National Library of Energy BETA

Sample records for themes carbon dynamics

  1. Ten themes of viscous liquid dynamics

    E-Print Network [OSTI]

    Jeppe C. Dyre

    2006-12-06

    Ten "themes" of viscous liquid physics are discussed with a focus on how they point to a general description of equilibrium viscous liquid dynamics (i.e., fluctuations) at a given temperature. This description is based on standard time-dependent Ginzburg-Landau equations for the density fields, stress tensor fields, potential energy density field, and fields quantifying molecular orientations. One characteristic aspect of the theory is that density has the appearance of a non-conserved field. Another characteristic feature is long-wavelength dominance of the dynamics, which not only simplifies the theory by allowing for an ultra-local Hamiltonian (free energy), but also explains the observed general independence of chemistry. Whereas there are no long-ranged static (i.e., equal-time) correlations in the model, there are important long-ranged dynamic correlations on the alpha time scale.

  2. Research Theme Paper Research Themes...............................................................................................................................................3

    E-Print Network [OSTI]

    Wapstra, Erik

    Research Theme Paper May 2015 #12;Contents Research Themes&S).......................................................................................8 Environment, Resources and Sustainability Research Programs&M)...................................................................................................13 MA&M Research Program

  3. Carbon dynamics in arctic vegetation 

    E-Print Network [OSTI]

    Street, Lorna Elizabeth

    2011-11-24

    Rapid climate change in Arctic regions is of concern due to important feedbacks between the Arctic land surface and the global climate system. A large amount of organic carbon (C) is currently stored in Arctic soils; if ...

  4. Carbon dynamics of terrestrial ecosystems on the Tibetan Plateau

    E-Print Network [OSTI]

    Xiao, Jingfeng

    RESEARCH PAPER Carbon dynamics of terrestrial ecosystems on the Tibetan Plateau during the 20th tundra to evergreen tropics. Its soils are dominated by permafrost and are rich in organic carbon. Its, the carbon dynamics of the Tibetan Plateau have not been well quantified under changes of climate and per

  5. The Social Dynamics of Carbon Capture and Storage

    E-Print Network [OSTI]

    The Social Dynamics of Carbon Capture and Storage Understanding CCS Representations, Governance studies. He works as a Research Associate at the Scottish Carbon Capture and Storage research centre works on assessing options for removal and storage of CO2. This includes techno-economic, socio

  6. Hydrogen Raman shifts in carbon nanotubes from molecular dynamics simulation

    E-Print Network [OSTI]

    Hydrogen Raman shifts in carbon nanotubes from molecular dynamics simulation S.J.V. Frankland *, D hydrogen in individual single-shell carbon nanotubes and nanotube ropes using a semiclassical model. The calculations predict that isolated hydrogen molecules inside of nanotubes have a Raman frequency that increases

  7. Dynamics of carbon sequestration in a coastal wetland using radiocarbon measurements

    E-Print Network [OSTI]

    Dynamics of carbon sequestration in a coastal wetland using radiocarbon measurements Yonghoon Choi1. Wang (2004), Dynamics of carbon sequestration in a coastal wetland using radiocarbon measurements carbon cycle. However, the dynamics of carbon (C) cycling in coastal wetlands and its response to sea

  8. Entropy-driven structure and dynamics in carbon nanocrystallites

    SciTech Connect (OSTI)

    McNutt, Nicholas W; Wang, Qifei; Rios, Orlando; Keffer, David J

    2014-01-01

    New carbon composite materials are being developed that contain carbon nanocrystallites in the range of 5 17 A in radius dispersed within an amorphous carbon matrix. Evaluating the applicability of these materials for use in battery electrodes requires a molecular-level understanding of the thermodynamic, structural, and dynamic properties of the nanocrystallites. Herein, molecular dynamics simulations reveal the molecular-level mechanisms for such experimental observations as the increased spacing between carbon planes in nanocrystallites as a function of decreasing crystallite size. As the width of this spacing impacts Li-ion capacity, an explanation of the origin of this distance is relevant to understanding anode performance. It is thus shown that the structural configuration of these crystallites is a function of entropy. The magnitude of out-of-plane ripples, binding energy between layers, and frequency of characteristic planar modes are reported over a range of nanocrystallite sizes and temperatures. This fundamental information for layered carbon nanocrystallites may be used to explain enhanced lithium ion diffusion within the carbon composites.

  9. Fire dynamics and carbon cycling of miombo woodlands

    E-Print Network [OSTI]

    Fire dynamics and carbon cycling of miombo woodlands Supervised by Mat Williams & Casey Ryan #12 extraction · Fire #12;#12;Research Questions 1. How does fire activity relate to forest biomass? 2. Can fire be linked to tree mortality? 3. Can modelling techniques be used to understand the impact of fire in SE

  10. Patterns of Carbon, Nitrogen and Phosphorus Dynamics in

    E-Print Network [OSTI]

    Moore, Tim

    Patterns of Carbon, Nitrogen and Phosphorus Dynamics in Decomposing Foliar Litter in Canadian Group 1 Department of Geography and Centre for Climate and Global Change Research, McGill University, Montre´al, Quebec, Canada; 2 Pacific Forestry Centre, Canadian Forest Service, Victoria, British Columbia

  11. 2014 THIRD YEAR THEME PAPER GUIDELINES

    E-Print Network [OSTI]

    Rose, Michael R.

    2014 THIRD YEAR THEME PAPER GUIDELINES Students will complete a Theme Paper requirement in their third year of study. The Theme Paper can take. SUBMISSION GUIDELINES Students may submit their Third Year Theme Paper anytime from

  12. Carbon and Greenhouse Gas Dynamics in Annual Grasslands: Effects of Management and Potential for Climate Change Mitigation

    E-Print Network [OSTI]

    Ryals, Rebecca

    2012-01-01

    dynamics and potential carbon sequestration by rangelands.G. E. Schuman. 2007. Carbon sequestration and rangelands: Aconcepts and carbon sequestration in cropland soils. Soil &

  13. Carbon Trading Markets Objective: Come to a comprehensive understanding of the structure, dynamics,

    E-Print Network [OSTI]

    Wolberg, George

    Carbon Trading Markets Objective: Come to a comprehensive understanding of the structure, dynamics, strengths, and limitations of current carbon trading markets. Background: Since 1995, a cap applied to carbon, resulting in many different markets for carbon offsets and carbon emissions permits

  14. Molecular Dynamics in Formation Process of Single-Walled Carbon Nanotubes Yasushi SHIBUTA and Shigeo MARUYAMA

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Molecular Dynamics in Formation Process of Single-Walled Carbon Nanotubes Yasushi SHIBUTA The mechanism in the nucleation and formation of single-walled carbon nanotubes (SWNTs) was investigated using molecular dynamics simulations. When initial state was chosen so that carbon and nickel atoms were randomly

  15. Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes Shigeo MARUYAMA1,2

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes * Shigeo-8656 The hydrogen storage mechanism of SWNTs was studied through molecular dynamics simulations. Assuming the simple : Molecular Dynamics Method, Hydrogen Storage, Single Walled Carbon Nanotubes, Lennard-Jones, Adsorption

  16. Enhancing practice Quality Enhancement Themes

    E-Print Network [OSTI]

    Azzopardi, Leif

    .sparqs.org.uk) a national programme of Enhancement Themes aimed at developing and sharing good practice to enhance of establishing a programme of development activities, which draw on national and international good practice Scotland #12;Contents Acknowledgements 1 1 Outline and scope 2 2 A guide for readers 3 3 Practical

  17. Molecular dynamics simulations of the elastic properties of polymer/carbon nanotube composites

    E-Print Network [OSTI]

    Elliott, James

    Molecular dynamics simulations of the elastic properties of polymer/carbon nanotube composites Yue of polymer/CNT composites was initially reported by Ajayan et al. [3]. In their research, multi-wall carbon 20 June 2006 Abstract Carbon nanotubes (CNTs) are promising additives to polymeric materials due

  18. Mechanical properties of connected carbon nanorings via molecular dynamics simulation Nan Chen and Mark T. Lusk*

    E-Print Network [OSTI]

    van Duin, Adri

    over carbon reinforced resins currently used in industry.5­7 Other approaches for mechanical design as elementary construction components, but other carbon nanostructures may offer additional choices in designingMechanical properties of connected carbon nanorings via molecular dynamics simulation Nan Chen

  19. Molecular Dynamics Simulation of Nucleation Process of Single-Walled Carbon Nanotubes

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Molecular Dynamics Simulation of Nucleation Process of Single-Walled Carbon Nanotubes YASUSHI SHIBUTA, SHIGEO MARUYAMA Nucleation process of single-walled carbon nanotubes by the catalytic chemical with randomly distributed carbon-source molecules and a nickel cluster to investigate the metal-catalyzed growth

  20. Purification of carbon nanotubes by dynamic oxidation in air Nikolay Dementev,a

    E-Print Network [OSTI]

    Borguet, Eric

    ) are nanometre-wide hollow carbon structures with exceptional mechanical and elec- tronic properties.1 such as oxygen, carbon dioxide, water vapor or ozone. A detailed overview of existing purification techniquesPurification of carbon nanotubes by dynamic oxidation in air Nikolay Dementev,a Sebastian Osswald

  1. Permafrost carbon—climate feedback is sensitive to deep soil carbon decomposability but not deep soil nitrogen dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Koven, Charles D.; Lawrence, David M.; Riley, William J.

    2015-03-09

    Permafrost soils contain enormous amounts of organic carbon whose stability is contingent on remaining frozen. With future warming, these soils may release carbon to the atmosphere and act as a positive feedback to climate change. Significant uncertainty remains on the postthaw carbon dynamics of permafrost-affected ecosystems, in particular since most of the carbon resides at depth where decomposition dynamics may differ from surface soils, and since nitrogen mineralized by decomposition may enhance plant growth. Here we show, using a carbon–nitrogen model that includes permafrost processes forced in an unmitigated warming scenario, that the future carbon balance of the permafrost regionmore »is highly sensitive to the decomposability of deeper carbon, with the net balance ranging from 21 Pg C to 164 Pg C losses by 2300. Increased soil nitrogen mineralization reduces nutrient limitations, but the impact of deep nitrogen on the carbon budget is small due to enhanced nitrogen availability from warming surface soils and seasonal asynchrony between deeper nitrogen availability and plant nitrogen demands. The future carbon balance of this region is projected to hinge more on the rate and extent of permafrost thaw and soil decomposition than on enhanced nitrogen availability for vegetation growth resulting from permafrost thaw.« less

  2. Manakin Themes: customizing the look-and-feel of DSpace 

    E-Print Network [OSTI]

    Maslov, Alexey; Green, Cody; Mikeal, Adam; Phillips, Scott; Leggett, John

    2007-07-16

    the result using default settings Install The xmlui.xconf configuration file Theme settings Theme path URL matching rules: regex, handle, or both Theme name Documentation Theme creation tutorial www.di.tamu.edu/projects/xmlui/manakin/resources/ThemeTutorial...

  3. 2014 THIRD YEAR THEME PAPER Scoring Policy

    E-Print Network [OSTI]

    Loudon, Catherine

    2014 THIRD YEAR THEME PAPER Scoring Policy SCHOOL OF EDUCATION 4/8/2014 Ph.D. in Education FIRST ROUND SUBMISSION: Rolling Deadline from passing SYRP to September 15, 2014 of Year 4 Third Year Theme the student's paper advisor and an anonymous faculty reader, shall grade each Third Year Theme Paper and each

  4. Finite Element Modelling and Molecular Dynamic Simulations of Carbon nanotubes/ Polymer Composites 

    E-Print Network [OSTI]

    Gaddamanugu, Dhatri

    2010-07-14

    Modeling of single-walled carbon nanotubes, multi-walled nanotubes and nanotube reinforced polymer composites using both the Finite Element method and the Molecular Dynamic simulation technique is presented. Nanotubes subjected to mechanical loading...

  5. A Dynamical Systems Analysis of the Data Assimilation Linked Ecosystem Carbon (DALEC) Models

    E-Print Network [OSTI]

    Skeldon, Anne C.

    A Dynamical Systems Analysis of the Data Assimilation Linked Ecosystem Carbon (DALEC) Models Anna M make it ever more important to understand the processes involved in Earth systems, such as the carbon with it the ability to perform ever- more detailed studies of the Earth system and its components. Such studies help

  6. Molecular dynamics simulation of formation process of single-walled carbon nanotubes by CCVD method

    E-Print Network [OSTI]

    Maruyama, Shigeo

    chemical vapor deposition (CCVD) method [4-7] has been contrived for a scalable, large-scale production of SWNTs, with various carbon-source molecules tested such as carbon monoxide [4, 7], methane [5 simulations [10, 11] with the Brenner potential [12] or tight-binding molecular dynamics (TBMD) simulation [13

  7. A System Dynamics Study of Carbon Cycling and Electricity Generation from Energy Crops

    E-Print Network [OSTI]

    Ford, Andrew

    Energy Information Administration GHG Green House Gasses GORCAM Graz-Oak Ridge Carbon Accounting Model1 A System Dynamics Study of Carbon Cycling and Electricity Generation from Energy Crops Hilary calling for a cap-and- trade program, was reintroduced in the United States Senate this year. The Energy

  8. Dynamics of Surfactant-Suspended Single-Walled Carbon Nanotubes in a Centrifugal Field

    E-Print Network [OSTI]

    Dynamics of Surfactant-Suspended Single-Walled Carbon Nanotubes in a Centrifugal Field Nitish Nair-suspended single-walled carbon nanotubes in a density gradient, while being subjected to a centrifugal field position in the gradient after centrifugation has been completed. Analysis of the spatial concentration

  9. -Environmental variation, vegetation distribution, carbon dynamics, and water/energy exchange -301 Journal of Vegetation Science 13: 301-314, 2002

    E-Print Network [OSTI]

    McGuire, A. David

    - Environmental variation, vegetation distribution, carbon dynamics, and water/energy exchange environmental variables, vegetation distribution, carbon dynamics, and water and energy exchange distribution, carbon stocks and turnover, and water and energy exchange are related to environmental variation

  10. Diffusive Dynamics of Water inside Hydrophobic Carbon Micropores Studied by Neutron Spectroscopy and Molecular Dynamics Simulation

    E-Print Network [OSTI]

    S. O. Diallo; L. Vlcek; E. Mamontov; J. K. Keum; Jihua Chen; J. S. Hayes Jr.; A. A. Chialvo

    2014-12-15

    When water molecules are confined to nanoscale spacings, such as in the nanometer size pores of activated carbon fiber (ACF), their freezing point gets suppressed down to very low temperatures ($\\sim$ 150 K), leading to a metastable liquid state with remarkable physical properties. We have investigated the ambient pressure diffusive dynamics of water in microporous Kynol\\texttrademark ACF-10 (average pore size $\\sim$11.6 {\\AA}, with primarily slit-like pores) from temperature $T=$ 280 K in its stable liquid state down to $T=$ 230 K into the metastable supercooled phase. The observed characteristic relaxation times and diffusion coefficients are found to be respectively higher and lower than those in bulk water, indicating a slowing down of the water mobility with decreasing temperature. The observed temperature-dependent average relaxation time $$ when compared to previous findings indicate that it is the size of the confining pores - not their shape - that primarily affects the dynamics of water for pore sizes larger than 10 {\\AA}. The experimental observations are compared to complementary molecular dynamics simulations of a model system, in which we studied the diffusion of water within the 11.6 {\\AA} gap of two parallel graphene sheets. We find generally a reasonable agreement between the observed and calculated relaxation times at the low momentum transfer $Q$ ($Q\\le 0.9$ \\AA${^{-1}}$). At high $Q$ however, where localized dynamics becomes relevant, this ideal system does not satisfactorily reproduce the measurements. The best agreement is obtained for the diffusion parameter $D$ associated with the hydrogen-site when a representative stretched exponential function, rather than the standard bi-modal exponential model, is used to parameterize the self-correlation function $I(Q,t)$.

  11. Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes Shigeo MARUYAMA #12;The hydrogen storage mechanism of SWNTs was studied through molecular dynamics simulations,12) Fig. 6 Hydrogen storage inside each SWNT #12;Table 1 Potential parameters between SWNTs Tube d0 [Å

  12. Dynamics of decadally cycling carbon in subsurface soils

    E-Print Network [OSTI]

    Koarashi, Jun; Hockaday, William C; Masiello, Caroline A; Trumbore, Susan E

    2012-01-01

    of organic carbon in deep soil layers controlled by freshcarbon input G03033 from fresh liter to deep mineral soils,Soil Sci. Soc. Am. J. , 71, 347–354, doi:

  13. Carbon dynamics of the Weddell Gyre, Southern Ocean

    E-Print Network [OSTI]

    Naveira Garabato, Alberto

    .058 ± 0.010 Pg C yrÀ1 derived from the inversion. However, a wintertime outgassing signal similar in size suppresses the winter outgassing signal, while its biological pump and deepwater formation act as key]) and outgassing of upwelled natural dissolved inorganic carbon (DIC) (0.4Pg C yrÀ1 ) [Mikaloff Fletcher et al

  14. Climate Theme Global Tropical Moored Buoy Array

    E-Print Network [OSTI]

    Climate Theme Global Tropical Moored Buoy Array: Observing, Understanding Observing System for Climate #12;Performance 4 Global Tropical Moored Buoy Array: A coordinated multi-national effort to develop and sustain moored buoy observing systems for climate research

  15. Strategic Theme 1- Energy Security | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Strategic Theme 1- Energy Security Strategic Theme 1- Energy Security An article describing the ways in which America can create an economically strong requires reliable, clean,...

  16. Monthly Theme Hazardous Waste Disposal July 2009 Monthly Theme for discussion at Department Meetings -July 2009

    E-Print Network [OSTI]

    Calgary, University of

    Monthly Theme ­ Hazardous Waste Disposal ­ July 2009 Monthly Theme for discussion at Department Meetings - July 2009 Hazardous Waste Disposal Often a waste pick-up is initiated but the waste isn't picked that it would be beneficial to have a stand and deliver course on Hazardous Waste Disposal offered

  17. Monthly Theme January 2010 Movement of Hazardous Materials between or within buildings Monthly Theme January 2010

    E-Print Network [OSTI]

    Calgary, University of

    Monthly Theme January 2010 ­ Movement of Hazardous Materials between or within buildings Monthly Theme ­ January 2010 MOVEMENT OF HAZARDOUS MATERIALS BETWEEN OR WITHIN BUILDINGS Effective immediately for pick-up. This will reduce the transport hazard and cost when purchasing from Chemistry Stores (40% mark

  18. Introduction to Theme "Genomics in Ecology,

    E-Print Network [OSTI]

    Shaffer, H. Bradley

    Introduction to Theme "Genomics in Ecology, Evolution, and Systematics" H. Bradley Shaffer1, Los Angeles, California 90095; email: brad.shaffer@ucla.edu 2 Center for Genomics and Systems Biology.1146/annurev-ecolsys-081913-123118 Copyright c 2013 by Annual Reviews. All rights reserved Keywords genome

  19. Collision dynamics of polyatomic molecules containing carbon rings at low temperatures

    SciTech Connect (OSTI)

    Li, Zhiying; Heller, Eric J.; Krems, Roman V.

    2014-09-14

    We explore the collision dynamics of complex hydrocarbon molecules (benzene, coronene, adamantane, and anthracene) containing carbon rings in a cold buffer gas of {sup 3}He. For benzene, we present a comparative analysis of the fully classical and fully quantum calculations of elastic and inelastic scattering cross sections at collision energies between 1 and 10 cm{sup ?1}. The quantum calculations are performed using the time-independent coupled channel approach and the coupled-states approximation. We show that the coupled-states approximation is accurate at collision energies between 1 and 20 cm{sup ?1}. For the classical dynamics calculations, we develop an approach exploiting the rigidity of the carbon rings and including low-energy vibrational modes without holonomic constraints. Our results illustrate the effect of the molecular shape and the vibrational degrees of freedom on the formation of long-lived resonance states that lead to low-temperature clustering.

  20. Molecular dynamics simulation for arrangement of nickel atoms filled in carbon nanotubes

    SciTech Connect (OSTI)

    Bai, Liu Zhenyu, Zhao; Lirui, Liu

    2014-08-28

    Carbon Nanotubes (CNTs) filled with metals can be used in capacitors, sensors, rechargeable batteries, and so on. Atomic arrangement of the metals has an important role in the function of the composites. The tips of CNTs were opened, and then nickel was filled by means of hydrothermal oxidation/ultrasonic vibration method. The tests of TEM, HREM, and EDX (energy-dispersive X-ray spectroscopy) analysis showed that Ni was filled in CNTs successfully. The atomic arrangement of nickel filled into single wall carbon nanotubes was investigated by molecular dynamics simulation. The radial distribution function and bond orientation order were established to analyze the atomic arrangement of nickel filled in carbon nanotubes during the cooling process. The results show that nickel atoms became in order gradually and preferably crystallized on the inner wall of carbon nanotubes when the temperature decreased from 1600?K. After it cooled to 100?K, the arrangement of nickel atoms in outermost circle was regular and dense, but there were many defects far from the wall of CNTs. According to the calculation of bond orientation order parameters Q{sub 6} and its visualization, the structure of nickel is Face-centered cube (f.c.c). (1,1,1){sub Ni} was close on the inner surface of carbon nanotubes. Radial direction of CNTs was [1,1,1] crystal orientation. Axial direction of CNTs, namely, filling direction, was [1{sup ¯}, 1{sup ¯},2] crystal orientation.

  1. Terrestrial Carbon Cycle Dynamics under Recent and Future Climate Change H. DAMON MATTHEWS, ANDREW J. WEAVER, AND KATRIN J. MEISSNER

    E-Print Network [OSTI]

    Meissner, Katrin Juliane

    extensive research over the past several years, the uncertainty range on estimates of terrestrial carbonTerrestrial Carbon Cycle Dynamics under Recent and Future Climate Change H. DAMON MATTHEWS, ANDREW, Victoria, British Columbia, Canada (Manuscript received 18 June 2004, in final form 21 October 2004

  2. Molecular dynamics study of the stability of a carbon nanotube atop a catalytic nanoparticle

    E-Print Network [OSTI]

    Verkhovtsev, Alexey V; Solov'yov, Andrey V

    2014-01-01

    The stability of a single-walled carbon nanotube placed on top of a catalytic nickel nanoparticle is investigated by means of molecular dynamics simulations. As a case study, we consider the $(12,0)$ nanotube consisting of 720 carbon atoms and the icosahedral Ni$_{309}$ cluster. An explicit set of constant-temperature simulations is performed in order to cover a broad temperature range from 400 to 1200 K, at which a successful growth of carbon nanotubes has been achieved experimentally by means of chemical vapor deposition. The stability of the system depending on parameters of the involved interatomic interactions is analyzed. It is demonstrated that different scenarios of the nanotube dynamics atop the nanoparticle are possible depending on the parameters of the Ni-C potential. When the interaction is weak the nanotube is stable and resembles its highly symmetric structure, while an increase of the interaction energy leads to the abrupt collapse of the nanotube in the initial stage of simulation. In order t...

  3. Molecular dynamics study of interfacial confinement effects of aqueous NaCl brines in nanoporous carbon

    SciTech Connect (OSTI)

    Wander, M. C. F.; Shuford, K. L.

    2010-12-09

    In this paper, studies of aqueous electrolyte solutions in contact with a family of porous carbon geometries using classical molecular dynamics simulations are presented. These simulations provide an atomic scale depiction of ion transport dynamics in different environments to elucidate power of aqueous electrolyte supercapacitors. The electrolyte contains alkali metal and halide ions, which allow for the examination of size trends within specific geometries as well as trends in concentration. The electrode pores are modeled as planar graphite sheets and carbon nanotubes with interstices ranging from one to four nanometers. Ordered layers form parallel to the carbon surface, which facilitates focused ion motion under slightly confining conditions. As a result, the ion’s diffusivities are enhanced in the direction of the slit or pore. Further confining the system leads to decreased ion diffusivities. The ions are fully hydrated in all but the smallest slits and pores with those sizes showing increased ion pairing. There is strong evidence of charge separation perpendicular to the surface at all size scales, concentrations, and ion types, providing a useful baseline for examining differential capacitance behavior and future studies on energy storage. These systems show promise as high-power electrical energy storage devices.

  4. Reaction Dynamics at a C Atom Dynamics of the Simplest Reaction of a Carbon

    E-Print Network [OSTI]

    Zare, Richard N.

    work includes new potential energy surface calculations,[2­6] direct dynamics studies,[7] calculation reaction. By using the well-established photoloc tech- nique,[12] we find that at a collision energy of 1 in the same direction as the incoming H atom, thus indicating a rebound mechanism.[13] The H + D2 reaction

  5. Significance of microbial asynchronous anabolism to soil carbon dynamics driven by litter inputs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fan, Zhaosheng; Liang, Chao

    2015-04-02

    Soil organic carbon (SOC) plays an important role in the global carbon cycle. However, it remains largely unknown how plant litter inputs impact magnitude, composition and source configuration of the SOC stocks over long term through microbial catabolism and anabolism, mostly due to uncoupled research on litter decomposition and SOC formation. This limits our ability to predict soil system responses to changes in land-use and climate. Here, we examine how microbes act as a valve controlling carbon sequestrated from plant litters versus released to the atmosphere in natural ecosystems amended with plant litters varying in quantity and quality. We findmore »that litter quality – not quantity – regulates long-term SOC dynamics under different plausible scenarios. Long-term changes in bulk SOC stock occur only when the quality of carbon inputs causes asynchronous change in a microbial physiological trait, defined as ‘‘microbial biosynthesis acceleration’’ (MBA). This is the first theoretical demonstration that the response of the SOC stocks to litter inputs is critically determined by the microbial physiology. Our work suggests that total SOC at an equilibrium state may be an intrinsic property of a given ecosystem, which ultimately is controlled by the asynchronous MBA between microbial functional groups.« less

  6. Variations on a Theme Issue 8 

    E-Print Network [OSTI]

    Piacentini, Valerie; Clark, Sheila

    1984-01-01

    lot of the farm animals went wild, too, when the people left .. l1 "I'm not sure I like the sound of that," McCoy said dubiously. "Wild country, scattered population, possibly dangerous animals roaming around ... It "Just like Vulcan," k:irk said..., Sheila Clark, Valerie Piacentini Printing of masters - Janet Quartan Printing - Warped Out Publications Distracting - Shan a (Don't you get tired of playing with paper?) Var-iations on a Theme 8, in which Kirk and Spack find their leave less r...

  7. Variations on a Theme Issue 4 

    E-Print Network [OSTI]

    Piacentini, Valerie; Clark, Sheila

    1980-01-01

    and Sheila Clark covel' by Roo illustrations by Virginia Lee Smith Variations on a Theme 4, priCG ?1. 25 inside the U.K., is put out by the ST!,H 'mEK Action Group and is available from Sheila Clark 6 Craig111ill Cottages Strathmartino by Dundee... Scotland. Foreign rates - \\\\6.00 US airmail, $3.50 surface (?2.50 airmail, ?1.50 surface) Australia, ?2.75 airmail, ?1.50 surface Europe, ?1.50. If you pay by dollar cheque, bank draft, please add $1.00 per total order to cover bank charges. STAG...

  8. Theme 1 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar FuelTechnologyTel: Name:Departmentand in complex with1 Theme 1

  9. Theme 2 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar FuelTechnologyTel: Name:Departmentand in complex with1 Theme 12

  10. Theme 3 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar FuelTechnologyTel: Name:Departmentand in complex with1 Theme 123

  11. Theme 1 Members | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. Jeffrey publication of thetime it1 Members Theme

  12. Theme 2 Members | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. Jeffrey publication of thetime it1 Members Theme2

  13. NREL: Energy Systems Integration Facility - Research Themes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJessework usesof EnergyY-12Working with UsDevelopmentThemes Access to

  14. Modeling microbial dynamics in heterogeneous environments: Growth on soil carbon sources

    SciTech Connect (OSTI)

    Resat, Haluk; Bailey, Vanessa L.; McCue, Lee Ann; Konopka, Allan

    2012-01-01

    We have developed a new hybrid model to study how microbial dynamics are affected by the heterogeneity in the physical structure of the environment. The modeling framework can represent porous media such as soil. The individual based biological model can explicitly simulate microbial diversity, and cell metabolism is regulated via optimal allocation of cellular resources to enzyme synthesis, control of growth rate by protein synthesis capacity, and shifts to dormancy. This model was developed to study how microbial community functioning is influenced by local environmental conditions and by the functional attributes of individual microbes. Different strategies for acquisition of carbon from polymeric cellulose were investigated. Bacteria that express membrane-associated hydrolase had different growth and survival dynamics in soil pores than bacteria that release extracellular hydrolases. The kinetic differences may suggest different functional roles for these two classes of microbes in cellulose utilization. Our model predicted an emergent behavior in which co-existence led to higher cellulose utilization efficiency and reduced stochasticity. Microbial community dynamics were simulated at two spatial scales: micro-pores that resemble 6-20 {micro}m size portions of the soil physical structure and in 111 {micro}m size soil aggregates with a random pore structure. Trends in dynamic properties were very similar at these two scales, implying that micro-scale studies can be useful approximations to aggregate scale studies when local effects on microbial dynamics are studied.

  15. 1. Mission and Theme The University Transportation Center

    E-Print Network [OSTI]

    Carver, Jeffrey C.

    are specifically examined for compliance with the theme. This is illustrated by the following pie chart, which

  16. Dynamics and Disequilibrium Carbon Chemistry in Hot Jupiter Atmospheres, With Application to HD 209458b

    E-Print Network [OSTI]

    Curtis S. Cooper; Adam P. Showman

    2006-05-30

    Chemical equilibrium considerations suggest that, assuming solar elemental abundances, carbon on HD 209458b is sequestered primarily as carbon monoxide (CO) and methane (CH4). The relative mole fractions of CO(g) and CH4(g) in chemical equilibrium are expected to vary greatly according to variations in local temperature and pressure. We show, however, that in the p = 1--1000 mbar range, chemical equilibrium does not hold. To explore disequilibrium effects, we couple the chemical kinetics of CO and CH4 to a three-dimensional numerical model of HD 209458b's atmospheric circulation. These simulations show that vigorous dynamics caused by uneven heating of this tidally locked planet homogenize the CO and CH4 concentrations at p < 1 bar, even in the presence of lateral temperature variations of ~500--1000 K. In the 1--1000 mbar pressure range, we find that over 98% of the carbon is in CO. This is true even in cool regions where CH4 is much more stable thermodynamically. Our work shows furthermore that planets 300--500 K cooler than HD 209458b can also have abundant CO in their upper layers due to disequilibrium effects. We demonstrate several interesting observational consequences of these results.

  17. Variations on a theme of Grothendieck

    E-Print Network [OSTI]

    Johan Martens; Michael Thaddeus

    2015-05-22

    Grothendieck and Harder proved that every principal bundle over the projective line with split reductive structure group (and trivial over the generic point) can be reduced to a maximal torus. Furthermore, this reduction is unique modulo automorphisms and the Weyl group. In a series of six variations on this theme, we prove corresponding results for principal bundles over the following schemes and stacks: (1) a line modulo the group of nth roots of unity; (2) a football, that is, an orbifold of genus zero with two marked points; (3) a gerbe over a football whose structure group is the nth roots of unity; (4) a chain of lines meeting in nodes; (5) a line modulo an action of a split torus; and (6) a chain modulo an action of a split torus. We also prove that the automorphism groups of such bundles are smooth, affine, and connected.

  18. Tracking Dynamics Using Sensor Networks: Some Recurring Themes

    E-Print Network [OSTI]

    Ramamritham, Krithi

    interconnected sensors are being used to build ­ smart buildings that make efficient use of energy, ­ smart vehicles that improve efficiency, assist drivers and help in navigation, ­ robots to monitor water bodies (energy) efficiently, adaptably, i.e., continuously evolve to changing condi- tions, and resiliently

  19. Some General Themes in Catalysis at LANL

    SciTech Connect (OSTI)

    Gordon, John C.

