National Library of Energy BETA

Sample records for temperature water vapor

  1. Reaction kinetics for the high temperature oxidation of Pu--1wt%Ga in water vapor

    SciTech Connect (OSTI)

    Stakebake, J L; Saba, M A

    1988-01-01

    Oxidation of plutonium metal is greatly accelerated by the presence of water vapor. The magnitude of the effect of water vapor on oxidation kinetics is determined by temperature, water concentration, and oxygen concentration. Most of the previous work has been directed toward evaluating the effect of moisture on the atmospheric oxidation of plutonium. Work on the isolation and characterization of the water reaction with plutonium has been very limited. The present work was undertaken to determine the kinetics of the plutonium--water reaction over a wide range of temperature and pressure. Reaction kinetics were measured using a vacuum microbalance system. The temperature range investigated was 100--500/degree/C. The effect of water vapor pressure on reaction kinetics was determined at 300/degree/C by varying the water pressure from 0.1 to 15 Torr. 2 figs.

  2. Observed Increase of TTL Temperature and Water Vapor in Polluted Couds over Asia

    SciTech Connect (OSTI)

    Su, Hui; Jiang, Jonathan; Liu, Xiaohong; Penner, J.; Read, William G.; Massie, Steven T.; Schoeberl, Mark R.; Colarco, Peter; Livesey, Nathaniel J.; Santee, Michelle L.

    2011-06-01

    Aerosols can affect cloud particle size and lifetime, which impacts precipitation, radiation and climate. Previous studies1-4 suggested that reduced ice cloud particle size and fall speed due to the influence of aerosols may increase evaporation of ice crystals and/or cloud radiative heating in the tropical tropopause layer (TTL), leading to higher water vapor abundance in air entering the stratosphere. Observational substantiation of such processes is still lacking. Here, we analyze new observations from multiple NASA satellites to show the imprint of pollution influence on stratospheric water vapor. We focus our analysis on the highly-polluted South and East Asia region during boreal summer. We find that "polluted" ice clouds have smaller ice effective radius than "clean" clouds. In the TTL, the polluted clouds are associated with warmer temperature and higher specific humidity than the clean clouds. The water vapor difference between the polluted and clean clouds cannot be explained by other meteorological factors, such as updraft and detrainment strength. Therefore, the observed higher water vapor entry value into the stratosphere in the polluted clouds than in the clean clouds is likely a manifestation of aerosol pollution influence on stratospheric water vapor. Given the radiative and chemical importance of stratospheric water vapor, the increasing emission of aerosols over Asia may have profound impacts on stratospheric chemistry and global energy balance and water cycle.

  3. Temperature and Water Vapor Variance Scaling in Global Models: Comparisons to Satellite and Aircraft Data

    E-Print Network [OSTI]

    Wood, Robert

    Infrared Sounder (AIRS) are compared to those generated by state-of-the-art numerical weather prediction controlling cloud processes at the subgrid scale in NWP and climate models (Cusack et al. 1999; Tompkins 2002Temperature and Water Vapor Variance Scaling in Global Models: Comparisons to Satellite

  4. Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds

    SciTech Connect (OSTI)

    Westwater, Edgeworth

    2011-05-06

    The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement (ARM) Program. At the North Slope of Alaska (NSA), both microwave radiometers (MWR) and the MWRProfiler (MWRP), been used operationally by ARM for passive retrievals of the quantities: Precipitable Water Vapor (PWV) and Liquid Water Path (LWP). However, it has been convincingly shown that these instruments are inadequate to measure low amounts of PWV and LWP. In the case of water vapor, this is especially important during the Arctic winter, when PWV is frequently less than 2 mm. For low amounts of LWP (< 50 g/m{sup 2}), the MWR and MWRP retrievals have an accuracy that is also not acceptable. To address some of these needs, in March-April 2004, NOAA and ARM conducted the NSA Arctic Winter Radiometric Experiment - Water Vapor Intensive Operational Period at the ARM NSA/Adjacent Arctic Ocean (NSA/AAO) site. After this experiment, the radiometer group at NOAA moved to the Center for Environmental Technology (CET) of the Department of Electrical and Computer Engineering of the University of Colorado at Boulder. During this 2004 experiment, a total of 220 radiosondes were launched, and radiometric data from 22.235 to 380 GHz were obtained. Primary instruments included the ARM MWR and MWRP, a Global Positioning System (GPS), as well as the CET Ground-based Scanning Radiometer (GSR). We have analyzed data from these instruments to answer several questions of importance to ARM, including: (a) techniques for improved water vapor measurements; (b) improved calibration techniques during cloudy conditions; (c) the spectral response of radiometers to a variety of conditions: clear, liquid, ice, and mixed phase clouds; and (d) forward modeling of microwave and millimeter wave brightness temperatures from 22 to 380 GHz. Many of these results have been published in the open literature. During the third year of this contract, we participated in another ARM-sponsored experiment at the NSA during February-March 2007. This experiment is called the Radiative Heating in Underexplored Bands Campaign (RHUBC) and the GSR was operated successfully for the duration of the campaign. One of the principal goals of the experiment was to provide retrievals of water vapor during PWV amounts less than 2 mm and to compare GSR data with ARM radiometers and radiosondes. A secondary goal was to compare the radiometric response of the microwave and millimeter wavelength radiometers to water and ice clouds. In this final report, we will include the separate progress reports for each of the three years of the project and follow with a section on major accomplishments of the project.

  5. Electro-Osmosis and Water Uptake in Polymer Electrolytes in Equilibrium with Water Vapor at Low Temperatures

    SciTech Connect (OSTI)

    Gallagher, K. G.; Pivovar, B. S.; Fuller, T. F.

    2009-01-01

    Water uptake and electro-osmosis are investigated to improve the understanding and aid the modeling of water transport in proton-exchange membrane fuel cells (PEMFCs) below 0 C. Measurements of water sorption isotherms show a significant reduction in the water capacity of polymer electrolytes below 0 C. This reduced water content is attributed to the lower vapor pressure of ice compared to supercooled liquid water. At -25 C, 1100 equivalent weight Nafion in equilibrium with vapor over ice has 8 moles of water per sulfonic acid group. Measurements of the electro-osmotic drag coefficient for Nafion and both random and multiblock copolymer sulfonated poly(arylene ether sulfone) (BPSH) chemistries are reported for vapor equilibrated samples below 0 C. The electro-osmotic drag coefficient of BPSH chemistries is found to be {approx}0.4, and that of Nafion is {approx}1. No significant temperature effect on the drag coefficient is found. The implication of an electro-osmotic drag coefficient less than unity is discussed in terms of proton conduction mechanisms. Simulations of the ohmically limited current below 0 C show that a reduced water uptake below 0 C results in a significant decrease in PEMFC performance.

  6. The role of water vapor and solar radiation in determining temperature changes and trends measured at Armagh, 18812000

    E-Print Network [OSTI]

    The role of water vapor and solar radiation in determining temperature changes and trends measured radiation was associated with the concurrent changes measured in specific humidity; the remaining quarter was associated with increases in the concentrations of carbon dioxide and other anthropogenic radiatively active

  7. Water vapor and temperature inversions near the 0 deg C level over the tropical western Pacific. Master's thesis

    SciTech Connect (OSTI)

    Hart, K.A.

    1994-01-01

    During the Intensive Observation Period (IOP), several periods of water vapor and temperature inversions near the 0 deg C level were observed. Satellite and radiosonde data from TOGA COARE are used to document the large-scale conditions and thermodynamic and kinematic structures present during three extended periods in which moisture and temperature inversions near the freezing level were very pronounced. Observations from each case are synthesized into schematics which represent typical structures of the inversion phenomena. Frequency distributions of the inversion phenomena along with climatological humidity and temperature profiles are calculated for the four-month IOP.

  8. Electro-Osmosis and Water Uptake in Polymer Electrolytes in Equilibrium with Water Vapor at Low Temperatures

    SciTech Connect (OSTI)

    Gallagher, K. G.; Pivovar, B. S.; Fuller, T. F.

    2008-01-01

    Measurements of the electro-osmotic drag coefficient for Nafion{reg_sign} and both random and multi-block co-polymer sulfonated poly(arylene ether sulfone) (BPSH) chemistries are reported for vapor equilibrated samples below 0 C. No significant change in the drag coefficient behavior for Nafion from that reported above 0 C is found. However BPSH is found to have a drag coefficient of 0.4. The implication of a drag coefficient less than unity in the interpretation of conduction mechanisms is discussed. Measurements of water sorption isotherms below 0 C are also presented. A significant reduction in the capacity of polymer electrolytes to store water below 0 C is found. This reduced water content is a result of the lower vapor pressure of ice compared to supercooled liquid.

  9. Water vapor distribution in protoplanetary disks

    SciTech Connect (OSTI)

    Du, Fujun; Bergin, Edwin A.

    2014-09-01

    Water vapor has been detected in protoplanetary disks. In this work, we model the distribution of water vapor in protoplanetary disks with a thermo-chemical code. For a set of parameterized disk models, we calculate the distribution of dust temperature and radiation field of the disk with a Monte Carlo method, and then solve the gas temperature distribution and chemical composition. The radiative transfer includes detailed treatment of scattering by atomic hydrogen and absorption by water of Ly? photons, since the Ly? line dominates the UV spectrum of accreting young stars. In a fiducial model, we find that warm water vapor with temperature around 300 K is mainly distributed in a small and well-confined region in the inner disk. The inner boundary of the warm water region is where the shielding of UV field due to dust and water itself become significant. The outer boundary is where the dust temperature drops below the water condensation temperature. A more luminous central star leads to a more extended distribution of warm water vapor, while dust growth and settling tends to reduce the amount of warm water vapor. Based on typical assumptions regarding the elemental oxygen abundance and the water chemistry, the column density of warm water vapor can be as high as 10{sup 22} cm{sup –2}. A small amount of hot water vapor with temperature higher than ?300 K exists in a more extended region in the upper atmosphere of the disk. Cold water vapor with temperature lower than 100 K is distributed over the entire disk, produced by photodesorption of the water ice.

  10. G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product

    SciTech Connect (OSTI)

    Koontz, A; Cadeddu, M

    2012-12-05

    The G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) value-added product (VAP) computes precipitable water vapor using neural network techniques from data measured by the GVR. The GVR reports time-series measurements of brightness temperatures for four channels located at 183.3 ± 1, 3, 7, and 14 GHz.

  11. Hydrogen Ingress in Steels During High-Temperature Oxidation in Water Vapor

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL; Fayek, Mostafa [ORNL; Keiser, James R [ORNL; Meyer III, Harry M [ORNL; More, Karren Leslie [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Wesolowski, David J [ORNL; Cole, David R [ORNL

    2011-01-01

    It is well established that hydrogen derived from water vapour can penetrate oxidizing alloys with detrimental effect. However, the complexities of tracking hydrogen in these materials have prevented the direct profiling of hydrogen ingress needed to understand these phenomena. Here we report hydrogen profiles in industrially-relevant alumina- and chromia- forming steels correlated with the local oxide-metal nano/microstructure by use of SIMS D2O tracer studies and experimental protocols to optimize D retention. The D profiles unexpectedly varied markedly among the alloys examined, which indicates mechanistic complexity but also the potential to mitigate detrimental water vapour effects by manipulation of alloy chemistry.

  12. Water vapor distribution in protoplanetary disks

    E-Print Network [OSTI]

    Du, Fujun

    2014-01-01

    Water vapor has been detected in protoplanetary disks. In this work we model the distribution of water vapor in protoplanetary disks with a thermo-chemical code. For a set of parameterized disk models, we calculate the distribution of dust temperature and radiation field of the disk with a Monte Carlo method, and then solve the gas temperature distribution and chemical composition. The radiative transfer includes detailed treatment of scattering by atomic hydrogen and absorption by water of Lyman alpha photons, since the Lyman alpha line dominates the UV spectrum of accreting young stars. In a fiducial model, we find that warm water vapor with temperature around 300 K is mainly distributed in a small and well-confined region in the inner disk. The inner boundary of the warm water region is where the shielding of UV field due to dust and water itself become significant. The outer boundary is where the dust temperature drops below the water condensation temperature. A more luminous central star leads to a more ...

  13. Water Vapor Experiment Concludes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricN A 035(92/02)ManagementWatchingWater Tanks(Technical3

  14. Glenwood Springs Vapor Caves Pool & Spa Low Temperature Geothermal...

    Open Energy Info (EERE)

    Vapor Caves Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Glenwood Springs Vapor Caves Pool & Spa Low Temperature Geothermal Facility Facility...

  15. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    2004-02-19

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  16. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  17. Environmental Chemistry at Vapor/Water Interfaces

    E-Print Network [OSTI]

    Environmental Chemistry at Vapor/Water Interfaces: Insights from Vibrational Sum Frequency for manyyearsowingtoitscomplexityandimportanceindescribingawiderange of physical phenomena. The vapor/water interface is particularly interesting from an environmental for these systems is highlighted. A future perspective toward the application of VSFG to the study of environmental

  18. Ozone, water vapor, and temperature in the upper tropical troposphere: Variations over a decade of MOZAIC measurements

    E-Print Network [OSTI]

    Bortz, Sarah E; Prather, Michael J; Cammas, Jean-Pierre; Thouret, Valérie; Smit, Herman

    2006-01-01

    An extension of the measurement of ozone and water vapour byin-service Aircraft (MOZAIC) ozone climatologies usingcomparison with SHADOZ ozone and MODIS aerosol, J. Geophys.

  19. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1998-01-01

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma.

  20. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, P.

    1998-06-02

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma. 5 figs.

  1. Adsorption of radon and water vapor on commercial activated carbons

    SciTech Connect (OSTI)

    Hassan, N.M. [Westinghouse Savannah River Co., Aiken, SC (United States); Ghosh, T.K.; Hines, A.L.; Loyalka, S.K. [Univ. of Missouri, Columbia, MO (United States)

    1995-02-01

    Equilibrium adsorption isotherms are reported for radon and water vapor on two commercial activated carbons: coconut shell Type PCB and hardwood Type BD. The isotherms of the water vapor were measured gravimetrically at 298 K. The isotherms of radon from dry nitrogen were obtained at 293, 298, and 308 K while the data for the mixture of radon and water vapor were measured at 298 K. The concentrations of radon in the gas and solid phases were measured simultaneously, once the adsorption equilibrium and the radioactive equilibrium between the radon and its daughter products were established. The shape of the isotherms was of Type III for the radon and Type V for the water vapor, according to Brunauer`s classification. The adsorption mechanism was similar for both the radon and the water vapor, being physical adsorption on the macropore surface area in the low pressure region and micropore filling near saturation pressure. The uptake capacity of radon decreased both with increasing temperature and relative humidity. The heat of adsorption data indicated that the PCB- and the BD-activated carbons provided a heterogeneous surface for radon adsorption. The equilibrium data for radon were correlated with a modified Freundlich equation.

  2. Effect of higher water vapor content on TBC performance

    SciTech Connect (OSTI)

    Pint, Bruce A; Haynes, James A

    2012-01-01

    Coal gasification, or IGCC (integrated gasification combined cycle), is one pathway toward cleaner use of coal for power generation with lower emissions. However, when coal-derived synthesis gas (i.e., syngas) is burned in turbines designed for natural gas, turbine manufacturers recommend 'derating,' or lowering the maximum temperature, which lowers the efficiency of the turbine, making electricity from IGCC more expensive. One possible reason for the derating is the higher water vapor contents in the exhaust gas. Water vapor has a detrimental effect on many oxidation-resistant high-temperature materials. In a turbine hot section, Ni-base superalloys are coated with a thermal barrier coating (TBC) allowing the gas temperature to be higher than the superalloy solidus temperature. TBCs have a low thermal conductivity ceramic top coating (typically Y{sub 2}O{sub 3}-stabilized ZrO{sub 2}, or YSZ) and an oxidation-resistant metallic bond coating. For land-based gas turbines, the industry standard is air plasma sprayed (APS) YSZ and high velocity oxygen fuel (HVOF) sprayed NiCoCrAlY bond coatings. To investigate the role of higher water vapor content on TBC performance and possible mitigation strategies, furnace cycling experiments were conducted in dry O{sub 2} and air with 10% (typical with natural gas or jet fuel) or 50 vol% water vapor. Cycle frequency and temperature were accelerated to one hour at 1100 C (with 10 minute cooling to {approx}30 C between each thermal cycle) to induce early failures in coatings that are expected to operate for several years with a metal temperature of {approx}900 C. Coupons (16 mm diameter x 2 mm thick) of commercial second-generation single crystal superalloy CMSX4 were HVOF coated on both sides with {approx}125 {micro}m of Ni-22wt%Co-17Cr-12Al either with 0.7Y or 0.7Y-0.3Hf-0.4Si. One side was then coated with 190-240 {micro}m of APS YSZ. Coatings were cycled until the YSZ top coating spalled. Figure 2 shows the results of the initial phase of experiments. Compared to dry O{sub 2}, the addition of 10% water vapor decreased the lifetime of MCrAlY by {approx}30% for the conventional CMSX4 substrates. Higher average lifetimes were observed with Hf in the bond coating, but a similar decrease in lifetime was observed when water vapor was added. The addition of Y and La to the superalloy substrate did not change the YSZ lifetime with 10% water vapor. However, increasing water vapor content from 10 to 50% did not further decrease the lifetime of either bond coating with the doped superalloy substrate. Thus, these results suggest that higher water vapor contents cannot explain the derating of syngas-fired turbines, and other factors such as sulfur and ash from imperfect syngas cleanup (or upset conditions) need to be explored. Researchers continue to study effects of water vapor on thermally grown alumina scale adhesion and growth rate, and are looking for bond coating compositions more resistant to oxidation in the presence of water vapor.

  3. Fixation of nitrogen in the presence of water vapor

    DOE Patents [OSTI]

    Harteck, Paul (Santa Barbara, CA)

    1984-01-01

    A process for the fixation of nitrogen is disclosed which comprises combining a mixture of nitrogen, oxygen, metal oxide and water vapor, initially heating the combination to initiate a reaction which forms nitrate, but at a temperature and pressure range below the dissociation pressure of the nitrate. With or without the water component, the yield of fixed nitrogen is increased by the use of a Linde Molecular Sieve Catalyst.

  4. Water Vapor around Sgr B2

    E-Print Network [OSTI]

    J. Cernicharo; J. R. Goicoechea; J. R. Pardo; A. Asensio Ramos

    2006-01-16

    We have conducted a study combining H2O lines in two spectral regions. First, Infrared Space Observatory observations of several H2O thermal lines seen in absorption toward Sgr B2(M) at a spectral resolution of 35 kms^-1 have been analyzed. Second, an IRAM-30m telescope map of the para-H2O 3_13-2_20 line at 183.31 GHz, seen in emission, has also been obtained and analyzed. The H2O lines seen in absorption are optically thick and are formed in the outermost gas of the condensations in front of the far-IR continuum sources. They probe a maximum visual extinction of ~5 to 10 mag. Radiative transfer models indicate that these lines are quite insensitive to temperature and gas density, and that IR photons from the dust play a dominant role in the excitation of the involved H2O rotational levels. The water vapor abundance in the region is (1-2)x10^-5. The relatively low H2O/OH abundance ratio in the region, 2-4, is a signature of UV photon dominated surface layers traced by far-IR observations.

  5. The role of water vapor feedback in unperturbed climate variability and global warming

    SciTech Connect (OSTI)

    Hall, A.; Manabe, Syukuro

    1999-08-01

    To understand the role of water vapor feedback in unperturbed surface temperature variability, a version of the Geophysical Fluid Dynamics Laboratory coupled ocean-atmosphere model is integrated for 1,000 yr in two configurations, one with water vapor feedback and one without. To understand the role of water vapor feedback in global warming, two 500-yr integrations were also performed in which CO{sub 2} was doubled in both model configurations. The final surface global warming in the model with water vapor feedback is 3.38 C, while in the one without it is only 1.05 C. However, the model`s water vapor feedback has a larger impact on surface warming in response to a doubling of CO{sub 2} than it does on internally generated, low-frequency, global-mean surface temperature anomalies. Water vapor feedback`s strength therefore depends on the type of temperature anomaly it affects. Finally, the authors compare the local and global-mean surface temperature time series from both unperturbed variability experiments to the observed record. The experiment without water vapor feedback does not have enough global-scale variability to reproduce the magnitude of the variability in the observed global-mean record, whether or not one removes the warming trend observed over the past century. In contrast, the amount of variability in the experiment with water vapor feedback is comparable to that of the global-mean record, provided the observed warming trend is removed. Thus, the authors are unable to simulate the observed levels of variability without water vapor feedback.

  6. WATER TEMPERATURE RECORDS FROM

    E-Print Network [OSTI]

    ? WATER TEMPERATURE RECORDS FROM CALIFORNIA'S CENTRAL VALLEY 1939-1948 Marine Biological i STATES DEPARTMENT OF THE INTERIOR FISH AND WILDLIFE SERVICE #12;#12;a WATER TEMPERATURE RECORDS FROM arid to avoid delay in publication. Washington D. CWATER TEMPERATURE RECORDS FROM

  7. An optical water vapor sensor for unmanned aerial vehicles

    SciTech Connect (OSTI)

    Timothy A. Berkoff; Paul L. Kebabian; Robert A. McClatchy; Charles E. Kolb; Andrew Freedman

    1998-12-01

    The water vapor sensor developed by Aerodyne Research, based on the optical absorption of light at {approximately}935 nm, has been successfully demonstrated on board the Pacific Northwest National Laboratory's Gulfstream-1 research aircraft during the Department of Energy's ARM Intensive Operations Period in August 1998. Data taken during this field campaign show excellent agreement with a chilled mirror and Lyman-alpha hygrometers and measurements confirm the ability to measure rapid, absolute water vapor fluctuations with a high degree of instrument stability and accuracy, with a noise level as low 10 ppmv (1 Hz measurement bandwidth). The construction of this small, lightweight sensor contains several unique elements which result in several significant advantages when compared to other techniques. First, the low power consumption Argon discharge lamp provides an optical beam at a fixed wavelength without a need for temperature or precision current control. The multi-pass absorption cell developed for this instrument provides a compact, low cost method that can survive deployment in the field. Fiber-optic cables, which are used to convey to light between the absorption cell, light source, and detection modules enable remote placement of the absorption cell from the opto-electronics module. Finally, the sensor does not use any moving parts which removes a significant source of potential malfunction. The result is an instrument which maintained its calibration throughout the field measurement campaign, and was not affected by high vibration and large uncontrolled temperature excursions. We believe that the development of an accurate, fast response water vapor monitor described in this report will open up new avenues of aerial-vehicle-based atmospheric research which have been relatively unexplored due to the lack of suitable low-cost, light-weight instrumentation.

  8. Diffusion barriers in the kinetics of water vapor adsorption/desorption on activated carbons

    SciTech Connect (OSTI)

    Harding, A.W.; Foley, N.J.; Thomas, K.M. [Univ. of Newcastle upon Tyne (United Kingdom)] [Univ. of Newcastle upon Tyne (United Kingdom); Norman, P.R.; Francis, D.C. [CBD, Salisbury (United Kingdom)] [CBD, Salisbury (United Kingdom)

    1998-07-07

    The adsorption of water vapor on a highly microporous coconut-shell-derived carbon and a mesoporous wood-derived carbon was studied. These carbons were chosen as they had markedly different porous structures. The adsorption and desorption characteristics of water vapor on the activated carbons were investigated over the relative pressure range p/p{degree} = 0--0.9 for temperatures in the range 285--313 K in a static water vapor system. The adsorption isotherms were analyzed using the Dubinin-Serpinski equation, and this provided an assessment of the polarity of the carbons. The kinetics of water vapor adsorption and desorption were studied with different amounts of preadsorbed water for set changes in pressure relative to the saturated vapor pressure (p/p{degree}). The adsorption kinetics for each relative pressure step were compared and used to calculate the activation energies for the vapor pressure increments. The kinetic results are discussed in relation to their relative position on the equilibrium isotherm and the adsorption mechanism of water vapor on activated carbons.

  9. The Water Vapor Abundance in Orion KL Outflows

    E-Print Network [OSTI]

    J. Cernicharo; J. R. Goicoechea; F. Daniel; M. R. Lerate; M. J. Barlow; B. M. Swinyard; E. van Dishoeck; T. L. Lim; S. Viti; J. Yates

    2006-08-16

    We present the detection and modeling of more than 70 far-IR pure rotational lines of water vapor, including the 18O and 17O isotopologues, towards Orion KL. Observations were performed with the Long Wavelength Spectrometer Fabry-Perot (LWS/FP; R~6800-9700) on board the Infrared Space Observatory (ISO) between ~43 and ~197 um. The water line profiles evolve from P-Cygni type profiles (even for the H2O18 lines) to pure emission at wavelengths above ~100 um. We find that most of the water emission/absorption arises from an extended flow of gas expanding at 25+-5 kms^-1. Non-local radiative transfer models show that much of the water excitation and line profile formation is driven by the dust continuum emission. The derived beam averaged water abundance is 2-3x10^-5. The inferred gas temperature Tk=80-100 K suggests that: (i) water could have been formed in the "plateau" by gas phase neutral-neutral reactions with activation barriers if the gas was previously heated (e.g. by shocks) to >500 K and/or (ii) H2O formation in the outflow is dominated by in-situ evaporation of grain water-ice mantles and/or (iii) H2O was formed in the innermost and warmer regions (e.g. the hot core) and was swept up in ~1000 yr, the dynamical timescale of the outflow.

  10. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Vignola, F.; Andreas, A.

    2013-08-22

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  11. Water vapor and the dynamics of climate changes

    E-Print Network [OSTI]

    Schneider, Tapio

    Water vapor is not only Earth's dominant greenhouse gas. Through the release of latent heat when it condenses, it also plays an active role in dynamic processes that shape the global circulation of the atmosphere and thus ...

  12. Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement 

    E-Print Network [OSTI]

    Tong, Yunwei

    2013-11-08

    This dissertation has two key objectives: the first objective is to develop a method of predicting and quantifying the amount of water that can enter into a pavement system by vapor transport; the second objective is to ...

  13. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Vignola, F.; Andreas, A.

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  14. COLD WATER VAPOR IN THE BARNARD 5 MOLECULAR CLOUD

    SciTech Connect (OSTI)

    Wirström, E. S.; Persson, C. M.; Charnley, S. B.; Cordiner, M. A.; Buckle, J. V.; Takakuwa, S.

    2014-06-20

    After more than 30 yr of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds; however, there is only one region where cold (?10 K) water vapor has been detected—L1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at work—likely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H{sub 2}O (J = 1{sub 10}-1{sub 01}) at 556.9360 GHz toward two positions in the cold molecular cloud, Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

  15. Gas phase reaction of sulfur trioxide with water vapor

    SciTech Connect (OSTI)

    Kolb, C.E.; Molina, M.J.; Jayne, J.T.; Meads, R.F.; Worsnop, D.R.

    1994-12-31

    Sulfur trioxide (SO3) has long been known to react with water to produce sulfuric acid (H2S04). It has been commonly assumed that the gas phase reaction in the Earth`s atmosphere between SO3 and water vapor to produce sulfuric acid vapor is an important step in the production of sulfuric acid aerosol particles. The kinetics of the gas phase reaction of SO3 with water vapor have previously been studied by Castleman and co-workers, Wang et al and Reiner and Arnold. Each of these studies was carried out in a flow reactor, with the first two studies performed at low pressure (1-10 Torr) and the latter from approx. 30 to 260 Torr. Each of these studies measured SO3 decays over a range of H2O vapor levels, obtaining data consistent with interpreting the reaction of gaseous SO3 and H2O as a bimolecular process. It is not clear why previous experimental studies failed to observe a nonlinear dependence of SO3 consumption on water vapor concentration. It is probable that sufficient water dimer exists in much of the Earth`s atmosphere to allow dimer reactions to participate in sulfuric acid vapor formation.

  16. Removal of Sarin Aerosol and Vapor by Water Sprays

    SciTech Connect (OSTI)

    Brockmann, John E.

    1998-09-01

    Falling water drops can collect particles and soluble or reactive vapor from the gas through which they fall. Rain is known to remove particles and vapors by the process of rainout. Water sprays can be used to remove radioactive aerosol from the atmosphere of a nuclear reactor containment building. There is a potential for water sprays to be used as a mitigation technique to remove chemical or bio- logical agents from the air. This paper is a quick-look at water spray removal. It is not definitive but rather provides a reasonable basic model for particle and gas removal and presents an example calcu- lation of sarin removal from a BART station. This work ~ a starting point and the results indicate that further modeling and exploration of additional mechanisms for particle and vapor removal may prove beneficial.

  17. VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM

    E-Print Network [OSTI]

    VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE the vapor-liquid equilibrium of water (between 323 and 573 K), carbon dioxide (between 230 and 290 K) and their binary mixtures (between 348 and 393 K). The properties of supercritical carbon dioxide were determined

  18. MODELING THE EFFECT OF WATER VAPOR ON THE INTERFACIAL BEHAVIOR OF HIGH-TEMPERATURE AIR IN CONTACT WITH Fe20Cr SURFACES

    SciTech Connect (OSTI)

    Chialvo, Ariel A [ORNL; Brady, Michael P [ORNL; Keiser, James R [ORNL; Cole, David R [ORNL

    2011-01-01

    The purpose of this communication is to provide an atomistic view, via molecular dynamic simulation, of the contrasting interfacial behavior between high temperature dry- and (10-40 vol%) wet-air in contact with stainless steels as represented by Fe20Cr. It was found that H2O preferentially adsorbs and displaces oxygen at the metal/fluid interface. Comparison of these findings with experimental studies reported in the literature is discussed. Keywords: Fe-Cr alloys, metal-fluid interfacial behavior, wet-air, molecular simulation

  19. Summary Weusedthreemethodstomeasureboundarylayer conductance to heat transfer (gbH) and water vapor transfer

    E-Print Network [OSTI]

    Martin, Timothy

    Summary Weusedthreemethodstomeasureboundarylayer conductance to heat transfer (gbH) and water vapor of transpiration). The boundary layer conductance to heat transfer is small enough that leaf temperature can become diffusion, the boundary layer around a leaf also provides resistance to the transfer of heat between a leaf

  20. Low temperature photochemical vapor deposition of alloy and mixed metal oxide films

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA)

    1992-01-01

    Method and apparatus for formation of an alloy thin film, or a mixed metal oxide thin film, on a substrate at relatively low temperatures. Precursor vapor(s) containing the desired thin film constituents is positioned adjacent to the substrate and irradiated by light having wavelengths in a selected wavelength range, to dissociate the gas(es) and provide atoms or molecules containing only the desired constituents. These gases then deposit at relatively low temperatures as a thin film on the substrate. The precursor vapor(s) is formed by vaporization of one or more precursor materials, where the vaporization temperature(s) is selected to control the ratio of concentration of metals present in the precursor vapor(s) and/or the total precursor vapor pressure.

  1. Water Vapor Variability Across Spatial Scales: Insights for Theory, Parameterization, and Model Assessment

    E-Print Network [OSTI]

    Pressel, Kyle Gregory

    2012-01-01

    11 2 Scaling of Water Vapor Structure Functions as 2.1cloud model. q is the total water mixing-ratio and q ? isAIRS Exponents from AIRS Data Water Vapor Time Series from a

  2. Experimental Study of Water Vapor Adsorption on Geothermal

    E-Print Network [OSTI]

    Stanford University

    SGP-TR-148 Experimental Study of Water Vapor Adsorption on Geothermal Reservoir Rocks Shubo Shang Geothermal Program under Department of Energy Grant No. DE-FG07-90IDI2934,and by the Department of Petroleum Engineering, Stanford University Stanford Geothermal Program Interdisciplinary Research in Engineering

  3. Wavelength-modulation laser hygrometer for ultrasensitive detection of water vapor in

    E-Print Network [OSTI]

    Wavelength-modulation laser hygrometer for ultrasensitive detection of water vapor in semiconductor.5 mol mol of water vapor in air. The pressure- broadening coefficients for water broadened by helium 0- eter WMLH for the ultrasensitive detection of water vapor.11 For detecting H2O this instrument com

  4. EFFECT OF FILTER TEMPERATURE ON TRAPPING ZINC VAPOR

    SciTech Connect (OSTI)

    Korinko, P.

    2011-03-25

    To address the {sup 65}Zn contamination issue in the TEF, a multi-task experimental program was initiated. The first experimental task was completed and is reported in Ref. 1. The results of the second experimental task are reported here. This task examined the effect of filter temperature on trapping efficiency and deposit morphology. Based on the first experimental tasks that examined filter pore size and trapping efficiency, stainless steel filter media with a 20 {micro}m pore size was selected. A series of experiments using these filters was conducted during this second task to determine the effect of filter temperature on zinc vapor trapping efficiency, adhesion and morphology. The tests were conducted with the filters heated to 60, 120, and 200 C; the zinc source material was heated to 400 C for all the experiments to provide a consistent zinc source. The samples were evaluated for mass change, deposit adhesion and morphology. As expected from the physical vapor deposition literature, a difference in deposit morphology and appearance was observed between the three filter temperatures. The filter held at 60 C had the largest average mass gain while the 120 and 200 C filters exhibited similar but lower weight gains. The standard deviations were large and suggest that all three temperatures exhibited comparable gains. No zinc was detected on the backside surface of the filters indicating high efficiency for front and internal trapping. A zinc rich deposit was formed on the surface of the 60 C filter. Based on a simple tape adhesion test, the surface zinc was readily removed from the 60 C filter while less zinc deposit was removed from the 120 and 200 C filter samples. It is surmised that the higher temperatures enable the zinc to deposit within the filter media rather than on the surface. Based on the findings that all three statistically trapped the same quantity of zinc vapor and that the higher temperatures resulted in a more adherent/better trapped product, operating the filters at 120 to 200 C is recommended.

  5. Calculation of the Dimer Equilibrium Constant of Heavy Water Saturated Vapor

    E-Print Network [OSTI]

    L. A. Bulavin; S. V. Khrapatiy; V. N. Makhlaichuk

    2015-03-13

    Water is the most common substance on Earth.The discovery of heavy water and its further study have shown that the change of hydrogen for deuterium leads to the significant differences in their properties.The triple point temperature of heavy water is higher,at the same time the critical temperature is lower.Experimental values of the second virial coefficient of the EOS for the vapor of normal and heavy water differ at all temperatures.This fact can influence the values of the dimerization constant for the heavy water vapor.The equilibrium properties of the dimerization process are described with the methods of chemical thermodynamics.The chemical potentials for monomers (m) and dimers (d)are the functions of their concentrations.The interactions of monomer-dimer and dimer-dimer types are taken into account within the solution of equation for chemical potentials.The obtained expression for the dimerization constant contains the contributions of these types.The averaged potentials are modeled by the Sutherland potential.Theoretical values of the dimerization constant for the heavy water vapor at different temperatures are compared to those for normal water.We see the exceeding of the values for the heavy water at all temperatures.This fact is in good agreement with all experimental data that is available.The excess is related to the differences in the character of the heat excitations of the dimers of normal and heavy water,their rotational constants and energy of their vibrational excitations.Significant role is also played by the monomer-dimer and dimer-dimer interactions.

  6. Low Temperature Chemical Vapor Deposition Of Thin Film Magnets

    DOE Patents [OSTI]

    Miller, Joel S. (Salt Lake City, UT); Pokhodnya, Kostyantyn I. (Salt Lake City, UT)

    2003-12-09

    A thin-film magnet formed from a gas-phase reaction of tetracyanoetheylene (TCNE) OR (TCNQ), 7,7,8,8-tetracyano-P-quinodimethane, and a vanadium-containing compound such as vanadium hexcarbonyl (V(CO).sub.6) and bis(benzene)vanalium (V(C.sub.6 H.sub.6).sub.2) and a process of forming a magnetic thin film upon at least one substrate by chemical vapor deposition (CVD) at a process temperature not exceeding approximately 90.degree. C. and in the absence of a solvent. The magnetic thin film is particularly suitable for being disposed upon rigid or flexible substrates at temperatures in the range of 40.degree. C. and 70.degree. C. The present invention exhibits air-stable characteristics and qualities and is particularly suitable for providing being disposed upon a wide variety of substrates.

  7. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode DesigngovCampaignsSpring Single Column ModelRSPExperimentgovCampaignsWater Cycle

  8. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode DesigngovCampaignsSpring Single Column ModelRSPExperimentgovCampaignsWater

  9. Correlation Between Opacity and Surface Water Vapor Pressure Measurements at Rio Frio

    E-Print Network [OSTI]

    Groppi, Christopher

    Correlation Between Opacity and Surface Water Vapor Pressure Measurements at Rio Frio M.A. Holdaway 1, 1996 Abstract We use the surface water vapor pressure measured by weather stations at 4060 m opacity. The surface water vapor pressure is inverted some 20% of the time at night and some 35

  10. Measurements of the Vapor Pressure of Supercooled Water Using Infrared Spectroscopy

    E-Print Network [OSTI]

    Kostinski, Alex

    Measurements of the Vapor Pressure of Supercooled Water Using Infrared Spectroscopy WILL CANTRELL 14 May 2007, in final form 6 December 2007) ABSTRACT Measurements are presented of the vapor pressure' data correspond to the vapor pressure of liquid water, not a mixture of liquid water and ice. Values

  11. Energy and water vapor transport across a simplified cloud-clear air interface

    E-Print Network [OSTI]

    Gallana, Luca; De Santi, Francesca; Iovieno, Michele; Tordella, Daniela

    2015-01-01

    We consider a simplified physics of the could interface where condensation, evaporation and radiation are neglected and momentum, thermal energy and water vapor transport is represented in terms of the Boussinesq model coupled to a passive scalar transport equation for the vapor. The interface is modeled as a layer separating two isotropic turbulent regions with different kinetic energy and vapor concentration. In particular, we focus on the small scale part of the inertial range as well as on the dissipative range of scales which are important to the micro-physics of warm clouds. We have numerically investigated stably stratified interfaces by locally perturbing at an initial instant the standard temperature lapse rate at the cloud interface and then observing the temporal evolution of the system. When the buoyancy term becomes of the same order of the inertial one, we observe a spatial redistribution of the kinetic energy which produce a concomitant pit of kinetic energy within the mixing layer. In this sit...

  12. Potential energy of atmospheric water vapor and the air motions induced by water vapor condensation on different spatial scales

    E-Print Network [OSTI]

    Anastassia M. Makarieva; Victor G. Gorshkov

    2010-03-29

    Basic physical principles are considered that are responsible for the origin of dynamic air flow upon condensation of water vapor, the partial pressure of which represents a store of potential energy in the atmosphere of Earth. Quantitative characteristics of such flow are presented for several spatial scales. It is shown that maximum condensation-induced velocities reach 160 m/s and are realized in compact circulation patterns like tornadoes.

