National Library of Energy BETA

Sample records for test isotope geothermometry

  1. Geothermometry At Nevada Test And Training Range Area (Sabin...

    Open Energy Info (EERE)

    Geothermometry At Nevada Test And Training Range Area (Sabin, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At...

  2. Multicomponent Equilibrium Models for Testing Geothermometry Approaches

    SciTech Connect (OSTI)

    Cooper, D. Craig; Carl D. Palmer; Robert W. Smith; Travis L. McLing

    2013-02-01

    Geothermometry is an important tool for estimating deep reservoir temperature from the geochemical composition of shallower and cooler waters. The underlying assumption of geothermometry is that the waters collected from shallow wells and seeps maintain a chemical signature that reflects equilibrium in the deeper reservoir. Many of the geothermometers used in practice are based on correlation between water temperatures and composition or using thermodynamic calculations based a subset (typically silica, cations or cation ratios) of the dissolved constituents. An alternative approach is to use complete water compositions and equilibrium geochemical modeling to calculate the degree of disequilibrium (saturation index) for large number of potential reservoir minerals as a function of temperature. We have constructed several “forward” geochemical models using The Geochemist’s Workbench to simulate the change in chemical composition of reservoir fluids as they migrate toward the surface. These models explicitly account for the formation (mass and composition) of a steam phase and equilibrium partitioning of volatile components (e.g., CO2, H2S, and H2) into the steam as a result of pressure decreases associated with upward fluid migration from depth. We use the synthetic data generated from these simulations to determine the advantages and limitations of various geothermometry and optimization approaches for estimating the likely conditions (e.g., temperature, pCO2) to which the water was exposed in the deep subsurface. We demonstrate the magnitude of errors that can result from boiling, loss of volatiles, and analytical error from sampling and instrumental analysis. The estimated reservoir temperatures for these scenarios are also compared to conventional geothermometers. These results can help improve estimation of geothermal resource temperature during exploration and early development.

  3. Improved Geothermometry Through Multivariate Reaction Path Modeling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators Improved Geothermometry...

  4. Isotope Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam:on OpeneiAlbanianStudy)savings time. | OpenEIOpen

  5. Mineral Selection for Multicomponent Equilibrium Geothermometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plamer, C. D.; Ohly, S. R.; Smith, R. W.; Neupane, G.; McLing, T.; Mattson, E.

    2015-04-01

    Muliticomponent geothermometry requires knowledge of the mineral phases in the reservoir with which the geothermal fluids may be equilibrated.

  6. Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher...

    Open Energy Info (EERE)

    Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Nw...

  7. Geothermometry At Central Nevada Seismic Zone Region (Shevenell...

    Open Energy Info (EERE)

    Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry...

  8. Corrosion testing using isotopes

    DOE Patents [OSTI]

    Hohorst, F.A.

    1995-12-05

    A method is described for determining the corrosion behavior of a material with respect to a medium in contact with the material by: implanting a substantially chemically inert gas in a matrix so that corrosion experienced by the material causes the inert gas to enter the medium; placing the medium in contact with the material; and measuring the amount of inert gas which enters the medium. A test sample of a material whose resistance to corrosion by a medium is to be tested is described composed of: a body of the material, which body has a surface to be contacted by the medium; and a substantially chemically inert gas implanted into the body to a depth below the surface. A test sample of a material whose resistance to corrosion by a medium is to be tested is described composed of: a substrate of material which is easily corroded by the medium, the substrate having a surface; a substantially chemically inert gas implanted into the substrate; and a sheet of the material whose resistance to corrosion is to be tested, the sheet being disposed against the surface of the substrate and having a defined thickness. 3 figs.

  9. Microbial impacts on geothermometry temperature predictions

    SciTech Connect (OSTI)

    Yoshiko Fujita; David W. Reed; Kaitlyn R. Nowak; Vicki S. Thompson; Travis L. McLing; Robert W. Smith

    2013-02-01

    Conventional geothermometry approaches assume that the composition of a collected water sample originating in a deep geothermal reservoir still reflects chemical equilibration of the water with the deep reservoir rocks. However, for geothermal prospecting samples whose temperatures have dropped to <120°C, temperature predictions may be skewed by the activity of microorganisms; microbial metabolism can drastically and rapidly change the water’s chemistry. We hypothesize that knowledge of microbial impacts on exploration sample geochemistry can be used to constrain input into geothermometry models and thereby improve the reliability of reservoir temperature predictions. To evaluate this hypothesis we have chosen to focus on sulfur cycling, because of the significant changes in redox state and pH associated with sulfur chemistry. Redox and pH are critical factors in defining the mineral-fluid equilibria that form the basis of solute geothermometry approaches. Initially we are developing assays to detect the process of sulfate reduction, using knowledge of genes specific to sulfate reducing microorganisms. The assays rely on a common molecular biological technique known as quantitative polymerase chain reaction (qPCR), which allows estimation of the number of target organisms in a particular sample by enumerating genes specific to the organisms rather than actually retrieving and characterizing the organisms themselves. For quantitation of sulfate reducing genes using qPCR, we constructed a plasmid (a piece of DNA) containing portions of two genes (known as dsrA and dsrB) that are directly involved with sulfate reduction and unique to sulfate reducing microorganisms. Using the plasmid as well as DNA from other microorganisms known to be sulfate reducers or non-sulfate reducers, we developed qPCR protocols and showed the assay’s specificity to sulfate reducers and that a qPCR standard curve using the plasmid was linear over >5 orders of magnitude. As a first test with actual field samples, the assay was applied to DNA extracted from water collected at springs located in and around the town of Soda Springs, Idaho. Soda Springs is located in the fold and thrust belt on the eastern boundary of the track of the Yellowstone Hotspot, where a deep carbon dioxide source believed to originate from Mississippian limestone contacts acidic hydrothermal fluids at depth. Both sulfate and sulfide have been measured in samples collected previously at Soda Springs. Preliminary results indicate that sulfate reducing genes were present in each of the samples tested. Our work supports evaluation of the potential for microbial processes to have altered water chemistry in geothermal exploration samples.

  10. Category:Isotope Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to: navigation,Ground Gravity Survey JumpInjectivity

  11. Strontium Isotopes Test Long-Term Zonal Isolation of Injected...

    Office of Scientific and Technical Information (OSTI)

    Strontium Isotopes Test Long-Term Zonal Isolation of Injected and Marcellus Formation Water after Hydraulic Fracturing Citation Details In-Document Search Title: Strontium Isotopes...

  12. Geothermometry At Walker-Lane Transitional Zone Region (Shevenell...

    Open Energy Info (EERE)

    De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Walker-Lane Transitional Zone Region (Shevenell & De Rocher,...

  13. Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl...

    Open Energy Info (EERE)

    Et Al., 1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl, Et Al., 1976)...

  14. Geothermometry At Long Valley Caldera Geothermal Area (Mariner...

    Open Energy Info (EERE)

    Mariner & Willey, 1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Long Valley Caldera Geothermal Area (Mariner & Willey,...

  15. Category:Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to: navigation, searchGeophysicalCategoryGeothermometry

  16. New Mexico conservative ion water chemistry data and chalcedony geothermometry

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shari Kelley

    2015-10-21

    Compilation of boron, lithium, bromine, and silica data from wells and springs throughout New Mexico from a wide variety of sources. The chalcedony geothermometry calculation is included in this file.

  17. Mineral Selection for Multicomponent Equilibrium Geothermometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plamer, C. D.; Ohly, S. R.; Smith, R. W.; Neupane, G.; McLing, T.; Mattson, E.

    2015-04-01

    Multicomponent geothermometry requires knowledge of the mineral phases in the reservoir with which the geothermal fluids may be equilibrated. These minerals phases are most often alteration products rather than primary minerals. We have reviewed the literature on geothermal systems representing most major geologic environments typically associated with geothermal activity and identified potential alteration products in various environments. We have included this information in RTEst, a code we have developed to estimate reservoir conditions (temperature, CO2 fugacity) from the geochemistry of near-surface geothermal waters. The information has been included in RTEst through the addition of filters that decrease the potential numbermore »of minerals from all possibilities based on the basis species to those that are more relevant to the particular conditions in which the user is interested. The three groups of filters include host rock type (tholeiitic, calc-alkaline, silicic, siliciclastic, carbonate), water type (acidic, neutral), and the temperature range over which the alteration minerals were formed (low, medium, high). The user-chosen mineral assemblage is checked to make sure that it does not violate the Gibbs phase rule. The user can select one of three mineral saturation weighting schemes that decrease the chance the optimization from being skewed by reaction stoichiometry or analytical uncertainty.« less

  18. METHOD TO TEST ISOTOPIC SEPARATION EFFICIENCY OF PALLADIUM PACKED COLUMNS

    SciTech Connect (OSTI)

    Heung, L; Gregory Staack, G; James Klein, J; William Jacobs, W

    2007-06-27

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam use, were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages using the test results. The effects of column diameter, metal foam and gas flow rate were identified.

  19. Tests of isotopic separation efficiency of palladium packed columns

    SciTech Connect (OSTI)

    Heung, L. K.; Staack, G. C.; Klein, J. E.; Jacobs, W. D.

    2008-07-15

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam presence were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages based on the test results. The effects of column diameter, metal foam presence and gas flow rate were identified. (authors)

  20. Isotope Geothermometry At Lightning Dock Geothermal Area (Witcher, 2006) |

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder at 8, 13RenewableIrem GeothermalIslip Terrace,Open Energy

  1. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Physics Isotopes Isotopes Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Get Expertise...

  2. Consistency test of neutrinoless double beta decay with one isotope

    E-Print Network [OSTI]

    Michael Duerr; Manfred Lindner; Kai Zuber

    2011-11-17

    We discuss a consistency test which makes it possible to discriminate unknown nuclear background lines from neutrinoless double beta decay with only one isotope. By considering both the transition to the ground state and to the first excited $0^+$ state, a sufficiently large detector can reveal if neutrinoless double beta decay or some other nuclear physics process is at work. Such a detector could therefore simultaneously provide a consistency test for a certain range of Majorana masses and be sensitive to lower values of the effective Majorana mass.

  3. Consistency test of neutrinoless double beta decay with one isotope

    SciTech Connect (OSTI)

    Duerr, Michael; Lindner, Manfred [Max-Planck-Institut fuer Kernphysik, Postfach 10 39 80, 69029 Heidelberg (Germany); Zuber, Kai [Technical University Dresden, Institut fuer Kern- und Teilchenphysik, 01069 Dresden (Germany)

    2011-11-01

    We discuss a consistency test which makes it possible to discriminate unknown nuclear background lines from neutrinoless double beta decay with only one isotope. By considering both the transition to the ground state and to the first excited 0{sup +} state, a sufficiently large detector can reveal if neutrinoless double beta decay or some other nuclear physics process is at work. Such a detector could therefore simultaneously provide a consistency test for a certain range of Majorana masses and be sensitive to lower values of the effective Majorana mass .

  4. Category:Liquid Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to: navigation,Ground Gravity SurveyIsotopicLabLiquid

  5. Standard test method for uranium and plutonium concentrations and isotopic abundances by thermal ionization mass spectrometry

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2005-01-01

    1.1 This test method covers the determination of the concentration and isotopic composition of uranium and plutonium in solutions. The purified uranium or plutonium from samples ranging from nuclear materials to environmental or bioassay matrices is loaded onto a mass spectrometric filament. The isotopic ratio is determined by thermal ionization mass spectrometry, the concentration is determined by isotope dilution. 1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish safety and health practices and determine the applicability of regulatory limitations prior to use.

  6. Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers

    E-Print Network [OSTI]

    Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers November 2006; published 4 May 2007. [1] Understanding factors that control methane exchange between soils-scale variations in soil methane emissions: (1) consumption of methane by methanotrophic bacteria, (2) quantity

  7. Geochemistry Sampling for Traditional and Multicomponent Equilibrium Geothermometry in Southeast Idaho

    SciTech Connect (OSTI)

    Cannon, Cody; Wood, Thomas; Neupane, Ghanashyam; McLing, Travis; Mattson, Earl; Dobson, Patrick; Conrad, Mark

    2014-10-01

    The Eastern Snake River Plain (ESRP) is an area of high regional heat flux due the movement of the North American Plate over the Yellowstone Hotspot beginning ca.16 Ma. Temperature gradients between 45-60 °C/km (up to double the global average) have been calculated from deep wells that penetrate the upper aquifer system (Blackwell 1989). Despite the high geothermal potential, thermal signatures from hot springs and wells are effectively masked by the rapid flow of cold groundwater through the highly permeable basalts of the Eastern Snake River Plain aquifer (ESRPA) (up to 500+ m thick). This preliminary study is part of an effort to more accurately predict temperatures of the ESRP deep thermal reservoir while accounting for the effects of the prolific cold water aquifer system above. This study combines the use of traditional geothermometry, mixing models, and a multicomponent equilibrium geothermometry (MEG) tool to investigate the geothermal potential of the ESRP. In March, 2014, a collaborative team including members of the University of Idaho, the Idaho National Laboratory, and the Lawrence Berkeley National Laboratory collected 14 thermal water samples from and adjacent to the Eastern Snake River Plain. The preliminary results of chemical analyses and geothermometry applied to these samples are presented herein.

  8. Stable isotopic study of precipitation and spring discharge on the Nevada Test Site

    SciTech Connect (OSTI)

    Ingraham, N.L.; Jacobson, R.L.; Hess, J.W.; Lyles, B.F. . Water Resources Center Nevada Univ., Reno, NV . Water Resources Center)

    1990-07-01

    Precipitation was collected in southern Nevada (on the Nevada Test Site) on a semi-regular monthly basis at 41 locations for six years for stable isotopic analysis. The precipitation record shows two time-based regimes. For the first three years of collection, the precipitation was highly variable with several large events and several dry periods. During the last three years of collection, the precipitation was much more even with no large events. However, there is no correlation between the variability in the amount of precipitation and the stable isotopic composition of precipitation. In addition, the oxygen isotope composition and discharge of two springs, Whiterock Spring and Cane Spring, issuing from perched water tables, were monitored for five years in a similar time frame as for the precipitation. 17 refs., 42 figs., 3 tabs.

  9. An experimental investigation into the effects of fluid composition on certain geothermometry methods 

    E-Print Network [OSTI]

    Pope, Leslie Anne

    1985-01-01

    to the surface and the rock type through which it flows, 4) the geothermal gradient, 6) the flow rate to the surface, 6) steam loss, 7) mixing with other thermal waters, and 8 ) dilution by non-thermal waters . In the geothermometry methods discussed... to be called the quartz geothermometer. The equation for the quartz geothermometer is based on the dissolution reaction of pure quartz as shown by the following reaction: 2 (qtz) 2 (aq) For pure quartz, the activity is equal to one, and the equilibrium...

  10. Test results of a new detector system for gamma ray isotopic measurements

    SciTech Connect (OSTI)

    Malcom, J.E.; Bonner, C.A.; Hurd, J.R.; Fleissner,

    1993-08-01

    A new type of gamma-ray detector system for isotopic measurements has been developed. This new system, a ``Duo detector`` array, consists of two intrinsic germanium detectors, a planar followed by a coaxial mounted on the same axis within a single cryostat assembly. This configuration allows the isotopic analysis system to take advantage of spectral data results that are collected simultaneously from different gamma-ray energy regimes. Princeton Gamma Tech (PGT) produced several prototypes of this Duo detector array which were then tested by Rocky Flats personnel until the design was optimized. An application for this detector design is in automated, roboticized NDA systems such as those being developed at the Los Alamos TA-55 Plutonium Facility. The Duo detector design reduces the space necessary for the isotopic instrument by a factor of two (only one liquid nitrogen dewar is needed), and also reduces the complexity of the mechanical systems and controlling software. Data will be presented on measurements of nuclear material with a Duo detector for a wide variety of matrices. Results indicate that the maximum count rate can be increased up to 100,000 counts per second yet maintaining excellent resolution and energy rate product.

  11. Geothermometry At Long Valley Caldera Geothermal Area (Farrar...

    Open Energy Info (EERE)

    stages of hydrothermal activity, flow, and recharge in the Long Valley caldera groundwater system. Fluids were sampled from LVEW during flow testing in May 2000, July 2000,...

  12. Standard test method for isotopic abundance analysis of uranium hexa?uoride and uranyl nitrate solutions by multi-collector, inductively coupled plasma-mass spectrometry

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    Standard test method for isotopic abundance analysis of uranium hexa?uoride and uranyl nitrate solutions by multi-collector, inductively coupled plasma-mass spectrometry

  13. Fuel and core testing plan for a target fueled isotope production reactor.

    SciTech Connect (OSTI)

    Coats, Richard Lee; Dahl, James J.; Parma, Edward J., Jr.

    2010-12-01

    In recent years there has been an unstable supply of the critical diagnostic medical isotope 99Tc. Several concepts and designs have been proposed to produce 99Mo the parent nuclide of 99Tc, at a commercial scale sufficient to stabilize the world supply. This work lays out a testing and experiment plan for a proposed 2 MW open pool reactor fueled by Low Enriched Uranium (LEU) 99Mo targets. The experiments and tests necessary to support licensing of the reactor design are described and how these experiments and tests will help establish the safe operating envelop for a medical isotope production reactor is discussed. The experiments and tests will facilitate a focused and efficient licensing process in order to bring on line a needed production reactor dedicated to supplying medical isotopes. The Target Fuel Isotope Reactor (TFIR) design calls for an active core region that is approximately 40 cm in diameter and 40 cm in fuel height. It contains up to 150 cylindrical, 1-cm diameter, LEU oxide fuel pins clad with Zircaloy (zirconium alloy), in an annular hexagonal array on a {approx}2.0 cm pitch surrounded, radially, by a graphite or a Be reflector. The reactor is similar to U.S. university reactors in power, hardware, and safety/control systems. Fuel/target pin fabrication is based on existing light water reactor fuel fabrication processes. However, as part of licensing process, experiments must be conducted to confirm analytical predictions of steady-state power and accident conditions. The experiment and test plan will be conducted in phases and will utilize existing facilities at the U.S. Department of Energy's Sandia National Laboratories. The first phase is to validate the predicted reactor core neutronics at delayed critical, zero power and very low power. This will be accomplished by using the Sandia Critical Experiment (CX) platform. A full scale TFIR core will be built in the CX and delayed critical measurements will be taken. For low power experiments, fuel pins can be removed after the experiment and using Sandia's metrology lab, relative power profiles (radially and axially) can be determined. In addition to validating neutronic analyses, confirming heat transfer properties of the target/fuel pins and core will be conducted. Fuel/target pin power limits can be verified with out-of-pile (electrical heating) thermal-hydraulic experiments. This will yield data on the heat flux across the Zircaloy clad and establish safety margin and operating limits. Using Sandia's Annular Core Research Reactor (ACRR) a 4 MW TRIGA type research reactor, target/fuel pins can be driven to desired fission power levels for long durations. Post experiment inspection of the pins can be conducted in the Auxiliary Hot Cell Facility to observe changes in the mechanical properties of the LEU matrix and burn-up effects. Transient tests can also be conducted at the ACRR to observe target/fuel pin performance during accident conditions. Target/fuel pins will be placed in double experiment containment and driven by pulsing the ACRR until target/fuel failure is observed. This will allow for extrapolation of analytical work to confirm safety margins.

  14. Geothermal Reservoir Temperatures in Southeastern Idaho using Multicomponent Geothermometry

    SciTech Connect (OSTI)

    Neupane, Ghanashyam; Mattson, Earl D.; McLing, Travis L.; Palmer, Carl D.; Smith, Robert W.; Wood, Thomas R.; Podgorney, Robert K.

    2015-03-01

    Southeastern Idaho exhibits numerous warm springs, warm water from shallow wells, and hot water within oil and gas test wells that indicate a potential for geothermal development in the area. Although the area exhibits several thermal expressions, the measured geothermal gradients vary substantially (19 – 61 ºC/km) within this area, potentially suggesting a redistribution of heat in the overlying ground water from deeper geothermal reservoirs. We have estimated reservoir temperatures from measured water compositions using an inverse modeling technique (Reservoir Temperature Estimator, RTEst) that calculates the temperature at which multiple minerals are simultaneously at equilibrium while explicitly accounting for the possible loss of volatile constituents (e.g., CO2), boiling and/or water mixing. Compositions of a selected group of thermal waters representing southeastern Idaho hot/warm springs and wells were used for the development of temperature estimates. The temperature estimates in the the region varied from moderately warm (59 ºC) to over 175 ºC. Specifically, hot springs near Preston, Idaho resulted in the highest temperature estimates in the region.

  15. Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

  16. Measurement of (alpha,n) reaction cross sections of erbium isotopes for testing astrophysical rate predictions

    E-Print Network [OSTI]

    G. G Kiss; T. Szücs; T. Rauscher; Zs Török; L. Csedreki; Zs Fülöp; Gy Gyürky; Z. Halász

    2015-03-06

    The $\\gamma$-process in core-collapse and/or type Ia supernova explosions is thought to explain the origin of the majority of the so-called $p$ nuclei (the 35 proton-rich isotopes between Se and Hg). Reaction rates for $\\gamma$-process reaction network studies have to be predicted using Hauser-Feshbach statistical model calculations. Recent investigations have shown problems in the prediction of $\\alpha$-widths at astrophysical energies which are an essential input for the statistical model. It has an impact on the reliability of abundance predictions in the upper mass range of the $p$ nuclei. With the measurement of the $^{164,166}$Er($\\alpha$,n)$^{167,169}$Yb reaction cross sections at energies close to the astrophysically relevant energy range we tested the recently suggested low energy modification of the $\\alpha$+nucleus optical potential in a mass region where $\\gamma$-process calculations exhibit an underproduction of the $p$ nuclei. Using the same optical potential for the $\\alpha$-width which was derived from combined $^{162}$Er($\\alpha$,n) and $^{162}$Er($\\alpha$,$\\gamma$) measurement makes it plausible that a low-energy modification of the optical $\\alpha$+nucleus potential is needed.

  17. Standard Test Method for Isotopic Analysis of Uranium Hexafluoride by Single-Standard Gas Source Multiple Collector Mass Spectrometer Method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2011-01-01

    1.1 This test method is applicable to the isotopic analysis of uranium hexafluoride (UF6) with 235U concentrations less than or equal to 5 % and 234U, 236U concentrations of 0.0002 to 0.1 %. 1.2 This test method may be applicable to the analysis of the entire range of 235U isotopic compositions providing that adequate Certified Reference Materials (CRMs or traceable standards) are available. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety health practices and determine the applicability of regulatory limitations prior to use.

  18. Standard test method for isotopic analysis of hydrolyzed uranium hexafluoride and uranyl nitrate solutions by thermal ionization mass spectrometry

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2005-01-01

    1.1 This method applies to the determination of isotopic composition in hydrolyzed nuclear grade uranium hexafluoride. It covers isotopic abundance of 235U between 0.1 and 5.0 % mass fraction, abundance of 234U between 0.0055 and 0.05 % mass fraction, and abundance of 236U between 0.0003 and 0.5 % mass fraction. This test method may be applicable to other isotopic abundance providing that corresponding standards are available. 1.2 This test method can apply to uranyl nitrate solutions. This can be achieved either by transforming the uranyl nitrate solution to a uranyl fluoride solution prior to the deposition on the filaments or directly by depositing the uranyl nitrate solution on the filaments. In the latter case, a calibration with uranyl nitrate standards must be performed. 1.3 This test method can also apply to other nuclear grade matrices (for example, uranium oxides) by providing a chemical transformation to uranyl fluoride or uranyl nitrate solution. 1.4 This standard does not purport to address al...

  19. Precision Test of Many-Body QED in the Be$^+$ $2p$ Fine Structure Doublet Using Short-Lived Isotopes

    E-Print Network [OSTI]

    Nörtershäuser, Wilfried; Krieger, Andreas; Pachucki, Krzysztof; Puchalski, Mariusz; Blaum, Klaus; Bissell, Mark L; Frömmgen, Nadja; Hammen, Michael; Kowalska, Magdalena; Krämer, Jörg; Kreim, Kim; Neugart, Rainer; Neyens, Gerda; Sánchez, Rodolfo; Yordanov, Deyan T

    2015-01-01

    Absolute transition frequencies of the $2s\\; ^2{\\rm S}_{1/2} \\rightarrow 2p\\;^2\\mathrm{P}_{1/2,3/2}$ transitions in Be$^+$ were measured for the isotopes $^{7,9-12}$Be. The fine structure splitting of the $2p$ state and its isotope dependence are extracted and compared to results of \\textit{ab initio} calculations using explicitly correlated basis functions, including relativistic and quantum electrodynamics effects at the order of $m \\alpha^6$ and $m \\alpha^7 \\ln \\alpha$. Accuracy has been improved in both the theory and experiment by 2 orders of magnitude, and good agreement is observed. This represents one of the most accurate tests of quantum electrodynamics for many-electron systems, being insensitive to nuclear uncertainties.

  20. Geothermometry At Nevada Test And Training Range Area (Sabin, Et Al., 2004)

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpenFishOpen Energy1976)| Open

  1. ForCent model development and testing using the Enriched Background Isotope Study experiment

    SciTech Connect (OSTI)

    Parton, W.J.; Hanson, P. J.; Swanston, C.; Torn, M.; Trumbore, S. E.; Riley, W.; Kelly, R.

    2010-10-01

    The ForCent forest ecosystem model was developed by making major revisions to the DayCent model including: (1) adding a humus organic pool, (2) incorporating a detailed root growth model, and (3) including plant phenological growth patterns. Observed plant production and soil respiration data from 1993 to 2000 were used to demonstrate that the ForCent model could accurately simulate ecosystem carbon dynamics for the Oak Ridge National Laboratory deciduous forest. A comparison of ForCent versus observed soil pool {sup 14}C signature ({Delta} {sup 14}C) data from the Enriched Background Isotope Study {sup 14}C experiment (1999-2006) shows that the model correctly simulates the temporal dynamics of the {sup 14}C label as it moved from the surface litter and roots into the mineral soil organic matter pools. ForCent model validation was performed by comparing the observed Enriched Background Isotope Study experimental data with simulated live and dead root biomass {Delta} {sup 14}C data, and with soil respiration {Delta} {sup 14}C (mineral soil, humus layer, leaf litter layer, and total soil respiration) data. Results show that the model correctly simulates the impact of the Enriched Background Isotope Study {sup 14}C experimental treatments on soil respiration {Delta} {sup 14}C values for the different soil organic matter pools. Model results suggest that a two-pool root growth model correctly represents root carbon dynamics and inputs to the soil. The model fitting process and sensitivity analysis exposed uncertainty in our estimates of the fraction of mineral soil in the slow and passive pools, dissolved organic carbon flux out of the litter layer into the mineral soil, and mixing of the humus layer into the mineral soil layer.

  2. Improved Geothermometry Through Multivariate Reaction-path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators: Final Report

    SciTech Connect (OSTI)

    Mattson, Earl; Smith, Robert; Fujita, Yoshiko; McLing, Travis; Neupane, Ghanashyam; Palmer, Carl; Reed, David; Thompson, Vicki

    2015-03-01

    The project was aimed at demonstrating that the geothermometric predictions can be improved through the application of multi-element reaction path modeling that accounts for lithologic and tectonic settings, while also accounting for biological influences on geochemical temperature indicators. The limited utilization of chemical signatures by individual traditional geothermometer in the development of reservoir temperature estimates may have been constraining their reliability for evaluation of potential geothermal resources. This project, however, was intended to build a geothermometry tool which can integrate multi-component reaction path modeling with process-optimization capability that can be applied to dilute, low-temperature water samples to consistently predict reservoir temperature within ±30 °C. The project was also intended to evaluate the extent to which microbiological processes can modulate the geochemical signals in some thermal waters and influence the geothermometric predictions.

  3. Design and Nuclear-Safety Related Simulations of Bare-Pellet Test Irradiations for the Production of Pu-238 in the High Flux Isotope Reactor using COMSOL

    SciTech Connect (OSTI)

    Freels, James D; Jain, Prashant K; Hobbs, Randy W

    2012-01-01

    The Oak Ridge National Laboratory (ORNL)is developing technology to produce plutonium-238 for the National Aeronautics and Space Administration (NASA) as a power source material for powering vehicles while in deep-space[1]. The High Flux Isotope Reactor (HFIR) of ORNL has been utilized to perform test irradiations of incapsulated neptunium oxide (NpO2) and aluminum powder bare pellets for purposes of understanding the performance of the pellets during irradiation[2]. Post irradiation examinations (PIE) are currently underway to assess the effect of temperature, thermal expansion, swelling due to gas production, fission products, and other phenomena

  4. Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:BoreOpen Energy InformationOpen EnergyRocher,

  5. Strategic Isotope Production | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing facility (IMET) are routinely used in the production, purification, packaging, and shipping of a number of isotopes of national importance, including: 75Se, 63Ni,...

  6. Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California.

    SciTech Connect (OSTI)

    James B. Paces; Zell E. Peterman; Kiyoto Futa; Thomas A. Oliver; and Brian D. Marshall.

    2007-08-07

    Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values for Paleozoic seawater present at the time of deposition. Many of the samples have 87Sr/86Sr compositions that remain relatively unmodified from expected seawater values. However, rocks underlying the northern Nevada Test Site as well as rocks exposed at Bare Mountain commonly have elevated 87Sr/86Sr values derived from post-depositional addition of radiogenic Sr most likely from fluids circulating through rubidium-rich Paleozoic strata or Precambrian basement rocks.

  7. Transportation of medical isotopes

    SciTech Connect (OSTI)

    Nielsen, D.L.

    1997-11-19

    A Draft Technical Information Document (HNF-1855) is being prepared to evaluate proposed interim tritium and medical isotope production at the Fast Flux Test Facility (FFTF). This assessment examines the potential health and safety impacts of transportation operations associated with the production of medical isotopes. Incident-free and accidental impacts are assessed using bounding source terms for the shipment of nonradiological target materials to the Hanford Site, the shipment of irradiated targets from the FFTF to the 325 Building, and the shipment of medical isotope products from the 325 Building to medical distributors. The health and safety consequences to workers and the public from the incident-free transportation of targets and isotope products would be within acceptable levels. For transportation accidents, risks to works and the public also would be within acceptable levels. This assessment is based on best information available at this time. As the medical isotope program matures, this analysis will be revised, if necessary, to support development of a final revision to the Technical Information Document.

  8. Laser separation of medical isotopes

    SciTech Connect (OSTI)

    Eerkens, J.W.; Puglishi, D.A.; Miller, W.H.

    1996-12-31

    There is an increasing demand for different separated isotopes as feed material for reactor and cyclotron-produced radioisotopes used by a fast-growing radiopharmaceutical industry. One new technology that may meet future demands for medical isotopes is molecular laser isotope separation (MLIS). This method was investigated for the enrichment of uranium in the 1970`s and 1980s by Los Alamos National Laboratory, Isotope Technologies, and others around the world. While South Africa and Japan have continued the development of MLIS for uranium and are testing pilot units, around 1985 the United States dropped the LANL MLIS program in favor of AVLIS (atomic vapor LIS), which uses electron-beam-heated uranium metal vapor. AVLIS appears difficult and expensive to apply to most isotopes of medical interest, however, whereas MLIS technology, which is based on cooled hexafluorides or other gaseous molecules, can be adapted more readily. The attraction of MLIS for radiopharmaceutical firms is that it allows them to operate their own dedicated separators for small-quantity productions of critical medical isotopes, rather than having to depend on large enrichment complexes run by governments, which are only optimal for large-quantity productions. At the University of Missouri, the authors are investigating LIS of molybdenum isotopes using MoF{sub 6}, which behaves in a way similar to UF{sub 6}, studied in the past.

  9. Stable Isotope Enrichment Capabilities at ORNL

    SciTech Connect (OSTI)

    Egle, Brian; Aaron, W Scott; Hart, Kevin J

    2013-01-01

    The Oak Ridge National Laboratory (ORNL) and the US Department of Energy Nuclear Physics Program have built a high-resolution Electromagnetic Isotope Separator (EMIS) as a prototype for reestablishing a US based enrichment capability for stable isotopes. ORNL has over 60 years of experience providing enriched stable isotopes and related technical services to the international accelerator target community, as well as medical, research, industrial, national security, and other communities. ORNL is investigating the combined use of electromagnetic and gas centrifuge isotope separation technologies to provide research quantities (milligram to several kilograms) of enriched stable isotopes. In preparation for implementing a larger scale production facility, a 10 mA high-resolution EMIS prototype has been built and tested. Initial testing of the device has simultaneously collected greater than 98% enriched samples of all the molybdenum isotopes from natural abundance feedstock.

  10. Testing the Mutually Enhanced Magicity Effect in Nuclear Incompressibility via the Giant Monopole Resonance in the $^{204,206,208}$Pb Isotopes

    E-Print Network [OSTI]

    D. Patel; U. Garg; M. Fujiwara; T. Adachi; H. Akimune; G. P. A. Berg; M. N. Harakeh; M. Itoh; C. Iwamoto; A. Long; J. T. Matta; T. Murakami; A. Okamoto; K. Sault; R. Talwar; M. Uchida; M. Yosoi

    2013-08-09

    Using inelastic $\\alpha$-scattering at extremely forward angles, including $0^\\circ$, the strength distributions of the isoscalar giant monopole resonance (ISGMR) have been measured in the $^{204,206,208}$Pb isotopes in order to examine the proposed mutually enhanced magicity (MEM) effect on the nuclear incompressibility. The MEM effect had been suggested as a likely explanation of the "softness" of nuclear incompressibility observed in the ISGMR measurements in the Sn and Cd isotopes. Our experimental results rule out any manifestation of the MEM effect in nuclear incompressibility and leave the question of the softness of the open-shell nuclei unresolved still.

  11. Isotopes Products

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATIONIntroducing theActivation byIs a SmallIsotope

  12. Standard test method for determination of uranium or plutonium isotopic composition or concentration by the total evaporation method using a thermal ionization mass spectrometer

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2007-01-01

    1.1 This method describes the determination of the isotopic composition and/or the concentration of uranium and plutonium as nitrate solutions by the thermal ionization mass spectrometric (TIMS) total evaporation method. Purified uranium or plutonium nitrate solutions are loaded onto a degassed metal filament and placed in the mass spectrometer. Under computer control, ion currents are generated by heating of the filament(s). The ion beams are continually measured until the sample is exhausted. The measured ion currents are integrated over the course of the run, and normalized to a reference isotope ion current to yield isotopic ratios. 1.2 In principle, the total evaporation method should yield isotopic ratios that do not require mass bias correction. In practice, some samples may require this bias correction. When compared to the conventional TIMS method, the total evaporation method is approximately two times faster, improves precision from two to four fold, and utilizes smaller sample sizes. 1.3 The tot...

  13. Liquid Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma, Arizona:Oregon: Energy ResourcesGrove, Iowa: EnergyLipscomb County,

  14. Gas Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdistoWhiskeyFootprintGEXA Corp. (Delaware)GalvestonWind Jump2008) |Gas

  15. EIS-0310: Accomplishing Expanded Civilian Nuclear Energy Research and Development and Isotope Production Missions in the United States, Including the Role of the Fast Flux Test Facility

    Office of Energy Efficiency and Renewable Energy (EERE)

    This PEIS will evaluate the potential environmental impacts of the proposed enhancement of the existing infrastructure, including the possible role of the Fast Flux Test Facility (FFTF), located at...

  16. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus. 2 figures.

  17. Stable isotope enrichment

    ScienceCinema (OSTI)

    Egle, Brian

    2014-07-15

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  18. Stable isotope enrichment

    SciTech Connect (OSTI)

    Egle, Brian

    2014-07-14

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  19. Geochemical and Isotopic Evaluation of Groundwater Movement in Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada Test Site, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-02-01

    This report describes the results of a comprehensive geochemical evaluation of the groundwater flow system in the Yucca Flat/Climax Mine Corrective Action Unit (CAU). The main objectives of this study are to identify probable pathways for groundwater flow within the study area and to develop constraints on groundwater transit times between selected data collection sites. This work provides an independent means of testing and verifying predictive flow models being developed for this CAU using finite element methods. The Yucca Flat/Climax Mine CAU constitutes the largest of six underground test areas on the Nevada Test Site (NTS) specified for remedial action in the ''Federal Facility Agreement and Consent Order''. A total of 747 underground nuclear detonations were conducted in this CAU. Approximately 23 percent of these detonations were conducted below or near the water table, resulting in groundwater contamination in the vicinity and possibly downgradient of these underground test locations. Therefore, a rigorous evaluation of the groundwater flow system in this CAU is necessary to assess potential long-term risks to the public water supply at downgradient locations.