    2012-07-19

    Some general themes in catalysis at LANL are: (1) Storage and release of energy within chemical bonds (e.g. H{sub 2} storage in and release from covalent bonds, N{sub 2} functionalization, CO{sub 2} functionalization, H{sub 2} oxidation/evolution, O{sub 2} reduction/evolution); (2) Can we control the chemistry of reactive substrates to effect energy relevant transformations in non-traditional media (e.g. can we promote C-C couplings, dehydrations, or hydrogenations in water under relatively mild conditions)? (3) Can we supplant precious metal or rare earth catalysts to effect these transformations, by using earth abundant metals/elements instead? Can we use organocatalysis and circumvent the use of metals completely? (4) Can we improve upon existing rare earth catalyst systems (e.g. in rare earth oxides pertinent to fluid cracking or polymerization) and reduce amounts required for catalytic efficacy? Carbohydrates can be accessed from non-food based biomass sources such as woody residues and switchgrass. After extracted from the plant source, our goal is to upgrade these classes of molecules into useful fuels.

  20. Using Theory to Model Polymer Properties There are two general themes to this research: (1) polymer degradation that occurs when

    E-Print Network [OSTI]

    the polymer with nanoinclusions of carbon nanotubes and graphene sheets and other structures. PolymerUsing Theory to Model Polymer Properties There are two general themes to this research: (1) polymer degradation that occurs when polymers are exposed to low earth orbit conditions, and (2) polymer mechanical

  1. Dynamic response of phenolic resin and its carbon-nanotube composites to shock wave loading

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Arman, B.; An, Q.; Luo, S. N.; Desai, T. G.; Tonks, D. L.; C?ag??n, T.; Goddard, III, W. A.

    2011-01-04

    We investigate with nonreactive molecular dynamics simulations the dynamic response of phenolic resin and its carbon-nanotube (CNT) composites to shock wave compression. For phenolic resin, our simulations yield shock states in agreement with experiments on similar polymers except the “phase change” observed in experiments, indicating that such phase change is chemical in nature. The elastic–plastic transition is characterized by shear stress relaxation and atomic-level slip, and phenolic resin shows strong strain hardening. Shock loading of the CNT-resin composites is applied parallel or perpendicular to the CNT axis, and the composites demonstrate anisotropy in wave propagation, yield and CNT deformation. Themore »CNTs induce stress concentrations in the composites and may increase the yield strength. Our simulations indicate that the bulk shock response of the composites depends on the volume fraction, length ratio, impact cross-section, and geometry of the CNT components; the short CNTs in current simulations have insignificant effect on the bulk response of resin polymer.« less

  2. Uncertainties and novel prospects in the study of the soil carbon dynamics

    E-Print Network [OSTI]

    Wang, Yang

    Protocol has resulted in an effort to look towards living biomass and soils for carbon sequestration. In order for carbon credits to be meaningful, sustained carbon sequestration for decades or longer, an effort has been made to look towards soils and living biomass for carbon sequestration. Since soils

  3. Development of a dynamic simulator for a natural gas combined cycle (NGCC) power plant with post-combustion carbon capture

    SciTech Connect (OSTI)

    Liese, E.; Zitney, S.

    2012-01-01

    The AVESTAR Center located at the U.S. Department of Energy’s National Energy Technology Laboratory and West Virginia University is a world-class research and training environment dedicated to using dynamic process simulation as a tool for advancing the safe, efficient and reliable operation of clean energy plants with CO{sub 2} capture. The AVESTAR Center was launched with a high-fidelity dynamic simulator for an Integrated Gasification Combined Cycle (IGCC) power plant with pre-combustion carbon capture. The IGCC dynamic simulator offers full-scope Operator Training Simulator (OTS) Human Machine Interface (HMI) graphics for realistic, real-time control room operation and is integrated with a 3D virtual Immersive Training Simulator (ITS), thus allowing joint control room and field operator training. The IGCC OTS/ITS solution combines a “gasification with CO{sub 2} capture” process simulator with a “combined cycle” power simulator into a single high-performance dynamic simulation framework. This presentation will describe progress on the development of a natural gas combined cycle (NGCC) dynamic simulator based on the syngas-fired combined cycle portion of AVESTAR’s IGCC dynamic simulator. The 574 MW gross NGCC power plant design consisting of two advanced F-class gas turbines, two heat recovery steam generators (HRSGs), and a steam turbine in a multi-shaft 2x2x1 configuration will be reviewed. Plans for integrating a post-combustion carbon capture system will also be discussed.

  4. Gas dynamic effects on formation of carbon dimers in laser-produced plasmas

    E-Print Network [OSTI]

    Harilal, S. S.

    production, carbon laser-produced plasma (LPP) research was a main focus over the last several years.1

  5. Uncertainties and novel prospects in the study of the soil carbon dynamics

    E-Print Network [OSTI]

    Drive, Tallahassee, FL 32306-4100, USA b Wetland Ecology Program, Florida A&M University, Tallahassee the component fluxes of the global carbon cycle and for studying the soil carbon cycle. Most significant development in the soil carbon cycle study is the application of accelerator mass spectrometry (AMS

  6. Priorities, Themes, & Strategic Objectives President Wolfe's UM System Priorities

    E-Print Network [OSTI]

    Missouri-Rolla, University of

    Priorities, Themes, & Strategic Objectives President Wolfe's UM System Priorities I. Strategic 2012-2013 Strategic Objectives I. Strategic Planning Enhancement Refine process to align with campus parents, alumni, employers, and the local community. IV. Resource Management/Operational Excellence Focus

  7. Effects of afforestation and forest management on soil carbon dynamics and trace gas emissions in a Sitka spruce (Picea sitchensis (Bong) Carr.) forest 

    E-Print Network [OSTI]

    Zerva, Argyro

    The establishment and intensive management of forests for the production of timber can have significant effects on the soil carbon dynamics. The establishment of forest on organic soils under grasslands may lead to ...

  8. A molecular dynamics study of the effect of a substrate on catalytic metal clusters in nucleation process of single-walled carbon nanotubes

    E-Print Network [OSTI]

    Maruyama, Shigeo

    process of single-walled carbon nanotubes Yasushi Shibuta1 *, Shigeo Maruyama2 1 Department of Materials of the substrate on catalytic metal clusters in nucleation process of single-walled carbon nanotubes was studied by classical molecular dynamics (MD) simulation. The melting point of a nickel cluster decreased

  9. TOC Total organic carbon MBC Microbial biomass carbon

    E-Print Network [OSTI]

    Virginia Tech

    C Carbon TOC Total organic carbon MBC Microbial biomass carbon Active C Pool Indicated by Light, the relationship between carbon dynamics including total organic carbon (TOC) storage, microbial biomass carbon and microbial biomass carbon in subsoil 4 years after rehabilitation · Microbial biomass carbon had a positive

  10. Dissolved organic carbon dynamics in anaerobic sediments of the Santa Monica Basin

    E-Print Network [OSTI]

    2013-01-01

    an organic-rich coastal sediment. Geochim. Cosmochim. Actaorganic carbon in sediments from the North Carolinaexchange between deep ocean sediments and sea water. Nature

  11. UPDATED Year One Self-Evaluation Report Standard One: Mission, Core Themes, and Expectations

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    UPDATED Year One Self-Evaluation Report Standard One: Mission, Core Themes, and Expectations.................................................................................6 Chapter One ­ Standard One: Mission, Core Themes, and Expectations...........................................................................................................................10 Section 1B. Core Themes

  12. Year One Self-Evaluation Report Standard One: Mission, Core Themes, and Expectations

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Year One Self-Evaluation Report Standard One: Mission, Core Themes, and Expectations Submitted ...........................................................................12 Chapter One ­ Standard One: Mission, Core Themes, and Expectations..........................................................................................................................20 Section 1B. Core Themes

  13. Hybrid DFT Functional-Based Static and Molecular Dynamics Studies of Excess Electron in Liquid Ethylene Carbonate

    SciTech Connect (OSTI)

    Yu, J. M.; Balbuena, P. B.; Budzien, J. L.; Leung, Kevin

    2011-02-22

    We applied static and dynamic hybrid functional density functional theory (DFT) calculations to study the interactions of one and two excess electrons with ethylene carbonate (EC) liquid and clusters. Optimal structures of (EC)n and (EC)n- clusters devoid of Li+ ions, n = 1–6, were obtained. The excess electron was found to be localized on a single EC in all cases, and the EC dimeric radical anion exhibits a reduced barrier associated with the breaking of the ethylene carbon–oxygen covalent bond compared to EC-. In ab initio molecular dynamics (AIMD) simulations of EC- solvated in liquid EC, large fluctuations in the carbonyl carbon–oxygen bond lengths were observed. AIMD simulations of a two-electron attack on EC in EC liquid and on Li metal surfaces yielded products similar to those predicted using nonhybrid DFT functionals, except that CO release did not occur for all attempted initial configurations in the liquid state.

  14. ORIGINAL PAPER Long-term black carbon dynamics in cultivated soil

    E-Print Network [OSTI]

    Lehmann, Johannes

    the term BC is used to describe the residual product from incomplete combustion of biomass either by land XPS Introduction Black carbon (BC) is a C-rich organic material derived from incomplete combustion climate change largely through anthropogenic emissions of carbon dioxide originat- ing from fossil fuel

  15. Carbon flow and ecosystem dynamics in the Mississippi River plume described by inverse analysis 

    E-Print Network [OSTI]

    Breed, Greg Allen

    2002-01-01

    excess organic carbon from autotrophic regions to heterotrophic regions. In contrast, the winter result indicated a plume that was net-heterotrophic in all 4 subregions with high aerobic bacterial respiration and relatively low primary production...

  16. Carbon Dynamics in Aquatic Ecosystems in Response to Elevated Atmospheric CO2 and Altered Nutrients Availability

    E-Print Network [OSTI]

    Song, Chao

    2011-04-26

    Aquatic ecosystems will experience altered inorganic carbon, nitrogen and phosphorous availability in the future due to elevated atmospheric CO2, stronger stratification and anthropogenic activities. Despite its importance in modulating global...

  17. 10/21/11 Interpre've Themes

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    different results that are both correct. General Idea Classical physics instrucWc/Non-Local · UnintuiWve COURSES STUDIED · PHYS 2130 ­ General Physics III (modern physics10/21/11 1 Interpre've Themes in Quantum Physics: Curriculum Development

  18. Water is Theme For UNL at September's Husker Harvest Days

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    Water is Theme For UNL at September's Husker Harvest Days "Nebraska is fortunate to have a vibrant water-related research and programming community. This year's colloquium features the best of the best Water Center and Water Resources Research Initiative. In addition to presentations, the colloquium

  19. Water is Theme For UNL at September's Husker Harvest Days

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    Water is Theme For UNL at September's Husker Harvest Days University of Nebraska's Institute of Agriculture and Natural Resources (IANR) will highlight the latest in water research, education Harvest Days show in Grand Island this September. "We are very excited to be rolling out a very new look

  20. FINDINGS IN BRIEF THEME: Water, aquaculture and fish

    E-Print Network [OSTI]

    FINDINGS IN BRIEF THEME: Water, aquaculture and fish Photo:Jan-ErikJohansson,SLU Sustainable feed for farmed fish Farmed predatory fish (salmon, cod, etc.) need large quantities of feed, which at pre- sent consists of wildcaught marine fish spe- cies that are endangered to varying degrees. SLU researchers have

  1. Data Swapping: Variations on a Theme by Dalenius and Reiss

    E-Print Network [OSTI]

    Fienberg, Stephen E.

    Data Swapping: Variations on a Theme by Dalenius and Reiss Stephen E. Fienberg1, and Julie Mc@stat.cmu.edu Abstract. Data swapping, a term introduced in 1978 by Dalenius and Reiss for a new method of statistical disclosure protection in confidential data bases, has taken on new meanings and been linked to new

  2. Dynamic simulation of a solar-driven carbon dioxide transcritical power system for small scale combined heat and power production

    SciTech Connect (OSTI)

    Chen, Y.; Lundqvist, Per; Pridasawas, Wimolsiri

    2010-07-15

    Carbon dioxide is an environmental benign natural working fluid and has been proposed as a working media for a solar-driven power system. In the current work, the dynamic performance of a small scale solar-driven carbon dioxide power system is analyzed by dynamic simulation tool TRNSYS 16 and Engineering Equation Solver (EES) using co-solving technique. Both daily performance and yearly performance of the proposed system have been simulated. Different system operating parameters, which will influence the system performance, have been discussed. Under the Swedish climatic condition, the maximum daily power production is about 12 kW h and the maximum monthly power production is about 215 kW h with the proposed system working conditions. Besides the power being produced, the system can also produce about 10 times much thermal energy, which can be used for space heating, domestic hot water supply or driving absorption chillers. The simulation results show that the proposed system is a promising and environmental benign alternative for conventional low-grade heat source utilization system. (author)

  3. Evaluating aerosol direct radiative effects on global terrestrial ecosystem carbon dynamics from

    E-Print Network [OSTI]

    Zhuang, Qianlai

    loading normally induces lower solar energy arriving at the land surface whereas plant photosynthesis of diffuse solar radiation for plant carbon uptake. Comparing with direct-beam solar radiation, diffuse solar to quantify aerosol effects on downward solar radiation. Simulations with and without considering the aerosol

  4. Multicomponent ballistic transport in narrow single wall carbon nanotubes: Analytic model and molecular dynamics simulations

    E-Print Network [OSTI]

    Adler, Joan

    online 27 January 2011) The transport of gas mixtures through molecular-sieve membranes such as narrow The transport of gas mixtures through molecular-sieve membranes and catalysts has been a subject of intensive inMulticomponent ballistic transport in narrow single wall carbon nanotubes: Analytic model

  5. Highly nonlinear contact interaction and dynamic energy dissipation by forest of carbon nanotubes

    E-Print Network [OSTI]

    Daraio, Chiara

    dynamic conditions nor their ability for energy storage/ dissipation at high-strain rate deformation to growth, 5 nm thick film of cobalt metal catalyst was evaporated onto a silicon (100) substrate

  6. Understanding and Improving Household Energy Consumption and Carbon Emissions Policies - A System Dynamics Approach 

    E-Print Network [OSTI]

    Oladokun, M.; Motawa, I.; Banfill, P.

    2012-01-01

    The purpose of this paper is to propose and demonstrate the application of system dynamics modeling approach to analyze and study the behavior the complex interrelationships among the different policies/interventions aimed ...

  7. A Molecular Dynamics Simulation of Hydrogen Storage in Single Walled Carbon Nanotubes Shigeo MARUYAMA, Eng. Res. Inst., The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656

    E-Print Network [OSTI]

    Maruyama, Shigeo

    A Molecular Dynamics Simulation of Hydrogen Storage in Single Walled Carbon Nanotubes Shigeo : Molecular Dynamics Method, Hydrogen Storage, Single Walled Carbon Nanotubes, Lennard-Jones (1-4) (5) Dillon,10) A = 2.361×10-21 J/Å SWNT 5376 or 9000 Hydrogen Molecules 30 nm 10 nm 3.388 nm 7 Full SWNT (560 C atoms

  8. Molecular dynamics simulation of diffusion coefficients and structural properties of some alkylbenzenes in supercritical carbon dioxide at infinite dilution

    SciTech Connect (OSTI)

    Wang, Jinyang; Zhong, Haimin; Qiu, Wenda; Chen, Liuping; Feng, Huajie

    2014-03-14

    The binary infinite dilute diffusion coefficients, D{sub 12}{sup ?}, of some alkylbenzenes (Ph-C{sub n}, from Ph-H to Ph-C{sub 12}) from 313 K to 333 K at 15 MPa in supercritical carbon dioxide (scCO{sub 2}) have been studied by molecular dynamics (MD) simulation. The MD values agree well with the experimental ones, which indicate MD simulation technique is a powerful way to predict and obtain diffusion coefficients of solutes in supercritical fluids. Besides, the local structures of Ph-C{sub n}/CO{sub 2} fluids are further investigated by calculating radial distribution functions and coordination numbers. It qualitatively convinces that the first solvation shell of Ph-C{sub n} in scCO{sub 2} is significantly influenced by the structure of Ph-C{sub n} solute. Meanwhile, the mean end-to-end distance, the mean radius of gyration and dihedral angle distribution are calculated to gain an insight into the structural properties of Ph-C{sub n} in scCO{sub 2}. The abnormal trends of radial distribution functions and coordination numbers can be reasonably explained in term of molecular flexibility. Moreover, the computed results of dihedral angle clarify that flexibility of long-chain Ph-C{sub n} is the result of internal rotation of C-C single bond (?{sub c-c}) in alkyl chain. It is interesting that compared with n-alkane, because of the existence of benzene ring, the flexibility of alkyl chain in Ph-C{sub n} with same carbon atom number is significantly reduced, as a result, the carbon chain dependence of diffusion behaviors for long-chain n-alkane (n ? 5) and long-chain Ph-C{sub n} (n ? 4) in scCO{sub 2} are different.

  9. On the optical properties of carbon nanotubes--Part I. A general formula for the dynamical optical conductivity

    E-Print Network [OSTI]

    Morten Rasmussen; Benjamin Ricaud; Baptiste Savoie

    2015-08-13

    This paper is the first one of a series of two articles in which we revisit the optical properties of single-walled carbon nanotubes (SWNT). Produced by rolling up a graphene sheet, SWNT owe their intriguing properties to their cylindrical quasi-one-dimensional (quasi-1D) structure (the ratio length/radius is experimentally of order of 10^3). We model SWNT by circular cylinders of small diameters on the surface of which the conduction electron gas is confined by the electric field generated by the fixed carbon ions. The pair-interaction potential considered is the 3D Coulomb potential restricted to the cylinder. To reflect the quasi-1D structure, we introduce a 1D effective many-body Hamiltonian which is the starting-point of our analysis. To investigate the optical properties, we consider a perturbation by a uniform time-dependent electric field modeling an incident light beam along the longitudinal direction. By using Kubo's method, we derive within the linear response theory an asymptotic expansion in the low-temperature regime for the dynamical optical conductivity at fixed density of particles. The leading term only involves the eigenvalues and associated eigenfunctions of the (unperturbed) 1D effective many-body Hamiltonian, and allows us to account for the sharp peaks observed in the optical absorption spectrum of SWNT.

  10. Non-Fourier heat conduction in a single-walled carbon nanotube: Classical molecular dynamics simulations

    E-Print Network [OSTI]

    Maruyama, Shigeo

    of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan Non-stationary heat conduction in a single-picoseconds. The investigation was based on classical molecular dynamics simulations, where the heat pulse was generated. In a typical macroscopic description, a well-known model of heat wave propagation was formulated by Cattaneo

  11. A PRA~ATIC CONCEPT OF THEME AND RHEME FOR MACHINE Christa Hauenschild

    E-Print Network [OSTI]

    , Universitat Konstanz, Postfach 5560, D-7750 Konst anz The concept of theme and rheme we want to propose

  12. Error Dynamics: The Dynamic Emergence of Error Avoidance and

    E-Print Network [OSTI]

    Bickhard, Mark H.

    . Standard such notions are, however, arguably limited and bad notions, being based on untenable models of learning about error and of handling error knowledge constitute a complex major theme in evolution VICARIANTS Avoiding Error. The central theme is a progressive elaboration of kinds of dynamics that manage

  13. Fossil resource and energy security dynamics in conventional and carbon-constrained worlds

    SciTech Connect (OSTI)

    McCollum, David; Bauer, Nico; Calvin, Katherine V.; Kitous, Alban; Riahi, Keywan

    2014-04-01

    Fossil resource endowments and the future development of fossil fuel prices are important factors that will critically influence the nature and direction of the global energy system. In this paper we analyze a multi-model ensemble of long-term energy and emissions scenarios that were developed within the framework of the EMF27 integrated assessment model inter-comparison exercise. The diverse nature of these models highlights large uncertainties in the likely development of fossil resource (coal, oil, and natural gas) consumption, trade, and prices over the course of the twenty-first century and under different climate policy frameworks. We explore and explain some of the differences across scenarios and models and compare the scenario results with fossil resource estimates from the literature. A robust finding across the suite of IAMs is that the cumulative fossil fuel consumption foreseen by the models is well within the bounds of estimated recoverable reserves and resources. Hence, fossil resource constraints are, in and of themselves, unlikely to limit future GHG emissions. Our analysis also shows that climate mitigation policies could lead to a major reallocation of financial flows between regions, in terms of expenditures on fossil fuels and carbon, and can help to alleviate near-term energy security concerns via the reductions in oil imports and increases in energy system diversity they will help to motivate.

  14. Dynamics of multiple viscoelastic carbon nanotube based nanocomposites with axial magnetic field

    SciTech Connect (OSTI)

    Karli?i?, Danilo; Caji?, Milan; Murmu, Tony; Kozi?, Predrag; Adhikari, Sondipon

    2014-06-21

    Nanocomposites and magnetic field effects on nanostructures have received great attention in recent years. A large amount of research work was focused on developing the proper theoretical framework for describing many physical effects appearing in structures on nanoscale level. Great step in this direction was successful application of nonlocal continuum field theory of Eringen. In the present paper, the free transverse vibration analysis is carried out for the system composed of multiple single walled carbon nanotubes (MSWCNT) embedded in a polymer matrix and under the influence of an axial magnetic field. Equivalent nonlocal model of MSWCNT is adopted as viscoelastically coupled multi-nanobeam system (MNBS) under the influence of longitudinal magnetic field. Governing equations of motion are derived using the Newton second low and nonlocal Rayleigh beam theory, which take into account small-scale effects, the effect of nanobeam angular acceleration, internal damping and Maxwell relation. Explicit expressions for complex natural frequency are derived based on the method of separation of variables and trigonometric method for the “Clamped-Chain” system. In addition, an analytical method is proposed in order to obtain asymptotic damped natural frequency and the critical damping ratio, which are independent of boundary conditions and a number of nanobeams in MNBS. The validity of obtained results is confirmed by comparing the results obtained for complex frequencies via trigonometric method with the results obtained by using numerical methods. The influence of the longitudinal magnetic field on the free vibration response of viscoelastically coupled MNBS is discussed in detail. In addition, numerical results are presented to point out the effects of the nonlocal parameter, internal damping, and parameters of viscoelastic medium on complex natural frequencies of the system. The results demonstrate the efficiency of the suggested methodology to find the closed form solutions for the free vibration response of multiple nanostructure systems under the influence of magnetic field.

  15. Dynamic Evolution of Cement Composition and Transport Properties under Conditions Relevant to Geological Carbon Sequestration

    SciTech Connect (OSTI)

    Brunet, Jean-Patrick Leopold; Li, Li; Karpyn, Zuleima T.; Strazisar, Brian; Bromhal Grant

    2013-08-01

    Assessing the possibility of CO{sub 2} leakage is one of the major challenges for geological carbon sequestration. Injected CO{sub 2} can react with wellbore cement, which can potentially change cement composition and transport properties. In this work, we develop a reactive transport model based on experimental observations to understand and predict the property evolution of cement in direct contact with CO{sub 2}-saturated brine under diffusion-controlled conditions. The model reproduced the observed zones of portlandite depletion and calcite formation. Cement alteration is initially fast and slows down at later times. This work also quantified the role of initial cement properties, in particular the ratio of the initial portlandite content to porosity (defined here as ?), in determining the evolution of cement properties. Portlandite-rich cement with large ? values results in a localized “sharp” reactive diffusive front characterized by calcite precipitation, leading to significant porosity reduction, which eventually clogs the pore space and prevents further acid penetration. Severe degradation occurs at the cement–brine interface with large ? values. This alteration increases effective permeability by orders of magnitude for fluids that preferentially flow through the degraded zone. The significant porosity decrease in the calcite zone also leads to orders of magnitude decrease in effective permeability, where fluids flow through the low-permeability calcite zone. The developed reactive transport model provides a valuable tool to link cement–CO{sub 2} reactions with the evolution of porosity and permeability. It can be used to quantify and predict long-term wellbore cement behavior and can facilitate the risk assessment associated with geological CO{sub 2} sequestration.

  16. Computational fluid dynamics simulations of oxy-coal combustion for carbon capture at atmospheric and elevated pressures

    E-Print Network [OSTI]

    Chen, Lei, Ph. D. Massachusetts Institute of Technology

    2013-01-01

    Oxy-fuel combustion of solid fuels, often performed in a mixture of oxygen and wet or dry recycled carbon dioxide, has gained significant interest in the last two decades as one of the leading carbon capture technologies ...

  17. Solvent vapor recovery by pressure swing adsorption. 1: Experimental transient and periodic dynamics of the butane-activated carbon system

    SciTech Connect (OSTI)

    Liu, Y.; Holland, C.E.; Ritter, J.A.

    1998-11-01

    An experimental investigation was carried out for the separation and recovery of butane vapor (10 to 40 vol%) from nitrogen using Westvaco BAX activated carbon in a twin-bed pressure swing adsorption (PSA) system utilizing a 4-step Skarstrom-type cycle. Twenty-four runs, covering a broad range of process and initial column conditions, were performed to investigate the transient and period process dynamics. In all cases the approach to the periodic state was very slow, taking up to 160 cycles depending on the initial condition of the beds; and peak bed temperatures of up to 105 C were observed depending on both the initial condition of the beds and the process conditions. Also, the periodic state of each run was unique when approaching a new periodic state from less contaminated beds. The uniqueness of the periodic states, together with the exceedingly high peak temperatures, inferred much about the practice of preconditioning beds to avoid high temperature excursions. The periodic enriched butane vapor concentration histories also gave considerable insight into new cycle designs for improved solvent vapor enrichment.

  18. UK Energy Research Centre Demand Reduction Theme, University of Oxford

    E-Print Network [OSTI]

    for the Environment South Parks Road Oxford OX1 3QY www.eci.ox.ac.uk www.ukerc.ac.uk #12;UK Energy Research Centre 2 1 than carbon taxes or upstream measures would, but there is little evidence to substantiate

  19. Energy Materials and Processes, An EMSL Science Theme Advisory Panel Workshop

    SciTech Connect (OSTI)

    Burk, Linda H.

    2014-12-16

    The report summarizes discussions at the Energy Materials and Process EMSL Science Theme Advisory Panel Workshop held July 7-8, 2014.

  20. Biodiversity. Future theme issues will include Tourism and Heritage Cuisines, Heritage Tour-

    E-Print Network [OSTI]

    Delson, Eric

    Biodiversity. Future theme issues will include Tourism and Heritage Cuisines, Heritage Tour- ism coordinate review of all standard submissions (other than brief notes and book reviews), combining three

  1. ISRM -Lisbon -General Report Theme T1 -Robert Hack -10 July 2007 1 Rock Engineering and

    E-Print Network [OSTI]

    Hack, Robert

    ISRM - Lisbon - General Report Theme T1 - Robert Hack - 10 July 2007 1 Rock Engineering Observation (ITC), The Netherlands Robert Hack General Report International Society for Rock Mechanics ­ ISRM 11th Congress ­ Lisbon - July 2007 #12;ISRM - Lisbon - General Report Theme T1 - Robert Hack - 10

  2. Fisheries Utilization Research-50 Years in Retrospect, Part II: The Enduring Research Themes

    E-Print Network [OSTI]

    Fisheries Utilization Research-50 Years in Retrospect, Part II: The Enduring Research Themes JOHN A. DASSOW Introduction The enduring themes of fisheries util ization research are neither surprising, the quality, nutrition, and safe ty of fishery products comprise the triad of past and future utilization

  3. SICSA Data Science theme Call for bids to support Data Science activity

    E-Print Network [OSTI]

    St Andrews, University of

    SICSA Data Science theme Call for bids to support Data Science activity Researchers across SICSA are invited to bid to the Data Science theme for funds in support of events, workshops, and/or other activities that will make a significant contribution to their data science research agenda(s). The Data

  4. Quantification of Terrestrial Ecosystem Carbon Dynamics in the Conterminous United States Combining a Process-Based Biogeochemical Model and MODIS and AmeriFlux data

    SciTech Connect (OSTI)

    Chen, Min; Zhuang, Qianlai; Cook, David R.; Coulter, Richard L.; Pekour, Mikhail S.; Scott, Russell L.; Munger, J. W.; Bible, Ken

    2011-09-21

    Satellite remote sensing provides continuous temporal and spatial information of terrestrial 24 ecosystems. Using these remote sensing data and eddy flux measurements and biogeochemical 25 models, such as the Terrestrial Ecosystem Model (TEM), should provide a more adequate 26 quantification of carbon dynamics of terrestrial ecosystems. Here we use Moderate Resolution 27 Imaging Spectroradiometer (MODIS) Enhanced Vegetation Index (EVI), Land Surface Water Index 28 (LSWI) and carbon flux data of AmeriFlux to conduct such a study. We first modify the gross primary 29 production (GPP) modeling in TEM by incorporating EVI and LSWI to account for the effects of the 30 changes of canopy photosynthetic capacity, phenology and water stress. Second, we parameterize and 31 verify the new version of TEM with eddy flux data. We then apply the model to the conterminous 32 United States over the period 2000-2005 at a 0.05o ×0.05o spatial resolution. We find that the new 33 version of TEM generally captured the expected temporal and spatial patterns of regional carbon 34 dynamics. We estimate that regional GPP is between 7.02 and 7.78 Pg C yr-1 and net primary 35 production (NPP) ranges from 3.81 to 4.38 Pg C yr-1 and net ecosystem production (NEP) varies 36 within 0.08-0.73 Pg C yr-1 over the period 2000-2005 for the conterminous United States. The 37 uncertainty due to parameterization is 0.34, 0.65 and 0.18 Pg C yr-1 for the regional estimates of GPP, 38 NPP and NEP, respectively. The effects of extreme climate and disturbances such as severe drought in 39 2002 and destructive Hurricane Katrina in 2005 were captured by the model. Our study provides a 40 new independent and more adequate measure of carbon fluxes for the conterminous United States, 41 which will benefit studies of carbon-climate feedback and facilitate policy-making of carbon 42 management and climate.

  5. Quantification of terrestrial ecosystem carbon dynamics in the conterminous United States combining a process-based biogeochemical model and MODIS and AmeriFlux data

    SciTech Connect (OSTI)

    Chen, Min; Zhuang, Qianlai; Cook, D.; Coulter, Richard L.; Pekour, Mikhail S.; Scott, Russell L.; Munger, J. W.; Bible, Ken

    2011-08-31

    Satellite remote sensing provides continuous temporal and spatial information of terrestrial ecosystems. Using these remote sensing data and eddy flux measurements and biogeochemical models, such as the Terrestrial Ecosystem Model (TEM), should provide a more adequate quantification of carbon dynamics of terrestrial ecosystems. Here we use Moderate Resolution Imaging Spectroradiometer (MODIS) Enhanced Vegetation Index (EVI), Land Surface Water Index (LSWI) and carbon flux data of AmeriFlux to conduct such a study. We first modify the gross primary production (GPP) modeling in TEM by incorporating EVI and LSWI to account for the effects of the changes of canopy photosynthetic capacity, phenology and water stress. Second, we parameterize and verify the new version of TEM with eddy flux data. We then apply the model to the conterminous United States over the period 2000-2005 at a 0.05-0.05 spatial resolution. We find that the new version of TEM made improvement over the previous version and generally captured the expected temporal and spatial patterns of regional carbon dynamics. We estimate that regional GPP is between 7.02 and 7.78 PgC yr{sup -1} and net primary production (NPP) ranges from 3.81 to 4.38 Pg Cyr{sup -1} and net ecosystem production (NEP) varies within 0.08- 0.73 PgC yr{sup -1} over the period 2000-2005 for the conterminous United States. The uncertainty due to parameterization is 0.34, 0.65 and 0.18 PgC yr{sup -1} for the regional estimates of GPP, NPP and NEP, respectively. The effects of extreme climate and disturbances such as severe drought in 2002 and destructive Hurricane Katrina in 2005 were captured by the model. Our study provides a new independent and more adequate measure of carbon fluxes for the conterminous United States, which will benefit studies of carbon-climate feedback and facilitate policy-making of carbon management and climate.

