (United States)

1998-03-01T23:59:59.000Z

183

Zinc phosphate conversion coatings  

DOE Patents (OSTI)

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

Sugama, Toshifumi (Wading River, NY)

1997-01-01T23:59:59.000Z

184

Effects of thermal annealing on the microstructure of sputtered Al{sub 2}O{sub 3} coatings  

SciTech Connect

The morphology and microstructure of Al{sub 2}O{sub 3} thin films deposited by pulsed direct current magnetron sputtering were studied in the as-grown state and after vacuum annealing at 1000 deg. C for 12 h using transmission electron microscopy. For the coating deposited under low ion bombardment conditions, the film consists of small {gamma}- and/or {delta}-Al{sub 2}O{sub 3} grains embedded in an amorphous matrix. The grain size at the region close to the interface to the substrate was much larger than that of the remaining layer. Growth of the {gamma}-Al{sub 2}O{sub 3} phase is promoted during annealing but no transformation to {alpha}-Al{sub 2}O{sub 3} was detected. For high-energetic growth conditions, clear evidence for {gamma}-Al{sub 2}O{sub 3} formation was found in the upper part of the coating with grain size much larger than for low-energetic growth, but the film was predominately amorphous at the interface region. Annealing resulted in the transformation of {gamma}-Al{sub 2}O{sub 3} to {alpha}-Al{sub 2}O{sub 3}, while the mainly amorphous part crystallized to {gamma}-Al{sub 2}O{sub 3}.

Edlmayr, V.; Harzer, T. P.; Hoffmann, R.; Kiener, D.; Scheu, C.; Mitterer, C. [Department of Physical Metallurgy and Materials Testing, University of Leoben, A-8700 Leoben (Austria); Department of Chemistry, Ludwig-Maximilians-University of Munich, D-81377 Munich (Germany); Department of Physical Metallurgy and Materials Testing, University of Leoben, A-8700 Leoben (Austria)

2011-07-15T23:59:59.000Z

185

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: Combined stability in isothermal ageing and thermal cycling with YSZ coated ferritic stainless steels  

Science Conference Proceedings (OSTI)

An alkali-containing silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel cell (SOFC) applications. The glass contains about 17 mole% alkalis (K+Na) and has low glass transition and softening temperatures. It remains vitreous and compliant around 750-800oC after sealing without substantial crystallization, as contrary to conventional glass-ceramic sealants, which experience rapid crystallization after the sealing process. The glassy nature and low characteristic temperatures can reduce residual stresses and result in the potential for crack healing. In a previous study, the glass was found to have good thermal cycle stability and was chemically compatible with YSZ coating during short term testing. In the current study, the compliant glass was further evaluated in a more realistic way in that the sealed glass couples were first isothermally aged for 1000h followed by thermal cycling. High temperature leakage was measured. The chemical compatibility was also investigated with powder mixtures at 700 and 800oC to enhance potential interfacial reaction. In addition, interfacial microstructure was examined with scanning electron microscopy and evaluated with regard to the leakage and chemical compatibility results.

Chou, Y. S.; Thomsen, Edwin C.; Choi, Jung-Pyung; Stevenson, Jeffry W.

2012-01-01T23:59:59.000Z

186

Development of nondestructive evaluation methods for ceramic coatings.  

Science Conference Proceedings (OSTI)

Various nondestructive evaluation (NDE) technologies are being developed to study the use of ceramic coatings on components in the hot-gas path of advanced low-emission gas-fired turbines. The types of ceramic coatings include thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs). TBCs are under development for vanes, blades, and combustor liners to allow hotter gas-path temperatures, and EBCs are under development to reduce environmental damage to high-temperature components made of ceramic matrix composites. The NDE methods will be used to (a) provide data to assess the reliability of new coating application processes, (b) identify defective components that could cause unscheduled outages, (c) track growth rates of defects during component use in engines, and (d) allow rational judgment for replace/repair/re-use decisions regarding components. Advances in TBC application, both electron beam-physical vapor deposition (EB-PVD) and air plasma spraying (APS), are allowing higher temperatures in the hot-gas path. However, as TBCs become ''prime reliant,'' their condition at scheduled or unscheduled outages must be known. NDE methods are under development to assess the condition of the TBC for pre-spall conditions. EB-PVD test samples with up to 70 thermal cycles have been studied by a newly developed method involving polarized laser back-scatter NDE. Results suggest a correlation between the NDE laser data and the TBC/bond-coat topography. This finding is important because several theories directed toward understanding the pre-spall condition suggest that the topography in the thermally grown oxide layer changes significantly as a function of the number of thermal cycles. Tests have also been conducted with this NDE method on APS TBCs. Results suggest that the pre-spall condition is detected for these coatings. One-sided, high-speed thermal imaging also has shown promise for NDE of APS coatings. Testing of SiC/SiC composites for combustor liners has demonstrated that environmental EBCs are required to reduce oxidation-induced recession rates. NDE technologies, primarily one-sided and through-thickness thermal imaging, are under development to detect delaminations and degradation of EBCs. Recent results have demonstrated that NDE thermal image data correctly detected pre-spall regions of a barium-strontium-alumino-silicate coating on melt-infiltrated SiC/SiC. The NDE data were verified with field test data from a combustor liner in a 4.5 MW(e) natural-gas-fired turbine. The shape of the spalled EBC region and the growth of the spalled EBC region after various engine run times were correlated with boroscope image data from field tests. An effort has recently been started to address NDE development for oxide/oxide ceramic composites with an EBC. We will discuss the NDE methods under development for TBCs, recent NDE test results from thermally cycled TBCs, NDE results from EBCs on SiC/SiC, and the new effort directed toward oxide/oxide materials.

Ellingson, W. A.; Deemer, C.; Sun, J. G.; Erdman, S.; Muliere, D.; Wheeler, B.

2002-04-29T23:59:59.000Z

187

Coatings and Surface Treatments for Application on a Martensitic ...  

Science Conference Proceedings (OSTI)

Long-Term Surface Restoration Effect Introduced by Advanced Lubricant Additive · Nanocomposite Thermal Spray Coatings. New Hardfacing Overlay Claddings ...

188

Advanced Environmental Barrier Coatings for Gas Turbine ...  

Science Conference Proceedings (OSTI)

Symposium, Ceramic Matrix Composites ... and recession in water vapor rich hot- section applications such as combustor liners, vanes, shrouds, and blades.

189

Solar Selective Absorption Coatings - Energy Innovation Portal  

Sandia has developed a new class of solar selective absorber coatings that significantly improve the thermal conversion efficiency of solar units by reducing ...

190

Hydrogen Permeation Resistant Coatings  

DOE Green Energy (OSTI)

As the National Hydrogen Economy continues to develop and evolve the need for structural materials that can resist hydrogen assisted degradation will become critical. To date austenitic stainless steel materials have been shown to be mildly susceptible to hydrogen attack which results in lower mechanical and fracture strengths. As a result, hydrogen permeation barrier coatings may be applied to these ferrous alloys to retard hydrogen ingress. Hydrogen is known to be very mobile in materials of construction. In this study, the permeation resistance of bare stainless steel samples and coated stainless steel samples was tested. The permeation resistance was measured using a modular permeation rig using a pressure rise technique. The coating microstructure and permeation results will be discussed in this document as will some additional testing.

KORINKO, PAUL; ADAMS, THAD; CREECH, GREGGORY

2005-06-15T23:59:59.000Z

191

Corrosion resistant coatings suitable for elevated temperature application  

DOE Patents (OSTI)

The present invention relates to corrosion resistance coatings suitable for elevated temperature applications, which employ compositions of iron (Fe), chromium (Cr), nickel (Ni) and/or aluminum (Al). The compositions may be configured to regulate the diffusion of metals between a coating and a substrate, which may then influence coating performance, via the formation of an inter-diffusion barrier layer. The inter-diffusion barrier layer may comprise a face-centered cubic phase.

Chan, Kwai S. (San Antonio, TX); Cheruvu, Narayana Sastry (San Antonio, TX); Liang, Wuwei (Austin, TX)

2012-07-31T23:59:59.000Z

192

Development of Low Thermal Expansion Superalloys  

Science Conference Proceedings (OSTI)

For heat resistant alloys it is useful to decrease the thermal expansion for improved adherance of low thermal expansion ceramic coatings like silicon nitride,.

193

DEVELOPMENT OF PROTECTIVE COATINGS FOR SINGLE CRYSTAL TURBINE BLADES  

DOE Green Energy (OSTI)

Turbine blades in coal derived syngas systems are subject to oxidation and corrosion due to high steam temperature and pressure. Thermal barrier coatings (TBCs) are developed to address these problems. The emphasis is on prime-reliant design and a better coating architecture, having high temperature and corrosion resistance properties for turbine blades. In Phase I, UES Inc. proposed to develop, characterize and optimize a prime reliant TBC system, having smooth and defect-free NiCoCrAlY bond layer and a defect free oxide sublayer, using a filtered arc technology. Phase I work demonstrated the deposition of highly dense, smooth and defect free NiCoCrAlY bond coat on a single crystal CMSX-4 substrate and the deposition of alpha-alumina and yttrium aluminum garnet (YAG) sublayer on top of the bond coat. Isothermal and cyclic oxidation test and pre- and post-characterization of these layers, in Phase I work, (with and without top TBC layer of commercial EB PVD YSZ) revealed significant performance enhancement.

Amarendra K. Rai

2006-12-04T23:59:59.000Z

194

Slide 1  

NLE Websites -- All DOE Office Websites (Extended Search)

Fabrication Thermal Barrier Coating Challenges for High Temperature Systems NOVEL THERMALLY-SPRAYED ARCHITECTURES FOR HIGH TEMPERATURE THERMAL BARRIER COATING SYSTEMS Yang Tan,...

195

POLYTETRAFLUOROETHYLENE-RICH POLYPHENLENESULFIDE BLEND TOP COATINGS FOR MITIGATING CORROSION OF CARBON STEEL IN 300 DEGREE CELCIUS BRINE.  

DOE Green Energy (OSTI)

We evaluated usefulness of a coating system consisting of an underlying polyphenylenesulfide (PPS) layer and top polytetrafluoroethylene (PTFE)-blended PPS layer as low friction, water repellent, anti-corrosion barrier film for carbon steel steam separators in geothermal power plants. The experiments were designed to obtain information on kinetic coefficient of friction, surface free energy, hydrothermal oxidation, alteration of molecular structure, thermal stability, and corrosion protection of the coating after immersing the coated carbon steel coupons for up to 35 days in CO{sub 2}-laden brine at 300 C. The superficial layer of the assembled coating was occupied by PTFE self-segregated from PPS during the melt-flowing process of this blend polymer; it conferred an outstanding slipperiness and water repellent properties because of its low friction and surface free energy. However, PTFE underwent hydrothermal oxidation in hot brine, transforming its molecular structure into an alkylated polyfluorocarboxylate salt complex linked to Na. Although such molecular transformation increased the friction and surface free energy, and also impaired the thermal stability of PTFE, the top PTFE-rich PPS layer significantly contributed to preventing the permeation of moisture and corrosive electrolytes through the coating film, so mitigating the corrosion of carbon steel.

SUGAMA, T.; JUNG, D.

2006-06-01T23:59:59.000Z

196

Protective coatings and sealants for solar applications  

DOE Green Energy (OSTI)

An aging study has been completed which evaluated a number of polymeric materials for potential use as (1) protective coatings for back surfaces of mirrors and (2) solar heliostat edge seals. These investigations were conducted in an artificial weathering chamber that accelerated thermal cycling. The primary mirror failure mode was observed to be silver corrosion resulting from moisture exposure. To increase mirror longevity in current heliostat designs, intimate bonding at all the composite interfaces is essential to minimize moisture pathways to the silvered surface. If any voids or delaminations are present, mirror degradation will eventually occur. Delaminations can also occur as the result of mechanical stresses brought about by mismatches in the various materials coefficients of thermal expansion. If good bonding cannot be achieved or mechanical stresses avoided, then improved moisture barriers must be designed to assure mirror longevity. With good adhesion, a KRATON rubber was found to exhibit superior back surface mirror protection (12 months in environmental chamber with no corrosion). An ultraviolet stabilized butyl rubber appeared to be the best edge seal. All heliostats edge sealed with silicones showed silver corrosion which indicated either poor bonding or moisture permeation.

Wischmann, K. B.; Gonzales, M. H.

1980-09-01T23:59:59.000Z

197

Bioactive Coatings  

Science Conference Proceedings (OSTI)

Oct 10, 2012 ... Tailoring the Surface Properties of Parylene Biocompatible Coating: Martina Cihova1; Quoc Nguyen2; Varshni Singh2; 1Karlsruhe Institute of ...

198

High-Performance Corrosion-Resistant Materials: Iron-Based Amorphous-Metal Thermal-Spray Coatings: SAM HPCRM Program ? FY04 Annual Report ? Rev. 0 - DARPA DSO & DOE OCRWM Co-Sponsored Advanced Materials Program  

Science Conference Proceedings (OSTI)

The multi-institutional High Performance Corrosion Resistant Materials (HPCRM) Team is cosponsored by the Defense Advanced Projects Agency (DARPA) Defense Science Office (DSO) and the Department of Energy (DOE) Office of Civilian Radioactive Waste Management (OCRWM), and has developed new corrosion-resistant, iron-based amorphous metals that can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The Fe-based corrosion-resistant, amorphous-metal coatings under development may prove of importance for applications on ships. Such coatings could be used as an 'integral drip shield' on spent fuel containers, as well as protective coatings that could be applied over welds, thereby preventing exposure to environments that might cause stress corrosion cracking. In the future, such new high-performance iron-based materials could be substituted for more-expensive nickel-based alloys, thereby enabling a reduction in the $58-billion life cycle cost for the long-term storage of the Nation's spent nuclear fuel by tens of percent.

Farmer, J; Haslam, J; Wong, F; Ji, S; Day, S; Branagan, D; Marshall, M; Meacham, B; Buffa, E; Blue, C; Rivard, J; Beardsley, M; Buffa, E; Blue, C; Rivard, J; Beardsley, M; Weaver, D; Aprigliano, L; Kohler, L; Bayles, R; Lemieux, E; Wolejsza, T; Martin, F; Yang, N; Lucadamo, G; Perepezko, J; Hildal, K; Kaufman, L; Heuer, A; Ernst, F; Michal, G; Kahn, H; Lavernia, E

2007-09-19T23:59:59.000Z

199

Protective Coatings Assessment  

Science Conference Proceedings (OSTI)

It is well known that fireside corrosion of waterwall panels in coal-fired boilers increased with the introduction of low NOx combustion systems since the early 1980s. This report describes ongoing work to evaluate protective coating solutions used to mitigate the wastage due to corrosion, and to determine which provide the greatest resistance to the circumferential cracking phenomena. It includes recent laboratory corrosion assisted thermal fatigue tests and analyses of field-exposed samples of ...

2012-12-17T23:59:59.000Z

200

A Micro-Indentation Method for Assessment of TBC Bond Coat ...  

Science Conference Proceedings (OSTI)

Sep 16, 2007 ... NETL bond-coated coupons were subjected to cumulative rapid thermal cycling, and after every 100 high temperature thermal cycles, ...

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201

Progress to Develop an Advanced Solar-Selective Coating  

DOE Green Energy (OSTI)

The progress to develop a durable advanced solar-selective coating will be described. Experimental work has focused on modeling high-temperature, solar-selective coatings; depositing the individual layers and modeled coatings; measuring the optical, thermal, morphology, and compositional properties and using the data to validate the modeled and deposited properties; re-optimizing the coating; and testing the coating performance and durability.

Kennedy, C. E.

2008-03-01T23:59:59.000Z

202

Richards Barrier LA Reference Design Feature Evaluation  

Science Conference Proceedings (OSTI)

The Richards Barrier is one of the design features of the repository to be considered for the License Application (LA), Richards was a soil scientist who first described the diversion of moisture between two materials with different hydrologic properties. In this report, a Richards Barrier is a special type of backfill with a fine-grained material (such as sand) overlaying a coarse-grained material (such as gravel). Water that enters an emplacement drift will first encounter the fine-grained material and be transported around the coarse-grained material covering the waste package, thus protecting the waste package from contact with most of the groundwater. The objective of this report is to discuss the benefits and liabilities to the repository by the inclusion of a Richards Barrier type backfill in emplacement drifts. The Richards Barrier can act as a barrier to water flow, can reduce the waste package material dissolution rate, limit mobilization of the radionuclides, and can provide structural protection for the waste package. The scope of this report is to: (1) Analyze the behavior of barrier materials following the intrusion of groundwater for influxes of 1 to 300 mm per year. The report will demonstrate diversion of groundwater intrusions into the barrier over an extended time period when seismic activity and consolidation may cause the potential for liquefaction and settlement of the Richards Barrier. (2) Review the thermal effects of the Richards Barrier on material behavior. (3) Analyze the effect of rockfall on the performance of the Richards Barrier and the depth of the barrier required to protect waste packages under the barrier. (4) Review radiological and heating conditions on placement of multiple layers of the barrier. Subsurface Nuclear Safety personnel will perform calculations to determine the radiation reduction-time relationship and shielding capacity of the barrier. (5) Evaluate the effects of ventilation on cooling of emplacement drifts and dusting potential. (6) Evaluate drift conditions and configurations to determine the suitability of Richards Barrier installation methodology. (7) Perform cost assessment of barrier material placement. (8) Evaluate the feature with criteria that will be supplied by the License Application Design Selection (LADS) Team. (9) Comment on the use of depleted uranium as a Richards Barrier material.

N.E. Kramer

1999-11-17T23:59:59.000Z

203

Constructing Hydraulic Barriers in Deep Geologic Formations  

Science Conference Proceedings (OSTI)

Many construction methods have been developed to create hydraulic barriers to depths of 30 to 50 meters, but few have been proposed for depths on the order of 500 meters. For these deep hydraulic barriers, most methods are potentially feasible for soil but not for hard rock. In the course of researching methods of isolating large subterranean blocks of oil shale, the authors have developed a wax thermal permeation method for constructing hydraulic barriers in rock to depths of over 500 meters in competent or even fractured rock as well as soil. The technology is similar to freeze wall methods, but produces a permanent barrier; and is potentially applicable in both dry and water saturated formations. Like freeze wall barriers, the wax thermal permeation method utilizes a large number of vertical or horizontal boreholes around the perimeter to be contained. However, instead of cooling the boreholes, they are heated. After heating these boreholes, a specially formulated molten wax based grout is pumped into the boreholes where it seals fractures and also permeates radially outward to form a series of columns of wax-impregnated rock. Rows of overlapping columns can then form a durable hydraulic barrier. These barriers can also be angled above a geologic repository to help prevent influx of water due to atypical rainfall events. Applications of the technique to constructing containment structures around existing shallow waste burial sites and water shutoff for mining are also described. (authors)

Carter, E.E.; Carter, P.E. [Technologies Co, Texas (United States); Cooper, D.C. [Ph.D. Idaho National Laboratory, Idaho Falls, ID (United States)

2008-07-01T23:59:59.000Z

204

HIGH SURFACE AREA SILICON CARBIDE-COATED CARBON AEROGEL ...  

Carbon aerogels can be coated with sol-gel silica and the silica can be converted to silicon carbide, improving the thermal stability of the carbon ae ...

205

A Study of Advanced Materials for Gas Turbine Coatings at Elevated Temperatures Using Selected Microstructures and Characteristic Environments for Syngas Combustion  

DOE Green Energy (OSTI)

Thermal barrier coatings (TBCs) that can be suitable for use in industrial gas turbine engines have been processed and compared with electron beam physical vapor deposition (EBPVD) microstructures for applications in advanced gas turbines that use coal-derived synthesis gas. Thermo-physical properties have been evaluated of the processed air plasma sprayed TBCs with standard APS-STD and vertically cracked APS-VC coatings samples up to 1300 C. Porosity of these selected coatings with related microstructural effects have been analyzed in this study. Wet and dry thermal cycling studies at 1125 C and spalling resistance thermal cycling studies to 1200 C have also been carried out. Type I and Type II hot corrosion tests were carried out to investigate the effects of microstructure variations and additions of alumina in YSZ top coats in multi-layered TBC structures. The thermal modeling of turbine blade has also been carried out that gives the capability to predict in-service performance temperature gradients. In addition to isothermal high temperature oxidation kinetics analysis in YSZ thermal barrier coatings of NiCoCrAlY bond coats with 0.25% Hf. This can affect the failure behavior depending on the control of the thermally grown oxide (TGO) growth at the interface. The TGO growth kinetics is seen to be parabolic and the activation energies correspond to interfacial growth kinetics that is controlled by the diffusion of O{sub 2} in Al{sub 2}O{sub 3}. The difference between oxidation behavior of the VC and STD structures are attributed to the effects of microstructure morphology and porosity on oxygen ingression into the zirconia and TGO layers. The isothermal oxidation resistance of the STD and VC microstructures is similar at temperatures up to 1200 C. However, the generally thicker TGO layer thicknesses and the slightly faster oxidation rates in the VC microstructures are attributed to the increased ingression of oxygen through the grain boundaries of the vertically cracked microstructures. The plasma sprayed TBC microstructure (VC and STD) with NiCoCrAlY-Hf bond coat are stable up to 1100 C. However, as with other TBC structures, a considerable amount of interdiffusion was observed in the different layers, although the TBC growth was self-limiting and parabolic. The addition of Hf to the VC microstructure appears to have some potential for the future development of robust TBCs with improved isothermal and service temperatures in advanced gas turbines.

Ravinder Diwan; Patrick Mensah; Guoqiang Li; Nalini Uppu; Strphen Akwaboa; Monica Silva; Ebubekir Beyazoglu; Ogad Agu; Naresh Polasa; Lawrence Bazille; Douglas Wolfe; Purush Sahoo

2011-02-10T23:59:59.000Z

206

Coated Particle Fuel Development Lab (CPFDL) | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Coated Particle Fuel Development Lab Coated Particle Fuel Development Lab May 30, 2013 Computer controlled fluidized bed CVD particle coating system The Coated Particle Fuel Development Laboratory is a modern, integrated facility for laboratory scale fabrication and characterization of uranium-bearing coated particle fuel (CPF). Within this facility, tri-isotropic (TRISO) coatings are deposited on various fuel kernels by chemical vapor deposition (CVD), particles are pressed into fuel compacts for irradiation, and state-of-the-art materials property characterization is performed, all under an NQA-1 compliant Quality Assurance program. Current work includes fabrication and characterization of coated particle fuels to support the Next Generation Nuclear Plant, Advanced Small Modular Reactors, Nuclear Thermal Propulsion, and Advanced Light Water Reactor

207

Mechanism-Based Testing Methodology for Improving the Oxidation, Hot Corrosion and Impact Resistance of High-Temperature Coatings for Advanced Gas Turbines  

NLE Websites -- All DOE Office Websites (Extended Search)

Pittsburgh Pittsburgh University of Pittsburgh PIs: F. S. Pettit, G. H. Meier Subcontractor: J. L. Beuth SCIES Project 02- 01- SR101 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (05/01/02, 36 Month Duration + 6 mo No-Cost Extension) $ 458,420 Total Contract Value ($ 412,695 DOE) Mechanism-Based Testing Methodology For Improving the Oxidation, Hot Corrosion and Impact Resistance of High- Temperature Coatings for Advanced Gas Turbines University of Pittsburgh - Carnegie Mellon University University of Pittsburgh University of Pittsburgh In the next generation gas turbine, resistance to thermal cycling damage may be as important as resistance to long isothermal exposures. Moreover, metallic coatings and Thermal Barrier

208

Metal matrix coated fiber composites and the methods of manufacturing such composites  

DOE Patents (OSTI)

A fiber coating which allows ceramic or metal fibers to be wetted by molten metals is disclosed. The coating inhibits degradation of the physical properties caused by chemical reaction between the fiber and the coating itself or between the fiber and the metal matrix. The fiber coating preferably includes at least a wetting layer, and in some applications, a wetting layer and a barrier layer between the fiber and the wetting layer. The wetting layer promotes fiber wetting by the metal matrix. The barrier layer inhibits fiber degradation. The fiber coating permits the fibers to be infiltrated with the metal matrix resulting in composites having unique properties not obtainable in pure materials.