  20. Price Quotes and Isotope Ordering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ordering Price Quotes and Isotope Ordering Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Isotope...

  1. Discovery of the Indium Isotopes

    E-Print Network [OSTI]

    S. Amos; M. Thoennessen

    2010-09-08

    Thirty-eight indium isotopes (A = 98-135) have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  2. Discovery of the Titanium Isotopes

    E-Print Network [OSTI]

    D. Meierfrankenfeld; M. Thoennessen

    2010-09-08

    Twentyfive titanium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  3. Discovery of the Mercury Isotopes

    E-Print Network [OSTI]

    D. Meierfrankenfeld; M. Thoennessen

    2010-09-08

    Forty mercury isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  4. Discovery of the Cobalt Isotopes

    E-Print Network [OSTI]

    T. Szymanski; M. Thoennessen

    2009-09-04

    Twenty-six cobalt isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  5. Discovery of the Tin Isotopes

    E-Print Network [OSTI]

    S. Amos; M. Thoennessen

    2010-09-08

    Thirty-eight tin isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  6. Discovery of the Cadmium Isotopes

    E-Print Network [OSTI]

    S. Amos; M. Thoennessen

    2009-10-22

    Thirty-seven cadmium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  7. (Carbon isotope fractionation inplants)

    SciTech Connect (OSTI)

    O'Leary, M.H.

    1990-01-01

    The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.

  8. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

    1987-04-28

    A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

  9. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Munich, DE); Boyer, Keith (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM)

    1988-01-01

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  10. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1986-08-15

    The atomic vapor laser isotope separation (AVLIS) process for the enrichment of uranium is evaluated. (AIP)

  11. Perchlorate Isotope Forensics

    SciTech Connect (OSTI)

    Bohlke, J. K. [U.S. Geological Survey, Reston, VA; Sturchio, N. C. [University of Illinois, Chicago; Gu, Baohua [ORNL; Horita, Juske [ORNL; Brown, Gilbert M [ORNL; Jackson, W. Andrew [Tennessee Technological University; Batista, Jacimaria [University of Nevada, Las Vegas

    2006-01-01

    Perchlorate has been detected recently in a variety of soils, waters, plants, and food products at levels that may be detrimental to human health. These discoveries have generated considerable interest in perchlorate source identification. In this study, comprehensive stable isotope analyses ({sup 37}Cl/{sup 35}Cl and {sup 18}O/{sup 17}O/{sup 16}O) of perchlorate from known synthetic and natural sources reveal systematic differences in isotopic characteristics that are related to the formation mechanisms. In addition, isotopic analyses of perchlorate extracted from groundwater and surface water demonstrate the feasibility of identifying perchlorate sources in contaminated environments on the basis of this technique. Both natural and synthetic sources of perchlorate have been identified in water samples from some perchlorate occurrences in the United States by the isotopic method.

  12. Plasma isotope separation methods

    SciTech Connect (OSTI)

    Grossman, M.W. ); Shepp, T.A. )

    1991-12-01

    Isotope separation has many important industrial, medical, and research applications. Large-scale processes have typically utilized complex cascade systems; for example, the gas centrifuge. Alternatively, high single-stage enrichment processes (as in the case of the calutron) are very energy intensive. Plasma-based methods being developed for the past 15 to 20 years have attempted to overcome these two drawbacks. In this review, six major types of isotope separation methods which involve plasma phenomena are discussed. These methods are: plasma centrifuge, AVLIS (atomic vapor laser isotope separation), ion wave, ICR (ion-cyclotron resonance), calutron, and gas discharge. The emphasis of this paper is to describe the plasma phenomena in these major categories. An attempt was made to include enough references so that more detailed study or evaluation of a particular method could readily be pursued. A brief discussion of isotope separation using mass balance concepts is also carried out.

  13. Hydrogen Isotope Exchange Properties of Porous Solids Containing Hydrogen

    SciTech Connect (OSTI)

    HEUNG, LEUNGK.

    2004-08-18

    Porous solids such as activated alumina, silica and molecular sieves generally contain significant amounts of hydrogen atoms in the form of H2O or OH even at high temperature and low humidity environment. A significant amount of this hydrogen is available for reversible isotopic exchange. This exchange reaction is slow under normal conditions and does not render itself to practical applications. But if the exchange kinetics is improved this reaction has the potential to be used for tritium removal from gas streams or for hydrogen isotopic separation.The use of catalysts to improve the exchange kinetics between hydrogen isotope in the gas phase and that in the solid phase was investigated. Granules of alumina, silica and molecular sieve were coated with platinum or palladium as the catalyst. The granules were packed in a 2-cm diameter column for isotope exchange tests. Gas streams containing different concentrations of deuterium in nitrogen or argon were fed through the protium saturated column. Isotope concentration in column effluent was monitored to generate isotope break-through curves. The curves were analyzed to produce information on the kinetics and capacity of the material. The results showed that all materials tested provided some extent of isotope exchange but some were superior both in kinetics and capacity. This paper will present the test results.

  14. Use of Stable Isotopes in Forensic Analysis of Microorganisms

    SciTech Connect (OSTI)

    Kreuzer-Martin, Helen W.; Hegg, Eric L.

    2012-01-18

    The use of isotopic signatures for forensic analysis of biological materials is well-established, and the same general principles that apply to interpretation of stable isotope content of C, N, O, and H apply to the analysis of microorganisms. Heterotrophic microorganisms derive their isotopic content from their growth substrates, which are largely plant and animal products, and the water in their culture medium. Thus the isotope signatures of microbes are tied to their growth environment. The C, N, O, and H isotope ratios of spores have been demonstrated to constitute highly discriminating signatures for sample matching. They can rule out specific samples of media and/or water as possible production media, and can predict isotope ratio ranges of the culture media and water used to produce a given sample. These applications have been developed and tested through analyses of approximately 250 samples of Bacillus subtilis spores and over 500 samples of culture media, providing a strong statistical basis for data interpretation. A Bayesian statistical framework for integrating stable isotope data with other types of signatures derived from microorganisms has been able to characterize the culture medium used to produce spores of various Bacillus species, leveraging isotopic differences in different medium types and demonstrating the power of data integration for forensic investigations.

  15. Isotope and Nuclear Chemistry Division annual report, FY 1983

    SciTech Connect (OSTI)

    Heiken, J.H.; Lindberg, H.A. (eds.)

    1984-05-01

    This report describes progress in the major research and development programs carried out in FY 1983 by the Isotope and Nuclear Chemistry Division. It covers radiochemical diagnostics of weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production, separation, and applications (including biomedical applications); element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced analytical techniques; development and applications; atmospheric chemistry and transport; and earth and planetary processes.

  16. Method for separating boron isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM)

    1978-01-01

    A method of separating boron isotopes .sup.10 B and .sup.11 B by laser-induced selective excitation and photodissociation of BCl.sub.3 molecules containing a particular boron isotope. The photodissociation products react with an appropriate chemical scavenger and the reaction products may readily be separated from undissociated BCl.sub.3, thus effecting the desired separation of the boron isotopes.

  17. Isotop kl. B Supportlab.

    E-Print Network [OSTI]

    Isotop kl. B lab. Nærlager Supportlab. Supportlab. Supportlab. Lab. GMO1/BSL2 Supportlab. Supportlab. Supportlab. Supportlab. Lab. GMO1/BSL2 Vareindlevering post/frost Kontor Sofastue / Thekøkken. GMO1/BSL2 Supportlab. �velseslab, eksist. �velseslab, eksist. Forberedelseslab. Rum, køl/ centrifuge

  18. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, C.A.; Worden, E.F.

    1995-08-22

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of {sup 167}Er. The hyperfine structure of {sup 167}Er was used to find two three-step photoionization pathways having a common upper energy level. 3 figs.

  19. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, Christopher A. (3035 Ferdale Ct., Pleasanton, CA 94566); Worden, Earl F. (117 Vereda del Ciervo, Diablo, CA 94528)

    1995-01-01

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  20. RESOLUTION OF URANIUM ISOTOPES WITH KINETIC PHOSPHORESCENCE ANALYSIS

    SciTech Connect (OSTI)

    Miley, Sarah M.; Hylden, Anne T.; Friese, Judah I.

    2013-04-01

    This study was conducted to test the ability of the Chemchek™ Kinetic Phosphorescence Analyzer Model KPA-11 with an auto-sampler to resolve the difference in phosphorescent decay rates of several different uranium isotopes, and therefore identify the uranium isotope ratios present in a sample. Kinetic phosphorescence analysis (KPA) is a technique that provides rapid, accurate, and precise determination of uranium concentration in aqueous solutions. Utilizing a pulsed-laser source to excite an aqueous solution of uranium, this technique measures the phosphorescent emission intensity over time to determine the phosphorescence decay profile. The phosphorescence intensity at the onset of decay is proportional to the uranium concentration in the sample. Calibration with uranium standards results in the accurate determination of actual concentration of the sample. Different isotopes of uranium, however, have unique properties which should result in different phosphorescence decay rates seen via KPA. Results show that a KPA is capable of resolving uranium isotopes.

  1. Undesirable options - The U. S. isotope crisis

    SciTech Connect (OSTI)

    Not Available

    1993-04-01

    When a Canadian reactor failed in late 1990, it shut off a principle supply of iridium-192, an isotope critical to gamma radiography. Following the failure of the Canadian reactor, iridium sources inside the US were largely undependable in terms of both cost and schedule. The scheduling problems are outlined in the following testimony; prices increased 35% on one occasion, and then saw another increase of 60%. On August 3, 1992 Congressman Mike Synar requested that ASNT member Donny Dicharry present testimony on behalf of ASNT, the Nondestructive Testing Management Association (NDTMA), and Source Production and Equipment Co., Inc. (SPEC) concerning the Department of Energy's isotope program and the iridium-192 shortage. Excerpts from the testimony are given.

  2. Isotopically labeled compositions and method

    DOE Patents [OSTI]

    Schmidt, Jurgen G. (Los Alamos, NM); Kimball, David B. (Los Alamos, NM); Alvarez, Marc A. (Santa Fe, NM); Williams, Robert F. (Los Alamos, NM); Martinez, Rudolfo A. (Santa Fe, NM)

    2011-07-12

    Compounds having stable isotopes .sup.13C and/or .sup.2H were synthesized from precursor compositions having solid phase supports or affinity tags.

  3. Quantifying uncertainty in stable isotope mixing models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davis, Paul; Syme, James; Heikoop, Jeffrey; Fessenden-Rahn, Julianna; Perkins, George; Newman, Brent; Chrystal, Abbey E.; Hagerty, Shannon B.

    2015-05-19

    Mixing models are powerful tools for identifying biogeochemical sources and determining mixing fractions in a sample. However, identification of actual source contributors is often not simple, and source compositions typically vary or even overlap, significantly increasing model uncertainty in calculated mixing fractions. This study compares three probabilistic methods, SIAR [Parnell et al., 2010] a pure Monte Carlo technique (PMC), and Stable Isotope Reference Source (SIRS) mixing model, a new technique that estimates mixing in systems with more than three sources and/or uncertain source compositions. In this paper, we use nitrate stable isotope examples (?15N and ?18O) but all methods testedmore »are applicable to other tracers. In Phase I of a three-phase blind test, we compared methods for a set of six-source nitrate problems. PMC was unable to find solutions for two of the target water samples. The Bayesian method, SIAR, experienced anchoring problems, and SIRS calculated mixing fractions that most closely approximated the known mixing fractions. For that reason, SIRS was the only approach used in the next phase of testing. In Phase II, the problem was broadened where any subset of the six sources could be a possible solution to the mixing problem. Results showed a high rate of Type I errors where solutions included sources that were not contributing to the sample. In Phase III some sources were eliminated based on assumed site knowledge and assumed nitrate concentrations, substantially reduced mixing fraction uncertainties and lowered the Type I error rate. These results demonstrate that valuable insights into stable isotope mixing problems result from probabilistic mixing model approaches like SIRS. The results also emphasize the importance of identifying a minimal set of potential sources and quantifying uncertainties in source isotopic composition as well as demonstrating the value of additional information in reducing the uncertainty in calculated mixing fractions.« less

  4. RADIOCHEMICAL STUDIES OF NEUTRON DEFICIENT ACTINIDE ISOTOPES

    E-Print Network [OSTI]

    Williams, Kimberly Eve

    2011-01-01

    Isotope Targets and Foils, AERE-R 5097, Paper 10 (1965). V.Isotope Targets and Foils, AERE-R 5097 Paper 12 (1965). K.M.Isotope Targets and Foils, AERE-R-5097 Paper 11 (1965). M.

  5. Isotope Specific Remediation Media and Systems - 13614

    SciTech Connect (OSTI)

    Denton, Mark S.; Mertz, Joshua L. [Kurion, Inc. Oak Ridge, Tennessee 37831 (United States)] [Kurion, Inc. Oak Ridge, Tennessee 37831 (United States); Morita, Keisuke [Japan Atomic Energy Agency, Tokai Research and Development Center, Fukushima Project Team, Tokai-mura, Ibaraki-ken, 319-1195 (Japan)] [Japan Atomic Energy Agency, Tokai Research and Development Center, Fukushima Project Team, Tokai-mura, Ibaraki-ken, 319-1195 (Japan)

    2013-07-01

    On March 11, 2011, now two years ago, the magnitude 9.0 Great East Japan earthquake, Tohoku, hit off the Fukushima coast of Japan. While, of course, most of the outcome of this unprecedented natural and manmade disaster was a negative, both in Japan and worldwide, there have been some extremely invaluable lessons learned and new emergency recovery technologies and systems developed. As always, the mother of invention is necessity. Among these developments has been the development and full-scale implementation of proven isotope specific media (ISMs) with the intent of surgically removing specific hazardous isotopes for the purpose of minimizing dose to workers and the environment. The first such ISMs to be deployed at the Fukushima site were those removing cesium (Cs-137) and iodine (I-129). Since deployment on June 17, 2011, along with treated cooling water recycle, some 70% of the curies in the building liquid wastes have been removed by the Kurion system alone. The current levels of cesium are now only 2% of the original levels. Such an unprecedented, 'external cooling system' not only allowed the eventual cold shut down of the reactors in mid-December, 2011, but has allowed workers to concentrate on the cleanup of other areas of the site. Water treatment will continue for quite some time due to continued leakage into the buildings and the eventual goal of cleaning up the reactors and fuel pools themselves. With the cesium removal now in routine operation, other isotopes of concern are likely to become priorities. One such isotope is that of strontium, and yttrium (Sr-90 and Y-90), which is still at original levels causing further dose issues as well as impediments to discharge of the treated waste waters. For over a year now, a new synthetic strontium specific media has been under development and testing both in our licensed facility in Oak Ridge, Tennessee, but also in confirmatory tests by the Japan Atomic Energy Agency (JAEA) in Japan for Tokyo Electric Power Company (TEPCO). The tests have proven quite successful, even in high salt conditions, and, with loading and dose calculations being completed, will be proposed to add to the existing cesium system. There is no doubt, as high gamma isotopes are removed, other recalcitrant isotopes such as this will require innovative removal media, systems and techniques. Also coming out of this international effort are other ISM media and systems that can be applied more broadly to both Commercial Nuclear Power Plants (NPPs) as well as in Department of Energy (DOE) applications. This cesium and strontium specific media has further been successfully tested in 2012 at a Magnox station in the UK. The resulting proposed mitigation systems for pond and vault cleanup look quite promising. An extremely unusual ISM for carbon 14 (C-14), nickel (Ni-63) and cesium (Cs-137) has been developed for Diablo Canyon NPP for dose reduction testing in their fuel pool. These media will be deployed in Submersible Media Filter (SMF) and Submersible Columns (SC) systems adapted to standard Tri-Nuclear{sup R} housings common in the U.S. and UK. External Vessel Systems (mini-Fukushima) have also been developed as a second mitigation system for D and D and outages. Finally, technetium (Tc- 99) specific media developed for the Waste Treatment Plant (WTP) recycle or condensate (secondary) waste streams (WM 2011) are being further perfected and tested for At-Tank Tc-99 removal, as well as At Tank Cs media. In addition to the on-going media development, systems for deploying such media have developed over the last year and are in laboratory- and full-scale testing. These systems include the fore mentioned Submersible Media Filters (SMF), Submersible Columns (SC) and external pilot- and full-scale, lead-lag, canister systems. This paper will include the media development and testing, as well as that of the deployment systems themselves. (authors)

  6. Advanced isotope separation

    SciTech Connect (OSTI)

    Not Available

    1982-05-04

    The Study Group briefly reviewed the technical status of the three Advanced Isotope Separation (AIS) processes. It also reviewed the evaluation work that has been carried out by DOE's Process Evaluation Board (PEB) and the Union Carbide Corporation-Nuclear Division (UCCND). The Study Group briefly reviewed a recent draft assessment made for DOE staff of the nonproliferation implications of the AIS technologies. The staff also very briefly summarized the status of GCEP and Advanced Centrifuge development. The Study Group concluded that: (1) there has not been sufficient progress to provide a firm scientific, technical or economic basis on which to select one of the three competing AIS processes for full-scale engineering development at this time; and (2) however, should budgetary restraints or other factors force such a selection, we believe that the evaluation process that is being carried out by the PEB provides the best basis available for making a decision. The Study Group recommended that: (1) any decisions on AIS processes should include a comparison with gas centrifuge processes, and should not be made independently from the plutonium isotope program; (2) in evaluating the various enrichment processes, all applicable costs (including R and D and sales overhead) and an appropriate discounting approach should be included in order to make comparisons on a private industry basis; (3) if the three AIS programs continue with limited resources, the work should be reoriented to focus only on the most pressing technical problems; and (4) if a decision is made to develop the Atomic Vapor Laser Isotope Separation process, the solid collector option should be pursued in parallel to alleviate the potential program impact of liquid collector thermal control problems.

  7. The marine biogeochemistry of zinc isotopes

    E-Print Network [OSTI]

    John, Seth G

    2007-01-01

    Zinc (Zn) stable isotopes can record information about important oceanographic processes. This thesis presents data on Zn isotopes in anthropogenic materials, hydrothermal fluids and minerals, cultured marine phytoplankton, ...

  8. Isotope Research 229 Th production

    E-Print Network [OSTI]

    Isotope Research ­ 229 Th production We recently completed an ARRA-funded project of this type on 229 Th production reactions [Str11]. This long-lived isotope is important as a precursor to 225 Ac of accelerator production of 229 Th via the 230 Th(p,2n)229 Pa reaction. The 229 Pa decays primarily by electron

  9. Isotopically Enriched Films and Nanostructures by Ultrafast Pulsed Laser Deposition

    SciTech Connect (OSTI)

    Peter Pronko

    2004-12-13

    This project involved a systematic study to apply newly discovered isotopic enrichment effects in laser ablation plumes to the fabrication of isotopically engineered thin films, superlattices, and nanostructures. The approach to this program involved using ultrafast lasers as a method for generating ablated plasmas that have preferentially structured isotopic content in the body of the ablation plasma plumes. In examining these results we have attempted to interpret the observations in terms of a plasma centrifuge process that is driven by the internal electro-magnetic fields of the plasma itself. The research plan involved studying the following phenomena in regard to the ablation plume and the isotopic mass distribution within it: (1) Test basic equations of steady state centrifugal motion in the ablation plasma. (2) Investigate angular distribution of ions in the ablation plasmas. (3) Examine interactions of plasma ions with self-generated magnetic fields. (3) Investigate ion to neutral ratios in the ablation plasmas. (5) Test concepts of plasma pumping. (6) Fabricate isotopically enriched nanostructures.

  10. Forensic Applications of Light-Element Stable Isotope Ratios of Ricinus communis Seeds and Ricin Preparations

    SciTech Connect (OSTI)

    Kreuzer, Helen W.; West, Jason B.; Ehleringer, James

    2013-01-01

    Seeds of the castor plant Ricinus communis, also known as castor beans, are of forensic interest because they are the source of the poison ricin. We have tested whether stable isotope ratios of castor seeds and ricin prepared by various methods can be used as a forensic signature. We collected over 300 castor seed samples from locations around the world and measured the C, N, O, and H stable isotope ratios of the whole seeds, oil, and three types of ricin preparations. Our results demonstrate that N isotope ratios can be used to correlate ricin prepared by any of these methods to source seeds. Further, stable isotope ratios distinguished >99% of crude and purified ricin protein samples in pair-wise comparison tests. Stable isotope ratios therefore constitute a valuable forensic signature for ricin preparations.

  11. Integrated Chemical Geothermometry System for Geothermal Exploration

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Develop practical and reliable system to predict geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids.

  12. Geothermometry (Klein, 2007) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessment InsettingGridGeothermeon(Klein,

  13. Category:Gas Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to: navigation, search GEOTHERMALFacebook

  14. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  15. Compelling Research Opportunities using Isotopes

    SciTech Connect (OSTI)

    2009-04-23

    Isotopes are vital to the science and technology base of the US economy. Isotopes, both stable and radioactive, are essential tools in the growing science, technology, engineering, and health enterprises of the 21st century. The scientific discoveries and associated advances made as a result of the availability of isotopes today span widely from medicine to biology, physics, chemistry, and a broad range of applications in environmental and material sciences. Isotope issues have become crucial aspects of homeland security. Isotopes are utilized in new resource development, in energy from bio-fuels, petrochemical and nuclear fuels, in drug discovery, health care therapies and diagnostics, in nutrition, in agriculture, and in many other areas. The development and production of isotope products unavailable or difficult to get commercially have been most recently the responsibility of the Department of Energy's Nuclear Energy program. The President's FY09 Budget request proposed the transfer of the Isotope Production program to the Department of Energy's Office of Science in Nuclear Physics and to rename it the National Isotope Production and Application program (NIPA). The transfer has now taken place with the signing of the 2009 appropriations bill. In preparation for this, the Nuclear Science Advisory Committee (NSAC) was requested to establish a standing subcommittee, the NSAC Isotope Subcommittee (NSACI), to advise the DOE Office of Nuclear Physics. The request came in the form of two charges: one, on setting research priorities in the short term for the most compelling opportunities from the vast array of disciplines that develop and use isotopes and two, on making a long term strategic plan for the NIPA program. This is the final report to address charge 1. NSACI membership is comprised of experts from the diverse research communities, industry, production, and homeland security. NSACI discussed research opportunities divided into three areas: (1) medicine, pharmaceuticals, and biology, (2) physical sciences and engineering, and (3) national security and other applications. In each area, compelling research opportunities were considered and the subcommittee as a whole determined the final priorities for research opportunities as the foundations for the recommendations. While it was challenging to prioritize across disciplines, our order of recommendations reflect the compelling research prioritization along with consideration of time urgency for action as well as various geopolitical market issues. Common observations to all areas of research include the needs for domestic availability of crucial stable and radioactive isotopes and the education of the skilled workforce that will develop new advances using isotopes in the future. The six recommendations of NSACI reflect these concerns and the compelling research opportunities for potential new discoveries. The science case for each of the recommendations is elaborated in the respective chapters.

  16. Raman scattering method and apparatus for measuring isotope ratios and isotopic abundances

    DOE Patents [OSTI]

    Harney, Robert C. (5665 Charlotte Way, No. 80, Livermore, CA 94550); Bloom, Stewart D. (141 Via Serena, Alamo, CA 94507)

    1978-01-01

    Raman scattering is used to measure isotope ratios and/or isotopic abundances. A beam of quasi-monochromatic photons is directed onto the sample to be analyzed, and the resulting Raman-scattered photons are detected and counted for each isotopic species of interest. These photon counts are treated mathematically to yield the desired isotope ratios or isotopic abundances.

  17. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means. 3 figures.

  18. Physics with isotopically controlled semiconductors

    SciTech Connect (OSTI)

    Haller, E. E., E-mail: eehaller@lbl.gov [University of California at Berkeley, Department of Materials Science and Engineering (United States)

    2010-07-15

    This paper is based on a tutorial presentation at the International Conference on Defects in Semiconductors (ICDS-25) held in Saint Petersburg, Russia in July 2009. The tutorial focused on a review of recent research involving isotopically controlled semiconductors. Studies with isotopically enriched semiconductor structures experienced a dramatic expansion at the end of the Cold War when significant quantities of enriched isotopes of elements forming semiconductors became available for worldwide collaborations. Isotopes of an element differ in nuclear mass, may have different nuclear spins and undergo different nuclear reactions. Among the latter, the capture of thermal neutrons which can lead to neutron transmutation doping, is the most prominent effect for semiconductors. Experimental and theoretical research exploiting the differences in all the properties has been conducted and will be illustrated with selected examples.

  19. Thermal Neutron Capture Cross Sections of the Palladium Isotopes

    E-Print Network [OSTI]

    2006-01-01

    CROSS SECTIONS OF THE PALLADIUM ISOTOPES R.B. Firestone ? ,? ? for all stable Palladium isotopes with the guidedscheme is complete. The Palladium isotope decay schemes are

  20. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer therapy gets a boost from new isotope Isotope production facility produces cancer-fighting actinium A new medical isotope project shows promise for rapidly producing major...

  1. Isotope specific arbitrary material sorter

    DOE Patents [OSTI]

    Barty, Christopher P.J.

    2015-12-08

    A laser-based mono-energetic gamma-ray source is used to provide a rapid and unique, isotope specific method for sorting materials. The objects to be sorted are passed on a conveyor in front of a MEGa-ray beam which has been tuned to the nuclear resonance fluorescence transition of the desired material. As the material containing the desired isotope traverses the beam, a reduction in the transmitted MEGa-ray beam occurs. Alternately, the laser-based mono-energetic gamma-ray source is used to provide non-destructive and non-intrusive, quantitative determination of the absolute amount of a specific isotope contained within pipe as part of a moving fluid or quasi-fluid material stream.

  2. AVLIS enrichment of medical isotopes

    SciTech Connect (OSTI)

    Haynam, C.A.; Scheibner, K.F.; Stern, R.C.; Worden, E.F.

    1996-12-31

    Under the Sponsorship of the United states Enrichment Corporation (USEC), we are currently investigating the large scale separation of several isotopes of medical interest using atomic vapor isotope separation (AVLIS). This work includes analysis and experiments in the enrichment of thallium 203 as a precursor to the production of thallium 201 used in cardiac imaging following heart attacks, on the stripping of strontium 84 from natural strontium as precursor to the production of strontium 89, and on the stripping of lead 210 from lead used in integrated circuits to reduce the number of alpha particle induced logic errors.

  3. Online Catalog of Isotope Products from DOE's National Isotope Development Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. The Isotope subprogram supports the production, and the development of production techniques of radioactive and stable isotopes that are in short supply for research and applications. Isotopes are high-priority commodities of strategic importance for the Nation and are essential for energy, medical, and national security applications and for basic research; a goal of the program is to make critical isotopes more readily available to meet domestic U.S. needs. This subprogram is steward of the Isotope Production Facility (IPF) at Los Alamos National Laboratory (LANL), the Brookhaven Linear Isotope Producer (BLIP) facility at BNL, and hot cell facilities for processing isotopes at ORNL, BNL and LANL. The subprogram also coordinates and supports isotope production at a suite of university, national laboratory, and commercial accelerator and reactor facilities throughout the Nation to promote a reliable supply of domestic isotopes. The National Isotope Development Center (NIDC) at ORNL coordinates isotope production across the many facilities and manages the business operations of the sale and distribution of isotopes.

  4. Isotope Development & Production | Nuclear Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Separation & Processing Strategic Isotope Production Super Heavy Element Discovery Nuclear Security Science & Technology Nuclear Systems Modeling, Simulation & Validation...

  5. Isotope and Nuclear Chemistry Division annual report FY 1986, October 1985-September 1986

    SciTech Connect (OSTI)

    Heiken, J.H. (ed.)

    1987-06-01

    This report describes progress in the major research and development programs carried out in FY 1986 by the Isotope and Nuclear Chemistry Division. The report includes articles on radiochemical diagnostics and weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production and separation; chemical biology and nuclear medicine; element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced concepts and technology; and atmospheric chemistry.

  6. Isotope Cancer Treatment Research at LANL

    ScienceCinema (OSTI)

    Weidner, John; Nortier, Meiring

    2014-06-02

    Los Alamos National Laboratory has produced medical isotopes for diagnostic and imaging purposes for more than 30 years. Now LANL researchers have branched out into isotope cancer treatment studies. New results show that an accelerator-based approach can produce clinical trial quantities of actinium-225, an isotope that has promise as a way to kill tumors without damaging surrounding healthy cells.

  7. Test Automation Test Automation

    E-Print Network [OSTI]

    Mousavi, Mohammad

    Test Automation Test Automation Mohammad Mousavi Eindhoven University of Technology, The Netherlands Software Testing 2013 Mousavi: Test Automation #12;Test Automation Outline Test Automation Mousavi: Test Automation #12;Test Automation Why? Challenges of Manual Testing Test-case design: Choosing inputs

  8. Experimental Test of Self-Shielding in VUV Photodissociation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the...

  9. Fractionation of sulfur isotopes by Desulfovibrio vulgaris mutants lacking hydrogenases or type I tetraheme cytochrome c[subscript 3

    E-Print Network [OSTI]

    Sim, Min Sub

    The sulfur isotope effect produced by sulfate reducing microbes is commonly used to trace biogeochemical cycles of sulfur and carbon in aquatic and sedimentary environments. To test the contribution of intracellular coupling ...

  10. The production of ultra-high purity single isotopes or tailored isotope mixtures by ICP-MS

    SciTech Connect (OSTI)

    Liezers, Martin; Farmer, Orville T.; Dion, Michael P.; Thomas, Linda MP; Eiden, Gregory C.

    2015-01-01

    We report the development and testing of a simple collector arrangement for a commercial quadrupole ICP-MS that for the first time has been used to produce small quantities of highly enriched (>99.99%) single isotopes, with deposition rates >10 ng/hour. The collector assembly replaces the standard instrument detector allowing for implantation with simultaneous monitoring of the incident ion current. Even under zero bias implant conditions, low energy (<10 eV), ion collection efficiency was observed to be very high ~99%. 151Eu ion currents of 0.1-0.5 nA were collected on a simple, planar foil without resorting to any type of cup configuration. Recovery of the enriched isotope from such foils is much simpler than from a more complex cup configuration. High rejection of adjacent mass isotopes was demonstrated by selectively implanting 167Er without any discernible co-implantation of 166Er and 168Er. The important analytical possibilities of the new approach to isotope ratio measurement, tracer purification and radiation measurements are discussed.

  11. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  12. Alternative applications of atomic vapor laser isotope separation technology

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This report was commissioned by the Secretary of Energy. It summarizes the main features of atomic vapor laser isotope separation (AVLIS) technology and subsystems; evaluates applications, beyond those of uranium enrichment, suggested by Lawrence Livermore National Laboratory (LLNL) and a wide range of US industries and individuals; recommends further work on several applications; recommends the provision of facilities for evaluating potential new applications; and recommends the full involvement of end users from the very beginning in the development of any application. Specifically excluded from this report is an evaluation of the main AVLIS missions, uranium enrichment and purification of plutonium for weapons. In evaluating many of the alternative applications, it became clear that industry should play a greater and earlier role in the definition and development of technologies with the Department of Energy (DOE) if the nation is to derive significant commercial benefit. Applications of AVLIS to the separation of alternate (nonuranium) isotopes were considered. The use of {sup 157}Gd as burnable poison in the nuclear fuel cycle, the use {sup 12}C for isotopically pure diamond, and the use of plutonium isotopes for several nonweapons applications are examples of commercially useful products that might be produced at a cost less than the product value. Separations of other isotopes such as the elemental constituents of semiconductors were suggested; it is recommended that proposed applications be tested by using existing supplies to establish their value before more efficient enrichment processes are developed. Some applications are clear, but their production costs are too high, the window of opportunity in the market has passed, or societal constraints (e.g., on reprocessing of reactor fuel) discourage implementation.

  13. Successful application of lead isotopes in source apportionment, legal proceedings, remediation and monitoring

    SciTech Connect (OSTI)

    Gulson, Brian, E-mail: brian.gulson@mq.edu.au [Graduate School of the Environment, Faculty of Science, Macquarie University, Sydney, NSW 2109 (Australia) [Graduate School of the Environment, Faculty of Science, Macquarie University, Sydney, NSW 2109 (Australia); CSIRO Earth Science and Resource Engineering North Ryde, NSW 1670 (Australia); Korsch, Michael [CSIRO Earth Science and Resource Engineering North Ryde, NSW 1670 (Australia)] [CSIRO Earth Science and Resource Engineering North Ryde, NSW 1670 (Australia); Winchester, Wayne; Devenish, Matthew; Hobbs, Thad [Esperance Cleanup and Recovery Project, Western Australia (WA) Department of Transport, Esperance 6450 (Australia)] [Esperance Cleanup and Recovery Project, Western Australia (WA) Department of Transport, Esperance 6450 (Australia); Main, Cleve; Smith, Gerard [Animal Health Laboratory, Department of Agriculture and Food, Perth 6151, WA (Australia)] [Animal Health Laboratory, Department of Agriculture and Food, Perth 6151, WA (Australia); Rosman, Kevin; Howearth, Lynette; Burn-Nunes, Laurie [Curtin University, Department of Imaging and Applied Physics, Bentley 6102, WA (Australia)] [Curtin University, Department of Imaging and Applied Physics, Bentley 6102, WA (Australia); Seow, Jimmy; Oxford, Cameron [Department of Environment and Conservation, Booragoon 6154, WA (Australia)] [Department of Environment and Conservation, Booragoon 6154, WA (Australia); Yun, Gracie; Gillam, Lindsay [Department of Health, East Perth 6004, WA (Australia)] [Department of Health, East Perth 6004, WA (Australia); Crisp, Michelle [LED (Locals for Esperance Development), Esperance 6450, WA (Australia)] [LED (Locals for Esperance Development), Esperance 6450, WA (Australia)

    2012-01-15

    In late 2006, the seaside community in Esperance Western Australia was alerted to thousands of native bird species dying. The source of the lead (Pb) was determined by Pb isotopes to derive from the handling of Pb carbonate concentrate through the Port, which began in July 2005. Concern was expressed for the impact of this on the community. Our objectives were to employ Pb isotope ratios to evaluate the source of Pb in environmental samples for use in legal proceedings, and for use in remediation and monitoring. Isotope measurements were undertaken of bird livers, plants, drinking water, soil, harbour sediments, air, bulk ceiling dust, gutter sludge, surface swabs and blood. The unique lead isotopic signature of the contaminating Pb carbonate enabled diagnostic apportionment of lead in samples. Apart from some soil and water samples, the proportion of contaminating Pb was >95% in the environmental samples. Lead isotopes were critical in resolving legal proceedings, are being used in the remediation of premises, were used in monitoring of workers involved in the decontamination of the storage facility, and monitoring transport of the concentrate through another port facility. Air samples show the continued presence of contaminant Pb, more than one year after shipping of concentrate ceased, probably arising from dust resuspension. Brief details of the comprehensive testing and cleanup of the Esperance community are provided along with the role of the Community. Lead isotopic analyses can provide significant benefits to regulatory agencies, interested parties, and the community where the signature is able to be characterised with a high degree of certainty. - Highlights: Black-Right-Pointing-Triangle Lead carbonate concentrate. Black-Right-Pointing-Triangle Successful use of Pb isotopes in identifying sources of Pb arising from transport and shipping. Black-Right-Pointing-Triangle Use of Pb isotopes in legal proceedings and their use in cleanup of residences. Black-Right-Pointing-Triangle Use of Pb isotopes in cleanup of a residual 9000 tonnes of Pb carbonate and in ongoing monitoring.

  14. Isotope separation with the RICH detector of the AMS Experiment

    E-Print Network [OSTI]

    Arruda, Luísa; Borges, João; Carmo, Fernando; Gonçalves, Patrícia; Pereira, Rui; Pimenta, Mário

    2007-01-01

    The Alpha Magnetic Spectrometer (AMS), to be installed on the International Space Station (ISS) in 2008, is a cosmic ray detector with several subsystems, one of which is a proximity focusing Ring Imaging Cherenkov (RICH) detector. This detector will be equipped with a dual radiator (aerogel+NaF), a lateral conical mirror and a detection plane made of 680 photomultipliers and light guides, enabling precise measurements of particle electric charge and velocity. Combining velocity measurements with data on particle rigidity from the AMS Tracker it is possible to obtain a measurement for particle mass, allowing the separation of isotopes. A Monte Carlo simulation of the RICH detector, based on realistic properties measured at ion beam tests, was performed to evaluate isotope separation capabilities. Results for three elements -- H (Z=1), He (Z=2) and Be (Z=4) -- are presented.

