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Sample records for test isotope geothermometry

  1. Isotope Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  2. Geothermometry At Nevada Test And Training Range Area (Sabin...

    Open Energy Info (EERE)

    Nevada Test And Training Range Area (Sabin, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Nevada Test And...

  3. Geology, hydrothermal petrology, stable isotope geochemistry, and fluid inclusion geothermometry of LASL geothermal test well C/T-1 (Mesa 31-1), East Mesa, Imperial Valley, California, USA

    SciTech Connect (OSTI)

    Miller, K.R.; Elders, W.A.

    1980-08-01

    Borehole Mesa 31-1 (LASL C/T-1) is an 1899-m (6231-ft) deep well located in the northwestern part of the East Mesa Geothermal Field. Mesa 31-1 is the first Calibration/Test Well (C/T-1) in the Los Alamos Scientific Laboratory (LASL), Geothermal Log Interpretation Program. The purpose of this study is to provide a compilation of drillhole data, drill cuttings, well lithology, and formation petrology that will serve to support the use of well LASL C/T-1 as a calibration/test well for geothermal logging. In addition, reviews of fluid chemistry, stable isotope studies, isotopic and fluid inclusion geothermometry, and the temperature log data are presented. This study provides the basic data on the geology and hydrothermal alteration of the rocks in LASL C/T-1 as background for the interpretation of wireline logs.

  4. Category:Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Technique Subcategories This category has the following 2 subcategories, out of 2 total. G Gas Geothermometry 1 pages I Isotope Geothermometry 1 pages Pages in...

  5. Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    In The Past 20 Years- Geochemistry In Geothermal Exploration Resource Evaluation And Reservoir Management Geothermometry (Powell and Cumming, 2010) Any Spreadsheets for...

  6. Liquid Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  7. Gas Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  8. Category:Gas Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Gas Geothermometry Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Gas Geothermometry page? For detailed information on Gas...

  9. Geothermometry At Yellowstone Region (Fournier, 1979) | Open...

    Open Energy Info (EERE)

    Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Enthalpy-Chloride digram. Not exactly cation geothermometry...

  10. Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher...

    Open Energy Info (EERE)

    Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Nw...

  11. Geothermometry At Central Nevada Seismic Zone Region (Shevenell...

    Open Energy Info (EERE)

    Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry...

  12. Geothermometry At Blackfoot Reservoir Area (Hutsinpiller & Parry...

    Open Energy Info (EERE)

    Activity Details Location Blackfoot Reservoir Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown References Amy Hutsinpiller, W. T....

  13. Corrosion testing using isotopes

    DOE Patents [OSTI]

    Hohorst, F.A.

    1995-12-05

    A method is described for determining the corrosion behavior of a material with respect to a medium in contact with the material by: implanting a substantially chemically inert gas in a matrix so that corrosion experienced by the material causes the inert gas to enter the medium; placing the medium in contact with the material; and measuring the amount of inert gas which enters the medium. A test sample of a material whose resistance to corrosion by a medium is to be tested is described composed of: a body of the material, which body has a surface to be contacted by the medium; and a substantially chemically inert gas implanted into the body to a depth below the surface. A test sample of a material whose resistance to corrosion by a medium is to be tested is described composed of: a substrate of material which is easily corroded by the medium, the substrate having a surface; a substantially chemically inert gas implanted into the substrate; and a sheet of the material whose resistance to corrosion is to be tested, the sheet being disposed against the surface of the substrate and having a defined thickness. 3 figs.

  14. Corrosion testing using isotopes

    DOE Patents [OSTI]

    Hohorst, Frederick A. (Idaho Falls, ID)

    1995-12-05

    A method for determining the corrosion behavior of a material with respect to a medium in contact with the material by: implanting a substantially chemically inert gas in a matrix so that corrosion experienced by the material causes the inert gas to enter the medium; placing the medium in contact with the material; and measuring the amount of inert gas which enters the medium. A test sample of a material whose resistance to corrosion by a medium is to be tested, composed of: a body of the material, which body has a surface to be contacted by the medium; and a substantially chemically inert gas implanted into the body to a depth below the surface. A test sample of a material whose resistance to corrosion by a medium is to be tested, composed of: a substrate of material which is easily corroded by the medium, the substrate having a surface; a substantially chemically inert gas implanted into the substrate; and a sheet of the material whose resistance to corrosion is to be tested, the sheet being disposed against the surface of the substrate and having a defined thickness.

  15. Improved Geothermometry Through Multivariate Reaction Path Modeling and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators | Department of Energy Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation

  16. Geothermometry At Fish Lake Valley Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Fish Lake Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Fish Lake Valley Area (DOE GTP) Exploration...

  17. Geothermometry At Blue Mountain Geothermal Area (Casteel, Et...

    Open Energy Info (EERE)

    Details Location Blue Mountain Geothermal Area Exploration Technique Geothermometry Activity Date 2010 - 2010 Usefulness useful DOE-funding Unknown Exploration Basis A water...

  18. Geothermometry At Upper Hot Creek Ranch Area (Benoit & Blackwell...

    Open Energy Info (EERE)

    Activity Details Location Upper Hot Creek Ranch Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Ten water samples were collected...

  19. Geothermometry At Clear Lake Area (Thompson, Et Al., 1992) |...

    Open Energy Info (EERE)

    Activity Details Location Clear Lake Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Based on the above discussion,...

  20. Geothermometry At Chena Geothermal Area (Kolker, 2008) | Open...

    Open Energy Info (EERE)

    1973 - 1974 Usefulness not indicated DOE-funding Unknown Exploration Basis Masters thesis Norma Biggar, Geophysical Institute University of Alaska Notes Geothermometry...

  1. Geothermometry At Mt St Helens Area (Shevenell & Goff, 1995)...

    Open Energy Info (EERE)

    St Helens Area (Shevenell & Goff, 1995) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Mt St Helens Area (Shevenell & Goff,...

  2. Geothermometry At Desert Queen Area (Garchar & Arehart, 2008...

    Open Energy Info (EERE)

    Desert Queen Area (Garchar & Arehart, 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Desert Queen Area (Garchar &...

  3. Geothermometry At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Silver Peak Area (DOE GTP) Exploration Activity...

  4. Geothermometry At Alum Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Alum Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Alum Area (DOE GTP) Exploration Activity Details Location...

  5. Geothermometry At The Needles Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At The Needles Area (DOE GTP) Exploration Activity...

  6. Geothermometry At New River Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    New River Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At New River Area (DOE GTP) Exploration Activity Details...

  7. Geothermometry At Fort Bliss Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Fort Bliss Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Fort Bliss Area (DOE GTP) Exploration Activity...

  8. Geothermometry At Walker-Lane Transitional Zone Region (Shevenell...

    Open Energy Info (EERE)

    (Shevenell & De Rocher, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness...

  9. Geothermometry At Walker-Lane Transitional Zone Region (Laney...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness...

  10. Geothermometry At Akutan Fumaroles Area (Kolker, Et Al., 2010...

    Open Energy Info (EERE)

    Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes The chemistry of the hot springs strongly suggests the existence of a neutral chloride reservoir...

  11. Geothermometry At Lassen Volcanic National Park Area (Thompson...

    Open Energy Info (EERE)

    Thompson, 1985) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Lassen Volcanic National Park Area (Thompson, 1985) Exploration...

  12. New Mexico conservative ion water chemistry data and chalcedony geothermometry

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shari Kelley

    2015-10-21

    Compilation of boron, lithium, bromine, and silica data from wells and springs throughout New Mexico from a wide variety of sources. The chalcedony geothermometry calculation is included in this file.

  13. Strontium Isotopes Test Long-Term Zonal Isolation of Injected...

    Office of Scientific and Technical Information (OSTI)

    Test Long-Term Zonal Isolation of Injected and Marcellus Formation Water after Hydraulic Fracturing Citation Details In-Document Search Title: Strontium Isotopes Test Long-Term ...

  14. Mineral Selection for Multicomponent Equilibrium Geothermometry

    SciTech Connect (OSTI)

    Plamer, C. D.; Ohly, S. R.; Smith, R. W.; Neupane, G.; McLing, T.; Mattson, E.

    2015-04-01

    Multicomponent geothermometry requires knowledge of the mineral phases in the reservoir with which the geothermal fluids may be equilibrated. These minerals phases are most often alteration products rather than primary minerals. We have reviewed the literature on geothermal systems representing most major geologic environments typically associated with geothermal activity and identified potential alteration products in various environments. We have included this information in RTEst, a code we have developed to estimate reservoir conditions (temperature, CO2 fugacity) from the geochemistry of near-surface geothermal waters. The information has been included in RTEst through the addition of filters that decrease the potential number of minerals from all possibilities based on the basis species to those that are more relevant to the particular conditions in which the user is interested. The three groups of filters include host rock type (tholeiitic, calc-alkaline, silicic, siliciclastic, carbonate), water type (acidic, neutral), and the temperature range over which the alteration minerals were formed (low, medium, high). The user-chosen mineral assemblage is checked to make sure that it does not violate the Gibbs phase rule. The user can select one of three mineral saturation weighting schemes that decrease the chance the optimization from being skewed by reaction stoichiometry or analytical uncertainty.

  15. Mineral Selection for Multicomponent Equilibrium Geothermometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plamer, C. D.; Ohly, S. R.; Smith, R. W.; Neupane, G.; McLing, T.; Mattson, E.

    2015-04-01

    Multicomponent geothermometry requires knowledge of the mineral phases in the reservoir with which the geothermal fluids may be equilibrated. These minerals phases are most often alteration products rather than primary minerals. We have reviewed the literature on geothermal systems representing most major geologic environments typically associated with geothermal activity and identified potential alteration products in various environments. We have included this information in RTEst, a code we have developed to estimate reservoir conditions (temperature, CO2 fugacity) from the geochemistry of near-surface geothermal waters. The information has been included in RTEst through the addition of filters that decrease the potential numbermore » of minerals from all possibilities based on the basis species to those that are more relevant to the particular conditions in which the user is interested. The three groups of filters include host rock type (tholeiitic, calc-alkaline, silicic, siliciclastic, carbonate), water type (acidic, neutral), and the temperature range over which the alteration minerals were formed (low, medium, high). The user-chosen mineral assemblage is checked to make sure that it does not violate the Gibbs phase rule. The user can select one of three mineral saturation weighting schemes that decrease the chance the optimization from being skewed by reaction stoichiometry or analytical uncertainty.« less

  16. Isotope Geothermometry At Lightning Dock Geothermal Area (Witcher...

    Open Energy Info (EERE)

    Usefulness useful DOE-funding Unknown Exploration Basis Part of the Geothermal Resource Evaluation and Definition (GRED) Program administered by DOE-AAO under Cooperative...

  17. METHOD TO TEST ISOTOPIC SEPARATION EFFICIENCY OF PALLADIUM PACKED COLUMNS

    SciTech Connect (OSTI)

    Heung, L; Gregory Staack, G; James Klein, J; William Jacobs, W

    2007-06-27

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam use, were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages using the test results. The effects of column diameter, metal foam and gas flow rate were identified.

  18. Tests of isotopic separation efficiency of palladium packed columns

    SciTech Connect (OSTI)

    Heung, L. K.; Staack, G. C.; Klein, J. E.; Jacobs, W. D.

    2008-07-15

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam presence were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages based on the test results. The effects of column diameter, metal foam presence and gas flow rate were identified. (authors)

  19. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Science » Nuclear Physics » Isotopes Isotopes Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Get Expertise Eva Birnbaum (505) 665-7167 Email Wolfgang Runde (505) 667-3350 Email Isotope Production and Applications isotopes Isotopes produced at IPF are critical for medical diagnosis and disease treatment. These positron emission tomography images were made possible using isotopes produced at LANL.

  20. Consistency test of neutrinoless double beta decay with one isotope

    SciTech Connect (OSTI)

    Duerr, Michael; Lindner, Manfred [Max-Planck-Institut fuer Kernphysik, Postfach 10 39 80, 69029 Heidelberg (Germany); Zuber, Kai [Technical University Dresden, Institut fuer Kern- und Teilchenphysik, 01069 Dresden (Germany)

    2011-11-01

    We discuss a consistency test which makes it possible to discriminate unknown nuclear background lines from neutrinoless double beta decay with only one isotope. By considering both the transition to the ground state and to the first excited 0{sup +} state, a sufficiently large detector can reveal if neutrinoless double beta decay or some other nuclear physics process is at work. Such a detector could therefore simultaneously provide a consistency test for a certain range of Majorana masses and be sensitive to lower values of the effective Majorana mass .

  1. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    while LANL-produced germanium-68 is used to calibrate Positron Emission Tomography (PET) equipment used for a broad spectrum of diagnostic procedures. Some isotopes produced,...

  2. Geothermometry At Coso Geothermal Area (1980) | Open Energy Informatio...

    Open Energy Info (EERE)

    DOE-funding Unknown Exploration Basis Fluid temperature of feed water Notes Cation and sulfate isotope geothermometers indicate that the reservoir feeding water to the Coso Hot...

  3. Geothermometry At Long Valley Caldera Geothermal Area (Mariner...

    Open Energy Info (EERE)

    California R.O. Fournier, Michael L. Sorey, Robert H. Mariner, Alfred H. Truesdell (1979) Chemical and Isotopic Prediction of Aquifer Temperatures in the Geothermal System at Long...

  4. Geochemistry Sampling for Traditional and Multicomponent Equilibrium Geothermometry in Southeast Idaho

    SciTech Connect (OSTI)

    Cannon, Cody; Wood, Thomas; Neupane, Ghanashyam; McLing, Travis; Mattson, Earl; Dobson, Patrick; Conrad, Mark

    2014-10-01

    The Eastern Snake River Plain (ESRP) is an area of high regional heat flux due the movement of the North American Plate over the Yellowstone Hotspot beginning ca.16 Ma. Temperature gradients between 45-60 C/km (up to double the global average) have been calculated from deep wells that penetrate the upper aquifer system (Blackwell 1989). Despite the high geothermal potential, thermal signatures from hot springs and wells are effectively masked by the rapid flow of cold groundwater through the highly permeable basalts of the Eastern Snake River Plain aquifer (ESRPA) (up to 500+ m thick). This preliminary study is part of an effort to more accurately predict temperatures of the ESRP deep thermal reservoir while accounting for the effects of the prolific cold water aquifer system above. This study combines the use of traditional geothermometry, mixing models, and a multicomponent equilibrium geothermometry (MEG) tool to investigate the geothermal potential of the ESRP. In March, 2014, a collaborative team including members of the University of Idaho, the Idaho National Laboratory, and the Lawrence Berkeley National Laboratory collected 14 thermal water samples from and adjacent to the Eastern Snake River Plain. The preliminary results of chemical analyses and geothermometry applied to these samples are presented herein.

  5. Strontium Isotopes Test Long-Term Zonal Isolation of Injected and Marcellus

    Office of Scientific and Technical Information (OSTI)

    Formation Water after Hydraulic Fracturing (Journal Article) | SciTech Connect Strontium Isotopes Test Long-Term Zonal Isolation of Injected and Marcellus Formation Water after Hydraulic Fracturing Citation Details In-Document Search Title: Strontium Isotopes Test Long-Term Zonal Isolation of Injected and Marcellus Formation Water after Hydraulic Fracturing Authors: Kolesar Kohl, Courtney A ; Capo, Rosemary C ; Stewart, Brian W ; Wall, Andrew J ; Schroeder, Karl T ; Hammack, Richard W ;

  6. Geothermometry At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    were carried out in conjunction with geologic mapping to test the application of these ground-based techniques to geothermal exploration at three prospects in Nevada by Henkle...

  7. Geothermometry At Long Valley Caldera Geothermal Area (Farrar...

    Open Energy Info (EERE)

    stages of hydrothermal activity, flow, and recharge in the Long Valley caldera groundwater system. Fluids were sampled from LVEW during flow testing in May 2000, July 2000,...

  8. Geothermometry At Reese River Area (Henkle & Ronne, 2008) | Open...

    Open Energy Info (EERE)

    DOE-funding Unknown Notes Four formation water samples were collected from well 56-4, during an airlift test which took place between November 11 and November 14, 2007....

  9. Stable isotopic study of precipitation and spring discharge on the Nevada Test Site

    SciTech Connect (OSTI)

    Ingraham, N.L.; Jacobson, R.L.; Hess, J.W.; Lyles, B.F. . Water Resources Center Nevada Univ., Reno, NV . Water Resources Center)

    1990-07-01

    Precipitation was collected in southern Nevada (on the Nevada Test Site) on a semi-regular monthly basis at 41 locations for six years for stable isotopic analysis. The precipitation record shows two time-based regimes. For the first three years of collection, the precipitation was highly variable with several large events and several dry periods. During the last three years of collection, the precipitation was much more even with no large events. However, there is no correlation between the variability in the amount of precipitation and the stable isotopic composition of precipitation. In addition, the oxygen isotope composition and discharge of two springs, Whiterock Spring and Cane Spring, issuing from perched water tables, were monitored for five years in a similar time frame as for the precipitation. 17 refs., 42 figs., 3 tabs.

  10. Geothermometry At Lassen Volcanic National Park Area (Janik ...

    Open Energy Info (EERE)

    sample taken had a pH of 8.35 and contained 2100 ppm Cl and 0.55 ppm NH3. Ratios of Na+K+ and Na+Cl remained nearly constant throughout the flow test. Cation geothermometers...

  11. Geothermal Reservoir Temperatures in Southeastern Idaho using Multicomponent Geothermometry

    SciTech Connect (OSTI)

    Neupane, Ghanashyam; Mattson, Earl D.; McLing, Travis L.; Palmer, Carl D.; Smith, Robert W.; Wood, Thomas R.; Podgorney, Robert K.

    2015-03-01

    Southeastern Idaho exhibits numerous warm springs, warm water from shallow wells, and hot water within oil and gas test wells that indicate a potential for geothermal development in the area. Although the area exhibits several thermal expressions, the measured geothermal gradients vary substantially (19 61 C/km) within this area, potentially suggesting a redistribution of heat in the overlying ground water from deeper geothermal reservoirs. We have estimated reservoir temperatures from measured water compositions using an inverse modeling technique (Reservoir Temperature Estimator, RTEst) that calculates the temperature at which multiple minerals are simultaneously at equilibrium while explicitly accounting for the possible loss of volatile constituents (e.g., CO2), boiling and/or water mixing. Compositions of a selected group of thermal waters representing southeastern Idaho hot/warm springs and wells were used for the development of temperature estimates. The temperature estimates in the the region varied from moderately warm (59 C) to over 175 C. Specifically, hot springs near Preston, Idaho resulted in the highest temperature estimates in the region.

  12. Test results of a new detector system for gamma ray isotopic measurements

    SciTech Connect (OSTI)

    Malcom, J.E.; Bonner, C.A.; Hurd, J.R.; Fleissner,

    1993-08-01

    A new type of gamma-ray detector system for isotopic measurements has been developed. This new system, a ``Duo detector`` array, consists of two intrinsic germanium detectors, a planar followed by a coaxial mounted on the same axis within a single cryostat assembly. This configuration allows the isotopic analysis system to take advantage of spectral data results that are collected simultaneously from different gamma-ray energy regimes. Princeton Gamma Tech (PGT) produced several prototypes of this Duo detector array which were then tested by Rocky Flats personnel until the design was optimized. An application for this detector design is in automated, roboticized NDA systems such as those being developed at the Los Alamos TA-55 Plutonium Facility. The Duo detector design reduces the space necessary for the isotopic instrument by a factor of two (only one liquid nitrogen dewar is needed), and also reduces the complexity of the mechanical systems and controlling software. Data will be presented on measurements of nuclear material with a Duo detector for a wide variety of matrices. Results indicate that the maximum count rate can be increased up to 100,000 counts per second yet maintaining excellent resolution and energy rate product.

  13. Improved Geothermometry Through Multivariate Reaction-path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators: Final Report

    SciTech Connect (OSTI)

    Mattson, Earl; Smith, Robert; Fujita, Yoshiko; McLing, Travis; Neupane, Ghanashyam; Palmer, Carl; Reed, David; Thompson, Vicki

    2015-03-01

    The project was aimed at demonstrating that the geothermometric predictions can be improved through the application of multi-element reaction path modeling that accounts for lithologic and tectonic settings, while also accounting for biological influences on geochemical temperature indicators. The limited utilization of chemical signatures by individual traditional geothermometer in the development of reservoir temperature estimates may have been constraining their reliability for evaluation of potential geothermal resources. This project, however, was intended to build a geothermometry tool which can integrate multi-component reaction path modeling with process-optimization capability that can be applied to dilute, low-temperature water samples to consistently predict reservoir temperature within 30 C. The project was also intended to evaluate the extent to which microbiological processes can modulate the geochemical signals in some thermal waters and influence the geothermometric predictions.

  14. Collaborative Proposal. Development of an Isotope-Enabled CESM for Testing Abrupt Climate Changes

    SciTech Connect (OSTI)

    Otto-Bliesner, Bette

    2015-12-10

    We have made significant landmarks in our proposed work in the last 4 years (3 years plus 1 year of no cost extension). We have developed the simulation capability of the major isotopes in CESM. In particular, we have completed the implementation of the stable water isotopes18O, δD) into the components for the atmosphere, ocean, land surface, runoff transport, sea ice, and coupler. In addition, the carbon isotopes (abiotic and biotic radiocarbon, δ13 C) have been implemented into the CESM ocean and land models, and long spinup simulations have been completed (Jahn et al., 2015). Furthermore, we have added abiotic Neodymium to the CESM ocean model as a tracer of ocean circulation, also measured by the proxy data community. Fullycoupled simulations with the stable water isotopes and ocean radiocarbon are currently being run for the preindustrial and also the Last Glacial Maximum. We have secured 19 million core-hours on the NWSC Yellowstone supercomputer for 12 months. Together with some CESM Paleoclimate Working Group CSL Yellowstone core hours, we are guaranteed sufficient computing for the spin-up experiments and deglaciation simulations for 21 to 15ka.

  15. Isotopic Analysis- Fluid At Fenton Hill HDR Geothermal Area ...

    Open Energy Info (EERE)

    Interactions in the Fenton Hill, New Mexico, Hot Dry Rock Geothermal Systems I. Fluid Mixing and Chemical Geothermometry Additional References Retrieved from "http:...

  16. Isotope Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science and Production 35 years of experience in isotope production, processing, and applications. Llllll Committed to the safe and reliable production of radioisotopes, products, and services. Contact: Kevin John LANL Isotope Program Manager kjohn@lanl.gov 505-667-3602 Sponsored by the Department of Energy National Isotope Program http://www.nuclear.energy.gov/isotopes/nelsotopes2a.html Isotopes for Environmental Science Isotopes produced at Los Alamos National Laboratory are used as

  17. Design and Nuclear-Safety Related Simulations of Bare-Pellet Test Irradiations for the Production of Pu-238 in the High Flux Isotope Reactor using COMSOL

    SciTech Connect (OSTI)

    Freels, James D; Jain, Prashant K; Hobbs, Randy W

    2012-01-01

    The Oak Ridge National Laboratory (ORNL)is developing technology to produce plutonium-238 for the National Aeronautics and Space Administration (NASA) as a power source material for powering vehicles while in deep-space[1]. The High Flux Isotope Reactor (HFIR) of ORNL has been utilized to perform test irradiations of incapsulated neptunium oxide (NpO2) and aluminum powder bare pellets for purposes of understanding the performance of the pellets during irradiation[2]. Post irradiation examinations (PIE) are currently underway to assess the effect of temperature, thermal expansion, swelling due to gas production, fission products, and other phenomena

  18. Isotope geochemistry

    SciTech Connect (OSTI)

    Cole, D.R.; Curtis, D.B.; DePaolo, D.J.; Gerlach, T.M.; Laul, J.C.; Shaw, H.; Smith, B.M.; Sturchio, N.C.

    1990-09-01

    This document represents the consensus of members of the ad hoc Committee on Isotope Geochemistry in the US Department of Energy; the committee is composed of researchers in isotope geochemistry from seven of the national laboratories. Information included in this document was presented at workshops at Lawrence Berkeley Laboratory (April 1989) and at Los Alamos National Laboratory (August 1989).

  19. Isotopes Products

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotopes Products Isotopes Products Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Products stress and rest Stress and rest Rb-82 PET images in a patient with dipyridamole stress-inducible lateral wall and apical ischemia. (http://www.fac.org.ar/scvc/llave/image/machac/machaci.htm#f2,3,4) Strontium-82 is supplied to our customers for use in Sr-82/Rb-82 generator technologies. The generators in turn are supplied to

  20. Geochemistry and Isotopes of Fluids from Sulphur Springs, Valles...

    Open Energy Info (EERE)

    >Non-condensible gases consist of roughly 99% CO2 with minor amounts of H2S, H2, and CH4. Empirical gas geothermometry suggests a deep reservoir temperature of 215 to 280C....

  1. Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California.

    SciTech Connect (OSTI)

    James B. Paces; Zell E. Peterman; Kiyoto Futa; Thomas A. Oliver; and Brian D. Marshall.

    2007-08-07

    Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values for Paleozoic seawater present at the time of deposition. Many of the samples have 87Sr/86Sr compositions that remain relatively unmodified from expected seawater values. However, rocks underlying the northern Nevada Test Site as well as rocks exposed at Bare Mountain commonly have elevated 87Sr/86Sr values derived from post-depositional addition of radiogenic Sr most likely from fluids circulating through rubidium-rich Paleozoic strata or Precambrian basement rocks.

  2. Transportation of medical isotopes

    SciTech Connect (OSTI)

    Nielsen, D.L.

    1997-11-19

    A Draft Technical Information Document (HNF-1855) is being prepared to evaluate proposed interim tritium and medical isotope production at the Fast Flux Test Facility (FFTF). This assessment examines the potential health and safety impacts of transportation operations associated with the production of medical isotopes. Incident-free and accidental impacts are assessed using bounding source terms for the shipment of nonradiological target materials to the Hanford Site, the shipment of irradiated targets from the FFTF to the 325 Building, and the shipment of medical isotope products from the 325 Building to medical distributors. The health and safety consequences to workers and the public from the incident-free transportation of targets and isotope products would be within acceptable levels. For transportation accidents, risks to works and the public also would be within acceptable levels. This assessment is based on best information available at this time. As the medical isotope program matures, this analysis will be revised, if necessary, to support development of a final revision to the Technical Information Document.

  3. I ISOTOPES

    Office of Legacy Management (LM)

    fl6-6 ' , WTELEEYNE I ISOTOPES i - ' 50<77 /,' y. 6 IWL-5025-473 SUBSURFACE URASIUM OJ: THE GROUNDS OF NL BEARINGS, ALBAh'Y Heyitt Iv. Jeter Douglas M. Eagleson Fred J. Frullo TELEDYNE ISOTOPES 50 VAK BUREN A\!EMJE WESTKOOD, NEK JERSEY 07675 7 Dcccmhcr 1953 Prepnrcd for NL f%carings/NL Tndustrics, Inc. 1130 CCVltrill AXr~lMIC Allmy, New York 12205 TABLE OF CONTEhTS 1.0 INTRODUCTION 2.0 METHODS 2.1 Soil Sampling 2.2 Sample Preparation 2.3 Analysis of Samples 3.0 RESULTS 4.0 SUMMARY REFERENCES

  4. Laser separation of medical isotopes

    SciTech Connect (OSTI)

    Eerkens, J.W.; Puglishi, D.A.; Miller, W.H.

    1996-12-31

    There is an increasing demand for different separated isotopes as feed material for reactor and cyclotron-produced radioisotopes used by a fast-growing radiopharmaceutical industry. One new technology that may meet future demands for medical isotopes is molecular laser isotope separation (MLIS). This method was investigated for the enrichment of uranium in the 1970`s and 1980s by Los Alamos National Laboratory, Isotope Technologies, and others around the world. While South Africa and Japan have continued the development of MLIS for uranium and are testing pilot units, around 1985 the United States dropped the LANL MLIS program in favor of AVLIS (atomic vapor LIS), which uses electron-beam-heated uranium metal vapor. AVLIS appears difficult and expensive to apply to most isotopes of medical interest, however, whereas MLIS technology, which is based on cooled hexafluorides or other gaseous molecules, can be adapted more readily. The attraction of MLIS for radiopharmaceutical firms is that it allows them to operate their own dedicated separators for small-quantity productions of critical medical isotopes, rather than having to depend on large enrichment complexes run by governments, which are only optimal for large-quantity productions. At the University of Missouri, the authors are investigating LIS of molybdenum isotopes using MoF{sub 6}, which behaves in a way similar to UF{sub 6}, studied in the past.

  5. Stable Isotope Enrichment Capabilities at ORNL

    SciTech Connect (OSTI)

    Egle, Brian; Aaron, W Scott; Hart, Kevin J

    2013-01-01

    The Oak Ridge National Laboratory (ORNL) and the US Department of Energy Nuclear Physics Program have built a high-resolution Electromagnetic Isotope Separator (EMIS) as a prototype for reestablishing a US based enrichment capability for stable isotopes. ORNL has over 60 years of experience providing enriched stable isotopes and related technical services to the international accelerator target community, as well as medical, research, industrial, national security, and other communities. ORNL is investigating the combined use of electromagnetic and gas centrifuge isotope separation technologies to provide research quantities (milligram to several kilograms) of enriched stable isotopes. In preparation for implementing a larger scale production facility, a 10 mA high-resolution EMIS prototype has been built and tested. Initial testing of the device has simultaneously collected greater than 98% enriched samples of all the molybdenum isotopes from natural abundance feedstock.

  6. Stable isotope studies

    SciTech Connect (OSTI)

    Ishida, T.

    1992-01-01

    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  7. Isotopic Analysis-Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Estimate deep reservoir temperature Notes The oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes have been tested. Methods are...

  8. Isotopic Analysis-Fluid At Yellowstone Caldera Geothermal Region...

    Open Energy Info (EERE)

    Estimate deep reservoir temperature Notes The oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes have been tested. Methods are...

  9. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer therapy gets a boost from new isotope Isotope production facility produces cancer-fighting actinium A new medical isotope project shows promise for rapidly producing major quantities of a new cancer-treatment agent, actinium 225 (Ac-225). April 11, 2012 Los Alamos scientist Meiring Nortier holds a thorium foil test target for the proof-of-concept production experiments. Los Alamos scientist Meiring Nortier holds a thorium foil test target for the proof-of-concept production experiments.

  10. Conceptual Geologic Model and Native State Model of the Roosevelt...

    Open Energy Info (EERE)

    (Faulder, 1991) Geothermometry At Roosevelt Hot Springs Geothermal Area (Faulder, 1991) Ground Gravity Survey At Roosevelt Hot Springs Geothermal Area (Faulder, 1991) Isotopic...

  11. EIS-0310: Accomplishing Expanded Civilian Nuclear Energy Research and Development and Isotope Production Missions in the United States, Including the Role of the Fast Flux Test Facility

    Broader source: Energy.gov [DOE]

    This PEIS will evaluate the potential environmental impacts of the proposed enhancement of the existing infrastructure, including the possible role of the Fast Flux Test Facility (FFTF), located at...

  12. ARM - Measurement - Isotope ratio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsIsotope ratio ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Isotope ratio Ratio of stable isotope concentrations. Categories Atmospheric State, Atmospheric Carbon Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those

  13. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus. 2 figures.

  14. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, Jakob (Brookline, MA)

    1991-01-01

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus.

  15. Geochemical and Isotopic Evaluation of Groundwater Movement in Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada Test Site, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-02-01

    This report describes the results of a comprehensive geochemical evaluation of the groundwater flow system in the Yucca Flat/Climax Mine Corrective Action Unit (CAU). The main objectives of this study are to identify probable pathways for groundwater flow within the study area and to develop constraints on groundwater transit times between selected data collection sites. This work provides an independent means of testing and verifying predictive flow models being developed for this CAU using finite element methods. The Yucca Flat/Climax Mine CAU constitutes the largest of six underground test areas on the Nevada Test Site (NTS) specified for remedial action in the ''Federal Facility Agreement and Consent Order''. A total of 747 underground nuclear detonations were conducted in this CAU. Approximately 23 percent of these detonations were conducted below or near the water table, resulting in groundwater contamination in the vicinity and possibly downgradient of these underground test locations. Therefore, a rigorous evaluation of the groundwater flow system in this CAU is necessary to assess potential long-term risks to the public water supply at downgradient locations.

  16. Stable isotope enrichment

    SciTech Connect (OSTI)

    Egle, Brian

    2014-07-14

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  17. Stable isotope enrichment

    ScienceCinema (OSTI)

    Egle, Brian

    2014-07-15

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  18. Price Quotes and Isotope Ordering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ordering Price Quotes and Isotope Ordering Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Isotope...

  19. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Munich, DE); Boyer, Keith (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM)

    1988-01-01

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  20. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

    1987-04-28

    A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

  1. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1987-01-01

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  2. Research and Medical Isotope Reactor Supply | Y-12 National Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Complex Research and Medical ... Research and Medical Isotope Reactor Supply Our goal is to fuel research and test reactors with low-enriched uranium. Y-12 tops the short list of the world's most secure, reliable uranium feedstock suppliers for dozens of research and test reactors on six continents. These reactors can be used to test materials, irradiate new reactor fuel designs and produce medical isotopes for diagnostic and therapeutic purposes, as examples. The LEU is used to fabricate

  3. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1986-08-15

    The atomic vapor laser isotope separation (AVLIS) process for the enrichment of uranium is evaluated. (AIP)

  4. Plasma isotope separation methods

    SciTech Connect (OSTI)

    Grossman, M.W. ); Shepp, T.A. )

    1991-12-01

    Isotope separation has many important industrial, medical, and research applications. Large-scale processes have typically utilized complex cascade systems; for example, the gas centrifuge. Alternatively, high single-stage enrichment processes (as in the case of the calutron) are very energy intensive. Plasma-based methods being developed for the past 15 to 20 years have attempted to overcome these two drawbacks. In this review, six major types of isotope separation methods which involve plasma phenomena are discussed. These methods are: plasma centrifuge, AVLIS (atomic vapor laser isotope separation), ion wave, ICR (ion-cyclotron resonance), calutron, and gas discharge. The emphasis of this paper is to describe the plasma phenomena in these major categories. An attempt was made to include enough references so that more detailed study or evaluation of a particular method could readily be pursued. A brief discussion of isotope separation using mass balance concepts is also carried out.

  5. Enforcement Letter, International Isotopes Idaho Inc- August 20, 1999

    Broader source: Energy.gov [DOE]

    Issued to International Isotopes Idaho, Inc. related to the Relocation of an Irradiated Pellet at the Test Reactor Area Hot Cell Facility at the Idaho National Engineering and Environmental Laboratory

  6. Research and Medical Isotope Reactor Supply | Y-12 National Security...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research and Medical ... Research and Medical Isotope Reactor Supply Our goal is to fuel research and test reactors with low-enriched uranium. Y-12 tops the short list of the...

  7. Improved Geothermometry Through Multivariate Reaction Path Modeling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    enhanced geothermal systems (EGS) | geothermal 2015 peer review Chemical Impact of Elevated CO2on Geothermal Energy Production track 2: hydrothermal | geothermal 2015 peer review...

