National Library of Energy BETA

Sample records for temperature syngas cleanup

  1. EA-1867: Scale-up of High-Temperature Syngas Cleanup Technology, Polk County, Florida

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to provide cost-shared funding to RTI International (RTI) for its proposed project to demonstrate the precommercial scale-up of RTI’s high-temperature syngas cleanup and carbon capture and sequestration technologies.

  2. DOE-Sponsored Syngas Cleanup Demonstration Project Reaches Development Milestone

    Broader source: Energy.gov [DOE]

    In a project sponsored by the U.S. Department of Energy (DOE), a demonstration-scale application of RTI International’s warm synthesis gas (syngas) cleanup process technology has achieved a key operational milestone at Tampa Electric Company’s coal gasification plant in Polk County, Fla.

  3. Microsoft PowerPoint - DFT Syngas Cleanup_3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Density Functional Theory Study of Syngas Cleanup with Ceria-Based Rare Earth Oxides Matthew D. Krcha 1 , Adam D. Mayernick 1 , Michael J. Janik 1 , Kerry M. Dooley 2 1 Department of Chemical Engineering, The Pennsylvania State University, University Park, PA 2 Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA Goal & Motivation H 2 S Adsorption Methane Conversion References Acknowledgements 1. Nolan et al. Surface Science 595 (2005) 223 2. K.M. Dooley, S.

  4. DOE-Sponsored Syngas Cleanup Demonstration Project Reaches Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the syngas is burned in a combustion turbine to produce electricity, while excess heat from the combustion turbine is recovered to generate more electricity in a steam turbine. ...

  5. Task 3.3: Warm Syngas Cleanup and Catalytic Processes for Syngas...

    Office of Scientific and Technical Information (OSTI)

    The goal for this subtask is the development of advanced syngas conversion technologies. Two areas of investigation were evaluated: Sorption-Enhanced Synthetic Natural Gas ...

  6. Syngas Enhanced High Efficiency Low Temperature Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant ...

  7. Task 3.3: Warm Syngas Cleanup and Catalytic Processes for Syngas Conversion to Fuels Subtask 3: Advanced Syngas Conversion to Fuels

    SciTech Connect (OSTI)

    Lebarbier Dagel, Vanessa M.; Li, J.; Taylor, Charles E.; Wang, Yong; Dagle, Robert A.; Deshmane, Chinmay A.; Bao, Xinhe

    2014-03-31

    This collaborative joint research project is in the area of advanced gasification and conversion, within the Chinese Academy of Sciences (CAS)-National Energy Technology Laboratory (NETL)-Pacific Northwest National Laboratory (PNNL) Memorandum of Understanding. The goal for this subtask is the development of advanced syngas conversion technologies. Two areas of investigation were evaluated: Sorption-Enhanced Synthetic Natural Gas Production from Syngas The conversion of synthetic gas (syngas) to synthetic natural gas (SNG) is typically catalyzed by nickel catalysts performed at moderate temperatures (275 to 325°C). The reaction is highly exothermic and substantial heat is liberated, which can lead to process thermal imbalance and destruction of the catalyst. As a result, conversion per pass is typically limited, and substantial syngas recycle is employed. Commercial methanation catalysts and processes have been developed by Haldor Topsoe, and in some reports, they have indicated that there is a need and opportunity for thermally more robust methanation catalysts to allow for higher per-pass conversion in methanation units. SNG process requires the syngas feed with a higher H2/CO ratio than typically produced from gasification processes. Therefore, the water-gas shift reaction (WGS) will be required to tailor the H2/CO ratio. Integration with CO2 separation could potentially eliminate the need for a separate WGS unit, thereby integrating WGS, methanation, and CO2 capture into one single unit operation and, consequently, leading to improved process efficiency. The SNG process also has the benefit of producing a product stream with high CO2 concentrations, which makes CO2 separation more readily achievable. The use of either adsorbents or membranes that selectively separate the CO2 from the H2 and CO would shift the methanation reaction (by driving WGS for hydrogen production) and greatly improve the overall efficiency and economics of the process. The scope of this

  8. Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engines | Department of Energy Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant potential exists for clean diesel combustion by recouping exhaust energy to generate syngas either with a dedicated reformer or in-cylinder fuel reforming. p-10_hou.pdf (155.5 KB) More Documents & Publications Adaptive PCCI with Variable Orifice Injector for Low Cost High Efficiency

  9. High temperature electrolysis for syngas production

    DOE Patents [OSTI]

    Stoots, Carl M.; O'Brien, James E.; Herring, James Stephen; Lessing, Paul A.; Hawkes, Grant L.; Hartvigsen, Joseph J.

    2011-05-31

    Syngas components hydrogen and carbon monoxide may be formed by the decomposition of carbon dioxide and water or steam by a solid-oxide electrolysis cell to form carbon monoxide and hydrogen, a portion of which may be reacted with carbon dioxide to form carbon monoxide. One or more of the components for the process, such as steam, energy, or electricity, may be provided using a nuclear power source.

  10. Trace-Metal Scavenging from Biomass Syngas with Novel High-Temperature Sorbents

    SciTech Connect (OSTI)

    Gale, Thomas K.; Walsh, Pete M.

    2007-03-21

    Effective syngas cleanup is one of the remaining major technical challenges yet to be resolved and one that will provide the most benefit to the suite of bio-thermochemical process technologies. Beyond tars and acid gases, which are themselves a significant detriment to reforming catalysts and associated equipment, semi-volatile metals can also damage cleanup systems, catalysts, and contaminate the fungible products. Metals are a difficult challenge to deal with whether using hot-gas filtration or low-temperature processing. Even though most of the metal tends to condense before the barrier filter of hot-gas cleanup systems, some small percentage of the metal (large enough to damage syngas-reforming catalysts, the candle filters themselves, and gas turbine blades) does pass through these barrier filters along with the clean syngas. Low-temperature processing requires expensive measures to remove metals from the process stream. Significant costs are required to remove these metals and if they are not removed before contacting the catalyst, they will significantly reduce the life of the catalyst. One approach to solving the metals problem is to use high-temperature sorbents to capture all of the semi-volatile metals upstream of the barrier filter, which would prevent even small amounts of metal from passing through the filter with the clean syngas. High Temperature sorbents have already been developed that have been shown to be effective at capturing semi-volatile metals from vitiated combustion effluent, i.e., high-temperature flue gas. The objective on this project was to evaluate these same sorbents for their ability to scavenge metals from inert, reducing, and real syngas environments. Subsequently, it was the objective of this project to develop designer sorbents and an injection technology that would optimize the effectiveness of these sorbents at capturing metals from syngas, protecting the barrier filters from damage, and protecting the catalysts and other

  11. Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas

    SciTech Connect (OSTI)

    Turk, Brian; Gupta, Raghubir; Sharma, Pradeepkumar; Albritton, Johnny; Jamal, Aqil

    2010-09-30

    One of the key obstacles for the introduction of commercial gasification technology for the production of power with Integrated Gasification Combined Cycle (IGCC) plants or the production of value added chemicals, transportation fuels, and hydrogen has been the cost of these systems. This situation is particularly challenging because the United States has ample coal resources available as raw materials and effective use of these raw materials could help us meet our energy and transportation fuel needs while significantly reducing our need to import oil. One component of the cost of these systems that faces strong challenges for continuous improvement is removing the undesirable components present in the syngas. The need to limit the increase in cost of electricity to < 35% for new coal-based power plants which include CO{sub 2} capture and sequestration addresses both the growing social concern for global climate change resulting from the emission of greenhouse gas and in particular CO{sub 2} and the need to control cost increases to power production necessary to meet this social objective. Similar improvements to technologies for trace contaminants are getting similar pressure to reduce environmental emissions and reduce production costs for the syngas to enable production of chemicals from coal that is cost competitive with oil and natural gas. RTI, with DOE/NETL support, has been developing sorbent technologies that enable capture of trace contaminants and CO{sub 2} at temperatures above 400 °F that achieve better capture performance, lower costs and higher thermal efficiency. This report describes the specific work of sorbent development for mercury (Hg), arsenic (As), selenium (Se), cadmium (Cd), and phosphorous (P) and CO{sub 2} removal. Because the typical concentrations of Hg, As, Se, Cd, and P are less than 10 ppmv, the focus has been on single-use sorbents with sufficient capacity to ensure replacement costs are cost effective. The research in this

  12. THE PRODUCTION OF SYNGAS VIA HIGH TEMPERATURE ELECTROLYSIS AND BIO-MASS GASIFICATION

    SciTech Connect (OSTI)

    M. G. McKellar; G. L. Hawkes; J. E. O'Brien

    2008-11-01

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to improve the hydrogen production efficiency of the steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon dioxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K.

  13. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 9: Mixed Alcohols From Syngas -- State of Technology

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    This deliverable is for Task 9, Mixed Alcohols from Syngas: State of Technology, as part of National Renewable Energy Laboratory (NREL) Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Task 9 supplements the work previously done by NREL in the mixed alcohols section of the 2003 technical report Preliminary Screening--Technical and Economic Assessment of Synthesis Gas to Fuels and Chemicals with Emphasis on the Potential for Biomass-Derived Syngas.

  14. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect (OSTI)

    Celik, Ismail B.

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that

  15. Progress toward Biomass and Coal-Derived Syngas Warm Cleanup: Proof-of-Concept Process Demonstration of Multicontaminant Removal for Biomass Application

    SciTech Connect (OSTI)

    Howard, Christopher J.; Dagle, Robert A.; Lebarbier, Vanessa MC; Rainbolt, James E.; Li, Liyu; King, David L.

    2013-06-19

    Systems comprising of multiple sorbent and catalytic beds have been developed for the warm syngas cleanup of coal- and biomass-derived syngas. Tailored specifically for biomass application the process described here consists of six primary unit operations: 1) Na2CO3 bed for HCl removal, 2) two regenerable ZnO beds for bulk H2S removal, 3) ZnO bed for H2S polishing, 4) NiCu/SBA-16 sorbent for trace metal (e.g. AsH3) removal, 5) steam reforming catalyst bed for tars and light hydrocarbons reformation and NH3 decomposition, and a 6) Cu-based LT-WGS catalyst bed. Simulated biomass-derived syngas containing a multitude of inorganic contaminants (H2S, AsH3, HCl, and NH3) and hydrocarbon additives (methane, ethylene, benzene, and naphthalene) was used to demonstrate process effectiveness. The efficiency of the process was demonstrated for a period of 175 hours, during which no signs of deactivation were observed. Post-run analysis revealed small levels of sulfur slipped through the sorbent bed train to the two downstream catalytic beds. Future improvements could be made to the trace metal polishing sorbent to ensure complete inorganic contaminant removal (to low ppb level) prior to the catalytic steps. However, dual, regenerating ZnO beds were effective for continuous removal for the vast majority of the sulfur present in the feed gas. The process was effective for complete AsH3 and HCl removal. The steam reforming catalyst completely reformed all the hydrocarbons present in the feed (methane, ethylene, benzene, and naphthalene) to additional syngas. However, post-run evaluation, under kinetically-controlled conditions, indicates deactivation of the steam reforming catalyst. Spent material characterization suggests this is attributed, in part, to coke formation, likely due to the presence of benzene and/or naphthalene in the feed. Future adaptation of this technology may require dual, regenerable steam reformers. The process and materials described in this report hold

  16. HIGH-TEMPERATURE CO-ELECTROLYSIS OF H2O AND CO2 FOR SYNGAS PRODUCTION

    SciTech Connect (OSTI)

    Stoots, C.M.

    2006-11-01

    Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen content (an example is the Athabasca Oil Sands). Additionally, the higher contents of sulfur and nitrogen of these resources requires processes such as hydrotreating to meet environmental requirements. In the mean time, with the price of oil currently over $50 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. South Africa has used synfuels to power a significant number of their buses, trucks, and taxicabs. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to investigate the feasibility of producing syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. The syngas can then be used for synthetic fuel production. This program is a combination of experimental and computational activities. Since the solid oxide electrolyte material is a conductor of oxygen ions, CO can be produced by electrolyzing CO2 sequestered from some greenhouse gas-emitting process. Under certain conditions, however, CO can further electrolyze to produce carbon, which can then deposit on cell surfaces and reduce cell performance. The understanding of the co-electrolysis of steam and CO2 is also complicated by the competing water-gas shift reaction. Results of experiments and calculations to date of CO2 and CO2/H2O electrolysis will be presented and discussed. These will include

  17. Key Issues in Syngas Cleanup

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Res. 2005, 44, 7945-7956. 7. Nitsch, X. et al., Energy Fuels 2013, 27, 5459-5465. 9 T 900C for tar conversion? EQUILIBRIUM DATA SAYS SO T increase 600 950C, less tar ...

  18. Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode

    SciTech Connect (OSTI)

    Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

    2012-07-01

    Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

  19. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect (OSTI)

    Howard Meyer

    2010-11-30

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energy’s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process – High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  20. HIGH-TEMPERATURE ELECTROLYSIS FOR LARGE-SCALE HYDROGEN AND SYNGAS PRODUCTION FROM NUCLEAR ENERGY SYSTEM SIMULATION AND ECONOMICS

    SciTech Connect (OSTI)

    J. E. O'Brien; M. G. McKellar; E. A. Harvego; C. M. Stoots

    2009-05-01

    A research and development program is under way at the Idaho National Laboratory (INL) to assess the technological and scale-up issues associated with the implementation of solid-oxide electrolysis cell technology for efficient high-temperature hydrogen production from steam. This work is supported by the US Department of Energy, Office of Nuclear Energy, under the Nuclear Hydrogen Initiative. This paper will provide an overview of large-scale system modeling results and economic analyses that have been completed to date. System analysis results have been obtained using the commercial code UniSim, augmented with a custom high-temperature electrolyzer module. Economic analysis results were based on the DOE H2A analysis methodology. The process flow diagrams for the system simulations include an advanced nuclear reactor as a source of high-temperature process heat, a power cycle and a coupled steam electrolysis loop. Several reactor types and power cycles have been considered, over a range of reactor outlet temperatures. Pure steam electrolysis for hydrogen production as well as coelectrolysis for syngas production from steam/carbon dioxide mixtures have both been considered. In addition, the feasibility of coupling the high-temperature electrolysis process to biomass and coal-based synthetic fuels production has been considered. These simulations demonstrate that the addition of supplementary nuclear hydrogen to synthetic fuels production from any carbon source minimizes emissions of carbon dioxide during the production process.

  1. Process for producing ethanol from syngas

    DOE Patents [OSTI]

    Krause, Theodore R; Rathke, Jerome W; Chen, Michael J

    2013-05-14

    The invention provides a method for producing ethanol, the method comprising establishing an atmosphere containing methanol forming catalyst and ethanol forming catalyst; injecting syngas into the atmosphere at a temperature and for a time sufficient to produce methanol; and contacting the produced methanol with additional syngas at a temperature and for a time sufficient to produce ethanol. The invention also provides an integrated system for producing methanol and ethanol from syngas, the system comprising an atmosphere isolated from the ambient environment; a first catalyst to produce methanol from syngas wherein the first catalyst resides in the atmosphere; a second catalyst to product ethanol from methanol and syngas, wherein the second catalyst resides in the atmosphere; a conduit for introducing syngas to the atmosphere; and a device for removing ethanol from the atmosphere. The exothermicity of the method and system obviates the need for input of additional heat from outside the atmosphere.

  2. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  3. A perspective on syngas from coal

    SciTech Connect (OSTI)

    Rath, L.K.; Longanbach, J.R. )

    1991-01-01

    Syngas, a mixture of hydrogen and carbon monoxide, has been produced from coal for more than 100 years. But today most syngas is produced from noncoal feedstocks, by catalytic steam reforming of natural gas and naphtha or partial oxidation of heavy hydrocarbons such as petroleum resid. Three types of syngas, characterized by their H{sub 2}/CO ratio, are needed. Low ratio, H{sub 2}/CO = 0.4-0.8, syngas can be used in recently developed processes such as the Liquid Phase Methanol synthesis and the Shell Fischer-Tropsch wax synthesis; moderate ratio, H{sub 2}/CO = 0.8-1.5, syngas is used in the Tennessee Eastman coal based synthesis of methanol and acetic anhydride; high ratio, H{sub 2}/CO = 1.8-2.5, syngas is used in traditional methanol synthesis and the Fischer-Tropsch synthesis at Sasol. Different types of gasifiers are available for the production of syngas. These include Lurgi fixed-bed dry bottom and slagging gasifiers, agglomerating fluidized-bed gasifiers, single and two-stage entrained slurry feed gasifiers, and single-stage entrained dry feed gasifiers. The cost of syngas from subbituminous coal is shown to be relatively insensitive to the H{sub 2}/CO ratio produced and may soon be competitive with natural gas-based syngas in some parts of the country due to the increasing demand for and cost of natural gas. Recent in this paper, DOE sponsored research on three topics on the production of syngas from coal, coal gasifiers for the direct production of high hydrogen content syngas, advanced methods to separate hydrogen from syngas at elevated temperatures and biological conversion of coal to syngas, are also discussed.

  4. Thermodynamic analysis of interactions between Ni-based solid oxide fuel cells (SOFC) anodes and trace species in a survey of coal syngas

    SciTech Connect (OSTI)

    Andrew Martinez; Kirk Gerdes; Randall Gemmen; James Postona

    2010-03-20

    A thermodynamic analysis was conducted to characterize the effects of trace contaminants in syngas derived from coal gasification on solid oxide fuel cell (SOFC) anode material. The effluents from 15 different gasification facilities were considered to assess the impact of fuel composition on anode susceptibility to contamination. For each syngas case, the study considers the magnitude of contaminant exposure resulting from operation of a warm gas cleanup unit at two different temperatures and operation of a nickel-based SOFC at three different temperatures. Contaminant elements arsenic (As), phosphorous (P), and antimony (Sb) are predicted to be present in warm gas cleanup effluent and will interact with the nickel (Ni) components of a SOFC anode. Phosphorous is the trace element found in the largest concentration of the three contaminants and is potentially the most detrimental. Poisoning was found to depend on the composition of the syngas as well as system operating conditions. Results for all trace elements tended to show invariance with cleanup operating temperature, but results were sensitive to syngas bulk composition. Synthesis gas with high steam content tended to resist poisoning.

  5. Phosphorus, Sulfur, and Chlorine in Fuel Gases: Impact on High Temperature Fuel Cell Performance and Clean-Up Options

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phosphorus, Sulfur, and Chlorine in Fuel Gases: Impact on High Temperature Fuel Cell Performance and Clean-Up Options OLGA A MARINA Pacific Northwest National Laboratory Workshop on Gas Clean-Up for Fuel Cell Applications March 6-7, 2014 57% net electrical efficiency on methane 8 SOFC cells per furnace with independent gas flow Multi-cell MCFC test stand 2 High Temperature Fuel Cell R&D at PNNL; Impurities Overview OA Marina Selected Impurities in Biogas/Landfill Gas: Cell/stack/system

  6. Biomass Gas Clean-Up Using a Therminator

    SciTech Connect (OSTI)

    2006-04-01

    Clean-up and conditioning of syngas is a key technical barrier to the commercialization of biomass gasification systems. Current technologies do not meet the necessary performance, cost, and environmental criteria to achieve commercialization of biomass gasification technologies.

  7. Trace Metal Scavenging from Biomass Syngas Using Novel Sorbents

    SciTech Connect (OSTI)

    2006-04-01

    This project is investigating the use of high-temperature powder sorbents for scavenging alkalis and heavy metals from biomass-derived syngas.

  8. Overview of Contaminant Removal From Coal-Derived Syngas

    SciTech Connect (OSTI)

    Layne, A.W.; Alvin, M.A.; Granite, E.; Pennline, H.W.; Siriwardane, R.V.; Keairns, D.; Newby, R.A.

    2007-11-01

    subsequent reheat to the required higher temperatures.
    From a historical perspective, the evolution of advanced syngas cleaning systems applied in IGCC and chemical and fuel synthesis plants has followed a path of configuring a series of individual cleaning steps, one for each syngas contaminant, each step controlled to its individual temperature and sorbent and catalyst needs. As the number of syngas contaminants of interest has increased (particulates, hydrogen sulfide, carbonyl sulfide, halides such as hydrogen chloride, ammonia, hydrogen cyanide, alkali metals, metal carbonyls, mercury, arsenic, selenium, and cadmium) and the degree of syngas cleaning has become more severe, the potential feasibility of advanced humid gas cleaning has diminished. A focus on multi-contaminant syngas cleaning is needed to enhance the potential cost savings, and performance of humid gas cleaning will focus on multi-contaminant syngas cleaning. Groups of several syngas contaminants to be removed simultaneously need to be considered, resulting in significant gas cleaning system intensification. Intensified, multi-contaminant cleaning processes need to be devised and their potential performance characteristics understood through small-scale testing, conceptual design evaluation, and scale-up assessment with integration into the power generation system. Results of a 1-year study undertaken by DOE/NETL are presented to define improved power plant configurations and technology for advanced multi-contaminant cleanup options.

