National Library of Energy BETA

Sample records for temperature solid element

  1. Room Temperature Dispenser Photocathode Using Elemental Cesium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Room Temperature Dispenser Photocathode Using Elemental Cesium Room Temperature Dispenser Photocathode Using Elemental Cesium Los Alamos National Laboratory (LANL) researchers have...

  2. High temperature solid state storage cell

    DOE Patents [OSTI]

    Rea, Jesse R.; Kallianidis, Milton; Kelsey, G. Stephen

    1983-01-01

    A completely solid state high temperature storage cell comprised of a solid rechargeable cathode such as TiS.sub.2, a solid electrolyte which remains solid at the high temperature operating conditions of the cell and which exhibits high ionic conductivity at such elevated temperatures such as an electrolyte comprised of lithium iodide, and a solid lithium or other alkali metal alloy anode (such as a lithium-silicon alloy) with 5-50% by weight of said anode being comprised of said solid electrolyte.

  3. DYNA3D Material Model 71 - Solid Element Test Problem

    SciTech Connect (OSTI)

    Zywicz, E

    2008-01-24

    A general phenomenological-based elasto-plastic nonlinear isotropic strain hardening material model was implemented in DYNA3D for use in solid, beam, truss, and shell elements. The constitutive model, Model 71, is based upon conventional J2 plasticity and affords optional temperature and rate dependence (visco-plasticity). The expressions for strain hardening, temperature dependence, and rate dependence allow it to represent a wide variety of material responses. Options to capture temperature changes due to adiabatic heating and thermal straining are incorporated into the constitutive framework as well. The verification problem developed for this constitutive model consists of four uni-axial right cylinders subject to constant true strain-rate boundary conditions. Three of the specimens have different constant strain rates imposed, while the fourth specimen is subjected to several strain rate jumps. The material parameters developed by Fehlmann (2005) for 21-6-9 Nitronic steel are utilized. As demonstrated below, the finite element (FE) simulations are in excellent agreement with the theoretical responses and indicated the model is functioning as desired. Consequently, this problem serves as both a verification problem and regression test problem for DYNA3D.

  4. Support tube for high temperature solid electrolyte electrochemical cell

    DOE Patents [OSTI]

    Ruka, Roswell J.; Rossing, Barry R.

    1986-01-01

    Disclosed is a compound having a fluorite-like structure comprising a solid solution having the general formula [(ZrO.sub.2).sub.1-x (MO.sub.s).sub.x ].sub.1-y [(La.sub.m A.sub.1-m).sub.2-z (Mn.sub.n B.sub.1-n).sub.z O.sub.r ].sub.y where MO.sub.5 is an oxide selected from the group consisting of calcia, yttria, rare earth oxides, and mixtures thereof, x is about 0.1 to 0.3, y is about 0.005 to about 0.06, z is about 0.1 to about 1.9, A is yttrium, rare earth element, alkaline earth element, or mixture thereof, B is iron, nickel, cobalt, or mixture thereof, m is 0.3 to 1, n is 0.5 to 1, and r is 2 to 4. A porous tube made from such a composition can be coated with an electrically conducting mixed oxide electrode such as lanthanum manganite, and can be used in making high temperature electrochemical cells such as solid electrolyte fuel cells.

  5. High temperature thermoelectric properties of the solid-solution...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: High temperature thermoelectric properties of the solid-solution zintl phase EuCd6-xZnxSb Citation Details In-Document Search Title: High temperature ...

  6. The NSLS 100 element solid state array detector

    SciTech Connect (OSTI)

    Furenlid, L.R.; Kraner, H.W.; Rogers, L.C.; Stephani, D.; Beuttenmuller, R.H.; Beren, J. ); Cramer, S.P. . Dept. of Applied Science)

    1991-01-01

    X-ray absorption studies of dilute samples require fluorescence detection techniques. Since signal-to-noise ratios are governed by the ratio of fluorescent to scattered photons counted by a detector, solid state detectors which can discriminate between fluorescence and scattered photons have become the instruments of choice for trace element measurements. Commercially available 13 element Ge array detectors permitting total count rates < 500,000 counts per second are now in routine use. Since x-ray absorption beamlines at high brightness synchrotron sources can already illuminate most dilute samples with enough flux to saturate the current generation of solid state detectors, the development of next-generation instruments with significantly higher total count rates is essential. We present the design and current status of the 100 element Si array detector being developed in a collaboration between the NSLS and the Instrumentation Division at Brookhaven National Laboratory. The detecting array consists of a 10*10 matrix of 4mm * 4mm elements laid out on a single piece of ultra-high purity silicon mounted at the front end of a liquid nitrogen dewar assembly. A matrix of charge sensitive integrating preamplifiers feed signals to an array of shaping amplifiers, single channel analyzers, and scalers. An electronic switch, delay amplifier, linear gate, digital scope, peak sensing A to D converter, and histogramming memory module provide for complete diagnostics and channel calibration. The entire instrument is controlled by a LabView 2 application on a MacII ci; the software also provides full control over beamline hardware and performs the data collection.