Weeks, Jr., Joseph K. (Salt Lake City, UT); Gensse, Chantal (Salt Lake City, UT)

1993-01-01T23:59:59.000Z

209

Coated ceramic breeder materials  

DOE Patents (OSTI)

A lithium containing ceramic breeder material is described which is coated with a neutron multiplier such as Beryllium (Be), Beryllium Oxide (BeO), or other material having a higher thermal conductivity than the lithium ceramic material itself. In addition to exhibiting certain thermal conductivity properties, the neutron multiplier must be capable of withstanding the high temperatures (700/sup 0/ to 1300/sup 0/K) experienced in a breeder blanket of a fusion reactor. State of the art considerations have indicated several possible configurations for the lithium containing ceramic breeders, including a sphere-pac arrangement or sintered pellets or blocks. When one adds a neutron multiplier such as Be or BeO into a sphere-pac bed of lithium containing ceramic breeders, current concepts include mixing the neutron multiplier randomly into the sphere-pac bed in the form of small spheres of a size comparable to that of the lithium ceramic particles. The present invention shows that a sphere-pac bed of breeder particles coated with a neutron multiplier such as Be and BeO has an improved thermal conductivity when compared with that of a bed of uncoated breeder particles randomly mixed with Be or BeO spheres having the same breeder/multiplier composition ratio.

Tam, S.W.; Johnson, C.E.

1986-08-22T23:59:59.000Z

210

TURBINE THERMAL MANAGEMENT NETL Team Technical Coordinator: ...  

NLE Websites -- All DOE Office Websites (Extended Search)

TURBINE THERMAL MANAGEMENT NETL Team Technical Coordinator: Maryanne Alvin Name Project Role Affiliation University Project Title Gleeson, Brian M PI Pitt Bond Coat and Extreme...

211

Radiant barrier applications: Symposium and workshop proceedings  

Science Conference Proceedings (OSTI)

Electric utilities and their customers are continually looking for ways to improve the thermal integrity of buildings. Radiant barrier systems can reduce summer air conditioning loads by reducing radiant heat transfer in attics. EPRI conducted two programs to help utilities with radiant barriers. A Symposium and Workshop were conducted in April 1988. The Symposium reviewed the state of the art in radiant barriers. The Workshop brought industry experts together to identify research needs for radiant barriers. The Workshop found that research is needed in six major areas. Listed in order of importance these are: (1) Field and laboratory testing, (2) Materials research, (3) Modeling, (4) Materials standards, (5) Economic issues, and (6) Installation methods. The leading research topics within these six major areas in order of importance include:(1) Modeling to fill voids in existing field data and aid in the development of performance standards, (2) Calculation of energy savings for various configurations, (3) Analysis of existing data to better understand radiant barrier performance, (4) Assessment of the effect of dust accumulation on performance, (5) Development of standard testing procedures, (6) Development of systems standards, (7) Measurement of changes in the emissivity of radiant barrier materials with time, (8) Determination of the possibility of moisture accumulation under horizontal radiant barriers during heating season operation, (9) Ventilation effects, (10) Configuration testing, (11) Costs of new and retrofit applications, and (12) Characterization of side effects. 34 refs., 5 figs.

Isaksen, L.

1989-02-01T23:59:59.000Z

212

Composite ceria-coated aerogels and methods of making the same  

DOE Patents (OSTI)

Ceria-coated aerogels can include an aerogel support material having a stabilized ceria coating thereon. The ceria coating can be formed by solution or vapor deposition of alcogels or aerogels. Additional catalytic metal species can also be incorporated into the coating to form multi-metallic compounds having improved catalytic activity. Further, the ceria coated aerogels retain high surface areas at elevated temperatures. Thus, improvements in catalytic activity and thermal stability can be achieved using these ceria-coated composite aerogels.

Eyring, Edward M; Ernst, Richard D; Turpin, Gregory C; Dunn, Brian C

2013-05-07T23:59:59.000Z

213

DEVELOPMENT AND TESTING OF A CERIA-ZIRCONIA TOUGHENED ALUMINA PROTOTYPE FILTER ELEMENT MADE OF RETICULATED CERAMIC FOAM COATED WITH A CERAMIC MEMBRANE ACTING AS BARRIER FILTER FOR FLY ASH  

SciTech Connect

The objective of this work was to fabricate subscale candle filters using a Ce-ZTA reticulated foam material. Specifically Selee fabricated 60mm diameter cylinders with one closed end and one flanged end. Selee Corporation developed a small pore size (5-10 {micro}m) filtration membrane which was applied to the reticulated foam surface to provide a barrier filter surface. The specific tasks to be performed were as follows: (Task 1) Filter Element Development--To fabricate subscale filter elements from zirconia toughened alumina using the reticulated foam manufacturing process. The filter elements were required to meet dimensional tolerances specified by an appropriate filter system supplier. The subscale filter elements were fabricated with integral flanges and end caps, that is, with no glued joints. (Task 2) Membrane Development--To develop a small pore filtration membrane that is to be applied to the reticulated foam material. This membrane was to provide filtration characteristics that meet gas turbine requirements and pressure drop or permeability requirements specified by the filter system supplier. (Task 3) Subscale Filter Element Fabrication--To fabricate six subscale filter elements with integral flanges and closed ends, as well as fine pore size filtration membranes. Three filters were to have a central clean gas channel, while three would have no central channel. The filters were to be provided to FETC for testing in laboratory systems or pilot scale exposure systems as appropriate. The candles were to meet dimensional tolerances as provided by filter system suppliers.

Guilio A. Rossi; Kenneth R. Butcher; Stacia M. Wagner

1999-02-19T23:59:59.000Z

214

Methods and systems to thermally protect fuel nozzles in combustion systems  

SciTech Connect

A method of assembling a gas turbine engine is provided. The method includes coupling a combustor in flow communication with a compressor such that the combustor receives at least some of the air discharged by the compressor. A fuel nozzle assembly is coupled to the combustor and includes at least one fuel nozzle that includes a plurality of interior surfaces, wherein a thermal barrier coating is applied across at least one of the plurality of interior surfaces to facilitate shielding the interior surfaces from combustion gases.

Helmick, David Andrew; Johnson, Thomas Edward; York, William David; Lacy, Benjamin Paul

2013-12-17T23:59:59.000Z

215

Insulator coating for high temperature alloys method for producing insulator coating for high temperature alloys  

DOE Patents (OSTI)

A method for fabricating an electrically insulating coating on a surface is disclosed comprising coating the surface with a metal, and reacting the metal coated surface with a nonmetal so as to create a film on the metal-coated surface. Alternatively, the invention provides for a method for producing a noncorrosive, electrically insulating coating on a surface saturated with a nonmetal comprising supplying a molten fluid, dissolving a metal in the molten fluid to create a mixture, and contacting the mixture with the saturated surface. Lastly, the invention provides an electrically insulative coating comprising an underlying structural substrate coated with an oxide or nitride compound. This invention has applications to breeding blankets for fusion reactors as well as to alkali metal thermal to electric converters.

Park, J.H.

1994-12-31T23:59:59.000Z

216

Hydrogen permeation resistant barrier  

DOE Patents (OSTI)

A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

McGuire, J.C.; Brehm, W.F.

1980-02-08T23:59:59.000Z

217

Hydrogen permeation resistant barrier  

DOE Patents (OSTI)

A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

McGuire, Joseph C. (Richland, WA); Brehm, William F. (Richland, WA)

1982-01-01T23:59:59.000Z

218

Nanoscale Reinforced, Polymer Derived Ceramic Matrix Coatings  

Science Conference Proceedings (OSTI)

The goal of this project was to explore and develop a novel class of nanoscale reinforced ceramic coatings for high temperature (600-1000 C) corrosion protection of metallic components in a coal-fired environment. It was focused on developing coatings that are easy to process and low cost. The approach was to use high-yield preceramic polymers loaded with nano-size fillers. The complex interplay of the particles in the polymer, their role in controlling shrinkage and phase evolution during thermal treatment, resulting densification and microstructural evolution, mechanical properties and effectiveness as corrosion protection coatings were investigated. Fe-and Ni-based alloys currently used in coal-fired environments do not possess the requisite corrosion and oxidation resistance for next generation of advanced power systems. One example of this is the power plants that use ultra supercritical steam as the working fluid. The increase in thermal efficiency of the plant and decrease in pollutant emissions are only possible by changing the properties of steam from supercritical to ultra supercritical. However, the conditions, 650 C and 34.5 MPa, are too severe and result in higher rate of corrosion due to higher metal temperatures. Coating the metallic components with ceramics that are resistant to corrosion, oxidation and erosion, is an economical and immediate solution to this problem. Good high temperature corrosion protection ceramic coatings for metallic structures must have a set of properties that are difficult to achieve using established processing techniques. The required properties include ease of coating complex shapes, low processing temperatures, thermal expansion match with metallic structures and good mechanical and chemical properties. Nanoscale reinforced composite coatings in which the matrix is derived from preceramic polymers have the potential to meet these requirements. The research was focused on developing suitable material systems and processing techniques for these coatings. In addition, we investigated the effect of microstructure on the mechanical properties and oxidation protection ability of the coatings. Coatings were developed to provide oxidation protection to both ferritic and austentic alloys and Ni-based alloys. The coatings that we developed are based on low viscosity pre-ceramic polymers. Thus they can be easily applied to any shape by using a variety of techniques including dip-coating, spray-coating and painting. The polymers are loaded with a variety of nanoparticles. The nanoparticles have two primary roles: control of the final composition and phases (and hence the properties); and control of the shrinkage during thermal decomposition of the polymer. Thus the selection of the nanoparticles was the most critical aspect of this project. Based on the results of the processing studies, the performance of selected coatings in oxidizing conditions (both static and cyclic) was investigated.

Rajendra Bordia

2009-07-31T23:59:59.000Z

219

Silicon Oxynitride Thin Film Barriers for PV Packaging (Poster)  

DOE Green Energy (OSTI)

Dielectric, adhesion-promoting, moisture barriers comprised of silicon oxynitride thin film materials (SiOxNy with various material stoichiometric compositions x,y) were applied to: 1) bare and pre-coated soda-lime silicate glass (coated with transparent conductive oxide SnO2:F and/or aluminum), and polymer substrates (polyethylene terephthalate, PET, or polyethylene napthalate, PEN); plus 2) pre- deposited photovoltaic (PV) cells and mini-modules consisting of amorphous silicon (a-Si) and copper indium gallium diselenide (CIGS) thin-film PV technologies. We used plasma enhanced chemical vapor deposition (PECVD) process with dilute silane, nitrogen, and nitrous oxide/oxygen gas mixtures in a low-power (< or = 10 milliW per cm2) RF discharge at ~ 0.2 Torr pressure, and low substrate temperatures < or = 100(degrees)C, over deposition areas ~ 1000 cm2. Barrier properties of the resulting PV cells and coated-glass packaging structures were studied with subsequent stressing in damp-heat exposure at 85(degrees)C/85% RH. Preliminary results on PV cells and coated glass indicate the palpable benefits of the barriers in mitigating moisture intrusion and degradation of the underlying structures using SiOxNy coatings with thicknesses in the range of 100-200 nm.

del Cueto, J. A.; Glick, S. H.; Terwilliger, K. M.; Jorgensen, G. J.; Pankow, J. W.; Keyes, B. M.; Gedvilas, L. M.; Pern, F. J.

2006-10-03T23:59:59.000Z

220

Microstructure, Processing, Performance Relationships for High Temperature Coatings  

SciTech Connect

This work evaluates the suitability of iron aluminide coatings for use in high temperature fossil fuel combustion environments, such as boiler applications. The coatings are applied using High Velocity Oxy-Fuel (HVOF) thermal spray techniques. Iron aluminide coatings, with the nominal composition of Fe3Al, were applied to various high temperature structural materials (316 Stainless Steel, 9Cr-1Mo steel and Inconel 600) that typically lack inherent resistance to environmental degradation found in fossil fuel combustion atmospheres. Coating/substrate combinations were subjected to thermal cycling to evaluate the effect of HVOF parameters, coating thickness, substrate material and substrate surface roughness on the resistance to coating delamination and cracking. It was found that substrate surface roughness had a profound influence on the performance of a given substrate/coating system and that surface preparation techniques will need to be tailored to the specific substrate material. Also, higher particle velocity during HVOF thermal spray deposition of the iron aluminide coatings tended to result in better-performing coating/substrate systems with less delamination at the coating/substrate interface. Some combinations of HVOF parameters, coating thickness and substrate materials were found to perform extremely well even at temperatures up to 900oC. However, in some cases, substantial reactions at the interface were observed.

Thomas M. Lillo

2011-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Thermal insulation of window glass  

SciTech Connect

The thermal insulation of window glass can be increased by a factor of two using spray-on semiconductive SnO/sub 2/: Sb or IN/sub 2/O/sub 3/: Sn coatings. (auth)

Sievers, A.J.

1973-11-01T23:59:59.000Z

222

Coating Materials  

Science Conference Proceedings (OSTI)

Table 14 Compositions of unmelted frit batches for high-temperature service silicate-based coatings...Sodium nitrate 5.0 4.0 4.4 . . . 3.8 . . . . . . Fluorspar 4.5 3.2 2.8 . . . 3.0 . . . . . . Tricobalt tetroxide 0.6 . . . 0.4 . . . 0.5 . . . . . . Nickel oxide 0.6 . . . 0.4 . . . 0.6 . . . . . . Manganese dioxide 1.8 . . . 1.1 . . . 1.1 . . . . . . Barium carbonate . . . . . . . . . 26.3 . . . 56.6 56.6...

223

Retractable barrier strip  

DOE Patents (OSTI)

A portable barrier strip having retractable tire-puncture spikes for puncturing a vehicle tire. The tire-puncture spikes have an armed position for puncturing a tire and a retracted position for not puncturing a tire. The strip comprises a plurality of barrier blocks having the tire-puncture spikes removably disposed in a shaft that is rotatably disposed in each barrier block. The plurality of barrier blocks hare hingedly interconnected by complementary hinges integrally formed into the side of each barrier block which allow the strip to be rolled for easy storage and retrieval, but which prevent irregular or back bending of the strip. The shafts of adjacent barrier blocks are pivotally interconnected via a double hinged universal joint to accommodate irregularities in a roadway surface and to transmit torsional motion of the shaft from block to block. A single flexshaft cable is connected to the shaft of an end block to allow a user to selectively cause the shafts of a plurality of adjacently connected barrier blocks to rotate the tire-puncture spikes to the armed position for puncturing a vehicle tire, and to the retracted position for not puncturing the tire. The flexshaft is provided with a resiliently biased retracting mechanism, and a release latch for allowing the spikes to be quickly retracted after the intended vehicle tire is punctured.

Marts, Donna J. (Idaho Falls, ID); Barker, Stacey G. (Idaho Falls, ID); Wowczuk, Andrew (Wheeling, WV); Vellenoweth, Thomas E. (Wheeling, WV)

2002-01-01T23:59:59.000Z

224

Ceramic Coatings for Corrosion Resistant Nuclear Waste Container Evaluated in Simulated Ground Water at 90?C  

SciTech Connect

Ceramic materials have been considered as corrosion resistant coatings for nuclear waste containers. Their suitability can be derived from the fully oxidized state for selected metal oxides. Several types of ceramic coatings applied to plain carbon steel substrates by thermal spray techniques have been exposed to 90 C simulated ground water for nearly 6 years. In some cases no apparent macroscopic damage such as coating spallation was observed in coatings. Thermal spray processes examined in this work included plasma spray, High Velocity Oxy Fuel (HVOF), and Detonation Gun. Some thermal spray coatings have demonstrated superior corrosion protection for the plain carbon steel substrate. In particular the HVOF and Detonation Gun thermal spray processes produced coatings with low connected porosity, which limited the growth rate of corrosion products. It was also demonstrated that these coatings resisted spallation of the coating even when an intentional flaw (which allowed for corrosion of the carbon steel substrate underneath the ceramic coating) was placed in the coating. A model for prediction of the corrosion protection provided by ceramic coatings is presented. The model includes the effect of the morphology and amount of the porosity within the thermal spray coating and provides a prediction of the exposure time needed to produce a crack in the ceramic coating.

Haslam, J J; Farmer, J C

2004-03-31T23:59:59.000Z

225

Corrosion resistant coating  

DOE Patents (OSTI)

A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

Wrobleski, D.A.; Benicewicz, B.C.; Thompson, K.G.; Bryan, C.J.

1997-08-19T23:59:59.000Z

226

Produced Conversion Coatings  

Science Conference Proceedings (OSTI)

Chemical conversion coatings are commonly applied to Mg alloys as paint bases and in some cases as stand-alone protection. Traditional conversion coatings ...

227

Thin film gallium arsenide solar cell research. Third quarterly project report, September 1, 1980-November 30, 1980. [Antireflection coating  

DOE Green Energy (OSTI)

The major objective of this contract is to produce gallium arsenide solar cells of 10% conversion efficiency in films of less than 10 micrometers thick which have been deposited by chemical vapor deposition on graphite or tungsten coated graphite substrates. Major efforts during this quarter were directed to: (1) the optimization of the deposition of gallium arsenide films of 10 ..mu..m thickness or less on tungsten/graphic substrates, (2) the investigation of the effectiveness of various grain boundary passivation techniques, (3) the deposition of tantalum pentoxide by ion beam sputtering as an antireflection coating, (4) the deposition of gallium aluminium arsenide by the organometallic process, and (5) the fabrication and characterization of large area Schottky barrier type solar cells from gallium arsenide films of about 10 ..mu..m thickness. Various grain boundary passivation techniques, such as the anodic oxidation, thermal oxidation, and ruthenium treatment, have been investigated. The combination of thermal oxidation and ruthenium treatment has been used to fabricate Schottky barrier type solar cells. Large area MOS solar cells of 9 cm/sup 2/ area with AMl efficiency of 8.5% have been fabricated from ruthenium treated gallium arsenide films of 10 ..mu..m thickness. The construction of the apparatus for the deposition of gallium aluminum arsenide by the organometallic process has been completed. The deposition of good quality tantalum pentoxide film as an antireflection coating has been carried out by the ion beam sputtering technique. The short-circuit current density and AMl efficiency of the solar cells are increased by approximately 60%, with a slight increase in the open-circuit voltage. Details are presented. (WHK)

Chu, S. S.

1980-12-01T23:59:59.000Z

228

Mercury Oxidation via Catalytic Barrier Filters Phase II  

SciTech Connect

In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

2007-09-30T23:59:59.000Z

229

Paint Coatings  

Science Conference Proceedings (OSTI)

Table 4   Test requirements and time to failure of various coatings...20â??30 0.8â??1.2 150 200â??500 Light zinc phosphate+lacquer paint 23â??28 0.9â??1.1 120 150â??250 Dry film lubrication, air cured 8â??13 0.3â??0.5 â?¦ 50â??100 Heavy zinc phosphate+dry film lubrication, baked 12â??25 0.5â??1.0 100 500â??1000 CARC topcoat 46â??56 1.8â??2.2 â?¦ 25â??50 Light zinc phosphate+CARC primer+topcoat 76â??127 3â??5...

230

Retractable barrier strip  

Science Conference Proceedings (OSTI)

A portable barrier strip having retractable tire-puncture means for puncturing a vehicle tire. The tire-puncture means, such as spikes, have an armed position for puncturing a tire and a retracted position for not puncturing a tire. The strip comprises a plurality of barrier blocks having the tire-puncture means removably disposed in a shaft that is rotatably disposed in each barrier block. The shaft removably and pivotally interconnects the plurality of barrier blocks. Actuation cables cause the shaft to rotate the tire-puncture means to the armed position for puncturing a vehicle tire and to the retracted position for not puncturing the tire. Each tire-puncture means is received in a hollow-bed portion of its respective barrier block when in the retracted position. The barrier strip rests stable in its deployed position and substantially motionless as a tire rolls thereon and over. The strip is rolled up for retrieval, portability, and storage purposes, and extended and unrolled in its deployed position for use.

Marts, Donna J. (Idaho Falls, ID); Barker, Stacey G. (Idaho Falls, ID); McQueen, Miles A. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

231

Retractable barrier strip  

DOE Patents (OSTI)

A portable barrier strip is described having retractable tire-puncture means for puncturing a vehicle tire. The tire-puncture means, such as spikes, have an armed position for puncturing a tire and a retracted position for not puncturing a tire. The strip comprises a plurality of barrier blocks having the tire-puncture means removably disposed in a shaft that is rotatably disposed in each barrier block. The shaft removably and pivotally interconnects the plurality of barrier blocks. Actuation cables cause the shaft to rotate the tire-puncture means to the armed position for puncturing a vehicle tire and to the retracted position for not puncturing the tire. Each tire-puncture means is received in a hollow-bed portion of its respective barrier block when in the retracted position. The barrier strip rests in its deployed position and substantially motionless as a tire rolls thereon and over. The strip is rolled up for retrieval, portability, and storage purposes, and extended and unrolled in its deployed position for use. 13 figs.

Marts, D.J.; Barker, S.G.; McQueen, M.A.

1996-04-16T23:59:59.000Z

232

Photovoltaic-thermal collectors  

DOE Patents (OSTI)

A photovoltaic-thermal solar cell including a semiconductor body having antireflective top and bottom surfaces and coated on each said surface with a patterned electrode covering less than 10% of the surface area. A thermal-absorbing surface is spaced apart from the bottom surface of the semiconductor and a heat-exchange fluid is passed between the bottom surface and the heat-absorbing surface.

Cox, III, Charles H. (Carlisle, MA)

1984-04-24T23:59:59.000Z

233

010- High Temperature Mechanical Properties of CVD-SiC Coating ...  

Science Conference Proceedings (OSTI)

... nuclear coated fuel particles is to maintain the strength of the whole particle. .... on Thermal Energy Storage Materials - Tris(Hydroxymethyl)Aminomethane ...

234

Comparison of HVOF Sprayed MCrAlY Coating and Nickel ...  

Science Conference Proceedings (OSTI)

... coatings based on the application requirements and not on substrate physical properties such as thermal expansion rate Esp. within the same class of alloys.

235

Vacuum barrier for excimer lasers  

DOE Patents (OSTI)

A barrier for separating the vacuum area of a diode from the pressurized gas area of an excimer laser. The barrier is a composite material comprising layers of a metal such as copper, along with layers of polyimide, and a matrix of graphite fiber yarns impregnated with epoxy. The barrier is stronger than conventional foil barriers, and allows greater electron throughput. 3 figs.

Shurter, R.P.

1992-09-15T23:59:59.000Z

236

Thermal Design of Refractory Lined Pressure Oxidation Autoclaves  

Science Conference Proceedings (OSTI)

... for designing a refractory lining as a thermal barrier in pressure oxidation autoclaves. ... Incorporating Radiant Heat Exchange into Finite Element Models of ...

237

Removing Barriers to Innovations: Related Codes and Standards CSI Team  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Removing Barriers to Innovation Removing Barriers to Innovation Related Codes and Standards CSI Team PAM COLE Pacific Northwest National Laboratory Building America Technical Update Meeting, April 29-30, 2013, Denver, CO PNNL-SA-95120 Background/History Transformation of U.S. housing markets to favor high- performance homes faces significant challenges, from education to technology to infrastructure and cost barriers. Some of the most difficult challenges involve industry codes and standards that may prevent or slow the innovation process. Building America Research has a history of: Successful market innovations and transformation and overcoming codes and standards barriers. Top 3 Existing Innovations C/S Challenges Thermal Bypass Air Barrier Requirements: Building America research teams effectively

238

Superoleophilic Particles and Coatings  

Researchers at ORNL have developed a superoleophilic coating that pins a layer of oil to a specially coated substrate and particularly to the surface of the coating. The pinning action keeps the oil from leeching out of the coating, even when the ...

239

Resistive coating for current conductors in cryogenic applications  

DOE Patents (OSTI)

This invention relates to a resistive or semiconducting coating for use on current conductors in cryogenic applications. This includes copper-clad superconductor wire, copper wire used for stabilizing superconductor magnets, and for hyperconductors. The coating is a film of cuprous sulfide (Cu.sub.2 S) that has been found not to degrade the properties of the conductors. It is very adherent to the respective conductors and satisfies the mechanical, thermal and electrical requirements of coatings for the conductors.

Hirayama, Chikara (Murrysville, PA); Wagner, George R. (Murrysville, PA)

1982-05-18T23:59:59.000Z

240

Method of installing subsurface barrier  

DOE Patents (OSTI)

Systems, components, and methods relating to subterranean containment barriers. Laterally adjacent tubular casings having male interlock structures and multiple female interlock structures defining recesses for receiving a male interlock structure are used to create subterranean barriers for containing and treating buried waste and its effluents. The multiple female interlock structures enable the barriers to be varied around subsurface objects and to form barrier sidewalls. The barrier may be used for treating and monitoring a zone of interest.

Nickelson, Reva A. (Shelley, ID); Richardson, John G. (Idaho Falls, ID); Kostelnik, Kevin M. (Idaho Falls, ID); Sloan, Paul A. (Rigby, ID)

2007-10-09T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Barrier Coatings for U-Mo Microspheres Created Via Low ...  