  13. Calculation of the Dimer Equilibrium Constant of Heavy Water Saturated Vapor

    E-Print Network [OSTI]

    Bulavin, L A; Makhlaichuk, V N

    2015-01-01

    Water is the most common substance on Earth.The discovery of heavy water and its further study have shown that the change of hydrogen for deuterium leads to the significant differences in their properties.The triple point temperature of heavy water is higher,at the same time the critical temperature is lower.Experimental values of the second virial coefficient of the EOS for the vapor of normal and heavy water differ at all temperatures.This fact can influence the values of the dimerization constant for the heavy water vapor.The equilibrium properties of the dimerization process are described with the methods of chemical thermodynamics.The chemical potentials for monomers (m) and dimers (d)are the functions of their concentrations.The interactions of monomer-dimer and dimer-dimer types are taken into account within the solution of equation for chemical potentials.The obtained expression for the dimerization constant contains the contributions of these types.The averaged potentials are modeled by the Sutherlan...

  14. In-Reactor Oxidation of Zircaloy-4 Under Low Water Vapor Pressures

    SciTech Connect (OSTI)

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin; Longhurst, Glen

    2015-01-01

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330° and 370°C). Data from these tests will be used to support fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr-4 over the specified range of test conditions. Comparisons between in- and ex- reactor test results were performed to evaluate the influence of irradiation.

  15. In-reactor oxidation of zircaloy-4 under low water vapor pressures

    SciTech Connect (OSTI)

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin K.; Longhurst, Glen R.

    2015-01-01

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370 ºC). Data from these tests will be used to support the fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr- 4 over the specified range of test conditions. Comparisons between in- and ex-reactor test results were performed to evaluate the influence of irradiation.

  16. ARM - Field Campaign - ARM-FIRE Water Vapor Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See22, 2012III ARM DatagovCampaignsARM-FIRE Water Vapor

  17. ARM - Field Campaign - Fall 1997 Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01)govCampaignsFIRE-Arctic CloudShortwave IOP ARM DataWater Vapor

  18. Profiling the atmospheric water vapor content using a GPS-Meteorology network

    E-Print Network [OSTI]

    Mountziaris, T. J.

    Profiling the atmospheric water vapor content using a GPS-Meteorology network Jayson Maldonado-Meteorological stations. Research Objectives · Develop the hardware necessary for the collection atmospheric water content gives the real Water Vapor Content (WVC) in 3D instead of the Zenith Delay. Future Work · Testing

  19. Low temperature chemical vapor deposition of Co thin films from Co2(CO)8

    E-Print Network [OSTI]

    Wang, Gwo-Ching

    Low temperature chemical vapor deposition of Co thin films from Co2(CO)8 D.-X. Yea,*, S. Pimanpanga chemical vapor deposition with a metallorganic Co2(CO)8 precursor. After Ar sputtering of the surface, Co2(CO)8, has been extensively used in cobalt CVD and is attractive, since Co is in its elemental

  20. A study of the minimum meniscus radius as a function of vapor temperature using heat pipes 

    E-Print Network [OSTI]

    Sonnier, Ronald James

    1973-01-01

    A STUDY OF THE MINIMUM MENISCUS RADIUS AS A FUNCTION OF VAPOR TEMPERATURE USING HEAT PIPES A Thesis by RONALD JAMES SONNIER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree... MASTER OF SCIENCE May 1973 Major Subject: Mechanical Engineering A STUDY OF THE MINIMUM MENISCUS RADIUS AS A FUNCTION OF VAPOR TEMPERATURE USING HEAT PIPES A Thesis by RONALD JAMES SONNIER Approved as to style and content by: Chairman C ittee...

  1. Savings Project: Lower Water Heating Temperature | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Savings Project: Lower Water Heating Temperature Savings Project: Lower Water Heating Temperature Addthis Project Level Easy Energy Savings 12-30 annually for each 10F...

  2. Observational evidence of changes in water vapor, clouds, and radiation at the ARM SGP site

    E-Print Network [OSTI]

    Dong, Xiquan

    Observational evidence of changes in water vapor, clouds, and radiation at the ARM SGP site Xiquan then increased until the present. Using 8 years of data collected at the ARM Southern Great Plains (SGP) surface evidence of changes in water vapor, clouds, and radiation at the ARM SGP site, Geophys. Res. Lett., 33, L

  3. Desalination-of water by vapor-phase transport through hydrophobic nanopores

    E-Print Network [OSTI]

    Lee, Jongho

    We propose a new approach to desalination of water whereby a pressure difference across a vapor-trapping nanopore induces selective transport of water by isothermal evaporation and condensation across the pore. Transport ...

  4. Room temperature water Leidenfrost droplets

    E-Print Network [OSTI]

    Franck Celestini; Thomas Frisch; Yves Pomeau

    2013-08-05

    We experimentally investigate the Leidenfrost effect at pressures ranging from 1 to 0.05 atmospheric pressure. As a direct consequence of the Clausius-Clapeyron phase diagram of water, the droplet temperature can be at ambient temperature in a non-sophisticated lab environment. Furthermore, the lifetime of the Leidenfrost droplet is significantly increased in this low pressure environment. The temperature and pressure dependance of the evaporation rate are successfully tested against a recently proposed model. These results may pave a way to reach efficient Leidenfrost micro-fluidic and milli-fluidic applications.

  5. High-temperature alkali vapor cells with antirelaxation surface coatings S. J. Seltzera

    E-Print Network [OSTI]

    Romalis, Mike

    High-temperature alkali vapor cells with antirelaxation surface coatings S. J. Seltzera and M. V 2009; accepted 31 August 2009; published online 2 December 2009 Antirelaxation surface coatings allow coatings were previously unavailable for operation at temperatures above 80 °C. We demonstrate

  6. Roles of Oxygen and Water Vapor in the Oxidation of Halogen Terminated Ge(111) Surfaces

    SciTech Connect (OSTI)

    Sun, Shiyu; /Stanford U., Phys. Dept.; Sun, Yun; Liu, Zhi; Lee, Dong-Ick; Pianette, Piero; /SLAC, SSRL

    2006-12-18

    The initial stage of the oxidation of Cl and Br terminated Ge(111) surfaces is studied using photoelectron spectroscopy. The authors perform controlled experiments to differentiate the effects of different factors in oxidation, and find that water vapor and oxygen play different roles. Water vapor effectively replaces the halogen termination layers with the hydroxyl group, but does not oxidize the surfaces further. In contrast, little oxidation is observed for Cl and Br terminated surfaces with dry oxygen alone. However, with the help of water vapor, oxygen oxidizes the surface by breaking the Ge-Ge back bonds instead of changing the termination layer.

  7. Latitudinal survey of middle atmospheric water vapor revealed by shipboard microwave spectroscopy. Master's thesis

    SciTech Connect (OSTI)

    Schrader, M.L.

    1994-05-01

    Water vapor is one of the most important greenhouse gases and is an important tracer of atmospheric motions in the middle atmosphere. It also plays an important role in the chemistry of the middle atmosphere and through its photodissociation by solar radiation, it is the major source of hydrogen escaping to space. Ground-based microwave measurements conducted in the 1980s have provided a fair understanding of the seasonal variation of mesospheric water vapor in the northern hemisphere mid-latitudes, but the global distribution of water vapor in the middle atmosphere is only beginning to be revealed by space-based measurements.

  8. Heats of vaporization of room temperature ionic liquids by tunable vacuum ultraviolet photoionization

    SciTech Connect (OSTI)

    Chambreau, Steven D.; Vaghjiani, Ghanshyam L.; To, Albert; Koh, Christine; Strasser, Daniel; Kostko, Oleg; Leone, Stephen R.

    2009-11-25

    The heats of vaporization of the room temperature ionic liquids (RTILs) N-butyl-N-methylpyrrolidinium bistrifluorosulfonylimide, N-butyl-N-methylpyrrolidinium dicyanamide, and 1-butyl-3-methylimidazolium dicyanamide are determined using a heated effusive vapor source in conjunction with single photon ionization by a tunable vacuum ultraviolet synchrotron source. The relative gas phase ionic liquid vapor densities in the effusive beam are monitored by clearly distinguished dissociative photoionization processes via a time-of-flight mass spectrometer at a tunable vacuum ultraviolet beamline 9.0.2.3 (Chemical Dynamics Beamline) at the Advanced Light Source synchrotron facility. Resulting in relatively few assumptions, through the analysis of both parent cations and fragment cations, the heat of vaporization of N-butyl-N-methylpyrrolidinium bistrifluorosulfonylimide is determined to be Delta Hvap(298.15 K) = 195+-19 kJ mol-1. The observed heats of vaporization of 1-butyl-3-methylimidazolium dicyanamide (Delta Hvap(298.15 K) = 174+-12 kJ mol-1) and N-butyl-N-methylpyrrolidinium dicyanamide (Delta Hvap(298.15 K) = 171+-12 kJ mol-1) are consistent with reported experimental values using electron impact ionization. The tunable vacuum ultraviolet source has enabled accurate measurement of photoion appearance energies. These appearance energies are in good agreement with MP2 calculations for dissociative photoionization of the ion pair. These experimental heats of vaporization, photoion appearance energies, and ab initio calculations corroborate vaporization of these RTILs as intact cation-anion ion pairs.

  9. Distribution of binding energies of a water molecule in the water liquid-vapor interface

    SciTech Connect (OSTI)

    Chempath, Shaji [Los Alamos National Laboratory; Pratt, Lawrence R [TULANE UNIV

    2008-01-01

    Distributions of binding energies of a water molecule in the water liquid-vapor interface are obtained on the basis of molecular simulation with the SPC/E model of water. These binding energies together with the observed interfacial density profile are used to test a minimally conditioned Gaussian quasi-chemical statistical thermodynamic theory. Binding energy distributions for water molecules in that interfacial region clearly exhibit a composite structure. A minimally conditioned Gaussian quasi-chemical model that is accurate for the free energy of bulk liquid water breaks down for water molecules in the liquid-vapor interfacial region. This breakdown is associated with the fact that this minimally conditioned Gaussian model would be inaccurate for the statistical thermodynamics of a dilute gas. Aggressive conditioning greatly improves the performance of that Gaussian quasi-chemical model. The analogy between the Gaussian quasi-chemical model and dielectric models of hydration free energies suggests that naive dielectric models without the conditioning features of quasi-chemical theory will be unreliable for these interfacial problems. Multi-Gaussian models that address the composite nature of the binding energy distributions observed in the interfacial region might provide a mechanism for correcting dielectric models for practical applications.

  10. Water Vapor Turbulence Profiles in Stationary Continental Convective Mixed Layers

    SciTech Connect (OSTI)

    Turner, D. D.; Wulfmeyer, Volker; Berg, Larry K.; Schween, Jan

    2014-10-08

    The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program’s Raman lidar at the ARM Southern Great Plains (SGP) site in north-central Oklahoma has collected water vapor mixing ratio (q) profile data more than 90% of the time since October 2004. Three hundred (300) cases were identified where the convective boundary layer was quasi-stationary and well-mixed for a 2-hour period, and q mean, variance, third order moment, and skewness profiles were derived from the 10-s, 75-m resolution data. These cases span the entire calendar year, and demonstrate that the q variance profiles at the mixed layer (ML) top changes seasonally, but is more related to the gradient of q across the interfacial layer. The q variance at the top of the ML shows only weak correlations (r < 0.3) with sensible heat flux, Deardorff convective velocity scale, and turbulence kinetic energy measured at the surface. The median q skewness profile is most negative at 0.85 zi, zero at approximately zi, and positive above zi, where zi is the depth of the convective ML. The spread in the q skewness profiles is smallest between 0.95 zi and zi. The q skewness at altitudes between 0.6 zi and 1.2 zi is correlated with the magnitude of the q variance at zi, with increasingly negative values of skewness observed lower down in the ML as the variance at zi increases, suggesting that in cases with larger variance at zi there is deeper penetration of the warm, dry free tropospheric air into the ML.

  11. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu (Palo Alto, CA); Ly, Jennifer (San Jose, CA); Aldajani, Tiem (San Jose, CA); Baker, Richard W. (Palo Alto, CA)

    2011-08-23

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  12. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  13. Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle

    SciTech Connect (OSTI)

    Hosni, Mohammad H.

    2014-03-30

    Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerant’s pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development of the cycle and have gained an in-depth understanding of the governing fundamental knowledge, based on the laws of physics and thermodynamics and verified with our testing results. Through this research, we are identifying optimal working fluid and operating conditions to eventually demonstrate the core technology for space cooling or other applications.

  14. Nanoimprint mold fabrication and replication by room-temperature conformal chemical vapor deposition

    E-Print Network [OSTI]

    Nanoimprint mold fabrication and replication by room-temperature conformal chemical vapor for the replication of molds for nanoimprint lithography NIL without solvents or etching. A thin hard amorphous from the polymer original, the thin hard film forms a NIL mold that is the inverse of the polymer

  15. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR�¢����s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument�¢����s robustness in a real-world situation.

  16. The Determination of the Water Vapor Content in the Pulkovo VKM-100 Multipass Vacuum Cell Using Polymer Sensors of Humidity

    E-Print Network [OSTI]

    Galkin, V D; Nikanorova, I N; Sal'nikov, I B; Leiterer, U; Alekseeva, G A; Novikov, V V; Dauß, D

    2010-01-01

    In spectral studies of water vapor under laboratory conditions (determination of molecular constants, measurement for spectral transmission functions), the amount of water vapor in the time of the measurements is one of the most essential parameters, which should be determined accurately. We discuss the application for this purpose of polymer sensors of humidity manufactured by Praktik-NC (Moscow) and used in the Pulkovo VKM-100 multipass vacuum cell. These sensors were examined in the laboratory of Lindenberg Meteorological observatory (Germany) by comparison between their readings and those of standard measuring devices for various values of relative humidity, pressure, and temperature. We also carried out measurements of relative humidity in boxes with saline solution, in which the relative humidity that corresponds to a given solution is guaranteed with the accuracy of several tenths of percent. The analysis of the results of the laboratory examination of the sensors and extended sets of measurements made...

  17. Glass softening, crystallization, and vaporization of nano-aggregates of Amorphous Solid Water: Fast Scanning Calorimetry studies

    E-Print Network [OSTI]

    Deepanjan Bhattacharya; Liam OReilly; Vlad Sadtchenko

    2014-10-31

    Fast scanning calorimetry (FSC) was employed to investigate glass softening dynamics in amorphous solid water (ASW) nano-aggregates with thicknesses ranging from 2 to 20 nm. ASW nano-aggregates were prepared by vapor-deposition on the surface of a tungsten filament near 141 K and then heated at a rate of 100 kK/s. The resulting thermogram complex endo- and exothermal features were analyzed using a simple model. The results of the analysis show that glass softening of ASW nano-aggregates takes place at 160 K and vaporization of ASW nano-aggregates can take place at temperatures as low as 185 K. The results of these studies are discussed in conjunction with results of past studies of glass softening dynamics in water in various confining geometries.

  18. Hydrogen isotope recovery using a cathode water vapor feed PEM electrolyzer

    SciTech Connect (OSTI)

    Fox, E. B.; Greenway, S. D.; Ekechukwu, A. A. [Savannah River National Laboratory: 999-2W, Aiken, SC 29208 (United States)

    2008-07-15

    A critical component of tritium glovebox operations is the recovery of high value tritium from the water vapor in the glove box atmosphere. One proposed method to improve existing tritium recovery systems is to replace the disposable hot magnesium beds used to separate the hydrogen and oxygen in water with continuous use Proton Exchange Membrane Electrolyzers (PEMEs). This study examines radiation exposure to the membrane of a PEME and examines the sizing difference that would be needed if the electrolyzer were operated with a cathode water vapor feed instead of an anode liquid water feed. (authors)

  19. Experimental Study of Water Droplet Vaporization on Nanostructured Surfaces

    E-Print Network [OSTI]

    Padilla, Jorge

    2014-01-01

    temperature range, T Leid , as a function of average contact angle,temperature range, T Leid , as a function of average contact angle,temperature and onset of nucleate boiling as a function contact angle

  20. A meta-analysis of water vapor deuterium-excess in the midlatitude atmospheric surface layer

    E-Print Network [OSTI]

    Minnesota, University of

    are in natural ecosystems, a forest (Borden Forest, Ontario, Canada) and a grassland (Duolun, China). We found.1029/2011GB004246. 1. Introduction [2] Water vapor is the most important atmospheric greenhouse gas and temporal variability in the isotopic composition of water in the air and also on the land surface (i

  1. Two Stage Vapor Compression Heat Pump with Solution Circuits: Catering to Simultaneous Chilling and Water Heating Needs 

    E-Print Network [OSTI]

    Rane, M. V.; Radermacher, R.

    1992-01-01

    The benefits of using a two stage vapor compression heat pump with ammonia water solution circuits (VCHSC) to simultaneously provide chilled water for air conditioning and hot water for various uses are reviewed. The performance results for a two...

  2. Stratospheric Temperatures and Water Loss from Moist Greenhouse Atmospheres of Earth-like Planets

    E-Print Network [OSTI]

    Kasting, James F; Kopparapu, Ravi Kumar

    2015-01-01

    A radiative-convective climate model is used to calculate stratospheric temperatures and water vapor concentrations for ozone-free atmospheres warmer than that of modern Earth. Cold, dry stratospheres are predicted at low surface temperatures, in agreement with recent 3-D calculations. However, at surface temperatures above 350 K, the stratosphere warms and water vapor becomes a major upper atmospheric constituent, allowing water to be lost by photodissociation and hydrogen escape. Hence, a 'moist greenhouse' explanation for loss of water from Venus, or some exoplanet receiving a comparable amount of stellar radiation, remains a viable hypothesis. Temperatures in the upper parts of such atmospheres are well below those estimated for a gray atmosphere, and this factor should be taken into account when performing 'inverse' climate calculations to determine habitable zone boundaries using 1-D models.

  3. Savings Project: Lower Water Heating Temperature | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Thermostats Savings Project: Lower Water Heating Temperature Tips: Passive Solar Heating and Cooling Where to insulate. Adding insulation in the areas shown here may be...

  4. PROGRESS REPORT OF FY 2004 ACTIVITIES: IMPROVED WATER VAPOR AND CLOUD RETRIEVALS AT THE NSA/AAO

    SciTech Connect (OSTI)

    E. R. Westwater; V. V. Leuskiy; M. Klein; A. J. Gasiewski; and J. A. Shaw

    2004-11-01

    The basic goals of the research are to develop and test algorithms and deploy instruments that improve measurements of water vapor, cloud liquid, and cloud coverage, with a focus on the Arctic conditions of cold temperatures and low concentrations of water vapor. The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement Program. Although several technologies have been investigated to measure these column amounts, microwave radiometers (MWR) have been used operationally by the ARM program for passive retrievals of these quantities: precipitable water vapor (PWV) and integrated water liquid (IWL). The technology of PWV and IWL retrievals has advanced steadily since the basic 2-channel MWR was first deployed at ARM CART sites Important advances are the development and refinement of the tipcal calibration method [1,2], and improvement of forward model radiative transfer algorithms [3,4]. However, the concern still remains that current instruments deployed by ARM may be inadequate to measure low amounts of PWV and IWL. In the case of water vapor, this is especially important because of the possibility of scaling and/or quality control of radiosondes by the water amount. Extremely dry conditions, with PWV less than 3 mm, commonly occur in Polar Regions during the winter months. Accurate measurements of the PWV during such dry conditions are needed to improve our understanding of the regional radiation energy budgets. The results of a 1999 experiment conducted at the ARM North Slope of Alaska/Adjacent Arctic Ocean (NSA/AAO) site during March of 1999 [5] have shown that the strength associated with the 183 GHz water vapor absorption line makes radiometry in this frequency regime suitable for measuring low amounts of PWV. As a portion of our research, we conducted another millimeter wave radiometric experiment at the NSA/AAO in March-April 2004. This experiment relied heavily on our experiences of the 1999 experiment. Particular attention was paid to issues of radiometric calibration and radiosonde intercomparisons. Our theoretical and experimental work also supplements efforts by industry (F. Solheim, Private Communication) to develop sub-millimeter radiometers for ARM deployment. In addition to quantitative improvement of water vapor measurements at cold temperature, the impact of adding millimeter-wave window channels to improve the sensitivity to arctic clouds was studied. We also deployed an Infrared Cloud Imager (ICI) during this experiment, both for measuring continuous day-night statistics of the study of cloud coverage and identifying conditions suitable for tipcal analysis. This system provided the first capability of determining spatial cloud statistics continuously in both day and night at the NSA site and has been used to demonstrate that biases exist in inferring cloud statistics from either zenith-pointing active sensors (lidars or radars) or sky imagers that rely on scattered sunlight in daytime and star maps at night [6].

  5. Materials, methods and devices to detect and quantify water vapor concentrations in an atmosphere

    DOE Patents [OSTI]

    Allendorf, Mark D; Robinson, Alex L

    2014-12-09

    We have demonstrated that a surface acoustic wave (SAW) sensor coated with a nanoporous framework material (NFM) film can perform ultrasensitive water vapor detection at concentrations in air from 0.05 to 12,000 ppmv at 1 atmosphere pressure. The method is extendable to other MEMS-based sensors, such as microcantilevers, or to quartz crystal microbalance sensors. We identify a specific NFM that provides high sensitivity and selectivity to water vapor. However, our approach is generalizable to detection of other species using NFM to provide sensitivity and selectivity.

  6. AFM pictures of the surfaces of glass RPC electrodes damaged by water vapor contamination

    E-Print Network [OSTI]

    T. Kubo; E. Nakano; Y. Teramoto

    2002-11-08

    We present surface pictures of the damaged electrodes from the Glass Resistive Plate Chambers (GRPCs) taken by an Atomic Force Microscope (AFM). For the test, a set of chambers were operated with freon mixed gas (damaged) and freonless gas (not damaged), contaminated with 1000 to 2000 ppm of water vapor. In the AFM pictures, clear differences in damage are seen between the electrodes in the chambers with the freon mixed gas and the freonless gas; a combination of freon and water vapor caused the damage.

  7. Fresh Water Increased temperature means higher proportion of water

    E-Print Network [OSTI]

    Houston, Paul L.

    Fresh Water Increased temperature means higher proportion of water falling on surface higher evaporation higher rainfall greater intensity of floods and droughts. Water use has grown four on How much storage compared to average flow Demand as percentage of supply How much ground water is used

  8. Detection of water vapor in the terrestrial planet forming region of a transition disk

    E-Print Network [OSTI]

    Salyk, Colette; Richter, Matthew J; Zhang, Ke; Blake, Geoffrey A; Pontoppidan, Klaus M

    2015-01-01

    We report a detection of water vapor in the protoplanetary disk around DoAr 44 with the Texas Echelon Cross Echelle Spectrograph --- a visitor instrument on the Gemini north telescope. The DoAr 44 disk consists of an optically thick inner ring and outer disk, separated by a dust-cleared 36 AU gap, and has therefore been termed "pre-transitional". To date, this is the only disk with a large inner gap known to harbor detectable quantities of warm (T=450 K) water vapor. In this work, we detect and spectrally resolve three mid-infrared pure rotational emission lines of water vapor from this source, and use the shapes of the emission lines to constrain the location of the water vapor. We find that the emission originates near 0.3 AU --- the inner disk region. This characteristic region coincides with that inferred for both optically thick and thin thermal infrared dust emission, as well as rovibrational CO emission. The presence of water in the dust-depleted region implies substantial columns of hydrogen (>10^{22}...

  9. A NORMETEX MODEL 15 M3/HR WATER VAPOR PUMPING TEST

    SciTech Connect (OSTI)

    Klein, J.; Fowley, M.; Steeper, T.

    2010-12-20

    Tests were performed using a Model 15 m{sup 3}/hr Normetex vacuum pump to determine if pump performance degraded after pumping a humid gas stream. An air feed stream containing 30% water vapor was introduced into the pump for 365 hours with the outlet pressure of the pump near the condensation conditions of the water. Performance of the pump was tested before and after the water vapor pumping test and indicated no loss in performance of the pump. The pump also appeared to tolerate small amounts of condensed water of short duration without increased noise, vibration, or other adverse indications. The Normetex pump was backed by a dual-head diaphragm pump which was affected by the condensation of water and produced some drift in operating conditions during the test.

  10. Low-temperature germanium ultra-high vacuum chemical vapor deposition for back-end photonic integration

    E-Print Network [OSTI]

    Kimerling, Lionel C.

    Polycrystalline germanium (poly-Ge) grown on amorphous Si (a-Si) by ultra-high vacuum chemical vapor deposition (UHVCVD) over oxide barriers at low temperatures (Tles450degC) exhibits a larger grain size and lower defect ...

  11. Managing water temperatures below hydroelectric facilities

    SciTech Connect (OSTI)

    Johnson, P.L.; Vermeyen, T.B.; O`Haver, G.G.

    1995-05-01

    Due to drought-related water temperature problems in the Bureau of Reclamation`s California Central Valley Project in the early 1990`s, engineers were forced to bypass water from the plants during critical periods. This was done at considerable cost in the form of lost revenue. As a result, an alternative method of lowering water temperature was developed and it has successfully lowered water temperatures downstream from hydroelectric facilities by using flexible rubber curtains. This innovative technology is aiding the survival of endangered fish populations. This article outlines the efforts and discusses the implementation of this method at several hydroelectric facilities in the area.

  12. Water vapor on supergiants. The 12 micron TEXES spectra of mu Cephei

    E-Print Network [OSTI]

    N. Ryde; M. J. Richter; G. M. Harper; K. Eriksson; D. L. Lambert

    2006-03-15

    Several recent papers have argued for warm, semi-detached, molecular layers surrounding red giant and supergiant stars, a concept known as a MOLsphere. Spectroscopic and interferometric analyses have often corroborated this general picture. Here, we present high-resolution spectroscopic data of pure rotational lines of water vapor at 12 microns for the supergiant mu Cephei. This star has often been used to test the concept of molecular layers around supergiants. Given the prediction of an isothermal, optically thick water-vapor layer in Local Thermodynamic Equilibrium around the star (MOLsphere), we expected the 12 micron lines to be in emission or at least in absorption but filled in by emission from the molecular layer around the star. Our data, however, show the contrary; we find definite absorption. Thus, our data do not easily fit into the suggested isothermal MOLsphere scenario. The 12 micron lines, therefore, put new, strong constraints on the MOLsphere concept and on the nature of water seen in signatures across the spectra of early M supergiants. We also find that the absorption is even stronger than that calculated from a standard, spherically symmetric model photosphere without any surrounding layers. A cool model photosphere, representing cool outer layers is, however, able to reproduce the lines, but this model does not account for water vapor emission at 6 microns. Thus, a unified model for water vapor on mu Cephei appears to be lacking. It does seem necessary to model the underlying photospheres of these supergiants in their whole complexity. The strong water vapor lines clearly reveal inadequacies of classical model atmospheres.

  13. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  14. Measurement of Water Vapor Concentration using Tunable Diode Laser Absorption Spectroscopy 

    E-Print Network [OSTI]

    Barrett, Alexander B.

    2010-07-14

    Tunable diode laser spectroscopy and the Beer-Lambert relation has been used to measure the absorption of water vapor both in an absorption cell and in a shock tube. The purpose of this thesis is to develop a laser diagnostic capable of determining...

  15. Multilayer Cloud Detection with the MODIS Near-Infrared Water Vapor Absorption Band

    E-Print Network [OSTI]

    Baum, Bryan A.

    Multilayer Cloud Detection with the MODIS Near-Infrared Water Vapor Absorption Band GALINA WIND,*,1 spacecraft includes an algorithm for detecting multilayered clouds in daytime. The main objective of this algorithm is to detect multilayered cloud scenes, specifically optically thin ice cloud overlying a lower

  16. Validation of TES Temperature and Water Vapor Retrievals with ARM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentric viewingValidating extended

  17. Remote sensing of total integrated water vapor, wind speed, and cloud liquid water over the ocean using the Special Sensor Microwave/Imager (SSM/I) 

    E-Print Network [OSTI]

    Manning, Norman Willis William

    1997-01-01

    A modified D-matrix retrieval method is the basis of the refined total integrated water vapor (TIWV), total integrated cloud liquid water (CLW), and surface wind speed (WS) retrieval methods that are developed. The 85 GHZ ...

  18. WATER TEMPERATURES Marine BiolOiical Laboratory

    E-Print Network [OSTI]

    =temperature data are valuable to several agencies working in the Sacramento River basin,, Fishery researchers collection is further restricted to waters of the Sacramento Valley and the Sacramento - San Joaquin Delta the exceotion of readings from Sacramento River near the Sacramento Water Works and Sacramento River at Hay

  19. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single Family Homes (Revised)

    SciTech Connect (OSTI)

    Cummings, J.; Withers, C.; Martin, E.; Moyer, N.

    2012-10-01

    This document focuses on managing the driving forces which move air and moisture across the building envelope. While other previously published Measure Guidelines focus on elimination of air pathways, the ultimate goal of this Measure Guideline is to manage drivers which cause air flow and water vapor transport across the building envelope (and also within the home), control air infiltration, keep relative humidity (RH) within acceptable limits, avoid combustion safety problems, improve occupant comfort, and reduce house energy use.

  20. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes

    SciTech Connect (OSTI)

    Cummings, James; Withers, Charles; Martin, Eric; Moyer, Neil

    2012-10-01

    This report is a revision of an earlier report titled: Measure Guideline: Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes. Revisions include: Information in the text box on page 1 was revised to reflect the most accurate information regarding classifications as referenced in the 2012 International Residential Code. “Measure Guideline” was dropped from the title of the report. An addition was made to the reference list.

  1. The molecular structure of the interface between water and a hydrophobic substrate is liquid-vapor like

    E-Print Network [OSTI]

    Adam P. Willard; David Chandler

    2014-07-16

    With molecular simulation for water and a tunable hydrophobic substrate, we apply the instantaneous interface construction [A. P. Willard and D. Chandler, J. Phys. Chem. B, 114, 1954 (2010)] to examine the similarity between a water-vapor interface and a water-hydrophobic surface interface. The intrinsic interface refers to molecular structure in terms of distances from the instantaneous interface. We show that attractive interactions between a hydrophobic surface and water affect capillary wave fluctuations of the instantaneous liquid interface, but these attractive interactions have essentially no effect on the intrinsic interface. Further, the intrinsic interface of liquid water and a hydrophobic substrate differs little from that of water and its vapor.The same is not true, we show, for an interface between water and a hydrophilic substrate. In that case, strong directional substrate-water interactions disrupt the liquid-vapor-like interfacial hydrogen bonding network.

  2. Fractionation of soil gases by diffusion of water vapor, gravitational settling, and thermal diffusion

    SciTech Connect (OSTI)

    Severinghaus, J.P.; Bender, M.L. [Univ. of Rhode Island, RI (United States)] [Univ. of Rhode Island, RI (United States); Keeling, R.F. [Scripps Institution of Oceanography, LaJolla, CA (United States)] [Scripps Institution of Oceanography, LaJolla, CA (United States); Broecker, W.S. [Lamont-Doherty Earth Observatory, Palisades, NY (United States)] [Lamont-Doherty Earth Observatory, Palisades, NY (United States)

    1996-03-01

    Air sampled from the moist unsaturated zone in a sand dune exhibits depletion in the heavy isotopes of N{sub 2} and O{sub 2}. We propose that the depletion is caused by a diffusive flux of water vapor out of the dune, which sweeps out the other gases, forcing them to diffuse back into the dune. The heavy isotopes of N{sub 2} and O{sub 2} diffuse back more slowly, resulting in a steady-state depletion of the heavy isotopesin the dune interior. We predict the effect`s magnitude with molecular diffusion theory and reproduce it in a laboratory simulation, finding good agreement between field, theory, and lab. The magnitude of the effect is governed by the ratio of the binary diffusivities against water vapor of a pair of gases, and increases {approximately} linearly with the difference between the water vapor mole fraction of the site and the advectively mixed reservoir with which it is in diffusive contact (in most cases the atmosphere). 32 refs., 1 fig., 3 tabs.

  3. Warm Springs Water District District Heating Low Temperature...

    Open Energy Info (EERE)

    Warm Springs Water District District Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Warm Springs Water District District Heating Low Temperature...

  4. ARM: G-band (183 GHz) Vapor Radiometer profiler: 15 microwave brightness temperatures from 170.0 to 183.3 GHz

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    G-band (183 GHz) Vapor Radiometer profiler: 15 microwave brightness temperatures from 170.0 to 183.3 GHz

  5. G-Band Vapor Radiometer Profiler (GVRP) Handbook

    SciTech Connect (OSTI)

    Caddeau, MP

    2010-06-23

    The G-Band Vapor Radiometer Profiler (GVRP) provides time-series measurements of brightness temperatures from 15 channels between 170 and 183.310 GHz. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. Channels between 170.0 and 176.0 GHz are particularly sensitive to the presence of liquid water. The sensitivity to water vapor of the 183.31-GHz line is approximately 30 times higher than at the frequencies of the two-channel microwave radiometer (MWR) for a precipitable water vapor (PWV) amount of less than 2.5 mm. Measurements from the GVRP instrument are therefore especially useful during low-humidity conditions (PWV < 5 mm). In addition to integrated water vapor and liquid water, the GVRP can provide low-resolution vertical profiles of water vapor in very dry conditions.

  6. Numerical modeling of water injection into vapor-dominated geothermal reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    s equation, which expresses vapor pressure as a function ofT+ 273.15 ) ( is the vapor pressure lowering (VPL) factor.P sat is the saturated vapor pressure of bulk aqueous phase,

  7. Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-11-01

    A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

  8. Method of condensing vaporized water in situ to treat tar sands formations

    DOE Patents [OSTI]

    Hsu, Chia-Fu (Rijswijk, NL)

    2010-03-16

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  9. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  10. Comparison of Water Vapor Measurements by Airborne Sun Photometer and Diode Laser Hygrometer on the NASA DC-8

    SciTech Connect (OSTI)

    Livingston, J. M.; Schmid, Beat; Russell, P. B.; Podolske, James R.; Redemann, Jens; Diskin, G. S.

    2008-10-29

    In January-February 2003 the 14-channel NASA Ames Airborne Tracking Sunphotometer 30 (AATS) and the NASA Langley/Ames Diode Laser Hygrometer (DLH) were flown on the NASA DC-8 aircraft. AATS measured column water vapor on the aircraft-to-sun path, while DLH measured local water vapor in the free stream between the aircraft fuselage and an outboard engine cowling. The AATS and DLH measurements were compared for two DC-8 vertical profiles by differentiating the AATS column measurement and/or integrating the DLH local measurement over the altitude range of each profile (7.7-10 km and 1.2-12.5 km). These comparisons extend, for the first time, tests of AATS water vapor retrievals to altitudes >~6 km and column contents <0.1 g cm-2. To our knowledge this is the first time suborbital spectroscopic water vapor measurements using the 940-nm band have been tested in conditions so high and dry. For both profiles layer water vapor (LWV) from AATS and DLH were highly correlated, with r2 0.998, rms difference 7.2% and bias (AATS minus DLH) 0.9%. For water vapor densities AATS and DLH had r2 0.968, rms difference 27.6%, and bias (AATS minus DLH) -4.2%. These results compare favorably with previous comparisons of AATS water vapor to in situ results for altitudes <~6 km, columns ~0.1 to 5 g cm-2 and densities ~0.1 to 17 g m-3.

  11. Airborne Sun photometer measurements of aerosol optical depth and columnar water vapor during the Puerto Rico Dust Experiment and

    E-Print Network [OSTI]

    Christopher, Sundar A.

    Airborne Sun photometer measurements of aerosol optical depth and columnar water vapor during to within 0.004­0.030 with coincident data obtained with an AERONET Sun/ sky radiometer located on Cabras Dynamics: Remote sensing; KEYWORDS: PRIDE, airborne Sun photometer, aerosol optical depth, columnar water

  12. Isotope and Temperature Effects in Liquid Water Probed by Soft...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Wednesday, 24 September 2008 00:00...

  13. Vapor Barriers or Vapor Diffusion Retarders | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    retarders. Materials such as rigid foam insulation, reinforced plastics, aluminum, and stainless steel are relatively resistant to water vapor diffusion. These types of vapor...

  14. Effects of drinking water temperature on water consumption, respiration rates, and body temperatures of lactating Holstein cows in summer 

    E-Print Network [OSTI]

    Lanham, Jeffrey Kent

    1985-01-01

    EFFECTS OF DRINKING WATER TEMPERATURE ON WATER CONSUMPTION, RESPIRATION RATES, AND BODY TEMPERATURES OF LACTATING HOLSTEIN COWS IN SUMMER A Thesis by JEFFREY KENT LANHAM Submitted to the Graduate College of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1985 Major Subject: Nutrition EFFECTS OF DRINKING WATER TEMPERATURE ON WATER CONSUMPTION, RESPIRATION RATES, AND BODY TEMPERATURES OF LACTATING HOLSTEIN COWS IN SUMMER A Thesis...

  15. Treatment of Produced Water Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Lynn E. Katz; Kerry A. Kinney; Robert S. Bowman; Enid J. Sullivan; Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Craig R. Altare

    2006-01-31

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. Produced waters typically contain a high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component as well as chemicals added during the oil-production process. It has been estimated that a total of 14 billion barrels of produced water were generated in 2002 from onshore operations (Veil, 2004). Although much of this produced water is disposed via reinjection, environmental and cost considerations can make surface discharge of this water a more practical means of disposal. In addition, reinjection is not always a feasible option because of geographic, economic, or regulatory considerations. In these situations, it may be desirable, and often necessary from a regulatory viewpoint, to treat produced water before discharge. It may also be feasible to treat waters that slightly exceed regulatory limits for re-use in arid or drought-prone areas, rather than losing them to reinjection. A previous project conducted under DOE Contract DE-AC26-99BC15221 demonstrated that surfactant modified zeolite (SMZ) represents a potential treatment technology for produced water containing BTEX. Laboratory and field experiments suggest that: (1) sorption of benzene, toluene, ethylbenzene and xylenes (BTEX) to SMZ follows linear isotherms in which sorption increases with increasing solute hydrophobicity; (2) the presence of high salt concentrations substantially increases the capacity of the SMZ for BTEX; (3) competitive sorption among the BTEX compounds is negligible; and, (4) complete recovery of the SMZ sorption capacity for BTEX can be achieved by air sparging the SMZ. This report summarizes research for a follow on project to optimize the regeneration process for multiple sorption/regeneration cycles, and to develop and incorporate a vapor phase bioreactor (VPB) system for treatment of the off-gas generated during air sparging. To this end, we conducted batch and column laboratory SMZ and VPB experiments with synthetic and actual produced waters. Based on the results of the laboratory testing, a pilot scale study was designed and conducted to evaluate the combined SMZ/VPB process. An economic and regulatory feasibility analysis was also completed as part of the current study to assess the viability of the process for various water re-use options.