  6. Prediction of the Three-Phase Coexistence Conditions of Pure Methane and Carbon Dioxide Hydrates Using Molecular Dynamics Simulations 

    E-Print Network [OSTI]

    Costandy, Joseph GN

    2015-06-12

    different molecules can form hydrates when mixed with water at relatively low temperatures and high pressures, including methane, ethane, propane, iso-butane, carbon dioxide, nitrogen and hydrogen. The accurate prediction of thermodynamic properties...

  7. Scaling up of Carbon Exchange Dynamics from AmeriFlux Sites to a Super-Region in the Eastern United States

    SciTech Connect (OSTI)

    Hans Peter Schmid; Craig Wayson

    2009-05-05

    The primary objective of this project was to evaluate carbon exchange dynamics across a region of North America between the Great Plains and the East Coast. This region contains about 40 active carbon cycle research (AmeriFlux) sites in a variety of climatic and landuse settings, from upland forest to urban development. The core research involved a scaling strategy that uses measured fluxes of CO{sub 2}, energy, water, and other biophysical and biometric parameters to train and calibrate surface-vegetation-atmosphere models, in conjunction with satellite (MODIS) derived drivers. To achieve matching of measured and modeled fluxes, the ecosystem parameters of the models will be adjusted to the dynamically variable flux-tower footprints following Schmid (1997). High-resolution vegetation index variations around the flux sites have been derived from Landsat data for this purpose. The calibrated models are being used in conjunction with MODIS data, atmospheric re-analysis data, and digital land-cover databases to derive ecosystem exchange fluxes over the study domain.

  8. Centennial-scale interactions between the carbon cycle and anthropogenic climate change using a dynamic Earth system model

    E-Print Network [OSTI]

    Winguth, Arne

    a dynamic Earth system model A. Winguth Center for Climatic Research, Department of Atmospheric and Oceanic; accepted 26 October 2005; published 15 December 2005. [1] A complex Earth system model including atmosphere and anthropogenic climate change using a dynamic Earth system model, Geophys. Res. Lett., 32, L23714, doi:10

  9. Lee, McCarl, and Gillig The Dynamic Competitiveness of U.S. Agricultural and Forest Carbon Sequestration

    E-Print Network [OSTI]

    McCarl, Bruce A.

    the emissions efficiency of fossil fuel usage, or 3 #12;Lee, McCarl, and Gillig · actions reducing the dependence on fossil fuel sources by switching fuels. The costs of such actions were a prominent argument can play an important role but that the relative importance of strategies depends on carbon price

  10. How Citizens and Politicians Talk About Their Carbon Footprint: A Discourse Analysis 

    E-Print Network [OSTI]

    MacRitchie, Julie

    2010-06-30

    citizens and politicians talk about their carbon footprint. One-on-one interviews were conducted and then transcribed and analysed using discursive psychology techniques, similar to Edwards and Potter (1992). Three themes of interest emerged from...

  11. Formation, characterization and dynamics of onion like carbon structures from nanodiamonds using reactive force-fields for electrical energy storage

    SciTech Connect (OSTI)

    Ganesh, Panchapakesan; Kent, Paul R; Mochalin, Vadym N

    2011-01-01

    We simulate the experimentally observed graphitization of nanodiamonds into multi-shell onion-like carbon nanostructures, also called carbon onions, at different temperatures, using reactive force fields. The simulations include long-range Coulomb and van der Waals interactions. Our results suggest that long-range interactions play a crucial role in the phase-stability and the graphitization process. Graphitization is both enthalpically and entropically driven and can hence be controlled with temperature. The outer layers of the nanodiamond have a lower kinetic barrier toward graphitization irrespective of the size of the nanodiamond and graphitize within a few-hundred picoseconds, with a large volume increase. The inner core of the nanodiamonds displays a large size-dependent kinetic barrier, and graphitizes much more slowly with abrupt jumps in the internal energy. It eventually graphitizes by releasing pressure and expands once the outer shells have graphitized. The degree of transformation at a particular temperature is thereby determined by a delicate balance between the thermal energy, long-range interactions, and the entropic/enthalpic free energy gained by graphitization. Upon full graphitization, a multi-shell carbon nanostructure appears, with a shell-shell spacing of about {approx}3.4 {angstrom} for all sizes. The shells are highly defective with predominantly five- and seven-membered rings to curve space. Larger nanodiamonds with a diameter of 4 nm can graphitize into spiral structures with a large ({approx}29-atom carbon ring) pore opening on the outermost shell. Such a large one-way channel is most attractive for a controlled insertion of molecules/ions such as Li ions, water, or ionic liquids, for increased electrochemical capacitor or battery electrode applications.

  12. Computability and Dynamical Systems: a Perspective

    E-Print Network [OSTI]

    Graça, Daniel S.

    Computability and Dynamical Systems: a Perspective Daniel S. Gra¸ca SQIG - IT and DM In this paper we look at dynamical systems from a computability per- spective. We survey some topics and themes of research for dynamical systems and then see how they can be fitted in a computational frame- work. We

  13. 3, 409447, 2006 Modeling carbon

    E-Print Network [OSTI]

    Boyer, Edmond

    not only impaired the soil fertility but also increased the amount of carbon dioxide (CO2) emitted fromBGD 3, 409­447, 2006 Modeling carbon dynamics in farmland of China F. Zhang et al. Title Page impacts of management alternatives on soil carbon storage of farmland in Northwest China F. Zhang1,3 , C

  14. Formation, characterization, and dynamics of onion-like carbon structures for electrical energy storage from nanodiamonds using reactive force fields

    SciTech Connect (OSTI)

    Ganesh, P.; Kent, P. R. C.; Mochalin, V.

    2011-10-01

    We simulate the experimentally observed graphitization of nanodiamonds into multi-shell onion-like carbonnanostructures, also called carbon onions, at different temperatures, using reactive force fields. The simulations include long-range Coulomb and van der Waals interactions. Our results suggest that long-range interactions play a crucial role in the phase-stability and the graphitization process. Graphitization is both enthalpically and entropically driven and can hence be controlled with temperature. The outer layers of the nanodiamond have a lower kinetic barrier toward graphitization irrespective of the size of the nanodiamond and graphitize within a few-hundred picoseconds, with a large volume increase. The inner core of the nanodiamonds displays a large size-dependent kinetic barrier, and graphitizes much more slowly with abrupt jumps in the internal energy. It eventually graphitizes by releasing pressure and expands once the outer shells have graphitized. The degree of transformation at a particular temperature is thereby determined by a delicate balance between the thermal energy, long-range interactions, and the entropic/enthalpic free energy gained by graphitization. Upon full graphitization, a multi-shell carbonnanostructure appears, with a shell-shell spacing of about ~3.4 Å for all sizes. The shells are highly defective with predominantly five- and seven-membered rings to curve space. Larger nanodiamonds with a diameter of 4 nm can graphitize into spiral structures with a large (~29-atom carbon ring) pore opening on the outermost shell. Such a large one-way channel is most attractive for a controlled insertion of molecules/ions such as Li ions, water, or ionic liquids, for increased electrochemical capacitor or battery electrode applications.

  15. January 2008 Journal of Engineering Education 95 A Theme-Based Seminar on Environmental

    E-Print Network [OSTI]

    Langen, Tom A.

    January 2008 Journal of Engineering Education 95 A Theme-Based Seminar on Environmental Department of Civil and Environmental Engineering Clarkson University TOM A. LANGEN Department of Biology SUSAN E. POWERS Department of Civil and Environmental Engineering Clarkson University ABSTRACT We

  16. Variations on the theme of invariants: conceptual and mathematical dualities in physics vs biology1

    E-Print Network [OSTI]

    Longo, Giuseppe

    1 Variations on the theme of invariants: conceptual and mathematical dualities in physics vs biology1 Giulia Frezza* Giuseppe Longo# 1. Through the looking glass: could physics and biology reflect peculiarities. Especially during the elaboration of theoretical extensions of physics by new observables (Bailly

  17. STUDENT CONFERENCE IN CONSERVATION SCIENCE, THEME: BIODIVERSITY IN AFRICA PRESENT STATE, CHALLENGES AND

    E-Print Network [OSTI]

    STUDENT CONFERENCE IN CONSERVATION SCIENCE, THEME: BIODIVERSITY IN AFRICA ­ PRESENT STATE. Prepared by Tendai Musvuugwa The student conference in conservation science was held this year in Nairobi of habitat health. Other studies presented during the conference focussed on the Mau Forest in Kenya's Rift

  18. INRIA, Evaluation of Theme Robotique Project-team e-Motion

    E-Print Network [OSTI]

    Laugier, Christian

    INRIA, Evaluation of Theme Robotique Project-team e-Motion March 2009 Project-team title : e-Motion Scientific leader : Christian Laugier Research center : INRIA Grenoble Rh^one-Alpes Common project 4 1 #12;Changes in staff Number of scientific staff that joined or left the project-team during

  19. ASSOCIATION OF PACIFIC RIM UNIVERSITIES (APRU) Theme: Global Challenges Pacific Perspectives

    E-Print Network [OSTI]

    Pulfrey, David L.

    ASSOCIATION OF PACIFIC RIM UNIVERSITIES (APRU) Theme: Global Challenges ­ Pacific Perspectives Symposium: APRU Responses to Asia-Pacific Issues Stephen J. Toope, UBC ­ Thursday, July 1, 2010 ASK? These are complex global challenges, yes, but to what extent are they also "Asia-Pacific issues?" Most importantly

  20. Worming up to composting in Montreal By Yannis Themelis (EEC Jr. Associate)

    E-Print Network [OSTI]

    Columbia University

    Worming up to composting in Montreal By Yannis Themelis (EEC Jr. Associate) Five years ago, Olivier it was time his fellow urbanites get acquainted with his intimate knowledge on garbage and composting. However, when it came to urban composting, Pelletier had one problem: How would he convince people living

  1. The Science of Team Science: Origins and Themes The Science of Team Science

    E-Print Network [OSTI]

    Finley Jr., Russell L.

    The Science of Team Science: Origins and Themes The Science of Team Science Overview of the Field, PhD Abstract: The science of team science encompasses an amalgam of conceptual and methodologic about the cost effectiveness of public- and private-sector investments in team-based science

  2. FAU CLIMATE CHANGE INITIATIVE PRIORITY THEME: RESEARCH, ENGINEERING, AND ADAPTATION TO A CHANGING CLIMATE

    E-Print Network [OSTI]

    Fernandez, Eduardo

    FAU CLIMATE CHANGE INITIATIVE PRIORITY THEME: RESEARCH, ENGINEERING, AND ADAPTATION TO A CHANGING CLIMATE "I am persuaded that global climate change is one of the most important issues that we will face climate change, is the most important threat to fisheries worldwide" U.S. National Oceanographic

  3. Developing the global exploration roadmap: An example using the humans to the lunar surface theme

    E-Print Network [OSTI]

    Developing the global exploration roadmap: An example using the humans to the lunar surface theme C: Space exploration Lunar exploration Global exploration roadmap Test bed a b s t r a c t The development of the Global Exploration Roadmap (GER) by 12 space agencies participating in the International Space

  4. Inventory of U.S. 2012 dioxin emissions to atmosphere Henri Dwyer, Nickolas J. Themelis

    E-Print Network [OSTI]

    Inventory of U.S. 2012 dioxin emissions to atmosphere Henri Dwyer, Nickolas J. Themelis Earth: Total dioxins TEQ dioxins Dioxin sources U.S. inventory Waste-to-energy WTE Emissions Landfill fires a b s t r a c t In 2006, the U.S. EPA published an inventory of dioxin emissions for the U.S. covering

  5. Climate Analysis The central theme of the Climate Analysis Division is the analysis and

    E-Print Network [OSTI]

    Haak, Hein

    Climate Analysis The central theme of the Climate Analysis Division is the analysis and diagnosis of the climate and its variability on the basis of observations and models. The objective of this research of climate change scenarios for impact studies using downscaling techniques. The research can be summarised

  6. Vol. 37/3 Proceedings RMS September 2002 167 Continuing the theme of using

    E-Print Network [OSTI]

    Barrett, Steve D.

    Vol. 37/3 Proceedings RMS September 2002 167 Continuing the theme of using software as a tool to a user. Some of these may be standard data acquisition parameters generated by the microscope system soft of a particular microscope system may have an option to save the images in a `standard' file format (such as TIFF

  7. Don't trash waste-to-energy plants By NICKOLAS THEMELIS

    E-Print Network [OSTI]

    Columbia University

    Don't trash waste-to-energy plants By NICKOLAS THEMELIS October 21, 2009 2:00 AM Some on waste-to-energy (WTE) facilities to achieve that goal. As director of the Earth Engineering Center a house in East Sandwich that is now my permanent home. Both of us were absolutely delighted 15 years ago

  8. Modeled Interactive Effects of Precipitation, temperature, and [CO2] on Ecosystem Carbon and Water Dynamics in Different Climatic Zones

    SciTech Connect (OSTI)

    Luo, Yiqi [University of Oklahoma; Gerten, Dieter [Potsdam Institute for Climate Impact Research, Potsdam, Germany; Le Maire, Guerric [Laboratoire des Sciences du Climat et de l'Environement, France; Parton, William [University of Colorado, Fort Collins; Weng, Ensheng [University of Oklahoma, Norman; Zhou, Xuhuui [University of Oklahoma; Keough, Cindy [University of Colorado, Fort Collins; Beier, Claus [Riso National Laboratory, Roskilde, Denmark; Ciais, Philippe [Laboratoire des Sciences du Climat et de l'Environement, France; Cramer, Wolfgang [Potsdam Institute for Climate Impact Research, Potsdam, Germany; Dukes, Jeff [University of Massachusetts, Boston; Emmett, Bridget [Centre for Ecology and Hydrology, Bangor, Gwynedd, United Kingdom; Hanson, Paul J [ORNL; Knapp, Alan [Colorado State University, Fort Collins; Linder, Sune [Swedish University of Agricultural Sciences, Upsalla, Sweden; Nepstad, Daniel [Woods Hole Oceanographic Institution (WHOI), Woods Hole, MA; Rustad, Lindsey [USDA Forest Service

    2008-01-01

    Interactive effects of multiple global change factors on ecosystem processes are complex. It is relatively expensive to explore those interactions in manipulative experiments. We conducted a modeling analysis to identify potentially important interactions and to stimulate hypothesis formulation for experimental research. Four models were used to quantify interactive effects of climate warming (T), altered precipitation amounts [doubled (DP) and halved (HP)] and seasonality (SP, moving precipitation in July and August to January and February to create summer drought), and elevated [CO2] (C) on net primary production (NPP), heterotrophic respiration (Rh), net ecosystem production (NEP), transpiration, and runoff.We examined those responses in seven ecosystems, including forests, grasslands, and heathlands in different climate zones. The modeling analysis showed that none of the threeway interactions among T, C, and altered precipitation was substantial for either carbon or water processes, nor consistent among the seven ecosystems. However, two-way interactive effects on NPP, Rh, and NEP were generally positive (i.e. amplification of one factor s effect by the other factor) between T and C or between T and DP. A negative interaction (i.e. depression of one factor s effect by the other factor) occurred for simulated NPP between T and HP. The interactive effects on runoff were positive between T and HP. Four pairs of two-way interactive effects on plant transpiration were positive and two pairs negative. In addition, wet sites generally had smaller relative changes in NPP, Rh, runoff, and transpiration but larger absolute changes in NEP than dry sites in response to the treatments. The modeling results suggest new hypotheses to be tested in multifactor global change experiments. Likewise, more experimental evidence is needed for the further improvement of ecosystem models in order to adequately simulate complex interactive processes.

  9. Quantitative in-situ scanning electron microscope pull-out experiments and molecular dynamics simulations of carbon nanotubes embedded in palladium

    SciTech Connect (OSTI)

    Hartmann, S., E-mail: steffen.hartmann@etit.tu-chemnitz.de; Blaudeck, T.; Hermann, S.; Wunderle, B. [Technische Universität Chemnitz, Reichenhainer Str. 70, 09126 Chemnitz (Germany); Hölck, O. [Technische Universität Chemnitz, Reichenhainer Str. 70, 09126 Chemnitz (Germany); Fraunhofer IZM Berlin, Gustav-Meyer-Allee 25, 13355 Berlin (Germany); Schulz, S. E.; Gessner, T. [Technische Universität Chemnitz, Reichenhainer Str. 70, 09126 Chemnitz (Germany); Fraunhofer ENAS Chemnitz, Technologie-Campus 3, 09126 Chemnitz (Germany)

    2014-04-14

    In this paper, we present our results of experimental and numerical pull-out tests on carbon nanotubes (CNTs) embedded in palladium. We prepared simple specimens by employing standard silicon wafers, physical vapor deposition of palladium and deposition of CNTs with a simple drop coating technique. An AFM cantilever with known stiffness connected to a nanomanipulation system was utilized inside a scanning electron microscope (SEM) as a force sensor to determine forces acting on a CNT during the pull-out process. SEM-images of the cantilever attached to a CNT have been evaluated for subsequent displacement steps with greyscale correlation to determine the cantilever deflection. We compare the experimentally obtained pull-out forces with values of numerical investigations by means of molecular dynamics and give interpretations for deviations according to material impurities or defects and their influence on the pull-out data. We find a very good agreement of force data from simulation and experiment, which is 17 nN and in the range of 10–61 nN, respectively. Our findings contribute to the ongoing research of the mechanical characterization of CNT-metal interfaces. This is of significant interest for the design of future mechanical sensors utilizing the intrinsic piezoresistive effect of CNTs or other future devices incorporating CNT-metal interfaces.

  10. Abstract--We describe an approach to using standard data mining algorithms to help analyse recurring themes in game

    E-Print Network [OSTI]

    Togelius, Julian

    Abstract-- We describe an approach to using standard data mining algorithms to help analyse recurring themes in game design across several games, and to help suggest novel game design ideas mining have been used to identify archetypes and recurring themes. The results of the qualitative

  11. Global patterns and controls of soil organic carbon dynamics as simulated by multiple terrestrial biosphere models: Current status and future directions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tian, Hanqin; Lu, Chaoqun; Yang, Jia; Banger, Kamaljit; Huntzinger, Deborah N.; Schwalm, Christopher R.; Michalak, Anna M.; Cook, Robert; Ciais, Philippe; Hayes, Daniel; et al

    2015-06-05

    Soil is the largest organic carbon (C) pool of terrestrial ecosystems, and C loss from soil accounts for a large proportion of land-atmosphere C exchange. Therefore, a small change in soil organic C (SOC) can affect atmospheric carbon dioxide (CO?) concentration and climate change. In the past decades, a wide variety of studies have been conducted to quantify global SOC stocks and soil C exchange with the atmosphere through site measurements, inventories, and empirical/process-based modeling. However, these estimates are highly uncertain, and identifying major driving forces controlling soil C dynamics remains a key research challenge. This study has compiled century-longmore »(1901–2010) estimates of SOC storage and heterotrophic respiration (Rh) from 10 terrestrial biosphere models (TBMs) in the Multi-scale Synthesis and Terrestrial Model Intercomparison Project and two observation-based data sets. The 10 TBM ensemble shows that global SOC estimate ranges from 425 to 2111 Pg C (1 Pg = 10¹? g) with a median value of 1158 Pg C in 2010. The models estimate a broad range of Rh from 35 to 69 Pg C yr?¹ with a median value of 51 Pg C yr?¹ during 2001–2010. The largest uncertainty in SOC stocks exists in the 40–65°N latitude whereas the largest cross-model divergence in Rh are in the tropics. The modeled SOC change during 1901–2010 ranges from –70 Pg C to 86 Pg C, but in some models the SOC change has a different sign from the change of total C stock, implying very different contribution of vegetation and soil pools in determining the terrestrial C budget among models. The model ensemble-estimated mean residence time of SOC shows a reduction of 3.4 years over the past century, which accelerate C cycling through the land biosphere. All the models agreed that climate and land use changes decreased SOC stocks, while elevated atmospheric CO? and nitrogen deposition over intact ecosystems increased SOC stocks—even though the responses varied significantly among models. Model representations of temperature and moisture sensitivity, nutrient limitation, and land use partially explain the divergent estimates of global SOC stocks and soil C fluxes in this study. In addition, a major source of systematic error in model estimations relates to nonmodeled SOC storage in wetlands and peatlands, as well as to old C storage in deep soil layers.« less

  12. Characterization of Carbon-Based Biomaterials 

    E-Print Network [OSTI]

    Zhou, Yan

    2014-04-24

    This research evaluates carbon-based biomaterials and investigates their fundamental mechanisms in bio-lubrication. Approaches include experimental investigation combined with molecular dynamics simulation. There are four ...

  13. Carbon sequestration

    E-Print Network [OSTI]

    Carbon sequestration is the process of capture and long-term storage of atmospheric carbon dioxide (CO 2).[1] Carbon sequestration describes long-term storage of carbon dioxide or other forms of carbon to either mitigate or defer global warming and avoid ...

  14. The dynamical evolution of the fragmented, bipolar dust shell around the carbon star IRC +10216: Rapid changes of a PPN-like structure?

    E-Print Network [OSTI]

    R. Osterbart; Y. Balega; T. Bloecker; A. Men'shchikov; G. Weigelt

    2000-03-22

    We present high-resolution J-, H-, and K-band observations and the first H-K color image of the carbon star IRC +10216. The images were reconstructed from 6m telescope speckle interferograms using the bispectrum speckle interferometry method. The H and K images with resolutions between 70mas and 92mas consist of several compact components within a 0.2" radius and a fainter asymmetric nebula. The brightest four components are denoted with A to D in the order of decreasing brightness in the 1996 image. A comparison of our images from 1995, 1996, 1997, and 1998 gives - almost like a movie of five frames - insight into the dynamical evolution of the inner nebula. For instance, the separation of the two brightest components A and B increased from 191 mas in 1995 to 265 mas in 1998. At the same time, component B is fading and the components C and D become brighter. The X-shaped bipolar structure of the nebula, most prominently present in the J-band image, implies an asymmetric mass loss. Such asymmetries are often present in protoplanetary nebulae but are unexpected for AGB stars. IRC +10216 is thus likely to be very advanced in its AGB evolution, shortly before turning into a protoplanetary nebula. The cometary shapes of A in the H and J images and in the 0.79 micron and 1.06 micron HST images suggest that the core of A is not the central star, but the southern lobe of a bipolar structure. The position of the central star is probably at or near the position of component B, where the H-K color has a value of 4.2. If the star is at or near B, then the components A, C, and D are likely to be located at the inner boundary of the dust shell.

  15. Atmospheric carbon dioxide and the global carbon cycle

    SciTech Connect (OSTI)

    Trabalka, J R [ed.

    1985-12-01

    This state-of-the-art volume presents discussions on the global cycle of carbon, the dynamic balance among global atmospheric CO2 sources and sinks. Separate abstracts have been prepared for the individual papers. (ACR)

  16. International politics of low carbon technology development: carbon capture and storage (CCS) in India 

    E-Print Network [OSTI]

    Kapila, Rudra Vidhumani

    2015-11-26

    This thesis explores the international political dynamics of developing low carbon technology. Specifically, Carbon Capture and Storage (CCS) technology as a climate mitigation strategy in a developing country context ...

  17. Development of the ANL plant dynamics code and control strategies for the supercritical carbon dioxide Brayton cycle and code validation with data from the Sandia small-scale supercritical carbon dioxide Brayton cycle test loop.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J.

    2011-11-07

    Significant progress has been made in the ongoing development of the Argonne National Laboratory (ANL) Plant Dynamics Code (PDC), the ongoing investigation and development of control strategies, and the analysis of system transient behavior for supercritical carbon dioxide (S-CO{sub 2}) Brayton cycles. Several code modifications have been introduced during FY2011 to extend the range of applicability of the PDC and to improve its calculational stability and speed. A new and innovative approach was developed to couple the Plant Dynamics Code for S-CO{sub 2} cycle calculations with SAS4A/SASSYS-1 Liquid Metal Reactor Code System calculations for the transient system level behavior on the reactor side of a Sodium-Cooled Fast Reactor (SFR) or Lead-Cooled Fast Reactor (LFR). The new code system allows use of the full capabilities of both codes such that whole-plant transients can now be simulated without additional user interaction. Several other code modifications, including the introduction of compressor surge control, a new approach for determining the solution time step for efficient computational speed, an updated treatment of S-CO{sub 2} cycle flow mergers and splits, a modified enthalpy equation to improve the treatment of negative flow, and a revised solution of the reactor heat exchanger (RHX) equations coupling the S-CO{sub 2} cycle to the reactor, were introduced to the PDC in FY2011. All of these modifications have improved the code computational stability and computational speed, while not significantly affecting the results of transient calculations. The improved PDC was used to continue the investigation of S-CO{sub 2} cycle control and transient behavior. The coupled PDC-SAS4A/SASSYS-1 code capability was used to study the dynamic characteristics of a S-CO{sub 2} cycle coupled to a SFR plant. Cycle control was investigated in terms of the ability of the cycle to respond to a linear reduction in the electrical grid demand from 100% to 0% at a rate of 5%/minute. It was determined that utilization of turbine throttling control below 50% load improves the cycle efficiency significantly. Consequently, the cycle control strategy has been updated to include turbine throttle valve control. The new control strategy still relies on inventory control in the 50%-90% load range and turbine bypass for fine and fast generator output adjustments, but it now also includes turbine throttling control in the 0%-50% load range. In an attempt to investigate the feasibility of using the S-CO{sub 2} cycle for normal decay heat removal from the reactor, the cycle control study was extended beyond the investigation of normal load following. It was shown that such operation is possible with the extension of the inventory and the turbine throttling controls. However, the cycle operation in this range is calculated to be so inefficient that energy would need to be supplied from the electrical grid assuming that the generator could be capable of being operated in a motoring mode with an input electrical energy from the grid having a magnitude of about 20% of the nominal plant output electrical power level in order to maintain circulation of the CO{sub 2} in the cycle. The work on investigation of cycle operation at low power level will be continued in the future. In addition to the cycle control study, the coupled PDC-SAS4A/SASSYS-1 code system was also used to simulate thermal transients in the sodium-to-CO{sub 2} heat exchanger. Several possible conditions with the potential to introduce significant changes to the heat exchanger temperatures were identified and simulated. The conditions range from reactor scram and primary sodium pump failure or intermediate sodium pump failure on the reactor side to pipe breaks and valve malfunctions on the S-CO{sub 2} side. It was found that the maximum possible rate of the heat exchanger wall temperature change for the particular heat exchanger design assumed is limited to {+-}7 C/s for less than 10 seconds. Modeling in the Plant Dynamics Code has been compared with available data from the Sandia Natio

  18. Dynamic coupling of volcanic CO2 flow and wind at the Horseshoe Lake tree kill, Mammoth Mountain, CA

    E-Print Network [OSTI]

    Lewicki, J.L.; Hilley, G.E.; Tosha, T.; Aoyagi, R.; Yamamoto, K.; Benson, S.M.

    2006-01-01

    Dynamics of carbon dioxide emission at Mammoth Mountain,Howle (1998), Magmatic carbon dioxide emissions at MammothHausback (1998), Carbon dioxide and helium emissions from a

  19. A molecular dynamics study of the graphitization ability of transition metals for catalysis of carbon nanotube growth via chemical vapor deposition

    E-Print Network [OSTI]

    Elliott, James

    of carbon nanotube growth via chemical vapor deposition Yasushi Shibuta a,*, James A. Elliott b a Department for carbon nanotube growth via chemical vapor deposition has been investigated via classical molecular and graphene sheet was found to be higher than for clusters comprising cobalt or nickel, since the high energy

  20. Title: A Sustainability-Themed Science and Technology Center at Cornell? Abstract: NSF has announced a new competition for Science and

    E-Print Network [OSTI]

    Walter, M.Todd

    Title: A Sustainability-Themed Science and Technology Center at Cornell? Abstract: NSF has how a new sustainability-themed STC would conduct world-class research through partnerships among

  1. The theme of illusion in plays by Eugene O'Neill 

    E-Print Network [OSTI]

    McMullan, Barbara Lynn

    1965-01-01

    Subject; English THE THEME OF ILLUSION IN PLAYS BY EUGENE O' NEILL A Thesis By Barbara Lynn McMullan Wi~ ** airman o emmy e ea o ar men em er ~ ~+c~~ M ~gE. ~ em er August, 1965 ACKNOWLEDGENENTS I wish to thank Dr. C. D. Laverty, Mr. K. E..., today' s man lusts after the advances, the "spoils" of civi- lization at, the same time that he yearns for his old innocence, his old simplicity. To this point Harry Slochower writes in "Eugene O'Neill's Lost Moderns": "Somethin'" drives them P O...

  2. Emerging themes from the SRP engagement process As part of the development of UVic's Strategic Research Plan, a

    E-Print Network [OSTI]

    Victoria, University of

    Emerging themes from the SRP engagement process As part of the development of UVic's Strategic the plan's development. Some high level messages emerging so far include: · Community-engaged research

  3. Carbon Smackdown: Carbon Capture

    SciTech Connect (OSTI)

    Jeffrey Long

    2010-07-12

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  4. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  5. Grassland carbon and nitrogen dynamics: effects of seasonal fire and clipping in a mixed-grass prairie of the southern great plains 

    E-Print Network [OSTI]

    Harris, Wylie Neal

    2006-08-16

    Plant production and soil microbial biomass (SMB) in grassland ecosystems are linked by flows of carbon (C) and nitrogen (N) between the two groups of organisms. In native mixed grasslands of the southern Great Plains, these cycles are strongly...

  6. The Allocation of European Union Allowances: Lessons, Unifying Themes and General Principles

    E-Print Network [OSTI]

    Buchner, Barbara.

    A critical issue in dealing with climate change is deciding who has a right to emit carbon dioxide (CO2), and under what conditions, when those emissions are limited. The European Union Emissions Trading Scheme (EU ETS) ...

  7. Carbon Storage in Young Growth Coast Redwood Stands

    E-Print Network [OSTI]

    Abstract Carbon sequestration is an emerging forest management objective within California and around the dynamics of carbon sequestration and to accurately measure carbon storage is essential to insure successful per acre making the argument for use of the species in long-term carbon sequestration projects self

  8. Atmospheric Carbon Dioxide Variability in the Community Earth System Model: Evaluation and Transient Dynamics during the Twentieth and Twenty-First Centuries

    E-Print Network [OSTI]

    Hoffman, Forrest M.

    pathways (RCPs 4.5 and 8.5) using the Community Earth System Model­Biogeochemistry (CESM1- BGC). CO2 fuel emissions and terrestrial carbon exchange. In the RCP8.5 simulation, where CO2 increased to 1150 emitted by human activities is taken up by the ocean or terrestrial ecosystems, with 45% remaining

  9. Impact of dynamic feedbacks between sedimentation, sea-level rise, and biomass production on near-surface marsh stratigraphy and carbon accumulation

    E-Print Network [OSTI]

    Mudd, Simon Marius

    -surface marsh stratigraphy and carbon accumulation Simon M. Mudd a,*, Susan M. Howell b , James T. Morris c model we explore how marsh stratigraphy responds to sediment supply and the rate of sea- level rise. It is calibrated and tested using an extensive data set of both marsh stratigraphy and measurements of vegetation

  10. Evaluating the Contribution of Climate Forcing and Forest Dynamics to Accelerating Carbon Sequestration by Forest Ecosystems in the Northeastern U.S.: Final Report

    SciTech Connect (OSTI)

    Munger, J. William; Foster, David R.; Richardson, Andrew D.