  9. Environmental Cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Cleanup Tour Environmental Cleanup See how LANL is cleaning up the environmental legacy of the Manhattan Project and Cold War

  10. Environmental Cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Cleanup Tour Environmental Cleanup See how LANL is cleaning up the environmental legacy of the Manhattan Project and Cold War Open full screen to view more You are...

  11. Cleanup at Rocky Flats

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News » Cleanup Progress Reports Cleanup Progress Reports Documents Available for Download February 22, 2016 Cleanup Progress Report - 2015 Oak Ridge's cleanup accomplishments during 2015. January 1, 2015 Cleanup Progress Report - 2014 Oak Ridge's cleanup accomplishments during 2014 January 1, 2014 Cleanup Progress Report - 2013 Oak Ridge's cleanup accomplishments in 2013. January 1, 2013 Cleanup Progress Report - 2012 Oak Ridge's cleanup accomplishments during 2012. January 2, 2012 Cleanup

  12. Low Cost High-H2 Syngas Production for Power and Liquid Fuels

    SciTech Connect (OSTI)

    Zhou, S. James

    2015-07-31

    This report summarizes the technical progress made of the research project entitled “Low Cost High-H2 Syngas Production for Power and Liquid Fuels,” under DOE Contract No. DE-FE-0011958. The period of performance was October 1, 2013 through July 30, 2015. The overall objectives of this project was to determine the technical and economic feasibility of a systems approach for producing high hydrogen syngas from coal with the potential to reduce significantly the cost of producing power, chemical-grade hydrogen or liquid fuels, with carbon capture to reduce the environmental impact of gasification. The project encompasses several areas of study and the results are summarized here. (1) Experimental work to determine the technical feasibility of a novel hybrid polymer/metal H2-membrane to recover pure H2 from a coal-derived syngas was done. This task was not successful. Membranes were synthesized and show impermeability of any gases at required conditions. The cause of this impermeability was most likely due to the densification of the porous polymer membrane support made from polybenzimidazole (PBI) at test temperatures above 250 °C. (2) Bench-scale experimental work was performed to extend GTI's current database on the University of California Sulfur Recovery Process-High Pressure (UCSRP-HP) and recently renamed Sulfur Removal and Recovery (SR2) process for syngas cleanup including removal of sulfur and other trace contaminants, such as, chlorides and ammonia. The SR2 process tests show >90% H2S conversion with outlet H2S concentrations less than 4 ppmv, and 80-90% ammonia and chloride removal with high mass transfer rates. (3) Techno-economic analyses (TEA) were done for the production of electric power, chemical-grade hydrogen and diesel fuels, from a mixture of coal- plus natural gas-derived syngas using the Aerojet Rocketdyne (AR) Advanced Compact coal gasifier and a natural gas partial oxidation reactor (POX) with SR2 technology. Due to the unsuccessful

  13. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  14. Environmental Cleanup Stories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cleanup Feature Stories community-environmentassetsimagesicon-environment.jpg Environmental Cleanup Stories Our environmental stewardship commitment: clean up the past,...

  15. HIGH EFFICIENCY SYNGAS GENERATION

    SciTech Connect (OSTI)

    Robert J. Copeland; Yevgenia Gershanovich; Brian Windecker

    2005-02-01

    This project investigated an efficient and low cost method of auto-thermally reforming natural gas to hydrogen and carbon monoxide. Reforming is the highest cost step in producing products such as methanol and Fisher Tropsch liquids (i.e., gas to liquids); and reducing the cost of reforming is the key to reducing the cost of these products. Steam reforming is expensive because of the high cost of the high nickel alloy reforming tubes (i.e., indirectly fired reforming tubes). Conventional auto-thermal or Partial Oxidation (POX) reforming minimizes the size and cost of the reformers and provides a near optimum mixture of CO and hydrogen. However POX requires pure oxygen, which consumes power and significantly increases the cost to reforming. Our high efficiency process extracts oxygen from low-pressure air with novel oxygen sorbent and transfers the oxygen to a nickel-catalyzed reformer. The syngas is generated at process pressure (typically 20 to 40 bar) without nitrogen dilution and has a 1CO to 2H{sub 2} ratio that is near optimum for the subsequent production of Fisher-Tropsch liquid to liquids and other chemicals (i.e., Gas to Liquids, GTL). Our high process efficiency comes from the way we transfer the oxygen into the reformer. All of the components of the process, except for the oxygen sorbent, are commonly used in commercial practice. A process based on a longlived, regenerable, oxygen transfer sorbent could substantially reduce the cost of natural gas reforming to syngas. Lower cost syngas (CO + 2H{sub 2}) that is the feedstock for GTL would reduce the cost of GTL and for other commercial applications (e.g., methanol, other organic chemicals). The vast gas resources of Alaska's North Slope (ANS) offer more than 22 Tcf of gas and GTL production in this application alone, and could account for as much as 300,000 to 700,000 bpd for 20 to 30+ years. We developed a new sorbent, which is an essential part of the High Efficiency Oxygen Process (HOP). We tested the

  16. SYSTEM ANALYSIS OF NUCLEAR-ASSISTED SYNGAS PRODUCTION FROM COAL

    SciTech Connect (OSTI)

    E. A. Harvego; M. G. McKellar; J. E. O'Brien

    2008-09-01

    A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via high-temperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 66.1% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency.

  17. Dimethyl ether production from methanol and/or syngas

    DOE Patents [OSTI]

    Dagle, Robert A; Wang, Yong; Baker, Eddie G; Hu, Jianli

    2015-02-17

    Disclosed are methods for producing dimethyl ether (DME) from methanol and for producing DME directly from syngas, such as syngas from biomass. Also disclosed are apparatus for DME production. The disclosed processes generally function at higher temperatures with lower contact times and at lower pressures than conventional processes so as to produce higher DME yields than do conventional processes. Certain embodiments of the processes are carried out in reactors providing greater surface to volume ratios than the presently used DME reactors. Certain embodiments of the processes are carried out in systems comprising multiple microchannel reactors.

  18. Cooling Strategies for Vane Leading Edges in a Syngas Environment Including Effects of Deposition and Turbulence

    SciTech Connect (OSTI)

    Ames, Forrest; Bons, Jeffrey

    2014-09-30

    The Department of Energy has goals to move land based gas turbine systems to alternate fuels including coal derived synthetic gas and hydrogen. Coal is the most abundant energy resource in the US and in the world and it is economically advantageous to develop power systems which can use coal. Integrated gasification combined cycles are (IGCC) expected to allow the clean use of coal derived fuels while improving the ability to capture and sequester carbon dioxide. These cycles will need to maintain or increase turbine entry temperatures to develop competitive efficiencies. The use of coal derived syngas introduces a range of potential contaminants into the hot section of the gas turbine including sulfur, iron, calcium, and various alkali metals. Depending on the effectiveness of the gas clean up processes, there exists significant likelihood that the remaining materials will become molten in the combustion process and potentially deposit on downstream turbine surfaces. Past evidence suggests that deposition will be a strong function of increasing temperature. Currently, even with the best gas cleanup processes a small level of particulate matter in the syngas is expected. Consequently, particulate deposition is expected to be an important consideration in the design of turbine components. The leading edge region of first stage vanes most often have higher deposition rates than other areas due to strong fluid acceleration and streamline curvature in the vicinity of the surface. This region remains one of the most difficult areas in a turbine nozzle to cool due to high inlet temperatures and only a small pressure ratio for cooling. The leading edge of a vane often has relatively high heat transfer coefficients and is often cooled using showerhead film cooling arrays. The throat of the first stage nozzle is another area where deposition potentially has a strongly adverse effect on turbine performance as this region meters the turbine inlet flow. Based on roughness

  19. Coal-Derived Warm Syngas Purification and CO2 Capture-Assisted Methane Production

    SciTech Connect (OSTI)

    Dagle, Robert A.; King, David L.; Li, Xiaohong S.; Xing, Rong; Spies, Kurt A.; Zhu, Yunhua; Rainbolt, James E.; Li, Liyu; Braunberger, B.

    2014-10-01

    Gasifier-derived syngas from coal has many applications in the area of catalytic transformation to fuels and chemicals. Raw syngas must be treated to remove a number of impurities that would otherwise poison the synthesis catalysts. Inorganic impurities include alkali salts, chloride, sulfur compounds, heavy metals, ammonia, and various P, As, Sb, and Se- containing compounds. Systems comprising multiple sorbent and catalytic beds have been developed for the removal of impurities from gasified coal using a warm cleanup approach. This approach has the potential to be more economic than the currently available acid gas removal (AGR) approaches and improves upon currently available processes that do not provide the level of impurity removal that is required for catalytic synthesis application. Gasification also lends itself much more readily to the capture of CO2, important in the regulation and control of greenhouse gas emissions. CO2 capture material was developed and in this study was demonstrated to assist in methane production from the purified syngas. Simultaneous CO2 sorption enhances the CO methanation reaction through relaxation of thermodynamic constraint, thus providing economic benefit rather than simply consisting of an add-on cost for carbon capture and release. Molten and pre-molten LiNaKCO3 can promote MgO and MgO-based double salts to capture CO2 with high cycling capacity. A stable cycling CO2 capacity up to 13 mmol/g was demonstrated. This capture material was specifically developed in this study to operate in the same temperature range and therefore integrate effectively with warm gas cleanup and methane synthesis. By combining syngas methanation, water-gas-shift, and CO2 sorption in a single reactor, single pass yield to methane of 99% was demonstrated at 10 bar and 330°C when using a 20 wt% Ni/MgAl2O4 catalyst and a molten-phase promoted Mg

  20. Imperium/Lanzatech Syngas Fermentation Project - Biomass Gasification and Syngas Conditioning for Fermentation Evaluation: Cooperative Research and Development Final Report, CRADA Number CRD-12-474

    SciTech Connect (OSTI)

    Wilcox, E.

    2014-09-01

    LanzaTech and NREL will investigate the integration between biomass gasification and LanzaTech's proprietary gas fermentation process to produce ethanol and 2,3-butanediol. Using three feed materials (woody biomass, agricultural residue and herbaceous grass) NREL will produce syngas via steam indirect gasification and syngas conditioning over a range of process relevant operating conditions. The gasification temperature, steam-to-biomass ratio of the biomass feed into the gasifier, and several levels of syngas conditioning (based on temperature) will be varied to produce multiple syngas streams that will be fed directly to 10 liter seed fermenters operating with the Lanzatech organism. The NREL gasification system will then be integrated with LanzaTech's laboratory pilot unit to produce large-scale samples of ethanol and 2,3-butanediol for conversion to fuels and chemicals.

  1. Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper

    SciTech Connect (OSTI)

    A.M. Gandrik

    2012-04-01

    This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

  2. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01

    This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

  3. DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants July 13, 2009 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy (DOE) announces a collaborative project with Research Triangle Institute (RTI) International to design, build, and test a warm gas cleanup system to remove multiple contaminants from coal-derived syngas. The 50-MWe system will include technologies to remove

  4. Legacy Cleanup Completion Project

    Broader source: Energy.gov [DOE]

    Presentation from the 2015 DOE National Cleanup Workshop by Christine Gelles, Associate Deputy Assistant Secretary, Waste Management EM HQ.

  5. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Wood Feedstock

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for treatment of wood-derived syngas for use in the synthesis of liquid fuels. Two different 2,000 metric tonne per day gasification schemes, a low-pressure, indirect system using the gasifier, and a high-pressure, direct system using gasification technology were evaluated. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  6. Material Testing of Coated Alloys in a Syngas Combustion Environment...

    Office of Scientific and Technical Information (OSTI)

    Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6 - Activity ... Title: Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6 - ...

  7. Syngas Generator Use for Retrofit DPF Active Regeneration on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generator Use for Retrofit DPF Active Regeneration on a Medium Duty Truck Syngas Generator Use for Retrofit DPF Active Regeneration on a Medium Duty Truck Syngas enables low ...

  8. Peer Review 2013 Dutta Syngas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Review 2013 Dutta Syngas Peer Review 2013 Dutta Syngas thermochemicalconversiondutta3611.pdf (891.29 KB) More Documents & Publications 2013 Peer Review ...

  9. Dimethyl ether synthesis from syngas in slurry phase

    SciTech Connect (OSTI)

    Han, Y.Z.; Fujimoto, K.; Shikata, T.

    1997-12-31

    Dimethyl ether (DME) is one of the important chemicals derived from synthesis gas. It can be widely used in syngas conversion, production of olefins, or MTG gasoline. Recently, is has been noticed as a substitute of LPG used as home fuel. In the present study, dimethyl ether was effectively synthesized from CO rich syngas (H{sub 2}/CO=1/1) over hybrid catalyst containing a Cu-Zn-Al(O) based methanol synthesis catalyst and {gamma}-alumina in an agitated slurry reactor under relatively mild reaction conditions: temperature 230--300 C, pressure 2.0--5.0 MPa, contact time 2.0--10 gram-cat.-h/mol. The catalysts used as the methanol active components were commercially available Cu-Zn-Al(O) based catalysts, BASF S385 and ICI 51-2. Two kinds of {gamma}-alumina ALO4 (standard catalyst of the Catalysis Society of Japan) and N612N (NIKKI Co., Japan) were used as the methanol dehydration components. The slurry was prepared by mixing the fine powder (<100 mesh) of catalyst components with purified n-hexadecane. The catalysts were reduced by a mixing gas containing 20% syngas and 80% nitrogen with a three-hour programmed temperature raising from room temperature to the final temperature. All products were analyzed by gas chromatographs. Results are given and discussed.

  10. Laminar flame speeds of moist syngas mixtures

    SciTech Connect (OSTI)

    Das, Apurba K. [Department of Mechanical and Aerospace Engineering, Case Western Reserve University, Cleveland, OH 44106 (United States); Kumar, Kamal; Sung, Chih-Jen [Department of Mechanical Engineering, University of Connecticut, Storrs, CT 06269 (United States)

    2011-02-15

    This work experimentally investigates the effect of the presence of water vapor on the laminar flame speeds of moist syngas/air mixtures using the counterflow twin-flame configuration. The experimental results presented here are for fuel lean syngas mixtures with molar percentage of hydrogen in the hydrogen and carbon monoxide mixture varying from 5% to 100%, for an unburned mixture temperature of 323 K, and under atmospheric pressure. At a given equivalence ratio, the effect of varying amount of water vapor addition on the measured laminar flame speed is demonstrated. The experimental laminar flame speeds are also compared with computed values using chemical kinetic mechanisms reported in the literature. It is found that laminar flame speed varies non-monotonically with addition of water for the carbon monoxide rich mixtures. It first increases with increasing amount of water addition, reaches a maximum value, and then decreases. An integrated reaction path analysis is further conducted to understand the controlling mechanism responsible for the non-monotonic variation in laminar flame speed due to water addition. On the other hand, for higher values of H{sub 2}/CO ratio the laminar flame speed monotonically decreases with increasing water addition. It is shown that the competition between the chemical and thermal effects of water addition leads to the observed response. Furthermore, reaction rate sensitivity analysis as well as binary diffusion coefficient sensitivity analysis are conducted to identify the possible sources of discrepancy between the experimental and predicted values. The sensitivity results indicate that the reaction rate constant of H{sub 2}+OH = H{sub 2}O+H is worth revisiting and refinement of binary diffusion coefficient data of N{sub 2}-H{sub 2}O, N{sub 2}-H{sub 2}, and H{sub 2}-H{sub 2}O pairs can be considered. (author)

  11. A Study of Advanced Materials for Gas Turbine Coatings at Elevated Temperatures Using Selected Microstructures and Characteristic Environments for Syngas Combustion

    SciTech Connect (OSTI)

    Ravinder Diwan; Patrick Mensah; Guoqiang Li; Nalini Uppu; Strphen Akwaboa; Monica Silva; Ebubekir Beyazoglu; Ogad Agu; Naresh Polasa; Lawrence Bazille; Douglas Wolfe; Purush Sahoo

    2011-02-10

    Thermal barrier coatings (TBCs) that can be suitable for use in industrial gas turbine engines have been processed and compared with electron beam physical vapor deposition (EBPVD) microstructures for applications in advanced gas turbines that use coal-derived synthesis gas. Thermo-physical properties have been evaluated of the processed air plasma sprayed TBCs with standard APS-STD and vertically cracked APS-VC coatings samples up to 1300 C. Porosity of these selected coatings with related microstructural effects have been analyzed in this study. Wet and dry thermal cycling studies at 1125 C and spalling resistance thermal cycling studies to 1200 C have also been carried out. Type I and Type II hot corrosion tests were carried out to investigate the effects of microstructure variations and additions of alumina in YSZ top coats in multi-layered TBC structures. The thermal modeling of turbine blade has also been carried out that gives the capability to predict in-service performance temperature gradients. In addition to isothermal high temperature oxidation kinetics analysis in YSZ thermal barrier coatings of NiCoCrAlY bond coats with 0.25% Hf. This can affect the failure behavior depending on the control of the thermally grown oxide (TGO) growth at the interface. The TGO growth kinetics is seen to be parabolic and the activation energies correspond to interfacial growth kinetics that is controlled by the diffusion of O{sub 2} in Al{sub 2}O{sub 3}. The difference between oxidation behavior of the VC and STD structures are attributed to the effects of microstructure morphology and porosity on oxygen ingression into the zirconia and TGO layers. The isothermal oxidation resistance of the STD and VC microstructures is similar at temperatures up to 1200 C. However, the generally thicker TGO layer thicknesses and the slightly faster oxidation rates in the VC microstructures are attributed to the increased ingression of oxygen through the grain boundaries of the vertically

  12. Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa M.; Albrecht, Karl O.; Li, Jinjing; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2013-05-13

    Synthesis gas (syngas) can be used to synthesize a variety of fuels and chemicals. Domestic transportation and military operational interests have driven continued focus on domestic syngas-based fuels production. Liquid transportation fuels may be made from syngas via four basic processes: 1) higher alcohols, 2) Fischer-Tropsch (FT), 3) methanol-to-gasoline (MTG), and 4) methanol-to-olefins (MTO) and olefins-to-gasoline/distillate (MOGD). Compared to FT and higher alcohols, MTG and MTO-MOGD have received less attention in recent years. Due to the high capital cost of these synthetic fuel plants, the production cost of the finished fuel cannot compete with petroleum-derived fuel. Pacific Northwest National Laboratory has recently evaluated one way to potentially reduce capital cost and overall production cost for MTG by combining the methanol and MTG syntheses in a single reactor. The concept consists of mixing the conventional MTG catalyst (i.e. HZSM-5) with an alcohol synthesis catalyst. It was found that a methanol synthesis catalyst, stable at high temperature (i.e. Pd/ZnO/Al2O3) [1], when mixed with ZSM-5, was active for syngas conversion. Relatively high syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed as they are intermediates to the final hydrocarbon product. However, selectivity control was difficult to achieve as formation of undesirable durene and light hydrocarbons was problematic [2]. The objective of the present study was thus to evaluate other potential composite catalyst systems and optimize the reactions conditions for the conversion of syngas to hydrocarbon fuels, through the use of mixed alcohol intermediates. Mixed alcohols are of interest as they have recently been reported to produce higher yields of gasoline compared to methanol [3]. 1. Lebarbier, V.M., Dagle, R.A., Kovarik, L., Lizarazo-Adarme, J.A., King, D.L., Palo, D.R., Catalyst Science & Technology, 2012, 2

  13. 2016 National Cleanup Workshop | Department of Energy

    Office of Environmental Management (EM)

    6 National Cleanup Workshop 2016 National Cleanup Workshop 2016 National Cleanup Workshop The Energy Communities Alliance (ECA) will be holding the 2016 National Cleanup Workshop ...

  14. Site Transition Process Upon Cleanup Completion | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process Upon Cleanup Completion Site Transition Process Upon Cleanup Completion Site Transition Process Upon Cleanup Completion PDF icon Site Transition Process Upon Cleanup ...

  15. Syngas treating options for IGCC power plants

    SciTech Connect (OSTI)

    Wen, H.; Mohammad-zadeh, Y.

    1996-12-31

    Increased environmental awareness, lower cost of gas turbine based combined cycle power plants, and advances in gasification processes have made the integrated gasification combined cycle (IGCC) a viable technology to convert solid fuel to useful energy. The raw solid fuel derived synthesis gas (syngas) contains contaminants that should be removed before combustion in a gas turbine. Therefore, an important process in a gasification based plant is the cleaning of syngas. This paper provides information about various syngas treating technologies and describes their optimal selections for power generation or cogeneration of steam for industrial applications.