  8. Colorado thermal spring water geothermometry (public dataset...

    Open Energy Info (EERE)

    chemical geothermometers for Colorado thermal springs. Data citations include Barrett, J. K. and Pearl, R. H. (1976), George, R. D., Curtis, H. A., Lester, O. C., Crook, J. K.,...

  9. Geothermometry (Klein, 2007) | Open Energy Information

    Open Energy Info (EERE)

    In The Past 20 Years- Geochemistry In Geothermal Exploration Resource Evaluation And Reservoir Management Additional References Retrieved from "http:en.openei.orgw...

  10. Integrated Chemical Geothermometry System for Geothermal Exploration

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Develop practical and reliable system to predict geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids.

  11. Separation of sulfur isotopes

    DOE Patents [OSTI]

    DeWitt, Robert; Jepson, Bernhart E.; Schwind, Roger A.

    1976-06-22

    Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

  12. Isotope separation apparatus

    DOE Patents [OSTI]

    Arnush, Donald (Rancho Palos Verdes, CA); MacKenzie, Kenneth R. (Pacific Palisades, CA); Wuerker, Ralph F. (Palos Verdes Estates, CA)

    1980-01-01

    Isotope separation apparatus consisting of a plurality of cells disposed adjacent to each other in an evacuated container. A common magnetic field is established extending through all of the cells. A source of energetic electrons at one end of the container generates electrons which pass through the cells along the magnetic field lines. Each cell includes an array of collector plates arranged in parallel or in tandem within a common magnetic field. Sets of collector plates are disposed adjacent to each other in each cell. Means are provided for differentially energizing ions of a desired isotope by applying energy at the cyclotron resonant frequency of the desired isotope. As a result, the energized desired ions are preferentially collected by the collector plates.

  13. Hydrogen Isotope Exchange Properties of Porous Solids Containing Hydrogen

    SciTech Connect (OSTI)

    HEUNG, LEUNGK.

    2004-08-18

    Porous solids such as activated alumina, silica and molecular sieves generally contain significant amounts of hydrogen atoms in the form of H2O or OH even at high temperature and low humidity environment. A significant amount of this hydrogen is available for reversible isotopic exchange. This exchange reaction is slow under normal conditions and does not render itself to practical applications. But if the exchange kinetics is improved this reaction has the potential to be used for tritium removal from gas streams or for hydrogen isotopic separation.The use of catalysts to improve the exchange kinetics between hydrogen isotope in the gas phase and that in the solid phase was investigated. Granules of alumina, silica and molecular sieve were coated with platinum or palladium as the catalyst. The granules were packed in a 2-cm diameter column for isotope exchange tests. Gas streams containing different concentrations of deuterium in nitrogen or argon were fed through the protium saturated column. Isotope concentration in column effluent was monitored to generate isotope break-through curves. The curves were analyzed to produce information on the kinetics and capacity of the material. The results showed that all materials tested provided some extent of isotope exchange but some were superior both in kinetics and capacity. This paper will present the test results.

  14. Method for separating boron isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM)

    1978-01-01

    A method of separating boron isotopes .sup.10 B and .sup.11 B by laser-induced selective excitation and photodissociation of BCl.sub.3 molecules containing a particular boron isotope. The photodissociation products react with an appropriate chemical scavenger and the reaction products may readily be separated from undissociated BCl.sub.3, thus effecting the desired separation of the boron isotopes.

  15. Use of Stable Isotopes in Forensic Analysis of Microorganisms

    SciTech Connect (OSTI)

    Kreuzer-Martin, Helen W.; Hegg, Eric L.

    2012-01-18

    The use of isotopic signatures for forensic analysis of biological materials is well-established, and the same general principles that apply to interpretation of stable isotope content of C, N, O, and H apply to the analysis of microorganisms. Heterotrophic microorganisms derive their isotopic content from their growth substrates, which are largely plant and animal products, and the water in their culture medium. Thus the isotope signatures of microbes are tied to their growth environment. The C, N, O, and H isotope ratios of spores have been demonstrated to constitute highly discriminating signatures for sample matching. They can rule out specific samples of media and/or water as possible production media, and can predict isotope ratio ranges of the culture media and water used to produce a given sample. These applications have been developed and tested through analyses of approximately 250 samples of Bacillus subtilis spores and over 500 samples of culture media, providing a strong statistical basis for data interpretation. A Bayesian statistical framework for integrating stable isotope data with other types of signatures derived from microorganisms has been able to characterize the culture medium used to produce spores of various Bacillus species, leveraging isotopic differences in different medium types and demonstrating the power of data integration for forensic investigations.

  16. Price Quotes and Isotope Ordering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ordering Price Quotes and Isotope Ordering Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Isotope Business Office Oak Ridge National Laboratory 1 Bethel Valley Rd Bldg. 5700, Room R111 MS-6158 Oak Ridge, TN 37830-6158 Phone: (865) 574-6984 Fax: (865) 574-6986 http://www.isotopes.gov/ Technical Support Information regarding technical details on listed and unlisted isotopes may be obtained from: Mark Brugh Team

  17. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, C.A.; Worden, E.F.

    1995-08-22

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of {sup 167}Er. The hyperfine structure of {sup 167}Er was used to find two three-step photoionization pathways having a common upper energy level. 3 figs.

  18. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, Christopher A.; Worden, Earl F.

    1995-01-01

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  19. Quantifying uncertainty in stable isotope mixing models

    SciTech Connect (OSTI)

    Davis, Paul; Syme, James; Heikoop, Jeffrey; Fessenden-Rahn, Julianna; Perkins, George; Newman, Brent; Chrystal, Abbey E.; Hagerty, Shannon B.

    2015-05-19

    Mixing models are powerful tools for identifying biogeochemical sources and determining mixing fractions in a sample. However, identification of actual source contributors is often not simple, and source compositions typically vary or even overlap, significantly increasing model uncertainty in calculated mixing fractions. This study compares three probabilistic methods, SIAR [Parnell et al., 2010] a pure Monte Carlo technique (PMC), and Stable Isotope Reference Source (SIRS) mixing model, a new technique that estimates mixing in systems with more than three sources and/or uncertain source compositions. In this paper, we use nitrate stable isotope examples (?15N and ?18O) but all methods tested are applicable to other tracers. In Phase I of a three-phase blind test, we compared methods for a set of six-source nitrate problems. PMC was unable to find solutions for two of the target water samples. The Bayesian method, SIAR, experienced anchoring problems, and SIRS calculated mixing fractions that most closely approximated the known mixing fractions. For that reason, SIRS was the only approach used in the next phase of testing. In Phase II, the problem was broadened where any subset of the six sources could be a possible solution to the mixing problem. Results showed a high rate of Type I errors where solutions included sources that were not contributing to the sample. In Phase III some sources were eliminated based on assumed site knowledge and assumed nitrate concentrations, substantially reduced mixing fraction uncertainties and lowered the Type I error rate. These results demonstrate that valuable insights into stable isotope mixing problems result from probabilistic mixing model approaches like SIRS. The results also emphasize the importance of identifying a minimal set of potential sources and quantifying uncertainties in source isotopic composition as well as demonstrating the value of additional information in reducing the uncertainty in calculated mixing fractions.

  20. Isotopically labeled compositions and method

    DOE Patents [OSTI]

    Schmidt, Jurgen G. (Los Alamos, NM); Kimball, David B. (Los Alamos, NM); Alvarez, Marc A. (Santa Fe, NM); Williams, Robert F. (Los Alamos, NM); Martinez, Rudolfo A. (Santa Fe, NM)

    2011-07-12

    Compounds having stable isotopes .sup.13C and/or .sup.2H were synthesized from precursor compositions having solid phase supports or affinity tags.

  1. Advanced isotope separation

    SciTech Connect (OSTI)

    Not Available

    1982-05-04

    The Study Group briefly reviewed the technical status of the three Advanced Isotope Separation (AIS) processes. It also reviewed the evaluation work that has been carried out by DOE's Process Evaluation Board (PEB) and the Union Carbide Corporation-Nuclear Division (UCCND). The Study Group briefly reviewed a recent draft assessment made for DOE staff of the nonproliferation implications of the AIS technologies. The staff also very briefly summarized the status of GCEP and Advanced Centrifuge development. The Study Group concluded that: (1) there has not been sufficient progress to provide a firm scientific, technical or economic basis on which to select one of the three competing AIS processes for full-scale engineering development at this time; and (2) however, should budgetary restraints or other factors force such a selection, we believe that the evaluation process that is being carried out by the PEB provides the best basis available for making a decision. The Study Group recommended that: (1) any decisions on AIS processes should include a comparison with gas centrifuge processes, and should not be made independently from the plutonium isotope program; (2) in evaluating the various enrichment processes, all applicable costs (including R and D and sales overhead) and an appropriate discounting approach should be included in order to make comparisons on a private industry basis; (3) if the three AIS programs continue with limited resources, the work should be reoriented to focus only on the most pressing technical problems; and (4) if a decision is made to develop the Atomic Vapor Laser Isotope Separation process, the solid collector option should be pursued in parallel to alleviate the potential program impact of liquid collector thermal control problems.

  2. RESOLUTION OF URANIUM ISOTOPES WITH KINETIC PHOSPHORESCENCE ANALYSIS

    SciTech Connect (OSTI)

    Miley, Sarah M.; Hylden, Anne T.; Friese, Judah I.

    2013-04-01

    This study was conducted to test the ability of the Chemchek Kinetic Phosphorescence Analyzer Model KPA-11 with an auto-sampler to resolve the difference in phosphorescent decay rates of several different uranium isotopes, and therefore identify the uranium isotope ratios present in a sample. Kinetic phosphorescence analysis (KPA) is a technique that provides rapid, accurate, and precise determination of uranium concentration in aqueous solutions. Utilizing a pulsed-laser source to excite an aqueous solution of uranium, this technique measures the phosphorescent emission intensity over time to determine the phosphorescence decay profile. The phosphorescence intensity at the onset of decay is proportional to the uranium concentration in the sample. Calibration with uranium standards results in the accurate determination of actual concentration of the sample. Different isotopes of uranium, however, have unique properties which should result in different phosphorescence decay rates seen via KPA. Results show that a KPA is capable of resolving uranium isotopes.

  3. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T. (Livermore, CA)

    1981-01-01

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  4. Isotope Program Transportation | Department of Energy

    Office of Environmental Management (EM)

    Isotope Program Transportation Isotope Program Transportation PDF icon Isotope Program Transportation More Documents & Publications Nuclear Fuel Storage and Transportation Planning Project Overview Section 180(c) Ad Hoc Working Group DOE Office of Nuclear Energy

  5. Quantifying uncertainty in stable isotope mixing models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davis, Paul; Syme, James; Heikoop, Jeffrey; Fessenden-Rahn, Julianna; Perkins, George; Newman, Brent; Chrystal, Abbey E.; Hagerty, Shannon B.

    2015-05-19

    Mixing models are powerful tools for identifying biogeochemical sources and determining mixing fractions in a sample. However, identification of actual source contributors is often not simple, and source compositions typically vary or even overlap, significantly increasing model uncertainty in calculated mixing fractions. This study compares three probabilistic methods, SIAR [Parnell et al., 2010] a pure Monte Carlo technique (PMC), and Stable Isotope Reference Source (SIRS) mixing model, a new technique that estimates mixing in systems with more than three sources and/or uncertain source compositions. In this paper, we use nitrate stable isotope examples (δ15N and δ18O) but all methods testedmore » are applicable to other tracers. In Phase I of a three-phase blind test, we compared methods for a set of six-source nitrate problems. PMC was unable to find solutions for two of the target water samples. The Bayesian method, SIAR, experienced anchoring problems, and SIRS calculated mixing fractions that most closely approximated the known mixing fractions. For that reason, SIRS was the only approach used in the next phase of testing. In Phase II, the problem was broadened where any subset of the six sources could be a possible solution to the mixing problem. Results showed a high rate of Type I errors where solutions included sources that were not contributing to the sample. In Phase III some sources were eliminated based on assumed site knowledge and assumed nitrate concentrations, substantially reduced mixing fraction uncertainties and lowered the Type I error rate. These results demonstrate that valuable insights into stable isotope mixing problems result from probabilistic mixing model approaches like SIRS. The results also emphasize the importance of identifying a minimal set of potential sources and quantifying uncertainties in source isotopic composition as well as demonstrating the value of additional information in reducing the uncertainty in calculated mixing fractions.« less

  6. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, R.J.; Thorne, J.M.; Cluff, C.L.

    1981-01-23

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)-dichloroborane as the feed material. The photolysis can readily by achieved with CO/sub 2/ laser radiation and using fluences significantly below those required to dissociate BCl/sub 3/.

  7. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, Reed J. (Los Alamos, NM); Thorne, James M. (Provo, UT); Cluff, Coran L. (Provo, UT); Hayes, John K. (Salt Lake City, UT)

    1984-01-01

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)dichloroborane as the feed material. The photolysis can readily be achieved with CO.sub.2 laser radiation and using fluences significantly below those required to dissociate BCl.sub.3.

  8. Isotope separation by laser means

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1982-06-15

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  9. Compelling Research Opportunities using Isotopes

    SciTech Connect (OSTI)

    2009-04-23

    Isotopes are vital to the science and technology base of the US economy. Isotopes, both stable and radioactive, are essential tools in the growing science, technology, engineering, and health enterprises of the 21st century. The scientific discoveries and associated advances made as a result of the availability of isotopes today span widely from medicine to biology, physics, chemistry, and a broad range of applications in environmental and material sciences. Isotope issues have become crucial aspects of homeland security. Isotopes are utilized in new resource development, in energy from bio-fuels, petrochemical and nuclear fuels, in drug discovery, health care therapies and diagnostics, in nutrition, in agriculture, and in many other areas. The development and production of isotope products unavailable or difficult to get commercially have been most recently the responsibility of the Department of Energy's Nuclear Energy program. The President's FY09 Budget request proposed the transfer of the Isotope Production program to the Department of Energy's Office of Science in Nuclear Physics and to rename it the National Isotope Production and Application program (NIPA). The transfer has now taken place with the signing of the 2009 appropriations bill. In preparation for this, the Nuclear Science Advisory Committee (NSAC) was requested to establish a standing subcommittee, the NSAC Isotope Subcommittee (NSACI), to advise the DOE Office of Nuclear Physics. The request came in the form of two charges: one, on setting research priorities in the short term for the most compelling opportunities from the vast array of disciplines that develop and use isotopes and two, on making a long term strategic plan for the NIPA program. This is the final report to address charge 1. NSACI membership is comprised of experts from the diverse research communities, industry, production, and homeland security. NSACI discussed research opportunities divided into three areas: (1) medicine, pharmaceuticals, and biology, (2) physical sciences and engineering, and (3) national security and other applications. In each area, compelling research opportunities were considered and the subcommittee as a whole determined the final priorities for research opportunities as the foundations for the recommendations. While it was challenging to prioritize across disciplines, our order of recommendations reflect the compelling research prioritization along with consideration of time urgency for action as well as various geopolitical market issues. Common observations to all areas of research include the needs for domestic availability of crucial stable and radioactive isotopes and the education of the skilled workforce that will develop new advances using isotopes in the future. The six recommendations of NSACI reflect these concerns and the compelling research opportunities for potential new discoveries. The science case for each of the recommendations is elaborated in the respective chapters.

  10. Isotope Production at the Hanford Site in Richland, Washington

    SciTech Connect (OSTI)

    Ammoniums

    1999-06-01

    This report was prepared in response to a request from the Nuclear Energy Research Advisory Committee (NERAC) subcommittee on ''Long-Term Isotope Research and Production Plans.'' The NERAC subcommittee has asked for a reply to a number of questions regarding (1) ''How well does the Department of Energy (DOE) infrastructure sme the need for commercial and medical isotopes?'' and (2) ''What should be the long-term role of the federal government in providing commercial and medical isotopes?' Our report addresses the questions raised by the NERAC subcommittee, and especially the 10 issues that were raised under the first of the above questions (see Appendix). These issues are related to the isotope products offered by the DOE Isotope Production Sites, the capabilities and condition of the facilities used to produce these products, the management of the isotope production programs at DOE laboratories, and the customer service record of the DOE Isotope Production sites. An important component of our report is a description of the Fast Flux Test Facility (FFTF) reactor at the Hbford Site and the future plans for its utilization as a source of radioisotopes needed by nuclear medicine physicians, by researchers, and by customers in the commercial sector. In response to the second question raised by the NERAC subcommittee, it is our firm belief that the supply of isotopes provided by DOE for medical, industrial, and research applications must be strengthened in the near future. Many of the radioisotopes currently used for medical diagnosis and therapy of cancer and other diseases are imported from Canada, Europe, and Asia. This situation places the control of isotope availability, quality, and pricing in the hands of non-U.S. suppliers. It is our opinion that the needs of the U.S. customers for isotopes and isotope products are not being adequately served, and that the DOE infrastructure and facilities devoted to the supply of these products must be improved This perception forms one of the fundamental bases for our proposal that the FFTF, which is currently in a standby condition, be reactivated to supply nuclear services and products such as radioisotopes needed by the U.S. medical, industrial, and research communities.

  11. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  12. Y-12 begins to separate lithium isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    begins to separate lithium isotopes During the years from 1946 through the early 1950s, Y-12 continued to expand as needed to meet the demand for a growing primary mission of machining uranium. The increased support was required as the nuclear weapon stockpile was being built and the testing of new designs continued. With the decision by President Truman to develop the hydrogen bomb, Y-12 soon became engaged in manufacturing parts for both the standard atomic weapons and the new designs being

  13. Raman scattering method and apparatus for measuring isotope ratios and isotopic abundances

    DOE Patents [OSTI]

    Harney, Robert C.; Bloom, Stewart D.

    1978-01-01

    Raman scattering is used to measure isotope ratios and/or isotopic abundances. A beam of quasi-monochromatic photons is directed onto the sample to be analyzed, and the resulting Raman-scattered photons are detected and counted for each isotopic species of interest. These photon counts are treated mathematically to yield the desired isotope ratios or isotopic abundances.

  14. Isotopically Enriched Films and Nanostructures by Ultrafast Pulsed Laser Deposition

    SciTech Connect (OSTI)

    Peter Pronko

    2004-12-13

    This project involved a systematic study to apply newly discovered isotopic enrichment effects in laser ablation plumes to the fabrication of isotopically engineered thin films, superlattices, and nanostructures. The approach to this program involved using ultrafast lasers as a method for generating ablated plasmas that have preferentially structured isotopic content in the body of the ablation plasma plumes. In examining these results we have attempted to interpret the observations in terms of a plasma centrifuge process that is driven by the internal electro-magnetic fields of the plasma itself. The research plan involved studying the following phenomena in regard to the ablation plume and the isotopic mass distribution within it: (1) Test basic equations of steady state centrifugal motion in the ablation plasma. (2) Investigate angular distribution of ions in the ablation plasmas. (3) Examine interactions of plasma ions with self-generated magnetic fields. (3) Investigate ion to neutral ratios in the ablation plasmas. (5) Test concepts of plasma pumping. (6) Fabricate isotopically enriched nanostructures.

  15. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means. 3 figures.

  16. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, Jakob (Brookline, MA)

    1991-01-01

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means.

  17. Forensic Applications of Light-Element Stable Isotope Ratios of Ricinus communis Seeds and Ricin Preparations

    SciTech Connect (OSTI)

    Kreuzer, Helen W.; West, Jason B.; Ehleringer, James

    2013-01-01

    Seeds of the castor plant Ricinus communis, also known as castor beans, are of forensic interest because they are the source of the poison ricin. We have tested whether stable isotope ratios of castor seeds and ricin prepared by various methods can be used as a forensic signature. We collected over 300 castor seed samples from locations around the world and measured the C, N, O, and H stable isotope ratios of the whole seeds, oil, and three types of ricin preparations. Our results demonstrate that N isotope ratios can be used to correlate ricin prepared by any of these methods to source seeds. Further, stable isotope ratios distinguished >99% of crude and purified ricin protein samples in pair-wise comparison tests. Stable isotope ratios therefore constitute a valuable forensic signature for ricin preparations.

  18. Preliminary Notice of Violation, International Isotopes Idaho, Inc.- EA-2000-04

    Broader source: Energy.gov [DOE]

    Issued to International Isotopes Idaho, Inc., related to Work Planning and Control Deficiencies associated with Replacement of Exhaust Ventilation Filters at the Test Reactor Area Hot Cell Facility at the Idaho National Engineering and Environmental Laboratory, May 19, 2000

  19. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer therapy gets a boost from new isotope Isotope production facility produces cancer-fighting actinium A new medical isotope project shows promise for rapidly producing major...

  20. Isotope specific arbitrary material sorter

    DOE Patents [OSTI]

    Barty, Christopher P.J.

    2015-12-08

    A laser-based mono-energetic gamma-ray source is used to provide a rapid and unique, isotope specific method for sorting materials. The objects to be sorted are passed on a conveyor in front of a MEGa-ray beam which has been tuned to the nuclear resonance fluorescence transition of the desired material. As the material containing the desired isotope traverses the beam, a reduction in the transmitted MEGa-ray beam occurs. Alternately, the laser-based mono-energetic gamma-ray source is used to provide non-destructive and non-intrusive, quantitative determination of the absolute amount of a specific isotope contained within pipe as part of a moving fluid or quasi-fluid material stream.

  1. AVLIS enrichment of medical isotopes

    SciTech Connect (OSTI)

    Haynam, C.A.; Scheibner, K.F.; Stern, R.C.; Worden, E.F.

    1996-12-31

    Under the Sponsorship of the United states Enrichment Corporation (USEC), we are currently investigating the large scale separation of several isotopes of medical interest using atomic vapor isotope separation (AVLIS). This work includes analysis and experiments in the enrichment of thallium 203 as a precursor to the production of thallium 201 used in cardiac imaging following heart attacks, on the stripping of strontium 84 from natural strontium as precursor to the production of strontium 89, and on the stripping of lead 210 from lead used in integrated circuits to reduce the number of alpha particle induced logic errors.

  2. Online Catalog of Isotope Products from DOE's National Isotope Development Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. The Isotope subprogram supports the production, and the development of production techniques of radioactive and stable isotopes that are in short supply for research and applications. Isotopes are high-priority commodities of strategic importance for the Nation and are essential for energy, medical, and national security applications and for basic research; a goal of the program is to make critical isotopes more readily available to meet domestic U.S. needs. This subprogram is steward of the Isotope Production Facility (IPF) at Los Alamos National Laboratory (LANL), the Brookhaven Linear Isotope Producer (BLIP) facility at BNL, and hot cell facilities for processing isotopes at ORNL, BNL and LANL. The subprogram also coordinates and supports isotope production at a suite of university, national laboratory, and commercial accelerator and reactor facilities throughout the Nation to promote a reliable supply of domestic isotopes. The National Isotope Development Center (NIDC) at ORNL coordinates isotope production across the many facilities and manages the business operations of the sale and distribution of isotopes.

  3. Isotopes for cancer and cardiac care

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotopes for cancer Isotopes for cancer and cardiac care Eva Birnbaum is interviewed on KSFR radio on the Lab's Isotope Program February 4, 2016 hot cell facility A worker uses remote manipulator arms to handle a highly radioactive target inside the Lab's radiochemistry hot cell facility. Isotopes from Los Alamos are used for the diagnosis of cardiac disease, for the calibration of PET scanners which in turn diagnose cancer, neurological disease, inflammatory diseases, trauma, and other

  4. Science with Beams of Radioactive Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pacifichem 2015 Pacifichem 2015 The International Chemical Congress of Pacific Basin Societies Science with Beams of Radioactive Isotopes (# 340) Honolulu, Hawaii, USA December 15-20, 2015 Science with Beams of Radioactive Isotopes (# 340) All of the elements that make up the periodic chart have been created from nuclear reactions. Many of the stable nuclei in the universe are daughters of unstable isotopes, and their true origin lies in the stellar reactions of these radioactive isotopes. Thus

  5. Isotope Cancer Treatment Research at LANL

    ScienceCinema (OSTI)

    Weidner, John; Nortier, Meiring

    2014-06-02

    Los Alamos National Laboratory has produced medical isotopes for diagnostic and imaging purposes for more than 30 years. Now LANL researchers have branched out into isotope cancer treatment studies. New results show that an accelerator-based approach can produce clinical trial quantities of actinium-225, an isotope that has promise as a way to kill tumors without damaging surrounding healthy cells.

  6. Isotope and Nuclear Chemistry Division annual report FY 1986, October 1985-September 1986

    SciTech Connect (OSTI)

    Heiken, J.H. (ed.)

    1987-06-01

    This report describes progress in the major research and development programs carried out in FY 1986 by the Isotope and Nuclear Chemistry Division. The report includes articles on radiochemical diagnostics and weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production and separation; chemical biology and nuclear medicine; element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced concepts and technology; and atmospheric chemistry.

  7. Measuring SNM Isotopic Distributions using FRAM

    SciTech Connect (OSTI)

    Geist, William H.

    2015-12-02

    The first group of slides provides background information on the isotopic composition of plutonium. It is shown that 240Pu is the critical isotope in neutron coincidence/multiplicity counting. Next, response function analysis to determine isotopic composition is discussed. The isotopic composition can be determined by measuring the net peak counts from each isotope and then taking the ratio of the counts for each isotope relative to the total counts for the element. Then FRAM (Fixed energy Response function Analysis with Multiple efficiencies) is explained. FRAM can control data acquisition, automatically analyze newly acquired data, analyze previously acquired data, provide information on the quality of the analysis, and facilitate analysis in unusual situations (non-standard energy calibrations, gamma rays from non-SNM isotopes, poor spectra (within limits)).

  8. Laser ablation molecular isotopic spectrometry of carbon isotopes

    SciTech Connect (OSTI)

    Bol'shakov, Alexander A.; Jain, Jinesh; Russo, Richard E.; McIntyre, Dustin; Mao, Xianglei

    2015-08-28

    Quantitative determination of carbon isotopes using Laser Ablation Molecular Isotopic Spectrometry (LAMIS) is described. Optical emission of diatomic molecules CN and C2 is used in these measurements. Two quantification approaches are presented:empirical calibration of spectra using a set of reference standards and numerical fitting of a simulated spectrum to the experimental one. Formation mechanisms of C2 and CN in laser ablation plasma are briefly reviewed to provide insights for implementation of LAMIS measurements. A simulated spectrum of the 12C2 Swan system was synthesized using four constituents within 473.5–476.5 nm. Simulation included three branches of 12C2 (1-0), branches R(0-0) and R(1-1), and branch P(9-8) of 12C2. Spectral positions of the tail lines in R(0-0) and R(1-1) were experimentally measured, since they were not accurately known before. The Swan band (1-0) of the isotopologue 13C12C was also simulated. Fitting to the experimental spectrumyielded the ratio 13C/12C = 1.08% in a good agreement with measurements by isotope ratio mass spectrometry. LAMIS promises to be useful in coal, oil and shale exploration, carbon sequestration monitoring, and agronomy studies

  9. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  10. Performance testing accountability measurements

    SciTech Connect (OSTI)

    Oldham, R.D.; Mitchell, W.G.; Spaletto, M.I.

    1993-12-31

    The New Brunswick Laboratory (NBL) provides assessment support to the DOE Operations Offices in the area of Material Control and Accountability (MC and A). During surveys of facilities, the Operations Offices have begun to request from NBL either assistance in providing materials for performance testing of accountability measurements or both materials and personnel to do performance testing. To meet these needs, NBL has developed measurement and measurement control performance test procedures and materials. The present NBL repertoire of performance tests include the following: (1) mass measurement performance testing procedures using calibrated and traceable test weights, (2) uranium elemental concentration (assay) measurement performance tests which use ampulated solutions of normal uranyl nitrate containing approximately 7 milligrams of uranium per gram of solution, and (3) uranium isotopic measurement performance tests which use ampulated uranyl nitrate solutions with enrichments ranging from 4% to 90% U-235. The preparation, characterization, and packaging of the uranium isotopic and assay performance test materials were done in cooperation with the NBL Safeguards Measurements Evaluation Program since these materials can be used for both purposes.

  11. Experimental Test of Self-Shielding in VUV Photodissociation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the ...

  12. Alternative applications of atomic vapor laser isotope separation technology

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This report was commissioned by the Secretary of Energy. It summarizes the main features of atomic vapor laser isotope separation (AVLIS) technology and subsystems; evaluates applications, beyond those of uranium enrichment, suggested by Lawrence Livermore National Laboratory (LLNL) and a wide range of US industries and individuals; recommends further work on several applications; recommends the provision of facilities for evaluating potential new applications; and recommends the full involvement of end users from the very beginning in the development of any application. Specifically excluded from this report is an evaluation of the main AVLIS missions, uranium enrichment and purification of plutonium for weapons. In evaluating many of the alternative applications, it became clear that industry should play a greater and earlier role in the definition and development of technologies with the Department of Energy (DOE) if the nation is to derive significant commercial benefit. Applications of AVLIS to the separation of alternate (nonuranium) isotopes were considered. The use of {sup 157}Gd as burnable poison in the nuclear fuel cycle, the use {sup 12}C for isotopically pure diamond, and the use of plutonium isotopes for several nonweapons applications are examples of commercially useful products that might be produced at a cost less than the product value. Separations of other isotopes such as the elemental constituents of semiconductors were suggested; it is recommended that proposed applications be tested by using existing supplies to establish their value before more efficient enrichment processes are developed. Some applications are clear, but their production costs are too high, the window of opportunity in the market has passed, or societal constraints (e.g., on reprocessing of reactor fuel) discourage implementation.

  13. EIS-0249: Medical Isotopes Production Project

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential environmental impacts of a proposal to establish a production capability for molybdenum-99 (Mo-99) and related medical isotopes.

  14. Categorical Exclusion 4577: Lithium Isotope Separation & Enrichment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Isotope Separation & Enrichment Technologies (4577) Program or Field Office: Y-12 Site Office Location(s) (CityCountyState): Oak Ridge, Anderson County, Tennessee...

  15. Uranium isotopes fingerprint biotic reduction

    SciTech Connect (OSTI)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-04-20

    Knowledge of paleo-redox conditions in the Earths history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U), i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earths crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.

  16. Uranium isotopes fingerprint biotic reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-04-20

    Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U),more » i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.« less

  17. Spatial periphery of lithium isotopes

    SciTech Connect (OSTI)

    Galanina, L. I. Zelenskaja, N. S.

    2013-12-15

    The spatial structure of lithium isotopes is studied with the aid of the charge-exchange and (t, p) reactions on lithium nuclei. It is shown that an excited isobaric-analog state of {sup 6}Li (0{sup +}, 3.56MeV) has a halo structure formed by a proton and a neutron, that, in the {sup 9}Li nucleus, there is virtually no neutron halo, and that {sup 11}Li is a Borromean nucleus formed by a {sup 9}Li core and a two-neutron halo manifesting itself in cigar-like and dineutron configurations.

  18. Uranium molecular laser isotope separation

    SciTech Connect (OSTI)

    Jensen, R.J.; Sullivan, A.

    1982-01-01

    The Molecular Laser Isotope Separation program is moving into the engineering phase, and it is possible to determine in some detail the plant cost terms involved in the process economics. A brief description of the MLIS process physics is given as a motivation to the engineering and economics discussion. Much of the plant cost arises from lasers and the overall optical system. In the paper, the authors discuss lasers as operating units and systems, along with temporal multiplexing and Raman shifting. Estimates of plant laser costs are given.

  19. Isotopic prediction of eruption volume at continental volcanoes

    SciTech Connect (OSTI)

    Perry, F.V.; Valentine, G.A.; Crowe, B.M.

    1997-10-01

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The objective of this project was to determine whether isotopic techniques can be used to assess the eruption potential and eruption volume of continental stratovolcanoes. Large-volume eruptions from stratovolcanoes pose significant hazards to population and infrastructure in many parts of the world. We are testing whether this technique will allow a short- to medium-term (decades to millennia) probabilistic hazard assessment of large-volume eruptions. If successful, the technique will be useful to countries or regions that must consider medium to long-term volcanic (e.g., nuclear waste facilities). We have begun sample acquisition and isotopic measurements at two stratovolcanoes, Pico de Orizaba in eastern Mexico and Daisen in western Japan.

  20. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  1. Geothermometry At Teels Marsh Area (Coolbaugh, Et Al., 2006)...

    Open Energy Info (EERE)

    useful DOE-funding Unknown Notes Follow up (to ASTER satellite imaging) analysis of spring and well waters yielded geothermometer reservoir estimates up to 192C References...

  2. Geothermometry At Rhodes Marsh Area (Coolbaugh, Et Al., 2006...

    Open Energy Info (EERE)

    useful DOE-funding Unknown Notes Follow up (to ASTER satellite imaging) analysis of spring and well waters yielded geothermometer reservoir estimates up to 162C References...

  3. Geothermometry At Salt Wells Area (Edmiston & Benoit, 1984) ...

    Open Energy Info (EERE)

    and drilled during the early 1980's that had not been documented previously in the literature, (2) summarize and compare chemical and temperature data from known moderate- to...

  4. Geochemistry And Geothermometry Of Spring Water From The Blackfoot...

    Open Energy Info (EERE)

    for eight springs along the Corral Creek drainage. The springs along Corral Creek have Na-K-Ca temperatures that average 354C, a direct result of high potassium concentrations in...

  5. Geothermometry At Hot Springs Ranch Area (Szybinski, 2006) |...

    Open Energy Info (EERE)

    of two distinct waters in this group of samples (Tom Powell of Thermochem Inc., personal communication, 2005). Powell found that MDH, TRS-1 and TRS-6 are the most prospective...

  6. Geothermometry At Coso Geothermal Area (1978) | Open Energy Informatio...

    Open Energy Info (EERE)

    analysis to determine fluid origin. The surface expression of fumarole and acid sulfate pools and shallow steam wells gives a false indication of an extensive vapor...

  7. Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl...

    Open Energy Info (EERE)

    Celcius References R.H. Pearl, J.K. Barrett (1976) Geothermal resources of the Upper San Luis and Arkansas valleys, Colorado Additional References Retrieved from "http:...

  8. Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward...

    Open Energy Info (EERE)

    Area. References S. H. Ward, W. T. Parry, W. P. Nash, W. R. Sill, K. L. Cook, R. B. Smith, D. S. Chapman, F. H. Brown, J. A. Whelan, J. R. Bowman (1978) A Summary of the...

  9. Geothermometry At Raft River Geothermal Area (1980) | Open Energy...

    Open Energy Info (EERE)

    River geothermal system, Cassia County, Idaho Urban, T.C.; Diment, W.H.; Nathenson, M.; Smith, E.P.; Ziagos, J.P.; Shaeffer, M.H. (1 January 1986) Temperature,...

  10. Geothermometry At Long Valley Caldera Geothermal Area (Sorey...

    Open Energy Info (EERE)

    studies, and seem to prove useful in most cases (Flexser, 1991; Goff et al., 1991; Smith and Suemnicht, 1991). Results from these studies are also summarized in Sorey et al....