    2014-10-01

    This report summarizes work to improve quantitative understanding of the terrestrial ecosystem processes that control carbon sequestration in unmanaged forests It builds upon the comprehensive long-term observations of CO2 fluxes, climate and forest structure and function at the Harvard Forest in Petersham, MA. This record includes the longest CO2 flux time series in the world. The site is a keystone for the AmeriFlux network. Project Description The project synthesizes observations made at the Harvard Forest HFEMS and Hemlock towers, which represent the dominant mixed deciduous and coniferous forest types in the northeastern United States. The 20+ year record of carbon uptake at Harvard Forest and the associated comprehensive meteorological and biometric data, comprise one of the best data sets to challenge ecosystem models on time scales spanning hourly, daily, monthly, interannual and multi-decadal intervals, as needed to understand ecosystem change and climate feedbacks.

  11. Oceanflux ESA Support to Science Element Upwelling Theme Scientific and societal issues

    E-Print Network [OSTI]

    ) such as carbon dioxide (CO2), nitrous oxide (N2O) and methane (CH4) are important for understanding the global, chemical, biological, atmosphere-ocean interactions, etc.) interact with each other at different spatial organization, typical of fully developed turbulence. The methodology, based on the Microcanonical Multifractal

  12. Title: Prompt Creation of New Radiation Belts Cluster: Cross-Theme Theory and Data Analysis/SECTP

    E-Print Network [OSTI]

    Lotko, William

    Title: Prompt Creation of New Radiation Belts Cluster: Cross-Theme Theory and Data Analysis/SECTP Contributor: William Lotko/Dartmouth College · Radiation belt genesis via shock-induced magnetospheric compression The unexpected creation of new electron and proton radiation belts during the March 24, 1991

  13. Nuclear Power and Its Fuel Cycle No technological system more dramatically illustrates the central themes of this book-

    E-Print Network [OSTI]

    Kammen, Daniel M.

    109 7 Nuclear Power and Its Fuel Cycle No technological system more dramatically illustrates public opinion toward nuclear technology. But probably the biggest obstacle to further nuclear the central themes of this book- the complexity of real world applications of technology and the pitfalls

  14. Brain-Computer Interfaces for HCI and In this workshop we study the research themes and the

    E-Print Network [OSTI]

    Nijholt, Anton

    Brain-Computer Interfaces for HCI and Games Abstract In this workshop we study the research themes and the state-of-the-art of brain-computer interaction. Brain- computer interface research has seen much for the treatment of neurological disorders. Here, however, we look at brain-computer interaction especially

  15. Experience us with dark theme 0 comments TweetTweet 12 3 0ShareShare TEXT SIZEE-MAIL

    E-Print Network [OSTI]

    Trainor, Laurel J.

    Experience us with dark theme 0 comments TweetTweet 12 3 0ShareShare TEXT SIZEE-MAIL Bouncing been facing the baby then performed several simple tasks #12;Around the web 5 Nice Things Guys Do in Sexual ... 1 comment · 2 days ago Joe -- I'm astonished that a web site that bills itself "science world

  16. Title: Prompt Creation of New Radiation Belts Cluster: Cross-Theme Theory and Data Analysis/SECTP

    E-Print Network [OSTI]

    Lotko, William

    Title: Prompt Creation of New Radiation Belts Cluster: Cross-Theme Theory and Data Analysis-pushing code for radiation belt particles in a global MHD simulation of the solar wind/SECTP Contributor: William Lotko/Dartmouth College · Radiation belt genesis via shock-induced magnetospheric

  17. Natural materials for carbon capture.

    SciTech Connect (OSTI)

    Myshakin, Evgeniy M.; Romanov, Vyacheslav N.; Cygan, Randall Timothy

    2010-11-01

    Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

  18. All themed buffets include tea and water. Buffets are priced per person with a minimum of 20 guests and a maximum of two

    E-Print Network [OSTI]

    THEMED BUFFETS All themed buffets include tea and water. Buffets are priced per person Green beans, fire-roasted seasonal vegetables or broccoli. THEMEDBUFFETS Oklahoma Grill Buffet #12, smoked sausage, grilled portobello (vegetarian). VEGETABLES green beans, seasonal fire-roasted vegetables

  19. A 10-year content analysis to assess research theme areas in agricultural education: gap analysis of future research priorities in the discipline. 

    E-Print Network [OSTI]

    Edgar, Leslie Dawn

    2009-05-15

    content analysis of research published in premier journals in agricultural education. The study ascertained primary research themes, types of research conducted, prolifically published authors, frequently cited authors, and frequently cited referenced... of Applied Communications (41%); and Journal of Leadership Education (41%). The study identified primary and secondary research themes, prolific authorship, research methods and types, and frequently cited authors and referenced works in each...

  20. Reassessing Fast Water Transport Through Carbon Nanotubes

    E-Print Network [OSTI]

    McGaughey, Alan

    carbon nanotubes (CNTs) with diameters ranging from 1.66 to 4.99 nm is examined using molecular dynamics rates of pressure-driven water through membranes of 1.6 and 7 nm diameter carbon nanotubes (CNTs in the molecular sieving, chemical detection, and drug delivery fields, where such high flow rates would

  1. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  2. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  3. Carbon Sequestration

    SciTech Connect (OSTI)

    2013-05-06

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  4. Linkage of MIKE SHE to Wetland-DNDC for carbon budgeting and anaerobic biogeochemistry

    E-Print Network [OSTI]

    . Introduction Increasing emissions of carbon dioxide, methane, and other greenhouse gases (GHGs) are believed 2004 Key words: Biogeochemical modeling, Carbon dynamics, Forest wetland, Greenhouse gases emission and forest management practices on GHGs emissions and carbon dynamics to test the capabilities of the models

  5. Carbon particles

    DOE Patents [OSTI]

    Hunt, Arlon J. (Oakland, CA)

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  6. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  7. El Nino -Southern Oscillations: Phenomenology and dynamical background Eli Tziperman

    E-Print Network [OSTI]

    Tziperman, Eli

    Lecture 1 El Nino - Southern Oscillations: Phenomenology and dynamical background Eli Tziperman 1 and animations are available on the El Nino theme page at http://www.pmel.noaa.gov/tao/elnino/nino- home anomalies during La Nina, normal conditions and during El Nino are shown in Fig. 15. The slope

  8. Area of Interest 1, CO2 at the Interface. Nature and Dynamics of the Reservoir/Caprock Contact and Implications for Carbon Storage Performance

    SciTech Connect (OSTI)

    Mozley, Peter; Evans, James; Dewers, Thomas

    2014-10-31

    We examined the influence of geologic features present at the reservoir/caprock interface on the transmission of supercritical CO2 into and through caprock. We focused on the case of deformation-band faults in reservoir lithologies that intersect the interface and transition to opening-mode fractures in caprock lithologies. Deformation-band faults are exceeding common in potential CO2 injection units and our fieldwork in Utah indicates that this sort of transition is common. To quantify the impact of these interface features on flow and transport we first described the sedimentology and permeability characteristics of selected sites along the Navajo Sandstone (reservoir lithology) and Carmel Formation (caprock lithology) interface, and along the Slickrock Member (reservoir lithology) and Earthy Member (caprock lithology) of the Entrada Sandstone interface, and used this information to construct conceptual permeability models for numerical analysis. We then examined the impact of these structures on flow using single-phase and multiphase numerical flow models for these study sites. Key findings include: (1) Deformation-band faults strongly compartmentalize the reservoir and largely block cross-fault flow of supercritical CO2. (2) Significant flow of CO2 through the fractures is possible, however, the magnitude is dependent on the small-scale geometry of the contact between the opening-mode fracture and the deformation band fault. (3) Due to the presence of permeable units in the caprock, caprock units are capable of storing significant volumes of CO2, particularly when the fracture network does not extend all the way through the caprock. The large-scale distribution of these deformation-bandfault-to-opening-mode-fractures is related to the curvature of the beds, with greater densities of fractures in high curvature regions. We also examined core and outcrops from the Mount Simon Sandstone and Eau Claire Formation reservoir/caprock interface in order to extend our work to a reservoir/caprock pair this is currently being assessed for long-term carbon storage. These analyses indicate that interface features similar to those observed at the Utah sites 3 were not observed. Although not directly related to our main study topic, one byproduct of our investigation is documentation of exceptionally high degrees of heterogeneity in the pore-size distribution of the Mount Simon Sandstone. This suggests that the unit has a greater-than-normal potential for residual trapping of supercritical CO2.

  9. Simple dynamics as a tool In this chapter, the progression of the course from simple to complicated dynamics

    E-Print Network [OSTI]

    Katok, Anatole

    uses. Accordingly, the main theme of this chapter is to present case studies of using the Contraction theory of differential equations. In this chapter we maintain the same standard of proof as in the course development, and are standard tools in dynamics. This chapter does not present nearly all such applications

  10. Numerical Investigation of the Effect of Chirality of Carbon Nanotube on the Interfacial Thermal Resistance 

    E-Print Network [OSTI]

    Hu, Yuzhu

    2014-06-05

    . In this study, the interfacial thermal resistance between a carbon nanotube (CNT) and carbonate molten salt eutectics were calculated by using numerical models that were then implemented in Molecular Dynamics (MD) simulations. The estimates for “R_(k)” obtained...

  11. Carbon investment funds

    SciTech Connect (OSTI)

    2007-01-15

    The report is a study of the development of funds to invest in the purchase of carbon credits. It takes a look at the growing market for carbon credits, the rise of carbon investment funds, and the current state of carbon investing. Topics covered in the report include: Overview of climate change, greenhouse gases, and the Kyoto Protocols. Analysis of the alternatives for reducing carbon emissions including nitrous oxide reduction, coal mine methane capture and carbon capture and storage; Discussion of the different types of carbon credits; Discussion of the basics of carbon trading; Evaluation of the current status of carbon investing; and Profiles of 37 major carbon investment funds worldwide.

  12. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    Li, M. Daskin. 2009. Carbon Footprint and the Management ofThe Importance of Carbon Footprint Estimation Boundaries.Carbon accounting and carbon footprint - more than just

  13. Public Review Draft: A Method for Assessing Carbon Stocks, Carbon

    E-Print Network [OSTI]

    Public Review Draft: A Method for Assessing Carbon Stocks, Carbon Sequestration, and Greenhouse, and Zhu, Zhiliang, 2010, Public review draft; A method for assessing carbon stocks, carbon sequestration

  14. Carbon Fiber Consortium | Partnerships | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Fiber Consortium SHARE Carbon Fiber Consortium Oak Ridge Carbon Fiber Composites Consortium The Oak Ridge Carbon Fiber Composites Consortium was established in 2011 to...

  15. Photophysics of carbon nanotubes

    E-Print Network [OSTI]

    Samsonidze, Georgii G

    2007-01-01

    This thesis reviews the recent advances made in optical studies of single-wall carbon nanotubes. Studying the electronic and vibrational properties of carbon nanotubes, we find that carbon nanotubes less than 1 nm in ...

  16. Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production

    E-Print Network [OSTI]

    Narasayya, Vivek

    #12;Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward

  17. Multiscale remote sensing of plant physiology and carbon uptake 

    E-Print Network [OSTI]

    Atherton, Jon Mark

    2012-06-25

    This study investigated the use of optical remote sensing for estimating leaf and canopy scale light use efficiency (LUE) and carbon exchange. In addition, a new leaf level model capable of predicting dynamic changes in ...

  18. Control strategies for supercritical carbon dioxide power conversion systems

    E-Print Network [OSTI]

    Carstens, Nathan, 1978-

    2007-01-01

    The supercritical carbon dioxide (S-C02) recompression cycle is a promising advanced power conversion cycle which couples well to numerous advanced nuclear reactor designs. This thesis investigates the dynamic simulation ...

  19. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B. (16716 Martincoit Rd., Poway, CA 92064)

    1993-01-01

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  20. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  1. Ecosystem Carbon Storage Across the GrasslandForest Transition

    E-Print Network [OSTI]

    Silman, Miles R.

    of the large soil carbon stocks under an afforestation scenario exist. Key words: Peru; Manu National Park, JBF, and PM conceived of or designed this study; AG, MRS, MZ, GCD, WRF, and KCG performed re- search in the newly created carbon markets and funds (Glenday 2006). Similarly, the size and dynamics of the above

  2. Ecosystem Carbon Storage Across the GrasslandForest Transition

    E-Print Network [OSTI]

    Malhi, Yadvinder

    of the large soil carbon stocks under an afforestation scenario exist. Key words: Peru; Manu National Park 2010 Author Contributions: AG, MRS, YM, JBF, and PM conceived of or designed this study; AG, MRS, MZ in the newly created carbon markets and funds (Glenday 2006). Similarly, the size and dynamics of the above

  3. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  4. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  5. Relationships between daytime carbon dioxide uptake and absorbed photosynthetically active radiation for three different mountain/plains

    E-Print Network [OSTI]

    Hunt Jr., E. Raymond

    Relationships between daytime carbon dioxide uptake and absorbed photosynthetically active and Atmospheric Dynamics: Boundary layer processes; KEYWORDS: CO2 flux, absorbed PAR, carbon cycle, remote sensing Change: Biogeochemical processes (4805); 1640 Global Change: Remote sensing; 3307 Meteorology

  6. Toilet Theme Park

    E-Print Network [OSTI]

    Hacker, Randi

    2013-02-27

    of the world's first toilet culture park centered around a toilet-shaped building that was once the home of Sim Jae-duck, founder of the World Toilet Association, a group dedicated to bringing hygienic bathrooms to all world citizens. Famously born in his poor...

  7. ARM - Research Themes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of raregovAboutRecovery Act Recovery Act Logo Subscribe FAQsgovScienceResearch

  8. 1) From: Nickolas Themelis to WHO Communications Office, Dec 9, 2008 To: Setiogi, Sari; Osseiran, Nada WHO

    E-Print Network [OSTI]

    Columbia University

    by the US waste-to- energy industry (activated carbon injection fabric bag filters, etc.) by 2000 reduced of combustion gases and waste or fuel feed. Good combustion practices include management o by products of industrial processes but can also result from natural processes, such as volcanic eruptions

  9. Image Framing in Climate Change News Stories, p-1 Image Themes and Frames in U.S. Print News Stories about Climate Change

    E-Print Network [OSTI]

    Hespanha, João Pedro

    Image Framing in Climate Change News Stories, p-1 Image Themes and Frames in U.S. Print News Stories about Climate Change Stacy Rebich-Hespanha, Ronald E. Rice, Daniel R. Montello, Sean Retzloff, Sandrine Tien & João P. Hespanha Research on frames in climate change news coverage has advanced

  10. Strategy for SUPA Condensed Matter and Material Physics Theme, 2012 Introduction Condensed Matter and Materials Physics (CMMP) as a field is dually motivated by

    E-Print Network [OSTI]

    Greenaway, Alan

    Strategy for SUPA Condensed Matter and Material Physics Theme, 2012 Introduction Condensed Matter optics Energy/Photonics: photovoltaics, solid-state lighting and fuel-cells PALS: statistical mechanics the best students who are available on the UK, European, and world-wide markets. With this in mind

  11. Drug discovery, design and development is an overarching theme for much of the research taking place through the University's Department of Pharmacy and Pharmacology.

    E-Print Network [OSTI]

    Burton, Geoffrey R.

    Drug discovery, design and development is an overarching theme for much of the research taking and central nervous system disorders such as epilepsy, depression, anxiety and drug abuse. The following. University of Bath Drug discovery and development at Bath #12;Tumour-selective delivery of potent drugs

  12. Theme Issue "Trends in Formal Description Techniques" In the 80s, we witnessed the development and international standardization of the Formal

    E-Print Network [OSTI]

    Bredereke, Jan - Fachbereich 3

    Page 1 Theme Issue "Trends in Formal Description Techniques" Editorial In the 80s, we witnessed the development and international standardization of the Formal Description Techniques (FDTs) Estelle, LOTOS underwent substantial extensions, while the Estelle and LOTOS standards remained relatively stable

  13. 2.7 Research Testbeds and Data Practices (DATA) These projects are both testbeds and empirical research; the common theme is collaboration, both local and

    E-Print Network [OSTI]

    Soatto, Stefano

    research; the common theme is collaboration, both local and distributed. We are exploring multiple aspects Reuse and Exchange is a technology project that builds upon our earlier work in CENS data practices, extending it to deploy new technical standards to represent and to link research objects. We partnered

  14. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J. (6204 Shadow Mountain Dr., Austin, TX 78731)

    1998-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  15. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J. (6204 Shadow Mountain Dr., Austin, TX 78731)

    1999-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  16. Carbon Nanotube Based Sensors

    SciTech Connect (OSTI)

    Jiang, Mian; Lin, Yuehe

    2006-11-01

    This review article provides a comprehensive review on sensors and biosensors based on functionalized carbon nanotubes.

  17. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, R.J.

    1998-02-10

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

  18. Carbon Monoxide Environmental Public

    E-Print Network [OSTI]

    The National Workgroup on Carbon Monoxide Surveillance Formed in April 2005 Membership: EPHT grantees Academic

  19. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Fulvio, Pasquale Fernando; Mayes, Richard T.; Wang, Xiqing; Sun, Xiao-Guang; Guo, Bingkun

    2014-09-09

    A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

  20. Effects of grazing intensity on soil carbon stocks following deforestation of a Hawaiian dry tropical forest

    E-Print Network [OSTI]

    Elmore, Andrew J.

    : carbon isotopes, elevation, Hawai'i, imaging spectroscopy, land-use change, pastures, remote sensing be addressed, future changes in ecosystem dynamics and atmospheric carbon dioxide cannot be easily predictedEffects of grazing intensity on soil carbon stocks following deforestation of a Hawaiian dry

  1. Global carbon budget 2014

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Le Quéré, C.; Moriarty, R.; Andrew, R. M.; Peters, G. P.; Ciais, P.; Friedlingstein, P.; Jones, S. D.; Sitch, S.; Tans, P.; Arneth, A.; et al

    2015-05-08

    Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates, consistency within and among components, alongside methodology and data limitations. CO2 emissionsmore »from fossil fuel combustion and cement production (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover-change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO2, and land-cover-change (some including nitrogen–carbon interactions). We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as ±1?;, reflecting the current capacity to characterise the annual estimates of each component of the global carbon budget. For the last decade available (2004–2013), EFF was 8.9 ± 0.4 GtC yr?¹,ELUC 0.9 ± 0.5 GtC yr?¹, GATM 4.3 ± 0.1 GtC yr?¹, SOCEAN 2.6 ± 0.5 GtC yr?¹, and SLAND 2.9 ± 0.8 GtC yr?¹. For year 2013 alone, EFF grew to 9.9 ± 0.5 GtC yr?¹, 2.3% above 2012, continuing the growth trend in these emissions, ELUC was 0.9 ± 0.5 GtC yr?¹, GATM was 5.4 ± 0.2 GtC yr?¹, SOCEAN was 2.9 ± 0.5 GtC yr?¹, and SLAND was 2.5 ± 0.9 GtC yr?¹. GATM was high in 2013, reflecting a steady increase in EFF and smaller and opposite changes between SOCEAN and SLAND compared to the past decade (2004–2013). The global atmospheric CO2 concentration reached 395.31 ± 0.10 ppm averaged over 2013. We estimate that EFF will increase by 2.5% (1.3–3.5%) to 10.1 ± 0.6 GtC in 2014 (37.0 ± 2.2 GtCO2 yr?¹), 65% above emissions in 1990, based on projections of world gross domestic product and recent changes in the carbon intensity of the global economy. From this projection of EFF and assumed constant ELUC for 2014, cumulative emissions of CO2 will reach about 545 ± 55 GtC (2000 ± 200 GtCO2) for 1870–2014, about 75% from EFF and 25% from ELUC. This paper documents changes in the methods and data sets used in this new carbon budget compared with previous publications of this living data set (Le Quéré et al., 2013, 2014). All observations presented here can be downloaded from the Carbon Dioxide Information Analysis Center (doi:10.3334/CDIAC/GCP_2014).« less

  2. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA)

    2012-04-10

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  3. Carbon Nanostructure-Based Sensors

    E-Print Network [OSTI]

    Sarkar, Tapan

    2012-01-01

    Control of Single-Walled Carbon Nanotube Functionalization.M. S. Characterizing carbon nanotube samples with resonancewith a Single-Walled Carbon Nanotube Capacitor. Science

  4. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  5. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou (Berkeley, CA); Crespi, Vincent Henry (Darien, IL); Louie, Steven Gwon Sheng (Berkeley, CA); Zettl, Alexander Karlwalter (Kensington, CA)

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  6. Carbon nanotube nanoelectrode arrays

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Lin, Yuehe (Richland, WA); Yantasee, Wassana (Richland, WA); Liu, Guodong (Fargo, ND); Lu, Fang (Burlingame, CA); Tu, Yi (Camarillo, CA)

    2008-11-18

    The present invention relates to microelectode arrays (MEAs), and more particularly to carbon nanotube nanoelectrode arrays (CNT-NEAs) for chemical and biological sensing, and methods of use. A nanoelectrode array includes a carbon nanotube material comprising an array of substantially linear carbon nanotubes each having a proximal end and a distal end, the proximal end of the carbon nanotubes are attached to a catalyst substrate material so as to form the array with a pre-determined site density, wherein the carbon nanotubes are aligned with respect to one another within the array; an electrically insulating layer on the surface of the carbon nanotube material, whereby the distal end of the carbon nanotubes extend beyond the electrically insulating layer; a second adhesive electrically insulating layer on the surface of the electrically insulating layer, whereby the distal end of the carbon nanotubes extend beyond the second adhesive electrically insulating layer; and a metal wire attached to the catalyst substrate material.

  7. Does carbon dioxide pool or stream in the subsurface?

    E-Print Network [OSTI]

    Cardoso, Silvana S S

    2014-01-01

    Pools of carbon dioxide are found in natural geological accumulations and in engineered storage in saline aquifers. It has been thought that once this CO2 dissolves in the formation water, making it denser, convection streams would transport it efficiently to depth, but this may not be so. Here, we assess the impact of natural chemical reactions between the dissolved CO2 and the rock formation on the convection streams in the subsurface. We show that, while in carbonate rocks the streaming of dissolved carbon dioxide persists, the chemical interactions in silicate-rich rocks may curb this transport drastically and even inhibit it altogether. New laboratory experiments confirm the curtailing of convection by reaction. Wide and narrow streams of dense carbon-rich water are shut-off gradually as reaction strength increases until all transport of the pooled carbon dioxide occurs by slow molecular diffusion. These results show that the complex fluid dynamic and kinetic interactions between pooled carbon dioxide an...

  8. ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh

    E-Print Network [OSTI]

    California at Santa Barbara, University of

    1 ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh Bren hall 3422, suh Week 1: Introduction to carbon footprint and carbon account - Background: carbon awareness, major out a report or a web site about carbon footprint results of a product or of a company. Write a two

  9. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  10. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F. (Los Angeles, CA); Vajo, John J. (West Hills, CA); Cumberland, Robert W. (Malibu, CA); Liu, Ping (Irvine, CA); Salguero, Tina T. (Encino, CA)

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  11. Carbon Footprint Towson University

    E-Print Network [OSTI]

    Fath, Brian D.

    Carbon Footprint Towson University GHG Inventory for Educational Institutes Getting Starting.TM The Carbon Footprint 8 The Constellation Experience A Broad Inventory 1. Scope I-Direct Emissions works.TM The Carbon Footprint 10 The Constellation Experience A Broad Inventory 3. Scope III

  12. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  13. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  14. Extension of the supercritical carbon dioxide brayton cycle to low reactor power operation: investigations using the coupled anl plant dynamics code-SAS4A/SASSYS-1 liquid metal reactor code system.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J.

    2012-05-10

    Significant progress has been made on the development of a control strategy for the supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle enabling removal of power from an autonomous load following Sodium-Cooled Fast Reactor (SFR) down to decay heat levels such that the S-CO{sub 2} cycle can be used to cool the reactor until decay heat can be removed by the normal shutdown heat removal system or a passive decay heat removal system such as Direct Reactor Auxiliary Cooling System (DRACS) loops with DRACS in-vessel heat exchangers. This capability of the new control strategy eliminates the need for use of a separate shutdown heat removal system which might also use supercritical CO{sub 2}. It has been found that this capability can be achieved by introducing a new control mechanism involving shaft speed control for the common shaft joining the turbine and two compressors following reduction of the load demand from the electrical grid to zero. Following disconnection of the generator from the electrical grid, heat is removed from the intermediate sodium circuit through the sodium-to-CO{sub 2} heat exchanger, the turbine solely drives the two compressors, and heat is rejected from the cycle through the CO{sub 2}-to-water cooler. To investigate the effectiveness of shaft speed control, calculations are carried out using the coupled Plant Dynamics Code-SAS4A/SASSYS-1 code for a linear load reduction transient for a 1000 MWt metallic-fueled SFR with autonomous load following. No deliberate motion of control rods or adjustment of sodium pump speeds is assumed to take place. It is assumed that the S-CO{sub 2} turbomachinery shaft speed linearly decreases from 100 to 20% nominal following reduction of grid load to zero. The reactor power is calculated to autonomously decrease down to 3% nominal providing a lengthy window in time for the switchover to the normal shutdown heat removal system or for a passive decay heat removal system to become effective. However, the calculations reveal that the compressor conditions are calculated to approach surge such that the need for a surge control system for each compressor is identified. Thus, it is demonstrated that the S-CO{sub 2} cycle can operate in the initial decay heat removal mode even with autonomous reactor control. Because external power is not needed to drive the compressors, the results show that the S-CO{sub 2} cycle can be used for initial decay heat removal for a lengthy interval in time in the absence of any off-site electrical power. The turbine provides sufficient power to drive the compressors. Combined with autonomous reactor control, this represents a significant safety advantage of the S-CO{sub 2} cycle by maintaining removal of the reactor power until the core decay heat falls to levels well below those for which the passive decay heat removal system is designed. The new control strategy is an alternative to a split-shaft layout involving separate power and compressor turbines which had previously been identified as a promising approach enabling heat removal from a SFR at low power levels. The current results indicate that the split-shaft configuration does not provide any significant benefits for the S-CO{sub 2} cycle over the current single-shaft layout with shaft speed control. It has been demonstrated that when connected to the grid the single-shaft cycle can effectively follow the load over the entire range. No compressor speed variation is needed while power is delivered to the grid. When the system is disconnected from the grid, the shaft speed can be changed as effectively as it would be with the split-shaft arrangement. In the split-shaft configuration, zero generator power means disconnection of the power turbine, such that the resulting system will be almost identical to the single-shaft arrangement. Without this advantage of the split-shaft configuration, the economic benefits of the single-shaft arrangement, provided by just one turbine and lower losses at the design point, are more important to the overall cycle performance. Therefore, the single-shaft

  15. Soil carbon sensitivity to temperature and carbon use efficiency compared across microbial-ecosystem models of varying complexity

    SciTech Connect (OSTI)

    Li, Jianwei [University of Oklahoma] [University of Oklahoma; Wang, Gangsheng [ORNL] [ORNL; Allison, Steven D. [University of California, Irvine] [University of California, Irvine; Mayes, Melanie [ORNL] [ORNL; Luo, Yiqi [University of Oklahoma] [University of Oklahoma

    2014-01-01

    Global ecosystem models may require microbial components to accurately predict feedbacks between climate warming and soil decomposition, but it is unclear what parameters and levels of complexity are ideal for scaling up to the globe. Here we conducted a model comparison using a conventional model with first-order decay and three microbial models of increasing complexity that simulate short- to long-term soil carbon dynamics. We focused on soil carbon responses to microbial carbon use efficiency (CUE) and temperature. Three scenarios were implemented in all models: constant CUE (held at 0.31), varied CUE ( 0.016 C 1), and 50 % acclimated CUE ( 0.008 C 1). Whereas the conventional model always showed soil carbon losses with increasing temperature, the microbial models each predicted a temperature threshold above which warming led to soil carbon gain. The location of this threshold depended on CUE scenario, with higher temperature thresholds under the acclimated and constant scenarios. This result suggests that the temperature sensitivity of CUE and the structure of the soil carbon model together regulate the long-term soil carbon response to warming. Equilibrium soil carbon stocks predicted by the microbial models were much less sensitive to changing inputs compared to the conventional model. Although many soil carbon dynamics were similar across microbial models, the most complex model showed less pronounced oscillations. Thus, adding model complexity (i.e. including enzyme pools) could improve the mechanistic representation of soil carbon dynamics during the transient phase in certain ecosystems. This study suggests that model structure and CUE parameterization should be carefully evaluated when scaling up microbial models to ecosystems and the globe.

  16. Photoelectron Imaging of Hydrated Carbon Dioxide Cluster Anions Eric Surber, Richard Mabbs, Terefe Habteyes, and Andrei Sanov*

    E-Print Network [OSTI]

    Sanov, Andrei

    Photoelectron Imaging of Hydrated Carbon Dioxide Cluster Anions Eric Surber, Richard Mabbs, Terefe solvation on the electronic structure and photodetachment dynamics of hydrated carbon dioxide cluster anions and carbon dioxide. The effect of hydration on the electronic structure of ions has far- reaching

  17. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  18. Organic carbon burial forcing of the carbon cycle from

    E-Print Network [OSTI]

    Derry, Louis A.

    Organic carbon burial forcing of the carbon cycle from Himalayan erosion Christian France . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Weathering and erosion can affect the long-term ocean­atmo- sphere budget of carbon dioxide both through of Neogene Himalayan erosion on the carbon cycle is an increase in the amount of organic carbon

  19. CARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE

    E-Print Network [OSTI]

    Bateman, Ian J.

    constraint to these relationships, with the carbon dioxide emissions from fossil fuel consumption pressingCARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE by Dennis Anderson CSERGE GEC Working Paper 92-28 #12;CARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE by Dennis Anderson

  20. Carbon Code Requirements for voluntary carbon sequestration projects

    E-Print Network [OSTI]

    and individuals wishing to reduce their carbon footprint while also delivering a range of other environmentalWoodland Carbon Code Requirements for voluntary carbon sequestration projects ® Version 1.2 July of group schemes 8 2.6 Monitoring 9 2.7 Carbon statements and reporting 9 2.8 Woodland Carbon Code

  1. Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions

    E-Print Network [OSTI]

    Balser, Dana S.

    Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions Dana S. Balser D. Anish Roshi (Raman (Agnes Scott College) #12;Carbon RRLs Carbon Radio Recombination Lines (RRLs) NGC 2024 (Orion B) IC 1795 (W3) Palmer et al. (1967) #12;Carbon RRLs Photodissociation Regions (PDRs) Hollenbach & Tielens (1997

  2. Carbon Sequestration via Mineral Carbonation: Overview and Assessment

    E-Print Network [OSTI]

    1 Carbon Sequestration via Mineral Carbonation: Overview and Assessment 14 March 2002 Howard Herzog overview and assessment of carbon sequestration by mineral carbonation (referred to as "mineral sequestration R&D. The first is that carbonates have a lower energy state than CO2. Therefore, at least

  3. Project Profile: Carbon Dioxide Shuttling Thermochemical Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Profile: Carbon Dioxide Shuttling Thermochemical Storage Using Strontium Carbonate Project Profile: Carbon Dioxide Shuttling Thermochemical Storage Using Strontium...

  4. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Wang, Xiqing (Oak Ridge, TN)

    2012-02-14

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  5. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2013-08-20

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  6. Sandia Energy - Scattering Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scattering Dynamics Home Transportation Energy Predictive Simulation of Engines Combustion Chemistry Chemical Dynamics Scattering Dynamics Scattering DynamicsAshley...