  16. A Review of Materials for Gas Turbines Firing Syngas Fuels

    SciTech Connect (OSTI)

    Gibbons, Thomas; Wright, Ian G

    2009-05-01

    Following the extensive development work carried out in the 1990's, gas turbine combined-cycle (GTCC) systems burning natural gas represent a reliable and efficient power generation technology widely used in many parts of the world. A critical factor was that, in order to operate at the high turbine entry temperatures required for high efficiency operation, aero-engine technology, i.e., single-crystal blades, thermal barrier coatings, and sophisticated cooling techniques had to be rapidly scaled up and introduced into these large gas turbines. The problems with reliability that resulted have been largely overcome, so that the high-efficiency GTCC power generation system is now a mature technology, capable of achieving high levels of availability. The high price of natural gas and concern about emission of greenhouse gases has focused attention on the desirability of replacing natural gas with gas derived from coal (syngas) in these gas turbine systems, since typical systems analyses indicate that IGCC plants have some potential to fulfil the requirement for a zero-emissions power generation system. In this review, the current status of materials for the critical hot gas path parts in large gas turbines is briefly considered in the context of the need to burn syngas. A critical factor is that the syngas is a low-Btu fuel, and the higher mass flow compared to natural gas will tend to increase the power output of the engine. However, modifications to the turbine and to the combustion system also will be necessary. It will be shown that many of the materials used in current engines will also be applicable to units burning syngas but, since the combustion environment will contain a greater level of impurities (especially sulfur, water vapor, and particulates), the durability of some components may be prejudiced. Consequently, some effort will be needed to develop improved coatings to resist attack by sulfur-containing compounds, and also erosion.

  17. Cleanup Progress Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    News » Cleanup Progress Reports Cleanup Progress Reports Documents Available for Download February 22, 2016 Cleanup Progress Report - 2015 Oak Ridge's cleanup accomplishments during 2015. January 1, 2015 Cleanup Progress Report - 2014 Oak Ridge's cleanup accomplishments during 2014 January 1, 2014 Cleanup Progress Report - 2013 Oak Ridge's cleanup accomplishments in 2013. January 1, 2013 Cleanup Progress Report - 2012 Oak Ridge's cleanup accomplishments during 2012. January 2, 2012 Cleanup

  18. Mitigation of Syngas Cooler Plugging and Fouling

    SciTech Connect (OSTI)

    Bockelie, Michael J.

    2015-06-29

    This Final Report summarizes research performed to develop a technology to mitigate the plugging and fouling that occurs in the syngas cooler used in many Integrated Gasification Combined Cycle (IGCC) plants. The syngas cooler is a firetube heat exchanger located downstream of the gasifier. It offers high thermal efficiency, but its’ reliability has generally been lower than other process equipment in the gasification island. The buildup of ash deposits that form on the fireside surfaces in the syngas cooler (i.e., fouling) lead to reduced equipment life and increased maintenance costs. Our approach to address this problem is that fouling of the syngas cooler cannot be eliminated, but it can be better managed. The research program was funded by DOE using two budget periods: Budget Period 1 (BP1) and Budget Period 2 (BP2). The project used a combination of laboratory scale experiments, analysis of syngas cooler deposits, modeling and guidance from industry to develop a better understanding of fouling mechanisms and to develop and evaluate strategies to mitigate syngas cooler fouling and thereby improve syngas cooler performance. The work effort in BP 1 and BP 2 focused on developing a better understanding of the mechanisms that lead to syngas cooler plugging and fouling and investigating promising concepts to mitigate syngas cooler plugging and fouling. The work effort focused on the following: • analysis of syngas cooler deposits and fuels provided by an IGCC plant collaborating with this project; • performing Jet cleaning tests in the University of Utah Laminar Entrained Flow Reactor to determine the bond strength between an ash deposit to a metal plate, as well as implementing planned equipment modifications to the University of Utah Laminar Entrained Flow Reactor and the one ton per day, pressurized Pilot Scale Gasifier; • performing Computational Fluid Dynamic modeling of industrially relevant syngas cooler configurations to develop a better

  19. Feedstock Pathways for Bio-oil and Syngas Conversi (Technical...

    Office of Scientific and Technical Information (OSTI)

    Feedstock Pathways for Bio-oil and Syngas Conversi Citation Details In-Document Search Title: Feedstock Pathways for Bio-oil and Syngas Conversi You are accessing a document ...

  20. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Syngas Upgrading to Hydrocarbon Fuels Technology Pathway Syngas Upgrading to Hydrocarbon Fuels Technology Pathway This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates

  1. Syngas Generator Use for Retrofit DPF Active Regeneration on a Medium Duty

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Truck | Department of Energy Generator Use for Retrofit DPF Active Regeneration on a Medium Duty Truck Syngas Generator Use for Retrofit DPF Active Regeneration on a Medium Duty Truck Syngas enables low temperature in-use active regeneration of DPFs based on real-world data from a vehicle tested for over 1,000 hours deer09_towgood.pdf (186.5 KB) More Documents & Publications Characterizing Test Methods and Emissions Reduction Performance of In-Use Diesel Retrofit Technologies from the

  2. Mixed conducting membranes for syngas production

    DOE Patents [OSTI]

    Dyer, Paul Nigel; Carolan, Michael Francis; Butt, Darryl; Van Doorn, Rene Hendrick Elias; Cutler, Raymond Ashton

    2002-01-01

    This invention presents a new class of multicomponent metallic oxides which are particularly suited toward use in fabricating components used in processes for producing syngas. The non-stoichiometric, A-site rich compositions of the present invention are represented by the formula (Ln.sub.x Ca.sub.1-x).sub.y FeO.sub.3-.delta. wherein Ln is La or a mixture of lanthanides comprising La, and wherein 1.0>x>0.5, 1.1.gtoreq.y>1.0 and .delta. is a number which renders the composition of matter charge neutral. Solid-state membranes formed from these compositions provide a favorable balance of oxygen permeance and resistance to degradation when employed in processes for producing syngas. This invention also presents a process for making syngas which utilizes such membranes.

  3. Reactor water cleanup system

    DOE Patents [OSTI]

    Gluntz, Douglas M.; Taft, William E.

    1994-01-01

    A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling.

  4. Reactor water cleanup system

    DOE Patents [OSTI]

    Gluntz, D.M.; Taft, W.E.

    1994-12-20

    A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

  5. Cleanup Sites | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cleanup Sites Cleanup Sites Center Map As the largest environmental cleanup program in the world, EM has been charged with the responsibility of cleaning up 107 sites across the country whose area is equal to the combined area of Rhode Island and Delaware. To date, EM has made substantial progress in nearly every area of nuclear waste cleanup and completed cleanup at 91 of these sites. The "active" sites continue to have ongoing cleanup projects under EM's purview. Use the interactive

  6. EA-1867: Final Environmental Assessment

    Broader source: Energy.gov [DOE]

    RTI International Scale-Up of High-Temperature Syngas Cleanup and Carbon Capture and Sequestration Technologies, Polk County, Florida

  7. DRAFT Central Plateau Cleanup Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Matt McCormick, DOE-RL Hanford Advisory Board Committee of the Whole Meeting May 12, 2010 Proposed Tri-Party Agreement Changes to Central Plateau Cleanup Work 2 Purpose * Provide overview of the proposed TPA change packages - Central Plateau cleanup - Mixed low-level and transuranic mixed waste milestones (M-091 Series) Proposed Central Plateau Cleanup Milestones 3 4 Proposed TPA Changes for Comprehensive Central Plateau Cleanup Approach Overview - Proposed TPA Changes for Comprehensive Central

  8. Cleanup Sites | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sites Cleanup Sites The 33,500-acre Oak Ridge Reservation, outlined in red, contains three primary cleanup areas-- the East Tennessee Technology Park, Oak Ridge National Laboratory, and Y-12 National Security Complex. The 33,500-acre Oak Ridge Reservation, outlined in red, contains three primary cleanup areas-- the East Tennessee Technology Park, Oak Ridge National Laboratory, and Y-12 National Security Complex. Oak Ridge has three primary cleanup sites within the Oak Ridge Reservation-the Oak

  9. Environmental Cleanup | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Cleanup Environmental Cleanup Learn more about the history, cleanup activities and possible future uses of the Hanford Site, a 586-square-mile government site in southeast Washington State. | Video courtesy of the Energy Department. The Energy Department is committed to a safe, complete cleanup of the environmental legacy of five decades of government-sponsored nuclear weapons development and nuclear energy research. As part of this mission, we safely and cost-effectively transport

  10. SIMULTANEOUS PRODUCTION OF HIGH-PURITY HYDROGEN AND SEQUESTRATION-READY CO2 FROM SYNGAS

    SciTech Connect (OSTI)

    Linda Denton; Hana Lorethova; Tomasz Wiltowski; Court Moorefield; Parag Kulkarni; Vladimir Zamansky; Ravi Kumar

    2003-12-01

    This final report summarizes the progress made on the program ''Simultaneous Production of High-Purity Hydrogen and Sequestration-Ready CO{sub 2} from Syngas (contract number DE-FG26-99FT40682)'', during October 2000 through September of 2003. GE Energy and Environmental Research (GE-EER) and Southern Illinois University (SIU) at Carbondale conducted the research work for this program. This program addresses improved methods to efficiently produce simultaneous streams of high-purity hydrogen and separated carbon dioxide from synthesis gas (syngas). The syngas may be produced through either gasification of coal or reforming of natural gas. The process of production of H{sub 2} and separated CO{sub 2} utilizes a dual-bed reactor and regenerator system. The reactor produces hydrogen and the regenerator produces separated CO{sub 2}. The dual-bed system can be operated under either a circulating fluidized-bed configuration or a cyclic fixed-bed configuration. Both configurations were evaluated in this project. The experimental effort was divided into lab-scale work at SIU and bench-scale work at GE-EER. Tests in a lab-scale fluidized bed system demonstrated the process for the conversion of syngas to high purity H{sub 2} and separated CO{sub 2}. The lab-scale system generated up to 95% H{sub 2} (on a dry basis). Extensive thermodynamic analysis of chemical reactions between the syngas and the fluidized solids determined an optimum range of temperature and pressure operation, where the extent of the undesirable reactions is minimum. The cycling of the process between hydrogen generation and oxygen regeneration has been demonstrated. The fluidized solids did not regenerate completely and the hydrogen purity in the reuse cycle dropped to 70% from 95% (on a dry basis). Changes in morphology and particle size may be the most dominant factor affecting the efficiency of the repeated cycling between hydrogen production and oxygen regeneration. The concept of simultaneous

  11. FEEDSTOCK-FLEXIBLE REFORMER SYSTEM (FFRS) FOR SOLID OXIDE FUEL CELL (SOFC)- QUALITY SYNGAS

    SciTech Connect (OSTI)

    Kelly Jezierski; Andrew Tadd; Johannes Schwank; Roland Kibler; David McLean; Mahesh Samineni; Ryan Smith; Sameer Parvathikar; Joe Mayne; Tom Westrich; Jerry Mader; F. Michael Faubert

    2010-07-30

    The U.S. Department of Energy National Energy Technology Laboratory funded this research collaboration effort between NextEnergy and the University of Michigan, who successfully designed, built, and tested a reformer system, which produced highquality syngas for use in SOFC and other applications, and a novel reactor system, which allowed for facile illumination of photocatalysts. Carbon and raw biomass gasification, sulfur tolerance of non-Platinum Group Metals (PGM) based (Ni/CeZrO2) reforming catalysts, photocatalysis reactions based on TiO2, and mild pyrolysis of biomass in ionic liquids (ILs) were investigated at low and medium temperatures (primarily 450 to 850 C) in an attempt to retain some structural value of the starting biomass. Despite a wide range of processes and feedstock composition, a literature survey showed that, gasifier products had narrow variation in composition, a restriction used to develop operating schemes for syngas cleanup. Three distinct reaction conditions were investigated: equilibrium, autothermal reforming of hydrocarbons, and the addition of O2 and steam to match the final (C/H/O) composition. Initial results showed rapid and significant deactivation of Ni/CeZrO2 catalysts upon introduction of thiophene, but both stable and unstable performance in the presence of sulfur were obtained. The key linkage appeared to be the hydrodesulfurization activity of the Ni reforming catalysts. For feed stoichiometries where high H2 production was thermodynamically favored, stable, albeit lower, H2 and CO production were obtained; but lower thermodynamic H2 concentrations resulted in continued catalyst deactivation and eventual poisoning. High H2 levels resulted in thiophene converting to H2S and S surface desorption, leading to stable performance; low H2 levels resulted in unconverted S and loss in H2 and CO production, as well as loss in thiophene conversion. Bimetallic catalysts did not outperform Ni-only catalysts, and small Ni particles were

  12. Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report

    SciTech Connect (OSTI)

    Dayton, David C

    2010-03-24

    Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested

  13. WIPP Accelerating Cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ACCELERATING CLEANUP: PATHS TO CLOSURE CARLSBAD AREA OFFICE JUNE 1998 I. Operations/Field Overview CAO Mission The mission of the Carlsbad Area Office (CAO) is to protect human health and the environment by opening and operating the Waste Isolation Pilot Plant (WIPP) for safe disposal of transuranic (TRU) waste and by establishing an effective system for management of TRU waste from generation to disposal. It includes personnel assigned to CAO, WIPP site operations, transportation, and other

  14. Syngas into Fuel: Optofluidic Solar Concentrators

    SciTech Connect (OSTI)

    2010-10-01

    Broad Funding Opportunity Announcement Project: Ohio State has developed an iron-based material and process for converting syngas—a synthetic gas mixture—into electricity, H2, and/or liquid fuel with zero CO2 emissions. Traditional carbon capture methods use chemical solvents or special membranes to separate CO2 from the gas exhaust from coal-fired power plants. Ohio State’s technology uses an iron-based oxygen carrier to generate CO2 and H2 from syngas in separate, pure product streams by means of a circulating bed reactor configuration. The end products of the system are H2, electricity, and/or liquid fuel, all of which are useful sources of power that can come from coal or syngas derived from biomass. Ohio State is developing a high-pressure pilot-scale unit to demonstrate this process at the National Carbon Capture Center.

  15. New Catalyst Boosts Selective Formation of Olefins from Syngas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Catalyst Boosts Selective Formation of Olefins from Syngas New Catalyst Boosts Selective Formation of Olefins from Syngas Print Wednesday, 10 August 2016 00:00 Experiments at the ALS have helped to explain how a new catalyst significantly boosts the formation of light olefin molecules-important building blocks in the petrochemical industry-from a basic gas mixture called syngas (synthesis gas). A research team from China recently developed the nanocomposite catalyst and used ambient-pressure

  16. Catalysts for Syngas-Derived Alcohol Synthesis - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Catalysts for Syngas-Derived Alcohol Synthesis Improves the conversion of syngas from natural gas, coal, or biomass National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication Pyrochlore-Based Catalysts for Syngas-Derived Alcohol Synthesis (294 KB) Technology Marketing Summary This technology provides an advantageous means to

  17. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (‘syngas’) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  18. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathway This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion...

  19. Catalysts for converting syngas into liquid hydrocarbons and methods thereof

    DOE Patents [OSTI]

    Yu, Fei; Yan, Qiangu; Batchelor, William

    2016-03-15

    The presently-disclosed subject matter includes methods for producing liquid hydrocarbons from syngas. In some embodiments the syngas is obtained from biomass and/or comprises a relatively high amount of nitrogen and/or carbon dioxide. In some embodiments the present methods can convert syngas into liquid hydrocarbons through a one-stage process. Also provided are catalysts for producing liquid hydrocarbons from syngas, wherein the catalysts include a base material, a transition metal, and a promoter. In some embodiments the base material includes a zeolite-iron material or a cobalt-molybdenum carbide material. In still further embodiments the promoter can include an alkali metal.

  20. Bioenergy Technologies Office Conversion R&D Pathway: Syngas...

    Office of Environmental Management (EM)

    Syngas Upgrading to Hydrocarbon Fuels Bioenergy Technologies Office Conversion R&D ... chosen to convert biomass into hydrocarbon fuels by the Bioenergy Technologies Office. ...

  1. HIGH EFFICIENCY SYNGAS GENERATION (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    HIGH EFFICIENCY SYNGAS GENERATION Citation Details ... Conventional auto-thermal or Partial Oxidation (POX) ... However POX requires pure oxygen, which consumes power and ...

  2. he Hanford Story Tank Waste Cleanup | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    he Hanford Story Tank Waste Cleanup he Hanford Story Tank Waste Cleanup Addthis Description The Hanford Story Tank Waste Cleanup

  3. 2015 DOE National Cleanup Workshop

    Broader source: Energy.gov [DOE]

    Photos from the 2015 DOE National Cleanup Workshop held on Sept. 29 & 30, 2015, in the Washington, D.C. area.

  4. Polk power station syngas cooling system

    SciTech Connect (OSTI)

    Jenkins, S.D.

    1995-01-01

    Tampa Electric Company (TEC) is in the site development and construction phase of the new Polk Power Station Unit No. 1. This will be the first unit at a new site and will use Integrated Gasification Combined Cycle (IGCC) Technology. The unit will utilize Texaco`s oxygen-blown, entrained-flow coal gasification, along with combined cycle power generation, to produce nominal 260MW. Integral to the gasification process is the syngas cooling system. The design, integration, fabrication, transportation, and erection of this equipment have provided and continue to provide major challenges for this project.

  5. From Cleanup to Stewardship | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    From Cleanup to Stewardship From Cleanup to Stewardship From Cleanup to Stewardship, a Companion Report to Accelerating Cleanup: Paths to Closure and Background Information Supporting the Scoping Process Required for the 1998 PEIS Settlement Study. Long-term stewardship was expected to be needed at more than 100 DOE sites after EM completed cleanup of the waste and contamination resulting from nuclear research and nuclear weapons production over the past 50 years. From Cleanup to Stewardship

  6. Nuclear radiation cleanup and uranium prospecting (Patent) |...

    Office of Scientific and Technical Information (OSTI)

    Nuclear radiation cleanup and uranium prospecting Citation Details In-Document Search Title: Nuclear radiation cleanup and uranium prospecting Apparatus, systems, and methods for...

  7. Nuclear radiation cleanup and uranium prospecting (Patent) |...

    Office of Scientific and Technical Information (OSTI)

    Nuclear radiation cleanup and uranium prospecting Citation Details In-Document Search Title: Nuclear radiation cleanup and uranium prospecting You are accessing a document from...

  8. Independent Oversight Activity Report, Idaho Cleanup Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Idaho Cleanup Project - November 2013 Independent Oversight Activity Report, Idaho Cleanup Project - November 2013 November 2013 Pre-restart Visit to the Integrated Waste Treatment...

  9. New Contract Helps Portsmouth GDP Cleanup

    Broader source: Energy.gov [DOE]

    To accelerate the Portsmouth GDP cleanup efforts left over from the Cold War, the Department of Energy made a huge step forward in our nuclear environmental cleanup efforts.

  10. Environmental Remediation program completes legacy mercury cleanup...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stories Legacy slope-side cleanup Environmental Remediation program completes legacy mercury cleanup near Smith's Marketplace Los Alamos National Laboratory performed a ...

  11. Petrochemicals from coal-derived syngas

    SciTech Connect (OSTI)

    Sardesai, A.; Lee, S.

    1996-12-31

    The development of the Liquid Phase Dimethyl Ether (LPDME) process has established a means to effectively convert CO-rich syngas to dimethyl ether (DME) in a mechanically agitated slurry reactor. By operating in a dual catalyst mode, in-situ produced methanol may be converted to DME, thereby alleviating the chemical equilibrium limitation imposed on the methanol synthesis reaction. As a result, higher syngas conversions and methyl productivities are seen over methanol synthesis alone. This effective route to DME production over methanol has led to the development of conversion technologies based on a DME feedstock. Oxygenates, in particular, ethers and their precursors, are very important as potential clean fuel additives and have been postulated through vinylation/hydrogenation and oxidative coupling reactions. Specialty chemicals such as methyl acetate and acetic acid have widescale industrial importance in the conversion to ethanol from a non-agricultural feedstock. Vapor phase oxidative dimerization of DME over tin based catalysts produced precursors of ethylene glycol. Finally, DME has been extensively used as a feedstock for hydrocarbon synthesis including olefins, paraffins and gasoline range hydrocarbons, over zeolite based catalysts with a 46% increase in product selectivity over methanol. The efficient production of DME in the liquid phase has given it widescale industrial significance as a potential replacement for methanol and as a keystone for more important petrochemicals.