  15. Isotope separation with the RICH detector of the AMS Experiment

    E-Print Network [OSTI]

    Luísa Arruda; Fernando Barão; João Borges; Fernando Carmo; Patrícia Gonçalves; Rui Pereira; Mário Pimenta

    2007-10-03

    The Alpha Magnetic Spectrometer (AMS), to be installed on the International Space Station (ISS) in 2008, is a cosmic ray detector with several subsystems, one of which is a proximity focusing Ring Imaging Cherenkov (RICH) detector. This detector will be equipped with a dual radiator (aerogel+NaF), a lateral conical mirror and a detection plane made of 680 photomultipliers and light guides, enabling precise measurements of particle electric charge and velocity. Combining velocity measurements with data on particle rigidity from the AMS Tracker it is possible to obtain a measurement for particle mass, allowing the separation of isotopes. A Monte Carlo simulation of the RICH detector, based on realistic properties measured at ion beam tests, was performed to evaluate isotope separation capabilities. Results for three elements -- H (Z=1), He (Z=2) and Be (Z=4) -- are presented.

  16. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  17. EIS-0249: Medical Isotopes Production Project

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential environmental impacts of a proposal to establish a production capability for molybdenum-99 (Mo-99) and related medical isotopes.

  18. Stable Isotope Protocols: Sampling and Sample Processing

    E-Print Network [OSTI]

    Levin, Lisa A; Currin, Carolyn

    2012-01-01

    plants, benthic microalgae [BMI], benthic macroalgae) andin a dessicator, prior to analysis. A.2 Benthic microalgaeBenthic microalgae (BMI) can be collected for isotope

  19. Integration of Nontraditional Isotopic Systems Into Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nontraditional Isotopic Systems Into Reaction-Transport Models of EGS For Exploration, Evaluation of Water-Rock Interaction, and Impacts of Water Chemistry on Reservoir...

  20. Development of the laser isotope separation method (AVLIS) for obtaining weight amounts of highly enriched {sup 150}Nd isotope

    SciTech Connect (OSTI)

    Babichev, A P; Grigoriev, Igor' S; Grigoriev, A I; Dorovskii, A P; D'yachkov, Aleksei B; Kovalevich, S K; Kochetov, V A; Kuznetsov, V A; Labozin, Valerii P; Matrakhov, A V; Mironov, Sergei M; Nikulin, Sergei A; Pesnya, A V; Timofeev, N I; Firsov, Valerii A; Tsvetkov, G O; Shatalova, G G

    2005-10-31

    Results obtained at the first stage of development of the experimental technique for obtaining weight amounts of the highly enriched {sup 150}Nd isotope by laser photoionisation are presented. The vaporiser and the laser are designed, and various methods of irradiation of neodymium vapour and extraction of photoions are tested. The product yield {approx}40 mg h{sup -1} for the {approx}60% enrichment and 25 mg h{sup -1} for the {approx}65% enrichment is achieved for a vaporiser of length 27 cm. The cost of constructing the facility for preparing 50 kg of the {sup 150}Nd isotope, intended for determining the neutrino mass, is estimated. This estimate shows that the cost of production can be lowered by a factor of 5-7 compared to the electromagnetic method. (invited paper)

  1. Discovery of Isotopes of Elements with Z $\\ge$ 100

    E-Print Network [OSTI]

    M. Thoennessen

    2012-03-09

    Currently, 163 isotopes of elements with Z $\\ge$ 100 have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  2. Uranium isotopes fingerprint biotic reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-04-20

    Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U),more »i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.« less

  3. Spatial periphery of lithium isotopes

    SciTech Connect (OSTI)

    Galanina, L. I., E-mail: galan_lidiya@mail.ru; Zelenskaja, N. S. [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)

    2013-12-15

    The spatial structure of lithium isotopes is studied with the aid of the charge-exchange and (t, p) reactions on lithium nuclei. It is shown that an excited isobaric-analog state of {sup 6}Li (0{sup +}, 3.56MeV) has a halo structure formed by a proton and a neutron, that, in the {sup 9}Li nucleus, there is virtually no neutron halo, and that {sup 11}Li is a Borromean nucleus formed by a {sup 9}Li core and a two-neutron halo manifesting itself in cigar-like and dineutron configurations.

  4. Uranium molecular laser isotope separation

    SciTech Connect (OSTI)

    Jensen, R.J.; Sullivan, A.

    1982-01-01

    The Molecular Laser Isotope Separation program is moving into the engineering phase, and it is possible to determine in some detail the plant cost terms involved in the process economics. A brief description of the MLIS process physics is given as a motivation to the engineering and economics discussion. Much of the plant cost arises from lasers and the overall optical system. In the paper, the authors discuss lasers as operating units and systems, along with temporal multiplexing and Raman shifting. Estimates of plant laser costs are given.

  5. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area (Farrar, Et Al., 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic...

  6. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area (Welhan, Et Al., 1988) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic...

  7. BETA DECAY MEASUREMENTS OF NEUTRON DEFICIENT CESIUM ISOTOPES

    E-Print Network [OSTI]

    Parry, R.F.

    2010-01-01

    OF NEUTRON DEFICIENT CESIUM ISOTOPES by Roger Franklin Parryof Neutron Deficient Cesium Isotopes Table of ContentsReferences Wapstra xenon and cesium mass excess values 108

  8. Atom-Probe Tomographic Measurement of Trapped Hydrogen Isotopes...

    Office of Environmental Management (EM)

    Atom-Probe Tomographic Measurement of Trapped Hydrogen Isotopes Atom-Probe Tomographic Measurement of Trapped Hydrogen Isotopes Presentation from the 34th Tritium Focus Group...

  9. Advances in Hydrogen Isotope Separation Using Thermal Cycling...

    Office of Environmental Management (EM)

    Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Presentation...

  10. Hydrogen Isotope Research Center (HRC), University of Toyama...

    Office of Environmental Management (EM)

    Hydrogen Isotope Research Center (HRC), University of Toyama Hydrogen Isotope Research Center (HRC), University of Toyama Presentation from the 34th Tritium Focus Group Meeting...

  11. 2008 Workshop on The Nation's Needs for Isotopes: Present and...

    Office of Science (SC) Website

    and radioactive isotope products that are used worldwide. Hundreds of applications in medicine, industry, national security and research depend on isotopes as vital components. The...

  12. Permeation of Multiple Isotopes in the Transition Between Surface...

    Office of Environmental Management (EM)

    Permeation of Multiple Isotopes in the Transition Between Surface- and Diffusion-Limited Regimes Permeation of Multiple Isotopes in the Transition Between Surface- and...

  13. Isotopic Analysis At Central Nevada Seismic Zone Region (Kennedy...

    Open Energy Info (EERE)

    Isotopic Analysis At Central Nevada Seismic Zone Region (Kennedy & Van Soest, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic...

  14. Positive and inverse isotope effect on superconductivity

    E-Print Network [OSTI]

    Tian De Cao

    2009-09-04

    This article improves the BCS theory to include the inverse isotope effect on superconductivity. An affective model can be deduced from the model including electron-phonon interactions, and the phonon-induced attraction is simply and clearly explained on the electron Green function. The focus of this work is on how the positive or inverse isotope effect occurs in superconductors.

  15. [Carbon isotope fractionation inplants]. Final report

    SciTech Connect (OSTI)

    O`Leary, M.H.

    1990-12-31

    The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.

  16. The Quest for the Heaviest Uranium Isotope

    E-Print Network [OSTI]

    S. Schramm; D. Gridnev; D. V. Tarasov; V. N. Tarasov; W. Greiner

    2012-01-17

    We study Uranium isotopes and surrounding elements at very large neutron number excess. Relativistic mean field and Skyrme-type approaches with different parametrizations are used in the study. Most models show clear indications for isotopes that are stable with respect to neutron emission far beyond N=184 up to the range of around N=258.

  17. Efficient palladium isotope chromatograph for hydrogen (EPIC)

    SciTech Connect (OSTI)

    Embury, M.C.; Ellefson, R.E.; Melke, H.B. )

    1992-03-01

    The Efficient Palladium Isotope Chromatograph (EPIC) is a rapid cycling, computer-operated displacement chromatograph for the separation of hydrogen isotopes. EPIC incorporates several features that optimize product throughput and purity. This paper describes this palladium displacement chromatograph, the operations with protium and deuterium, and the design modifications for operation with tritium.

  18. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01

    constructed to enrich liquid UF6 slightly as feed for thej) b. Optimum a. s: .X. UF6 feed, (kg per year) XBL 7912 -

  19. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01

    scale use of gas centrifuges for uranium is imminent, andUranium Enrichment (1978). United States Gas Centrifuge

  20. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenryInhibitingInteractivePGAS andUniversityCancer therapy gets

  1. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  2. Upgrading scientific capabilities at the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    West, C.D.; Farrar, M.B.

    1997-07-14

    Following termination of the Advanced Neutron Source (ANS) Project, a program of upgrades to the Department of Energy`s High Flux Isotope Reactor (HFIR) was devised by a team of researchers and reactor operators and has been proposed to the department. HFIR is a multipurpose research reactor, commissioned in 1965, with missions in four nationally important areas: isotope production, especially transuranic isotopes; neutron scattering; neutron activation analysis; and irradiation testing of materials. For neutron scattering, there are two major enhancements and several smaller ones. The first is the installation of a small, hydrogen cold neutron source in one of the four existing beam tubes: because of the high reactor power, and the use of new design concepts developed for ANS, the cold source will be as bright as, or brighter than, the Institute Laue Langevin liquid deuterium vertical cold source, although space limitations mean that there will be far fewer cold beams and instruments at HFIR. This project is underway, and the cold source is expected to come on line following an extended shutdown in 1999 to replace the reactor`s beryllium reflector. The second major change proposed would put five thermal neutron guides at an existing beam port and construct a new guide hall to accommodate instruments on these very intense beams.

  3. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, Karl F. (Tracy, CA); Haynam, Christopher A. (Pleasanton, CA); Johnson, Michael A. (Pleasanton, CA); Worden, Earl F. (Diablo, CA)

    1999-01-01

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207.

  4. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, K.F.; Haynam, C.A.; Johnson, M.A.; Worden, E.F.

    1999-08-31

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207. 5 figs.

  5. The Atomic Vapor Laser Isotope Separation Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management`s position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  6. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1985-11-08

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power reactor fuel has been under development for over 10 years. In June 1985 the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for the internationally competitive production of uranium separative work. The economic basis for this decision is considered, with an indicated of the constraints placed on the process figures of merit and the process laser system. We then trace an atom through a generic AVLIS separator and give examples of the physical steps encountered, the models used to describe the process physics, the fundamental parameters involved, and the role of diagnostic laser measurements.

  7. Apparatus for storing hydrogen isotopes

    DOE Patents [OSTI]

    McMullen, John W. (Los Alamos, NM); Wheeler, Michael G. (Los Alamos, NM); Cullingford, Hatice S. (Houston, TX); Sherman, Robert H. (Los Alamos, NM)

    1985-01-01

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas(es) is (are) stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forming at a significantly lower temperature).

  8. Isotopic Studies of Contaminant Transport at the Hanford Site, WA

    E-Print Network [OSTI]

    Christensen, J.N.; Conrad, M.E.; DePaolo, D.J.; Dresel, P.E.

    2008-01-01

    1977. Subcommission on geochronology: Convention on the useby W. Sharp, Berkeley Geochronology Center). Isotopic

  9. Short course on St-02 applications of isotope dilutions and isotopic measurements

    SciTech Connect (OSTI)

    Miller, P.

    1998-01-05

    This short course includes information on these topics and subtopics: (I) Nuclear Properties: (A) Historic roots; (B) Nomenclature; (C) Nuclear Stability and abundance; (D) Uses of isotopic techniques; (II) Instrumentation: (A) Sources; (B) Mass resolving elements; (C) Detectors; (III) Making Isotopic Measurements by ICP-MS: (A) Deadtime Correction; (B) Mass Discrimination; (C) Signal /Noise considerations; (IV) Applications and examples: (A) Isotope dilution; (B) Double Spike; (C) Biological Application; (D) Environmental Application; (E) Geological.

  10. Oxygen isotopes in crystalline silicates of comet Wild 2: A comparison of oxygen isotope systematics between Wild 2 particles

    E-Print Network [OSTI]

    Meyers, Stephen R.

    Oxygen isotopes in crystalline silicates of comet Wild 2: A comparison of oxygen isotope 2012 Keywords: oxygen isotope ratios crystalline silicate comet 81P/Wild 2 solar system formation Stardust Abstract: Oxygen three-isotope ratios of nine crystalline silicate particles from comet Wild 2

  11. Neutron Deficient Isotopes of Rhodium and Palladium

    E-Print Network [OSTI]

    Perlman, I.

    2010-01-01

    S OF RHODI U! \\~ AFD PALLADIUM by Manfred Lindner and I.Isotopes of B." odinm. and Palladium Hanfred Lindner and 1.i.a ABSTRACT A palladium activit;)r assigned to mass

  12. Atomic vapor laser isotope separation process

    DOE Patents [OSTI]

    Wyeth, R.W.; Paisner, J.A.; Story, T.

    1990-08-21

    A laser spectroscopy system is utilized in an atomic vapor laser isotope separation process. The system determines spectral components of an atomic vapor utilizing a laser heterodyne technique. 23 figs.

  13. Nonequilibrium clumped isotope signals in microbial methane

    E-Print Network [OSTI]

    Wang, David T.

    Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its ...

  14. A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER

    E-Print Network [OSTI]

    O'Donnell, Tom

    A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER FOR PRODUCTION OF NEUTRON-RICH NUCLEI ( 136 Xe Superconducting Cyclotron Laboratory's weekly \\Green Sheet," 30 July 1999 #12; c Thomas W. O'Donnell 2000 All

  15. Photodisintegration of the isotope {sup 116}Cd

    SciTech Connect (OSTI)

    Belyshev, S. S.; Ishkhanov, B. S. [Moscow State University (Russian Federation)] [Moscow State University (Russian Federation); Orlin, V. N.; Stopani, K. A.; Khankin, V. V.; Shvedunov, N. V., E-mail: gg.swedn@gmail.com [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)

    2013-08-15

    The results obtained by measuring the yields of photodisintegration of the isotope {sup 116}Cd irradiated with bremsstrahlung photons whose spectrum had an endpoint energy of 55 MeV are presented and compared with the results of theoretical calculations.

  16. The Isotopic Abundances of Magnesium in Stars

    E-Print Network [OSTI]

    Pamela Gay; David L. Lambert

    1999-11-11

    Isotopic abundance ratios 24^Mg:25^Mg:26^Mg are derived for 20 stars from high- resolution spectra of the MgH A-X 0-0 band at 5140AA. With the exception of the weak g-band giant HR 1299, the stars are dwarfs that sample the metallicity range -1.8 < [Fe/H] <0.0. The abundance of 25^Mg amd 26^Mg relative to the dominant isotope 24^Mg decreases with decreasing [Fe/H] in fair accord with predictions from a recent model of galactic chemical evolution in which the Mg isotopes are synthesised by massive stars. Several stars appear especially enriched in the heavier Mg isotopes suggesting contamination by material from the envelopes of intermediate-mass AGB stars.

  17. GEOL 715: STABLE ISOTOPE GEOCHEMISTRY (Spring, 2015)

    E-Print Network [OSTI]

    , nomenclature, standards -kinetic and equilibrium fractionation processes -mass and isotope budgets -Rayleigh in terrestrial plants and plankton -applications: carbon budgets, tracking anthropogenic CO2, carbon export rates sources, trophic levels, terrestrial vs marine sources 3. Recent advances: -mass independent fractionation

  18. The Giant Monopole Resonance in Pb isotopes

    E-Print Network [OSTI]

    Elias Khan

    2009-07-20

    The extraction of the nuclear incompressibility from the isoscalar giant monopole resonance (GMR) measurements is analysed. Both pairing and mutually enhanced magicity (MEM) effects play a role in the shift of the GMR energy between the doubly closed shell $^{208}$Pb nucleus and other Pb isotopes. Pairing effects are microscopically predicted whereas the MEM effect is phenomenologically evaluated. Accurate measurements of the GMR in open-shell Pb isotopes are called for.

  19. Environmental assessment: special isotope separation process selection

    SciTech Connect (OSTI)

    Not Available

    1986-04-01

    This Environmental Assessment (EA) evaluates the differences in potential environmental impacts between two plutonium Special Isotope Separation (SIS) technologies: Atomic Vapor Laser Isotope Separation (AVLIS) and Molecular Laser Isotope Separation (MLIS). Both SIS technologies use PuO/sub 2/ as feed; AVLIS converts feed to plutonium metal and MLIS converts feed to PuF/sub 6/. The AVLIS process uses laser energy to selectively photoionize and electrostatically separate plutonium isotopes from an atomic vapor stream. The MLIS process uses laser energy to selectively disassociate specific isotopes of plutonium in the form of PuF/sub 6/ molecules to create PuF/sub 5/ for collection and further processing. Both processes produce plutonium metal as their product. An evaluation of differences in potential environmental impacts attributed to the construction of an SIS facility, based on either technology, included a comparison of construction materials, land areas required, and the size of the design and construction workforce. The differences in potential environmental impacts from operating an SIS facility were also compared. No large differences in potential environmental impacts would be expected from the use of process chemicals. An AVLIS or an MLIS facility would produce operating effluents that would meet all applicable radiation, chemical, and hazardous waste standards and would be constructed to protect workers, the public and the environment. This EA has not revealed any significant differences in the potential environmental impacts that could occur as a result of deploying either the AVLIS or the MLIS Special Isotope Separation technology.

  20. An efficient palladium isotope chromatograph (EPIC) for hydrogen

    SciTech Connect (OSTI)

    Rutherford, W.M.

    1989-06-20

    The efficient palladium isotope chromatography (EPIC) system is based on a palladium displacement chromatograph developed and tested for the preparative scale separation of the isotopes of hydrogen. Rapid cycling and high efficiency are obtained by use of high-performance packing operating at an elevated temperature (80/degree/C) and elevated pressure (1.5 atm). The process, which was tested with a 50/50 mixture of hydrogen and deuterium, depends on the exploitation of thermally driven pressure differences to recover and recycle the mixed transition zone between the bands of the pure components and also to recover and recycle the hydrogen gas used as the displacing agent. The purity of the product is significantly enhanced by partially backfilling the column with pure deuterium at the beginning of each displacement cycle. The computer-controlled system operates continuously, and it is capable of separating 2.2 std L/hr of feed at product assays of 99.86 at. % hydrogen and 99.992 at. % deuterium. 11 refs., 5 figs., 1 tab.

  1. An ion guide laser ion source for isobar-suppressed rare isotope beams

    SciTech Connect (OSTI)

    Raeder, Sebastian Ames, Friedhelm; Bishop, Daryl; Bricault, Pierre; Kunz, Peter; Mjøs, Anders; Heggen, Henning; Institute of Applied Physics, TU Darmstadt, Schlossgartenstr. 7, 64289 Darmstadt ; Lassen, Jens Teigelhöfer, Andrea; Department of Physics and Astronomy, University of Manitoba, Winnipeg, Manitoba R3T 2N2

    2014-03-15

    Modern experiments at isotope separator on-line (ISOL) facilities like ISAC at TRIUMF often depend critically on the purity of the delivered rare isotope beams. Therefore, highly selective ion sources are essential. This article presents the development and successful on-line operation of an ion guide laser ion source (IG-LIS) for the production of ion beams free of isobaric contamination. Thermionic ions from the hot ISOL target are suppressed by an electrostatic potential barrier, while neutral radio nuclides effusing out are resonantly ionized by laser radiation within a quadrupole ion guide behind this barrier. The IG-LIS was developed through detailed thermal and ion optics simulation studies and off-line tests with stable isotopes. In a first on-line run with a SiC target a suppression of surface-ionized Na contaminants in the ion beam of up to six orders of magnitude was demonstrated.

  2. Bulk chemical and Hfâ??W isotopic consequences of incomplete accretion during planet formation

    E-Print Network [OSTI]

    Dwyer, Christina A; Nimmo, Francis; Chambers, John E

    2015-01-01

    Bulk chemical and Hf–W isotopic consequences of incompletestyle affects the bulk chemical and isotopic outcomes ofto investigate the bulk chemical and isotopic consequences

  3. COUPLING LEAD ISOTOPE ANALYSIS AND PETROGRAPHY TO CHARACTERIZE FABRICS OF STORAGE AND TRADE

    E-Print Network [OSTI]

    Claeys, Philippe

    COUPLING LEAD ISOTOPE ANALYSIS AND PETROGRAPHY TO CHARACTERIZE FABRICS OF STORAGE AND TRADE of petrography and lead isotopes within pottery provenance study. KEYWORDS: LEAD ISOTOPES, THIN SECTION, SHERD

  4. An EBIS system for rare isotope science project in Korea

    SciTech Connect (OSTI)

    Kim, Jongwon E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Han, Jae-Eun E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Son, Hyock-Jun E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Yi, Kun-Hui E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Zhao, Liangji E-mail: kim@far-tech.com; Kim, Jin-Soo E-mail: kim@far-tech.com

    2015-01-09

    An EBIS system has been designed to be used as a charge breeder for the post accelerator of an ISOL system. An electron gun, which is designed to produce a maximum current of 3 A at the beam energy of 20 kV, will be acquired from the Budker Institute, Novosibirsk. Electron beam optics calculations of the EBIS system as well as of the gun assembly have been performed using PBGUNS and TRAK. A superconducting solenoid with a maximum field of 6 T is to be used to compress the electron beam. A test stand, which includes the gun assembly and a high-power electron beam collector, is being designed and will be ready for the gun test in the end of this year. Charge breeding simulation using EBIS0D and CBSIM has been performed for a few key isotopes.

  5. TRIFID (TRansuranic Isotopic Fraction Interrogation Device): A second generation plutonium isotopic analysis system

    SciTech Connect (OSTI)

    Fleissner, J G; Coressel, T W; Freier, D A; Macklin, L L

    1989-01-01

    The TRIFID (Transuranic Isotopic Fraction Interrogation Device) system is a second generation plutonium isotopic analysis system which incorporates many new and unique features in the area of isotopic data acquisition and isotopic analysis instrument consisting of a Canberra Series 95-MCA interfaced to a Compaq 386 computer. The entire TRIFID software package, including MCA communications and isotopic analysis routines, was developed using the C programming language. Extensive use has been made of user friendly screens and menus for ease of operation and training and to facilitate use by technical level operators. Automated TRIFID features provide for MCA/ADC setup and acquisition, spectral storage, isotopic analysis, and report generation. One unique feature of the TRIFID system design allows it to be pre-programed for an entire day's counting. The isotopic analysis module (EPICS) contains an expert system formalism which is used to detect and assay for spectral interferences, and to automatically adjust peak fitting constraints based on spectral intensity variations. A TRIFID system has been in operation in a production laboratory at the Rocky Flats Plant since September 1988. Marked decreases in training and hands-on operation time have been achieved in comparison to the older, preceding isotopic systems. 2 refs., 3 figs.

  6. Resolving the stellar sources of isotopically rare presolar silicate grains through Mg and Fe isotopic analyses

    SciTech Connect (OSTI)

    Nguyen, Ann N.; Messenger, Scott, E-mail: lan-anh.n.nguyen@nasa.gov [Robert M. Walker Laboratory for Space Science, Astromaterials Research and Exploration Science Directorate, NASA Johnson Space Center, Houston, TX 77058 (United States)

    2014-04-01

    We conducted multi-element isotopic analyses of 11 presolar silicate grains from the Acfer 094 meteorite having unusual O isotopic compositions. Eight grains are {sup 18}O-rich, one is {sup 16}O-rich, and two are extremely {sup 17}O-rich. We constrained the grains' stellar sources by measuring their Si and Mg isotopic ratios, and also the {sup 54}Fe/{sup 56}Fe and {sup 57}Fe/{sup 56}Fe ratios for five grains. The Mg and Fe isotopic measurements were conducted after surrounding matrix grains were removed for more accurate ratios. Most of the {sup 18}O-rich silicates had anomalous Mg isotopic ratios, and their combined isotopic constraints are consistent with origins in low-mass Type II supernovae (SNe II) rather than high-metallicity stars. The isotopic ratios of the {sup 16}O-rich silicate are also consistent with an SN origin. Mixing small amounts of interior stellar material with the stellar envelope replicated all measured isotopic ratios except for {sup 29}Si/{sup 28}Si and {sup 54}Fe/{sup 56}Fe in some grains. The {sup 29}Si/{sup 28}Si ratios of all SN-derived grains are matched by doubling the {sup 29}Si yield in the Ne- and Si-burning zones. The {sup 54}Fe/{sup 56}Fe ratios of the grains imply elemental fractionation in the Si/S zone, or introduction of isotopically solar Fe by secondary processing. The two highly {sup 17}O-rich silicates exhibited significant {sup 25}Mg and/or {sup 26}Mg enrichments and their isotopic ratios are best explained by strong dilution of 1.15 M {sub ?} CO nova matter. We estimate that ?12% and 1% of presolar silicates have SN and nova origins, respectively, similar to presolar SiC and oxides. This implies that asymptotic giant branch stars are the dominant dust producers in the galaxy.

  7. Laser Isotope Separation Employing Condensation Repression

    SciTech Connect (OSTI)

    Eerkens, Jeff W.; Miller, William H.

    2004-09-15

    Molecular laser isotope separation (MLIS) techniques using condensation repression (CR) harvesting are reviewed and compared with atomic vapor laser isotope separation (AVLIS), gaseous diffusion (DIF), ultracentrifuges (UCF), and electromagnetic separations (EMS). Two different CR-MLIS or CRISLA (Condensation Repression Isotope Separation by Laser Activation) approaches have been under investigation at the University of Missouri (MU), one involving supersonic super-cooled free jets and dimer formation, and the other subsonic cold-wall condensation. Both employ mixtures of an isotopomer (e.g. {sup i}QF{sub 6}) and a carrier gas, operated at low temperatures and pressures. Present theories of VT relaxation, dimerization, and condensation are found to be unsatisfactory to explain/predict experimental CRISLA results. They were replaced by fundamentally new models that allow ab-initio calculation of isotope enrichments and predictions of condensation parameters for laser-excited and non-excited vapors which are in good agreement with experiment. Because of supersonic speeds, throughputs for free-jet CRISLA are a thousand times higher than cold-wall CRISLA schemes, and thus preferred for large-quantity Uranium enrichments. For small-quantity separations of (radioactive) medical isotopes, the simpler coldwall CRISLA method may be adequate.

  8. The Atomic Vapor Laser Isotope Separation Program. [Atomic Vapor Laser Isotope Separation (AVLIS) Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management's position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  9. Overview of the U.S. Department of Energy's Isotope Programs

    SciTech Connect (OSTI)

    Carty, J.

    2004-10-05

    This presentation provides an overview of the U.S. Department of Energy's Isotopes Program. The charter of the Isotope Programs covers the production and sale of radioactive and stable isotopes, associated byproducts, surplus materials, and related isotope services.

  10. Sieving hydrogen isotopes through two dimensional crystals

    E-Print Network [OSTI]

    M. Lozada-Hidalgo; S. Hu; O. Marshall; A. Mishchenko; A. N. Grigorenko; R. A. W. Dryfe; B. Radha; I. V. Grigorieva; A. K. Geim

    2015-11-20

    One-atom-thick crystals are impermeable to atoms and molecules, but hydrogen ions (thermal protons) penetrate through them. We show that monolayers of graphene and boron nitride can be used to separate hydrogen ion isotopes. Employing electrical measurements and mass spectrometry, we find that deuterons permeate through these crystals much slower than protons, resulting in a separation factor of 10 at room temperature. The isotope effect is attributed to a difference of about 60 meV between zero-point energies of incident protons and deuterons, which translates into the equivalent difference in the activation barriers posed by two dimensional crystals. In addition to providing insight into the proton transport mechanism, the demonstrated approach offers a competitive and scalable way for hydrogen isotope enrichment.

  11. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1993-01-01

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  12. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-03-30

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  13. Apparatus for separating and recovering hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

  14. Sieving hydrogen isotopes through two dimensional crystals

    E-Print Network [OSTI]

    Lozada-Hidalgo, M; Marshall, O; Mishchenko, A; Grigorenko, A N; Dryfe, R A W; Radha, B; Grigorieva, I V; Geim, A K

    2015-01-01

    One-atom-thick crystals are impermeable to atoms and molecules, but hydrogen ions (thermal protons) penetrate through them. We show that monolayers of graphene and boron nitride can be used to separate hydrogen ion isotopes. Employing electrical measurements and mass spectrometry, we find that deuterons permeate through these crystals much slower than protons, resulting in a separation factor of 10 at room temperature. The isotope effect is attributed to a difference of about 60 meV between zero-point energies of incident protons and deuterons, which translates into the equivalent difference in the activation barriers posed by two dimensional crystals. In addition to providing insight into the proton transport mechanism, the demonstrated approach offers a competitive and scalable way for hydrogen isotope enrichment.

  15. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-05-08

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

  16. Diffusion in silicon isotope heterostructures

    SciTech Connect (OSTI)

    Silvestri, Hughes Howland

    2004-05-14

    The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and {sup 28}Si enriched layers, enables the observation of {sup 30}Si self-diffusion from the natural layers into the {sup 28}Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffusion created regions of the multilayer structure that were extrinsic at the diffusion temperatures. In these regions, the Fermi level shift due to the extrinsic condition altered the concentration and charge state of the native defects involved in the diffusion process, which affected the dopant and self-diffusion. The simultaneously recorded diffusion profiles enabled the modeling of the coupled dopant and self-diffusion. From the modeling of the simultaneous diffusion, the dopant diffusion mechanisms, the native defect charge states, and the self- and dopant diffusion coefficients can be determined. This information is necessary to enhance the physical modeling of dopant diffusion in Si. It is of particular interest to the modeling of future electronic Si devices, where the nanometer-scale features have created the need for precise physical models of atomic diffusion in Si. The modeling of the experimental profiles of simultaneous diffusion of B and Si under p-type extrinsic conditions revealed that both species are mediated by neutral and singly, positively charged Si self-interstitials. The diffusion of As and Si under extrinsic n-type conditions yielded a model consisting of the interstitialcy and vacancy mechanisms of diffusion via singly negatively charged self-interstitials and neutral vacancies. The simultaneous diffusion of P and Si has been modeled on the basis of neutral and singly negatively charged self-interstitials and neutral and singly positively charged P species. Additionally, the temperature dependence of the diffusion coefficient of Si in Ge was measured over the temperature range of 550 C to 900 C using a buried Si layer in an epitaxially grown Ge layer.

  17. PHYSICAL, MAGNETIC, SEDIMENTOLOGICAL, GEOCHEMICAL, ISOTOPIC AND MICROPALEONTOLOGICAL FEATURES OF RAPIDLY DEPOSITED

    E-Print Network [OSTI]

    PHYSICAL, MAGNETIC, SEDIMENTOLOGICAL, GEOCHEMICAL, ISOTOPIC AND MICROPALEONTOLOGICAL FEATURES Sediments, Québec City. Symposium preceedings: 103-108. ABSTRACT: Sedimentological, geochemical, isotopic

  18. Heavy metals and lead isotopes in sdB stars

    E-Print Network [OSTI]

    S. O'Toole; U. Heber

    2006-12-19

    We present a detailed abundance analysis of high-resolution ultraviolet echelle spectra of five subdwarf B stars obtained with HST-STIS The goal of our observations was to test the hypothesis that pulsations in sdBs are correlated to the surface abundances of iron-group elements. We study two pulsators and three non-pulsators and determined abundances for 25 elements including the iron group and even heavier elements such as tin and lead using LTE spectrum synthesis techniques. We find strong enrichments of heavy elements up to 2.9dex with respect to solar which are probably caused by atomic diffusion processes. No clear-cut correlation between pulsations and metal abundances becomes apparent. Abundances for lead isotopes are derived from very high resolution spectra using an UV line of triply ionised lead. As Pb terminates the s-process sequence Pb isotopic abundance ratios yield important constraints. It is very difficult to measure them in hot stars. For the first time we were able to measure them in two subluminous B stars and conclude that the 207Pb/208Pb is solar.

  19. Method for production of an isotopically enriched compound

    DOE Patents [OSTI]

    Watrous, Matthew G.

    2012-12-11

    A method is presented for producing and isolating an isotopically enriched compound of a desired isotope from a parent radionuclide. The method includes forming, or placing, a precipitate containing a parent radionuclide of the desired daughter isotope in a first reaction zone and allowing sufficient time for the parent to decay into the desired gaseous daughter radioisotope. The method further contemplates collecting the desired daughter isotope as a solid in a second reaction zone through the application of temperatures below the freezing point of the desired isotope to a second reaction zone that is connected to the first reaction zone. Specifically, a method is presented for producing isotopically enriched compounds of xenon, including the radioactive isotope Xe-131m and the stable isotope Xe-131.

  20. Isotope and Temperature Effects in Liquid Water Probed by Soft...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Wednesday, 24 September 2008 00:00...

  1. Oxygen isotope records of carboniferous seasonality on the Russian platform 

    E-Print Network [OSTI]

    Wang, Huayu

    1998-01-01

    Seven isotopic and eight trace element (TE) profiles across shell growth lines are presented, based on over 1000 stable isotope and electron microprobe analyses on six brachiopod shells (Gigantoproductus), to quantify seasonal temperature change...

  2. Physiology of multiple sulfur isotope fractionation during microbial sulfate reduction

    E-Print Network [OSTI]

    Sim, Min Sub

    2012-01-01

    Microbial sulfate reduction (MSR) utilizes sulfate as an electron acceptor and produces sulfide that is depleted in heavy isotopes of sulfur relative to starting sulfate. The fractionation of S-isotopes is commonly used ...

  3. Hydrogen isotope fractionation during lipid biosynthesis by Haloarcula marismortui

    E-Print Network [OSTI]

    Hydrogen isotope fractionation during lipid biosynthesis by Haloarcula marismortui Sitindra S studied the controls on the fractionation of hydrogen isotopes during lipid biosynthesis by Haloarcula marismortui, a halophilic archaea, in pure culture experiments by varying organic substrate, the hydrogen

  4. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  5. Coherent photonuclear reactions for isotope transmutation

    E-Print Network [OSTI]

    H. Ejiri; S. Date

    2011-02-22

    Coherent photonuclear isotope transmutation (CPIT) produces exclusively radioactive isotopes (RIs) by coherent photonuclear reactions via E1 giant resonances. Photons to be used are medium energy photons produced by laser photons backscattered off GeV electrons. The cross sections are as large as 0.2 - 0.6 b, being independent of individual nuclides. A large fraction of photons is effectively used for the photonuclear reactions, while the scattered GeV electrons remain in the storage ring to be re-used. CPIT with medium energy photons provides specific/desired RIs with the high rate and the high density for nuclear science, molecular biology and for nuclear medicines.

  6. Stable carbon and nitrogen isotope enrichment in primate tissues

    E-Print Network [OSTI]

    Crowley, Brooke E.; Carter, Melinda L.; Karpanty, Sarah M.; Zihlman, Adrienne L.; Koch, Paul L.; Dominy, Nathaniel J.