  7. Activated Carbon Injection

    ScienceCinema (OSTI)

    None

    2014-07-22

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  8. Activated Carbon Injection

    SciTech Connect (OSTI)

    2014-07-16

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  9. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    Y. Li, M. Daskin. 2009. Carbon Footprint and the ManagementJ. van Houtum. 2011. E?ect of carbon emission regulations onStreamlined Enterprise Carbon Footprinting. Environmental

  10. Effect of Different Carbon Sources on the Growth of Single-Walled Carbon Nanotube from MCM-41 Containing Nickel

    SciTech Connect (OSTI)

    Chen,Y.; Wang, B.; Li, L.; Yang, Y.; Ciuparu, D.; Lim, S.; Haller, G.; Pfefferle, L.

    2007-01-01

    Chemical vapor deposition growth of single-walled carbon nanotubes (SWCNTs) was studied using three representative carbon source sources: CO, ethanol, and methane, and a catalyst of Ni ions incorporated in MCM-41. The resulting SWCNTs were compared for similar reaction conditions. Carbon deposits were analyzed by multi-excitation wavelength Raman, TGA, TEM and AFM. Catalytic particles in the Ni-MCM-41 catalysts were characterized by TEM and synchrotron light source X-ray absorption spectroscopy. Under similar synthesis conditions, SWCNTs produced from CO had a relatively smaller diameter, while those from ethanol had a larger diameter. Methane could not produce SWCNTs on Ni-MCM-41 under the conditions used in this research. These results demonstrate that three carbon sources affect the dynamic balances between metallic cluster formation and carbon deposition/precipitation on the metallic cluster surface. Controlling SWCNT diameter relies on precisely regulating this dynamic process. Using different carbon sources we are able to shift this dynamic balance and produce SWCNTs with different mean diameters.

  11. Cropland carbon fluxes in the United States: increasing Geospatial Resolution of Inventory-Based Carbon Accounting

    SciTech Connect (OSTI)

    West, Tristram O. [ORNL; Brandt, Craig C [ORNL; Baskaran, Latha Malar [ORNL; Hellwinckel, Chad M [ORNL; Marland, Gregg [ORNL; Nelson, Richard G [ORNL; De La Torre Ugarte, Daniel G [ORNL; Post, Wilfred M [ORNL

    2010-01-01

    Net annual soil carbon change, fossil fuel emissions from cropland production, and cropland net primary productivity were estimated and spatially distributed using land cover defined by the Moderate Resolution Imaging Spectroradiometer (MODIS) and by the Cropland Data Layer (CDL). Spatially resolved estimates of net ecosystem exchange (NEE) and net ecosystem carbon balance (NECB) were developed. NEE represents net on-site vertical fluxes of carbon. NECB represents all on-site and off-site carbon fluxes associated with crop production. Estimates of cropland NEE using moderate resolution (~1km2) land cover data were generated for the conterminous US and compared with higher resolution (30m) estimates of NEE and with direct measurements of CO2 flux from croplands in Illinois and Nebraska. Estimates of NEE using the CDL (30m resolution) had a higher correlation with eddy covariance flux tower estimates compared with estimates of NEE using MODIS. Estimates of NECB are primarily driven by net soil carbon change, fossil-fuel emissions associated with crop production, and CO2 emissions from the application of agricultural lime. NEE and NECB for US croplands were -274 and 7 Tg C yr-1 for 2004, respectively. Use of moderate to high resolution satellite-based land cover data enables improved estimates of cropland carbon dynamics.

  12. Market-Based Emissions Regulation and Industry Dynamics

    E-Print Network [OSTI]

    Fowlie, Meredith

    We assess the long-run dynamic implications of market-based regulation of carbon dioxide emissions in the US Portland cement industry. We consider several alternative policy designs, including mechanisms that use production ...

  13. Linear Dynamic Programs for Resource Management Marek Petrik

    E-Print Network [OSTI]

    Zilberstein, Shlomo

    dynamic programming, a method used to optimize hydroelectric systems. 1 Introduction Sequential decision a river reservoir to produce hydroelectric power. Among renewable sources, hydroelectricity has the lowest management can therefore significantly reduce carbon emissions. Hydroelectric power is usually produced

  14. Dynamic reduced order modeling of entrained flow gasifiers

    E-Print Network [OSTI]

    Monaghan, Rory F. D. (Rory Francis Desmond)

    2010-01-01

    Gasification-based energy systems coupled with carbon dioxide capture and storage technologies have the potential to reduce greenhouse gas emissions from continued use of abundant and secure fossil fuels. Dynamic reduced ...

  15. Longitudinal solitons in carbon nanotubes

    SciTech Connect (OSTI)

    Astakhova, T. Yu.; Gurin, O. D.; Menon, M.; Vinogradov, G. A.

    2001-07-15

    We present results on soliton excitations in carbon nanotubes (CNT's) using Brenner's many-body potential. Our numerical simulations demonstrate high soliton stability in (10,10) CNT's. The interactions of solitons and solitary excitation with CNT defect are found to be inelastic if the excitations and defects length scales are comparable, resulting in a substantial part of soliton energy being distributed inhomogeneously over the defect bonds. In these solitary-excitation--cap collisions the local energy of a few bonds in the cap can exceed the average energy by an order of magnitude and more. This phenomenon, denoted the ''Tsunami effect,'' can contribute dynamically to the recently proposed ''kinky chemistry.'' We also present results of changes in the local density of states and variations in the atomic partial charges estimated at different time instants of the solitary-excitation Tsunami at the nanotube cap.

  16. Carbon Park Environmental Impact Assessment

    E-Print Network [OSTI]

    of offsetting the University's carbon footprint, promoting biodiversity and establishing easily maintained Carbon Park Environmental Impact Assessment A B.E.S.T. Project By, Adam Bond 2011 #12; Bishop's University Carbon Park

  17. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of...

  18. Carbon Dioxide & Global Warming

    E-Print Network [OSTI]

    Miami, University of

    Carbon Dioxide & Global Warming University of MiaMi rosenstiel sChool of Marine anD atMospheriC s , organic carbon, and other chemicals that contribute to global warming in a variety of studies. DownCienCe 4600 rickenbacker Causeway Miami, florida 33149 http://www.rsmas.miami.edu the Chemistry of Global

  19. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, Stephen E. (Pinole, CA); Moses, William W. (Berkeley, CA)

    1991-01-01

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses.

  20. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  1. Acoustic energy dissipation and thermalization in carbon nanotubes: Atomistic modeling and mesoscopic description

    E-Print Network [OSTI]

    Nicholson, David A.

    The exchange of energy between low-frequency mechanical oscillations and high-frequency vibrational modes in carbon nanotubes (CNTs) is a process that plays an important role in a range of dynamic phenomena involving the ...

  2. Elucidating Nucleation and Growth Behavior of Single-Walled Carbon Nanotubes obtained via Catalyzed Synthesis 

    E-Print Network [OSTI]

    Burgos Beltran, Juan Carlos

    2014-11-07

    The catalytic growth of single-walled carbon nanotubes (SWCNTs) is studied using reactive molecular dynamics (RMD) simulations and density functional theory (DFT) calculations. Computational calculations are performed in order to achieve a better...

  3. Exciton diffusion in semiconducting single-walled carbon nanotubes studied by transient absorption microscopy

    E-Print Network [OSTI]

    Ruzicka, Brian Andrew; Wang, Rui; Lohrman, Jessica; Ren, Shenqiang; Zhao, Hui

    2012-11-09

    Spatiotemporal dynamics of excitons in isolated semiconducting single-walled carbon nanotubes are studied using transient absorption microscopy. Differential reflection and transmission of an 810-nm probe pulse after excitation by a 750-nm pump...

  4. CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA: REPORT TO THE LEGISLATURE Regional Carbon Sequestration Partnership (WESTCARB) studies that we used, including Cameron Downey

  5. Axial obliquity control on the greenhouse carbon budget through middle-to high-latitude reservoirs

    E-Print Network [OSTI]

    Meyers, Stephen R.

    Axial obliquity control on the greenhouse carbon budget through middle- to high-latitude reservoirs for past greenhouse climates. Carbon-isotope data indicate systematic, million-year-scale transfers-stable character, they might have provided an important control on the dynamics and stability of the greenhouse

  6. Highly efficient separation of carbon dioxide by a metal-organic framework replete with

    E-Print Network [OSTI]

    Yaghi, Omar M.

    media. carbon dioxide capture dynamic adsorption reticular chemistry Selective removal of CO2 fromHighly efficient separation of carbon dioxide by a metal-organic framework replete with open metal capture of CO2, which is essential for natural gas purifi- cation and CO2 sequestration, has been reported

  7. Atomic hydrogen interactions with amorphous carbon thin films Bhavin N. Jariwala,1

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Atomic hydrogen interactions with amorphous carbon thin films Bhavin N. Jariwala,1 Cristian V-scale interactions of H atoms with hydrogenated amorphous carbon a-C:H films were identified using molecular dynamics through a detailed analysis of the MD trajectories. The MD simulations showed that hydrogenation occurs

  8. Structural Testing of 9 m Carbon Fiber Wind Turbine Research Blades*

    E-Print Network [OSTI]

    Structural Testing of 9 m Carbon Fiber Wind Turbine Research Blades* Joshua Paquette Sandia Laboratory** , Golden, CO, 80401 Three 9 m carbon fiber wind turbine blades have been designed through Systems Consulting (GEC) , Dynamic Design Engineering , and MDZ Consulting§§ ; and seven blades from each

  9. Physiological impacts of elevated carbon dioxide and ocean acidification Rachael M. Heuer* and Martin Grosell*

    E-Print Network [OSTI]

    Grosell, Martin

    Physiological impacts of elevated carbon dioxide and ocean acidification on fish Rachael M. Heuer, Grosell M. Physiological impacts of elevated carbon dioxide and ocean acidification on fish. Am J Physiol in dynamic regulation of acid-base transport pathways across species, exposure levels, and exposure duration

  10. North America's forests are thought to be a significant sink for atmospheric carbon.

    E-Print Network [OSTI]

    Lawrence, Rick L.

    reflects the frequency of disturbance. In fact, one explanation for the forest sink in the eastern United carbon flux reflect a lack of detailed knowledge about the effects of forest disturbance and recovery highlighted forest disturbance as a critical factor constraining carbon dynamics [Wofsy and Harris, 2002

  11. Simulating the Impact of a Carbon Market Electricity System in the Western U.S.A.

    E-Print Network [OSTI]

    Ford, Andrew

    , electricity markets, power plants, transmission network, renewable resources, system dynamics, computerSimulating the Impact of a Carbon Market on the Electricity System in the Western U.S.A. Andrew and trade market to control carbon emissions in the western electricity system. The simulations indicate

  12. Trading Water for Carbon with Biological Carbon Sequestration

    E-Print Network [OSTI]

    Jackson, Robert B.

    Trading Water for Carbon with Biological Carbon Sequestration Robert B. Jackson,1 * Esteban G. Farley,1 David C. le Maitre,5 Bruce A. McCarl,6 Brian C. Murray7 Carbon sequestration strategies plantations feature prominently among tools for carbon sequestration (1­8). Plantations typi- cally combine

  13. IMPACCT: Carbon Capture Technology

    SciTech Connect (OSTI)

    2012-01-01

    IMPACCT Project: IMPACCT’s 15 projects seek to develop technologies for existing coal-fired power plants that will lower the cost of carbon capture. Short for “Innovative Materials and Processes for Advanced Carbon Capture Technologies,” the IMPACCT Project is geared toward minimizing the cost of removing carbon dioxide (CO2) from coal-fired power plant exhaust by developing materials and processes that have never before been considered for this application. Retrofitting coal-fired power plants to capture the CO2 they produce would enable greenhouse gas reductions without forcing these plants to close, shifting away from the inexpensive and abundant U.S. coal supply.

  14. Improving carbon fixation pathways

    SciTech Connect (OSTI)

    Ducat, DC; Silver, PA

    2012-08-01

    A recent resurgence in basic and applied research on photosynthesis has been driven in part by recognition that fulfilling future food and energy requirements will necessitate improvements in crop carbon-fixation efficiencies. Photosynthesis in traditional terrestrial crops is being reexamined in light of molecular strategies employed by photosynthetic microbes to enhance the activity of the Calvin cycle. Synthetic biology is well-situated to provide original approaches for compartmentalizing and enhancing photosynthetic reactions in a species independent manner. Furthermore, the elucidation of alternative carbon-fixation routes distinct from the Calvin cycle raises possibilities that novel pathways and organisms can be utilized to fix atmospheric carbon dioxide into useful materials.

  15. Altered Belowground Carbon Cycling Following Land-Use Change

    E-Print Network [OSTI]

    DeLucia, Evan H.

    Pesquisas Espaciais, Cachoeira Paulista, SP, Brazil ABSTRACT Belowground carbon (C) dynamics of terrestrial to be thoroughly quantified through field measurements. Here, we show that belowground C cycling pathways grasses; establishment phase. INTRODUCTION Terrestrial ecosystems have a pervasive influence on the global

  16. Research Report Forests and carbon

    E-Print Network [OSTI]

    , baseline, carbon, climate change mitigation, forestry, quality assurance, sequestration. FCRP013/FCResearch Report Forests and carbon: a review of additionality #12;#12;Forests and carbon: a review. ISBN 978-0-85538-816-4 Valatin, G. (2011). Forests and carbon: a review of additionality. Forestry

  17. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng

    2009-03-24

    This chapter summarizes the recent development of carbon nanotube based electrochemical biosensors work at PNNL.

  18. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng; J. A. Schwarz, C. Contescu, K. Putyera

    2004-04-01

    This invited review article summarizes recent work on biosensor development based on carbon nanotubes

  19. Method for synthesizing carbon nanotubes

    DOE Patents [OSTI]

    Fan, Hongyou

    2012-09-04

    A method for preparing a precursor solution for synthesis of carbon nanomaterials, where a polar solvent is added to at least one block copolymer and at least one carbohydrate compound, and the precursor solution is processed using a self-assembly process and subsequent heating to form nanoporous carbon films, porous carbon nanotubes, and porous carbon nanoparticles.

  20. ATK - Supersonic Carbon Capture

    ScienceCinema (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO); Calayag, Bon (ATK, Program Manager)

    2014-04-11

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  1. ATK - Supersonic Carbon Capture

    SciTech Connect (OSTI)

    Castrogiovanni, Anthony; Calayag, Bon

    2014-03-05

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  2. CARBON DIOXIDE EMISSION REDUCTION

    E-Print Network [OSTI]

    Delaware, University of

    ........................................................................................ 21 2.3.5 Pulp and paper industry Technologies and Measures in Pulp and Paper IndustryCARBON DIOXIDE EMISSION REDUCTION TECHNOLOGIES AND MEASURES IN US INDUSTRIAL SECTOR FINAL REPORT

  3. Activated carbon aerogels

    SciTech Connect (OSTI)

    Hanzawa, Y.; Kaneko, K. [Chiba Univ. (Japan)] [Chiba Univ. (Japan); Pekala, R.W. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); Dresselhaus, M.S. [Massachusetts Inst. of Technology, Cambridge, MA (United States)] [Massachusetts Inst. of Technology, Cambridge, MA (United States)

    1996-12-25

    Activated carbon aerogels were obtained from the CO{sub 2} activation of the carbon aerogels. The adsorption isotherms of nitrogen on activated carbon aerogels at 77 K were measured and analyzed by the high-resolution {alpha}{sub s} plot to evaluate their porosities. The {alpha}{sub s} plot showed an upward deviation from linearity below {alpha}{sub s} = 0.5, suggesting that the presence of micropores becomes more predominant with the extent of the activation. Activation increased noticeably the pore volume and the surface area (the maximum value: 2600 m{sup 2}.g{sup -1}) without change of the basic network structure of primary particles. Activated carbon aerogels had a bimodal pore size distribution of uniform micropores and mesopores. 16 refs., 2 figs., 1 tab.

  4. Regional Carbon Sequestration Partnerships

    Broader source: Energy.gov [DOE]

    DOE has created a network of seven Regional Carbon Sequestration Partnerships (RCSPs) to help develop the technology, infrastructure, and regulations to implement large-scale CO2 storage (also...

  5. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01

    S O N I A YE H Low Carbon Fuel Standards The most direct andalternative transportation fuels is to spur innovation withstandard for upstream fuel producers. hen it comes to energy

  6. Black Carbon’s Properties and Role in the Environment: A Comprehensive Review

    E-Print Network [OSTI]

    Shrestha, Gyami

    2010-01-01

    black carbon and carbon dioxide emissions. Energ. Policyreduces predicted carbon dioxide emissions estimation by upincrease rates of carbon dioxide emissions [135,136]. Due to

  7. Black Carbon’s Properties and Role in the Environment: A Comprehensive Review

    E-Print Network [OSTI]

    Shrestha, Gyami

    2010-01-01

    Keywords: soil carbon sequestration; carbon budget;of an energy efficient carbon sequestration mechanism, asin the later section on carbon sequestration. In atmospheric

  8. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  9. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  10. Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3)

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2 monoxide (CO), carbon dioxide (CO2), and molecular oxygen (O2) with varying carbon-to-oxygen ratios from 1 and destruction pathways of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3

  11. Separation of carbon dioxide from flue emissions using Endex principles

    E-Print Network [OSTI]

    Ball, R

    2009-01-01

    In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

  12. Measurement of carbon capture efficiency and stored carbon leakage

    SciTech Connect (OSTI)

    Keeling, Ralph F.; Dubey, Manvendra K.

    2013-01-29

    Data representative of a measured carbon dioxide (CO.sub.2) concentration and of a measured oxygen (O.sub.2) concentration at a measurement location can be used to determine whether the measured carbon dioxide concentration at the measurement location is elevated relative to a baseline carbon dioxide concentration due to escape of carbon dioxide from a source associated with a carbon capture and storage process. Optionally, the data can be used to quantify a carbon dioxide concentration increase at the first location that is attributable to escape of carbon dioxide from the source and to calculate a rate of escape of carbon dioxide from the source by executing a model of gas-phase transport using at least the first carbon dioxide concentration increase. Related systems, methods, and articles of manufacture are also described.

  13. Simple Dynamic Gasifier Model That Runs in Aspen Dynamics

    SciTech Connect (OSTI)

    Robinson, P.J.; Luyben, W.L. [Lehigh University, Bethlehem, PA (United States). Dept. of Chemical Engineering

    2008-10-15

    Gasification (or partial oxidation) is a vital component of 'clean coal' technology. Sulfur and nitrogen emissions can be reduced, overall energy efficiency is increased, and carbon dioxide recovery and sequestration are facilitated. Gasification units in an electric power generation plant produce a fuel for driving combustion turbines. Gasification units in a chemical plant generate gas, which can be used to produce a wide spectrum of chemical products. Future plants are predicted to be hybrid power/chemical plants with gasification as the key unit operation. The widely used process simulator Aspen Plus provides a library of models that can be used to develop an overall gasifier model that handles solids. So steady-state design and optimization studies of processes with gasifiers can be undertaken. This paper presents a simple approximate method for achieving the objective of having a gasifier model that can be exported into Aspen Dynamics. The basic idea is to use a high molecular weight hydrocarbon that is present in the Aspen library as a pseudofuel. This component should have the same 1:1 hydrogen-to-carbon ratio that is found in coal and biomass. For many plantwide dynamic studies, a rigorous high-fidelity dynamic model of the gasifier is not needed because its dynamics are very fast and the gasifier gas volume is a relatively small fraction of the total volume of the entire plant. The proposed approximate model captures the essential macroscale thermal, flow, composition, and pressure dynamics. This paper does not attempt to optimize the design or control of gasifiers but merely presents an idea of how to dynamically simulate coal gasification in an approximate way.

  14. WESTCARB Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The West Coast Regional Carbon Sequestration Partnership (known as WESTCARB) was established in Fall 2003. It is one of seven research partnerships co-funded by DOE to characterize regional carbon sequestration opportunities and conduct pilot-scale validation tests. The California Energy Commission manages WESTCARB and is a major co-funder. WESTCARB is characterizing the extent and capacity of geologic formations capable of storing CO2, known as sinks. Results are entered into a geographic information system (GIS) database, along with the location of major CO2-emitting point sources in each of the six WESTCARB states, enabling researchers and the public to gauge the proximity of candidate CO2 storage sites to emission sources and the feasibility of linking them via pipelines. Specifically, the WESTCARB GIS database (also known as the carbon atlas) stores layers of geologic information about potential underground storage sites, such as porosity and nearby fault-lines and aquifers. Researchers use these data, along with interpreted geophysical data and available oil and gas well logs to estimate the region's potential geologic storage capacity. The database also depicts existing pipeline routes and rights-of-way and lands that could be off-limits, which can aid the development of a regional carbon management strategy. The WESTCARB Carbon Atlas, which is accessible to the public, provides a resource for public discourse on practical solutions for regional CO2 management. A key WESTCARB partner, the Utah Automated Geographic Reference Center, has developed data serving procedures to enable the WESTCARB Carbon Atlas to be integrated with those from other regional partnerships, thereby supporting the U.S. Department of Energy's national carbon atlas, NATCARB

  15. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  16. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  17. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  18. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  19. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  20. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  1. Carbon allocation and accumulation in conifers

    SciTech Connect (OSTI)

    Gower, S.T.; Isebrands, J.G.; Sheriff, D.W.

    1995-07-01

    Forests cover approximately 33% of the land surface of the earth, yet they are responsible for 65% of the annual carbon (C) accumulated by all terrestrial biomes. In general, total C content and net primary production rates are greater for forests than for other biomes, but C budgets differ greatly among forests. Despite several decades of research on forest C budgets, there is still an incomplete understanding of the factors controlling C allocation. Yet, if we are to understand how changing global events such as land use, climate change, atmospheric N deposition, ozone, and elevated atmospheric CO{sub 2} affect the global C budget, a mechanistic understanding of C assimilation, partitioning, and allocation is necessary. The objective of this chapter is to review the major factors that influence C allocation and accumulation in conifer trees and forests. In keeping with the theme of this book, we will focus primarily on evergreen conifers. However, even among evergreen conifers, leaf, canopy, and stand-level C and nutrient allocation patterns differ, often as a function of leaf development and longevity. The terminology related to C allocation literature is often inconsistent, confusing and inadequate for understanding and integrating past and current research. For example, terms often used synonymously to describe C flow or movement include translocation, transport, distribution, allocation, partitioning, apportionment, and biomass allocation. A common terminology is needed because different terms have different meanings to readers. In this paper we use C allocation, partitioning, and accumulation according to the definitions of Dickson and Isebrands (1993). Partitioning is the process of C flow into and among different chemical, storage, and transport pools. Allocation is the distribution of C to different plant parts within the plant (i.e., source to sink). Accumulation is the end product of the process of C allocation.

  2. On carbon footprints and growing energy use

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01

    On carbon footprints and growing energy use Curtis M.reductions in the carbon footprint of a growing organizationhis own organization's carbon footprint and answers this

  3. ASSESSMENT OF HOUSEHOLD CARBON FOOTPRINT REDUCTION POTENTIALS

    E-Print Network [OSTI]

    Masanet, Eric

    2010-01-01

    of  American household carbon footprint. ” Ecological and  limitations) of carbon footprint estimates toward of the art in carbon footprint analyses for California, 

  4. Carbon contamination topography analysis of EUV masks

    E-Print Network [OSTI]

    Fan, Y.-J.

    2010-01-01

    induced carbon contamination of extreme ultraviolet optics,"and A. Izumi. "Carbon contamination of EL'V mask: filmEffect of Carbon Contamination on the Printing Performance

  5. Conductive Carbon Coatings for Electrode Materials

    E-Print Network [OSTI]

    Doeff, Marca M.; Kostecki, Robert; Wilcox, James; Lau, Grace

    2007-01-01

    Raman spectrum of the carbon coating. Deconvoluted peaksConductive Carbon Coatings for Electrode Materials Marca M.for optimizing the carbon coatings on non-conductive battery

  6. Participatory Carbon Monitoring: Operational Guidance for National...

    Open Energy Info (EERE)

    Participatory Carbon Monitoring: Operational Guidance for National REDD+ Carbon Accounting Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Participatory Carbon...

  7. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01

    around Surface-Attached Carbon Nanotubes. Ind. Eng. Chem.the flexural rigidity of carbon nanotube ensembles. AppliedNanotechnology in Carbon Materials. Acta Metallurgica, 1997.

  8. Carbon-particle generator

    DOE Patents [OSTI]

    Hunt, A.J.

    1982-09-29

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  9. What is carbon monoxide? Carbon monoxide (CO) is a poisonous,

    E-Print Network [OSTI]

    Johnson, Eric E.

    other material containing carbon such as gasoline, kerosene, oil, propane, coal, or wood. Forges, blast is the internal combustion engine. How does CO harm you? Carbon monoxide is harmful when breathed because

  10. Carbon Capture and Storage

    SciTech Connect (OSTI)

    Friedmann, S

    2007-10-03

    Carbon capture and sequestration (CCS) is the long-term isolation of carbon dioxide from the atmosphere through physical, chemical, biological, or engineered processes. This includes a range of approaches including soil carbon sequestration (e.g., through no-till farming), terrestrial biomass sequestration (e.g., through planting forests), direct ocean injection of CO{sub 2} either onto the deep seafloor or into the intermediate depths, injection into deep geological formations, or even direct conversion of CO{sub 2} to carbonate minerals. Some of these approaches are considered geoengineering (see the appropriate chapter herein). All are considered in the 2005 special report by the Intergovernmental Panel on Climate Change (IPCC 2005). Of the range of options available, geological carbon sequestration (GCS) appears to be the most actionable and economic option for major greenhouse gas reduction in the next 10-30 years. The basis for this interest includes several factors: (1) The potential capacities are large based on initial estimates. Formal estimates for global storage potential vary substantially, but are likely to be between 800 and 3300 Gt of C (3000 and 10,000 Gt of CO{sub 2}), with significant capacity located reasonably near large point sources of the CO{sub 2}. (2) GCS can begin operations with demonstrated technology. Carbon dioxide has been separated from large point sources for nearly 100 years, and has been injected underground for over 30 years (below). (3) Testing of GCS at intermediate scale is feasible. In the US, Canada, and many industrial countries, large CO{sub 2} sources like power plants and refineries lie near prospective storage sites. These plants could be retrofit today and injection begun (while bearing in mind scientific uncertainties and unknowns). Indeed, some have, and three projects described here provide a great deal of information on the operational needs and field implementation of CCS. Part of this interest comes from several key documents written in the last three years that provide information on the status, economics, technology, and impact of CCS. These are cited throughout this text and identified as key references at the end of this manuscript. When coupled with improvements in energy efficiency, renewable energy supplies, and nuclear power, CCS help dramatically reduce current and future emissions (US CCTP 2005, MIT 2007). If CCS is not available as a carbon management option, it will be much more difficult and much more expensive to stabilize atmospheric CO{sub 2} emissions. Recent estimates put the cost of carbon abatement without CCS to be 30-80% higher that if CCS were to be available (Edmonds et al. 2004).

  11. Carbon | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to: navigation, search Name: Carbon Trade LtdCarbon Jump

  12. Dynamic Reconstruction

    E-Print Network [OSTI]

    Horn, Berthold Klaus Paul

    Dynamic reconstruction is a method for generating images or image sequences from data obtained using moving radiation detection systems. While coded apertures are used as examples of the underlying information collection ...

  13. ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION EFFORTS

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION examines biological carbon sequestration using a grassland restoration as a model system. Chapter 1 for biological carbon sequestration. In this analysis, we found that significantly greater soil carbon

  14. COPLBI-811; NO. OF PAGES 6 Please cite this article in press as: Pawlowski WP. Chromosome organization and dynamics in plants, Curr Opin Plant Biol (2010), doi:10.1016/j.pbi.2010.09.015

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    2010-01-01

    cells as well as during cell division, particularly meiosis. This research has been fueled by new organization and dynamics in plants, Curr Opin Plant Biol (2010), doi:10.1016/j.pbi.2010.09.015 Available:1­6 This review comes from a themed issue on Cell biology Edited by Christian Luschnig and Claire Grierson 1369

  15. theme | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (UtilityMichigan)data bookresult formats Homestormtext in "Maxtheme

  16. OpenEI Community - theme

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly Smart Grid Data available for downloadGRR 3rd Quarter

  17. Cumulative Carbon and Just Allocation of the Global Carbon Commons

    E-Print Network [OSTI]

    goal for a theory of justice: first to reduce the growth rate of global carbon dioxide emissions such activitiespersist.In thispaper the conceptis usedto addressthe question offair allocation of carbon emissions nations could continue emissions for much longer before exhausting theirfair share of the Carbon Commons

  18. Health News -US study sheds light on schizophrenia genetics http://www.netdoctor.co.uk/interactive/news/theme_news_detail.php?id=800692655&tab_id=116[8/10/2011 11:03:09 AM

    E-Print Network [OSTI]

    Health News - US study sheds light on schizophrenia genetics http://www.netdoctor.co.uk/interactive/news/theme_news_detail.php?id=800692655&tab_id=116[8/10/2011 11:03:09 AM] Home Diseases and conditions Healthy living Health A-Zs Health Discussion All health news » Latest news » Latest stories US study sheds light on schizophrenia genetics Last

  19. Sensor applications of carbon nanotubes

    E-Print Network [OSTI]

    Rushfeldt, Scott I

    2005-01-01

    A search of published research on sensing mechanisms of carbon nanotubes was performed to identify applications in which carbon nanotubes might improve on current sensor technologies, in either offering improved performance, ...

  20. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure...

  1. Carbon nanotubes: synthesis and functionalization 

    E-Print Network [OSTI]

    Andrews, Robert

    2007-01-01

    conditions were then used as the basis of several comparative CVD experiments showing that the quality of nanotubes and the yield of carbon depended on the availability of carbon to react. The availability could be controlled by the varying concentration...

  2. The Australian terrestrial carbon budget

    E-Print Network [OSTI]

    2013-01-01

    the Australian National Green- house Gas Inventory (DCCEE,fuel emissions Carbon and green house gas (GHG) accounts are

  3. Carbon cloth supported electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA); Ammon, Robert L. (Baldwin both of, PA)

    1982-01-01

    A flow-by anode is disclosed made by preparing a liquid suspension of about to about 18% by weight solids, the solids comprising about 3.5 to about 8% of a powdered catalyst of platinum, palladium, palladium oxide, or mixtures thereof; about 60 to about 76% carbon powder (support) having a particle size less than about 20 m.mu.m and about 20 to about 33% of an inert binder having a particle size of less than about 500 m.mu.m. A sufficient amount of the suspension is poured over a carbon cloth to form a layer of solids about 0.01 to about 0.05 cm thick on the carbon cloth when the electrode is completed. A vacuum was applied to the opposite side of the carbon cloth to remove the liquid and the catalyst layer/cloth assembly is dried and compressed at about 10 to about 50 MPa's. The binder is then sintered in an inert atmosphere to complete the electrode. The electrode is used for the oxidation of sulfur dioxide in a sulfur based hybrid cycle for the decomposition of water.

  4. Carbon Footprint Calculator

    Broader source: Energy.gov [DOE]

    This calculator estimates the amount of carbon emissions you and members of your household are responsible for. It does not include emissions associated with your work or getting to work if you commute by public transportation. It was developed by IEEE Spectrum magazine.

  5. CARBON -14 PHYSICAL DATA

    E-Print Network [OSTI]

    Vallino, Joseph J.

    CARBON - 14 [14C] PHYSICAL DATA · Beta Energy: 156 keV (maximum) 49 keV (average) (100% abundance on wipes. #12;RADIATION MONITORING DOSIMETERS · Not needed (beta energy too low). · 14C Beta Dose Rate: 6) · Effective Half-Life: 40 days (unbound) · Specific Activity: 4460 mCi/gram · Maximum Beta Range in Air: 24

  6. Carbon smackdown: wind warriors

    ScienceCinema (OSTI)

    Glen Dahlbacka of the Accelerator & Fusion Research Division and Ryan Wiser of the Environmental Energy Technologies Division are the speakers.