  11. Geothermometry At Socorro Mountain Area (Owens, Et Al., 2005...

    Open Energy Info (EERE)

    thermal waters with a minimum of 82oC at depth References Lara Owens, Richard Baars, David Norman, Harold Tobin (2005) New Methods In Exploration At The Socorro Peak Kgra- A...

  12. Geothermometry At Long Valley Caldera Geothermal Area (McKenzie...

    Open Energy Info (EERE)

    published in 1976 (Mariner and Willey, 1976). Details of sampling practices and field treatment are detailed in the text. Water samples were passed through a 0.7x4 cm column...

  13. Geothermometry At Salt Wells Area (Coolbaugh, Et Al., 2006) ...

    Open Energy Info (EERE)

    and ICP emission for anions. The hottest sampled spring appears to match the location and temperature of the Borax Spring, first described in 1885, but reportedly inactive in 1981...

  14. Geothermometry At Northern Basin & Range Region (Cole, 1983)...

    Open Energy Info (EERE)

    Fish (Wilson), Twin Peak, Cudahy, Laverkin, Grantsville, Crystal Prison, Arrowhead, Red Hill, Monroe, Joseph, Castilla, Saratoga, Thermo, Crater, Wasatch, Beck, Deseret, Big...

  15. Geothermometry At Lahaina-Kaanapali Area (Thomas, 1986) | Open...

    Open Energy Info (EERE)

    Date Usefulness not indicated DOE-funding Unknown Notes Groundwater temperature and chemistry surveys were similarly unable to identify any detectable thermal influence on...

  16. Geothermometry At Northern Basin & Range Region (Laney, 2005...

    Open Energy Info (EERE)

    Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which...

  17. Geothermometry At Buffalo Valley Hot Springs Area (Laney, 2005...

    Open Energy Info (EERE)

    Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which...

  18. Geothermometry At Nw Basin & Range Region (Laney, 2005) | Open...

    Open Energy Info (EERE)

    Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which...

  19. Geothermometry At Central Nevada Seismic Zone Region (Laney,...

    Open Energy Info (EERE)

    Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which...

  20. Geothermometry At Kawaihae Area (Thomas, 1986) | Open Energy...

    Open Energy Info (EERE)

    however, the data that are available strongly substantiate the presence of a thermal resource. A measured water temperature of 31 degrees C in one well is clearly above normal...

  1. Geothermometry At Columbus Salt Marsh Area (Shevenell, Et Al...

    Open Energy Info (EERE)

    References Lisa Shevenell, Mark Coolbaugh, Chris Sladek, Rick Zehner, Chris Kratt, James Faulds, Robin Penfield (2008) Our Evolving Knowledge Of Nevada'S Geothermal Resource...

  2. Geothermometry At Teels Marsh Area (Shevenell, Et Al., 2008)...

    Open Energy Info (EERE)

    References Lisa Shevenell, Mark Coolbaugh, Chris Sladek, Rick Zehner, Chris Kratt, James Faulds, Robin Penfield (2008) Our Evolving Knowledge Of Nevada'S Geothermal Resource...

  3. Geothermometry At Rhodes Marsh Area (Shevenell, Et Al., 2008...

    Open Energy Info (EERE)

    References Lisa Shevenell, Mark Coolbaugh, Chris Sladek, Rick Zehner, Chris Kratt, James Faulds, Robin Penfield (2008) Our Evolving Knowledge Of Nevada'S Geothermal Resource...

  4. Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008...

    Open Energy Info (EERE)

    Mark Coolbaugh, Chris Sladek, Rick Zehner, Robin Penfield, Ben Delwiche (2008) A New Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys...

  5. Geothermometry At U.S. Midwest Region (Vugrinovich, 1987) | Open...

    Open Energy Info (EERE)

    Activity Date Usefulness useful DOE-funding Unknown Notes Michigan "The silica heat flow estimator does provide estimates of surface heat flow which appear to be in good...

  6. Geothermometry At Lualualei Valley Area (Thomas, 1986) | Open...

    Open Energy Info (EERE)

    have been commonly used in Hawaii for identifying geothermal potential (i.e. silica concentration and chloride to magnesium ion ratios) were anomalous in the groundwater of this...

  7. Development of the laser isotope separation method (AVLIS) for obtaining weight amounts of highly enriched {sup 150}Nd isotope

    SciTech Connect (OSTI)

    Babichev, A P; Grigoriev, Igor' S; Grigoriev, A I; Dorovskii, A P; D'yachkov, Aleksei B; Kovalevich, S K; Kochetov, V A; Kuznetsov, V A; Labozin, Valerii P; Matrakhov, A V; Mironov, Sergei M; Nikulin, Sergei A; Pesnya, A V; Timofeev, N I; Firsov, Valerii A; Tsvetkov, G O; Shatalova, G G

    2005-10-31

    Results obtained at the first stage of development of the experimental technique for obtaining weight amounts of the highly enriched {sup 150}Nd isotope by laser photoionisation are presented. The vaporiser and the laser are designed, and various methods of irradiation of neodymium vapour and extraction of photoions are tested. The product yield {approx}40 mg h{sup -1} for the {approx}60% enrichment and 25 mg h{sup -1} for the {approx}65% enrichment is achieved for a vaporiser of length 27 cm. The cost of constructing the facility for preparing 50 kg of the {sup 150}Nd isotope, intended for determining the neutrino mass, is estimated. This estimate shows that the cost of production can be lowered by a factor of 5-7 compared to the electromagnetic method. (invited paper)

  8. Final Report, NEAC Subcommittee for Isotope Research & Production Planning

    Office of Environmental Management (EM)

    | Department of Energy Final Report, NEAC Subcommittee for Isotope Research & Production Planning Final Report, NEAC Subcommittee for Isotope Research & Production Planning Isotopes, including both radioactive and stable isotopes, make important contributions to research, medicine, and industry in the United States and throughout the world. For nearly fifty years, the Department of Energy (DOE) has actively promoted the use of isotopes by funding (a) production of isotopes at a

  9. Advanced Mass Spectrometers for Hydrogen Isotope Analyses

    SciTech Connect (OSTI)

    Chastagner, P.

    2001-08-01

    This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

  10. Isotope separation by selective photodissociation of glyoxal

    DOE Patents [OSTI]

    Marling, John B.

    1976-01-01

    Dissociation products, mainly formaldehyde and carbon monoxide, enriched in a desired isotope of carbon, oxygen, or hydrogen are obtained by the selective photodissociation of glyoxal wherein glyoxal is subjected to electromagnetic radiation of a predetermined wavelength such that photon absorption excites and induces dissociation of only those molecules of glyoxal containing the desired isotope.

  11. Efficient palladium isotope chromatograph for hydrogen (EPIC)

    SciTech Connect (OSTI)

    Embury, M.C.; Ellefson, R.E.; Melke, H.B. )

    1992-03-01

    The Efficient Palladium Isotope Chromatograph (EPIC) is a rapid cycling, computer-operated displacement chromatograph for the separation of hydrogen isotopes. EPIC incorporates several features that optimize product throughput and purity. This paper describes this palladium displacement chromatograph, the operations with protium and deuterium, and the design modifications for operation with tritium.

  12. Plutonium Isotopes in the Terrestrial Environment at the Savannah...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Plutonium Isotopes in the Terrestrial Environment at the Savannah River Site, USA. A Long-Term Study Citation Details In-Document Search Title: Plutonium Isotopes...

  13. Isotopic Analysis At Fenton Hill Hdr Geothermal Area (Goff, Et...

    Open Energy Info (EERE)

    Isotopic Analysis At Fenton Hill Hdr Geothermal Area (Goff, Et Al., 1981) Redirect page Jump to: navigation, search REDIRECT Isotopic Analysis- Fluid At Fenton Hill Hdr Geothermal...

  14. Advances in Hydrogen Isotope Separation Using Thermal Cycling...

    Office of Environmental Management (EM)

    Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Presentation...

  15. Cancer-fighting treatment gets boost from Isotope Production...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer-fighting treatment gets boost from Isotope Production Facility Cancer-fighting treatment gets boost from Isotope Production Facility New capability expands existing program,...

  16. Permeation of Multiple Isotopes in the Transition Between Surface...

    Office of Environmental Management (EM)

    Permeation of Multiple Isotopes in the Transition Between Surface- and Diffusion-Limited Regimes Permeation of Multiple Isotopes in the Transition Between Surface- and...

  17. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  18. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, K.F.; Haynam, C.A.; Johnson, M.A.; Worden, E.F.

    1999-08-31

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207. 5 figs.

  19. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, Karl F. (Tracy, CA); Haynam, Christopher A. (Pleasanton, CA); Johnson, Michael A. (Pleasanton, CA); Worden, Earl F. (Diablo, CA)

    1999-01-01

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207.

  20. Apparatus for storing hydrogen isotopes

    DOE Patents [OSTI]

    McMullen, John W. (Los Alamos, NM); Wheeler, Michael G. (Los Alamos, NM); Cullingford, Hatice S. (Houston, TX); Sherman, Robert H. (Los Alamos, NM)

    1985-01-01

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas(es) is (are) stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forming at a significantly lower temperature).

  1. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1985-11-08

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power reactor fuel has been under development for over 10 years. In June 1985 the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for the internationally competitive production of uranium separative work. The economic basis for this decision is considered, with an indicated of the constraints placed on the process figures of merit and the process laser system. We then trace an atom through a generic AVLIS separator and give examples of the physical steps encountered, the models used to describe the process physics, the fundamental parameters involved, and the role of diagnostic laser measurements.

  2. The Atomic Vapor Laser Isotope Separation Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management`s position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  3. Isotope separation by photoselective dissociative electron capture

    DOE Patents [OSTI]

    Stevens, C.G.

    1978-08-29

    Disclosed is a method of separating isotopes based on photoselective electron capture dissociation of molecules having an electron capture cross section dependence on the vibrational state of the molecule. A molecular isotope source material is irradiated to selectively excite those molecules containing a desired isotope to a predetermined vibrational state having associated therewith an electron capture energy region substantially non-overlapping with the electron capture energy ranges associated with the lowest vibration states of the molecules. The isotope source is also subjected to electrons having an energy corresponding to the non-overlapping electron capture region whereby the selectively excited molecules preferentially capture electrons and dissociate into negative ions and neutrals. The desired isotope may be in the negative ion product or in the neutral product depending upon the mechanism of dissociation of the particular isotope source used. The dissociation product enriched in the desired isotope is then separated from the reaction system by conventional means. Specifically, [sup 235]UF[sub 6] is separated from a UF[sub 6] mixture by selective excitation followed by dissociative electron capture into [sup 235]UF[sub 5]- and F. 2 figs.

  4. Isotope separation by photoselective dissociative electron capture

    DOE Patents [OSTI]

    Stevens, Charles G. [Pleasanton, CA

    1978-08-29

    A method of separating isotopes based on photoselective electron capture dissociation of molecules having an electron capture cross section dependence on the vibrational state of the molecule. A molecular isotope source material is irradiated to selectively excite those molecules containing a desired isotope to a predetermined vibrational state having associated therewith an electron capture energy region substantially non-overlapping with the electron capture energy ranges associated with the lowest vibration states of the molecules. The isotope source is also subjected to electrons having an energy corresponding to the non-overlapping electron capture region whereby the selectively excited molecules preferentially capture electrons and dissociate into negative ions and neutrals. The desired isotope may be in the negative ion product or in the neutral product depending upon the mechanism of dissociation of the particular isotope source used. The dissociation product enriched in the desired isotope is then separated from the reaction system by conventional means. Specifically, .sup.235 UF.sub.6 is separated from a UF.sub.6 mixture by selective excitation followed by dissociative electron capture into .sup.235 UF.sub.5 - and F.

  5. Automated Nuclear Data Test Suite

    Energy Science and Technology Software Center (OSTI)

    2013-01-09

    Provides python routines to create a database of test problems in a user-defined directory tree, to query the database using user-defined parameters, to generate a list of test urns, to automatically run with user-defined particle transport codes. Includes natural isotope abundance data, and a table of benchmark effective for fast critical assemblies. Does not include input decks, cross-section libraries, or particle transport codes.

  6. Isotope effects on desorption kinetics of hydrogen isotopes implanted into stainless steel by glow discharge

    SciTech Connect (OSTI)

    Matsuyama, M.; Kondo, M.; Noda, N.; Tanaka, M.; Nishimura, K.

    2015-03-15

    In a fusion device the control of fuel particles implies to know the desorption rate of hydrogen isotopes by the plasma-facing materials. In this paper desorption kinetics of hydrogen isotopes implanted into type 316L stainless steel by glow discharge have been studied by experiment and numerical calculation. The temperature of a maximum desorption rate depends on glow discharge time and heating rate. Desorption spectra observed under various experimental conditions have been successfully reproduced by numerical simulations that are based on a diffusion-limited process. It is suggested, therefore, that desorption rate of a hydrogen isotope implanted into the stainless steel is limited by a diffusion process of hydrogen isotope atoms in bulk. Furthermore, small isotope effects were observed for the diffusion process of hydrogen isotope atoms. (authors)

  7. Isotope-enriched protein standards for computational amide I spectroscopy

    SciTech Connect (OSTI)

    Reppert, Mike; Roy, Anish R.; Tokmakoff, Andrei

    2015-03-28

    We present a systematic isotope labeling study of the protein G mutant NuG2b as a step toward the production of reliable, structurally stable, experimental standards for amide I infrared spectroscopic simulations. By introducing isotope enriched amino acids into a minimal growth medium during bacterial expression, we induce uniform labeling of the amide bonds following specific amino acids, avoiding the need for chemical peptide synthesis. We use experimental data to test several common amide I frequency maps and explore the influence of various factors on map performance. Comparison of the predicted absorption frequencies for the four maps tested with empirical assignments to our experimental spectra yields a root-mean-square error of 6-12 cm{sup −1}, with outliers of at least 12 cm{sup −1} in all models. This means that the predictions may be useful for predicting general trends such as changes in hydrogen bonding configuration; however, for finer structural constraints or absolute frequency assignments, the models are unreliable. The results indicate the need for careful testing of existing literature maps and shed light on possible next steps for the development of quantitative spectral maps.

  8. Atomic vapor laser isotope separation process

    DOE Patents [OSTI]

    Wyeth, R.W.; Paisner, J.A.; Story, T.

    1990-08-21

    A laser spectroscopy system is utilized in an atomic vapor laser isotope separation process. The system determines spectral components of an atomic vapor utilizing a laser heterodyne technique. 23 figs.

  9. Isotope separation by photochromatography (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Isotope separation by photochromatography Citation Details In-Document Search Title: Isotope separation by photochromatography An isotope separation method which comprises physically adsorbing an isotopically mixed molecular species on an adsorptive surface and irradiating the adsorbed molecules with radiation of a predetermined wavelength which will selectively excite a desired isotopic species. Sufficient energy is transferred to the excited molecules to desorb them from the surface

  10. Environmental assessment: special isotope separation process selection

    SciTech Connect (OSTI)

    Not Available

    1986-04-01

    This Environmental Assessment (EA) evaluates the differences in potential environmental impacts between two plutonium Special Isotope Separation (SIS) technologies: Atomic Vapor Laser Isotope Separation (AVLIS) and Molecular Laser Isotope Separation (MLIS). Both SIS technologies use PuO/sub 2/ as feed; AVLIS converts feed to plutonium metal and MLIS converts feed to PuF/sub 6/. The AVLIS process uses laser energy to selectively photoionize and electrostatically separate plutonium isotopes from an atomic vapor stream. The MLIS process uses laser energy to selectively disassociate specific isotopes of plutonium in the form of PuF/sub 6/ molecules to create PuF/sub 5/ for collection and further processing. Both processes produce plutonium metal as their product. An evaluation of differences in potential environmental impacts attributed to the construction of an SIS facility, based on either technology, included a comparison of construction materials, land areas required, and the size of the design and construction workforce. The differences in potential environmental impacts from operating an SIS facility were also compared. No large differences in potential environmental impacts would be expected from the use of process chemicals. An AVLIS or an MLIS facility would produce operating effluents that would meet all applicable radiation, chemical, and hazardous waste standards and would be constructed to protect workers, the public and the environment. This EA has not revealed any significant differences in the potential environmental impacts that could occur as a result of deploying either the AVLIS or the MLIS Special Isotope Separation technology.

  11. TRIFID (TRansuranic Isotopic Fraction Interrogation Device): A second generation plutonium isotopic analysis system

    SciTech Connect (OSTI)

    Fleissner, J G; Coressel, T W; Freier, D A; Macklin, L L

    1989-01-01

    The TRIFID (Transuranic Isotopic Fraction Interrogation Device) system is a second generation plutonium isotopic analysis system which incorporates many new and unique features in the area of isotopic data acquisition and isotopic analysis instrument consisting of a Canberra Series 95-MCA interfaced to a Compaq 386 computer. The entire TRIFID software package, including MCA communications and isotopic analysis routines, was developed using the C programming language. Extensive use has been made of user friendly screens and menus for ease of operation and training and to facilitate use by technical level operators. Automated TRIFID features provide for MCA/ADC setup and acquisition, spectral storage, isotopic analysis, and report generation. One unique feature of the TRIFID system design allows it to be pre-programed for an entire day's counting. The isotopic analysis module (EPICS) contains an expert system formalism which is used to detect and assay for spectral interferences, and to automatically adjust peak fitting constraints based on spectral intensity variations. A TRIFID system has been in operation in a production laboratory at the Rocky Flats Plant since September 1988. Marked decreases in training and hands-on operation time have been achieved in comparison to the older, preceding isotopic systems. 2 refs., 3 figs.

  12. Chemical and isotopic data for groundwater in southern Nevada

    SciTech Connect (OSTI)

    Rose, T. P., LLNL

    1997-07-01

    This document presents a compilation of chemical and isotopic data for groundwater samples analyzed by Lawrence Livermore National Laboratory (LLNL) in support of the Hydrology and Radionuclide Migration Program (HRMP) and the Underground Test Area Program (UGTA) for the U.S. Department of Energy, Nevada Operations Office. Included are data for 107 samples collected from wells and springs located on and around the Nevada Test Site (NTS), within an area approximately bounded by latitudes 36{sup o} to 38{sup o}15'N and longitudes 115{sup o} to 117{sup o}15'W. The samples were collected during the time period 1992 to early 1997. The data represents one of the largest internally consistent geochemical data sets to be gathered for groundwater in southern Nevada. This database is available in electronic or hardcopy formats to interested parties upon request. In addition to the LLNL data we have included a table of selected isotopic data summarized from a larger database compiled by GeoTrans, Inc. (1994). This data is included for comparative purposes as a means of placing the LLNL data in the context of other data for the same geographic region.

  13. An efficient palladium isotope chromatograph (EPIC) for hydrogen

    SciTech Connect (OSTI)

    Rutherford, W.M.

    1989-06-20

    The efficient palladium isotope chromatography (EPIC) system is based on a palladium displacement chromatograph developed and tested for the preparative scale separation of the isotopes of hydrogen. Rapid cycling and high efficiency are obtained by use of high-performance packing operating at an elevated temperature (80/degree/C) and elevated pressure (1.5 atm). The process, which was tested with a 50/50 mixture of hydrogen and deuterium, depends on the exploitation of thermally driven pressure differences to recover and recycle the mixed transition zone between the bands of the pure components and also to recover and recycle the hydrogen gas used as the displacing agent. The purity of the product is significantly enhanced by partially backfilling the column with pure deuterium at the beginning of each displacement cycle. The computer-controlled system operates continuously, and it is capable of separating 2.2 std L/hr of feed at product assays of 99.86 at. % hydrogen and 99.992 at. % deuterium. 11 refs., 5 figs., 1 tab.

  14. Improved precision and accuracy in quantifying plutonium isotope ratios by RIMS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Isselhardt, B. H.; Savina, M. R.; Kucher, A.; Gates, S. D.; Knight, K. B.; Hutcheon, I. D.

    2015-09-01

    Resonance ionization mass spectrometry (RIMS) holds the promise of rapid, isobar-free quantification of actinide isotope ratios in as-received materials (i.e. not chemically purified). Recent progress in achieving this potential using two Pu test materials is presented. RIMS measurements were conducted multiple times over a period of two months on two different Pu solutions deposited on metal surfaces. Measurements were bracketed with a Pu isotopic standard, and yielded absolute accuracies of the measured 240Pu/239Pu ratios of 0.7% and 0.58%, with precisions (95% confidence intervals) of 1.49% and 0.91%. In conclusion, the minor isotope 238Pu was also quantified despite the presence ofmore » a significant quantity of 238U in the samples.« less

  15. An ion guide laser ion source for isobar-suppressed rare isotope beams

    SciTech Connect (OSTI)

    Raeder, Sebastian Ames, Friedhelm; Bishop, Daryl; Bricault, Pierre; Kunz, Peter; Mjs, Anders; Heggen, Henning; Institute of Applied Physics, TU Darmstadt, Schlossgartenstr. 7, 64289 Darmstadt ; Lassen, Jens Teigelhfer, Andrea; Department of Physics and Astronomy, University of Manitoba, Winnipeg, Manitoba R3T 2N2

    2014-03-15

    Modern experiments at isotope separator on-line (ISOL) facilities like ISAC at TRIUMF often depend critically on the purity of the delivered rare isotope beams. Therefore, highly selective ion sources are essential. This article presents the development and successful on-line operation of an ion guide laser ion source (IG-LIS) for the production of ion beams free of isobaric contamination. Thermionic ions from the hot ISOL target are suppressed by an electrostatic potential barrier, while neutral radio nuclides effusing out are resonantly ionized by laser radiation within a quadrupole ion guide behind this barrier. The IG-LIS was developed through detailed thermal and ion optics simulation studies and off-line tests with stable isotopes. In a first on-line run with a SiC target a suppression of surface-ionized Na contaminants in the ion beam of up to six orders of magnitude was demonstrated.

  16. Laser Isotope Separation Employing Condensation Repression

    SciTech Connect (OSTI)

    Eerkens, Jeff W.; Miller, William H.

    2004-09-15

    Molecular laser isotope separation (MLIS) techniques using condensation repression (CR) harvesting are reviewed and compared with atomic vapor laser isotope separation (AVLIS), gaseous diffusion (DIF), ultracentrifuges (UCF), and electromagnetic separations (EMS). Two different CR-MLIS or CRISLA (Condensation Repression Isotope Separation by Laser Activation) approaches have been under investigation at the University of Missouri (MU), one involving supersonic super-cooled free jets and dimer formation, and the other subsonic cold-wall condensation. Both employ mixtures of an isotopomer (e.g. {sup i}QF{sub 6}) and a carrier gas, operated at low temperatures and pressures. Present theories of VT relaxation, dimerization, and condensation are found to be unsatisfactory to explain/predict experimental CRISLA results. They were replaced by fundamentally new models that allow ab-initio calculation of isotope enrichments and predictions of condensation parameters for laser-excited and non-excited vapors which are in good agreement with experiment. Because of supersonic speeds, throughputs for free-jet CRISLA are a thousand times higher than cold-wall CRISLA schemes, and thus preferred for large-quantity Uranium enrichments. For small-quantity separations of (radioactive) medical isotopes, the simpler coldwall CRISLA method may be adequate.

  17. An EBIS system for rare isotope science project in Korea

    SciTech Connect (OSTI)

    Kim, Jongwon E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Han, Jae-Eun E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Son, Hyock-Jun E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Yi, Kun-Hui E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Zhao, Liangji E-mail: kim@far-tech.com; Kim, Jin-Soo E-mail: kim@far-tech.com

    2015-01-09

    An EBIS system has been designed to be used as a charge breeder for the post accelerator of an ISOL system. An electron gun, which is designed to produce a maximum current of 3 A at the beam energy of 20 kV, will be acquired from the Budker Institute, Novosibirsk. Electron beam optics calculations of the EBIS system as well as of the gun assembly have been performed using PBGUNS and TRAK. A superconducting solenoid with a maximum field of 6 T is to be used to compress the electron beam. A test stand, which includes the gun assembly and a high-power electron beam collector, is being designed and will be ready for the gun test in the end of this year. Charge breeding simulation using EBIS0D and CBSIM has been performed for a few key isotopes.

  18. Diffusion in silicon isotope heterostructures

    SciTech Connect (OSTI)

    Silvestri, Hughes Howland

    2004-05-14

    The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and {sup 28}Si enriched layers, enables the observation of {sup 30}Si self-diffusion from the natural layers into the {sup 28}Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffusion created regions of the multilayer structure that were extrinsic at the diffusion temperatures. In these regions, the Fermi level shift due to the extrinsic condition altered the concentration and charge state of the native defects involved in the diffusion process, which affected the dopant and self-diffusion. The simultaneously recorded diffusion profiles enabled the modeling of the coupled dopant and self-diffusion. From the modeling of the simultaneous diffusion, the dopant diffusion mechanisms, the native defect charge states, and the self- and dopant diffusion coefficients can be determined. This information is necessary to enhance the physical modeling of dopant diffusion in Si. It is of particular interest to the modeling of future electronic Si devices, where the nanometer-scale features have created the need for precise physical models of atomic diffusion in Si. The modeling of the experimental profiles of simultaneous diffusion of B and Si under p-type extrinsic conditions revealed that both species are mediated by neutral and singly, positively charged Si self-interstitials. The diffusion of As and Si under extrinsic n-type conditions yielded a model consisting of the interstitialcy and vacancy mechanisms of diffusion via singly negatively charged self-interstitials and neutral vacancies. The simultaneous diffusion of P and Si has been modeled on the basis of neutral and singly negatively charged self-interstitials and neutral and singly positively charged P species. Additionally, the temperature dependence of the diffusion coefficient of Si in Ge was measured over the temperature range of 550 C to 900 C using a buried Si layer in an epitaxially grown Ge layer.

  19. The Atomic Vapor Laser Isotope Separation Program. [Atomic Vapor Laser Isotope Separation (AVLIS) Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management's position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  20. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1993-01-01

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  1. Apparatus for separating and recovering hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

  2. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-03-30

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  3. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-05-08

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

  4. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Lyman, John L. (Los Alamos, NM); Aldridge, III, Jack P. (Los Alamos, NM)

    1987-01-01

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

  5. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

    1987-04-07

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

  6. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  7. Overview of the U.S. Department of Energy's Isotope Programs

    SciTech Connect (OSTI)

    Carty, J.

    2004-10-05

    This presentation provides an overview of the U.S. Department of Energy's Isotopes Program. The charter of the Isotope Programs covers the production and sale of radioactive and stable isotopes, associated byproducts, surplus materials, and related isotope services.

  8. Ion laser isotope enrichment by photo-predissociation of formaldehyde

    DOE Patents [OSTI]

    Marling, John B.

    1977-06-17

    Enrichment of carbon, hydrogen and/or oxygen isotopes by means of isotopically selective photo-predissociation of formaldehyde is achieved by irradiation with a fixed frequency ion laser, specifically, a neon, cadmium, or xenon ion laser.

  9. Method for production of an isotopically enriched compound

    DOE Patents [OSTI]

    Watrous, Matthew G.

    2012-12-11

    A method is presented for producing and isolating an isotopically enriched compound of a desired isotope from a parent radionuclide. The method includes forming, or placing, a precipitate containing a parent radionuclide of the desired daughter isotope in a first reaction zone and allowing sufficient time for the parent to decay into the desired gaseous daughter radioisotope. The method further contemplates collecting the desired daughter isotope as a solid in a second reaction zone through the application of temperatures below the freezing point of the desired isotope to a second reaction zone that is connected to the first reaction zone. Specifically, a method is presented for producing isotopically enriched compounds of xenon, including the radioactive isotope Xe-131m and the stable isotope Xe-131.

  10. Isotopic Analysis- Rock At Coso Geothermal Area (1984) | Open...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis- Rock At Coso Geothermal Area (1984) Exploration Activity Details Location Coso Geothermal Area Exploration Technique...

  11. Discovery of palladium, antimony, tellurium, iodine, and xenon isotopes

    SciTech Connect (OSTI)

    Kathawa, J.; Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-01-15

    Currently, thirty-eight palladium, thirty-eight antimony, thirty-nine tellurium, thirty-eight iodine, and forty xenon isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  12. Laser Isotope Enrichment for Medical and Industrial Applications

    SciTech Connect (OSTI)

    Leonard Bond

    2006-07-01

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for irradiation to produce medical radioisotopes. 2) Pure isotopes for semiconductors. 3) Low neutron capture isotopes for various uses in nuclear reactors. 4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old calutrons (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation repression. In this scheme a gas, of the selected isotopes for enrichment, is irradiated with a laser at a particular wavelength that would excite only one of the isotopes. The entire gas is subject to low temperatures sufficient to cause condensation on a cold surface. Those molecules in the gas that the laser excited are not as likely to condense as are the unexcited molecules. Hence the gas drawn out of the system will be enriched in the isotope that was excited by the laser. We have evaluated the relative energy required in this process if applied on a commercial scale. We estimate the energy required for laser isotope enrichment is about 20% of that required in centrifuge separations, and 2% of that required by use of "calutrons".

  13. Strontium-isotope stratigraphy of Enewetak Atoll

    SciTech Connect (OSTI)

    Ludwig, K.R.; Halley, R.B.; Simmons, K.R.; Peterman, Z.E.

    1988-02-01

    /sup 87/Sr//sup 86/Sr ratios determined for samples from a 350 m core of Neogene lagoonal, shallow-water limestones from Enewetak Atoll display a remarkably informative trend. Like the recently published data for Deep Sea Drilling Project (DSDP) carbonates, /sup 87/Sr//sup 86/Sr at Enewetak increases monotonically but not smoothly from the early Miocene to the Pleistocene. The data show intervals of little or no change in /sup 87/Sr//sup 86/Sr, punctuated by sharp transitions to lower values toward greater core depths. The sharp transitions correlate with observed solution disconformities caused by periods of subaerial erosion, whereas the intervals of little or no change in /sup 87/Sr//sup 86/Sr correspond to intervals of rapid accumulation of shallow-water carbonate sediments. When converted to numerical ages using the published DSDP 590B trend, the best-resolved time breaks are at 282 m (12.3 to 18.2 Ma missing) and 121.6 m (3.0 to 5.3 Ma missing) below the lagoon floor. At Enewetak, Sr isotopes offer a stratigraphic resolution for these shallow-marine Neogene carbonates comparable to that of nannofossil zonation in deep-sea carbonates (0.3-3 m.y.). In addition, the correlation of times of Sr-isotope breaks at Enewetak with times of rapid Sr-isotope change in the DSDP 590B samples confirms the importance of sea-level changes in the evolution of global-marine Sr isotopes and shows that the Sr-isotope response to sea-level falls is rapid.

  14. Enriching stable isotopes: Alternative use for Urenco technology

    SciTech Connect (OSTI)

    Rakhorst, H.; de Jong, P.G.T.; Dawson, P.D.

    1996-12-31

    The International Urenco Group utilizes a technologically advanced centrifuge process to enrich uranium in the fissionable isotope {sup 235}U. The group operates plants in the United Kingdom, the Netherlands, and Germany and currently holds a 10% share of the multibillion dollar world enrichment market. In the early 1990s, Urenco embarked on a strategy of building on the company`s uniquely advanced centrifuge process and laser isotope separation (LIS) experience to enrich nonradioactive isotopes colloquially known as stable isotopes. This paper summarizes the present status of Urenco`s stable isotopes business.

  15. Method of enhancing selective isotope desorption from metals

    DOE Patents [OSTI]

    Knize, Randall J. (Plainsboro, NJ); Cecchi, Joseph L. (Lawrenceville, NJ)

    1984-01-01

    A method of enhancing the thermal desorption of a first isotope of a diatomic gas from a metal comprises the steps of (a) establishing a partial pressure of a second isotope of the diatomic gas in vicinity of the metal; heating the metal to a temperature such that the first isotope is desorbed from the metal; and reducing the partial pressure of the desorbed first isotope while maintaining the partial pressure of the second isotope substantially constant. The method is especially useful for enhancing the desorption of tritium from the Zr-Al getter in a plasma confinement device.

  16. NEST-GENERATION TCAP HYDROGEN ISOTOPE SEPARATION PROCESS

    SciTech Connect (OSTI)

    Heung, L; Henry Sessions, H; Anita Poore, A; William Jacobs, W; Christopher Williams, C

    2007-08-07

    A thermal cycling absorption process (TCAP) for hydrogen isotope separation has been in operation at Savannah River Site since 1994. The process uses a hot/cold nitrogen system to cycle the temperature of the separation column. The hot/cold nitrogen system requires the use of large compressors, heat exchanges, valves and piping that is bulky and maintenance intensive. A new compact thermal cycling (CTC) design has recently been developed. This new design uses liquid nitrogen tubes and electric heaters to heat and cool the column directly so that the bulky hot/cold nitrogen system can be eliminated. This CTC design is simple and is easy to implement, and will be the next generation TCAP system at SRS. A twelve-meter column has been fabricated and installed in the laboratory to demonstrate its performance. The design of the system and its test results to date is discussed.

  17. Method of preparing mercury with an arbitrary isotopic distribution

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

    1986-01-01

    This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg.sub.2 Cl.sub.2, corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H.sub.2 O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H.sub.2 O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered.

  18. Method of preparing mercury with an arbitrary isotopic distribution

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1986-12-16

    This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg[sub 2]Cl[sub 2], corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H[sub 2]O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H[sub 2]O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered. 1 fig.

  19. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  20. Separation Of Uranium And Plutonium Isotopes For Measurement By Multi Collector Inductively Coupled Plasma Mass Spectroscopy

    SciTech Connect (OSTI)

    Martinelli, R E; Hamilton, T F; Williams, R W; Kehl, S R

    2009-03-29

    Uranium (U) and plutonium (Pu) isotopes in coral soils, contaminated by nuclear weapons testing in the northern Marshall Islands, were isolated by ion-exchange chromatography and analyzed by mass spectrometry. The soil samples were spiked with {sup 233}U and {sup 242}Pu tracers, dissolved in minerals acids, and U and Pu isotopes isolated and purified on commercially available ion-exchange columns. The ion-exchange technique employed a TEVA{reg_sign} column coupled to a UTEVA{reg_sign} column. U and Pu isotope fractions were then further isolated using separate elution schemes, and the purified fractions containing U and Pu isotopes analyzed sequentially using multi-collector inductively coupled plasma mass spectrometer (MCICP-MS). High precision measurements of {sup 234}U/{sup 235}U, {sup 238}U/{sup 235}U, {sup 236}U/{sup 235}U, and {sup 240}Pu/{sup 239}Pu in soil samples were attained using the described methodology and instrumentation, and provide a basis for conducting more detailed assessments of the behavior and transfer of uranium and plutonium in the environment.

  1. Regioselective synthesis using the deuterium isotope effect

    SciTech Connect (OSTI)

    Miyano, M.