Science Conference Proceedings (OSTI)

Establishment of a Rotating Electrode System for Production of Uranium Alloy ... Homogenization of Low Enriched Uranium-10 wt. pct Molybdenum Alloy ...

242

Nanostructured Environmental Barrier Coatings for Corrosion Resistance in Recovery Boilers.  

E-Print Network (OSTI)

??Corrosion of components in a recovery boiler is a major problem faced by the pulp and paper industry. The superheater tubes get severely corroded due… (more)

Rao, Shishir

2011-01-01T23:59:59.000Z

243

Environmental Barrier Coatings for CMC - Programmaster.org  

Science Conference Proceedings (OSTI)

Symposium, International Symposium on Ceramic Matrix Composites ... which was later applied on combustor liners of a Solar Turbines' industrial gas turbine ...

244

Passivation coating for flexible substrate mirrors  

DOE Patents (OSTI)

A protective diffusion barrier for metalized mirror structures is provided by a layer of coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate before metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors. Also, the silver or other reflective metal layer on mirrors comprising thin, light-weight, flexible substrates of metal or polymer sheets coated with glassy layers can be protected with silicon nitride according to this invention. 13 figs.

Tracy, C.E.; Benson, D.K.

1988-10-19T23:59:59.000Z

245

Cold Sprayed Aluminum Based Glassy Coatings for Improved ...  

Science Conference Proceedings (OSTI)

The cold sprayed Al-BMG coating revealed a very dense structure with nearly zero ... Effect of Thermal Cycling and Sliding on the Structure of Cu-Nb Nanolaminates ... Based on Oscillatory Voltage Wave Forms for Insulating Film Depositions.

246

Advances in Surface Engineering: Alloyed and Composite Coatings II  

Science Conference Proceedings (OSTI)

Cold Sprayed Aluminum Based Glassy Coatings for Improved Corrosion and Wear ... Effect of Thermal Cycling and Sliding on the Structure of Cu-Nb Nanolaminates ... Based on Oscillatory Voltage Wave Forms for Insulating Film Depositions.

247

Bonding Mechanism of Cold Spray Coating on Magnesium Alloys  

Science Conference Proceedings (OSTI)

Cold Sprayed Aluminum Based Glassy Coatings for Improved Corrosion and Wear ... Effect of Thermal Cycling and Sliding on the Structure of Cu-Nb Nanolaminates ... Based on Oscillatory Voltage Wave Forms for Insulating Film Depositions.

248

SunShot Initiative: High-Performance Nanostructured Coating  

NLE Websites -- All DOE Office Websites (Extended Search)

High-Performance Nanostructured High-Performance Nanostructured Coating to someone by E-mail Share SunShot Initiative: High-Performance Nanostructured Coating on Facebook Tweet about SunShot Initiative: High-Performance Nanostructured Coating on Twitter Bookmark SunShot Initiative: High-Performance Nanostructured Coating on Google Bookmark SunShot Initiative: High-Performance Nanostructured Coating on Delicious Rank SunShot Initiative: High-Performance Nanostructured Coating on Digg Find More places to share SunShot Initiative: High-Performance Nanostructured Coating on AddThis.com... Concentrating Solar Power Systems Components Competitive Awards CSP Research & Development Thermal Storage CSP Recovery Act Baseload CSP SunShot Multidisciplinary University Research Initiative CSP Heat Integration for Baseload Renewable Energy Deployment

249

Barriers to energy conservation  

SciTech Connect

This study provides policy guidance to the FEA in its efforts to break down barriers to the efficient usage of finite energy sources. Such efforts may involve mechanisms to promote the more-efficient usage of current energy sources or to break down the barriers that presently inhibit the introduction of alternative energy sources. The major concern is with the energy used by finished products and not with the energy used in the production process itself. A wide range of such products, including many forms of construction, are dealt with. The primary exceptions are the various kinds of motor vehicles, which have been thoroughly covered both in Congressional hearings and in other studies. A large number of different types of barriers and potential incentives were examined during the study. They range from those that are essentially purely energy-related, such as the absence of adequate technology, to constraints that only unintentionally inhibit efficient energy usage (e.g., the antitrust laws).

1975-11-01T23:59:59.000Z

250

An Insight into a Solid State Coating Process for High Temperature ...  

Science Conference Proceedings (OSTI)

A comparison with the coating produced via thermal spray, cold spray and arc cladding processes ... A Review of Metallic Systems Used in Offshore, Sour Environments: The Effect of ... High-temperature Foam-reinforced Thermal Insulation.

251

Thermal insulated glazing unit  

SciTech Connect

An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas.

Selkowitz, Stephen E. (Piedmont, CA); Arasteh, Dariush K. (Oakland, CA); Hartmann, John L. (Seattle, WA)

1991-01-01T23:59:59.000Z

252

Thermal insulated glazing unit  

DOE Patents (OSTI)

An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas. 2 figs.

Selkowitz, S.E.; Arasteh, D.K.; Hartmann, J.L.

1988-04-05T23:59:59.000Z

253

Apparatus for coating powders  

SciTech Connect

A process and apparatus for coating small particles and fibers. The process involves agitation by vibrating or tumbling the particles or fibers to promote coating uniformly, removing adsorbed gases and static charges from the particles or fibers by an initial plasma cleaning, and coating the particles or fibers with one or more coatings, a first coating being an adhesion coating, and with subsequent coatings being deposited in-situ to prevent contamination at layer interfaces. The first coating is of an adhesion forming element (i.e. W, Zr, Re, Cr, Ti) of a 100-10,000 .ANG. thickness and the second coating or final coating of a multiple (0.1-10 microns) being Cu or Ag, for example for brazing processes, or other desired materials that defines the new surface related properties of the particles. An essential feature of the coating process is the capability to deposit in-situ without interruption to prevent the formation of a contaminated interface that could adversely affect the coating adhesion. The process may include screening of the material to be coated and either continuous or intermittent vibration to prevent agglomeration of the material to be coated.

Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Alford, Craig S. (Tracy, CA); McKernan, Mark A. (Livermore, CA)

2000-01-01T23:59:59.000Z

254

Engineered Barrier System: Physical and Chemical Environment  

Science Conference Proceedings (OSTI)

The conceptual and predictive models documented in this Engineered Barrier System: Physical and Chemical Environment Model report describe the evolution of the physical and chemical conditions within the waste emplacement drifts of the repository. The modeling approaches and model output data will be used in the total system performance assessment (TSPA-LA) to assess the performance of the engineered barrier system and the waste form. These models evaluate the range of potential water compositions within the emplacement drifts, resulting from the interaction of introduced materials and minerals in dust with water seeping into the drifts and with aqueous solutions forming by deliquescence of dust (as influenced by atmospheric conditions), and from thermal-hydrological-chemical (THC) processes in the drift. These models also consider the uncertainty and variability in water chemistry inside the drift and the compositions of introduced materials within the drift. This report develops and documents a set of process- and abstraction-level models that constitute the engineered barrier system: physical and chemical environment model. Where possible, these models use information directly from other process model reports as input, which promotes integration among process models used for total system performance assessment. Specific tasks and activities of modeling the physical and chemical environment are included in the technical work plan ''Technical Work Plan for: In-Drift Geochemistry Modeling'' (BSC 2004 [DIRS 166519]). As described in the technical work plan, the development of this report is coordinated with the development of other engineered barrier system analysis model reports.

P. Dixon

2004-04-26T23:59:59.000Z

255

Plasma Surface Modification of Polymer Backsheets: Origins of Future Interfacial Barrier/Backsheet Failure  

DOE Green Energy (OSTI)

Flexible polymer substrates coated with inorganic oxide moisture barriers are a potential replacement for glass backsheets in thin film PV modules. Silicon oxynitride (SiOxNy) deposited by PECVD on polyethylene terephthalate (PET) represents one potential new backsheet candidate. Barrier deposition runs at NREL have typically included a nitrogen-rich plasma pretreatment prior to actual barrier deposition with the intention of cleaning the PET surface as well as enhancing adhesion of the SiOxNy barrier film to PET; however, test coupons of PET/barrier/EVA/TPE failed after damp heat exposure. PET substrates exposed to plasma conditions similar to those used in pre-treatment were examined by X-ray photoelectron spectroscopy (XPS) to reveal new low molecular weight PET fragments are created which are volatile upon heating and water soluble. Failure analysis of the coupons determined that the moisture barrier is, in fact, transferred to the encapsulant side.

Pankow, J. W.; Glick, S. H.

2005-11-01T23:59:59.000Z

256

Coated graphite articles useful in metallurgical processes and method for making same  

DOE Patents (OSTI)

Graphite articles including crucibles and molds used in metallurgical processes involving the melting and the handling of molten metals and alloys that are reactive with carbon when in a molten state and at process temperatures up to about 2000.degree. C. are provided with a multiple-layer coating for inhibiting carbon diffusion from the graphite into the molten metal or alloys. The coating is provided by a first coating increment of a carbide-forming metal on selected surfaces of the graphite, a second coating increment of a carbide forming metal and a refractory metal oxide, and a third coating increment of a refractory metal oxide. The second coating increment provides thermal shock absorbing characteristics to prevent delamination of the coating during temperature cycling. A wash coat of unstabilized zirconia or titanium nitride can be applied onto the third coating increment to facilitate release of melts from the coating.

Holcombe, Cressie E. (Knoxville, TN); Bird, Eugene L. (Knoxville, TN)

1995-01-01T23:59:59.000Z

257

Geophysical characterization of subsurface barriers  

SciTech Connect

An option for controlling contaminant migration from plumes and buried waste sites is to construct a subsurface barrier of a low-permeability material. The successful application of subsurface barriers requires processes to verify the emplacement and effectiveness of barrier and to monitor the performance of a barrier after emplacement. Non destructive and remote sensing techniques, such as geophysical methods, are possible technologies to address these needs. The changes in mechanical, hydrologic and chemical properties associated with the emplacement of an engineered barrier will affect geophysical properties such a seismic velocity, electrical conductivity, and dielectric constant. Also, the barrier, once emplaced and interacting with the in situ geologic system, may affect the paths along which electrical current flows in the subsurface. These changes in properties and processes facilitate the detection and monitoring of the barrier. The approaches to characterizing and monitoring engineered barriers can be divided between (1) methods that directly image the barrier using the contrasts in physical properties between the barrier and the host soil or rock and (2) methods that reflect flow processes around or through the barrier. For example, seismic methods that delineate the changes in density and stiffness associated with the barrier represents a direct imaging method. Electrical self potential methods and flow probes based on heat flow methods represent techniques that can delineate the flow path or flow processes around and through a barrier.

Borns, D.J.

1995-08-01T23:59:59.000Z

258

Development of spray coated cathodes for RITS-6.  

SciTech Connect

This report documents work conducted in FY13 to conduct a feasibility study on thermal spray coated cathodes to be used in the RITS-6 accelerator in an attempt to improve surface uniformity and repeatability. Currently, the cathodes are coated with colloidal silver by means of painting by hand. It is believed that improving the cathode coating process could simplify experimental setup and improve flash x-ray radiographic performance. This report documents the experimental setup and summarizes the results of our feasibility study. Lastly, it describes the path forward and potential challenges that must be overcome in order to improve the process for creating uniform and repeatable silver coatings for cathodes.

Simpson, Sean; Leckbee, Joshua J.; Miller, Stephen Samuel

2013-09-01T23:59:59.000Z

259

Method of fabricating silicon carbide coatings on graphite surfaces  

DOE Patents (OSTI)

The vacuum plasma spray process produces well-bonded, dense, stress-free coatings for a variety of materials on a wide range of substrates. The process is used in many industries to provide for the excellent wear, corrosion resistance, and high temperature behavior of the fabricated coatings. In this application, silicon metal is deposited on graphite. This invention discloses the optimum processing parameters for as-sprayed coating qualities. The method also discloses the effect of thermal cycling on silicon samples in an inert helium atmosphere at about 1600.degree.C. which transforms the coating to silicon carbide.

Varacalle, Jr., Dominic J. (Idaho Falls, ID); Herman, Herbert (Port Jefferson, NY); Burchell, Timothy D. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

260

Vacuum barrier for excimer lasers  

DOE Patents (OSTI)

This invention is comprised of a barrier for separating the vacuum area of a diode from the pressurized gas area of an excimer laser. The barrier is a composite material comprising layers of a metal such as copper, along with layers of polyimide, and a matrix of graphite fiber yearns impregnated with epoxy. The barrier is stronger than conventional foil barriers, and allows greater electron throughput.

Shurter, R.P.

1990-10-10T23:59:59.000Z

Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Superoleophilic Particles and Coatings  

UT-B ID 201002370 06.2012 Technology Summary Researchers at ORNL have developed a superoleophilic coating that pins a layer of oil to a specially coated substrate and ...

262

Coating Surfaces with Superhydrophobic Powder  

Researchers at ORNL have developed a method of modifying existing coating techniques to include a bonded superhydrophobic outer coating layer. ...

263

Multiphase Nano-Composite Coatings for Achieving Energy Optimization  

SciTech Connect

UES Inc. and ANL teamed in this work to develop novel coating systems for the protection of surfaces from thermal degradation mainly in two applications; Machining and Die casting. These coatings were specifically designed for the purpose by incorporating required material phases and the overall architecture, which led to reduce the energy usage and increase efficiency of the operations. Following the UES/ANL'Â?s feasibility work, the coatings were developed utilizing High power impulse magnetron sputtering (HiPMS) and Large area filtered arc deposition (LAFAD) techniques. Toughness, hardness and oxidation resistance: contrasting qualities have been mixed in the right proportion to attain the suitable material characteristic for the cause. Hafnium diboride (HfB2) based materials provided such a system and its properties were tamed to attain the right combination of toughness and hardness by working on the microstructure and architecture of coatings. An effective interfacing material (graded concentrations of topcoat) was also achieved in this work to provide the required adhesion between the substrate and the coating. Combination of an appropriate bond coat and a functional top coat provided the present thermal degradation resistant coating for cutting tools and die-casting applications. Laboratory level performance tests and industrial level application tests by partner companies (Beta Site Testing) were used for the development of these coatings.

Dr. Jose Nainaparampil

2012-03-26T23:59:59.000Z

264

Spin coating of electrolytes  

DOE Patents (OSTI)

Methods for spin coating electrolytic materials onto substrates are disclosed. More particularly, methods for depositing solid coatings of ion-conducting material onto planar substrates and onto electrodes are disclosed. These spin coating methods are employed to fabricate electrochemical sensors for use in measuring, detecting and quantifying gases and liquids.

Stetter, Joseph R. (Naperville, IL); Maclay, G. Jordan (Maywood, IL)

1989-01-01T23:59:59.000Z

265

PIT Coating Requirements Analysis  

SciTech Connect

This study identifies the applicable requirements for procurement and installation of a coating intended for tank farm valve and pump pit interior surfaces. These requirements are intended to be incorporated into project specification documents and design media. This study also evaluates previously recommended coatings and identifies requirement-compliant coating products.

MINTEER, D.J.

2000-10-20T23:59:59.000Z

266

Breaking Down the Barriers  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Breaking Down the Barriers Breaking Down the Barriers Engaging Agency Legal Resources to be Part of the Solution Daniel Gore US Coast Guard Energy Manager X ESPC ISC Kodiak ESPC/UESC Unit Contract Type Coast Guard Alternatively Financed Project Status Estimated Contract Value (Millions) Under Consideration Initial Proposal Delayed by lack of Contracting Officer or Champion Detailed Design Study Recently Awarded TRACEN Cape May ESPC X TRACEN Petaluma PPA X X ISC San Pedro UESC X X CG Academy ESPC X TRACEN Cape May UESC X Air Station Borenquin ESPC X X Sector New York (3 sites) ESPC X X CG Yard (BAMF) ESPC X E-City ESPC X West Coast - 9 Sites ESPC X Five Essentials for Alt. Financed Project * Site approval * Technical Champion * Contracting Officer * Financial Analyst * Legal Support

267

Underground waste barrier structure  

DOE Patents (OSTI)

Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.

Saha, Anuj J. (Hamburg, NY); Grant, David C. (Gibsonia, PA)

1988-01-01T23:59:59.000Z

268

Enhancing Thermal Conductivity and Reducing Friction  

NLE Websites -- All DOE Office Websites (Extended Search)

Laboratory currently has several projects underway to develop advanced fluids, films, coatings, and Laboratory currently has several projects underway to develop advanced fluids, films, coatings, and processes to improve thermal conductivity and reduce friction. These measures are helping to increase energy efficiency for next-generation transportation applications. Superhard and Slick Coating (SSC) Opportunity: Friction, wear, and lubrication strongly affect the energy efficiency, durability, and environmental compatibility of

269

Barrier breaching device  

DOE Patents (OSTI)

A barrier breaching device that is designed primarily for opening holes in interior walls of buildings uses detonating fuse for explosive force. The fuse acts as the ribs or spokes of an umbrella-like device that may be opened up to form a cone. The cone is placed against the wall so that detonating fuse that rings the base of the device and which is ignited by the spoke-like fuses serves to cut a circular hole in the wall.

Honodel, Charles A. (Tracy, CA)

1985-01-01T23:59:59.000Z

270

Barrier breaching device  

DOE Patents (OSTI)

A barrier breaching device that is designed primarily for opening holes in interior walls of buildings uses detonating fuse for explosive force. The fuse acts as the ribs or spokes of an umbrella-like device that may be opened up to form a cone. The cone is placed against the wall so that detonating fuse that rings the base of the device and which is ignited by the spoke-like fuses serves to cut a circular hole in the wall.

Honodel, C.A.

1983-06-01T23:59:59.000Z

271

Effectiveness of Cool Roof Coatings with Ceramic Particles  

SciTech Connect

Liquid applied coatings promoted as cool roof coatings, including several with ceramic particles, were tested at Oak Ridge National Laboratory (ORNL), Oak Ridge, Tenn., for the purpose of quantifying their thermal performances. Solar reflectance measurements were made for new samples and aged samples using a portable reflectometer (ASTM C1549, Standard Test Method for Determination of Solar Reflectance Near Ambient Temperature Using a Portable Solar Reflectometer) and for new samples using the integrating spheres method (ASTM E903, Standard Test Method for Solar Absorptance, Reflectance, and Transmittance of Materials Using Integrating Spheres). Thermal emittance was measured for the new samples using a portable emissometer (ASTM C1371, Standard Test Method for Determination of Emittance of Materials Near Room 1 Proceedings of the 2011 International Roofing Symposium Temperature Using Portable Emissometers). Thermal conductivity of the coatings was measured using a FOX 304 heat flow meter (ASTM C518, Standard Test Method for Steady-State Thermal Transmission Properties by Means of the Heat Flow Meter Apparatus). The surface properties of the cool roof coatings had higher solar reflectance than the reference black and white material, but there were no significant differences among coatings with and without ceramics. The coatings were applied to EPDM (ethylene propylene diene monomer) membranes and installed on the Roof Thermal Research Apparatus (RTRA), an instrumented facility at ORNL for testing roofs. Roof temperatures and heat flux through the roof were obtained for a year of exposure in east Tennessee. The field tests showed significant reduction in cooling required compared with the black reference roof (~80 percent) and a modest reduction in cooling compared with the white reference roof (~33 percent). The coating material with the highest solar reflectivity (no ceramic particles) demonstrated the best overall thermal performance (combination of reducing the cooling load cost and not incurring a large heating penalty cost) and suggests solar reflectivity is the significant characteristic for selecting cool roof coatings.

Brehob, Ellen G [ORNL; Desjarlais, Andre Omer [ORNL; Atchley, Jerald Allen [ORNL

2011-01-01T23:59:59.000Z

272

Quantification of corrosion resistance of a new-class of criticality control materials: thermal-spray coatings of high-boron iron-based amorphous metals - Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4  

Science Conference Proceedings (OSTI)

An iron-based amorphous metal, Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} (SAM2X5), with very good corrosion resistance was developed. This material was produced as a melt-spun ribbon, as well as gas atomized powder and a thermal-spray coating. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. Earlier studies have shown that ingots and melt-spun ribbons of these materials have good passive film stability in these environments. Thermal spray coatings of these materials have now been produced, and have undergone a variety of corrosion testing, including both atmospheric and long-term immersion testing. The modes and rates of corrosion have been determined in the various environments, and are reported here.

Farmer, J C; Choi, J S; Shaw, C K; Rebak, R; Day, S D; Lian, T; Hailey, P; Payer, J H; Branagan, D J; Aprigliano, L F

2007-03-28T23:59:59.000Z

273

Metal matrix coated fiber composites and the methods of manufacturing such composites  

DOE Patents (OSTI)

A fiber coating which allows ceramic or metal fibers to be wetted by molten metals is disclosed. The coating inhibits degradation of the physical properties caused by chemical reaction between the fiber and the coating itself or between the fiber and the metal matrix. The fiber coating preferably includes at least a wetting layer, and in some applications, a wetting layer and a barrier layer between the fiber and the wetting layer. The wetting layer promotes fiber wetting by the metal matrix. The barrier layer inhibits fiber degradation. The fiber coating permits the fibers to be infiltrated with the metal matrix resulting in composites having unique properties not obtainable in pure materials. 8 figures.

Weeks, J.K. Jr.; Gensse, C.

1993-09-14T23:59:59.000Z

274

Thermal spray applications for power plant components  

Science Conference Proceedings (OSTI)

Power plants usually are located near water and many are in salt water environments. Corrosion occurring in these environments is a problem often solved with thermal spray coatings. The use of thermal spray aluminum and zinc in three power plants for various components is reviewed. Special emphasis is on the cooling tower at the Seabrook, New Hampshire plant. A guide to selection of the coating and process also is given.

Sampson, E.R.

2000-03-01T23:59:59.000Z

275

Recent Approaches and Challenges in Smart Coatings  

Science Conference Proceedings (OSTI)

Self-healing coatings -Self-cleaning and superhydrophobic coatings - Chemical Conversion Coatings - Nano- and Micro-capsules Based Polymer Coatings

276

Tag: coat drive  

NLE Websites -- All DOE Office Websites (Extended Search)

9/all en Warm coats, big thanks 9/all en Warm coats, big thanks http://www.y12.doe.gov/community/warm-coats-big-thanks

Y-12 employees help people face some of the coldest temperatures East Tennessee has seen in a long time.
  • coats-big-thanks" rel="tag" title="Warm coats, big thanks">Read more about Warm coats, big thanks Thu, 09 Jan 2014 19:23:39 +0000 pam

  • 277

    Where radiant barriers really shine  

    Science Conference Proceedings (OSTI)

    Manufactures of radiant barrier materials claim their products significantly cut cooling costs by reducing summertime radiant heat gain through attics and ceilings. A new study confirms that radiant barriers can indeed conserve cooling energy. However, the study`s authors found that radiant barriers are much more effective at reducing energy losses from attic air conditioner duct runs than at directly lowering heat transfer through the attic floor into conditioned living space. Furthermore the study demonstrated that radiant barrier savings can be significant even in a new well-weatherized house and that these saving may justify specifying smaller capacity cooling systems. This article discusses the findings of the study.

    Engel, R.

    1996-07-01T23:59:59.000Z

    278

    Field Guide: Coatings Assessment  

    Science Conference Proceedings (OSTI)

    The Electric Power Research Institute (EPRI) has numerous products to help plant personnel meet the challenges of working with aging systems, structures, and components, but none that comprehensively address protective coatings and linings. This field guide provides a compilation of protective coating and lining information in a form that allows the user to have a ready reference available during condition assessment of the various protective coatings and linings used in the plant.

    2012-05-14T23:59:59.000Z

    279

    Polymeric and Conversion Coatings  

    Science Conference Proceedings (OSTI)

    Oct 19, 2011 ... Ongoing research reveals that the search for appropriate conversion ... of the coated alloy was ~ 250 mV more noble compared to bare alloy.

    280

    COPPER COATED URANIUM ARTICLE  

    DOE Patents (OSTI)

    Various techniques and methods for obtaining coppercoated uranium are given. Specifically disclosed are a group of complex uranium coatings having successive layers of nickel, copper, lead, and tin.

    Gray, A.G.

    1958-10-01T23:59:59.000Z

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    281

    Ocean Barrier Layers’ Effect on Tropical Cyclone Intensification  

    SciTech Connect

    Improving a tropical cyclone's forecast and mitigating its destructive potential requires knowledge of various environmental factors that influence the cyclone's path and intensity. Herein, using a combination of observations and model simulations, we systematically demonstrate that tropical cyclone intensification is significantly affected by salinity-induced barrier layers, which are 'quasi-permanent' features in the upper tropical oceans. When tropical cyclones pass over regions with barrier layers, the increased stratification and stability within the layer reduce storm-induced vertical mixing and sea surface temperature cooling. This causes an increase in enthalpy flux from the ocean to the atmosphere and, consequently, an intensification of tropical cyclones. On average, the tropical cyclone intensification rate is nearly 50% higher over regions with barrier layers, compared to regions without. Our finding, which underscores the importance of observing not only the upper-ocean thermal structure but also the salinity structure in deep tropical barrier layer regions, may be a key to more skillful predictions of tropical cyclone intensities through improved ocean state estimates and simulations of barrier layer processes. As the hydrological cycle responds to global warming, any associated changes in the barrier layer distribution must be considered in projecting future tropical cyclone activity.