    2010-09-01

    July 16. 2010 carbon smackdown summer lecture: learn how Berkeley Lab scientists are developing wind turbines to be used in an urban setting, as well as analyzing what it will take to increase the adoption of wind energy in the U.S.

  7. Carbon-Fuelled Future

    SciTech Connect (OSTI)

    Appel, Aaron M.

    2014-09-12

    Whether due to changes in policy or consumption of available fossil fuels, alternative sources of energy will be required, especially given the rising global energy demand. However, one of the main factors limiting the widespread utilization of renewable energy, such as wind, solar, wave or geothermal, is our ability to store energy. Storage of energy from carbon-neutral sources, such as electricity from solar or wind, can be accomplished through many routes. One approach is to store energy in the form of chemical bonds, as fuels. The conversion of low-energy compounds, such as water and carbon dioxide, to higher energy molecules, such as hydrogen or carbon-based fuels, enables the storage of carbon-neutral energy on a very large scale. The author¹s work in this area is supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  8. OF CARBON FIBERS TURBINE BLADE

    E-Print Network [OSTI]

    THE USE IN WIND DESIGN: OF CARBON FIBERS TURBINE BLADE A SERI-8BLADE EXAMPLE Cheng Printed March 2000 The Use of Carbon Fibers in Wind Turbine Blade Design: a SERI-8 Blade Example Cheng represent different volumes of carbon fibers in the blade, were also studied for two design options

  9. 4, 21112145, 2007 Enhanced carbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    are generally low in productivity and carbon (C) storage. We report, however, large increases in C sequestration . Carbon sequestration following afforestation was associated with increased N use efficiency as reflected of terrestrial ecosystems that leads to increased carbon (C) sequestration. One of those means is afforestation

  10. 4, 99123, 2007 Amazon carbon

    E-Print Network [OSTI]

    Boyer, Edmond

    , suggested much larger estimates for tropical forest carbon sequestration in the Ama- zon BasinBGD 4, 99­123, 2007 Amazon carbon balanc J. Lloyd et al. Title Page Abstract Introduction Discussions is the access reviewed discussion forum of Biogeosciences An airborne regional carbon balance

  11. Carbon Nanomaterials: The Ideal Interconnect

    E-Print Network [OSTI]

    Carbon Nanomaterials: The Ideal Interconnect Technology for Next- Generation ICs Hong Li, Chuan Xu-generation ICs. In this research, carbon nanomaterials, with their many attractive properties, are emerging-a`-vis optical and RF interconnects, and we illustrate why carbon nanomaterials constitute the ideal intercon

  12. Dispersion toughened silicon carbon ceramics

    DOE Patents [OSTI]

    Wei, G.C.

    1984-01-01

    Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

  13. Apparatus for producing carbon-coated nanoparticles and carbon nanospheres

    DOE Patents [OSTI]

    Perry, W. Lee; Weigle, John C.; Phillips, Jonathan

    2015-10-20

    An apparatus for producing carbon-coated nano- or micron-scale particles comprising a container for entraining particles in an aerosol gas, providing an inlet for carbon-containing gas, providing an inlet for plasma gas, a proximate torch for mixing the aerosol gas, the carbon-containing gas, and the plasma gas, bombarding the mixed gases with microwaves, and providing a collection device for gathering the resulting carbon-coated nano- or micron-scale particles. Also disclosed is a method and apparatus for making hollow carbon nano- or micro-scale spheres.

  14. Distributed Energy Resources for Carbon Emissions Mitigation

    E-Print Network [OSTI]

    Firestone, Ryan; Marnay, Chris

    2008-01-01

    Distributed Energy Resource Technology Characterizations. ”ABORATORY Distributed Energy Resources for Carbon Emissions5128 Distributed Energy Resources for Carbon Emissions

  15. Electrobiocommodities from Carbon Dioxide: Enhancing Microbial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Electrobiocommodities from Carbon Dioxide:...

  16. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  17. Development and Commercialization of Alternative Carbon Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alternative Carbon Fiber Precursors and Conversion Technologies - Advanced Conversion Development and Commercialization of Alternative Carbon Fiber Precursors and Conversion...

  18. Manufacturing Energy and Carbon Footprint References | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    References Manufacturing Energy and Carbon Footprint References footprintreferences.pdf More Documents & Publications 2010 Manufacturing Energy and Carbon Footprints: References...

  19. Effects of ion irradiation on supported carbon nanotubes and nanotube-substrate A. V. Krasheninnikov, K. Nordlund, and J. Keinonen

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    Effects of ion irradiation on supported carbon nanotubes and nanotube-substrate interfaces A. V of Helsinki, Finland ABSTRACT We employ molecular dynamics to study the effects of ion irradiation on carbon by forming nanotube-substrate bonds which appear near irradiation-induced defects. INTRODUCTION Recent

  20. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    SciTech Connect (OSTI)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions, relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.

  1. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions,more »relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.« less

  2. CALCULATING THE CARBON FOOTPRINT SUPPLY CHAIN FOR

    E-Print Network [OSTI]

    Su, Xiao

    CALCULATING THE CARBON FOOTPRINT SUPPLY CHAIN FOR THE SEMICONDUCTOR INDUSTRY By: Yasser Dessouky #12;Carbon Footprint Supply Chain Carbon Trust defines carbon footprint of a supply chain as follows: "The carbon footprint of a product is the carbon dioxide emitted across the supply chain for a single

  3. Carbon Capture and Storage, 2008

    SciTech Connect (OSTI)

    2009-03-19

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  4. Carbon Capture and Storage, 2008

    ScienceCinema (OSTI)

    None

    2010-01-08

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  5. Southwest Regional Partnership on Carbon Sequestration

    SciTech Connect (OSTI)

    Brian McPherson

    2006-04-01

    The Southwest Partnership on Carbon Sequestration completed several more tasks during the period of April 1, 2005-September 30, 2005. The main objective of the Southwest Partnership project is to evaluate and demonstrate the means for achieving an 18% reduction in carbon intensity by 2012. While Phase 2 planning is well under way, the content of this report focuses exclusively on Phase 1 objectives completed during this reporting period. Progress during this period was focused in the three areas: geological carbon storage capacity in New Mexico, terrestrial sequestration capacity for the project area, and the Integrated Assessment Model efforts. The geologic storage capacity of New Mexico was analyzed and Blanco Mesaverde (which extends into Colorado) and Basin Dakota Pools were chosen as top two choices for the further analysis for CO{sub 2} sequestration in the system dynamics model preliminary analysis. Terrestrial sequestration capacity analysis showed that the four states analyzed thus far (Arizona, Colorado, New Mexico and Utah) have relatively limited potential to sequester carbon in terrestrial systems, mainly due to the aridity of these areas, but the large land area offered could make up for the limited capacity per hectare. Best opportunities were thought to be in eastern Colorado/New Mexico. The Integrated Assessment team expanded the initial test case model to include all New Mexico sinks and sources in a new, revised prototype model in 2005. The allocation mechanism, or ''String of Pearls'' concept, utilizes potential pipeline routes as the links between all combinations of the source to various sinks. This technique lays the groundwork for future, additional ''String of Pearls'' analyses throughout the SW Partnership and other regions as well.

  6. Carbon K-edge Spectra of Carbonate Minerals

    SciTech Connect (OSTI)

    Brandes, J.; Wirick, S; Jacobsen, C

    2010-01-01

    Carbon K-edge X-ray spectroscopy has been applied to the study of a wide range of organic samples, from polymers and coals to interstellar dust particles. Identification of carbonaceous materials within these samples is accomplished by the pattern of resonances in the 280-320 eV energy region. Carbonate minerals are often encountered in the study of natural samples, and have been identified by a distinctive resonance at 290.3 eV. Here C K-edge and Ca L-edge spectra from a range of carbonate minerals are presented. Although all carbonates exhibit a sharp 290 eV resonance, both the precise position of this resonance and the positions of other resonances vary among minerals. The relative strengths of the different carbonate resonances also vary with crystal orientation to the linearly polarized X-ray beam. Intriguingly, several carbonate minerals also exhibit a strong 288.6 eV resonance, consistent with the position of a carbonyl resonance rather than carbonate. Calcite and aragonite, although indistinguishable spectrally at the C K-edge, exhibited significantly different spectra at the Ca L-edge. The distinctive spectral fingerprints of carbonates provide an identification tool, allowing for the examination of such processes as carbon sequestration in minerals, Mn substitution in marine calcium carbonates (dolomitization) and serpentinization of basalts.

  7. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, M.; Yuh, C.Y.

    1996-12-03

    A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

  8. Carbon Fiber Technology Facility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels| Departmentof Energy CaliforniaContentsForumCarbon Fiber

  9. Vertically Aligned Carbon Nanofiber Based Biosensor Platform for Glucose Sensor

    SciTech Connect (OSTI)

    Mamun, Khandaker Abdullah Al; Tulip, Fahmida S; Macarthur, Kimberly C; McFarlane, Nicole M; Islam, Syed K

    2014-01-01

    Vertically aligned carbon nanofibers (VACNFs) have recently become an important tool for biosensor design. Carbon nanofibers (CNF) have excellent conductive and structural properties with many irregularities and defect sites in addition to exposed carboxyl groups throughout their surfaces. These properties allow a better immobilization matrix compared to carbon nanotubes and offer better resolution when compared with the FET-based biosensors. VACNFs can be deterministically grown on silicon substrates allowing optimization of the structures for various biosensor applications. Two VACNF electrode architectures have been employed in this study and a comparison of their performances has been made in terms of sensitivity, sensing limitations, dynamic range, and response time. The usage of VACNF platform as a glucose sensor has been verified in this study by selecting an optimum architecture based on the VACNF forest density. Read More: http://www.worldscientific.com/doi/abs/10.1142/S0129156414500062

  10. Response of SOI image sensor to therapeutic carbon ion beam

    E-Print Network [OSTI]

    Matsumura, Akihiko

    2015-01-01

    Carbon ion radiotherapy is known as a less invasive cancer treatment. The radiation quality is an important parameter to evaluate the biological effect and the clinical dose from the measured physical dose. The performance of SOPHIAS detector, which is the SOI image sensor having a wide dynamic range and large active area, was tested by using therapeutic carbon ion beam at Gunma University Heavy Ion Medical Center (GHMC). It was shown that the primary carbon and secondary particles can be distinguishable by SOPHIAS detector. On the other hand, a LET dependence was observed especially at the high LET region. This phenomenon will be studied by using the device simulator together with Monte Carlo simulation.

  11. Carbon K-Edge XANES Spectromicroscopy of Natural Graphite

    SciTech Connect (OSTI)

    Brandes,J.; Cody, G.; Rumble, D.; Haberstroh, P.; Wirick, S.; Gelinas, Y.; Morais-Cabral, J.

    2008-01-01

    The black carbon continuum is composed of a series of carbon-rich components derived from combustion or metamorphism and characterized by contrasting environmental behavior and susceptibility to oxidation. In this work, we present a micro-scale density fractionation method that allows isolating the small quantities of soot-like and graphitic material usually found in natural samples. Organic carbon and {delta}{sup 13}C mass balance calculations were used to quantify the relative contributions of the two fractions to thermally-stable organic matter from a series of aquatic sediments. Varying proportions of soot-like and graphitic material were found in these samples, with large variations in {delta}{sup 13}C signatures suggesting important differences in their origin and/or dynamics in the environment.

  12. Reactive transport modeling of stable carbon isotope fractionation in a multi-phase multi-component system during carbon sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Shuo; DePaolo, Donald J.; Zheng, Liange; Mayer, Bernhard

    2014-12-31

    Carbon stable isotopes can be used in characterization and monitoring of CO2 sequestration sites to track the migration of the CO2 plume and identify leakage sources, and to evaluate the chemical reactions that take place in the CO2-water-rock system. However, there are few tools available to incorporate stable isotope information into flow and transport codes used for CO2 sequestration problems. We present a numerical tool for modeling the transport of stable carbon isotopes in multiphase reactive systems relevant to geologic carbon sequestration. The code is an extension of the reactive transport code TOUGHREACT. The transport module of TOUGHREACT was modifiedmore »to include separate isotopic species of CO2 gas and dissolved inorganic carbon (CO2, CO32-, HCO3-,…). Any process of transport or reaction influencing a given carbon species also influences its isotopic ratio. Isotopic fractionation is thus fully integrated within the dynamic system. The chemical module and database have been expanded to include isotopic exchange and fractionation between the carbon species in both gas and aqueous phases. The performance of the code is verified by modeling ideal systems and comparing with theoretical results. Efforts are also made to fit field data from the Pembina CO2 injection project in Canada. We show that the exchange of carbon isotopes between dissolved and gaseous carbon species combined with fluid flow and transport, produce isotopic effects that are significantly different from simple two-component mixing. These effects are important for understanding the isotopic variations observed in field demonstrations.« less

  13. Reactive transport modeling of stable carbon isotope fractionation in a multi-phase multi-component system during carbon sequestration

    SciTech Connect (OSTI)

    Zhang, Shuo [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); DePaolo, Donald J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zheng, Liange [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Mayer, Bernhard [Univ. of Calgary (Canada). Dept. of Geosciences

    2014-12-31

    Carbon stable isotopes can be used in characterization and monitoring of CO2 sequestration sites to track the migration of the CO2 plume and identify leakage sources, and to evaluate the chemical reactions that take place in the CO2-water-rock system. However, there are few tools available to incorporate stable isotope information into flow and transport codes used for CO2 sequestration problems. We present a numerical tool for modeling the transport of stable carbon isotopes in multiphase reactive systems relevant to geologic carbon sequestration. The code is an extension of the reactive transport code TOUGHREACT. The transport module of TOUGHREACT was modified to include separate isotopic species of CO2 gas and dissolved inorganic carbon (CO2, CO32-, HCO3-,…). Any process of transport or reaction influencing a given carbon species also influences its isotopic ratio. Isotopic fractionation is thus fully integrated within the dynamic system. The chemical module and database have been expanded to include isotopic exchange and fractionation between the carbon species in both gas and aqueous phases. The performance of the code is verified by modeling ideal systems and comparing with theoretical results. Efforts are also made to fit field data from the Pembina CO2 injection project in Canada. We show that the exchange of carbon isotopes between dissolved and gaseous carbon species combined with fluid flow and transport, produce isotopic effects that are significantly different from simple two-component mixing. These effects are important for understanding the isotopic variations observed in field demonstrations.

  14. Carbon Capital: The Political Ecology of Carbon Forestry and Development in Chiapas, Mexico

    E-Print Network [OSTI]

    Osborne, Tracey Muttoo

    2010-01-01

    B v + B d ) C T = Total carbon B v = biomass contained indevelopment through carbon sequestration: experiences in2000) Rural livelihoods and carbon management, IIED Natural

  15. Nucleation and stabilization of carbon-rich structures in interstellar media

    SciTech Connect (OSTI)

    Patra, N.; Král, P.; Sadeghpour, H. R. E-mail: pkral@uic.edu

    2014-04-10

    We study the conditions under which carbon clusters of different sizes form and stabilize. We describe the approach to equilibrium by simulating tenuous carbon gas dynamics to long times. First, we use reactive molecular dynamics simulations to describe the nucleation of long chains, large clusters, and complex cage structures in carbon- and hydrogen-rich interstellar gas phases. We study how temperature, particle density, the presence of hydrogen, and carbon inflow affect the nucleation of molecular moieties with different characteristics, in accordance with astrophysical conditions. We extend the simulations to densities that are orders of magnitude lower than current laboratory densities, to temperatures that are relevant to circumstellar environments of planetary nebulae, and microsecond formation times. We correlate cluster size distributions from the simulations with thermodynamic equilibrium at low temperatures and gas densities, where entropy plays a significant role.

  16. Graphitization of small diamond cluster --Molecular dynamics simulation A. Brdka a,, T.W. Zerda b

    E-Print Network [OSTI]

    Powles, Rebecca

    Elsevier B.V. All rights reserved. Keywords: Nanodiamond; Graphitization; Molecular dynamics simulation 1 of nanodiamond clus- ters (nD-c) [2] is the method that can provide carbon onions with uniform size in a large

  17. Analysis of condensate banking dynamics in a gas condensate reservoir under different injection schemes 

    E-Print Network [OSTI]

    Sandoval Rodriguez, Angelica Patricia

    2002-01-01

    condensate reservoir under natural depletion, and injection of methane, injection of carbon dioxide, produced gas recycling and water injection. To monitor the condensate banking dynamics near the wellbore area, such as oil saturation and compositional...

  18. A white paper on relevant aspects of Population Dynamics, Marine Community Ecology, and Oceanography

    E-Print Network [OSTI]

    , and Oceanography of Marine Microbes for the Department of Energy Genomes to Life project: CARBON SEQUESTRATIONA white paper on relevant aspects of Population Dynamics, Marine Community Ecology ........................................................................................................7 Introductory Marine Community Ecology

  19. Method for joining carbon-carbon composites to metals

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Moorhead, A.J.

    1997-07-15

    A method for joining carbon-carbon composites to metals by brazing. Conventional brazing of recently developed carbon-bonded carbon fiber (CBCF) material to a metal substrate is limited by the tendency of the braze alloy to ``wick`` into the CBCF composite rather than to form a strong bond. The surface of the CBCF composite that is to be bonded is first sealed with a fairly dense carbonaceous layer achieved by any of several methods. The sealed surface is then brazed to the metal substrate by vacuum brazing with a Ti-Cu-Be alloy. 1 fig.

  20. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    in the life-cycle assessment (LCA) and carbon footprintingto integrate the economics- and LCA-based perspectives onto life-cycle assessment (LCA). The existing literature on

  1. Geologic Carbon Sequestration and Biosequestration (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    DePaolo, Don [Director, LBNL Earth Sciences Division

    2011-06-08

    Don DePaolo, Director of LBNL's Earth Sciences Division, speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  2. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Technologies Project Type Topic 2 Supercritical Carbon Dioxide Reservoir Rock Chemical Interactions Project Description Supercritical CO2 is currently becoming a more...

  3. Assessing carbon dynamics in natural and perturbed boreal aquatic systems

    E-Print Network [OSTI]

    ; Tremblay et al., 2005]. [3] Reservoirs are typically created for water flow regu- lation or for hydro power

  4. Entropy-driven structure and dynamics in carbon nanocrystallites (Journal

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) | SciTech(Journal(Patent) |(JournalArticle) | SciTech Connect

  5. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    Area Southeast  Regional  Carbon  Sequestration  PartnershipCoast  Regional  Carbon  Sequestration  Partnership Water  West  Coast  Regional  Carbon  Sequestration  Partnership  (

  6. Risk assessment framework for geologic carbon sequestration sites

    E-Print Network [OSTI]

    Oldenburg, C.

    2010-01-01

    carbon sequestration risk assessment, in Carbon Dioxidecarbon sequestration risk assessment, Energy Procedia,Risk Assessment Framework for Geologic Carbon Sequestration

  7. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    for  Geologic  Carbon  Sequestration. ”   International  of  Energy.  “Carbon  Sequestration  Atlas  of  the  Water  Extracted  from  Carbon  Sequestration  Projects."  

  8. The 2009 IEEE International Conference on Automation and Logistics will be held from August 5 to 7, 2009 in the historical city of Shenyang, China. The theme of

    E-Print Network [OSTI]

    Liu, Derong

    The 2009 IEEE International Conference on Automation and Logistics will be held from August 5 to 7 and Logistics in the Information Age", reflecting the fast growing interests in research, development and applications in the dynamic and exciting areas of advanced intelligent automation and logistics. Shenyang

  9. Agricultural land use dynamics in the Brazilian Amazon based on remote sensing and census data

    E-Print Network [OSTI]

    Camara, Gilberto

    that carbon dioxide (CO2) from land use change contributed to 12% (in terms of CO2 equivalents) of the totalAgricultural land use dynamics in the Brazilian Amazon based on remote sensing and census data of biodiversity, erosion, floods, lowered water tables, as well as increased release of carbon into the atmosphere

  10. Effect of Nanoporosity on the Thermal Conductivity of Amorphous Carbon

    E-Print Network [OSTI]

    Fujii, Amanda

    2014-01-01

    Carbon aerogels . . . . . . . . . . . . . . .carbon thin films [6, 7, 15, 16] and carbon aerogels [10,law relations for carbon aerogels are also included [10,

  11. Carbon Sequestration Advisory Committee (Nebraska)

    Broader source: Energy.gov [DOE]

    Under this statute, the Director of Natural Resources will document and quantify carbon sequestration and greenhouse emissions reductions associated with agricultural practices, management systems,...

  12. Manufacturing Energy and Carbon Footprint

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Export 113 Combustion Emissions (MMT CO 2 e Million Metric Tons Carbon Dioxide Equivalent) Total Emissions Offsite Emissions + Onsite Emissions Energy (TBtu ...

  13. Carbon-assisted flyer plates

    SciTech Connect (OSTI)

    Stahl, David B.; Paisley, Dennis L.

    1994-01-01

    A laser driven flyer plate utilizing an optical fiber connected to a laser. The end of the optical fiber has a layer of carbon and a metal layer deposited onto it. The carbon layer provides the laser induced plasma which is superior to the plasma produced from most metals. The carbon layer plasma is capable of providing a flatter flyer plate, converting more of the laser energy to driving plasma, promoting a higher flyer plate acceleration, and providing a more uniform pulse behind the plate. In another embodiment, the laser is in optical communication with a substrate onto which a layer of carbon and a layer of metal have been deposited.

  14. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stands to improve climate modeling Environmental microbiology In 2009, the Department of Energy established the Los Alamos Science Focus Area in Soil Metagenomics & Carbon Cycling...

  15. Carbon Sequestration Atlas IV Video

    ScienceCinema (OSTI)

    Rodosta, Traci

    2014-06-27

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  16. Carbon Sequestration Atlas IV Video

    SciTech Connect (OSTI)

    Rodosta, Traci

    2013-04-19

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  17. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  18. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  19. Carbon Capture FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from thecarbon capture faqs faq-header-big.jpg CARBON

  20. Carbon Storage Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from thecarbon captureCarbon Storage AtlasStorage

  1. ARM - Carbon Cycle Balance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments? We would love to hear from you! Send us agovInstrumentswrf-chem Comments? We wouldCampaign JournalCarbon

  2. (Carbon isotope fractionation inplants)

    SciTech Connect (OSTI)

    O'Leary, M.H.

    1990-01-01

    The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.

  3. Tropical forest soil microbial communities couple iron and carbon biogeochemistry

    SciTech Connect (OSTI)

    Dubinsky, E.A.; Silver, W.L.; Firestone, M.K.

    2009-10-15

    We report that iron-reducing bacteria are primary mediators of anaerobic carbon oxidation in upland tropical soils spanning a rainfall gradient (3500 - 5000 mm yr-1) in northeast Puerto Rico. The abundant rainfall and high net primary productivity of these tropical forests provide optimal soil habitat for iron-reducing and iron-oxidizing bacteria. Spatially and temporally dynamic redox conditions make iron-transforming microbial communities central to the belowground carbon cycle in these wet tropical forests. The exceedingly high abundance of iron-reducing bacteria (up to 1.2 x 10{sup 9} cells per gram soil) indicated that they possess extensive metabolic capacity to catalyze the reduction of iron minerals. In soils from the higher rainfall sites, measured rates of ferric iron reduction could account for up to 44 % of organic carbon oxidation. Iron reducers appeared to compete with methanogens when labile carbon availability was limited. We found large numbers of bacteria that oxidize reduced iron at sites with high rates of iron reduction and large numbers of iron-reducers. the coexistence of large populations of ironreducing and iron-oxidizing bacteria is evidence for rapid iron cycling between its reduced and oxidized states, and suggests that mutualistic interactions among these bacteria ultimately fuel organic carbon oxidation and inhibit CH4 production in these upland tropical forests.

  4. University of Aberdeen Carbon Management Plan

    E-Print Network [OSTI]

    Levi, Ran

    of Aberdeen is committed to reducing its carbon footprint and to playing its part in limiting the worstUniversity of Aberdeen Carbon Management Plan Higher Education Carbon Management Programme working with Page 1 The University of Aberdeen Carbon Management Programme Carbon Management Plan (CMP

  5. University of Dundee Carbon Management Plan

    E-Print Network [OSTI]

    Davidson, Fordyce A.

    Carbon Management Strategy 2.1 Our low carbon vision 6 2.2 Context and drivers for Carbon Management 6 2 and sources of funding 18 6 Actions to Embed Carbon Management in Your Organisation 19 6.1 Corporate Strategy Appendix A: Carbon Management Matrix - Embedding 23 Appendix B: Energy Prices 24 #12;3 FOREWORD FROM

  6. Carbon Management Plan 1. Executive summary 5

    E-Print Network [OSTI]

    Haase, Markus

    Carbon Management Plan June 2011 #12;2 #12;3 CONTENTS 1. Executive summary 5 2. Introduction 15 3. Background and context 16 4. Carbon management strategy 18 5. Carbon emissions baseline and projections 22 6. Past actions and achievements 30 7. Carbon Management Plan implementation 33 8. Carbon Management Plan

  7. Water and Carbon Dioxide Adsorption at Olivine Surfaces

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Bylaska, Eric J.; Felmy, Andrew R.

    2013-11-14

    Plane-wave density functional theory (DFT) calculations were performed to simulate water and carbon dioxide adsorption at the (010) surface of five olivine minerals, namely, forsterite (Mg2SiO4), calcio-olivine (Ca2SiO4), tephroite (Mn2SiO4), fayalite (Fe2SiO4), and Co-olivine (Co2SiO4). Adsorption energies per water molecule obtained from energy minimizations varied from -78 kJ mol-1 for fayalite to -128 kJ mol-1 for calcio-olivine at sub-monolayer coverage and became less exothermic as coverage increased. In contrast, carbon dioxide adsorption energies at sub-monolayer coverage ranged from -20 kJ mol-1 for fayalite to -59 kJ mol-1 for calcio-olivine. Therefore, the DFT calculations show a strong driving force for carbon dioxide displacement by water at the surface of all olivine minerals in a competitive adsorption scenario. Additionally, adsorption energies for both water and carbon dioxide were found to be more exothermic for the alkaline-earth (AE) olivines than for the transition-metal (TM) olivines and to not correlate with the solvation enthalpies of the corresponding divalent cations. However, a correlation was obtained with the charge of the surface divalent cation indicating that the more ionic character of the AE cations in the olivine structure relative to the TM cations leads to greater interactions with adsorbed water and carbon dioxide molecules at the surface and thus more exothermic adsorption energies for the AE olivines. For calcio-olivine, which exhibits the highest divalent cation charge of the five olivines, ab initio molecular dynamics simulations showed that this effect leads both water and carbon dioxide to react with the surface and form hydroxyl groups and a carbonate-like species, respectively.

  8. Hierarchical Dynamic Models

    E-Print Network [OSTI]

    Penny, Will

    Hierarchical Dynamic Models Will Penny OU Processes Embedding OU(2) process Dynamic Models Hierarchical Dynamic Models Will Penny 26th May 2011 #12;Hierarchical Dynamic Models Will Penny OU Processes Dynamic Models Will Penny OU Processes Embedding OU(2) process Dynamic Models Generalised coordinates

  9. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide

    Broader source: Energy.gov [DOE]

    Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock interactions.

  10. Carbon Mineralization and Labile Organic Carbon Pools in the Sandy

    E-Print Network [OSTI]

    Grunwald, Sabine

    Carbon Mineralization and Labile Organic Carbon Pools in the Sandy Soils of a North Florida mineralization were best explained by TOC (62%) and hot-water- extractable C (59%), whereas acid-hydrolyzable C mineralization and clay content were directly linearly correlated, indicating a possible stimulatory effect

  11. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  12. Intermediate Temperature Carbon - Carbon Composite Structures. CRADA Final Report

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar [ORNL

    2007-06-01

    The objective of this Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC (the "Contractor") and Synterials, Inc. (the "Participant") was to demonstrate promising processing methods, which can lead to producing Carbon-Carbon Composites (CCC), with tensile and interlaminar properties comparable to those of organic matrix composites and environmental stability at 1200 F for long periods of time. The participant synthesized carbon-carbon composites with two different fiber coatings and three different matrices. Both parties evaluated the tensile and interlaminar properties of these materials and characterized the microstructure of the matrices and interfaces. It was found that fiber coatings of carbon and boron carbide provided the best environmental protection and resulted in composites with high tensile strength.

  13. Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao

    E-Print Network [OSTI]

    Barthelat, Francois

    Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao promising carbon uptake results and is a viable option for carbonation curing. Carbon sequestration increase in Carbon dioxide (CO2) emissions over the past five decades, specific ways to reduce

  14. Fluid dynamics of sinking carbon dioxide hydrate particle releases for direct ocean carbon sequestration

    E-Print Network [OSTI]

    Chow, Aaron C. (Aaron Chunghin), 1978-

    2008-01-01

    One strategy to remove anthropogenic CO? from the atmosphere to mitigate climate change is by direct ocean injection. Liquid CO? can react with seawater to form solid partially reacted CO? hydrate composite particles (pure ...

  15. A synthesis of carbon in international trade

    E-Print Network [OSTI]

    Peters, G. P; Davis, S. J; Andrew, R.

    2012-01-01

    and Peters, G. P. : Carbon Footprint of Nations: A Global,analysis for na- tional carbon footprint accounting, Eco.study of the UK’s carbon footprint, Eco. Syst. Res. , 22,

  16. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    carbon-intensive fossil fuel, increased by 4.8 percent. 2.8. Carbon dioxide emissions and carbon sequestration from nonfuel uses of energy inputs Nonfuel uses of fossil fuels (for...

  17. Who Pays a Price on Carbon?

    E-Print Network [OSTI]

    Grainger, Corbett A.; Kolstad, Charles D.

    2010-01-01

    on a per-capita basis a carbon price is much more regressiveadverse distributional effects of a carbon emissions policy.Distributional incidence · Carbon tax · Tradable permits Q52

  18. DENSITY OF STATES CALCULATIONS FOR CARBON

    E-Print Network [OSTI]

    Adler, Joan

    DENSITY OF STATES CALCULATIONS FOR CARBON ALLOTROPES AND MIXTURES EDUARDO WARSZAWSKI #12;#12;DENSITY OF STATES CALCULATIONS FOR CARBON ALLOTROPES AND MIXTURES Research Thesis Submitted in Partial;#12;Contents Abstract xiii 1 Introduction 1 1.1 Carbon allotropes

  19. Carbon Nanotubes: Bearing Stress Like Never Before

    E-Print Network [OSTI]

    Limaye, Aditya

    2013-01-01

    of the mechanical properties of carbon nanotube– polymercomposites. Carbon, 44. 1624 – 1652 doi: 10.1016/j.R.H. , & Hart, A.J. (2013). Carbon Nanotubes: Present and

  20. CARBON MARKETS AROUND THE WORLD Ashley Lawson

    E-Print Network [OSTI]

    California at Davis, University of

    CARBON MARKETS AROUND THE WORLD Ashley Lawson Senior Analyst, Thomson Reuters Point Carbon only pilot trading carbon 6 #12;Shenzhen · Policy ­ Intensity-based ETS started June 18, 2013

  1. Permafrost soils and carbon cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; Michaelson, G. J.; Shur, Y. L.

    2015-02-05

    Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous organic carbon stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global carbon cycle and the potential vulnerability of the region's soil organic carbon (SOC) stocks to changing climatic conditions. Inmore »this review, we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils, and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of organic carbon stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this organic carbon to permafrost thaw under a warming climate. Overall, frozen conditions and cryopedogenic processes, such as cryoturbation, have slowed decomposition and enhanced the sequestration of organic carbon in permafrost-affected soils over millennial timescales. Due to the low temperatures, the organic matter in permafrost soils is often less humified than in more temperate soils, making some portion of this stored organic carbon relatively vulnerable to mineralization upon thawing of permafrost.« less

  2. 2013 Carbon Management Research Symposium

    E-Print Network [OSTI]

    . BACKGROUND · As a first step towards developing risk assessment strategies for carbon sequestration projects2013 Carbon Management Research Symposium Effects of Formation Heterogeneity on CO2 Gas Phase Attenuation in the Shallow Subsurface During Possible Leakage from Geologic Sequestration Sites Michael

  3. Method for producing carbon nanotubes

    DOE Patents [OSTI]

    Phillips, Jonathan (Santa Fe, NM); Perry, William L. (Jemez Springs, NM); Chen, Chun-Ku (Albuquerque, NM)

    2006-02-14

    Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

  4. Process for making hollow carbon spheres

    DOE Patents [OSTI]

    Luhrs, Claudia C.; Phillips, Jonathan; Richard, Monique N.; Knapp, Angela Michelle

    2013-04-16

    A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.