  12. Site Cleanup | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Unlike many EM cleanup sites, Oak Ridge has numerous ongoing missions aside from EM. The ... is increased safety and more real estate to expand missions and research at the site. ...

  13. Environmental Management (EM) Cleanup Projects

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2008-09-24

    The guide supports DOE O 413.3A, Program and Project Management for the Acquisition of Capital Assets, and provides guidance on environmental management cleanup projects. Canceled by DOE N 251.105.

  14. Oak Ridge National Laboratory Cleanup

    Office of Energy Efficiency and Renewable Energy (EERE)

    This fact sheet provides an update on all of the current cleanup projects at the site, and it also lists the major projects that were completed at the Oak Ridge National Laboratory.

  15. East Tennessee Technology Park Cleanup

    Office of Energy Efficiency and Renewable Energy (EERE)

    This fact sheet provides an update on all of the current cleanup projects at the site, and it also lists the major projects that were completed at the East Tennessee Technology Park.

  16. U-PLANT GEOGRAPHIC ZONE CLEANUP PROTOTYPE

    SciTech Connect (OSTI)

    ROMINE, L.D.

    2006-02-01

    The U Plant geographic zone (UPZ) occupies 0.83 square kilometers on the Hanford Site Central Plateau (200 Area). It encompasses the U Plant canyon (221-U Facility), ancillary facilities that supported the canyon, soil waste sites, and underground pipelines. The UPZ cleanup initiative coordinates the cleanup of the major facilities, ancillary facilities, waste sites, and contaminated pipelines (collectively identified as ''cleanup items'') within the geographic zone. The UPZ was selected as a geographic cleanup zone prototype for resolving regulatory, technical, and stakeholder issues and demonstrating cleanup methods for several reasons: most of the area is inactive, sufficient characterization information is available to support decisions, cleanup of the high-risk waste sites will help protect the groundwater, and the zone contains a representative cross-section of the types of cleanup actions that will be required in other geographic zones. The UPZ cleanup demonstrates the first of 22 integrated zone cleanup actions on the Hanford Site Central Plateau to address threats to groundwater, the environment, and human health. The UPZ contains more than 100 individual cleanup items. Cleanup actions in the zone will be undertaken using multiple regulatory processes and decision documents. Cleanup actions will include building demolition, waste site and pipeline excavation, and the construction of multiple, large engineered barriers. In some cases, different cleanup actions may be taken at item locations that are immediately adjacent to each other. The cleanup planning and field activities for each cleanup item must be undertaken in a coordinated and cohesive manner to ensure effective execution of the UPZ cleanup initiative. The UPZ zone cleanup implementation plan (ZCIP) was developed to address the need for a fundamental integration tool for UPZ cleanup. As UPZ cleanup planning and implementation moves forward, the ZCIP is intended to be a living document that will

  17. Methods and systems for producing syngas

    DOE Patents [OSTI]

    Hawkes, Grant L; O'Brien, James E; Stoots, Carl M; Herring, J. Stephen; McKellar, Michael G; Wood, Richard A; Carrington, Robert A; Boardman, Richard D

    2013-02-05

    Methods and systems are provided for producing syngas utilizing heat from thermochemical conversion of a carbonaceous fuel to support decomposition of at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells. Simultaneous decomposition of carbon dioxide and water or steam by one or more solid-oxide electrolysis cells may be employed to produce hydrogen and carbon monoxide. A portion of oxygen produced from at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells is fed at a controlled flow rate in a gasifier or combustor to oxidize the carbonaceous fuel to control the carbon dioxide to carbon monoxide ratio produced.

  18. Upper Los Alamos Canyon Cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Upper Los Alamos Canyon Cleanup Upper Los Alamos Canyon Cleanup The Upper Los Alamos Canyon Project involves cleaning up hazardous materials left over from some of the Laboratory's earliest activities. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Located along Los Alamos Canyon from 7th Street to the Pajarito Ski Hill, the Upper Los Alamos Canyon Project involves examining sites in present and former Laboratory

  19. Central Plateau Inner Area Cleanup Principles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inner Area Cleanup Principles * Cleanup Principles are the initial conditions and approaches to developing cleanup decisions in the Inner Area * These Principles will guide the development of the Remedial Investigations and Feasibility Studies (RI/FS) * These Principles will help DOE produce RI/FS documents to better meet regulator expectations * Formal agreement on cleanup, as influenced by these Principles, does not happen until the Record of Decision What are Cleanup Principles? 2 * The Inner

  20. New Catalyst Boosts Selective Formation of Olefins from Syngas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Catalyst Boosts Selective Formation of Olefins from Syngas Print Experiments at the ALS have helped to explain how a new catalyst significantly boosts the formation of light olefin molecules-important building blocks in the petrochemical industry-from a basic gas mixture called syngas (synthesis gas). A research team from China recently developed the nanocomposite catalyst and used ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) to investigate the chemical changes occurring at the

  1. New Catalyst Boosts Selective Formation of Olefins from Syngas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Catalyst Boosts Selective Formation of Olefins from Syngas Print Experiments at the ALS have helped to explain how a new catalyst significantly boosts the formation of light olefin molecules-important building blocks in the petrochemical industry-from a basic gas mixture called syngas (synthesis gas). A research team from China recently developed the nanocomposite catalyst and used ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) to investigate the chemical changes occurring at the

  2. New Catalyst Boosts Selective Formation of Olefins from Syngas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Catalyst Boosts Selective Formation of Olefins from Syngas Print Experiments at the ALS have helped to explain how a new catalyst significantly boosts the formation of light olefin molecules-important building blocks in the petrochemical industry-from a basic gas mixture called syngas (synthesis gas). A research team from China recently developed the nanocomposite catalyst and used ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) to investigate the chemical changes occurring at the

  3. New Catalyst Boosts Selective Formation of Olefins from Syngas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalyst Boosts Selective Formation of Olefins from Syngas Print Experiments at the ALS have helped to explain how a new catalyst significantly boosts the formation of light olefin molecules-important building blocks in the petrochemical industry-from a basic gas mixture called syngas (synthesis gas). A research team from China recently developed the nanocomposite catalyst and used ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) to investigate the chemical changes occurring at the

  4. New Catalyst Boosts Selective Formation of Olefins from Syngas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Catalyst Boosts Selective Formation of Olefins from Syngas Print Experiments at the ALS have helped to explain how a new catalyst significantly boosts the formation of light olefin molecules-important building blocks in the petrochemical industry-from a basic gas mixture called syngas (synthesis gas). A research team from China recently developed the nanocomposite catalyst and used ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) to investigate the chemical changes occurring at the

  5. A Hybrid Catalytic Route to Fuels from Biomass Syngas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 21, 2013 Gasification Mike Schultz, PhD., Project PI A Hybrid Catalytic Route to Fuels from Biomass Syngas Project Goal A hybrid biorefinery design that enables the production of jet fuel and other hydrocarbon fuels from waste biomass System Integration, Optimization and Analysis Integration Gasification & Syngas Conditioning Fermentation & Alcohol Recovery Catalysis Catalysis Gasoline Jet Fuel Diesel Butadiene MEK EtOH 2,3BD Wood Stover Switchgrass Improve Economics and Process

  6. Accelerating cleanup: Paths to closure

    SciTech Connect (OSTI)

    1998-06-01

    This report describes the status of Environmental Management`s (EM`s) cleanup program and a direction forward to complete achievement of the 2006 vision. Achieving the 2006 vision results in significant benefits related to accomplishing EM program objectives. As DOE sites accelerate cleanup activities, risks to public health, the environment, and worker safety and health are all reduced. Finding more efficient ways to conduct work can result in making compliance with applicable environmental requirements easier to achieve. Finally, as cleanup activities at sites are completed, the EM program can focus attention and resources on the small number of sites with more complex cleanup challenges. Chapter 1 describes the process by which this report has been developed and what it hopes to accomplish, its relationship to the EM decision-making process, and a general background of the EM mission and program. Chapter 2 describes how the site-by-site projections were constructed, and summarizes, for each of DOE`s 11 Operations/Field Offices, the projected costs and schedules for completing the cleanup mission. Chapter 3 presents summaries of the detailed cleanup projections from three of the 11 Operations/Field Offices: Rocky Flats (Colorado), Richland (Washington), and Savannah River (South Carolina). The remaining eight Operations/Field Office summaries are in Appendix E. Chapter 4 reviews the cost drivers, budgetary constraints, and performance enhancements underlying the detailed analysis of the 353 projects that comprise EM`s accelerated cleanup and closure effort. Chapter 5 describes a management system to support the EM program. Chapter 6 provides responses to the general comments received on the February draft of this document.

  7. Nanoparticle scaffolds for syngas-fed solid oxide fuel cells

    SciTech Connect (OSTI)

    Boldrin, Paul; Ruiz-Trejo, Enrique; Yu, Jingwen; Gruar, Robert I.; Tighe, Christopher J.; Chang, Kee-Chul; Ilavsky, Jan; Darr, Jawwad A.; Brandon, Nigel

    2014-12-17

    Incorporation of nanoparticles into devices such as solid oxide fuel cells (SOFCs) may provide benefits such as higher surface areas or finer control over microstructure. However, their use with traditional fabrication techniques such as screen-printing is problematic. Here, we show that mixing larger commercial particles with nanoparticles allows traditional ink formulation and screen-printing to be used while still providing benefits of nanoparticles such as increased porosity and lower sintering temperatures. SOFC anodes were produced by impregnating ceria–gadolinia (CGO) scaffolds with nickel nitrate solution. The scaffolds were produced from inks containing a mixture of hydrothermally-synthesised nanoparticle CGO, commercial CGO and polymeric pore formers. The scaffolds were heat-treated at either 1000 or 1300 °C, and were mechanically stable. In situ ultra-small X-ray scattering (USAXS) shows that the nanoparticles begin sintering around 900–1000 °C. Analysis by USAXS and scanning electron microscopy (SEM) revealed that the low temperature heat-treated scaffolds possessed higher porosity. Impregnated scaffolds were used to produce symmetrical cells, with the lower temperature heat-treated scaffolds showing improved gas diffusion, but poorer charge transfer. Using these scaffolds, lower temperature heat-treated cells of Ni–CGO/200 μm YSZ/CGO-LSCF performed better at 700 °C (and below) in hydrogen, and performed better at all temperatures using syngas, with power densities of up to 0.15 W cm-2 at 800 °C. This approach has the potential to allow the use of a wider range of materials and finer control over microstructure.

  8. Nanoparticle scaffolds for syngas-fed solid oxide fuel cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boldrin, Paul; Ruiz-Trejo, Enrique; Yu, Jingwen; Gruar, Robert I.; Tighe, Christopher J.; Chang, Kee-Chul; Ilavsky, Jan; Darr, Jawwad A.; Brandon, Nigel

    2014-12-17

    Incorporation of nanoparticles into devices such as solid oxide fuel cells (SOFCs) may provide benefits such as higher surface areas or finer control over microstructure. However, their use with traditional fabrication techniques such as screen-printing is problematic. Here, we show that mixing larger commercial particles with nanoparticles allows traditional ink formulation and screen-printing to be used while still providing benefits of nanoparticles such as increased porosity and lower sintering temperatures. SOFC anodes were produced by impregnating ceria–gadolinia (CGO) scaffolds with nickel nitrate solution. The scaffolds were produced from inks containing a mixture of hydrothermally-synthesised nanoparticle CGO, commercial CGO and polymericmore » pore formers. The scaffolds were heat-treated at either 1000 or 1300 °C, and were mechanically stable. In situ ultra-small X-ray scattering (USAXS) shows that the nanoparticles begin sintering around 900–1000 °C. Analysis by USAXS and scanning electron microscopy (SEM) revealed that the low temperature heat-treated scaffolds possessed higher porosity. Impregnated scaffolds were used to produce symmetrical cells, with the lower temperature heat-treated scaffolds showing improved gas diffusion, but poorer charge transfer. Using these scaffolds, lower temperature heat-treated cells of Ni–CGO/200 μm YSZ/CGO-LSCF performed better at 700 °C (and below) in hydrogen, and performed better at all temperatures using syngas, with power densities of up to 0.15 W cm-2 at 800 °C. This approach has the potential to allow the use of a wider range of materials and finer control over microstructure.« less

  9. Particulate hot gas stream cleanup technical issues

    SciTech Connect (OSTI)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  10. Novel syngas-based process for methyl methacrylate

    SciTech Connect (OSTI)

    Gogate, M.R.; Spivey, J.J.; Zoeller, J.R.; Choi, G.N.; Tam, S.S.; Tischer, R.E.; Srivastava, R.D.

    1996-12-31

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel are developing a novel process for synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the U.S. Department of Energy, Pittsburgh Energy Technology Center. This three-step process consists of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Eastman has focused on the research on propionate synthesis step. The resultant Mo catalysts work efficiently at much less severe conditions (170{degrees}C and 30 atm) than the conventional Ni catalysts (270{degrees}C and 180 atm). Bechtel has performed an extensive cost analysis, which shows that Eastman`s propionate synthesis process is competitive with other technologies to produce the anhydride. In the second step, RTI and Eastman have developed active and stable V-SI-P and Ta metal oxide catalysts for condensation reactions of propionates with formaldehyde. RTI has demonstrated a novel correlation among the catalyst acid-base properties, condensation reaction yield, and long-term catalyst activity. Current research focuses on enhancing the condensation reaction yields, acid-base properties, in situ condensation in a high- temperature, high-pressure (HTHP) slurry reactor, and alternate formaldehyde feedstocks. Based on Eastman and RTI laboratory reactor operating data, a cost estimate is also being developed for the integrated process.

  11. Voluntary Protection Program Onsite Review, Idaho Cleanup Project...

    Energy Savers [EERE]

    Idaho Cleanup Project- June 2007 Voluntary Protection Program Onsite Review, Idaho Cleanup Project- June 2007 June 2007 Evaluation to determine whether the Idaho Cleanup Project is...

  12. West Valley Demonstration Project Site Cleanup By the Numbers...

    Office of Environmental Management (EM)

    West Valley Demonstration Project Site Cleanup By the Numbers West Valley Demonstration Project Site Cleanup By the Numbers West Valley Demonstration Project Site Cleanup By the ...

  13. Radiological cleanup of Enewetak Atoll

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    For 8 years, from 1972 until 1980, the United States planned and carried out the radiological cleanup, rehabilitation, and resettlement of Enewetak Atoll in the Marshall Islands. This documentary records, from the perspective of DOD, the background, decisions, actions, and results of this major national and international effort. The documentary is designed: First, to provide a historical document which records with accuracy this major event in the history of Enewetak Atoll, the Marshall Islands, the Trust Territory of the Pacific Islands, Micronesia, the Pacific Basin, and the United States. Second, to provide a definitive record of the radiological contamination of the Atoll. Third, to provide a detailed record of the radiological exposure of the cleanup forces themselves. Fourth, to provide a useful guide for subsequent radiological cleanup efforts elsewhere.

  14. Argonne National Lab Cleanup schedule

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Takes Steps to Complete Clean-Up of Argonne by 2003; Schedule for Shipping Waste to WIPP is 'Good News' for Illinois CARLSBAD, N.M., May 15, 2000 - The U.S. Department of Energy (DOE) reinforced plans to complete the clean-up of its Argonne National Laboratory-East site in Illinois by 2003 by accelerating its schedule for shipping transuranic waste to DOE's permanent disposal site in New Mexico. Previously, the shipments were not expected to begin before 2003. Under the accelerated schedule,

  15. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    BEN W.-L. JANG; GERALD N. CHOI; JAMES J. SPIVEY; JOSPEH R. ZOELLER; RICHARD D. COLBERG

    1999-01-20

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. The research team has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, we are currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter(Oct.-Dec./98), we have investigated the condensation between methyl propionate and formaldehyde (MP/HCHO=4.5/1) at various reaction temperatures(280-360EC) over 5%, 10%, and 20% Nb O /SiO catalysts. The conversion of HCHO increases with reaction 2 5 2 temperature and niobium loading. MMA+MAA selectivity goes through a maximum with the temperature over both 10% and 20% Nb O /SiO . The selectivities to MMA+MAA are 67.2%, 2 5 2 72.3%and 58.1% at 320EC over 5%, 10%, 20% Nb O /SiO , respectively. However, the 2 5 2 conversion of formaldehyde decreases rapidly with time on stream. The results suggest that silica supported niobium catalysts are active and selective for condensation of MP with HCHO, but deactivation needs to be minimized for the consideration of commercial application. We have preliminarily investigated the partial oxidation of dimethyl ether(DME) over 5% Nb O /SiO catalyst. Reactant gas mixture of 0.1% DME, 0.1% O and balance nitrogen is 2 5 2 2 studied with temperature ranging from 200°C to 500°C. The conversion of DME first increases with temperature reaching an maximum at 400°C then decreases. The selectivity to HCHO also increases with reaction temperature first. But the selectivity to HCHO decreases at temperature above 350

  16. Stimulus Funding Will Accelerate Cleanup In Idaho

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CLEANUP PROJECT ARRA FACT SHEET 1119 Kb Energy Secretary Chu Announces 6 Billion in Recovery Act Funding for Environmental Cleanup 88 Kb Editorial Date March 31, 2008 By Bradley...

  17. Production of methane-rich syngas from hydrocarbon fuels using multi-functional catalyst/capture agent

    DOE Patents [OSTI]

    Siefert, Nicholas S; Shekhawat, Dushyant; Berry, David A; Surdoval, Wayne A

    2014-12-30

    The disclosure provides a gasification process for the production of a methane-rich syngas at temperatures exceeding 700.degree. C. through the use of an alkali hydroxide MOH, using a gasification mixture comprised of at least 0.25 moles and less than 2 moles of water for each mole of carbon, and at least 0.15 moles and less than 2 moles of alkali hydroxide MOH for each mole of carbon. These relative amounts allow the production of a methane-rich syngas at temperatures exceeding 700.degree. C. by enabling a series of reactions which generate H.sub.2 and CH.sub.4, and mitigate the reforming of methane. The process provides a methane-rich syngas comprised of roughly 20% (dry molar percentage) CH.sub.4 at temperatures above 700.degree. C., and may effectively operate within an IGFC cycle at reactor temperatures between 700-900.degree. C. and pressures in excess of 10 atmospheres.

  18. National Cleanup Workshops | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Cleanup Workshops National Cleanup Workshops The Energy Communities Alliance (ECA), in cooperation with the Department of Energy (DOE) and the Energy Facility Contractors Group (EFCOG), held the first National Cleanup Workshop Sept. 29 and 30, 2015, in the Washington, D.C. area. The workshop brought together senior DOE executives, officials from DOE sites, industry executives, and other stakeholders to discuss EM's progress in the cleanup of the environmental legacy of the nation's

  19. Washington Closure Hanford: Cleanup Progress Along Hanford's...

    Broader source: Energy.gov (indexed) [DOE]

    Sax, President, Washington Closure Hanford. Washington Closure Hanford: Cleanup Progress Along Hanford's River Corridor More Documents & Publications 2014 Congressional Nuclear...

  20. 2016 National Cleanup Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 National Cleanup Workshop 2016 National Cleanup Workshop 2016 National Cleanup Workshop The Energy Communities Alliance (ECA) will be holding the 2016 National Cleanup Workshop Sept. 14-15, 2016, at the Hilton Alexandria Mark Center in Alexandria, Va. Cooperating organizations for the event include the Department of Energy (DOE) and the Energy Facility Contractors Group (EFCOG). The workshop will bring together senior DOE executives, officials from DOE sites, industry executives, and other

  1. Method for regeneration and activity improvement of syngas conversion catalyst

    DOE Patents [OSTI]

    Lucki, Stanley J.; Brennan, James A.

    1980-01-01

    A method is disclosed for the treatment of single particle iron-containing syngas (synthes.s gas) conversion catalysts comprising iron, a crystalline acidic aluminosilicate zeolite having a silica to alumina ratio of at least 12, a pore size greater than about 5 Angstrom units and a constraint index of about 1-12 and a matrix. The catalyst does not contain promoters and the treatment is applicable to either the regeneration of said spent single particle iron-containing catalyst or for the initial activation of fresh catalyst. The treatment involves air oxidation, hydrogen reduction, followed by a second air oxidation and contact of the iron-containing single particle catalyst with syngas prior to its use for the catalytic conversion of said syngas. The single particle iron-containing catalysts are prepared from a water insoluble organic iron compound.