    2010-01-01

    of sample treatment and diagenesis on the isotopic integrityHare PE (1986) Effects of diagenesis on strontium, carbon,

  7. Discovery of palladium, antimony, tellurium, iodine, and xenon isotopes

    E-Print Network [OSTI]

    J. Kathawa; C. Fry; M. Thoennessen

    2012-01-20

    Currently, thirty-eight palladium, thirty-eight antimony, thirty-nine tellurium, thirty-eight iodine, and forty xenon isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  8. Discovery of palladium, antimony, tellurium, iodine, and xenon isotopes

    SciTech Connect (OSTI)

    Kathawa, J.; Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-01-15

    Currently, thirty-eight palladium, thirty-eight antimony, thirty-nine tellurium, thirty-eight iodine, and forty xenon isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  9. Discovery of Cesium, Lanthanum, Praseodymium and Promethium Isotopes

    E-Print Network [OSTI]

    E. May; M. Thoennessen

    2011-09-08

    Currently, forty-one cesium, thirty-five lanthanum, thirty-two praseodymium, and thirty-one promethium, isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  10. Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila

    E-Print Network [OSTI]

    Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila Sitindra S Accepted 7 September 2013 Available online 16 September 2013 a b s t r a c t Hydrogen isotope ratio values from recording the hydrogen isotope composition of ambient water, dD values of lipids also depend

  11. Discovery of Gallium, Germanium, Lutetium, and Hafnium Isotopes

    E-Print Network [OSTI]

    Gross, J L

    2011-01-01

    Currently, twenty-eight gallium, thirty-one germanium, thirty-five lutetium, and thirty-six hafnium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  12. Discovery of Gallium, Germanium, Lutetium, and Hafnium Isotopes

    E-Print Network [OSTI]

    J. L. Gross; M. Thoennessen

    2011-09-28

    Currently, twenty-eight gallium, thirty-one germanium, thirty-five lutetium, and thirty-six hafnium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  13. Discovery of the actinium, thorium, protactinium, and uranium isotopes

    E-Print Network [OSTI]

    C. Fry; M. Thoennessen

    2012-03-06

    Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  14. Evidence of magnetic isotope effects during thermochemical sulfate reduction

    E-Print Network [OSTI]

    Kaufman, Alan Jay

    such as adsorption of S-bearing com- pounds on surfaces of solids (13). Magnetic isotope effects are expressedEvidence of magnetic isotope effects during thermochemical sulfate reduction Harry Oduroa,b,1 S are attributed to a magnetic isotope effect (MIE) associated with the formation of thiol-disulfide, ion

  15. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    A. Nystrom; M. Thoennessen

    2011-02-11

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  16. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    Nystrom, A

    2011-01-01

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  17. E.L. Grossman Chapter 10 Oxygen Isotope Stratigraphy

    E-Print Network [OSTI]

    Grossman, Ethan L.

    E.L. Grossman Chapter 10 Oxygen Isotope Stratigraphy Abstract:Variations in the 18 O/16 O ratios isotope stratigraphy, however, is hampered by the lack of unaltered authigenic marine sediments. Chapter.6. Oxygen Isotope Stratigraphy 188 10.6.1. Cenozoic 188 10.6.2. Mesozoic 191 10.6.3. Paleozoic 193

  18. Discovery of Samarium, Europium, Gadolinium, and Terbium Isotopes

    E-Print Network [OSTI]

    E. May; M. Thoennessen

    2012-01-19

    Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  19. Discovery of the astatine, radon, francium, and radium isotopes

    E-Print Network [OSTI]

    C. Fry; M. Thoennessen

    2012-05-26

    Currently, thirty-nine astatine, thirty-nine radon, thirty-five francium, and thirty-four radium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  20. Discovery of the thallium, lead, bismuth, and polonium isotopes

    E-Print Network [OSTI]

    C. Fry; M. Thoennessen

    2012-01-21

    Currently, forty-two thallium, forty-two lead, forty-one bismuth, and forty-two polonium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  1. Discovery of dysprosium, holmium, erbium, thulium and ytterbium isotopes

    E-Print Network [OSTI]

    C. Fry; M. Thoennessen

    2012-05-26

    Currently, 31 dysprosium, 32 holmium, 32 erbium, 33 thulium and 31 ytterbium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  2. Discovery of Tantalum, Rhenium, Osmium, and Iridium Isotopes

    E-Print Network [OSTI]

    R. Robinson; M. Thoennessen

    2011-09-02

    Currently, thirty-eight tantalum, thirty-eight rhenium, thirty-nine osmium, and thirty-eight iridium, isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  3. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  4. Laser Isotope Enrichment for Medical and Industrial Applications

    SciTech Connect (OSTI)

    Leonard Bond

    2006-07-01

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for irradiation to produce medical radioisotopes. 2) Pure isotopes for semiconductors. 3) Low neutron capture isotopes for various uses in nuclear reactors. 4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old ”calutrons” (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation repression. In this scheme a gas, of the selected isotopes for enrichment, is irradiated with a laser at a particular wavelength that would excite only one of the isotopes. The entire gas is subject to low temperatures sufficient to cause condensation on a cold surface. Those molecules in the gas that the laser excited are not as likely to condense as are the unexcited molecules. Hence the gas drawn out of the system will be enriched in the isotope that was excited by the laser. We have evaluated the relative energy required in this process if applied on a commercial scale. We estimate the energy required for laser isotope enrichment is about 20% of that required in centrifuge separations, and 2% of that required by use of "calutrons".

  5. Radioactive isotopes in Danish drinking water

    E-Print Network [OSTI]

    Radioactive isotopes in Danish drinking water Sven P. Nielsen Risø National Laboratory Working OF INVESTIGATION 11 3 DESCRIPTION OF INVESTIGATION 12 4 RADIOACTIVITY IN DRINKING WATER 13 5 SAMPLING 15 6 27 #12;4 #12;5 Preface This project for investigation of radioactivity in drinking water shall

  6. Water isotopes and the general circulation

    E-Print Network [OSTI]

    Noone, David

    quantities are equator to pole temperature gradient, and the vertical thermal stratification #12;Isotopic" is the fractionation factor is a function of temperature F depends on large scale circulation and thermal state Both, temperature gradient/condensation) 2. Entrainment of non-depleted water (humidity, stratification/sheer) #12

  7. INTRODUCTION The oxygen isotopic compositions of minerals

    E-Print Network [OSTI]

    González, Luis A.

    .5 ka) and the associated migration of prairie into and out of the area (the prairie period; Dorale et of the Gulf of Mexico, Pacific, andArctic air masses (Bryson, 1966; Fig. 1). Gulf of Mexico air sup- plies of Mexico air masses and its precipitation is isotopically more negative than gulf moisture (e.g., typically

  8. NEST-GENERATION TCAP HYDROGEN ISOTOPE SEPARATION PROCESS

    SciTech Connect (OSTI)

    Heung, L; Henry Sessions, H; Anita Poore, A; William Jacobs, W; Christopher Williams, C

    2007-08-07

    A thermal cycling absorption process (TCAP) for hydrogen isotope separation has been in operation at Savannah River Site since 1994. The process uses a hot/cold nitrogen system to cycle the temperature of the separation column. The hot/cold nitrogen system requires the use of large compressors, heat exchanges, valves and piping that is bulky and maintenance intensive. A new compact thermal cycling (CTC) design has recently been developed. This new design uses liquid nitrogen tubes and electric heaters to heat and cool the column directly so that the bulky hot/cold nitrogen system can be eliminated. This CTC design is simple and is easy to implement, and will be the next generation TCAP system at SRS. A twelve-meter column has been fabricated and installed in the laboratory to demonstrate its performance. The design of the system and its test results to date is discussed.

  9. Non-canonical mass laws in equilibrium isotopic fractionations: Evidence from the vapor pressure isotope effect of SF6

    E-Print Network [OSTI]

    Cartigny, Pierre

    Non-canonical mass laws in equilibrium isotopic fractionations: Evidence from the vapor pressure report experimental observations of the vapor pressure isotope effect, including 33 S/32 S and 34 S/32. That equilibrium involves a reversed vapor pressure isotope effect; i.e., vapor is between 2& and 3& higher in 34 S

  10. Strontium-isotope stratigraphy of Enewetak Atoll

    SciTech Connect (OSTI)

    Ludwig, K.R.; Halley, R.B.; Simmons, K.R.; Peterman, Z.E.

    1988-02-01

    /sup 87/Sr//sup 86/Sr ratios determined for samples from a 350 m core of Neogene lagoonal, shallow-water limestones from Enewetak Atoll display a remarkably informative trend. Like the recently published data for Deep Sea Drilling Project (DSDP) carbonates, /sup 87/Sr//sup 86/Sr at Enewetak increases monotonically but not smoothly from the early Miocene to the Pleistocene. The data show intervals of little or no change in /sup 87/Sr//sup 86/Sr, punctuated by sharp transitions to lower values toward greater core depths. The sharp transitions correlate with observed solution disconformities caused by periods of subaerial erosion, whereas the intervals of little or no change in /sup 87/Sr//sup 86/Sr correspond to intervals of rapid accumulation of shallow-water carbonate sediments. When converted to numerical ages using the published DSDP 590B trend, the best-resolved time breaks are at 282 m (12.3 to 18.2 Ma missing) and 121.6 m (3.0 to 5.3 Ma missing) below the lagoon floor. At Enewetak, Sr isotopes offer a stratigraphic resolution for these shallow-marine Neogene carbonates comparable to that of nannofossil zonation in deep-sea carbonates (0.3-3 m.y.). In addition, the correlation of times of Sr-isotope breaks at Enewetak with times of rapid Sr-isotope change in the DSDP 590B samples confirms the importance of sea-level changes in the evolution of global-marine Sr isotopes and shows that the Sr-isotope response to sea-level falls is rapid.

  11. Enriching stable isotopes: Alternative use for Urenco technology

    SciTech Connect (OSTI)

    Rakhorst, H.; de Jong, P.G.T.; Dawson, P.D.

    1996-12-31

    The International Urenco Group utilizes a technologically advanced centrifuge process to enrich uranium in the fissionable isotope {sup 235}U. The group operates plants in the United Kingdom, the Netherlands, and Germany and currently holds a 10% share of the multibillion dollar world enrichment market. In the early 1990s, Urenco embarked on a strategy of building on the company`s uniquely advanced centrifuge process and laser isotope separation (LIS) experience to enrich nonradioactive isotopes colloquially known as stable isotopes. This paper summarizes the present status of Urenco`s stable isotopes business.

  12. Geochemistry And Geothermometry Of Spring Water From The Blackfoot...

    Open Energy Info (EERE)

    high-angle normal faults of Tertiary to Holocene age appear to be the dominant structural control of spring activity. Surface spring-water temperatures average 14C except for a...

  13. Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward...

    Open Energy Info (EERE)

    Area. References S. H. Ward, W. T. Parry, W. P. Nash, W. R. Sill, K. L. Cook, R. B. Smith, D. S. Chapman, F. H. Brown, J. A. Whelan, J. R. Bowman (1978) A Summary of the...

  14. Geothermometry At Long Valley Caldera Geothermal Area (Sorey...

    Open Energy Info (EERE)

    studies, and seem to prove useful in most cases (Flexser, 1991; Goff et al., 1991; Smith and Suemnicht, 1991). Results from these studies are also summarized in Sorey et al....

  15. Geothermometry At Long Valley Caldera Geothermal Area (McKenzie...

    Open Energy Info (EERE)

    resin. The resin was treated with 100 mL of 0.5 M sodium chloride in order to remove barium sulfate, which was precipitated by standard gravimetric methods, dried, and then...

  16. Geothermometry At Akutan Fumaroles Area (Kolker, Et Al., 2010) | Open

    Open Energy Info (EERE)

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  17. Geothermometry At Blackfoot Reservoir Area (Hutsinpiller & Parry, 1985) |

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpen Energy Information

  18. Geothermometry At Blue Mountain Geothermal Area (Casteel, Et Al., 2010) |

    Open Energy Info (EERE)

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  19. Geothermometry At Buffalo Valley Hot Springs Area (Laney, 2005) | Open

    Open Energy Info (EERE)

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  20. Geothermometry At Central Nevada Seismic Zone Region (Laney, 2005) | Open

    Open Energy Info (EERE)

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  1. Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpen EnergyEnergyRocher, 2005) |

  2. Geothermometry At Chena Geothermal Area (Kolker, 2008) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpen EnergyEnergyRocher, 2005)

  3. Geothermometry At Coso Geothermal Area (1978) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpen

  4. Geothermometry At Fort Bliss Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpenFish Lake Valley Area

  5. Geothermometry At Hot Springs Ranch Area (Szybinski, 2006) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpenFish Lake Valley

  6. Geothermometry At Kawaihae Area (Thomas, 1986) | Open Energy Information

    Open Energy Info (EERE)

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  7. Geothermometry At Kilauea East Rift Geothermal Area (Thomas, 1986) | Open

    Open Energy Info (EERE)

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  8. Geothermometry At Lahaina-Kaanapali Area (Thomas, 1986) | Open Energy

    Open Energy Info (EERE)

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  9. Geothermometry At Lassen Volcanic National Park Area (Janik & Mclaren,

    Open Energy Info (EERE)

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  10. Geothermometry At Lassen Volcanic National Park Area (Thompson, 1985) |

    Open Energy Info (EERE)

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  11. Geothermometry At Long Valley Caldera Geothermal Area (Mariner & Willey,

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpenFishOpen Energy1976) | Open

  12. Geothermometry At Lualualei Valley Area (Thomas, 1986) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpenFishOpen Energy1976) ||

  13. Geothermometry At New River Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore TechnologiesAssessmentOpenFishOpen Energy1976)|

  14. Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward, Et Al.,

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:BoreOpen Energy Information Shevenell & De1978) |

  15. Geothermometry At The Needles Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

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  16. Geothermometry At Yellowstone Region (Fournier, 1979) | Open Energy

    Open Energy Info (EERE)

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  17. Geochemistry And Geothermometry Of Spring Water From The Blackfoot

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdistoWhiskeyFootprintGEXAGemini SolarMichigan:Region,Reservoir Region,

  18. Geothermometry At Alum Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages RecentPlant < Geothermal(Redirected from PowerWaterAlum

  19. Geothermometry At Coso Geothermal Area (1980) | Open Energy Information

    Open Energy Info (EERE)

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  20. Geothermometry At Raft River Geothermal Area (1980) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages RecentPlant < Geothermal(Redirected2008) | Open

  1. Geothermometry At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages RecentPlant <Silver Peak Area (DOE GTP) Jump to:

  2. Colorado thermal spring water geothermometry (public dataset) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures Jump to: navigation,EnergyColoradoBank

  3. Improved Geothermometry Through Multivariate Reaction Path Modeling and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingREnergy ToolsCoordination BetweenImplementation

  4. Separation Of Uranium And Plutonium Isotopes For Measurement By Multi Collector Inductively Coupled Plasma Mass Spectroscopy

    SciTech Connect (OSTI)

    Martinelli, R E; Hamilton, T F; Williams, R W; Kehl, S R

    2009-03-29

    Uranium (U) and plutonium (Pu) isotopes in coral soils, contaminated by nuclear weapons testing in the northern Marshall Islands, were isolated by ion-exchange chromatography and analyzed by mass spectrometry. The soil samples were spiked with {sup 233}U and {sup 242}Pu tracers, dissolved in minerals acids, and U and Pu isotopes isolated and purified on commercially available ion-exchange columns. The ion-exchange technique employed a TEVA{reg_sign} column coupled to a UTEVA{reg_sign} column. U and Pu isotope fractions were then further isolated using separate elution schemes, and the purified fractions containing U and Pu isotopes analyzed sequentially using multi-collector inductively coupled plasma mass spectrometer (MCICP-MS). High precision measurements of {sup 234}U/{sup 235}U, {sup 238}U/{sup 235}U, {sup 236}U/{sup 235}U, and {sup 240}Pu/{sup 239}Pu in soil samples were attained using the described methodology and instrumentation, and provide a basis for conducting more detailed assessments of the behavior and transfer of uranium and plutonium in the environment.

  5. Method of preparing mercury with an arbitrary isotopic distribution

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1986-12-16

    This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg[sub 2]Cl[sub 2], corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H[sub 2]O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H[sub 2]O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered. 1 fig.

  6. Evaluation of selected ex-reactor accidents related to the tritium and medical isotope production mission at the FFTF

    SciTech Connect (OSTI)

    Himes, D.A.

    1997-11-17

    The Fast Flux Test Facility (FFTF) has been proposed as a production facility for tritium and medical isotopes. A range of postulated accidents related to ex-reactor irradiated fuel and target handling were identified and evaluated using new source terms for the higher fuel enrichment and for the tritium and medical isotope targets. In addition, two in-containment sodium spill accidents were re-evaluated to estimate effects of increased fuel enrichment and the presence of the Rapid Retrieval System. Radiological and toxicological consequences of the analyzed accidents were found to be well within applicable risk guidelines.

  7. Regioselective synthesis using the deuterium isotope effect

    SciTech Connect (OSTI)

    Miyano, M.

    1981-04-24

    Dehydration of 1a by various procedures invariably produced more exo olefin 2a than endo olefin 3a. This could be reversed by introduction of deuterium in the Me-21 group of the starting material. Thus, dehydration of 1b could afford more endo olefin 3b than exo olefin 2b due to the deuterium isotope effect. A regioselective synthesis of 18-oxoprogesterone (15a) from 3..beta..-hydroxypregn-5-en-20-one (5a) was carried out taking advantage of the deuterium isotope effect as depicted in Scheme I. The key steps were dehydration of 7b to predominantly endo olefin 9b and removal of the deuteriums from 18-oxoprogesterone-17..cap alpha..,21,21,21-d/sub 4/ (15b) to give 15a.

  8. Hydrogen isotopic exchange over palladium metal

    SciTech Connect (OSTI)

    Carstens, D.H.W.; Encinias, P.D.

    1990-01-01

    We have recently developed the laser-Raman technique as a means of unambiguously measuring the partial pressures of all possible hydrogen isotopes in the gas phase. Using this technique we have investigated the hydrogen-deuterium exchange in a number of metals. This report presents detailed data for isotopic exchange in the palladium hydride system over the temperature range 26{degree}C to -100{degree}C at a pressure of 7 atm. First order kinetic rate constants and activation energies are summarized for the forward (hydride to deuteride) and reverse (deuteride to hydride) exchange processes. In addition, we have found that small amounts (100 ppm) of impurities in the exchange gases considerably slow the exchange kinetics with the effect increasing down the series CH{sub 4}, CO{sub 2}, H{sub 2}O, and CO. 9 refs., 4 figs., 1 tab.

  9. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  10. First AID (Atom counting for Isotopic Determination).

    SciTech Connect (OSTI)

    Roach, J. L. (Jeffrey L.); Israel, K. M. (Kimberly M.); Steiner, R. E. (Robert E.); Duffy, C. J. (Clarence J.); Roench, F. R. (Fred R.)

    2002-01-01

    Los Alamos National Laboratory (LANL) has established an in vitro bioassay monitoring program in compliance with the requirements in the Code of Federal Regulations, 10 CFR 835, Occupational Radiation Protection. One aspect of this program involves monitoring plutonium levels in at-risk workers. High-risk workers are monitored using the ultra-sensitive Therrnal Ionization Mass Spectrometry (TIMS) technique to ensure compliance with DOE standards. TIMS is used to measure atom ratios of 239Pua nd 240Puw ith respect to a tracer isotope ('Pu). These ratios are then used to calculate the amount of 239Pu and 240Pup resent. This low-level atom counting technique allows the calculation of the concentration levels of 239Pu and 240Pu in urine for at risk workers. From these concentration levels, dose assessments can be made and worker exposure levels can be monitored. Detection limits for TIMS analysis are on the order of millions of atoms, which translates to activity levels of 150 aCi 239Pua nd 500 aCi for 240Pu. pCi for Our poster presentation will discuss the ultra-sensitive, low-level analytical technique used to measure plutonium isotopes and the data verification methods used for validating isotopic measurements.

  11. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  12. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  13. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  14. Estimates of Radioxenon Released from Southern Hemisphere Medical isotope Production Facilities Using Measured Air Concentrations and Atmospheric Transport Modeling

    SciTech Connect (OSTI)

    Eslinger, Paul W.; Friese, Judah I.; Lowrey, Justin D.; McIntyre, Justin I.; Miley, Harry S.; Schrom, Brian T.

    2014-09-01

    Abstract The International Monitoring System (IMS) of the Comprehensive-Nuclear-Test-Ban-Treaty monitors the atmosphere for radioactive xenon leaking from underground nuclear explosions. Emissions from medical isotope production represent a challenging background signal when determining whether measured radioxenon in the atmosphere is associated with a nuclear explosion prohibited by the treaty. The Australian Nuclear Science and Technology Organisation (ANSTO) operates a reactor and medical isotope production facility in Lucas Heights, Australia. This study uses two years of release data from the ANSTO medical isotope production facility and Xe-133 data from three IMS sampling locations to estimate the annual releases of Xe-133 from medical isotope production facilities in Argentina, South Africa, and Indonesia. Atmospheric dilution factors derived from a global atmospheric transport model were used in an optimization scheme to estimate annual release values by facility. The annual releases of about 6.8×1014 Bq from the ANSTO medical isotope production facility are in good agreement with the sampled concentrations at these three IMS sampling locations. Annual release estimates for the facility in South Africa vary from 1.2×1016 to 2.5×1016 Bq and estimates for the facility in Indonesia vary from 6.1×1013 to 3.6×1014 Bq. Although some releases from the facility in Argentina may reach these IMS sampling locations, the solution to the objective function is insensitive to the magnitude of those releases.

  15. Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collister, R.; Gwinner, G.; Tandecki, M.; Behr, J. A.; Pearson, M. R.; Zhang, J.; Orozco, L. A.; Aubin, S.; Gomez, E.; FrPNC Collaboration

    2014-11-07

    We present the isotope shifts of the 7s1/2 to 7p1/2 transition for francium isotopes ²???²¹³Fr with reference to ²²¹Fr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s1/2 to 7p3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D? and D? transitions, of sufficient precision to differentiate between ab initio calculations.

  16. Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collister, R.; Gwinner, G.; Tandecki, M.; Behr, J. A.; Pearson, M. R.; Zhang, J.; Orozco, L. A.; Aubin, S.; Gomez, E.; FrPNC Collaboration

    2014-11-01

    We present the isotope shifts of the 7s1/2 to 7p1/2 transition for francium isotopes ²???²¹³Fr with reference to ²²¹Fr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s1/2 to 7p3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D? and D? transitions, of sufficient precision to differentiate between ab initio calculations.

  17. Sustainability of gamma-ray isotopics evaluation codes

    SciTech Connect (OSTI)

    Vo, Duc [Los Alamos National Laboratory; Koskelo, Markku [AQUILA TECHNOLOGIES; Mcginnis, Brent [ORNL; Wang, Tzu - Feng [LLNL; Peerani, Paolo [IPSC, ISPRA, ITALY; Renha, Geraldo [ABACC, BRAZIL; Dias, Fabio C [NECB, BRAZIL

    2010-01-01

    In November 2005, the international workshop 'Gamma Evaluation Codes for Plutonium and Uranium Isotope Abundance Measurements by High-Resolution Gamma Spectrometry: Current Status and Future Challenges' was held in Karlsruhe, Germany. Some of the main issues discussed during the November 2005 meeting were related to concerns voiced by international inspectorate authorities such as the International Atomic Energy Agency (IAEA), the European Atomic Energy Community (EURATOM), and the Brazilian-Argentine Agency for Accounting and Control of Nuclear Materials (ABACC) about the standardization and sustainability of gamma-ray isotopic analysis codes that are commonly used during safeguards inspections. A follow-up international workshop was conducted in Oak Ridge, TN in 2008. This workshop was in response to needs expressed by the international safeguards community during the Karlsruhe meeting and recommendations made under Action Sheet 14; a cooperative effort between the U. S. Department of Energy and ABACC. The purpose of the Oak Ridge workshop was to bring code developers and end users together to better understand the capabilities and limitations of the codes; to discuss mechanisms to ensure these codes are sustained and quality tested; and to ensure updates or revisions are performed in a controlled manner. During an Action Sheet 14 meeting held in Rio de Janeiro, Brazil in which the IAEA and EURATOM participated as observers, and in subsequent meetings of the European Safeguards Research and Development Association (ESARDA), all parties agreed that the regional working group initially established under the DOE/ABACC cooperation should be expanded to an international working group. The purpose of the international working group is to provide a forum to exchange information, discuss technical developments, and validate and test the various codes. However, progress to formally establish the working has been slowed by a lack of dedicated funding and competing priorities within the various international organizations. Recently, the ESARDA Nondestructive Assay Working Group established a dedicated website for the International Working Group on Gamma Spectrometry Techniques (1 WG-GST). In this paper, we will explore specific steps that should be taken to strengthen this working group's ability to affect development of a common testing platform and address concerns regarding applicability, sustainability and version control for these important codes.

  18. System and method for high precision isotope ratio destructive analysis

    SciTech Connect (OSTI)

    Bushaw, Bruce A; Anheier, Norman C; Phillips, Jon R

    2013-07-02

    A system and process are disclosed that provide high accuracy and high precision destructive analysis measurements for isotope ratio determination of relative isotope abundance distributions in liquids, solids, and particulate samples. The invention utilizes a collinear probe beam to interrogate a laser ablated plume. This invention provides enhanced single-shot detection sensitivity approaching the femtogram range, and isotope ratios that can be determined at approximately 1% or better precision and accuracy (relative standard deviation).

  19. Thermal neutron capture cross sections of tellurium isotopes

    SciTech Connect (OSTI)

    Tomandl, I.; Honzatko, J.; von Egidy, T.; Wirth, H.-F.; Belgya, T.; Lakatos, M.; Szentmiklosi, L.; Revay, Zs.; Molnar, G.L.; Firestone, R.B.; Bondarenko, V.

    2004-03-01

    New values for thermal neutron capture cross sections of the tellurium isotopes 122Te, 124Te, 125Te, 126Te, 128Te, and 130Te are reported. These values are based on a combination of newly determined partial g-ray cross sections obtained from experiments on targets contained natural Te and gamma intensities per capture of individual Te isotopes. Isomeric ratios for the thermal neutron capture on the even tellurium isotopes are also given.

  20. Early Onset of Ground State Deformation in Neutron Deficient Polonium Isotopes

    SciTech Connect (OSTI)

    Cocolios, T. E.; Van de Walle, J.; Dexters, W.; Bastin, B.; Buescher, J.; Darby, I. G.; Huyse, M.; Keupers, M.; Kudryavtsev, Yu.; Van Duppen, P.; Seliverstov, M. D.; Andreyev, A. N.; Antalic, S.; Barzakh, A. E.; Fedorov, D. V.; Molkanov, P. L.; Fedosseyev, V. N.; Marsh, B. A.; Flanagan, K. T.; Franchoo, S.

    2011-02-04

    In-source resonant ionization laser spectroscopy of the even-A polonium isotopes {sup 192-210,216,218}Po has been performed using the 6p{sup 3}7s {sup 5}S{sub 2} to 6p{sup 3}7p {sup 5}P{sub 2} ({lambda}=843.38 nm) transition in the polonium atom (Po-I) at the CERN ISOLDE facility. The comparison of the measured isotope shifts in {sup 200-210}Po with a previous data set allows us to test for the first time recent large-scale atomic calculations that are essential to extract the changes in the mean-square charge radius of the atomic nucleus. When going to lighter masses, a surprisingly large and early departure from sphericity is observed, which is only partly reproduced by beyond mean field calculations.

  1. LANL/Green Star spectrometer tests

    SciTech Connect (OSTI)

    Sampson, T.E.; Cremers, T.L.; Vo, D.T. [Los Alamos National Lab., NM (United States); Seldiakov, Y.P.; Dorin, A.B.; Kondrashov, M.V. [Green Star, Moscow (Russian Federation); Timoshin, V.I. [VNIINM, Moscow (Russian Federation)

    1997-12-01

    The US and Russia have agreed to the joint development of a nondestructive assay system for use to support the dismantlement of nuclear weapons in Russia. This nondestructive assay system will be used to measure plutonium produced by the conversion of Russian nuclear weapons. The NDA system for Russia will be patterned after the ARIES NDA system being constructed at Los Alamos. One goal of the program is to produce an NDA system for use in Russia that maximizes the use of Russian resources to facilitate maintenance and future upgrades. The Green Star SBS50 Single Board Spectrometer system (Green Star Ltd., Moscow, Russia) has been suggested for use as the data acquisition component for gamma ray instruments in the system. Possible uses are for plutonium isotopic analysis and also segmented gamma scanning. Green Star has also developed analysis software for the SBS50. This software, both plutonium isotopic analysis and uranium enrichment analysis, was developed specifically for customs/border inspection applications (low counting rate applications and identification as opposed to quantification) and was not intended for MC and A applications. Because of the relative immaturity of the Green Star plutonium isotopic analysis software (it has been under development for only one year and is patterned after US development circa 1980), it was tentatively agreed, before the tests, that the Russian NDA system would use the Los Alamos PC/FRAM software for plutonium isotopic analysis. However, it was also decided to include the Green Star plutonium isotopic software in the testing, both to quantify its performance for MC and A applications and also to provide additional data to Green Star for further development of their software. The main purpose of the testing was to evaluate the SBS-50 spectrometer as a data acquisition device for use with LANL software.

  2. High Flux Isotope Reactor system RELAP5 input model

    SciTech Connect (OSTI)

    Morris, D.G.; Wendel, M.W.

    1993-01-01

    A thermal-hydraulic computational model of the High Flux Isotope Reactor (HFIR) has been developed using the RELAP5 program. The purpose of the model is to provide a state-of-the art thermal-hydraulic simulation tool for analyzing selected hypothetical accident scenarios for a revised HFIR Safety Analysis Report (SAR). The model includes (1) a detailed representation of the reactor core and other vessel components, (2) three heat exchanger/pump cells, (3) pressurizing pumps and letdown valves, and (4) secondary coolant system (with less detail than the primary system). Data from HFIR operation, component tests, tests in facility mockups and the HFIR, HFIR specific experiments, and other pertinent experiments performed independent of HFIR were used to construct the model and validate it to the extent permitted by the data. The detailed version of the model has been used to simulate loss-of-coolant accidents (LOCAs), while the abbreviated version has been developed for the operational transients that allow use of a less detailed nodalization. Analysis of station blackout with core long-term decay heat removal via natural convection has been performed using the core and vessel portions of the detailed model.

  3. Isotopic Analysis- Fluid At Dixie Valley Geothermal Area (Kennedy...

    Open Energy Info (EERE)

    this study was to investigate the relationship between known geothermal resources with deep, fault hosted permeable fluid flow pathways and the helium Isotopic composition of the...

  4. Hydrogeological And Isotopic Survey Of Geothermal Fields In The...

    Open Energy Info (EERE)

    Hydrogeological And Isotopic Survey Of Geothermal Fields In The Buyuk Menderes Graben, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  5. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    Isotopic Analysis- Rock Activity Date - 2004 Usefulness useful regional reconnaissance DOE-funding Unknown Exploration Basis The study was undertaken to refine understanding of...

  6. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area...

    Open Energy Info (EERE)

    Area Exploration Technique Isotopic Analysis- Rock Activity Date Usefulness not indicated DOE-funding Unknown References Hisatoshi Ito, Kazuhiro Tanaka (1995) Insights On The...

  7. Isotopic Analysis- Rock At Kilauea East Rift Geothermal Area...

    Open Energy Info (EERE)

    Technique Isotopic Analysis- Rock Activity Date 1989 - 2000 Usefulness not indicated DOE-funding Unknown Exploration Basis The purpose of this study was to analyze deep core...

  8. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    Isotopic Analysis- Rock Activity Date - 2004 Usefulness useful regional reconnaissance DOE-funding Unknown Exploration Basis The study was undertaken to refine understanding of...

  9. Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...

    Open Energy Info (EERE)

    Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope Compositions of Dissolved Sulfate and Water from Hot Springs and Shallow Drillholes Jump to: navigation, search...

  10. Geothermal reservoir temperatures estimated from the oxygen isotope...

    Open Energy Info (EERE)

    Geothermal reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search...

  11. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Stable-isotope analyses were carried out on hydrothermal minerals sampled from the deep metamorphic units at Larderello, Italy. The D18O values obtained for the most...

  12. Isotopic Analysis- Fluid At Valles Caldera - Redondo Area (Rao...

    Open Energy Info (EERE)

    Fluid At Valles Caldera - Redondo Area (Rao, Et Al., 1996) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Valles...

  13. Isotopic Analysis- Fluid At Fenton Hill HDR Geothermal Area ...

    Open Energy Info (EERE)

    Geothermal Area (Rao, Et Al., 1996) Exploration Activity Details Location Fenton Hill HDR Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1996 - 1996...

  14. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Et Al., 1996) Exploration Activity Details Location Valles Caldera - Sulphur Springs Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1996 - 1996...

  15. Isotope Geochemistry of Thermal and Nonthermal Waters in the...

    Open Energy Info (EERE)

    Canyon. Isotopic evidence shows that these springs consist of three components: (1) deep geothermal fluid, (2) surficial andor near-surface groundwater, and (3) relatively old,...

  16. Chemical and isotopic characteristics of the coso east flank...

    Open Energy Info (EERE)

    Christenson, B. W.; Kennedy, B. M.; Adams, M. C.; Bjornstad, S. C.; Buck, C. . 182007. Chemical and isotopic characteristics of the coso east flank hydrothermal fluids:...

  17. Isotopic Composition of Carbon in Fluids from the Long Valley...

    Open Energy Info (EERE)

    Isotopic Composition of Carbon in Fluids from the Long Valley Geothermal System, California, In- Proceedings of the Second Workshop on Hydrologic and Geochemical Monitoring in the...

  18. Temperature effects on the behavior of liquid hydrogen isotopes...

    Office of Scientific and Technical Information (OSTI)

    liquid hydrogen isotopes inside a spherical-shell directly driven inertial confinement fusion target Kim, K.; Mok, L.S. 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; LASER TARGETS;...

  19. A Helium Isotope Perspective On The Dixie Valley, Nevada, Hydrothermal...

    Open Energy Info (EERE)

    System. Geothermics. () . Related Geothermal Exploration Activities Activities (4) Direct-Current Resistivity Survey At Dixie Valley Geothermal Area (Laney, 2005) Isotopic...

  20. Hydrochemical and isotopic effects associated with petroleum fuel biodegradation pathways

    E-Print Network [OSTI]

    Sheffield, University of

    Hydrochemical and isotopic effects associated with petroleum fuel biodegradation pathways attenuation capacity in this dual- porosity aquifer. D 2005 Published by Elsevier B.V. Keywords: MTBE; BTEX

  1. Chemical and Isotopic Prediction of Aquifer Temperatures in the...

    Open Energy Info (EERE)

    Help Apps Datasets Community Login | Sign Up Search Page Edit with form History Chemical and Isotopic Prediction of Aquifer Temperatures in the Geothermal System at Long...

  2. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Fluid Activity Date - 1982 Usefulness useful DOE-funding Unknown Notes Field, chemical, and isotopic data for 95 thermal and nonthermal waters in and around the Valles...

  3. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    Fluid Activity Date - 1982 Usefulness useful DOE-funding Unknown Notes Field, chemical, and isotopic data for 95 thermal and nonthermal waters in and around the Valles...

  4. Chemical And Isotopic Investigation Of Warm Springs Associated...

    Open Energy Info (EERE)

    Chemical And Isotopic Investigation Of Warm Springs Associated With Normal Faults In Utah Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  5. Chemical and light-stable isotope characteristics of waters from...

    Open Energy Info (EERE)

    Chemical and light-stable isotope characteristics of waters from the raft river geothermal area and environs, Cassia County, Idaho, Box Elder county, Utah Jump to: navigation,...

  6. MyUni Tests Tests.............................................................................................................................................. 2

    E-Print Network [OSTI]

    Balasuriya, Sanjeeva

    MyUni ­ Tests Tests.............................................................................................................................................. 2 Test question types.................................................................................................................... 2 Create a test

  7. Amino acid biosignatures : implications for the detection of extinct or extant microbial communities on Mars

    E-Print Network [OSTI]

    Aubrey, Andrew D.

    2008-01-01

    acid racemization to geochronology and geothermometry. Orig.Amino Acid Racemization to Geochronology and Geothermometry.acid racemization to geochronology and geothermometry. Orig.

  8. Amino Acid Biosignatures - Implications for the Detection of Extinct or Extant Microbial Communities on Mars

    E-Print Network [OSTI]

    Aubrey, Andrew D

    2008-01-01

    acid racemization to geochronology and geothermometry. Orig.Amino Acid Racemization to Geochronology and Geothermometry.acid racemization to geochronology and geothermometry. Orig.

  9. Apparatus for isotopic alteration of mercury vapor

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Gloucester, MA); Marcucci, Rudolph V. (Danvers, MA)

    1988-01-01

    An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

  10. Final Report "Structure of Rare Isotopes"

    SciTech Connect (OSTI)

    Papenbrock, Thomas

    2012-05-09

    The Junior Investigator grant 'Structure of Rare Isotopes' (DE-FG02-07ER41529) supported research in low-energy nuclear theory from September 1, 2007 to August 31, 2010. It was the main goal of the proposed research to develop and optimize an occupation-number-based energy functional for the computation of nuclear masses, and this aim has been reached. Furthermore, progress was made in linking two and three-body forces from low-momentum interactions to pairing properties in nuclear density functionals, and in the description of deformed nuclei within an effective theory.

  11. Holocene hydrologic balance of tropical South America from oxygen isotopes of lake sediment opal, Venezuelan Andes

    E-Print Network [OSTI]

    Wolfe, Alexander P.