  16. Diode laser spectroscopic measurements and theoretical calculations of line parameters of nitrogen broadened water vapor overtone transitions in the

    E-Print Network [OSTI]

    Gamache, Robert R.

    Diode laser spectroscopic measurements and theoretical calculations of line parameters of nitrogen region are measured by using a tunable diode laser spectrometer. Water vapor is kept at its saturated. in the presence of perturbers like oxygen, nitrogen, air, argon etc [11-13]. 3 #12;FTIR and diode laser

  17. Retrieval of Moisture from Simulated GPS Slant-Path Water Vapor Observations Using 3DVAR with Anisotropic Recursive Filters

    E-Print Network [OSTI]

    Xue, Ming

    Retrieval of Moisture from Simulated GPS Slant-Path Water Vapor Observations Using 3DVAR with Anisotropic Recursive Filters HAIXIA LIU AND MING XUE Center for Analysis and Prediction of Storms, and School) ABSTRACT Anisotropic recursive filters are implemented within a three-dimensional variational data

  18. Nature of the Mesoscale Boundary Layer Height and Water Vapor Variability Observed 14 June 2002 during the IHOP_2002 Campaign

    E-Print Network [OSTI]

    Nature of the Mesoscale Boundary Layer Height and Water Vapor Variability Observed 14 June 2002, Boulder, Colorado (Manuscript received 4 September 2007, in final form 23 June 2008) ABSTRACT Mesoscale at the mesoscale, with the spatial pattern and the magnitude of the variability changing from day to day. On 14

  19. TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM

    SciTech Connect (OSTI)

    LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

    2003-10-01

    Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and assembled to treat the off-gas from the SMZ regeneration process. These columns will be used both in the laboratory and in the proposed field testing to be conducted next year. Innocula for the columns that degrade all of the BTEX columns have been developed.

  20. Continuous ultra-thin MoS{sub 2} films grown by low-temperature physical vapor deposition

    SciTech Connect (OSTI)

    Muratore, C. [Department of Chemical and Materials Engineering, University of Dayton, Dayton, Ohio 45469 (United States); Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Hu, J. J.; Bultman, J. E.; Jespersen, M. L. [Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); University of Dayton Research Institute, Dayton, Ohio 45469 (United States); Wang, B.; Haque, M. A. [Department of Mechanical and Nuclear Engineering, Pennsylvania State University, College Park, Pennsylvania 16802 (United States); Shamberger, P. J.; McConney, M. E.; Naguy, R. D.; Voevodin, A. A. [Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States)

    2014-06-30

    Uniform growth of pristine two dimensional (2D) materials over large areas at lower temperatures without sacrifice of their unique physical properties is a critical pre-requisite for seamless integration of next-generation van der Waals heterostructures into functional devices. This Letter describes a vapor phase growth technique for precisely controlled synthesis of continuous, uniform molecular layers of MoS{sub 2} on silicon dioxide and highly oriented pyrolitic graphite substrates of over several square centimeters at 350?°C. Synthesis of few-layer MoS{sub 2} in this ultra-high vacuum physical vapor deposition process yields materials with key optical and electronic properties identical to exfoliated layers. The films are composed of nano-scale domains with strong chemical binding between domain boundaries, allowing lift-off from the substrate and electronic transport measurements from contacts with separation on the order of centimeters.

  1. Low temperature junction growth using hot-wire chemical vapor deposition

    DOE Patents [OSTI]

    Wang, Qi; Page, Matthew; Iwaniczko, Eugene; Wang, Tihu; Yan, Yanfa

    2014-02-04

    A system and a process for forming a semi-conductor device, and solar cells (10) formed thereby. The process includes preparing a substrate (12) for deposition of a junction layer (14); forming the junction layer (14) on the substrate (12) using hot wire chemical vapor deposition; and, finishing the semi-conductor device.

  2. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W.

    2014-05-14

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 Å away from the surface.

  3. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01

    and transport properties of carbon dioxide for molecularinterfacial properties of binary carbon dioxide – waterCarbon dioxide’s liquid—vapor coexistence curve and critical properties

  4. Water Power Calculator Temperature and Analog Input/Output Module Ambient Temperature Testing

    SciTech Connect (OSTI)

    Mark D. McKay

    2011-02-01

    Water Power Calculator Temperature and Analog input/output Module Ambient Temperature Testing A series of three ambient temperature tests were conducted for the Water Power Calculator development using the INL Calibration Laboratory’s Tenney Environmental Chamber. The ambient temperature test results demonstrate that the Moore Industries Temperature Input Modules, Analog Input Module and Analog Output Module, ambient temperature response meet or exceed the manufactures specifications

  5. Solar High Temperature Water-Splitting Cycle with Quantum Boost

    SciTech Connect (OSTI)

    Taylor, Robin; Davenport, Roger; Talbot, Jan; Herz, Richard; Genders, David; Symons, Peter; Brown, Lloyd

    2014-04-25

    A sulfur family chemical cycle having ammonia as the working fluid and reagent was developed as a cost-effective and efficient hydrogen production technology based on a solar thermochemical water-splitting cycle. The sulfur ammonia (SA) cycle is a renewable and sustainable process that is unique in that it is an all-fluid cycle (i.e., with no solids handling). It uses a moderate temperature solar plant with the solar receiver operating at 800°C. All electricity needed is generated internally from recovered heat. The plant would operate continuously with low cost storage and it is a good potential solar thermochemical hydrogen production cycle for reaching the DOE cost goals. Two approaches were considered for the hydrogen production step of the SA cycle: (1) photocatalytic, and (2) electrolytic oxidation of ammonium sulfite to ammonium sulfate in aqueous solutions. Also, two sub-cycles were evaluated for the oxygen evolution side of the SA cycle: (1) zinc sulfate/zinc oxide, and (2) potassium sulfate/potassium pyrosulfate. The laboratory testing and optimization of all the process steps for each version of the SA cycle were proven in the laboratory or have been fully demonstrated by others, but further optimization is still possible and needed. The solar configuration evolved to a 50 MW(thermal) central receiver system with a North heliostat field, a cavity receiver, and NaCl molten salt storage to allow continuous operation. The H2A economic model was used to optimize and trade-off SA cycle configurations. Parametric studies of chemical plant performance have indicated process efficiencies of ~20%. Although the current process efficiency is technically acceptable, an increased efficiency is needed if the DOE cost targets are to be reached. There are two interrelated areas in which there is the potential for significant efficiency improvements: electrolysis cell voltage and excessive water vaporization. Methods to significantly reduce water evaporation are proposed for future activities. Electrolysis membranes that permit higher temperatures and lower voltages are attainable. The oxygen half cycle will need further development and improvement.

  6. A new photocatalytic material was synthesized to investigate its performance for the photoreduction of carbon dioxide (CO2) in the presence of water vapor (H2O) to valuable products

    E-Print Network [OSTI]

    of carbon dioxide (CO2) in the presence of water vapor (H2O) to valuable products such as carbon monoxide-TiO2 nano-composite for the reduction of carbon dioxide in the presence of water vapor

  7. Effects of Storage Container Color and Shading on Water Temperature 

    E-Print Network [OSTI]

    Clayton, James Brent

    2012-07-16

    of the middle storage container block ........................................................................................................... 16 5 Mean water temperature inside storage containers painted with different colors kept at varying... of every organism together, while giving that organism flexibility and structure. Water is the universal solvent, carrying oxygen, nutrients, and other important chemicals needed by organisms. Water moderates the earth?s temperature, allowing life...

  8. Numerical modeling of water injection into vapor-dominated geothermal reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    Renewable Energy, Office of Geothermal Technologies, of theTransport in Fractured Geothermal Reservoirs, Geothermics,Depletion of Vapor-Dominated Geothermal Reservoirs, Lawrence

  9. Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects

    E-Print Network [OSTI]

    Chickos, James S.

    Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor pressures as a function of temperature and enthalpies of vaporization of a series of both liquid and solid. The applicability of this technique is first demonstrated by reproducing the vapor pressure isotope effect

  10. Water vapor in the spectrum of the extrasolar planet HD 189733b. II. The eclipse

    SciTech Connect (OSTI)

    Crouzet, Nicolas; McCullough, Peter R.; Deming, Drake; Madhusudhan, Nikku

    2014-11-10

    Spectroscopic observations of exoplanets are crucial to infer the composition and properties of their atmospheres. HD 189733b is one of the most extensively studied exoplanets and is a cornerstone for hot Jupiter models. In this paper, we report the dayside emission spectrum of HD 189733b in the wavelength range 1.1-1.7 ?m obtained with the Hubble Space Telescope Wide Field Camera 3 (WFC3) in spatial scan mode. The quality of the data is such that even a straightforward analysis yields a high-precision Poisson noise-limited spectrum: the median 1? uncertainty is 57 ppm per 0.02 ?m bin. We also build a white-light curve correcting for systematic effects and derive an absolute eclipse depth of 96 ± 39 ppm. The resulting spectrum shows marginal evidence for water vapor absorption, but can also be well explained by a blackbody spectrum. However, the combination of these WFC3 data with previous Spitzer photometric observations is best explained by a dayside atmosphere of HD 189733b with no thermal inversion and a nearly solar or subsolar H{sub 2}O abundance in a cloud-free atmosphere. Alternatively, this apparent subsolar abundance may be the result of clouds or hazes that future studies need to investigate.

  11. Occurrence of Low-Temperature Geothermal Waters in the United...

    Open Energy Info (EERE)

    Occurrence of Low-Temperature Geothermal Waters in the United States, in Assessment of Geothermal Resources of the United States -- 1978 Jump to: navigation, search OpenEI...

  12. The effect of varying oven temperatures and residence times on thermal desorption of n-hexane and 1-hexene from diffusive organic vapor dosimeters 

    E-Print Network [OSTI]

    Steele, Kenneth Garnett

    1981-01-01

    Temperatures Averaged Over Three Days and Three Residence Times 54 LIST OF FIGURES 1. Breakdown of 3M Organic Vapor Monitor 2. Removing Draft Shield and Retaining Ring from 3M Organic Vapor Monitor 3. Elutriation Cap in place on 3M Monitor 4. Inserting 3... to various organic vapors used in the manufac- ture of a wide variety of products was commonplace. As man's awareness grew regarding the adverse effects of these substances on the individuals using them, the need for reliable monitoring methods to measure...

  13. The Effect of High Temperature Annealing on the Grain Characteristics of a Thin Chemical Vapor Deposition Silicon Carbide Layer.

    SciTech Connect (OSTI)

    Isabella J van Rooyen; Philippus M van Rooyen; Mary Lou Dunzik-Gougar

    2013-08-01

    The unique combination of thermo-mechanical and physiochemical properties of silicon carbide (SiC) provides interest and opportunity for its use in nuclear applications. One of the applications of SiC is as a very thin layer in the TRi-ISOtropic (TRISO) coated fuel particles for high temperature gas reactors (HTGRs). This SiC layer, produced by chemical vapor deposition (CVD), is designed to withstand the pressures of fission and transmutation product gases in a high temperature, radiation environment. Various researchers have demonstrated that macroscopic properties can be affected by changes in the distribution of grain boundary plane orientations and misorientations [1 - 3]. Additionally, various researchers have attributed the release behavior of Ag through the SiC layer as a grain boundary diffusion phenomenon [4 - 6]; further highlighting the importance of understanding the actual grain characteristics of the SiC layer. Both historic HTGR fission product release studies and recent experiments at Idaho National Laboratory (INL) [7] have shown that the release of Ag-110m is strongly temperature dependent. Although the maximum normal operating fuel temperature of a HTGR design is in the range of 1000-1250°C, the temperature may reach 1600°C under postulated accident conditions. The aim of this specific study is therefore to determine the magnitude of temperature dependence on SiC grain characteristics, expanding upon initial studies by Van Rooyen et al, [8; 9].

  14. Method and apparatus for simulating atmospheric absorption of solar energy due to water vapor and CO{sub 2}

    DOE Patents [OSTI]

    Sopori, B.L.

    1995-06-20

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.

  15. Method and apparatus for simulating atomospheric absorption of solar energy due to water vapor and CO.sub.2

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Denver, CO)

    1995-01-01

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth's surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO.sub.2 and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO.sub.2 and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO.sub.2 and moisture.

  16. Ultra-narrow ferromagnetic resonance in organic-based thin films grown via low temperature chemical vapor deposition

    SciTech Connect (OSTI)

    Yu, H.; Harberts, M.; Adur, R.; Hammel, P. Chris; Johnston-Halperin, E., E-mail: ejh@physics.osu.edu, E-mail: epstein@physics.osu.edu [Department of Physics, The Ohio State University, Columbus, Ohio 43210-1117 (United States); Lu, Y. [Department of Chemistry, The Ohio State University, Columbus, Ohio 43210-1173 (United States); Epstein, A. J., E-mail: ejh@physics.osu.edu, E-mail: epstein@physics.osu.edu [Department of Physics, The Ohio State University, Columbus, Ohio 43210-1117 (United States); Department of Chemistry, The Ohio State University, Columbus, Ohio 43210-1173 (United States)

    2014-07-07

    We present the growth of thin films of the organic-based ferrimagnetic semiconductor V[TCNE]{sub x} (x???2, TCNE: tetracyanoethylene) via chemical vapor deposition. Under optimized growth conditions, we observe a significant increase in magnetic homogeneity, as evidenced by a Curie temperature above 600?K and sharp magnetization switching. Further, ferromagnetic resonance studies reveal a single resonance with full width at half maximum linewidth of 1.4?G, comparable to the narrowest lines measured in inorganic magnetic materials and in contrast to previous studies that showed multiple resonance features. These characteristics are promising for the development of high frequency electronic devices that take advantage of the unique properties of this organic-based material, such as the potential for low cost synthesis combined with low temperature and conformal deposition on a wide variety of substrates.

  17. Isobaric vapor-liquid equilibria of the water + 1-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-09-01

    Isobaric vapor-liquid equilibria for the water + 1-propanol system are reported at 30, 60, and 100 kPa. The results were found to be thermodynamically consistent according to Van Ness-Byer-Gibbs, Kojima, and Wisniak methods. The system shows a minimum boiling azeotrope, and the azeotropic composition is scarcely shifted with pressure. Results were compared with literature values. The data were correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC liquid-phase activity coefficient models.

  18. High-temperature calcium vapor cell for spectroscopy on the P1 intercombination line

    E-Print Network [OSTI]

    Hart, Gus

    valves and glass-to-metal seals. We have observed over 50% absorption in a single pass through the cell- nitely above room temperature. Using this low-temperature estimate we calculated that a single pass

  19. Low temperature barrier wellbores formed using water flushing

    DOE Patents [OSTI]

    McKinzie, II; John, Billy [Houston, TX; Keltner, Thomas Joseph [Spring, TX

    2009-03-10

    A method of forming an opening for a low temperature well is described. The method includes drilling an opening in a formation. Water is introduced into the opening to displace drilling fluid or indigenous gas in the formation adjacent to a portion of the opening. Water is produced from the opening. A low temperature fluid is applied to the opening.

  20. The Laboratory Complex for the Calibration of Photometers Using the Optical Method for Determination of the Water Vapor Content in the Earth Atmosphere

    E-Print Network [OSTI]

    Galkin, V D; Nikanorova, I N; Leiterer, U; Niebert, T; Alekseeva, G A; Novikov, V V; Ilyin, G N; Pakhomov, V P

    2010-01-01

    We describe the laboratory complex for the calibration of photometers that are used in weather service to measure the water vapor content in the Earth atmosphere. The complex was built up in Pulkovo Observatory and developed within the framework of collaboration between Pulkovo Observatory and Lindenberg Meteorological Observatory (Meteorologisches Observatorium Lindenberg - Richard-A{\\ss}mann-Observatorium, Lindenberg, Germany). It is used to obtain calibration dependences for individual devices, and also to develop and compare various methods of construction of calibration dependences. These techniques are based on direct calibration of the photometers, on the use of spectral laboratory transmission functions for water vapor, on calculation methods using spectroscopical databases for individual lines. We hope that when the parameters of the equipment are taken into account in detail and new results for the absorptive power of water vapor are used, the accuracy of determination of the water vapor content in ...

  1. Correlation between water-vapor transport from the Gulf of Mexico and precipitation in the eastern United States 

    E-Print Network [OSTI]

    Wright, John Vinson

    1973-01-01

    CORRELATION BETWEEN WATER-V'POR TRANSPORT FROM THE GULF OF MEXICO AND PR CIPITATION IN THE EASTERN UNITED STATES A Thesis John Vinson Wright, Jr. Subiaitted to the Gw. . duate College ot Texas A&M University in parti ' fulfillment... of the reourres, ent for the degre oi MASTER OF SCIENCE May 197B Ma]or Sub]ect: Meteorology CORRELATION BETWEEN WATER-VAPOR TRANSPORT FROM THE GULF OF MEXICO AND PRECIPITATION IN THE EASTERN UNITED STATFS A Thesis by John Vinson Wright, Jr. Approved ac...

  2. Treatment of Produced Waters Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Lynn E. Katz; Kerry A. Kinney; R. S. Bowman; E. J. Sullivan

    2005-03-11

    This report summarizes work performed on this project from October 2004 through March 2005. In previous work, a surfactant modified zeolite (SMZ) was shown to be an effective system for removing BTEX contaminants from produced water. Additional work on this project demonstrated that a compost-based biofilter could biodegrade the BTEX contaminants found in the SMZ regeneration waste gas stream. However, it was also determined that the BTEX concentrations in the waste gas stream varied significantly during the regeneration period and the initial BTEX concentrations were too high for the biofilter to handle effectively. A series of experiments were conducted to determine the feasibility of using a passive adsorption column placed upstream of the biofilter to attenuate the peak gas-phase VOC concentrations delivered to the biofilter during the SMZ regeneration process. In preparation for the field test of the SMZ/VPB treatment system in New Mexico, a pilot-scale SMZ system was also designed and constructed during this reporting period. Finally, a cost and feasibility analysis was also completed. To investigate the merits of the passive buffering system during SMZ regeneration, two adsorbents, SMZ and granular activated carbon (GAC) were investigated in flow-through laboratory-scale columns to determine their capacity to handle steady and unsteady VOC feed conditions. When subjected to a toluene-contaminated air stream, the column containing SMZ reduced the peak inlet 1000 ppmv toluene concentration to 630 ppmv at a 10 second contact time. This level of buffering was insufficient to ensure complete removal in the downstream biofilter and the contact time was longer than desired. For this reason, using SMZ as a passive buffering system for the gas phase contaminants was not pursued further. In contrast to the SMZ results, GAC was found to be an effective adsorbent to handle the peak contaminant concentrations that occur early during the SMZ regeneration process. At a one second residence time, the GAC bed reduced peak contaminant concentrations by 97%. After the initial peak, the inlet VOC concentration in the SMZ regeneration gas stream drops exponentially with time. During this period, the contaminants on the GAC subsequently desorbed at a nearly steady rate over the next 45 hours resulting in a relatively steady effluent concentration of approximately 25 ppm{sub v}. This lower concentration is readily degradable by a downstream vapor phase biofilter (VPB) and the steady nature of the feed stream will prevent the biomass in the VPB from enduring starvation conditions between SMZ regeneration cycles. Repetitive sorption and desorption cycles that would be expected in the field were also investigated. It was determined that although the GAC initially lost some VOC sorption capacity, the adsorption and desorption profiles stabilized after approximately 6 cycles indicating that a GAC bed should be suitable for continuous operation. In preparation for the pilot field testing of the SMZ/VPB system, design, ''in-house'' construction and testing of the field system were completed during this project period. The design of the SMZ system for the pilot test was based on previous investigations by the PI's in Wyoming, 2002 and on analyses of the produced water at the field site in New Mexico. The field tests are scheduled for summer, 2005. A cost survey, feasibility of application and cost analyses were completed to investigate the long term effectiveness of the SMZ/VPB system as a method of treating produced water for re-use. Several factors were investigated, including: current costs to treat and dispose of produced water, end-use water quality requirements, and state and federal permitting requirements.

  3. Water injection as a means for reducing non-condensible andcorrosive gases in steam produced from vapor-dominated reservoirs

    SciTech Connect (OSTI)

    Pruess, Karsten; Spycher, Nicolas; Kneafsey, Timothy J.

    2007-01-08

    Large-scale water injection at The Geysers, California, hasgenerated substantial benefits in terms of sustaining reservoir pressuresand production rates, as well as improving steam composition by reducingthe content of non-condensible gases (NCGs). Two effects have beenrecognized and discussed in the literature as contributing to improvedsteam composition, (1) boiling of injectate provides a source of "clean"steam to production wells, and (2) pressurization effects induced byboiling of injected water reduce upflow of native steam with large NCGconcentrations from depth. In this paper we focus on a possibleadditional effect that could reduce NCGs in produced steam by dissolutionin a condensed aqueous phase.Boiling of injectate causes pressurizationeffects that will fairly rapidly migrate outward, away from the injectionpoint. Pressure increases will cause an increase in the saturation ofcondensed phase due to vapor adsorption on mineral surfaces, andcapillary condensation in small pores. NCGs will dissolve in theadditional condensed phase which, depending upon their solubility, mayreduce NCG concentrations in residual steam.We have analyzed thepartitioning of HCl between vapor and aqueous phases, and have performednumerical simulations of injection into superheated vapor zones. Oursimulations provide evidence that dissolution in the condensed phase canindeed reduce NCG concentrations in produced steam.

  4. Sulfurization of carbon surface for vapor phase mercury removal I: Effect of temperature and sulfurization protocol

    E-Print Network [OSTI]

    Borguet, Eric

    a fixed bed reactor system to determine the effects of sorbent properties, temperature (200­800 °C; Impregnation; Temperature programmed desorption; Surface properties 1. Introduction Hydrogen sulfide, such as the Integrated Gasification Combined Cycle (IGCC) process [4], and the coal gas cleaning process [5], removal

  5. Isobaric vapor-liquid equilibria of the water + 2-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica] [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica

    1996-05-01

    Distillation is perhaps the separation process most widely used in the chemical processing industry. The correct design of distillation columns requires the availability of accurate and, if possible, thermodynamically consistent vapor-liquid equilibria (VLE) data. The present work is part of a project studying the effect of pressure on the behavior of the azeotropic point in mixtures in which at least one component is an alcohol. Isobaric vapor-liquid equilibria were obtained for the water + 2-propanol system at 30, 60, and 100 kPa. The activity coefficients were found to be thermodynamically consistent by the methods of Van Ness-Byer-Gibbs, Kojima, and Wisniak. The data were correlated with five liquid phase activity coefficient models (Margules, Van Laar, Wilson, NRTL, and UNIQUAC).

  6. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

    1985-01-01

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  7. Temperatures, heat flow, and water chemistry from drill holes...

    Open Energy Info (EERE)

    Temperatures, heat flow, and water chemistry from drill holes in the Raft River geothermal system, Cassia County, Idaho Jump to: navigation, search OpenEI Reference LibraryAdd to...

  8. Energy Savings with High Temperature Water Generation Systems 

    E-Print Network [OSTI]

    Manicke, A. C.

    1982-01-01

    rapidly. This paper will present and evaluate the use of a high temperature water (HTW) system and a conventional steam system. Solid, liquid and gaseous fuel applications will be presented along with the application of HTW to Cogeneration Systems. Life...

  9. Wavelet-Based Multiresolution Analysis of Wivenhoe Dam Water Temperatures

    E-Print Network [OSTI]

    Percival, Don

    Wavelet-Based Multiresolution Analysis of Wivenhoe Dam Water Temperatures Don Percival Applied monitoring program recently upgraded with perma- nent installation of vertical profilers at Lake Wivenhoe dam in a subtropical dam as a function of time and depth · will concentrate on a 600+ day segment of temperature fluc

  10. 4-62 The water in a rigid tank is cooled until the vapor starts condensing. The initial pressure in the tank is to be determined.

    E-Print Network [OSTI]

    Bahrami, Majid

    4-32 4-62 The water in a rigid tank is cooled until the vapor starts condensing. The initial pressure in the tank is to be determined. Analysis This is a constant volume process (v = V /m = constant@21 qgvvv (Table A-4) since the vapor starts condensing at 150qC. Then from Table A-6, H2O T1= 250qC P1

  11. Analysis of the Application of the Optical Method to the Measurements of the Water Vapor Content in the Atmosphere. I. Basic Concepts

    E-Print Network [OSTI]

    Galkin, V D; Alekseeva, G A; Berger, F -H; Leiterer, U; Naebert, T; Nikanorova, I N; Novikov, V V; Pakhomov, V P; Sal'nikov, I B

    2010-01-01

    We retrieved the total content of the atmospheric water vapor from extensive sets of photometric data obtained since 1995 at Lindenberg Meteorological Observatory with star and sun photometers. Different methods of determination of the empirical parameters that are necessary for the retrieval are discussed. The instruments were independently calibrated using laboratory measurements made at Pulkovo Observatory with the VKM-100 multi-pass vacuum cell. The empirical parameters were also calculated by the simulation of the atmospheric absorption by water vapor, using the MODRAN-4 program package for different model atmospheres. The results are compared to those presented in the literature, obtained with different instruments and methods of the retrieval. The accuracy of the empirical parameters used for the power approximation that links the water vapor content with the observed absorption is analyzed. Currently, the calibration and measurement errors yield the uncertainty of about 10% in the total column water v...

  12. First order structure function analysis of statistical scale invariance n the AIRS Observed Water Vapor Field

    E-Print Network [OSTI]

    Placella, S.A.

    2014-01-01

    to a rapid in- crease in water potential when dry soil is2011) Validation of heavy-water stable isotope probing forrainfall also causes acute water potential changes that are

  13. Numerical modeling of water injection into vapor-dominated geothermal reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    Effects in the Simulation of Water Injection into DepletedPorous Media, Advances in Water Resources, Vol. 27, pp.CA 94720 K_Pruess@lbl.gov Abstract Water injection has been

  14. Effect of Water Vapor on the 1100oC Oxidation Behavior of Plasma-Sprayed TBCs with HVOF NiCoCrAlX Bond Coatings

    SciTech Connect (OSTI)

    Haynes, James A; Unocic, Kinga A; Pint, Bruce A

    2013-01-01

    With the goal of investigating the reported detrimental effect of water vapor on thermal barrier coating (TBC) performance, furnace cycle experiments were conducted in dry O2 and air with 10 and 50% water vapor at 1100 C. The TBC systems evaluated were air plasma-sprayed (APS), yttria-stabilized zirconia (YSZ) top coatings with high velocity oxy fuel (HVOF)-deposited NiCoCrAlY or NiCoCrAlYHfSi bond coating. Average TBC lifetime was reduced by ~30% in air with 10% water vapor compared to cycling in dry O2, using 1h cycle durations. Superalloy substrates with Y and La additions also were investigated but showed no statistical change in the average TBC lifetime compared to the base CMSX4 superalloy. In all cases, the bond coating with Hf and Si additions increased YSZ lifetime by 20% or more. Experiments that increased water vapor to 50% showed no further decrease in TBC lifetime. Increasing the cycle frequency to 100h resulted in a large increase in TBC lifetime, especially for the NiCoCrAlYHfSi bond coatings. Co-doping the NiCoCrAl bond coat with Y and Hf was beneficial to TBC lifetime, but did not mitigate the detrimental impact of water vapor.

  15. The Hydrated Proton at the Water Liquid/Vapor Interface Matt K. Petersen, Srinivasan S. Iyengar, Tyler J. F. Day, and Gregory A. Voth*,

    E-Print Network [OSTI]

    Iyengar, Srinivasan S.

    The Hydrated Proton at the Water Liquid/Vapor Interface Matt K. Petersen, Srinivasan S. Iyengar ReceiVed: July 23, 2004; In Final Form: August 22, 2004 The hydrated proton was studied at the water the migration of the excess proton to and about the interface through the fluctuating bond topology described

  16. Atmosphere and Ocean: Water (drought topic begins at slide 26)

    E-Print Network [OSTI]

    water: the `vapor pressure' exerted by H2O molecules increases exponenEally with temperature ( it boils when that vapor pressure equals the ambient pressure: Humans & Nature 23 May 2012 GFD Lab: www.ocean.washington.edu/research/gfd #12;water vapor

  17. Numerical modeling of water injection into vapor-dominated geothermal reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    reaches the saturation temperature at prevailing reservoirsaturation profiles at different times in the top reservoir

  18. Interactions of gaseous HNO3 and water with individual and mixed alkyl self-assembled monolayers at room temperature.

    E-Print Network [OSTI]

    Nishino, Noriko; Hollingsworth, Scott A; Stern, Abraham C; Roeselová, Martina; Tobias, Douglas J; Finlayson-Pitts, Barbara J

    2014-01-01

    of even small amounts of water vapor (revised Fig.  of the CI and POZ by water under tropospheric http://mechanism and the effects of water and irradiation remain 

  19. Using radiative transfer models to study the atmospheric water vapor content and to eliminate telluric lines from high-resolution optical spectra

    E-Print Network [OSTI]

    Gardini, A; Pérez, E; Quesada, J A; Funke, B

    2012-01-01

    The Radiative Transfer Model (RTM) and the retrieval algorithm, incorporated in the SCIATRAN 2.2 software package developed at the Institute of Remote Sensing/Institute of Enviromental Physics of Bremen University (Germany), allows to simulate, among other things, radiance/irradiance spectra in the 2400-24 000 {\\AA} range. In this work we present applications of RTM to two case studies. In the first case the RTM was used to simulate direct solar irradiance spectra, with different water vapor amounts, for the study of the water vapor content in the atmosphere above Sierra Nevada Observatory. Simulated spectra were compared with those measured with a spectrometer operating in the 8000-10 000 {\\AA} range. In the second case the RTM was used to generate telluric model spectra to subtract the atmospheric contribution and correct high-resolution stellar spectra from atmospheric water vapor and oxygen lines. The results of both studies are discussed.

  20. Analytical and experimental study of a liquid desiccant heat and mass exchanger operating near water freezing temperature

    E-Print Network [OSTI]

    Pineda Vargas, Sergio Manuel

    2009-01-01

    exchanger operating near water freezing temperature A Thesisoperating near water freezing temperature Copyright © 2009operating near water freezing temperature Sergio M. Pineda

  1. SIZE AND TEMPERATURE DEPENDENCE IN THE FAR-IR SPECTRA OF WATER ICE PARTICLES

    SciTech Connect (OSTI)

    Medcraft, Chris; McNaughton, Don; Thompson, Chris D. [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Appadoo, Dominique [Australian Synchrotron, Blackburn Road, Clayton, Victoria 3168 (Australia); Bauerecker, Sigurd [Institut fuer Physikalische und Theoretische Chemie, Technische Universitaet Braunschweig, Hans-Sommer-Strasse 10, D-38106 Braunschweig (Germany); Robertson, Evan G., E-mail: E.Robertson@latrobe.edu.au [Department of Chemistry and La Trobe Institute of Molecular Sciences, La Trobe University, Bundoora, Victoria 3086 (Australia)

    2012-10-10

    Spectra of water-ice aerosol particles have been measured in the far-IR region using synchrotron radiation. The particles in the nanoscale size regime of 1-100 nm were formed by rapid collisional cooling at temperatures ranging from 4 to 190 K. The spectra show the characteristic bands centered near 44 {mu}m (230 cm{sup -1}) and 62 {mu}m (160 cm{sup -1}) associated with the intermolecular lattice modes of crystalline ice at all temperatures, in contrast to previous studies of thin films formed by vapor deposition where amorphous ice is generated below 140 K. The bands shift to higher wavenumber values as the temperature is reduced, consistent with the trend seen in earlier studies, but in our experiments the actual peak positions in the aerosol particle spectra are consistently higher by ca. 4 cm{sup -1}. This finding has implications for the potential use of these spectral features as a temperature probe. The particle sizes are small enough for their spectra to be free of scattering effects, and therefore provide a means to assess imaginary refractive index values obtained through Kramers-Kronig analyses of thin film spectra.

  2. Vapor Transport in Dry Soils

    SciTech Connect (OSTI)

    Gee, Glendon W.; Ward, Anderson L.

    2001-11-16

    Water-vapor movement in soils is a complex process, controlled by both diffusion and advection and influenced by pressure and thermal gradients acting across tortuous flow paths. Wide-ranging interest in water-vapor transport includes both theoretical and practical aspects. Just how pressure and thermal gradients enhance water-vapor flow is still not completely understood and subject to ongoing research. Practical aspects include dryland farming (surface mulching), water harvesting (aerial wells), fertilizer placement, and migration of contaminants at waste-sites. The following article describes the processes and practical applications of water-vapor transport, with emphasis on unsaturated (dry) soil systems.

  3. Water Body Temperature Model for Assessing Climate Change Impacts

    E-Print Network [OSTI]

    climatological data and thermal pollution from river-based power plants to historical river flow data in orderWater Body Temperature Model for Assessing Climate Change Impacts on Thermal Cooling Ken Strzepek Climate Change Impacts on Thermal Cooling Ken Strzepek* , Charles Fant* , Yohannes Gebretsadik , Megan

  4. Technologies for Upgrading Light Water Reactor Outlet Temperature

    SciTech Connect (OSTI)

    Daniel S. Wendt; Piyush Sabharwall; Vivek Utgikar

    2013-07-01

    Nuclear energy could potentially be utilized in hybrid energy systems to produce synthetic fuels and feedstocks from indigenous carbon sources such as coal and biomass. First generation nuclear hybrid energy system (NHES) technology will most likely be based on conventional light water reactors (LWRs). However, these LWRs provide thermal energy at temperatures of approximately 300°C, while the desired temperatures for many chemical processes are much higher. In order to realize the benefits of nuclear hybrid energy systems with the current LWR reactor fleets, selection and development of a complimentary temperature upgrading technology is necessary. This paper provides an initial assessment of technologies that may be well suited toward LWR outlet temperature upgrading for powering elevated temperature industrial and chemical processes during periods of off-peak power demand. Chemical heat transformers (CHTs) are a technology with the potential to meet LWR temperature upgrading requirements for NHESs. CHTs utilize chemical heat of reaction to change the temperature at which selected heat sources supply or consume thermal energy. CHTs could directly utilize LWR heat output without intermediate mechanical or electrical power conversion operations and the associated thermodynamic losses. CHT thermal characteristics are determined by selection of the chemical working pair and operating conditions. This paper discusses the chemical working pairs applicable to LWR outlet temperature upgrading and the CHT operating conditions required for providing process heat in NHES applications.

  5. Column closure studies of lower tropospheric aerosol and water vapor during ACE-Asia using airborne Sun photometer and airborne in situ

    E-Print Network [OSTI]

    Sun photometer and airborne in situ and ship-based lidar measurements B. Schmid,1 D. A. Hegg,2 J. Wang (closure) between solar beam attenuation by aerosols and water vapor measured by airborne Sun photometry agreement with airborne Sun photometry in the marine boundary layer but is considerably lower in layers

  6. Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Heterocycles and Related Compounds

    E-Print Network [OSTI]

    Chickos, James S.

    Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures The vaporization enthalpies and vapor pressures of the liqiud phase from T ) 298.15 K to T ) 500 K of a series in the literature was measured on a hydrated form. Vapor pressures and normal boiling temperatures for the liquid

  7. Vaporization Enthalpy and Vapor Pressure of Valproic Acid by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    Vaporization Enthalpy and Vapor Pressure of Valproic Acid by Correlation Gas Chromatography Joe A-propylpentanoic acid) is reported, and the vapor pressures of a series on aliphatic carboxylic acids are used to evaluate its vapor pressure as a function of temperature. The vaporization enthalpy was derived

  8. Ocean Water Vapor and Cloud Burden Trends Derived from the Topex Microwave Radiometer

    E-Print Network [OSTI]

    Ruf, Christopher

    algorithm is a log-linear regression algorithm with coefficients that are stratified by wind speed and water. TMR OBSERVATIONS The TMR flew in a 10-day non-sun-synchronous exact repeat orbit with an inclination

  9. The Use of Water Vapor as a Refrigerant: Impact of Cycle Modifications on Commercial Viability

    SciTech Connect (OSTI)

    Brandon F. Lachner, Jr.; Gregory F. Nellis; Douglas T. Reindl

    2004-08-30

    This project investigated the economic viability of using water as the refrigerant in a 1000-ton chiller application. The most attractive water cycle configuration was found to be a flash-intercooled, two-stage cycle using centrifugal compressors and direct contact heat exchangers. Component level models were developed that could be used to predict the size and performance of the compressors and heat exchangers in this cycle as well as in a baseline, R-134a refrigeration cycle consistent with chillers in use today. A survey of several chiller manufacturers provided information that was used to validate and refine these component models. The component models were integrated into cycle models that were subsequently used to investigate the life-cycle costs of both an R-134a and water refrigeration cycle. It was found that the first cost associated with the water as a refrigerant cycle greatly exceeded the savings in operating costs associated with its somewhat higher COP. Therefore, the water refrigeration cycle is not an economically attractive option to today's R-134a refrigeration system. There are a number of other issues, most notably the requirements associated with purging non-condensable gases that accumulate in a direct contact heat exchanger, which will further reduce the economic viability of the water cycle.

  10. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    1996-12-31

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  11. Cloud Liquid Water Measurements

    E-Print Network [OSTI]

    Delene, David J.

    of heat to vaporize drops. Power is supplied to coil to maintain a constant temperature. P ­ Total Power #12;Wet Power Term Energy is transferred to heat droplets to to the boiling point and vaporize;Liquid Water Content Formula Combine the Wet and Dry Power Terms PC Ts-TaPv x Mldv[Lvcw Tv-Ta] · M

  12. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  13. The vapor pressures of explosives

    SciTech Connect (OSTI)

    Ewing, Robert G.; Waltman, Melanie J.; Atkinson, David A.; Grate, Jay W.; Hotchkiss, Peter

    2013-01-05

    The vapor pressures of many explosive compounds are extremely low and thus determining accurate values proves difficult. Many researchers, using a variety of methods, have measured and reported the vapor pressures of explosives compounds at single temperatures, or as a function of temperature using vapor pressure equations. There are large variations in reported vapor pressures for many of these compounds, and some errors exist within individual papers. This article provides a review of explosive vapor pressures and describes the methods used to determine them. We have compiled primary vapor pressure relationships traceable to the original citations and include the temperature ranges for which they have been determined. Corrected values are reported as needed and described in the text. In addition, after critically examining the available data, we calculate and tabulate vapor pressures at 25 °C.

  14. Isobaric vapor-liquid equilibria for binary and ternary systems composed of water, 1-propanol, and 2-propanol at 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-11-01

    Isobaric vapor-liquid equilibria data were obtained for the 2-propanol + 1-propanol binary system and the water + 1-propanol + 2-propanol ternary system at 100 kPa. The data were found to be thermodynamically consistent according to the Van Ness-Byer-Gibbs method for the binary system and according to the McDermott-Ellis method for the ternary one. The binary system is well represented by assuming ideal behavior. The binary interaction parameters obtained from this and previous work are used to predict the vapor-liquid equilibrium for the ternary system using the UNIQUAC, NRTL, and Wilson models. The ternary system is well predicted from binary data.