  2. Synthesis of Methyl Methacrylate From Coal-Derived Syngas

    SciTech Connect (OSTI)

    Ben W.-L. Jang; Gerald N. Choi; James J. Spivey; Jospeh R. Zoeller; Richard D. Colberg; Samuel S. Tam

    1998-07-27

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter(April-June, 1998), RTI has modified the reactor system including a new preheater and new temperature settings for the preheater. Continuous condensation of formaldehyde with propionic acid were carried out over 10% Nb O /SiO at 300°C without 2 5 2 interruption. Five activity and four regeneration cycles have been completed without plugging or material balance problems. The results show that 10% Nb O /SiO deactivates slowly with time 2 5 2 but can be regenerated, at least four times, to 100% of its original activity with 2% O in nitrogen 2 at 400°C. The cycles continue with consistent 90-95% of carbon balance. The reaction is scheduled to complete with 6 activity cycles and 5 regenerations. Used catalysts will be analyzed with TGA and XPS to determine bulk and surface coke content and coke properties. RTI will start the investigation of effects of propionic acid/formaldehyde ratio on reaction activity and product selectivity over 20% Nb O /SiO catalysts.

  3. Zero Emissions Coal Syngas Oxygen Turbo Machinery

    SciTech Connect (OSTI)

    Dennis Horazak

    2010-12-31

    Siemens Energy, Inc. (formerly Siemens Westinghouse Power Corporation) worked with Clean Energy Systems and Florida Turbine Technologies to demonstrate the commercial feasibility of advanced turbines for oxy-fuel based power systems that discharge negligible CO{sub 2} into the atmosphere. The approach builds upon ultra supercritical steam turbine and advanced gas turbine technology with the goal of attaining plant efficiencies above 50% in the 2015 timeframe. Conceptual designs were developed for baseline, near term, and long term oxy-fuel turbine cycles, representing commercial introductions of increasingly advanced thermal conditions and increasing exposure to steam-CO{sub 2} mixtures. An economic analysis and market demand study was performed by Science Applications International Corp. (SAIC), and indicated that long-term oxy-fuel turbine cycles start to look attractive in 2025 when the CO{sub 2} tax is assumed to reach $40/ ton, and by 2030 it has a clear advantage over both IGCC with sequestration and pulverized coal with sequestration. A separate risk analysis of the oxy-fuel combustor, HP turbine, re-heater, and IP turbine of the long-term cycle identified and categorized risks and proposed mitigation measures. In 2007 the program began to focus on a potential oxy-fuel turbine power generation demonstration project in the 2012 -13 time period while still maintaining a link to the requirements of the long-term oxy-syngas cycle. The SGT-900 turbine was identified as the best fit for modification into an intermediate pressure turbine (IPT) for this application. The base metals, bond coats, thermal barrier coatings (TBCs), and rotor materials used in the SGT-900 were tested for their ability to operate in the steam- CO{sub 2} environment of the oxy-fuel OFT-900. Test results indicated that these same materials would operate satisfactorily, and the plan, is to use SGT-900materials for the OFT-900. Follow-on programs for corrosion testing and evaluation of crack

  4. DRAFT Central Plateau Cleanup Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J.D. Dowell: DOE-RL John Price: Ecology Dennis Faulk: EPA October 9, 2012 2 River Corridor * 100 Area interim actions extended to - Incorporate 154 additional waste sites - Address prior extensive deep excavation of hexavalent chromium contamination * 100 Area decision documents - Extend 100 B/C decision documents schedule to enable collection of additional groundwater data for cleanup decision - Delay 100-N document several months to avoid overlap of public comment 3 River Corridor * 100 Area -

  5. Accelerated cleanup risk reduction

    SciTech Connect (OSTI)

    Knapp, R.B.; Aines, R.M.; Blake, R.G.; Copeland, A.B.; Newmark, R.L.; Tompson, A.F.B.

    1998-02-01

    There is no proven technology for remediating contaminant plume source regions in a heterogeneous subsurface. This project is an interdisciplinary effort to develop the requisite new technologies so that will be rapidly accepted by the remediation community. Our technology focus is hydrous pyrolysis/oxidation (HPO) which is a novel in situ thermal technique. We have expanded this core technology to leverage the action of steam injection and place an in situ microbial filter downstream to intercept and destroy the accelerated movement of contaminated groundwater. Most contaminant plume source regions, including the chlorinated solvent plume at LLNL, are in subsurface media characterized by a wide range in hydraulic conductivity. At LLNL, the main conduits for contaminant transport are buried stream channels composed of gravels and sands; these have a hydraulic conductivity in the range of 10{sup -1} to 10{sup -2} cm/s. Clay and silt units with a hydraulic conductivity of 10{sup -1} to 10{sup -6} cm/s bound these buried channels; these are barriers to groundwater movement and contain the highest contaminant concentrations in the source region. New remediation technologies are required because the current ones preferentially access the high conductivity units. HPO is an innovative process for the in situ destruction of contaminants in the entire subsurface. It operates by the injection of steam. We have demonstrated in laboratory experiments that many contaminants rapidly oxidize to harmless compounds at temperatures easily achieved by injecting steam, provided sufficient dissolved oxygen is present. One important challenge in a heterogeneous source region is getting heat, contaminants, and an oxidizing agent in the same place at the same time. We have used the NUFT computer program to simulate the cyclic injection of steam into a contaminated aquifer for design of a field demonstration. We used an 8 hour, steam/oxygen injection cycle followed by a 56 hour relaxation

  6. NOVEL SLURRY PHASE DIESEL CATALYSTS FOR COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Dr. Dragomir B. Bukur; Dr. Ketil Hanssen; Alec Klinghoffer; Dr. Lech Nowicki; Patricia O'Dowd; Dr. Hien Pham; Jian Xu

    2001-01-07

    This report describes research conducted to support the DOE program in novel slurry phase catalysts for converting coal-derived synthesis gas to diesel fuels. The primary objective of this research program is to develop attrition resistant catalysts that exhibit high activities for conversion of coal-derived syngas.

  7. Chemical Kinetics in Support of Syngas Turbine Combustion

    SciTech Connect (OSTI)

    Dryer, Frederick

    2007-07-31

    This document is the final report on an overall program formulated to extend our prior work in developing and validating kinetic models for the CO/hydrogen/oxygen reaction by carefully analyzing the individual and interactive behavior of specific elementary and subsets of elementary reactions at conditions of interest to syngas combustion in gas turbines. A summary of the tasks performed under this work are: 1. Determine experimentally the third body efficiencies in H+O{sub 2}+M = HO{sub 2}+M (R1) for CO{sub 2} and H{sub 2}O. 2. Using published literature data and the results in this program, further develop the present H{sub 2}/O{sub 2}/diluent and CO/H{sub 2}/O{sub 2}/diluent mechanisms for dilution with CO{sub 2}, H{sub 2}O and N{sub 2} through comparisons with new experimental validation targets for H{sub 2}-CO-O{sub 2}-N{sub 2} reaction kinetics in the presence of significant diluent fractions of CO{sub 2} and/or H{sub 2}O, at high pressures. (task amplified to especially address ignition delay issues, see below). 3. Analyze and demonstrate issues related to NOx interactions with syngas combustion chemistry (task amplified to include interactions of iron pentacarbonyl with syngas combustion chemistry, see below). 4. Publish results, including updated syngas kinetic model. Results are summarized in this document and its appendices. Three archival papers which contain a majority of the research results have appeared. Those results not published elsewhere are highlighted here, and will appear as part of future publications. Portions of the work appearing in the above publications were also supported in part by the Department of Energy under Grant No. DE-FG02-86ER-13503. As a result of and during the research under the present contract, we became aware of other reported results that revealed substantial differences between experimental characterizations of ignition delays for syngas mixtures and ignition delay predictions based upon homogenous kinetic modeling. We

  8. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    BEN W.-L. JANG; GERALD N. CHOI; JAMES J. SPIVEY; JOSPEH R. ZOELLER; RICHARD D. COLBERG

    1998-10-20

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter (July-September, 1998), the project team has completed the continuous condensation of formaldehyde with propionic acid over 10% Nb{sub 2}O{sub 5}/SiO{sub 2} at 300 C. Six activity and five regeneration cycles have been completed. The results show that 10% Nb{sub 2}O{sub 5}/SiO{sub 2} deactivates slowly with time but can be regenerated to its original activity with 2% O{sub 2} in nitrogen over night at 400 C. We have investigated the effects of regeneration, propionic acid/formaldehyde ratio (PA/HCHO = 4.5/1 to 1.5/1) and reaction temperature(280-300 C) on reaction activity and product selectivity over 20% Nb{sub 2}O{sub 5}/SiO{sub 2} catalysts. The regeneration effect on 20% Nb{sub 2}O{sub 5}/SiO{sub 2} is similar to the effect on 10% Nb{sub 2}O{sub 5}/SiO{sub 2}. The regeneration can bring the deactivated catalyst to its original activity. However, the selectivity to MAA decreases with regeneration while the selectivity to DEK and CO{sub 2} increases. When PA/HCHO ratio is decreased from 4.5/1 to 2.25/1 then to 1.5/1 at 300 C the MAA yield decreases but the MAA selectivity first increases then decreases. Decreasing the reaction temperature from 300 C to 280 C decreases the MAA yield from 39.5% to 30.7% but increases the MAA selectivity from 73.7% to 82.2%. The

  9. 2014 Congressional Nuclear Cleanup Caucus Briefings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Congressional Nuclear Cleanup Caucus Briefings 2014 Congressional Nuclear Cleanup Caucus Briefings The Congressional Nuclear Cleanup Caucus serves as a way to brief members of Congress and their staff on EM headquarters and site activities, including budget, safety and project progress. FY15 Budget Overview for Cleanup Caucus (1.78 MB) Idaho Cleanup Project (1.36 MB) Advanced Mixed Waste Treatment Project (2.3 MB) Richland Operations Office Cleanup Strategy, Scope (8.93 MB) Idaho Cleanup

  10. EA-1867: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    No Significant Impact RTI International Scale-Up of High-Temperature Syngas Cleanup and Carbon Capture and Sequestration Technologies, Polk County, Florida (October 2011) DOE...

  11. EA-1867: Draft Environmental Assessment

    Broader source: Energy.gov [DOE]

    RTI International Scale-Up of High-Temperature Syngas Cleanup and Carbon Capture and Sequestration Technologies, Polk County, Florida (October 2011)

  12. Legacy Cleanup Contract Awarded | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Legacy Cleanup Contract Awarded Legacy Cleanup Contract Awarded September 23, 2015 - 6:00pm Addthis Cincinnati - The U.S. Department of Energy (DOE) today announced the award of a Cost-Plus-Award Fee contract to Los Alamos National Security, LLC (LANS) of Los Alamos, NM. This bridge contract is for the Office of Environmental Management (EM) funded legacy cleanup activities at the Los Alamos National Laboratory (LANL). LANS is formed by the University of California, Bechtel, Babcock & Wilcox

  13. Lab completes record year for environmental cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Record year for environmental cleanup Lab completes record year for environmental cleanup Personnel conducted more field investigations and cleanup campaigns than ever and completed a record number of Lab shipments to WIPP. December 16, 2010 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new

  14. Researching Fe catalyst suitable for CO{sub 2}-containing syngas for Fischer-Tropsch synthesis

    SciTech Connect (OSTI)

    Wensheng Ning; Naoto Koizumi; Muneyoshi Yamada

    2009-09-15

    Fischer-Tropsch (FT) synthesis is a technology to produce liquid fuels from coal, natural gas, and biomass as an alternate to crude oil. However, the quantity of emitted CO{sub 2} from the FT process consisting of syngas preparation, FT synthesis, and product workup is one of the serious disadvantages of FT process. The conversion of CO{sub 2} into hydrocarbons is one of the promising methods to decrease CO{sub 2} emissions. Effects of promoter addition on the activity of precipitated Fe catalysts for the conversion of CO{sub 2} were studied using pure CO{sub 2} and CO{sub 2}-containing syngas feeds. The results suggested that CO{sub 2} can be activated by suitable promoter(s) for hydrocarbon synthesis at low temperature. Low K content is suitable for increasing hydrocarbon yield. The Fe catalysts promoted by equal Zn and Cu have higher CO and CO{sub 2} conversion and decreased CH{sub 4} selectivity. 36 refs., 7 figs., 3 tabs.

  15. DRAFT Central Plateau Cleanup Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Doug Shoop: DOE-RL John Price: Ecology Dave Einan: EPA November 2, 2012 2 River Corridor * 100 Area interim actions extended to 3/31/17 - Incorporate 154 additional waste sites - Address prior extensive deep excavation of hexavalent chromium contamination * 100 Area decision documents - Extend 100 B/C decision documents schedule to 12/15/16 to enable collection of additional groundwater data for cleanup decision - Delay 100-N document to 6/30/13 to avoid too many documents out for public comment

  16. The ABCs of Hanford Cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ABC's of Hanford Cleanup A B C ARRA Budget Community Relations Plan Asbestos Branching Out Columbia River Workshops Baton Chromium Badgers

  17. Hanford Site Cleanup Completion Framework - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plan Single-Shell Tank Evaluations Deep Vadose Zone 100-F RIFS Sitewide Probabilistic Seismic Hazard Analysis Environmental Hanford Site Cleanup Completion Framework Email Email...

  18. National Cleanup Workshops | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    executives, and other stakeholders to discuss EM's progress in the cleanup of the environmental legacy of the nation's Manhattan Project and Cold War nuclear weapons program. ...

  19. Tank Farm Area Cleanup Decision-Making

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area Cleanup Decision-Making Groundwater Vadose Zone Single Shell Tank System Closure (tanks, structures and pipelines) * Washington State Hazardous Waste Management Act (Resource...

  20. Independent Oversight Assessment, Idaho Cleanup Project Sodium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Treatment Project - November 2012 November 2012 Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project This report...

  1. Richland Operations Office Cleanup Strategy, Scope

    Broader source: Energy.gov (indexed) [DOE]

    nation's plutonium between 1945-1985 * Home to the first full-scale production reactor (B Reactor) * Transitioned to cleanup in 1989 B Reactor Complex during operations ...

  2. Long-Term Demonstration of Hydrogen Production from Coal at Elevated Temperatures Year 6 - Activity 1.12 - Development of a National Center for Hydrogen Technology

    SciTech Connect (OSTI)

    Stanislowski, Joshua; Tolbert, Scott; Curran, Tyler; Swanson, Michael

    2012-04-30

    The Energy & Environmental Research Center (EERC) has continued the work of the National Center for Hydrogen Technology® (NCHT®) Program Year 6 Task 1.12 project to expose hydrogen separation membranes to coal-derived syngas. In this follow-on project, the EERC has exposed two membranes to coal-derived syngas produced in the pilot-scale transport reactor development unit (TRDU). Western Research Institute (WRI), with funding from the State of Wyoming Clean Coal Technology Program and the North Dakota Industrial Commission, contracted with the EERC to conduct testing of WRI’s coal-upgrading/gasification technology for subbituminous and lignite coals in the EERC’s TRDU. This gasifier fires nominally 200–500 lb/hour of fuel and is the pilot-scale version of the full-scale gasifier currently being constructed in Kemper County, Mississippi. A slipstream of the syngas was used to demonstrate warm-gas cleanup and hydrogen separation using membrane technology. Two membranes were exposed to coal-derived syngas, and the impact of coal-derived impurities was evaluated. This report summarizes the performance of WRI’s patent-pending coalupgrading/ gasification technology in the EERC’s TRDU and presents the results of the warm-gas cleanup and hydrogen separation tests. Overall, the WRI coal-upgrading/gasification technology was shown to produce a syngas significantly lower in CO2 content and significantly higher in CO content than syngas produced from the raw fuels. Warm-gas cleanup technologies were shown to be capable of reducing sulfur in the syngas to 1 ppm. Each of the membranes tested was able to produce at least 2 lb/day of hydrogen from coal-derived syngas.

  3. A Hybrid Catalytic Route to Fuels from Biomass Syngas Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LanzaTech. All rights reserved. 1 A Hybrid Catalytic Route to Fuels from Biomass Syngas BETO's Project Peer Review, March 2015 Alexandria, VA Alice Havill Senior Process Engineer Project Principle Investigator Hybrid Catalytic Route to Fuels from Biomass Syngas Project Objective: develop a hybrid conversion technology for catalytic upgrading of biomass- derived syngas to jet fuel and chemicals while ensure the cost, quality and environmental requirements of the aviation industry are met System

  4. EERE Success Story-Washington: When Life Gives You Solar, Make Syngas |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy When Life Gives You Solar, Make Syngas EERE Success Story-Washington: When Life Gives You Solar, Make Syngas November 8, 2013 - 12:00am Addthis Pacific Northwest National Laboratory (PNNL) is developing a new method for combining solar energy with modified natural gas power plants. This concentrating solar power (CSP) system harnesses sunlight to produce syngas, which is a fuel capable of driving a standard heat engine to produce electricity. In addition to offsetting

  5. Executing Legacy Clean-up at LANL | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Executing Legacy Clean-up at LANL Executing Legacy Clean-up at LANL Topic: DOE presented on the proposed new campaign approach to clean-up at Los Alamos National Laboratory, and ...

  6. CONSTRUCTION OF KEY CLEANUP PROJECT GAINS GOOD GROUND AT SRS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CONSTRUCTION OF KEY CLEANUP PROJECT GAINS GOOD GROUND AT SRS CONSTRUCTION OF KEY CLEANUP PROJECT GAINS GOOD GROUND AT SRS June 1, 2010 - 12:00pm Addthis CONSTRUCTION OF KEY CLEANUP ...

  7. EM Tackles Cleanup at Tonopah Test Range | Department of Energy

    Office of Environmental Management (EM)

    Tackles Cleanup at Tonopah Test Range EM Tackles Cleanup at Tonopah Test Range September 30, 2014 - 12:00pm Addthis Field technicians survey a shaker used in past cleanup ...

  8. Washington Closure Hanford: Cleanup Progress Along Hanford's River Corridor

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Washington Closure Hanford: Cleanup Progress Along Hanford's River Corridor Washington Closure Hanford: Cleanup Progress Along Hanford's River Corridor Presentation from the 2015 DOE National Cleanup Workshop by Scott Sax, President, Washington Closure Hanford. Washington Closure Hanford: Cleanup Progress Along Hanford's River Corridor (10.41 MB) More Documents & Publications 2014 Congressional Nuclear Cleanup Caucus Briefings 2013 Congressional Nuclear Cleanup

  9. HANFORD SITE RIVER CORRIDOR CLEANUP

    SciTech Connect (OSTI)

    BAZZELL, K.D.

    2006-02-01

    In 2005, the US Department of Energy (DOE) launched the third generation of closure contracts, including the River Corridor Closure (RCC) Contract at Hanford. Over the past decade, significant progress has been made on cleaning up the river shore that bordes Hanford. However, the most important cleanup challenges lie ahead. In March 2005, DOE awarded the Hanford River Corridor Closure Contract to Washington Closure Hanford (WCH), a limited liability company owned by Washington Group International, Bechtel National and CH2M HILL. It is a single-purpose company whose goal is to safely and efficiently accelerate cleanup in the 544 km{sup 2} Hanford river corridor and reduce or eliminate future obligations to DOE for maintaining long-term stewardship over the site. The RCC Contract is a cost-plus-incentive-fee closure contract, which incentivizes the contractor to reduce cost and accelerate the schedule. At $1.9 billion and seven years, WCH has accelerated cleaning up Hanford's river corridor significantly compared to the $3.2 billion and 10 years originally estimated by the US Army Corps of Engineers. Predictable funding is one of the key features of the new contract, with funding set by contract at $183 million in fiscal year (FY) 2006 and peaking at $387 million in FY2012. Another feature of the contract allows for Washington Closure to perform up to 40% of the value of the contract and subcontract the balance. One of the major challenges in the next few years will be to identify and qualify sufficient subcontractors to meet the goal.

  10. Lawrence Berkeley National Laboratory Launches Cleanup and Demolition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lawrence Berkeley National Laboratory Launches Cleanup and Demolition Project Lawrence Berkeley National Laboratory Launches Cleanup and Demolition Project June 30, 2015 - 12:00pm ...

  11. Passive Groundwater Cleanup Measures Save Savannah River Site...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars November 25, ...

  12. Technology Development Advances EM Cleanup | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development Advances EM Cleanup Technology Development Advances EM Cleanup The unique nature of many of EM's remaining facilities will require a strong and responsive engineering ...

  13. Energy Department Extends Contract for Cleanup of Portsmouth...

    Office of Environmental Management (EM)

    Energy Department Extends Contract for Cleanup of Portsmouth Gaseous Diffusion Plant Energy Department Extends Contract for Cleanup of Portsmouth Gaseous Diffusion Plant March 28, ...