    Balaguru, Karthik; Chang, P.; Saravanan, R.; Leung, Lai-Yung R.; Xu, Zhao; Li, M.; Hsieh, J.

    2012-09-04T23:59:59.000Z

    282

    Shockwave Induced Spraying: A New Cost-Effective Solid-State ...  

    Science Conference Proceedings (OSTI)

    Similar to Cold Spray, SISP can produce thick coatings onto a diversity of surfaces ... for corrosion protection, thermal insulation, thermal dissipation, wear resistance, ... Coating Interface of Air-Plasma Sprayed Thermal Barrier Coating Systems.

    283

    Chemical Conversion Coating  

    Science Conference Proceedings (OSTI)

    Table 16   Applications of aluminum using chemical conversion coatings...doors 6063 Acrylic paint (b) Cans 3004 Sanitary lacquer Fencing 6061 None applied Chromate conversion coatings Aircraft fuselage skins 7075 clad with 7072 Zinc chromate primer Electronic chassis 6061-T4 None applied Cast missile bulkhead 356-T6 None applied Screen 5056 clad with 6253 Clear varnish...

    284

    Radiation Control Coatings Installed on Federal Buildings at Tyndall Air Force Base  

    DOE Green Energy (OSTI)

    The technical objectives of this CRADA comprise technology deployment and energy conservation efforts with the radiation control coatings industry and the utility sector. The results of this collaboration include a high-level data reporting, analysis and management system to support the deployment efforts. The technical objectives include successfully install, commission, operate, maintain and document the performance of radiation control coatings on roofs at Tyndall AFB and the Buildings Technology Center at the Oak Ridge National Laboratory; determine the life cycle savings that can be achieved by using radiation control coatings on entire roofs at Tyndall AFB, based on documented installed cost and operating maintenance costs with and without the coatings; determine if any specific improvements are required in the coatings before they can be successfully deployed in the federal sector; determine the most effective way to facilitate the widespread and rapid deployment of radiation control coatings in the federal sector; and clearly define any barriers to deployment.

    Kaba, R.L.; Petrie, T.W.

    1999-03-16T23:59:59.000Z

    285

    LEVELING METAL COATINGS  

    DOE Patents (OSTI)

    A method is described for applying metallic coatings to a cylinder of uranium. An aluminum-silicon coat is applied by a process consisting of first cleaning the article by immersion for 5 minutes in 50% nitric acid at 65 C. The article then is dipped through a flux, prepared by adding 10% sodium fluoride to 90% of a flux comprising 53% potassium chloride, 42% lithium chloride, and 5% sodium chloride at 560 for 2 minutes and then directly into a molten metal bath comprising 99% aluminun and 12% silicon at 620 C for 3 minutes. While the coating is yet molten the article is transferred to a pair of steel rollers and rolled until the coating solidifies. By varying the composition of the flux other metals such as zinc, lead or the like may be coated on uranium in a similar manner.

    Gage, H.A.

    1959-02-10T23:59:59.000Z

    286

    Nanoscale Properties of In-Situ Formed Tribofilms and Thermal Films  

    Science Conference Proceedings (OSTI)

    Thermal films were also deposited on surfaces and the role of additive chemistry on growth kinetics ... Microscale Sliding Contacts on Solid Lubricant Coatings.

    287

    Laser Processing and Hard Coatings  

    Science Conference Proceedings (OSTI)

    Mar 5, 2013 ... Advances in Surface Engineering: Alloyed and Composite Coatings II: Laser Processing and Hard Coatings Sponsored by: TMS Materials ...

    288

    Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders  

    SciTech Connect

    This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

    Asit Biswas Andrew J. Sherman

    2006-09-25T23:59:59.000Z

    289

    A low temperature process of applying high strength metal coatings to a substrate and article produced thereby  

    DOE Patents (OSTI)

    This invention is comprised of a method of applying a dense (about 99% of theoretical density) metal coating to a substrate using a converging/diverging nozzle to nebulize metal into a plume with uniform mass and thermal fluxes and a metal droplet size distribution of about 5--15 microns. Coatings may be deposited on substrates which thermally degrade at temperatures far below the melting point of the metals deposited thereon. Coated articles having strong mechanical bonds are also disclosed.

    Ploger, S.A.; Watson, L.D.

    1990-10-18T23:59:59.000Z

    290

    Organometallic Polymer Coatings for Geothermal-Fluid-Sprayed Air-Cooled Condensers: Preprint  

    DOE Green Energy (OSTI)

    Researchers are developing polymer-based coating systems to reduce scaling and corrosion of air-cooled condensers that use a geothermal fluid spray for heat transfer augmentation. These coating systems act as barriers to corrosion to protect aluminum fins and steel tubing; they are formulated to resist the strong attachment of scale. Field tests have been done to determine the corrosion and scaling issues related to brine spraying and a promising organometallic polymer has been evaluated in salt spray tests.

    Gawlik, K.; Sugama, T.; Jung, D.

    2002-08-01T23:59:59.000Z

    291

    Dry Barrier Mix in Reduction Cell Cathodes  

    Science Conference Proceedings (OSTI)

    Presentation Title, Dry Barrier Mix in Reduction Cell Cathodes ... successfully tested as a replacement for barrier bricks in several reduction cell technology types ...

    292

    Better Buildings Neighborhood Program: Phoenix Overcomes Barriers...  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Phoenix Overcomes Barriers and Energizes Homeowners to Make Upgrades to someone by E-mail Share Better Buildings Neighborhood Program: Phoenix Overcomes Barriers and Energizes...

    293

    Visual and energy performance of switchable windows with antireflection coatings  

    Science Conference Proceedings (OSTI)

    The aim of this project was to investigate how the visual appearance and energy performance of switchable or smart windows can be improved by using antireflective coatings. For this study clear float glass, low-e glass and electrochromic glass were treated with antireflection (AR) coatings. Such a coating considerably increases the transmittance of solar radiation in general and the visible transmittance in particular. For switchable glazing based on absorptive electrochromic layers in their dark state it is necessary to use a low-emissivity coating on the inner pane of a double glazed window in order to reject the absorbed heat. In principle all surfaces can be coated with AR coatings, and it was shown that a thin AR coating on the low-e surface neither influences the thermal emissivity nor the U-value of the glazing. The study showed that the use of AR coatings in switchable glazing significantly increases the light transmittance in the transparent state. It is believed that this is important for a high level of user acceptance of such windows. (author)

    Jonsson, Andreas; Roos, Arne [Department of Engineering Sciences, Uppsala University, P.O. Box 534, SE-751 21 Uppsala (Sweden)

    2010-08-15T23:59:59.000Z

    294

    ORNL Radiant Barrier - ETSD Division  

    NLE Websites -- All DOE Office Websites (Extended Search)

    in Zone 2), radiant barriers could reduce your utility bills by as much as 150 per year using average residential electricity prices. If you're able to participate in one of...

    295

    Influence of Dust on the Emissivity of Radiant Barriers  

    E-Print Network (OSTI)

    A model of the radiant heat transfer in attics containing dusty radiant barriers was developed. The geometrical model was a triangular enclosure in which the temperatures of the enclosing surfaces were known. The dust particles were simulated as areas of diameter equal to the mean diameter of the real dust to be analyzed and an emissivity substantially larger than the emissivity of the radiant barrier. Several shape factors were calculated using shape factor algebra, including a procedure to find the shape factor between a small rectangle and a triangular surface perpendicular to the rectangular plane. The thermal model was developed using the "Net Radiation Method" in which the net heat exchange between the surfaces surrounding the enclosure was found by solving a system of equations that has as many equations as the number of surfaces involved in the calculations. This led to the necessity of solving a very large system of equations in order to account for the dust particles in a representative amount. The solution of the system of equations provided the heat flux for each element of the enclosure. Finally, replacing the radiant barrier and the dust particles for an equivalent surface corresponding to the dusty radiant barrier provided the means to calculate the emissivity of this dusty radiant barrier. The theoretical model was tested to assess its validity. The experimentation was carried out using a reflection emissometer to measure the increase of the emissivity of aluminum radiant barrier when known quantities of dust were artificially applied to it. The experimental results showed good agreement with the theoretical model. A linear relationship between the emissivity and the area of dust coverage was found. The simple relation developed can be used in future research which still has to deal with the determination of the area of dust coverage by using the geometrical model of dust superposition or other statistical model to simulate the random location of random size dust particles over the radiant barrier.

    Noboa, Homero L.

    1991-12-01T23:59:59.000Z

    296

    Electrical insulator assembly with oxygen permeation barrier  

    DOE Patents (OSTI)

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29T23:59:59.000Z

    297

    Electrical insulator assembly with oxygen permeation barrier  

    DOE Patents (OSTI)

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

    Van Der Beck, Roland R. (Lansdale, PA); Bond, James A. (Exton, PA)

    1994-01-01T23:59:59.000Z

    298

    Superhydrophic Coatings - ORNL  

    The result is a coating which causes liquids to “bead up” on the surface of a ... Brian R. D’Urson and John T. Simpson, ... Materials Science UT-Battelle, LLC

    299

    Coating Manufacturing Methods  

    Science Conference Proceedings (OSTI)

    Oct 30, 2013 ... Examples will include energy saving (smart radiators for satellites, low emissivity ... Finally, specific functional applications such as electrical contact and coatings on ... The study is supported by RFBR, research project No.

    300

    Friction surfaced Stellite6 coatings  

    SciTech Connect

    Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material for friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.

    Rao, K. Prasad; Damodaram, R. [Department of Metallurgical and Materials Engineering - Indian Institute of Technology Madras, Chennai 600 036 (India); Rafi, H. Khalid, E-mail: khalidrafi@gmail.com [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai 600 036 (India); Ram, G.D. Janaki [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai 600 036 (India); Reddy, G. Madhusudhan [Metal Joining Group, Defence Metallurgical Research Laboratory (DMRL) Kanchanbagh, Hyderabad 500 058 (India); Nagalakshmi, R. [Welding Research Institute, Bharat Heavy Electricals Limited, Tiruchirappalli 620 014 (India)

    2012-08-15T23:59:59.000Z

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    301

    METAL COATING BATHS  

    DOE Patents (OSTI)

    A method is presented for restoring the effectiveness of bronze coating baths used for hot dip coating of uranium. Such baths, containing a high proportion of copper, lose their ability to wet uranium surfaces after a period of use. The ability of such a bath to wet uranium can be restored by adding a small amount of metallic aluminum to the bath, and skimming the resultant hard alloy from the surface.

    Robinson, J.W.

    1958-08-26T23:59:59.000Z

    302

    Spin coating apparatus  

    DOE Patents (OSTI)

    A spin coating apparatus requires less cleanroom air flow than prior spin coating apparatus to minimize cleanroom contamination. A shaped exhaust duct from the spin coater maintains process quality while requiring reduced cleanroom air flow. The exhaust duct can decrease in cross section as it extends from the wafer, minimizing eddy formation. The exhaust duct can conform to entrainment streamlines to minimize eddy formation and reduce interprocess contamination at minimal cleanroom air flow rates.

    Torczynski, John R. (Albuquerque, NM)

    2000-01-01T23:59:59.000Z

    303

    THERMAL RECOVERY  

    NLE Websites -- All DOE Office Websites (Extended Search)

    THERMAL RECOVERY Thermal recovery comprises the techniques of steamflooding, cyclic steam stimulation, and in situ combustion. In steamflooding, high-temperature steam is injected...

    304

    Commercial oxide paints as coatings for SiGe thermoelectric materials  

    DOE Green Energy (OSTI)

    Silicon-germanium alloys are used as thermoelectric materials for radioisotope thermoelectric generators. One problem is the loss of the alloy by sublimation. In the Unicouple, sublimation was minimized by a Si/sub 3/N/sub 4/ coating. In the Multicouple design the application of Si/sub 3/N/sub 4/ coatings which is done at high temperature is not practical. Suppression of sublimation in the Multicouple design is presently accomplished by applying glass coatings. The difficulties encountered with the glass coatings are associated with the poor adherence of the coatings. In the present study, commercial oxide points (mainly ZrO/sub 2/) which have low thermal expansion coefficients are used as coating materials. No spalling from the surface of the coated sample occurred in 1506 hours at 1080/sup 0/C in vacuum, and sublimation was reduced significantly. Zirconium silicate was observed on the surface by x-ray diffraction.

    Amano, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

    1986-08-25T23:59:59.000Z

    305

    Cooperative Research and Development for Advanced Materials in Advanced Industrial Gas Turbines Final Technical Report  

    SciTech Connect

    Evaluation of the performance of innovative thermal barrier coating systems for applications at high temperatures in advanced industrical gas turbines.

    Ramesh Subramanian

    2006-04-19T23:59:59.000Z

    306

    Plasma Surface Modification of Polymer Backsheets: Origins of Future Interfacial Barrier/Backsheet Failure (Poster)  

    DOE Green Energy (OSTI)

    Flexible polymer substrates coated with inorganic oxide moisture barriers are a potential replacement for glass backsheets in thin-film PV (photovoltaic) modules. Silicon oxynitride (SiO{sub x}N{sub y}) deposited by plasma enhanced chemical vapor deposition (PECVD) on polyethylene terephthalate (PET) represents one potential new backsheet candidate. Barrier deposition runs at NREL have included a nitrogen-rich plasma pretreatment prior to barrier deposition with the intention of cleaning the PET surface and enhancing adhesion of the SiO{sub x}N{sub y} barrier film to PET; however, test coupons of PET/barrier/EVA/TPE failed after damp-heat exposure. (EVA is ethylene vinyl acetate and TPE is Tedlar{reg_sign}-PET-EVA). PET substrates exposed to plasma conditions similar to those used in pretreatment were examined by X-ray photoelectron spectroscopy (XPS) to reveal that new low molecular weight PET fragments were created at the PET surface. These fragments are responsible for barrier/PET interfacial failure and barrier transfer to the EVA encapsulant side following damp heat exposure.

    Pankow, J. W.; Glick, S. H.

    2006-05-01T23:59:59.000Z

    307

    Controlling internal barrier in low loss BaTiO3 supercapacitors  

    E-Print Network (OSTI)

    Supercapacitor behavior has been reported in a number of oxides including reduced BaTiO3 ferroelectric ceramics. These so-called giant properties are however not easily controlled. We show here that the continuous coating of individual BaTiO3 grains by a silica shell in combination with Spark Plasma Sintering is a way to process bulk composites having supercapacitor features with low dielectric losses and temperature stability. The silica shell acts both as an oxidation barrier during the processing and as a dielectric barrier in the final composite. 1 Commercial supercapacitors are using polycrystalline materials in which metallic grains or foils (like tantalum) with extended specific surface are covered by their respective oxides (like tantalum oxide). The resulting barrier layers locate electronic and ionic space charges, increasing the capacitance density. While such barrier layer supercapacitors are of everyday use, 1,2 an improved control of the interfaces barrier in such advanced materials would lead to increased functionalities: higher charge storage ability, lower losses and increased cut-off frequency. We show here that individual coating of ferroelectric BaTiO3 grains by a silica shell followed by a fast sintering in reducing conditions leads to such stable

    U-c. Chung; C. Elissalde; S. Mornet; M. Maglione; C. Estournès

    2009-01-01T23:59:59.000Z

    308

    SunShot Initiative: Lowering Barriers  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Lowering Barriers to someone by Lowering Barriers to someone by E-mail Share SunShot Initiative: Lowering Barriers on Facebook Tweet about SunShot Initiative: Lowering Barriers on Twitter Bookmark SunShot Initiative: Lowering Barriers on Google Bookmark SunShot Initiative: Lowering Barriers on Delicious Rank SunShot Initiative: Lowering Barriers on Digg Find More places to share SunShot Initiative: Lowering Barriers on AddThis.com... Concentrating Solar Power Photovoltaics Systems Integration Balance of Systems Reducing Non-Hardware Costs Lowering Barriers Fostering Growth Lowering Barriers DOE is working to improve solar market conditions in order to create green jobs and increase the availability of clean, renewable energy for Americans. Efforts to promote favorable policies and encourage easier

    309

    Experimental Study of Non-thermal Plasma Injection System Converting NOx in Simulated Diesel Emissions  

    Science Conference Proceedings (OSTI)

    In order to study the removal effect of non-thermal plasma (NTP) after-treatment system on diesel engine harmful emissions, a dielectric barrier discharge (DBD) plasma reactor is designed, and the NOx removal effect is studied under the conditions of ... Keywords: Non-thermal Plasma(NTP), Dielectric Barrier Discharge(DBD, Diesel Engine, Nox

    Jing Wang; Yixi Cai; Jun Wang; Dongli Ran

    2010-11-01T23:59:59.000Z

    310

    Residual Stress Evolution in Plasma-Sprayed Thermal Barrier ...  

    Science Conference Proceedings (OSTI)

    ... Office of Industrial Technologies, Project Officer, Patricia Hoffman, Advanced Turbine Systems Program, is gratefully acknowledged. Page 4. ...

    2002-02-15T23:59:59.000Z

    311

    HYDROGEN OUTGASSING AND SURFACE PROPERTIES OF TIN COATED STAINLESS STEEL CHAMBERS.  

    DOE Green Energy (OSTI)

    The stainless steel vacuum chambers of the 248m accumulator ring of Spallation Neutron Source (SNS) are coated with {approx} 100 nm of titanium nitride (TiN) to reduce the secondary electron yield. The coating is produced by DC magnetron sputtering using a long cathode imbedded with permanent magnets. The outgassing rates of several SNS half-cell chambers were measured with and without TiN coating, and before and after in-situ bake. One potential benefit of a TiN coating is to serve as hydrogen permeation barrier that reduces the ultimate outgassing rate. By varying the coating parameters, films of different surface roughness were produced and analyzed by Auger electron spectroscopy, scanning electron microscopy and atomic force microscopy to illustrate the dependence of the outgassing on the film structure.

    HE,P.; HSEUH,H.C.; MAPES,M.; TODD,R.; WEISS,D.; WILSON,D.

    2002-11-11T23:59:59.000Z

    312

    Levelized cost of coating (LCOC) for selective absorber materials.  

    SciTech Connect

    A new metric has been developed to evaluate and compare selective absorber coatings for concentrating solar power applications. Previous metrics have typically considered the performance of the selective coating (i.e., solar absorptance and thermal emittance), but cost and durability were not considered. This report describes the development of the levelized cost of coating (LCOC), which is similar to the levelized cost of energy (LCOE) commonly used to evaluate alternative energy technologies. The LCOC is defined as the ratio of the annualized cost of the coating (and associated costs such as labor and number of heliostats required) to the average annual thermal energy produced by the receiver. The baseline LCOC using Pyromark 2500 paint was found to be %240.055/MWht, and the distribution of LCOC values relative to this baseline were determined in a probabilistic analysis to range from -%241.6/MWht to %247.3/MWht, accounting for the cost of additional (or fewer) heliostats required to yield the same baseline average annual thermal energy produced by the receiver. A stepwise multiple rank regression analysis showed that the initial solar absorptance was the most significant parameter impacting the LCOC, followed by thermal emittance, degradation rate, reapplication interval, and downtime during reapplication.

    Ho, Clifford Kuofei; Pacheco, James Edward

    2013-09-01T23:59:59.000Z

    313

    Effect of Thermal Aging on SCC, Material Properties and Fracture ...  

    Science Conference Proceedings (OSTI)

    A Microstructural Investigation on the Effect of Cold Work on Environmentally Assisted ... Relaxation of Cold Worked 316 and Solution Annealed 304L Stainless Steels in Thermal and .... Protective Insulated Coating for SCC Mitigation in BWRs.

    314

    METHOD OF PROTECTIVELY COATING URANIUM  

    DOE Patents (OSTI)

    A method is described for protectively coating uranium with zine comprising cleaning the U for coating by pickling in concentrated HNO/sub 3/, dipping the cleaned U into a bath of molten zinc between 430 to 600 C and containing less than 0 01% each of Fe and Pb, and withdrawing and cooling to solidify the coating. The zinccoated uranium may be given a; econd coating with another metal niore resistant to the corrosive influences particularly concerned. A coating of Pb containing small proportions of Ag or Sn, or Al containing small proportions of Si may be applied over the zinc coatings by dipping in molten baths of these metals.

    Eubank, L.D.; Boller, E.R.

    1959-02-01T23:59:59.000Z

    315

    Oxidation-resistant interfacial coatings for fiber-reinforced ceramic composites  

    DOE Patents (OSTI)

    A ceramic-matrix composite having a multilayered interfacial coating adapted to protect the reinforcing fibers from long-term oxidation, while allowing these to bridge the wake of advancing cracks in the matrix, is provided by selectively mismatching materials within adjacent layers of the interfacial coating, the materials having different coefficients of thermal expansion so that a low toughness interface region is created to promote crack deflection either within an interior layer of the mismatched interfacial coating or between adjacent layers of the mismatched interfacial coating.

    Lara-Curzio, Edgar; More, Karren L.; Lee, Woo Y.

    1999-04-22T23:59:59.000Z

    316

    Fiber coating method  

    DOE Patents (OSTI)

    A coating is applied to reinforcing fibers arranged into a tow by coaxially aligning the tow with an adjacent separation layer and winding or wrapping the tow and separation layer onto a support structure in an interleaved manner so that the separation layer separates a wrap of the tow from an adjacent wrap of the tow. A coating can then be uniformly applied to the reinforcing fibers without defects caused by fiber tow to fiber tow contact. The separation layer can be a carbon fiber veil.

    Corman, Gregory Scot (Ballston Lake, NY)

    2001-01-01T23:59:59.000Z

    317

    Fiber coating method  

    DOE Patents (OSTI)

    A coating is applied to reinforcing fibers arranged into a tow by coaxially aligning the tow with an adjacent separation layer and winding or wrapping the tow and separation layer onto a support structure in an interleaved manner so that the separation layer separates a wrap of the tow from an adjacent wrap of the tow. A coating can then be uniformly applied to the reinforcing fibers without defects caused by fiber tow to fiber tow contact. The separation layer can be a carbon fiber veil.

    Corman, Gregory Scot (Ballston Lake, NY)

    2003-04-15T23:59:59.000Z

    318

    Nontoxic foul-release coatings  

    SciTech Connect

    The Electric Power Research Institute (EPRI) under project RP-1689-9 evaluated 30 non-toxic coatings for biofouling control on steel and concrete surfaces of cooling water intakes and piping. Seven coatings were evaluated at seven sites for 2 year. The remaining 23 coatings were exposed for a variety of time lengths at the Battelle Marine Laboratory at Daytona Beach, Florida. Accelerated corrosion tests and inspection of the test panels to determine coating life were also conducted. Results of several utility conducted tests were also solicited. Silicone-based coatings performed the best with predicted lives of 2 to 4 year. Although the non-toxic coatings can be fouled by biogrowth, the rate of fouling is less and the coating can be easily cleaned. A cost-benefit methodology is presented to aid utilities to assess the potential use of non-toxic foul-release coatings at power plant cooling systems. 12 refs., 16 figs., 35 tabs.

    Not Available

    1989-10-01T23:59:59.000Z

    319

    Vented Cavity Radiant Barrier Assembly And Method  

    DOE Patents (OSTI)

    A vented cavity radiant barrier assembly (2) includes a barrier (12), typically a PV module, having inner and outer surfaces (18, 22). A support assembly (14) is secured to the barrier and extends inwardly from the inner surface of the barrier to a building surface (14) creating a vented cavity (24) between the building surface and the barrier inner surface. A low emissivity element (20) is mounted at or between the building surface and the barrier inner surface. At least part of the cavity exit (30) is higher than the cavity entrance (28) to promote cooling air flow through the cavity.

    Dinwoodie, Thomas L. (Piedmont, CA); Jackaway, Adam D. (Berkeley, CA)

    2000-05-16T23:59:59.000Z

    320

    Phase-change radiative thermal diode  

    E-Print Network (OSTI)

    A thermal diode transports heat mainly in one preferential direction rather than in the opposite direction. This behavior is generally due to the non-linear dependence of certain physical properties with respect to the temperature. Here we introduce a radiative thermal diode which rectifies heat transport thanks to the phase transitions of materials. Rectification coefficients greater than 70% and up to 90% are shown, even for small temperature differences. This result could have important applications in the development of futur contactless thermal circuits or in the conception of radiative coatings for thermal management.