    Holocene hydrologic balance of tropical South America from oxygen isotopes of lake sediment opal.V. All rights reserved. Keywords: oxygen isotopes; biogenic opal; hydrologic balance; Holocene; Venezuela

  12. Neutron Stimulated Emission Computed Tomography of Stable Isotopes

    E-Print Network [OSTI]

    on the development of a new molecular imaging technique using inelastic scattering of fast neutrons. Earlier studies characteristic gamma photons through inelastic scattering of an external neutron beam. These stable isotopes canNeutron Stimulated Emission Computed Tomography of Stable Isotopes Carey E. Floyd Jr.*ab , Calvin

  13. Packed bed reactor for photochemical sup 196 Hg isotope separation

    SciTech Connect (OSTI)

    Grossman, M.W.; Speer, R.

    1992-03-03

    This patent describes a photochemical reactor useful for the isotopic enrichment of a predetermined isotope of mercury comprising a reactor cell and a monoisotopic light source It comprises: a plurality of transparent, straight reactor cell tubes disposed axially within the internal volume of the reactor cell to increase the surface area thereof for production deposition.

  14. Nitrogen isotope effects on glutamate decarboxylase from Escherichia coli

    SciTech Connect (OSTI)

    Abell, L.M.; O'Leary, M.H.

    1988-05-03

    The nitrogen isotope effect on the decarboxylation of glutamic acid by glutamate decarboxylase from Escherichia coli has been measured by comparison of the isotopic composition of the amino nitrogen of the product ..gamma..-aminobutyric acid isolated after 10-20% reaction with that of the starting glutamic acid. At pH 4.7, 37 /sup 0/C, the isotope effect is k/sup 14//k/sup 15/ = 0.9855 +/- 0.0006 when compared to unprotonated glutamic acid. Interpretation of this result requires knowledge of the equilibrium nitrogen isotope effect for Schiff base formation. This equilibrium isotope effect is K/sup 14//K/sup 15/ - 0.9824 for the formation of the unprotonated Schiff base between unprotonated valine and salicylaldehyde. Analysis of the nitrogen isotope effect on decarboxylation of glutamic acid and of the previously measured carbon isotope effect on this same reaction shows that decarboxylation and Schiff base formation are jointly rate limiting. The enzyme-bound Schiff base between glutamate and pyridoxal 5'-phosphate partitions approximately 2:1 between decarboxylation and return to the starting state. The nitrogen isotope effect also reveals that the Schiff base nitrogen is protonated in this intermediate.

  15. Lithium Isotope History of Cenozoic Seawater: Changes in Silicate Weathering

    E-Print Network [OSTI]

    Paytan, Adina

    Lithium Isotope History of Cenozoic Seawater: Changes in Silicate Weathering and Reverse Weathering 70 Ma · Overview of the Marine Lithium Cycle · Analytical Challenges · 68 Million Year Seawater Lithium Isotope Record (Forams) · Interpretation Standard: NIST L-SVEC Li (SRM 8545) #12;100 Ma Climate

  16. Tracking the lithium isotopic evolution of the mantle using carbonatites

    E-Print Network [OSTI]

    Mcdonough, William F.

    Tracking the lithium isotopic evolution of the mantle using carbonatites Ralf Halama a,, William F. © 2007 Elsevier B.V. All rights reserved. Keywords: lithium isotopes; carbonatites; mantle geochemistry 1. Introduction Lithium (Li) is an incompatible element that is typi- cally enriched 10 to 50-fold in crustal

  17. Sandia National Laboratories Medical Isotope Reactor concept.

    SciTech Connect (OSTI)

    Coats, Richard Lee; Dahl, James J.; Parma, Edward J., Jr.

    2010-04-01

    This report describes the Sandia National Laboratories Medical Isotope Reactor and hot cell facility concepts. The reactor proposed is designed to be capable of producing 100% of the U.S. demand for the medical isotope {sup 99}Mo. The concept is novel in that the fuel for the reactor and the targets for the {sup 99}Mo production are the same. There is no driver core required. The fuel pins that are in the reactor core are processed on a 7 to 21 day irradiation cycle. The fuel is low enriched uranium oxide enriched to less than 20% {sup 235}U. The fuel pins are approximately 1 cm in diameter and 30 to 40 cm in height, clad with Zircaloy (zirconium alloy). Approximately 90 to 150 fuel pins are arranged in the core in a water pool {approx}30 ft deep. The reactor power level is 1 to 2 MW. The reactor concept is a simple design that is passively safe and maintains negative reactivity coefficients. The total radionuclide inventory in the reactor core is minimized since the fuel/target pins are removed and processed after 7 to 21 days. The fuel fabrication, reactor design and operation, and {sup 99}Mo production processing use well-developed technologies that minimize the technological and licensing risks. There are no impediments that prevent this type of reactor, along with its collocated hot cell facility, from being designed, fabricated, and licensed today.

  18. Supported palladium materials for isotope separation

    SciTech Connect (OSTI)

    Rutherford, W.M.; Ellis, R.E.; Abell, G.C.

    1988-01-21

    Several palladium packing materials were investigated for their suitability for use in the separation of hydrogen isotopes by displacement chromatography. The materials included palladium on Chromosorb and several formulations of palladium on commercially available alpha-alumina-based catalyst supports. All materials showed some degradation upon being subjected to repeated hydriding-dehydriding cycles; however, the degradation did not lead to unacceptably low permeability to gas flow. Dynamic performance of the packings was evaluated by displacement of deuterium with protium at several temperatures and flow rates. Isotopic exchange was generally rapid. However, high surface area packings (greater than 4 m/sup 2//g) yielded transition zones that were initially sharp, but had long ''tails'' at deuterium concentrations below 5%. Best results were obtained with a packing containing 48.2% palladium on Norton catalyst support No. SA5*21 (surface area = 0.33 m/sup 2//g). Improved performance was observed as the displacement temperature was increased to 80/sup 0/C from 22/sup 0/C. The slight decrease in equilibrium separation was more than offset by improved kinetics at the higher temperature. 19 figs., 6 tabs.

  19. Process for recovery of daughter isotopes from a source material

    DOE Patents [OSTI]

    Tranter, Troy J.; Todd, Terry A.; Lewis, Leroy C.; Henscheid, Joseph P.

    2005-10-04

    The invention includes a method of separating isotopes from a mixture containing at least two isotopes in a solution. A first isotope is precipitated and is collected from the solution. A daughter isotope is generated and collected from the first isotope. The invention includes a method of producing an actinium-225/bismuth-213 product from a material containing thorium-229 and thorium-232. A solution is formed containing nitric acid and the material and iodate is added to form a thorium iodate precipitate. A supernatant is separated from the thorium iodate precipitate and a second volume of nitric acid is added to the precipitate. The precipitate is stored and a decay product comprising actinium-225 and bismuth-213 is generated in the second volume of nitric acid which is then separated from the thorium iodate precipitate, filtered, and treated using at least one chromatographic procedure. The invention also includes a system for producing an actinium-225/bismuth-213 product.

  20. Special isotope separation at the Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Hendrickson, P.D.

    1989-02-03

    The SIS facilities will include a Plutonium Processing Facility (PPF), a Laser Support Facility (LSF), and all associated equipment required for isotope separation. The SIS Plant will process fuel-grade plutonium into weapons-grade plutonium using Atomic Vapor Laser Isotope Separation (AVLIS) and supporting chemical processes. The AVLIS process uses precisely tuned visible laser light to selectively ionize or excite specific plutonium isotopes in a vapor stream. The ionized plutonium isotopes (Pu 240, Pu 238 and Pu 241) are then separated from the plutonium isotope of interest (Pu 239). Chemical processes are required to (1) prepare the AVLIS plutonium feed for processing, remove americium-241, and cast plutonium metal into forms that meet AVLIS processing requirements; (2) recover and, if required, purify the AVLIS plutonium product; and (3) recover and process the AVLIS separated by-products. This presentation describes the production facility and some of the plutonium processes.

  1. Development of a portable mass spectrometric system for determination of isotopic composition of solid uranium samples using fluorine volatilization. Final report

    SciTech Connect (OSTI)

    Loge, G.

    1994-09-30

    Using hardware and materials supplied by LANL, a prototype quadrupole mass spectrometer system designed for portable field analysis of isotopic composition of solid uranium samples was assembled and tested. The system contained the capability for fluorine volatilization of solid uranium samples with gas introduction, which was successfully tested and demonstrated using 100 mg samples of U{sub 3}O{sub 8}. Determination of precision and accuracy for measuring isotopic composition was performed using isotopic standards. Use with soil samples containing uranium were also attempted. Silicates in the soil forming SiF{sub 4} were found to be a kinetic bottleneck to the formation of UF{sub 6}. This could be avoided by performing some sort of chemical separation as a pre-treatment step, which was demonstrated using nitric acid.

  2. Nuclear Proliferation Using Laser Isotope Separation -- Verification Options

    SciTech Connect (OSTI)

    Erickson, S A

    2001-10-15

    Two levels of nonproliferation verification exist. Signatories of the basic agreements under the Nuclear Non-proliferation Treaty (NPT) agree to open their nuclear sites to inspection by the IAEA. A more detailed and intrusive level was developed following the determination that Iraq had begun a nuclear weapons development program that was not detected by the original level of verification methods. This level, referred to as 93+2 and detailed in model protocol INFCIRC/540, allows the IAEA to do environmental monitoring of non-declared facilities that are suspected of containing proliferation activity, and possibly further inspections, as well as allowing more detailed inspections of declared sites. 56 countries have signed a Strengthened Safeguards Systems Additional Protocol as of 16 July 2001. These additional inspections can be done on the instigation of the IAEA itself, or after requests by other parties to the NPT, based on information that they have collected. Since information able to cause suspicion of proliferation could arrive at any country, it is important that countries have procedures in place that will assist them in making decisions related to these inspections. Furthermore, IAEA inspection resources are limited, and therefore care needs to be taken to make best use of these resources. Most of the nonproliferation verification inspections may be concentrated on establishing that diversion of nuclear materials is not occurring, but some fraction will be related to determining if undeclared sites have nuclear materials production taking place within them. Of these, most suspicions will likely be related to the major existing technologies for uranium enrichment and reprocessing for plutonium extraction, as it would seem most likely that nations attempting proliferation would use tested means of producing nuclear materials. However, as technology continues to advance and new methods of enrichment and reprocessing are developed, inspection-related procedures will need to be adapted to keep up with them. In order to make 93+2 inspections more useful, a systematic way of finding clues to nuclear proliferation would be useful. Also, to cope with the possible use of newer technology for proliferation, the list of clues might need to be expanded. This paper discusses the development and recognition of such clues. It concentrates on laser isotope separation (LIS) as a new proliferation technology, and uses Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) as an example of LIS that is well known.

  3. Shell model description of Ge isotopes

    E-Print Network [OSTI]

    J. G. Hirsch; P. C. Srivastava

    2012-04-12

    A shell model study of the low energy region of the spectra in Ge isotopes for $38\\leq N\\leq 50$ is presented, analyzing the excitation energies, quadrupole moments, $B(E2)$ values and occupation numbers. The theoretical results have been compared with the available experimental data. The shell model calculations have been performed employing three different effective interactions and valence spaces.We have used two effective shell model interactions, JUN45 and jj44b, for the valence space $f_{5/2} \\, p \\,g_{9/2}$ without truncation. To include the proton subshell $f_{7/2}$ in valence space we have employed the $fpg$ effective interaction due to Sorlin {\\it et al.}, with $^{48}$Ca as a core and a truncation in the number of excited particles.

  4. Compact hydrogen/helium isotope mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM); Scime, Earl E. (Morgantown, WV)

    1996-01-01

    The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

  5. Giant Quadrupole-Resonance in Ni Isotopes 

    E-Print Network [OSTI]

    Youngblood, David H.; Lui, YW; Garg, U.; Peterson, R. J.

    1992-01-01

    VOLUME 45, NUMBER 5 MAY 1992 Giant quadrupole resonance in Ni isotopes D. H. Youngblood and Y.-%. Lui Texas A&M UniUersity, College Station, Texas 77843 U. Garg University of Notre Dame, South Bend, Indiana 46556 R. J. Peterson University... (%) 58+12 76+14 78+14 90+16 Cp 0.80+0.04 0.84+0.04 0.82+0. 12 1.05+0. 10 2174 YOUNGBLOOD, LUI, GARG, AND PETERSON 45 1000 100 60Ni(n, n') E = 129 MeV 1 000 100 58Ni(n, n') 10 10 100 z' 1000 64Ni(n, n') 1OO~y 64 Ni 100 10 I s & & I...

  6. Chemical and isotopic determination from complex spectra

    SciTech Connect (OSTI)

    Zardecki, A.; Strittmatter, R.B.

    1995-07-01

    Challenges for proliferation detection include remote, high- sensitivity detection of chemical effluents from suspect facilities and enhanced detection sensitivity for nuclear material. Both the identification of chemical effluents with lidar and enhanced nuclear material detection from radiation sensors involve determining constituents from complex spectra. In this paper, we extend techniques used to analyze time series to the analysis of spectral data. Pattern identification methods are applied to spectral data for domains where standard matrix inversion may not be suitable because of detection statistics. We use a feed-forward, back-propagation neural network in which the nodes of the input layer are fed with the observed spectral data. The nodes of the output layer contain the identification and concentration of the isotope or chemical effluent the sensor is to identify. We will discuss the neural network architecture, together with preliminary results obtained from the training process.

  7. Laser-isotope-separation technology. [Review; economics

    SciTech Connect (OSTI)

    Jensen, R.J.; Blair, L.S.

    1981-01-01

    The Molecular Laser Isotope Separation (MLIS) process currently under development is discussed as an operative example of the use of lasers for material processing. The MLIS process, which uses infrared and ultraviolet lasers to process uranium hexafluoride (UF/sub 6/) resulting in enriched uranium fuel to be used in electrical-power-producing nuclear reactor, is reviewed. The economics of the MLIS enrichment process is compared with conventional enrichment technique, and the projected availability of MLIS enrichment capability is related to estimated demands for U.S. enrichment service. The lasers required in the Los Alamos MLIS program are discussed in detail, and their performance and operational characteristics are summarized. Finally, the timely development of low-cost, highly efficient ultraviolet and infrared lasers is shownd to be the critical element controlling the ultimate deployment of MLIS uranium enrichment. 8 figures, 7 tables.

  8. Temperature dependence of carbon isotope fractionation in CAM plants

    SciTech Connect (OSTI)

    Deleens, E.; Treichel, I.; O'Leary, M.H.

    1985-09-01

    The carbon isotope fractionation associated with nocturnal malic acid synthesis in Kalanchoe daigremontiana and Bryophyllum tubiflorum was calculated from the isotopic composition of carbon-4 of malic acid, after appropriate corrections. In the lowest temperature treatment (17/sup 0/C nights, 23/sup 0/C days), the isotope fractionation for both plants is -4% per thousand (that is, malate is enriched in /sup 13/C relative to the atmosphere). For K. daigremontiana, the isotope fractionation decreases with increasing temperature, becoming approximately 0% per thousand at 27/sup 0/C/33/sup 0/C. Detailed analysis of temperature effects on the isotope fractionation indicates that stomatal aperture decreases with increasing temperature and carboxylation capacity increases. For B. tubiflorum, the temperature dependence of the isotope fractionation is smaller and is principally attributed to the normal temperature dependences of the rates of diffusion and carboxylation steps. The small change in the isotopic composition of remaining malic acid in both species which is observed during deacidification indicates that malate release, rather than decarboxylation, is rate limiting in the deacidification process. 28 references, 1 figure, 4 tables.

  9. Test Images

    E-Print Network [OSTI]

    Test Images. I hope to have a set of test images for the course soon. Some images are available now; some will have to wait until I can find another 100-200

  10. Meatiness Testing 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    The purpose of this research was to investigate the ignition phenomena of selected polymeric materials using the Hot Wire Ignition Test. This test is prescribed by Underwriters Laboratories as one of various requirements ...

  11. Verification Testing Test Driven Development Testing with JUnit Verification

    E-Print Network [OSTI]

    Peters, Dennis

    Verification Testing Test Driven Development Testing with JUnit Verification Any activity should be verified. #12;Verification Testing Test Driven Development Testing with JUnit Approaches to verification 1 Testing 2 Static Analysis · Peer review · Insepction/Walk-through/Structured review · Formal

  12. A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy

    E-Print Network [OSTI]

    Paytan, Adina

    A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy Abstract: The sulfur isotopic.4. Measurement and Materials for Sulfur Isotope Stratigraphy 171 9.4.1. Isotope Analyses 171 9.4.2. Materials. The features in the record can also be used to correlate between stratigraphic sections and sequences

  13. Evolution of the geothermal fluids at Los Azufres, Mexico, as traced by noble gas isotopes, 18

    E-Print Network [OSTI]

    Evolution of the geothermal fluids at Los Azufres, Mexico, as traced by noble gas isotopes, 18 O, D: Noble gases Strontium isotopes Helium isotopes Geothermal energy Los Azufres Araró Mexico Isotopes of noble gases, CO2, H2O and Sr were measured in 10 geothermal wells and 8 hot springs, fumaroles and mud

  14. The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

    E-Print Network [OSTI]

    The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

  15. Coupled molybdenum, iron and uranium stable isotopes as oceanic paleoredox proxies during the Paleoproterozoic Shunga Event

    E-Print Network [OSTI]

    Coupled molybdenum, iron and uranium stable isotopes as oceanic paleoredox proxies during isotopes Uranium isotopes Iron isotopes Paleoproterozoic Euxinic The Paleoproterozoic Era was a time that the studied section was deposited under dominantly euxinic conditions (anoxic and sulfidic) and that the lower

  16. Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

  17. Direct analysis of air filter samples for alpha emitting isotopes

    SciTech Connect (OSTI)

    Mohagheghi, A.H.; Ghanbari, F.; Ebara, S.B.; Enghauser, M.E. [Sandia National Labs., Albuquerque, NM (United States); Bakhtiar, S.N. [Westinghouse WIPP, Carlsbad, NM (United States)

    1997-04-01

    The traditional method for determination of alpha emitting isotopes on air filters has been to process the samples by radiochemical methods. However, this method is too slow for cases of incidents involving radioactive materials where the determination of personnel received dose is urgent. A method is developed to directly analyze the air filters taken from personal and area air monitors. The site knowledge is used in combination with alpha spectral information to identify isotopes. A mathematical function is developed to estimate the activity for each isotope. The strengths and weaknesses of the method are discussed.

  18. Method for isotopic analysis of chlorinated organic compounds

    DOE Patents [OSTI]

    Holt, B.D.; Sturchio, N.C.

    1999-08-24

    The present invention provides a method for preparing a VOC sample for carbon and chlorine isotope ratio analysis by mass spectrometer. A VOC sample is placed in a combustion tube and reacted with CuO to form CO{sub 2} and CuCl. The CO{sub 2} is then extracted and analyzed for the carbon isotope ratio. The CuCl is separated from the excess CuO and reacted with CH{sub 3}I to form CH{sub 3}Cl, extracted and analyzed for chlorine isotope ratio. 9 figs.

  19. Cost Estimate for Laser Isotope Separation for RIA

    SciTech Connect (OSTI)

    Scheibner, K

    2004-11-01

    Isotope enrichment of some elements is required in support of the Rare Isotope Accelerator (RIA) in order to obtain the beam intensities, source efficiencies and/or source lifetime required by RIA. The economics of using Atomic Vapor Laser Isotope Separation (AVLIS) technology as well as ElectroMagnetic (EM) separation technology has been evaluated. It is concluded that such an AVLIS would be about 10 times less expensive than a facility based on electromagnetic separation - $17 M versus $170 M. In addition, the AVLIS facility footprint would be about 10 times smaller, and operations would require about 4 years (including 2 years of startup) versus about 11 years for an EM facility.

  20. Multiple-sulfur isotope effects during photolysis of carbonyl sulfide

    E-Print Network [OSTI]

    Lin, Ying

    Laboratory experiments were carried out to determine sulfur isotope effects during ultraviolet photolysis of carbonyl sulfide (OCS) to carbon monoxide (CO) and elemental sulfur (S[superscript 0]). The OCS gas at 3.7 to 501 ...

  1. The HIgh Flux Isotope Reactor: Past, Present, and Future

    SciTech Connect (OSTI)

    Beierschmitt, Kelly J [ORNL; Farrar, Mike B [ORNL

    2009-01-01

    HFIR construction began in 1965 and completed in 1966. During the first 15 years of operation, the heavy actinide isotope production mission was dominant. HFIR is now positioned as one of the most versataile research reactors in the world.

  2. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

    1980-08-12

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  3. AN ISOTOPE HYDROLOGY STUDY OF THE KILAUEA VOLCANO AREA, HAWAII

    E-Print Network [OSTI]

    AN ISOTOPE HYDROLOGY STUDY OF THE KILAUEA VOLCANO AREA, HAWAII STUDY OF THE KILAUEA VOLCANO AREA, HAWAII M.A. Scholl, S.E. Ingebritsen, C.J. Janik, and J.P. Kauahikaua

  4. Carbon stable isotopes suggest that hippopotamus-vectored nutrients subsidize

    E-Print Network [OSTI]

    Lewison, Rebecca

    Carbon stable isotopes suggest that hippopotamus-vectored nutrients subsidize aquatic consumers that hippopotamus-vectored nutrients subsidize aquatic consumers in an East African river. Ecosphere 6(4):52. http

  5. A Strontium Isotopic Study Of Newberry Volcano, Central Oregon...

    Open Energy Info (EERE)

    content with 87Sr86Sr suggests that some isotopic ratios reflect shallow crustal contamination, but the data also suggest that two mantle sources, a prominent one at 0.7036 and...

  6. The marine geochemistry of iron and iron isotopes

    E-Print Network [OSTI]

    Bergquist, Bridget A., 1973-

    2004-01-01

    This thesis addressed questions about the Fe cycle by measuring detailed profiles and transects of Fe species in the ocean and also by exploring the use of a new tracer of Fe, Fe isotopic fractionation. In the subtropical ...

  7. Extraction of -cellulose from mummified wood for stable isotopic analysis

    E-Print Network [OSTI]

    Gedalof, Ze'ev

    Extraction of -cellulose from mummified wood for stable isotopic analysis Benjamin A. Hook a cellulose can provide valuable paleocli- matic information at annual and subannual resolution, from time the trees grew. In the mummified wood, polysaccharides (hemicellulose, -cellulose) are frequently

  8. COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION...

    Office of Scientific and Technical Information (OSTI)

    COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION OF sup 26Al BY A NEARBY SUPERNOVA Citation Details In-Document Search Title: COLLATERAL EFFECTS ON SOLAR...

  9. Global isotopic signatures of oceanic island basalts / by

    E-Print Network [OSTI]

    Oschmann, Lynn A

    1991-01-01

    Sr, Nd and Pb isotopic analyses of 477 samples representing 30 islands or island groups, 3 seamounts or seamount chains, 2 oceanic ridges and 1 oceanic plateau [for a total of 36 geographic features] are compiled to form ...

  10. Surface-cycling of rhenium and its isotopes

    E-Print Network [OSTI]

    Miller, Christian Alexander

    2009-01-01

    The application of elemental and isotopic metal palaeoredox tracers to the geologic past rests on an understanding of modern metal cycles. This study reevaluates the surface-cycling of Mo and Re in near-surface reservoirs. ...

  11. The isotopic composition of plant and soil biomarkers of pollution

    E-Print Network [OSTI]

    Randerson, JT; Pataki, DE; Wang, W; Herzenach, M; Grulke, NE

    2010-01-01

    these isotopes are “decoupled”. Wankel et al. (2006) studied15:1301–1346 Kendall C, Elliott EM, Wankel SD (2007) Tracingmapping. Springer, Berlin Wankel SD, Kendall C, Francis CA,

  12. Delayed neutron energy spectrum measurements of actinide waste isotopes 

    E-Print Network [OSTI]

    Comfort, Christopher M.

    1998-01-01

    was irradiated using the Texas A&M Nuclear Science Center Reactor (NSCR). Three proton recoil detectors, operating individually, in conjunction with MCNP calculated response functions, were used to measure the delayed neutron energy spectra of each isotope...

  13. Evidence of magnetic isotope effects during thermochemical sulfate reduction

    E-Print Network [OSTI]

    Oduro, Harry D.

    Thermochemical sulfate reduction experiments with simple amino acid and dilute concentrations of sulfate reveal significant degrees of mass-independent sulfur isotope fractionation. Enrichments of up to 13‰ for [superscript ...

  14. Uranium accountancy in Atomic Vapor Laser Isotope Separation

    SciTech Connect (OSTI)

    Carver, R.D.

    1986-01-01

    The AVLIS program pioneers the large scale industrial application of lasers to produce low cost enriched uranium fuel for light water reactors. In the process developed at Lawrence Livermore National Laboratory, normal uranium is vaporized by an electron beam, and a precisely tuned laser beam selectively photo-ionizes the uranium-235 isotopes. These ions are moved in an electromagnetic field to be condensed on the product collector. All other uranium isotopes remain uncharged and pass through the collector section to condense as tails. Tracking the three types of uranium through the process presents special problems in accountancy. After demonstration runs, the uranium on the collector was analyzed for isotopic content by Battelle Pacific Northwest Laboratory. Their results were checked at LLNL by analysis of parallel samples. The differences in isotopic composition as reported by the two laboratories were not significant.

  15. FY09 PROGRESS: MULTI-ISOTOPE PROCESS (MIP) MONITOR

    SciTech Connect (OSTI)

    Schwantes, Jon M.; Orton, Christopher R.; Fraga, Carlos G.; Christensen, Richard; Laspe, Amy R.; Ward, Rebecca M.

    2009-10-18

    Model and experimental estimates of the Multi-Isotope Process Monitor performance for determining burnup after dissolution and acid concentration during solvent extraction steps during reprocessing of spent nuclear fuel are presented.

  16. Chemical and Isotopic Composition of Casa Diablo Hot Spring:...

    Open Energy Info (EERE)

    Chemical and Isotopic Composition of Casa Diablo Hot Spring: Magmatic CO2 near Mammoth Lakes, CA Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference...

  17. Isotopic Anomalies in CP Stars: Helium, Mercury, Platinum, and Calcium

    E-Print Network [OSTI]

    C. R. Cowley; S. Hubrig; F. Castelli

    2007-11-15

    We review the classical observational results for isotopic abundance variations for several elements in CP stars. We concentrate on the "newest" anomaly, in calcium. The cosmically very rare isotope, Ca-48 can rival and even dominate the more common, alpha nuclide, Ca-40. Relevant examples are found in the hot, non-magnetic HgMn stars, and the field horizontal-branch star, Feige 86. The calcium anomaly is also present in cool, magnetic stars, including the notorious HD 101065, Przybylski's star.

  18. Separation of the isotopes of boron by chemical exchange reactions

    DOE Patents [OSTI]

    McCandless, Frank P. (Bozeman, MT); Herbst, Ronald S. (Idaho Falls, ID)

    1995-01-01

    The isotopes of boron, .sup.10 B and .sup.11 B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF.sub.3 and a liquid BF.sub.3 . donor molecular addition complex formed between BF.sub.3 gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone.

  19. Configuration mixing effects in neutron-rich carbon isotopes

    E-Print Network [OSTI]

    C. X. Yuan; F. R. Xu; C. Qi

    2015-07-24

    Shell model calculations are done to study the structure of neutron-rich carbon isotopes. For both even-A and odd-A neutron-rich carbon isotopes, the energy levels are strongly affected by the configuration mixing of valence neutrons. The calculated energy levels in the nucleus $^{17}$C are significantly improved compared with experimental values when the model space of the three valence neutrons is enlarged from pure $\

  20. Configuration mixing effects in neutron-rich carbon isotopes

    E-Print Network [OSTI]

    Yuan, C X; Qi, C

    2015-01-01

    Shell model calculations are done to study the structure of neutron-rich carbon isotopes. For both even-A and odd-A neutron-rich carbon isotopes, the energy levels are strongly affected by the configuration mixing of valence neutrons. The calculated energy levels in the nucleus $^{17}$C are significantly improved compared with experimental values when the model space of the three valence neutrons is enlarged from pure $\

  1. Measurement of zinc stable isotope ratios in biogeochemical matrices by double-spike MC-ICPMS and determination of the isotope ratio pool available for plants from soil

    E-Print Network [OSTI]

    2010-01-01

    of the isotope ratio pool available for plants from soil Timto characterize the Zn isotope pool available to plants in athe composition of the Zn pool available to the plants [21,

  2. Proton radii of Be, B, and C isotopes

    E-Print Network [OSTI]

    Yoshiko Kanada-En'yo

    2014-11-04

    We investigate the neutron number $(N)$ dependence of root mean square radii of point proton distribution (proton radii) of Be, B, and C isotopes with the theoretical method of variation after spin-parity projection in the framework of antisymmetrized molecular dynamics (AMD). The proton radii in Be and B isotopes changes rapidly as $N$ increases, reflecting the cluster structure change along the isotope chains, whereas, those in C isotopes show a weak $N$ dependence because of the stable proton structure in nuclei with $Z=6$. In neutron-rich Be and B isotopes, the proton radii are remarkably increased by the enhancement of the two-center cluster structure in the prolately deformed neutron structure. We compare the $N$ dependence of the calculated proton radii with the experimental ones reduced from the charge radii determined by isotope shift and those deduced from the charge changing interaction cross section. It is found that the $N$ dependence of proton radii can be a probe to clarify enhancement and weakening of cluster structures.

  3. METALLICITY-DEPENDENT GALACTIC ISOTOPIC DECOMPOSITION FOR NUCLEOSYNTHESIS

    SciTech Connect (OSTI)

    West, Christopher; Heger, Alexander, E-mail: west0482@umn.edu, E-mail: alexander.heger@monash.edu [Minnesota Institute for Astrophysics, School of Physics and Astronomy, University of Minnesota, Minneapolis, MN 55455 (United States)

    2013-09-01

    All stellar evolution models for nucleosynthesis require an initial isotopic abundance set to use as a starting point. Generally, our knowledge of isotopic abundances of stars is fairly incomplete except for the Sun. We present a first model for a complete average isotopic decomposition as a function of metallicity. Our model is based on the underlying nuclear astrophysics processes, and is fitted to observational data, rather than traditional forward galactic chemical evolution modeling which integrates stellar yields beginning from big bang nucleosynthesis. We first decompose the isotopic solar abundance pattern into contributions from astrophysical sources. Each contribution is then assumed to scale as a function of metallicity. The resulting total isotopic abundances are summed into elemental abundances and fitted to available halo and disk stellar data to constrain the model's free parameter values. This procedure allows us to use available elemental observational data to reconstruct and constrain both the much needed complete isotopic evolution that is not accessible to current observations, and the underlying astrophysical processes. As an example, our model finds a best fit for Type Ia contributing {approx_equal} 0.7 to the solar Fe abundance, and Type Ia onset occurring at [Fe/H] {approx_equal} -1.1, in agreement with typical values.

  4. Possible differences in biological availability of isotopes of plutonium: Report of a workshop

    SciTech Connect (OSTI)

    Kercher, J.R.; Gallegos, G.M.

    1993-09-01

    This paper presents the results of a workshop conducted on the apparent different bioavailability of isotopes {sup 238}Pu and {sup 239}Pu. There is a substantial body of evidence that {sup 238}Pu as commonly found in the environment is more biologically available than {sup 239}Pu. Studies of the Trinity Site, Nevada Test Site from nonnuclear and nuclear events, Rocky Flats, Enewetak and Bikini, and the arctic tundra support this conclusion and indicate that the bioavailability of {sup 238}Pu is more than an order of magnitude greater than that of {sup 239}Pu. Plant and soil studies from controlled environments and from Savannah River indicate no isotopic difference in availability of Pu to plants; whereas studies at the Trinity Site do suggest a difference. While it is possible that these observations can be explained by problems in the experimental procedure and analytical techniques, this possibility is remote given the ubiquitous nature of the observations. Studies of solubility of Pu in the stomach contents of cattle grazing at the Nevada Test Site and from fish from Bikini Atoll both found that {sup 238}Pu was more soluble than {sup 239}Pu. Studies of the Los Alamos effluent stream indicate that as particle size decreases, the content of {sup 238}Pu relative to {sup 239}Pu increases.

  5. Laser isotope purification of lead for use in semiconductor chip interconnects

    SciTech Connect (OSTI)

    Scheibner, K.; Haynam, C.; Worden, E.; Esser, B.

    1996-03-19

    Lead, used throughout the electronics industries, typically contains small amounts of radioactive {sup 210}Pb (a daughter product of the planets ubiquitous {sup 238}U) whose {sup 210}Po daughter emits an {alpha}-particle that is known to cause soft errors in electronic circuits. The {sup 210}Pb is not separable by chemical means. This paper describes the generic Atomic Vapor Laser Isotope Separation (AVLIS) process developed at the Lawrence Livermore National Laboratory (LLNL) over the last 20 years, with particular emphasis on recent efforts to develop the process physics and component technologies required to remove the offending {sup 210}Pb using lasers. We have constructed a developmental facility that includes a process laser development area and a test bed for the vaporizer and ion and product collectors. We will be testing much of the equipment and demonstrating pilot scale AVLIS on a surrogate material later this year. Detection of the very low alpha emission even from commercially available low-alpha lead is challenging. LLNL`s detection capabilities will be described. The goal of the development of lead purification technology is to demonstrate the capability in FY97, and to deploy a production machine capable of up to several MT/y of isotopically purified material, possible beginning in FY98.

  6. Laser isotope purification of lead for use in semiconductor chip interconnects

    SciTech Connect (OSTI)

    Scheibner, K.; Haynam, C.; Worden, E.; Esser, B.

    1996-02-01

    Lead, used throughout the electronics industries, typically contains small amounts of radioactive {sup 210}Pb (a daughter product of the planet`s ubiquitous {sup 210}U) whose {sup 210}Po daughter emits and {alpha}-particle that is known to cause soft errors in electronic circuits. The {sup 210}Pb is not easily separable by chemical means. This paper describes the generic Atomic Vapor Laser Isotope Separation (AVLIS) process developed at the Lawrence Livermore National Laboratory (LLNL) over the last 20 years, with particular emphasis on recent efforts to develop the process physics and component technologies required to remove the offending {sup 210}Pb using lasers. We have constructed a developmental facility that includes a process laser development area and a test bed for the vaporizer and ion and product collectors. We will be testing much of the equipment and demonstrating pilot-scale AVLIS on a surrogate material later this year. Detection of the very low alpha emission even from commercially available low-alpha lead is challenging. LLNL`s detection capabilities will be described. The goal of the development of lead purification technology is to demonstrate the capability in FY97, and to begin filling orders of up to several MT/y of isotopically purified material in FY98.

  7. Fast Flux Test Facility (FFTF) Briefing Book 1 Summary

    SciTech Connect (OSTI)

    WJ Apley

    1997-12-01

    This report documents the results of evaluations preformed during 1997 to determine what, if an, future role the Fast Flux Test Facility (FFTF) might have in support of the Department of Energy’s tritium productions strategy. An evaluation was also conducted to assess the potential for the FFTF to produce medical isotopes. No safety, environmental, or technical issues associated with producing 1.5 kilograms of tritium per year in the FFTF have been identified that would change the previous evaluations by the Department of Energy, the JASON panel, or Putnam, Hayes & Bartlett. The FFTF can be refitted and restated by July 2002 for a total expenditure of $371 million, with an additional $64 million of startup expense necessary to incorporate the production of medical isotopes. Therapeutic and diagnostic applications of reactor-generated medical isotopes will increase dramatically over the next decade. Essential medical isotopes can be produced in the FFTF simultaneously with tritium production, and while a stand-alone medical isotope mission for the facility cannot be economically justified given current marker conditions, conservative estimates based on a report by Frost &Sullivan indicate that 60% of the annual operational costs (reactor and fuel supply) could be offset by revenues from medical isotope production within 10 yeas of restart. The recommendation of the report is for the Department of Energy to continue to maintain the FFTF in standby and proceed with preparation of appropriate Nations Environmental Policy Act documentation in full consultation with the public to consider the FFTF as an interim tritium production option (1.5 kilograms/year) with a secondary mission of producing medical isotopes.

  8. Liquid targets for isotope production Jerry Nolen

    E-Print Network [OSTI]

    McDonald, Kirk

    W E-beam-on-Target Test at ANL MCNPX : for RIA, 200-kW uranium beam on Li peak energy deposition = 2 MW/cm3 1MeV, 20 mA, 1mm e-beam on Li deposited in the first 4 mm Test Objectives: Using

  9. Lithium isotopic systematics of A-type granites and their mafic enclaves: Further constraints on the Li isotopic composition of the continental crust

    E-Print Network [OSTI]

    Mcdonough, William F.