  14. Savannah River Site Takes on Another Environmental Cleanup Challenge...

    Office of Environmental Management (EM)

    Savannah River Site Takes on Another Environmental Cleanup Challenge: Coal-Fired Ash Savannah River Site Takes on Another Environmental Cleanup Challenge: Coal-Fired Ash July 29, ...

  15. Protocol_for_Environmental_Management_Cleanup_Projects_(clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ProtocolforEnvironmentalManagementCleanupProjects(clean).pdf ProtocolforEnvironmentalManagementCleanupProjects(clean).pdf PDF icon ProtocolforEnvironmentalManagement...

  16. New Idaho Cleanup Project Contractor Unveils Management Team...

    Office of Environmental Management (EM)

    Idaho Cleanup Project Contractor Unveils Management Team New Idaho Cleanup Project Contractor Unveils Management Team April 27, 2016 - 12:35pm Addthis IDAHO FALLS, Idaho - EM's new ...

  17. Probing Fukushima with cosmic rays should speed cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing Fukushima with cosmic rays should speed cleanup Probing Fukushima with cosmic rays should speed cleanup The initiative could reduce the time required to clean up the ...

  18. EM's Defense Waste Processing Facility Achieves Waste Cleanup...

    Office of Environmental Management (EM)

    Defense Waste Processing Facility Achieves Waste Cleanup Milestone EM's Defense Waste Processing Facility Achieves Waste Cleanup Milestone January 14, 2016 - 12:10pm Addthis The ...

  19. Assessment of Nuclear Safety Culture at the Idaho Cleanup Project...

    Office of Environmental Management (EM)

    the Idaho Cleanup Project Sodium Bearing Waste Treatment Project May 2011 November 2012 ... the Idaho Cleanup Project Sodium Bearing Waste Treatment Project Table of Contents 1.0 ...

  20. DOE Awards Small Business Contract to Support Cleanup of New...

    Energy Savers [EERE]

    Small Business Contract to Support Cleanup of New York West Valley Demonstration Project DOE Awards Small Business Contract to Support Cleanup of New York West Valley Demonstration ...

  1. Legacy Clean-up Completion Project Overview | Department of Energy

    Office of Environmental Management (EM)

    Legacy Clean-up Completion Project Overview Legacy Clean-up Completion Project Overview Topic: Bob Pfaff provided the members with information regarding the status of the Fiscal ...

  2. Novel polymer membrane process for pre-combustion CO{sub 2} capture from coal-fired syngas

    SciTech Connect (OSTI)

    Merkel, Tim

    2011-09-14

    This final report describes work conducted for the Department of Energy (DOE NETL) on development of a novel polymer membrane process for pre-combustion CO{sub 2} capture from coalfired syngas (award number DE-FE0001124). The work was conducted by Membrane Technology and Research, Inc. (MTR) from September 15, 2009, through December 14, 2011. Tetramer Technologies, LLC (Tetramer) was our subcontract partner on this project. The National Carbon Capture Center (NCCC) at Wilsonville, AL, provided access to syngas gasifier test facilities. The main objective of this project was to develop a cost-effective membrane process that could be used in the relatively near-term to capture CO{sub 2} from shifted syngas generated by a coal-fired Integrated Gasification Combined Cycle (IGCC) power plant. In this project, novel polymeric membranes (designated as Proteus™ membranes) with separation properties superior to conventional polymeric membranes were developed. Hydrogen permeance of up to 800 gpu and H{sub 2}/CO{sub 2} selectivity of >12 was achieved using a simulated syngas mixture at 150°C and 50 psig, which exceeds the original project targets of 200 gpu for hydrogen permeance and 10 for H{sub 2}/CO{sub 2} selectivity. Lab-scale Proteus membrane modules (with a membrane area of 0.13 m{sup 2}) were also developed using scaled-up Proteus membranes and high temperature stable module components identified during this project. A mixed-gas hydrogen permeance of about 160 gpu and H{sub 2}/CO{sub 2} selectivity of >12 was achieved using a simulated syngas mixture at 150°C and 100 psig. We believe that a significant improvement in the membrane and module performance is likely with additional development work. Both Proteus membranes and lab-scale Proteus membrane modules were further evaluated using coal-derived syngas streams at the National Carbon Capture Center (NCCC). The results indicate that all module components, including the Proteus membrane, were stable under the field

  3. System and process for the production of syngas and fuel gasses

    SciTech Connect (OSTI)

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M; Benefiel, Bradley C

    2015-04-21

    The production of gasses and, more particularly, to systems and methods for the production of syngas and fuel gasses including the production of hydrogen are set forth. In one embodiment system and method includes a reactor having a molten pool of a material comprising sodium carbonate. A supply of conditioned water is in communication with the reactor. A supply of carbon containing material is also in communication with the reactor. In one particular embodiment, the carbon containing material may include vacuum residuum (VR). The water and VR may be kept at desired temperatures and pressures compatible with the process that is to take place in the reactor. When introduced into the reactor, the water, the VR and the molten pool may be homogenously mixed in an environment in which chemical reactions take place including the production of hydrogen and other gasses.

  4. System and process for the production of syngas and fuel gasses

    DOE Patents [OSTI]

    Bingham, Dennis N; Kllingler, Kerry M; Turner, Terry D; Wilding, Bruce M; Benefiel, Bradley C

    2014-04-01

    The production of gasses and, more particularly, to systems and methods for the production of syngas and fuel gasses including the production of hydrogen are set forth. In one embodiment system and method includes a reactor having a molten pool of a material comprising sodium carbonate. A supply of conditioned water is in communication with the reactor. A supply of carbon containing material is also in communication with the reactor. In one particular embodiment, the carbon containing material may include vacuum residuum (VR). The water and VR may be kept at desired temperatures and pressures compatible with the process that is to take place in the reactor. When introduced into the reactor, the water, the VR and the molten pool may be homogenously mixed in an environment in which chemical reactions take place including the production of hydrogen and other gasses.

  5. Environmental Cleanup Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Cleanup Reports Environmental Cleanup Reports June 2, 2015 Audit Report: DOE/IG-0937 The Status of Cleanup at the Department of Energy's Paducah Site September 18, 2014 Audit Report: OAS-M-14-11 Follow-Up on the Management of the Plutonium Finishing Plant Project September 26, 2013 Audit Report: OAS-L-13-15 The Radioactive Liquid Waste Treatment Facility Replacement Project at Los Alamos National Laboratory August 8, 2013 Audit Report: OAS-M-13-03 Cost Transfers at the Department's

  6. Bench- and Pilot-Scale Studies of Reaction and Regeneration of Ni-Mg-K/Al2O3 for Catalytic Conditioning of Biomass-Derived Syngas

    SciTech Connect (OSTI)

    Magrini-Bair, K. A.; Jablonski, W. S.; Parent, Y. O.; Yung, M. M.

    2012-05-01

    The National Renewable Energy Laboratory (NREL) is collaborating with both industrial and academic partners to develop technologies to help enable commercialization of biofuels produced from lignocellulosic biomass feedstocks. The focus of this paper is to report how various operating processes, utilized in-house and by collaborators, influence the catalytic activity during conditioning of biomass-derived syngas. Efficient cleaning and conditioning of biomass-derived syngas for use in fuel synthesis continues to be a significant technical barrier to commercialization. Multifunctional, fluidizable catalysts are being developed to reform undesired tars and light hydrocarbons, especially methane, to additional syngas, which can improve utilization of biomass carbon. This approach also eliminates both the need for downstream methane reforming and the production of an aqueous waste stream from tar scrubbing. This work was conducted with NiMgK/Al{sub 2}O{sub 3} catalysts. These catalysts were assessed for methane reforming performance in (i) fixed-bed, bench-scale tests with model syngas simulating that produced by oak gasification, and in pilot-scale, (ii) fluidized tests with actual oak-derived syngas, and (iii) recirculating/regenerating tests using model syngas. Bench-scale tests showed that the catalyst could be completely regenerated over several reforming reaction cycles. Pilot-scale tests using raw syngas showed that the catalyst lost activity from cycle to cycle when it was regenerated, though it was shown that bench-scale regeneration by steam oxidation and H{sub 2} reduction did not cause this deactivation. Characterization by TPR indicates that the loss of a low temperature nickel oxide reduction feature is related to the catalyst deactivation, which is ascribed to nickel being incorporated into a spinel nickel aluminate that is not reduced with the given activation protocol. Results for 100 h time-on-stream using a recirculating/regenerating reactor suggest

  7. Synthesis of methanol and dimethyl ether from syngas over Pd/ZnO/Al2O3 catalysts

    SciTech Connect (OSTI)

    Lebarbier, Vanessa M.; Dagle, Robert A.; Kovarik, Libor; Lizarazo-Adarme, Jair A.; King, David L.; Palo, Daniel R.

    2012-01-01

    A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250C to 380C. High temperatures (e.g. 380C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSVs and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pd particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

  8. Syngas Production By Thermochemical Conversion Of H2o And Co2 Mixtures Using A Novel Reactor Design

    SciTech Connect (OSTI)

    Pearlman, Howard; Chen, Chien-Hua

    2014-08-27

    The Department of Energy awarded Advanced Cooling Technologies, Inc. (ACT) an SBIR Phase II contract (#DE-SC0004729) to develop a high-temperature solar thermochemical reactor for syngas production using water and/or carbon dioxide as feedstocks. The technology aims to provide a renewable and sustainable alternative to fossil fuels, promote energy independence and mitigate adverse issues associated with climate change by essentially recycling carbon from carbon dioxide emitted by the combustion of hydrocarbon fuels. To commercialize the technology and drive down the cost of solar fuels, new advances are needed in materials development and reactor design, both of which are integral elements in this program.

  9. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V.; Cicero, Daniel C. (U.S. Department of Energy, National Energy Technology Laboratory, Morgantown); Stiegel, Gary J.; Gupta, Raghubir P. (U.S. Department of Energy, National Energy Technology Laboratory, Pittsburgh); Turk, Brian S. (Research Triangle Institute)

    2001-11-06

    A fixed-bed regenerable desulfurization sorbent, identified as RVS-land developed by researchers at the U.S. Department of Energy's National Energy Technology Laboratory, was awarded the R&D 100 award in 2000 and is currently offered as a commercial product by Sued-Chemie Inc. An extensive testing program for this sorbent was undertaken which included tests at a wide range of temperatures, pressures and gas compositions both simulated and generated in an actual gasifier for sulfidation and regeneration. This testing has demonstrated that during these desulfurization tests, the RVS-1 sorbent maintained an effluent H2S concentration of <5 ppmv at temperatures from 260 to 600 C (500-1100 F) and pressures of 203-2026 kPa(2 to 20 atm) with a feed containing 1.2 vol% H{sub 2}S. The types of syngas tested ranged from an oxygen-blown Texaco gasifier to biomass-generated syngas. The RVS-1 sorbent has high crush strength and attrition resistance, which, unlike past sorbent formulations, does not decrease with extended testing at actual at operating conditions. The sulfur capacity of the sorbent is roughly 17 to 20 wt.% and also remains constant during extended testing (>25 cycles). In addition to H{sub 2}S, the RVS-1 sorbent has also demonstrated the ability to remove dimethyl sulfide and carbonyl sulfide from syngas. During regeneration, the RVS-1 sorbent has been regenerated with dilute oxygen streams (1 to 7 vol% O{sub 2}) at temperatures as low as 370 C (700 F) and pressures of 304-709 kPa(3 to 7 atm). Although regeneration can be initiated at 370 C (700 F), regeneration temperatures in excess of 538 C (1000 F) were found to be optimal. The presence of steam, carbon dioxide or sulfur dioxide (up to 6 vol%) did not have any visible effect on regeneration or sorbent performance during either sulfidation or regeneration. A number of commercial tests involving RVS-1 have been either conducted or are planned in the near future. The RVS-1 sorbent has been tested by Epyx, Aspen

  10. Hazardous waste cleanup: the preliminaries

    SciTech Connect (OSTI)

    Amos, K.

    1985-08-01

    This article describes the lengthiness and cost of the preliminary steps in a hazardous waste cleanup. The article describes the S-Area lawsuit, an area near Niagara Falls, New York which was an inactive chemical dump. Contaminated sludge was found at a nearby water treatment plant and was traced back to S-Area. In the past five years, S-Area negotiations have cost the U.S. Environmental Protection Agency two million dollars for advice on how work should proceed for the plant and the landfill. This lawsuit was one of the first in the U.S. against a chemical company for endangering the public through unsound waste disposal practices. Negotiation was selected instead of a trial for several reasons which are outlined. S-Area may serve as a model for other such settlements, as it provides for a flexible plan, open to consideration of alternate technologies that may be developed in the future. It contains a phased approach to both defining and evaluating existing problems, then suggesting remedies. It also requires monitoring for at least 35 years or until no danger remains.

  11. Well cleanup and completion apparatus

    SciTech Connect (OSTI)

    Brieger, E.F.

    1984-03-13

    A well cleanup and completion apparatus and technique. A packer is located downhole in a borehole, and a tool string comprising a one-way vent assembly and a one-way circulating valve assembly is connected above a perforating gun. The tool string is used to run the gun downhole through the packer until the gun arrives at a location adjacent to the formation to be perforated. During this time, the packer assembly must be in a configuration which admits flow from the lower to the upper annulus. Cleaning fluid is circulated down the entire tool string to the one-way circulating valve assembly located immediately above the firing head of the gun, thereby displacing fluid from the lower annulus, and cleaning any debris from the gun firing head. The packer is next closed, the gun detonated, whereupon the formation is perforated and production fluid flows through the perforations, up the lower annulus, into the one-way vent assembly located below the packer, into the tubing, and to the surface of the ground. Accordingly, the apparatus enables the gun and the borehole annulus adjacent the gun to be cleaned, thereby assuring that the well is properly completed in a single trip into the wellbore.

  12. RTOs favored to bat in cleanup position

    SciTech Connect (OSTI)

    McIlvaine, R.W.

    1995-02-01

    In the volatile organic compound treatment industry, the regenerative thermal oxidizer is the cleanup hitter. In comparison to recent modest growth in the catalytic and recuperative thermal gas treatment segments, growth in RTO sales has been spectacular. An RTO uses a series of packed ceramic beds operated in a cyclical fashion to store the heat generated by VOC combustion. Heat recovery is achieved by redirecting the gas flow periodically so incoming process gas flows through a media-filled vessel that has been heated by contact with the fully combusted gas. Once the incoming gas has been pre-heated by contact with the hot ceramic media, it proceeds to the combustion chamber. After combustion, this maximally hot gas exits through a different ceramic bed, transferring its residual heat in the process. Degree of heat recovery typically approaches 90 percent, and substantially reduces the amount of supplemental fuel required to maintain the necessary temperature for proper combustion efficiency, resulting in significantly reduced operating costs.

  13. Commercial Environmental Cleanup -- The products and services...

    Office of Scientific and Technical Information (OSTI)

    The database of the commercial cleanup products and services Directory will be offered on the Internet in the future and will be available on the Homepage www.doe.gjpo.com. ...

  14. Y-12 National Security Complex Cleanup

    Broader source: Energy.gov [DOE]

    This fact sheet provides an update on all of the current cleanup projects at the site, and it also lists the major projects completed at the Y-12 National Security Complex.

  15. Nuclear radiation cleanup and uranium prospecting

    DOE Patents [OSTI]

    Mariella, Jr., Raymond P.; Dardenne, Yves M.

    2016-02-02

    Apparatus, systems, and methods for nuclear radiation cleanup and uranium prospecting include the steps of identifying an area; collecting samples; sample preparation; identification, assay, and analysis; and relating the samples to the area.

  16. Environmental Cleanup Reports | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Audit of Moab Mill Tailings Cleanup Project April 9, 2010 Audit Report: OAS-RA-10-07 Management Alert on Environmental Management's Select Strategy for Disposition of Savannah...

  17. Task 4.9 -- Value-added products from syngas

    SciTech Connect (OSTI)

    Olson, E.S.; Sharma, R.K.

    1997-02-01

    The work on advanced fuel forms in 1996 focused on the synthesis of higher alcohols from mixtures of hydrogen and carbon dioxide (syngas) from coal gasification. The conversion of coal gasification products to commercially valuable alcohols will provide an important new market for current and future gasification plants. Initial work in this project utilized a novel molybdenum sulfide catalyst previously shown to be active for hydrodesulfurization reactions of coal liquids. The support for the active metal sulfide is a layered mixed oxide (hydrotalcite) capable of interaction with the metal sites for catalysis of carbon monoxide reductions. These catalysts have a high surface area, are highly porous, and have basic and acidic functionality. A pressurized fixed-bed flow-through reactor was constructed, and the MoS{sub 2} catalysts were tested with syngas under a variety of conditions. Unfortunately, the catalysts, even with higher molybdenum loading and addition of promoters, failed to give alcohol products. A batch reactor test of the catalyst was also conducted, but did not produce alcohol products. Group 8 metals have been used previously in catalysts for syngas reactions. Ruthenium and rhodium catalysts were prepared by impregnation of a hydrotalcite support. Tests with these catalysts in flow-through reactors also did not produce the desired alcohol products. The formation of higher alcohols from smaller ones, such as methanol and ethanol, could be commercially important if high selectivity could be achieved. The methanol and ethanol would be derived from syngas and fermentation, respectively. Based on previous work in other laboratories, it was hypothesized that the hydrotalcite supported MoS{sub 2} or Ru or Rh catalysts could catalyze the formation of butyl alcohols. Although the desired 1-butanol was obtained in batch reactions with the promoted Ru catalyst, the reaction was not as selective as desired. Product suitable for a lower-vapor-pressure gasoline

  18. Paducah Cleanup Scope | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Scope Paducah Cleanup Scope This graphic illustrates the organization of the Media/Activity-Specific OUs and Primary Projects. Check marks indicate completed projects and gradient boxes indicate projects in progress. This graphic illustrates the organization of the Media/Activity-Specific OUs and Primary Projects. Check marks indicate completed projects and gradient boxes indicate projects in progress. The overall environmental cleanup strategy at Paducah is based on taking near-term actions to

  19. Los Alamos National Laboratory names cleanup subcontractors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cleanup subcontractors named Los Alamos National Laboratory names cleanup subcontractors The three companies are Los Alamos Technical Associates (LATA), Portage Inc., and ARSEC Environmental, LLC (ARSEC). August 14, 2009 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos

  20. Cleanup Progress Report - 2011 | Department of Energy

    Energy Savers [EERE]

    1 Cleanup Progress Report - 2011 In this issue, learn about EM's accomplishments in 2011 across the Oak Ridge Reservation. There are many more stories contained within the issue, but here are some of the highlights from each site. East Tennessee Technology Park DOE Selects New Cleanup Contractor K-25 East Wing Demolition Begins K-33 Building Demolished Oak Ridge National Laboratory 2000 Complex Demolition Completed Bethel Valley Burial Ground Remediation Completed Bethel Valley Groundwater

  1. Lab completes first Recovery Act cleanup project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANL Recovery Act cleanup Lab completes first Recovery Act cleanup project The $13 million project involved demolition of an 18,000-square-foot former nuclear fusion research facility. August 4, 2010 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory sits

  2. Credibility and trust in federal facility cleanups

    SciTech Connect (OSTI)

    Raynes, D.B.

    1995-12-01

    The most important indicator of a well-managed site cleanup effort may no longer be funding or scientific expertise. While support for federal facility cleanup has included appropriations of more than $10 billion annually, these expenditures alone are unlikely to assure progress toward environmental remediation. {open_quotes}Trust{close_quotes} is now overwhelmingly mentioned as a prerequisite for progress with site cleanup in DOE`s weapons complex. In part, federal budget deficits are forcing participants to focus on factors that build consensus and lead to cost-effective cleanup actions. In some cases, the stakeholders at cleanup sites are making efforts to work cooperatively with federal agencies. A report by 40 representatives of federal agencies, tribal and state governments, associations, and others developed recommendations to create a {open_quotes}new era of trust and consensus-building that allows all parties to get on with the job of cleaning up federal facilities in a manner that reflects the priorities and concerns of all stakeholders.{close_quotes} Changes are underway affecting how federal agencies work with federal and state regulators reflecting this concept of shared responsibility for conducting cleanup. This paper addresses these changes and provides examples of the successes and failures underway.