    1981-04-24

    Dehydration of 1a by various procedures invariably produced more exo olefin 2a than endo olefin 3a. This could be reversed by introduction of deuterium in the Me-21 group of the starting material. Thus, dehydration of 1b could afford more endo olefin 3b than exo olefin 2b due to the deuterium isotope effect. A regioselective synthesis of 18-oxoprogesterone (15a) from 3..beta..-hydroxypregn-5-en-20-one (5a) was carried out taking advantage of the deuterium isotope effect as depicted in Scheme I. The key steps were dehydration of 7b to predominantly endo olefin 9b and removal of the deuteriums from 18-oxoprogesterone-17..cap alpha..,21,21,21-d/sub 4/ (15b) to give 15a.

  2. Hydrogen isotopic exchange over palladium metal

    SciTech Connect (OSTI)

    Carstens, D.H.W.; Encinias, P.D.

    1990-01-01

    We have recently developed the laser-Raman technique as a means of unambiguously measuring the partial pressures of all possible hydrogen isotopes in the gas phase. Using this technique we have investigated the hydrogen-deuterium exchange in a number of metals. This report presents detailed data for isotopic exchange in the palladium hydride system over the temperature range 26{degree}C to -100{degree}C at a pressure of 7 atm. First order kinetic rate constants and activation energies are summarized for the forward (hydride to deuteride) and reverse (deuteride to hydride) exchange processes. In addition, we have found that small amounts (100 ppm) of impurities in the exchange gases considerably slow the exchange kinetics with the effect increasing down the series CH{sub 4}, CO{sub 2}, H{sub 2}O, and CO. 9 refs., 4 figs., 1 tab.

  3. Optically pumped isotopic ammonia laser system

    DOE Patents [OSTI]

    Buchwald, Melvin I.; Jones, Claude R.; Nelson, Leonard Y.

    1982-01-01

    An optically pumped isotopic ammonia laser system which is capable of producing a plurality of frequencies in the middle infrared spectral region. Two optical pumping mechanisms are disclosed, i.e., pumping on R(J) and lasing on P(J) in response to enhancement of rotational cascade lasing including stimulated Raman effects, and, pumping on R(J) and lasing on P(J+2). The disclosed apparatus for optical pumping include a hole coupled cavity and a grating coupled cavity.

  4. Concerning the Facility for Rare Isotope Beams

    ScienceCinema (OSTI)

    Symons, James

    2013-05-29

    James Symons, Nuclear Science Division Director at Lawrence Berkeley Lab, and Daniela Leitner, head of operations at Berkeley Lab's 88-Inch Cyclotron, discuss major contributions to the new Facility for Rare Isotope Beams (FRIB) at Michigan State University, including ion source, which will based on the VENUS source built for the 88-Inch Cyclotron, and the GRETA gamma-ray detector now under construction there.

  5. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  6. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  7. First AID (Atom counting for Isotopic Determination).

    SciTech Connect (OSTI)

    Roach, J. L. (Jeffrey L.); Israel, K. M. (Kimberly M.); Steiner, R. E. (Robert E.); Duffy, C. J. (Clarence J.); Roench, F. R. (Fred R.)

    2002-01-01

    Los Alamos National Laboratory (LANL) has established an in vitro bioassay monitoring program in compliance with the requirements in the Code of Federal Regulations, 10 CFR 835, Occupational Radiation Protection. One aspect of this program involves monitoring plutonium levels in at-risk workers. High-risk workers are monitored using the ultra-sensitive Therrnal Ionization Mass Spectrometry (TIMS) technique to ensure compliance with DOE standards. TIMS is used to measure atom ratios of 239Pua nd 240Puw ith respect to a tracer isotope ('Pu). These ratios are then used to calculate the amount of 239Pu and 240Pup resent. This low-level atom counting technique allows the calculation of the concentration levels of 239Pu and 240Pu in urine for at risk workers. From these concentration levels, dose assessments can be made and worker exposure levels can be monitored. Detection limits for TIMS analysis are on the order of millions of atoms, which translates to activity levels of 150 aCi 239Pua nd 500 aCi for 240Pu. pCi for Our poster presentation will discuss the ultra-sensitive, low-level analytical technique used to measure plutonium isotopes and the data verification methods used for validating isotopic measurements.

  8. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  9. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  10. U.S. Department of Energy Isotope Program

    SciTech Connect (OSTI)

    2015-06-23

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. PNNLs Isotope Program operates in a multi-program category-2 nuclear facility, the Radiochemical Processing Laboratory (RPL), that contains 16 hot cells and 20 gloveboxes. As part of the DOE Isotope Program, the Pacific Northwest National Laboratory dispenses strontium-90, neptunium-237, radium-223, and thorium-227. PNNLs Isotope Program uses a dedicated hot-cell for strontium-90 dispensing and a dedicated glovebox for radium-223 and thorium-227 dispensing. PNNLs Isotope Program has access to state of the art analytical equipment in the RPL to support their research and production activities. DOE Isotope Program funded research at PNNL has advanced the application of automated radiochemistry for isotope such as zirconium-89 and astatine-211 in partnership with the University of Washington.

  11. Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collister, R.; Gwinner, G.; Tandecki, M.; Behr, J. A.; Pearson, M. R.; Zhang, J.; Orozco, L. A.; Aubin, S.; Gomez, E.; FrPNC Collaboration

    2014-11-07

    We present the isotope shifts of the 7s1/2 to 7p1/2 transition for francium isotopes ²⁰⁶⁻²¹³Fr with reference to ²²¹Fr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s1/2 to 7p3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D₁ and D₂ transitions, of sufficient precision to differentiate between ab initio calculations.

  12. Evaluation of selected ex-reactor accidents related to the tritium and medical isotope production mission at the FFTF

    SciTech Connect (OSTI)

    Himes, D.A.

    1997-11-17

    The Fast Flux Test Facility (FFTF) has been proposed as a production facility for tritium and medical isotopes. A range of postulated accidents related to ex-reactor irradiated fuel and target handling were identified and evaluated using new source terms for the higher fuel enrichment and for the tritium and medical isotope targets. In addition, two in-containment sodium spill accidents were re-evaluated to estimate effects of increased fuel enrichment and the presence of the Rapid Retrieval System. Radiological and toxicological consequences of the analyzed accidents were found to be well within applicable risk guidelines.

  13. Mapping quadrupole collectivity in the Cd isotopes: The breakdown of

    Office of Scientific and Technical Information (OSTI)

    harmonic vibrational motion (Journal Article) | SciTech Connect Mapping quadrupole collectivity in the Cd isotopes: The breakdown of harmonic vibrational motion Citation Details In-Document Search Title: Mapping quadrupole collectivity in the Cd isotopes: The breakdown of harmonic vibrational motion The stable Cd isotopes have long been used as paradigms for spherical vibrational motion. Extensive investigations with in-beam {gamma} spectroscopy have resulted in very-well-established level

  14. Fact Sheet: Facility For Rare Isotope Beams (FRIB) Applicant Selection |

    Energy Savers [EERE]

    Department of Energy Facility For Rare Isotope Beams (FRIB) Applicant Selection Fact Sheet: Facility For Rare Isotope Beams (FRIB) Applicant Selection December 11, 2008 - 8:51am Addthis Based on the analyses and recommendations over the last decade, the U.S. Department of Energy (DOE) Office of Science determined that the establishment of a Facility for Rare Isotope Beams (FRIB) is a high priority for the future of U.S. nuclear science research. This determination and supporting rationale

  15. Nitrogen concentration and isotope dataset for environmental samples from

    Office of Scientific and Technical Information (OSTI)

    2012 and 2013, Barrow, Alaska (Dataset) | Data Explorer Data Explorer Search Results Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska Title: Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska Dataset includes nitrate concentrations for polygonal active layer samples, snowmelt; ammonium concentrations for active layer samples; nitrate isotopes for active layer samples, snowmelt,

  16. System and method for high precision isotope ratio destructive analysis

    DOE Patents [OSTI]

    Bushaw, Bruce A; Anheier, Norman C; Phillips, Jon R

    2013-07-02

    A system and process are disclosed that provide high accuracy and high precision destructive analysis measurements for isotope ratio determination of relative isotope abundance distributions in liquids, solids, and particulate samples. The invention utilizes a collinear probe beam to interrogate a laser ablated plume. This invention provides enhanced single-shot detection sensitivity approaching the femtogram range, and isotope ratios that can be determined at approximately 1% or better precision and accuracy (relative standard deviation).

  17. COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technical Challenges | Princeton Plasma Physics Lab February 4, 2015, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and Technical Challenges Dr. Georg Bollen Michigan State University - The Facility for Rare Isotope Beams Wednesday Colloquium, February 4, 2015, "Facility for Rare Isotope Beams - Scientific Opportunities and Technial Chanllenges", Dr. Georg Bollen Colloquium Committee: The Princeton Plasma Physics

  18. Expert Panel: Forecast Future Demand for Medical Isotopes | Department of

    Office of Environmental Management (EM)

    Energy Expert Panel: Forecast Future Demand for Medical Isotopes Expert Panel: Forecast Future Demand for Medical Isotopes The Expert Panel has concluded that the Department of Energy and National Institutes of Health must develop the capability to produce a diverse supply of radioisotopes for medical use in quantities sufficient to support research and clinical activities. Such a capability would prevent shortages of isotopes, reduce American dependence on foreign radionuclide sources and

  19. Isotopic Analysis- Fluid At Roosevelt Hot Springs Geothermal...

    Open Energy Info (EERE)

    Unknown Exploration Basis Faulder 1991 Conceptual Geological Model compilation and literature review of the Roosevelt Hot Springs Geothermal Area. Notes Stable isotope analysis...

  20. Isotopic Analysis At Lassen Volcanic National Park Area (Janik...

    Open Energy Info (EERE)

    Park Area (Janik & Mclaren, 2010) Exploration Activity Details Location Lassen Volcanic National Park Area Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness...

  1. Method of isotope separation by chemi-ionization

    DOE Patents [OSTI]

    Wexler, Sol; Young, Charles E.

    1977-05-17

    A method for separating specific isotopes present in an isotopic mixture by aerodynamically accelerating a gaseous compound to form a jet of molecules, and passing the jet through a stream of electron donor atoms whereby an electron transfer takes place, thus forming negative ions of the molecules. The molecular ions are then passed through a radiofrequency quadrupole mass filter to separate the specific isotopes. This method may be used for any compounds having a sufficiently high electron affinity to permit negative ion formation, and is especially useful for the separation of plutonium and uranium isotopes.

  2. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    Exploration Activity: Isotopic Analysis At Valles Caldera - Redondo Geothermal Area (Phillips, 2004) Exploration Activity Details Location Valles Caldera - Redondo Geothermal Area...

  3. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    Phillips, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal Area...

  4. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Info (EERE)

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  5. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Through 30 September Activity T. Winnett, Cathy J. Janik (1986) Isotopic Composition of Carbon in Fluids from the Long Valley Geothermal System, California, In- Proceedings of...

  6. Isotopic Analysis At Newberry Caldera Area (Goles & Lambert,...

    Open Energy Info (EERE)

    Rock Activity Date Usefulness not indicated DOE-funding Unknown References Gordon G. Goles, Richard St J. Lambert (1990) A Strontium Isotopic Study Of Newberry Volcano,...

  7. Isotopic Analysis At Nw Basin & Range Region (Laney, 2005) |...

    Open Energy Info (EERE)

    Location Northwest Basin and Range Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  8. Isotopic Analysis At Central Nevada Seismic Zone Region (Laney...

    Open Energy Info (EERE)

    Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  9. Isotopic Analysis- Fluid At Coso Geothermal Area (1990) | Open...

    Open Energy Info (EERE)

    Exploration Activity Details Location Coso Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  10. Isotopic Analysis At Clear Lake Area (Thompson, Et Al., 1992...

    Open Energy Info (EERE)

    Exploration Activity Details Location Clear Lake Area Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness useful DOE-funding Unknown Notes Deuterium and...

  11. Isotopic Analysis- Fluid At Indian Valley Hot Springs Geothermal...

    Open Energy Info (EERE)

    Details Location Indian Valley Hot Springs Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  12. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area...

    Open Energy Info (EERE)

    Details Location Valles Caldera - Sulphur Springs Area Exploration Technique Isotopic Analysis- Rock Activity Date Usefulness not indicated DOE-funding Unknown References...

  13. Isotopic Analysis At Northern Basin & Range Region (Laney, 2005...

    Open Energy Info (EERE)

    Location Northern Basin and Range Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  14. Isotopic Analysis- Fluid At Sierra Valley Geothermal Area (1990...

    Open Energy Info (EERE)

    Activity Details Location Sierra Valley Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  15. Isotopic Analysis At Buffalo Valley Hot Springs Area (Laney,...

    Open Energy Info (EERE)

    Activity Details Location Buffalo Valley Hot Springs Area Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  16. John De Laeter Centre For Isotope Research | Open Energy Information

    Open Energy Info (EERE)

    2013 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for John De Laeter Centre For Isotope Research Citation Curtin University. John...

  17. Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans, Et Al., 2002) Exploration Activity Details...

  18. Isotopic Analysis- Fluid At Rose Valley Geothermal Area (1990...

    Open Energy Info (EERE)

    Rose Valley Geothermal Area (1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Rose Valley Geothermal Area (1990)...

  19. Isotopic Analysis At Yellowstone Region (Sturchio, Et Al., 1990...

    Open Energy Info (EERE)

    Yellowstone Caldera Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness could be useful with more improvements DOE-funding Unknown Notes...

  20. Isotopic Analysis- Fluid At Coso Geothermal Area (1982) | Open...

    Open Energy Info (EERE)

    Details Location Coso Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1982 Usefulness not indicated DOE-funding Unknown Exploration Basis...

  1. Isotopic Analysis At Long Valley Caldera Geothermal Area (Smith...

    Open Energy Info (EERE)

    Smith & Suemnicht, 1991) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Long Valley Caldera Geothermal Area (Smith &...

  2. Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...

    Open Energy Info (EERE)

    western United States. Limited analyses of spring and borehole fluids and existing experimental rate studies suggest that dissolved sulfate and water are probably in isotopic...

  3. Isotope separation by photochromatography (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    The method is particularly applicable to the separation of hydrogen isotopes. Authors: Suslick, Kenneth S. 1 + Show Author Affiliations (Stanford, CA) Publication Date: ...

  4. Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 2000...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 2000) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  5. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    Goff, Et Al., 1982) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Valles Caldera - Redondo Geothermal Area (Goff, Et Al.,...

  6. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    WoldeGabriel & Goff, 1992) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

  7. Isotopic Analysis- Fluid At Valles Caldera - Redondo Area (Rao...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  8. Isotopic Analysis At Yellowstone Region (Goff & Janik, 2002)...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Yellowstone Region (Goff & Janik, 2002) Exploration...

  9. Isotopic Analysis At Jemez Springs Area (Rao, Et Al., 1996) ...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  10. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  11. Isotopic Analysis- Fluid At Fenton Hill HDR Geothermal Area ...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  12. Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 1995...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 1995) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  13. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs Geothermal Area (Goff, Et Al., 1982) Exploration Activity Details Location Valles Caldera - Sulphur Springs...

  14. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs Geothermal Area (Goff, Et Al., 1985) Exploration Activity Details Location Valles Caldera - Sulphur Springs...

  15. Isotopic Analysis At Jemez Springs Area (Goff & Janik, 2002)...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Jemez Springs Area (Goff & Janik, 2002) Exploration...

  16. Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Long Valley Caldera Geothermal Area (Taylor & Gerlach, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Long...

  17. Hydrogeological And Isotopic Survey Of Geothermal Fields In The...

    Open Energy Info (EERE)

    Hydrogeological And Isotopic Survey Of Geothermal Fields In The Buyuk Menderes Graben, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  18. Isotopic Analysis- Fluid At Salt Wells Area (Shevenell & Garside...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 2002 -...

  19. Temperature effects on the behavior of liquid hydrogen isotopes...

    Office of Scientific and Technical Information (OSTI)

    liquid hydrogen isotopes inside a spherical-shell directly driven inertial confinement fusion target Kim, K.; Mok, L.S. 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; LASER TARGETS;...

  20. Isotopic Analysis At San Juan Volcanic Field Area (Larson & Jr...

    Open Energy Info (EERE)

    San Juan Volcanic Field Area (Larson & Jr, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At San Juan Volcanic Field...

  1. Small-Scale Reactor for the Production of Medical Isotopes -...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    shortage of medical isotopes-specifically Molybdenum 99 (Mo-99) which is essential in cancer treatment, diagnostics, and medical imaging. The US is completely dependent on foreign...

  2. Isotopic Analysis- Gas At Chena Geothermal Area (Kolker, Et Al...

    Open Energy Info (EERE)

    Date 2007 - 2007 Usefulness useful DOE-funding Unknown Exploration Basis Lawrence Berkeley National Laboratory sampling and analysis of He isotopes from Chena Hot Springs....

  3. Isotopic Analysis At Walker-Lane Transitional Zone Region (Laney...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date...

  4. Isotopic Analysis At Northern Basin & Range Region (Cole, 1983...

    Open Energy Info (EERE)

    Cole, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Northern Basin & Range Region (Cole, 1983) Exploration Activity...

  5. Isotopic Analysis-Fluid At Raft River Geothermal Area (1982)...

    Open Energy Info (EERE)

    GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis-Fluid At Raft River Geothermal Area (1982) Exploration Activity Details Location Raft River...

  6. Isotopic Analysis-Fluid At Raft River Geothermal Area (1977)...

    Open Energy Info (EERE)

    GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis-Fluid At Raft River Geothermal Area (1977) Exploration Activity Details Location Raft River...

  7. Helium isotopes in geothermal systems- Iceland, The Geysers,...

    Open Energy Info (EERE)

    isotopes in geothermal systems- Iceland, The Geysers, Raft River and Steamboat Springs Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium...

  8. Estimates of Radioxenon Released from Southern Hemisphere Medical isotope Production Facilities Using Measured Air Concentrations and Atmospheric Transport Modeling

    SciTech Connect (OSTI)

    Eslinger, Paul W.; Friese, Judah I.; Lowrey, Justin D.; McIntyre, Justin I.; Miley, Harry S.; Schrom, Brian T.

    2014-09-01

    Abstract The International Monitoring System (IMS) of the Comprehensive-Nuclear-Test-Ban-Treaty monitors the atmosphere for radioactive xenon leaking from underground nuclear explosions. Emissions from medical isotope production represent a challenging background signal when determining whether measured radioxenon in the atmosphere is associated with a nuclear explosion prohibited by the treaty. The Australian Nuclear Science and Technology Organisation (ANSTO) operates a reactor and medical isotope production facility in Lucas Heights, Australia. This study uses two years of release data from the ANSTO medical isotope production facility and Xe-133 data from three IMS sampling locations to estimate the annual releases of Xe-133 from medical isotope production facilities in Argentina, South Africa, and Indonesia. Atmospheric dilution factors derived from a global atmospheric transport model were used in an optimization scheme to estimate annual release values by facility. The annual releases of about 6.81014 Bq from the ANSTO medical isotope production facility are in good agreement with the sampled concentrations at these three IMS sampling locations. Annual release estimates for the facility in South Africa vary from 1.21016 to 2.51016 Bq and estimates for the facility in Indonesia vary from 6.11013 to 3.61014 Bq. Although some releases from the facility in Argentina may reach these IMS sampling locations, the solution to the objective function is insensitive to the magnitude of those releases.

  9. Apparatus for isotopic alteration of mercury vapor

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Gloucester, MA); Marcucci, Rudolph V. (Danvers, MA)

    1988-01-01

    An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

  10. Laser-assisted isotope separation of tritium

    DOE Patents [OSTI]

    Herman, Irving P. (Castro Valley, CA); Marling, Jack B. (Livermore, CA)

    1983-01-01

    Methods for laser-assisted isotope separation of tritium, using infrared multiple photon dissociation of tritium-bearing products in the gas phase. One such process involves the steps of (1) catalytic exchange of a deuterium-bearing molecule XYD with tritiated water DTO from sources such as a heavy water fission reactor, to produce the tritium-bearing working molecules XYT and (2) photoselective dissociation of XYT to form a tritium-rich product. By an analogous procedure, tritium is separated from tritium-bearing materials that contain predominately hydrogen such as a light water coolant from fission or fusion reactors.

  11. Multiphysics Model of Palladium Hydride Isotope Exchange Accounting for Higher Dimensionality

    SciTech Connect (OSTI)

    Gharagozloo, Patricia E.; Eliassi, Mehdi; Bon, Bradley Luis

    2015-03-01

    This report summarizes computational model developm ent and simulations results for a series of isotope exchange dynamics experiments i ncluding long and thin isothermal beds similar to the Foltz and Melius beds and a lar ger non-isothermal experiment on the NENG7 test bed. The multiphysics 2D axi-symmetr ic model simulates the temperature and pressure dependent exchange reactio n kinetics, pressure and isotope dependent stoichiometry, heat generation from the r eaction, reacting gas flow through porous media, and non-uniformities in the bed perme ability. The new model is now able to replicate the curved reaction front and asy mmetry of the exit gas mass fractions over time. The improved understanding of the exchange process and its dependence on the non-uniform bed properties and te mperatures in these larger systems is critical to the future design of such sy stems.

  12. Early Onset of Ground State Deformation in Neutron Deficient Polonium Isotopes

    SciTech Connect (OSTI)

    Cocolios, T. E.; Van de Walle, J.; Dexters, W.; Bastin, B.; Buescher, J.; Darby, I. G.; Huyse, M.; Keupers, M.; Kudryavtsev, Yu.; Van Duppen, P.; Seliverstov, M. D.; Andreyev, A. N.; Antalic, S.; Barzakh, A. E.; Fedorov, D. V.; Molkanov, P. L.; Fedosseyev, V. N.; Marsh, B. A.; Flanagan, K. T.; Franchoo, S.

    2011-02-04

    In-source resonant ionization laser spectroscopy of the even-A polonium isotopes {sup 192-210,216,218}Po has been performed using the 6p{sup 3}7s {sup 5}S{sub 2} to 6p{sup 3}7p {sup 5}P{sub 2} ({lambda}=843.38 nm) transition in the polonium atom (Po-I) at the CERN ISOLDE facility. The comparison of the measured isotope shifts in {sup 200-210}Po with a previous data set allows us to test for the first time recent large-scale atomic calculations that are essential to extract the changes in the mean-square charge radius of the atomic nucleus. When going to lighter masses, a surprisingly large and early departure from sphericity is observed, which is only partly reproduced by beyond mean field calculations.

  13. Experimental Test of Self-Shielding in VUV Photodissociation of CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the elements found in its constituent bodies. A case in point is oxygen with three stable isotopes dominated by oxygen-16, with minute fractions of oxygen-17 and oxygen-18. Primitive objects whose formation predates the Earth's, such as the calcium-aluminum-rich inclusions in the Allende meteorite, have relatively lower fractions

  14. Experimental Test of Self-Shielding in VUV Photodissociation of CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the elements found in its constituent bodies. A case in point is oxygen with three stable isotopes dominated by oxygen-16, with minute fractions of oxygen-17 and oxygen-18. Primitive objects whose formation predates the Earth's, such as the calcium-aluminum-rich inclusions in the Allende meteorite, have relatively lower fractions

  15. Experimental Test of Self-Shielding in VUV Photodissociation of CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the elements found in its constituent bodies. A case in point is oxygen with three stable isotopes dominated by oxygen-16, with minute fractions of oxygen-17 and oxygen-18. Primitive objects whose formation predates the Earth's, such as the calcium-aluminum-rich inclusions in the Allende meteorite, have relatively lower fractions

  16. Experimental Test of Self-Shielding in VUV Photodissociation of CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the elements found in its constituent bodies. A case in point is oxygen with three stable isotopes dominated by oxygen-16, with minute fractions of oxygen-17 and oxygen-18. Primitive objects whose formation predates the Earth's, such as the calcium-aluminum-rich inclusions in the Allende meteorite, have relatively lower fractions

  17. Experimental Test of Self-Shielding in VUV Photodissociation of CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the elements found in its constituent bodies. A case in point is oxygen with three stable isotopes dominated by oxygen-16, with minute fractions of oxygen-17 and oxygen-18. Primitive objects whose formation predates the Earth's, such as the calcium-aluminum-rich inclusions in the Allende meteorite, have relatively lower fractions

  18. Experimental Test of Self-Shielding in VUV Photodissociation of CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Print One way to test models of the solar system's formation is to compare the isotopic abundances of the elements found in its constituent bodies. A case in point is oxygen with three stable isotopes dominated by oxygen-16, with minute fractions of oxygen-17 and oxygen-18. Primitive objects whose formation predates the Earth's, such as the calcium-aluminum-rich inclusions in the Allende meteorite, have relatively lower fractions

  19. Plutonium Isotopic Gamma-Ray Analysis

    Energy Science and Technology Software Center (OSTI)

    1992-01-08

    The MGA8 (Multiple Group Analysis) program determines the relative abundances of plutonium and other actinide isotopes in different materials. The program analyzes spectra taken of such samples using a 4096-channel germanium (Ge) gamma-ray spectrometer. The code can be run in a one or two detector mode. The first spectrum, which is required and must be taken at a gain of 0.075 Kev/channel with a high resolution planar detector, contains the 0-300 Kev energy region. Themore »second spectrum, which is optional, must be taken at a gain of 0.25 Kev/channel; it becomes important when analyzing high burnup samples (concentration of Pu241 greater than one percent). Isotopic analysis precisions of one percent or better can be obtained, and no calibrations are required. The system also measures the abundances of U235, U238, Np237, and Am241. A special calibration option is available to perform a one-time peak-shape characterization when first using a new detector system.« less

  20. Plutonium Isotopic Gamma-Ray Analysis

    Energy Science and Technology Software Center (OSTI)

    1992-01-08

    The MGA8 (Multiple Group Analysis) program determines the relative abundances of plutonium and other actinide isotopes in different materials. The program analyzes spectra taken of such samples using a 4096-channel germanium (Ge) gamma-ray spectrometer. The code can be run in a one or two detector mode. The first spectrum, which is required and must be taken at a gain of 0.075 Kev/channel with a high resolution planar detector, contains the 0-300 Kev energy region. Themore » second spectrum, which is optional, must be taken at a gain of 0.25 Kev/channel; it becomes important when analyzing high burnup samples (concentration of Pu241 greater than one percent). Isotopic analysis precisions of one percent or better can be obtained, and no calibrations are required. The system also measures the abundances of U235, U238, Np237, and Am241. A special calibration option is available to perform a one-time peak-shape characterization when first using a new detector system.« less

  1. Sandia National Laboratories Medical Isotope Reactor concept.

    SciTech Connect (OSTI)

    Coats, Richard Lee; Dahl, James J.; Parma, Edward J., Jr.

    2010-04-01

    This report describes the Sandia National Laboratories Medical Isotope Reactor and hot cell facility concepts. The reactor proposed is designed to be capable of producing 100% of the U.S. demand for the medical isotope {sup 99}Mo. The concept is novel in that the fuel for the reactor and the targets for the {sup 99}Mo production are the same. There is no driver core required. The fuel pins that are in the reactor core are processed on a 7 to 21 day irradiation cycle. The fuel is low enriched uranium oxide enriched to less than 20% {sup 235}U. The fuel pins are approximately 1 cm in diameter and 30 to 40 cm in height, clad with Zircaloy (zirconium alloy). Approximately 90 to 150 fuel pins are arranged in the core in a water pool {approx}30 ft deep. The reactor power level is 1 to 2 MW. The reactor concept is a simple design that is passively safe and maintains negative reactivity coefficients. The total radionuclide inventory in the reactor core is minimized since the fuel/target pins are removed and processed after 7 to 21 days. The fuel fabrication, reactor design and operation, and {sup 99}Mo production processing use well-developed technologies that minimize the technological and licensing risks. There are no impediments that prevent this type of reactor, along with its collocated hot cell facility, from being designed, fabricated, and licensed today.

  2. Supported palladium materials for isotope separation

    SciTech Connect (OSTI)

    Rutherford, W.M.; Ellis, R.E.; Abell, G.C.

    1988-01-21

    Several palladium packing materials were investigated for their suitability for use in the separation of hydrogen isotopes by displacement chromatography. The materials included palladium on Chromosorb and several formulations of palladium on commercially available alpha-alumina-based catalyst supports. All materials showed some degradation upon being subjected to repeated hydriding-dehydriding cycles; however, the degradation did not lead to unacceptably low permeability to gas flow. Dynamic performance of the packings was evaluated by displacement of deuterium with protium at several temperatures and flow rates. Isotopic exchange was generally rapid. However, high surface area packings (greater than 4 m/sup 2//g) yielded transition zones that were initially sharp, but had long ''tails'' at deuterium concentrations below 5%. Best results were obtained with a packing containing 48.2% palladium on Norton catalyst support No. SA5*21 (surface area = 0.33 m/sup 2//g). Improved performance was observed as the displacement temperature was increased to 80/sup 0/C from 22/sup 0/C. The slight decrease in equilibrium separation was more than offset by improved kinetics at the higher temperature. 19 figs., 6 tabs.

  3. Process for recovery of daughter isotopes from a source material

    DOE Patents [OSTI]

    Tranter, Troy J.; Todd, Terry A.; Lewis, Leroy C.; Henscheid, Joseph P.

    2005-10-04

    The invention includes a method of separating isotopes from a mixture containing at least two isotopes in a solution. A first isotope is precipitated and is collected from the solution. A daughter isotope is generated and collected from the first isotope. The invention includes a method of producing an actinium-225/bismuth-213 product from a material containing thorium-229 and thorium-232. A solution is formed containing nitric acid and the material and iodate is added to form a thorium iodate precipitate. A supernatant is separated from the thorium iodate precipitate and a second volume of nitric acid is added to the precipitate. The precipitate is stored and a decay product comprising actinium-225 and bismuth-213 is generated in the second volume of nitric acid which is then separated from the thorium iodate precipitate, filtered, and treated using at least one chromatographic procedure. The invention also includes a system for producing an actinium-225/bismuth-213 product.

  4. Special isotope separation at the Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Hendrickson, P.D.

    1989-02-03

    The SIS facilities will include a Plutonium Processing Facility (PPF), a Laser Support Facility (LSF), and all associated equipment required for isotope separation. The SIS Plant will process fuel-grade plutonium into weapons-grade plutonium using Atomic Vapor Laser Isotope Separation (AVLIS) and supporting chemical processes. The AVLIS process uses precisely tuned visible laser light to selectively ionize or excite specific plutonium isotopes in a vapor stream. The ionized plutonium isotopes (Pu 240, Pu 238 and Pu 241) are then separated from the plutonium isotope of interest (Pu 239). Chemical processes are required to (1) prepare the AVLIS plutonium feed for processing, remove americium-241, and cast plutonium metal into forms that meet AVLIS processing requirements; (2) recover and, if required, purify the AVLIS plutonium product; and (3) recover and process the AVLIS separated by-products. This presentation describes the production facility and some of the plutonium processes.

  5. Helium isotopes and tectonics in southern Italy

    SciTech Connect (OSTI)

    Sano, Yuji; Wakita, Hiroshi ); Nuccio, M.P. ); Italiano, F.

    1989-06-01

    Geodynamic evolution of southern Italy can be understood within the framework of the Mediterranean-Alpine System. Subduction of a plate along the Sicily-Calabrian forearc under the Tyrrhenian Sea has been suggested by many geophysicists, although it is not yet confirmed and remains somewhat controversial. Helium isotope ratios provide useful information on the geotectonic structure of the region. The authors report here the {sup 3}H/{sup 4}He ratios of terrestrial gas samples from southern Italy. The observed {sup 3}He/{sup 4}He ratios are relatively high in the Eolian volcanic arc region and low in the other areas. Dichotomous explanations are presented. Firstly, volcanic arc-forearc hypothesis suggests the subduction along the Sicily-Calabrian forearc. Secondly, horizontal transport hypothesis is described based on the relationship between the ratios and radial distance from the recent spreading basin in Southern Tyrrhenian Sea.

  6. Compact hydrogen/helium isotope mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM); Scime, Earl E. (Morgantown, WV)

    1996-01-01

    The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

  7. Photolytic separation of isotopes in cryogenic solution

    DOE Patents [OSTI]

    Freund, Samuel M. (Santa Fe, NM); Maier, II, William B. (Los Alamos, NM); Holland, Redus F. (Los Alamos, NM); Beattie, Willard H. (Los Alamos, NM)

    1985-01-01

    Separation of carbon isotopes by photolysis of CS.sub.2 in cryogenic solutions of nitrogen, krypton and argon with 206 nm light from an iodine resonance lamp is reported. The spectral distribution of the ultraviolet absorption depends on solvent. Thus, in liquid nitrogen the photolytic decomposition rate of .sup.13 CS.sub.2 is greater than that of .sup.12 CS.sub.2 (because the absorption of 206 nm radiation is greater for .sup.13 CS.sub.2), whereas in liquid krypton and liquid argon the reverse is true. The shift in ultraviolet spectrum is a general phenomenon readily characterized as a function of solvent polarizability, and exhibits behavior similar to that for vibrational transitions occurring in the infrared.

  8. Laser-isotope-separation technology. [Review; economics

    SciTech Connect (OSTI)

    Jensen, R.J.; Blair, L.S.

    1981-01-01

    The Molecular Laser Isotope Separation (MLIS) process currently under development is discussed as an operative example of the use of lasers for material processing. The MLIS process, which uses infrared and ultraviolet lasers to process uranium hexafluoride (UF/sub 6/) resulting in enriched uranium fuel to be used in electrical-power-producing nuclear reactor, is reviewed. The economics of the MLIS enrichment process is compared with conventional enrichment technique, and the projected availability of MLIS enrichment capability is related to estimated demands for U.S. enrichment service. The lasers required in the Los Alamos MLIS program are discussed in detail, and their performance and operational characteristics are summarized. Finally, the timely development of low-cost, highly efficient ultraviolet and infrared lasers is shownd to be the critical element controlling the ultimate deployment of MLIS uranium enrichment. 8 figures, 7 tables.

  9. Nuclear Proliferation Using Laser Isotope Separation -- Verification Options

    SciTech Connect (OSTI)

    Erickson, S A

    2001-10-15

    Two levels of nonproliferation verification exist. Signatories of the basic agreements under the Nuclear Non-proliferation Treaty (NPT) agree to open their nuclear sites to inspection by the IAEA. A more detailed and intrusive level was developed following the determination that Iraq had begun a nuclear weapons development program that was not detected by the original level of verification methods. This level, referred to as 93+2 and detailed in model protocol INFCIRC/540, allows the IAEA to do environmental monitoring of non-declared facilities that are suspected of containing proliferation activity, and possibly further inspections, as well as allowing more detailed inspections of declared sites. 56 countries have signed a Strengthened Safeguards Systems Additional Protocol as of 16 July 2001. These additional inspections can be done on the instigation of the IAEA itself, or after requests by other parties to the NPT, based on information that they have collected. Since information able to cause suspicion of proliferation could arrive at any country, it is important that countries have procedures in place that will assist them in making decisions related to these inspections. Furthermore, IAEA inspection resources are limited, and therefore care needs to be taken to make best use of these resources. Most of the nonproliferation verification inspections may be concentrated on establishing that diversion of nuclear materials is not occurring, but some fraction will be related to determining if undeclared sites have nuclear materials production taking place within them. Of these, most suspicions will likely be related to the major existing technologies for uranium enrichment and reprocessing for plutonium extraction, as it would seem most likely that nations attempting proliferation would use tested means of producing nuclear materials. However, as technology continues to advance and new methods of enrichment and reprocessing are developed, inspection-related procedures will need to be adapted to keep up with them. In order to make 93+2 inspections more useful, a systematic way of finding clues to nuclear proliferation would be useful. Also, to cope with the possible use of newer technology for proliferation, the list of clues might need to be expanded. This paper discusses the development and recognition of such clues. It concentrates on laser isotope separation (LIS) as a new proliferation technology, and uses Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) as an example of LIS that is well known.