    Lithium isotopic systematics of A-type granites and their mafic enclaves: Further constraints form 6 February 2009 Accepted 15 February 2009 Editor: D.B. Dingwell Keywords: Lithium isotopes A-type granite Mafic enclave Continental crust Lithium concentrations and isotopic compositions of 39 A

  10. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation, and plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the elective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to form an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of dvelopment, cost, advantages and drawbacks of the five processes, (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  11. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the selective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to from an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of development, cost, advantages and drawbacks of the five processes (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  12. High Flux Isotope Reactor cold neutron source reference design concept

    SciTech Connect (OSTI)

    Selby, D.L.; Lucas, A.T.; Hyman, C.R.

    1998-05-01

    In February 1995, Oak Ridge National Laboratory`s (ORNL`s) deputy director formed a group to examine the need for upgrades to the High Flux Isotope Reactor (HFIR) system in light of the cancellation of the Advanced neutron Source Project. One of the major findings of this study was that there was an immediate need for the installation of a cold neutron source facility in the HFIR complex. In May 1995, a team was formed to examine the feasibility of retrofitting a liquid hydrogen (LH{sub 2}) cold source facility into an existing HFIR beam tube. The results of this feasibility study indicated that the most practical location for such a cold source was the HB-4 beam tube. This location provides a potential flux environment higher than the Institut Laue-Langevin (ILL) vertical cold source and maximizes the space available for a future cold neutron guide hall expansion. It was determined that this cold neutron beam would be comparable, in cold neutron brightness, to the best facilities in the world, and a decision was made to complete a preconceptual design study with the intention of proceeding with an activity to install a working LH{sub 2} cold source in the HFIR HB-4 beam tube. During the development of the reference design the liquid hydrogen concept was changed to a supercritical hydrogen system for a number of reasons. This report documents the reference supercritical hydrogen design and its performance. The cold source project has been divided into four phases: (1) preconceptual, (2) conceptual design and testing, (3) detailed design and procurement, and (4) installation and operation. This report marks the conclusion of the conceptual design phase and establishes the baseline reference concept.

  13. IUPAC Periodic Table of Isotopes for the Educational Community

    SciTech Connect (OSTI)

    Holden N. E.; Holden,N.E.; Coplen,T.B.

    2012-07-15

    John Dalton first proposed the concept of atomic weights of the elements in the first decade of the nineteenth century. These atomic weights of the chemical elements were thought of as constants of nature, similar to the speed of light. Dmitri Mendeleev arranged the atomic weights of the elements in ascending order of value and used the systematic variation of their chemical properties to produce his Periodic Table of the Elements in 1869. Measurement of atomic weight values became an important chemical activity for a century and a half. Theodore Richards received a Noble Prize for his work in this area. In 1913, Fredrick Soddy found a species of radium, which had an atomic weight value of 228, compared to the familiar radium gas value of 226. Soddy coined the term 'isotope' (Greek for 'in the same place') to account for this second atomic weight value in the radium position of the Periodic Table. Both of these isotopes of radium are radioactive. Radioactive isotopes are energetically unstable and will decay (disintegrate) over time. The time it takes for one half of a sample of a given radioactive isotope to decay is the half-life of that isotope. In addition to having different atomic weight values, radium-226 and radium-228 also have different half-life values. Around the same time as Soddy's work, J.J. Thomson (discoverer of the electron) identified two stable (non-radioactive) isotopes of the same element, neon. Over the next 40 years, the majority of the known chemical elements were found to have two or more stable (or long-lived radioactive isotopes that contribute significantly to the determination of the atomic weights of the elements).

  14. Test Comparability

    E-Print Network [OSTI]

    Keller, Christine; Shulenburger, David E.

    2010-01-01

    stream_size 3106 stream_content_type text/plain stream_name Test Comparability ChangeJuly (2).pdf.txt stream_source_info Test Comparability ChangeJuly (2).pdf.txt Content-Encoding UTF-8 Content-Type text/plain; charset=UTF-8... KU ScholarWorks | http://kuscholarworks.ku.edu Test Comparability 2010 by Christine Keller and David Shulenburger This work has been made available by the University of Kansas Libraries’ Office of Scholarly Communication and Copyright. Please share...

  15. Preliminary Notice of Violation, International Isotopes Idaho...

    Broader source: Energy.gov (indexed) [DOE]

    Ventilation Filters at the Test Reactor Area Hot Cell Facility at the Idaho National Engineering and Environmental Laboratory, On May 19, 2000, the U.S. Department of Energy...

  16. Isotope Ratio Triangulation: A Method for Determining Uranium Isotope Ratios and Application to the Search for Uranium Isotope Anomalies in the Mineral Titanite 

    E-Print Network [OSTI]

    Hill, Joseph Roger

    2014-11-10

    The U-Pb dating methods used in many geochronology laboratories take advantage of a mixed 235U-233U spike for precise uranium isotopic measurements and current data reduction algorithms assume a uniform 238U/235U value of 137.88. Recent re...

  17. Test Automation Ant JUnit Test Automation

    E-Print Network [OSTI]

    Mousavi, Mohammad

    Test Automation Ant JUnit Test Automation Mohammad Mousavi Eindhoven University of Technology, The Netherlands Software Testing 2012 Mousavi: Test Automation #12;Test Automation Ant JUnit Outline Test Automation Ant JUnit Mousavi: Test Automation #12;Test Automation Ant JUnit Why? Challenges of Manual Testing

  18. Examining the stability of thermally fissile Th and U isotopes

    E-Print Network [OSTI]

    Bharat Kumar; S. K. Biswal; S. K. Singh; S. K. Patra

    2015-08-03

    The properties of recently predicted thermally fissile Th and U isotopes are studied within the framework of relativistic mean field (RMF) approach using axially deformed basis. We calculated the ground, first intrinsic excited state and matter density for highly neutron-rich thorium and uranium isotopes. The possible modes of decay like $\\alpha$-decay and $\\beta$-decay are analyzed. We found that the neutron-rich isotopes are stable against $\\alpha$-decay, however they are very much unstable against $\\beta$-decay. The life time of these nuclei predicted to be tens of second against $\\beta$-decay. If these nuclei utilize before their decay time, a lots of energy can be produced within the help of multi-fragmentation fission. Also, these nuclei have a great implication in astrophysical point of view. The total nucleonic densities distribution are calculated, from which the clusters inside the parent nuclei are determined. %Most of the thorium isotopes are $\\alpha$ emitters, where as some %of them have short half-lives. In some cases, we found the isomeric states with energy range from 2 to 3 MeV and three minima in the potential energy surface of $^{228-230}$Th and $^{228-234}$U isotopes.

  19. System for recovery of daughter isotopes from a source material

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID) [Idaho Falls, ID; Todd, Terry A. (Aberdeen, ID) [Aberdeen, ID; Lewis, Leroy C. (Idaho Falls, ID) [Idaho Falls, ID; Henscheid, Joseph P. (Idaho Falls, ID) [Idaho Falls, ID

    2009-08-04

    A method of separating isotopes from a mixture containing at least two isotopes in a solution is disclosed. A first isotope is precipitated and is collected from the solution. A daughter isotope is generated and collected from the first isotope. The invention includes a method of producing an actinium-225/bismuth-213 product from a material containing thorium-229 and thorium-232. A solution is formed containing nitric acid and the material containing thorium-229 and thorium-232, and iodate is added to form a thorium iodate precipitate. A supernatant is separated from the thorium iodate precipitate and a second volume of nitric acid is added to the thorium iodate precipitate. The thorium iodate precipitate is stored and a decay product comprising actinium-225 and bismuth-213 is generated in the second volume of nitric acid, which is then separated from the thorium iodate precipitate, filtered, and treated using at least one chromatographic procedure. A system for producing an actinium-225/bismuth-213 product is also disclosed.

  20. The use of carbon stable isotope ratios in drugs characterization

    SciTech Connect (OSTI)

    Magdas, D. A., E-mail: gabriela.cristea@itim-cj.ro; Cristea, G., E-mail: gabriela.cristea@itim-cj.ro; Bot, A., E-mail: gabriela.cristea@itim-cj.ro; Mirel, V., E-mail: gabriela.cristea@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

    2013-11-13

    Isotopic Ratio Mass Spectrometry (IRMS) is an effective toll to be used for drug product authentication. The isotopic composition could be used to assist in the differentiation between batches of drugs and assist in the identification of counterfeit materials on the market. Only two factors affect the isotopic ratios in pharmaceutical components: the isotopic composition of the raw materials and the synthetic processes performed upon them. Counterfeiting of pharmaceutical drugs threatens consumer confidence in drug products companies' economical well-being. In this preliminary study, the analyzed samples consist in two types of commercially available analgesics, which were purchases from Romanian pharmacies. Differences in ?{sup 13}C between batches from ?29.7 to ?31.6% were observed, demonstrating that this method can be used to differentiate among individual drug batches and subsequently identify counterfeits on the market. On the other hand, carbon isotopic ratios differences among producers were recorded, the variations being between ?31.3 to ?34.9% for the same type of analgesic, but from different manufactures.

  1. On the origin of the lightest Molybdenum isotopes

    E-Print Network [OSTI]

    Jacob Lund Fisker; Robert D. Hoffman; Jason Pruet

    2009-01-15

    We discuss implications of recent precision measurements for the Rh93 proton separation energy for the production of the lightest molybdenum isotopes in proton-rich type II supernova ejecta. It has recently been shown that a novel neutrino-induced process makes these ejecta a promising site for the production of the light molybdenum isotopes and other "p-nuclei" with atomic mass near 100. The origin of these isotopes has long been uncertain. A distinguishing feature of nucleosynthesis in neutrino-irradiated outflows is that the relative production of Mo92 and Mo94 is set by a competition governed by the proton separation energy of Rh93. We use detailed nuclear network calculations and the recent experimental results for this proton separation energy to place constraints on the outflow characteristics that produce the lightest molybdenum isotopes in their solar proportions. It is found that for the conditions calculated in recent two-dimensional supernova simulations, and also for a large range of outflow characteristics around these conditions, the solar ratio of Mo92 to Mo94 cannot be achieved. This suggests that either proton-rich winds from type II supernova do not exclusively produce both isotopes, or that these winds are qualitatively different than calculated in today's supernova models.

  2. Isotope exchange kinetics in metal hydrides I : TPLUG model.

    SciTech Connect (OSTI)

    Larson, Rich; James, Scott Carlton; Nilson, Robert H.

    2011-05-01

    A one-dimensional isobaric reactor model is used to simulate hydrogen isotope exchange processes taking place during flow through a powdered palladium bed. This simple model is designed to serve primarily as a platform for the initial development of detailed chemical mechanisms that can then be refined with the aid of more complex reactor descriptions. The one-dimensional model is based on the Sandia in-house code TPLUG, which solves a transient set of governing equations including an overall mass balance for the gas phase, material balances for all of the gas-phase and surface species, and an ideal gas equation of state. An energy equation can also be solved if thermodynamic properties for all of the species involved are known. The code is coupled with the Chemkin package to facilitate the incorporation of arbitrary multistep reaction mechanisms into the simulations. This capability is used here to test and optimize a basic mechanism describing the surface chemistry at or near the interface between the gas phase and a palladium particle. The mechanism includes reversible dissociative adsorptions of the three gas-phase species on the particle surface as well as atomic migrations between the surface and the bulk. The migration steps are more general than those used previously in that they do not require simultaneous movement of two atoms in opposite directions; this makes possible the creation and destruction of bulk vacancies and thus allows the model to account for variations in the bulk stoichiometry with isotopic composition. The optimization code APPSPACK is used to adjust the mass-action rate constants so as to achieve the best possible fit to a given set of experimental data, subject to a set of rigorous thermodynamic constraints. When data for nearly isothermal and isobaric deuterium-to-hydrogen (D {yields} H) and hydrogen-to-deuterium (H {yields} D) exchanges are fitted simultaneously, results for the former are excellent, while those for the latter show pronounced deviations at long times. These discrepancies can be overcome by postulating the presence of a surface poison such as carbon monoxide, but this explanation is highly speculative. When the method is applied to D {yields} H exchanges intentionally poisoned by known amounts of CO, the fitting results are noticeably degraded from those for the nominally CO-free system but are still tolerable. When TPLUG is used to simulate a blowdown-type experiment, which is characterized by large and rapid changes in both pressure and temperature, discrepancies are even more apparent. Thus, it can be concluded that the best use of TPLUG is not in simulating realistic exchange scenarios, but in extracting preliminary estimates for the kinetic parameters from experiments in which variations in temperature and pressure are intentionally minimized.

  3. Simple, rapid method for the preparation of isotopically labeled formaldehyde

    DOE Patents [OSTI]

    Hooker, Jacob Matthew (Port Jefferson, NY); Schonberger, Matthias (Mains, DE); Schieferstein, Hanno (Aabergen, DE); Fowler, Joanna S. (Bellport, NY)

    2011-10-04

    Isotopically labeled formaldehyde (*C.sup..sctn.H.sub.2O) is prepared from labeled methyl iodide (*C.sup..sctn.H.sub.3I) by reaction with an oxygen nucleophile having a pendant leaving group. The mild and efficient reaction conditions result in good yields of *C.sup..sctn.H.sub.2O with little or no *C isotopic dilution. The simple, efficient production of .sup.11CH.sub.2O is described. The use of the .sup.11CH.sub.2O for the formation of positron emission tomography tracer compounds is described. The reaction can be incorporated into automated equipment available to radiochemistry laboratories. The isotopically labeled formaldehyde can be used in a variety of reactions to provide radiotracer compounds for imaging studies as well as for scintillation counting and autoradiography.

  4. Rare Isotopes in Cosmic Explosions and Accelerators on Earth

    ScienceCinema (OSTI)

    Schatz, Hendrick [Michigan State University, East Lansing, Michigan, United States

    2010-01-08

    Rare isotopes are nature?s stepping stones to produce the heavy elements, and they are produced in large quantities in stellar explosions. Despite their fleeting existence, they shape the composition of the universe and the observable features of stellar explosions. The challenge for nuclear science is to produce and study the very same rare isotopes so as to understand the origin of the elements and a range of astronomical observations. I will review the progress that has been made to date in astronomy and nuclear physics, and the prospects of finally addressing many of the outstanding issues with the future Facility for Rare Isotope Beams (FRIB), which DOE will build at Michigan State University.

  5. AFCI Fuel Irradiation Test Plan, Test Specimens AFC-1Æ and AFC-1F

    SciTech Connect (OSTI)

    D. C. Crawford; S. L. Hayes; B. A. Hilton; M. K. Meyer; R. G. Ambrosek; G. S. Chang; D. J. Utterbeck

    2003-11-01

    The U. S. Advanced Fuel Cycle Initiative (AFCI) seeks to develop and demonstrate the technologies needed to transmute the long-lived transuranic actinide isotopes contained in spent nuclear fuel into shorter-lived fission products, thereby dramatically decreasing the volume of material requiring disposition and the long-term radiotoxicity and heat load of high-level waste sent to a geologic repository (DOE, 2003). One important component of the technology development is actinide-bearing transmutation fuel forms containing plutonium, neptunium, americium (and possibly curium) isotopes. There are little irradiation performance data available on non-fertile fuel forms, which would maximize the destruction rate of plutonium, and low-fertile (i.e., uranium-bearing) fuel forms, which would support a sustainable nuclear energy option. Initial scoping level irradiation tests on a variety of candidate fuel forms are needed to establish a transmutation fuel form design and evaluate deployment of transmutation fuels.

  6. Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

    E-Print Network [OSTI]

    2010-01-01

    and stable isotope compositions of natural gas hydrates: acarbon isotopic composition of methane from natural gases of

  7. Pb Isotopes as an Indicator of the Asian Contribution to Particulate Air Pollution in Urban California

    SciTech Connect (OSTI)

    Ewing, Stephanie A.; Christensen, John N.; Brown, Shaun T.; Vancuren, Richard A.; Cliff, Steven S.; DePaolo, Donald J.

    2010-10-25

    During the last two decades, expanding industrial activity in east Asia has led to increased production of airborne pollutants that can be transported to North America. Previous efforts to detect this trans-Pacific pollution have relied upon remote sensing and remote sample locations. We tested whether Pb isotope ratios in airborne particles can be used to directly evaluate the Asian contribution to airborne particles of anthropogenic origin in western North America, using a time series of samples from a pair of sites upwind and downwind of the San Francisco Bay Area. Our results for airborne Pb at these sites indicate a median value of 29 Asian origin, based on mixing relations between distinct regional sample groups. This trans-Pacific Pb is present in small quantities but serves as a tracer for airborne particles within the growing Asian industrial plume. We then applied this analysis to archived samples from urban sites in central California. Taken together, our results suggest that the analysis of Pb isotopes can reveal the distribution of airborne particles affected by Asian industrial pollution at urban sites in northern California. Under suitable circumstances, this analysis can improve understanding of the global transport of pollution, independent of transport models.

  8. Low-temperature chemistry between water and hydroxyl radicals: H/D isotopic effects

    E-Print Network [OSTI]

    Lamberts, T; Puletti, F; Ioppolo, S; Cuppen, H M; Linnartz, H

    2015-01-01

    Sets of systematic laboratory experiments are presented -- combining Ultra High Vacuum cryogenic and plasma-line deposition techniques -- that allow us to compare H/D isotopic effects in the reaction of H2O (D2O) ice with the hydroxyl radical OD (OH). The latter is known to play a key role as intermediate species in the solid-state formation of water on icy grains in space. The main finding of our work is that the reaction H2O + OD --> OH + HDO occurs and that this may affect the HDO/H2O abundances in space. The opposite reaction D2O + OH --> OD + HDO is much less effective, and also given the lower D2O abundances in space not expected to be of astronomical relevance. The experimental results are extended to the other four possible reactions between hydroxyl and water isotopes and are subsequently used as input for Kinetic Monte Carlo simulations. This way we interpret our findings in an astronomical context, qualitatively testing the influence of the reaction rates.

  9. Shell structure of potassium isotopes deduced from their magnetic moments

    E-Print Network [OSTI]

    J. Papuga; M. L. Bissell; K. Kreim; C. Barbieri; K. Blaum; M. De Rydt; T. Duguet; R. F. Garcia Ruiz; H. Heylen; M. Kowalska; R. Neugart; G. Neyens; W. Nortershauser; M. M. Rajabali; R. Sanchez; N. Smirnova; V. Soma; D. T. Yordanov

    2014-10-03

    \\item[Background] Ground-state spins and magnetic moments are sensitive to the nuclear wave function, thus they are powerful probes to study the nuclear structure of isotopes far from stability. \\item[Purpose] Extend our knowledge about the evolution of the $1/2^+$ and $3/2^+$ states for K isotopes beyond the $N = 28$ shell gap. \\item[Method] High-resolution collinear laser spectroscopy on bunched atomic beams. \\item[Results] From measured hyperfine structure spectra of K isotopes, nuclear spins and magnetic moments of the ground states were obtained for isotopes from $N = 19$ up to $N = 32$. In order to draw conclusions about the composition of the wave functions and the occupation of the levels, the experimental data were compared to shell-model calculations using SDPF-NR and SDPF-U effective interactions. In addition, a detailed discussion about the evolution of the gap between proton $1d_{3/2}$ and $2s_{1/2}$ in the shell model and {\\it{ab initio}} framework is also presented. \\item[Conclusions] The dominant component of the wave function for the odd-$A$ isotopes up to $^{45}$K is a $\\pi 1d_{3/2}^{-1}$ hole. For $^{47,49}$K, the main component originates from a $\\pi 2s_{1/2}^{-1}$ hole configuration and it inverts back to the $\\pi 1d_{3/2}^{-1}$ in $^{51}$K. For all even-$A$ isotopes, the dominant configuration arises from a $\\pi 1d_{3/2}^{-1}$ hole coupled to a neutron in the $\

  10. Quantifying Uranium Isotope Ratios Using Resonance Ionization Mass Spectrometry: The Influence of Laser Parameters on Relative Ionization Probability

    E-Print Network [OSTI]

    Isselhardt, Brett Hallen

    2011-01-01

    4.5 Uranium Isotope Ratio Measurements . . . . . .4.32 Uranium sputtered from three U-rich materials of varying uranium isotopic

  11. DESIGN OF A SUBCRITICAL AQUEOUS TARGET SYSTEM FOR MEDICAL ISOTOPE PRODUCTION 

    E-Print Network [OSTI]

    Vega, Richard Manuel

    2013-12-10

    The United States consumes almost half of all medical isotopes produced worldwide, and relies on foreign sources for nearly its entire supply. These isotopes are produced in nuclear reactors which are very costly to construct. A domestic supply may...

  12. Lead Isotopic Variations of the Pacific and Implications for Paleogene Water Mass Composition 

    E-Print Network [OSTI]

    Subt, Cristina

    2013-11-13

    meridional temperature gradients. Nd isotopes indicate high-latitude convection in the Pacific Ocean during this interval, with deep waters mixing in the tropical Pacific. Here we investigate the evolution of the Pb isotopic composition of water masses...

  13. Uranium-series isotope and thermal constraints on the rate and depth of silicic magma genesis

    E-Print Network [OSTI]

    Sandiford, Mike

    Uranium-series isotope and thermal constraints on the rate and depth of silicic magma genesis A Sciences, University of Durham, South Road, Durham DH1 3LE, UK Abstract: Uranium-series isotopes provide

  14. Intramolecular Isotope Effects for the Study of Reactions with MassTransfer Limitations 

    E-Print Network [OSTI]

    Wagner, Joshua G.

    2010-01-16

    The research presented provides a method to use the comparison of intermolecular isotope effects vs. the intramolecular isotope effects for the study of reactions in which study of the rate limiting step is ambiguous due to interfering mass transfer...

  15. CARBON ISOTOPE STRATIGRAPHY AND DIAGENESIS OF PENNSYLVANIAN (DESMOINESIAN-MISSOURIAN) CARBONATES IN EAST-CENTRAL IDAHO 

    E-Print Network [OSTI]

    Wood, Stephanie

    2011-05-10

    Carbon isotope stratigraphy of carbonate sediments is instrumental in examining major perturbations in the global carbon cycle and in correlating strata. However, the primary isotopic signal recorded in these sediments can vary with depositional...

  16. Tuesday, March 24, 2009 POSTER SESSION I: EARLY NEBULAR PROCESSES: MODELS AND ISOTOPES

    E-Print Network [OSTI]

    Rathbun, Julie A.

    to H2O in adsorption/desorption kinetics. Nielsen S. G. Prytulak J. Halliday A. N. Vanadium Isotope presents the first method that produces high precision vanadium isotope data for terrestrial rocks

  17. Fragment Isotope Distributions and the Isospin Dependent Equation of State

    E-Print Network [OSTI]

    W. P. Tan; B-A. Li; R. Donangelo; C. K. Gelbke; M-J. van Goetherm; X. D. Liu; W. G. Lynch; S. Souza; M. B. Tsang; G. Verde; A. Wagner; N. S. Xu

    2001-04-21

    Calculations predict a connection between the isotopic composition of particles emitted during an energetic nucleus-nucleus collision and the density dependence of the asymmetry term of the nuclear equation of state (EOS). This connection is investigated for central 112Sn+112Sn and 124Sn+124Sn collisions at E/A=50 MeV in the limit of an equilibrated freezeout condition. Comparisons between measured isotopic yields ratios and theoretical predictions in the equilibrium limit are used to assess the sensitivity to the density dependence of the asymmetry term of the EOS. This analysis suggests that such comparisons may provide an opportunity to constrain the asymmetry term of the EOS.

  18. Equations of state and phase diagrams of hydrogen isotopes

    SciTech Connect (OSTI)

    Urlin, V. D.

    2013-11-15

    A new form of the semiempirical equation of state proposed for the liquid phase of hydrogen isotopes is based on the assumption that its structure is formed by cells some of which contain hydrogen molecules and others contain hydrogen atoms. The values of parameters in the equations of state of the solid (molecular and atomic) phases as well as of the liquid phase of hydrogen isotopes (protium and deuterium) are determined. Phase diagrams, shock adiabats, isentropes, isotherms, and the electrical conductivity of compressed hydrogen are calculated. Comparison of the results of calculations with available experimental data in a wide pressure range demonstrates satisfactory coincidence.

  19. Shape transition in the even-even Cerium isotopes

    E-Print Network [OSTI]

    B. Mohammed-Azizi; A. Helmaoui; D. E. Medjadi

    2015-04-29

    The deformation energy of the even-even nuclei of the Cerium isotopic chain is investigated by means of the Macroscopic-Microscopic method with a semi-classical shell correction. We consider axially symmetric shapes. Binding energy and two neutron separation energy are also evaluated. For the sake of clarity several important details of the calculations are also given. It turns out that all these nuclei have prolate equilibrium shape. The regions of maximum deformation are obtained around N=64 and N=102. There is no critical-point of quantum phase transition in this isotopic chain.

  20. Atomic vapor laser isotope separation using resonance ionization

    SciTech Connect (OSTI)

    Comaskey, B.; Crane, J.; Erbert, G.; Haynam, C.; Johnson, M.; Morris, J.; Paisner, J.; Solarz, R.; Worden, E.

    1986-09-01

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power-reactor fuel has been under development for over 10 years. In June 1985, the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for enriched uranium. Resonance photoionization is the heart of the AVLIS process. We discuss those fundamental atomic parameters that are necessary for describing isotope-selective resonant multistep photoionization along with the measurement techniques that we use. We illustrate the methodology adopted with examples of other elements that are under study in our program.

  1. Isotope powered Stirling generator for terrestrial applications

    SciTech Connect (OSTI)

    Tingey, G.L.; Sorensen, G.C.; Ross, B.A.

    1995-01-01

    An electric power supply, small enough to be man-portable, is being developed for remote, terrestrial applications. This system is designed for an operating lifetime of five years without maintenance or refueling. A small Radioisotope Stirling Generator (RSG) has been developed. The energy source of the generator is a 60 watt plutonium-238 fuel clad used in the General Purpose Heat Sources (GPHS) developed for space applications. A free piston Stirling Engine drives a linear alternator to convert the heat to power. The system weighs about 7.5 kg and produces 11 watts AC power with a conversion efficiency of 18.5%. Two engine models have been designed, fabricated, and tested to date: (a) a developmental model instrumented to confirm and test parameters, and (b) an electrically heated model with an electrical heater equipped power input leads. Critical components have been tested for 10,000 to 20,000 hours. One complete generator has been operating for over 11,000 hours. Radioisotope heated prototypes are expected to be fabricated and tested in late 1995.

  2. Method for enriching a middle isotope using vibration-vibration pumping

    DOE Patents [OSTI]

    Rich, Joseph W. (East Aurora, NY); Homicz, Gregory F. (Getzville, NY); Bergman, Richard C. (Corfu, NY)

    1989-01-01

    Method for producing isotopically enriched material by vibration-vibration excitation of gaseous molecules wherein a middle mass isotope of an isotopic mixture including lighter and heavier mass isotopes preferentially populates a higher vibrational mode and chemically reacts to provide a product in which it is enriched. The method can be used for vibration-vibration enrichment of .sup.17 O in a CO reactant mixture.

  3. Dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources

    DOE Patents [OSTI]

    Barty, Christopher P.J.

    2013-02-05

    A dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources includes a detector arrangement consists of three detectors downstream from the object under observation. The latter detector, which operates as a beam monitor, is an integrating detector that monitors the total beam power arriving at its surface. The first detector and the middle detector each include an integrating detector surrounding a foil. The foils of these two detectors are made of the same atomic material, but each foil is a different isotope, e.g., the first foil may comprise U235 and second foil may comprise U238. The integrating detectors surrounding these pieces of foil measure the total power scattered from the foil and can be similar in composition to the final beam monitor. Non-resonant photons will, after calibration, scatter equally from both foils.

  4. Verifying Test Hypotheses -HOL/TestGen Verifying Test Hypotheses -HOL/TestGen

    E-Print Network [OSTI]

    Verifying Test Hypotheses - HOL/TestGen Verifying Test Hypotheses - HOL/TestGen An Experiment in Test and Proof Thomas Malcher January 20, 2014 1 / 20 #12;Verifying Test Hypotheses - HOL/TestGen HOL/TestGen Outline Introduction Test Hypotheses HOL/TestGen - Demo Verifying Test Hypotheses Conclusion 2 / 20 #12

  5. LEAD ISOTOPIC ANALYSIS FOR THE IDENTIFICATION OF LATE BRONZE AGE POTTERY FROM HALA SULTAN

    E-Print Network [OSTI]

    Claeys, Philippe

    LEAD ISOTOPIC ANALYSIS FOR THE IDENTIFICATION OF LATE BRONZE AGE POTTERY FROM HALA SULTAN TEKKE, 9000 Ghent 5 Department of Geology, Université de Liège, Allée du 6­Août B18, 4000 Liège Lead isotopic the effectiveness of using lead isotopic analysis in provenance studies, along with other analytical techniques

  6. Lead isotopes in sediments of the Loire River (France): natural versus anthropogenic origin

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Lead isotopes in sediments of the Loire River (France): natural versus anthropogenic origin France) were investigated by means of lead isotopes determined on the labile sediment fraction, or acid-extractable matter (AEM). The combination of trace elements and lead isotopes allows deciphering the origin

  7. COUPLING LEAD ISOTOPE ANALYSIS AND PETROGRAPHY TO CHARACTERIZE FABRICS OF STORAGE AND TRADE

    E-Print Network [OSTI]

    Claeys, Philippe

    COUPLING LEAD ISOTOPE ANALYSIS AND PETROGRAPHY TO CHARACTERIZE FABRICS OF STORAGE AND TRADE Brussels, Belgium 6 Director of research at Hala Sultan Tekke, Area 8, Cyprus Lead isotopes, thin sections and com- pared to lead isotope results on the same samples. This study shows that a specific

  8. Dynamic isotope effect on the product energy partitioning in CH2OH ~CHO H2

    E-Print Network [OSTI]

    Kim, Myung Soo

    Dynamic isotope effect on the product energy partitioning in CH2OH ~CHO H2 Young Min Rheea March 1998; accepted 1 July 1998 The deuterium isotope effect on the product energy partitioning. Close inspection of the potential energy surface revealed that the isotope effect on KER and the product

  9. Hydrogen isotopic variability in leaf waxes among terrestrial and aquatic plants around Blood Pond, Massachusetts (USA)

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    Hydrogen isotopic variability in leaf waxes among terrestrial and aquatic plants around Blood Pond interpretation of the hydrogen isotope ratios of plant leaf waxes extracted from sediments requires a thor- ough at a single site to determine how leaf wax hydro- gen isotope (D/H) ratios differ in different plant types

  10. Hydrogen isotope fractionation in freshwater algae: I. Variations among lipids and species

    E-Print Network [OSTI]

    Sachs, Julian P.

    Hydrogen isotope fractionation in freshwater algae: I. Variations among lipids and species Zhaohui in media containing different concentrations of deuterium. The hydrogen isotopic ratios of lipids that lipid dD values can be used to determine water dD values, hydrogen isotope fractionation was found

  11. Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying Holocene climate change in

    E-Print Network [OSTI]

    Hren, Michael

    Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying Holocene isotopes of goethite from ferricrete deposits were measured from both northern and southern Rocky Mountain in oxygen isotope values of 14 C-dated goethites in the northern Rocky Mountains suggests a regional

  12. Using phylogenetic probes for quantification of stable isotope labeling and microbial community analysis

    DOE Patents [OSTI]

    Brodie, Eoin L; DeSantis, Todd Z; Karaoz, Ulas; Andersen, Gary L

    2014-12-09

    Herein is described methods for a high-sensitivity means to measure the incorporation of stable isotope labeled substrates into RNA following stable isotope probing experiments (SIP). RNA is hybridized to a set of probes such as phylogenetic microarrays and isotope incorporation is quantified such as by secondary ion mass spectrometer imaging (NanoSIMS).

  13. Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jeff Heikoop; Heather Throckmorton

    2015-05-15

    Dataset includes nitrate concentrations for polygonal active layer samples, snowmelt; ammonium concentrations for active layer samples; nitrate isotopes for active layer samples, snowmelt, permafrost; ammonium isotopes for active layer samples; and nitrogen isotopes for soils and dissolved organic nitrogen extracted from soil pore waters.

  14. Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jeff Heikoop; Heather Throckmorton

    Dataset includes nitrate concentrations for polygonal active layer samples, snowmelt; ammonium concentrations for active layer samples; nitrate isotopes for active layer samples, snowmelt, permafrost; ammonium isotopes for active layer samples; and nitrogen isotopes for soils and dissolved organic nitrogen extracted from soil pore waters.

  15. An intramolecular theory of the mass-independent isotope effect for ozone. I.

    E-Print Network [OSTI]

    Hathorn, Bryan C.

    An intramolecular theory of the mass-independent isotope effect for ozone. I. B. C. Hathorn and R-independent isotope effect for ozone formation and dissociation is described. The experiments include the enrichment and asymmetric ozone isotopomers, the enrichment of ozone formed from heavily enriched oxygen isotopes

  16. Carbon Isotope Constraints on the Deglacial CO2 Rise from Ice Cores

    E-Print Network [OSTI]

    Stocker, Thomas

    controls the isotopic fractionation during air/sea gas exchange. The continuous rain of isotopically light carbon storage, which result in a net change in the carbon isotopic composition of the ocean--EPICA (Europe- an Project for Ice Coring in Antarctica) Dome C and Talos Dome--performed with three independent

  17. Lithium isotopic systematics of granites and pegmatites from the Black Hills, South Dakota

    E-Print Network [OSTI]

    Rudnick, Roberta L.

    Lithium isotopic systematics of granites and pegmatites from the Black Hills, South Dakota Fang compositions may reflect Li isotopic fractionation resulting from extensive crystal-melt fractionation. Lithium fractionation in the near­surface environment of > 60 (Tomascak, 2004). Lithium isotopic fractionation has been

  18. Extreme lithium isotopic fractionation during continental weathering revealed in saprolites from South Carolina

    E-Print Network [OSTI]

    Rudnick, Roberta L.

    Extreme lithium isotopic fractionation during continental weathering revealed in saprolites from in revised form 6 July 2004 Abstract The lithium concentration and isotopic composition of two saprolites the behavior of lithium isotopes during continental weathering. Both saprolites show a general trend

  19. Nitrogen isotope dynamics of the Cariaco Basin, Venezuela Robert C. Thunell,1

    E-Print Network [OSTI]

    Sigman, Daniel M.

    Nitrogen isotope dynamics of the Cariaco Basin, Venezuela Robert C. Thunell,1 Daniel M. Sigman,2 of Venezuela. Water column denitrification occurring in the basin has only a very small isotopic imprint-Karger, Y. Astor, and R. Varela (2004), Nitrogen isotope dynamics of the Cariaco Basin, Venezuela, Global

  20. Stable-carbon isotope composition of Poaceae pollen: an assessment for

    E-Print Network [OSTI]

    Hu, Feng Sheng

    2006 Abstract: Plants using the C3 and C4 photosynthetic pathways differ in carbon-isotope composition-isotope compositions primarily because they use different enzymes for initial carbon fixation: ribulose-1Stable-carbon isotope composition of Poaceae pollen: an assessment for reconstructing C3 and C4

  1. Physical controls on the isotopic composition of soil-respired CO2

    E-Print Network [OSTI]

    Physical controls on the isotopic composition of soil-respired CO2 Nick Nickerson1 and Dave Risk1] Measurement of the isotopic composition of soil and soil-respired CO2 (d13 CO2) has become an invaluable tool in understanding the effects of diffusive transport on soil CO2 isotopic composition, it is crucial

  2. Discovery of Isotopes of the Transuranium Elements with 93 <= Z <= 98

    E-Print Network [OSTI]

    C. Fry; M. Thoennessen

    2012-04-26

    One hundred and five isotopes of the transuranium elements neptunium, plutonium, americium, curium, berkelium and californium have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  3. Holocene precipitation seasonality captured by a dual hydrogen and oxygen isotope approach at Steel Lake, Minnesota

    E-Print Network [OSTI]

    Hu, Feng Sheng

    Holocene precipitation seasonality captured by a dual hydrogen and oxygen isotope approach at SteelMenocal Keywords: seasonal precipitation middle Holocene oxygen isotopes hydrogen isotopes forest­prairie boundary midcontinental North America. However, neither the climatic driver nor the seasonal character of precipitation

  4. Comparison of isotopic transmutation modelling codes 

    E-Print Network [OSTI]

    Beard, Carl Allen

    1990-01-01

    test case involved modelling a fission pulse, while the second concerned the modelling of a long irradiation period. CINDER-10 was found to utilize an analytically based solution scheme allowing it to correctly model nearly all possible nuclear... Contribution of Fission Products to Total Decay Heat at a Cooling Time of 10 Seconds Due to a Fission Pulse . . . . . . . . . . . 30 Contribution of Fission Products tg Total Decay Heat at a Cooling Time of 10 Seconds Due to a Fission Pulse 31 III...