  3. HARVESTING EMSP RESEARCH RESULTS FOR WASTE CLEANUP

    SciTech Connect (OSTI)

    Guillen, Donna Post; Nielson, R. Bruce; Phillips, Ann Marie; Lebow, Scott

    2003-02-27

    The extent of environmental contamination created by the nuclear weapons legacy combined with expensive, ineffective waste cleanup strategies at many U.S. Department of Energy (DOE) sites prompted Congress to pass the FY96 Energy and Water Development Appropriations Act, which directed the DOE to: ''provide sufficient attention and resources to longer-term basic science research, which needs to be done to ultimately reduce cleanup costs'', ''develop a program that takes advantage of laboratory and university expertise, and'' ''seek new and innovative cleanup methods to replace current conventional approaches which are often costly and ineffective.'' In response, the DOE initiated the Environmental Management Science Program (EMSP)-a targeted, long-term research program intended to produce solutions to DOE's most pressing environmental problems. EMSP funds basic research to lower cleanup cost and reduce risk to workers, the public, and the environment; direct the nation's scientific infrastructure towards cleanup of contaminated waste sites; and bridge the gap between fundamental research and technology development activities. EMSP research projects are competitively awarded based on the project's scientific, merit coupled with relevance to addressing DOE site needs. This paper describes selected EMSP research projects with long, mid, and short-term deployment potential and discusses the impacts, focus, and results of the research. Results of EMSP research are intended to accelerate cleanup schedules, reduce cost or risk for current baselines, provide alternatives for contingency planning, or provide solutions to problems where no solutions exist.

  4. Gasification of refinery sludge in an updraft reactor for syngas production

    SciTech Connect (OSTI)

    Ahmed, Reem; Eldmerdash, Usama; Sinnathambi, Chandra M.

    2014-10-24

    The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H{sub 2}, CH{sub 4} compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO{sub 2}+C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm{sup −3} of, and 2.5 Nm{sup 3} kg{sup −1} respectively.

  5. NUMERICAL SIMULATIONS OF THE EFFECTS OF CHANGING FUEL FOR TURBINES FIRED BY NATURAL GAS AND SYNGAS

    SciTech Connect (OSTI)

    Sabau, Adrian S; Wright, Ian G

    2007-01-01

    Gas turbines in integrated gasification combined cycle (IGCC) power plants burn a fuel gas (syngas) in which the proportions of hydrocarbons, H2, CO, water vapor, and minor impurity levels may vary significantly from those in natural gas, depending on the input feed to the gasifier and the gasification process. A data structure and computational methodology is presented for the numerical simulation of a turbine thermodynamic cycle for various fuel types, air/fuel ratios, and coolant flow rates. The approach used allowed efficient handling of turbine components and different variable constraints due to fuel changes. Examples are presented for a turbine with four stages and cooled blades. The blades were considered to be cooled in an open circuit, with air provided from appropriate compressor stages. Results are presented for the temperatures of the hot gas, alloy surface (coating-superalloy interface), and coolant, as well as for cooling flow rates. Based on the results of the numerical simulations, values were calculated for the fuel flow rates, airflow ratios, and coolant flow rates required to maintain the superalloy in the first stage blade at the desired temperature when the fuel was changed from natural gas (NG) to syngas (SG). One NG case was conducted to assess the effect of coolant pressure matching between the compressor extraction points and corresponding turbine injection points. It was found that pressure matching is a feature that must be considered for high combustion temperatures. The first series of SG simulations was conducted using the same inlet mass flow and pressure ratios as those for the NG case. The results showed that higher coolant flow rates and a larger number of cooled turbine rows were needed for the SG case. Thus, for this first case, the turbine size would be different for SG than for NG. In order to maintain the original turbine configuration (i.e., geometry, diameters, blade heights, angles, and cooling circuit characteristics) for

  6. 2015 DOE National Cleanup Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 DOE National Cleanup Workshop 2015 DOE National Cleanup Workshop Assistant Secretary Regalbuto Lays out Vision, Priorities to Advance Cleanup for EM Program Assistant Secretary Regalbuto Lays out Vision, Priorities to Advance Cleanup for EM Program DOE Assistant Secretary for Environmental Management Monica Regalbuto speaks to more than 350 people at the National Cleanup Workshop just outside Washington, D.C. Read more Panelists Update Workshop Participants on Waste Isolation Pilot Plant

  7. Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

    2010-12-31

    Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants

  8. Micro-Mixing Lean-Premix System for Ultra-Low Emission Hydrogen/Syngas Combustion

    SciTech Connect (OSTI)

    Erlendur Steinthorsson; Brian Hollon; Adel Mansour

    2010-06-30

    The focus of this project was to develop the next generation of fuel injection technologies for environmentally friendly, hydrogen syngas combustion in gas turbine engines that satisfy DOE's objectives of reducing NOx emissions to 3 ppm. Building on Parker Hannifin's proven Macrolamination technology for liquid fuels, Parker developed a scalable high-performing multi-point injector that utilizes multiple, small mixing cups in place of a single conventional large-scale premixer. Due to the small size, fuel and air mix rapidly within the cups, providing a well-premixed fuel-air mixture at the cup exit in a short time. Detailed studies and experimentation with single-cup micro-mixing injectors were conducted to elucidate the effects of various injector design attributes and operating conditions on combustion efficiency, lean stability and emissions and strategies were developed to mitigate the impact of flashback. In the final phase of the program, a full-scale 1.3-MWth multi-cup injector was built and tested at pressures from 6.9bar (100psi) to 12.4bar (180psi) and flame temperatures up to 2000K (3150 F) using mixtures of hydrogen and natural gas as fuel with nitrogen and carbon dioxide as diluents. The injector operated without flash back on fuel mixtures ranging from 100% natural gas to 100% hydrogen and emissions were shown to be insensitive to combustor pressure. NOx emissions of 3-ppm were achieved at a flame temperature of 1750K (2690 F) when operating on a fuel mixture containing 50% hydrogen and 50% natural gas by volume with 40% nitrogen dilution and 1.5-ppm NOx was achieved at a flame temperature of 1680K (2564 F) using only 10% nitrogen dilution. NOx emissions of 3.5-ppm were demonstrated at a flame temperature of 1730K (2650 F) with only 10% carbon dioxide dilution. Finally, 3.6-ppm NOx emissions were demonstrated at a flame temperature over 1600K (2420 F) when operating on 100% hydrogen fuel with 30% carbon dioxide dilution. Superior operability was

  9. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas. A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture

    SciTech Connect (OSTI)

    Lebarbier, Vanessa M.C.; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2013-07-08

    Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325°C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600°C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700ºC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600°C. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent

  10. Central Plateau Cleanup Final Comments and Responses Document on Proposed Changes to Central Plateau Cleanup Page 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Responses on Proposed TPA Changes to Central Plateau Cleanup Final Comments and Responses Document on Proposed Changes to Central Plateau Cleanup Page 1 Comments and Responses to the Tentative Agreement on Hanford Federal Facility Agreement and Consent Order Implementing Changes to Central Plateau Cleanup October 2010 Comments and Responses on Proposed TPA Changes to Central Plateau Cleanup Final Comments and Responses Document on Proposed Changes to Central Plateau Cleanup Page 2 Public

  11. SUBTASK 3.12 – GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL

    SciTech Connect (OSTI)

    Stanislowski, Joshua; Curran, Tyler; Henderson, Ann

    2014-06-30

    The goal of this project was to evaluate the performance of Illinois No. 6 coal blended with biomass in a small-scale entrained-flow gasifier and demonstrate the production of liquid fuels under three scenarios. The first scenario used traditional techniques for cleaning the syngas prior to Fischer–Tropsch (FT) synthesis, including gas sweetening with a physical solvent. In the second scenario, the CO2 was not removed from the gas stream prior to FT synthesis. In the third scenario, only warm-gas cleanup techniques were used, such that the feed gas to the FT unit contained both moisture and CO2. The results of the testing showed that the liquid fuels production from the FT catalyst was significantly hindered by the presence of moisture and CO2 in the syngas. Further testing would be needed to determine if this thermally efficient process is feasible with other FT catalysts. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the Illinois Clean Coal Institute.

  12. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    SciTech Connect (OSTI)

    E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; John Hemmings

    2005-05-01

    This final report summarizes work accomplished in the Program from January 1, 2001 through December 31, 2004. Most of the key technical objectives for this program were achieved. A breakthrough material system has lead to the development of an OTM (oxygen transport membrane) compact planar reactor design capable of producing either syngas or hydrogen. The planar reactor shows significant advantages in thermal efficiency and a step change reduction in costs compared to either autothermal reforming or steam methane reforming with CO{sub 2} recovery. Syngas derived ultra-clean transportation fuels were tested in the Nuvera fuel cell modular pressurized reactor and in International Truck and Engine single cylinder test engines. The studies compared emission and engine performance of conventional base fuels to various formulations of ultra-clean gasoline or diesel fuels. A proprietary BP oxygenate showed significant advantage in both applications for reducing emissions with minimal impact on performance. In addition, a study to evaluate new fuel formulations for an HCCI engine was completed.

  13. Investigation of nitrogen dilution effects on the laminar burning velocity and flame stability of syngas fuel at atmospheric condition

    SciTech Connect (OSTI)

    Prathap, C.; Ray, Anjan; Ravi, M.R. [Department of Mechanical Engineering, Indian Institute of Technology, Delhi, New Delhi 110016 (India)

    2008-10-15

    The objective of this investigation was to study the effect of dilution with nitrogen on the laminar burning velocity and flame stability of syngas fuel (50% H{sub 2}-50% CO by volume)-air (21% O{sub 2}-79% N{sub 2} by volume) mixtures. The syngas fuel composition considered in this work comprised x% N{sub 2} by volume and (100-x)% an equimolar mixture of CO and H{sub 2}. The proportion x (i.e., %N{sub 2}) was varied from 0 to 60% while the H{sub 2}/CO ratio was always kept as unity. Spherically expanding flames were generated by centrally igniting homogeneous fuel-air gas mixtures in a 40-L cylindrical combustion chamber fitted with optical windows. Shadowgraphy technique with a high-speed imaging camera was used to record the propagating spherical flames. Unstretched burning velocity was calculated following the Karlovitz theory for weakly stretched flames. Also, Markstein length was calculated to investigate the flame stability conditions for the fuel-air mixtures under consideration. Experiments were conducted for syngas fuel with different nitrogen proportions (0-60%) at 0.1 MPa (absolute), 302{+-}3K, and equivalence ratios ranging from 0.6 to 3.5. All the measurements were compared with the numerical predictions obtained using RUN-1DL and PREMIX with a contemporary chemical kinetic scheme. Dilution with nitrogen in different proportions in syngas resulted in (a) decrease in laminar burning velocity due to reduction in heat release and increase in heat capacity of unburned gas mixture and hence the flame temperature, (b) shift in occurrence of peak laminar burning velocity from {phi}=2.0 for 0% N{sub 2} dilution to {phi}=1.4 for 60% N{sub 2} dilution, (c) augmentation of the coupled effect of flame stretch and preferential diffusion on laminar burning velocity, and (d) shift in the equivalence ratio for transition from stable to unstable flames from {phi}=0.6 for 0% N{sub 2} dilution to {phi}=1.0 for 60% N{sub 2} dilution. The present work also indicated that

  14. NREL Patents a Catalyst that Removes Syngas Tar, Boosting the Economics of Biofuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Patents a Catalyst that Removes Syngas Tar, Boosting the Economics of Biofuels NREL has patented a catalyst that reforms tar into syngas, a breakthrough that can accelerate the process of getting biomass ready for fuel synthesis and use as a drop-in fuel. The process also can help reduce greenhouse gases because the biomass that is used in fuel gets combusted into carbon dioxide, which is food for future biomass. The result is that 90% of carbon emissions get recycled into new biomass. Syngas is

  15. Clearing the Way for Hanford Site Cleanup | Department of Energy

    Energy Savers [EERE]

    Clearing the Way for Hanford Site Cleanup Clearing the Way for Hanford Site Cleanup August 15, 2016 - 12:30pm Addthis Clearing the Way for Hanford Site Cleanup Clearing the Way for Hanford Site Cleanup Clearing the Way for Hanford Site Cleanup Clearing the Way for Hanford Site Cleanup RICHLAND, Wash. - Watch time-lapse footage of workers preparing the T Plant canyon deck at the Hanford Site to receive K-West Reactor Fuel Storage Basin sludge by removing the legacy equipment shown in the 2012

  16. The Application of NEPA to CERCLA Cleanups

    Broader source: Energy.gov [DOE]

    On March 31, 1994, officials from the Departrnent of Energy (DOE), the Environmental Protection Agency (EPA), and the Council on Environmental Quality (CEQ) met with then Acting Assistant Attorney General Lois Schiffer and other representatives of the Department of Justice (DOJ) to discuss the issue of the relationship of the National Environmental Policy Act (NEPA) to the cleanup of federal facilities under the CERCLA Superfund program. The meeting focused on proposals for addressing problems that have arisen from DOE's attempts to integrate the procedural and analytical approaches of NEPA into the CERCLA cleanup process. This document describes what was discussed at the meeting and the consensus reached there.

  17. SYNTHESIS OF METHACRYLATES FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Jang, B.W.L.; Spivey, J.J.; Gogate, M.R.; Zoeller, J.R.; Colberg, R.D.; Choi, G.N.

    1999-12-01

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel have developed a novel process for synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the US Department of Energy/Fossil Energy Technology Center (DOE/FETC). This project has resulted in five US patents (four already published and one pending publication). It has served as the basis for the technical and economic assessment of the production of this high-volume intermediate from coal-derived synthesis gas. The three-step process consists of the synthesis of a propionate from ethylene carbonylation using coal-derived CO, condensation of the propionate with formaldehyde to form methacrylic acid (MAA); and esterification of MAA with methanol to yield MMA. The first two steps, propionate synthesis and condensation catalysis, are the key technical challenges and the focus of the research presented here.

  18. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Makarand R. Gogate; James J. Spivey; Joseph R. Zoeller; Richard D. Colberg; Gerald N. Choi; Samuel S. Tam

    1999-04-21

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. The research team has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, we are currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter (January-March/99), in-situ formaldehyde generation and condensation with methyl propionate were tested over various catalysts and reaction conditions. The patent application is in preparation and the results are retained for future reports.

  19. NREL Patents a Catalyst that Removes Syngas Tar, Boosting the Economics of Biofuels (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-08-01

    NREL has patented a catalyst that reforms tar into syngas, a breakthrough that can accelerate the process of getting biomass ready for fuel synthesis and use as a drop-in fuel.

  20. Bioenergy Technologies Office Conversion R&D Pathway: Syngas Upgrading to Hydrocarbon Fuels

    Broader source: Energy.gov [DOE]

    Syngas upgrading to hydrocarbon fuels is one of eight priority pathways chosen to convert biomass into hydrocarbon fuels by the Bioenergy Technologies Office. These pathways were down-selected from an initial list of 18.

  1. EM, UCOR Quickly Reconcile Oak Ridge Cleanup Contract | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EM, UCOR Quickly Reconcile Oak Ridge Cleanup Contract EM, UCOR Quickly Reconcile Oak Ridge Cleanup Contract July 12, 2012 - 12:00pm Addthis DOE and UCOR employees held an event ...

  2. DOE Awards Contract for Moab Mill Tailings Cleanup | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Moab Mill Tailings Cleanup DOE Awards Contract for Moab Mill Tailings Cleanup November 4, ... has awarded a competitive small business contract worth 121.2 million over the next five ...

  3. EM's Richland Operations Office Completes Chromium Cleanup along Columbia River

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – EM’s Richland Operations Office and cleanup contractor Washington Closure Hanford have completed cleanup of chromium-contaminated soil along the Columbia River at the Hanford Site.

  4. EM Presents Video Highlights of Cleanup Across DOE Complex in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presents Video Highlights of Cleanup Across DOE Complex in YouTube Playlist EM Presents Video Highlights of Cleanup Across DOE Complex in YouTube Playlist April 20, 2016 - 12:00pm ...

  5. Recovery Act funds advance cleanup efforts at Cold War site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cleanup efforts at Cold War site Recovery Act funds advance cleanup efforts at Cold War site A local small business, ARSEC Environmental, LLC, of White Rock, NM, won a 2 million ...

  6. DOE Completes Cleanup at New York, California Sites | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Completes Cleanup at New York, California Sites DOE Completes Cleanup at New York, California Sites July 1, 2011 - 12:00am Addthis WASHINGTON, D.C. - Last month, the U.S....

  7. EM's Cleanup Mission: 16 Sites in 11 States Remaining

    Broader source: Energy.gov [DOE]

    At the end of fiscal year 2013, EM completed cleanup and closed 90 sites in 28 states. This included cleanup and closure of 85 smaller sites and five major nuclear sites: Rocky Flats, Fernald, Mound, Pinellas, and Weldon Spring.

  8. Site Transition Process upon Completion of the Cleanup Mission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE's internal site transition process for Cleanup to long-term stewardship, post-cleanup, ... a Landlord Program Secretarial Office or to Legacy Management for long-term stewardship. ...

  9. DOE Completes TRU Waste Cleanup at Bettis | Department of Energy

    Office of Environmental Management (EM)

    TRU Waste Cleanup at Bettis DOE Completes TRU Waste Cleanup at Bettis September 23, 2011 - 12:00pm Addthis Media Contact Deb Gill www.wipp.energy.gov 575-234-7270 CARLSBAD, N.M. - ...

  10. A message of appreciation from ORP to its cleanup partners |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A message of appreciation from ORP to its cleanup partners A message of appreciation from ORP to its cleanup partners Addthis Description A message of appreciation from ORP to its ...

  11. Chromium Groundwater Cleanup in Mortandad Canyon

    Broader source: Energy.gov [DOE]

    At the September 24, 2014 Board meeting Cheryl Rodriguez DOE and Danny Katzman LANL, Provided Information on the Status of the Characterization of the Chromium Groundwater Plume in Mortandad Canyon. Possible Clean-up Strategies were also covered in the Information Provided.

  12. EM Releases Supporting Materials From DOE's First National Cleanup

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop | Department of Energy EM Releases Supporting Materials From DOE's First National Cleanup Workshop EM Releases Supporting Materials From DOE's First National Cleanup Workshop November 9, 2015 - 10:00am Addthis EM Releases Supporting Materials From DOE’s First National Cleanup Workshop WASHINGTON, D.C. - EM is making available support materials from the first-ever DOE National Cleanup Workshop. The materials include links to 15 videos that capture addresses by Energy Secretary

  13. ETTP Cleanup and Reindustrialization Finishing What We Started

    Broader source: Energy.gov [DOE]

    Presentation from the 2015 DOE National Cleanup Workshop by Ken Rueter, President, URS-CH2M Oak Ridge (UCOR).

  14. Voluntary Protection Program Onsite Review, Idaho Cleanup Project- October 2010

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether Idaho Cleanup Project is continuing to perform at a level deserving DOE-VPP Star recognition.

  15. DOE National Cleanup Workshop 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Cleanup Workshop 2015 DOE National Cleanup Workshop 2015 May 17, 2016 - 1:45pm Addthis DOE Acquisition Outlook and Challenges John Hale III, Director of the Office of Small and Disadvantage Business Utilization (OSDBU) at the Department of Energy, spoke at the 1st Annual DOE National Cleanup Workshop, held in September 2015. This year, the Energy Communities Alliance (ECA) will be holding the 2016 National Cleanup Workshop on September 14-15, 2016, at the Hilton Alexandria Mark Center

  16. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what

  17. Top EM Leadership to Participate in 2016 National Cleanup Workshop |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Top EM Leadership to Participate in 2016 National Cleanup Workshop Top EM Leadership to Participate in 2016 National Cleanup Workshop March 9, 2016 - 12:00pm Addthis Top EM Leadership to Participate in 2016 National Cleanup Workshop WASHINGTON, D.C. - EM's senior leaders are set to join the 2016 National Cleanup Workshop in mid-September in the Washington, D.C.-area. The nuclear cleanup program's leaders scheduled to take part in the workshop include Assistant Secretary

  18. Synthesis of acrylates and methacrylates from coal-derived syngas. Quarterly report, October--December 1996

    SciTech Connect (OSTI)

    1997-05-02

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the US Department of Energy, Federal Energy Technology Center. This three-step process consists of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Eastman has focused on the propionate synthesis step. the resultant Mo catalysts work efficiently at much less severe conditions (170{degrees}C and 30 atm) than the conventional Ni catalysts (270{degrees}C and 180 atm). Bechtel has performed an extensive cost analysis which shows that Eastman`s propionate synthesis step is competitive with other technologies to produce the anhydride. In the second step, RTI and Eastman have developed active and stable V-Si-P ternary metal oxide catalysts Nb/SiO{sub 2} and Ta/SiO{sub 2} catalysts for the condensation of propionic anhydride and acid with formaldehyde. RTI has demonstrated a novel correlation among the catalyst acid-base properties, condensation reaction yield, and long-term catalyst activity. Current research focuses on enhancing the condensation reaction yields by better understanding of the acid-base property correlation, in situ condensation in a high-temperature, high- pressure (HTHP) slurry reactor, and alternate formaldehyde feedstocks. Based on Eastman and RTI laboratory data, a cost estimate is also being developed for the integrated process.