  15. Extremely Luminous Water Vapor Emission from a Type 2 Quasar at Redshift z = 0.66

    E-Print Network [OSTI]

    Richard Barvainis; Robert Antonucci

    2005-06-10

    A search for water masers in 47 Sloan Digital Sky Survey Type 2 quasars using the Green Bank Telescope has yielded a detection at a redshift of z = 0.660. This maser is more than an order of magnitude higher in redshift than any previously known and, with a total isotropic luminosity of 23,000 L_sun, also the most powerful. The presence and detectability of water masers in quasars at z ~ 0.3-0.8 may provide a better understanding of quasar molecular tori and disks, as well as fundamental quasar and galaxy properties such as black hole masses. Water masers at cosmologically interesting distances may also eventually provide, via direct distance determinations, a new cosmological observable for testing the reality and properties of dark energy, currently inferred primarily through Type 1a supernova measurements.

  16. Retrieval of water vapor profiles over ocean using SSM/I and SSM/T-2 

    E-Print Network [OSTI]

    Blankenship, Clay Bruce

    1997-01-01

    The SSM/T-2 (Special Sensor Microwave Temperature-2) and SSM/I (Special Sensor Microwave Imager) are two microwave radiometers aboard the DMSP (Defense Meteorological Space Program) series of satellites. The SSM/T-2 was designed for retrieval...

  17. Temperature dependence of bulk viscosity in water using acoustic spectroscopy

    E-Print Network [OSTI]

    M. J. Holmes; N. G. Parker; M. J. W. Povey

    2010-02-16

    Despite its fundamental role in the dynamics of compressible fluids, bulk viscosity has received little experimental attention and there remains a paucity of measured data. Acoustic spectroscopy provides a robust and accurate approach to measuring this parameter. Working from the Navier-Stokes model of a compressible fluid one can show that the bulk viscosity makes a significant and measurable contribution to the frequency-squared acoustic attenuation. Here we employ this methodology to determine the bulk viscosity of Millipore water over a temperature range of 7 to 50 degrees Celsius. The measured attenuation spectra are consistent with the theoretical predictions, while the bulk viscosity of water is found to be approximately three times larger than its shear counterpart, reinforcing its significance in acoustic propagation. Moreover, our results demonstrate that this technique can be readily and generally applied to fluids to accurately determine their temperature dependent bulk viscosities.

  18. Two-day wave observations of UARS Microwave Limb Sounder mesospheric water vapor and temperature

    E-Print Network [OSTI]

    Limpasuvan, Varavut

    of phase. Poleward heat flux associated with upward wave energy propagation in the Southern Hemisphere Carolina, USA Dong L. Wu Jet Propulsion Laboratory, California Institute of Technology, Pasadena

  19. Improved Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58 84 168Organic

  20. Measurements of the Infrared SpectraLines of Water Vapor at Atmospheric Temperatures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on dark matter By SarahMODELING CLOUD1 H( 7Measurements of the

  1. Synthesis of SiO{sub 2}/?-SiC/graphite hybrid composite by low temperature hot filament chemical vapor deposition

    SciTech Connect (OSTI)

    Zhang, Zhikun; Bi, Kaifeng; Liu, Yanhong; Qin, Fuwen; Liu, Hongzhu; Bian, Jiming; Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences, Shanghai 200050 ; Zhang, Dong; Miao, Lihua; Department of Computer and Mathematical Basic Teaching, Shenyang Medical College, Shenyan 110034

    2013-11-18

    ?-SiC thin films were synthesized directly on graphite by hot filament chemical vapor deposition at low temperature. SiH{sub 4} diluted in hydrogen was employed as the silicon source, while graphite was functioned as both substrate and carbon source for the as-grown ?-SiC films. X-ray diffraction and Fourier transform infrared analysis indicate that SiO{sub 2}/?-SiC/graphite hybrid composite was formed after post annealing treatment, and its crystalline quality can be remarkably improved under optimized annealing conditions. The possible growth mechanism was proposed based on in situ etching of graphite by reactive hydrogen radicals at the atomic level.

  2. Water mist injection in oil shale retorting

    DOE Patents [OSTI]

    Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

    1980-07-30

    Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

  3. Diagnosis of Solar Water Heaters Using Solar Storage Tank Surface Temperature Data: Preprint

    SciTech Connect (OSTI)

    Burch, J.; Magnuson, L.; Barker, G.; Bullwinkel, M.

    2009-04-01

    Study of solar water heaters by using surface temperature data of solar storage tanks to diagnose proper operations.

  4. Control of the water fugacity at high pressures and temperatures: Applications to the incorporation mechanisms of water in olivine

    E-Print Network [OSTI]

    Control of the water fugacity at high pressures and temperatures: Applications to the incorporation t A new method is developed to control water fugacity at a fixed pressure and temperature. We use two. The chemical environment of the olivine crystal was controlled by the water fugacity buffer, the Ni­NiO oxygen

  5. Simulating the water content and temperature changes in an experimental embankment using meteorological data

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Simulating the water content and temperature changes in an experimental embankment using on the soil response such as changes in water content and temperature as well as the induced vertical from the base of embankment. In this study, the changes in temperature, volumetric water content

  6. Covariation of coastal water temperature and microbial pollution at interannual to tidal periods

    E-Print Network [OSTI]

    Winant, Clinton D.

    Covariation of coastal water temperature and microbial pollution at interannual to tidal periods. G. Monismith (2004), Covariation of coastal water temperature and microbial pollution at interannual the relationship between water temperature and fecal pollution in the surf zone at Huntington and Newport Beach

  7. Airborne thermal remote sensing for water temperature assessment in rivers and streams

    E-Print Network [OSTI]

    Brown, Sally

    ). Stream temperature monitoring presents challenges for water resource managers charged with the taskAirborne thermal remote sensing for water temperature assessment in rivers and streams Christian E are needed to assess spatial patterns of stream temperature at scales relevant to issues in water quality

  8. Low-temperature growth and orientational control in RuO{sub 2} thin films by metal-organic chemical vapor deposition

    SciTech Connect (OSTI)

    Bai, G.R.; Wang, A.; Foster, C.M.; Vetrone, J.; Patel, J.; Wu, X.

    1996-08-01

    For growth temperatures in the range of 275 C to 425 C, highly conductive RuO{sub 2} thin films with either (110)- or (101)-textured orientations have been grown by metal-organic chemical vapor deposition (MOCVD) on both SiO{sub 2}/Si(001) and Pt/Ti/SiO{sub 2}/Si(001) substrates. Both the growth temperature and growth rate were used to control the type and degree of orientational texture of the RuO{sub 2} films. In the upper part of this growth temperature range ({approximately} 350 C) and at a low growth rate (< 30 {angstrom}/min.), the RuO{sub 2} films favored a (110)-textured. In contrast, at the lower part of this growth temperature range ({approximately} 300 C) and at a high growth rate (> 30 {angstrom}/min.), the RuO{sub 2} films favored a (101)-textured. In contrast, a higher growth temperatures (> 425 C) always produced randomly-oriented polycrystalline films. For either of these low-temperature growth processes, the films produced were crack-free, well-adhered to the substrates, and had smooth, specular surfaces. Atomic force microscopy showed that the films had a dense microstructure with an average grain size of 50--80 nm and a rms. surface roughness of {approximately} 3--10 nm. Four-probe electrical transport measurements showed that the films were highly conductive with resistivities of 34--40 {micro}{Omega}-cm ({at} 25 C).

  9. Monitoring water stress using time series of observed to unstressed surface temperature difference

    E-Print Network [OSTI]

    Gentine, Pierre

    Monitoring water stress using time series of observed to unstressed surface temperature difference to monitor stress have shifted from establishing empirical relationships between combined vegetation cover/temperature surface temperature as a baseline to monitor water stress. The unstressed temperature is the equilibrium

  10. Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids

    E-Print Network [OSTI]

    Chickos, James S.

    Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids Joe A vapor pressures of both the subcooled liquid and solid state for those materials that are solids at T/K = 298.15. Equations for the prediction of vapor pressure from T/K = 298.15 to the boiling temperature

  11. ARM Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden Documentation Data Management Facility009 ARM Orientation454063Value-AddedARM

  12. ARM - Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow,ProductstoacessProductsrlprofrlprofmerge1turnPlainsVisiting the SGPWater

  13. Analysis of temperatures and water levels in wells to estimatealluvial aquifer hydraulic conductivities

    SciTech Connect (OSTI)

    Su, Grace W.; Jasperse, James; Seymour, Donald; Constantz, Jim

    2003-06-19

    Well water temperatures are often collected simultaneously with water levels; however, temperature data are generally considered only as a water quality parameter and are not utilized as an environmental tracer. In this paper, water levels and seasonal temperatures are used to estimate hydraulic conductivities in a stream-aquifer system. To demonstrate this method, temperatures and water levels are analyzed from six observation wells along an example study site, the Russian River in Sonoma County, California. The range in seasonal ground water temperatures in these wells varied from <0.28C in two wells to {approx}88C in the other four wells from June to October 2000. The temperature probes in the six wells are located at depths between 3.5 and 7.1 m relative to the river channel. Hydraulic conductivities are estimated by matching simulated ground water temperatures to the observed ground water temperatures. An anisotropy of 5 (horizontal to vertical hydraulic conductivity) generally gives the best fit to the observed temperatures. Estimated conductivities vary over an order of magnitude in the six locations analyzed. In some locations, a change in the observed temperature profile occurred during the study, most likely due to deposition of fine-grained sediment and organic matter plugging the streambed. A reasonable fit to this change in the temperature profile is obtained by decreasing the hydraulic conductivity in the simulations. This study demonstrates that seasonal ground water temperatures monitored in observation wells provide an effective means of estimating hydraulic conductivities in alluvial aquifers.

  14. Water transport inside a single-walled carbon nanotube driven by temperature gradient

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Water transport inside a single-walled carbon nanotube driven by temperature gradient J. Shiomi that the water cluster is transported with the average acceleration proportional to the temperature gradient of the confined water is sufficient to realize the transport. Particularly for the system with hydrophobic

  15. Interpreting the temperature of water at cold springs and the importance of gravitational potential energy

    E-Print Network [OSTI]

    Manga, Michael

    the temperature of water at cold springs and the importance of gravitational potential energy, Water Resour. ResInterpreting the temperature of water at cold springs and the importance of gravitational potential energy Michael Manga and James W. Kirchner Department of Earth and Planetary Science, University

  16. Effects of pressure, temperature, and hydrogen during graphene growth on SiC(0001) using propane-hydrogen chemical vapor deposition

    SciTech Connect (OSTI)

    Michon, A.; Vezian, S.; Roudon, E.; Lefebvre, D.; Portail, M.; Zielinski, M.; Chassagne, T.

    2013-05-28

    Graphene growth from a propane flow in a hydrogen environment (propane-hydrogen chemical vapor deposition (CVD)) on SiC differentiates from other growth methods in that it offers the possibility to obtain various graphene structures on the Si-face depending on growth conditions. The different structures include the (6{radical}3 Multiplication-Sign 6{radical}3)-R30 Degree-Sign reconstruction of the graphene/SiC interface, which is commonly observed on the Si-face, but also the rotational disorder which is generally observed on the C-face. In this work, growth mechanisms leading to the formation of the different structures are studied and discussed. For that purpose, we have grown graphene on SiC(0001) (Si-face) using propane-hydrogen CVD at various pressure and temperature and studied these samples extensively by means of low energy electron diffraction and atomic force microscopy. Pressure and temperature conditions leading to the formation of the different structures are identified and plotted in a pressure-temperature diagram. This diagram, together with other characterizations (X-ray photoemission and scanning tunneling microscopy), is the basis of further discussions on the carbon supply mechanisms and on the kinetics effects. The entire work underlines the important role of hydrogen during growth and its effects on the final graphene structure.

  17. Vapor Pressures and Vaporization Enthalpies of the n-Alkanes from C21 to C30 at T ) 298.15 K by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    Vapor Pressures and Vaporization Enthalpies of the n-Alkanes from C21 to C30 at T ) 298.15 K pressures of these n-alkanes from T ) 298.15 to 575 K. The vapor pressure and vaporization enthalpy results-alkanes exhibit very low vapor pressures at ambient temperatures, vapor pressure measurement for most

  18. Water temperature and acidity regime shape dominance and beta-diversity patterns in the plant communities of springs

    E-Print Network [OSTI]

    Schweiger, Andreas H.; Beierkuhnlein, Carl

    2014-01-01

    related to spring types? Fresh- water Science, 31, 481–498.Beierkuhnlein — Acidity, water temperature and oligarchySpring fen vegetation and water chemistry in the Western

  19. M. Bahrami ENSC 461 (S 11) Gas Vapor Mixtures and HVAC 1 Gas Vapor Mixtures and HVAC

    E-Print Network [OSTI]

    Bahrami, Majid

    to the vapor pressure: Tdp = Tsat@ Pv Sling Psychrometer: a rotating set of thermometers one of which measuresM. Bahrami ENSC 461 (S 11) Gas Vapor Mixtures and HVAC 1 Gas Vapor Mixtures and HVAC Atmospheric air normally contains some water vapor (moisture). The dry-air contains no water. Although the amount

  20. Effect of temperature and glycerol on the hydrogen-bond dynamics of water

    E-Print Network [OSTI]

    Pavan K. GhattyVenkataKrishna; Edward C. Uberbacher

    2015-08-27

    The effect of glycerol, water and glycerol-water binary mixtures on the structure and dynamics of biomolecules has been well studied. However, a lot remains to be learned about the effect of varying glycerol concentration and temperature on the dynamics of water. We have studied the effect of concentration and temperature on the hydrogen bonded network formed by water molecules. A strong correlation between the relaxation time of the network and average number of hydrogen bonds per water molecules was found. The radial distribution function of water oxygen and hydrogen atoms clarifies the effect of concentration on the structure and clustering of water.

  1. New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells

    Broader source: Energy.gov [DOE]

    Presentation on New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  2. The effect of water content, cooling rate, and growth temperature on the freezing temperature of 4 Tillandsia species 

    E-Print Network [OSTI]

    Hagar, Christopher Flint

    1990-01-01

    the exotherm initiation temperatures (EIT) of leaf sections. The effect of 2 growth temperatures (5 and 25oC) on the absolute water content and EIT of T. recurvata and T. usneoides was also determined. All p * * pt T. mb'1 ', f o t ld temperatures at 80... minimum winter temperatures of their different northern boundaries. Cooling rate affected the EIT of T. recurvata and T. d* b t t T. b~l' T. o tll . L f t of the former 2 species froze at colder temperatures when cooled at a rate of 25oC per hour than...

  3. Numerical Analysis of Water Temperature Distribution in the Tank of ASHPWH it ha Cylindrical Condenser 

    E-Print Network [OSTI]

    Wang, D.; Shan, S.; Wang, R.

    2006-01-01

    Air source heat pump water heaters (ASHPWH) are becoming increasingly popular for saving energy, protecting the environment and security purposes. The water temperature distribution in the tank is an important parameter for an ASHPWH. This paper...

  4. Species-specific phenological responses to winter temperature and precipitation in a water-limited ecosystem

    E-Print Network [OSTI]

    Mazer, SJ; Gerst, KL; Matthews, ER; Evenden, A

    2015-01-01

    to winter temperature and precipitation in a water-limitedthe timing and magnitude of precipitation (i.e. , larger butof monthly and annual precipitation (PPT, mm), mean monthly

  5. Vapor generation methods for explosives detection research

    SciTech Connect (OSTI)

    Grate, Jay W.; Ewing, Robert G.; Atkinson, David A.

    2012-12-01

    The generation of calibrated vapor samples of explosives compounds remains a challenge due to the low vapor pressures of the explosives, adsorption of explosives on container and tubing walls, and the requirement to manage (typically) multiple temperature zones as the vapor is generated, diluted, and delivered. Methods that have been described to generate vapors can be classified as continuous or pulsed flow vapor generators. Vapor sources for continuous flow generators are typically explosives compounds supported on a solid support, or compounds contained in a permeation or diffusion device. Sources are held at elevated isothermal temperatures. Similar sources can be used for pulsed vapor generators; however, pulsed systems may also use injection of solutions onto heated surfaces with generation of both solvent and explosives vapors, transient peaks from a gas chromatograph, or vapors generated by s programmed thermal desorption. This article reviews vapor generator approaches with emphasis on the method of generating the vapors and on practical aspects of vapor dilution and handling. In addition, a gas chromatographic system with two ovens that is configurable with up to four heating ropes is proposed that could serve as a single integrated platform for explosives vapor generation and device testing. Issues related to standards, calibration, and safety are also discussed.

  6. Plant Water Use and Growth in Response to Soil Salinity in Irrigated Agriculture

    E-Print Network [OSTI]

    Runkle, Benjamin Reade

    2009-01-01

    air temperature and vapor pressure deficit is hard tounder higher temperatures and vapor pressure deficits thanThe headspace vapor pressure and sample temperature then

  7. Means and method for vapor generation

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1984-01-01

    A liquid, in heat transfer contact with a surface heated to a temperature well above the vaporization temperature of the liquid, will undergo a multiphase (liquid-vapor) transformation from 0% vapor to 100% vapor. During this transition, the temperature driving force or heat flux and the coefficients of heat transfer across the fluid-solid interface, and the vapor percentage influence the type of heating of the fluid--starting as "feedwater" heating where no vapors are present, progressing to "nucleate" heating where vaporization begins and some vapors are present, and concluding with "film" heating where only vapors are present. Unstable heating between nucleate and film heating can occur, accompanied by possibly large and rapid temperature shifts in the structures. This invention provides for injecting into the region of potential unstable heating and proximate the heated surface superheated vapors in sufficient quantities operable to rapidly increase the vapor percentage of the multiphase mixture by perhaps 10-30% and thereby effectively shift the multiphase mixture beyond the unstable heating region and up to the stable film heating region.

  8. Diversity of deep-water cetaceans in relation to temperature: implications for ocean warming

    E-Print Network [OSTI]

    Myers, Ransom A.

    LETTER Diversity of deep-water cetaceans in relation to temperature: implications for ocean warming anthropogenic change. Here we analyse a large, long-term data set of sightings of deep-water cetaceans from that deep-water oceanic communities that dominate > 60% of the planetÕs surface may reorganize in response

  9. Near-field thermal radiative transfer and thermoacoustic effects from vapor plumes produced by pulsed CO{sub 2} laser ablation of bulk water

    SciTech Connect (OSTI)

    Kudryashov, S. I.; Lyon, Kevin; Allen, S. D.

    2006-12-15

    Submillimeter deep heating of bulk water by thermal radiation from ablative water plumes produced by a 10.6 {mu}m transversely excited atmospheric CO{sub 2} laser and the related acoustic generation has been studied using a contact time-resolved photoacoustic technique. Effective penetration depths of thermal radiation in water were measured as a function of incident laser fluence and the corresponding plume temperatures were estimated. The near-field thermal and thermoacoustic effects of thermal radiation in laser-ablated bulk water and their potential near-field implications are discussed.

  10. NMR Studies on the Temperature-Dependent Dynamics of Confined Water

    E-Print Network [OSTI]

    Matthias Sattig; Stefan Reutter; Franz Fujara; Mayke Werner; Gerd Buntkowsky; Michael Vogel

    2014-07-16

    We use $^2$H NMR to study the rotational motion of supercooled water in silica pores of various diameters, specifically, in the MCM-41 materials C10, C12, and C14. Combination of spin-lattice relaxation, line-shape, and stimulated-echo analyses allows us to determine correlation times in very broad time and temperature ranges. For the studied pore diameters, 2.1-2.9 nm, we find two crossovers in the temperature-dependent correlation times of liquid water upon cooling. At 220-230 K, a first kink in the temperature dependence is accompanied by a solidification of a fraction of the confined water, implying that the observed crossover is due to a change from bulk-like to interface-dominated water dynamics, rather than to a liquid-liquid phase transition. Moreover, the results provide evidence that $\\alpha$ process-like dynamics is probed above the crossover temperature, whereas $\\beta$ process-like dynamics is observed below. At 180-190 K, we find a second change of the temperature dependence, which resembles that reported for the $\\beta$ process of supercooled liquids during the glass transition, suggesting a value of $T_g\\!\\approx\\!185$ K for interface-affected liquid water. In the high-temperature range, $T\\!>\\!225$ K, the temperature dependence of water reorientation is weaker in the smaller C10 pores than in the larger C12 and C14 pores, where it is more bulk-like, indicating a significant effect of the silica confinement on the $\\alpha$ process of water in the former 2.1 nm confinement. By contrast, the temperature dependence of water reorientation is largely independent of the confinement size and described by an Arrhenius law with an activation energy of $E_a\\!\\approx\\!0.5\\ $eV in the low-temperature range, $T\\!water.

  11. Jan 26, 2005 MAE 4263 Vapor Power Systems

    E-Print Network [OSTI]

    Jan 26, 2005 MAE 4263 Vapor Power Systems Problem 1-4: Draw a symbolic turbine and indicate the integral Equation 1-18 Wout = m Z T2 T1 cpdT where cp for air is obtained from Equation 1-19 Wout = m Z T2 at the correct temperature (neglecting compressibility of liquid water) from page 779 wideal = 0:0010171 m3 kg (1

  12. Response of fish to different simulated rates of water temperature increase

    SciTech Connect (OSTI)

    Wike, L.D.; Tuckfield, R.C.

    1992-08-01

    We initiated this study to define the limits of effluent-temperature rate increases during reactor restart, which will help minimize fish kills. We constructed an apparatus for exposing fish to various temperature-increase regimens and conducted two experiments based on information from system tests and scoping runs. In the rate experiment, we acclimated the fish to 20{degree}C, and then raised the temperature to 40{degree}C at varying rates. Because scoping runs and literature suggested that acclimation temperature may affect temperature-related mortality, we conducted an acclimation experiment. We acclimated the fish to various temperatures, then raised the temperatures to 39--40{degree}C at a rate of 2{degree}C every 12 hours. Based on the analysis of the data, we recommend temperature-increase rates during reactor restart of 2.5{degree}C every nine hours if ambient water temperatures are over 20{degree}C. If water temperatures are at or below 20{degree}C, we recommend temperature-increase rates of 2.5{degree}C every 12 hours. No regulation of temperature is required after effluent temperatures reach 40{degree}C. We recommend further studies, including expanded testing with the simulation system and behavioral and bioenergetic investigations that may further refine acceptable rates of effluent-temperature increases.

  13. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  14. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  15. The Progress on Low-Cost, High-Quality, High-Temperature Superconducting Tapes Deposited by the Combustion Chemical Vapor Deposition Process

    SciTech Connect (OSTI)

    Shoup, S.S.; White, M.K.; Krebs, S.L.; Darnell, N.; King, A.C.; Mattox, D.S.; Campbell, I.H.; Marken, K.R.; Hong, S.; Czabaj, B.; Paranthaman, M.; Christen, H.M.; Zhai, H.-Y. Specht, E.

    2008-06-24

    The innovative Combustion Chemical Vapor Deposition (CCVD) process is a non-vacuum technique that is being investigated to enable next generation products in several application areas including high-temperature superconductors (HTS). In combination with the Rolling Assisted Biaxially Textured Substrate (RABiTS) technology, the CCVD process has significant promise to provide low-cost, high-quality lengths of YBCO coated conductor. Over 100 meter lengths of both Ni and Ni-W (3 at. Wt.%) substrates with a surface roughness of 12-18 nm were produced. The CCVD technology has been used to deposit both buffer layer coatings as well as YBCO superconducting layers. Buffer layer architecture of strontium titanate (SrTiO{sub 3}) and ceria (CeO{sub 2}) have been deposited by CCVD on textured nickel substrates and optimized to appropriate thicknesses and microstructures to provide templates for growing PLD YBCO with a J{sub c} of 1.1 MA/cm{sup 2} at 77 K and self-field. The CCVD buffer layers have been scaled to meter plus lengths with good epitaxial uniformity along the length. A short sample cut from one of the lengths enabled high critical current density PLD YBCO. Films of CCVD YBCO superconductors have been grown on single crystal substrates with critical current densities over 1 MA/cm{sup 2}. In addition, superconducting YBCO films with an I{sub c} of 60 A/cm-width (J{sub c} = 1.5 MA/cm{sup 2}) were grown on ORNL RABiTS (CeO{sub 2}/YSZ/Y{sub 2}O{sub 3}/Ni/Ni-3W) using CCVD process.

  16. Low-Temperature Geothermal Water in Utah: A compilation of Data...

    Open Energy Info (EERE)

    Low-Temperature Geothermal Water in Utah: A compilation of Data for Thermal Wells and Springs Through 1993 Jump to: navigation, search OpenEI Reference LibraryAdd to library Web...

  17. Design and Experiments of a Solar Low-temperature Hot Water Floor Radiant Heating System 

    E-Print Network [OSTI]

    Wu, Z.; Li, D.

    2006-01-01

    The solar low-temperature hot water floor radiant heating system combines solar energy heating with floor radiant heating. This kind of environmental heating way not only saves fossil resources and reduces pollution, but ...

  18. Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

  19. Water Body Temperature Model for Assessing Climate Change Impacts on Thermal Cooling

    E-Print Network [OSTI]

    Strzepek, K.

    We develop and test a physically based semi-Lagrangian water body temperature model to apply climatological data and thermal pollution from river-based power plants to historical river flow data in order to better understand ...

  20. Large Field Erected and Packaged High Temperature Water (HTW) Generators for Coal Firing 

    E-Print Network [OSTI]

    Boushell, C. C.

    1980-01-01

    The purpose of the paper is to disseminate information on the energy savings possible with High Temperature Water (HTW) for heating and industrial process application and to provide information on coal fired HTW generator ...

  1. Water heat pipe frozen startup and shutdown transients with internal temperature, pressure and visual observations 

    E-Print Network [OSTI]

    Reinarts, Thomas Raymond

    1989-01-01

    WATER HEAT PIPE FROZEN STARTUP AND SHUTDOWN TRANSIENTS WITH INTERNAL TEMPERATURE, PRESSURE AND VISUAL OBSERVATIONS A Thesis by THOMAS RAYMOND REINARTS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1989 Major Subject: Nuclear Engineering WATER HEAT PIPE FROZEN STARTUP AND SHUTDOWN TRANSIENTS WITH INTERNAL TEMPERATURE, PRESSURE AND VISUAL OBSERVATIONS A Thesis THOMAS RAYMOND REINARTS...

  2. A combined droplet train and ambient pressure photoemission spectrometer for the investigation of liquid/vapor interfaces

    E-Print Network [OSTI]

    Starr, David E.

    2008-01-01

    ambient conditions the vapor pressure of water or aqueousrange (e.g. , the equilibrium vapor pressure of water at itsUHV conditions due to the vapor pressure of the liquids, but

  3. Molecular tagging thermometry for transient temperature mapping within a water droplet

    E-Print Network [OSTI]

    Hu, Hui

    temperature measurements within a small water droplet over a solid surface. For MTT measurement, a pulsed-induced phosphorescence is imaged at two successive times after the same laser excitation pulse. The temperature measurements of liquid droplets for combustion applications [1­3]. Laser- induced phosphorescence (LIP

  4. Calibration factor of track etch detectors at different temperatures of water 

    E-Print Network [OSTI]

    Yasmeen, Nuzhat

    1997-01-01

    Research was performed to determine track density as a function of radon exposure in water and exposure temperature for the track etch detectors Kodak LR II 5 Type 2 and CR-39. Films were submerged in water containing a known concentration...

  5. Influence of Water Content and Temperature on Molecular Mobility and Intracellular Glasses in Seeds and Pollen1

    E-Print Network [OSTI]

    Hemminga, Marcus A.

    Influence of Water Content and Temperature on Molecular Mobility and Intracellular Glasses in Seeds heating. This temperature increased with decreasing water content of the samples. Differential scanning water content, the molecular mobility reached a minimum, and increased again at very low water content

  6. Supraoptimal root-zone temperature effects on water use of three Cercis spp 

    E-Print Network [OSTI]

    Lawrence, Beth Jez

    1993-01-01

    Committee: Dr. Jayne M. Zajicek Stem flow rates of three Cercis spp. exposed to supraoptimal root- zone temperatures were characterized in a controlled environment chamber using a water bath to maintain treatment temperatures. Flow rates of sap... in the xylem were measured every 15 sec and averaged over 15 min intervals. Sap flow measurements were correlated to root-zone temperatures recorded during the same time intervals. Whole plant transpiration was also measured gravimetrically. Root...

  7. Control of flow through a vapor generator

    DOE Patents [OSTI]

    Radcliff, Thomas D.

    2005-11-08

    In a Rankine cycle system wherein a vapor generator receives heat from exhaust gases, provision is made to avoid overheating of the refrigerant during ORC system shut down while at the same time preventing condensation of those gases within the vapor generator when its temperature drops below a threshold temperature by diverting the flow of hot gases to ambient and to thereby draw ambient air through the vapor generator in the process. In one embodiment, a bistable ejector is adjustable between one position, in which the hot gases flow through the vapor generator, to another position wherein the gases are diverted away from the vapor generator. Another embodiment provides for a fixed valve ejector with a bias towards discharging to ambient, but with a fan on the downstream side of said vapor generator for overcoming this bias.

  8. The Effect of vapor subcooling on film condensation of metals

    E-Print Network [OSTI]

    Fedorovich, Eugene D.

    1968-01-01

    This work presents an analysis of the interfacial "vapor-condensate" temperature distribution, which includes the effect of subcooling (supersaturation) in the vapor. Experimental data from previous investigators for ...

  9. MEMS Lubrication by In-Situ Tribochemical Reactions From the Vapor Phase.

    SciTech Connect (OSTI)

    Dugger, Michael T.; Asay, David B.; Kim, Seong H.

    2008-01-01

    Vapor Phase Lubrication (VPL) of silicon surfaces with pentanol has been demonstrated. Two potential show stoppers with respect to application of this approach to real MEMS devices have been investigated. Water vapor was found to reduce the effectiveness of VPL with alcohol for a given alcohol concentration, but the basic reaction mechanism observed in water-free environments is still active, and devices operated much longer in mixed alcohol and water vapor environments than with chemisorbed monolayer lubricants alone. Complex MEMS gear trains were successfully lubricated with alcohol vapors, resulting in a factor of 104 improvement in operating life without failure. Complex devices could be made to fail if operated at much higher frequencies than previously used, and there is some evidence that the observed failure is due to accumulation of reaction products at deeply buried interfaces. However, if hypothetical reaction mechanisms involving heated surfaces are valid, then the failures observed at high frequency may not be relevant to operation at normal frequencies. Therefore, this work demonstrates that VPL is a viable approach for complex MEMS devices in conventional packages. Further study of the VPL reaction mechanisms are recommended so that the vapor composition may be optimized for low friction and for different substrate materials with potential application to conventionally fabricated, metal alloy parts in weapons systems. Reaction kinetics should be studied to define effective lubrication regimes as a function of the partial pressure of the vapor phase constituent, interfacial shear rate, substrate composition, and temperature.

  10. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  11. A modeling investigation of canopy-air oxygen isotopic exchange of water vapor and carbon dioxide in a soybean field

    E-Print Network [OSTI]

    Lee, Xuhui

    of terrestrial vegetation to the global CO2 and H2O cycles. In this paper, a simple isotopic land surface model theory of leaf water isotopic composition, a canopy kinetic fractionation factor, and a big with CO2 and H2O exchange in terrestrial ecosystems. Cuntz et al. [2003a, 2003b] and Hoffmann et al. [2004

  12. Diffusion Dynamics of Water Molecules in a LiCl Solution: a Low-Temperature Crossover

    SciTech Connect (OSTI)

    Mamontov, Eugene [ORNL

    2009-01-01

    A quasielastic neutron scattering experiment probing the dynamics of water molecules on the pico- to nanosecond time scale in an aqueous solution of lithium chloride has detected a crossover at about 220-230 K between the high-temperature non-Arrhenius and low-temperature Arrhenius behavior. This is the first experiment where the crossover in the dynamics of water molecules is detected in bulk rather than in confinement. The results suggest that the dynamic crossover observed in the current and many recent experiments is not linked to the specific properties of water; instead, it may represent a more general dynamic transition.

  13. Effects of drinking water temperature on respiration rates, body temperatures, dry matter intake, and milk production in lactating Holstein cows in summer 

    E-Print Network [OSTI]

    Milam, Kyle Zohn

    1985-01-01

    EFFECTS OF DRINKING WATER TEMPERATURE ON RESPIRATION RATES, BODY TEMPERATURES, DRY MATTER INTAKE, AND MILK PRODUCTION IN LACTATING HOLSTEIN COWS IN SUMMER A Thesis by KYLE ZOHN MILAM Submitted to the Graduate College of Texas A&M University... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1985 Major Subject: Nutrition EFFECTS OF DRINKING WATER TEMPERATURE ON RESPIRATION RATES, BODY TEMPERATURES, DRY MATTER INTAKE, AND MILK PRODUCTION IN LACTATING HOLSTEIN...

  14. Dynamic hydrocarbon separation in high-temperature, high-pressure, liquid n-alkane water vapor systems by steam distillation 

    E-Print Network [OSTI]

    Vlierboom, Casper-Maarten

    1987-01-01

    of 345 'F and 126 psia 78 43. Rate Effect on the n-Octane Distribution for a n-Hexane- n-Heptane ? n-Octane Ternary Mixture at Saturated Steam Conditions of 345 F and 126 psia 79 44. Comparison of Experimental and Calculated K-values for a n... Conditions of 345 'F and 126 psia 88 xv1 LIST OF FIGURES (Cont. ) Fig. Page 48. Comparison of n-Hexane K-value for a n-Hexane - n-Heptane- n-Octane Ternary Mixture at Saturated Steam Conditions of 345 'F and 126 psia 49. Comparison of n-Heptane K-value...

  15. Long Term Field Development of a Surfactant Modified Zeolite/Vapor Phase Bioreactor System for Treatment of Produced Waters for Power Generation

    SciTech Connect (OSTI)

    Lynn Katz; Kerry Kinney; Robert Bowman; Enid Sullivan; Soondong Kwon; Elaine Darby; Li-Jung Chen; Craig Altare

    2007-12-31

    The main goal of this research was to investigate the feasibility of using a combined physicochemical/biological treatment system to remove the organic constituents present in saline produced water. In order to meet this objective, a physical/chemical adsorption process was developed and two separate biological treatment techniques were investigated. Two previous research projects focused on the development of the surfactant modified zeolite adsorption process (DE-AC26-99BC15221) and development of a vapor phase biofilter (VPB) to treat the regeneration off-gas from the surfactant modified zeolite (SMZ) adsorption system (DE-FC26-02NT15461). In this research, the SMZ/VPB was modified to more effectively attenuate peak loads and to maintain stable biodegradation of the BTEX constituents from the produced water. Specifically, a load equalization system was incorporated into the regeneration flow stream. In addition, a membrane bioreactor (MBR) system was tested for its ability to simultaneously remove the aromatic hydrocarbon and carboxylate components from produced water. The specific objectives related to these efforts included the following: (1) Optimize the performance VPBs treating the transient loading expected during SMZ regeneration: (a) Evaluate the impact of biofilter operating parameters on process performance under stable operating conditions. (b) Investigate how transient loads affect biofilter performance, and identify an appropriate technology to improve biological treatment performance during the transient regeneration period of an SMZ adsorption system. (c) Examine the merits of a load equalization technology to attenuate peak VOC loads prior to a VPB system. (d) Evaluate the capability of an SMZ/VPB to remove BTEX from produced water in a field trial. (2) Investigate the feasibility of MBR treatment of produced water: (a) Evaluate the biodegradation of carboxylates and BTEX constituents from synthetic produced water in a laboratory-scale MBR. (b) Evaluate the capability of an SMZ/MBR system to remove carboxylates and BTEX from produced water in a field trial. Laboratory experiments were conducted to provide a better understanding of each component of the SMZ/VPB and SMZ/MBR process. Laboratory VPB studies were designed to address the issue of influent variability and periodic operation (see DE-FC26-02NT15461). These experiments examined multiple influent loading cycles and variable concentration loadings that simulate air sparging as the regeneration option for the SMZ system. Two pilot studies were conducted at a produced water processing facility near Farmington, New Mexico. The first field test evaluated SMZ adsorption, SMZ regeneration, VPB buffering, and VPB performance, and the second test focused on MBR and SMZ/MBR operation. The design of the field studies were based on the results from the previous field tests and laboratory studies. Both of the biological treatment systems were capable of removing the BTEX constituents in the laboratory and in the field over a range of operating conditions. For the VPB, separation of the BTEX constituents from the saline aqueous phase yielded high removal efficiencies. However, carboxylates remained in the aqueous phase and were not removed in the combined VPB/SMZ system. In contrast, the MBR was capable of directly treating the saline produced water and simultaneously removing the BTEX and carboxylate constituents. The major limitation of the MBR system is the potential for membrane fouling, particularly when the system is treating produced water under field conditions. The combined process was able to effectively pretreat water for reverse osmosis treatment and subsequent downstream reuse options including utilization in power generation facilities. The specific conclusions that can be drawn from this study are summarized.

  16. Detection of Far-Infrared Water Vapor, Hydroxyl, and Carbon Monoxide Emissions from the Supernova Remnant 3C 391

    E-Print Network [OSTI]

    William T. Reach; Jeonghee Rho

    1998-09-01

    We report the detection of shock-excited far-infrared emission of H2O, OH, and CO from the supernova remnant 3C 391, using the ISO Long-Wavelength Spectrometer. This is the first detection of thermal H2O and OH emission from a supernova remnant. For two other remnants, W~28 and W~44, CO emission was detected but OH was only detected in absorption. The observed H2O and OH emission lines arise from levels within ~400 K of the ground state, consistent with collisional excitation in warm, dense gas created after the passage of the shock front through the dense clumps in the pre-shock cloud. The post-shock gas we observe has a density ~2x10^5 cm^{-3} and temperature 100-1000 K, and the relative abundances of CO:OH:H2O in the emitting region are 100:1:7 for a temperature of 200 K. The presence of a significant column of warm H2O suggests that the chemistry has been significantly changed by the shock. The existence of significant column densities of both OH and H2O, which is at odds with models for non-dissociative shocks into dense gas, could be due to photodissociation of H2O or a mix of fast and slow shocks through regions with different pre-shock density.

  17. Vapor spill pipe monitor

    DOE Patents [OSTI]

    Bianchini, G.M.; McRae, T.G.