    Ben-Abdallah, Philippe

    2013-01-01T23:59:59.000Z

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    321

    Interdiffusion between Zr Diffusion Barrier and U-Mo Alloy  

    Science Conference Proceedings (OSTI)

    U-Mo alloys are being developed as low enrichment uranium fuels under the Reduced Enrichment for Research and Test Reactor (RERTR) program. Significant reactions have been observed between U-Mo fuels and Al or Al alloy matrix. Refractory metal Zr has been proposed as barrier material to reduce the interactions. In order to investigate the compatibility and barrier effects between U-Mo alloy and Zr, solid-to-solid U-10wt.%Mo vs. Zr diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 °C for various times. The microstructures and concentration profiles due to interdiffusion and reactions were examined via scanning electron microscopy and electron probe microanalysis, respectively. Intermetallic phase Mo2Zr was found at the interface and its population increased when annealing temperature decreased. Diffusion paths were also plotted on the U-Mo-Zr ternary phase diagrams with good consistency. The growth rate of interdiffusion zone between U-10wt.%Mo and Zr was also calculated under the assumption of parabolic diffusion, and was determined to be about 103 times lower than the growth rate of diffusional interaction layer found in diffusion couples U-10wt.%Mo vs. Al or Al-Si alloy. Other desirable physical properties of Zr as barrier material, such as neutron adsorption rate, melting point and thermal conductivity are presented as supplementary information to demonstrate the great potential of Zr as the diffusion barrier for U-Mo fuel systems in RERTR.

    K. Huang; Y. Park; Y. H. Sohn

    2012-12-01T23:59:59.000Z

    322

    Analysis of annual energy savings due to radiant barriers  

    Science Conference Proceedings (OSTI)

    Radiant barriers are receiving increasing attention as an energy conservation measure for residential buildings, especially for warmer climates. They are being actively promoted for use in residential attics, sometimes with exaggerated claims about savings in utility bills that will results from their installation. In order to provide consumers with factual information that would assist them in deciding upon an investment in a radiant barrier, the Department of Energy, along with an industry advisory panel, has developed a Radiant Barrier Fact Sheet. A major part of this fact sheet is estimates of energy savings that might be expected from radiant barriers in various climates. This paper presents the details of the methodology underlying the energy savings estimates, and gives a summary of values listed in the Fact Sheet. The energy savings estimates were obtained from calculations using a detailed attic thermal model coupled with DOE-2.1C. A life cycle cost analysis was performed to estimate the present value savings on utility fuel costs. The results show that the fuel cost savings vary significantly with the level of conventional insulation already in the attic and from one climate to another.

    Wilkes, K.E.

    1990-01-01T23:59:59.000Z

    323

    Nanolens Window Coatings for Daylighting  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Nanolens Window Coatings for Nanolens Window Coatings for Daylighting Kyle J. Alvine Pacific Northwest National Laboratory Kyle.alvine@pnnl.gov / (509) - 372 - 4475 April 4 th , 2013 Demonstration of the effect To develop a novel, low-cost window coating to double daylight penetration to offset lighting energy use 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem Statement: PNNL is developing a novel, low-cost window coating to redirect daylight deeper into buildings to significantly offset lighting energy.

    324

    Superhydrophobic Coatings - Energy Innovation Portal  

    Technology Marketing Summary ORNL researchers have developed a variety of materials and processes to produce coatings with superhydrophobic properties ...

    325

    Nanolens Window Coatings for Daylighting  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Nanolens Window Coatings for Nanolens Window Coatings for Daylighting Kyle J. Alvine Pacific Northwest National Laboratory Kyle.alvine@pnnl.gov / (509) - 372 - 4475 April 4 th , 2013 Demonstration of the effect To develop a novel, low-cost window coating to double daylight penetration to offset lighting energy use 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem Statement: PNNL is developing a novel, low-cost window coating to redirect daylight deeper into buildings to significantly offset lighting energy.

    326

    Plastic Schottky barrier solar cells  

    SciTech Connect

    A photovoltaic cell structure is fabricated from an active medium including an undoped, intrinsically p-type organic semiconductor comprising polyacetylene. When a film of such material is in rectifying contact with a magnesium electrode, a Schottky-barrier junction is obtained within the body of the cell structure. Also, a gold overlayer passivates the magnesium layer on the undoped polyacetylene film.

    Waldrop, James R. (Thousand Oaks, CA); Cohen, Marshall J. (Thousand Oaks, CA)

    1984-01-24T23:59:59.000Z

    327

    Simulated Attic Radiant Barrier Performance  

    Science Conference Proceedings (OSTI)

    A recent EPRI evaluation determined that attic radiant barriers installed under roof decks are increasingly effective in reducing cooling energy use as insolation increases and ceiling insulation thickness decreases. A savings worksheet included in this report allows rapid estimation of these energy cost impacts.

    1991-03-29T23:59:59.000Z

    328

    Coating method for graphite  

    DOE Patents (OSTI)

    A method of limiting carbon contamination from graphite ware used in induction melting of uranium alloys is provided. The graphite surface is coated with a suspension of Y/sub 2/O/sub 3/ particles in water containing about 1.5 to 4 percent by weight sodium carboxymethylcellulose.

    Banker, J.G.; Holcombe, C.E. Jr.

    1975-11-06T23:59:59.000Z

    329

    Coatings for gas turbines; Specialized coatings boost, maintain turbine efficiency  

    SciTech Connect

    Airlines have been coating their jet engines for the past 30 years, thereby avoiding corrosion, erosion and wear. More recently, operators of mechanical-drive gas turbines have come to realize the value of coatings as a way to keep down costs. This paper describes specialized coatings technology which has evolved for gas turbines. Coatings have been designed for specific areas and even specific components within the turbine. Because operators must often request these coatings when buying new equipment or at overhaul, a basic understanding of the technology is presented.

    1988-10-01T23:59:59.000Z

    330

    Active cooling-based surface confinement system for thermal soil treatment  

    DOE Patents (OSTI)

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders. 1 fig.

    Aines, R.D.; Newmark, R.L.

    1997-10-28T23:59:59.000Z

    331

    Active cooling-based surface confinement system for thermal soil treatment  

    DOE Patents (OSTI)

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders.

    Aines, Roger D. (Livermore, CA); Newmark, Robin L. (Pleasanton, CA)

    1997-01-01T23:59:59.000Z

    332

    Engineered Infills for Concrete Barriers  

    Science Conference Proceedings (OSTI)

    ... INEEL Idaho National Engineering and Environmental Laboratory ... a 240 MW thermal sodium–cooled, graphite ... for cement based waste forms which ...

    2011-05-20T23:59:59.000Z

    333

    Gamma Survey of a Permeable Reactive Barrier at Monticello, Utah...  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Gamma Survey of a Permeable Reactive Barrier at Monticello, Utah Gamma Survey of a Permeable Reactive Barrier at Monticello, Utah Gamma Survey of a Permeable Reactive Barrier at...

    334

    Coastal Barrier Resources Act | Open Energy Information  

    Open Energy Info (EERE)

    Barrier Resources Act Barrier Resources Act Jump to: navigation, search Statute Name Coastal Barrier Resources Act Year 1982 Url [[File:|160px|link=]] Description References Wikipedia[1] FWS Coastal Barrier Resources Act Webpage[2] The Coastal Barrier Resources Act of the United States was enacted October 18, 1982. The United States Congress passed this Act in order to address the many problems associated with coastal barrier development. CBRA designated various undeveloped coastal barriers, which were illustrated by a set of maps adopted by law, to be included in the John H. Chafee Coastal Barrier Resources System (CBRS). These designated areas were made ineligible for both direct and indirect Federal expenditures and financial assistance, which are believed to encourage development of fragile,

    335

    Electrical Calcium Test for Measuring Barrier Permeability ...  

    Energy Analysis; Energy Storage ... Technology Marketing Summary Moisture or water vapor barriers are important in ... Software techniques for data an ...

    336

    Effects of volatile coatings on the morphology and optical detection of combustion-generated black carbon particles.  

    SciTech Connect

    We have measured time-resolved laser-induced incandescence (LII) from combustion-generated mature soot extracted from a burner and (1) coated with oleic acid or (2) coated with oleic acid and then thermally denuded using a thermodenuder. The soot samples were size selected using a differential mobility analyser and characterized with a scanning mobility particle sizer, centrifugal particle mass analyser, and transmission electron microscope. The results demonstrate a strong influence of coatings particle morphology and on the magnitude and temporal evolution of the LII signal. For coated particles higher laser fluences are required to reach LII signal levels comparable to those of uncoated particles. This effect is predominantly attributable to the additional energy needed to vaporize the coating while heating the particle. LII signals are higher and signal decay rates are significantly slower for thermally denuded particles relative to coated or uncoated particles, particularly at low and intermediate laser fluences.

    Bambha, Ray P.; Dansson, Mark Alex; Schrader, Paul E.; Michelsen, Hope A.

    2013-09-01T23:59:59.000Z

    337

    Heat barrier for use in a nuclear reactor facility  

    DOE Patents (OSTI)

    A thermal barrier for use in a nuclear reactor facility is disclosed herein. Generally, the thermal barrier comprises a flexible, heat-resistant web mounted over the annular space between the reactor vessel and the guard vessel in order to prevent convection currents generated in the nitrogen atmosphere in this space from entering the relatively cooler atmosphere of the reactor cavity which surrounds these vessels. Preferably, the flexible web includes a blanket of heat-insulating material formed from fibers of a refractory material, such as alumina and silica, sandwiched between a heat-resistant, metallic cloth made from stainless steel wire. In use, the web is mounted between the upper edges of the guard vessel and the flange of a sealing ring which surrounds the reactor vessel with a sufficient enough slack to avoid being pulled taut as a result of thermal differential expansion between the two vessels. The flexible web replaces the rigid and relatively complicated structures employed in the prior art for insulating the reactor cavity from the convection currents generated between the reactor vessel and the guard vessel.

    Keegan, Charles P. (South Huntingdon Twp., Westmoreland County, PA)

    1988-01-01T23:59:59.000Z

    338

    NERSC's Hopper Breaks Petaflops Barrier  

    NLE Websites -- All DOE Office Websites (Extended Search)

    NERSC's Hopper Breaks NERSC's Hopper Breaks Petaflops Barrier NERSC's Hopper Breaks Petaflops Barrier Ranks 5th in the World November 14, 2010 Media Contact: Jon Bashor, jbashor@lbl.gov, 510-486-5849 hopper1.jpg NERSC's Cray XE6-Hopper BERKELEY, Calif.-The Department of Energy's National Energy Research Scientific Computing Center (NERSC), already one of the world's leading centers for scientific productivity, is now home to the fifth most powerful supercomputer in the world and the second most powerful in the United States, according to the latest edition of the TOP500 list, the definitive ranking of the world's top computers NERSC's newest supercomputer, a 153,408 processor-core Cray XE6 system, posted a performance of 1.05 petaflops (quadrillions of calculations per second) running the Linpack benchmark. In keeping with NERSC's tradition of

    339

    Mirror thermal noise in laser interferometer gravitational wave detectors operating at room and cryogenic temperature  

    E-Print Network (OSTI)

    Mirror thermal noise is and will remain one of the main limitations to the sensitivity of gravitational wave detectors based on laser interferometers. We report about projected mirror thermal noise due to losses in the mirror coatings and substrates. The evaluation includes all kind of thermal noises presently known. Several of the envisaged substrate and coating materials are considered. The results for mirrors operated at room temperature and at cryogenic temperature are reported.

    Janyce Franc; Nazario Morgado; Raffaele Flaminio; Ronny Nawrodt; Iain Martin; Liam Cunningham; Alan Cumming; Sheila Rowan; James Hough

    2009-12-01T23:59:59.000Z

    340

    Materials - Coatings & Lubricants  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Coatings and Lubricants: Coatings and Lubricants: Super-Hard and Ultra-Low-Friction Films for Friction and Wear Control Ali Erdemir researches nanolubricants. Ali Erdemir researches nanolubricants. The many rolling, rotating and sliding mechanical assemblies in advanced transportation vehicles present friction and wear challenges for automotive engineers. These systems operate under severe conditions-high loads, speeds and temperatures-that currently available materials and lubricants do not tolerate well. Improving the surface friction and wear characteristics of the mechanical system components is an opportunity for engineers, and the use of super-hard, slippery surface films offers promise. Argonne scientists have developed a number of smooth, wear-resistant, low-friction nanocomposite nitride and diamond-like carbon films that have

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    341

    Antithrombogenic Polymer Coating.  

    DOE Patents (OSTI)

    An article having a non-thrombogenic surface and a process for making the article are disclosed. The article is formed by (i) coating a polymeric substrate with a crosslinked chemical combination of a polymer having at least two amino substituted side chains, a crosslinking agent containing at least two crosslinking functional groups which react with amino groups on the polymer, and a linking agent containing a first functional group which reacts with a third functional group of the crosslinking agent, and (ii) contacting the coating on the substrate with an antithrombogenic agent which covalently bonds to a second functional group of the linking agent. In one example embodiment, the polymer is a polyamide having amino substituted alkyl chains on one side of the polyamide backbone, the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl, the linking agent is a polyhydrazide and the antithrombogenic agent is heparin.

    Huang, Zhi Heng (San Ramon, CA); McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

    2003-01-21T23:59:59.000Z

    342

    Removing Barriers to Interdisciplinary Research  

    E-Print Network (OSTI)

    A significant amount of high-impact contemporary scientific research occurs where biology, computer science, engineering and chemistry converge. Although programmes have been put in place to support such work, the complex dynamics of interdisciplinarity are still poorly understood. In this paper we interrogate the nature of interdisciplinary research and how we might measure its "success", identify potential barriers to its implementation, and suggest possible mechanisms for removing these impediments.

    Naomi Jacobs; Martyn Amos

    2010-12-19T23:59:59.000Z

    343

    State Barriers to CHP Development  

    E-Print Network (OSTI)

    Every year, ACEEE collects data on regulatory policies in each state that theoretically serve to promote and discourage combined heat and power (CHP) development. In our annual State Energy Efficiency Scorecard (5), we assess the regulatory environment for CHP in each state and score states based on the favorability of their policies for CHP. As part of an effort to make this Scorecard more robust, ACEEE is conducting research to determine the practical realities of CHP development in each state from the perspective of CHP developers and technical assistance agencies. Preliminary research has shown that while certain regulations-and lack of regulations-can greatly influence the attractiveness or success of a project, there are market barriers outside the realm of policy that deserve a great deal of exploration and attention. Traditional regulatory barriers to CHP, such as interconnection procedures, air emissions regulations, and utility standby rates, do pose challenges for development in many states. However, discussions with CHP developers have revealed that many of these issues are overshadowed by economic and financial barriers, as well as other hidden market hurdles. Among these hurdles are the availability of natural gas at reasonable prices, the spark spread in a given region, the effectiveness of CHP developers, the presence of a devoted CHP champion at a host site, and the availability of financing mechanisms to mitigate the upfront capital burden on new projects. This paper will examine each region of the country and each state to determine specific barriers and outline a state-by-state market overview for CHP.

    Chittum, A.; Kaufman, N.

    2011-01-01T23:59:59.000Z

    344

    Materials characterization of WNxCy, WNx and WCx films for advanced barriers  

    Science Conference Proceedings (OSTI)

    A ternary WN"xC"y system was deposited in a thermal ALD (atomic layer deposition) reactor from ASM at 300^oC in a process sequence using tungsten hexafluoride (WF"6), triethyl borane (TEB) and ammonia (NH"3) as precursors. The WC"x layers were deposited ... Keywords: ALD, Atomic layer deposition, Barrier, WCx, WNx, WNxCy

    H. Volders; Z. Tökei; H. Bender; B. Brijs; R. Caluwaerts; L. Carbonell; T. Conard; C. Drijbooms; A. Franquet; S. Garaud; I. Hoflijk; A. Moussa; F. Sinapi; Y. Travaly; D. Vanhaeren; G. Vereecke; C. Zhao; W. -M. Li; H. Sprey; A. M. Jonas

    2007-11-01T23:59:59.000Z

    345

    Double barrier system for an in situ conversion process  

    DOE Patents (OSTI)

    A barrier system for a subsurface treatment area is described. The barrier system includes a first barrier formed around at least a portion of the subsurface treatment area. The first barrier is configured to inhibit fluid from exiting or entering the subsurface treatment area. A second barrier is formed around at least a portion of the first barrier. A separation space exists between the first barrier and the second barrier.

    McKinzie, Billy John [Houston, TX; Vinegar, Harold J [Bellaire, TX; Cowan, Kenneth Michael [Sugar land, TX; Deeg, Wolfgang Friedrich Johann [Houston, TX; Wong, Sau-Wai [Rijswijk, NL

    2009-05-05T23:59:59.000Z

    346

    Silicon nitride protective coatings for silvered glass mirrors  

    DOE Patents (OSTI)

    A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate prior to metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors.

    Tracy, C.E.; Benson, D.K.

    1984-07-20T23:59:59.000Z

    347

    Solar selective coatings  

    DOE Green Energy (OSTI)

    The definition, fabrication, and specification of solar selective absorber surfaces are discussed. Also, the nature of solar radiation and thermal radiation in relation to selective surfaces is considered. (WHK)

    Mattox, D. M.

    1977-01-01T23:59:59.000Z

    348

    HIGHWAY INFRASTRUCTURE FOCUS AREA NEXT-GENERATION INFRASTRUCTURE MATERIALS VOLUME I - TECHNICAL PROPOSAL & MANAGEMENTENHANCEMENT OF TRANSPORTATION INFRASTRUCTURE WITH IRON-BASED AMORPHOUS-METAL AND CERAMIC COATINGS  

    Science Conference Proceedings (OSTI)

    The infrastructure for transportation in the United States allows for a high level of mobility and freight activity for the current population of 300 million residents, and several million business establishments. According to a Department of Transportation study, more than 230 million motor vehicles, ships, airplanes, and railroads cars were used on 6.4 million kilometers (4 million miles) of highways, railroads, airports, and waterways in 1998. Pipelines and storage tanks were considered to be part of this deteriorating infrastructure. The annual direct cost of corrosion in the infrastructure category was estimated to be approximately $22.6 billion in 1998. There were 583,000 bridges in the United States in 1998. Of this total, 200,000 bridges were steel, 235,000 were conventional reinforced concrete, 108,000 bridges were constructed using pre-stressed concrete, and the balance was made using other materials of construction. Approximately 15 percent of the bridges accounted for at this point in time were structurally deficient, primarily due to corrosion of steel and steel reinforcement. Iron-based amorphous metals, including SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe{sub 48}Mo{sub 14}Cr{sub 15}Y{sub 2}C{sub 15}B{sub 6}) have been developed, and have very good corrosion resistance. These materials have been prepared as a melt-spun ribbons, as well as gas atomized powders and thermal-spray coatings. During electrochemical testing in several environments, including seawater at 90 C, the passive film stabilities of these materials were found to be comparable to that of more expensive high-performance alloys, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates. These materials also performed very well in standard salt fog tests. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. These amorphous alloys appear to maintain their corrosion resistance up to the glass transition temperature. Visionary research is proposed to extend the application of corrosion-resistant iron-based amorphous metal coatings, and variants of these coatings, to protection of the Nation's transportation infrastructure. Specific objectives of the proposed work are: (1) fabrication of appropriate test samples for evaluation of concept; (2) collection of production and test data for coated steel reinforcement bars, enabling systematic comparison of various coating options, based upon performance and economic considerations; and (3) construction and testing of concrete structures with coated steel reinforcement bars, thereby demonstrating the value of amorphous-metal coatings. The benefits of ceramic coatings as thermal barriers will also be addressed.

    Farmer, J C

    2007-12-04T23:59:59.000Z

    349

    Optimization of solar-selective paint coatings. Final report, September 15, 1980-June 15, 1982  

    DOE Green Energy (OSTI)

    The objective of this program was the development of low-cost, high-performance, solar-selective paint coatings for solar flat-plate collector (FPC) use and passive thermal wall application. Thickness-sensitive selective paint (TSSP) coating development was intended to demonstrate large-scale producibility. Thickness-insensitive selective paint (TISP) coating development was intended to develop and optimize the coating for passive solar systems and FPC applications. Low-cost, high-performance TSSP coatings and processes were developed to demonstrate large-scale producibility and meet all program goals. Dip, spray, roll, laminating and gravure processes were investigated and used to produce final samples. High-speed gravure coating was selected as the most promising process for solar foil fabrication. Development and optimization of TISP coatings was not completely successful. A variation in reflective metal pigment was suspected of being the primary problem, although other variables may have contributed. Consistent repeating of optical properties of these coatings achieved on the previous program was not achieved. However, a new method of achieving better control of coating components was conceived and preliminary development initiated. The new concept was described as an engineered pigment approach. The engineered pigment approach uses TSSP-coated metal foil particles instead of uncoated aluminum flakes in a liquid TSSP coating. The approach offers many advantages over the use of uncoated aluminum flakes: control of particle flatness, size, and thickness; control of the optical selectivity of each particle; and control of the liquid TSSP coating surrounding the coated particles.

    McChesney, M.A.; Zimmer, P.B.; Lin, R.J.H.

    1982-06-01T23:59:59.000Z

    350

    Albany, OR * Anchorage, AK * Morgantown, WV * Pittsburgh, PA...  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Unique Low Thermal Conductivity Thermal Barrier Coating (TBC) Architectures-UES Background Gas turbine engines used in integrated gasification combined cycle power plants require...

    351

    CX-010296: Categorical Exclusion Determination | Department of...  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    6: Categorical Exclusion Determination CX-010296: Categorical Exclusion Determination Thermal Barrier Coatings for the LTC Engine - Heat Loss, Combustion, Thermal vs. Catalytic...

    352

    COMBUSTION TURBINE (CT) HOT SECTION COATING LIFE MANAGEMENT  

    Science Conference Proceedings (OSTI)

    The integrity of coatings used in hot section components of combustion turbine is crucial to the reliability of the buckets. This project was initiated in recognition of the need for predicting the life of coatings analytically, and non destructively; correspondingly, three principal tasks were established. Task 1, with the objective of analytically developing stress, strain and temperature distributions in the bucket and thereby predicting thermal fatigue (TMF) damage for various operating conditions; Task 2 with the objective of developing eddy current techniques to measure both TMF damage and general degradation of coatings and, Task 3, with the objective of developing mechanism based algorithms. This report is a record of the progress to date on these 3 key tasks. Two supporting tasks relating to field validation (Task 4) and economic analysis (Task 5) have not yet been initiated.

    R. Viswanathan; K. Krzywosz; S. Cheruvu; E. Wan

    2002-08-09T23:59:59.000Z

    353

    UV Curable Coatings -- Marketing Kit  

    Science Conference Proceedings (OSTI)

    Ultra violet (UV) curable coatings are being successfully applied to electric motors, metal shafts, cell phones, printing, plastic packaging, and wood laminates. Demand is expected to expand to an even greater number of end products as issues related to environmental well-being, finish quality, cost reductions, and manufacturing efficiencies drive this market. This UV Curable Coatings-Marketing Kit is designed to help utility sales and marketing personnel present UV curable coating opportunities to custo...

    2000-07-27T23:59:59.000Z

    354

    Ceramic electrolyte coating and methods  

    SciTech Connect

    Aqueous coating slurries useful in depositing a dense coating of a ceramic electrolyte material (e.g., yttrium-stabilized zirconia) onto a porous substrate of a ceramic electrode material (e.g., lanthanum strontium manganite or nickel/zirconia) and processes for preparing an aqueous suspension of a ceramic electrolyte material and an aqueous spray coating slurry including a ceramic electrolyte material. The invention also includes processes for depositing an aqueous spray coating slurry including a ceramic electrolyte material onto pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.