  19. Synthesis of Methyl Methacrylate from Coal-Derived Syngas

    SciTech Connect (OSTI)

    Gerald N. Choi; James J. Spivey; Jospeh R. Zoeller; Makarand R. Gogate; Richard D. Colberg; Samuel S. Tam

    1998-04-17

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last month, RTI has finalized the design of a fixed-bed microreactor system for DME partial oxidation reactions. RTI incorporated some design changes to the feed blending system, so as to be able to blend varying proportions of DME and oxygen. RTI has also examined the flammability limits of DME-air mixtures. Since the lower flammability limit of DME in air is 3.6 volume percent, RTI will use a nominal feed composition of 1.6 percent in air, which is less than half the lower explosion limit for DME-air mixtures. This nominal feed composition is thus considered operationally safe, for DME partial oxidation reactions. RTI is also currently developing an analytical system for DME partial oxidation reaction system.

  20. Richland Operations Office Cleanup Strategy, Scope

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Richland Operations Office Cleanup Strategy, Scope Matt McCormick Manager Richland Operations Office May 1, 2014 John Ciucci Chief Operating Officer CH2M HILL Plateau Remediation Company Scott Sax President and Project Manager Washington Closure Hanford Frank Armijo President and General Manager Mission Support Alliance www.energy.gov/EM 2 Richland Operations Office Hanford Site History Hanford * Hanford began in 1943 as part of the Manhattan Project * Production of plutonium increased during

  1. Cleanup Progress Report - 2010 | Department of Energy

    Energy Savers [EERE]

    0 Cleanup Progress Report - 2010 In this issue, learn about EM's accomplishments in 2010 across the Oak Ridge Reservation. There are many more stories contained within the issue, but here are some of the highlights from each site. East Tennessee Technology Park K-25 Building West Wing Demolished Contaminated Surface Water, Groundwater at ETTP Addressed Reindustrialization Program Continues Effort to Privatize ETTP Oak Ridge National Laboratory Demolition Completed at 3026 C&D Six Facilities

  2. Cleanup Progress Report - 2012 | Department of Energy

    Energy Savers [EERE]

    2 Cleanup Progress Report - 2012 In this issue, learn about EM's accomplishments in 2012 across the Oak Ridge Reservation. There are many more stories contained within the issue, but here are some of the highlights from each site. East Tennessee Technology Park K-25 Building demolition continues DOE selects commemoration options for K-25 Closure activities continue for TSCA Incinerator Oak Ridge National Laboratory Contaminated Tank W-1A and soil removed Isotope Row material removed Several

  3. Cleanup Progress Report - 2014 | Department of Energy

    Energy Savers [EERE]

    4 Cleanup Progress Report - 2014 Read about EM's accomplishments across the Oak Ridge Reservation in 2014. Some of the stories include: East Tennessee Technology Park K-25 Building demolished K-31 demolition begins Progress continues on commemorating the K-25 Site Parcels transferred as ETTP Reindustrialization progresses Oak Ridge National Laboratory Waste handling plan approved for Molten Salt Reactor Experiment Facility Prep work continues for U-233 disposition Y-12 National Security Complex

  4. Cleanup Progress Report - 2015 | Department of Energy

    Energy Savers [EERE]

    5 Cleanup Progress Report - 2015 Read about EM's accomplishments across the Oak Ridge Reservation in 2015. Some of the stories include: East Tennessee Technology Park K-31 Building demolition completed K-27 Building demolition will eliminate final ETTP gaseous diffusion facility K-1037 demo prep begins K-25 historic preservation efforts progress Reindustrialization Program continues land reuse efforts Oak Ridge National Laboratory Components removed from Oak Ridge Research Reactor Prep work

  5. Microsoft Word - California_cleanup.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WIPP Completes California Sites Cleanup CARLSBAD, N.M., June 14, 2010 - The U.S. Department of Energy's Carlsbad Field Office (CBFO) has successfully completed its campaign to clean up all defense- related transuranic (TRU) waste at California's Vallecitos Nuclear Center (VNC) near Sunol and Lawrence Livermore National Laboratory (LLNL) Site 300, east of Livermore. The last shipment of defense related TRU waste from VNC was shipped to Idaho National Laboratory on June 7. Following the

  6. Porous Anode Model for Coal Syngas Fuelled SOFC: Combined Mass and Energy Transport Normal to Cell Plane

    SciTech Connect (OSTI)

    Gerdes, K.R.; Gemmen, R.S.

    2008-06-01

    Solid oxide fuel cells are being developed for integrated gasification combined cycle hybrid power systems. It is therefore necessary to evaluate the coupled temperature and concentration profiles for SOFC anodes exposed to coal syngas. In this work the SOFC anode was treated as a porous composite of 50/50 (volume) Ni / YSZ. Porous transport was modeled using the dusty gas model (DGM) and included two pore reactions, namely water gas shift and steam reforming of methane. The thermal transport model considered heat exchange by radiation between the interconnect and SOFC surface, convective transfer from bulk gas flow over the anode, heat generation terms due to pore reactions, and heat generation terms at the electrolyte boundary due to electrochemical reactions, ohmic heating, and concentration polarization. Composition profiles throughout the porous anode were considered for the DGM alone and were compared to the DGM including energy (DGME). The cases examined were for current densities ranging from 0.000-0.750 A/cm2 and for pressures from 1-19 atm absolute. Simulation results predict that the average cell operating temperature will increase 10 to 60°C relative to the furnace wall with inclusion of the energy equations. However, the thermal gradients within the anode are small due to the good thermal conductivity of the Ni-based anode. The effect of inclusion of energy transport on the hydrogen concentration profile is mixed depending on the independent parameter considered, with relative insensitivity to changes in the current density, but modest sensitivity to changes in operating pressure. Consideration of the thermal transport is important for determination of the interaction of coal syngas trace species with the anode, but is less critical for material stability.

  7. Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, G.; Gerdes, K.; Song, X.; Chen, Y.; Shutthanandan, V.; Englehard, M.; Zhu, Z.; Thevuthasan, S.; Gemmen, R.

    2012-01-01

    Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  8. Cleanup of Nuclear Licensed Facility 57

    SciTech Connect (OSTI)

    Jeanjacques, Michel; Bremond, Marie Pierre; Marchand, Carole; Poyau, Cecile; Viallefont, Cecile; Gautier, Laurent; Masure, Frederic

    2008-01-15

    necessary methods of analysis for monitoring it were also developed. The research and development program finally ended on 30 June 1995. The NLF 57 cleanup program was intended to reduce the nuclear and conventional hazards and minimize the quantities of HLW and MLW during the subsequent dismantling work. To facilitate the organization of the cleanup work, it was divided into categories by type: - treatment and removal of nuclear material, - removal of radioactive sources, - treatment and removal of aqueous liquid waste, - treatment and removal of organic effluents, - treatment and removal of solid waste, - pumping out of the PETRUS tank, - flushing and decontamination of the tanks, - cleanup of Buildings 18 and 91/54. To estimate the cost of the operations and to monitor the progress of the work, an indicator system was put in place based on work units representative of the operation. The values of the work units were periodically updated on the basis of experience feedback. The cleanup progress is now 92% complete (06/12/31): - treatment and removal of nuclear material: 100%, - removal of radioactive sources: 100%, - treatment and removal of aqueous liquid waste: 64%, - treatment and removal of organic effluents: 87%, - treatment and removal of solid waste: 99%, - pumping out of the PETRUS tank: 69%, - flushing and decontamination of tank: 75%, - section cleaning of Buildings 18 and 91/: 90%. The DRSN/SAFAR is the delegated Project Owner for cleanup and dismantling operations. It is also the prime contractor for the cleanup and dismantling operations. SAFAR itself is responsible for operations relating to the CEA activity and those with technical risks (Removal of nuclear materials, Removal of radioactive sources, Pumping out plutonium and transuranic contaminated solvent and Flushing and decontamination of tanks and pipes). All other operations are sub-contracted to specialist companies. The NLF57 cleanup program as executed is capable of attaining activity levels

  9. Effects of Combustion-Induced Vortex Breakdown on Flashback Limits of Syngas-Fueled Gas Turbine Combustors

    SciTech Connect (OSTI)

    Ahsan Choudhuri

    2011-03-31

    Turbine combustors of advanced power systems have goals to achieve very low pollutants emissions, fuel variability, and fuel flexibility. Future generation gas turbine combustors should tolerate fuel compositions ranging from natural gas to a broad range of syngas without sacrificing operational advantages and low emission characteristics. Additionally, current designs of advanced turbine combustors use various degrees of swirl and lean premixing for stabilizing flames and controlling high temperature NOx formation zones. However, issues of fuel variability and NOx control through premixing also bring a number of concerns, especially combustor flashback and flame blowout. Flashback is a combustion condition at which the flame propagates upstream against the gas stream into the burner tube. Flashback is a critical issue for premixed combustor designs, because it not only causes serious hardware damages but also increases pollutant emissions. In swirl stabilized lean premixed turbine combustors onset of flashback may occur due to (i) boundary layer flame propagation (critical velocity gradient), (ii) turbulent flame propagation in core flow, (iii) combustion instabilities, and (iv) upstream flame propagation induced by combustion induced vortex breakdown (CIVB). Flashback due to first two foregoing mechanisms is a topic of classical interest and has been studied extensively. Generally, analytical theories and experimental determinations of laminar and turbulent burning velocities model these mechanisms with sufficient precision for design usages. However, the swirling flow complicates the flashback processes in premixed combustions and the first two mechanisms inadequately describe the flashback propensity of most practical combustor designs. The presence of hydrogen in syngas significantly increases the potential for flashback. Due to high laminar burning velocity and low lean flammability limit, hydrogen tends to shift the combustor operating conditions towards

  10. Synthesis of acrylates and Methacrylates from Coal-Derived Syngas

    SciTech Connect (OSTI)

    1997-05-12

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the U.S. Department of Energy, Federal Energy Technology Center. This three-step process consists of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Eastman has focused on the propionate synthesis step. The resultant Mo catalysts work efficiently at much less severe conditions (170{degrees}C and 30 atm) than the conventional Ni catalysts (270{degrees} C and 180 atm). Bechtel has performed an extensive cost analysis which shows that Eastman`s propionate synthesis step is competitive with other technologies to produce the anhydride. Eastman and Bechtel have also compared the RTI- Eastman-Bechtel three-step methanol route to five other process routes to MMA. The results show that the product MMA can be produced at 520/lb, for a 250 Mlb/year MMA plant, and this product cost is competitive to all other process routes to MMA, except propyne carbonylation. In the second step, RTI and Eastman have developed active and stable V-SI-P tertiary metal oxide catalysts, Nb/Si0{sub 2}, and Ta/Si0{sub 2} catalysts for condensation of propionic anhydride or propionic acid with formaldehyde. RTI has demonstrated a novel correlation among the catalyst acid-base properties, condensation reaction yield, and long-term catalyst performance. Eastman and Bechtel have used the RTI experimental results of a 20 percent Nb/Si0{sub 2} catalyst, in terms of reactant conversions, MAA selectivities, and MAA yield, for their economic analysis. Recent research focuses on enhancing the condensation reaction yields, a better understanding of the acid-base property correlation and enhancing the catalyst lifetime.

  11. Biomass Gas Cleanup Using a Therminator

    SciTech Connect (OSTI)

    Dayton, David C; Kataria, Atish; Gupta, Rabhubir

    2012-03-06

    The objective of the project is to develop and demonstrate a novel fluidized-bed process module called a Therminator to simultaneously destroy and/or remove tar, NH3 and H2S from raw syngas produced by a fluidized-bed biomass gasifier. The raw syngas contains as much as 10 g/m3 of tar, 4,000 ppmv of NH3 and 100 ppmv of H2S. The goal of the Therminator module would be to use promising regenerable catalysts developed for removing tar, ammonia, and H2S down to low levels (around 10 ppm). Tars are cracked to a non-condensable gas and coke that would deposit on the acid catalyst. We will deposit coke, much like a fluid catalytic cracker (FCC) in a petroleum refinery. The deposited coke fouls the catalyst, much like FCC, but the coke would be burned off in the regenerator and the regenerated catalyst would be returned to the cracker. The rapid circulation between the cracker and regenerator would ensure the availability of the required amount of regenerated catalyst to accomplish our goal. Also, by removing sulfur down to less than 10 ppmv, NH3 decomposition would also be possible in the cracker at 600-700°C. In the cracker, tar decomposes and lays down coke on the acid sites of the catalyst, NH3 is decomposed using a small amount of metal (e.g., nickel or iron) catalyst incorporated into the catalyst matrix, and H2S is removed by a small amount of a metal oxide (e.g. zinc oxide or zinc titanate) by the H2S-metal oxide reaction to form metal sulfide. After a tolerable decline in activity for these reactions, the catalyst particles (and additives) are transported to the regenerator where they are exposed to air to remove the coke and to regenerate the metal sulfide back to metal oxide. Sulfate formation is avoided by running the regeneration with slightly sub-stoichiometric quantity of oxygen. Following regeneration, the catalyst is transported back to the cracker and the cycling continues. Analogous to an FCC reactor system, rapid cycling will allow the use of very

  12. Washington Closure Hanford: Ten Years of River Corridor Cleanup |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Washington Closure Hanford: Ten Years of River Corridor Cleanup Washington Closure Hanford: Ten Years of River Corridor Cleanup December 17, 2015 - 12:30pm Addthis Contract-Timeline-E1511010_4-B_756px.jpg This timeline shows contractor Washington Closure Hanford's accomplishments over the past 10 years through its River Corridor Closure Contract. Addthis Related Articles EM Update Newsletter Spotlights River Corridor Cleanup at Hanford Site River Corridor Achievements

  13. OFFICE OF ENVIRONMENTAL MANAGEMENT NAMES NEW IDAHO CLEANUP MANAGER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Danielle Miller (208) 526-5709 For Immediate Release May 30, 2014 OFFICE OF ENVIRONMENTAL MANAGEMENT NAMES NEW IDAHO CLEANUP MANAGER Idaho Falls, ID - The U.S. Department of Energy Office of Environmental Management today announced that John (Jack) Zimmerman has been named Deputy Manager of its highly-successful Idaho Cleanup program, which oversees the environmental cleanup and waste management mission at DOE's Idaho site. Mr. Zimmerman has more than 25 years of experience in nuclear

  14. The Office of Environmental Management Non-Defense Environmental Cleanup |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Non-Defense Environmental Cleanup The Office of Environmental Management Non-Defense Environmental Cleanup Microsoft Word - 8E2A4440.doc (100.45 KB) More Documents & Publications Microsoft Word - PSRP Updates 6-25-10_v2 The Office of Environmental Management (EM) Defense Environmental Cleanup The Office of Environmental Management Uranium Enrichment D&D

  15. November 2015 Newsletter - Los Alamos Field Office Legacy Cleanup |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy November 2015 Newsletter - Los Alamos Field Office Legacy Cleanup November 2015 Newsletter - Los Alamos Field Office Legacy Cleanup November 30, 2015 - 12:00pm Addthis TA-21-286 being demolished TA-21-286 being demolished Safety Safety and health record for October is clean Safe storage plan for nitrate salts has been completed and implemented. Contracts/Acquisition Removing concrete at the airport landfill Los Alamos Legacy Cleanup Bridge Contract commenced October 1

  16. Environmental Remediation program completes legacy mercury cleanup near

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Smith's Marketplace Stories » Legacy slope-side cleanup Environmental Remediation program completes legacy mercury cleanup near Smith's Marketplace Los Alamos National Laboratory performed a high-angle canyon-side cleanup on U.S. Department of Energy property just south of Smith's Marketplace. May 1, 2015 A telescoping crane hoists a spider excavator over Los Alamos Canyon before placing it on the canyon slope to excavate historically contaminated soil. In ongoing efforts to reduce the

  17. Energy Technology Engineering Center (ETEC) Cleanup By the Numbers |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Technology Engineering Center (ETEC) Cleanup By the Numbers Energy Technology Engineering Center (ETEC) Cleanup By the Numbers Energy Technology Engineering Center (ETEC) Cleanup By the Numbers In 2015, EM developed site infographics highlighting each sites history and important metrics including: Decontamination and demolition of facilities and waste sites Secure storage of spent fuel Retrieval of radioactive sludge and saltcake from tanks Treatment of

  18. Lab receives an additional $19 million for environmental cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab receives an additional $19 million for environmental cleanup Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue: September 1, 2016 all issues All Issues » submit Lab receives an additional $19 million for environmental cleanup Lab also selects local businesses for five-year contracts June 1, 2013 Governor Susana Martinez visited the Lab in May to urge additional funding for cleanup Governor Susana Martinez visited the Lab in May to

  19. IDAHO OPERATIONS OFFICE NAMES NEW IDAHO CLEANUP PROJECT MANAGER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    doe logo Media Contact: Brad Bugger (208) 526-0833 For Immediate Release: Wednesday, June 29, 2011 IDAHO OPERATIONS OFFICE NAMES NEW IDAHO CLEANUP PROJECT MANAGER Idaho Falls, ID � The Department of Energy Idaho Operations Office today announced that James Cooper has been named deputy manager of its highly-successful Idaho Cleanup Project, which oversees the environmental cleanup and waste management mission at DOE's Idaho site. Cooper has more than 30 years of experience in commercial and

  20. Cleanup Performance Prompts Contract Changes at Hanford's River...

    Office of Environmental Management (EM)

    Performance Prompts Contract Changes at Hanford's River Corridor Cleanup Performance Prompts Contract Changes at Hanford's River Corridor June 30, 2015 - 12:00pm Addthis RICHLAND, ...

  1. Cleanup Contractor Achieves ‘Elite’ Nuclear Material Accountability Status

    Office of Energy Efficiency and Renewable Energy (EERE)

    PADUCAH, Ky. – EM’s cleanup contractor at the Paducah site has received national acclaim for timeliness of reporting and promptness in reconciling nuclear material inventories.

  2. Manhattan Project Truck Unearthed in Recovery Act Cleanup | Department...

    Broader source: Energy.gov (indexed) [DOE]

    A Los Alamos National Laboratory (LANL) excavation crew working on an American Recovery and Reinvestment Act cleanup project has uncovered the remnants of a 1940s military truck ...

  3. Cleanup Contractor at Paducah Site Receives Performance Excellence Award

    Broader source: Energy.gov [DOE]

    PADUCAH, Ky. – The environmental cleanup contractor at EM’s Paducah site has been honored for demonstrating serious commitment to performance improvement principles.

  4. FY14 Guidelines for Brownfields Cleanup Grants | Open Energy...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: FY14 Guidelines for Brownfields Cleanup GrantsPermittingRegulatory...

  5. Idaho Governor Praises DOE, Contractor Effort for Resuming Critical Cleanup

    Office of Environmental Management (EM)

    Project | Department of Energy Governor Praises DOE, Contractor Effort for Resuming Critical Cleanup Project Idaho Governor Praises DOE, Contractor Effort for Resuming Critical Cleanup Project July 30, 2013 - 12:00pm Addthis Idaho Governor C.L. “Butch” Otter discusses the importance of completing the cleanup mission at the Idaho site. Idaho Governor C.L. "Butch" Otter discusses the importance of completing the cleanup mission at the Idaho site. An exterior view of the

  6. Recommendation 220: Recommendation Regarding Maintaining Funding for Cleanup

    Broader source: Energy.gov [DOE]

    The Environmental Management Site-Specific Advisory Board recommends that funding for cleanup at DOE sites should be maintained as a top priority.

  7. Secretary Chu, Governor Gregoire Issue Statement on Hanford Cleanup

    Broader source: Energy.gov [DOE]

    U.S. Energy Secretary Steven Chu and Governor Chris Gregoire issued a joint statement on the cleanup efforts underway at Hanford.

  8. Workers at Hanford Site Achieve Recovery Act Legacy Cleanup Goals...

    Office of Environmental Management (EM)

    Recovery and Reinvestment Act goals to accelerate the cleanup of legacy waste and fuels. Workers recently achieved three waste management goals ahead of a Sept. 30, 2011 target. ...

  9. Abandoned Uranium Mine Technical Services and Cleanup Industry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abandoned Uranium Mine Technical Services and Cleanup Industry Day In January 2015, the United States (U.S.) and the Anadarko Litigation Trust ("Litigation Trust") entered into a...

  10. Example Cleanup: Removal of Polychlorinated Biphenyls from Hillside...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Example Cleanup Removal of Polychlorinated Biphenyls from Hillside 140 Removing the source is one of three defenses in depth, as illustrated at the PCB removal from Hillside 140. ...