    1983-06-23

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

  18. A new water anomaly: the temperature dependence of the proton mean kinetic energy

    E-Print Network [OSTI]

    Davide Flammini; Fabio Bruni; Maria Antonietta Ricci

    2009-01-28

    The mean kinetic energy of protons in water is determined by Deep Inelastic Neutron Scattering experiments, performed above and below the temperature of maximum density and in the supercooled phase. The temperature dependence of this energy shows an anomalous behavior, as it occurs for many water properties. In particular two regions of maximum kinetic energy are identified: the first one, in the supercooled phase in the range 269 K - 272 K, and a second one above 273 K. In both these regions the measured proton kinetic energy exceedes the theoretical prediction based on a semi-classical model. Noteworthy, the proton mean kinetic energy has a maximum at 277 K, the temperature of the maximum density of water. In the supercooled metastable phase the measured mean kinetic energy and the proton momentum distribution clearly indicate proton delocalization between two H-bonded oxygens.

  19. Evaluation of Ice Water Content Retrievals from Cloud Radar Reflectivity and Temperature Using a Large Airborne In Situ Microphysical Database

    E-Print Network [OSTI]

    Protat, Alain

    Evaluation of Ice Water Content Retrievals from Cloud Radar Reflectivity and Temperature Using the performances of the proposed ice water content (IWC)­radar reflectivity Z and IWC­Z­temperature T relationships produce a very different ice water path, spanning an order of magnitude (Stephens et al. 2002). Clouds

  20. Increasing gas hydrate formation temperature for desalination of high salinity produced water with secondary guests

    SciTech Connect (OSTI)

    Cha, Jong-Ho [ORISE; Seol, Yongkoo [U.S. DOE

    2013-01-01

    We suggest a new gas hydrate-based desalination process using water-immiscible hydrate formers; cyclopentane (CP) and cyclohexane (CH) as secondary hydrate guests to alleviate temperature requirements for hydrate formation. The hydrate formation reactions were carried out in an isobaric condition of 3.1 MPa to find the upper temperature limit of CO2 hydrate formation. Simulated produced water (8.95 wt % salinity) mixed with the hydrate formers shows an increased upper temperature limit from ?2 °C for simple CO2 hydrate to 16 and 7 °C for double (CO2 + CP) and (CO2 + CH) hydrates, respectively. The resulting conversion rate to double hydrate turned out to be similar to that with simple CO2 hydrate at the upper temperature limit. Hydrate formation rates (Rf) for the double hydrates with CP and CH are shown to be 22 and 16 times higher, respectively, than that of the simple CO2 hydrate at the upper temperature limit. Such mild hydrate formation temperature and fast formation kinetics indicate increased energy efficiency of the double hydrate system for the desalination process. Dissociated water from the hydrates shows greater than 90% salt removal efficiency for the hydrates with the secondary guests, which is also improved from about 70% salt removal efficiency for the simple hydrates.

  1. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

    1995-09-26

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

  2. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, John P. (Idaho Falls, ID); Larson, Ronald A. (Idaho Falls, ID); Goodrich, Lorenzo D. (Shelley, ID); Hall, Harold J. (Idaho Falls, ID); Stoddard, Billy D. (Idaho Falls, ID); Davis, Sean G. (Idaho Falls, ID); Kaser, Timothy G. (Idaho Falls, ID); Conrad, Frank J. (Albuquerque, NM)

    1995-01-01

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet.

  3. Chemical vapor deposition of antimicrobial polymer coatings

    E-Print Network [OSTI]

    Martin, Tyler Philip, 1977-

    2007-01-01

    There is large and growing interest in making a wide variety of materials and surfaces antimicrobial. Initiated chemical vapor deposition (iCVD), a solventless low-temperature process, is used to form thin films of polymers ...

  4. Chemical vapor infiltration using microwave energy

    DOE Patents [OSTI]

    Devlin, David J. (Los Alamos, NM); Currier, Robert P. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Barbero, Robert S. (Santa Cruz, NM)

    1993-01-01

    A method for producing reinforced ceramic composite articles by means of chemical vapor infiltration and deposition in which an inverted temperature gradient is utilized. Microwave energy is the source of heat for the process.

  5. Effect of GOR, Temperature, and Initial Water Saturation on Solution-Gas Drive in

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    of the stock-tank oil from Hamaca field (in Venezuela) used in our tests are 560,000 cp (at 24°C) and 8 on the effect of initial water saturation, solution GOR, and temperature. We used Hamaca stock-tank crude (from of the paper, we will discuss the results, followed by a number of conclusions. Experimental Live Oil. Stock

  6. Natural Swimming Speed of Dascyllus reticulatus Increases with Water Temperature1 Cigdem Beyan1

    E-Print Network [OSTI]

    Fisher, Bob

    Abstract13 Recent research on the relationship between coral reef water temperature and fish14 swimming; Lough, 2007; Johansen and Jones,18 2011). Evaluating the behaviour of coral reef associated fish species, the speed20 of freely swimming fish in a natural setting is investigated as a function of seasonal21 changes

  7. Model to Predict Temperature and Capillary Pressure Driven Water Transport in PEFCs After Shutdown

    E-Print Network [OSTI]

    Mench, Matthew M.

    Model to Predict Temperature and Capillary Pressure Driven Water Transport in PEFCs After Shutdown-912 Korea To enhance durability and cold-start performance of polymer electrolyte fuel cells PEFCs in the PEFC components after shutdown, which for the first time includes thermo-osmotic flow in the membrane

  8. Warm Air Rises Use food coloring and different temperatures of water to demonstrate that warm air rises.

    E-Print Network [OSTI]

    Johnson, Cari

    Warm Air Rises Use food coloring and different temperatures of water to demonstrate that warm air of the cold water because warm air (or water) is less dense than cold air (or water). This concept can be seen the bottom floor of a house. Less dense warm air settles on top of cold air when winds are light

  9. T emporal structure in the deep-water temperature of four Swiss lakes: A short-term climatic change indicator?

    E-Print Network [OSTI]

    Livingstone, David M.

    7 T emporal structure in the deep-water temperature of four Swiss lakes: A short-term climatic in the hypolimnion. Since in temperate latitudes coupling between deep water and atmosphere is at its strongest in atmospheric forcing on the deep-water temper- ature may well be greater than any seasonal influences. The deep-water

  10. Improved temperature regulation of process water systems for the APS storage ring.

    SciTech Connect (OSTI)

    Putnam, C.; Dortwegt, R.

    2002-10-10

    Beam stability and operational reliability of critical mechanical systems are key performance issues for synchrotron accelerators such as the Advanced Photon Source (APS). Stability is influenced by temperature fluctuations of the process water (PW) used for cooling and/or temperature conditioning storage ring (SR) components such as vacuum chambers, magnets, absorbers, etc. Operational reliability is crucial in maintaining facility beam operations and remaining within downtime ''budgets.'' Water systems for the APS storage ring were originally provided with a distributive control system (DCS) capable of regulation to {+-}1.0 F, as specified by facility design requirements. After several years of operation, a particular mode of component mortality indicated a need for upgrade of the temperature control system. The upgrade that was implemented was chosen for both improved component reliability and temperature stability (now on the order of {+-}0.2 F for copper components and {+-}0.05 F for aluminum components). The design employs a network of programmable logic controllers (PLCs) for temperature control that functions under supervision of the existing DCS. The human-machine interface (HMI) of the PLC system employs RSView32 software. The PLC system also interfaces with the EPICS accelerator control system to provide monitoring of temperature control parameters. Eventual supervision of the PLC system by EPICS is possible with this design.

  11. Terrestrial Water Storage

    E-Print Network [OSTI]

    Rodell, M; Chambers, D P; Famiglietti, Jay

    2013-01-01

    with Subantarctic Mode Water. J. Geophys. Res. , 116,Global Climate] Stratospheric water vapor [in “State of the18 2. Total column water

  12. The effect of temperature and relative humidity levels upon charcoal tube sampling for vinyl choloride 

    E-Print Network [OSTI]

    McCaskill, Gerald Daniel

    1983-01-01

    hygienist involves sorbent tubes. '~(hen correctly applied, samples collected in this manner yield time- weighted average values for airborne concentrations to which the individual of interest is exposed. To correctly use the results of this sampling.... This is a significant finding due to the fact that as the ambient air tem- perature rises, so does its capability to hoId water vapor. At 90! relative humidity, the amount of water vapor in the air virtually doubles when the ambient air temperature...

  13. Superheated water drops in hot oil

    E-Print Network [OSTI]

    Soto, Enrique; Belmonte, Andrew

    2009-01-01

    Drops of water at room temperature were released in hot oil, which had a temperature higher than that of the boiling point of water. Initially, the drop temperature increases slowly mainly due to heat transfer diffusion; convective heat transfer is small because the motion takes place at a small Reynolds number. Once the drop reaches the bottom of the container, it sticks to the surface with a certain contact angle. Then, a part of the drop vaporizes: the nucleation point may appear at the wall, the interface or the bulk of the drop. The vapor expands inside the drop and deforms its interface. The way in which the vapor expands, either smooth or violent, depends on the location of the nucleation point and oil temperature. Furthermore, for temperatures close to the boiling point of water, the drops are stable (overheated); the vaporization does not occur spontaneously but it may be triggered with an external perturbation. In this case the growth of the vapor bubble is rather violent. Many visualization for dif...

  14. Recycling nickel electroplating rinse waters by low temperature evaporation and reverse osmosis

    SciTech Connect (OSTI)

    Lindsey, T.C.; Randall, P.M.

    1993-08-01

    Low temperature evaporation and reverse osmosis systems were each evaluated (on a pilot scale) on their respective ability to process rinse water collected from a nickel electroplating operation. Each system offered advantages under specific operating conditions. The low temperature evaporation system was best suited to processing solutions with relatively high (greater than 4,000 to 5,000 mg/L) nickel concentrations. The reverse osmosis system was best adapted to conditions where the feed solution had a relatively low (less than4,000 to 5,000 mg/L) nickel concentration. In electroplating operations where relatively dilute rinse water solutions must be concentrated to levels acceptable for replacement in the plating bath, a combination of the two technologies might provide the best process alternative.

  15. LNG fire and vapor control system technologies

    SciTech Connect (OSTI)

    Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

    1982-06-01

    This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

  16. One-Dimensional Ceria as Catalyst for the Low-Temperature Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Han, W.; Wen, W; Hanson, J; Teng, X; Marinkovic, N; Rodriguez, J

    2009-01-01

    Synchrotron-based in situ time-resolved X-ray diffraction and X-ray absorption spectroscopy were used to study pure ceria and Pd-loaded ceria nanotubes and nanorods (1D-ceria) as catalysts for the water-gas shift (WGS) reaction. While bulk ceria is very poor as WGS catalysts, pure 1D-ceria displayed catalytic activity at a temperature as low as 300 C. The reduction of the pure 1D-ceria in pure hydrogen started at 150 C, which is a much lower temperature than those previously reported for the reduction of 3D ceria nanoparticles. This low reduction temperature reflects the novel morphology of the oxide systems and may be responsible for the low-temperature WGS catalytic activity seen for the 1D-ceria. Pd-loaded 1D ceria displayed significant WGS activity starting at 200 C. During pretreatment in H{sub 2}, the ceria lattice parameter increased significantly around 60 C, which indicates that Pd-oxygen interactions may facilitate the reduction of Pd-loaded 1D-ceria. Pd and ceria both participate in the formation of the active sites for the catalytic reactions. The low-temperature hydrogen pretreatment results in higher WGS activity for Pd-loaded 1D-ceria.

  17. Petrology and geochemistry of Alto Peak, a vapor-cored hydrothermal system, Leyte Province, Philippines

    SciTech Connect (OSTI)

    Reyes, A.G.; Giggenbach, W.F.; Saleras, J.R.M.; Salonga, N.D.; Vergara, M.C.

    1993-10-01

    Based on detailed petrological information on secondary mineral assemblages and the composition of fluids trapped in inclusions and discharged from five wells, the Alto Peak geothermal field was found to represent a combined vapor and liquid-dominated system. A central core or chimney, with a diameter of about 1 km, a height of some 3 km and occupied by a high gas vapor (1.1 to 5.6 molal CO{sub 2}), is surrounded by an envelope of intermediate salinity water (7,000 mg/kg Cl) with temperatures between 250 and 350 C. The transition from purely vapor-dominated to liquid-dominated zones takes place via two-phase zones occupied by fluid mixtures of highly variable compositions. Much of the lower temperature, mature neutral pH Cl water is likely to have formed during an earlier stage in the evolution of the system. High temperatures of > 300 C, and associated alteration, are limited to wells AP-1D and the lower parts of AP-2D and are ascribed to re-heating by recent magmatic intrusions. The isotopic composition of the well discharges suggests that they contain some 40 to 50% of magmatic water. Alto Peak is considered a typical example of hydrothermal systems associated with many dormant volcanoes.

  18. Development of an Accurate Feed-Forward Temperature Control Tankless Water Heater

    SciTech Connect (OSTI)

    David Yuill

    2008-06-30

    The following document is the final report for DE-FC26-05NT42327: Development of an Accurate Feed-Forward Temperature Control Tankless Water Heater. This work was carried out under a cooperative agreement from the Department of Energy's National Energy Technology Laboratory, with additional funding from Keltech, Inc. The objective of the project was to improve the temperature control performance of an electric tankless water heater (TWH). The reason for doing this is to minimize or eliminate one of the barriers to wider adoption of the TWH. TWH use less energy than typical (storage) water heaters because of the elimination of standby losses, so wider adoption will lead to reduced energy consumption. The project was carried out by Building Solutions, Inc. (BSI), a small business based in Omaha, Nebraska. BSI partnered with Keltech, Inc., a manufacturer of electric tankless water heaters based in Delton, Michigan. Additional work was carried out by the University of Nebraska and Mike Coward. A background study revealed several advantages and disadvantages to TWH. Besides using less energy than storage heaters, TWH provide an endless supply of hot water, have a longer life, use less floor space, can be used at point-of-use, and are suitable as boosters to enable alternative water heating technologies, such as solar or heat-pump water heaters. Their disadvantages are their higher cost, large instantaneous power requirement, and poor temperature control. A test method was developed to quantify performance under a representative range of disturbances to flow rate and inlet temperature. A device capable of conducting this test was designed and built. Some heaters currently on the market were tested, and were found to perform quite poorly. A new controller was designed using model predictive control (MPC). This control method required an accurate dynamic model to be created and required significant tuning to the controller before good control was achieved. The MPC design was then implemented on a prototype heater that was being developed simultaneously with the controller development. (The prototype's geometry and components are based on a currently marketed heater, but several improvements have been made.) The MPC's temperature control performance was a vast improvement over the existing controller. With a benchmark for superior control performance established, five additional control methods were tested. One problem with MPC control is that it was found to be extremely difficult to implement in a TWH, so that it is unlikely to be widely adopted by manufacturers. Therefore the five additional control methods were selected based on their simplicity; each could be implemented by a typical manufacturer. It was found that one of these methods performed as well as MPC, or even better under many circumstances. This method uses a Feedback-Compensated Feed-Forward algorithm that was developed for this project. Due to its simplicity and excellent performance this method was selected as the controller of choice. A final higher-capacity prototype heater that uses Feedback-Compensated Feed-Forward control was constructed. This prototype has many improvements over the currently marketed heaters: (1) excellent control; (2) a modular design that allows for different capacity heaters to be built easily; (3) built-in fault detection and diagnosis; (4) a secondary remote user-interface; and (5) a TRIAC switching algorithm that will minimize 'flicker factor'. The design and engineering of this prototype unit will allow it to be built without an increase in cost, compared with the currently marketed heater. A design rendering of the new product is shown below. It will be launched with a new marketing campaign by Keltech in early 2009.

  19. Hydrogen production by high temperature water splitting using electron conducting membranes

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Wang, Shuangyan; Dorris, Stephen E.; Lee, Tae H.

    2006-08-08

    A device and method for separating water into hydrogen and oxygen is disclosed. A first substantially gas impervious solid electron-conducting membrane for selectively passing protons or hydrogen is provided and spaced from a second substantially gas impervious solid electron-conducting membrane for selectively passing oxygen. When steam is passed between the two membranes at dissociation temperatures the hydrogen from the dissociation of steam selectively and continuously passes through the first membrane and oxygen selectively and continuously passes through the second membrane, thereby continuously driving the dissociation of steam producing hydrogen and oxygen. The oxygen is thereafter reacted with methane to produce syngas which optimally may be reacted in a water gas shift reaction to produce CO2 and H2.

  20. Nuclear spin conversion of water inside fullerene cages detected by low-temperature nuclear magnetic resonance

    SciTech Connect (OSTI)

    Mamone, Salvatore Concistrè, Maria; Carignani, Elisa; Meier, Benno; Krachmalnicoff, Andrea; Johannessen, Ole G.; Denning, Mark; Carravetta, Marina; Whitby, Richard J.; Levitt, Malcolm H.; Lei, Xuegong; Li, Yongjun; Goh, Kelvin; Horsewill, Anthony J.

    2014-05-21

    The water-endofullerene H{sub 2}O@C{sub 60} provides a unique chemical system in which freely rotating water molecules are confined inside homogeneous and symmetrical carbon cages. The spin conversion between the ortho and para species of the endohedral H{sub 2}O was studied in the solid phase by low-temperature nuclear magnetic resonance. The experimental data are consistent with a second-order kinetics, indicating a bimolecular spin conversion process. Numerical simulations suggest the simultaneous presence of a spin diffusion process allowing neighbouring ortho and para molecules to exchange their angular momenta. Cross-polarization experiments found no evidence that the spin conversion of the endohedral H{sub 2}O molecules is catalysed by {sup 13}C nuclei present in the cages.

  1. Effect of temperature, WPS (water-phase salt) and phenolic contents on4 Listeria monocytogenes growth rates on cold-smoked salmon and evaluation5

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 2 3 Effect of temperature, WPS (water-phase salt) and phenolic contents on4 Listeria models, taking into account the effects of temperature, water24 phase salt content, phenolic content

  2. Hydrogen production by high-temperature water splitting using electron-conducting membranes

    DOE Patents [OSTI]

    Lee, Tae H.; Wang, Shuangyan; Dorris, Stephen E.; Balachandran, Uthamalingam

    2004-04-27

    A device and method for separating water into hydrogen and oxygen is disclosed. A first substantially gas impervious solid electron-conducting membrane for selectively passing hydrogen is provided and spaced from a second substantially gas impervious solid electron-conducting membrane for selectively passing oxygen. When steam is passed between the two membranes at disassociation temperatures the hydrogen from the disassociation of steam selectively and continuously passes through the first membrane and oxygen selectively and continuously passes through the second membrane, thereby continuously driving the disassociation of steam producing hydrogen and oxygen.

  3. VAPORIZATION THERMODYNAMICS OF KCl. COMBINING VAPOR PRESSURE AND GRAVIMETRIC DATA

    E-Print Network [OSTI]

    Rudnyi, Evgenii B.

    1 VAPORIZATION THERMODYNAMICS OF KCl. COMBINING VAPOR PRESSURE AND GRAVIMETRIC DATA Rudnyi E of thermodynamic properties of the vapor and the vaporization process, coupling pressure measurements. INTRODUCTION The vapor pressure of a substance is an important system property in many applications. Its value

  4. Groundwater and Terrestrial Water Storage, 

    E-Print Network [OSTI]

    Rodell, M; Chambers, D P; Famiglietti, J S

    2011-01-01

    2003: Tracking fresh water from space. Science, 301, 1485–2007: Mea- suring surface water from space. Rev. Geophys. ,2011:, Stratospheric water vapor trends over Boulder, Colo-

  5. Method and apparatus to measure vapor pressure in a flow system

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Biblarz, Oscar (Swampscott, MA)

    1991-01-01

    The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process.

  6. Vapor Barriers or Vapor Diffusion Retarders | Department of Energy

    Energy Savers [EERE]

    vapor retarders: Class I vapor retarders (0.1 perms or less): Glass Sheet metal Polyethylene sheet Rubber membrane Class II vapor retarders (greater than 0.1 perms and less...

  7. An experimental and kinetic study of syngas/air combustion at elevated temperatures and the effect of water addition

    E-Print Network [OSTI]

    Qiao, Li

    . Introduction Synthetic gas (syngas) is a mixture of carbon monoxide and hydrogen in various compositionsAn experimental and kinetic study of syngas/air combustion at elevated temperatures and the effect 20 December 2011 Keywords: Syngas combustion Elevated temperatures Water addition Laminar flame speed

  8. Long-term Temperature Trends in the Deep Waters of the Weddell Sea Robin Robertson*, Martin Visbeck, Arnold L. Gordon, and E. Fahrbach1

    E-Print Network [OSTI]

    Robertson, Robin

    Long-term Temperature Trends in the Deep Waters of the Weddell Sea Robin Robertson*, Martin Visbeck November 28, 2001 #12;Long-term Temperature Trends in the Deep Waters of the Weddell Sea 2 Abstract Warming of the deep water in the Weddell Sea has important implications for Antarctic Bottom Water (AABW) formation

  9. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  10. 1-Dimensional Numerical Model of Thermal Conduction and Vapor Diffusion

    E-Print Network [OSTI]

    Schörghofer, Norbert

    developed by Samar Khatiwala, 2001 extended to variable thermal properties and irregular grid by Norbert Sch for c. Upper boundary condition: a) Radiation Q + k T z z=0 = T4 z=0 Q is the incoming solar flux of Water Vapor with Phase Transitions developed by Norbert Sch¨orghofer, 2003­2004 3 phases: vapor, free

  11. Apparatus and method to control atmospheric water vapor composition and concentration during dynamic cooling of biological tissues in conjunction with laser irradiations

    DOE Patents [OSTI]

    Nelson, J. Stuart (Laguna Niguel, CA); Anvari, Bahman (Houston, TX); Tanenbaum, B. Samuel (Irvine, CA); Milner, Thomas E. (Austin, TX)

    1999-01-01

    Cryogen spray cooling of skin surface with millisecond cryogen spurts is an effective method for establishing a controlled temperature distribution in tissue and protecting the epidermis from nonspecific thermal injury during laser mediated dermatological procedures. Control of humidity level, spraying distance and cryogen boiling point is material to the resulting surface temperature. Decreasing the ambient humidity level results in less ice formation on the skin surface without altering the surface temperature during the cryogen spurt. For a particular delivery nozzle, increasing the spraying distance to 85 millimeters lowers the surface temperature. The methodology comprises establishing a controlled humidity level in the theater of operation of the irradiation site of the biological tissues before and/or during the cryogenic spray cooling of the biological tissue. At cold temperatures calibration was achieved by mounting a thermistor on a thermoelectric cooler. The thermal electric cooler was cooled from from 20.degree. C. to about -20.degree. C. while measuring its infrared emission.

  12. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1986-08-15

    The atomic vapor laser isotope separation (AVLIS) process for the enrichment of uranium is evaluated. (AIP)

  13. DYNAMIC MODEL OF AN INDUSTRIAL HEAT PUMP USING WATER AS REFRIGERANT

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 DYNAMIC MODEL OF AN INDUSTRIAL HEAT PUMP USING WATER AS REFRIGERANT CHAMOUN MARWAN to improve industrial energy efficiency, the development of a high temperature heat pump using water vapor as refrigerant is investigated. Technical problems restraining the feasibility of this industrial heat pump

  14. Plot size and location within a cotton block: their effects on the canopy temperature function and crop water stress index 

    E-Print Network [OSTI]

    Gaitan, Camilo Alberto

    1988-01-01

    in the cotton block, using the theoretical lower baseline. Table 23. CWSI and linear regression of the CTF for two 0. 6 PET water treatment plots randomly located in the cotton block, using the theoretical lower baseline. . . . . 82 Table 24. Summary... to evaluate the effects of a randomized plot design on the crop water stress index (CWSI) and canopy temperature function (CTF) of cotton. Trickle irrigated cotton at the Agricultural Research Station near Pecos Texas was used to investigate...

  15. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, Terry W. (Tracy, CA); Ault, Earl R. (Dublin, CA); Moses, Edward I. (Castro Valley, CA)

    1992-01-01

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

  16. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, T.W.; Ault, E.R.; Moses, E.I.

    1992-12-01

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment. 2 figs.

  17. Initiated chemical vapor deposition of functional polyacrylic thin films

    E-Print Network [OSTI]

    Mao, Yu, 1975-

    2005-01-01

    Initiated chemical vapor deposition (iCVD) was explored as a novel method for synthesis of functional polyacrylic thin films. The process introduces a peroxide initiator, which can be decomposed at low temperatures (<200?C) ...

  18. Use Vapor Recompression to Recover Low-Pressure Waste Steam,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    that it can be reused. Vapor recompression relies upon a mechanical compressor or steam jet ejector to increase the temperature of the latent heat in steam to render it usable for...

  19. Species-specific phenological responses to winter temperature and precipitation in a water-limited ecosystem

    E-Print Network [OSTI]

    Mazer, SJ; Gerst, KL; Gerst, KL; Matthews, ER; Matthews, ER; Evenden, A

    2015-01-01

    and precipitation in a water-limited ecosystem S USAN J. Mand precipitation in a water-limited ecosystem. Ecosphere 6(information is available from water-limited ecosystems. In

  20. New constraints on water temperature at Lake Bonneville from carbonate clumped isotopes

    E-Print Network [OSTI]

    Mering, John Arthur

    2015-01-01

    Wilkinson, B.H. , 1986. Water chemistry and sedimentologicalmarl deposition. Environ. Geol. Water Sci. 8, 229–236. doi:of Great Salt Lake: History, Water Balance, Conditions, Lake

  1. Optical characterization of InN layers grown by high-pressure chemical vapor deposition

    E-Print Network [OSTI]

    Dietz, Nikolaus

    Optical characterization of InN layers grown by high-pressure chemical vapor deposition M. Alevli properties of InN layers grown by high-pressure chemical vapor deposition have been studied. Raman, infrared at elevated temperatures, a high-pressure chemical vapor deposition HPCVD system has been established at GSU.6

  2. Temperature and Length Scale Dependence of Solvophobic Solvation in a Single-site Water-like Liquid

    E-Print Network [OSTI]

    John R. Dowdle; Sergey V. Buldyrev; H. Eugene Stanley; Pablo G. Debenedetti; Peter J. Rossky

    2012-11-01

    The temperature and length scale dependence of solvation properties of spherical hard solvophobic solutes is investigated in the Jagla liquid, a simple liquid that consists of particles interacting via a spherically symmetric potential combining a hard core repulsion and a longer ranged soft core interaction, yet exhibits water-like anomalies. The results are compared with equivalent calculations for a model of a typical atomic liquid, the Lennard-Jones (LJ) potential, and with predictions for hydrophobic solvation in water using the cavity equation of state and the extended simple point charge (SPC/E) model. We find that the Jagla liquid captures the qualitative thermodynamic behavior of hydrophobic hydration as a function of temperature for both small and large length scale solutes. In particular, for both the Jagla liquid and water, we observe temperature-dependent enthalpy and entropy of solvation for all solute sizes as well as a negative solvation entropy for sufficiently small solutes at low temperature. The results suggest that, compared to a simple liquid, it is the presence of a second thermally accessible repulsive energy scale, acting to increasingly favor larger separations for decreasing temperature, that is the essential characteristic of a liquid that favors low-density, open structures and models hydrophobic hydration, and that it is the presence of this second energy scale that leads to the similarity in the behavior of water and the Jagla liquid. The implications of the temperature and length scale dependence of solvation free energies in water-like liquids are explored with a simple model for the aggregation of solvophobic solutes. We show how aggregate stability depends upon the size of the aggregate and the size of its constituent solutes, and we relate this dependence to cold-induced destabilization phenomena such as the cold-induced denaturation of proteins.

  3. Controlling the vapor pressure of a mercury lamp

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

    1988-01-01

    The invention described herein discloses a method and apparatus for controlling the Hg vapor pressure within a lamp. This is done by establishing and controlling two temperature zones within the lamp. One zone is colder than the other zone. The first zone is called the cold spot. By controlling the temperature of the cold spot, the Hg vapor pressure within the lamp is controlled. Likewise, by controlling the Hg vapor pressure of the lamp, the intensity and linewidth of the radiation emitted from the lamp is controlled.

  4. Controlling the vapor pressure of a mercury lamp

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1988-05-24

    The invention described herein discloses a method and apparatus for controlling the Hg vapor pressure within a lamp. This is done by establishing and controlling two temperature zones within the lamp. One zone is colder than the other zone. The first zone is called the cold spot. By controlling the temperature of the cold spot, the Hg vapor pressure within the lamp is controlled. Likewise, by controlling the Hg vapor pressure of the lamp, the intensity and linewidth of the radiation emitted from the lamp is controlled. 2 figs.

  5. In-well vapor stripping drilling and characterization work plan

    SciTech Connect (OSTI)

    Koegler, K.J.

    1994-03-13

    This work plan provides the information necessary for drilling, sampling, and hydrologic testing of wells to be completed in support of a demonstration of the in-well vapor stripping system. The in-well vapor stripping system is a remediation technology designed to preferentially extract volatile organic compounds (VOCs) from contaminated groundwater by converting them to a vapor phase. Air-lift pumping is used to lift and aerate groundwater within the well. The volatiles escaping the aerated water are drawn off by a slight vacuum and treated at the surface while the water is allowed to infiltrate the vadose zone back to the watertable.

  6. Investigation of Temperature-Driven Water Transport in Polymer Electrolyte Fuel Cell: Phase-Change-Induced Flow

    E-Print Network [OSTI]

    Mench, Matthew M.

    Investigation of Temperature-Driven Water Transport in Polymer Electrolyte Fuel Cell: Phase and durability for polymer electrolyte fuel cells PEFCs . The most commonly used polymer electrolyte membranes-Change-Induced Flow Soowhan Kim* and M. M. Mench**,z Fuel Cell Dynamics and Diagnostics Laboratory, Department

  7. Proposal for the Purchase, Without a Call for Tenders, of a Medium-Temperature Hot Water Boiler for the 300 GeV Accelerator

    E-Print Network [OSTI]

    1976-01-01

    Proposal for the Purchase, Without a Call for Tenders, of a Medium-Temperature Hot Water Boiler for the 300 GeV Accelerator

  8. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels, Phase 2: Evaluations of Field Samples and Laboratory Blends

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; LaViolette, M.

    2010-04-01

    Study to measure the flammability of gasoline/ethanol fuel vapors at low ambient temperatures and develop a mathematical model to predict temperatures at which flammable vapors were likely to form.

  9. The Coordinated Control of a Central Air Conditioning System Based on Variable Chilled Water Temperature and Variable Chilled Water Flow 

    E-Print Network [OSTI]

    Liu, J.; Mai, Y.; Liu, X.

    2006-01-01

    At present, regulation of water flow by means of pump frequency conversion is one of the major methods for power-saving in central air conditioning systems. In this article, optimization regulation for central air conditioning system on the basis...

  10. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, Richard A. (Newington, CT); Szydlowski, Donald F. (East Hartford, CT); Sawyer, Richard D. (Canton, CT)

    1983-01-01

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

  11. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  12. Ex 6.1(a) The vapor pressure of dichloromethane at 24.1C is 400 Torr and its enthalpy of vaporization is 28.7 kJ mol-1

    E-Print Network [OSTI]

    Findley, Gary L.

    Ex 6.1(a) The vapor pressure of dichloromethane at 24.1°C is 400 Torr and its enthalpy of vaporization is 28.7 kJ mol-1 . Estimate the temperature at which its vapor pressure is 500 Torr. Ex 6.3(a) The vapor pressure of a liquid in the temperature range 200 K to 260 K was found to fit the expression ln

  13. Deserts are water-controlled ecosystems characterized by high ambient temperature (Ta), intense solar radiation,

    E-Print Network [OSTI]

    Williams, Jos. B.

    , it can be argued that rates of energy flow through desert ecosystems are controlled by available water dominated by, the availability of water in desert ecosystems. Animals that occupy arid climes face the challenge of meeting their daily energy and water requirements in an environment that, on average, provides

  14. Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Fisher, II, James C

    2013-12-31

    The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

  15. Method of physical vapor deposition of metal oxides on semiconductors

    DOE Patents [OSTI]

    Norton, David P. (Knoxville, TN)

    2001-01-01

    A process for growing a metal oxide thin film upon a semiconductor surface with a physical vapor deposition technique in a high-vacuum environment and a structure formed with the process involves the steps of heating the semiconductor surface and introducing hydrogen gas into the high-vacuum environment to develop conditions at the semiconductor surface which are favorable for growing the desired metal oxide upon the semiconductor surface yet is unfavorable for the formation of any native oxides upon the semiconductor. More specifically, the temperature of the semiconductor surface and the ratio of hydrogen partial pressure to water pressure within the vacuum environment are high enough to render the formation of native oxides on the semiconductor surface thermodynamically unstable yet are not so high that the formation of the desired metal oxide on the semiconductor surface is thermodynamically unstable. Having established these conditions, constituent atoms of the metal oxide to be deposited upon the semiconductor surface are directed toward the surface of the semiconductor by a physical vapor deposition technique so that the atoms come to rest upon the semiconductor surface as a thin film of metal oxide with no native oxide at the semiconductor surface/thin film interface. An example of a structure formed by this method includes an epitaxial thin film of (001)-oriented CeO.sub.2 overlying a substrate of (001) Ge.

  16. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  17. Measurements of Evaporation Kinetics of Pure Water and Salt Solutions

    E-Print Network [OSTI]

    Drisdell, Walter

    2010-01-01

    sat is the equilibrium vapor pressure, and the accommodationB (1969) Algorithms For Vapor Pressure Of Water Over Aqueous= p 2 ? mkT , where p is the vapor pressure above the liquid

  18. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  19. Evaluating Water Vapor in the NCAR CAM3 Climate Model with RRTMG/McICA using Modeled and Observed AIRS Spectral Radiances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansasCommunitiesof Energy8) Wigner Home ·the Effect ofEvaluating Water

  20. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1985-11-08

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power reactor fuel has been under development for over 10 years. In June 1985 the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for the internationally competitive production of uranium separative work. The economic basis for this decision is considered, with an indicated of the constraints placed on the process figures of merit and the process laser system. We then trace an atom through a generic AVLIS separator and give examples of the physical steps encountered, the models used to describe the process physics, the fundamental parameters involved, and the role of diagnostic laser measurements.

  1. Synthesis of zeolite from Italian coal fly ash: Differences in crystallization temperature using seawater instead of distilled water

    SciTech Connect (OSTI)

    Belviso, Claudia; Cavalcante, Francesco; Fiore, Saverio

    2010-05-15

    In this study Italian coal fly ash was converted into several types of zeolite in laboratory experiments with temperatures of crystallization ranging from 35 up to 90 deg. C. Distilled and seawater were used during the hydrothermal synthesis process in separate experiments, after a pre-treatment fusion with NaOH. The results indicate that zeolites could be formed from different kind of Italian coal fly ash at low temperature of crystallization using both distilled and seawater. SEM data and the powder patterns of X-ray diffraction analysis show that faujasite, zeolite ZK-5 and sodalite were synthesized when using both distilled and seawater; zeolite A crystallized only using distilled water. In particular the experiments indicate that the synthesis of zeolite X and zeolite ZK-5 takes place at lower temperatures when using seawater (35 and 45 deg. C, respectively). The formation of sodalite is always competitive with zeolite X which shows a metastable behaviour at higher temperatures (70-90 deg. C). The chemical composition of the fly ash source could be responsible of the differences on the starting time of synthesized zeolite with distilled water, in any case our data show that the formation of specific zeolites takes place always at lower temperatures when using seawater.

  2. An experimental investigaion of seawater/basalt interactions: the role of water/rock ratios and temperature gradients 

    E-Print Network [OSTI]

    Archer, Paul Lawrence

    1978-01-01

    in the precipitation of Fe-sulfides (pyri te and pyrrhoti te) in both 5/1 and 50/1 water/rock ratio systems. As a result of this precipitation, Fe was effectively fractionated from Mn and the Fe/Mn ratio of the fluid decreased. Because the 50/1 systems had lower pH.... EPR). This investi- gation also provides data potentially useful in predicting the occur- rence and kind of mineralization at ocean spreading centers as a function of the temperature and water/rock ratio regime of that system. 11 METHODS Ex...

  3. Extracting the pair distribution function of liquids and liquid-vapor surfaces by grazing incidence x-ray diffraction mode

    E-Print Network [OSTI]

    Vakni, David

    of the top most layers of the water/vapor interface. Our results indicate water restructuring at the vapor/water 2008; published online 24 July 2008 We show that the structure factor S q of water can be obtained from . Performing the measurements below the critical angle for total reflectivity yields the structure factor

  4. Laboratory test plan in-well vapor stripping system

    SciTech Connect (OSTI)

    Koegler, K.J

    1994-07-01

    This test plan describes the activities that will be conducted as a part of the laboratory testing of a full-scale mockup of the Stanford in-well vapor stripping system. These tests will be conducted to delineate design parameters for the in-well vapor stripping unit and to identify and quantify variables that are sensitive to the dynamic hydraulic effects induced by operation of the system. No radioactive materials are involved in this test. In-well vapor stripping has been used successfully as an alternative to conventional pump-and-treat technology for remediation of volatile organic compound (VOC) contaminated groundwater in Europe and more recently in the United States. In-well vapor stripping permits in situ remediation of VOC-contaminated groundwater by combining an in-well vapor stripping system with a treatment well is used to extract and discharge groundwater simultaneously, resulting in the establishment of a vertical circulation groundwater flow cell in the aquifer. Groundwater extracted from the aquifer via the lower screened interval is treated for VOCs by in-well vapor stripping within the treatment well. This stripping causes aqueous phase VOCs to partition preferentially into a vapor phase. Treated groundwater is discharged back to the aquifer via the upper screened interval of the treatment well, while the vapor phase VOCs are simultaneously removed from the well bore and contained at the surface with a vacuum extraction system. Groundwater entrained into the vertical circulation flow cell becomes sequentially cleaned of VOC contamination in an efficient manner without the need for surface treatment and handling of contaminated groundwater. An added benefit of in-well vapor stripping is the ability to perform vadose zone vapor extraction concurrently with groundwater remediation. This uses the vacuum extraction capabilities of the in-well vapor stripping configured with the upper screened interval placed into the vadose zone above the water table.