    Seabaugh, Matthew M. (Columbus, OH); Swartz, Scott L. (Columbus, OH); Dawson, William J. (Dublin, OH); McCormick, Buddy E. (Dublin, OH)

    2007-08-28T23:59:59.000Z

    355

    Experimental studies of tritium barrier concepts for fusion reactors  

    SciTech Connect

    Ongoing experimental studies at ANL aimed at the development of methods to reduce tritium migration in fusion reactor systems currently include (1) work on the development of multilayered metal composites and impurity-coated refractory metals as barriers to tritium permeation in elevated temperature (greater than 300$sup 0$C) structures and (2) investigations of the kinetics of tritium trapping reactions in inert gas purge streams under conditions that emulate fusion reactor environments. Significant results obtained thus far are (1) demonstration of greater than 50-fold reductions in the hydrogen permeability of stainless steel structures by using stainless steel-clad composites containing an intermediate layer of a selected copper alloy and (2) verification that surface-oxide coatings lead to greater than 100-fold reductions in the hydrogen permeability of vanadium, but that severe oxygen penetration and embrittlement of the vanadium occur at temperatures in the range from 300 to 800$sup 0$C and under conditions of extremely low oxygen potential. Other considerations pertaining to the large-scale use of metal composites in fusion reactors are discussed, and progress in efforts to demonstrate the fabricability of metal composites is reviewed. Also presented are results of studies of the efficiencies of (1) CuO and CuO-MnO$sub 2$ beds in converting HT to HTO and (2) magnesium metal beds in converting HTO to HT. (auth)

    Maroni, V.A.; Van Deventer, E.H.; Renner, T.A.; Pelto, R.H.; Wierdak, C.J.

    1975-01-01T23:59:59.000Z

    356

    Systematic Study of Fission Barriers of Excited Superheavy Nuclei  

    E-Print Network (OSTI)

    A systematic study of fission-barrier dependence on excitation energy has been performed using the self-consistent finite-temperature Hartree-Fock+BCS (FT-HF+BCS) formalism with the SkM* Skyrme energy density functional. The calculations have been carried out for even-even superheavy nuclei with Z ranging between 110 and 124. For an accurate description of fission pathways, the effects of triaxial and reflection-asymmetric degrees of freedom have been fully incorporated. Our survey demonstrates that the dependence of isentropic fission barriers on excitation energy changes rapidly with particle number, pointing to the importance of shell effects even at large excitation energies characteristic of compound nuclei. The fastest decrease of fission barriers with excitation energy is predicted for deformed nuclei around N=164 and spherical nuclei around N=184 that are strongly stabilized by ground-state shell effects. For nuclei 240Pu and 256Fm, which exhibit asymmetric spontaneous fission, our calculations predict a transition to symmetric fission at high excitation energies due to the thermal quenching of static reflection asymmetric deformations.

    J. A. Sheikh; W. Nazarewicz; J. C. Pei

    2009-04-24T23:59:59.000Z

    357

    Carbonaceous film coating  

    DOE Patents (OSTI)

    A method of making a carbonaceous film comprising heating tris(1,3,2-benzodiazaborolo)borazine or dodecahydro tris(1,3,2)diazaborine(1,2-a:1'2'-c:1''2''-e)borazine in an inert atmosphere in the presence of a substrate to a temperature at which the borazine compound decomposes, and the decomposition products deposit onto the substrate to form a thin, tenacious, highly reflective conductive coating having a narrow band gap which is susceptible of modification and a relatively low coefficient of friction.

    Maya, L.

    1988-04-27T23:59:59.000Z

    358

    Radiant Barrier Performance during the Heating Season  

    E-Print Network (OSTI)

    Results of winter experiments conducted in Central Texas are presented. The experiments were side-by-side tests using two identical 144 ft2 houses which responded similarly to weather variations prior to any retrofits. Two radiant barrier orientations were tested, horizontal barrier and barrier against the rafters, in vented and non-vented attics. The results compiled in this paper are for attics with R-19 fiberglass insulation. The data showed that radiant barriers were still effective during the winter season. During a typical day radiant barriers prevented approximately 9-17 percent of the indoor heat from escaping into the attic. No significant difference in moisture accumulation was detected in the attic with the radiant barrier.

    Medina, M. A.; O'Neal, D. L.; Turner, W. D.

    1992-05-01T23:59:59.000Z

    359

    A Study of Cooling Time Reduction of Interferometric Cryogenic Gravitational Wave Detectors Using a High-Emissivity Coating  

    E-Print Network (OSTI)

    In interferometric cryogenic gravitational wave detectors, there are plans to cool mirrors and their suspension systems (payloads) in order to reduce thermal noise, that is, one of the fundamental noise sources. Because of the large payload masses (several hundred kg in total) and their thermal isolation, a cooling time of several months is required. Our calculation shows that a high-emissivity coating (e.g. a diamond-like carbon (DLC) coating) can reduce the cooling time effectively by enhancing radiation heat transfer. Here, we have experimentally verified the effect of the DLC coating on the reduction of the cooling time.

    Sakakibara, Y; Suzuki, T; Yamamoto, K; Chen, D; Koike, S; Tokoku, C; Uchiyama, T; Ohashi, M; Kuroda, K

    2013-01-01T23:59:59.000Z

    360

    A Study of Cooling Time Reduction of Interferometric Cryogenic Gravitational Wave Detectors Using a High-Emissivity Coating  

    E-Print Network (OSTI)

    In interferometric cryogenic gravitational wave detectors, there are plans to cool mirrors and their suspension systems (payloads) in order to reduce thermal noise, that is, one of the fundamental noise sources. Because of the large payload masses (several hundred kg in total) and their thermal isolation, a cooling time of several months is required. Our calculation shows that a high-emissivity coating (e.g. a diamond-like carbon (DLC) coating) can reduce the cooling time effectively by enhancing radiation heat transfer. Here, we have experimentally verified the effect of the DLC coating on the reduction of the cooling time.

    Y. Sakakibara; N. Kimura; T. Suzuki; K. Yamamoto; D. Chen; S. Koike; C. Tokoku; T. Uchiyama; M. Ohashi; K. Kuroda

    2013-09-19T23:59:59.000Z

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    361

    Program on Technology Innovation: State of Knowledge Review of Nanostructured Coatings for Boiler Tube Applications  

    Science Conference Proceedings (OSTI)

    Since the adoption of low-NOx emission controls with staged burner systems, severe waterwall corrosion has been experienced in many utility boilers. Protective coatings applied by thermal spray processes have reduced the adverse effects of corrosion to some degree, especially in sub-critical boilers. However, the corrosion intensity observed in super-critical boilers, and foreseen in ultra super-critical units, requires coatings with protective capabilities beyond what has been achievable with convention...

    2007-03-12T23:59:59.000Z

    362

    Performance of composite coatings in a coal-fired boiler environment  

    Science Conference Proceedings (OSTI)

    Four samples of thermal spray coatings, each made from different core wire consumables by twin wire arc spray, were exposed for 18 months in a coal-fired boiler environment. The tests are described and the performance of each coating is evaluated. Results indicated that the four consumable wire alloys showed remarkable resistance to fly ash erosion and corrosion over the period of the test.

    Nava, J.C. [ME Technical Services, Bridgeton, MO (United States)

    2009-09-15T23:59:59.000Z

    363

    The development and testing of emissivity enhancement coatings for thermophotovoltaic (TPV) radiator applications  

    DOE Green Energy (OSTI)

    One requirement of a thermophotovoltaic (TPV) radiator is to efficiently emit photons at high temperatures to TPV cells for conversion to electric power. Because many candidate radiator materials with adequate structural properties display low emissivity, coatings or other surface modifications are required for enhancement of emissivity. Six plasma sprayed coatings and one textured surface demonstrated adequate thermal stability and emittance values of 0.8 or greater. Promising attributes of modified surfaces are identified.

    Cockeram, B.V.; Measures, D.P.; Mueller, A.J.

    1999-03-01T23:59:59.000Z

    364

    NANOSCALE BOEHMITE FILLER FOR CORROSION AND WEAR RESISTANT POLYPHENYLENESULFIDE COATINGS.  

    SciTech Connect

    The authors evaluated the usefulness of nanoscale boehmite crystals as a filler for anti-wear and anti-corrosion polyphenylenesulfide (PPS) coatings exposed to a very harsh, 300 C corrosive geothermal environment. The boehmite fillers dispersed uniformly into the PPS coating, conferring two advanced properties: First, they reduced markedly the rate of blasting wear; second, they increased the PPS's glass transition temperature and thermal decomposition temperature. The wear rate of PPS surfaces was reduced three times when 5wt% boehmite was incorporated into the PPS. During exposure for 15 days at 300 C, the PPS underwent hydrothermal oxidation, leading to the substitution of sulfide linkages by the sulfite linkages. However, such molecular alteration did not significantly diminish the ability of the coating to protect carbon steel against corrosion. In fact, PPS coating filled with boehmite of {le} 5wt% adequately mitigated its corrosion in brine at 300 C. One concern in using this filler was that it absorbs brine. Thus, adding an excess amount of boehmite was detrimental to achieving the maximum protection afforded by the coatings.

    SUGAMA,T.

    2003-06-26T23:59:59.000Z

    365

    Rejuvenating Permeable Reactive Barriers by Chemical Flushing  

    Energy.gov (U.S. Department of Energy (DOE))

    Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

    366

    BIBLIOGRAPHY ON INSTITUTIONAL BARRIERS TO ENERGY CONSERVATION  

    E-Print Network (OSTI)

    Barriers to Solar Heating and Cooling of Buildings. Preparedbuilding standards were proposed (which have since been implemented). Neighborhood planning and solar heating

    York, C.M.

    2011-01-01T23:59:59.000Z

    367

    Testing for the technology barrier: Applets - CECM  

    E-Print Network (OSTI)

    Sep 24, 1998 ... Testing for the technology barrier: Applets. The first stage was to support the creation of a set of focussed resources by a model teacher.

    368

    SunShot Initiative: Lowering Barriers  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Lowering Barriers DOE is working to improve solar market conditions in order to create green jobs and increase the availability of clean, renewable energy for Americans. Efforts to...

    369

    BIBLIOGRAPHY ON INSTITUTIONAL BARRIERS TO ENERGY CONSERVATION  

    E-Print Network (OSTI)

    and tax incentives to promote solar energy; state and localstate government can promote energy conservation and surmount institutional barriers through utilities regulation, land use control, tax incentives,

    York, C.M.

    2011-01-01T23:59:59.000Z

    370

    Development and Testing of High-Temperature Solar Selective Coatings  

    DOE Green Energy (OSTI)

    The Solar Energy Technologies Program is working to reduce the cost of parabolic trough solar power technology. System studies show that increasing the operating temperature of the solar field from 390 to >450 C will result in improved performance and cost reductions. This requires the development of new more-efficient selective coatings that have both high solar absorptance (>0.96) and low thermal emittance (<0.07) and are thermally stable above 450 C, ideally in air. Potential selective coatings were modeled, identified for laboratory prototyping, and manufactured at NREL. Optimization of the samples and high-temperature durability testing will be performed. Development of spectrally selective materials depends on reliable characterization of their optical properties. Protocols for testing the thermal/optical properties of selective coatings were developed and a round-robin experiment was conducted to verify and document the reflectance and high-temperature emittance measurements. The development, performance, and durability of these materials and future work will be described.

    Kennedy, C.; Price, H.

    2005-01-01T23:59:59.000Z

    371

    Thin film ion conducting coating  

    DOE Patents (OSTI)

    Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

    Goldner, Ronald B. (Lexington, MA); Haas, Terry (Sudbury, MA); Wong, Kwok-Keung (Watertown, MA); Seward, George (Arlington, MA)

    1989-01-01T23:59:59.000Z

    372

    Photovoltaic Electrical Contacts and Cell Coatings | Department...  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Photovoltaic Electrical Contacts and Cell Coatings Photovoltaic Electrical Contacts and Cell Coatings August 19, 2013 - 4:12pm Addthis The outermost layers of photovoltaic (PV)...

    373

    Abradable Coatings Increase Gas Turbine Engine Efficiency  

    Science Conference Proceedings (OSTI)

    Oct 11, 2007 ... This brief article covers the uses of abradable coatings, their development and their function. Wear at high speed, effect of tip width and coating ...

    374

    Solar selective absorption coatings - Energy Innovation Portal  

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron ...

    375

    Optimization of light emitting diodes based on bipolar double-barrier resonant-tunneling structures  

    Science Conference Proceedings (OSTI)

    A bipolar double-barrier resonant-tunneling light emitting diode will have maximum emitted light intensity if (1) electrons and holes simultaneously resonant-tunnel into the quantum well, (2) the charge carriers are entirely trapped in the well as the ... Keywords: Poisson equation, Schrodinger equation, automated computer code, bipolar double-barrier RTD structures, charge carriers, chemical compositions, doping profiles, electroluminescence, electroluminescence spectrum profile, electron-hole recombination, electron-hole recombination rate, geometric structures, light emitting diodes, near zero-field condition, optimisation, quantum well, resonant tunnelling diodes, resonant-tunneling LED, semiconductor device models, semiconductor quantum wells, temperature stability, theoretical modeling, thermal stability

    A. Kindlihagen; K. A. Chao; M. Willander; J. Genoe

    1995-11-01T23:59:59.000Z

    376

    Amorphous Coatings Produced by Spray Forming and Thermal ...  

    Science Conference Proceedings (OSTI)

    Corrosion of Mild Steel in Extreme Oil and Gas Environments · Corrosion ... Fluorescent Nanoparticle Tracers for Oil Exploration and Production · Formation of ...

    377

    Cold Sprayed Stainless Steel Coatings for Wear and Thermal ...  

    Science Conference Proceedings (OSTI)

    3D Meso-scale Modelling of Aluminum-alloy Welding Processes for Prediction of ... Frequency Modulation Effect on the Solidification of Alloy 718 Fusion Zone.

    378

    Novel Molten Metal Corrosion Resistance Thermal Sprayed Coatings  

    Science Conference Proceedings (OSTI)

    Synthesis and Characterization of Plasma Polymerized Thin Films Deposited from Benzene and Hexamethyldisiloxane Using (PECVD) Method · Synthesis of ...

    379

    Ceramic composite coatings  

    DOE Patents (OSTI)

    A thin, room-temperature-curing, ceramic composite for coating and patching metal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

    Wicks, G.G.

    1991-12-31T23:59:59.000Z

    380

    Ceramic composite coating  

    DOE Patents (OSTI)

    A thin, room-temperature-curing, ceramic composite for coating and patching metal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

    Wicks, G.G.

    1989-01-05T23:59:59.000Z

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    381

    Ceramic composite coating  

    DOE Patents (OSTI)

    A thin, room-temperature-curing, ceramic composite for coating and patching etal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

    Wicks, George G. (Aiken, SC)

    1997-01-01T23:59:59.000Z

    382

    Ceramic coating system or water oxidation environments  

    DOE Patents (OSTI)

    A process for water oxidation of combustible materials in which during at least a part of the oxidation corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises titanium dioxide coated onto a titanium metal substrate. Such ceramic composites have been found to be highly resistant to environments encountered in the process of supercritical water oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases, and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 700.degree. C. The ceramic composites are also resistant to degradation mechanisms caused by thermal stresses.

    Hong, Glenn T. (Tewksbury, MA)

    1996-01-01T23:59:59.000Z

    383

    Electrical imagining of engineered hydraulic barriers  

    SciTech Connect

    Electrical resistance tomography (ERT) was used to image the full-scale test emplacement of a thin-wall grout barrier installed by high-pressure jetting and a thick-wall polymer barrier installed by low-pressure permeation injection. Both case studies compared images of electrical resistivity before and after barrier installation. Barrier materials were imaged as anomalies which were more electrically conducting than the native sandy soils at the test sites. Although the spatial resolution of the ERT was insufficient to resolve flaws smaller than a reconstruction voxel (50 cm on a side), the images did show the spatial extent of the barrier materials and therefore the general shape of the structures. To verify barrier performance, ERT was also used to monitor a flood test of a thin-wall grout barrier. Electrical resistivity changes were imaged as a saltwater tracer moved through the barrier at locations which were later found to be defects in a wall or the joining of two walls.

    Daily, W.; Ramirez, A.L.

    2000-02-01T23:59:59.000Z

    384

    Progress Toward Developing a Durable High-Temperature Solar Selective Coating (Poster)  

    DOE Green Energy (OSTI)

    Increasing the operating temperature of parabolic trough solar fields from 400 C to >450 C will increase their efficiency and reduce the cost of electricity. Current coatings do not have the stability and performance necessary to move to higher operating temperatures. The objective is to develop new, more efficient selective coatings with both high solar absoprtance ({alpha} > 0.96) and low thermal emittance ({var_epsilon} < 0.07) that are thermally stable above 450 C, ideally in air, with improved durability and manufacturability, and reduced cost.

    Kennedy, C.; Price, H. W.

    2007-03-01T23:59:59.000Z

    385

    Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems  

    Science Conference Proceedings (OSTI)

    Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this period, we analyzed several coated and exposed samples of 409 steel by scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). We report here on findings of this analysis: (1) A SS409 coupon that was coated with multilayered combined nitrides of Ti, Al, and Si showed adherent coatings on the surface; (2) A similarly coated coupon, after exposure to simulated coal gas at 900 C for 300 h, revealed that the coating has cracked during the exposure; (3) An SS409 coupon that was coated with nitrides of Ti and Si with a barrier layer of tungsten in between to improve the adhesion of the coating and to prevent outward diffusion of iron to the surface. (4) A porous coupon was coated with nitrides of Ti and Al and examination of the coupon revealed deposition of Ti at the interior surfaces. A similarly prepared coupon was exposed to simulated coal gas at 370 C for 300 h, and it showed no corrosion.

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Jordi Perez-Mariano; Angel Sanjurjo

    2006-06-30T23:59:59.000Z

    386

    Permeable Reactive Barriers | Department of Energy  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barrier Field Projects Durango, Colorado DOE installed a PRB in October 1995 to treat ground water from a uranium mill tailings disposal site at Durango, Colorado Read more Cañon City, Colorado ESL personnel conduct tests and help evaluate performance at other PRB sites, such as Cotter Corporation's Cañon City site in Colorado. Read more Monticello, Utah Installation of a PRB hydraulically downgradient of the Monticello, Utah, millsite was completed June 30, 1999, as an Interim Remedial Action. Read more A permeable reactive barrier (PRB) is a zone of reactive material placed underground to intercept and react with a contaminant plume in ground water. Typically, PRBs are emplaced by replacing soils with reactive

    387

    Breaking the Fuel Cell Cost Barrier  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Breaking the Fuel Cell Cost Barrier Breaking the Fuel Cell Cost Barrier AMFC Workshop May 8 th , 2011, Arlington, VA Shimshon Gottesfeld, CTO The Fuel Cell Cost Challenge 2 CellEra's goal - achieve price parity with incumbents earlier on in market entry process ! Mainstream Polymer Electrolyte Fuel Cell ( PEM) Cost Barriers 3 Graphite / stainless steel hardware Acidic membrane Platinum based electrodes Cost barriers deeply embedded in core tech materials BOM-based cost barriers - 90% of stack cost Cost volatility - Platinum $500/Oz - $2,500/Oz The possibility of an OH - ion conducting membrane 4 Non-acidic membrane CellEra Took Advantage of this Opportunity A new type of membrane component with potential for strong fuel cell cost cuts was revealed in 2006, but was accompanied by general industry skepticism

    388

    Multi-layer waste containment barrier  

    DOE Patents (OSTI)

    An apparatus for constructing an underground containment barrier for containing an in-situ portion of earth. The apparatus includes an excavating device for simultaneously (i) excavating earthen material from beside the in-situ portion of earth without removing the in-situ portion and thereby forming an open side trench defined by opposing earthen sidewalls, and (ii) excavating earthen material from beneath the in-situ portion of earth without removing the in-situ portion and thereby forming a generally horizontal underground trench beneath the in-situ portion defined by opposing earthen sidewalls. The apparatus further includes a barrier-forming device attached to the excavating device for simultaneously forming a side barrier within the open trench and a generally horizontal, multi-layer barrier within the generally horizontal trench. The multi-layer barrier includes at least a first layer and a second layer.

    Smith, Ann Marie (Pocatello, ID); Gardner, Bradley M. (Idaho Falls, ID); Nickelson, David F. (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    389

    Geomembrane barriers using integral fiber optics to monitor barrier integrity  

    DOE Patents (OSTI)

    This invention provides a geomembrane or geotextile with embedded optical sensors that are used to monitor the status of containment site barriers. Fiber optic strands are used to form the sensors that can detect and monitor conditions at the sites such as breaches, slope creep, subsidence, leachate levels, fires, and types of materials present or leaking from the site. The strands are integral to the membrane or textile materials. The geosythetic membrane is deployed at the site in a fashion similar to carpet laying. Edges of the membrane or textile are joined to form a liner and the ends of the membrane or textile become the connection zones for obtaining signals from the sensors. A connection interface with a control system to generate Optical Time Delay Response or other light signals for transmission to the optic fiber strands or sensors and also to receive reflected signals from the sensors is included in the system. Software to interpret the sensor signals can be used in the geosythetic monitoring system.

    Staller, George E. (Albuquerque, NM); Wemple, Robert P. (Albuquerque, NM)

    1996-01-01T23:59:59.000Z

    390

    Geomembrane barriers using integral fiber optics to monitor barrier integrity  

    DOE Patents (OSTI)

    This invention provides a geomembrane or geotextile with embedded optical sensors that are used to monitor the status of containment site barriers. Fiber optic strands are used to form the sensors that can detect and monitor conditions at the sites such as breaches, slope creep, subsidence, leachate levels, fires, and types of materials present or leaking from the site. The strands are integral to the membrane or textile materials. The geosynthetic membrane is deployed at the site in a fashion similar to carpet laying. Edges of the membrane or textile are joined to form a liner and the ends of the membrane or textile become the connection zones for obtaining signals from the sensors. A connection interface with a control system to generate Optical Time Delay Response or other light signals for transmission to the optic fiber strands or sensors and also to receive reflected signals from the sensors is included in the system. Software to interpret the sensor signals can be used in the geosynthetic monitoring system. 6 figs.

    Staller, G.E.; Wemple, R.P.

    1996-10-22T23:59:59.000Z

    391

    Development of Recycling Compatible Pressure-Sensitive Adhesives and Coatings  

    SciTech Connect

    The objective of this project was the design of new water-based pressure-sensitive adhesive (PSA) products and coatings engineered for enhanced removal during the processing of recycled fiber. Research included the formulation, characterization, and performance measurements of new screenable coatings, testing of modified paper and board substrates and the design of test methods to characterize the inhibition of adhesive and coating fragmentation and relative removal efficiencies of developed formulations. This project was operated under the requirements that included commercially viable approaches be the focus, that findings be published in the open literature and that new strategies could not require changes in the methods and equipment used to produce PSA and PS labels or in the recycling process. The industrial partners benefited through the building of expertise in their company that they would not, and likely could not, have pursued if it had not been for the partnership. Results of research on water-based PSAs clearly identifies which PSA and paper facestock properties govern the fragmentation of the adhesive and provide multiple strategies for making (pressure-sensitive) PS labels for which the PSA is removed at very high efficiencies from recycling operations. The application of these results has led to the identification of several commercial products in Franklin International’s (industrial partner) product line that are recycling compatible. Several new formulations were also designed and are currently being scaled-up. Work on recycling compatible barrier coatings for corrugated containers examined the reinforcement of coatings using a small amount of exfoliated organically modified montmorillonite (OMMT). These OMMT/paraffin wax nanocomposites demonstrated significantly improved mechanical properties. Paraffin waxes containing clay were found to have significantly higher Young’s moduli and yield stress relative to the wax matrix, but the most impressive finding was the impact of the clay on the elongation at break; a nearly 400% increase was observed for a clay concentration of 0.5 wt.%. These coatings also demonstrate a number of other property enhancements, which make them a good candidate for continued research. Another approach explored in this research was the use of structured and self-cleaning surfaces. If the amount of coating utilized can be significantly reduced, the environmental impact is diminished.