  10. Direct analysis of air filter samples for alpha emitting isotopes

    SciTech Connect (OSTI)

    Mohagheghi, A.H.; Ghanbari, F.; Ebara, S.B.; Enghauser, M.E. [Sandia National Labs., Albuquerque, NM (United States); Bakhtiar, S.N. [Westinghouse WIPP, Carlsbad, NM (United States)

    1997-04-01

    The traditional method for determination of alpha emitting isotopes on air filters has been to process the samples by radiochemical methods. However, this method is too slow for cases of incidents involving radioactive materials where the determination of personnel received dose is urgent. A method is developed to directly analyze the air filters taken from personal and area air monitors. The site knowledge is used in combination with alpha spectral information to identify isotopes. A mathematical function is developed to estimate the activity for each isotope. The strengths and weaknesses of the method are discussed.

  11. Plutonium isotopic assay from alpha spectroscopy: A progress report

    SciTech Connect (OSTI)

    Baran, D.T.

    1995-12-31

    The Non-Destructive Assay (NDA) group at New Brunswick Laboratory (NBL) continues to develop and refine a computer program ALPHAFIT, a sophisticated peak-fitting routine for use in determining the isotopic abundances of Pu and U samples. The program uses up to seven parameters per peak fit and up to 12 peaks per region of interest to de-convolute typical complicated Pu a spectra. Preliminary results show decent fits for major peaks in the spectrum and calculated isotopic abundances of the major isotopes to {+-} 4%.

  12. Method for isotopic analysis of chlorinated organic compounds

    DOE Patents [OSTI]

    Holt, B.D.; Sturchio, N.C.

    1999-08-24

    The present invention provides a method for preparing a VOC sample for carbon and chlorine isotope ratio analysis by mass spectrometer. A VOC sample is placed in a combustion tube and reacted with CuO to form CO{sub 2} and CuCl. The CO{sub 2} is then extracted and analyzed for the carbon isotope ratio. The CuCl is separated from the excess CuO and reacted with CH{sub 3}I to form CH{sub 3}Cl, extracted and analyzed for chlorine isotope ratio. 9 figs.

  13. Isotopic mass-dependence of noble gas diffusion coefficients inwater

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2007-06-25

    Noble gas isotopes are used extensively as tracers inhydrologic and paleoclimatic studies. These applications requireknowledge of the isotopic mass (m) dependence of noble gas diffusioncoefficients in water (D), which has not been measured but is estimatedusing experimental D-values for the major isotopes along with an untestedrelationship from kinetic theory, D prop m-0.5. We applied moleculardynamics methods to determine the mass dependence of D for four noblegases at 298 K, finding that D prop m-beta with beta<0.2, whichrefutes the kinetic theory model underlying all currentapplications.

  14. Cost Estimate for Laser Isotope Separation for RIA

    SciTech Connect (OSTI)

    Scheibner, K

    2004-11-01

    Isotope enrichment of some elements is required in support of the Rare Isotope Accelerator (RIA) in order to obtain the beam intensities, source efficiencies and/or source lifetime required by RIA. The economics of using Atomic Vapor Laser Isotope Separation (AVLIS) technology as well as ElectroMagnetic (EM) separation technology has been evaluated. It is concluded that such an AVLIS would be about 10 times less expensive than a facility based on electromagnetic separation - $17 M versus $170 M. In addition, the AVLIS facility footprint would be about 10 times smaller, and operations would require about 4 years (including 2 years of startup) versus about 11 years for an EM facility.

  15. On-Site Inspection RadioIsotopic Spectroscopy (Osiris) System Development

    SciTech Connect (OSTI)

    Caffrey, Gus J.; Egger, Ann E.; Krebs, Kenneth M.; Milbrath, B. D.; Jordan, D. V.; Warren, G. A.; Wilmer, N. G.

    2015-09-01

    We have designed and tested hardware and software for the acquisition and analysis of high-resolution gamma-ray spectra during on-site inspections under the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The On-Site Inspection RadioIsotopic Spectroscopy—Osiris—software filters the spectral data to display only radioisotopic information relevant to CTBT on-site inspections, e.g.,132I. A set of over 100 fission-product spectra was employed for Osiris testing. These spectra were measured, where possible, or generated by modeling. The synthetic test spectral compositions include non-nuclear-explosion scenarios, e.g., a severe nuclear reactor accident, and nuclear-explosion scenarios such as a vented underground nuclear test. Comparing its computer-based analyses to expert visual analyses of the test spectra, Osiris correctly identifies CTBT-relevant fission product isotopes at the 95% level or better.The Osiris gamma-ray spectrometer is a mechanically-cooled, battery-powered ORTEC Transpec-100, chosen to avoid the need for liquid nitrogen during on-site inspections. The spectrometer was used successfully during the recent 2014 CTBT Integrated Field Exercise in Jordan. The spectrometer is controlled and the spectral data analyzed by a Panasonic Toughbook notebook computer. To date, software development has been the main focus of the Osiris project. In FY2016-17, we plan to modify the Osiris hardware, integrate the Osiris software and hardware, and conduct rigorous field tests to ensure that the Osiris system will function correctly during CTBT on-site inspections. The planned development will raise Osiris to technology readiness level TRL-8; transfer the Osiris technology to a commercial manufacturer, and demonstrate Osiris to potential CTBT on-site inspectors.

  16. Stable isotope studies. Final report, March 1, 1972--February 29, 1992

    SciTech Connect (OSTI)

    Ishida, T.

    1992-10-01

    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  17. Efficient and selective isotopic labeling of hemes to facilitate...

    Office of Scientific and Technical Information (OSTI)

    Here, a method for production of recombinant multiheme cytochromes c in Escherichia coli with isotopically labeled hemes is reported. A small tetraheme cytochrome of 12 kDa from ...

  18. Isotopic Analysis At Separation Creek Area (Van Soest, Et Al...

    Open Energy Info (EERE)

    Usefulness useful DOE-funding Unknown References M. C. van Soest, B. M. Kennedy, W. C. Evans, R. H. Mariner (2002) Mantle Helium And Carbon Isotopes In Separation Creek...

  19. COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION...

    Office of Scientific and Technical Information (OSTI)

    COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION OF sup 26Al BY A NEARBY SUPERNOVA Citation Details In-Document Search Title: COLLATERAL EFFECTS ON SOLAR ...

  20. Plutonium Isotopes in the Terrestrial Environment at the Savannah...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Plutonium Isotopes in the Terrestrial Environment at the Savannah River Site, USA. A Long-Term Study This work presents the findings of a ...

  1. Isotope Transport and Exchange within the Coso Geothermal System...

    Open Energy Info (EERE)

    and the nearby Coso Hot Springs using finite element models of single-phase, variable-density fluid flow, conductive- convective heat transfer, fluid-rock isotope exchange, and...

  2. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    of 36Cl- as a tracer isotope in geothermal systems. References F.M. Phillips, Fraser E. Goff, Francois D. Vuataz, H.W. Bentley, H.E. Gove (1984) 36Cl as a tracer in geothermal...

  3. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    isotope ratios in gases of thirty hot springs and geothermal wells and of five natural gas wells in the western United States show no relationship to regional conductive heat...

  4. An isotopic study of the Coso, California, geothermal area |...

    Open Energy Info (EERE)

    and vicinity and were analyzed for major chemical constituents and deltaD and delta18O. Non-thermal ground waters from the Coso Range were found to be isotopically heavier...

  5. Isotopic Analysis- Fluid At Dixie Valley Geothermal Area (Kennedy...

    Open Energy Info (EERE)

    suggest that helium isotopes are the best and possibly the only indication of deep permeability where high temperature fluids are masked beneath a cold reservoir. Notes 3He4He...

  6. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G.; Roberts, George W.

    1980-08-12

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  7. Microsoft Word - Transmittal Memo - FY 2007 Isotopes Final Report...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Californium-252 is used in a variety of applications in cancer treatment research. Helium- ... Isotopes play key roles in the diagnosis and treatment of several types of cancer, such as ...

  8. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Silicates In The Larderello Geothermal Field, Italy Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The...

  9. Uranium accountancy in Atomic Vapor Laser Isotope Separation

    SciTech Connect (OSTI)

    Carver, R.D.

    1986-01-01

    The AVLIS program pioneers the large scale industrial application of lasers to produce low cost enriched uranium fuel for light water reactors. In the process developed at Lawrence Livermore National Laboratory, normal uranium is vaporized by an electron beam, and a precisely tuned laser beam selectively photo-ionizes the uranium-235 isotopes. These ions are moved in an electromagnetic field to be condensed on the product collector. All other uranium isotopes remain uncharged and pass through the collector section to condense as tails. Tracking the three types of uranium through the process presents special problems in accountancy. After demonstration runs, the uranium on the collector was analyzed for isotopic content by Battelle Pacific Northwest Laboratory. Their results were checked at LLNL by analysis of parallel samples. The differences in isotopic composition as reported by the two laboratories were not significant.

  10. Chemical and light-stable isotope characteristics of waters from...

    Open Energy Info (EERE)

    light-stable isotope characteristics of waters from the raft river geothermal area and environs, Cassia County, Idaho, Box Elder county, Utah Jump to: navigation, search OpenEI...

  11. FY09 PROGRESS: MULTI-ISOTOPE PROCESS (MIP) MONITOR

    SciTech Connect (OSTI)

    Schwantes, Jon M.; Orton, Christopher R.; Fraga, Carlos G.; Christensen, Richard; Laspe, Amy R.; Ward, Rebecca M.

    2009-10-18

    Model and experimental estimates of the Multi-Isotope Process Monitor performance for determining burnup after dissolution and acid concentration during solvent extraction steps during reprocessing of spent nuclear fuel are presented.

  12. Heavy neodymium isotopes in the interacting boson (IBA-2) model

    SciTech Connect (OSTI)

    Giannatiempo, A.

    2011-08-15

    The N>82 even neodymium isotopes were studied in the framework of the IBA-2 model. The analysis was performed by using a very schematic Hamiltonian, particularly suited to investigate the U(5) {yields} SU(3) transition. The evolution of the excitation energy patterns and of the spectroscopic properties along the isotopic chain can be correctly reproduced when the role played by states of mixed symmetry character is also taken into account.

  13. GUM Analysis for TIMS and SIMS Isotopic Ratios in Graphite

    SciTech Connect (OSTI)

    Heasler, Patrick G.; Gerlach, David C.; Cliff, John B.; Petersen, Steven L.

    2007-04-01

    This report describes GUM calculations for TIMS and SIMS isotopic ratio measurements of reactor graphite samples. These isotopic ratios are used to estimate reactor burn-up, and currently consist of various ratios of U, Pu, and Boron impurities in the graphite samples. The GUM calculation is a propagation of error methodology that assigns uncertainties (in the form of standard error and confidence bound) to the final estimates.

  14. Separation of the isotopes of boron by chemical exchange reactions

    DOE Patents [OSTI]

    McCandless, Frank P. (Bozeman, MT); Herbst, Ronald S. (Idaho Falls, ID)

    1995-01-01

    The isotopes of boron, .sup.10 B and .sup.11 B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF.sub.3 and a liquid BF.sub.3 . donor molecular addition complex formed between BF.sub.3 gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone.

  15. Separation of the isotopes of boron by chemical exchange reactions

    DOE Patents [OSTI]

    McCandless, F.P.; Herbst, R.S.

    1995-05-30

    The isotopes of boron, {sup 10}B and {sup 11}B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF{sub 3} and a liquid BF{sub 3} donor molecular addition complex formed between BF{sub 3} gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone. 1 Fig.

  16. Plutonium Isotopes in the Terrestrial Environment at the Savannah River

    Office of Scientific and Technical Information (OSTI)

    Site, USA. A Long-Term Study (Journal Article) | SciTech Connect Journal Article: Plutonium Isotopes in the Terrestrial Environment at the Savannah River Site, USA. A Long-Term Study Citation Details In-Document Search Title: Plutonium Isotopes in the Terrestrial Environment at the Savannah River Site, USA. A Long-Term Study This work presents the findings of a long term plutonium study at Savannah River Site (SRS) conducted between 2003 and 2013. Terrestrial environmental samples were

  17. Isotopic evidence for a martian regolith component in martian meteorites.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Isotopic evidence for a martian regolith component in martian meteorites. Citation Details In-Document Search Title: Isotopic evidence for a martian regolith component in martian meteorites. No abstract prepared. Authors: Rao, M.N. ; Nyquist, L.E. ; Bogard, D.D. ; Garrison, D.H. ; Sutton, S. [1] ; UC) [2] + Show Author Affiliations (NASA JSC) ( Publication Date: 2009-03-23 OSTI Identifier: 1009059 Resource Type: Conference Resource Relation: Conference: Lunar

  18. Integration of Nontraditional Isotopic Systems Into Reaction-Transport

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Models of EGS For Exploration, Evaluation of Water-Rock Interaction, and Impacts of Water Chemistry on Reservoir Sustainability | Department of Energy Nontraditional Isotopic Systems Into Reaction-Transport Models of EGS For Exploration, Evaluation of Water-Rock Interaction, and Impacts of Water Chemistry on Reservoir Sustainability Integration of Nontraditional Isotopic Systems Into Reaction-Transport Models of EGS For Exploration, Evaluation of Water-Rock Interaction, and Impacts of Water

  19. Ab Initio Calculations of Even Oxygen Isotopes with Chiral

    Office of Scientific and Technical Information (OSTI)

    Two-Plus-Three-Nucleon Interactions (Journal Article) | SciTech Connect Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Citation Details In-Document Search Title: Ab Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Authors: Hergert, H. ; Binder, S. ; Calci, A. ; Langhammer, J. ; Roth, R. Publication Date: 2013-06-10 OSTI Identifier: 1102833 Type: Publisher's Accepted Manuscript Journal Name: Physical

  20. Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity Oxygen is one of the most ubiquitous elements in chemistry and materials science, yet one of the most elusive elements for spectroscopic investigation by solid-state Nuclear Magnetic Resonance (SSNMR). Used to determine the structure of materials and chemicals on the atomic scale, SSNMR requires nuclei that have magnetic moments. Yet, less than four of every 10,000 oxygen nuclei are 17O, the only NMR-active isotope of

  1. Investigation of the Photochemical Method for Uranium Isotope Separation

    DOE R&D Accomplishments [OSTI]

    Urey, H. C.

    1943-07-10

    To find a process for successful photochemical separation of isotopes several conditions have to be fulfilled. First, the different isotopes have to show some differences in the spectrum. Secondly, and equally important, this difference must be capable of being exploited in a photochemical process. Parts A and B outline the physical and chemical conditions, and the extent to which one might expect to find them fulfilled. Part C deals with the applicability of the process.

  2. Isotopic discontinuities in ground water beneath Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Stuckless, J.S.; Whelan, J.F.; Steinkampf, W.C.

    1991-05-01

    Analytical data for stable isotopes in ground water from beneath Yucca Mountain, when examined in map view, show areal patterns of heterogeneity that can be interpreted in terms of mixing of at least three end members. One end member must be isotopically heavy in terms of hydrogen and oxygen and have a young apparent {sup 14}C age such as water found at the north end of Yucca Mountain beneath Fortymile Wash. A second end member must contain isotopically heavy carbon and have an old apparent {sup 14}C age such as water from the Paleozoic aquifer. The third end member cannot be tightly defined. It must be isotopically lighter than the first with respect of hydrogen and oxygen and be intermediate to the first and second end members with respect to both apparent {sup 14}C age and {delta}{sup 13}C. The variable isotopic compositions of hydrogen and oxygen indicate that two of the end members are waters, but the variable carbon isotopic composition could represent either a third water end member or reaction of water with a carbon-bearing solids such as calcite. 15 refs., 4 figs., 1 tab.

  3. Forklift Test

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forklift Safety Test Instructions: All Training and Testing Material is for LSU CAMD Users ONLY! Please enter your personal information in the spaces below. A minimum passing score is 80% (8 out of 10) This test can only be taken once in a thirty day period. All fields are required to be filled in. Login: Login First Name: Last Name: Phone Number: Contact: 1. When carrying a load, always: a. tilt the load forward. b. center the load c. carry the load as high as possible d. none of the above 2.

  4. Crane Test

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Crane Safety Test Instructions: All Training and Testing Material is for LSU CAMD Users ONLY! Please enter your personal information in the spaces below. A minimum passing score is 80% (8 out of 10) This test can only be taken once in a thirty day period. All fields are required to be filled in. Login: Login First Name: Last Name: Phone Number: Contact: 1. The first thing you should do when using the crane is to: a. verify the battery power on the remote control. b. drag the load to the desired

  5. Fast Flux Test Facility (FFTF) Briefing Book 1 Summary

    SciTech Connect (OSTI)

    WJ Apley

    1997-12-01

    This report documents the results of evaluations preformed during 1997 to determine what, if an, future role the Fast Flux Test Facility (FFTF) might have in support of the Department of Energys tritium productions strategy. An evaluation was also conducted to assess the potential for the FFTF to produce medical isotopes. No safety, environmental, or technical issues associated with producing 1.5 kilograms of tritium per year in the FFTF have been identified that would change the previous evaluations by the Department of Energy, the JASON panel, or Putnam, Hayes & Bartlett. The FFTF can be refitted and restated by July 2002 for a total expenditure of $371 million, with an additional $64 million of startup expense necessary to incorporate the production of medical isotopes. Therapeutic and diagnostic applications of reactor-generated medical isotopes will increase dramatically over the next decade. Essential medical isotopes can be produced in the FFTF simultaneously with tritium production, and while a stand-alone medical isotope mission for the facility cannot be economically justified given current marker conditions, conservative estimates based on a report by Frost &Sullivan indicate that 60% of the annual operational costs (reactor and fuel supply) could be offset by revenues from medical isotope production within 10 yeas of restart. The recommendation of the report is for the Department of Energy to continue to maintain the FFTF in standby and proceed with preparation of appropriate Nations Environmental Policy Act documentation in full consultation with the public to consider the FFTF as an interim tritium production option (1.5 kilograms/year) with a secondary mission of producing medical isotopes.

  6. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation, and plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the elective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to form an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of dvelopment, cost, advantages and drawbacks of the five processes, (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  7. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the selective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to from an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of development, cost, advantages and drawbacks of the five processes (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  8. Experimental Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  9. Mechanical Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  10. Battery Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  11. High Flux Isotope Reactor cold neutron source reference design concept

    SciTech Connect (OSTI)

    Selby, D.L.; Lucas, A.T.; Hyman, C.R.

    1998-05-01

    In February 1995, Oak Ridge National Laboratory`s (ORNL`s) deputy director formed a group to examine the need for upgrades to the High Flux Isotope Reactor (HFIR) system in light of the cancellation of the Advanced neutron Source Project. One of the major findings of this study was that there was an immediate need for the installation of a cold neutron source facility in the HFIR complex. In May 1995, a team was formed to examine the feasibility of retrofitting a liquid hydrogen (LH{sub 2}) cold source facility into an existing HFIR beam tube. The results of this feasibility study indicated that the most practical location for such a cold source was the HB-4 beam tube. This location provides a potential flux environment higher than the Institut Laue-Langevin (ILL) vertical cold source and maximizes the space available for a future cold neutron guide hall expansion. It was determined that this cold neutron beam would be comparable, in cold neutron brightness, to the best facilities in the world, and a decision was made to complete a preconceptual design study with the intention of proceeding with an activity to install a working LH{sub 2} cold source in the HFIR HB-4 beam tube. During the development of the reference design the liquid hydrogen concept was changed to a supercritical hydrogen system for a number of reasons. This report documents the reference supercritical hydrogen design and its performance. The cold source project has been divided into four phases: (1) preconceptual, (2) conceptual design and testing, (3) detailed design and procurement, and (4) installation and operation. This report marks the conclusion of the conceptual design phase and establishes the baseline reference concept.

  12. Possible differences in biological availability of isotopes of plutonium: Report of a workshop

    SciTech Connect (OSTI)

    Kercher, J.R.; Gallegos, G.M.

    1993-09-01

    This paper presents the results of a workshop conducted on the apparent different bioavailability of isotopes {sup 238}Pu and {sup 239}Pu. There is a substantial body of evidence that {sup 238}Pu as commonly found in the environment is more biologically available than {sup 239}Pu. Studies of the Trinity Site, Nevada Test Site from nonnuclear and nuclear events, Rocky Flats, Enewetak and Bikini, and the arctic tundra support this conclusion and indicate that the bioavailability of {sup 238}Pu is more than an order of magnitude greater than that of {sup 239}Pu. Plant and soil studies from controlled environments and from Savannah River indicate no isotopic difference in availability of Pu to plants; whereas studies at the Trinity Site do suggest a difference. While it is possible that these observations can be explained by problems in the experimental procedure and analytical techniques, this possibility is remote given the ubiquitous nature of the observations. Studies of solubility of Pu in the stomach contents of cattle grazing at the Nevada Test Site and from fish from Bikini Atoll both found that {sup 238}Pu was more soluble than {sup 239}Pu. Studies of the Los Alamos effluent stream indicate that as particle size decreases, the content of {sup 238}Pu relative to {sup 239}Pu increases.

  13. Laser isotope purification of lead for use in semiconductor chip interconnects

    SciTech Connect (OSTI)

    Scheibner, K.; Haynam, C.; Worden, E.; Esser, B.

    1996-03-19

    Lead, used throughout the electronics industries, typically contains small amounts of radioactive {sup 210}Pb (a daughter product of the planets ubiquitous {sup 238}U) whose {sup 210}Po daughter emits an {alpha}-particle that is known to cause soft errors in electronic circuits. The {sup 210}Pb is not separable by chemical means. This paper describes the generic Atomic Vapor Laser Isotope Separation (AVLIS) process developed at the Lawrence Livermore National Laboratory (LLNL) over the last 20 years, with particular emphasis on recent efforts to develop the process physics and component technologies required to remove the offending {sup 210}Pb using lasers. We have constructed a developmental facility that includes a process laser development area and a test bed for the vaporizer and ion and product collectors. We will be testing much of the equipment and demonstrating pilot scale AVLIS on a surrogate material later this year. Detection of the very low alpha emission even from commercially available low-alpha lead is challenging. LLNL`s detection capabilities will be described. The goal of the development of lead purification technology is to demonstrate the capability in FY97, and to deploy a production machine capable of up to several MT/y of isotopically purified material, possible beginning in FY98.

  14. Laser isotope purification of lead for use in semiconductor chip interconnects

    SciTech Connect (OSTI)

    Scheibner, K.; Haynam, C.; Worden, E.; Esser, B.

    1996-02-01

    Lead, used throughout the electronics industries, typically contains small amounts of radioactive {sup 210}Pb (a daughter product of the planet`s ubiquitous {sup 210}U) whose {sup 210}Po daughter emits and {alpha}-particle that is known to cause soft errors in electronic circuits. The {sup 210}Pb is not easily separable by chemical means. This paper describes the generic Atomic Vapor Laser Isotope Separation (AVLIS) process developed at the Lawrence Livermore National Laboratory (LLNL) over the last 20 years, with particular emphasis on recent efforts to develop the process physics and component technologies required to remove the offending {sup 210}Pb using lasers. We have constructed a developmental facility that includes a process laser development area and a test bed for the vaporizer and ion and product collectors. We will be testing much of the equipment and demonstrating pilot-scale AVLIS on a surrogate material later this year. Detection of the very low alpha emission even from commercially available low-alpha lead is challenging. LLNL`s detection capabilities will be described. The goal of the development of lead purification technology is to demonstrate the capability in FY97, and to begin filling orders of up to several MT/y of isotopically purified material in FY98.

  15. IUPAC Periodic Table of Isotopes for the Educational Community

    SciTech Connect (OSTI)

    Holden N. E.; Holden,N.E.; Coplen,T.B.

    2012-07-15

    John Dalton first proposed the concept of atomic weights of the elements in the first decade of the nineteenth century. These atomic weights of the chemical elements were thought of as constants of nature, similar to the speed of light. Dmitri Mendeleev arranged the atomic weights of the elements in ascending order of value and used the systematic variation of their chemical properties to produce his Periodic Table of the Elements in 1869. Measurement of atomic weight values became an important chemical activity for a century and a half. Theodore Richards received a Noble Prize for his work in this area. In 1913, Fredrick Soddy found a species of radium, which had an atomic weight value of 228, compared to the familiar radium gas value of 226. Soddy coined the term 'isotope' (Greek for 'in the same place') to account for this second atomic weight value in the radium position of the Periodic Table. Both of these isotopes of radium are radioactive. Radioactive isotopes are energetically unstable and will decay (disintegrate) over time. The time it takes for one half of a sample of a given radioactive isotope to decay is the half-life of that isotope. In addition to having different atomic weight values, radium-226 and radium-228 also have different half-life values. Around the same time as Soddy's work, J.J. Thomson (discoverer of the electron) identified two stable (non-radioactive) isotopes of the same element, neon. Over the next 40 years, the majority of the known chemical elements were found to have two or more stable (or long-lived radioactive isotopes that contribute significantly to the determination of the atomic weights of the elements).

  16. Preliminary Notice of Violation, International Isotopes Idaho...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ventilation Filters at the Test Reactor Area Hot Cell Facility at the Idaho National Engineering and Environmental Laboratory, On May 19, 2000, the U.S. Department of Energy...

  17. Experimental Test of Self-Shielding in VUV Photodissociation of CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Test of Self-Shielding in VUV Photodissociation of CO Experimental Test of Self-Shielding in VUV Photodissociation of CO Print Wednesday, 25 March 2009 00:00 One way to test models of the solar system's formation is to compare the isotopic abundances of the elements found in its constituent bodies. A case in point is oxygen with three stable isotopes dominated by oxygen-16, with minute fractions of oxygen-17 and oxygen-18. Primitive objects whose formation predates the Earth's, such

  18. The use of carbon stable isotope ratios in drugs characterization

    SciTech Connect (OSTI)

    Magdas, D. A. Cristea, G. Bot, A. Mirel, V.

    2013-11-13

    Isotopic Ratio Mass Spectrometry (IRMS) is an effective toll to be used for drug product authentication. The isotopic composition could be used to assist in the differentiation between batches of drugs and assist in the identification of counterfeit materials on the market. Only two factors affect the isotopic ratios in pharmaceutical components: the isotopic composition of the raw materials and the synthetic processes performed upon them. Counterfeiting of pharmaceutical drugs threatens consumer confidence in drug products companies' economical well-being. In this preliminary study, the analyzed samples consist in two types of commercially available analgesics, which were purchases from Romanian pharmacies. Differences in ?{sup 13}C between batches from ?29.7 to ?31.6% were observed, demonstrating that this method can be used to differentiate among individual drug batches and subsequently identify counterfeits on the market. On the other hand, carbon isotopic ratios differences among producers were recorded, the variations being between ?31.3 to ?34.9% for the same type of analgesic, but from different manufactures.

  19. System for recovery of daughter isotopes from a source material

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID) [Idaho Falls, ID; Todd, Terry A. (Aberdeen, ID) [Aberdeen, ID; Lewis, Leroy C. (Idaho Falls, ID) [Idaho Falls, ID; Henscheid, Joseph P. (Idaho Falls, ID) [Idaho Falls, ID

    2009-08-04

    A method of separating isotopes from a mixture containing at least two isotopes in a solution is disclosed. A first isotope is precipitated and is collected from the solution. A daughter isotope is generated and collected from the first isotope. The invention includes a method of producing an actinium-225/bismuth-213 product from a material containing thorium-229 and thorium-232. A solution is formed containing nitric acid and the material containing thorium-229 and thorium-232, and iodate is added to form a thorium iodate precipitate. A supernatant is separated from the thorium iodate precipitate and a second volume of nitric acid is added to the thorium iodate precipitate. The thorium iodate precipitate is stored and a decay product comprising actinium-225 and bismuth-213 is generated in the second volume of nitric acid, which is then separated from the thorium iodate precipitate, filtered, and treated using at least one chromatographic procedure. A system for producing an actinium-225/bismuth-213 product is also disclosed.

  20. Natural mercury isotope variation in coal deposits and organic soils

    SciTech Connect (OSTI)

    Abir, Biswas; Joel D. Blum; Bridget A. Bergquist; Gerald J. Keeler; Zhouqing Xie

    2008-11-15

    There is a need to distinguish among sources of Hg to the atmosphere in order to more fully understand global Hg pollution. In this study we investigate whether coal deposits within the United States, China, and Russia-Kazakhstan, which are three of the five greatest coal-producing regions, have diagnostic Hg isotopic fingerprints that can be used to discriminate among Hg sources. We also investigate the Hg isotopic composition of modern organic soil horizons developed in areas distant from point sources of Hg in North America. Mercury stored in coal deposits displays a wide range of both mass dependent fractionation and mass independent fractionation. {delta}{sup 202}Hg varies in coals by 3{per_thousand} and {Delta}{sup 201}Hg varies by 0.9{per_thousand}. Combining these two Hg isotope signals results in what may be a unique isotopic 'fingerprint' for many coal deposits. Mass independent fractionation of mercury has been demonstrated to occur during photochemical reactions of mercury. This suggests that Hg found in most coal deposits was subjected to photochemical reduction near the Earth's surface prior to deposition. The similarity in MDF and MIF of modern organic soils and coals from North America suggests that Hg deposition from coal may have imprinted an isotopic signature on soils. This research offers a new tool for characterizing mercury inputs from natural and anthropogenic sources to the atmosphere and provides new insights into the geochemistry of mercury in coal and soils. 35 refs., 2 figs., 1 tab.

  1. Isotope exchange kinetics in metal hydrides I : TPLUG model.

    SciTech Connect (OSTI)

    Larson, Rich; James, Scott Carlton; Nilson, Robert H.

    2011-05-01

    A one-dimensional isobaric reactor model is used to simulate hydrogen isotope exchange processes taking place during flow through a powdered palladium bed. This simple model is designed to serve primarily as a platform for the initial development of detailed chemical mechanisms that can then be refined with the aid of more complex reactor descriptions. The one-dimensional model is based on the Sandia in-house code TPLUG, which solves a transient set of governing equations including an overall mass balance for the gas phase, material balances for all of the gas-phase and surface species, and an ideal gas equation of state. An energy equation can also be solved if thermodynamic properties for all of the species involved are known. The code is coupled with the Chemkin package to facilitate the incorporation of arbitrary multistep reaction mechanisms into the simulations. This capability is used here to test and optimize a basic mechanism describing the surface chemistry at or near the interface between the gas phase and a palladium particle. The mechanism includes reversible dissociative adsorptions of the three gas-phase species on the particle surface as well as atomic migrations between the surface and the bulk. The migration steps are more general than those used previously in that they do not require simultaneous movement of two atoms in opposite directions; this makes possible the creation and destruction of bulk vacancies and thus allows the model to account for variations in the bulk stoichiometry with isotopic composition. The optimization code APPSPACK is used to adjust the mass-action rate constants so as to achieve the best possible fit to a given set of experimental data, subject to a set of rigorous thermodynamic constraints. When data for nearly isothermal and isobaric deuterium-to-hydrogen (D {yields} H) and hydrogen-to-deuterium (H {yields} D) exchanges are fitted simultaneously, results for the former are excellent, while those for the latter show pronounced deviations at long times. These discrepancies can be overcome by postulating the presence of a surface poison such as carbon monoxide, but this explanation is highly speculative. When the method is applied to D {yields} H exchanges intentionally poisoned by known amounts of CO, the fitting results are noticeably degraded from those for the nominally CO-free system but are still tolerable. When TPLUG is used to simulate a blowdown-type experiment, which is characterized by large and rapid changes in both pressure and temperature, discrepancies are even more apparent. Thus, it can be concluded that the best use of TPLUG is not in simulating realistic exchange scenarios, but in extracting preliminary estimates for the kinetic parameters from experiments in which variations in temperature and pressure are intentionally minimized.

  2. Isotope Production and Distribution Program`s Fiscal Year 1997 financial statement audit

    SciTech Connect (OSTI)

    1998-03-27

    The Department of Energy Isotope Production and Distribution Program mission is to serve the national need for a reliable supply of isotope products and services for medicine, industry and research. The program produces and sells hundreds of stable and radioactive isotopes that are widely utilized by domestic and international customers. Isotopes are produced only where there is no U.S. private sector capability or other production capacity is insufficient to meet U.S. needs. The Department encourages private sector investment in new isotope production ventures and will sell or lease its existing facilities and inventories for commercial purposes. The Isotope Program reports to the Director of the Office of Nuclear Energy, Science and Technology. The Isotope Program operates under a revolving fund established by the Fiscal Year (FY) 1990 Energy and Water Appropriations Act and maintains financial viability by earning revenues from the sale of isotopes and services and through annual appropriations. The FY 1995 Energy and Water Appropriations Act modified predecessor acts to allow prices charged for Isotope Program products and services to be based on production costs, market value, the needs of the research community, and other factors. Although the Isotope Program functions as a business, prices set for small-volume, high-cost isotopes that are needed for research purposes may not achieve full-cost recovery. As a result, isotopes produced by the Isotope Program for research and development are priced to provide a reasonable return to the U.S. Government without discouraging their use. Commercial isotopes are sold on a cost-recovery basis. Because of its pricing structure, when selecting isotopes for production, the Isotope Program must constantly balance current isotope demand, market conditions, and societal benefits with its determination to operate at the lowest possible cost to U.S. taxpayers. Thus, this report provides a financial analysis of this situation.

  3. Simple, rapid method for the preparation of isotopically labeled formaldehyde

    DOE Patents [OSTI]

    Hooker, Jacob Matthew; Schonberger, Matthias; Schieferstein, Hanno; Fowler, Joanna S.

    2011-10-04

    Isotopically labeled formaldehyde (*C.sup..sctn.H.sub.2O) is prepared from labeled methyl iodide (*C.sup..sctn.H.sub.3I) by reaction with an oxygen nucleophile having a pendant leaving group. The mild and efficient reaction conditions result in good yields of *C.sup..sctn.H.sub.2O with little or no *C isotopic dilution. The simple, efficient production of .sup.11CH.sub.2O is described. The use of the .sup.11CH.sub.2O for the formation of positron emission tomography tracer compounds is described. The reaction can be incorporated into automated equipment available to radiochemistry laboratories. The isotopically labeled formaldehyde can be used in a variety of reactions to provide radiotracer compounds for imaging studies as well as for scintillation counting and autoradiography.