  5. Long-Term Oxidation of Candidate Cast Iron and Advanced Austenitic Stainless Steel Exhaust System Alloys from 650-800 C in Air with Water Vapor

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL; Muralidharan, Govindarajan [ORNL; Leonard, Donovan N [ORNL; Haynes, James A [ORNL

    2014-01-01

    The oxidation behavior of SiMo cast iron, Ni-resist D5S cast iron, cast chromia-forming austenitic stainless steels of varying Cr/Ni content based on CF8C plus, HK, and HP, and a developmental cast alumina-forming austenitic (AFA) stainless steel of interest for diesel exhaust system components were studied for up to 5000 h at 650-800 C in air with 10% H2O. At 650 C, the Ni-resist D5S exhibited moderately better oxidation resistance than did the SiMo cast iron. However, the D5S suffered from oxide scale spallation issues at 700 C and higher, whereas the oxide scales formed on SiMo cast iron remained adherent from 700-800 C despite oxide scales hundreds of microns thick. The oxidation of the SiMo cast iron exhibited unusual temperature dependence, with periods of slower oxidation kinetics at 750-800 C compared to 650-700 C due to continuous silica-rich scale formation at the higher temperatures. The oxidation of the cast chromia-forming austenitics trended with the level of Cr and Ni additions, with small mass losses consistent with Cr oxy-hydroxide volatilization processes for the higher 25Cr/25-35Ni HK and HP type alloys, and transition to rapid Fe-base oxide formation and scale spallation in the lower 19Cr/12Ni CF8C plus type alloy. In contrast, small positive mass changes consistent with protective alumina scale formation were observed for the cast AFA alloy under all conditions studied. Implications of these findings for diesel exhaust system components are discussed.

  6. Unusual Low Temperature Reactivity of Water. The CH + H2O Reaction as a Source of Interstellar Formaldehyde?

    E-Print Network [OSTI]

    Hickson, Kevin; Caubet, Philippe

    2013-01-01

    Water is an important reservoir species for oxygen in interstellar space and plays a key role in the physics of star formation through cooling by far-infrared emission. Whilst water vapour is present at high abundances in the outflows of protostars, its contribution to the chemical evolution of these regions is a minor one due to its limited low temperature reactivity in the gas-phase. Here, we performed kinetic experiments on the barrierless CH + H2O reaction in a supersonic flow reactor down to 50 K. The measured rate increases rapidly below room temperature, confirming and extending the predictions of earlier statistical calculations. The open product channels for this reaction suggest that this process could be an important gas-phase route for formaldehyde formation in protostellar envelopes.

  7. Influence of district heating water temperatures on the fuel saving and reduction of ecological cost of the heat generation

    SciTech Connect (OSTI)

    Portacha, J.; Smyk, A.; Zielinski, A.; Misiewicz, L.

    1998-07-01

    Results of examinations carried out on the district heating water temperature influence in the cogeneration plant with respect to both the fuel economy and the ecological cost reduction of heat generation for the purposes of heating and hot service water preparation are presented in this paper. The decrease of water return temperature effectively contributes to the increase of fuel savings in all the examined cases. The quantitative savings depend on the outlet water temperature of the cogeneration plant and on the fuel type combusted at the alternative heat generating plant. A mathematical model and a numerical method for calculations of annual cogeneration plant performance, e.g. annual heat and electrical energy produced in cogeneration mode, and the annual fuel consumption, are also discussed. In the discussed mathematical model, the variable operating conditions of cogeneration plant vs. outside temperature and method of control can be determined. The thermal system of cogeneration plant was decomposed into subsystems so as to set up the mathematical model. The determination of subsystem tasks, including a method of convenient aggregation thereof is an essential element of numerical method for calculations of a specific cogeneration plant thermal system under changing conditions. Costs of heat losses in the environment, resulting from the pollutants emission, being formed in the fuel combustion process in the heat sources, were defined. In addition, the environment quantitative and qualitative pollution characteristics were determined both for the heat generation in a cogeneration plant and for an alternative heat-generating plant. Based on the calculations, a profitable decrease of ecological costs is achieved in the cogeneration economy even if compared with the gas-fired heat generating plant. Ecological costs of coal-fired heat generating plant are almost three time higher than those of the comparable cogeneration plant.

  8. Dealing with big circulation flow, small temperature difference based on verified dynamic model simulations of a hot water district heating system 

    E-Print Network [OSTI]

    Zhong, L.

    2014-01-01

    d design en enclosure ex exchanger f fuel h heater int internal n number of HES o outside r return s supply sp set point sols solar radiation from south side v verify w, w2i water, water in secondary system for each HES z zone ESL... temperatures, solar radiation and wind speed; the heat balance has been regulated based on the average water temperature in the secondary system by adjusting the water mass flow rate (u1) of each HES in the primary system; and the water mass flow rate...

  9. COMPACT THERMAL MODEL FOR THE TRANSIENT TEMPERATURE PREDICTION OF A WATER-COOLED

    E-Print Network [OSTI]

    Daraio, Chiara

    heating application (process indus- try, district heating, etc.). After this, the resulting lower cooled with a heat sink, exploring the concept of hot water cooled electronics as a strategy to reduce as the heat sink outlet water tem- peratures during transient heat loads. The model is validated

  10. Rheological behavior of heavy oil and water mixtures at high pressures and high temperatures 

    E-Print Network [OSTI]

    Setiadarma, Agustinus

    2002-01-01

    mixtures. The second part of this study evaluated the same heavy oil sample with water mixtures. This research was done to predict the in-situ rheological behavior of heavy oil emulsions that always occurs in water or steam flooding processes. It is shown...

  11. Stratified vapor generator

    DOE Patents [OSTI]

    Bharathan, Desikan (Lakewood, CO); Hassani, Vahab (Golden, CO)

    2008-05-20

    A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

  12. Antarctic Science page 1 of 16 (2010) & Antarctic Science Ltd 2010 doi:10.1017/S0954102010000234 A dynamic physical model for soil temperature and water in

    E-Print Network [OSTI]

    Fountain, Andrew G.

    2010-01-01

    of capillary flows below the top 0.5 cm soil layer. Beginning with a completely saturated soil profile, soil A dynamic physical model for soil temperature and water in Taylor Valley, Antarctica H.W. HUNT1 , A and longwave radiation. Water fluxes included snowmelt, freezing/thawing of soil water, soil capillary flow

  13. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect (OSTI)

    Eric M. Suuberg; Vahur Oja

    1997-07-01

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  14. PROJECT PROFILE: Stable Perovskite Solar Cells via Chemical Vapor Deposition

    Broader source: Energy.gov [DOE]

    This project is focused on novel approaches to remove risk related to the development of hybrid perovskite solar cells (HPSCs). Researchers will synthesize a new and chemically stable hybrid organic-inorganic perovskite that eliminates decomposition of the absorber layer upon exposure to water vapor, which is a chief obstacle to widespread use of HPSC technology. They will also demonstrate a unique and industrially-scalable chemical vapor deposition method without halides or iodine, which are the main contributors to perovskite degradation.

  15. Temperature programmed desorption and infrared spectroscopic studies of thin water films on MgO(100)

    E-Print Network [OSTI]

    Reisler, Hanna

    solid to cubic ice is known to take place, and then re-cooling. Temperature programmed desorption traces annealed. Ó 2005 Published by Elsevier B.V. 1. Introduction Physical and chemical processes that transpire

  16. Promising Technology: Condensing Gas Water Heaters

    Broader source: Energy.gov [DOE]

    Condensing water heaters achieve higher efficiencies than conventional water heaters by capturing the latent heat from water vapor contained in the flue gases. Combustion gases are exhausted through a secondary heat exchanger where the latent heat of water vapor in the exhaust gas is transferred to the stored water. This technology enables the water heater to achieve thermal efficiencies up to 99%.

  17. Glycol-Water Interactions and co-existing phases and Temperature Dependent Solubility. An Example Of Carbon-Hydrogen Chemistry In Water

    E-Print Network [OSTI]

    Fredrick Michael

    2010-10-26

    Recently there has been great interest in Glycol-Water chemistry and solubility and temperature dependent phase dynamics. The Glycol-Water biochemistry of interactions is present in plant biology and chemistry, is of great interest to chemical engineers and biochemists as it is a paradigm of Carbon-Hydrogen Water organic chemistry. There is an interest moreover in formulating a simpler theory and computation model for the Glycol-Water interaction and phase dynamics, that is not fully quantum mechanical yet has the high accuracy available from a fully quantum mechanical theory of phase transitions of fluids and Fermi systems. Along these lines of research interest we have derived a Lennard-Jones -like theory of interacting molecules-Water in a dissolved adducts of Glycol-Water system interacting by Hydrogen bonds whose validity is supported at the scale of interactions by other independent molecular dynamics investigations that utilize force fields dependent on their experimental fittings to the Lennard-Jones potential and where we have relaxed or generalized the potential to arbitrary and possibly fractional powers. The theory then is a semi-classical theory as the repulsion of particles is incorporated in the Lennard-Jones -like potential's energy required to bring two molecules together, a repulsion of sorts. We derive distributions for the molecular species that are exactly solved, and are derived from maximum entropy, here the semi-classical analogue of the Hamiltonian superposition of quantum phase theory of fluids. We also derive the similar statistics from the microscopic SDEs stochastic differential dynamics equations, verifying the macroscopic state function entropic-thermodynamic derivation.

  18. A singular thermodynamically consistent temperature at the origin of the anomalous behavior of liquid water

    E-Print Network [OSTI]

    Mallamace, Francesco

    The density maximum of water dominates the thermodynamics of the system under ambient conditions, is strongly P-dependent, and disappears at a crossover pressure P[subscript cross] ~ 1.8 kbar. We study this variable across ...

  19. Insight into the molecular mechanism of water evaporation via the finite temperature string method

    E-Print Network [OSTI]

    Musolino, Nicholas

    The process of water's evaporation at its liquid/air interface has proven challenging to study experimentally and, because it constitutes a rare event on molecular time scales, presents a challenge for computer simulations ...

  20. Hydrogen embrittlement, grain boundary segregation, and stress corrosion cracking of alloy X-750 in low- and high-temperature water

    SciTech Connect (OSTI)

    Mills, W. J.; Lebo, M. R.; Kearns, J. J. [Bettis Atomic Power Lab., West Mifflin, PA (United States)

    1997-04-01

    The nature of intergranular stress corrosion cracking (SCC) of alloy X-750 was characterized in low- and high-temperature water by testing as-notched and precracked fracture mechanics specimens. Materials given the AH, BH, and HTH heat treatments were studied. While all heat treatments were susceptible to rapid low-temperature crack propagation (LTCP) below 150 C, conditions AH and BH were particularly susceptible. Low-temperature tests under various loading conditions (e.g., constant displacement, constant load, and increasing load) revealed that the maximum stress intensity factors (K{sub P{sub max}}) from conventional rising load tests provide conservative estimates of the critical loading conditions in highly susceptible heats, regardless of the load path history. For resistant heats, K{sub P{sub max}} provides a reasonable, but not necessarily conservative, estimate of the critical stress intensity factor for LTCP. Testing of as-notched specimens showed that LTCP will not initiate at a smooth surface or notch, but will readily occur if a cracklike defect is present. Comparison of the cracking response in water with that for hydrogen-precharged specimens tested in air demonstrated that LTCP is associated with hydrogen embrittlement of grain boundaries. The stress corrosion crack initiation and growth does occur in high-temperature water (>250 C), but crack growth rates are orders of magnitude lower than LTCP rates. The SCC resistance of HTH heats is far superior to that of AH heats as crack initiation times are two to three orders of magnitude greater and growth rates are one to two orders of magnitude lower.

  1. Copper vapor laser acoustic thermometry system

    DOE Patents [OSTI]

    Galkowski, Joseph J. (Livermore, CA)

    1987-01-01

    A copper vapor laser (CVL) acoustic thermometry system is disclosed. The invention couples an acoustic pulse a predetermined distance into a laser tube by means of a transducer and an alumina rod such that an echo pulse is returned along the alumina rod to the point of entry. The time differential between the point of entry of the acoustic pulse into the laser tube and the exit of the echo pulse is related to the temperature at the predetermined distance within the laser tube. This information is processed and can provide an accurate indication of the average temperature within the laser tube.

  2. Identification of mixing effects in stratified chilled-water storage tanks by analysis of time series temperature data

    SciTech Connect (OSTI)

    Caldwell, J.S.; Bahnfleth, W.P.

    1998-12-31

    Several one-dimensional models of mixing in stratified chilled-water thermal energy storage tanks have been proposed. In the simplest models, mixing is assumed to be uniform throughout the tank. Other models permit spatial variation of mixing intensity. Published models were developed by adjusting model parameters to achieve qualitative agreement with measured profiles. The literature does not describe quantitative criteria for evaluating the performance of mixing models. This paper describes a method that can be used to determine the relative spatial distribution of mixing effects directly from experimental data. It also illustrates a method for quantitative comparison of experimental and modeled temperature profiles. The mixing calculation procedure may be applied to instantaneous spatial temperature data if temperature sensor spacing is sufficiently small. When sensors are widely spaced, time series data taken at individual sensors provide better accuracy. A criterion for maximum sensor spacing is proposed. The application of these procedures to time series charge-cycle operating data from a full-scale chilled-water thermal storage system serving a large medical center is described. Results of this analysis indicate that mixing is localized near the inlet diffuser and that one-dimensional flow with streamwise conduction predominates in most of the tank.

  3. Evolution of temperature distributions in a full-scale stratified chilled-water storage tank with radial diffusers

    SciTech Connect (OSTI)

    Musser, A.; Bahnfleth, W.P.

    1998-10-01

    Temperature profiles in a full-scale, naturally stratified, chilled-water thermal storage tank are described. Tests were performed using a 1.4 million gallon (5,300 m{sup 3}), 44.5 ft (13.56 m) water depth cylindrical tank with radial diffusers. Nine charge and discharge cycle tests were performed for various flow rates, covering and extending beyond the normal operating range of the system. A method for obtaining thermocline thickness from field data was derived, and a relationship between inlet flow rate and initial thermocline thickness was established. Significant differences between profiles obtained for charge and discharge cycles at similar flow rates suggest that the free surface at the top of the tank allows more mixing to occur near the upper diffuser. A study of thermocline growth compares measured temperature profiles with those predicted by a numerical conduction model that uses temperature profiles measured early in the cycle as an initial condition. Comparison with the numerical study shows that, for high flow rate tests, large-scale mixing induced by the inlet diffuser can have significant effects on thermocline development, even after the thermocline has moved away from the inlet diffuser.

  4. Chemical Vapor Deposition of Fluoroalkylsilane Monolayer Films for Adhesion Control in Microelectromechanical Systems

    SciTech Connect (OSTI)

    MAYER,THOMAS M.; DE BOER,MAARTEN P.; SHINN,NEAL D.; CLEWS,PEGGY J.; MICHALSKE,TERRY A.

    2000-01-26

    We have developed a new process for applying a hydrophobic, low adhesion energy coating to microelectromechanical (MEMS) devices. Monolayer films are synthesized from tridecafluoro-1,1,2,2-tetrahydrooctyltrichlorosilane (FOTS) and water vapor in a low-pressure chemical vapor deposition process at room temperature. Film thickness is self-limiting by virtue of the inability of precursors to stick to the fluorocarbon surface of the film once it has formed. We have measured film densities of {approx}3 molecules nm{sup 2} and film thickness of {approx}1 nm. Films are hydrophobic, with a water contact angle >110{sup o}. We have also incorporated an in-situ downstream microwave plasma cleaning process, which provides a clean, reproducible oxide surface prior to film deposition. Adhesion tests on coated and uncoated MEMS test structures demonstrate superior performance of the FOTS coatings. Cleaned, uncoated cantilever beam structures exhibit high adhesion energies in a high humidity environment. An adhesion energy of 100 mJ m{sup -2} is observed after exposure to >90% relative humidity. Fluoroalkylsilane coated beams exhibit negligible adhesion at low humidity and {<=} 20 {micro}J m{sup -2} adhesion energy at >90% relative humidity. No obvious film degradation was observed for films exposed to >90% relative humidity at room temperature for >24 hr.

  5. Experimental Analysis of Water Based Drilling Fluid Aging Processes at High Temperature and High Pressure Conditions 

    E-Print Network [OSTI]

    Zigmond, Brandon

    2012-10-19

    , drilling fluid is of most importance and a technological challenge that can greatly affect the outcome of the overall operational efficiency. It is necessary to have a sound fundamental understanding of the behavior that water-based muds (WBM) exhibit when...

  6. 2H and 13C NMR studies on the temperature-dependent water and protein dynamics in hydrated elastin, myoglobin and collagen

    E-Print Network [OSTI]

    S. A. Lusceac; C. R. Herbers; M. Vogel

    2009-04-28

    2H NMR spin-lattice relaxation and line-shape analyses are performed to study the temperature-dependent dynamics of water in the hydration shells of myoglobin, elastin, and collagen.

  7. Global study of lake surface water temperature (LSWT) behaviour and the tuning of a 1-dimensional model to determine the LSWTs of large lakes worldwide 

    E-Print Network [OSTI]

    Layden, Aisling

    2014-11-27

    Lake surface water temperatures (LSWTs) of 246 globally distributed large lakes were derived from Along-Track Scanning Radiometers (ATSR) for the period 1991 to 2011. These LSWTs, derived in a systematic manner, presents ...

  8. Design, demonstration and evaluation of a thermal enhanced vapor extraction system

    SciTech Connect (OSTI)

    Phelan, J.; Reavis, B.; Swanson, J.

    1997-08-01

    The Thermal Enhanced Vapor Extraction System (TEVES), which combines powerline frequency heating (PLF) and radio frequency (RF) heating with vacuum soil vapor extraction, was used to effectively remove volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) from a pit in the chemical waste landfill (CWL) at Sandia National Laboratories (SNL) within a two month heating period. Volume average temperatures of 83{degrees}C and 112{degrees}C were reached for the PLF and RF heating periods, respectively, within the 15 ft x 45 ft x 18.5 ft deep treated volume. This resulted in the removal of 243 lb of measured toxic organic compounds (VOCs and SVOCs), 55 gallons of oil, and 11,000 gallons of water from the site. Reductions of up to 99% in total chromatographic organics (TCO) was achieved in the heated zone. Energy balance calculations for the PLF heating period showed that 36.4% of the heat added went to heating the soil, 38.5% went to evaporating water and organics, 4.2% went to sensible heat in the water, 7.1% went to heating the extracted air, and 6.6% was lost. For the RF heating period went to heating the soil, 23.5% went to evaporating water and organics, 2.4% went to sensible heat in the water, 7.5% went to heating extracted air, and 9.7% went to losses. Energy balance closure was 92.8% for the PLF heating and 98% for the RF heating. The energy input requirement per unit soil volume heated per unit temperature increase was 1.63 kWH/yd{sup 3}-{degrees}C for PLF heating and 0.73 kWH/yd{sup 3}{degrees}C for RF heating.

  9. Accident Performance of Light Water Reactor Cladding Materials

    SciTech Connect (OSTI)

    Nelson, Andrew T.

    2012-07-24

    During a loss of coolant accident as experienced at Fukushima, inadequate cooling of the reactor core forces component temperatures ever higher where they must withstand aggressive chemical environments. Conventional zirconium cladding alloys will readily oxidize in the presence of water vapor at elevated temperatures, rapidly degrading and likely failing. A cladding breach removes the critical barrier between actinides and fission products and the coolant, greatly increasing the probability of the release of radioactivity in the event of a containment failure. These factors have driven renewed international interest in both study and improvement of the materials used in commercial light water reactors. Characterization of a candidate cladding alloy or oxidation mitigation technique requires understanding of both the oxidation kinetics and hydrogen production as a function of temperature and atmosphere conditions. Researchers in the MST division supported by the DOE-NE Fuel Cycle Research and Development program are working to evaluate and quantify these parameters across a wide range of proposed cladding materials. The primary instrument employed is a simultaneous thermal analyzer (STA) equipped with a specialized water vapor furnace capable of maintaining temperatures above 1200 C in a range of atmospheres and water vapor contents. The STA utilizes thermogravimetric analysis and a coupled mass spectrometer to measure in situ oxidation and hydrogen production of candidate materials. This capability is unprecedented in study of materials under consideration for reactor cladding use, and is currently being expanded to investigate proposed coating techniques as well as the effect of coating defects on corrosion resistance.

  10. Steam-water two-phase flow in large diameter vertical piping at high pressures and temperatures

    SciTech Connect (OSTI)

    Hasanein, H.A.; Kawaji, Masahiro [Univ. of Toronto, Ontario (Canada); Chan, A.M.C. [Ontario Hydro Technologies, Toronto, Ontario (Canada); Yoshioka, Yuzuru [Japan Atomic Power Co., Tokyo (Japan)

    1996-08-01

    No information on steam/water two-phase flow behavior in large diameter pipes (10 inch or larger) at elevated pressures is available in the open literature. However, there are many applications, in the nuclear, chemical and petroleum industries among others where two-phase flows in large diameter pipes at elevated pressures and temperatures are encountered routinely or under accident scenarios. Experimental data on steam-water two-phase flow in a large diameter (20 inch, 50.08 cm I.D.) vertical pipe at elevated pressures and temperatures (2.8 MPa/230 C--6.4 MPa/280 C) have been obtained. Void fraction, two-phase mass flux, phase and velocity distributions as well as pressure drop along the test pipe have been measured using the Ontario Hydro Technologies (OHT) Pump Test Loop. The void fraction distributions were found to be axially symmetric and nearly flat over a wide range of two-phase flow conditions. The two-phase flow regime could be inferred from the dynamic void fluctuations data. For the 280 C tests, the flow was found to be relatively stable with bubbly flow at low average void fractions and churn turbulent or wispy-annular flow at higher void fractions. At 230 C, the flow became rather oscillatory and slugging was suspected at relatively low voids. It has also been found that the average void fractions in the test section can be determined reasonably accurately using the axial pressure drop data.

  11. Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas: Experimental vapor pressures, vaporization, fusion and sublimation enthalpies of a number of dialkyl, dibutyl phthalate, and bis(2-ethylhexyl) phthalate. New vaporization enthalpies and liquid vapor pressure

  12. The Vaporization Enthalpies and Vapor Pressures of Some Primary Amines of Pharmaceutical Importance by Correlation Gas

    E-Print Network [OSTI]

    Chickos, James S.

    The Vaporization Enthalpies and Vapor Pressures of Some Primary Amines of Pharmaceutical Importance Information ABSTRACT: Vapor pressures, vaporization, and sublimation enthalpies of several pharmaceuticals.5 ± 2.1); p(cr)/Pa = 0.12 ± 0.04]. Vapor pressure equations also derived from vapor pressureretention

  13. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATIONIntroducing theActivation byIs a SmallIsotope and Temperature

  14. Low-temperature chemistry between water and hydroxyl radicals: H/D isotopic effects

    E-Print Network [OSTI]

    Lamberts, T; Puletti, F; Ioppolo, S; Cuppen, H M; Linnartz, H

    2015-01-01

    Sets of systematic laboratory experiments are presented -- combining Ultra High Vacuum cryogenic and plasma-line deposition techniques -- that allow us to compare H/D isotopic effects in the reaction of H2O (D2O) ice with the hydroxyl radical OD (OH). The latter is known to play a key role as intermediate species in the solid-state formation of water on icy grains in space. The main finding of our work is that the reaction H2O + OD --> OH + HDO occurs and that this may affect the HDO/H2O abundances in space. The opposite reaction D2O + OH --> OD + HDO is much less effective, and also given the lower D2O abundances in space not expected to be of astronomical relevance. The experimental results are extended to the other four possible reactions between hydroxyl and water isotopes and are subsequently used as input for Kinetic Monte Carlo simulations. This way we interpret our findings in an astronomical context, qualitatively testing the influence of the reaction rates.

  15. Lateral Mobility of Amphiphiles Adsorbed at the Air/Water Interface

    E-Print Network [OSTI]

    Carlson, Eric David

    2009-01-01

    Liquid/Vapor Interface of Water. J. Phys. Chem. 1996 , 100,Pratt, L. R. Molecular Dynamics of the Water Liquid/VaporInterface of Water. J. Phys. Chem. 1987 , 91, 4873–4878 21.

  16. Chemical vapor deposition of epitaxial silicon

    DOE Patents [OSTI]

    Berkman, Samuel (Florham Park, NJ)

    1984-01-01

    A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

  17. Ship-based measurement of air-sea CO 2 exchange by eddy covariance

    E-Print Network [OSTI]

    Miller, Scott D; Marandino, Christa A; Saltzman, Eric S

    2010-01-01

    temperature, water vapor, and pressure fluctuations in thedue to water vapor, temperature, and pressure will affectand water vapor, respectively, and P is pressure [Webb et

  18. Method and apparatus to measure vapor pressure in a flow system

    DOE Patents [OSTI]

    Grossman, M.W.; Biblarz, O.

    1991-10-15

    The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process. 2 figures.

  19. Thermodynamic analysis and growth of ZrO2 by chloride chemical vapor deposition

    E-Print Network [OSTI]

    Anderson, Timothy J.

    for the chemical vapor deposition (CVD) of zirconia. The results showed zirconia formation would occur at high) and high temperatures (N800 °C). Using these calculations as a guide, single-phase monoclinic zirconia.46 mg cm-2 h-1 . © 2007 Elsevier B.V. All rights reserved. Keywords: Chemical vapor deposition; Zirconia

  20. Computational Chemistry-Based Identification of Ultra-Low Temperature Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Manos Mavrikakis

    2008-08-31

    The current work seeks to identify novel, catalytically-active, stable, poison-resistant LWGS catalysts that retain the superior activity typical of conventional Cu catalysts but can be operated at similar or lower temperatures. A database for the Binding Energies (BEs) of the LWGS relevant species, namely CO, O and OH on the most-stable, close-packed facets of a set of 17 catalytically relevant transition metals was established. This BE data and a database of previously established segregation energies was utilized to predict the stability of bimetallic NSAs that could be synthesized by combinations of the 17 parent transition metals. NSAs that were potentially stable both in vacuo and under the influence of strong-binding WGS intermediates were then selected for adsorption studies. A set of 40 NSAs were identified that satisfied all three screener criteria and the binding energies of CO, O and OH were calculated on a set of 66, 43 and 79 NSA candidates respectively. Several NSAs were found that bound intermediates weaker than the monometallic catalysts and were thus potentially poison-resistant. Finally, kinetic studies were performed and resulted in the discovery of a specific NSA-based bimetallic catalyst Cu/Pt that is potentially a promising LWGS catalyst. This stable Cu/Pt subsurface alloy is expected to provide facile H{sub 2}O activation and remain relatively resistant from the poisoning by CO, S and formate intermediates.

  1. Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors

    DOE Patents [OSTI]

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-10-14

    A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

  2. Concept Paper for Real-Time Temperature and Water QualityManagement for San Joaquin River Riparian Habitat Restoration

    SciTech Connect (OSTI)

    Quinn, Nigel W.T.

    2004-12-20

    The San Joaquin River Riparian Habitat Restoration Program (SJRRP) has recognized the potential importance of real-time monitoring and management to the success of the San Joaquin River (SJR) restoration endeavor. The first step to realizing making real-time management a reality on the middle San Joaquin River between Friant Dam and the Merced River will be the installation and operation of a network of permanent telemetered gauging stations that will allow optimization of reservoir releases made specifically for fish water temperature management. Given the limited reservoir storage volume available to the SJJRP, this functionality will allow the development of an adaptive management program, similar in concept to the VAMP though with different objectives. The virtue of this approach is that as management of the middle SJR becomes more routine, additional sensors can be added to the sensor network, initially deployed, to continue to improve conditions for anadromous fish.

  3. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Phillip, Bradley L. (20976 Fairmount Blvd., Shaker Heights, Cuyahoga County, OH 44120)

    1997-01-01

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compostions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  4. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Phillip, Bradley L. (Shaker Heights, OH)

    1997-01-01

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100.degree. C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  5. Compositional Variations in Vapor Deposited Samarium Zirconate Coatings

    E-Print Network [OSTI]

    Wadley, Haydn

    Compositional Variations in Vapor Deposited Samarium Zirconate Coatings A Thesis Presented temperatures instead have relied on the development of thermal barrier coating (TBC) systems. The thermal barrier coating systems applied to superalloys consist of three layers: (i) an aluminum rich metallic bond

  6. Drying of pulverized material with heated condensible vapor

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1986-01-01

    Apparatus for drying pulverized material utilizes a high enthalpy condensable vapor such as steam for removing moisture from the individual particles of the pulverized material. The initially wet particulate material is tangentially delivered by a carrier vapor flow to an upper portion of a generally vertical cylindrical separation drum. The lateral wall of the separation drum is provided with a plurality of flow guides for directing the vapor tangentially therein in the direction of particulate material flow. Positioned concentrically within the separation drum and along the longitudinal axis thereof is a water-cooled condensation cylinder which is provided with a plurality of collection plates, or fins, on the outer lateral surface thereof. The cooled collection fins are aligned counter to the flow of the pulverized material and high enthalpy vapor mixture to maximize water vapor condensation thereon. The condensed liquid which includes moisture removed from the pulverized material then flows downward along the outer surface of the coolant cylinder and is collected and removed. The particles travel in a shallow helix due to respective centrifugal and vertical acceleration forces applied thereto. The individual particles of the pulverized material are directed outwardly by the vortex flow where they contact the inner cylindrical surface of the separation drum and are then deposited at the bottom thereof for easy collection and removal. The pulverized material drying apparatus is particularly adapted for drying coal fines and facilitates the recovery of the pulverized coal.

  7. Drying of pulverized material with heated condensible vapor

    DOE Patents [OSTI]

    Carlson, L.W.

    1984-08-16

    Apparatus for drying pulverized material utilizes a high enthalpy condensable vapor such as steam for removing moisture from the individual particles of the pulverized material. The initially wet particulate material is tangentially delivered by a carrier vapor flow to an upper portion of a generally vertical cylindrical separation drum. The lateral wall of the separation drum is provided with a plurality of flow guides for directing the vapor tangentially therein in the direction of particulate material flow. Positioned concentrically within the separation drum and along the longitudinal axis thereof is a water-cooled condensation cylinder which is provided with a plurality of collection plates, or fines, on the outer lateral surface thereof. The cooled collection fines are aligned counter to the flow of the pulverized material and high enthalpy vapor mixture to maximize water vapor condensation thereon. The condensed liquid which includes moisture removed from the pulverized materials then flows downward along the outer surface of the coolant cylinder and is collected and removed. The particles travel in a shallow helix due to respective centrifugal and vertical acceleration forces applied thereto. The individual particles of the pulverized material are directed outwardly by the vortex flow where they contact the inner cylindrical surface of the separation drum and are then deposited at the bottom thereof for easy collection and removal. The pulverized material drying apparatus is particularly adapted for drying coal fines and facilitates the recovery of the pulverized coal. 2 figs.

  8. Treatment methods for breaking certain oil and water emulsions

    DOE Patents [OSTI]

    Sealock, Jr., L. John (W. Richland, WA); Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1992-01-01

    Disclosed are treatment methods for breaking emulsions of petroleum oil and salt water, fatty oil and water, and those resulting from liquefication of organic material. The emulsions are broken by heating to a predetermined temperature at or above about 200.degree. C. and pressurizing to a predetermined pressure above the vapor pressure of water at the predetermined temperature to produce a heated and pressurized fluid. The heated and pressurized fluid is contained in a single vessel at the predetermined temperature and pressure for a predetermined period of time to effectively separate the emulsion into substantially distinct first and second phases, the first phase comprising primarily the petroleum oil, the second phase comprising primarily the water. The first and second phases are separately withdrawn from the vessel at a withdraw temperature between about 200.degree. C. and 374.degree. C. and a withdraw pressure above the vapor pressure of water at the withdraw temperature. Where solids are present in the certain emulsions, the above described treatment may also effectively separate the certain emulsion into a substantially distinct third phase comprising primarily the solids.

  9. Portable vapor diffusion coefficient meter

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2007-06-12

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  10. Narrowband fluorescent nanodiamonds produced from chemical vapor deposition films

    E-Print Network [OSTI]

    Neu, Elke; Gross, Elke; Hepp, Christian; Steinmetz, David; Zscherpel, Elisabeth; Ghodbane, Slimane; Sternschulte, Hadwig; Steinmueller-Nethl, Doris; Liang, Yuejiang; Krueger, Anke; Becher, Christoph

    2011-01-01

    We report on the production of nanodiamonds (NDs) with 70-80 nm size via bead assisted sonic disintegration (BASD) of a polycrystalline chemical vapor deposition (CVD) film. The NDs display high crystalline quality as well as intense narrowband (7 nm) room temperature luminescence at 738 nm due to in situ incorporated silicon vacancy (SiV) centers. The fluorescence properties at room and cryogenic temperatures indicate that the NDs are, depending on preparation, applicable as single photon sources or as fluorescence labels.

  11. Narrowband fluorescent nanodiamonds produced from chemical vapor deposition films

    E-Print Network [OSTI]

    Elke Neu; Carsten Arend; Felix Guldner; Elke Gross; Christian Hepp; David Steinmetz; Elisabeth Zscherpel; Slimane Ghodbane; Hadwig Sternschulte; Doris Steinmueller-Nethl; Yuejiang Liang; Anke Krueger; Christoph Becher

    2011-05-24

    We report on the production of nanodiamonds (NDs) with 70-80 nm size via bead assisted sonic disintegration (BASD) of a polycrystalline chemical vapor deposition (CVD) film. The NDs display high crystalline quality as well as intense narrowband (7 nm) room temperature luminescence at 738 nm due to in situ incorporated silicon vacancy (SiV) centers. The fluorescence properties at room and cryogenic temperatures indicate that the NDs are, depending on preparation, applicable as single photon sources or as fluorescence labels.

  12. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  13. SiC rapid thermal carbonization of the (111)Si semiconductor-on-insulator structure and subsequent metalorganic chemical vapor deposition

    E-Print Network [OSTI]

    Cincinnati, University of

    vapor deposition with mixtures of propane and H2 at atmospheric pressure. Carbonization temperatures metalorganic chemical vapor deposition of GaN A. J. Steckla) and J. Devrajan University of Cincinnati . Metalorganic chemical vapor deposition growth of GaN on the 111 SiC SOI was carried out with trimethylgallium

  14. Application of Computational Fluid Dynamics in the Forced Dispersion Modeling of LNG Vapor Clouds 

    E-Print Network [OSTI]

    Kim, Byung-Kyu

    2013-05-31

    The safety and security of liquefied natural gas (LNG) facilities has prompted the need for continued study of LNG mitigation systems. Water spray systems are widely recognized as an effective measure for dispersing LNG vapor clouds. Currently...

  15. Optimization of multi-pressure himidification-dehumidification desalination using thermal vapor compression and hybridization

    E-Print Network [OSTI]

    Mistry, Karan Hemant

    Humidification-dehumidification (HD or HDH) desalination, and specifically HD driven by a thermal vapor compressor (TVC), is a thermal desalination method that has the potential to produce potable water efficiently in order ...

  16. Final report on the project entitled "The Effects of Disturbance & Climate on Carbon Storage & the Exchanges of CO2 Water Vapor & Energy Exchange of Evergreen Coniferous Forests in the Pacific Northwest: Integration of Eddy Flux, Plant and Soil Measurements at a Cluster of Supersites"

    SciTech Connect (OSTI)

    Beverly E. Law , Christoph K. Thomas

    2011-09-20

    This is the final technical report containing a summary of all findings with regard to the following objectives of the project: (1) To quantify and understand the effects of wildfire on carbon storage and the exchanges of energy, CO2, and water vapor in a chronosequence of ponderosa pine (disturbance gradient); (2) To investigate the effects of seasonal and interannual variation in climate on carbon storage and the exchanges of energy, CO2, and water vapor in mature conifer forests in two climate zones: mesic 40-yr old Douglas-fir and semi-arid 60-yr old ponderosa pine (climate gradient); (3) To reduce uncertainty in estimates of CO2 feedbacks to the atmosphere by providing an improved model formulation for existing biosphere-atmosphere models; and (4) To provide high quality data for AmeriFlux and the NACP on micrometeorology, meteorology, and biology of these systems. Objective (1): A study integrating satellite remote sensing, AmeriFlux data, and field surveys in a simulation modeling framework estimated that the pyrogenic carbon emissions, tree mortality, and net carbon exchange associated with four large wildfires that burned ~50,000 hectares in 2002-2003 were equivalent to 2.4% of Oregon statewide anthropogenic carbon emissions over the same two-year period. Most emissions were from the combustion of the forest floor and understory vegetation, and only about 1% of live tree mass was combusted on average. Objective (2): A study of multi-year flux records across a chronosequence of ponderosa pine forests yielded that the net carbon uptake is over three times greater at a mature pine forest compared with young pine. The larger leaf area and wetter and cooler soils of the mature forest mainly caused this effect. A study analyzing seven years of carbon and water dynamics showed that interannual and seasonal variability of net carbon exchange was primarily related to variability in growing season length, which was a linear function of plant-available soil moisture in spring and early summer. A multi-year drought (2001-2003) led to a significant reduction of net ecosystem exchange due to carry-over effects in soil moisture and carbohydrate reserves in plant-tissue. In the same forest, the interannual variability in the rate carbon is lost from the soil and forest floor is considerable and related to the variability in tree growth as much as it is to variability in soil climatic conditions. Objective (3): Flux data from the mature ponderosa pine site support a physical basis for filtering nighttime data with friction velocity above the canopy. An analysis of wind fields and heat transport in the subcanopy at the mesic 40-year old Douglas site yielded that the non-linear structure and behavior of spatial temperature gradients and the flow field require enhanced sensor networks to estimate advective fluxes in the subcanopy of forest to close the surface energy balance in forests. Reliable estimates for flux uncertainties are needed to improve model validation and data assimilation in process-based carbon models, inverse modeling studies and model-data synthesis, where the uncertainties may be as important as the fluxes themselves. An analysis of the time scale dependence of the random and flux sampling error yielded that the additional flux obtained by increasing the perturbation timescale beyond about 10 minutes is dominated by random sampling error, and therefore little confidence can be placed in its value. Artificial correlation between gross ecosystem productivity (GEP) and ecosystem respiration (Re) is a consequence of flux partitioning of eddy covariance flux data when GEP is computed as the difference between NEE and computed daytime Re (e.g. using nighttime Re extrapolated into daytime using soil or air temperatures). Tower-data must be adequately spatially averaged before comparison to gridded model output as the time variability of both is inherently different. The eddy-covariance data collected at the mature ponderosa pine site and the mesic Douglas fir site were used to develop and evaluate a new method to extra

  17. Interactions of gaseous HNO3 and water with individual and mixed alkyl self-assembled monolayers at room temperature.

    E-Print Network [OSTI]

    Nishino, Noriko; Hollingsworth, Scott A; Stern, Abraham C; Roeselová, Martina; Tobias, Douglas J; Finlayson-Pitts, Barbara J

    2014-01-01

    of gaseous HNO 3 and water with individual and mixed alkylon all SAM surfaces when water is removed. Results ofof gas-phase HNO 3 and water on organic films using a C8

  18. MMA Memo. No. 238 Precipitable Water at KP ---1993--1998

    E-Print Network [OSTI]

    Groppi, Christopher

    of each water molecule (mw = 18 amu), P 0 is the water vapor partial pressure at the surface, H is in K. Note that if you have a surface water vapor partial pressure measurement in hPa (a common is equal to the surface water vapor partial pressure in hPa (because T 0 is always ¸ 250­310 K

  19. Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

    DOE Patents [OSTI]

    Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

    2014-12-02

    The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

  20. Vaporization Enthalpies and Vapor Pressures of Two Insecticide Components, Muscalure and Empenthrin, by Correlation Gas

    E-Print Network [OSTI]

    Chickos, James S.