  5. Isotopic evidence for Mesoarchaean anoxia and changing atmospheric sulphur chemistry

    E-Print Network [OSTI]

    Kaufman, Alan Jay

    LETTERS Isotopic evidence for Mesoarchaean anoxia and changing atmospheric sulphur chemistry James changes in pre-2.45-Gyr-ago atmospheric pathways for non-mass-dependent chemistry and in the ultraviolet J. Kaufman1 The evolution of the Earth's atmosphere is marked by a transition from an early

  6. Carbon and Hydrogen Isotopic Effects in Microbial Methane

    E-Print Network [OSTI]

    Saleska, Scott

    6 Carbon and Hydrogen Isotopic Effects in Microbial Methane from Terrestrial Environments Jeffrey Chanton, Lia Chaser, Paul Glasser,Don Siegel Methane is the ultimate end-product of anaerobic respiration. Methane production via CO2 reduction does not consume CO2. Also, acetate can be written as 2CH20, so Eq. 6

  7. CRAD, Management- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Management in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  8. Apparatus and method for monitoring of gas having stable isotopes

    DOE Patents [OSTI]

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  9. Use of Strontium Isotopes to Identify Buried Water Main Leakage

    E-Print Network [OSTI]

    Jiao, Jiu Jimmy

    Use of Strontium Isotopes to Identify Buried Water Main Leakage Into Groundwater in a Highly water mains. The identification of leakage locations was done by conventional water quality parameters to identify leakage locations especially where the leakage is from drinking water mains because the chemical

  10. Examining the stability of thermally fissile Th and U isotopes

    E-Print Network [OSTI]

    Kumar, Bharat; Singh, S K; Patra, S K

    2015-01-01

    The properties of recently predicted thermally fissile Th and U isotopes are studied within the framework of relativistic mean field (RMF) approach using axially deformed basis. We calculated the ground, first intrinsic excited state and matter density for highly neutron-rich thorium and uranium isotopes. The possible modes of decay like $\\alpha$-decay and $\\beta$-decay are analyzed. We found that the neutron-rich isotopes are stable against $\\alpha$-decay, however they are very much unstable against $\\beta$-decay. The life time of these nuclei predicted to be tens of second against $\\beta$-decay. If these nuclei utilize before their decay time, a lots of energy can be produced within the help of multi-fragmentation fission. Also, these nuclei have a great implication in astrophysical point of view. The total nucleonic densities distribution are calculated, from which the clusters inside the parent nuclei are determined. %Most of the thorium isotopes are $\\alpha$ emitters, where as some %of them have short ha...

  11. Rare Isotope Beams for the 21st Century

    ScienceCinema (OSTI)

    James Symons

    2010-01-08

    In a scientific keynote address on Friday, June 12 at Michigan State University (MSU) in East Lansing, James Symons, Director of Berkeley Labs Nuclear Science Division (NSD), discussed the exciting research prospects of the new Facility for Rare Isotope Beams (FRIB) to be built at MSUs National Superconducting Cyclotron Laboratory.

  12. CRAD, Engineering- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Engineering Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  13. CRAD, Training- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Training Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  14. (Carbon isotope fractionation in plants): Annual technical progress report

    SciTech Connect (OSTI)

    O'Leary, M.H.

    1988-01-01

    Plants fractionate carbon isotopes during photosynthesis in ways which reflect photosynthetic pathway and environment. The fractionation is product of contributions from diffusion, carboxylation and other factors which can be understood using models which have been developed in our work. The object of our work is to use this fractionation to learn about the factors which control the efficiency of photosynthesis. Unlike previous studies, we do not rely principally on combustion methods, but instead develop more specific methods with substantially higher resolving power. We have recently developed a new short-term method for studying carbon isotope fractionation which promises to provide a level of detail about temperature, species, and light intensity effects on photosynthesis which has not been available until now. We are studying the isotopic compositions of metabolites (particularly aspartic acid) in C/sub 3/ plants in order to determine the role of phosphoenolpyruvate carboxylase in C/sub 3/ photosynthesis. We are studying the relative roles of diffusion and carboxylation in nocturnal CO/sub 2/ fixation in CAM plants. We are studying the use of isotopic content as an index of water-use efficiency in C/sub 3/ plants. We are developing new methods for studying carbon metabolism in plants. 3 refs

  15. Method of enhancing selective isotope desorption from metals

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1983-07-26

    This invention relates generally to the field of gas desorption from metals; and, more particularly, to a method of enhancing the selective desorption of a particular isotope of a gas from metals. Enhanced selective desorption is especially useful in the operation of fusion devices.

  16. 14. CARBON AND OXYGEN ISOTOPE ANALYSIS OF LAKE SEDIMENT CELLULOSE

    E-Print Network [OSTI]

    Edwards, Thomas W.D.

    14. CARBON AND OXYGEN ISOTOPE ANALYSIS OF LAKE SEDIMENT CELLULOSE: METHODS AND APPLICATIONS BRENT B and Environmental Sciences Wesleyan University, Middletown, CT USA 06459 Keywords: cellulose, lake sediment, oxygen of lake sediment cellulose is a recently developed paleolimnological approach that is gaining increasing

  17. Hydrogen Isotopic (D/H) Composition of Organic Matter

    E-Print Network [OSTI]

    Sessions, Alex L.

    Hydrogen Isotopic (D/H) Composition of Organic Matter During Diagenesis and Thermal Maturation difficult to interpret because the effects of hydrogen exchange and kinetic fractionations are confounded- crease in the D/H ratio of most organic hydrogen at the bulk and molecular levels, and suggest

  18. Advancement of isotope separation for the production of reference standards

    SciTech Connect (OSTI)

    Jared Horkley; Christopher McGrath; Andrew Edwards; Gaven Knighton; Kevin Carney; Jacob Davies; James Sommers; Jeffrey Giglio

    2012-03-01

    Idaho National Laboratory (INL) operates a mass separator that is currently producing high purity isotopes for use as internal standards for high precision isotope dilution mass spectrometry (IDMS). In 2008, INL began the revival of the vintage 1970’s era instrument. Advancements thus far include the successful upgrading and development of system components such as the vacuum system, power supplies, ion-producing components, and beam detection equipment. Progress has been made in the separation and collection of isotopic species including those of Ar, Kr, Xe, Sr, and Ba. Particular focuses on ion source improvements and developments have proven successful with demonstrated output beam currents of over 10 micro-amps 138Ba and 350nA 134Ba from a natural abundance source charge (approximately 2.4 percent 134Ba). In order to increase production and collection of relatively high quantities (mg levels) of pure isotopes, several advancements have been made in ion source designs, source material introduction, and beam detection and collection. These advancements and future developments will be presented.

  19. PLUTONIUM ISOTOPES I N THE NORTH ATLANTIC KEN 0. BUESSELER

    E-Print Network [OSTI]

    Buesseler, Ken

    PLUTONIUM ISOTOPES I N THE NORTH ATLANTIC by KEN 0. BUESSELER B.A., University of California The a r t i f i c i a l radionuclide Plutonium (Pu) has been introduced i n t o the environment p r i m

  20. Quantum origin of an anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Quantum origin of an anomalous isotope effect in ozone formation D. Babikov *, B.K. Kendrick, R mechanical calculations of the ðJ ¼ 0Þ energies and lifetimes of the metastable states of ozone on a new effect in the reaction that forms ozone because of their role in the energy transfer mechanism, in which

  1. Constraining magnesium cycling in marine sediments using magnesium isotopes

    E-Print Network [OSTI]

    Paytan, Adina

    . Extensive sampling of sedimentary pore-fluids by the Deep Sea Drilling Project (DSDP) and Ocean Drilling Abstract Magnesium concentrations in deep-sea sediment pore-fluids typically decrease down core due to net and differentiate these processes, we have measured magnesium isotopes in pore-fluids and sediment samples from

  2. CRAD, Maintenance- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Maintenance Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  3. Ab Initio Nuclear Structure and Reaction Calculations for Rare Isotopes

    SciTech Connect (OSTI)

    Draayer, Jerry P.

    2014-09-28

    We have developed a novel ab initio symmetry-adapted no-core shell model (SA-NCSM), which has opened the intermediate-mass region for ab initio investigations, thereby providing an opportunity for first-principle symmetry-guided applications to nuclear structure and reactions for nuclear isotopes from the lightest p-shell systems to intermediate-mass nuclei. This includes short-lived proton-rich nuclei on the path of X-ray burst nucleosynthesis and rare neutron-rich isotopes to be produced by the Facility for Rare Isotope Beams (FRIB). We have provided ab initio descriptions of high accuracy for low-lying (including collectivity-driven) states of isotopes of Li, He, Be, C, O, Ne, Mg, Al, and Si, and studied related strong- and weak-interaction driven reactions that are important, in astrophysics, for further understanding stellar evolution, X-ray bursts and triggering of s, p, and rp processes, and in applied physics, for electron and neutrino-nucleus scattering experiments as well as for fusion ignition at the National Ignition Facility (NIF).

  4. DEMONSTRATION OF THE NEXT-GENERATION TCAP HYDROGEN ISOTOPE SEPARATION PROCESS

    SciTech Connect (OSTI)

    Heung, L; Henry Sessions, H; Steve Xiao, S; Heather Mentzer, H

    2009-01-09

    The first generation of TCAP hydrogen isotope separation process has been in service for tritium separation at the Savannah River Site since 1994. To prepare for replacement, a next-generation TCAP process has been developed. This new process simplifies the column design and reduces the equipment requirements of the thermal cycling system. An experimental twelve-meter column was fabricated and installed in the laboratory to demonstrate its performance. This new design and its initial test results were presented at the 8th International Conference on Tritium Science and Technology and published in the proceedings. We have since completed the startup and demonstration the separation of protium and deuterium in the experimental unit. The unit has been operated for more than 200 cycles. A feed of 25% deuterium in protium was separated into two streams each better than 99.7% purity.

  5. Laser-induced separation of hydrogen isotopes in the liquid phase

    DOE Patents [OSTI]

    Freund, Samuel M. (Los Alamos, NM); Maier, II, William B. (Los Alamos, NM); Beattie, Willard H. (Los Alamos, NM); Holland, Redus F. (Los Alamos, NM)

    1980-01-01

    Hydrogen isotope separation is achieved by either (a) dissolving a hydrogen-bearing feedstock compound in a liquid solvent, or (b) liquefying a hydrogen-bearing feedstock compound, the liquid phase thus resulting being kept at a temperature at which spectral features of the feedstock relating to a particular hydrogen isotope are resolved, i.e., a clear-cut isotope shift is delineated, irradiating the liquid phase with monochromatic radiation of a wavelength which at least preferentially excites those molecules of the feedstock containing a first hydrogen isotope, inducing photochemical reaction in the excited molecules, and separating the reaction product containing the first isotope from the liquid phase.

  6. Strontium Isotopes Test Long-Term Zonal Isolation of Injected and Marcellus

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback System inStatus of the MEICThermometry.nanopillars inFormation

  7. Transient competitive complexation in biological kinetic isotope fractionation explains non-steady isotopic effects: Theory and application to denitrification in soils

    SciTech Connect (OSTI)

    Maggi, F.M.; Riley, W.J.

    2009-06-01

    The theoretical formulation of biological kinetic reactions in isotopic applications often assume first-order or Michaelis-Menten-Monod kinetics under the quasi-steady-state assumption to simplify the system kinetics. However, isotopic e ects have the same order of magnitude as the potential error introduced by these simpli cations. Both formulations lead to a constant fractionation factor which may yield incorrect estimations of the isotopic effect and a misleading interpretation of the isotopic signature of a reaction. We have analyzed the isotopic signature of denitri cation in biogeochemical soil systems by Menyailo and Hungate [2006], where high {sup 15}N{sub 2}O enrichment during N{sub 2}O production and inverse isotope fractionation during N{sub 2}O consumption could not be explained with first-order kinetics and the Rayleigh equation, or with the quasi-steady-state Michaelis-Menten-Monod kinetics. When the quasi-steady-state assumption was relaxed, transient Michaelis-Menten-Monod kinetics accurately reproduced the observations and aided in interpretation of experimental isotopic signatures. These results may imply a substantial revision in using the Rayleigh equation for interpretation of isotopic signatures and in modeling biological kinetic isotope fractionation with first-order kinetics or quasi-steady-state Michaelis-Menten-Monod kinetics.

  8. MONITORING SPENT NUCLEAR FUEL REPROCESSING CONDITIONS NON-DESTRUCTIVELY AND IN NEAR-REAL-TIME USING THE MULTI-ISOTOPE PROCESS (MIP) MONITOR

    SciTech Connect (OSTI)

    Orton, Christopher R.; Fraga, Carlos G.; Douglas, Matthew; Christensen, Richard; Schwantes, Jon M.

    2010-05-07

    Researchers from Pacific Northwest National Laboratory and The Ohio State University are working to develop a system for monitoring spent nuclear fuel reprocessing facilities on-line, nondestructively, and in near-real-time. This method, known as the Multi-Isotope Process (MIP) Monitor, is based upon the measurement of distribution patterns of a suite of indicator (radioactive) isotopes present within product and waste streams of a nuclear reprocessing facility. Signatures from these indicator isotopes are monitored on-line by gamma spectrometry and compared, in near-real-time, to patterns representing "normal" process conditions using multivariate pattern recognition software. By targeting gamma-emitting indicator isotopes, the MIP Monitor approach is compatible with the use of small, portable, high-resolution gamma detectors that may be easily deployed throughout an existing facility. In addition, utilization of a suite of radio-elements, including ones with multiple oxidation states, increases the likelihood that attempts to divert material via process manipulation would be detected. Proof-of-principle modeling exercises simulating changes in acid strength have been completed and the results are promising. Laboratory testing is currently under way and significant results are available. Recent experimental results, along with an overview of the method are presented.

  9. Heavy-atom isotope effects on the acid-catalyzed hydrolysis of methyl benzoate

    SciTech Connect (OSTI)

    Marlier, J.F.; O'Leary, M.H.

    1981-05-08

    Results of the use of a previously reported technique of four-heavy atom isotope effects for study of the acid-catalyzed hydrolysis of methyl benzoate are reported. Ether oxygen and methyl carbon isotope effects on the reaction were measured by the usual natural-abundance isotope-ratio technique. The carbonyl oxygen isotope effect was measured by the pseudo-natural-abundance double-label method as was the carbonyl carbon isotope effect. The results led to the assumption that the hydrolysis of methyl benzoate proceeds by way of a tetrahedral intermediate. The small amount of oxygen exchange with the solvent that accompanies the hydrolysis indicated that it is intermediate formation rather than decomposition that is rate determining. The small magnitude of the observed carbon isotope effect on the acid-catalyzed hydrolysis of methyl benzoate compared to carbon isotope effects on other reactions of this compound indicate that the transition state is relatively reactant-like. (BLM)

  10. OXYGEN ISOTOPE MEASUREMENTS OF A RARE MURCHISON TYPE A CAI AND ITS RIM. J. E. P. , J. I. Simon2

    E-Print Network [OSTI]

    to oxygen isotope zoning profiles measured from CAIs in other chondrites. MUM-1 Petrography: The petrography

  11. Trace element abundances and Sr-Nd-Pb isotopic constraints on the petrogenesis of Juan Fernandez lavas

    E-Print Network [OSTI]

    Truong, Thi Bich

    2015-01-01

    isotope disequilibrium and geochronology of glassy submarineGeochemistry and geochronology of the Society Islands: New

  12. Prototype to Test WHY prototype to test

    E-Print Network [OSTI]

    Prinz, Friedrich B.

    Prototype to Test METHOD WHY prototype to test HOW to prototype to test Prototyping to test or design space. The fundamental way you test your prototypes is by letting users experience them and react to them. In creating prototypes to test with users you have the opportunity to examine your solution

  13. Testing with JUnit Testing with JUnit

    E-Print Network [OSTI]

    Peters, Dennis

    Testing with JUnit Testing with JUnit Running a test case: 1 Get the component to a known state (set up). 2 Cause some event (the test case). 3 Check the behaviour. · Record pass/fail · Track statistics · Typically we want to do a lot of test cases so it makes sense to automate. · Test cases

  14. 137Cs(90Sr) and Pu isotopes in the Pacific Ocean sources & trends

    SciTech Connect (OSTI)

    Hamilton, T.F., Millies-Lacrox, J.C. [Service Mixte de Securite Radologique, Mondhery (France); Hong, G.H. [Korea Ocean Research and Development Institute, Ansan (Korea)

    1996-11-01

    The main source of artificial radioactivity in the world`s oceans can be attributed to worldwide fallout from atmospheric nuclear weapons testing. Measurements of selected artificial radionuclides in the Pacific Ocean were first conducted in the 1960`s where it was observed that fallout radioactivity had penetrated the deep ocean. Extensive studies carried out during the 1973-74 GEOSECS provided the first comprehensive data on the lateral and vertical distributions of {sup 9O}Sr, {sup 137}Cs and Pu isotopes in the Pacific on a basin wide scale. Estimates of radionuclide inventories in excess of amounts predicted to be delivered by global fallout alone were attributed to close-in fallout and tropospheric inputs from early U.S. tests conducted on Bikini and Enewetak Atolls in the Equatorial Pacific. In general, levels of fallout radionuclides (including {sup 9O}Sr, {sup 137}Cs and Pu isotopes) in the surface waters of the Pacific Ocean have decreased considerably over the past 4 decades and are now much more homogeneously distributed. Resuspension and the subsequent deposition of fallout radionuclides from previously deposited debris on land has become an important source term for the surface ocean. This can be clearly seen in measurements of fallout radionuclides in mineral aerosols over the Korean Peninsula (Yellow dust events). Radionuclides may also be transported from land to sea in river runoff-these transport mechanisms are more important in the Pacific Ocean where large quantities of river water and suspended sands/fluvial sediments reach the coastal zone. Another unique source of artificial radionuclides in the Pacific Ocean is derived from the slow resolubilization and transport of radionuclides deposited in contaminated lagoon and slope sediments near U.S. and French test sites. Although there is a small but significant flux of artificial radionuclides depositing on the sea floor, > 80% of the total 239, {sup 240}Pu inventory and > 95% of the total {sup 137}Cs inventory remains in the water column. Studies conducted through the 1980`s appear to be consistent with earlier findings and indicate that radionuclide inventories in mid-northern latitudes are at least a factor of two above those expected from global fallout alone. The long term persistence of close-in and/or stratospheric fallout from nuclear weapons testing in the Marshall Islands still appears to be the only plausible explanation for this anomaly.

  15. Stable Isotope Characterization of TICs/TIMs: Analytical Progress Report

    SciTech Connect (OSTI)

    Volpe, A M; Singleton, M J

    2009-06-05

    We measured twelve alkali cyanide samples that were also sent to ORNL and PNNL collaborators. While results indicate distinct {delta}{sup 13}C and {delta}{sup 15}N values that would be useful to signature studies, the alkali cyanides, especially NaCN, show chemical breakdown during storage that will influence forensic analysis. Carbon and nitrogen stable isotopic compositions of raw materials used to synthesis TETS were measured. Results indicate wide ranges in {delta}{sup 13}C and {delta}{sup 15}N values. Using these raw materials, LLNL scientists synthesized three batches of TETS following published procedures. Stable isotopic measurements of TETS synthesis products indicates nitrogen ({var_epsilon} {sup 15}N = -1.7 to -0.8) and carbon ({var_epsilon} {sup 13}C = -1.0 to -0.1) fractionation during production.

  16. Computer Study of Isotope Production in High Power Accelerators

    E-Print Network [OSTI]

    K. A. Van Riper; S. G. Mashnik; W. B. Wilson

    1999-01-25

    Methods for radionuclide production calculation in a high power proton accelerator have been developed and applied to study production of 22 isotopes by high-energy protons and neutrons. These methods are readily applicable to accelerator, and reactor, environments other than the particular model we considered and to the production of other radioactive and stable isotopes. We have also developed methods for evaluating cross sections from a wide variety of sources into a single cross section set and have produced an evaluated library covering about a third of all natural elements. These methods also are applicable to an expanded set of reactions. A 684 page detailed report on this study, with 37 tables and 264 color figures is available on the Web at http://t2.lanl.gov/publications/publications.html, or, if not accessible, in hard copy from the authors.

  17. Pulsed CO laser for isotope separation of uranium

    SciTech Connect (OSTI)

    Baranov, Igor Y.; Koptev, Andrey V. [Rocket-Space Technics Department, Baltic State Technical University, 1, 1st Krasnoarmeyskaya st.,St. Petersburg, 190005 (Russian Federation)

    2012-07-30

    This article proposes a technical solution for using a CO laser facility for the industrial separation of uranium used in the production of fuel for nuclear power plants, employing a method of laser isotope separation of uranium with condensation repression in a free jet. The laser operation with nanosecond pulse irradiation can provide an acceptable efficiency in the separating unit and a high efficiency of the laser with the wavelength of 5.3 {mu}m. In the present work we also introduce a calculation model and define the parameters of a mode-locked CO laser with a RF discharge in the supersonic stream. The average pulsed CO laser power of 3 kW is sufficient for efficient industrial isotope separation of uranium in one stage.

  18. Elastic scattering of Beryllium isotopes near the Coulomb barrier

    SciTech Connect (OSTI)

    Di Pietro, A.; Figuera, P. [INFN-Laboratori Nazionali del Sud, Catania (Italy); Amorini, F.; Fisichella, M.; Lattuada, M.; Musumarra, A.; Pellegriti, M. G.; Randisi, G.; Rizzo, F.; Santonocito, D.; Scalia, G.; Scuderi, V.; Strano, E.; Torresi, D. [Dipartimento di Fisica ed Astronomia Universita di Catania, Catania (Italy); INFN-Laboratori Nazionali del Sud, Catania (Italy); Papa, M. [INFN-Sezione di Catania, Catania (Italy); Acosta, L.; Martel, I.; Perez-Bernal, F. [Departamento de Fisica Aplicada Universidad de Huelva, Huelva (Spain); Borge, M. J. G.; Tengblad, O. [Instituto de Estructura de la Materia CSIC, Madrid (Spain)

    2011-10-28

    In this contribution, results of experiments performed with the three Beryllium isotopes {sup 9,10,11}Be on a medium mass {sup 64}Zn target, at a center of mass energy of {approx_equal}1.4 the Coulomb barrier, will be discussed. Elastic scattering angular distributions have been measured for the {sup 9,10}Be reactions. In the {sup 11}Be case the quasielastic scattering angular distribution was obtained. In the halo nucleus case, the angular distribution exhibit a non-Fresnel-type pattern with a strong damping of the Coulomb-nuclear interference peak. Moreover, it is found that the total reaction cross-section for the halo nucleus induced collision is more than double the ones extracted in the collisions induced by the non-halo Beryllium isotopes. A large contribution to the total-reaction cross-section in the {sup 11}Be case could be attributed to transfer and/or break-up events.

  19. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  20. Stable isotopes are a powerful way to describe and quantify trophic relationships in aquatic systems. Evaluating the ratios of carbon and nitrogen isotopes of consumers

    E-Print Network [OSTI]

    Lawrence, Deborah

    production in the Virginia Coast Reserve. #12;iii Results indicate that hydrogen isotope ratios can improve is not yet predictable. The application of hydrogen isotopes to marine food web studies warrants further and higher trophic levels. However, this method is only feasible when sources have distinct combinations

  1. FE ISOTOPE NUCLEOSYNTHESIS: CONSTRAINTS FROM FE ISOTOPIC ANALYSES OF PRESOLAR SILICATE GRAINS FROM ACFER 094. W. J. Ong and C. Floss. Laboratory for Space Sciences

    E-Print Network [OSTI]

    Floss, Christine

    FE ISOTOPE NUCLEOSYNTHESIS: CONSTRAINTS FROM FE ISOTOPIC ANALYSES OF PRESOLAR SILICATE GRAINS FROM information about fundamental astrophysical processes, such as stellar nucleosynthesis and galactic chemical evolution. Iron is of particular interest because of its importance in s-process nucleosynthesis. However

  2. NOVEL CONCEPTS FOR ISOTOPIC SEPARATION OF 3HE/4HE

    SciTech Connect (OSTI)

    Roy, L.; Nigg, H.; Watson, H.

    2012-09-04

    The research outlined below established theoretical proof-of-concept using ab initio calculations that {sup 3}He can be separated from {sup 4}He by taking advantage of weak van der Waals interactions with other higher molecular weight rare gases such as xenon. To the best of our knowledge, this is the only suggested method that exploits the physical differences of the isotopes using a chemical interaction.

  3. FUEL CYCLE ISOTOPE EVOLUTION BY TRANSMUTATION DYNAMICS OVER MULTIPLE RECYCLES

    SciTech Connect (OSTI)

    Samuel Bays; Steven Piet; Amaury Dumontier

    2010-06-01

    Because all actinides have the ability to fission appreciably in a fast neutron spectrum, these types of reactor systems are usually not associated with the buildup of higher mass actinides: curium, berkelium and californium. These higher actinides have high specific decay heat power, gamma and neutron source strengths, and are usually considered as a complication to the fuel manufacturing and transportation of fresh recycled transuranic fuel. This buildup issue has been studied widely for thermal reactor fuels. However, recent studies have shown that the transmutation physics associated with "gateway isotopes" dictates Cm-Bk-Cf buildup, even in fast burner reactors. Assuming a symbiotic fuel relationship with light water reactors (LWR), Pu-242 and Am-243 are formed in the LWRs and then are externally fed to the fast reactor as part of its overall transuranic fuel supply. These isotopes are created much more readily in a thermal than in fast spectrum systems due to the differences in the fast fission (i.e., above the fission threshold for non-fissile actinides) contribution. In a strictly breeding fast reactor this dependency on LWR transuranics would not exist, and thus avoids the introduction of LWR derived gateway isotopes into the fast reactor system. However in a transuranic burning fast reactor, the external supply of these gateway isotopes behaves as an external driving force towards the creation and build-up of Cm-Bk-Cf in the fuel cycle. It was found that though the Cm-Bk-Cf concentration in the equilibrium fuel cycle is dictated by the fast neutron spectrum, the time required to reach that equilibrium concentration is dictated by recycle, transmutation and decay storage dynamics.

  4. Literature survey of isotopic abundance data for 1987-1989

    SciTech Connect (OSTI)

    Holden, N.E. (Brookhaven National Lab., Upton, NY (USA))

    1989-08-09

    I have compiled all of the data on isotopic abundance measurements and their variation in nature for the time period since the last General Assembly. Most of the data deals with the variations in the abundances as given by per mil deviations from some standard. As such, they are not of major interest to the Atomic Weights Commission. However, there were some measurements which are of general interest in this list.

  5. An overview of copper-laser development for isotope separation

    SciTech Connect (OSTI)

    Warner, B.E.

    1987-03-13

    We have developed a copper-laser pumped dye-laser system that addresses all of the requirements for atomic vapor laser isotope separation. The requirement for high average power for the laser system has led to the development of copper-laser chains with injection-locked oscillators and multihundred-watt amplifiers. By continuously operating the Laser Demonstration Facility, we gain valuable data for further upgrade and optimization.

  6. ANALYSIS OF RICIN TOXIN PREPARATIONS FOR CARBOHYDRATE AND FATTY ACID ABUNDANCE AND ISOTOPE RATIO INFORMATION

    SciTech Connect (OSTI)

    Wunschel, David S.; Kreuzer-Martin, Helen W.; Antolick, Kathryn C.; Colburn, Heather A.; Moran, James J.; Melville, Angela M.

    2009-12-01

    This report describes method development and preliminary evaluation for analyzing castor samples for signatures of purifying ricin. Ricin purification from the source castor seeds is essentially a problem of protein purification using common biochemical methods. Indications of protein purification will likely manifest themselves as removal of the non-protein fractions of the seed. Two major, non-protein, types of biochemical constituents in the seed are the castor oil and various carbohydrates. The oil comprises roughly half the seed weight while the carbohydrate component comprises roughly half of the remaining “mash” left after oil and hull removal. Different castor oil and carbohydrate components can serve as indicators of specific toxin processing steps. Ricinoleic acid is a relatively unique fatty acid in nature and is the most abundant component of castor oil. The loss of ricinoleic acid indicates a step to remove oil from the seeds. The relative amounts of carbohydrates and carbohydrate-like compounds, including arabinose, xylose, myo-inositol fucose, rhamnose, glucosamine and mannose detected in the sample can also indicate specific processing steps. For instance, the differential loss of arabinose relative to mannose and N-acetyl glucosamine indicates enrichment for the protein fraction of the seed using protein precipitation. The methods developed in this project center on fatty acid and carbohydrate extraction from castor samples followed by derivatization to permit analysis by gas chromatography-mass spectrometry (GC-MS). Method descriptions herein include: the source and preparation of castor materials used for method evaluation, the equipment and description of procedure required for chemical derivatization, and the instrument parameters used in the analysis. Two types of derivatization methods describe analysis of carbohydrates and one procedure for analysis of fatty acids. Two types of GC-MS analysis is included in the method development, one employing a quadrupole MS system for compound identification and an isotope ratio MS for measuring the stable isotope ratios of deuterium and hydrogen (D/H) in fatty acids. Finally, the method for analyzing the compound abundance data is included. This study indicates that removal of ricinoleic acid is a conserved consequence of each processing step we tested. Furthermore, the stable isotope D/H ratio of ricinoleic acid distinguished between two of the three castor seed sources. Concentrations of arabinose, xylose, mannose, glucosamine and myo-inositol differentiated between crude or acetone extracted samples and samples produced by protein precipitation. Taken together these data illustrate the ability to distinguish between processes used to purify a ricin sample as well as potentially the source seeds.

  7. Experimental Validation of the Multi-Isotope Process Monitor Concept

    SciTech Connect (OSTI)

    Orton, Christopher R.; Schwantes, Jon M.; Fraga, Carlos G.; Douglas, Matthew; Christensen, Richard

    2010-05-13

    Researchers from Pacific Northwest National Laboratory, in conjunction with personnel from The Ohio State University, are working to develop a system for monitoring spent nuclear fuel reprocessing facilities on-line, non-destructively, and in near-real-time. This method, known as the Multi-Isotope Process (MIP) Monitor, is based upon the measurement of distribution patterns of a suite of indicator (radioactive) isotopes present within particular process streams. Distribution patterns, monitored on-line by gamma spectrometry, are then compared in near-real-time to patterns representing "normal" process conditions using multivariate pattern recognition software. By targeting gamma-emitting indicator isotopes, the MIP Monitor approach is compatible with the use of small, portable, high-resolution gamma detectors that may be easily deployed throughout the facility. In addition, utilization of a suite of radio-elements, including ones with multiple oxidation states, increases the likelihood that attempts to divert material via process manipulation would be detected. Proof-of-principle modeling exercises simulating changes in acid strength have been completed and the results are promising. Laboratory validation is currently under way and significant results are available. The latest experimental results, along with an overview of the method will be presented.

  8. Hanford Isotope Project strategic business analysis Cesium-137 (Cs-137)

    SciTech Connect (OSTI)

    NONE

    1995-10-01

    The purpose of this business analysis is to address the beneficial reuse of Cesium 137 (Cs-137) in order to utilize a valuable national asset and possibly save millions of tax dollars. Food irradiation is the front runner application along with other uses. This business analysis supports the objectives of the Department of Energy National Isotope Strategy distributed in August 1994 which describes the DOE plans for the production and distribution of isotope products and services. As part of the Department`s mission as stated in that document. ``The Department of Energy will also continue to produce and distribute other radioisotopes and enriched stable isotopes for medical diagnostics and therapeutics, industrial, agricultural, and other useful applications on a businesslike basis. This is consistent with the goals and objectives of the National Performance Review. The Department will endeavor to look at opportunities for private sector to co-fund or invest in new ventures. Also, the Department will seek to divest from ventures that can more profitably or reliably be operated by the private sector.``

  9. Orion Flight Test Exploration Flight Test-1

    E-Print Network [OSTI]

    Rathbun, Julie A.

    Orion Flight Test Exploration Flight Test-1 PRESS KIT/December 2014 www.nasa.gov NP-2014-11-020-JSC National Aeronautics and Space Administration #12;#12;Orion Flight Test December 2014 Contents Section Page ........................................................................................... 28 i #12;Orion Flight Test ii December 2014 #12;Orion Flight Test December 2014 Flight Overview

  10. Test and Test Equipment Joshua Lottich

    E-Print Network [OSTI]

    Patel, Chintan

    Test and Test Equipment Joshua Lottich CMPE 640 11/23/05 #12;Testing Verifies that manufactured chip meets design specifications. Cannot test for every potential defect. Modeling defects as faults allows for passing and failing of chips. Ideal test would capture all defects and pass only chips

  11. Test Preparation Options Free Test Prep Websites

    E-Print Network [OSTI]

    Stowell, Michael

    Test Preparation Options Free Test Prep Websites ACT: http: http://www.collegeboard.com/student/testing/sat/prep_one/test.html http://www.number2.com://testprep.princetonreview.com/CourseSearch/Search.aspx?itemCode=17&productType=F&rid=1&zip=803 02 Test Prep Classes Front Range Community College: Classes

  12. The ReA electron-beam ion trap charge breeder for reacceleration of rare isotopes

    SciTech Connect (OSTI)

    Lapierre, A.; Schwarz, S.; Kittimanapun, K.; Fogleman, J.; Krause, S.; Nash, S.; Rencsok, R.; Tobos, L.; Perdikakis, G.; Portillo, M.; Rodriguez, J. A.; Wittmer, W.; Wu, X.; Bollen, G.; Leitner, D.; Syphers, M. [National Superconducting Cyclotron Laboratory (NSCL), Michigan State University (MSU), 640 South Shaw Lane, East Lansing, MI 48824 (United States); Collaboration: ReA Team

    2013-04-19

    ReA is a post-accelerator at the National Superconducting Cyclotron Laboratory at Michigan State University. ReA is designed to reaccelerate rare isotopes to energies of a few MeV/u following production by projectile fragmentation and thermalization in a gas cell. The facility consists of four main components: an electron-beam ion trap (EBIT) charge breeder, an achromatic charge-over-mass (Q/A) separator, a radio-frequency quadrupole accelerator, and a superconducting radio-frequency linear accelerator. The EBIT charge breeder was specifically designed to efficiently capture continuous beams of singly charged ions injected at low energy (<60 keV), charge breed in less than 50 ms, and extract highly charged ions to the Q/A separator for charge-state selection and reacceleration through the accelerator structures. The use of highly charged ions to reach high beam energies is a key aspect that makes ReA a compact and cost-efficient post-accelerator. The EBIT is characterized by a high-current electron gun, a long multi-electrode trap structure and a dual magnet to provide both the high electron-beam current density necessary for fast charge breeding of short-lived isotopes as well as the high capture probability of injected beams. This paper presents an overview and the status of the ReA EBIT, which has extracted for reacceleration tests stable {sup 20}Ne{sup 8+} ion beams produced from injected gas and more recently {sup 39}K{sup 16+} beams by injecting stable {sup 39,41}K{sup +} ions from an external ion source.

  13. Chemical, multi-isotopic (Li-B-Sr-U-H-O) and thermal characterization of Triassic formation waters from the Paris Basin

    E-Print Network [OSTI]

    Boyer, Edmond

    Chemical, multi-isotopic (Li-B-Sr-U-H-O) and thermal characterization of Triassic formation waters Torche fields in the centre of the Basin. The multi- isotope characterization of Triassic formation to characterize sandstone formation waters. Keywords: lithium isotopes, boron isotopes, strontium isotopes

  14. A ROBUST ABSOLUTE DETECTION EFFICIENCY CALIBRATION METHOD UTILIZING BETA/GAMMA COINCIDENCE SIGNATURES AND ISOTOPICALLY PURIFIED NEUTRON ACTIVATED RADIOXENON ISOTOPES

    SciTech Connect (OSTI)

    McIntyre, Justin I.; Cooper, Matthew W.; Ely, James H.; Haas, Derek A.; Schrom, Brian T.