  4. Rare Isotopes in Cosmic Explosions and Accelerators on Earth

    ScienceCinema (OSTI)

    Schatz, Hendrick [Michigan State University, East Lansing, Michigan, United States

    2010-01-08

    Rare isotopes are nature?s stepping stones to produce the heavy elements, and they are produced in large quantities in stellar explosions. Despite their fleeting existence, they shape the composition of the universe and the observable features of stellar explosions. The challenge for nuclear science is to produce and study the very same rare isotopes so as to understand the origin of the elements and a range of astronomical observations. I will review the progress that has been made to date in astronomy and nuclear physics, and the prospects of finally addressing many of the outstanding issues with the future Facility for Rare Isotope Beams (FRIB), which DOE will build at Michigan State University.

  5. Microgrid Testing

    SciTech Connect (OSTI)

    Shirazi, M.; Kroposki, B.

    2012-01-01

    With the publication of IEEE 1574.4 Guide for Design, Operation, and Integration of Distributed Resource Island Systems with Electric Power Systems, there is an increasing amount of attention on not only the design and operations of microgrids, but also on the proper operation and testing of these systems. This standard provides alternative approaches and good practices for the design, operation, and integration of microgrids. This includes the ability to separate from and reconnect to part of the utility grid while providing power to the islanded power system. This presentation addresses the industry need to develop standardized testing and evaluation procedures for microgrids in order to assure quality operation in the grid connected and islanded modes of operation.

  6. Interactions of Hydrogen Isotopes and Oxides with Metal Tubes

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2008-08-01

    Understanding and accounting for interaction of hydrogen isotopes and their oxides with metal surfaces is important for persons working with tritium systems. Reported data from several investigators have shown that the processes of oxidation, adsorption, absorption, and permeation are all coupled and interactive. A computer model has been developed for predicting the interaction of hydrogen isotopes and their corresponding oxides in a flowing carrier gas stream with the walls of a metallic tube, particularly at low hydrogen concentrations. An experiment has been constructed to validate the predictive model. Predictions from modeling lead to unexpected experiment results.

  7. Equations of state and phase diagrams of hydrogen isotopes

    SciTech Connect (OSTI)

    Urlin, V. D.

    2013-11-15

    A new form of the semiempirical equation of state proposed for the liquid phase of hydrogen isotopes is based on the assumption that its structure is formed by cells some of which contain hydrogen molecules and others contain hydrogen atoms. The values of parameters in the equations of state of the solid (molecular and atomic) phases as well as of the liquid phase of hydrogen isotopes (protium and deuterium) are determined. Phase diagrams, shock adiabats, isentropes, isotherms, and the electrical conductivity of compressed hydrogen are calculated. Comparison of the results of calculations with available experimental data in a wide pressure range demonstrates satisfactory coincidence.

  8. Isotope Effects and Helium Retention Behavior in Vanadium Tritide

    SciTech Connect (OSTI)

    Bowman, Jr., R. C.; Attalla, A.; Craft, B. D.

    1985-04-01

    The relaxation times of the H, T, and 3He nuclei have been measured in vanadium hydride and tritide samples. Substantial isotope effects in both the phase transition temperatures and diffusion parameters have been found. When compared to hydrides, the tritide samples have lower transition temperatures and faster mobilities. The differences in the occupancies of the interstitial sites are largely responsible for these isotope effects. Most of the helium atoms generated by tritium decay remain trapped in microscopic bubbles formed with the VTx lattice. Evidence is presented for the gradual growth of the helium bubbles over periods of hundreds of days.

  9. Lesson 3 - Atoms and Isotopes | Department of Energy

    Energy Savers [EERE]

    3 - Atoms and Isotopes Lesson 3 - Atoms and Isotopes You've probably heard people refer to nuclear energy as "atomic energy." Why? Nuclear energy is the energy that is stored in the bonds of atoms, inside the nucleus. Nuclear power plants are designed to capture this energy as heat and convert it to electricity. This lesson looks closely at what atoms are and how atoms store energy. This lesson covers the following topics: Matter Molecules Elements Chemical reaction Periodic table The

  10. High Flux Isotope Reactor | Neutron Science at ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Flux Isotope Reactor High Flux Isotope Reactor Operating at 85 MW, HFIR is the highest flux reactor-based source of neutrons for research in the United States, and it provides one of the highest steady-state neutron fluxes of any research reactor in the world. The thermal and cold neutrons produced by HFIR are used to study physics, chemistry, materials science, engineering, and biology. The intense neutron flux, constant power density, and constant-length fuel cycles are used by more than

  11. Atomic vapor laser isotope separation using resonance ionization

    SciTech Connect (OSTI)

    Comaskey, B.; Crane, J.; Erbert, G.; Haynam, C.; Johnson, M.; Morris, J.; Paisner, J.; Solarz, R.; Worden, E.

    1986-09-01

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power-reactor fuel has been under development for over 10 years. In June 1985, the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for enriched uranium. Resonance photoionization is the heart of the AVLIS process. We discuss those fundamental atomic parameters that are necessary for describing isotope-selective resonant multistep photoionization along with the measurement techniques that we use. We illustrate the methodology adopted with examples of other elements that are under study in our program.

  12. AFCI Fuel Irradiation Test Plan, Test Specimens AFC-1 and AFC-1F

    SciTech Connect (OSTI)

    D. C. Crawford; S. L. Hayes; B. A. Hilton; M. K. Meyer; R. G. Ambrosek; G. S. Chang; D. J. Utterbeck

    2003-11-01

    The U. S. Advanced Fuel Cycle Initiative (AFCI) seeks to develop and demonstrate the technologies needed to transmute the long-lived transuranic actinide isotopes contained in spent nuclear fuel into shorter-lived fission products, thereby dramatically decreasing the volume of material requiring disposition and the long-term radiotoxicity and heat load of high-level waste sent to a geologic repository (DOE, 2003). One important component of the technology development is actinide-bearing transmutation fuel forms containing plutonium, neptunium, americium (and possibly curium) isotopes. There are little irradiation performance data available on non-fertile fuel forms, which would maximize the destruction rate of plutonium, and low-fertile (i.e., uranium-bearing) fuel forms, which would support a sustainable nuclear energy option. Initial scoping level irradiation tests on a variety of candidate fuel forms are needed to establish a transmutation fuel form design and evaluate deployment of transmutation fuels.

  13. Isotope powered Stirling generator for terrestrial applications

    SciTech Connect (OSTI)

    Tingey, G.L.; Sorensen, G.C.; Ross, B.A.

    1995-01-01

    An electric power supply, small enough to be man-portable, is being developed for remote, terrestrial applications. This system is designed for an operating lifetime of five years without maintenance or refueling. A small Radioisotope Stirling Generator (RSG) has been developed. The energy source of the generator is a 60 watt plutonium-238 fuel clad used in the General Purpose Heat Sources (GPHS) developed for space applications. A free piston Stirling Engine drives a linear alternator to convert the heat to power. The system weighs about 7.5 kg and produces 11 watts AC power with a conversion efficiency of 18.5%. Two engine models have been designed, fabricated, and tested to date: (a) a developmental model instrumented to confirm and test parameters, and (b) an electrically heated model with an electrical heater equipped power input leads. Critical components have been tested for 10,000 to 20,000 hours. One complete generator has been operating for over 11,000 hours. Radioisotope heated prototypes are expected to be fabricated and tested in late 1995.

  14. Isotope enrichment by frequency-tripled temperature tuned neodymium laser photolysis of formaldehyde

    DOE Patents [OSTI]

    Marling, John B.

    1977-01-01

    Enrichment of carbon, hydrogen and/or oxygen isotopes by means of isotopically selective photo-predissociation of formaldehyde is achieved by irradiation provided by a frequency-tripled, temperature tuned neodymium laser.

  15. Dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources

    DOE Patents [OSTI]

    Barty, Christopher P.J.

    2013-02-05

    A dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources includes a detector arrangement consists of three detectors downstream from the object under observation. The latter detector, which operates as a beam monitor, is an integrating detector that monitors the total beam power arriving at its surface. The first detector and the middle detector each include an integrating detector surrounding a foil. The foils of these two detectors are made of the same atomic material, but each foil is a different isotope, e.g., the first foil may comprise U235 and second foil may comprise U238. The integrating detectors surrounding these pieces of foil measure the total power scattered from the foil and can be similar in composition to the final beam monitor. Non-resonant photons will, after calibration, scatter equally from both foils.

  16. Method for enriching a middle isotope using vibration-vibration pumping

    DOE Patents [OSTI]

    Rich, Joseph W. (East Aurora, NY); Homicz, Gregory F. (Getzville, NY); Bergman, Richard C. (Corfu, NY)

    1989-01-01

    Method for producing isotopically enriched material by vibration-vibration excitation of gaseous molecules wherein a middle mass isotope of an isotopic mixture including lighter and heavier mass isotopes preferentially populates a higher vibrational mode and chemically reacts to provide a product in which it is enriched. The method can be used for vibration-vibration enrichment of .sup.17 O in a CO reactant mixture.

  17. Pb Isotopes as an Indicator of the Asian Contribution to Particulate Air Pollution in Urban California

    SciTech Connect (OSTI)

    Ewing, Stephanie A.; Christensen, John N.; Brown, Shaun T.; Vancuren, Richard A.; Cliff, Steven S.; DePaolo, Donald J.

    2010-10-25

    During the last two decades, expanding industrial activity in east Asia has led to increased production of airborne pollutants that can be transported to North America. Previous efforts to detect this trans-Pacific pollution have relied upon remote sensing and remote sample locations. We tested whether Pb isotope ratios in airborne particles can be used to directly evaluate the Asian contribution to airborne particles of anthropogenic origin in western North America, using a time series of samples from a pair of sites upwind and downwind of the San Francisco Bay Area. Our results for airborne Pb at these sites indicate a median value of 29 Asian origin, based on mixing relations between distinct regional sample groups. This trans-Pacific Pb is present in small quantities but serves as a tracer for airborne particles within the growing Asian industrial plume. We then applied this analysis to archived samples from urban sites in central California. Taken together, our results suggest that the analysis of Pb isotopes can reveal the distribution of airborne particles affected by Asian industrial pollution at urban sites in northern California. Under suitable circumstances, this analysis can improve understanding of the global transport of pollution, independent of transport models.

  18. Using phylogenetic probes for quantification of stable isotope labeling and microbial community analysis

    DOE Patents [OSTI]

    Brodie, Eoin L; DeSantis, Todd Z; Karaoz, Ulas; Andersen, Gary L

    2014-12-09

    Herein is described methods for a high-sensitivity means to measure the incorporation of stable isotope labeled substrates into RNA following stable isotope probing experiments (SIP). RNA is hybridized to a set of probes such as phylogenetic microarrays and isotope incorporation is quantified such as by secondary ion mass spectrometer imaging (NanoSIMS).

  19. Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jeff Heikoop; Heather Throckmorton

    2015-05-15

    Dataset includes nitrate concentrations for polygonal active layer samples, snowmelt; ammonium concentrations for active layer samples; nitrate isotopes for active layer samples, snowmelt, permafrost; ammonium isotopes for active layer samples; and nitrogen isotopes for soils and dissolved organic nitrogen extracted from soil pore waters.

  20. CRAD, Maintenance- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Maintenance Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  1. CRAD, Engineering- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Engineering Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  2. CRAD, Training- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Training Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  3. CRAD, Management- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Management in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  4. Ab Initio Nuclear Structure and Reaction Calculations for Rare Isotopes

    SciTech Connect (OSTI)

    Draayer, Jerry P.

    2014-09-28

    We have developed a novel ab initio symmetry-adapted no-core shell model (SA-NCSM), which has opened the intermediate-mass region for ab initio investigations, thereby providing an opportunity for first-principle symmetry-guided applications to nuclear structure and reactions for nuclear isotopes from the lightest p-shell systems to intermediate-mass nuclei. This includes short-lived proton-rich nuclei on the path of X-ray burst nucleosynthesis and rare neutron-rich isotopes to be produced by the Facility for Rare Isotope Beams (FRIB). We have provided ab initio descriptions of high accuracy for low-lying (including collectivity-driven) states of isotopes of Li, He, Be, C, O, Ne, Mg, Al, and Si, and studied related strong- and weak-interaction driven reactions that are important, in astrophysics, for further understanding stellar evolution, X-ray bursts and triggering of s, p, and rp processes, and in applied physics, for electron and neutrino-nucleus scattering experiments as well as for fusion ignition at the National Ignition Facility (NIF).

  5. Rare Isotope Beams for the 21st Century

    ScienceCinema (OSTI)

    James Symons

    2010-01-08

    In a scientific keynote address on Friday, June 12 at Michigan State University (MSU) in East Lansing, James Symons, Director of Berkeley Labs Nuclear Science Division (NSD), discussed the exciting research prospects of the new Facility for Rare Isotope Beams (FRIB) to be built at MSUs National Superconducting Cyclotron Laboratory.

  6. Apparatus and method for monitoring of gas having stable isotopes

    DOE Patents [OSTI]

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  7. Isotope production agreement benefits medical patients | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration Isotope production agreement benefits medical patients | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press

  8. Method of enhancing selective isotope desorption from metals

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1983-07-26

    This invention relates generally to the field of gas desorption from metals; and, more particularly, to a method of enhancing the selective desorption of a particular isotope of a gas from metals. Enhanced selective desorption is especially useful in the operation of fusion devices.

  9. Cascades for hydrogen isotope separation using metal hydrides

    SciTech Connect (OSTI)

    Hill, F.B.; Grzetic, V.

    1982-01-01

    Designs are presented for continuous countercurrent hydrogen isotope separation cascades based on the use of metal hydrides. The cascades are made up of pressure swing adsorption (PSA) or temperature swing adsorption (TSA) stages. The designs were evolved from consideration of previously conducted studies of the separation performance of four types of PSA and TSA processes.

  10. Laser-induced separation of hydrogen isotopes in the liquid phase

    DOE Patents [OSTI]

    Freund, Samuel M. (Los Alamos, NM); Maier, II, William B. (Los Alamos, NM); Beattie, Willard H. (Los Alamos, NM); Holland, Redus F. (Los Alamos, NM)

    1980-01-01

    Hydrogen isotope separation is achieved by either (a) dissolving a hydrogen-bearing feedstock compound in a liquid solvent, or (b) liquefying a hydrogen-bearing feedstock compound, the liquid phase thus resulting being kept at a temperature at which spectral features of the feedstock relating to a particular hydrogen isotope are resolved, i.e., a clear-cut isotope shift is delineated, irradiating the liquid phase with monochromatic radiation of a wavelength which at least preferentially excites those molecules of the feedstock containing a first hydrogen isotope, inducing photochemical reaction in the excited molecules, and separating the reaction product containing the first isotope from the liquid phase.

  11. DEMONSTRATION OF THE NEXT-GENERATION TCAP HYDROGEN ISOTOPE SEPARATION PROCESS

    SciTech Connect (OSTI)

    Heung, L; Henry Sessions, H; Steve Xiao, S; Heather Mentzer, H

    2009-01-09

    The first generation of TCAP hydrogen isotope separation process has been in service for tritium separation at the Savannah River Site since 1994. To prepare for replacement, a next-generation TCAP process has been developed. This new process simplifies the column design and reduces the equipment requirements of the thermal cycling system. An experimental twelve-meter column was fabricated and installed in the laboratory to demonstrate its performance. This new design and its initial test results were presented at the 8th International Conference on Tritium Science and Technology and published in the proceedings. We have since completed the startup and demonstration the separation of protium and deuterium in the experimental unit. The unit has been operated for more than 200 cycles. A feed of 25% deuterium in protium was separated into two streams each better than 99.7% purity.

  12. Dual pressure-dual temperature isotope exchange process

    DOE Patents [OSTI]

    Babcock, D.F.

    1974-02-12

    A liquid and a gas stream, each containing a desired isotope, flow countercurrently through two liquid-gas contacting towers maintained at different temperatures and pressures. The liquid is enriched in the isotope in one tower while the gas is enriched within the other and a portion of at least one of the enriched streams is withdrawn from the system for use or further enrichment. The tower operated at the lower temperature is also maintained at the lower pressure to prevent formation of solid solvates. Gas flow between the towers passes through an expander-compressor apparatas to recover work from the expansion of gas to the lower pressure and thereby compress the gas returning to the tower of higher pressure. (Official Gazette)

  13. Descriptions of carbon isotopes within the energy density functional theory

    SciTech Connect (OSTI)

    Ismail, Atef; Cheong, Lee Yen; Yahya, Noorhana; Tammam, M.

    2014-10-24

    Within the energy density functional (EDF) theory, the structure properties of Carbon isotopes are systematically studied. The shell model calculations are done for both even-A and odd-A nuclei, to study the structure of rich-neutron Carbon isotopes. The EDF theory indicates the single-neutron halo structures in {sup 15}C, {sup 17}C and {sup 19}C, and the two-neutron halo structures in {sup 16}C and {sup 22}C nuclei. It is also found that close to the neutron drip-line, there exist amazing increase in the neutron radii and decrease on the binding energies BE, which are tightly related with the blocking effect and correspondingly the blocking effect plays a significant role in the shell model configurations.

  14. Hydrogen isotope MicroChemLab FY15.

    SciTech Connect (OSTI)

    Robinson, David; Luo, Weifang; Stewart, Kenneth D.

    2015-09-01

    We have developed a new method to measure the composition of gaseous mixtures of any two hydrogen isotopes, as well as an inert gas component. When tritium is one of those hydrogen isotopes, there is usually some helium present, because the tritium decays to form helium at a rate of about 1% every 2 months. The usual way of measuring composition of these mixtures involves mass spectrometry, which involves bulky, energy-intensive, expensive instruments, including vacuum pumps that can quite undesirably disperse tritium. Our approach uses calorimetry of a small quantity of hydrogen-absorbing material to determine gas composition without consuming or dispersing the analytes. Our work was a proof of principle using a rather large and slow benchtop calorimeter. Incorporation of microfabricated calorimeters, such as those that have been developed in Sandias MicroChemLab program or that are now commercially available, would allow for faster measurements and a smaller instrument footprint.

  15. Reactor Fuel Isotopics and Code Validation for Nuclear Applications

    SciTech Connect (OSTI)

    Francis, Matthew W.; Weber, Charles F.; Pigni, Marco T.; Gauld, Ian C.

    2015-02-01

    Experimentally measured isotopic concentrations of well characterized spent nuclear fuel (SNF) samples have been collected and analyzed by previous researchers. These sets of experimental data have been used extensively to validate the accuracy of depletion code predictions for given sets of burnups, initial enrichments, and varying power histories for different reactor types. The purpose of this report is to present the diversity of data in a concise manner and summarize the current accuracy of depletion modeling. All calculations performed for this report were done using the Oak Ridge Isotope GENeration (ORIGEN) code, an internationally used irradiation and decay code solver within the SCALE comprehensive modeling and simulation code. The diversity of data given in this report includes key actinides, stable fission products, and radioactive fission products. In general, when using the current ENDF/B-VII.0 nuclear data libraries in SCALE, the major actinides are predicted to within 5% of the measured values. Large improvements were seen for several of the curium isotopes when using improved cross section data found in evaluated nuclear data file ENDF/B-VII.0 as compared to ENDF/B-V-based results. The impact of the flux spectrum on the plutonium isotope concentrations as a function of burnup was also shown. The general accuracy noted for the actinide samples for reactor types with burnups greater than 5,000 MWd/MTU was not observed for the low-burnup Hanford B samples. More work is needed in understanding these large discrepancies. The stable neodymium and samarium isotopes were predicted to within a few percent of the measured values. Large improvements were seen in prediction for a few of the samarium isotopes when using the ENDF/B-VII.0 libraries compared to results obtained with ENDF/B-V libraries. Very accurate predictions were obtained for 133Cs and 153Eu. However, the predicted values for the stable ruthenium and rhodium isotopes varied as much as 10% of the measured values, and 109Ag was consistently over-predicted by as much as 170%. In general, there is a larger uncertainty for modeling radioactive fission products when compared to either the actinides or the stable fission products in SNF. The relative C/E ratios ranged from a few percent for 137Cs up to 60% and 100% for 106Ru and 125Sb, respectively. Limited or no radioactive fission products data exist in the current data sets for reactor types other than PWRs and BWRs. More work is needed in obtaining a greater diversity of radioactive fission product data. While performing this survey, issues leading to inconsistencies in nuclear fission yield data were discovered that specifically impacted the fission product noble gases. Emphasis was given to this legacy data, and corrective actions were taken as described in this report. After the fission yield data were corrected, the stable xenon and krypton fission products were predicted to within 5% of their measurements. However, preliminary results not explicitly given in this report indicate that the relative C/E ratio for the radioactive isotope 85Kr varied as much as 10%. Due to the complex migration and the difficulty in measuring noble gases in the fuel, a more thorough investigation is needed to understand how accurately depletion codes can calculate these gas concentrations.

  16. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  17. Y-12 plant prepares to separate lithium isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plant prepares to separate lithium isotopes The Y-12 National Security Complex is one of three major Manhattan Project sites in Oak Ridge. Y-12 is the nation's sole storage location for weapons-grade uranium and is the Department of Energy's National Nuclear Security Administration's production facility for nuclear weapons "secondaries" -- the part of the weapon providing the enormous energy release that can be in excess of tens of megatons of instantaneous energy. Y-12 also assists

  18. FUEL CYCLE ISOTOPE EVOLUTION BY TRANSMUTATION DYNAMICS OVER MULTIPLE RECYCLES

    SciTech Connect (OSTI)

    Samuel Bays; Steven Piet; Amaury Dumontier

    2010-06-01

    Because all actinides have the ability to fission appreciably in a fast neutron spectrum, these types of reactor systems are usually not associated with the buildup of higher mass actinides: curium, berkelium and californium. These higher actinides have high specific decay heat power, gamma and neutron source strengths, and are usually considered as a complication to the fuel manufacturing and transportation of fresh recycled transuranic fuel. This buildup issue has been studied widely for thermal reactor fuels. However, recent studies have shown that the transmutation physics associated with "gateway isotopes" dictates Cm-Bk-Cf buildup, even in fast burner reactors. Assuming a symbiotic fuel relationship with light water reactors (LWR), Pu-242 and Am-243 are formed in the LWRs and then are externally fed to the fast reactor as part of its overall transuranic fuel supply. These isotopes are created much more readily in a thermal than in fast spectrum systems due to the differences in the fast fission (i.e., above the fission threshold for non-fissile actinides) contribution. In a strictly breeding fast reactor this dependency on LWR transuranics would not exist, and thus avoids the introduction of LWR derived gateway isotopes into the fast reactor system. However in a transuranic burning fast reactor, the external supply of these gateway isotopes behaves as an external driving force towards the creation and build-up of Cm-Bk-Cf in the fuel cycle. It was found that though the Cm-Bk-Cf concentration in the equilibrium fuel cycle is dictated by the fast neutron spectrum, the time required to reach that equilibrium concentration is dictated by recycle, transmutation and decay storage dynamics.

  19. DOE Isotope Program Announces Availability of Radionuclide Generators for

    Office of Science (SC) Website

    Medical Research | U.S. DOE Office of Science (SC) DOE Isotope Program Announces Availability of Radionuclide Generators for Medical Research Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email

  20. NOVEL CONCEPTS FOR ISOTOPIC SEPARATION OF 3HE/4HE

    SciTech Connect (OSTI)

    Roy, L.; Nigg, H.; Watson, H.

    2012-09-04

    The research outlined below established theoretical proof-of-concept using ab initio calculations that {sup 3}He can be separated from {sup 4}He by taking advantage of weak van der Waals interactions with other higher molecular weight rare gases such as xenon. To the best of our knowledge, this is the only suggested method that exploits the physical differences of the isotopes using a chemical interaction.

  1. Isotope Development & Production for Research and Applications (IDPRA) |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. DOE Office of Science (SC) Research » Isotope Development & Production for Research and Applications (IDPRA) Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email Us More Information »

  2. HEU Minimization and the Reliable Supply of Medical Isotopes Nuclear

    National Nuclear Security Administration (NNSA)

    Security Summit: Fact Sheet | National Nuclear Security Administration HEU Minimization and the Reliable Supply of Medical Isotopes Nuclear Security Summit: Fact Sheet | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget

  3. An overview of copper-laser development for isotope separation

    SciTech Connect (OSTI)

    Warner, B.E.

    1987-03-13

    We have developed a copper-laser pumped dye-laser system that addresses all of the requirements for atomic vapor laser isotope separation. The requirement for high average power for the laser system has led to the development of copper-laser chains with injection-locked oscillators and multihundred-watt amplifiers. By continuously operating the Laser Demonstration Facility, we gain valuable data for further upgrade and optimization.

  4. Hanford Isotope Project strategic business analysis Cesium-137 (Cs-137)

    SciTech Connect (OSTI)

    1995-10-01

    The purpose of this business analysis is to address the beneficial reuse of Cesium 137 (Cs-137) in order to utilize a valuable national asset and possibly save millions of tax dollars. Food irradiation is the front runner application along with other uses. This business analysis supports the objectives of the Department of Energy National Isotope Strategy distributed in August 1994 which describes the DOE plans for the production and distribution of isotope products and services. As part of the Department`s mission as stated in that document. ``The Department of Energy will also continue to produce and distribute other radioisotopes and enriched stable isotopes for medical diagnostics and therapeutics, industrial, agricultural, and other useful applications on a businesslike basis. This is consistent with the goals and objectives of the National Performance Review. The Department will endeavor to look at opportunities for private sector to co-fund or invest in new ventures. Also, the Department will seek to divest from ventures that can more profitably or reliably be operated by the private sector.``

  5. ANALYSIS OF RICIN TOXIN PREPARATIONS FOR CARBOHYDRATE AND FATTY ACID ABUNDANCE AND ISOTOPE RATIO INFORMATION

    SciTech Connect (OSTI)

    Wunschel, David S.; Kreuzer-Martin, Helen W.; Antolick, Kathryn C.; Colburn, Heather A.; Moran, James J.; Melville, Angela M.

    2009-12-01

    This report describes method development and preliminary evaluation for analyzing castor samples for signatures of purifying ricin. Ricin purification from the source castor seeds is essentially a problem of protein purification using common biochemical methods. Indications of protein purification will likely manifest themselves as removal of the non-protein fractions of the seed. Two major, non-protein, types of biochemical constituents in the seed are the castor oil and various carbohydrates. The oil comprises roughly half the seed weight while the carbohydrate component comprises roughly half of the remaining mash left after oil and hull removal. Different castor oil and carbohydrate components can serve as indicators of specific toxin processing steps. Ricinoleic acid is a relatively unique fatty acid in nature and is the most abundant component of castor oil. The loss of ricinoleic acid indicates a step to remove oil from the seeds. The relative amounts of carbohydrates and carbohydrate-like compounds, including arabinose, xylose, myo-inositol fucose, rhamnose, glucosamine and mannose detected in the sample can also indicate specific processing steps. For instance, the differential loss of arabinose relative to mannose and N-acetyl glucosamine indicates enrichment for the protein fraction of the seed using protein precipitation. The methods developed in this project center on fatty acid and carbohydrate extraction from castor samples followed by derivatization to permit analysis by gas chromatography-mass spectrometry (GC-MS). Method descriptions herein include: the source and preparation of castor materials used for method evaluation, the equipment and description of procedure required for chemical derivatization, and the instrument parameters used in the analysis. Two types of derivatization methods describe analysis of carbohydrates and one procedure for analysis of fatty acids. Two types of GC-MS analysis is included in the method development, one employing a quadrupole MS system for compound identification and an isotope ratio MS for measuring the stable isotope ratios of deuterium and hydrogen (D/H) in fatty acids. Finally, the method for analyzing the compound abundance data is included. This study indicates that removal of ricinoleic acid is a conserved consequence of each processing step we tested. Furthermore, the stable isotope D/H ratio of ricinoleic acid distinguished between two of the three castor seed sources. Concentrations of arabinose, xylose, mannose, glucosamine and myo-inositol differentiated between crude or acetone extracted samples and samples produced by protein precipitation. Taken together these data illustrate the ability to distinguish between processes used to purify a ricin sample as well as potentially the source seeds.

  6. Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data

    SciTech Connect (OSTI)

    Thomas, James; Decker, David; Patterson, Gary; Peterman, Zell; Mihevc, Todd; Larsen, Jessica; Hershey, Ronald

    2007-06-25

    Groundwater samples in the Yucca Mountain area were collected for chemical and isotopic analyses and measurements of water temperature, pH, specific conductivity, and alkalinity were obtained at the well or spring at the time of sampling. For this project, groundwater samples were analyzed for major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC). The U.S. Geological Survey (USGS) performed all the fieldwork on this project including measurement of water chemistry field parameters and sample collection. The major ions dissolved in the groundwater, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) were analyzed by the USGS. All preparation and processing of samples for DOC carbon isotopic analyses and geochemical modeling were performed by the Desert Research Institute (DRI). Analysis of the DOC carbon dioxide gas produced at DRI to obtain carbon-13 and carbon-14 values was conducted at the University of Arizona Accelerator Facility (a NSHE Yucca Mountain project QA qualified contract facility). The major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of DIC were used in geochemical modeling (NETPATH) to determine groundwater sources, flow paths, mixing, and ages. The carbon isotopes of DOC were used to calculate groundwater ages that are independent of DIC model corrected carbon-14 ages. The DIC model corrected carbon-14 calculated ages were used to evaluate groundwater travel times for mixtures of water including water beneath Yucca Mountain. When possible, groundwater travel times were calculated for groundwater flow from beneath Yucca Mountain to down gradient sample sites. DOC carbon-14 groundwater ages were also calculated for groundwaters in the Yucca Mountain area. When possible, groundwater travel times were estimated for groundwater flow from beneath Yucca Mountain to down gradient groundwater sample sites using the DOC calculated groundwater ages. The DIC calculated groundwater ages were compared with DOC calculated groundwater ages and both of these ages were compared to travel times developed in ground-water flow and transport models. If nuclear waste is stored in Yucca Mountain, the saturated zone is the final barrier against the release of radionuclides to the environment. The most recent rendition of the TSPA takes little credit for the presence of the saturated zone and is a testament to the inadequate understanding of this important barrier. If radionuclides reach the saturated zone beneath Yucca Mountain, then there is a travel time before they would leave the Yucca Mountain area and flow down gradient to the Amargosa Valley area. Knowing how long it takes groundwater in the saturated zone to flow from beneath Yucca Mountain to down gradient areas is critical information for potential radionuclide transport. Radionuclide transport in groundwater may be the quickest pathway for radionuclides in the proposed Yucca Mountain repository to reach land surface by way of groundwater pumped in Amargosa Valley. An alternative approach to ground-water flow and transport models to determine the travel time of radionuclides from beneath Yucca Mountain to down gradient areas in the saturated zone is by carbon-14 dating of both inorganic and organic carbon dissolved in the groundwater. A standard method of determining ground-water ages is to measure the carbon-13 and carbon-14 of DIC in the groundwater and then correct the measured carbon-14 along a flow path for geochemical reactions that involve carbon containing phases. These geochemical reactions are constrained by carbon-13 and isotopic fractionations. Without correcting for geochemical reactions, the ground-water ages calculated from only the differences in carbon-14 measured along a flow path (assuming the decrease in carbon-14 is due strictly to radioactive decay) could be tens of thousands of years too old. The computer program NETPATH, developed by the USGS, is the best geochemical program for correcting carbon-14 activities for geochemical r

  7. Accelerated Stress Testing, Qualification Testing, HAST, Field...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Accelerated Stress Testing, Qualification Testing, HAST, Field Experience This presentation, which was the opening session of the NREL 2013 Photovoltaic Module Reliability Workshop ...

  8. Measurements of charge state breeding efficiency at BNL test EBIS

    SciTech Connect (OSTI)

    Kondrashev, S.; Alessi, J.; Beebe, E.N.; Dickerson, C.; Ostroumov, P.N.; Pikin, A.; Savard, G.

    2011-04-02

    Charge breeding of singly charged ions is required to efficiently accelerate rare isotope ion beams for nuclear and astrophysics experiments, and to enhance the accuracy of low-energy Penning trap-assisted spectroscopy. An efficient charge breeder for the Californium Rare Isotope Breeder Upgrade (CARIBU) to the ANL Tandem Linear Accelerator System (ATLAS) facility is being developed using the BNL Test Electron Beam Ion Source (Test EBIS) as a prototype. Parameters of the CARIBU EBIS charge breeder are similar to those of the BNL Test EBIS except the electron beam current will be adjustable in the range from 1 to 2 {angstrom}. The electron beam current density in the CARIBU EBIS trap will be significantly higher than in existing operational charge state breeders based on the EBIS concept. The charge state breeding efficiency is expected to be about 25% for the isotope ions extracted from the CARIBU. For the success of our EBIS project, it is essential to demonstrate high breeding efficiency at the BNL Test EBIS tuned to the regime close to the parameters of the CARIBU EBIS at ANL. The breeding efficiency optimization and measurements have been successfully carried out using a Cs{sup +} surface ionization ion source for externally pulsed injection into the BNL Test EBIS. A Cs{sup +} ion beam with a total number of ions of 5 x 10{sup 8} and optimized pulse length of 70 {mu}s has been injected into the Test EBIS and charge-bred for 5.3 ms for two different electron beam currents 1 and 1.5 {angstrom}. In these experiments we have achieved 70% injection/extraction efficiency and breeding efficiency into the most abundant charge state 17%.

  9. Efficient and selective isotopic labeling of hemes to facilitate the study

    Office of Scientific and Technical Information (OSTI)

    of multiheme proteins (Journal Article) | SciTech Connect Efficient and selective isotopic labeling of hemes to facilitate the study of multiheme proteins Citation Details In-Document Search Title: Efficient and selective isotopic labeling of hemes to facilitate the study of multiheme proteins Specific isotopic labeling of hemes provides a unique opportunity to characterize the structure and function of heme-proteins. Unfortunately, present day methods do not allow efficient labeling in high

  10. Application of Environmental Isotopes to the Evaluation of the Origin of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contamination in a Desert Arroyo: Many Devils Wash, Shiprock, New Mexico | Department of Energy Application of Environmental Isotopes to the Evaluation of the Origin of Contamination in a Desert Arroyo: Many Devils Wash, Shiprock, New Mexico Application of Environmental Isotopes to the Evaluation of the Origin of Contamination in a Desert Arroyo: Many Devils Wash, Shiprock, New Mexico Application of Environmental Isotopes to the Evaluation of the Origin of Contamination in a Desert Arroyo:

  11. High Flux Isotope Reactor (HFIR) | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Facilities » High Flux Isotope Reactor (HFIR) Scientific User Facilities (SUF) Division SUF Home About User Facilities X-Ray Light Sources Neutron Scattering Facilities Spallation Neutron Source (SNS) High Flux Isotope Reactor (HFIR) Nanoscale Science Research Centers (NSRCs) Projects Accelerator & Detector Research Science Highlights Principal Investigators' Meetings BES Home Neutron Scattering Facilities High Flux Isotope Reactor (HFIR) Print Text Size: A A A FeedbackShare Page Quick

  12. Isotope Related Reports | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Isotope Related Reports Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email Us More Information » Isotope Development & Production for Research and Applications (IDPRA) Isotope Related Reports

  13. Isotope Program Facilities | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope Program Facilities Nuclear Physics (NP) NP Home About Research Facilities User Facilities Project Development Isotope Program Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email Us More Information » Facilities Isotope Program

  14. Resonance ionization laser ion sources for on-line isotope separators

    Office of Scientific and Technical Information (OSTI)

    (invited) (Journal Article) | SciTech Connect Resonance ionization laser ion sources for on-line isotope separators (invited) Citation Details In-Document Search Title: Resonance ionization laser ion sources for on-line isotope separators (invited) A Resonance Ionization Laser Ion Source (RILIS) is today considered an essential component of the majority of Isotope Separator On Line (ISOL) facilities; there are seven laser ion sources currently operational at ISOL facilities worldwide and

  15. Stable isotopes of authigenic minerals in variably-saturated fractured tuff

    SciTech Connect (OSTI)

    Weber, D.S.; Evans, D.D.