    Steven J. Severtson

    2010-02-15T23:59:59.000Z

    392

    SuperhydrophobicCoatings.indd  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Superhydrophobic Coating Superhydrophobic Coating 1 S S S S S S S S S Su u u u u u u u u u u u u u u u u up p p p p p p p p p p p p p p p p p pe e e e e e e e e e e e e e e e e e e e e e e e e e e er r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r rh h h h h h h h h h h h h h h h h h h h h h h h h h hy y y y y y y yd d d d d d d d d dr r r r r r ro o o op p p p ph h h h h h h ho o o o o o o o o ob b b b b bi i i ic c c c C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Co o o o o o o o o o o o o o o o o o o o o o o o o o o o oa a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a at t t t t t t t t t t t t t t t t t t t t t t t t t t t t t t ti i i i i i i i i i i i i i i i i i i i i i i in n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n ng g g g g g g g g g g g g g g g g g g g g g g 1 Superhydrophobic Coating 2 Sandia National Laboratories P.O. Box 5800, MS 1349 Albuquerque, NM 87106 C. Jeffrey Brinker Phone: 505-272-7627 Fax: 505-272-7336 cjbrink@sandia.gov AFFIRMATION: I affi rm that all information submitted as a part of, or supplemental to, this entry is a fair and accurate representation of this

    393

    Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines  

    E-Print Network (OSTI)

    In Search of a Low Barrier Hydrogen Bond in Proton Bridgedand J.A. Gerlt, “The Low Barrier Hydrogen Bond in EnzymaticShow That Low-Barrier Hydrogen Bonds do not Offer a

    Khodagholian, Sevana

    2010-01-01T23:59:59.000Z

    394

    Durability testing of antireflection coatings for solar applications  

    DOE Green Energy (OSTI)

    Antireflection (AR) coatings can be incorporated into highly transmitting glazings that, depending on their cost, performance, and durability of optical properties, can be economically viable in solar collectors, agricultural greenhouses, and PV systems. A number of AR-coated glazings have been prepared under the auspices of the International Energy Agency (IEA) Working Group on Durability of Materials for Solar Thermal Collectors. The AR coatings are of two types, including (1) various sol-gels applied to glass and (2) an embossed treatment of sheet acrylic. Typically, for unweathered glazings, a 4%--5% increase in solar-weighted transmittance has been achieved. For AR-coated glass, reflectance values as low as 0.5%--0.7% at selected wavelengths (680--720 nm) were obtained. To determine the durability of the hemispherical transmittance, several collaborating countries are testing these materials both outdoors and in accelerated weathering chambers. All materials exposed outdoors are affixed to mini-collector boxes to simulate flat-plate collector conditions. Results for candidate AR coatings weathered at geographically disperse outdoor test sites exhibit changes in spectral transmittance primarily in the high visible range (600--700 nm). Accelerated testing at measured levels of simulated solar irradiance and at different constant levels of temperature and relative humidity have been performed in different countries. Parallel testing with different levels of laboratory-controlled relevant stress factors permits the time-dependent performance of these materials to be compared with measured results from in-service outdoor exposure conditions. Coating adhesion and performance loss resulting from dirt and dust retention are also discussed.

    Jorgensen, G.; Brunold, S.; Koehl, M.; Nostell, P.; Roos, A.; Oversloot, H.

    2000-01-05T23:59:59.000Z

    395

    Power Electronics and Thermal Management Breakout Sessions  

    NLE Websites -- All DOE Office Websites (Extended Search)

    POWER ELECTRONICS AND THERMAL POWER ELECTRONICS AND THERMAL MANAGEMENT EV Everywhere Workshop July 24, 2012 Breakout Session #1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the Targets * Performance: Is achievable with these assumptions * Production Cost: $8/KW is achievable for PHEV40 and BEV300, $14/KW is okay for BEV100 * Production Efficiency: 95% system efficiency might be achievable * It is easier to achieve performance than cost targets * Integration of the different functionalities can help with achieving the targets * What is efficiency worth? What price do we place on it? Barriers Interfering with Reaching the Targets * Capacitors and magnetics (materials, performance, temperature, size, frequency, packaging) * Material cost, capacitors and magnetics are the priority

    396

    Composition profiling of solar coating materials. Final report, April 16, 1976-April 15, 1979  

    DOE Green Energy (OSTI)

    Auger electron composition vs. depth and optical analysis revealed that a very inexpensive-to-produce (15 min. 900/sup 0/C heat treatment in air) Cr/sub 2/O/sub 3/ layer on stainless steels provides an excellent diffusion barrier for preventing stainless steel constituents from entering into an IR reflective Mo coating. It was shown that with sputter deposition of Mo at high rate in a clean noble gas plasma, one can obtain Mo coatings of excellent IR reflectance (> 96% between 2.5 and 25 ..mu..m wavelength). The optical properties (..cap alpha.. and epsilon) of various other absorber surfaces such as stacked razor blades, cone or whisker-covered metal surfaces, plasma-sprayed chromic oxide coatings etc. were measured and explored. (MOW)

    Wehner, G.K.

    1979-09-01T23:59:59.000Z

    397

    Corrosion resistant neutron absorbing coatings  

    SciTech Connect

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

    Choi, Jor-Shan (El Cerrito, CA); Farmer, Joseph C. (Tracy, CA); Lee, Chuck K. (Hayward, CA); Walker, Jeffrey (Gaithersburg, MD); Russell, Paige (Las Vegas, NV); Kirkwood, Jon (Saint Leonard, MD); Yang, Nancy (Lafayette, CA); Champagne, Victor (Oxford, PA)

    2012-05-29T23:59:59.000Z

    398

    Electrically conductive polymer concrete coatings  

    DOE Patents (OSTI)

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

    Fontana, J.J.; Elling, D.; Reams, W.

    1990-03-13T23:59:59.000Z

    399

    Electrically conductive polymer concrete coatings  

    DOE Patents (OSTI)

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

    Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

    1990-01-01T23:59:59.000Z

    400

    Electrically conductive polymer concrete coatings  

    DOE Patents (OSTI)

    A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

    Fontana, J.J.; Elling, D.; Reams, W.

    1988-05-26T23:59:59.000Z

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    401

    Market barriers to energy efficiency  

    SciTech Connect

    Discussions of energy policy in an environmentally constrained world often focus on the use of tax instruments to internalize the external effects of energy utilization or achieve specified reductions in energy use in the most cost-effective manner. A substantial literature suggests, however, that significant opportunities exist to reduce energy utilization by implementing technologies that are cost-effective under prevailing economic conditions but that are not fully implemented by existing market institutions. This paper examines the theory of the market for energy-using equipment, showing that problems of imperfect information and transaction costs may bias rational consumers to purchase devices that use more energy than those that would be selected by a well-informed social planner guided by the criterion of economic efficiency. Consumers must base their purchase decisions on observed prices and expectations of postpurchase equipment performance. If it is difficult or costly for individuals to form accurate and precise expectations, the level of energy efficiency achieved by competitive markets will vary from the socially efficient outcome. Such market barriers'' suggest a role for regulatory intervention to improve market performance at prevailing energy prices.

    Howarth, R.B. (Lawrence Berkeley Lab., CA (United States)); Andersson, B. (Stockholm School of Economics (Sweden))

    1992-06-01T23:59:59.000Z

    402

    Market barriers to energy efficiency  

    SciTech Connect

    Discussions of energy policy in an environmentally constrained world often focus on the use of tax instruments to internalize the external effects of energy utilization or achieve specified reductions in energy use in the most cost-effective manner. A substantial literature suggests, however, that significant opportunities exist to reduce energy utilization by implementing technologies that are cost-effective under prevailing economic conditions but that are not fully implemented by existing market institutions. This paper examines the theory of the market for energy-using equipment, showing that problems of imperfect information and transaction costs may bias rational consumers to purchase devices that use more energy than those that would be selected by a well-informed social planner guided by the criterion of economic efficiency. Consumers must base their purchase decisions on observed prices and expectations of postpurchase equipment performance. If it is difficult or costly for individuals to form accurate and precise expectations, the level of energy efficiency achieved by competitive markets will vary from the socially efficient outcome. Such ``market barriers`` suggest a role for regulatory intervention to improve market performance at prevailing energy prices.

    Howarth, R.B. [Lawrence Berkeley Lab., CA (United States); Andersson, B. [Stockholm School of Economics (Sweden)

    1992-06-01T23:59:59.000Z

    403

    Performance Testing of Radiant Barriers  

    E-Print Network (OSTI)

    TVA has conducted a study to determine the effects of radiant barriers (RBI (i.e., material with a low emissivity surface facing an air space), when used with fiberglass, on attic heat transfer during summer and winter. This study employed five small test cells exposed to ambient conditions and having attics with gable and soffit vents. Three different RB configurations were tested and compared to the non-RR configuration. Heat flux transducers determined the heat transfer between the attic and conditioned space. The results showed that all RB con figurations significantly reduced heat gain through the ceiling during the summer. Reductions in heat gain during daylight and peak electric load hours were especially attractive. Roof temperatures for the RB configurations were only slightly higher than for the non-RB case. Heat transfer reductions for the RB configurations in the winter were smaller than those for the summer but were still significant in many, but not all, situations. Savings during night and peak electric load hours were especially attractive.

    Hall, J. A.

    1986-01-01T23:59:59.000Z

    404

    Permanent isolation surface barrier development plan  

    Science Conference Proceedings (OSTI)

    The exhumation and treatment of wastes may not always be the preferred alternative in the remediation of a waste site. In-place disposal alternatives, under certain circumstances, may be the most desirable alternatives to use in the protection of human health and the environment. The implementation of an in-place disposal alternative will likely require some type of protective covering that will provide long-term isolation of the wastes from the accessible environment. Even if the wastes are exhumed and treated, a long-term barrier may still be needed to adequately dispose of the treated wastes or any remaining waste residuals. Currently, no {open_quotes}proven{close_quotes} long-term barrier is available. The Hanford Site Permanent Isolation Surface Barrier Development Program (BDP) was organized to develop the technology needed to provide a long-term surface barrier capability for the Hanford Site. The permanent isolation barrier technology also could be used at other sites. Permanent isolation barriers use engineered layers of natural materials to create an integrated structure with redundant protective features. Drawings of conceptual permanent isolation surface barriers are shown. The natural construction materials (e.g., fine soil, sand, gravel, riprap, asphalt) have been selected to optimize barrier performance and longevity. The objective of current designs is to use natural materials to develop a maintenance-free permanent isolation surface barrier that isolates wastes for a minimum of 1,000 years by limiting water drainage to near-zero amounts; reducing the likelihood of plant, animal, and human intrusion; controlling the exhalation of noxious gases; and minimizing erosion-related problems.

    Wing, N.R.

    1994-01-01T23:59:59.000Z

    405

    Disposal barriers that release contaminants only by molecular diffusion  

    Science Conference Proceedings (OSTI)

    Engineered barriers can slow the movement of pollutants out of land disposal facilities in several ways. If the advective velocity is low, release will be primarily by molecular diffusion. Attenuation processes also work to slow the transport of many contaminants. Barriers that cause pollutants to be released almost entirely by molecular diffusion represent the best barriers achievable. Use of thick barrier materials will maximize the breakthrough time of contaminants that diffuse through the barrier. Thin barriers with exceedingly low permeabilities will not necessarily outperform thicker, more permeable liners. In fact, if diffusion is the dominant mechanism of release, the thicker, more permeable barrier may actually outperform the thinner barrier with lower permeability.

    Daniel, D.E.; Shackelford, C.D.

    1988-01-01T23:59:59.000Z

    406

    Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

    407

    Transport Properties for Triangular Barriers in Graphene  

    E-Print Network (OSTI)

    We theoretically study the electronic transport properties of Dirac fermions through one and double triangular barriers in graphene. Using the transfer matrix method, we determine the transmission, conductance and Fano factor. They are obtained to be various parameters dependent such as well width, barrier height and barrier width. Therefore, different discussions are given and comparison with the previous significant works is done. In particular, it is shown that at Dirac point the Dirac fermions always own a minimum conductance associated with a maximum Fano factor and change their behaviors in an oscillatory way (irregularly periodical tunneling peaks) when the potential of applied voltage is increased.

    Abderrahim El Mouhafid; Ahmed Jellal

    2013-03-03T23:59:59.000Z

    408

    Structurally Integrated Coatings for Wear and Corrosion  

    SciTech Connect

    Wear and corrosion of structures cuts across industries and continues to challenge materials scientists and engineers to develop cost effective solutions. Industries typically seek mature technologies that can be implemented for production with rapid or minimal development and have little appetite for the longer-term materials research and development required to solve complex problems. The collaborative work performed in this project addressed the complexity of this problem in a multi-year program that industries would be reluctant to undertake without government partnership. This effort built upon the prior development of Advanced Abrasion Resistant Materials conduct by Caterpillar Inc. under DOE Cooperative Agreement No. DE-FC26-01NT41054. In this referenced work, coatings were developed that exhibited significant wear life improvements over standard carburized heat treated steel in abrasive wear applications. The technology used in this referenced work, arc lamp fusing of thermal spray coatings, was one of the primary technical paths in this work effort. In addition to extending the capability of the coating technology to address corrosion issues, additional competitive coating technologies were evaluated to insure that the best technology was developed to meet the goals of the program. From this, plasma transferred arc (PTA) welding was selected as the second primary technology that was investigated. Specifically, this project developed improved, cost effective surfacing materials and processes for wear and corrosion resistance in both sliding and abrasive wear applications. Materials with wear and corrosion performance improvements that are 4 to 5 times greater than heat treated steels were developed. The materials developed were based on low cost material systems utilizing ferrous substrates and stainless steel type matrix with hard particulates formed from borides and carbides. Affordability was assessed against other competing hard surfacing or coating techniques, balanced with overall materials performance. State-of-the-art design and simulation capabilities were used to guide materials and process refinement. Caterpillar was the lead of the multi-partner collaborative project. Specific tasks were performed by the partners base on their unique capabilities. The project team was selected to include leaders in the field of material development, processing, modeling, and material characterization. Specifically, industrial members include the suppliers Deloro Stellite and Powder Alloy Corporation., who provided the experimental alloys and who aided in the development of the costs for the alloys, the Missouri University of Science and Technology and Iowa State University, who provided help in the alloy development and material characterization, QuesTek Innovations, a small company specializing the microstructural modeling of materials, and the DOE laboratories, Oak Ridge National Laboratory and National Energy Technology Laboratory (Albany), who provided unique coating process capability and wear characterization testing. The technologies developed in this program are expected to yield energy savings of about 50% over existing technologies, or 110 trillion BTUs per year by 2020 when fully implemented. Primary applications by Caterpillar are to replace the surface of machine components which are currently carburized and heat treated with new cladding materials with double the wear life. The new cladding technologies will consume less energy than carburizing. Thus, nearly 50% energy savings can be expected as a result from elimination of the heat treat process and the reduce wear of the materials. Additionally, when technologies from this project are applied on titanium or other non-ferrous substrates to make lighter weight, more wear resistant, and more efficient structures, significant fuel savings can be realized. With the anticipated drastic reduction in cost for refining titanium-containing ores, the usage of titanium alloys in earthmoving and related machinery is expected to increase multiple folds in the next d

    Beardsley, M. Brad; Sebright, Jason L.

    2008-11-18T23:59:59.000Z

    409

    Thermal Properties  

    Science Conference Proceedings (OSTI)

    Table 12   Thermal conductivities of polymers and other materials...40,000 2.8 Aluminum 24,000 1.7 Steel 5000 0.35 Granite 350 0.02 Crown glass (75 wt% silica) 90 0.006 Source: Ref 4...

    410

    BIBLIOGRAPHY ON INSTITUTIONAL BARRIERS TO ENERGY CONSERVATION  

    E-Print Network (OSTI)

    Neighborhood planning and solar heating and cooling in DavisLegal Barriers to Solar Heating and Cooling of Buildings.the interaction of solar energy heating/cooling/hot water

    York, C.M.

    2011-01-01T23:59:59.000Z

    411

    Surprising attractive potential barriers and repulsive wells  

    E-Print Network (OSTI)

    The fundamental fact is revealed that in the old good quantum mechanics there is possible such unexpected inversion: potential barriers can drag in wave-particles and wells can push them off.

    B. N. Zakhariev

    2008-05-06T23:59:59.000Z

    412

    Fission Barriers of Compound Superheavy Nuclei  

    E-Print Network (OSTI)

    The dependence of fission barriers on the excitation energy of the compound nucleus impacts the survival probability of superheavy nuclei synthesized in heavy-ion fusion reactions. In this work, we investigate the isentropic ...

    Sheikh, J. A.

    413

    Photovoltaic and thermophotovoltaic devices with quantum barriers  

    DOE Patents (OSTI)

    A photovoltaic or thermophotovoltaic device includes a diode formed by p-type material and n-type material joined at a p-n junction and including a depletion region adjacent to said p-n junction, and a quantum barrier disposed near or in the depletion region of the p-n junction so as to decrease device reverse saturation current density while maintaining device short circuit current density. In one embodiment, the quantum barrier is disposed on the n-type material side of the p-n junction and decreases the reverse saturation current density due to electrons while in another, the barrier is disposed on the p-type material side of the p-n junction and decreases the reverse saturation current density due to holes. In another embodiment, both types of quantum barriers are used.

    Wernsman, Bernard R. (Jefferson Hills, PA)

    2007-04-10T23:59:59.000Z

    414

    Economic Evaluation of Insulation/Radiant Barrier Systems for the State of Texas  

    E-Print Network (OSTI)

    This paper presents simulated performance of insulation/radiant barrier systems under different Texas climates. A transient heat and mass transfer model which predicts thermal performance of residential attics (Medina, 1992) was coupled with an "economic" subroutine. Simple payback periods were estimated which were based on current insulation and radiant barrier (RB) prices (materials and installation), and current and forecast electric rates. It was found that when the analyses were based solely on reductions of ceiling heat loads during the summer time, a combination of R-11 with RB was more effective than upgrading the insulation level to R-19. Similarly, adding a radiant barrier to an existing insulation level of R-19 proved more effective than upgrading to R-30. When heat gains to the cold air traveling inside A/C ducts (\\which are usually installed in attic spaces) were considered, all insulation/radiant barrier combinations showed faster payback periods than insulation upgrades, During the winter time, insulation upgrades proved to be more effective than insulation/radiant barrier combinations. The simple payback analyses presented herein include both summer and winter simulations.

    Medina, M. A.; Turner, W. D.; O'Neal, D. L.

    1994-01-01T23:59:59.000Z

    415

    Electron reflection from one-dimensional potential barriers  

    DOE Green Energy (OSTI)

    This report summarizes the relevant experimental evidence for electron reflectivity effects in TEC and describes the analytical effort to better understand electron reflectivity as a function of the potential configuration of the surface layer. The analyses consider rectangular and triangular barrier models with, and without, image potentials. The calculated results are presented and discussed. Details of the solutions are given in Appendices A, B, and C. The computer programs to obtain these results are listed in Appendix D. These analyses demonstrate that cesium-oxygen composites with potential discontinuities around one volt and 20 A thick can be expected to be highly reflective to thermal electrons. Consequently, such composites would be expected to have significant effects on TEC performance.

    Balestra, C.L.; Huffman, F.N.; Yang, C.C.

    1978-09-01T23:59:59.000Z

    416

    Liquid junction schottky barrier solar cell  

    DOE Patents (OSTI)

    A mixture of ceric ions (Ce.sup.+4) and cerous ions (Ce.sup.+3) in an aqueous electrolyte solution forms a Schottky barrier at the interface between an active region of silicon and the electrolyte solution. The barrier height obtained for hydrogenated amorphous silicon using the Ce.sup.+4 /Ce.sup.+3 redox couple is about 1.7 eV.

    Williams, Richard (Princeton, NJ)

    1980-01-01T23:59:59.000Z

    417

    Program on Technology Innovation: Liquid Precursor High-Velocity Oxy-Fuel Spray Process for Making Fine Structured and Highly Bonded Alloy Coatings  

    Science Conference Proceedings (OSTI)

    High velocity oxygen-fuel (HVOF) thermal spray processes are used in applications requiring the highest density and adhesion strength, which is not achievable in most other thermal spray processes. Like other thermal spray processes, however, a normal HVOF process is not able to apply fine powders less than 10m via a conventional powder feeder like other thermal spray processes. The advantages of using smaller nano-sized particles in a HVOF process include uniform coating, uniform microstructure, higher ...

    2007-03-28T23:59:59.000Z

    418

    Sputtering process and apparatus for coating powders  

    SciTech Connect

    A process and apparatus for coating small particles and fibers. The process involves agitation by vibrating or tumbling the particles or fibers to promote coating uniformly, removing adsorbed gases and static charges from the particles or fibers by an initial plasma cleaning, and coating the particles or fibers with one or more coatings, a first coating being an adhesion coating, and with subsequent coatings being deposited in-situ to prevent contamination at layer interfaces. The first coating is of an adhesion forming element (i.e. W, Zr, Re, Cr, Ti) of a 100-10,000 .ANG. thickness and the second coating or final coating of a multiple (0.1-10 microns) being Cu or Ag, for example for brazing processes, or other desired materials that defines the new surface related properties of the particles. An essential feature of the coating process is the capability to deposit in-situ without interruption to prevent the formation of a contaminated interface that could adversely affect the coating adhesion. The process may include screening of the material to be coated and either continuous or intermittent vibration to prevent agglomeration of the material to be coated.

    Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Alford, Craig S. (Tracy, CA); McKernan, Mark A. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    419

    Argonne CNM News: Ultrananocrystalline Diamond-Coated Membranes...  

    NLE Websites -- All DOE Office Websites (Extended Search)

    Ultrananocrystalline Diamond-Coated Membranes Show Promise for Medical Implant Applications SEM image of UNCD coated AAO membrane SEM image of AAO membrane coated with tungsten...

    420

    Wire Making Techniques - HTS Coated Conductors - Fact Sheet ...  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Wire Making Techniques - HTS Coated Conductors - Fact Sheet Wire Making Techniques - HTS Coated Conductors - Fact Sheet Wire Making Techniques - HTS Coated Conductors - Fact Sheet...

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    421

    Advanced Hot Section Materials and Coatings Test Rig  

    DOE Green Energy (OSTI)

    Phase I of the Hyperbaric Advanced Hot Section Materials & Coating Test Rig Program has been successfully completed. Florida Turbine Technologies has designed and planned the implementation of a laboratory rig capable of simulating the hot gas path conditions of coal gas fired industrial gas turbine engines. Potential uses of this rig include investigations into environmental attack of turbine materials and coatings exposed to syngas, erosion, and thermal-mechanical fatigue. The principle activities during Phase 1 of this project included providing several conceptual designs for the test section, evaluating various syngas-fueled rig combustor concepts, comparing the various test section concepts and then selecting a configuration for detail design. Conceptual definition and requirements of auxiliary systems and facilities were also prepared. Implementation planning also progressed, with schedules prepared and future project milestones defined. The results of these tasks continue to show rig feasibility, both technically and economically.

    Dan Davis

    2006-09-30T23:59:59.000Z

    422

    PROCESS OF COATING WITH NICKEL BY THE DECOMPOSITION OF NICKEL CARBONYL  

    DOE Patents (OSTI)

    An improved process is presented for the deposition of nickel coatings by the thermal decomposition of nickel carbonyl vapor. The improvement consists in incorporating a small amount of hydrogen sulfide gas in the nickel carbonyl plating gas. It is postulated that the hydrogen sulfide functions as a catalyst. i

    Hoover, T.B.

    1959-04-01T23:59:59.000Z

    423

    AQUIFER THERMAL ENERGY STORAGE  

    E-Print Network (OSTI)

    aquifers for thermal energy storage. Problems outlined aboveModeling of Thermal Energy Storage in Aquifers," Proceed-ings of Aquifer Thermal Energy Storage Workshop, Lawrence

    Tsang, C.-F.

    2011-01-01T23:59:59.000Z

    424

    AQUIFER THERMAL ENERGY STORAGE  

    E-Print Network (OSTI)

    using aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"Proceed- ings of Aquifer Thermal Energy Storage Workshop,

    Tsang, C.-F.

    2011-01-01T23:59:59.000Z

    425

    COATINGS FOR PROTECTION OF EQUIPMENT FOR BIOCHEMICAL PROCESSING OF GEOTHERMAL RESIDUES: PROGRESS REPORT FY 97  

    DOE Green Energy (OSTI)

    Thermal sprayed ethylene methacrylic acid (EMAA) and ethylene tetrafluoroethylene (ETFE), spray-and-bake ETFE and polyvinylidene fluoride (PVDF) and brushable ceramic-epoxy coatings were evaluated for corrosion protection in a biochemical process to treat geothermal residues. The findings are also relevant to other moderate temperature brine environments where corrosion is a problem. Coupon, Atlas cell, peel strength, cathodic disbondment and abrasion tests were performed in aggressive environments including geothermal sludge, hypersaline brine and sulfur-oxidizing bacteria (Thiobadus ferrooxidans) to determine suitability for protecting storage tanks and reaction vessels. It was found that all of the coatings were resistant to chemical attack and biodegradation at the test temperature of 55 C. The EMAA coatings protected 316L stainless steel from corrosion in coupon tests. However, corrosion of mild steel substrates thermal sprayed with EMAA and ETFE occurred in Atlas cell tests that simulated a lined reactor operating environment and this resulted in decreased adhesive strength. Peel tests to measure residual adhesion revealed that failure mode was dependent on exposure conditions. Long-term tests on the durability of ceramic-epoxy coatings in brine and bacteria are ongoing. Initial indications are that this coating has suitable characteristics. Abrasion tests showed that the ceramic-epoxy had good resistance to the abrasive effects of sludge. Thermal sprayed EMAA coatings also displayed abrasion resistance. Cathodic disbondment tests in brine at room temperature indicated that EMAA coatings are resistant to disbondment at applied potentials of {minus}780 to {minus}1,070 mV SCE for the test conditions and duration. Slight disbondment of one specimen occurred at a potential of {minus}1,500 mV SCE. The EMAA may be suited to use in conjunction with cathodic protection although further long-term, higher temperature testing would be needed.