  5. Nitrogen attenuation of terrestrial carbon cycle response to global environmental factors

    SciTech Connect (OSTI)

    Jain, Atul; Yang, Xiaojuan; Kheshgi, Haroon; Mcguire, David; Post, Wilfred M

    2009-01-01

    Nitrogen cycle dynamics have the capacity to attenuate the magnitude of global terrestrial carbon sinks and sources driven by CO2 fertilization and changes in climate. In this study, two versions of the terrestrial carbon and nitrogen cycle components of the Integrated Science Assessment Model (ISAM) are used to evaluate how variation in nitrogen availability influences terrestrial carbon sinks and sources in response to changes over the 20th century in global environmental factors including atmospheric CO2 concentration, nitrogen inputs, temperature, precipitation and land use. The two versions of ISAM vary in their treatment of nitrogen availability: ISAM-NC has a terrestrial carbon cycle model coupled to a fully dynamic nitrogen cycle while ISAM-C has an identical carbon cycle model but nitrogen availability is always in sufficient supply. Overall, the two versions of the model estimate approximately the same amount of global mean carbon uptake over the 20th century. However, comparisons of results of ISAM-NC relative to ISAM-C reveal that nitrogen dynamics: (1) reduced the 1990s carbon sink associated with increasing atmospheric CO2 by 0.53 PgC yr1 (1 Pg = 1015g), (2) reduced the 1990s carbon source associated with changes in temperature and precipitation of 0.34 PgC yr1 in the 1990s, (3) an enhanced sink associated with nitrogen inputs by 0.26 PgC yr1, and (4) enhanced the 1990s carbon source associated with changes in land use by 0.08 PgC yr1 in the 1990s. These effects of nitrogen limitation influenced the spatial distribution of the estimated exchange of CO2 with greater sink activity in high latitudes associated with climate effects and a smaller sink of CO2 in the southeastern United States caused by N limitation associated with both CO2 fertilization and forest regrowth. These results indicate that the dynamics of nitrogen availability are important to consider in assessing the spatial distribution and temporal dynamics of terrestrial carbon sources and sinks.

  6. Effects of litter traits, soil biota, and soil chemistry on soil carbon stocks at a common garden with 14 tree species

    E-Print Network [OSTI]

    2015-01-01

    Nematode density (min. soil) Bacterial-feeding nemat.C:N microb. biomass (min. soil) Ectomycorrh. sporocarp spp.R, McCartney D (2002) Soil carbon and nitrogen dynamics in

  7. Catalytic Growth of Macroscopic Carbon Nanofibers Bodies with Activated Carbon

    SciTech Connect (OSTI)

    Abdullah, N.; Muhammad, I. S.; Hamid, S. B. Abd.; Rinaldi, A.; Su, D. S.; Schlogl, R.

    2009-06-01

    Carbon-carbon composite of activated carbon and carbon nanofibers have been synthesized by growing Carbon nanofiber (CNF) on Palm shell-based Activated carbon (AC) with Ni catalyst. The composites are in an agglomerated shape due to the entanglement of the defective CNF between the AC particles forming a macroscopic body. The macroscopic size will allow the composite to be used as a stabile catalyst support and liquid adsorbent. The preparation of CNT/AC nanocarbon was initiated by pre-treating the activated carbon with nitric acid, followed by impregnation of 1 wt% loading of nickel (II) nitrate solutions in acetone. The catalyst precursor was calcined and reduced at 300 deg. C for an hour in each step. The catalytic growth of nanocarbon in C{sub 2}H{sub 4}/H{sub 2} was carried out at temperature of 550 deg. C for 2 hrs with different rotating angle in the fluidization system. SEM and N{sub 2} isotherms show the level of agglomeration which is a function of growth density and fluidization of the system. The effect of fluidization by rotating the reactor during growth with different speed give a significant impact on the agglomeration of the final CNF/AC composite and thus the amount of CNFs produced. The macrostructure body produced in this work of CNF/AC composite will have advantages in the adsorbent and catalyst support application, due to the mechanical and chemical properties of the material.

  8. Speeding Up Zeolite Evaluation for Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Speeding Up Zeolite Evaluation for Carbon Capture Speeding Up Zeolite Evaluation for Carbon Capture Zeolite.png Schematic of an important class of porous materials known as...

  9. Electrical Transport in Carbon Nanotubes and Graphene

    E-Print Network [OSTI]

    Liu, Gang

    2010-01-01

    Introduction to Carbon Nanotubes and Graphene Single wallCarbon nanotubes and graphene are the most popular Carbonin the Normal Metal – Graphene – Superconductor Junctions

  10. Who Pays a Price on Carbon?

    E-Print Network [OSTI]

    Grainger, Corbett A.; Kolstad, Charles D.

    2010-01-01

    that a fully auctioned emissions trading program (with aof a carbon tax or emissions trading system (Fullertona carbon tax or emissions trading system may have exemptions

  11. Contraction & Convergence: UK carbon emissions and the

    E-Print Network [OSTI]

    Watson, Andrew

    the EU's emissions trading scheme will do little to mitigate carbon emissions 4) Aviation growth must emissions. Keywords Contraction & Convergence; aviation; emissions trading; passengers; carbon dioxide #12

  12. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    Geochemical Process Relevant to Carbon Sequestration We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and...

  13. GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA to extend our thanks to the authors of various West Coast Regional Carbon Sequestration Partnership

  14. UCSF Sustainability Baseline Assessment: Carbon Footprint Analysis

    E-Print Network [OSTI]

    Yamamoto, Keith

    UCSF Sustainability Baseline Assessment: Carbon Footprint Analysis Final Issue Date: March 21, 2010 #12;Carbon Footprint Analysis Background This chapter of the Sustainability Assessment focuses on UCSF

  15. Climate policy and dependence on traded carbon

    E-Print Network [OSTI]

    Andrew, Robbie M; Davis, Steven J; Peters, Glen P

    2013-01-01

    and China. Russia’s net exports of fuel carbon grew 93% (by increasing exports of carbon from Russia, the Middle East

  16. Project Profile: Regenerative Carbonate-Based Thermochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Profile: Regenerative Carbonate-Based Thermochemical Energy Storage System for Concentrating Solar Power Project Profile: Regenerative Carbonate-Based Thermochemical Energy...

  17. Energy-Related Carbon Emissions in Manufacturing

    Reports and Publications (EIA)

    2000-01-01

    Energy-related carbon emissions in manufacturing analysis and issues related to the energy use, energy efficiency, and carbon emission indicators.

  18. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  19. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiochon, Georges A; Liang, Chengdu

    2014-01-14

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  20. DOE's Carbon Sequestration Partnership Program Adds Canadian...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE's Carbon Sequestration Partnership Program Adds Canadian Provinces DOE's Carbon Sequestration Partnership Program Adds Canadian Provinces February 16, 2005 - 10:14am Addthis...

  1. Carbon Sequestration Conference | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Sequestration Conference Carbon Sequestration Conference May 9, 2006 - 10:37am Addthis Remarks Prepared for Energy Secretary Samuel Bodman Thank you. It's a pleasure for me...

  2. ASSESSMENT OF HOUSEHOLD CARBON FOOTPRINT REDUCTION POTENTIALS

    E-Print Network [OSTI]

    Masanet, Eric

    2010-01-01

    21 Estimation of Home Energy and Supply Chain Carbonthe annual home energy and supply chain carbon footprints average direct home energy and supply chain carbon 

  3. Hydrogen Adsorption Induces Interlayer Carbon Bond Formation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Adsorption Induces Interlayer Carbon Bond Formation in Supported Few-Layer Graphene Friday, February 28, 2014 Among the allotropes of carbon, diamond has some of the most...

  4. Carbonic Acid Shows Promise in Geology, Biology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Surprising Secrets of Carbonic Acid Probing the Surprising Secrets of Carbonic Acid Berkeley Lab Study Holds Implications for Geological and Biological Processes October 23,...

  5. Carbon Fiber Technology Facility | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Fiber Technology Facility Carbon Fiber Technology Facility 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

  6. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01

    of well-aligned carbon nanotubes on nickel by hot-filamenton the growth of carbon nanotubes from nickel clusters—ancarbon nanotubes using monodisperse nickel nanoparticles

  7. Distributed Energy Resources for Carbon Emissions Mitigation

    E-Print Network [OSTI]

    Firestone, Ryan; Marnay, Chris

    2008-01-01

    2003. “Gas-Fired Distributed Energy Resource TechnologyATIONAL L ABORATORY Distributed Energy Resources for CarbonFirestone 5128 Distributed Energy Resources for Carbon

  8. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01

    H. Yang, and C. Liu, Hydrogen storage in carbon nanotubes.A. , et al. , Hydrogen storage in carbon nanostructures.M.G. , et al. , Hydrogen storage using physisorption-

  9. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiohon, Georges A; Liang, Chengdu

    2013-02-05

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  10. CFTF | Carbon Fiber Technology Facility | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BTRIC CNMS CSMB CFTF Working with CFTF HFIR MDF NTRC OLCF SNS Carbon Fiber Technology Facility Home | User Facilities | CFTF CFTF | Carbon Fiber Technology Facility SHARE Oak...

  11. California Low Carbon Fuels Infrastructure Investment Initiative...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Carbon Fuels Infrastructure Investment Initiative California Low Carbon Fuels Infrastructure Investment Initiative 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  12. SciTech Connect: "carbon sequestration"

    Office of Scientific and Technical Information (OSTI)

    carbon sequestration" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "carbon sequestration" Semantic Semantic Term Title: Full Text:...

  13. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  14. Macrobiotic Vertical Transport of Litter Derived Carbon

    E-Print Network [OSTI]

    Post, Wilfred M.

    Macrobiotic Vertical Transport of Litter Derived Carbon (Earthworm Phase) Mac Callaham Corey Babb in each treatment Sampling #12;Macrobiotic Vertical Transport of Litter Derived Carbon (millipede phase

  15. Neutron Scattering Studies of Liquid on or Confined in Nano- and Mesoporous Carbons, Including Carbide-Derived Carbons

    SciTech Connect (OSTI)

    Wesolowski, David J

    2014-07-01

    This project involved the synthesis of microporous graphitic-carbon powders with subnanometer average pore size, and very narrow pore size distributions, and the use of these materials in experimental studies of pore-fluid structure and dynamics. Samples of carbide-derived carbon powder, synthesized by extraction of the metal cations from TiC by a high temperature chlorination process, followed by high temperature vacuum annealing, were prepared by Ranjan Dash and his associates at CRADA partner Y-Carbon, Inc. The resulting material had average pore sizes ranging from 5 to 8 . These powders were used in two experiments conducted by researchers involved in the Energy Frontier Research Center Directed by David J. Wesolowski at ORNL, the Fluid Interface Reactions, Structures and Transport (FIRST) Center. FIRST-funded researchers at Drexel University collaborated with scientists at the Paul Scherrer Institute, Switzerland, to measure the expansion and contraction of the microporous carbon particles during charging and discharging of supercapactor electrodes composed of these particles (Hantell et al., 2011, Electrochemistry Communications, v. 13, pp. 1221-1224.) in an electrolyte composed of tetraethylammonium tetrafluoroborate dissolved in acetonitrile. In the second experiment, researchers at Oak Ridge National Laboratory and Drexel University conducted quasielastic neutron scattering studies of the diffusional dynamics of water imbibed into the micropores of the same material (Chathoth et al., 2011, EuroPhysics Journal, v. 95, pp. 56001/1-6). These studies helped to establish the role of pores approaching the size of the solvent and dissolved ions in altering diffusional dynamics, ion transport and physical response of conducting substrates to ion desolvation and entry into subnamometer pores.

  16. Argonne Terrestrial Carbon Cycle Data from Batavia Prairie and Agricultural Sites

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Matamala, Roser [ANL; Jastrow, Julie D.; Lesht, Barry [ANL; Cook, David [ANL; Pekour, Mikhail [ANL; Gonzalez-Meler, Miquel A. [University of Illinois at Chicago

    Carbon dioxide fluxes and stocks in terrestrial ecosystems are key measurements needed to constrain quantification of regional carbon sinks and sources and the mechanisms controlling them. This information is required to produce a sound carbon budget for North America. This project examines CO2 and energy fluxes from agricultural land and from restored tallgrass prairie to compare their carbon sequestration potentials. The study integrates eddy covariance measurements with biometric measurements of plant and soil carbon stocks for two systems in northeastern Illinois: 1) long-term cultivated land in corn-soybean rotation with conventional tillage, and 2) a 15 year-old restored prairie that represents a long-term application of CRP conversion of cultivated land to native vegetation. The study contributes to the North American Carbon Program (NACP) by providing information on the magnitude and distribution of carbon stocks and the processes that control carbon dynamics in cultivated and CRP-restored land in the Midwest. The prairie site has been functioning since October 2004 and the agricultural site since July 2005. (From http://www.atmos.anl.gov/ FERMI/index.html)

  17. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01

    facts: Average carbon dioxide emissions resulting fromcalculation of carbon dioxide (CO 2 ) emissions from fuel

  18. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1999-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid partides being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  19. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1999-04-27

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  20. Method for fabricating composite carbon foam

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    2001-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  1. Modeling dynamic crack propagation in fiber reinforced composites including frictional effects q

    E-Print Network [OSTI]

    Espinosa, Horacio D.

    Modeling dynamic crack propagation in fiber reinforced composites including frictional effects q S Abstract Dynamic crack propagation in a unidirectional carbon/epoxy composite is studied through finite deformation anisotropic visco-plastic model is used to describe the constitutive response of the composite

  2. A Molecular Dynamics Simulation of Hydrogen Storage by SWNTs Tatsuto Kimuraa

    E-Print Network [OSTI]

    Maruyama, Shigeo

    A Molecular Dynamics Simulation of Hydrogen Storage by SWNTs Tatsuto Kimuraa and Shigeo Maruyamab of efficient hydrogen storage [1] with SWNTs [2,3] was studied through classical molecular dynamics simulations adsorbed hydrogen molecules was almost proportional to the number of carbon atoms, and the storage amount

  3. Gas permeability of carbon aerogels

    SciTech Connect (OSTI)

    Kong, F.; LeMay, J.D.; Hulsey, S.S.; Alviso, C.T.; Pekala, R.W. (Chemistry and Materials Science Department, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States))

    1993-12-01

    Carbon aerogels are synthesized via the aqueous polycondensation of resorcinol with formaldehyde, followed by supercritical drying and subsequent pyrolysis at 1050 [degree]C. As a result of their interconnected porosity, ultrafine cell/pore size, and high surface area, carbon aerogels have many potential applications such as supercapacitors, battery electrodes, catalyst supports, and gas filters. The performance of carbon aerogels in the latter two applications depends on the permeability or gas flow conductance in these materials. By measuring the pressure differential across a thin specimen and the nitrogen gas flow rate in the viscous regime, the permeability of carbon aerogels was calculated from equations based upon Darcy's law. Our measurements show that carbon aerogels have permeabilities on the order of 10[sup [minus]12] to 10[sup [minus]10] cm[sup 2] over the density range from 0.05--0.44 g/cm[sup 3]. Like many other aerogel properties, the permeability of carbon aerogels follows a power law relationship with density, reflecting differences in the average mesopore size. Comparing the results from this study with the permeability of silica aerogels reported by other workers, we found that the permeability of aerogels is governed by a simple universal flow equation. This paper discusses the relationship between permeability, pore size, and density in carbon aerogels.

  4. Controls on terrestrial carbon feedbacks by productivity versus turnover in the CMIP5 Earth System Models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Koven, C. D.; Chambers, J. Q.; Georgiou, K.; Knox, R.; Negron-Juarez, R.; Riley, W. J.; Arora, V. K.; Brovkin, V.; Friedlingstein, P.; Jones, C. D.

    2015-09-07

    To better understand sources of uncertainty in projections of terrestrial carbon cycle feedbacks, we present an approach to separate the controls on modeled carbon changes. We separate carbon changes into four categories using a linearized, equilibrium approach: those arising from changed inputs (productivity-driven changes), and outputs (turnover-driven changes), of both the live and dead carbon pools. Using Coupled Model Intercomparison Project Phase 5 (CMIP5) simulations for five models, we find that changes to the live pools are primarily explained by productivity-driven changes, with only one model showing large compensating changes to live carbon turnover times. For dead carbon pools, themore »situation is more complex as all models predict a large reduction in turnover times in response to increases in productivity. This response arises from the common representation of a broad spectrum of decomposition turnover times via a multi-pool approach, in which flux-weighted turnover times are faster than mass-weighted turnover times. This leads to a shift in the distribution of carbon among dead pools in response to changes in inputs, and therefore a transient but long-lived reduction in turnover times. Since this behavior, a reduction in inferred turnover times resulting from an increase in inputs, is superficially similar to priming processes, but occurring without the mechanisms responsible for priming, we call the phenomenon "false priming", and show that it masks much of the intrinsic changes to dead carbon turnover times as a result of changing climate. These patterns hold across the fully coupled, biogeochemically coupled, and radiatively coupled 1 % yr?1 increasing CO2 experiments. We disaggregate inter-model uncertainty in the globally integrated equilibrium carbon responses to initial turnover times, initial productivity, fractional changes in turnover, and fractional changes in productivity. For both the live and dead carbon pools, inter-model spread in carbon changes arising from initial conditions is dominated by model disagreement on turnover times, whereas inter-model spread in carbon changes from fractional changes to these terms is dominated by model disagreement on changes to productivity in response to both warming and CO2 fertilization. However, the lack of changing turnover time control on carbon responses, for both live and dead carbon pools, in response to the imposed forcings may arise from a common lack of process representation behind changing turnover times (e.g., allocation and mortality for live carbon; permafrost, microbial dynamics, and mineral stabilization for dead carbon), rather than a true estimate of the importance of these processes.« less

  5. Controls on terrestrial carbon feedbacks by productivity vs. turnover in the CMIP5 Earth System Models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Koven, C. D.; Chambers, J. Q.; Georgiou, K.; Knox, R.; Negron-Juarez, R.; Riley, W. J.; Arora, V. K.; Brovkin, V.; Friedlingstein, P.; Jones, C. D.

    2015-04-16

    To better understand sources of uncertainty in projections of terrestrial carbon cycle feedbacks, we present an approach to separate the controls on modeled carbon changes. We separate carbon changes into 4 categories using a linearized, equilibrium approach: those arising from changed inputs (productivity-driven changes), and outputs (turnover-driven changes), and apply the analysis separately to the live and dead carbon pools. Using Coupled Model Intercomparison Project Phase 5 (CMIP5) simulations for 5 models, we find that changes to the live pools are primarily explained by productivity-driven changes, with only one model showing large compensating changes to live carbon turnover times. Formore »dead carbon pools, the situation is more complex as all models predict a large reduction in turnover times in response to increases in productivity. This responses arises from the common representation of a broad spectrum of decomposition turnover times via a multi-pool approach, in which flux-weighted turnover times are faster than mass-weighted turnover times. This leads to a shift in the distribution of carbon among dead pools in response to changes in inputs, and therefore a transient but long-lived reduction in turnover times in response to increases in productivity. Since this behavior, a reduction in inferred turnover times resulting from an increase in inputs, is superficially similar to priming processes, but occurring without the mechanisms responsible for priming, we call the phenomenon "false priming", and show that it masks much of the intrinsic changes to dead carbon turnover times as a result of changing climate. These patterns hold across the fully-coupled, biogeochemically-coupled, and radiatively-coupled 1% yr?1 increasing CO2 experiments. We disaggregate inter-model uncertainty in the globally-integrated equilibrium carbon responses to initial turnover times, inital productivity, fractional changes in turnover, and fractional changes in productivity. For both the live and dead carbon pools, inter-model spread in carbon changes arising from initial conditions is dominated by model disagreement on turnover times, whereas inter-model spread in carbon changes from fractional changes to these terms is dominated by model disagreement on changes to productivity in response to both warming and CO2 fertilization. However, the lack of changing turnover time control on carbon responses, for both live and dead carbon pools, in response to the imposed forcings may indicate a common lack of process representation behind changing turnover times (e.g., allocation and mortality for live carbon; permafrost, microbial dynamics, and mineral stabilization for dead carbon), rather than a true estimate of the uncertainty in these processes.« less

  6. Measuring supply chain carbon efficiency : a carbon label framework

    E-Print Network [OSTI]

    Craig, Anthony (Anthony J.)

    2012-01-01

    In the near term, efficiency improvements represent a key option for reducing the impacts of climate change. The growing awareness of climate change has increased the attention regarding the carbon emissions "embedded" in ...

  7. Carbon films produced from ionic liquid carbon precursors

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Lee, Je Seung

    2013-11-05

    The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ionic liquid has the general formula (X.sup.+a).sub.x(Y.sup.-b).sub.y, wherein the variables a and b are, independently, non-zero integers, and the subscript variables x and y are, independently, non-zero integers, such that ax=by, and at least one of X.sup.+ and Y.sup.- possesses at least one carbon-nitrogen unsaturated bond. The invention is also directed to a composition comprising a porous carbon film possessing a nitrogen content of at least 10 atom %.

  8. Carbon foam characterization tensile evaluation of carbon foam ligaments 

    E-Print Network [OSTI]

    Verdugo Rodriguez, Rogelio Alberto

    2004-09-30

    of the carbon foam ligaments (RVC) could be described with a one-population distribution, it is found that a two-population Weibull distribution is necessary to describe the distribution of strength of the SiC coated ligaments....

  9. Carbon dioxide hydrate particles for ocean carbon sequestration

    E-Print Network [OSTI]

    Chow, Aaron C.

    This paper presents strategies for producing negatively buoyant CO[subscript 2] hydrate composite particles for ocean carbon sequestration. Our study is based on recent field observations showing that a continuous-jet ...

  10. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    unresolved problems in life cycle assessment, Part 1: goalanalysis. Int. J. Life Cycle Assessment Roels, G. , U.S.that the focus in the life-cycle assessment (LCA) and carbon

  11. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  12. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (Auburn, AL); Dispennette, John M. (Auburn, AL)

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

  13. Carbone Lorraine | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to: navigation, search Name: Carbon Trade LtdCarbonCarbone

  14. The role of carbon in extrasolar planetary geodynamics and habitability

    SciTech Connect (OSTI)

    Unterborn, Cayman T.; Kabbes, Jason E.; Pigott, Jeffrey S.; Panero, Wendy R. [School of Earth Sciences, The Ohio State University, 125 South Oval Mall, Columbus, OH 43202 (United States); Reaman, Daniel M., E-mail: unterborn.1@buckeyemail.osu.edu [US Army Research Laboratory, RDRL-WML-B (Bldg. 390), Aberdeen Proving Ground, MD 21005 (United States)

    2014-10-01

    The proportions of oxygen, carbon, and major rock-forming elements (e.g., Mg, Fe, Si) determine a planet's dominant mineralogy. Variation in a planet's mineralogy subsequently affects planetary mantle dynamics as well as any deep water or carbon cycle. Through thermodynamic models and high pressure diamond anvil cell experiments, we demonstrate that the oxidation potential of C is above that of Fe at all pressures and temperatures, indicative of 0.1-2 Earth-mass planets. This means that for a planet with (Mg+2Si+Fe+2C)/O > 1, excess C in the mantle will be in the form of diamond. We find that an increase in C, and thus diamond, concentration slows convection relative to a silicate-dominated planet, due to diamond's ?3 order of magnitude increase in both viscosity and thermal conductivity. We assert then that in the C-(Mg+2Si+Fe)-O system, there is a compositional range in which a planet can be habitable. Planets outside of this range will be dynamically sluggish or stagnant, thus having limited carbon or water cycles leading to surface conditions inhospitable to life as we know it.

  15. Sandia Energy - Chemical Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Dynamics Home Transportation Energy Predictive Simulation of Engines Combustion Chemistry Chemical Dynamics Chemical DynamicsAshley Otero2015-10-28T02:45:37+00:00...

  16. Thermal resistance and phonon scattering at the interface between carbon nanotube and amorphous polyethylene

    E-Print Network [OSTI]

    Elliott, James

    dynamics study of heat conduction in carbon nanotube (CNT)/polyethylene (PE) composites. Particular thermal conductivity of a macroscopic CNT/PE composite is quantified based on an effective medium approximation model. Ó 2013 Elsevier Ltd. All rights reserved. 1. Introduction Polymer composites are employed

  17. Thermal resistance and phonon scattering at the interface between carbon nanotube and amorphous polyethylene

    E-Print Network [OSTI]

    Elliott, James

    polyethylene Sho Hida a , Takuma Hori a , Takuma Shiga a , James Elliott b , Junichiro Shiomi a,c, a Department dynamics study of heat conduction in carbon nanotube (CNT)/polyethylene (PE) composites. Particular across the CNT/polyethylene interfaces ($1 Â 10À7 m2 K WÀ1 ) and a moder- ate but non

  18. THE JOURNAL OF CHEMICAL PHYSICS 134, 044908 (2011) Multicomponent ballistic transport in narrow single wall carbon

    E-Print Network [OSTI]

    Adler, Joan

    2011-01-01

    online 27 January 2011) The transport of gas mixtures through molecular-sieve membranes such as narrow The transport of gas mixtures through molecular-sieve membranes and catalysts has been a subject of intensive in single wall carbon nanotubes: Analytic model and molecular dynamics simulations T. Mutat,1 J. Adler,1,a

  19. Understanding the effects of drought upon carbon allocation and cycling in an

    E-Print Network [OSTI]

    for the use of its field station and laboratory facilities, and Bene and Joca for committed field work root dynamics, in particular, presents methodological challenges. Thus, I critically review existing area per unit mass show the opposite pattern. The other major component of the below-ground carbon

  20. Fusion of Neutron-Rich O Ions on a Carbon Target at Near-Barrier Energies

    E-Print Network [OSTI]

    de Souza, Romualdo T.

    Fusion of Neutron-Rich O Ions on a Carbon Target at Near-Barrier Energies Indiana University: M in the outer crust · Superbursts observed for accreting neutron stars · Fusion of neutron-rich light nuclei as a possible heat source in neutron star crust Fusion cross-section · Dynamics of fusion reaction with neutron

  1. Influence of interfaces on diffusive-ballistic heat conduction of carbon Shiomi, Junichiro, Maruyama, Shigeo

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Influence of interfaces on diffusive-ballistic heat conduction of carbon nanotubes Shiomi and heat sinks/sources is expected to determine the overall heat transfer performance. Such interfaces and scattering dynamics at the interfaces. In the current study, this aspect is explored by using equilibrium

  2. Reactions of carbon atoms in pulsed molecular beams

    SciTech Connect (OSTI)

    Reisler, H. [Univ. of Southern California, Los Angeles (United States)

    1993-12-01

    This research program consists of a broad scope of experiments designed to unravel the chemistry of atomic carbon in its two spin states, P and D, by using well-controlled initial conditions and state-resolved detection of products. Prerequisite to the proposed studies (and the reason why so little is known about carbon atom reactions), is the development of clean sources of carbon atoms. Therefore, in parallel with the studies of its chemistry and reaction dynamics, the authors continuously explore new, state-specific and efficient ways of producing atomic carbon. In the current program, C({sup 3}P) is produced via laser ablation of graphite, and three areas of study are being pursued: (i) exothermic reactions with small inorganic molecules (e.g., O{sub 2}, N{sub 2}O, NO{sub 2}) that can proceed via multiple pathways; (ii) the influence of vibrational and translational energy on endothermic reactions involving H-containing reactants that yield CH products (e.g., H{sub 2}O H{sub 2}CO); (iii) reactions of C({sup 3}P) with free radicals (e.g., HCO, CH{sub 3}O). In addition, the authors plan to develop a source of C({sup 1}D) atoms by exploiting the pyrolysis of diazotetrazole and its salts in the ablation source. Another important goal involves collaboration with theoreticians in order to obtain relevant potential energy surfaces, rationalize the experimental results and predict the roles of translational and vibrational energies.

  3. Microbial Carbon Cycling in Permafrost-Affected Soils

    SciTech Connect (OSTI)

    Vishnivetskaya, T.; Liebner, Susanne; Wilhelm, Ronald; Wagner, Dirk

    2011-01-01

    The Arctic plays a key role in Earth s climate system as global warming is predicted to be most pronounced at high latitudes and because one third of the global carbon pool is stored in ecosystems of the northern latitudes. In order to improve our understanding of the present and future carbon dynamics in climate sensitive permafrost ecosystems, present studies concentrate on investigations of microbial controls of greenhouse gas fluxes, on the activity and structure of the involved microbial communities, and on their response to changing environmental conditions. Permafrost-affected soils can function as both a source and a sink for carbon dioxide and methane. Under anaerobic conditions, caused by flooding of the active layer and the effect of backwater above the permafrost table, the mineralization of organic matter can only be realized stepwise by specialized microorganisms. Important intermediates of the organic matter decomposition are hydrogen, carbon dioxide and acetate, which can be further reduced to methane by methanogenic archaea. Evolution of methane fluxes across the subsurface/atmosphere boundary will thereby strongly depend on the activity of anaerobic methanogenic archaea and obligately aerobic methane oxidizing proteobacteria, which are known to be abundant and to significantly reduce methane emissions in permafrost-affected soils. Therefore current studies on methane-cycling microorganisms are the object of particular attention in permafrost studies, because of their key role in the Arctic methane cycle and consequently of their significance for the global methane budget.

  4. Carbon Cycle Coastal Sensitivity to Sea

    E-Print Network [OSTI]

    For the Year 2000. Available online from the Carbon Dioxide Information Analysis Center [http to reduce carbon emissions from landuse change, and may also advance global terrestrial and climate an enormous 500 billion tones of carbon, more than 60 times annual anthropogenic carbon emissions

  5. Biochar and Carbon Sequestration: A Regional Perspective

    E-Print Network [OSTI]

    Everest, Graham R

    Biochar and Carbon Sequestration: A Regional Perspective A report prepared for East of England #12;Low Carbon Innovation Centre Report for EEDA Biochar and Carbon Sequestration: A Regional Perspective 20/04/2009 ii Biochar and Carbon Sequestration: A Regional Perspective A report prepared for East

  6. 6 Monthly Report on MMU Carbon

    E-Print Network [OSTI]

    Monthly Report on MMU Carbon Management Plan #12;2009/10 Emissions MMU Carbon Footprint Trajectory Project Footprint MMU Actual Carbon Footprint Projects that Reduced the 2009/10 CO2 Footprint #12;2010/11 Emissions6 Monthly Report on MMU Carbon Management Plan June 2011 let's make a sustainable planet #12

  7. Electrochemical implications of defects in carbon nanotubes

    E-Print Network [OSTI]

    Hoefer, Mark

    2012-01-01

    Electrochemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .on Electrochemistry . . . . . . . . . . . . . . . . . 4.3.1P. H. L. Notten. The electrochemistry of carbon nanotubes.