    1988-11-01

    Identifying stable isotope variation and mineralogical changes in fractured rock may help establish the history of climatic and geomorphological processes that might affect the isolation properties of a waste repository site. This study examines the use of the stable isotope ratios of oxygen ({sup 18}O/{sup 16}O) and carbon ({sup 13}C/{sup 12}C) in authigenic minerals as hydrogeochemical tools tracing low-temperature rock-water interaction in variably-saturated fractured stuff. Isotopic compositions of fracture-filling and rock matrix minerals in the Apache Leap tuff, near Superior, Arizona were concordant with geothermal temperatures and in equilibrium with water isotopically similar to present-day meteoric water and groundwater. Oxygen and carbon isotope ratios of fracture-filling, in unsaturated fractured tuff, displayed an isotopic gradient believed to result from near-surface isotopic enrichment due to evaporation rather than the effects of rock-water interaction. Oxygen isotope ratios of rock matrix opal samples exhibited an isotopic gradient believed to result from, leaching and reprecipitation of silica at depth. Methods and results can be used to further define primary flowpaths and the movement of water in variably-saturated fractured rock. 71 refs., 23 figs., 3 tabs.

  16. A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrotherm...

    Open Energy Info (EERE)

    through the isotopically lighter volcanic rocks of the caldera fill. Authors Fraser Goff, Harold A. Wollenberg, D. C. Brookins and Ronald W. Kistler Published Journal Journal...

  17. Isotope fractionation in surface ionization ion source of alkaline-earth iodides

    SciTech Connect (OSTI)

    Suzuki, T.; Kanzaki, C.; Nomura, M.; Fujii, Y.

    2012-02-15

    The relationship between the isotope fractionation of alkaline-earth elements in the surface ionization ion source and the evaporation filament current, i.e., filament temperature, was studied. It was confirmed that the isotope fractionation depends on the evaporation filament temperature; the isotope fractionation in the case of higher temperature of filament becomes larger. The ionization and evaporation process in the surface ionization ion source was discussed, and it was concluded that the isotope fractionation is suppressed by setting at the lower temperature of evaporation filament because the dissociations are inhibited on the evaporation filament.

  18. Isotopic Analysis At Seven Mile Hole Area (Larson, Et Al., 2009...

    Open Energy Info (EERE)

    Seven Mile Hole Area (Larson, Et Al., 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Seven Mile Hole Area (Larson, Et...

  19. Preliminary Notice of Violation, MAC Isotopes, LLC- EA- 1998-05

    Broader source: Energy.gov [DOE]

    Issued to MAC Isotopes, LLC, related to a Radioactive Material Release at the Idaho National Engineering and Environmental Laboratory, (1998-05)

  20. LANSCE | Materials Test Station

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos Neutron Science Center lansce.lanl.gov lansce-user-office@lanl.gov phone: 505.665.1010 mesa header Beam Status User Resources Run Cycle Proposals Visit Registration Schedules Experiment Reports User Satisfaction Survey Reviews Users User Office User Program STONE LANSCE User Group News & Media Media Events Profiles Highlights Seminars Activity Reports The Pulse About LANSCE History Leadership LINAC Outreach Affiliations Visiting LANSCE Facilities Isotope Production Facility Lujan

  1. Utilizing Isotopic Uranium Ratios in Groundwater Evaluations at FUSRAP Sites

    SciTech Connect (OSTI)

    Frederick, W.T.; Keil, K.G.; Rhodes, M.C.; Peterson, J.M.; MacDonell, M.M.

    2007-07-01

    The U.S. Army Corps of Engineers Buffalo District is evaluating environmental radioactive contamination at several Formerly Utilized Sites Remedial Action Program (FUSRAP) sites throughout New York, Pennsylvania, Ohio, and Indiana. The investigations follow the process defined in the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA). Groundwater data from the Niagara Falls Storage Site (NFSS) in Lewiston, New York were evaluated for isotopic uranium ratios, specifically uranium-234 versus uranium-238 (U- 234 and U-238, respectively), and the results were presented at Waste Management 2006. Since uranium naturally occurs in all groundwater, it can be difficult to distinguish where low-concentration impacts from past releases differ from the high end of a site-specific natural background range. In natural groundwater, the ratio of U-234 to U-238 exceeds 1 (unity) due to the alpha particle recoil effect, in which U-234 is preferentially mobilized to groundwater from adjacent rock or soil. This process is very slow and may take hundreds to thousands of years before a measurable increase is seen in the natural isotopic ratio. If site releases are the source of uranium being measured in groundwater, the U-234 to U-238 ratio is commonly closer to 1, which normally reflects FUSRAP-related, uranium-contaminated wastes and soils. This lower ratio occurs because not enough residence time has elapsed since the 1940's and 1950's for the alpha particle recoil effect to have significantly altered the contamination-derived ratio. An evaluation of NFSS-specific and regional groundwater data indicate that an isotopic ratio of 1.2 has been identified as a signature value to help distinguish natural groundwater, which may have a broad background range, from zones impacted by past releases. (authors)

  2. SLAC Accelerator Test Facilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FACET & TF Careers & Education Archived FACET User Facility Quick Launch About FACET & Test Facilities Expand About FACET & Test Facilities FACET & Test Facilities User Portal...

  3. CNP_TEST_SUITE

    Energy Science and Technology Software Center (OSTI)

    002854MLTPL00 Automated Nuclear Data Test Suite file:///usr/gapps/CNP_src/us/RR/test_suite_cz/cnp_test_suite

  4. A Method to Distill Hydrogen Isotopes from Lithium | Princeton Plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Lab to Distill Hydrogen Isotopes from Lithium This white paper outlines a method for the removal of tritium and deuterium from liquid lithium. The method is based on rapid or flash vaporization of a lithium jet, using high power electron beam heating. The quantity of lithium to be processed is taken to be 2 metric tonnes (the inventory postulated for the conceptual reactor design outlined in Lithium walls for fusion, also by this author), every 2 days, in order to limit the in-vessel

  5. Tunable dye laser amplifier chain for laser isotope separation

    SciTech Connect (OSTI)

    Grigoriev, Igor' S; D'yachkov, Aleksei B; Labozin, Valerii P; Mironov, Sergei M; Nikulin, Sergei A; Firsov, Valerii A

    2004-05-31

    A tunable dye laser amplifier chain developed for experiments on atomic vapour laser isotope separation (AVLIS) is described. The system, pumped by copper vapour lasers, consists of a master oscillator and an amplifier stage including a preamplifier and three main amplifiers working in the saturation mode. The master oscillator of the stage is a dye laser with a grazing incidence diffraction grating. Longitudinal pumping of the amplifiers is used. The efficiency of the main amplifiers is 50 % - 55 %. The average power of laser radiation at the output of the last amplifier is 100 W. (lasers. amplifiers)

  6. Fast and efficient charge breeding of the Californium rare isotope breeder upgrade electron beam ion source

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ostroumov, P. N.; Barcikowski, A.; Dickerson, C. A.; Perry, A.; Pikin, A. I.; Sharamentov, S. I.; Vondrasek, R. C.; Zinkann, G. P.

    2015-08-28

    The Electron Beam Ion Source (EBIS), developed to breed Californium Rare Isotope Breeder Upgrade (CARIBU) radioactive beams at Argonne Tandem Linac Accelerator System (ATLAS), is being tested off-line. A unique property of the EBIS is a combination of short breeding times, high repetition rates, and a large acceptance. Overall, we have implemented many innovative features during the design and construction of the CARIBU EBIS as compared to the existing EBIS breeders. The off-line charge breeding tests are being performed using a surface ionization source that produces singly charged cesium ions. The main goal of the off-line commissioning is to demonstratemore » stable operation of the EBIS at a 10 Hz repetition rate and a breeding efficiency into single charge state higher than 15%. These goals have been successfully achieved and exceeded. We have measured (20% ± 0.7%) breeding efficiency into the single charge state of 28+ cesium ions with the breeding time of 28 ms. In general, the current CARIBU EBIS operational parameters can provide charge breeding of any ions in the full mass range of periodic table with high efficiency, short breeding times, and sufficiently low charge-to-mass ratio, 1/6.3 for the heaviest masses, for further acceleration in ATLAS. In this study, we discuss the parameters of the EBIS and the charge breeding results in a pulsed injection mode with repetition rates up to 10 Hz.« less

  7. Fast and efficient charge breeding of the Californium rare isotope breeder upgrade electron beam ion source

    SciTech Connect (OSTI)

    Ostroumov, P. N.; Barcikowski, A.; Dickerson, C. A.; Perry, A.; Pikin, A. I.; Sharamentov, S. I.; Vondrasek, R. C.; Zinkann, G. P.

    2015-08-28

    The Electron Beam Ion Source (EBIS), developed to breed Californium Rare Isotope Breeder Upgrade (CARIBU) radioactive beams at Argonne Tandem Linac Accelerator System (ATLAS), is being tested off-line. A unique property of the EBIS is a combination of short breeding times, high repetition rates, and a large acceptance. Overall, we have implemented many innovative features during the design and construction of the CARIBU EBIS as compared to the existing EBIS breeders. The off-line charge breeding tests are being performed using a surface ionization source that produces singly charged cesium ions. The main goal of the off-line commissioning is to demonstrate stable operation of the EBIS at a 10 Hz repetition rate and a breeding efficiency into single charge state higher than 15%. These goals have been successfully achieved and exceeded. We have measured (20% 0.7%) breeding efficiency into the single charge state of 28+ cesium ions with the breeding time of 28 ms. In general, the current CARIBU EBIS operational parameters can provide charge breeding of any ions in the full mass range of periodic table with high efficiency, short breeding times, and sufficiently low charge-to-mass ratio, 1/6.3 for the heaviest masses, for further acceleration in ATLAS. In this study, we discuss the parameters of the EBIS and the charge breeding results in a pulsed injection mode with repetition rates up to 10 Hz.

  8. STATUS OF HIGH FLUX ISOTOPE REACTOR IRRADIATION OF SILICON CARBIDE/SILICON CARBIDE JOINTS

    SciTech Connect (OSTI)

    Katoh, Yutai; Koyanagi, Takaaki; Kiggans, Jim; Cetiner, Nesrin; McDuffee, Joel

    2014-09-01

    Development of silicon carbide (SiC) joints that retain adequate structural and functional properties in the anticipated service conditions is a critical milestone toward establishment of advanced SiC composite technology for the accident-tolerant light water reactor (LWR) fuels and core structures. Neutron irradiation is among the most critical factors that define the harsh service condition of LWR fuel during the normal operation. The overarching goal of the present joining and irradiation studies is to establish technologies for joining SiC-based materials for use as the LWR fuel cladding. The purpose of this work is to fabricate SiC joint specimens, characterize those joints in an unirradiated condition, and prepare rabbit capsules for neutron irradiation study on the fabricated specimens in the High Flux Isotope Reactor (HFIR). Torsional shear test specimens of chemically vapor-deposited SiC were prepared by seven different joining methods either at Oak Ridge National Laboratory or by industrial partners. The joint test specimens were characterized for shear strength and microstructures in an unirradiated condition. Rabbit irradiation capsules were designed and fabricated for neutron irradiation of these joint specimens at an LWR-relevant temperature. These rabbit capsules, already started irradiation in HFIR, are scheduled to complete irradiation to an LWR-relevant dose level in early 2015.

  9. An Evaluation of Activated Bismuth Isotopes in Environmental Samples From the Former Western Pacific Proving Grounds

    SciTech Connect (OSTI)

    Robison, W.L.; Brunk, J.A.; Jokela, T.A.

    2000-03-21

    {sup 207}Bi (t{sub 1/2}=32.2 y) was generated by activation of weapons material during a few ''clean'' nuclear tests at the U.S. Western Pacific Proving Grounds of Enewetak and Bikini Atolls. The radionuclides first appeared in the Enewetak environment during 1958 and in the environment of Bikini during 1956. Crater sediments from Bikini with high levels of {sup 207}Bi were analyzed by gamma spectrometry in an attempt to determine the relative concentrations of {sup 208}Bi (t{sup 1/2} = 3.68 x 10{sup 5} y). The bismuth isotopes were probably generated during the ''clean'', 9.3 Mt Poplar test held on 7/12/58. The atom ratio of {sup 208}Bi to {sup 207}Bi (R value) ranges from {approx}12 to over 200 in sections of core sediments from the largest nuclear crater at Bikini atoll. The presence of bismuth in the device is suggested to account for R values in excess of 10.

  10. Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

    SciTech Connect (OSTI)

    Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

    2005-10-31

    Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

  11. ZiaTest

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ZiaTest ZiaTest Description This test executes a new proposed standard benchmark method ... Specifically, the test consists of the following steps: Record a time stamp for when the ...

  12. test | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    test PDF icon test More Documents & Publications 2009 ECR FINAL REPORT 2010 Final ECR 2008 Report Environmental Conflict Resolution

  13. Utilization of Kinetic Isotope Effects for the Concentration of Tritium

    SciTech Connect (OSTI)

    Brown, Gilbert M.; Meyer, Thomas J.; Moyer, Bruce A.

    2000-06-01

    Work is in progress to develop methods for concentrating tritium in water based on large primary isotope effects in catalytic redox processes. Basic research is being conducted to develop the chemistry of a complete cyclic process. The process will remove tritium from H2O by concentrating it with respect to protio-water. This research involves developing chemical cycles that produce high concentration factors for HTO based on the discrimination of CH and C-T bonds in oxidation reactions. Several steps are required in a cyclic process for the concentration of tritium in water. In the first step, the tritium is incorporated in an organic compound. H-T discrimination occurs as the tritium containing compound is oxidized in a step involving a Ru(IV) oxo complex. Strong primary kinetic isotope effects lead to the oxidation of C-H bonds in preference to C-T bonds, and this reaction leads to concentration of tritium in the organic compound. The reduced form of the ruthenium compound can be reoxidized so that the oxidation step can be made catalytic.

  14. Stable isotope, site-specific mass tagging for protein identification

    DOE Patents [OSTI]

    Chen, Xian

    2006-10-24

    Proteolytic peptide mass mapping as measured by mass spectrometry provides an important method for the identification of proteins, which are usually identified by matching the measured and calculated m/z values of the proteolytic peptides. A unique identification is, however, heavily dependent upon the mass accuracy and sequence coverage of the fragment ions generated by peptide ionization. The present invention describes a method for increasing the specificity, accuracy and efficiency of the assignments of particular proteolytic peptides and consequent protein identification, by the incorporation of selected amino acid residue(s) enriched with stable isotope(s) into the protein sequence without the need for ultrahigh instrumental accuracy. Selected amino acid(s) are labeled with .sup.13C/.sup.15N/.sup.2H and incorporated into proteins in a sequence-specific manner during cell culturing. Each of these labeled amino acids carries a defined mass change encoded in its monoisotopic distribution pattern. Through their characteristic patterns, the peptides with mass tag(s) can then be readily distinguished from other peptides in mass spectra. The present method of identifying unique proteins can also be extended to protein complexes and will significantly increase data search specificity, efficiency and accuracy for protein identifications.

  15. Couplings between dipole and quadrupole vibrations in tin isotopes

    SciTech Connect (OSTI)

    Simenel, C.; Chomaz, Ph.

    2009-12-15

    We study the couplings between collective vibrations such as the isovector giant dipole and isoscalar giant quadrupole resonances in tin isotopes in the framework of the time-dependent Hartree-Fock theory with a Skyrme energy density functional. These couplings are a source of anharmonicity in the multiphonon spectrum. In particular, the residual interaction is known to couple the isovector giant dipole resonance with the isoscalar giant quadrupole resonance built on top of it, inducing a nonlinear evolution of the quadrupole moment after a dipole boost. This coupling also affects the dipole motion in a nucleus with a static or dynamical deformation induced by a quadrupole constraint or boost, respectively. Three methods associated with these different manifestations of the coupling are proposed to extract the corresponding matrix elements of the residual interaction. Numerical applications of the different methods to {sup 132}Sn are in good agreement with each other. Finally, several tin isotopes are considered to investigate the role of isospin and mass number on this coupling. A simple 1/A dependence of the residual matrix elements is found with no noticeable contribution from the isospin. This result is interpreted within the Goldhaber-Teller model.

  16. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  17. Liquid-phase thermal diffusion isotope separation apparatus and method having tapered column

    DOE Patents [OSTI]

    Rutherford, W.M.

    1985-12-04

    A thermal diffusion counterflow method and apparatus for separating isotopes in solution in which the solution is confined in a long, narrow, vertical slit which tapers from bottom to top. The variation in the width of the slit permits maintenance of a stable concentration distribution with relatively long columns, thus permitting isotopic separation superior to that obtained in the prior art.

  18. Liquid-phase thermal diffusion isotope separation apparatus and method having tapered column

    DOE Patents [OSTI]

    Rutherford, William M.

    1988-05-24

    A thermal diffusion counterflow method and apparatus for separating isotopes in solution in which the solution is confined in a long, narrow, vertical slit which tapers from bottom to top. The variation in the width of the slit permits maintenance of a stable concentration distribution with relatively long columns, thus permitting isotopic separation superior to that obtainable in the prior art.

  19. High Specific Activity Sn-117m by Post Irradiation Isotope Separation

    SciTech Connect (OSTI)

    DAuria, John

    2015-04-16

    ElectroMagnetic Isotope Separation (EMIS) is used in the production of enriched stable isotopes. We demonstrated the feasibility of using EMIS to produce medium Specific Activity 117mSm using high purity 116Sn target material irradiated in a high flux reactor.

  20. EIS-0136: Special Isotope Separation Project Idaho National Engineering Laboratory, Idaho Falls, Idaho

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this EIS to provide environmental input to the decision to construct the Special Isotope Separation Project, which would allow for the processing of existing fuel-grade plutonium into weapons-grade plutonium using the Atomic Laser Isotope Separation process.

  1. Significance of Isotopically Labile Organic Hydrogen in Thermal Maturation of Organic Matter

    SciTech Connect (OSTI)

    Arndt Schimmelmann; Maria Mastalerz

    2010-03-30

    Isotopically labile organic hydrogen in fossil fuels occupies chemical positions that participate in isotopic exchange and in chemical reactions during thermal maturation from kerogen to bitumen, oil and gas. Carbon-bound organic hydrogen is isotopically far less exchangeable than hydrogen bound to nitrogen, oxygen, or sulfur. We explore why organic hydrogen isotope ratios express a relationship with organic nitrogen isotope ratios in kerogen at low to moderate maturity. We develop and apply new techniques to utilize organic D/H ratios in organic matter fractions and on a molecular level as tools for exploration for fossil fuels and for paleoenvironmental research. The scope of our samples includes naturally and artificially matured substrates, such as coal, shale, oil and gas.

  2. Methods for separating medical isotopes using ionic liquids

    DOE Patents [OSTI]

    Luo, Huimin; Boll, Rose Ann; Bell, Jason Richard; Dai, Sheng

    2014-10-21

    A method for extracting a radioisotope from an aqueous solution, the method comprising: a) intimately mixing a non-chelating ionic liquid with the aqueous solution to transfer at least a portion of said radioisotope to said non-chelating ionic liquid; and b) separating the non-chelating ionic liquid from the aqueous solution. In preferred embodiments, the method achieves an extraction efficiency of at least 80%, or a separation factor of at least 1.times.10.sup.4 when more than one radioisotope is included in the aqueous solution. In particular embodiments, the method is applied to the separation of medical isotopes pairs, such as Th from Ac (Th-229/Ac-225, Ac-227/Th-227), or Ra from Ac (Ac-225 and Ra-225, Ac-227 and Ra-223), or Ra from Th (Th-227 and Ra-223, Th-229 and Ra-225).

  3. Intruder states in odd-mass Ag isotopes

    SciTech Connect (OSTI)

    Rogowski, J.; Alstad, J.; Brant, S.; Daniels, W.R.; De Frenne, D.; Heyde, K.; Jacobs, E.; Kaffrell, N.; Paar, V.; Skarnemark, G.; Trautmann, N. (Institut fuer Kernchemie, Universitaet Mainz, D-6500 Mainz (Federal Republic of Germany) Department of Chemistry, University of Oslo, N-0315 Oslo (Norway) Prirodoslovno-matematicki fakultet, University of Zagreb, 41000 Zagreb (Yugoslavia) Los Alamos National Laboratory, Los Alamos, NM (USA) Laboratorium voor Kernfysica, Proeftuinstraat 86, B-9000 Gent (Belgium) Department of Nuclear Chemistry, Chalmers University of Technology, S-41296 Goeteborg (Sweden))

    1990-12-01

    The information on the coexistence of deformed intruder states and normal spherical hole-core coupled states in odd-mass Ag nuclei has been extended to the neutron-rich isotopes {sup 113}Ag{sub 66} and {sup 115}Ag{sub 68}. Data have been obtained from an investigation of the {gamma} rays following the {beta}{sup {minus}} decay of the {sup 113,115}Pd precursors. A minimum for the excitation energy of the intruder states occurs in {sup 113}Ag{sub 66}, exactly at neutron midshell. The properties of the intruder states in {sup 109,111,113,115}Ag are discussed and a description in the framework of the interacting-boson-fermion model is presented.

  4. Isotopic generator for bismuth-212 and lead-212 from radium

    DOE Patents [OSTI]

    Atcher, Robert W. (Kensington, MD); Friedman, Arnold M. (Park Forest, IL); Hines, John (Glen Ellyn, IL)

    1987-01-01

    A method and apparatus for providing radionuclides of bismuth-212 and lead-212. Thorium-228 and carrier solution starting material is input to a radiologically contained portion of an isotopic generator system, and radium-224 is separated from thorium-228 which is retained by a strongly basic anion exchange column. The separated radium-224 is transferred to an accessible, strongly acidic cationic exchange column. The cationic column retains the radium-224, and natural radioactive decay generates bismuth-212 and lead-212. The cationic exchange column can also be separated from the contained portion of the system and utilized without the extraordinary safety measures necessary in the contained portion. Furthermore, the cationic exchange column provides over a relatively long time period the short lived lead-212 and bismuth-212 radionuclides which are useful for a variety of medical therapies.

  5. Performance and safety parameters for the high flux isotope reactor

    SciTech Connect (OSTI)

    Ilas, G. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831-6172 (United States); Primm III, T. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831-6172 (United States); Primm Consulting, LLC, 945 Laurel Hill Road, Knoxville, TN 37923 (United States)

    2012-07-01

    A Monte Carlo depletion model for the High Flux Isotope Reactor (HFIR) Cycle 400 and its use in calculating parameters of relevance to the reactor performance and safety during the reactor cycle are presented in this paper. This depletion model was developed to serve as a reference for the design of a low-enriched uranium (LEU) fuel for an ongoing study to convert HFIR from high-enriched uranium (HEU) to LEU fuel; both HEU and LEU depletion models use the same methodology and ENDF/B-VII nuclear data as discussed in this paper. The calculated HFIR Cycle 400 parameters, which are compared with measurement data from critical experiments performed at HFIR, data included in the HFIR Safety Analysis Report (SAR), or data reported by previous calculations, provide a basis for verification or updating of the corresponding SAR data. (authors)

  6. Performance and Safety Parameters for the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    Ilas, Germina [ORNL; Primm, Trent [Primm Consulting, LLC

    2012-01-01

    A Monte Carlo depletion model for the High Flux Isotope Reactor (HFIR) Cycle 400 and its use in calculating parameters of relevance to the reactor performance and safety during the reactor cycle are presented in this paper. This depletion model was developed to serve as a reference for the design of a low-enriched uranium (LEU) fuel for an ongoing study to convert HFIR from high-enriched uranium (HEU) to LEU fuel; both HEU and LEU depletion models use the same methodology and ENDV/B-VII nuclear data as discussed in this paper. The calculated HFIR Cycle 400 parameters, which are compared when available with measurement data from critical experiments performed at HFIR, data included in the HFIR Safety Analysis Report (SAR), or data reported by previous calculations, provide a basis for verification or updating of the corresponding SAR data.

  7. Utilizing Isotopic Uranium Ratios in Groundwater Evaluations at NFSS

    SciTech Connect (OSTI)

    Rhodes, M.C.; Keil, K.G.; Frederick, W.T.; Papura, T.R.; Leithner, J.S.; Peterson, J.M.; MacDonell, M.M.

    2006-07-01

    The U.S. Army Corps of Engineers (USACE) Buffalo District is currently evaluating environmental contamination at the Niagara Falls Storage Site (NFSS) under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) as part of its Formerly Utilized Sites Remedial Action Program (FUSRAP). The NFSS is located in the Town of Lewiston in western New York and has been used to store uranium-contaminated materials since 1944. Most of the radioactive materials are currently contained in an on-site structure, but past contamination remains in soil and groundwater. As a naturally occurring radionuclide, uranium is present in all groundwater. Because contamination levels at the site are quite low, it can be difficult to distinguish zones that have been impacted by the past releases from those at the high end of the natural background range. The differences in the isotopic ratio of uranium-234 (U-234) to uranium-238 (U-238) between natural groundwater systems and affected areas are being used in an innovative way to better define the nature and extent of groundwater contamination at NFSS. In natural groundwater, the ratio of U-234 to U-238 exceeds 1 due to the alpha particle recoil effect, in which U-234 is preferentially mobilized to groundwater from adjacent rock or soil. This process is very slow, and it can be hundreds to thousands of years before a measurable impact is seen in the isotopic ratio. Thus, as a result of the recoil effect, the ratio of U-234 to U-238 will be higher in natural groundwater than in contaminated groundwater. This means that if site releases were the source of the uranium being measured in groundwater at NFSS, the ratio of U-234 to U-238 would be expected to be very close to 1 (the same ratio that exists in wastes and soil at the site), because not enough time has elapsed for the alpha particle recoil effect to have significantly altered that ratio. From an evaluation of site and regional groundwater data, an isotopic ratio of 1.2 has been identified as a site-specific signature to help distinguish natural groundwater (e.g., at the high end of the background range) from zones impacted by past releases. This information is crucial for focusing the ongoing CERCLA evaluation and decision making process. This signature value is not applied as a bright line, e.g., to define samples with ratios of U-234 to U-238 above 1.2 as representing background and those with ratios below 1.2 as being affected by site releases. Rather, this ratio serves as a weight of evidence for use in conjunction with other site information, including historical activities, to form science-based decisions regarding contaminated groundwater. This novel approach for developing a groundwater signature from the isotopic uranium ratio has proven to be a very useful tool for NFSS, and it is now being considered for broader application. (authors)

  8. Cryogenic distribution for the Facility for Rare Isotope Beams

    SciTech Connect (OSTI)

    S. Jones, Dana Arenius, Adam Fila, P. Geutschow, Helmut Laumer, Matt Johnson, Cory S. Waltz, J. G. Weisend II

    2012-06-01

    The Facility for Rare Isotope Beams (FRIB) is a new National User Facility for nuclear science funded by the Department of Energy Office of Science and operated by Michigan State University. The FRIB accelerator linac consists of superconducting radio-frequency (SCRF) cavities operating at 2 K and SC magnets operating at 4.5 K all cooled by a large scale cryogenic refrigeration system. A major subsystem of the cryogenic system will be the distribution system whose primary components will include a distribution box, the transfer lines and the interconnect valve boxes at each cryogenic device. An overview of the conceptual design of the distribution system including engineering details, capabilities and schedule is described.

  9. CRYOGENIC ADSORPTION OF HYDROGEN ISOTOPES OVER NANO-STRUCTURED MATERIALS

    SciTech Connect (OSTI)

    Xiao, S.; Heung, L.

    2010-10-07

    Porous materials such as zeolites, activated carbon, silica gels, alumina and a number of industrial catalysts are compared and ranked for hydrogen and deuterium adsorption at liquid nitrogen temperature. All samples show higher D{sub 2} adsorption than that of H{sub 2}, in which a HY sample has the greatest isotopic effect while 13X has the highest hydrogen uptake capacity. Material's moisture content has significant impact to its hydrogen uptake. A material without adequate drying could result in complete loss of its adsorption capacity. Even though some materials present higher H{sub 2} adsorption capacity at full pressure, their adsorption at low vapor pressure may not be as good as others. Adsorption capacity in a dynamic system is much less than in a static system. A sharp desorption is also expected in case of temperature upset.

  10. Ion extraction and charge exchange in laser isotope separation

    SciTech Connect (OSTI)

    Hostein, D.; Doneddu, F.

    1996-02-01

    In the atomic vapor laser isotope separation (AVLIS) process, a vapor is ionized by pulsed laser beams, and the ions are extracted by negatively biased collectors. The authors compute the unsteady dynamics of the photoplasma using a two-dimensional (2-D) particle-in-cell (PIC) code. Collisions between ions and neutral species are simulated by a Monte Carlo technique. The plasma dynamics is visualized by snapshots of particle positions showing the directions of their velocities. The three kinds of particles (electrons, photo-ions, and ions created by charge exchange) are marked by different colors. The graphic outputs illustrate the motion of the electrons toward the anodes, the vertical drift of the plasma, its erosion by the transient ion sheath, and nonselective ionization by charge exchange.

  11. Application of computational fluid dynamics for the simulation of cryogenic molecular sieve bed absorber of hydrogen isotopes recovery system for Indian LLCB-TBM

    SciTech Connect (OSTI)

    Gayathri Devi, V.; Sircar, A.; Sarkar, B.

    2015-03-15

    One of the most challenging tasks in the design of the fuel cycle system lies in the effective design of Tritium Extraction System (TES) which involves proper extraction and purification of tritium in the fuel cycle of the fusion reactor. Indian Lead Lithium cooled Ceramic Breeder Test Blanket Module (LLCB-TBM) would extract hydrogen isotopes through Cryogenic Molecular Sieve Bed (CMSB) adsorber system. A prototype Hydrogen Isotopes Recovery System (HIRS) is being developed to validate the concepts for tritium extraction by adsorption mass transfer mechanism. In this study, a design model has been developed and analyzed to simulate the adsorption mass transfer kinetics in a fixed bed adsorption column. The simulation leads primarily to effective design of HIRS, which is a state-of-the-art technology. The paper describes the process simulation approach and the results of Computational Fluid Dynamics (CFD) analysis. The effects of different operating conditions are studied to investigate their influence on the hydrogen isotopes adsorption capacity. The results of the present simulation study would be used to understand the best optimized transport phenomenon before realizing the TES as a system for LLCB-TBM. (authors)

  12. Vendor System Vulnerability Testing Test Plan

    SciTech Connect (OSTI)

    James R. Davidson

    2005-01-01

    The Idaho National Laboratory (INL) prepared this generic test plan to provide clients (vendors, end users, program sponsors, etc.) with a sense of the scope and depth of vulnerability testing performed at the INLs Supervisory Control and Data Acquisition (SCADA) Test Bed and to serve as an example of such a plan. Although this test plan specifically addresses vulnerability testing of systems applied to the energy sector (electric/power transmission and distribution and oil and gas systems), it is generic enough to be applied to control systems used in other critical infrastructures such as the transportation sector, water/waste water sector, or hazardous chemical production facilities. The SCADA Test Bed is established at the INL as a testing environment to evaluate the security vulnerabilities of SCADA systems, energy management systems (EMS), and distributed control systems. It now supports multiple programs sponsored by the U.S. Department of Energy, the U.S. Department of Homeland Security, other government agencies, and private sector clients. This particular test plan applies to testing conducted on a SCADA/EMS provided by a vendor. Before performing detailed vulnerability testing of a SCADA/EMS, an as delivered baseline examination of the system is conducted, to establish a starting point for all-subsequent testing. The series of baseline tests document factory delivered defaults, system configuration, and potential configuration changes to aid in the development of a security plan for in depth vulnerability testing. The baseline test document is provided to the System Provider,a who evaluates the baseline report and provides recommendations to the system configuration to enhance the security profile of the baseline system. Vulnerability testing is then conducted at the SCADA Test Bed, which provides an in-depth security analysis of the Vendors system.b a. The term System Provider replaces the name of the company/organization providing the system being evaluated. This can be the system manufacturer, a system user, or a third party organization such as a government agency. b. The term Vendor (or Vendors) System replaces the name of the specific SCADA/EMS being tested.

  13. Utilization of Kinetic Isotope Effects for the Concentration of Tritium

    SciTech Connect (OSTI)

    Brown, Gilbert M.; Meyer, Thomas j.; Moyer, Bruce A.

    1999-06-01

    The objective of this research program is to develop methods for concentrating tritium in water based on large primary isotope effects in catalytic redox processes. Basic research is being conducted to develop the chemistry of a complete cyclic process. Because tritium (generally present as HTO) is in a rapidly established equilibrium with protio-water, it moves with groundwater and separation from water cannot be achieved by the usual pump-and-treat methods using sorbants. The general methodology developed in this work will be applicable to a number of DOE waste streams, and as a consequence of the process tritium will be incorporated into an organic compound that will not readily exchange the tritium with groundwater. The process to be developed will remove tritium from H2O by concentrating it with respect to protio-water. This research involves developing chemical cycles that produce high concentration factors for HTO and T2O based on the discrimination of C-H and C-T bonds in oxidation reactions. Several steps are required in a cyclic process for the concentration of tritium in water. In the first step the tritium is incorporated in an organic compound. H-T discrimination occurs as the tritium containing compound is oxidized in a step involving a Ru(IV) oxo complex. Strong primary kinetic isotope effects lead to the oxidation of C-H bonds in preference to C-T bonds, and this reaction leads to concentration of tritium in the organic compound. The reduced form of the ruthenium compound can be reoxidized so that the oxidation step can be made catalytic.

  14. Small Stirling dynamic isotope power system for robotic space missions

    SciTech Connect (OSTI)

    Bents, D.J.