    Vaporization Enthalpies and Vapor Pressures of Two Insecticide Components, Muscalure and Empenthrin: The vaporization enthalpies at T/K = 298.15 and vapor pressures from T/K = (298.15 to Tnb (normal boiling. Vaporization enthalpies of [(114.4 ± 1.0) and (114.5 ± 1.0)] kJ·mol-1 and vapor pressures, p/Pa = [(1.2 ± 0

  1. Direct Real-Time Detection of Vapors from Explosive Compounds

    SciTech Connect (OSTI)

    Ewing, Robert G.; Clowers, Brian H.; Atkinson, David A.

    2013-10-03

    The real-time detection of vapors from low volatility explosives including PETN, tetryl, RDX and nitroglycerine along with various compositions containing these substances is demonstrated. This was accomplished with an atmospheric flow tube (AFT) using a non-radioactive ionization source and coupled to a mass spectrometer. Direct vapor detection was demonstrated in less than 5 seconds at ambient temperature without sample pre-concentration. The several seconds of residence time of analytes in the AFT provides a significant opportunity for reactant ions to interact with analyte vapors to achieve ionization. This extended reaction time, combined with the selective ionization using the nitrate reactant ions (NO3- and NO3-•HNO3), enables highly sensitive explosives detection. Observed signals from diluted explosive vapors indicate detection limits below 10 ppqv using selected ion monitoring (SIM) of the explosive-nitrate adduct at m/z 349, 378, 284 and 289 for tetryl, PETN, RDX and NG respectively. Also provided is a demonstration of the vapor detection from 10 different energetic formulations, including double base propellants, plastic explosives and commercial blasting explosives using SIM for the NG, PETN and RDX product ions.

  2. Vapor etching of nuclear tracks in dielectric materials

    DOE Patents [OSTI]

    Musket, Ronald G. (Danville, CA); Porter, John D. (Berkeley, CA); Yoshiyama, James M. (Fremont, CA); Contolini, Robert J. (Lake Oswego, OR)

    2000-01-01

    A process involving vapor etching of nuclear tracks in dielectric materials for creating high aspect ratio (i.e., length much greater than diameter), isolated cylindrical holes in dielectric materials that have been exposed to high-energy atomic particles. The process includes cleaning the surface of the tracked material and exposing the cleaned surface to a vapor of a suitable etchant. Independent control of the temperatures of the vapor and the tracked materials provide the means to vary separately the etch rates for the latent track region and the non-tracked material. As a rule, the tracked regions etch at a greater rate than the non-tracked regions. In addition, the vapor-etched holes can be enlarged and smoothed by subsequent dipping in a liquid etchant. The 20-1000 nm diameter holes resulting from the vapor etching process can be useful as molds for electroplating nanometer-sized filaments, etching gate cavities for deposition of nano-cones, developing high-aspect ratio holes in trackable resists, and as filters for a variety of molecular-sized particles in virtually any liquid or gas by selecting the dielectric material that is compatible with the liquid or gas of interest.

  3. Partially sulfated lime-fly ash sorbents activated by water or steam for SO{sub 2} removal at a medium temperature

    SciTech Connect (OSTI)

    Liming Shi; Xuchang Xu

    2005-12-01

    Laboratory experiments were conducted to investigate the reactivity of partially sulfated lime-fly ash sorbents activated by water or steam for SO{sub 2} removal. Sulfation tests were performed at 550{sup o}C using a fixed bed reactor under conditions simulating economizer zone injection flue gas desulfurization. Activation experiments were conducted with water or steam using a range of temperatures between 100 and 550{sup o}C. The results showed that the reactivity of the sorbents was closely related to the content of Ca(OH){sub 2} formed in the activation process, which varied with the water or steam temperature. The sulfur dioxide capture capacity of Ca(OH){sub 2} in the sorbent is higher than that of CaO at a medium temperature. Water or steam temperatures in the range of 100-200{sup o}C are favorable to the formation of Ca(OH){sub 2} from CaO. 15 refs., 8 figs., 2 tabs.

  4. Vapor deposition of thin films

    DOE Patents [OSTI]

    Smith, David C. (Los Alamos, NM); Pattillo, Stevan G. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Sattelberger, Alfred P. (Los Alamos, NM)

    1992-01-01

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl).sub.3, iridium(allyl).sub.3, molybdenum(allyl).sub.4, tungsten(allyl).sub.4, rhenium(allyl).sub.4, platinum(allyl).sub.2, or palladium(allyl).sub.2 are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  5. Image Storage in Hot Vapors

    E-Print Network [OSTI]

    L. Zhao; T. Wang; Y. Xiao; S. F. Yelin

    2007-10-22

    We theoretically investigate image propagation and storage in hot atomic vapor. A $4f$ system is adopted for imaging and an atomic vapor cell is placed over the transform plane. The Fraunhofer diffraction pattern of an object in the object plane can thus be transformed into atomic Raman coherence according to the idea of ``light storage''. We investigate how the stored diffraction pattern evolves under diffusion. Our result indicates, under appropriate conditions, that an image can be reconstructed with high fidelity. The main reason for this procedure to work is the fact that diffusion of opposite-phase components of the diffraction pattern interfere destructively.

  6. Vapor deposition of thin films

    SciTech Connect (OSTI)

    Smith, D.C.; Pattillo, S.G.; Laia, J.R. Jr.; Sattelberger, A.P.

    1990-10-05

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl){sub 3}, iridium(allyl){sub 3}, molybdenum(allyl){sub 4}, tungsten(allyl){sub 4}, rhenium (allyl){sub 4}, platinum(allyl){sub 2}, or palladium(allyl){sub 2} are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  7. Fabrication and Characterization of Uranium-based High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bed chemical vapor deposition in a 50-mm diameter conical chamber within the coating furnace. Computer control of temperature and gas composition ensures reproducibility and...

  8. Vacuum vapor deposition gun assembly

    DOE Patents [OSTI]

    Zeren, Joseph D. (Boulder, CO)

    1985-01-01

    A vapor deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, a hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

  9. Atomic vapor laser isotope separation process

    DOE Patents [OSTI]

    Wyeth, R.W.; Paisner, J.A.; Story, T.

    1990-08-21

    A laser spectroscopy system is utilized in an atomic vapor laser isotope separation process. The system determines spectral components of an atomic vapor utilizing a laser heterodyne technique. 23 figs.

  10. The effect of environment, chemistry, and microstructure on the corrosion fatigue behavior of austenitic stainless steels in high temperature water

    E-Print Network [OSTI]

    O'Brien, Lindsay Beth

    2014-01-01

    The effect of sulfur on the corrosion fatigue crack growth of austenitic stainless steel was evaluated under Light Water Reactor (LWR) conditions of 288°C deaerated (less than 5ppb O?) water, to shed light on the accelerating ...

  11. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, A.

    1989-11-21

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

  12. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  13. THE JOURNAL OF CHEMICAL PHYSICS 142, 212408 (2015) Dynamics of water, methanol, and ethanol in a room temperature

    E-Print Network [OSTI]

    Fayer, Michael D.

    2015-01-01

    THE JOURNAL OF CHEMICAL PHYSICS 142, 212408 (2015) Dynamics of water, methanol, and ethanol with increasing alkyl chain length: water, methanol, and ethanol, diluted to low concentration in the room is increased: 23 ps for water, 28 ps for methanol, and 34 ps for ethanol. Although in each case, only a single

  14. Vapor-liquid equilibrium of the Mg(NO/sub 3/)/sub 2/-HNO/sub 3/-H/sub 2/O system

    SciTech Connect (OSTI)

    Thompson, B.E.; Derby, J.J.; Stalzer, E.H.

    1983-06-01

    The vapor-liquid equilibrium of the Mg(NO/sub 3/)/sub 2/-HNO/sub 3/-H/sub 2/O system in concentrations of 0 to 70 wt % Mg(NO/sub 3/)/sub 2/ and 0 to 75 wt % HNO/sub 3/ at atmospheric pressure was correlated by two approaches. One was based on a dissociation equilibrium expression in which the activities of the reacting species (HNO/sub 3/, NO/sub 3//sup -/, and H/sup +/) were approximated with mole fractions. The activity coefficients of the undissociated HNO/sub 3/ and H/sub 2/O were correlated as functions of the concentrations of magnesium nitrate and nitric acid by second-order polynomials. The average absolute difference between predicted and experimental values was 8% for the mole fraction of acid in the vapor and 8/sup 0/K for the bubble-point temperature. The second approach was to correlate the mean ionic rational activity coefficient of water with a form of the excess Gibbs energy composed of two terms. One term, a function of the ionic strength, accounts for the coulombic (ionic) interactions; the other term accounts for the non-coulombic (molecular) interactions. The average absolute difference between predicted and experimental values was 9% for the mole fraction of acid in the vapor, and 10/sup 0/K for the bubble-point temperature.

  15. Analysis of impact melt and vapor production in CTH for planetary applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Quintana, S. N.; Crawford, D. A.; Schultz, P. H.

    2015-05-19

    This study explores impact melt and vapor generation for a variety of impact speeds and materials using the shock physics code CTH. The study first compares the results of two common methods of impact melt and vapor generation to demonstrate that both the peak pressure method and final temperature method are appropriate for high-speed impact models (speeds greater than 10 km/s). However, for low-speed impact models (speeds less than 10 km/s), only the final temperature method is consistent with laboratory analyses to yield melting and vaporization. Finally, a constitutive model for material strength is important for low-speed impacts because strengthmore »can cause an increase in melting and vaporization.« less

  16. Reduced pressure and temperature reclamation of water using the GE Integrated Water-waste Management System for potential space flight application 

    E-Print Network [OSTI]

    Chowdhury, Hasan Imtiaz

    1989-01-01

    hardware and verify the results previously reported by GE, the following series of tests were performed: 1) Disassemble, clean, and reassemble the system. 2) Determine the condensation rate as a function of temperature of the evaporator and the condenser... derivative (PID) feedback control sensor. The cooling system devised has a capacity of 1465 W and is controlled by an on/otf temperature sensor operating through a time delay relay. B. RESULTS AND DISCUSSION The system characterization procedure consisted...

  17. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, L.D.; Cerni, T.A.

    1989-10-17

    Apparatus and method are disclosed which determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavelength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to an equation given in the patent where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4) + K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation. 11 figs.

  18. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, Loren D. (Morrison, CO); Cerni, Todd A. (Littleton, CO)

    1989-01-01

    Apparatus and method determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavlength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to: ##EQU1## where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4)+K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation.

  19. Vapor-like liquid coexistence densities affect the extension of the critical point's influence zone

    E-Print Network [OSTI]

    Rivera, Jose Luis; Guerra-Gonzalez, Roberto

    2015-01-01

    The critical point affects the coexistence behavior of the vapor-liquid equilibrium densities. The length of the critical influence zone is under debate because for some properties, like shear viscosity, the extension is only a few degrees, while for others, such as the density order parameter, the critical influence zone range covers up to hundreds of degrees below the critical temperature. Here we show that for a simple molecular potential of ethane, the critical influence zone covers a wide zone of tens of degrees (below the critical temperature) down to a transition temperature, at which the apparent critical influence zone vanishes and the transition temperature can be predicted through a pressure analysis of the coexisting bulk liquid phase. The liquid phases within the apparent critical influence zone show low densities, making them behave internally like their corresponding vapor phases. Therefore, the experimentally observed wide extension of the critical influence zone is due to a vapor-like effect ...

  20. On the physical adsorption of vapors by microporous carbons

    SciTech Connect (OSTI)

    Bradley, R.H. (Univ. of Technology, Loughborough (United Kingdom). Inst. of Surface Science and Technology); Rand, B. (Univ. of Leeds (United Kingdom). Division of Ceramics)

    1995-01-01

    The physical adsorption of nonpolar and polar vapors by active carbons is discussed in relation to pore structure and pore wall chemistry. For nonpolar vapors the Dubinin-Radushkevich equation is used to derive micropore volumes (W[sub 0]), average adsorption energies (E[sub 0]), and micropore widths (L) for a number of systems. These parameters are used to interpret the adsorption behavior of nitrogen which, because it is a relatively small molecule, is frequently used at 77 K to probe porosity and surface area. Results are presented for three carbons from differing precursors, namely, coal, coconut shells, and polyvinylidene chloride (PVDC) to illustrate the applicability of the technique. For the latter carbon increases in micropore size, induced by activation in carbon dioxide, and reductions in accessible pore volume caused by heat treatment in argon are also characterized and related to structural changes. The approach is then extended to the adsorption of larger hydrogen vapors, where the resulting W[sub 0] values may require correction for molecular packing effects which occur in the lower relative pressure regions of the isotherms, i.e., during the filling of ultramicropores. These packing effects are shown to limit the use of the Polanyi characteristic curve for correlating isotherm data for several vapors, of differing molecular size, by one adsorbent. Data for the adsorption of water, which is a strongly polar liquid, have been interpreted using the Dubinin-Serpinsky equation.

  1. Fire flood method for recovering petroleum from oil reservoirs of low permeability and temperature

    DOE Patents [OSTI]

    1984-08-14

    The present invention is directed to a method of enhanced oil recovery by fire flooding petroleum reservoirs characterized by a temperature of less than the critical temperature of carbon dioxide, a pore pressure greater than the saturated vapor pressure of carbon dioxide at said temperature (87.7.degree. F. at 1070 psia), and a permeability in the range of about 20 to 100 millidarcies. The in situ combustion of petroleum in the reservoir is provided by injecting into the reservoir a combustion supporting medium consisting essentially of oxygen, ozone, or a combination thereof. The heat of combustion and the products of this combustion which consist essentially of gaseous carbon dioxide and water vapor sufficiently decrease the viscosity of oil adjacent to fire front to form an oil bank which moves through the reservoir towards a recovery well ahead of the fire front. The gaseous carbon dioxide and the water vapor are driven into the reservoir ahead of the fire front by pressure at the injection well. As the gaseous carbon dioxide cools to less than about 88.degree. F. it is converted to liquid which is dissolved in the oil bank for further increasing the mobility thereof. By using essentially pure oxygen, ozone, or a combination thereof as the combustion supporting medium in these reservoirs the permeability requirements of the reservoirs are significantly decreased since the liquid carbon dioxide requires substantially less voidage volume than that required for gaseous combustion products.

  2. Effects of storage temperature and duration on release of antimony and bisphenol A from polyethylene terephthalate drinking water

    E-Print Network [OSTI]

    Ma, Lena

    polyethylene terephthalate drinking water bottles of China Ying-Ying Fan a , Jian-Lun Zheng a , Jing-Hua Ren Accepted 9 May 2014 Available online xxx Keywords: Polyethylene terephthalate Antimony Bisphenol A Release of antimony (Sb) and bisphenol A (BPA) from 16 brands of polyethylene terephthalate (PET) drinking water

  3. Interactive effects of elevated CO{sub 2}, drought and high temperature on plant water use efficiency

    SciTech Connect (OSTI)

    Theodore C. Hsiao

    1998-08-01

    Water use efficiency (WUE) by plants is a key determinant of productivity and survival of plants under water limiting or drought conditions. The aim of this project was to develop a mechanistic basis for predicting WUE without the prohibitive task of studying every plant species under a range of environmental conditions.

  4. Effect of smoke on subcanopy shaded light, canopy temperature, and carbon dioxide uptake in an Amazon rainforest

    E-Print Network [OSTI]

    Doughty, C. E.; Flanner, M. G.; Goulden, M. L.

    2010-01-01

    1997), Measuring and modeling carbon dioxide and water vaportechnique for evalu- ating carbon dioxide exchange rates ofof ecosystem?scale carbon dioxide, water vapor, and energy

  5. Temperature dependence of the vapour tension of methyl-substituted phenol derivatives

    SciTech Connect (OSTI)

    S.G. Gagarin [Institute of Mineral Fuels (Russian Federation)

    2007-05-15

    Notable among the coking products of coal are phenol and its derivatives, derived for the coal tar and water layer above ht tar. Given that phenol an its derivatives are mainly extracted from coal tar fractions by rectification, information on how the vapor tension of the individual components depends on the temperature is of great importance. For phenol and various substituted alkylphenols there are tabular data. In the pre-computer era these data were sufficient for the separation of phenol mixtures. However, the development and introduction of information technology in the coal industry and in the design process demands the mathematical description of the physicochemical processes of coking products. The temperature dependence of the saturated vapor pressure for organic compounds is commonly described by the Antoine equation.

  6. Process for recovering organic vapors from air

    DOE Patents [OSTI]

    Baker, Richard W. (Mountain View, CA)

    1985-01-01

    A process for recovering and concentrating organic vapor from a feed stream of air having an organic vapor content of no more than 20,000 ppm by volume. A thin semipermeable membrane is provided which has a feed side and a permeate side, a selectivity for organic vapor over air of at least 50, as measured by the ratio of organic vapor permeability to nitrogen permeability, and a permeability of organic vapor of at least 3.times.10.sup.-7 cm.sup.3 (STP) cm/cm.sup.2 sec.cm Hg. The feed stream is passed across the feed side of the thin semipermeable membrane while providing a pressure on the permeate side which is lower than the feed side by creating a partial vacuum on the permeate side so that organic vapor passes preferentially through the membrane to form an organic vapor depleted air stream on the feed side and an organic vapor enriched stream on the permeate side. The organic vapor which has passed through the membrane is compressed and condensed to recover the vapor as a liquid.

  7. “Multi-temperature” method for high-pressure sorption measurements on moist shales

    SciTech Connect (OSTI)

    Gasparik, Matus; Ghanizadeh, Amin; Gensterblum, Yves; Krooss, Bernhard M.

    2013-08-15

    A simple and effective experimental approach has been developed and tested to study the temperature dependence of high-pressure methane sorption in moist organic-rich shales. This method, denoted as “multi-temperature” (short “multi-T”) method, enables measuring multiple isotherms at varying temperatures in a single run. The measurement of individual sorption isotherms at different temperatures takes place in a closed system ensuring that the moisture content remains constant. The multi-T method was successfully tested for methane sorption on an organic-rich shale sample. Excess sorption isotherms for methane were measured at pressures of up to 25 MPa and at temperatures of 318.1 K, 338.1 K, and 348.1 K on dry and moisture-equilibrated samples. The measured isotherms were parameterized with a 3-parameter Langmuir-based excess sorption function, from which thermodynamic sorption parameters (enthalpy and entropy of adsorption) were obtained. Using these, we show that by taking explicitly into account water vapor as molecular species in the gas phase with temperature-dependent water vapor pressure during the experiment, more meaningful results are obtained with respect to thermodynamical considerations. The proposed method can be applied to any adsorbent system (coals, shales, industrial adsorbents) and any supercritical gas (e.g., CH{sub 4}, CO{sub 2}) and is particularly suitable for sorption measurements using the manometric (volumetric) method.

  8. Vapor Barriers or Vapor Diffusion Retarders | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment of EnergyResearchers at theAugust 1, 2013theEnergyThe1984 StartVapor

  9. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels

    SciTech Connect (OSTI)

    Gardiner, D.; Bardon, M.; Pucher, G.

    2008-10-01

    Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

  10. Water harvesting using a conducting polymer: A study by molecular dynamics simulation

    SciTech Connect (OSTI)

    Ostwal, Mayur M.; Sahimi, Muhammad; Tsotsis, Theodore T. [Mork Family Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, California 90089-1211 (United States)

    2009-06-15

    The results of extensive molecular simulations of adsorption and diffusion of water vapor in polyaniline, made conducting by doping it with HCl or HBr over a broad range of temperatures, are reported. The atomistic model of the polymers was generated using energy minimization, equilibrium molecular dynamics simulations, and two different force fields. The computed sorption isotherms are in excellent agreement with the experimental data. The computed activation energies for the diffusion of water molecules in the polymers also compare well with what has been reported in the literature. The results demonstrate the potential of conducting polyaniline for water harvesting from air.

  11. Kinetics of laser pulse vaporization of uranium dioxide by mass spectrometry

    SciTech Connect (OSTI)

    Tsai, C.

    1981-11-01

    Safety analyses of nuclear reactors require knowledge of the evaporation behavior of UO/sub 2/ at temperatures well above the melting point of 3140 K. In this study, rapid transient heating of a small spot on a UO/sub 2/ specimen was accomplished by a laser pulse, which generates a surface temperature excursion. This in turn vaporizes the target surface and the gas expands into vacuum. The surface temperature transient was monitored by a fast-response automatic optical pyrometer. The maximum surface temperatures investigated range from approx. 3700 K to approx. 4300 K. A computer program was developed to simulate the laser heating process and calculate the surface temperature evolution. The effect of the uncertainties of the high temperature material properties on the calculation was included in a sensitivity study for UO/sub 2/ vaporization. The measured surface temperatures were in satisfactory agreements.

  12. Meteorological Tables for Determination of Precipitable Water, Temperatures and Pressures Aloft for a Saturated Pseudoadiabatic Atmosphere -- in the Metric System 

    E-Print Network [OSTI]

    Eihle, W. O.; Powers, R. J.; Clark, R.A.

    1968-01-01

    The hydrometeorologist is often confronted with the problem of determination of precipitable water in the atmosphere based on surface dewpoints and the assumption of a saturated atmosphere with a pseudoadiabatic lapse rate. ...

  13. Three-phase K-values for n-alkanes co-existing with water at high temperatures 

    E-Print Network [OSTI]

    Forero Reyes, Helber Alfonso

    1992-01-01

    . Model. Heptane in all Billman's Runs. . Three-phase K-value vs. Pressure. Semiempirical Model. Heptane in all Billman's Runs. . Three-phase K-value vs. Temperature. Model. Octane in all Billman's Runs. Three-phase K-value vs. Pressure. Semiempirical... Model. Octane in all Billman's Runs. Three-phase K-value vs. Temperature. Model. Nonane in all Billman's Runs. . . . . . . . . . . . . . . . . . . . . . . . Three-phase K-value vs. Pressure. Semiempirical Model, Nonane in all Billman's Runs. . Three...

  14. Sustaining dry surfaces under water

    E-Print Network [OSTI]

    Paul R. Jones; Xiuqing Hao; Eduardo R. Cruz-Chu; Konrad Rykaczewski; Krishanu Nandy; Thomas M. Schutzius; Kripa K. Varanasi; Constantine M. Megaridis; Jens H. Walther; Petros Koumoutsakos; Horacio D. Espinosa; Neelesh A. Patankar

    2014-09-29

    Rough surfaces immersed under water remain practically dry if the liquid-solid contact is on roughness peaks, while the roughness valleys are filled with gas. Mechanisms that prevent water from invading the valleys are well studied. However, to remain practically dry under water, additional mechanisms need consideration. This is because trapped gas (e.g. air) in the roughness valleys can dissolve into the water pool, leading to invasion. Additionally, water vapor can also occupy the roughness valleys of immersed surfaces. If water vapor condenses, that too leads to invasion. These effects have not been investigated, and are critically important to maintain surfaces dry under water. In this work, we identify the critical roughness scale below which it is possible to sustain the vapor phase of water and/or trapped gases in roughness valleys - thus keeping the immersed surface dry. Theoretical predictions are consistent with molecular dynamics simulations and experiments.

  15. Mercury Vapor | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenariosMarysville MtMedical Area Total Egy PltMercuriusVapor Jump to:

  16. Coupling apparatus for a metal vapor laser

    DOE Patents [OSTI]

    Ball, D.G.; Miller, J.L.

    1993-02-23

    Coupling apparatus for a large bore metal vapor laser is disclosed. The coupling apparatus provides for coupling high voltage pulses (approximately 40 KV) to a metal vapor laser with a high repetition rate (approximately 5 KHz). The coupling apparatus utilizes existing thyratron circuits and provides suitable power input to a large bore metal vapor laser while maintaining satisfactory operating lifetimes for the existing thyratron circuits.

  17. Water Evaporation: A Transition Path Sampling Study

    E-Print Network [OSTI]

    Patrick Varilly; David Chandler

    2012-12-12

    We use transition path sampling to study evaporation in the SPC/E model of liquid water. Based on thousands of evaporation trajectories, we characterize the members of the transition state ensemble (TSE), which exhibit a liquid-vapor interface with predominantly negative mean curvature at the site of evaporation. We also find that after evaporation is complete, the distributions of translational and angular momenta of the evaporated water are Maxwellian with a temperature equal to that of the liquid. To characterize the evaporation trajectories in their entirety, we find that it suffices to project them onto just two coordinates: the distance of the evaporating molecule to the instantaneous liquid-vapor interface, and the velocity of the water along the average interface normal. In this projected space, we find that the TSE is well-captured by a simple model of ballistic escape from a deep potential well, with no additional barrier to evaporation beyond the cohesive strength of the liquid. Equivalently, they are consistent with a near-unity probability for a water molecule impinging upon a liquid droplet to condense. These results agree with previous simulations and with some, but not all, recent experiments.

  18. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  19. FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS

    Office of Scientific and Technical Information (OSTI)

    give a higher lower limit value than the completely vaporized sample. Conversely, the heavy fractions or residue give a smaller lower limit value. For this reason, there is...

  20. A simple grand canonical approach to compute the vapor pressure of bulk and finite size systems

    SciTech Connect (OSTI)

    Factorovich, Matías H.; Scherlis, Damián A.

    2014-02-14

    In this article we introduce a simple grand canonical screening (GCS) approach to accurately compute vapor pressures from molecular dynamics or Monte Carlo simulations. This procedure entails a screening of chemical potentials using a conventional grand canonical scheme, and therefore it is straightforward to implement for any kind of interface. The scheme is validated against data obtained from Gibbs ensemble simulations for water and argon. Then, it is applied to obtain the vapor pressure of the coarse-grained mW water model, and it is shown that the computed value is in excellent accord with the one formally deduced using statistical thermodynamics arguments. Finally, this methodology is used to calculate the vapor pressure of a water nanodroplet of 94 molecules. Interestingly, the result is in perfect agreement with the one predicted by the Kelvin equation for a homogeneous droplet of that size.

  1. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, V.J.; Johnson, S.A.

    1999-08-03

    A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

  2. Low temperature ion source for calutrons

    DOE Patents [OSTI]

    Veach, Allen M. (Oak Ridge, TN); Bell, Jr., William A. (Oak Ridge, TN); Howell, Jr., George D. (Clinton, TN)

    1981-01-01

    A new ion source assembly for calutrons has been provided for the efficient separation of elements having high vapor pressures. The strategic location of cooling pads and improved insulation permits operation of the source at lower temperatures. A vapor valve constructed of graphite and located in a constantly increasing temperature gradient provides reliable control of the vapor flow from the charge bottle to the arc chamber. A pronounced saving in calutron operating time and equipment maintenance has been achieved with the use of the present ion source.

  3. Self-tuning method for monitoring the density of a gas vapor component using a tunable laser

    DOE Patents [OSTI]

    Hagans, Karla (Livermore, CA); Berzins, Leon (Livermore, CA); Galkowski, Joseph (Livermore, CA); Seng, Rita (Tracy, CA)

    1996-01-01

    The present invention relates to a vapor density monitor and laser atomic absorption spectroscopy method for highly accurate, continuous monitoring of vapor densities, composition, flow velocity, internal and kinetic temperatures and constituent distributions. The vapor density monitor employs a diode laser, preferably of an external cavity design. By using a diode laser, the vapor density monitor is significantly less expensive and more reliable than prior art vapor density monitoring devices. In addition, the compact size of diode lasers enables the vapor density monitor to be portable. According to the method of the present invention, the density of a component of a gas vapor is calculated by tuning the diode laser to a frequency at which the amount of light absorbed by the component is at a minimum or a maximum within about 50 MHz of that frequency. Laser light from the diode laser is then transmitted at the determined frequency across a predetermined pathlength of the gas vapor. By comparing the amount of light transmitted by the diode laser to the amount of light transmitted after the laser light passes through the gas vapor, the density of the component can be determined using Beer's law.

  4. Self-tuning method for monitoring the density of a gas vapor component using a tunable laser

    DOE Patents [OSTI]

    Hagans, K.; Berzins, L.; Galkowski, J.; Seng, R.

    1996-08-27

    The present invention relates to a vapor density monitor and laser atomic absorption spectroscopy method for highly accurate, continuous monitoring of vapor densities, composition, flow velocity, internal and kinetic temperatures and constituent distributions. The vapor density monitor employs a diode laser, preferably of an external cavity design. By using a diode laser, the vapor density monitor is significantly less expensive and more reliable than prior art vapor density monitoring devices. In addition, the compact size of diode lasers enables the vapor density monitor to be portable. According to the method of the present invention, the density of a component of a gas vapor is calculated by tuning the diode laser to a frequency at which the amount of light absorbed by the component is at a minimum or a maximum within about 50 MHz of that frequency. Laser light from the diode laser is then transmitted at the determined frequency across a predetermined pathlength of the gas vapor. By comparing the amount of light transmitted by the diode laser to the amount of light transmitted after the laser light passes through the gas vapor, the density of the component can be determined using Beer`s law. 6 figs.

  5. Features of temperature control of fuel element cladding for pressurized water nuclear reactor “WWER-1000” while simulating reactor accidents

    SciTech Connect (OSTI)

    Zaytsev, P. A.; Priymak, S. V.; Usachev, V. B.; Oleynikov, P. P.; Soldatkin, D. M. [Scientific Research Institute, Scientific Industrial Association LUCH, Podolsk (Russian Federation)] [Scientific Research Institute, Scientific Industrial Association LUCH, Podolsk (Russian Federation)

    2013-09-11

    During the experiments simulating NPR (nuclear power reactor) accidents with a coolant loss fuel elements behavior in a steam-hydrogen medium was studied at the temperature changed with the rate from 1 to 100K/s within the range of 300÷1500 °C. Indications of the thermocouples fixed on the cladding notably differ from real values of the cladding temperatures in the area of measuring junction due to thermal resistance influence of the transition zones “cladding-junction” and “junction-coolant”. The estimating method of a measurement error was considered which can provide adequate accounting of the influence factors. The method is based on thermal probing of a thermocouple by electric current flashing through thermoelements under the coolant presence or absence, a response time registration and processing, calculation of thermal inertia value for a thermocouple junction. A formula was derived for calculation of methodical error under stationary mode and within the stage of linear increase in temperature, which will determine the conditions for the cladding depressurization. Some variants of the formula application were considered, and the values of methodical errors were established which reached ?5% of maximum value by the final moment of the stage of linear increase in the temperature.

  6. Interfacial Water-Transport Effects in Proton-Exchange Membranes

    E-Print Network [OSTI]

    Kienitz, Brian

    2010-01-01

    1993, "The Contact Angle  between Water and the Surface of Desorption, and Transport of Water in  Polymer Electrolyte Vaporization?Exchange Model  for Water Sorption and Flux in 

  7. Directly correlated transmission electron microscopy and atom probe tomography of grain boundary oxidation in a Ni-Al binary alloy exposed to high-temperature water.

    SciTech Connect (OSTI)

    Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

    2013-10-30

    Intergranular oxidation of a Ni-4Al alloy exposed to hydrogenated, high-temperature water was characterized using directly correlated transmission electron microscopy and atom probe tomography. These combined analyses revealed that discrete, well-separated oxides (NiAl2O4) precipitated along grain boundaries in the metal. Aluminum was depleted from the grain boundary between oxides and also from one side of the boundary as a result of grain boundary migration. The discrete oxide morphology, disconnected from the continuous surface oxidation, suggests intergranular solid-state internal oxidation of Al. Keywords: oxidation; grain boundaries; nickel alloys; atom probe tomography; transmission electron microscopy (TEM)

  8. Influence of clouds and diffuse radiation on ecosystem-atmosphere CO 2 and CO 18 O exchanges

    E-Print Network [OSTI]

    2009-01-01

    the canopy temperature and vapor pressure, which depends onto the same canopy vapor pressure and isotopic composition).air temperature, pressure, water vapor content, wind speed,

  9. Reductive Dehalogenation of Trichloroethene Vapors in an

    E-Print Network [OSTI]

    to treat trichloroethene (TCE) from waste gases generated by soil vapor extraction or dual-phase extraction and groundwater include soil vapor extraction (SVE) in combination with air sparging and dual-phase extraction methods such as incineration, catalytic oxidation, and adsorption onto activated carbon are currently

  10. Quantitative organic vapor-particle sampler

    DOE Patents [OSTI]

    Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

    1998-01-01

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  11. Temperature Stratification in a Cryogenic Fuel Tank Matthew J. Daigle1

    E-Print Network [OSTI]

    Daigle, Matthew

    temperature stratification effects driven by natural convec- tion in a liquid hydrogen cryogenic fuel tank has-evaporation of the hydrogen, as well as flows of hydrogen liquid and vapor in the presence of pressurizing helium gas = acceleration due to gravity; m/s2 Hl(v) = height of liquid (vapor); m J = gas/vapor or liquid mass flow rate

  12. Moving zone Marangoni drying of wet objects using naturally evaporated solvent vapor

    DOE Patents [OSTI]

    Britten, Jerald A. (Oakley, CA)

    1997-01-01

    A surface tension gradient driven flow (a Marangoni flow) is used to remove the thin film of water remaining on the surface of an object following rinsing. The process passively introduces by natural evaporation and diffusion of minute amounts of alcohol (or other suitable material) vapor in the immediate vicinity of a continuously refreshed meniscus of deionized water or another aqueous-based, nonsurfactant rinsing agent. Used in conjunction with cleaning, developing or wet etching application, rinsing coupled with Marangoni drying provides a single-step process for 1) cleaning, developing or etching, 2) rinsing, and 3) drying objects such as flat substrates or coatings on flat substrates without necessarily using heat, forced air flow, contact wiping, centrifugation or large amounts of flammable solvents. This process is useful in one-step cleaning and drying of large flat optical substrates, one-step developing/rinsing and drying or etching/rinsing/drying of large flat patterned substrates and flat panel displays during lithographic processing, and room-temperature rinsing/drying of other large parts, sheets or continuous rolls of material.

  13. Helium adsorption in silica aerogel near the liquid-vapor critical point

    E-Print Network [OSTI]

    Tobias Herman; James Day; John Beamish

    2005-05-18

    We have investigated the adsorption and desorption of helium near its liquid-vapor critical point in silica aerogels with porosities between 95% and 98%. We used a capacitive measurement technique which allowed us to probe the helium density inside the aerogel directly, even though the samples were surrounded by bulk helium. The aerogel's very low thermal conductivity resulted in long equilibration times so we monitored the pressure and the helium density, both inside the aerogel and in the surrounding bulk, and waited at each point until all had stabilized. Our measurements were made at temperatures far from the critical point, where a well defined liquid-vapor interface exists, and at temperatures up to the bulk critical point. Hysteresis between adsorption and desorption isotherms persisted to temperatures close to the liquid-vapor critical point and there was no sign of an equilibrium liquid-vapor transition once the hysteresis disappeared. Many features of our isotherms can be described in terms of capillary condensation, although this picture becomes less applicable as the liquid-vapor critical point is approached and it is unclear how it can be applied to aerogels, whose tenuous structure includes a wide range of length scales.

  14. Effect of hydrothermal condition on the formation of multi-component oxides of Ni-based metallic glass under high temperature water near the critical point

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, J. S.; Kim, S. Y.; Kim, D. H.; Ott, R. T.; Kim, H. G.; Lee, M. H.

    2015-07-01

    The specific feature of multi-component oxides synthesized by hydrothermal process under high temperature (633 K) and highly pressurized water (18.9 MPa) near critical point. Effects of hydrothermal processing duration times 24 hours and 72 hours, respectively, on the oxide formation of the Ni59Zr20Ti16Si2Sn3 metallic glass synthesized by powder metallurgy process were characterized by X-ray diffractometer, differential scanning calorimeter along with the particle size, morphology and crystalline phase of the oxides. The crystallization of the needle-shape NiTiO3, ZrTiO4 and ZrSnO4 ternary oxide phases observed on the surface of metallic glass at below glass transition temperature and the morphology of oxide phasesmore »changed to plate-shape around 2 ?m in diameter by the increase processing time. This hydrothermal processing in subcritical water provides accelerated dense metal oxide crystals due to the reaction medium being at higher pressure than conventional oxidation processing.« less

  15. Alteration of rhyolite in CO{sub 2} charged water at 200 and 350{degree}C: The unreactivity of CO{sub 2} at higher temperature

    SciTech Connect (OSTI)

    Bischoff, J.L.; Rosenbauer, R.J. [Geological Survey, Menlo Park, CA (United States)] [Geological Survey, Menlo Park, CA (United States)

    1996-10-01

    Geochemical and hydrologic modeling indicates that geothermal waters in the T > 270{degrees}C reservoirs beneath Yellowstone National Park have HCO{sub 3} {much_lt} Cl and contrast with waters in reservoirs at lower temperatures which attain HCO{sub 3} about equal to Cl. Experiments reacting rhyolite with 0.5 molal solutions of CO{sub 2} at 200{degrees} and 350{degrees}C were carried out to test the hypothesis of Fournier to explain the chemistry of these springs: that CO{sub 2} is relatively unreactive with volcanic rocks at temperatures >270{degrees}C. The experimental results strongly support this hypothesis. Extent of alteration is twenty-seven times greater at 200{degrees}C than at 350{degrees}C. The dominant process in the experiments appears to be the alteration of the albitic component of the rhyolite by dissolved CO{sub 2} to form a kaolinite-like alteration product plus quartz: 2NaAlSi{sub 3}O{sub 8} + 2CO{sub 2} + 3H{sub 2}O = 2Na{sup +} + 2HCO{sub 3}{sup -} + Al{sub 2}Si{sub 2}O{sub 5}(OH){sub 4} + 4SiO{sub 2}. CO{sub 2} reacts with water to form H{sub 2}CO{sub 3} which dissociates to H{sup +} and HCO{sub 3}{sup -}, more so at lower temperatures. Kinetic and thermodynamic considerations suggest that the reactivity of H{sub 2}CO{sub 3} with wallrocks is at its maximum between 150{degrees} and 200{degrees}C, consuming most of the H{sup +} and liberating equivalent amounts of cations and bicarbonate. Wallrocks in higher temperature reservoirs are relatively unreactive to dissolved CO{sub 2} which is eventually lost from the system by boiling. These observations also offer a possible explanation for the change in chemical sediments from chloride-dominated to bicarbonate-dominated salts found in the stratigraphic section at Searles Lake, California, the terminus of the Owens River which derives its dissolved load from hot springs of the Long Valley caldera. 21 refs., 5 figs., 2 tabs.