    ALLAN,M.L.

    1997-11-01T23:59:59.000Z

    426

    Use of coated silicon field emitters as neutralisers for fundamental physics missions in space  

    E-Print Network (OSTI)

    Spacecraft neutralisers are required as part of the ion propulsion system for accurate station keeping in fundamental physics missions. This paper describes the use of thin layers of insulating materials as coatings for the gated silicon field emitter array structure used in a spacecraft neutraliser. These thin coatings are postulated to reduce power consumption and reduce overheating. The power consumption and lifetime of aluminium nitride and amorphous hydrogenated diamond-like carbon coatings have been tested by current-voltage and endurance tests. Diamond-like carbon coatings were promising, performing better in endurance tests than uncoated samples, but further work is required to characterise the coating's physical properties and its effects on field emission. The thermal conductivity of the coating material had little effect on measured sample lifetimes. Aluminium nitride had reduced power consumption compared to diamond-like carbon coated and uncoated samples. A thin (~5 nm) layer of aluminium nitride was found to be optimal, meeting European Space Agency specifications for the neutraliser engineering model.

    K. L. Aplin; B. J. Kent; C. M. Collingwood; L. Wang; R. Stevens; S. E. Huq; A. Malik

    2005-09-05T23:59:59.000Z

    427

    ORGANIZATIONAL, INTERFACE AND FINANCIAL BARRIERS TO THE COMMERCIAL DEVELOPMENT OF COMMUNITY ENERGY SYSTEMS  

    E-Print Network (OSTI)

    Policy Evaluation Criteria. Organizational Barriers to MSW Ener.gy Organizational Barriers to Wind Energy

    Schladale, R.

    2010-01-01T23:59:59.000Z

    428

    ELECTROSTATICALLY ENHANCED BARRIER FILTER COLLECTION  

    SciTech Connect

    This work was performed through the University of North Dakota (UND) Chemical Engineering Department with assistance from UND's Energy & Environmental Research Center. This research was undertaken in response to the U.S. Department of Energy Federal Technology Center Program Solicitation No. DE-PS26-99FT40479, Support of Advanced Coal Research at U.S. Universities and Colleges. Specifically, this research was in support of the UCR Core Program and addressees Topic 1, Improved Hot-Gas Contaminant and Particulate Removal Techniques, introducing an advanced design for particulate removal. Integrated gasification combined cycle (IGCC) offers the potential for very high efficiency and clean electric generation. In IGCC, the product gas from the gasifier needs to be cleaned of particulate matter to avoid erosion and high-temperature corrosion difficulties arising with the turbine blades. Current methods involve cooling the gases to {approx}100 C to condense alkalis and remove sulfur and particulates using conventional scrubber technology. This ''cool'' gas is then directed to a turbine for electric generation. While IGCC has the potential to reach efficiencies of over 50%, the current need to cool the product gas for cleaning prior to firing it in a turbine is keeping IGCC from reaching its full potential. The objective of the current project was to develop a highly reliable particulate collector system that can meet the most stringent turbine requirements and emission standards, can operate at temperatures above 1500 F, is applicable for use with all U.S. coals, is compatible with various sorbent injection schemes for sulfur and alkali control, can be integrated into a variety of configurations for both pressurized gasification and combustion, increases allowable face velocity to reduce filter system capital cost, and is cost-competitive with existing technologies. The collector being developed is a new concept in particulate control called electrostatically enhanced barrier filter collection (EBFC). This concept combines electrostatic precipitation (ESP) with candle filters in a single unit. Similar technology has been recently proven on a commercial scale for atmospheric applications, but needed to be tested at high temperatures and pressures. The synergy obtained by combining the two control technologies into a single system should actually reduce filter system capital and operating costs and make the system more reliable. More specifically, the ESP is expected to significantly reduce candle filter load and also to limit ash reintrainment, allowing for full recovery of baseline pressure drop during backpulsing of the filters.

    John Erjavec; Michael D. Mann; Ryan Z. Knutson; Michael L. Swanson; Michael E. Collings

    2003-06-01T23:59:59.000Z

    429

    An evaluation of the fire barrier system thermo-lag 330-1  

    SciTech Connect

    This report presents the results of three fire endurance tests and one ampacity derating test set of the fire barrier system Thermo-Lag 330-1 Subliming Coating. Each test was performed using cable tray specimens protected by a nominal three-hour fire barrier envelope comprised of two layers of nominal 1/2 inch thick material. The fire barrier systems for two of the three fire endurance test articles and for the ampacity derating test article were installed in accordance with the manufacturer`s installations procedures. The barrier system for the third fire endurance test article was a full reproduction of one of the original manufacturer`s qualification test articles. This final test article included certain installation enhancements not considered typical of current nuclear power plant installations. The primary criteria for fire endurance performance evaluation was based on cable circuit integrity testing. Secondary consideration was also given to the temperature rise limits set forth in the ASTM E119 standard fire barrier test procedure. All three of the fire endurance specimens failed prematurely. Circuit integrity failures for the two fire endurance test articles with procedures-based installations were recorded at approximately 76 and 59 minutes into the exposures for a 6 inch wide and 12 inch wide cable tray respectively. Temperature excursion failures (single point) for these two test articles were noted at approximately 65 and 56 minutes respectively. The first circuit integrity failure for the full reproduction test article was recorded approximately 119 minutes into the exposure, and the first temperature excursion failure for this test article was recorded approximately 110 minutes into the exposure.

    Nowlen, S.P. [Sandia National Labs., Albuquerque, NM (United States). Components and Structures Safety and Reliability; Ross, S. [Science and Engineering Associates, Albuquerque, NM (United States)

    1994-09-01T23:59:59.000Z

    430

    Evaluation of End Mill Coatings  

    SciTech Connect

    Milling tests were run on families of High Speed Steel (HSS) end mills to determine their lives while machining 304 Stainless Steel. The end mills tested were made from M7, M42 and T15-CPM High Speed Steels. The end mills were also evaluated with no coatings as well as with Titanium Nitride (TiN) and Titanium Carbo-Nitride (TiCN) coatings to determine which combination of HSS and coating provided the highest increase in end mill life while increasing the cost of the tool the least. We found end mill made from M42 gave us the largest increase in tool life with the least increase in cost. The results of this study will be used by Cutting Tool Engineering in determining which end mill descriptions will be dropped from our tool catalog.

    L. J. Lazarus; R. L. Hester,

    2005-08-01T23:59:59.000Z

    431

    Dielectric Coatings for IACT Mirrors  

    E-Print Network (OSTI)

    Imaging Atmospheric Cherenkov Telescopes for very-high energy gamma-ray astronomy need mirror with high reflectance roughly in the wavelength between 300 and 550 nm. The current standard reflective layer of such mirrors is aluminum. Being permanently exposed to the environment they show a constant degradation over the years. New and improved dielectric coatings have been developed to enhance their resistance to environmental impact and to extend their possible lifetime. In addition, these customized coatings have an increased reflectance of over 95% and are designed to significantly lower the night-sky background contribution. The development of such coatings for mirrors with areas up to 2 m2 and low application temperatures to suite the composite materials used for the new mirror susbtrates of the Cherenkov Telescope Array (CTA) and the results of extensive durability tests are presented.

    Förster, A; Chadwick, P; Held, M

    2013-01-01T23:59:59.000Z

    432

    Phase II: Performance Evaluation of Permeable Reactive Barriers and  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Phase II: Performance Evaluation of Permeable Reactive Barriers and Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing U. S. Environmental Protection Agency Region 8 Support January 2004 Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing

    433

    Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

    Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

    Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

    434

    DEVELOPMENT OF NIOBIUM DIFFUSION BARRIERS FOR ALUMINUM-CLAD URANIUM ALLOY FUEL ELEMENTS  

    DOE Green Energy (OSTI)

    S>Nickel was used as a diffusion barrier for Al-clad uranium alloy fuel elements, operating at 650 nif- F in organiccooled reactors. Advanced organic-moderated reactor (AOMR) concepts include operating temperatures up to 850 nif- F. Since the interdiffusion of Al --Ni is 150 times faster at 850 nif- F than at 650 nif- F, an alternate diffusion barrier is required. Subsequent studies resuited in the selection of niobium. Several techniques for bonding niobium to the U--10 Mo fuel were investigated. After considerable development effort, electron beam vacuum deposition yielded adherent, nonporous, ductile coatings. Isostatic bonding, at 1050 nif- C and 12,000 psi for 1 hr, also resulted in metallurgically bonded niobium on the major surfaces of U-10 Mo fuel plates. Roll-bonding achieved metallurgically bonded plates on small test specimens, but was never reproduced on full-size plates. Vapor phase deposition, by H/sub 2/ reduction of NbCl/sub 5/, was also partially successful, but not reproducible. Ultrasonic bonding has shown promise in spot welding tests. Plasma-spray coating and electroplating in a fused salt bath were also considered, but not actively evaluated. (auth)

    Briggs, B.N.; Friske, W.H.

    1963-10-31T23:59:59.000Z

    435

    Method of preparing thermal insulation for high temperature microwave sintering operations  

    DOE Patents (OSTI)

    Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering. 1 fig.

    Holcombe, C.E.; Dykes, N.L.; Morrow, M.S.

    1996-07-16T23:59:59.000Z

    436

    Method of preparing thermal insulation for high temperature microwave sintering operations  

    DOE Patents (OSTI)

    Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering.

    Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN); Morrow, Marvin S. (Kingston, TN)

    1996-01-01T23:59:59.000Z

    437

    Thermal insulation for high temperature microwave sintering operations and method thereof  

    DOE Patents (OSTI)

    Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering. 1 fig.

    Holcombe, C.E.; Dykes, N.L.; Morrow, M.S.

    1995-09-12T23:59:59.000Z

    438

    Thermal insulation for high temperature microwave sintering operations and method thereof  

    DOE Patents (OSTI)

    Superior microwave transparent thermal insulations for high temperature microwave sintering operations were prepared. One embodiment of the thermal insulation comprises granules of boron nitride coated with a very thin layer of glassy carbon made by preparing a glassy carbon precursor and blending it with boron nitride powder to form a mixture. The blended mixture is granulated to form a grit which is dried and heated to form the granules of boron nitride coated with a glassy carbon. Alternatively, grains of glassy carbon are coated with boron nitride by blending a mixture of a slurry comprising boron nitride, boric acid binder, and methyl alcohol with glassy carbon grains to form a blended mixture. The blended mixture is dried to form grains of glassy carbon coated with boron nitride. In addition, a physical mixture of boron nitride powder and glassy carbon grains has also been shown to be an excellent thermal insulation material for microwave processing and sintering.

    Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN); Morrow, Marvin S. (Kingston, TN)

    1995-01-01T23:59:59.000Z

    439

    Cathode Coating (IN-09-061)  

    A team of scientists at Argonne National Laboratory has developed a special coating for the cathodes used in lithium batteries. With the coating, batteries charge and discharge more quickly, without a loss in performance.

    440

    Superhydrophobic Metal-Oxide Thin Film Coatings  

    Because of their numerous advantages and applications, considerable efforts have been expended to develop superhydrophobic (water repellant) coatings. However, traditional superhydrophobic coatings are soft in nature, with a Teflon-like surface ...

    Note: This page contains sample records for the topic "thermal barrier coating" from the National Library of EnergyBeta (NLEBeta).
    While these samples are representative of the content of NLEBeta,
    they are not comprehensive nor are they the most current set.
    We encourage you to perform a real-time search of NLEBeta
    to obtain the most current and comprehensive results.


    441

    Coated foams, preparation, uses and articles  

    DOE Patents (OSTI)

    Hydrophobic cellular material is coated with a thin hydrophilic polymer skin which stretches tightly over the foam but which does not fill the cells of the foam, thus resulting in a polymer-coated foam structure having a smoothness which was not possible in the prior art. In particular, when the hydrophobic cellular material is a specially chosen hydrophobic polymer foam and is formed into arbitrarily chosen shapes prior to the coating with hydrophilic polymer, inertial confinement fusion (ICF) targets of arbitrary shapes can be produced by subsequently coating the shapes with metal or with any other suitable material. New articles of manufacture are produced, including improved ICF targets, improved integrated circuits, and improved solar reflectors and solar collectors. In the coating method, the cell size of the hydrophobic cellular material, the viscosity of the polymer solution used to coat, and the surface tension of the polymer solution used to coat are all very important to the coating.

    Duchane, D.V.; Barthell, B.L.

    1982-10-21T23:59:59.000Z

    442

    Near-Surface Engineered Environmental Barrier Integrity  

    SciTech Connect

    The INEEL Environmental Systems Research and Analysis (ESRA) program has launched a new R&D project on Near-Surface Engineered Environmental Barrier Integrity to increase knowledge and capabilities for using engineering and ecological components to improve the integrity of near-surface barriers used to confine contaminants from the public and the environment. The knowledge gained and the capabilities built will help verify the adequacy of past remedial decisions and enable improved solutions for future cleanup decisions. The research is planned to (a) improve the knowledge of degradation mechanisms (weathering, biological, geological, chemical, radiological, and catastrophic) in times shorter than service life, (b) improve modeling of barrier degradation dynamics, (c) develop sensor systems to identify degradation prior to failure, and (d) provide a better basis for developing and testing of new barrier systems to increase reliability and reduce the risk of failure. Our project combines selected exploratory studies (benchtop and field scale), coupled effects accelerated aging testing and the meso-scale, testing of new monitoring concepts, and modeling of dynamic systems. The performance of evapo- transpiration, capillary, and grout-based barriers will be examined.

    Piet, Steven James; Breckenridge, Robert Paul; Beller, John Michael; Geesey, Gill Gregroy; Glenn, David Frankie; Jacobson, Jacob Jordan; Martian, Pete; Matthern, Gretchen Elise; Mattson, Earl Douglas; Porro, Indrek; Southworth, Finis Hio; Steffler, Eric Darwin; Stormberg, Angelica Isabel; Stormberg, Gregory John; Versteeg, Roelof Jan; White, Gregory J

    2002-08-01T23:59:59.000Z

    443

    Near-Surface Engineered Environmental Barrier Integrity  

    SciTech Connect

    The INEEL Environmental Systems Research and Analysis (ESRA) program has launched a new R and D project on Near-Surface Engineered Environmental Barrier Integrity to increase knowledge and capabilities for using engineering and ecological components to improve the integrity of near-surface barriers used to confine contaminants from the public and the environment. The knowledge gained and the capabilities built will help verify the adequacy of past remedial decisions and enable improved solutions for future cleanup decisions. The research is planned to (a) improve the knowledge of degradation mechanisms (weathering, biological, geological, chemical, radiological, and catastrophic) in times shorter than service life, (b) improve modeling of barrier degradation dynamics, (c) develop sensor systems to identify degradation prior to failure, and (d) provide a better basis for developing and testing of new barrier systems to increase reliability and reduce the risk of failure. Our project combine s selected exploratory studies (benchtop and field scale), coupled effects accelerated aging testing and the meso-scale, testing of new monitoring concepts, and modeling of dynamic systems. The performance of evapo-transpiration, capillary, and grout-based barriers will be examined.

    Piet, S.J.; Breckenridge, R.P.

    2002-05-15T23:59:59.000Z

    444

    Enhanced Densification of SDC Barrier Layers  

    DOE Green Energy (OSTI)

    This technical report explores the Enhanced Densification of SCD Barrier Layers A samaria-doped ceria (SDC) barrier layer separates the lanthanum strontium cobalt ferrite (LSCF) cathode from the yttria-stabilized zirconia (YSZ) electrolyte in a solid oxide fuel cell (SOFC) to prevent the formation of electrically resistive interfacial SrZrO{sub 3} layers that arise from the reaction of Sr from the LSCF with Zr from the YSZ. However, the sintering temperature of this SDC layer must be limited to {approx}1200 C to avoid extensive interdiffusion between SDC and YSZ to form a resistive CeO{sub 2}-ZrO{sub 2} solid solution. Therefore, the conventional SDC layer is often porous and therefore not as impervious to Sr-diffusion as would be desired. In the pursuit of improved SOFC performance, efforts have been directed toward increasing the density of the SDC barrier layer without increasing the sintering temperature. The density of the SDC barrier layer can be greatly increased through small amounts of Cu-doping of the SDC powder together with increased solids loading and use of an appropriate binder system in the screen print ink. However, the resulting performance of cells with these barrier layers did not exhibit the expected increase in accordance with that achieved with the prototypical PLD SDC layer. It was determined by XRD that increased sinterability of the SDC also results in increased interdiffusivity between the SDC and YSZ, resulting in formation of a highly resistive solid solution.

    Hardy, John S.; Templeton, Jared W.; Lu, Zigui; Stevenson, Jeffry W.

    2011-09-12T23:59:59.000Z

    445

    IMPROVEMENT OF THERMAL STABILITY OF LI-ION BATTERIES BY  

    E-Print Network (OSTI)

    and Commercial Building End-Use Energy Efficiency · Industrial/Agricultural/Water End-Use Energy EfficiencyIMPROVEMENT OF THERMAL STABILITY OF LI-ION BATTERIES BY POLYMER COATING OF LIMN2O4 Prepared For: California Energy Commission Energy Innovations Small Grant Program Prepared By: Pieter Stroeve, UC Davis

    446

    Environmental Coatings For Gas Turbine Engine Applications  

    Science Conference Proceedings (OSTI)

    Presentation Title, Environmental Coatings For Gas Turbine Engine Applications. Author(s), Ming Fu, Roger Wustman, Jeffrey Williams, Douglas Konitzer.

    447

    Coatings for SOFC Interconnects: Design, Deposition and ...  

    Science Conference Proceedings (OSTI)

    Engineering effective combinations of oxidation resistance, electronic conductivity and SOFC component compatibility has proven challenging for coating ...

    448

    Sputter coating of microspherical substrates by levitation  

    SciTech Connect

    Microspheres are substantially uniformly coated with metals or nonmetals by simultaneously levitating them and sputter coating them at total chamber pressures less than 1 torr. A collimated hole structure 12 comprising a parallel array of upwardly projecting individual gas outlets 16 is machined out to form a dimple 11. Glass microballoons, which are particularly useful in laser fusion applications, can be substantially uniformly coated using the coating method and apparatus.

    Lowe, Arthur T. (Tempe, AZ); Hosford, Charles D. (Los Alamos, NM)

    1981-01-01T23:59:59.000Z

    449

    Method of forming metallic coatings on polymeric substrates and of forming graded polymeric coatings or films  

    DOE Patents (OSTI)

    The invention described herein relates to methods of forming graded polymeric coatings or films on a desired substrate and of forming metallic coatings on polymeric or other nonmetallic substrates. In particular, it relates to methods of forming such coatings or films by sorption and/or diffusion of metals into coatings or films of polymeric material deposited by conventional techniques on a desired substrate.

    Liepins, R.

    1981-03-11T23:59:59.000Z

    450

    Renewable energy in Brazil: opportunities, barriers, and remedies  

    DOE Green Energy (OSTI)

    An overview of the major conclusions is presented according to the goals of the study; and contents of the various chapters of the report are outlined. All major energy planning organizations in Brazil at the federal and state level perceive an urgent need for petroleum substitution by means of energy-efficient technology, coal, hydroelectricity, biomass, solar, and wind. Technologies and applications considered of high priority for US/Brazilian cooperative efforts are the following: Energy-efficient technology, used with indigenous hydroelectricity, especially heat pumps to provide (1) low temperature hot water for industrial applications, and (2) air conditioning and hot water for residential and commercial applications; solar thermal technology for low and intermediate temperature industrial process heat, and for crop drying; and small wind turbines and photovoltaic power systems for irrigation pumping and other rural applications. Certain technologies were excluded from the scope of the study by mutual agreement because a great deal of activity in such technologies was already taking place in Brazil, or because commercialization prospects seemed remote, or because of regulatory barriers. Energy conversion systems employing biomass, small- and large-scale hydropower, ocean thermal energy gradients, and cogeneration systems are not examined.

    Jhirad, D.J.; Rutter, W.

    1982-03-01T23:59:59.000Z

    451

    APPLIEDPHYSICAL Kinetic regulation of coated vesicle secretion  

    E-Print Network (OSTI)

    that competes with the energy- consuming turnover of coat components between the membrane and the cytosol. We vesiculation of secretory membranes is impaired by the energy-consuming desorption of coat proteins, until on the membrane into elementary coat-building units, called monomers. The membrane-bound monomers then polymerize

    Sens, Pierre

    452

    Chemical vapor deposition of mullite coatings  

    DOE Patents (OSTI)

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01T23:59:59.000Z

    453

    Fission Barriers of Compound Superheavy Nuclei  

    E-Print Network (OSTI)

    The dependence of fission barriers on the excitation energy of the compound nucleus impacts the survival probability of superheavy nuclei synthesized in heavy-ion fusion reactions. In this work, we investigate the isentropic fission barriers by means of the self-consistent nuclear density functional theory. The relationship between isothermal and isentropic descriptions is demonstrated. Calculations have been carried out for $^{264}$Fm, $^{272}$Ds, $^{278}$112, $^{292}$114, and $^{312}$124. For nuclei around $^{278}$112 produced in "cold fusion" reactions, we predict a more rapid decrease of fission barriers with excitation energy as compared to the nuclei around $^{292}$114 synthesized in "hot fusion" experiments. This is explained in terms of the difference between the ground-state and saddle-point temperatures. The effect of the particle gas is found to be negligible in the range of temperatures studied.

    J. C. Pei; W. Nazarewicz; J. A. Sheikh; A. K. Kerman

    2009-01-07T23:59:59.000Z

    454

    UNDERWATER COATINGS FOR CONTAMINATION CONTROL  

    SciTech Connect

    The Idaho National Laboratory (INL) deactivated several aging nuclear fuel storage basins. Planners for this effort were greatly concerned that radioactive contamination present on the basin walls could become airborne as the sides of the basins became exposed during deactivation and allowed to dry after water removal. One way to control this airborne contamination was to fix the contamination in place while the pool walls were still submerged. There are many underwater coatings available on the market for marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives were easily applied and adhered well to the substrates (pool wall materials) found in INL fuel pools. Lab-scale experiments were conducted by applying fourteen different commercial underwater coatings to four substrate materials representative of the storage basin construction materials, and evaluating their performance. The coupons included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The evaluation criteria included ease of application, adherence to the four surfaces of interest, no change on water clarity or chemistry, non-hazardous in final applied form and be proven in underwater applications. A proprietary two-part, underwater epoxy owned by S. G. Pinney and Associates was selected from the underwater coatings tested for application to all four pools. Divers scrubbed loose contamination off the basin walls and floors using a ship hull scrubber and vacuumed up the sludge. The divers then applied the coating using a special powered roller with two separate heated hoses that allowed the epoxy to mix at the roller surface was used to eliminate pot time concerns. The walls were successfully coated and water was removed from the pools with no detectable airborne contamination releases.

    Julia L. Tripp; Kip Archibald; Ann Marie Phillips; Joseph Campbell

    2004-02-01T23:59:59.000Z

    455

    Plasma Sprayed Ni-Al Coatings for Safe Ending Heat Exchanger Tubes  

    DOE Green Energy (OSTI)

    Brookhaven National Laboratory (BNL) has developed thermally conductive composite liners for corrosion and scale protection in heat exchanger tubes exposed to geothermal brine. The liners cannot withstand roller expansion to connect the tubes to the tubesheet. It is not possible to line the ends of the tubes with the same material after roller expansion due to the nature of the current liner application process. It was requested that BNL evaluate plasma sprayed Ni-Al coatings for safe ending heat exchanger tubes exposed to geothermal brine. The tubes of interest had an internal diameter of 0.875 inches. It is not typical to thermal spray small diameter components or use such small standoff distances. In this project a nozzle extension was developed by Zatorski Coating Company to spray the tube ends as well as flat coupons for testing. Four different Ni-Al coatings were investigated. One of these was a ductilized Ni-AlB material developed at Oak Ridge National Laboratory. The coatings were examined by optical and scanning electron microscopy. In addition, the coatings were analyzed by X-ray diffraction and subjected to corrosion, tensile adhesion, microhardness and field tests in a volcanic pool in New Zealand.

    Allen, M.L.; Berndt, C.C.; Otterson, D.

    1998-11-01T23:59:59.000Z

    456

    Pressurized security barrier and alarm system  

    DOE Patents (OSTI)

    A security barrier for placement across a passageway is made up of interconnected pressurized tubing made up in a grid pattern with openings too small to allow passage. The tubing is connected to a pressure switch, located away from the barrier site, which activates an alarm upon occurrence of a pressure drop.