    1992-08-01

    The design of a multihundred-watt Dynamic Isotope Power System (DIPS), based on the US Department of Energy (DOE) General Purpose Heat Source (GPHS) and small (multihundred-watt) free-piston Stirling engine (FPSE), is being pursued as a potential lower cost alternative to radioisotope thermoelectric generators (RTG's). The design is targeted at the power needs of future unmanned deep space and planetary surface exploration missions ranging from scientific probes to Space Exploration Initiative precursor missions. Power level for these missions is less than a kilowatt. The incentive for any dynamic system is that it can save fuel and reduce costs and radiological hazard. Unlike DIPS based on turbomachinery conversion (e.g. Brayton), this small Stirling DIPS can be advantageously scaled to multihundred-watt unit size while preserving size and mass competitiveness with RTG's. Stirling conversion extends the competitive range for dynamic systems down to a few hundred watts--a power level not previously considered for dynamic systems. The challenge for Stirling conversion will be to demonstrate reliability and life similar to RTG experience. Since the competitive potential of FPSE as an isotope converter was first identified, work has focused on feasibility of directly integrating GPHS with the Stirling heater head. Thermal modeling of various radiatively coupled heat source/heater head geometries has been performed using data furnished by the developers of FPSE and GPHS. The analysis indicates that, for the 1050 K heater head configurations considered, GPHS fuel clad temperatures remain within acceptable operating limits. Based on these results, preliminary characterizations of multihundred-watt units have been established.

  15. Beta-decay measurements of neutron-deficient cesium isotopes

    SciTech Connect (OSTI)

    Parry, R.F.

    1983-03-01

    Beta decay endpoint energy measurements of the neutron deficient cesium isotopes were done using an energy spectrum shape fitting technique. This was a departure from the typical method of endpoint energy analysis, the Fermi-Kurie plot. A discussion of the shape fitting procedure and its improved features are discussed. These beta endpoint measurements have led to total decay energies (Q/sub EC/) of the neutron deficient /sup 119/ /sup 123/Cs isotopes. The total decay energies of /sup 122m/Cs (Q/sub EC/ = 6.95 +- 0.25 MeV) and /sup 119/Cs (Q/sub EC/ = 6.26 +- 0.29 MeV) were new measurements. The total decay energies of /sup 123/Cs (Q/sub EC/ = 4.05 +- 0.18 MeV), /sup 122g/Cs (Q/sub EC/ = 7.05 +- 0.18 MeV), /sup 121/Cs (Q/sub EC/ = 5.21 +- 0.22 MeV), and /sup 120/Cs (Q/sub EC/ = 7.38 +- 0.23 MeV) were measurements with significantly improved uncertainties as compared to the literature. Further, a combination of the energy levels derived from previous literature gamma-gamma coincident measurements and the experimental beta-coincident gamma decay energies has supported an improved level scheme for /sup 121/Xe and the proposal of three new energy levels in /sup 119/Xe. Comparison of the experimental cesium mass excesses (determined with our Q/sub EC/ values and known xenon mass excesses) with both the literature and theoretical predicted values showed general agreement except for /sup 120/Cs. Possible explanations for this deviation are discussed.

  16. Hanford isotope project strategic business analysis yttrium-90 (Y-90)

    SciTech Connect (OSTI)

    1995-10-01

    The purpose of this analysis is to address the short-term direction for the Hanford yttrium-90 (Y-90) project. Hanford is the sole DOE producer of Y-90, and is the largest repository for its source in this country. The production of Y-90 is part of the DOE Isotope Production and Distribution (IP and D) mission. The Y-90 is ``milked`` from strontium-90 (Sr-90), a byproduct of the previous Hanford missions. The use of Sr-90 to produce Y-90 could help reduce the amount of waste material processed and the related costs incurred by the clean-up mission, while providing medical and economic benefits. The cost of producing Y-90 is being subsidized by DOE-IP and D due to its use for research, and resultant low production level. It is possible that the sales of Y-90 could produce full cost recovery within two to three years, at two curies per week. Preliminary projections place the demand at between 20,000 and 50,000 curies per year within the next ten years, assuming FDA approval of one or more of the current therapies now in clinical trials. This level of production would incentivize private firms to commercialize the operation, and allow the government to recover some of its sunk costs. There are a number of potential barriers to the success of the Y-90 project, outside the control of the Hanford Site. The key issues include: efficacy, Food and Drug Administration (FDA) approval and medical community acceptance. There are at least three other sources for Y-90 available to the US users, but they appear to have limited resources to produce the isotope. Several companies have communicated interest in entering into agreements with Hanford for the processing and distribution of Y-90, including some of the major pharmaceutical firms in this country.

  17. Innovative lasers for uranium isotope separation. [Progress report

    SciTech Connect (OSTI)

    Brake, M.L.; Gilgenbach, R.M.

    1991-06-01

    Copper vapor lasers have important applications to uranium atomic vapor laser isotope separation (AVLIS). The authors have spent the first two years of their project investigating two innovative methods of exciting/pumping copper vapor lasers which have the potential to improve the efficiency and scaling of large laser systems used in uranium isotope separation. Experimental research has focused on the laser discharge kinetics of (1) microwave, and (2) electron beam excitation/pumping of large-volume copper vapor lasers. During the first year, the experiments have been designed and constructed and initial data has been taken. During the second year these experiments have been diagnosed. Highlights of some of the second year results as well as plans for the future include the following: Microwave resonant cavity produced copper vapor plasmas at 2.45 GHz, have been investigated. A CW (0--500 W) signal heats and vaporizes the copper chloride to provide the atomic copper vapor. A pulsed (5 kW, 0.5--5kHz) signal is added to the incoming CW signal via a hybrid mixer to excite the copper states to the laser levels. An enhancement of the visible radiation has been observed during the pulsed pardon of the signal. Electrical probe measurements have been implemented on the system to verify the results of the electromagnetic model formulated last year. Laser gain measurements have been initiated with the use of a commercial copper vapor laser. Measurements of the spatial profile of the emission are also currently being made. The authors plan to increase the amount of pulsed microwave power to the system by implementing a high power magnetron. A laser cavity will be designed and added to this system.

  18. ZEST flight test experiments, Kauai Test Facility, Hawaii. Test report

    SciTech Connect (OSTI)

    Cenkci, M.J.

    1991-07-01

    The Strategic Defense Initiative Organization (SDIO) is proposing to execute two ZEST flight experiments to obtain information related to the following objectives: validation of payload modeling; characterization of a high energy release cloud; and documentation of scientific phenomena that may occur as a result of releasing a high energy cloud. The proposed action is to design, develop, launch, and detonate two payloads carrying high energy explosives. Activities required to support this proposal include: (1) execution of component assembly tests at Space Data Division (SDD) in Chandler, Arizona and Los Alamos National Laboratory (LANL) in Los Alamos, New Mexico, and (2) execution of pre-flight flight test activities at Kauai Test Facility.

  19. Phase II: Field Detector Development For Undeclared/Declared Nuclear Testing For Treaty Verfiation Monitoring

    SciTech Connect (OSTI)

    Kriz, M.; Hunter, D.; Riley, T.

    2015-10-02

    Radioactive xenon isotopes are a critical part of the Comprehensive Nuclear Test Ban Treaty (CTBT) for the detection or confirmation of nuclear weapons tests as well as on-site treaty verification monitoring. On-site monitoring is not currently conducted because there are no commercially available small/robust field detector devices to measure the radioactive xenon isotopes. Xenon is an ideal signature to detect clandestine nuclear events since they are difficult to contain and can diffuse and migrate through soils due to their inert nature. There are four key radioxenon isotopes used in monitoring: 135Xe (9 hour half-life), 133mXe (2 day half-life), 133Xe (5 day half-life) and 131mXe (12 day half-life) that decay through beta emission and gamma emission. Savannah River National Laboratory (SRNL) is a leader in the field of gas collections and has developed highly selective molecular sieves that allow for the collection of xenon gas directly from air. Phase I assessed the development of a small, robust beta-gamma coincidence counting system, that combines collection and in situ detection methodologies. Phase II of the project began development of the custom electronics enabling 2D beta-gamma coincidence analysis in a field portable system. This will be a significant advancement for field detection/quantification of short-lived xenon isotopes that would not survive transport time for laboratory analysis.

  20. Major Partner Test Sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Test Partners Once a technology is ready to be tested at pilot or commercial scale, the cost of building a test facility becomes significant -- often beyond the funding ...

  1. Test | Open Energy Information

    Open Energy Info (EERE)

    Test Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Test Published Publisher Not Provided, Date Not Provided Report Number Test DOI Not Provided Check...

  2. Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power

    SciTech Connect (OSTI)

    Melius, C F; Foltz, G W

    1987-01-01

    A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  3. Chromium Isotope Fractionation During Reduction of Cr(VI) Under Saturated Flow Conditions

    SciTech Connect (OSTI)

    Jamieson-Hanes, Julia H.; Gibson, Blair D.; Lindsay, Matthew B.J.; Kim, Yeongkyoo; Ptacek, Carol J.; Blowes, David W.

    2012-10-25

    Chromium isotopes are potentially useful indicators of Cr(VI) reduction reactions in groundwater flow systems; however, the influence of transport on Cr isotope fractionation has not been fully examined. Laboratory batch and column experiments were conducted to evaluate isotopic fractionation of Cr during Cr(VI) reduction under both static and controlled flow conditions. Organic carbon was used to reduce Cr(VI) in simulated groundwater containing 20 mg L{sup -1} Cr(VI) in both batch and column experiments. Isotope measurements were performed on dissolved Cr on samples from the batch experiments, and on effluent and profile samples from the column experiment. Analysis of the residual solid-phase materials by scanning electron microscopy (SEM) and by X-ray absorption near edge structure (XANES) spectroscopy confirmed association of Cr(III) with organic carbon in the column solids. Decreases in dissolved Cr(VI) concentrations were coupled with increases in {delta}{sup 53}Cr, indicating that Cr isotope enrichment occurred during reduction of Cr(VI). The {delta}{sup 53}Cr data from the column experiment was fit by linear regression yielding a fractionation factor ({alpha}) of 0.9979, whereas the batch experiments exhibited Rayleigh-type isotope fractionation ({alpha} = 0.9965). The linear characteristic of the column {delta}{sup 53}Cr data may reflect the contribution of transport on Cr isotope fractionation.

  4. Central Receiver Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Receiver Test Facility - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us ... Applications National Solar Thermal Test Facility Nuclear Energy Systems ...

  5. NREL: Wind Research - Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing Photo of a large wind turbine blade sticking out of the structural testing laboratory; it is perpendicular to a building at the National Wind Technology Center. A...

  6. Limited Test Ban Treaty

    National Nuclear Security Administration (NNSA)

    Detection System (USNDS), which monitors compliance with the international Limited Test Ban Treaty (LTBT). The LTBT, signed by 108 countries, prohibits nuclear testing in the...

  7. OMB MPI Tests

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OMB MPI Tests OMB MPI Tests Description The Ohio MicroBenchmark suite is a collection of independent MPI message passing performance microbenchmarks developed and written at The...

  8. Development of a fast cyclotron gas stopper for intense rare isotope beams from projectile fragmentation: Study of ion extraction with a radiofrequency carpet

    SciTech Connect (OSTI)

    Bollen, Georg; Morrissey, David

    2011-01-16

    Research and development has been performed in support of the design of a future rare isotope beam facility in the US. An important aspect of plans for earlier RIA (Rare Isotope Accelerator) and a requirement of FRIB (Facility of Rare Isotope Beams) to be built at Michigan State University are the availability of so-called stopped beams for research that contributes to answering questions like how elements in the universe are created and to provide better insight into the nature of Fundamental Interactions. In order to create stopped beams techniques are required that transform fast rare isotopes beams as they are available directly after addresses questions like the origin of that will allow and High priority is given to the evaluation of intensity limitations and the efficiency of stopping of fast fragment beams in gas cells and to the exploration of options to increase the efficiency and the reduction of space charge effects. Systematic studies performed at MSU as part of the RIA R&D with a linear gas cell under conditions close to those expected at RIA and related simulations confirm that the efficiency of stopping and extracting ions decreases with increasing beam intensity. Similar results have also been observed at RIKEN in Japan. These results indicate the concepts presently under study will not be able to cover the full range of intensities of fast beams expected at RIA without major losses. The development of a more robust concept is therefore critical to the RIA concept. Recent new beam simulation studies performed at the NSCL show that the stopping of heavy ions in a weakly focusing gas-filled magnetic field can overcome the intensity limitation of present systems while simultaneously providing a much faster ion extraction. We propose to design and build such a cyclotron gas stopper and to test it at the NSCL under conditions as close as possible to those found at RIA.

  9. Delivery of completed irradiation vehicles and the quality assurance document to the High Flux Isotope Reactor for irradiation

    SciTech Connect (OSTI)

    Petrie, Christian M.; McDuffee, Joel Lee; Katoh, Yutai; Terrani, Kurt A.

    2015-10-01

    This report details the initial fabrication and delivery of two Fuel Cycle Research and Development (FCRD) irradiation capsules (ATFSC01 and ATFSC02), with associated quality assurance documentation, to the High Flux Isotope Reactor (HFIR). The capsules and documentation were delivered by September 30, 2015, thus meeting the deadline for milestone M3FT-15OR0202268. These irradiation experiments are testing silicon carbide composite tubes in order to obtain experimental validation of thermo-mechanical models of stress states in SiC cladding irradiated under a prototypic high heat flux. This document contains a copy of the completed capsule fabrication request sheets, which detail all constituent components, pertinent drawings, etc., along with a detailed summary of the capsule assembly process performed by the Thermal Hydraulics and Irradiation Engineering Group (THIEG) in the Reactor and Nuclear Systems Division (RNSD). A complete fabrication package record is maintained by the THIEG and is available upon request.

  10. DESIGN STUDY FOR A LOW-ENRICHED URANIUM CORE FOR THE HIGH FLUX ISOTOPE REACTOR, ANNUAL REPORT FOR FY 2010

    SciTech Connect (OSTI)

    Cook, David Howard; Freels, James D; Ilas, Germina; Jolly, Brian C; Miller, James Henry; Primm, Trent; Renfro, David G; Sease, John D; Pinkston, Daniel

    2011-02-01

    This report documents progress made during FY 2010 in studies of converting the High Flux Isotope Reactor (HFIR) from high enriched uranium (HEU) fuel to low enriched uranium (LEU) fuel. Conversion from HEU to LEU will require a change in fuel form from uranium oxide to a uranium-molybdenum alloy. With axial and radial grading of the fuel foil and an increase in reactor power to 100 MW, calculations indicate that the HFIR can be operated with LEU fuel with no degradation in performance to users from the current level. Studies are reported of support to a thermal hydraulic test loop design, the implementation of finite element, thermal hydraulic analysis capability, and infrastructure tasks at HFIR to upgrade the facility for operation at 100 MW. A discussion of difficulties with preparing a fuel specification for the uranium-molybdenum alloy is provided. Continuing development in the definition of the fuel fabrication process is described.

  11. Simple interpretation of shape evolution in Pt isotopes without intruder states

    SciTech Connect (OSTI)

    McCutchan, E.A.; Casten, R.F.; Zamfir, N.V.

    2005-06-01

    The most commonly accepted interpretation of the light Pt isotopes invokes the coexistence and mixing with proton intruder states from above the Z = 82 shell gap. Using an alternative description, interacting boson model (IBA) calculations are performed for the Pt isotopes with a simple, single configuration, two-parameter Hamiltonian. Excellent agreement is obtained for energies and electromagnetic transition strengths over the entire isotopic chain, spanning a wide variety of structures, and suggesting that these nuclei can be described more simply without the introduction of an intruder configuration. The Pt nuclei close to midshell are found to lie close to a region of phase/shape coexistence.

  12. Application of the Isotope Ratio Method to a Boiling Water Reactor

    SciTech Connect (OSTI)

    Frank, Douglas P.; Gerlach, David C.; Gesh, Christopher J.; Hurley, David E.; Meriwether, George H.; Mitchell, Mark R.; Reid, Bruce D.

    2010-08-11

    The isotope ratio method is a technique for estimating the energy or plutonium production in a fission reactor by measuring isotope ratios in non-fuel reactor components. The isotope ratios in these components can then be directly related to the cumulative energy production with standard reactor modeling methods. All reactor materials contain trace elemental impurities at parts per million levels, and the isotopes of these elements are transmuted by neutron irradiation in a predictable manner. While measuring the change in a particular isotopes concentration is possible, it is difficult to correlate to energy production because the initial concentration of that element may not be accurately known. However, if the ratio of two isotopes of the same element can be measured, the energy production can then be determined without knowing the absolute concentration of that impurity since the initial natural ratio is known. This is the fundamental principle underlying the isotope ratio method. Extremely sensitive mass-spectrometric methods are currently available that allow accurate measurements of the impurity isotope ratios in samples. Additionally, indicator elements with stable activation products have been identified so that their post-irradiation isotope ratios remain constant. This method has been successfully demonstrated on graphite-moderated reactors. Graphite reactors are particularly well-suited to such analyses since the graphite moderator is resident in the fueled region of the core for the entire period of operation. Applying this method to other reactor types is more difficult since the resident portions of the reactor available for sampling are either outside the fueled region of the core or structural components of individual fuel assemblies. The goal of this research is to show that the isotope ratio method can produce meaningful results for light water-moderated power reactors. In this work, we use the isotope ratio method to estimate the energy production in a boiling water reactor fuel bundle based on measurements taken from the corresponding fuel assembly channel. Our preliminary results are in good agreement with the actual operating history of the reactor during the cycle that the fuel bundle was resident in the core.

  13. Motivation for New Measurements on 241, 242, 243Am Isotopes (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Motivation for New Measurements on 241, 242, 243Am Isotopes Citation Details In-Document Search Title: Motivation for New Measurements on 241, 242, 243Am Isotopes The initial objective of this work was an updated review on the Am isotopes data since the next official release (3.1) of the JEFF3 evaluated data file is foreseen around June 2005. Alternatively, this work searches for the possible reasons of the observed discrepancies between differential and integral

  14. Integrated safeguards and security for the INEL Special Isotope Separation Plant

    SciTech Connect (OSTI)

    Warner, G.F.; Zack, N.R.

    1990-06-12

    This paper describes the approach that was taken in developing safeguards and security design criteria to be used for the Special Isotope Separation (SIS) Production Plant. The US Department of Energy has postponed the construction of the SIS Production Plant that was to be built at the Idaho National Engineering Laboratory (INEL) site located near Idaho Falls, Idaho. The SIS Plant planned to isotopically enrich plutonium utilizing the Atomic Vapor Laser Isotope Separation (AVLIS) process developed at the Lawrence Livermore National Laboratory. Westinghouse Idaho Nuclear Co., Inc. as a prime contractor to the DOE Idaho Operations Office, was to operate the Plant.

  15. Age and isotopic relationships among the angrites Lewis Cliff 86010 and Angra dos Reis

    SciTech Connect (OSTI)

    Lugmair, G.W. ); Galer, S.J.G. Max-Planck-Inst. fuer Chemie, Mainz )

    1992-04-01

    Results of a wide-ranging isotopic investigation of the unique Antarctican angrite LEW-86010 (LEW) are presented, together with a reassessment of the type angrite Angra dos Reis (ADOR). The principal objectives of this study are to obtain precise radiometric ages, initial Sr isotopic compositions, and to search for the erstwhile presence of the short-lived nuclei {sup 146}Sm and {sup 26}Al via their daughter products. The isotopic compositions of Sm, U, Ca, and Ti were also measured. This allows a detailed appraisal to be made of the relations between, and the genealogy of, these two angrites.

  16. Test report for core drilling ignitability testing

    SciTech Connect (OSTI)

    Witwer, K.S.

    1996-08-08

    Testing was carried out with the cooperation of Westinghouse Hanford Company and the United States Bureau of Mines at the Pittsburgh Research Center in Pennsylvania under the Memorandum of Agreement 14- 09-0050-3666. Several core drilling equipment items, specifically those which can come in contact with flammable gasses while drilling into some waste tanks, were tested under conditions similar to actual field sampling conditions. Rotary drilling against steel and rock as well as drop testing of several different pieces of equipment in a flammable gas environment were the specific items addressed. The test items completed either caused no ignition of the gas mixture, or, after having hardware changes or drilling parameters modified, produced no ignition in repeat testing.

  17. HICEV America Test Sequence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HICEV America TEST SEQUENCE Revision 0 November 1, 2004 Prepared by Electric Transportation Applications Prepared by: _______________________________ Date: __________ Garrett Beauregard Approved by: _______________________________________________ Date: _______________ Donald B. Karner HICEV America Test Sequence Page 1 2004 Electric Transportation Applications All Rights Reserved HICEV PERFORMANCE TEST PROCEDURE SEQUENCE The following test sequence shall be used for conduct of HICEV America

  18. NEV America Test Sequence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NEVAmerica TEST SEQUENCE Revision 2 Effective February 1, 2008 Prepared by Electric Transportation Applications Prepared by: _______________________________ Date: __________ Nick Fengler Approved by: _________ ________________________________ Date: _______________ ______ Donald B. Karner ©2008 Electric Transportation Applications All Rights Reserved NEVAmerica Test Sequence Rev 2 Page 1 NEV PERFORMANCE TEST PROCEDURE SEQUENCE The following test sequence shall be used for conduct of NEVAmerica

  19. Dynamometer Testing (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-11-01

    This fact sheet describes the dynamometer and its testing capabilities at the National Wind Technology Center.

  20. Solderability test system

    DOE Patents [OSTI]

    Yost, F.; Hosking, F.M.; Jellison, J.L.; Short, B.; Giversen, T.; Reed, J.R.

    1998-10-27

    A new test method to quantify capillary flow solderability on a printed wiring board surface finish. The test is based on solder flow from a pad onto narrow strips or lines. A test procedure and video image analysis technique were developed for conducting the test and evaluating the data. Feasibility tests revealed that the wetted distance was sensitive to the ratio of pad radius to line width (l/r), solder volume, and flux predry time. 11 figs.

  1. Solderability test system

    DOE Patents [OSTI]

    Yost, Fred; Hosking, Floyd M.; Jellison, James L.; Short, Bruce; Giversen, Terri; Reed, Jimmy R.

    1998-01-01

    A new test method to quantify capillary flow solderability on a printed wiring board surface finish. The test is based on solder flow from a pad onto narrow strips or lines. A test procedure and video image analysis technique were developed for conducting the test and evaluating the data. Feasibility tests revealed that the wetted distance was sensitive to the ratio of pad radius to line width (l/r), solder volume, and flux predry time.

  2. Major Partner Test Sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Test Partners Once a technology is ready to be tested at pilot or commercial scale, the cost of building a test facility becomes significant -- often beyond the funding provided for any one project. It then becomes critical to test the technology at a pre-existing facility willing to test experimental technologies. Not surprisingly, most commercial facilities are hesitant to interfere with their operations to experiment, but others, with a view towards the future, welcome promising

  3. Entry/Exit Port testing, test report

    SciTech Connect (OSTI)

    Winkelman, R.H.

    1993-05-01

    The Waste Receiving and Processing Module I (WRAP-1) facility must have the ability to allow 55-gallon drums to enter and exit glovebox enclosures. An Entry/Exit Port (Appendix 1, Figure 1), designed by United Engineers and Constructors (UE&C), is one method chosen for drum transfer. The Entry/Exit Port is to be used for entry of 55-gallon drums into both process entry gloveboxes, exit of 55-gallon drum waste pucks from the low-level waste (LLW) glovebox, and loadout of waste from the restricted waste management glovebox. The Entry/Exit Port relies on capture velocity air flow and a neoprene seal to provide alpha confinement when the Port is in the open and closed positions, respectively. Since the glovebox is in a slight vacuum, air flow is directed into the glovebox through the space between the overpack drum and glovebox floor. The air flow is to direct any airborne contamination into the glovebox. A neoprene seal is used to seal the Port door to the glovebox floor, thus maintaining confinement in the closed position. Entry/Exit Port testing took place February 17, 1993, through April 14, 1993, in the 305 building of Westinghouse Hanford Company. Testing was performed in accordance with the Entry/Exit Port Testing Test Plan, document number WHC-SD-WO26-TP-005. A prototype Entry/Exit Port built at the Hanford Site was tested using fluorescent paint pigment and smoke candles as simulant contaminants. This test report is an interim test report. Further developmental testing is required to test modifications made to the Port as the original design of the Port did not provide complete confinement during all stages of operation.

  4. ISOTOPIC RATIOS IN TITAN's METHANE: MEASUREMENTS AND MODELING

    SciTech Connect (OSTI)

    Nixon, C. A.; Achterberg, R. K.; Temelso, B.; Vinatier, S.; Bezard, B.; Coustenis, A.; Teanby, N. A.; Mandt, K. E.; Sherrill, C. D.; Irwin, P. G. J.; Jennings, D. E.; Romani, P. N.; Flasar, F. M.

    2012-04-20

    The existence of methane in Titan's atmosphere ({approx}6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of {approx}20 Myr. In this paper, we examine the clues available from isotopic ratios ({sup 12}C/{sup 13}C and D/H) in Titan's methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH{sub 4} collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: {sup 13}CH{sub 4}, {sup 12}CH{sub 3}D, and {sup 13}CH{sub 3}D. From these we compute estimates of {sup 12}C/{sup 13}C = 86.5 {+-} 8.2 and D/H = (1.59 {+-} 0.33) Multiplication-Sign 10{sup -4}, in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan's methane: CH{sub 4} + C{sub 2}H {yields} CH{sub 3} + C{sub 2}H{sub 2}. Using these new measurements and predictions we proceed to model the time evolution of {sup 12}C/{sup 13}C and D/H in Titan's methane under several prototypical replenishment scenarios. In our Model 1 (no resupply of CH{sub 4}), we find that the present-day {sup 12}C/{sup 13}C implies that the CH{sub 4} entered the atmosphere 60-1600 Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently-most likely less than 10 Myr ago-if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane.

  5. Femtosecond Laser Ablation Multicollector ICPMS Analysis of Uranium Isotopes in NIST Glass

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Springer, Kellen WE; Ward, Jesse D.; Jarman, Kenneth D.; Robinson, John W.; Endres, Mackenzie C.; Hart, Garret L.; Gonzalez, Jhanis J.; Oropeza, Dayana; Russo, Richard; Willingham, David G.; Naes, Benjamin E.; Fahey, Albert J.; Eiden, Gregory C.

    2015-02-06

    We have utilized femtosecond laser ablation coupled to multi-collector inductively couple plasma mass spectrometry to measure the uranium isotopic content of NIST 61x (x=0,2,4,6) glasses. The uranium content of these glasses is a linear two-component mixing between isotopically natural uranium and the isotopically depleted spike used in preparing the glasses. Laser ablation results match extremely well, generally within a few ppm, with solution analysis following sample dissolution and chemical separation. In addition to isotopic data, sample utilization efficiency measurements indicate that over 1% of ablated uranium atoms reach a mass spectrometer detector, making this technique extremely efficient. Laser sampling also allows for spatial analysis and our data indicate that rare uranium concentration inhomogeneities exist in NIST 616 glass.

  6. Quantum fluctuations and isotope effects in ab initio descriptions of water

    SciTech Connect (OSTI)

    Wang, Lu; Markland, Thomas E.; Ceriotti, Michele

    2014-09-14

    Isotope substitution is extensively used to investigate the microscopic behavior of hydrogen bonded systems such as liquid water. The changes in structure and stability of these systems upon isotope substitution arise entirely from the quantum mechanical nature of the nuclei. Here, we provide a fully ab initio determination of the isotope exchange free energy and fractionation ratio of hydrogen and deuterium in water treating exactly nuclear quantum effects and explicitly modeling the quantum nature of the electrons. This allows us to assess how quantum effects in water manifest as isotope effects, and unravel how the interplay between electronic exchange and correlation and nuclear quantum fluctuations determine the structure of the hydrogen bond in water.

  7. Microsoft Word - NETL-TRS-8-2015 Appalachian Basin Isotopes_7...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H, 13 C, 18 O, 226 Ra, and 228 Ra Isotope Concentrations in the Appalachian Basin: A ... Suggested Citation: Mordensky, S.; Schubert, B.; Verba, C.; Hakala, A. 2 H, 13 C, 18 O, ...

  8. Report of Survey of Oak Ridge Isotope Enrichment (Calutron) Facility Building 9204-3

    Broader source: Energy.gov [DOE]

    The purpose of this document is to report the results of a survey conducted at the Isotope Enrichment Facility (IEF, Calutron, Building 9204-3) on the Y-12 Plant property at the Oak Ridge Site. The...

  9. Isoscalar and neutron modes in the E 1 spectra of Ni isotopes...

    Office of Scientific and Technical Information (OSTI)

    Title: Isoscalar and neutron modes in the E 1 spectra of Ni isotopes and the relevance of shell effects and the continuum Authors: Papakonstantinou, P. ; Hergert, H. ; Roth, R. ...

  10. Hydrogen isotopes as a proxy for the [sup 18]O content of water...

    Office of Scientific and Technical Information (OSTI)

    the sup 18O content of water in carbonates Citation Details In-Document Search Title: Hydrogen isotopes as a proxy for the sup 18O content of water in carbonates Water ...

  11. U235: A Gamma Ray Analysis Code for Uranium Isotopic Determination

    Office of Scientific and Technical Information (OSTI)

    5727 U235: A Gamma Ray Analysis Code for Uranium Isotopic Determination DeLynn Clark December 1996 may not be those of the Laboratory. Work performed under the auspices of the U S...

  12. Principal physical problems in laser separation of weighable amounts of a rare ytterbium isotope

    SciTech Connect (OSTI)

    Yakovlenko, Sergei I

    1998-11-30

    A review is provided of the work on laser separation of Yb isotopes, carried out at the Institute of General Physics of the Russian Academy of Sciences and at the 'Lad' Scientific - Production Enterprise during the last 4 - 5 years. The processes of Yb isotope separation by the AVLIS (atomic vapour laser isotope separation) method were investigated both theoretically (by computer simulation) and experimentally. The main topics considered in the review are the ionisation selectivity, the formation of laser beams and of vapour flow in the cavity, and the extraction of ions from a plasma. A facility for producing highly enriched {sup 168}Yb on an industrial scale is described. The rate of production of the enriched ytterbium is now 5 - 10 mg h{sup -1} (over 1 g per month). Commercially viable production of the enriched {sup 168}Yb isotope by the AVLIS method was achieved for the first time anywhere in the world. (review)

  13. Understanding H isotope adsorption and absorption of Al-alloys using modeling and experiments (LDRD: #165724)

    SciTech Connect (OSTI)

    Ward, Donald K.; Zhou, Xiaowang; Karnesky, Richard A.; Kolasinski, Robert; Foster, Michael E.; Thurmer, Konrad; Chao, Paul; Epperly, Ethan Nicholas; Zimmerman, Jonathan A.; Wong, Bryan M.; Sills, Ryan B.

    2015-09-01

    Current austenitic stainless steel storage reservoirs for hydrogen isotopes (e.g. deuterium and tritium) have performance and operational life-limiting interactions (e.g. embrittlement) with H-isotopes. Aluminum alloys (e.g.AA2219), alternatively, have very low H-isotope solubilities, suggesting high resistance towards aging vulnerabilities. This report summarizes the work performed during the life of the Lab Directed Research and Development in the Nuclear Weapons investment area (165724), and provides invaluable modeling and experimental insights into the interactions of H isotopes with surfaces and bulk AlCu-alloys. The modeling work establishes and builds a multi-scale framework which includes: a density functional theory informed bond-order potential for classical molecular dynamics (MD), and subsequent use of MD simulations to inform defect level dislocation dynamics models. Furthermore, low energy ion scattering and thermal desorption spectroscopy experiments are performed to validate these models and add greater physical understanding to them.

  14. Sensitivity Test Analysis

    Energy Science and Technology Software Center (OSTI)

    1992-02-20

    SENSIT,MUSIG,COMSEN is a set of three related programs for sensitivity test analysis. SENSIT conducts sensitivity tests. These tests are also known as threshold tests, LD50 tests, gap tests, drop weight tests, etc. SENSIT interactively instructs the experimenter on the proper level at which to stress the next specimen, based on the results of previous responses. MUSIG analyzes the results of a sensitivity test to determine the mean and standard deviation of the underlying population bymore » computing maximum likelihood estimates of these parameters. MUSIG also computes likelihood ratio joint confidence regions and individual confidence intervals. COMSEN compares the results of two sensitivity tests to see if the underlying populations are significantly different. COMSEN provides an unbiased method of distinguishing between statistical variation of the estimates of the parameters of the population and true population difference.« less

  15. GUM Analysis for SIMS Isotopic Ratios in BEP0 Graphite Qualification Samples, Round 2

    SciTech Connect (OSTI)

    Gerlach, David C.; Heasler, Patrick G.; Reid, Bruce D.

    2009-01-01

    This report describes GUM calculations for TIMS and SIMS isotopic ratio measurements of reactor graphite samples. These isotopic ratios are used to estimate reactor burn-up, and currently consist of various ratios of U, Pu, and Boron impurities in the graphite samples. The GUM calculation is a propagation of error methodology that assigns uncertainties (in the form of standard error and confidence bound) to the final estimates.

  16. Isoscalar and neutron modes in the E 1 spectra of Ni isotopes and the

    Office of Scientific and Technical Information (OSTI)

    relevance of shell effects and the continuum (Journal Article) | SciTech Connect Isoscalar and neutron modes in the E 1 spectra of Ni isotopes and the relevance of shell effects and the continuum Citation Details In-Document Search This content will become publicly available on September 13, 2016 Title: Isoscalar and neutron modes in the E 1 spectra of Ni isotopes and the relevance of shell effects and the continuum Authors: Papakonstantinou, P. ; Hergert, H. ; Roth, R. Publication Date:

  17. Nuclear Science and Physics Data from the Isotopes Project, Lawrence Berkeley National Laboratory (LBNL)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Isotopes Project pages at Lawrence Berkeley National Laboratory have been a source of nuclear data and reference information since the mid-nineties. Almost all of the data, the results of analyses, the specialized charts and interfaces, and the extensive bibiographic references are fed to the National Nuclear Data Center (NNDC) at Brookhaven National Laboratory and maintained there. The Isotope Project pages at LBNL provide a glimpse of early versions for many of the nuclear data resources.

  18. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 moves a step closer Irradiated uranium fuel has been recycled and reused for molybdenum-99 (Mo-99) production, with virtually no losses in Mo-99 yields or uranium recovery. May 13, 2013 From left, Los Alamos scientists Roy Copping, Sean Reilly, and Daniel Rios. Copping examines the Buchi Multivapor P-12 Evaporator, and Reilly and Rios are at the Agilent Technologies Cary 60 UV-Vis Spectrometer. From left,

  19. Hydrogen Isotope Separation From Noble Gasses in Plasma Exhausts and Other

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas Streams --- Inventors Thomas A. Kozub, William R. Blanchard and Charles A. Gentile | Princeton Plasma Physics Lab Hydrogen Isotope Separation From Noble Gasses in Plasma Exhausts and Other Gas Streams --- Inventors Thomas A. Kozub, William R. Blanchard and Charles A. Gentile The objective of this invention is the removal of hydrogen isotopes from noble (intervention) gasses. In one configuration, it employs liquid lithium in thin layers on chevrons or other surfaces. Plasma exhaust,

  20. Laser isotope separation: Uranium. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-12-01

    The bibliography contains citations concerning the technology and assessment of laser separation of uranium isotopes, compounds, oxides, and alloys. Topics include uranium enrichment plants, isotope enriched materials, gaseous diffusion, centrifuge enrichment, reliability and safety, and atomic vapor separation. Citations also discuss commercial enrichment, market trends, licensing, international competition, and waste management. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)