  8. Climate policy and dependence on traded carbon

    E-Print Network [OSTI]

    Andrew, Robbie M; Davis, Steven J; Peters, Glen P

    2013-01-01

    embodied carbon content, apply rebates for emissions chargescarbon adjustments versus rebates J. Environ. Econom. Manag.

  9. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01

    carbon nanotube ceramic matrix composites. Acta Materialia,ceramic matrix material. These fiber reinforced composites

  10. Rapid oxidation/stabilization technique for carbon foams, carbon fibers and C/C composites

    DOE Patents [OSTI]

    Tan, Seng; Tan, Cher-Dip

    2004-05-11

    An enhanced method for the post processing, i.e. oxidation or stabilization, of carbon materials including, but not limited to, carbon foams, carbon fibers, dense carbon-carbon composites, carbon/ceramic and carbon/metal composites, which method requires relatively very short and more effective such processing steps. The introduction of an "oxygen spill over catalyst" into the carbon precursor by blending with the carbon starting material or exposure of the carbon precursor to such a material supplies required oxygen at the atomic level and permits oxidation/stabilization of carbon materials in a fraction of the time and with a fraction of the energy normally required to accomplish such carbon processing steps. Carbon based foams, solids, composites and fiber products made utilizing this method are also described.

  11. Increasing carbon nanotube forest density

    E-Print Network [OSTI]

    McCarthy, Alexander P

    2014-01-01

    The outstanding mechanical, electrical, thermal, and morphological properties of individual carbon nanotubes (CNTs) open up exciting potential applications in a wide range of fields. One such application is replacing the ...

  12. Method for making carbon films

    DOE Patents [OSTI]

    Tan, Ming X. (Livermore, CA)

    1999-01-01

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

  13. Method for making carbon films

    DOE Patents [OSTI]

    Tan, M.X.

    1999-07-29

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area ([approx equal]1000 m[sup 2] /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160 C for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750 C in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750--850 C for between 1--6 hours. 2 figs.

  14. Low density carbonized composite foams

    DOE Patents [OSTI]

    Kong, Fung-Ming (Pleasanton, CA)

    1991-01-01

    A carbonized composite foam having a density less than about 50 mg/cm.sup.3 and individual cell sizes no greater than about 1 .mu.m in diameter is described, and the process of making it.

  15. Reducing carbon dioxide to products

    DOE Patents [OSTI]

    Cole, Emily Barton; Sivasankar, Narayanappa; Parajuli, Rishi; Keets, Kate A

    2014-09-30

    A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

  16. Carbon-assisted flyer plates

    DOE Patents [OSTI]

    Stahl, D.B.; Paisley, D.L.

    1994-04-12

    A laser driven flyer plate is described utilizing an optical fiber connected to a laser. The end of the optical fiber has a layer of carbon and a metal layer deposited onto it. The carbon layer provides the laser induced plasma which is superior to the plasma produced from most metals. The carbon layer plasma is capable of providing a flatter flyer plate, converting more of the laser energy to driving plasma, promoting a higher flyer plate acceleration, and providing a more uniform pulse behind the plate. In another embodiment, the laser is in optical communication with a substrate onto which a layer of carbon and a layer of metal have been deposited. 2 figures.

  17. The Australian terrestrial carbon budget

    E-Print Network [OSTI]

    2013-01-01

    emissions from fossil-fuel com- bustion, Biogeosciences, 9,re- gional and national fossil-fuel CO 2 emissions, Carbontimes more carbon in fossil fuels than it emitted by burning

  18. Emerging Applications of Carbon Nanotubes

    E-Print Network [OSTI]

    Schnorr, Jan Markus

    On the basis of their unique electrical and mechanical properties, carbon nanotubes (CNTs) have attracted great attention in recent years. A diverse array of methods has been developed to modify CNTs and to assemble them ...

  19. Non-carbon induction furnace

    DOE Patents [OSTI]

    Holcombe, C.E.; Masters, D.R.; Pfeiler, W.A.

    1984-01-06

    The present invention is directed to an induction furnace for melting and casting highly pure metals and alloys such as uranium and uranium alloys in such a manner as to minimize contamination of the melt by carbon derived from the materials and the environment within the furnace. The subject furnace is constructed of non-carbon materials and is housed within a conventional vacuum chamber. The furnace comprises a ceramic oxide crucible for holding the charge of metal or alloys. The heating of the crucible is achieved by a plasma-sprayed tungsten susceptor surrounding the crucible which, in turn, is heated by an rf induction coil separated from the susceptor by a cylinder of inorganic insulation. The furnace of the present invention is capable of being rapidly cycled from ambient temperatures to about 1650/sup 0/C for effectively melting uranium and uranium alloys without the attendant carbon contamination problems previously encountered when using carbon-bearing furnace materials.

  20. Carbon-free induction furnace

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Knoxville, TN); Masters, David R. (Knoxville, TN); Pfeiler, William A. (Norris, TN)

    1985-01-01

    An induction furnace for melting and casting highly pure metals and alloys such as uranium and uranium alloys in such a manner as to minimize contamination of the melt by carbon derived from the materials and the environment within the furnace. The subject furnace is constructed of carbon free materials and is housed within a conventional vacuum chamber. The furnace comprises a ceramic oxide crucible for holding the charge of metal or alloy. The heating of the crucible is achieved by a plasma-sprayed tungsten susceptor surrounding the crucible which, in turn, is heated by an RF induction coil separated from the susceptor by a cylinder of inorganic insulation. The furnace of the present invention is capable of being rapidly cycled from ambient temperatures to about 1650.degree. C. for effectively melting uranium and uranium alloys without the attendant carbon contamination problems previously encountered when using carbon-bearing furnace materials.

  1. Activated carbon to the rescue

    SciTech Connect (OSTI)

    Sen, S.

    1996-03-01

    This article describes the response to pipeline spill of ethylene dichloride (EDC) on the property of an oil company. Activated carbon cleanup proceedure was used. During delivery, changeout, transport, storage, thermal reactivation, and return delivery to the site, the carbon never came into direct contact with operating personnel or the atmosphere. More than 10,000 tones of dredge soil and 50 million gallons of surface water were processed during the emergency response.

  2. Lithographically defined microporous carbon structures

    DOE Patents [OSTI]

    Burckel, David Bruce; Washburn, Cody M.; Polsky, Ronen; Brozik, Susan M.; Wheeler, David R.

    2013-01-08

    A lithographic method is used to fabricate porous carbon structures that can provide electrochemical electrodes having high surface area with uniform and controllable dimensions, providing enormous flexibility to tailor the electrodes toward specific applications. Metal nanoparticles deposited on the surface of the porous carbon electrodes exhibit ultra small dimensions with uniform size distribution. The resulting electrodes are rugged, electrically conductive and show excellent electrochemical behavior.

  3. Recuperative supercritical carbon dioxide cycle

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

    2014-11-18

    A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

  4. University of Glasgow Carbon Management Programme Carbon Management Plan working with

    E-Print Network [OSTI]

    Swain, Peter

    fully in the initiatives which will help us reduce our carbon footprint and combat climate changeUniversity of Glasgow Carbon Management Programme Carbon Management Plan working with Page 1 Carbon Management Programme Carbon Management Plan (CMP) Albert Young, 3 November 2009 #12;University of Glasgow

  5. Modeling the selectivity of activated carbons for efficient separation of hydrogen and carbon dioxide

    E-Print Network [OSTI]

    Wu, Jianzhong

    the separation of hydrogen and carbon dioxide via adsorption in activated carbons. In the simulations, both hydrogen and carbon dioxide molecules are modeled as Lennard-Jones spheres, and the activated carbons essentially no preference over the two gases and the selectivity of carbon dioxide relative to hydrogen falls

  6. Untangling the formation of the cyclic carbon trioxide isomer in low temperature carbon dioxide ices

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Untangling the formation of the cyclic carbon trioxide isomer in low temperature carbon dioxide of the cyclic carbon trioxide isomer, CO3(X 1 A1), in carbon-dioxide-rich extraterrestrial ices and in the atmospheres of Earth and Mars were investigated experimentally and theoretically. Carbon dioxide ices were

  7. Protein carbon content evolves in response to carbon availability and may influence

    E-Print Network [OSTI]

    Wagner, Andreas

    Protein carbon content evolves in response to carbon availability and may influence the fate that ancestral yeast strains preferentially express proteins with low carbon content during carbon limitation, relative to strains selected in the laboratory under carbon limitation. The likely reason

  8. Kinetic fractionation of carbon and oxygen isotopes during hydration of carbon dioxide

    E-Print Network [OSTI]

    Zeebe, Richard E.

    Kinetic fractionation of carbon and oxygen isotopes during hydration of carbon dioxide Richard E the inorganic hydration of carbon dioxide (CO2) in aqueous solution cause reduced stable carbon and oxygen of the carbon and oxygen kinetic isotope fractionation (KIF) during hydration of CO2. Here I use transition

  9. Transient simulations of Holocene atmospheric carbon dioxide and terrestrial carbon since the Last

    E-Print Network [OSTI]

    Fortunat, Joos

    Transient simulations of Holocene atmospheric carbon dioxide and terrestrial carbon since the Last ppm between 8 ka BP and pre-industrial time. The carbon component of the Bern Carbon Cycle Climate. Terrestrial carbon inventory changes related to climate and CO2 forcing, the greening of the Sahara, peat

  10. IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 38, NO. 12, DECEMBER 2010 3265 Combustion Dynamics of Plasma-Enhanced

    E-Print Network [OSTI]

    Lee, Tonghun

    -induced fluorescence images of hydroxyl (OH) and carbon monoxide (CO) radicals are obtained over a range of equivalence are significantly influenced by in situ fuel reforming at higher plasma powers. Index Terms--Carbon monoxide, fuelIEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 38, NO. 12, DECEMBER 2010 3265 Combustion Dynamics

  11. Carbon sequestration research and development

    SciTech Connect (OSTI)

    Reichle, Dave; Houghton, John; Kane, Bob; Ekmann, Jim; and others

    1999-12-31

    Predictions of global energy use in the next century suggest a continued increase in carbon emissions and rising concentrations of carbon dioxide (CO{sub 2}) in the atmosphere unless major changes are made in the way we produce and use energy--in particular, how we manage carbon. For example, the Intergovernmental Panel on Climate Change (IPCC) predicts in its 1995 ''business as usual'' energy scenario that future global emissions of CO{sub 2} to the atmosphere will increase from 7.4 billion tonnes of carbon (GtC) per year in 1997 to approximately 26 GtC/year by 2100. IPCC also projects a doubling of atmospheric CO{sub 2} concentration by the middle of next century and growing rates of increase beyond. Although the effects of increased CO{sub 2} levels on global climate are uncertain, many scientists agree that a doubling of atmospheric CO{sub 2} concentrations could have a variety of serious environmental consequences. The goal of this report is to identify key areas for research and development (R&D) that could lead to an understanding of the potential for future use of carbon sequestration as a major tool for managing carbon emissions. Under the leadership of DOE, researchers from universities, industry, other government agencies, and DOE national laboratories were brought together to develop the technical basis for conceiving a science and technology road map. That effort has resulted in this report, which develops much of the information needed for the road map.

  12. Scale-up of Carbon/Carbon Bipolar Plates

    SciTech Connect (OSTI)

    David P. Haack

    2009-04-08

    This project was focused upon developing a unique material technology for use in PEM fuel cell bipolar plates. The carbon/carbon composite material developed in this program is uniquely suited for use in fuel cell systems, as it is lightweight, highly conductive and corrosion resistant. The project further focused upon developing the manufacturing methodology to cost-effectively produce this material for use in commercial fuel cell systems. United Technology Fuel Cells Corp., a leading fuel cell developer was a subcontractor to the project was interested in the performance and low-cost potential of the material. The accomplishments of the program included the development and testing of a low-cost, fully molded, net-shape carbon-carbon bipolar plate. The process to cost-effectively manufacture these carbon-carbon bipolar plates was focused on extensively in this program. Key areas for cost-reduction that received attention in this program was net-shape molding of the detailed flow structures according to end-user design. Correlations between feature detail and process parameters were formed so that mold tooling could be accurately designed to meet a variety of flow field dimensions. A cost model was developed that predicted the cost of manufacture for the product in near-term volumes and long-term volumes (10+ million units per year). Because the roduct uses lowcost raw materials in quantities that are less than competitive tech, it was found that the cost of the product in high volume can be less than with other plate echnologies, and can meet the DOE goal of $4/kW for transportation applications. The excellent performance of the all-carbon plate in net shape was verified in fuel cell testing. Performance equivalent to much higher cost, fully machined graphite plates was found.

  13. The phase diagram and hardness of carbon nitrides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dong, Huafeng; Oganov, Artem R.; Moscow Inst. of Physics and Technology; Northwestern Polytechnical Univ., Xi'an; Zhu, Qiang; Qian, Guang-Rui

    2015-05-06

    Novel superhard materials, especially those with superior thermal and chemical stability, are needed to replace diamond. Carbon nitrides (C-N), which are likely to possess these characteristics and have even been expected to be harder than diamond, are excellent candidates. Here we report three new superhard and thermodynamically stable carbon nitride phases. Based on a systematic evolutionary structure searches, we report a complete phase diagram of the C-N system at 0–300 GPa and analyze the hardest metastable structures. Surprisingly, we find that at zero pressure, the earlier proposed graphitic-C3N4 structure (P6-bar m2) is dynamically unstable, and we find the lowest-energy structuremore »based on s-triazine unit and s-heptazine unit.« less

  14. The phase diagram and hardness of carbon nitrides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dong, Huafeng; Oganov, Artem R.; Zhu, Qiang; Qian, Guang-Rui

    2015-05-06

    Novel superhard materials, especially those with superior thermal and chemical stability, are needed to replace diamond. Carbon nitrides (C-N), which are likely to possess these characteristics and have even been expected to be harder than diamond, are excellent candidates. Here we report three new superhard and thermodynamically stable carbon nitride phases. Based on a systematic evolutionary structure searches, we report a complete phase diagram of the C-N system at 0–300 GPa and analyze the hardest metastable structures. Surprisingly, we find that at zero pressure, the earlier proposed graphitic-C3N4 structure (P_6m2) is dynamically unstable, and we find the lowest-energy structure based on s-triazine unit and s-heptazine unit.

  15. Broadband laser polarization control with aligned carbon nanotubes

    E-Print Network [OSTI]

    Yang, He; Lia, Diao; Chen, Ya; Mattila, Marco; Tian, Ying; Yong, Zhenzhong; Yang, Changxi; Tittonen, Ilkka; Ren, Zhaoyu; Bai, Jingtao; Li, Qingwen; Kauppinen, Esko I; Lipsanen, Harri; Sun, Zhipei

    2015-01-01

    We introduce a simple approach to fabricate aligned carbon nanotube (ACNT) device for broadband polarization control in fiber laser systems. The ACNT device was fabricated by pulling from as-fabricated vertically-aligned carbon nanotube arrays. Their anisotropic property is confirmed with optical and scanning electron microscopy, and with polarized Raman and absorption spectroscopy. The device was then integrated into fiber laser systems (at two technologically important wavelengths of 1 and 1.5 um) for polarization control. We obtained a linearly-polarized light output with the maximum extinction ratio of ~12 dB. The output polarization direction could be fully controlled by the ACNT alignment direction in both lasers. To the best of our knowledge, this is the first time that ACNT device is applied to polarization control in laser systems. Our results exhibit that the ACNT device is a simple, low-cost, and broadband polarizer to control laser polarization dynamics, for various photonic applications (such as ...

  16. Estimating Carbon Supply Curves for Global Forests and Other Land Uses April 2001, Discussion Paper 01-19

    SciTech Connect (OSTI)

    Sedjo, Roger; Sohngen, Brent; Mendelsohn, Robert

    2001-04-05

    This study develops cumulative carbon ''supply curves'' for global forests utilizing a dynamic timber supply model for sequestration of forest carbon. Because the period of concern is the next century, and particular time points within that century, the curves are not traditional Marshallian supply curves or steady-state supply curves. Rather, the focus is on cumulative carbon cost curves (quasi-supply curves) at various points in time over the next 100 years. The research estimates a number of long-term, cumulative, carbon quasi-supply curves under different price scenarios and for different time periods. The curves trace out the relationship between an intertemporal price path for carbon, as given by carbon shadow prices, and the cumulative carbon sequestered from the initiation of the shadow prices, set at 2000, to a selected future year (2010, 2050, 2100). The timber supply model demonstrates that cumulative carbon quasi-supply curves that can be generated through forestry significantly depend on initial carbon prices and expectations regarding the time profile of future carbon prices. Furthermore, long-run quasi-supply curves generated from a constant price will have somewhat different characteristics from quasi-supply curves generated with an expectation of rising carbon prices through time.The ?least-cost? curves vary the time periods under consideration and the time profile of carbon prices. The quasi-supply curves suggest that a policy of gradually increasing carbon prices will generate the least costly supply curves in the shorter periods of a decade or so. Over longer periods of time, however, such as 50 or 100 years, these advantages appear to dissipate.

  17. Carbonic Acid Pretreatment of Biomass

    SciTech Connect (OSTI)

    G. Peter van Walsum; Kemantha Jayawardhana; Damon Yourchisin; Robert McWilliams; Vanessa Castleberry

    2003-05-31

    This project sought to address six objectives, outlined below. The objectives were met through the completion of ten tasks. 1) Solidify the theoretical understanding of the binary CO2/H2O system at reaction temperatures and pressures. The thermodynamics of pH prediction have been improved to include a more rigorous treatment of non-ideal gas phases. However it was found that experimental attempts to confirm theoretical pH predictions were still off by a factor of about 1.8 pH units. Arrhenius experiments were carried out and the activation energy for carbonic acid appears to be substantially similar to sulfuric acid. Titration experiments have not yet confirmed or quantified the buffering or acid suppression effects of carbonic acid on biomass. 2) Modify the carbonic acid pretreatment severity function to include the effect of endogenous acid formation and carbonate buffering, if necessary. It was found that the existing severity functions serve adequately to account for endogenous acid production and carbonate effects. 3) Quantify the production of soluble carbohydrates at different reaction conditions and severity. Results show that carbonic acid has little effect on increasing soluble carbohydrate concentrations for pretreated aspen wood, compared to pretreatment with water alone. This appears to be connected to the release of endogenous acids by the substrate. A less acidic substrate such as corn stover would derive benefit from the use of carbonic acid. 4) Quantify the production of microbial inhibitors at selected reaction conditions and severity. It was found that the release of inhibitors was correlated to reaction severity and that carbonic acid did not appear to increase or decrease inhibition compared to pretreatment with water alone. 5) Assess the reactivity to enzymatic hydrolysis of material pretreated at selected reaction conditions and severity. Enzymatic hydrolysis rates increased with severity, but no advantage was detected for the use of carbonic acid compared to water alone. 6) Determine optimal conditions for carbonic acid pretreatment of aspen wood. Optimal severities appeared to be in the mid range tested. ASPEN-Plus modeling and economic analysis of the process indicate that the process could be cost competitive with sulfuric acid if the concentration of solids in the pretreatment is maintained very high (~50%). Lower solids concentrations result in larger reactors that become expensive to construct for high pressure applications.

  18. Extraneous Carbon Assessments in Radiocarbon Measurements of Black Carbon in Environmental Matrices

    E-Print Network [OSTI]

    Coppola, Alysha; Ziolkowski, L. A.; Druffel, E. R. M.

    2013-01-01

    rived (black/elemental) carbon in soils and sediments usingbon measurements of black carbon in aerosols and oceanMWI, Noack AG. 2000. Black carbon in soils and sediments:

  19. CARBON ISOTOPE STRATIGRAPHY AND DIAGENESIS OF PENNSYLVANIAN (DESMOINESIAN-MISSOURIAN) CARBONATES IN EAST-CENTRAL IDAHO 

    E-Print Network [OSTI]

    Wood, Stephanie

    2011-05-10

    Carbon isotope stratigraphy of carbonate sediments is instrumental in examining major perturbations in the global carbon cycle and in correlating strata. However, the primary isotopic signal recorded in these sediments can vary with depositional...

  20. Transactions Dynamic Article Links

    E-Print Network [OSTI]

    Boyer, Edmond

    the reversible hydration of carbon dioxide. CO2 + H2O HCO3 - + H+ (1) CAs are ubiquitous throughout nature of a metal-bound hydroxide, the catalytic species which nucleophilically attacks the incoming carbon dioxide.rsc.org/dalton COMMUNICATION Comparison between a- and b-carbonic anhydrases: can Zn(His)3(H2O) and Zn(His)(Cys)2(H2O) sites

  1. Carbon tax or carbon permits: The impact on generators' risks

    SciTech Connect (OSTI)

    Green, R.

    2008-07-01

    Volatile fuel prices affect both the cost and price of electricity in a liberalized market. Generators with the price-setting technology will face less risk to their profit margins than those with costs that are not correlated with price, even if those costs are not volatile. Emissions permit prices may respond to relative fuel prices, further increasing volatility. This paper simulates the impact of this on generators' profits, comparing an emissions trading scheme and a carbon tax against predictions for the UK in 2020. The carbon tax reduces the volatility faced by nuclear generators, but raises that faced by fossil fuel stations. Optimal portfolios would contain a higher proportion of nuclear plant if a carbon tax was adopted.

  2. Novel method for carbon nanofilament growth on carbon fibers

    SciTech Connect (OSTI)

    Phillips, Johathan; Luhrs, Claudia; Terani, Mehran; Al - Haik, Marwan; Garcia, Daniel; Taha, Mahmoud R

    2009-01-01

    Fiber reinforced structural composites such as fiber reinforced polymers (FRPs) have proven to be key materials for blast mitigation due to their enhanced mechanical performance. However, there is a need to further increase total energy absorption of the composites in order to retain structural integrity in high energy environments, for example, blast events. Research has shown that composite failure in high energy environments can be traced to their relatively low shear strength attributed to the limited bond strength between the matrix and the fibers. One area of focus for improving the strength of composite materials has been to create 'multi-scale' composites. The most common approach to date is to introduce carbon nanotubes into a more traditional composite consisting of epoxy with embedded micron scale fibers. The inclusion of carbon nanotubes (CNT) clearly toughens different matrices. Depositing CNT in brittle matrix increases stiffness by orders of magnitude. Currently, this approach to create multiscale composites is limited due to the difficulty of dispersing significant amounts of nanotubes. It has repeatedly been reported that phase separation occurs above relatively low weight percent loading (ca. 3%) due to the strong van der Waals forces between CNTs compared with that between CNT and polymer. Hence, the nanotubes tend to segregate and form inclusions. One means to prevent nanotube or nanofilament agglomeration is to anchor one end of the nanostructure, thereby creating a stable multi-phase structure. This is most easily done by literally growing the CNTs directly on micron scale fibers. Recently, CNT were grown on carbon fibers, both polyacrylonitrile- (PAN-) and pitch-based, by hot filament chemical vapor deposition (HFCVD) using H2 and CH4 as precursors. Nickel clusters were electrodeposited on the fiber surfaces to catalyze the growth and uniform CNT coatings were obtained on both the PAN- and pitch-based carbon fibers. Multiwalled CNTs with smooth walls and low impurity content were grown. Carbon nanofibers were also grown on a carbon fiber cloth using plasma enhanced chemical vapor deposition (CVD) from a mixture of acetylene and ammonia. In this case, a cobalt colloid was used to achieve a good coverage of nanofibers on carbon fibers in the cloth. Caveats to CNT growth include damage in the carbon fiber surface due to high-temperatures (>800 C). More recently, Qu et al. reported a new method for uniform deposition of CNT on carbon fibers. However, this method requires processing at 1100 C in the presence of oxygen and such high temperature is anticipated to deepen the damage in the carbon fibers. In the present work, multi-scale filaments (herein, linear carbon structures with multi-micron diameter are called 'fibers', all structures with sub-micron diameter are called 'filaments') were created with a low temperature (ca. 550 C) alternative to CVD growth of CNTs. Specifically, nano-scale filaments were rapidly generated (> 10 microns/hour) on commercial micron scale fibers via catalytic (Pd particles) growth from a fuel rich combustion environment at atmospheric pressure. This atmospheric pressure process, derived from the process called Graphitic Growth by Design (GSD), is rapid, the maximum temperature low enough (below 700 C) to avoid structural damage and the process inexpensive and readily scalable. In some cases, a significant and unexpected aspect of the process was the generation of 'three scale' materials. That is, materials with these three size characteristics were produced: (1) micrometer scale commercial PAN fibers, (2) a layer of 'long' sub-micrometer diameter scale carbon filaments, and (3) a dense layer of 'short' nanometer diameter filaments.

  3. Carbon fiber manufacturing via plasma technology

    DOE Patents [OSTI]

    Paulauskas, Felix L. (Knoxville, TN); Yarborough, Kenneth D. (Oak Ridge, TN); Meek, Thomas T. (Knoxville, TN)

    2002-01-01

    The disclosed invention introduces a novel method of manufacturing carbon and/or graphite fibers that avoids the high costs associated with conventional carbonization processes. The method of the present invention avoids these costs by utilizing plasma technology in connection with electromagnetic radiation to produce carbon and/or graphite fibers from fully or partially stabilized carbon fiber precursors. In general, the stabilized or partially stabilized carbon fiber precursors are placed under slight tension, in an oxygen-free atmosphere, and carbonized using a plasma and electromagnetic radiation having a power input which is increased as the fibers become more carbonized and progress towards a final carbon or graphite product. In an additional step, the final carbon or graphite product may be surface treated with an oxygen-plasma treatment to enhance adhesion to matrix materials.

  4. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1997-10-14

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (1) an x-ray density of at least 2.00 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 47%; and (b) graphite having the following properties: (1) an x-ray density of at least 2.20 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counter electrode. 10 figs.

  5. Ultra low friction carbon/carbon composites for extreme temperature applications

    DOE Patents [OSTI]

    Erdemir, Ali (Naperville, IL); Busch, Donald E. (Hinsdale, IL); Fenske, George R. (Downers Grove, IL); Lee, Sam (Gardena, CA); Shepherd, Gary (Los Alamitos, CA); Pruett, Gary J. (Cypress, CA)

    2001-01-01

    A carbon/carbon composite in which a carbon matrix containing a controlled amount of boron or a boron compound is reinforced with carbon fiber exhibits a low coefficient of friction, i.e., on the order of 0.04 to 0.1 at temperatures up to 600.degree. C., which is one of the lowest frictional coefficients for any type of carbonaceous material, including graphite, glassy carbon, diamond, diamond-like carbon and other forms of carbon material. The high degree of slipperiness of the carbon composite renders it particularly adapted for limiting friction and wear at elevated temperatures such as in seals, bearings, shafts, and flexible joints

  6. Blue carbon storage potential of marine carbonate deposits Project reference IAP/13/50. Please quote this reference when applying.

    E-Print Network [OSTI]

    Guo, Zaoyang

    IAPETUS Blue carbon storage potential of marine carbonate deposits Project reference IAP/13 Henrik Stahl, Scottish Association for Marine Science Key Words 1. Blue carbon 2. Carbonate 3. Coralline is referred to as `blue carbon' to differentiate it from terrestrial carbon stores. Known blue carbon sinks

  7. The reduction of carbon-carbon multiple bond systems 

    E-Print Network [OSTI]

    Ferguson, Donald Roy

    1965-01-01

    to the ability to the phenyl groups to disperse a charge on the benzylic carbon. In ether, an aprotic solvent, lithium reacts with diphenylacetylene 6 to form the lithium derivative of a substituted naphthelene. C6H5-CmC-C6H + Li m ~IC H ~C4Ha CaHs Cexs (12...) Hater or ethyl alcohol reacts with the lithium derivative to form 1, 2, 3-triphenylnaphthelene while reaction of the lithium derivative with carbon dioxide yields the corresponding salt of a 1-naphthoic acid. C4HS H + LiOH (13) Cd Hr C@H5 C@H5...

  8. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01

    Carbon sequestration and greenhouse gas emissions in urbanCarbon sequestration and greenhouse gas emissions in urbanCarbon sequestration and greenhouse gas emissions in urban

  9. City carbon budgets: Aligning incentives for climate-friendly communities

    E-Print Network [OSTI]

    Salon, Deborah; Sperling, Dan; Meier, Alan; Murphy, Sinnott; Gorham, Roger; Barrett, James

    2008-01-01

    2008. Shrinking the carbon footprint of metropolitantheir per capita carbon footprint by a predetermined percentor of lower carbon footprint (embodied emissions) building

  10. Carbon and Water Resource Management for Water Distribution Systems

    E-Print Network [OSTI]

    Hendrickson, Thomas Peter

    2013-01-01

    Buckley, C. A. ; Carbon footprint analysis for increasingeffectively reduce their carbon footprint. To accomplish7 February 2013. (8) The Carbon Footprint of Water; River

  11. Beryllium-7 labeled carbon particles and method of making

    DOE Patents [OSTI]

    Richards, P.; Mausner, L.F.; Prach, T.F.

    1985-04-29

    Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

  12. Perspectives on Carbon Capture and Sequestration in the United States

    E-Print Network [OSTI]

    Wong-Parodi, Gabrielle

    2011-01-01

    2006 Carbon sequestration: regional partnerships Accessed onCoast Carbon Sequestration Regional Partnership with supportCoast Regional Carbon Sequestration Partnership 2008 Public

  13. A LASER-BASED MONODISPERSE CARBON FIBER GENERATOR

    E-Print Network [OSTI]

    Loo, Billy W.

    2013-01-01

    BASED MONODISPERSE CARBON FIBER GENERATOR Billy W. Loo,BASED MONODISPERSE CARBON FIBER GENERATOR Billy W. Loo,BASED MONODISPERSE CARBON FIBER GENERATOR Billy W. Loo,

  14. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01

    Damage Costs of Carbon Dioxide Emissions: An Assessment ofper Megawatt Hrs) Carbon Dioxide Emissions Cost ($ per Year)Megawatt Hrs) Carbon Dioxide Emissions Cost MSA Emissions

  15. Autonomous observations of the ocean biological carbon pump

    E-Print Network [OSTI]

    Bishop, James K.B.

    2009-01-01

    efficiency of biological pump in the global ocean. JournalOcean Biological Carbon Pump Carbon Flux Explorerocean’s “biological carbon pump” (Broecker and Peng, 1982;

  16. Optically Functional Nanomaterials: Optothermally Responsive Composites and Carbon Nanotube Photovoltaics

    E-Print Network [OSTI]

    Okawa, David

    2010-01-01

    and Carbon Nanotube Photovoltaics by David Christopher OkawaPart II: Carbon Nanotube Photovoltaics Chapter 6:Carbon Nanotube – Polymer Photovoltaics 6.1 Polymer-Nanotube

  17. EFRC Carbon Capture and Sequestration Activities at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EFRC Carbon Capture and Sequestration Activities at NERSC EFRC Carbon Capture and Sequestration Activities at NERSC Why it Matters: Carbon dioxide (CO2) gas is considered to be...

  18. Tennessee: Oak Ridge National Laboratory Optimizes Carbon Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tennessee: Oak Ridge National Laboratory Optimizes Carbon Fiber Production, Reduces Carbon Fiber Costs by 30% Tennessee: Oak Ridge National Laboratory Optimizes Carbon Fiber...

  19. CVD Growth of Carbon Nanotubes Directly on Nickel Substrate

    E-Print Network [OSTI]

    Du, Chunsheng; Pan, Ning

    2005-01-01

    growth, carbon nanotubes, nickel substrates 1. Introductionto directly grow carbon nanotubes on nickel substrate underof the carbon nanotubes The nickel substrates were directly

  20. Mesoporous Carbon-based Materials for Alternative Energy Applications

    E-Print Network [OSTI]

    Cross, Kimberly Michelle

    2012-01-01

    Carbon-Silica Composite Aerogels." Nano Letters 2(3): 235.metal-carbonized aerogel composites as electrocatalysts forcarbons (Joo, 2001), carbon aerogels (Anderson, 2002; Ye,