  16. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    2008-01-15

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  17. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  18. After More Than 20 Years Operating, Hanford's Soil Vapor Extraction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    After More Than 20 Years Operating, Hanford's Soil Vapor Extraction Project Nears Completion After More Than 20 Years Operating, Hanford's Soil Vapor Extraction Project Nears...

  19. VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND...

    Office of Scientific and Technical Information (OSTI)

    VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS Citation Details In-Document Search Title: VAPOR PRESSURES OF THE...

  20. The role of polymer formation during vapor phase lubrication...

    Office of Scientific and Technical Information (OSTI)

    The role of polymer formation during vapor phase lubrication of silicon. Citation Details In-Document Search Title: The role of polymer formation during vapor phase lubrication of...

  1. Vapor-deposited porous films for energy conversion

    DOE Patents [OSTI]

    Jankowski, Alan F.; Hayes, Jeffrey P.; Morse, Jeffrey D.

    2005-07-05

    Metallic films are grown with a "spongelike" morphology in the as-deposited condition using planar magnetron sputtering. The morphology of the deposit is characterized by metallic continuity in three dimensions with continuous and open porosity on the submicron scale. The stabilization of the spongelike morphology is found over a limited range of the sputter deposition parameters, that is, of working gas pressure and substrate temperature. This spongelike morphology is an extension of the features as generally represented in the classic zone models of growth for physical vapor deposits. Nickel coatings were deposited with working gas pressures up 4 Pa and for substrate temperatures up to 1000 K. The morphology of the deposits is examined in plan and in cross section views with scanning electron microscopy (SEM). The parametric range of gas pressure and substrate temperature (relative to absolute melt point) under which the spongelike metal deposits are produced appear universal for other metals including gold, silver, and aluminum.

  2. GPS precipitable water measurements used in the analysis of California and Nevada climate

    E-Print Network [OSTI]

    Means, James Douglas

    2011-01-01

    Remote-Sensing Of Atmospheric Water-Vapor Using The GlobalWet Delays Onto Precipitable Water, Journal of AppliedRivers, Floods and the Water Resources of California, Water,

  3. Dosimeter for monitoring vapors and aerosols of organic compounds

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1987-07-14

    A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique. 7 figs.

  4. Unusual thermopower of inhomogeneous graphene grown by chemical vapor deposition

    SciTech Connect (OSTI)

    Nam, Youngwoo, E-mail: youngwoo.nam@chalmers.se [Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of); Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Sun, Jie; Lindvall, Niclas; Yurgens, August [Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Jae Yang, Seung; Rae Park, Chong [Department of Materials Science and Engineering, Seoul National University, Seoul 151-747 (Korea, Republic of); Woo Park, Yung [Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of)

    2014-01-13

    We report on thermopower (TEP) and resistance measurements of inhomogeneous graphene grown by chemical vapor deposition (CVD). Unlike the conventional resistance of pristine graphene, the gate-dependent TEP shows a large electron-hole asymmetry. This can be accounted for by inhomogeneity of the CVD-graphene where individual graphene regions contribute with different TEPs. At the high magnetic field and low temperature, the TEP has large fluctuations near the Dirac point associated with the disorder in the CVD-graphene. TEP measurements reveal additional characteristics of CVD-graphene, which are difficult to obtain from the measurement of resistance alone.

  5. Dosimeter for monitoring vapors and aerosols of organic compounds

    DOE Patents [OSTI]

    Vo-Dinh, Tuan (625 Gulfwood Rd., Knoxville, TN 37923)

    1987-01-01

    A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique.

  6. Specific Mass Estimates for A Vapor Core Reactor With MHD

    SciTech Connect (OSTI)

    Knight, Travis; Smith, Blair; Anghaie, Samim [Innovative Nuclear Space Power and Propulsion Institute (INSPI), PO Box 116502, University of Florida, Gainesville, FL 32611-6502 (United States)

    2002-07-01

    This study investigated the development of a system concept for space power generation and nuclear electric propulsion based on a vapor core reactor (VCR) with magnetohydrodynamic (MHD) power conversion system, coupled to a magnetoplasma-dynamic (MPD) thruster. The VCR is a liquid-vapor core reactor concept operating with metallic uranium or uranium tetrafluoride (UF{sub 4}) vapor as the fissioning fuel and alkali metals or their fluorides as working fluid in a closed Rankine cycle with MHD energy conversion. Gaseous and liquid-vapor core reactors can potentially provide the highest reactor and cycle temperature among all existing or proposed fission reactor designs. This unique feature makes this reactor concept a very natural and attractive candidate for very high power (10 to 1000 MWe) and low specific mass (0.4 to 5 kg/kWe) nuclear electric propulsion (NEP) applications since the MHD output could be coupled with minimal power conditioning to MPD thrusters or other types of thruster for producing thrust at very high specific impulse (I{sub sp} 1500 to 10,000 s). The exceptional specific mass performance of an optimized VCRMHD- NEP system could lead to a dramatic reduction in the cost and duration of manned or robotic interplanetary as well as interstellar missions. The VCR-MHD-NEP system could enable very efficient Mars cargo transfers or short (<8 month) Mars round trips with less initial mass in low Earth orbit (IMLEO). The system could also enable highly efficient lunar cargo transfer and rapid missions to other destinations throughout the solar system. (authors)

  7. Applications of Mechanical Vapor Recompression to Evaporation and Crystallization 

    E-Print Network [OSTI]

    Outland, J. S.

    1995-01-01

    is accomplished using centrifugal, axial-flow, or positive displacement compressors and these compressors can be powered by electricity, steam turbine or a gas turbine. The use of an MVR Evapo rator/Crystallizer provides a comparatively low cost means... Process Equipment Harvey,IL Here it can be seen that the economy or the pounds of water evaporated per pound of heating element is slightly less than 1.0. The vapors leaving the evapo rator flow to a condenser when their latent heat is absorbed...

  8. Atomic vapor laser isotope separation using resonance ionization

    SciTech Connect (OSTI)

    Comaskey, B.; Crane, J.; Erbert, G.; Haynam, C.; Johnson, M.; Morris, J.; Paisner, J.; Solarz, R.; Worden, E.

    1986-09-01

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power-reactor fuel has been under development for over 10 years. In June 1985, the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for enriched uranium. Resonance photoionization is the heart of the AVLIS process. We discuss those fundamental atomic parameters that are necessary for describing isotope-selective resonant multistep photoionization along with the measurement techniques that we use. We illustrate the methodology adopted with examples of other elements that are under study in our program.

  9. M . B a h r a m i ENSC 388 Experiment 2: Vapor Compression Refrigeration Cycle ENSC 388: Engineering Thermodynamics and Heat Transfer

    E-Print Network [OSTI]

    Bahrami, Majid

    , Evaporator 5 Expansion Valve 16 Power meter, Compressor 6 Hand Valve 17 Switchable Temperature Display 7 ON1 M . B a h r a m i ENSC 388 Experiment 2: Vapor Compression Refrigeration Cycle ENSC 388: Engineering Thermodynamics and Heat Transfer Experiment 2: Vapor Compression Refrigeration Cycle Objective

  10. The influence of substrate polarity on the structural quality of InN layers grown by high-pressure chemical vapor deposition

    E-Print Network [OSTI]

    Dietz, Nikolaus

    the growth temperatures to below 650 °C for low-pressure metal organic chemical vapor depo- sition MOCVDThe influence of substrate polarity on the structural quality of InN layers grown by high-pressure chemical vapor deposition N. Dietz,1,a M. Alevli,1 R. Atalay,1 G. Durkaya,1 R. Collazo,2 J. Tweedie,2 S

  11. Method and apparatus for enhanced heat recovery from steam generators and water heaters

    DOE Patents [OSTI]

    Knight, Richard A.; Rabovitser, Iosif K.; Wang, Dexin

    2006-06-27

    A heating system having a steam generator or water heater, at least one economizer, at least one condenser and at least one oxidant heater arranged in a manner so as to reduce the temperature and humidity of the exhaust gas (flue gas) stream and recover a major portion of the associated sensible and latent heat. The recovered heat is returned to the steam generator or water heater so as to increase the quantity of steam generated or water heated per quantity of fuel consumed. In addition, a portion of the water vapor produced by combustion of fuel is reclaimed for use as feed water, thereby reducing the make-up water requirement for the system.

  12. Recovering hydrocarbons from hydrocarbon-containing vapors

    DOE Patents [OSTI]

    Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

    1980-09-30

    Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

  13. Experimental investigations at high temperatures and pressures on melting and mineral solubility in systems of feldspars with water, with special reference to the origin of granite

    E-Print Network [OSTI]

    Makhluf, Adam Rafiq

    2015-01-01

    mixing properties of albite-water melts. Transactions of themelting and activities of water at high pressures. Americanfor determining the solubility of water in silicate melts.

  14. VAPOR COMPRESSION HEAT PUMP SYSTEM FIELD TESTS AT THE TECH COMPLEX

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    323 CHAPTER 17 VAPOR COMPRESSION HEAT PUMP SYSTEM FIELD TESTS AT THE TECH COMPLEX \\B E Van D for several novel and conventional heat pump systems for space conditioning and water heating. Systems tested include the Annual Cycle Energy System (ACES), solar assisted heat pumps (SAHP) both parallel and series

  15. Modeling of LNG Pool Spreading and Vaporization 

    E-Print Network [OSTI]

    Basha, Omar 1988-

    2012-11-20

    In this work, a source term model for estimating the rate of spreading and vaporization of LNG on land and sea is introduced. The model takes into account the composition changes of the boiling mixture, the varying thermodynamic properties due...

  16. An advanced vapor-compression desalination system 

    E-Print Network [OSTI]

    Lara Ruiz, Jorge Horacio Juan

    2006-04-12

    Currently, the two dominant desalination methods are reverse osmosis (RO) and multi-stage flash (MSF). RO requires large capital investment and maintenance, whereas MSF is too energy intensive. An innovative vapor-compression desalination system...

  17. Vapor Retarder Classification - Building America Top Innovation...

    Broader source: Energy.gov (indexed) [DOE]

    vapor retarder classification. Air-tight and well-insulated homes have little or no tolerance for drying if they get wet; moisture control is critical. This Top Innovation profile...

  18. Chemical vapor deposition of functionalized isobenzofuran polymers

    E-Print Network [OSTI]

    Olsson, Ylva Kristina

    2007-01-01

    This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

  19. Modeled Interactive Effects of Precipitation, temperature, and [CO2] on Ecosystem Carbon and Water Dynamics in Different Climatic Zones

    SciTech Connect (OSTI)

    Luo, Yiqi [University of Oklahoma; Gerten, Dieter [Potsdam Institute for Climate Impact Research, Potsdam, Germany; Le Maire, Guerric [Laboratoire des Sciences du Climat et de l'Environement, France; Parton, William [University of Colorado, Fort Collins; Weng, Ensheng [University of Oklahoma, Norman; Zhou, Xuhuui [University of Oklahoma; Keough, Cindy [University of Colorado, Fort Collins; Beier, Claus [Riso National Laboratory, Roskilde, Denmark; Ciais, Philippe [Laboratoire des Sciences du Climat et de l'Environement, France; Cramer, Wolfgang [Potsdam Institute for Climate Impact Research, Potsdam, Germany; Dukes, Jeff [University of Massachusetts, Boston; Emmett, Bridget [Centre for Ecology and Hydrology, Bangor, Gwynedd, United Kingdom; Hanson, Paul J [ORNL; Knapp, Alan [Colorado State University, Fort Collins; Linder, Sune [Swedish University of Agricultural Sciences, Upsalla, Sweden; Nepstad, Daniel [Woods Hole Oceanographic Institution (WHOI), Woods Hole, MA; Rustad, Lindsey [USDA Forest Service

    2008-01-01

    Interactive effects of multiple global change factors on ecosystem processes are complex. It is relatively expensive to explore those interactions in manipulative experiments. We conducted a modeling analysis to identify potentially important interactions and to stimulate hypothesis formulation for experimental research. Four models were used to quantify interactive effects of climate warming (T), altered precipitation amounts [doubled (DP) and halved (HP)] and seasonality (SP, moving precipitation in July and August to January and February to create summer drought), and elevated [CO2] (C) on net primary production (NPP), heterotrophic respiration (Rh), net ecosystem production (NEP), transpiration, and runoff.We examined those responses in seven ecosystems, including forests, grasslands, and heathlands in different climate zones. The modeling analysis showed that none of the threeway interactions among T, C, and altered precipitation was substantial for either carbon or water processes, nor consistent among the seven ecosystems. However, two-way interactive effects on NPP, Rh, and NEP were generally positive (i.e. amplification of one factor s effect by the other factor) between T and C or between T and DP. A negative interaction (i.e. depression of one factor s effect by the other factor) occurred for simulated NPP between T and HP. The interactive effects on runoff were positive between T and HP. Four pairs of two-way interactive effects on plant transpiration were positive and two pairs negative. In addition, wet sites generally had smaller relative changes in NPP, Rh, runoff, and transpiration but larger absolute changes in NEP than dry sites in response to the treatments. The modeling results suggest new hypotheses to be tested in multifactor global change experiments. Likewise, more experimental evidence is needed for the further improvement of ecosystem models in order to adequately simulate complex interactive processes.

  20. Growth Kinetics of the Homogeneously Nucleated Water Droplets: Simulation Results

    E-Print Network [OSTI]

    Mokshin, Anatolii V; 10.1088/1742-6596/394/1/012023

    2012-01-01

    The growth of homogeneously nucleated droplets in water vapor at the fixed temperatures T=273, 283, 293, 303, 313, 323, 333, 343, 353, 363 and 373 K (the pressure $p=1$ atm.) is investigated on the basis of the coarse-grained molecular dynamics simulation data with the mW-model. The treatment of simulation results is performed by means of the statistical method within the mean-first-passage-time approach, where the reaction coordinate is associated with the largest droplet size. It is found that the water droplet growth is characterized by the next features: (i) the rescaled growth law is unified at all the considered temperatures and (ii) the droplet growth evolves with acceleration and follows the power law.

  1. Deposition of silicon carbide films using a high vacuum metalorganic chemical vapor deposition method with a single source precursor

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    , high temperature, and high radiation environments. Conventional silicon carbide chemical vapor deposition CVD processes generally utilized multiple precursors such as silane and hydrocarbons, and required temperature alternatives to the conventional SiC CVD methods must be considered. To do this, a relatively

  2. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Tracy, C. Edwin (Golden, CO); King, David E. (Lakewood, CO); Stanley, James T. (Beaverton, OR)

    1994-01-01

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp.sup.3 -bonded diamond-type carbon films, comprising: a) providing a volatile hydrocarbon gas/H.sub.2 reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and b) directing a concentrated solar flux of from about 40 to about 60 watts/cm.sup.2 through said reactant mixture to produce substrate temperatures of about 750.degree. C. to about 950.degree. C. to activate deposition of the film on said substrate.

  3. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J.R.; Tracy, C.E.; King, D.E.; Stanley, J.T.

    1994-09-13

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp[sup 3]-bonded diamond-type carbon films, comprises: (a) providing a volatile hydrocarbon gas/H[sub 2] reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and (b) directing a concentrated solar flux of from about 40 to about 60 watts/cm[sup 2] through said reactant mixture to produce substrate temperatures of about 750 C to about 950 C to activate deposition of the film on said substrate. 11 figs.

  4. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-04-29

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  5. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-12-30

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100 C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  6. Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons

    E-Print Network [OSTI]

    Chickos, James S.

    of a thermochemical cycle, and agreement is within the combined experimental uncertainties. Vapor pressures pressures. Vaporization enthalpies of crystalline materials are also quite useful. Combined with fusion combined with fusion enthalpies have been used to provide independent confirmation of the magnitude

  7. Infrared study on room-temperature atomic layer deposition of HfO{sub 2} using tetrakis(ethylmethylamino)hafnium and remote plasma-excited oxidizing agents

    SciTech Connect (OSTI)

    Kanomata, Kensaku [Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510, Japan and Japan Society for the Promotion of Science, 5-3-1 Kojimachi, Chiyoda-ku, Tokyo 102-0083 (Japan); Ohba, Hisashi; Pungboon Pansila, P.; Ahmmad, Bashir; Kubota, Shigeru; Hirahara, Kazuhiro; Hirose, Fumihiko, E-mail: fhirose@yz.yamagata-u.ac.jp [Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510 (Japan)

    2015-01-01

    Room-temperature atomic layer deposition (ALD) of HfO{sub 2} was examined using tetrakis (ethylmethylamino)hafnium (TEMAH) and remote plasma-excited water and oxygen. A growth rate of 0.26?nm/cycle at room temperature was achieved, and the TEMAH adsorption and its oxidization on HfO{sub 2} were investigated by multiple internal reflection infrared absorption spectroscopy. It was observed that saturated adsorption of TEMAH occurs at exposures of ?1?×?10{sup 5}?L (1 L?=?1?×?10{sup ?6} Torr s) at room temperature, and the use of remote plasma-excited water and oxygen vapor is effective in oxidizing the TEMAH molecules on the HfO{sub 2} surface, to produce OH sites. The infrared study suggested that Hf–OH plays a role as an adsorption site for TEMAH. The reaction mechanism of room temperature HfO{sub 2} ALD is discussed in this paper.

  8. Using laser absorption spectroscopy to monitor composition and physical properties of metal vapors

    SciTech Connect (OSTI)

    Berzins, L.V.

    1993-09-03

    The Atomic Vapor Laser Isotope Separation (AVLIS) program has been using laser absorption spectroscopy to monitor vapor densities for over 15 years. Laser absorption spectroscopy has proven itself to be an accurate and reliable method to monitor both density and composition. During this time the diagnostic has moved from a research tool toward a robust component of a process control system. The hardware used for this diagnostic is discussed elsewhere at this symposium. This paper describes how the laser absorption spectroscopy diagnostic is used as a component of a process control system as well as supplying detailed measurements on vapor densities, composition, flow velocity, internal and kinetic temperatures, and constituent distributions. Examples will be drawn from the uranium AVLIS program. In addition potential applications such as composition control in the production of metal matrix composites or aircraft alloys will be discussed.

  9. Preconcentrator with high volume chiller for high vapor pressure particle detection

    DOE Patents [OSTI]

    Linker, Kevin L

    2013-10-22

    Apparatus and method for collecting particles of both high and low vapor pressure target materials entrained in a large volume sample gas stream. Large volume active cooling provides a cold air supply which is mixed with the sample gas stream to reduce the vapor pressure of the particles. In embodiments, a chiller cools air from ambient conditions to 0-15.degree. C. with the volumetric flow rate of the cold air supply being at least equal to the volumetric flow rate of the sample gas stream. In further embodiments an adsorption media is heated in at least two stages, a first of which is below a threshold temperature at which decomposition products of the high vapor pressure particle are generated.

  10. Modeling Water Management in Polymer-Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, Adam; Department of Chemical Engineering, University of California, Berkeley

    2008-01-01

    of predicted water contents and water management in ani.e . , temperature and water content), and thus many modelsfor the water uptake and water content using macroscopic

  11. Retrofit device to improve vapor compression cooling system performance by dynamic blower speed modulation

    DOE Patents [OSTI]

    Roth, Robert Paul; Hahn, David C.; Scaringe, Robert P.

    2015-12-08

    A device and method are provided to improve performance of a vapor compression system using a retrofittable control board to start up the vapor compression system with the evaporator blower initially set to a high speed. A baseline evaporator operating temperature with the evaporator blower operating at the high speed is recorded, and then the device detects if a predetermined acceptable change in evaporator temperature has occurred. The evaporator blower speed is reduced from the initially set high speed as long as there is only a negligible change in the measured evaporator temperature and therefore a negligible difference in the compressor's power consumption so as to obtain a net increase in the Coefficient of Performance.

  12. Hypothetical Thermodynamic Properties: Vapor Pressures and Vaporization Enthalpies of the Even n-Alkanes from C40 to C76 at T ) 298.15 K by

    E-Print Network [OSTI]

    Chickos, James S.

    Hypothetical Thermodynamic Properties: Vapor Pressures and Vaporization Enthalpies of the Even n in combination with earlier work to evaluate the vaporization enthalpies and vapor pressures of these n-alkanes from T ) (298.15 to 540) K. The vapor pressure and vaporization enthalpy results obtained are compared

  13. Vapor Pressures and Vaporization Enthalpies of the n-Alkanes from C31 to C38 at T ) 298.15 K by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    Vapor Pressures and Vaporization Enthalpies of the n-Alkanes from C31 to C38 at T ) 298.15 K with other literature values to evaluate the vaporization enthalpies and vapor pressures of these n-alkanes from T ) 298.15 to 575 K. The vapor pressure and vaporization enthalpy results obtained are compared

  14. EXAMINING THE SPECTROSCOPY OF WATER VAPOR IN THE ATMOSPHERE

    E-Print Network [OSTI]

    Petta, Jason

    Used to prove stable flow in C.O. Data Comparison and Analysis Linear Fit Within 3% error #12 and Analysis Plot VCSEL M.R. against Standard Calibrate According to Linear Fit Use Beers Law³ and Ideal Gas Designing Components for the Circuit Insert into steel, airtight container Record Spectra Data Comparison

  15. A Satellite Survey Cloud Cover and Water Vapor

    E-Print Network [OSTI]

    the trade wind inversion. Light pollution from Tocopilla, likely to increase in the years to come, also

  16. Desalination of water by vapor transport through hydrophobic nanopores

    E-Print Network [OSTI]

    Lee, Jongho, Ph. D. Massachusetts Institute of Technology

    2014-01-01

    Although Reverse osmosis (RO) is the state-of-the-art desalination technology, it still suffers from persistent drawbacks including low permeate flux, low selectivity for non-ionic species, and lack of resistance to chlorine. ...

  17. ARM - Field Campaign - Arctic Winter Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See22, 2012IIIAtlantic (ACE-ENA)StudygovCampaignsArctic

  18. ARM - Field Campaign - Single Frequency GPS Water Vapor Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design togovCampaignsMASRAD:govCampaignsReplicator SondegovCampaignsSingle Frequency

  19. Overview of the ARM/FIRE Water Vapor Experiment (AFWEX)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access toOctoberConsumption (MillionOther airborneandOverview of the

  20. Irrigation in California's Central Valley strengthens the southwestern U.S. water cycle

    E-Print Network [OSTI]

    Lo, Min-Hui; Famiglietti, James S

    2013-01-01

    on local surface energy and water budget parti- tioning [water vapor in the lower troposphere results in positive atmospheric moist static energy (water is applied, ET can increase sub- stantially as the land surface transitions to an energy-

  1. Method and Apparatus for Concentrating Vapors for Analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2008-10-07

    An apparatus and method are disclosed for pre-concentrating gaseous vapors for analysis. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable. Vapors sorbed and concentrated within the bed of the apparatus can be thermally desorbed achieving at least partial separation of vapor mixtures. The apparatus is suitable, e.g., for preconcentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than for direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications.

  2. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2006-07-26

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  3. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2007-10-23

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  4. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, T.

    1988-03-15

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

  5. Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems

    E-Print Network [OSTI]

    Ho, Tony

    2012-01-01

    pressure and entropy, pressure and vapor quality, andfluid at the high pressure vapor turbine exit. In the nexthigh pressure and low pressure vapor turbines. The increase

  6. THE KINETICS OF LASER PULSE VAPORIZATION OF URANIUM DIOXIDE BY MASS SPECTROMETRY

    E-Print Network [OSTI]

    Tsai, Chuen-horng

    2012-01-01

    resulting low vapor pressure and low heat of vaporizationresulting low vapor pressure and low heat of vaporizationyields the partial vapor pressure and the composition in the

  7. Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLANIs gravity aOverviewISM IntegratedIntegratingIntegration

  8. Electrical conductivity measurements of aqueous boric acid at 25--350{degree}C at saturation vapor pressure. Final report

    SciTech Connect (OSTI)

    Ho, P.C.; Palmer, D.A.

    1995-09-01

    Electrical conductance measurements of aqueous boric acid solutions (15-110 g/kg-H{sub 2}O {equivalent_to} 0.251--1.815 mol/kg-H{sub 2}O) were measured over the temperature range 25 to 75 C at saturation vapor pressures in glass cells with parallel platinum electrodes. Sixteen series of measurements were made involving three samples of boric acid from different sources. Conductance measurements were also made at 15.5 and 30.5 g/kg-H{sub 2}O over the temperature range 100 to 350 C at 50 C intervals with a metallic cell fitted with concentric platinum electrodes. The specific conductances of H{sub 3}BO{sub 3} (aq)were calculated after correction for the conductance of the solvent (water) and are tabulated in this report. At the specific conditions requested in the project description, namely a concentration of 110 g/kg-H{sub 2}O and 65 C, the specific conductance of boric acid is 293.2 {+-} 1.8 microSiemens/cm based on duplicate measurements of four independent solutions. The results from these tests will be utilized by the Tokamak Physics Experimental Project (TPX).

  9. Advancing Explosives Detection Capabilities: Vapor Detection

    SciTech Connect (OSTI)

    Atkinson, David

    2012-10-15

    A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

  10. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  11. Advancing Explosives Detection Capabilities: Vapor Detection

    ScienceCinema (OSTI)

    Atkinson, David

    2014-07-24

    A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

  12. Vapor intrusion modeling : limitations, improvements, and value of information analyses

    E-Print Network [OSTI]

    Friscia, Jessica M. (Jessica Marie)

    2014-01-01

    Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

  13. Type B Accident Investigation of the Acid Vapor Inhalation on...

    Energy Savers [EERE]

    of the Acid Vapor Inhalation on June 7, 2005, in TA-48, Building RC-1 Room 402 at the Los Alamos National Laboratory Type B Accident Investigation of the Acid Vapor Inhalation on...

  14. Moisture Durability of Vapor Permeable Insulating Sheathing (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-10-01

    In this project, Building America team Building Science Corporation researched some of the ramifications of using exterior, vapor permeable insulation on retrofit walls with vapor permeable cavity insulation. Retrofit strategies are a key factor in reducing exterior building stock consumption.

  15. MULTIPLY STRIPPED ION GENERATION IN THE METAL VAPOR VACUUM ARC

    E-Print Network [OSTI]

    Brown, I.G.

    2010-01-01

    the metal vapor vacuum arc plasma discharge. A new kind offrom a metal vapor vacuum arc plasma has been used to obtaindrives the vacuum arc plasma is created. The fundamental

  16. A Multiscale Simulator for Low Pressure Chemical Vapor Deposition

    E-Print Network [OSTI]

    A Multiscale Simulator for Low Pressure Chemical Vapor Deposition Matthias K. Gobbert Institute-6206 ABSTRACT An integrated simulator for chemical vapor deposition is introduced. In addition to a reactor

  17. OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL

    E-Print Network [OSTI]

    Stanford University

    OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL RESERVOIRS CONSIDERING ADSORPTION governing the behavior of vapor- dominated geothermal reservoirs. These mechanisms affect both was to determine the most effective injection strategy once these two effects are considered. Geothermal reservoir

  18. Water uptake, ionic conductivity and swelling properties of anion-exchange membrane

    SciTech Connect (OSTI)

    Duan, QJ; Ge, SH; Wang, CY

    2013-12-01

    Water uptake, ionic conductivity and dimensional change of the anion-exchange membrane made by Tokuyama Corporation (A201 membrane) are investigated at different temperatures and water activities. Specifically, the amount of water taken up by membranes exposed to water vapor and membranes soaked in liquid water is determined. The water uptake of the A201 membrane increases with water content as well as temperature. In addition, water sorption data shows Schroeder's paradox for the AEMs investigated. The swelling properties of the A201 membrane exhibit improved dimensional stability compared with Nafion membrane. Water sorption of the A201 membrane occurs with a substantial negative excess volume of mixing. The threshold value of hydrophilic fraction in the A201 membrane for ionic conductivity is around 0.34, above which, the conductivity begins to rise quickly. This indicates that a change in the connectivity of the hydrophilic domains occurs when hydrophilic fraction approaches 0.34. (C) 2013 Elsevier B.V. All rights reserved.

  19. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, E.P. Jr.

    1999-01-12

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed there between. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock. 2 figs.

  20. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, Jr., Edward P. (Idaho Falls, ID)

    1999-01-01

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

  1. Vapor-like liquid coexistence densities affect the extension of the critical point's influence zone

    E-Print Network [OSTI]

    Jose Luis Rivera; Homero Nicanor-Guzman; Roberto Guerra-Gonzalez

    2015-04-16

    The critical point affects the coexistence behavior of the vapor-liquid equilibrium densities. The length of the critical influence zone is under debate because for some properties, like shear viscosity, the extension is only a few degrees, while for others, such as the density order parameter, the critical influence zone range covers up to hundreds of degrees below the critical temperature. Here we show that for a simple molecular potential of ethane, the critical influence zone covers a wide zone of tens of degrees (below the critical temperature) down to a transition temperature, at which the apparent critical influence zone vanishes and the transition temperature can be predicted through a pressure analysis of the coexisting bulk liquid phase. The liquid phases within the apparent critical influence zone show low densities, making them behave internally like their corresponding vapor phases. Therefore, the experimentally observed wide extension of the critical influence zone is due to a vapor-like effect due to low bulk liquid phase densities.

  2. Temperature System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S. CoalMexicoConference Tight Oil1 Soil Water and Temperature

  3. Moisture Durability with Vapor-Permeable Insulating Sheathing

    SciTech Connect (OSTI)

    Lepage, R.; Lstiburek, J.

    2013-09-01

    Exterior sheathing insulation is an effective strategy in increasing the overall R-value of wall assemblies; other benefits include decreasing the effects of thermal bridging and increasing the moisture durability of the built assembly. Vapor-permeable exterior insulation, such as mineral board or expanded polystyrene foam, are one such product that may be used to achieve these benefits. However, uncertainty exists on the effects of inward driven moisture and the interaction of increased sheathing temperatures on the moisture durability of the edifice. To address these concerns, Building Science Corporation (BSC) conducted a series of hygrothermal models for cities representing a range of different climate zones. This report describes the research project, key research questions, and the procedures utilized to analyse the problems.

  4. Heat Recovery in Distillation by Mechanical Vapor Recompression 

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    1986-01-01

    IN DISTILLATION BY MECHANICAL VAPOR RECOMPRESSION Frederick E. Becker and Alexandra I. Zakak Tecogen, Inc., A Subsidiary of Thermo Electron Corporation Waltham, Massachusetts ABSTRACT A significant reduction in distillation tower energy requirements can..., and then recompressing the low-pressure bottom vapors and injecting them directly into the column bottom. The choice of either scheme is a function of the physical properties of the vapors; i.e., the specific volume of the top or bottom vapors may dictate the most...

  5. Uranium accountancy in Atomic Vapor Laser Isotope Separation

    SciTech Connect (OSTI)

    Carver, R.D.

    1986-01-01

    The AVLIS program pioneers the large scale industrial application of lasers to produce low cost enriched uranium fuel for light water reactors. In the process developed at Lawrence Livermore National Laboratory, normal uranium is vaporized by an electron beam, and a precisely tuned laser beam selectively photo-ionizes the uranium-235 isotopes. These ions are moved in an electromagnetic field to be condensed on the product collector. All other uranium isotopes remain uncharged and pass through the collector section to condense as tails. Tracking the three types of uranium through the process presents special problems in accountancy. After demonstration runs, the uranium on the collector was analyzed for isotopic content by Battelle Pacific Northwest Laboratory. Their results were checked at LLNL by analysis of parallel samples. The differences in isotopic composition as reported by the two laboratories were not significant.

  6. MODELLING AND SIMULATION OF LIQUID-VAPOR PHASE TRANSITION

    E-Print Network [OSTI]

    Faccanoni, Gloria

    . (,) P pressure law. G. Faccanoni DNS OF LIQUIDE-VAPOR PHASE TRANSITION 6 / 23 #12;Model Numerical Method. (,) P pressure law. G. Faccanoni DNS OF LIQUIDE-VAPOR PHASE TRANSITION 6 / 23 #12;Model Numerical Method Vapor = 0 x = 0 = 1Fictive fluid 0 pressure law

  7. Modeling engine oil vaporization and transport of the oil vapor in the piston ring pack on internal combustion engines

    E-Print Network [OSTI]

    Cho, Yeunwoo, 1973-

    2004-01-01

    A model was developed to study engine oil vaporization and oil vapor transport in the piston ring pack of internal combustion engines. With the assumption that the multi-grade oil can be modeled as a compound of several ...

  8. Study of the effects of noisy data on the determination of the enthalpy of vaporization from a vapor pressure equation 

    E-Print Network [OSTI]

    Casserly, Thomas Bryan

    2013-02-22

    Chemical engineers use software tools everyday to aid them in solving complex problems. Software packages simulate virtually every aspect of a chemical process, including the use of source vapor pressure data to fit empirical constants of a vapor...

  9. THE KINETICS OF LASER PULSE VAPORIZATION OF URANIUM DIOXIDE BY MASS SPECTROMETRY

    E-Print Network [OSTI]

    Tsai, C-h.

    2010-01-01

    The results of the vapor pressure and the vapor compositionyielded the partial vapor pressure of each species and therecommer.ded limits of total vapor pressure This work fitted

  10. Field application of an interpretation method of downhole temperature and pressure data for detecting water entry in horizontal/highly inclined gas wells 

    E-Print Network [OSTI]

    Achinivu, Ochi I.

    2009-05-15

    and temperature gauges and fiber optic sensors. The monitoring instruments are increasingly incorporated as part of the intelligent completion in oil wells where they provide bottomhole temperature, pressure and sometimes volumetric flow rate along the wellbore...

  11. Vapor Transport of a Volatile Solvent for a Multicomponent Aerosol Droplet

    E-Print Network [OSTI]

    James Q. Feng

    2015-07-19

    This work presents analytical formulas derived for evaluating vapor transport of a volatile solvent for an isolated multicomponent droplet in a quiescent environment, based on quasi-steady-state approximation. Among multiple solvent components, only one component is considered to be much more volatile than the rest such that other components are assumed to be nonvolatile remaining unchanged in the droplet during the process of (single-component) volatile solvent evaporation or condensation. For evaporating droplet, the droplet size often initially decreases following the familiar "d^2 law" at an accelerated rate. But toward the end, the rate of droplet size change diminishes due to the presence of nonvolatile cosolvent. Such an acceleration-deceleration reversal behavior is unique for evaporating multicomponent droplet, while the droplet of pure solvent has an accelerated rate of size change all the way through the end. This reversal behavior is also reflected in the droplet surface temperature evolution as "S-shaped" curves. However, a closer mathematical examination of conditions for acceleration-deceleration reversal indicates that the acceleration phase may disappear when the amount of nonvolatile cosolvent is relatively small and ambient vapor pressure is relatively high. Because the net effect of adding nonvolatile cosolvent is to reduce the mole fraction of the volatile solvent such that the saturation vapor pressure is lowered, vapor condensation onto the multicomponent droplet is predicted to occur when the ambient vapor pressure is subsaturated with respect to that for the pure volatile solvent. In this case, the droplet will grow asymptotically toward a finite size. But when the ambient vapor pressure becomes supersaturated with respect to that for the pure volatile solvent, the condensation growth of droplet can continue indefinitely without bound.

  12. Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank

    Office of Energy Efficiency and Renewable Energy (EERE)

    Case study covering Compact Membrane Systems, Inc. and its membrane vapor processor that recovers fuel vapors from gasoline refueling.

  13. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; John DuPoint

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

  14. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Levy, Edward; Bilirgen, Harun; DuPont, John

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

  15. Hot-Wire Chemical Vapor Deposition (HWCVD) technologies: Rapid, controllable growth of epitaxial silicon films

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2013-12-27

    NREL scientists have discovered a unique way to quickly grow epitaxial Si using hot-wire chemical vapor deposition (HWCVD), which holds the potential to greatly decrease costs within the manufacturing of Si substrates.  With NREL’s HWCVD technology, Si material use and costs are dramatically reduced with scalable manufacturing and lower deposition temperatures.  NREL’s unique HWCVD technique can easily be integrated into existing manufacturing processes, allowing...

  16. Falcon series data report: 1987 LNG vapor barrier verification field trials

    SciTech Connect (OSTI)

    Brown, T.C.; Cederwall, R.T.; Chan, S.T.; Ermak, D.L.; Koopman, R.P.; Lamson, K.C.; McClure, J.W.; Morris, L.K.

    1990-06-01

    A series of five Liquefied Natural Gas Spills up to 66 m{sup 3} in volume were performed on water within a vapor barrier structure at Frenchman Flat on the Nevada Test Site as a part of a joint government/industry study. This data report presents a description of the tests, the test apparatus, the instrumentation, the meteorological conditions, and the data from the tests. 16 refs., 27 figs., 8 tabs.

  17. Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell

    E-Print Network [OSTI]

    Natarajan, Dilip; Van Nguyen, Trung

    2003-03-27

    to the slower oxygen reduction kinetics and mass transport limitations imposed by the liquid water generated by the electrochemical reaction and electro-osmotic drag. The liquid water can hinder transport of the reactant species by blocking the pores... generated by the electrochemical reaction is removed from the catalyst layer by two mechanisms namely, evaporation and diffusion of water vapor and liquid water transport. The water vapor transport process is similar to the oxygen species, i.e. diffusion...

  18. A low-temperature source for the generation of uranium Henry U. Lee and Richard N. Zare

    E-Print Network [OSTI]

    -temperature uranium vapor source. The four boldface arrows point to where a mirror- like film is deposited whenA low-temperature source for the generation of uranium vapor Henry U. Lee and Richard N. Zare Department of Chemistry, Columbia University, New York, New York 10027 (Received 8 September 1975) Uranium

  19. Hypothetical Thermodynamic Properties: Vapor Pressures and Vaporization Enthalpies of the Even n-Alkanes from C78 to C92 at T ) 298.15 K by

    E-Print Network [OSTI]

    Chickos, James S.

    Hypothetical Thermodynamic Properties: Vapor Pressures and Vaporization Enthalpies of the Even n and vapor pressures of the n-alkanes from T ) (298.15 to 540) K for heneicosane to dononacontane. The vapor pressure and vaporization enthalpy results obtained are compared with estimated data from Morgan's "PERT2

  20. Apparatus and method for photochemical vapor deposition

    DOE Patents [OSTI]

    Jackson, Scott C. (Wilmington, DE); Rocheleau, Richard E. (Wilmington, DE)

    1987-03-31

    A photochemical vapor deposition apparatus includes a reactor housing having a window in one wall above a reaction chamber in the housing. A transparent curtain divides the reaction chamber into a reaction zone and a flush zone. At least one substrate is mounted in the reaction zone in light communication with the window so that ultraviolet radiation may penetrate through the window into the reaction zone. The window is kept clear by a gas flowing through the flush zone.