    2012-09-21

    Efforts to calibrate the absolute efficiency of gas cell radiations detectors have utilized a number of methodologies which allow adequate calibration but are time consuming and prone to a host of difficult-to-determine uncertainties. A method that extrapolates the total source strength from the measured beta and gamma gated beta coincidence signal was developed in the 1960’s and 1970’s. It has become clear that it is possible to achieve more consistent results across a range of isotopes and a range of activities using this method. Even more compelling is the ease with which this process can be used on routine samples to determine the total activity present in the detector. Additionally, recent advances in the generation of isotopically pure radioxenon samples of Xe-131m, Xe-133, and Xe-135 have allowed these measurement techniques to achieve much better results than would have been possible before when using mixed isotopic radioxenon source. This paper will discuss the beta/gamma absolute detection efficiency technique that utilizes several of the beta-gamma decay signatures to more precisely determine the beta and gamma efficiencies. It will than compare these results with other methods using pure sources of Xe-133, Xe-131m, and Xe-135 and a Xe-133/Xe-133m mix.

  15. Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data

    SciTech Connect (OSTI)

    Thomas, James; Decker, David; Patterson, Gary; Peterman, Zell; Mihevc, Todd; Larsen, Jessica; Hershey, Ronald

    2007-06-25

    Groundwater samples in the Yucca Mountain area were collected for chemical and isotopic analyses and measurements of water temperature, pH, specific conductivity, and alkalinity were obtained at the well or spring at the time of sampling. For this project, groundwater samples were analyzed for major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC). The U.S. Geological Survey (USGS) performed all the fieldwork on this project including measurement of water chemistry field parameters and sample collection. The major ions dissolved in the groundwater, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) were analyzed by the USGS. All preparation and processing of samples for DOC carbon isotopic analyses and geochemical modeling were performed by the Desert Research Institute (DRI). Analysis of the DOC carbon dioxide gas produced at DRI to obtain carbon-13 and carbon-14 values was conducted at the University of Arizona Accelerator Facility (a NSHE Yucca Mountain project QA qualified contract facility). The major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of DIC were used in geochemical modeling (NETPATH) to determine groundwater sources, flow paths, mixing, and ages. The carbon isotopes of DOC were used to calculate groundwater ages that are independent of DIC model corrected carbon-14 ages. The DIC model corrected carbon-14 calculated ages were used to evaluate groundwater travel times for mixtures of water including water beneath Yucca Mountain. When possible, groundwater travel times were calculated for groundwater flow from beneath Yucca Mountain to down gradient sample sites. DOC carbon-14 groundwater ages were also calculated for groundwaters in the Yucca Mountain area. When possible, groundwater travel times were estimated for groundwater flow from beneath Yucca Mountain to down gradient groundwater sample sites using the DOC calculated groundwater ages. The DIC calculated groundwater ages were compared with DOC calculated groundwater ages and both of these ages were compared to travel times developed in ground-water flow and transport models. If nuclear waste is stored in Yucca Mountain, the saturated zone is the final barrier against the release of radionuclides to the environment. The most recent rendition of the TSPA takes little credit for the presence of the saturated zone and is a testament to the inadequate understanding of this important barrier. If radionuclides reach the saturated zone beneath Yucca Mountain, then there is a travel time before they would leave the Yucca Mountain area and flow down gradient to the Amargosa Valley area. Knowing how long it takes groundwater in the saturated zone to flow from beneath Yucca Mountain to down gradient areas is critical information for potential radionuclide transport. Radionuclide transport in groundwater may be the quickest pathway for radionuclides in the proposed Yucca Mountain repository to reach land surface by way of groundwater pumped in Amargosa Valley. An alternative approach to ground-water flow and transport models to determine the travel time of radionuclides from beneath Yucca Mountain to down gradient areas in the saturated zone is by carbon-14 dating of both inorganic and organic carbon dissolved in the groundwater. A standard method of determining ground-water ages is to measure the carbon-13 and carbon-14 of DIC in the groundwater and then correct the measured carbon-14 along a flow path for geochemical reactions that involve carbon containing phases. These geochemical reactions are constrained by carbon-13 and isotopic fractionations. Without correcting for geochemical reactions, the ground-water ages calculated from only the differences in carbon-14 measured along a flow path (assuming the decrease in carbon-14 is due strictly to radioactive decay) could be tens of thousands of years too old. The computer program NETPATH, developed by the USGS, is the best geochemical program for correcting carbon-14 activities for geochemical r

  16. Fast and efficient charge breeding of the Californium rare isotope breeder upgrade electron beam ion source

    SciTech Connect (OSTI)

    Ostroumov, P. N.; Barcikowski, A.; Dickerson, C. A.; Perry, A.; Pikin, A. I.; Sharamentov, S. I.; Vondrasek, R. C.; Zinkann, G. P.

    2015-08-28

    The Electron Beam Ion Source (EBIS), developed to breed Californium Rare Isotope Breeder Upgrade (CARIBU) radioactive beams at Argonne Tandem Linac Accelerator System (ATLAS), is being tested off-line. A unique property of the EBIS is a combination of short breeding times, high repetition rates, and a large acceptance. Overall, we have implemented many innovative features during the design and construction of the CARIBU EBIS as compared to the existing EBIS breeders. The off-line charge breeding tests are being performed using a surface ionization source that produces singly charged cesium ions. The main goal of the off-line commissioning is to demonstrate stable operation of the EBIS at a 10 Hz repetition rate and a breeding efficiency into single charge state higher than 15%. These goals have been successfully achieved and exceeded. We have measured (20% ± 0.7%) breeding efficiency into the single charge state of 28+ cesium ions with the breeding time of 28 ms. In general, the current CARIBU EBIS operational parameters can provide charge breeding of any ions in the full mass range of periodic table with high efficiency, short breeding times, and sufficiently low charge-to-mass ratio, 1/6.3 for the heaviest masses, for further acceleration in ATLAS. In this study, we discuss the parameters of the EBIS and the charge breeding results in a pulsed injection mode with repetition rates up to 10 Hz.

  17. Fast and efficient charge breeding of the Californium rare isotope breeder upgrade electron beam ion source

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ostroumov, P. N.; Barcikowski, A.; Dickerson, C. A.; Perry, A.; Pikin, A. I.; Sharamentov, S. I.; Vondrasek, R. C.; Zinkann, G. P.

    2015-08-28

    The Electron Beam Ion Source (EBIS), developed to breed Californium Rare Isotope Breeder Upgrade (CARIBU) radioactive beams at Argonne Tandem Linac Accelerator System (ATLAS), is being tested off-line. A unique property of the EBIS is a combination of short breeding times, high repetition rates, and a large acceptance. Overall, we have implemented many innovative features during the design and construction of the CARIBU EBIS as compared to the existing EBIS breeders. The off-line charge breeding tests are being performed using a surface ionization source that produces singly charged cesium ions. The main goal of the off-line commissioning is to demonstratemore »stable operation of the EBIS at a 10 Hz repetition rate and a breeding efficiency into single charge state higher than 15%. These goals have been successfully achieved and exceeded. We have measured (20% ± 0.7%) breeding efficiency into the single charge state of 28+ cesium ions with the breeding time of 28 ms. In general, the current CARIBU EBIS operational parameters can provide charge breeding of any ions in the full mass range of periodic table with high efficiency, short breeding times, and sufficiently low charge-to-mass ratio, 1/6.3 for the heaviest masses, for further acceleration in ATLAS. In this study, we discuss the parameters of the EBIS and the charge breeding results in a pulsed injection mode with repetition rates up to 10 Hz.« less

  18. STATUS OF HIGH FLUX ISOTOPE REACTOR IRRADIATION OF SILICON CARBIDE/SILICON CARBIDE JOINTS

    SciTech Connect (OSTI)

    Katoh, Yutai; Koyanagi, Takaaki; Kiggans, Jim; Cetiner, Nesrin; McDuffee, Joel

    2014-09-01

    Development of silicon carbide (SiC) joints that retain adequate structural and functional properties in the anticipated service conditions is a critical milestone toward establishment of advanced SiC composite technology for the accident-tolerant light water reactor (LWR) fuels and core structures. Neutron irradiation is among the most critical factors that define the harsh service condition of LWR fuel during the normal operation. The overarching goal of the present joining and irradiation studies is to establish technologies for joining SiC-based materials for use as the LWR fuel cladding. The purpose of this work is to fabricate SiC joint specimens, characterize those joints in an unirradiated condition, and prepare rabbit capsules for neutron irradiation study on the fabricated specimens in the High Flux Isotope Reactor (HFIR). Torsional shear test specimens of chemically vapor-deposited SiC were prepared by seven different joining methods either at Oak Ridge National Laboratory or by industrial partners. The joint test specimens were characterized for shear strength and microstructures in an unirradiated condition. Rabbit irradiation capsules were designed and fabricated for neutron irradiation of these joint specimens at an LWR-relevant temperature. These rabbit capsules, already started irradiation in HFIR, are scheduled to complete irradiation to an LWR-relevant dose level in early 2015.

  19. An Evaluation of Activated Bismuth Isotopes in Environmental Samples From the Former Western Pacific Proving Grounds

    SciTech Connect (OSTI)

    Robison, W.L.; Brunk, J.A.; Jokela, T.A.

    2000-03-21

    {sup 207}Bi (t{sub 1/2}=32.2 y) was generated by activation of weapons material during a few ''clean'' nuclear tests at the U.S. Western Pacific Proving Grounds of Enewetak and Bikini Atolls. The radionuclides first appeared in the Enewetak environment during 1958 and in the environment of Bikini during 1956. Crater sediments from Bikini with high levels of {sup 207}Bi were analyzed by gamma spectrometry in an attempt to determine the relative concentrations of {sup 208}Bi (t{sup 1/2} = 3.68 x 10{sup 5} y). The bismuth isotopes were probably generated during the ''clean'', 9.3 Mt Poplar test held on 7/12/58. The atom ratio of {sup 208}Bi to {sup 207}Bi (R value) ranges from {approx}12 to over 200 in sections of core sediments from the largest nuclear crater at Bikini atoll. The presence of bismuth in the device is suggested to account for R values in excess of 10.

  20. Resonance ionization laser ion sources for on-line isotope separators...

    Office of Scientific and Technical Information (OSTI)

    Resonance ionization laser ion sources for on-line isotope separators (invited) Citation Details In-Document Search Title: Resonance ionization laser ion sources for on-line...

  1. A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrotherm...

    Open Energy Info (EERE)

    Caldera, California Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrothermal...

  2. Stable-Isotope Studies Of Rocks And Secondary Minerals In A Vapor...

    Open Energy Info (EERE)

    & Epstein, 1992) Isotopic Analysis At Geysers Area (Lambert & Epstein, 1992) Petrography Analysis At Geysers Area (Lambert & Epstein, 1992) Areas (1) Geysers Area Regions...

  3. Isotope effect studies of the pyridoxal 5'-phosphate dependent histidine decarboxylase from Morganella morganii

    SciTech Connect (OSTI)

    Abell, L.M.; O'Leary, M.H.

    1988-08-09

    The pyridoxal 5'-phosphate dependent histidine decarboxylase from Morganella morganii shows a nitrogen isotope effect k/sup 14//k/sup 15/ = 0.9770 +/- 0.0021, a carbon isotope effect k/sup 12//k/sup 13/ = 1.0308 +/- 0.0006, and a carbon isotope effect for L-(..cap alpha..-/sup 2/H)histidine of 1.0333 +/- 0.0001 at pH 6.3, 37/sup 0/C. These results indicate that the overall decarboxylation rate is limited jointly by the rate of Schiff base interchange and by the rate of decarboxylation. Although the observed isotope effects are quite different from those for the analogous glutamate decarboxylase from Escherichia coli, the intrinsic isotope effects for the two enzymes are essentially the same. The difference in observed isotope effects occurs because of a roughly twofold difference in the partitioning of the pyridoxal 5'-phosphate-substrate Schiff base between decarboxylation and Schiff base interchange. The observed nitrogen isotope effect requires that the imine nitrogen in this Schiff base is protonated. Comparison of carbon isotope effects for deuteriated and undeuteriated substrates reveals that the deuterium isotope effect on the decarboxylation step is about 1.20; thus, in the transition state for the decarboxylation step, the carbon-carbon bond is about two-thirds broken.

  4. Neutron rich Carbon and Oxygen isotopes with an odd number of neutrons

    E-Print Network [OSTI]

    Benoit Laurent; Nicole Vinh Mau

    2013-04-02

    We describe odd isotopes as formed of a core plus one neutron. We have calculated the modification of single neutron energies brought by couplings of the neutron with collective $2^+$ phonons in the cores. The results reproduce very well the inversion of $2s$ and $1d_{5/2}$ shells in carbon isotopes up to $^{19}$C while in oxygen isotopes the correction is also large but do not show any inversion in agreement with experiments. The calculated energies are close to the experimental ones in both series of isotopes except in $^{21}$C for the $2s$ state for which our coupling is too weak.

  5. A Mass Spectrometry Study of Isotope Separation in the Laser Plume

    E-Print Network [OSTI]

    Suen, Timothy Wu

    2012-01-01

    code for determining plutonium isotopic abundances. volumefor the Characterization of Plutonium and Highly EnrichedKoch, “Origin determination of plutonium material in nuclear

  6. Isotope fractionation in surface ionization ion source of alkaline-earth iodides

    SciTech Connect (OSTI)

    Suzuki, T.; Kanzaki, C.; Nomura, M.; Fujii, Y.

    2012-02-15

    The relationship between the isotope fractionation of alkaline-earth elements in the surface ionization ion source and the evaporation filament current, i.e., filament temperature, was studied. It was confirmed that the isotope fractionation depends on the evaporation filament temperature; the isotope fractionation in the case of higher temperature of filament becomes larger. The ionization and evaporation process in the surface ionization ion source was discussed, and it was concluded that the isotope fractionation is suppressed by setting at the lower temperature of evaporation filament because the dissociations are inhibited on the evaporation filament.

  7. Stable isotopes of authigenic minerals in variably-saturated fractured tuff

    SciTech Connect (OSTI)

    Weber, D.S.; Evans, D.D.

    1988-11-01

    Identifying stable isotope variation and mineralogical changes in fractured rock may help establish the history of climatic and geomorphological processes that might affect the isolation properties of a waste repository site. This study examines the use of the stable isotope ratios of oxygen ({sup 18}O/{sup 16}O) and carbon ({sup 13}C/{sup 12}C) in authigenic minerals as hydrogeochemical tools tracing low-temperature rock-water interaction in variably-saturated fractured stuff. Isotopic compositions of fracture-filling and rock matrix minerals in the Apache Leap tuff, near Superior, Arizona were concordant with geothermal temperatures and in equilibrium with water isotopically similar to present-day meteoric water and groundwater. Oxygen and carbon isotope ratios of fracture-filling, in unsaturated fractured tuff, displayed an isotopic gradient believed to result from near-surface isotopic enrichment due to evaporation rather than the effects of rock-water interaction. Oxygen isotope ratios of rock matrix opal samples exhibited an isotopic gradient believed to result from, leaching and reprecipitation of silica at depth. Methods and results can be used to further define primary flowpaths and the movement of water in variably-saturated fractured rock. 71 refs., 23 figs., 3 tabs.

  8. Carbon isotope ratios of organic compound fractions in oceanic suspended particles

    E-Print Network [OSTI]

    Hwang, Jeomshik; Druffel, Ellen R. M

    2006-01-01

    Radiocarbon evidence of fossil-carbon cycling in sediments1968), Metabolic fractionation of carbon isotopes in marineof particulate organic carbon using bomb 14 C, Nature,

  9. 2013 Workshop on Isotope Federal Supply and Demand | U.S. DOE...

    Office of Science (SC) Website

    of isotopes from a Federal perspective, in various areas including homeland defense, medicine, agriculture, and basic and applied research. Participants will engage in discussions...

  10. 2014 Workshop on Isotope Federal Supply and Demand | U.S. DOE...

    Office of Science (SC) Website

    of isotopes from a Federal perspective, in various areas including homeland defense, medicine, agriculture, and basic and applied research. Participants will engage in discussions...

  11. 2015 Workshop on Isotope Federal Supply and Demand | U.S. DOE...

    Office of Science (SC) Website

    of isotopes from a Federal perspective, in various areas including homeland defense, medicine, agriculture, and basic and applied research. Participants will engage in discussions...

  12. 2012 Workshop on Isotope Federal Supply and Demand | U.S. DOE...

    Office of Science (SC) Website

    of isotopes from a Federal perspective, in various areas including homeland defense, medicine, agriculture, and basic and applied research. Participants will engage in discussions...

  13. Intro Temporal Tests Declustering Methods Tests on SCEC data Spatiotemporal Test Discussion Testing for Poisson Behavior

    E-Print Network [OSTI]

    Stark, Philip B.

    Intro Temporal Tests Declustering Methods Tests on SCEC data Spatiotemporal Test Discussion Testing Seismological Society of America Annual Meeting San Diego, CA #12;Intro Temporal Tests Declustering Methods Tests on SCEC data Spatiotemporal Test Discussion Quake Physics versus Quake Statistics · Distribution

  14. Paired t testsPaired t tests Paired (dependent) t-testPaired (dependent) t test

    E-Print Network [OSTI]

    Wolverton, Steve

    Paired t testsPaired t tests #12;Paired (dependent) t-testPaired (dependent) t test · Compares test means from matched pairsCompares test means from matched pairs or two different samples from the same individualsindividuals ­ e.g., pretest & post test scores for the same group of students Ho: d = 0 d is thedifference

  15. CNP_TEST_SUITE

    Energy Science and Technology Software Center (OSTI)

    002854MLTPL00 Automated Nuclear Data Test Suite  file:///usr/gapps/CNP_src/us/RR/test_suite_cz/cnp_test_suite 

  16. CMVO Drug Testing Program Reasonable Suspicion Testing

    E-Print Network [OSTI]

    Sin, Peter

    CMVO Drug Testing Program Reasonable Suspicion Testing CMVO Revised Suspicion Form (Revised 6/08) Guidelines for Reasonable Suspicion Drug and Alcohol Testing: A supervisor, trained in accordance with 49 CFR involved in an incident that requires drug/alcohol testing as set forth in 382.307. Remember: Reasonable

  17. TEST STATION SALE OF PERFORMANCE TESTED BULLS

    E-Print Network [OSTI]

    Tennessee, University of

    in the test had to meet minimum performance requirements. Those were: CREEP NON-CREEP Adj 205 day wt. 560 520AS-B428 U T BULL TEST STATION SALE OF PERFORMANCE TESTED BULLS THURSDAY, MARCH 8, 2012 12:00 NOON IN GREENEVILLE AND KNOXVILLE LIVESTOCK CENTER http://animalscience.ag.utk.edu/ (For video) #12;UT BULL TEST

  18. CARBON ISOTOPE AND ISOTOPOMER FRACTIONATION IN COLD DENSE CLOUD CORES

    SciTech Connect (OSTI)

    Furuya, Kenji; Aikawa, Yuri [Department of Earth and Planetary Sciences, Kobe University, Kobe 657-8501 (Japan); Sakai, Nami; Yamamoto, Satoshi, E-mail: furuya@stu.kobe-u.ac.jp [Department of Physics and Research Center for the Early Universe, University of Tokyo, Bunkyo-ku, Tokyo 113-003 (Japan)

    2011-04-10

    We construct a gas-grain chemical network model which includes carbon isotopes ({sup 12}C and {sup 13}C) with an emphasis on isotopomer-exchange reactions. Temporal variations of molecular abundances, the carbon isotope ratios ({sup 12}CX/{sup 13}CX), and the isotopomer ratios ({sup 12}C{sup 13}CX/{sup 13}C{sup 12}CX) of CCH and CCS in cold dense cloud cores are investigated by numerical calculations. We confirm that the isotope ratios of molecules, both in the gas phase and grain surfaces, are significantly different depending on whether the molecule is formed from the carbon atom (ion) or the CO molecule. Molecules formed from carbon atoms have CX/{sup 13}CX ratios greater than the elemental abundance ratio of [{sup 12}C/{sup 13}C]. On the other hand, molecules formed from CO molecules have CX/{sup 13}CX ratios smaller than the [{sup 12}C/{sup 13}C] ratio. We reproduce the observed C{sup 13}CH/{sup 13}CCH ratio in TMC-1, if the isotopomer-exchange reaction, {sup 13}CCH + H {r_reversible} C{sup 13}CH + H + 8.1 K, proceeds with the forward rate coefficient k{sub f} > 10{sup -11} cm{sup 3} s{sup -1}. However, the C{sup 13}CS/{sup 13}CCS ratio is lower than that observed in TMC-1. We then assume the isotopomer-exchange reaction catalyzed by the H atom, {sup 13}CCS + H {r_reversible} C{sup 13}CS + H + 17.4 K. In the model with this reaction, we reproduce the observed C{sup 13}CS/{sup 13}CCS, CCS/C{sup 13}CS, and CCS/{sup 13}CCS ratios simultaneously.

  19. Thermal Neutron Capture Cross Sections of the PalladiumIsotopes

    SciTech Connect (OSTI)

    Firestone, R.B.; Krticka, M.; McNabb, D.P.; Sleaford, B.; Agvaanluvsan, U.; Belgya, T.; Revay, Zs.

    2006-07-17

    Precise gamma-ray thermal neutron capture cross sectionshave been measured at the Budapest Reactor for all elements withZ=1-83,92 except for He and Pm. These measurements and additional datafrom the literature been compiled to generate the Evaluated Gamma-rayActivation File (EGAF), which is disseminated by LBNL and the IAEA. Thesedata are nearly complete for most isotopes with Z<20 so the totalradiative thermal neutron capture cross sections can be determineddirectly from the decay scheme. For light isotopes agreement with therecommended values is generally satisfactory although large discrepanciesexist for 11B, 12,13C, 15N, 28,30Si, 34S, 37Cl, and 40,41K. Neutroncapture decay data for heavier isotopes are typically incomplete due tothe contribution of unresolved continuum transitions so only partialradiative thermal neutron capture cross sections can be determined. Thecontribution of the continuum to theneutron capture decay scheme arisesfrom a large number of unresolved levels and transitions and can becalculated by assuming that the fluctuations in level densities andtransition probabilities are statistical. We have calculated thecontinuum contribution to neutron capture decay for the palladiumisotopes with the Monte Carlo code DICEBOX. These calculations werenormalized to the experimental cross sections deexciting low excitationlevels to determine the total radiative thermal neutron capture crosssection. The resulting palladium cross sections values were determinedwith a precision comparable to the recommended values even when only onegamma-ray cross section was measured. The calculated and experimentallevel feedings could also be compared to determine spin and parityassignments for low-lying levels.

  20. Isotopic Survey of Lake Davis and the Local Groundwater

    SciTech Connect (OSTI)

    Ridley, M N; Moran, J E; Singleton, M J

    2007-08-21

    In September 2007, California Fish and Game (CAFG) plans to eradicate the northern pike from Lake Davis. As a result of the eradication treatment, local residents have concerns that the treatment might impact the local groundwater quality. To address the concerns of the residents, Lawrence Livermore National Laboratory (LLNL) recommended measuring the naturally occurring stable oxygen isotopes in local groundwater wells, Lake Davis, and the Lake Davis tributaries. The purpose of these measurements is to determine if the source of the local groundwater is either rain/snowmelt, Lake Davis/Big Grizzly Creek water or a mixture of Lake Davis/Big Grizzly Creek and rain/snowmelt. As a result of natural evaporation, Lake Davis and the water flowing into Big Grizzly Creek are naturally enriched in {sup 18}oxygen ({sup 18}O), and if a source of a well's water is Lake Davis or Big Grizzly Creek, the well water will contain a much higher concentration of {sup 18}O. This survey will allow for the identification of groundwater wells whose water source is Lake Davis or Big Grizzly Creek. The results of this survey will be useful in the development of a water-quality monitoring program for the upcoming Lake Davis treatment. LLNL analyzed 167 groundwater wells (Table 1), 12 monthly samples from Lake Davis (Table 2), 3 samples from Lake Davis tributaries (Table 2), and 8 Big Grizzly Creek samples (Table 2). Of the 167 groundwater wells sampled and analyzed, only 2 wells contained a significant component of evaporated water, with an isotope composition similar to Lake Davis water. The other 163 groundwater wells have isotope compositions which indicate that their water source is rain/snowmelt.

  1. Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

    SciTech Connect (OSTI)

    Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

    2005-10-31

    Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

  2. Isotopic Evolution of Saline Lakes in the Low-Latitude and Polar Regions

    SciTech Connect (OSTI)

    Horita, Juske [ORNL

    2009-01-01

    Isotopic fractionations associated with two primary processes (evaporation and freezing of water) are discussed, which are responsible for the formation and evolution of saline lakes in deserts from both low-latitude and the Polar regions. In an evaporative system, atmospheric parameters (humidity and isotopic composition of water vapor) have strong influence on the isotopic behavior of saline lakes, and in a freezing system, salinity build-up largely controls the extent of freezing and associated isotope fractionation. In both systems, salinity has a direct impact on the isotopic evolution of saline lakes. It is proposed that a steady-state 'terminal lake' model with short-term hydrologic and environmental perturbations can serve as a useful framework for investigating both evaporative and freezing processes of perennial saline lakes. Through re-assessment of own work and literature data for saline lakes, it was demonstrated that effective uses of the isotope activity compositions of brines and salinity-chemistry data could reveal dynamic changes and evolution in the isotopic compositions of saline lakes in response to hydrologic and environmental changes. The residence time of isotopic water molecules in lakes determines the nature of responses in the isotopic compositions following perturbations in the water and isotope balances (e.g., dilution by inflow, water deficit by increased evaporation, and/or reduction in inflow). The isotopic profiles of some saline lakes from the Polar regions show that they switched the two contrasting modes of operation between evaporative and freezing systems, in response to climate and hydrological changes in the past.

  3. New experimental limits on the alpha decays of lead isotopes

    E-Print Network [OSTI]

    J. W. Beeman; F. Bellini; L. Cardani; N. Casali; S. Di Domizio; E. Fiorini; L. Gironi; S. S. Nagorny; S. Nisi; F. Orio; L. Pattavina; G. Pessina; G. Piperno; S. Pirro; E. Previtali; C. Rusconi; C. Tomei; M. Vignati

    2012-12-12

    For the first time a PbWO4 crystal was grown using ancient Roman lead and it was run as a cryogenic detector. Thanks to the simultaneous and independent read-out of heat and scintillation light, the detector was able to discriminate beta/gamma interactions with respect to alpha particles down to low energies. New more stringent limits on the alpha decays of the lead isotopes are presented. In particular a limit of T_{1/2} > 1.4*10^20 y at a 90% C.L. was evaluated for the alpha decay of 204Pb to 200Hg.

  4. Estimation of neutron-induced spallation yields of krypton isotopes

    SciTech Connect (OSTI)

    Karol, P.J.; Tobin, M.J.; Shibata, S.

    1983-10-01

    A procedure is outlined for estimating cross sections for neutron-induced spallation products relative to those for proton-induced reactions. When combined with known proton spallation systematics, it is demonstrated that cumulative yields for cosmogenically-important stable /sup 84/Kr and /sup 86/Kr isotopes are approx.1.4 and approx.2.8 times greater, respectively, for incident neutrons compared to protons at 0.2< or =E< or =3.0 GeV for nearby medium mass targets. Yields for lighter kryptons are relatively insensitive to the identity of the incident nucleon.

  5. Thermal Neutron Capture Cross Sections Of The Palladium Isotopes

    SciTech Connect (OSTI)

    Firestone, R. B. [Lawrence Berkeley National Laboratory Berkeley CA 94720 (United States); Krtiaka, M. [Faculty of Mathematics and Physics, Charles University V Holesovickach 2, CZ-180 00 Prague 8 (Czech Republic); McNabb, D. P.; Sleaford, B.; Agvaanluvsan, U. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Belgya, T.; Revay, Zs. [Institute of Isotope and Surface Chemistry H-1525, Budapest (Hungary)

    2006-03-13

    We have measured precise thermal neutron capture {gamma}-ray cross sections cry for all stable Palladium isotopes with the guided thermal neutron beam from the Budapest Reactor. The data were compared with other data from the literature and have been evaluated into the Evaluated Gamma-ray Activation File (EGAF). Total radiative neutron capture cross-sections {sigma}{gamma} can be deduced from the sum of transition cross sections feeding the ground state of each isotope if the decay scheme is complete. The Palladium isotope decay schemes are incomplete, although transitions deexciting low-lying levels are known for each isotope. We have performed Monte Carlo simulations of the Palladium thermal neutron capture deexcitation schemes using the computer code DICEBOX. This program generates level schemes where levels below a critical energy Ecrit are taken from experiment, and those above Ecrit are calculated by a random discretization of an a priori known level density formula {rho}(E,J{pi}). Level de-excitation branching intensities are taken from experiment for levels below Ecrit the capture state, or calculated for levels above Ecrit assuming an a priori photon strength function and applying allowed selection rules and a Porter-Thomas distribution of widths. The advantage of this method is that calculational uncertainties can be investigated systematically. Calculated feeding to levels below Ecrit can be normalized to the measured cross section deexciting those levels to determine the total radiative neutron cross-section {sigma}{gamma}. In this paper we report the cross section measurements {sigma}{gamma}[102Pd(n,{gamma})]=0.9{+-}0.3 b, {sigma}{gamma}[104Pd(n,{gamma})=0.61{+-}0.11 b, {sigma}{gamma}[105Pd(n,{gamma})]=2.1.1{+-}1.5 b, {sigma}{gamma}[106Pd(n,{gamma})]=0.36{+-}0.05 b, {sigma}{gamma}[108Pd(n,{gamma})(0)]=7.6{+-}0.6 b, {sigma}{gamma}[108Pd(n,{gamma})(189)]=0.185{+-}0.011 b, and {sigma}{gamma}[110Pd(n,{gamma})]=0.10{+-}0.03 b. We have also determined from our statistical calculations that the neutron capture states in 107Pd are best described as 2+[59(4)%]+3+[41(4)%]. Agreement with literature values was excellent in most cases. We found significant discrepancies between our results for 102Pd and 110Pd and earlier values that could be resolved by re-evaluation of the earlier results.

  6. Oxygen and hydrogen isotopes in thermal waters at Zunil, Guatemala

    SciTech Connect (OSTI)

    Fournier, R.O.; Hanshaw, B.B.; Urrutia Sole, J.F.

    1982-10-01

    Enthalpy-chloride relations suggest that a deep reservoir exists at Zunil with a temperature near 300/sup 0/C. Water from that reservoir moves to shallower and cooler local reservoirs, where it mixes with diluted water and then attains a new water-rock chemical equilibrium. This mixed water, in turn, generally is further diluted before being discharged from thermal springs. The stable-isotopic composition of the thermal water indicates that recharge for the deep water at Zunil comes mainly from local sources. The presence of measurable tritium, which suggests that the deep water has been underground about 20 to 30 years, also indicates a local source for the recharge.

  7. Tunable dye laser amplifier chain for laser isotope separation

    SciTech Connect (OSTI)

    Grigoriev, Igor' S; D'yachkov, Aleksei B; Labozin, Valerii P; Mironov, Sergei M; Nikulin, Sergei A; Firsov, Valerii A

    2004-05-31

    A tunable dye laser amplifier chain developed for experiments on atomic vapour laser isotope separation (AVLIS) is described. The system, pumped by copper vapour lasers, consists of a master oscillator and an amplifier stage including a preamplifier and three main amplifiers working in the saturation mode. The master oscillator of the stage is a dye laser with a grazing incidence diffraction grating. Longitudinal pumping of the amplifiers is used. The efficiency of the main amplifiers is 50 % - 55 %. The average power of laser radiation at the output of the last amplifier is 100 W. (lasers. amplifiers)

  8. Categorical Exclusion 4577: Lithium Isotope Separation & Enrichment Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReportsDeterminatIonFornl Project Title: SortLithium Isotope

  9. Category:Isotopic Analysis- Rock | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to: navigation,Ground Gravity SurveyIsotopic Analysis-

  10. Isotope production agreement benefits medical patients | National Nuclear

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATIONIntroducing theActivation byIs a SmallIsotope andSecurity

  11. Bull Test ID 1181 2013 Florida Bull Test

    E-Print Network [OSTI]

    Jawitz, James W.

    Bull Test ID 1181 2013 Florida Bull Test #12;Bull Test ID 1182 2013 Florida Bull Test #12;Bull Test ID 1183 2013 Florida Bull Test #12;Bull Test ID 1184 2013 Florida Bull Test #12;Bull Test ID 1185 2013 Florida Bull Test #12;Bull Test ID 1186 2013 Florida Bull Test #12;Bull Test ID 1187 2013 Florida

  12. Bull Test ID 1140 2013 Florida Bull Test

    E-Print Network [OSTI]

    Jawitz, James W.

    Bull Test ID 1140 2013 Florida Bull Test #12;Bull Test ID 1141 2013 Florida Bull Test #12;Bull Test ID 1142 2013 Florida Bull Test #12;Bull Test ID 1143 2013 Florida Bull Test #12;Bull Test ID 1144 2013 Florida Bull Test #12;Bull Test ID 1145 2013 Florida Bull Test #12;Bull Test ID 1146 2013 Florida

  13. Bull Test ID 1077 2013 Florida Bull Test

    E-Print Network [OSTI]

    Jawitz, James W.

    14th Annual Florida Bull Test #12;Bull Test ID 1077 2013 Florida Bull Test #12;Bull Test ID 1078 2013 Florida Bull Test #12;Bull Test ID 1079 2013 Florida Bull Test #12;Bull Test ID 1080 2013 Florida Bull Test #12;Bull Test ID 1081 2013 Florida Bull Test #12;Bull Test ID 1082 2013 Florida Bull Test #12

  14. Bull Test ID 1098 2013 Florida Bull Test

    E-Print Network [OSTI]

    Jawitz, James W.

    Bull Test ID 1098 2013 Florida Bull Test #12;Bull Test ID 1099 2013 Florida Bull Test #12;Bull Test ID 1100 2013 Florida Bull Test #12;Bull Test ID 1101 2013 Florida Bull Test #12;Bull Test ID 1102 2013 Florida Bull Test #12;Bull Test ID 1103 2013 Florida Bull Test #12;Bull Test ID 1104 2013 Florida

  15. Bull Test ID 1118 2013 Florida Bull Test

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    Jawitz, James W.

    Bull Test ID 1118 2013 Florida Bull Test #12;Bull Test ID 1119 2013 Florida Bull Test #12;Bull Test ID 1120 2013 Florida Bull Test #12;Bull Test ID 1121 2013 Florida Bull Test #12;Bull Test ID 1122 2013 Florida Bull Test #12;Bull Test ID 1123 2013 Florida Bull Test #12;Bull Test ID 1124 2013 Florida

  16. Bull Test ID 1160 2013 Florida Bull Test

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    Jawitz, James W.

    Bull Test ID 1160 2013 Florida Bull Test #12;Bull Test ID 1161 2013 Florida Bull Test #12;Bull Test ID 1162 2013 Florida Bull Test #12;Bull Test ID 1163 2013 Florida Bull Test #12;Bull Test ID 1164 2013 Florida Bull Test #12;Bull Test ID 1165 2013 Florida Bull Test #12;Bull Test ID 1166 2013 Florida

  17. Unit Testing Discussion C

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    Massachusetts at Amherst, University of

    Unit Testing Discussion C #12;Unit Test public Method is smallest unit of code Input/output transformation Test if the method does what it claims Not exactly black box testing #12;Test if (actual result Expected Computed Input #12;Functionality Computation ­ Easy to test Time based Asynchronous interaction

  18. Effect of 13C isotope doping on the optical phonon modes in graphene: Localization and Raman spectroscopy

    E-Print Network [OSTI]

    Rodriguez-Nieva, J. F.

    The effect of [superscript 13]C isotope impurities on the phonon properties of graphene is discussed theoretically. We calculated the values of the phonon lifetimes due to isotope impurity scattering for all values of ...

  19. Evolution of Anthropogenic Pb and Pb isotopes in the deep North Atlantic Ocean and the Indian Ocean

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    Lee, Jong-Mi, Ph. D. Massachusetts Institute of Technology

    2013-01-01

    Pb and Pb isotopes in the ocean have varied on decadal to centennial time scales due to anthropogenic Pb inputs. Thus, tracing the temporal variation of Pb and Pb isotopes in the ocean provides information on the major ...

  20. Lithium isotopes in global mid-ocean ridge basalts Paul B. Tomascak a,*, Charles H. Langmuir b

    E-Print Network [OSTI]

    Langmuir, Charles H.

    Lithium isotopes in global mid-ocean ridge basalts Paul B. Tomascak a,*, Charles H. Langmuir b January 2008 Abstract The lithium isotope compositions of 30 well-characterized samples of glassy lavas