  7. The NSLS 100 element solid state array detector

    SciTech Connect (OSTI)

    Furenlid, L.R.; Kraner, H.W.; Rogers, L.C.; Stephani, D.; Beuttenmuller, R.H.; Beren, J.; Cramer, S.P.

    1991-12-31

    X-ray absorption studies of dilute samples require fluorescence detection techniques. Since signal-to-noise ratios are governed by the ratio of fluorescent to scattered photons counted by a detector, solid state detectors which can discriminate between fluorescence and scattered photons have become the instruments of choice for trace element measurements. Commercially available 13 element Ge array detectors permitting total count rates < 500,000 counts per second are now in routine use. Since x-ray absorption beamlines at high brightness synchrotron sources can already illuminate most dilute samples with enough flux to saturate the current generation of solid state detectors, the development of next-generation instruments with significantly higher total count rates is essential. We present the design and current status of the 100 element Si array detector being developed in a collaboration between the NSLS and the Instrumentation Division at Brookhaven National Laboratory. The detecting array consists of a 10*10 matrix of 4mm * 4mm elements laid out on a single piece of ultra-high purity silicon mounted at the front end of a liquid nitrogen dewar assembly. A matrix of charge sensitive integrating preamplifiers feed signals to an array of shaping amplifiers, single channel analyzers, and scalers. An electronic switch, delay amplifier, linear gate, digital scope, peak sensing A to D converter, and histogramming memory module provide for complete diagnostics and channel calibration. The entire instrument is controlled by a LabView 2 application on a MacII ci; the software also provides full control over beamline hardware and performs the data collection.

  8. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Isenberg, Arnold O.; Ruka, Roswell J.

    1986-01-01

    A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

  9. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Isenberg, Arnold O.; Ruka, Roswell J.; Zymboly, Gregory E.

    1985-01-01

    A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

  10. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Isenberg, Arnold O.; Ruka, Roswell J.

    1987-01-01

    A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

  11. High temperature solid electrolyte fuel cell configurations and interconnections

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills, PA)

    1984-01-01

    High temperature fuel cell configurations and interconnections are made including annular cells having a solid electrolyte sandwiched between thin film electrodes. The cells are electrically interconnected along an elongated axial outer surface.

  12. Solid oxide fuel cell operable over wide temperature range

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    2001-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  13. Novel Low Temperature Solid State Fuel Cells

    SciTech Connect (OSTI)

    Chen, Chonglin; Nash, Patrick; Liu, Jian; Collins, Gregory

    2009-12-15

    We have successfully fabricated (PrBa)Co{sub 2}O{sub 5+{delta}} and (LaBa)Co{sub 2}O{sub 5+{deleta}} epitaxial thin film on various single crystal substrates. Physical and electrochemical properties characterizations were carried out. Highly conductive oxygen-deficient double perovskite LnBaCo2O5+? thin films were grown on single crystal (001) SrTiO{sub 3} (STO), (001) MgO, (001) LaAlO{sub 3} and (110) NdGaO{sub 3} substrate by pulsed laser deposition. Microstructure studies from synchrotron X-ray diffraction and Transmission electron microscopy. High temperature transport properties was carried in different atmosphere (O{sub 2},Air, N{sub 2}) up to ~900K. Resistance response of (LaBa)Co{sub 2}O{sub 5+{delta}} epitaxial thin film was characterized in oxygen, nitrogen and 4% hydrogen over a wide range of temperature from 400?C up to 800?C. To determine the electrode performance and oxygen exchange kinetics of PrBaCo{sub 2}O{sub 5+{delta}}, multi-layered thin film based half cell was deposited on LaAlO{sub 3}(001) substrate. The temperature dependence of the resistance of this half ?cell structure was characterized by electrochemical impedance spectroscopy (EIS) within different temperature and gas environments. Anode supported fuel cells, with GCO:YSZ multilayer thin film as electrolyte and PBCO thin film as electrode, are fabricated on tape casted NiO/YSZ substrate. Full cell performance is characterized up to 800?C.

  14. High temperature solid oxide fuel development activities

    SciTech Connect (OSTI)

    Ray, E.R.

    1993-11-01

    This paper presents an overview of the Westinghouse tubular SOFC development activities and current program status. Goal is to develop a cell that can operate for 50,000 to 100,000 h. Test results are presented for multiple single cell tests which have now successfully exceeded 40,000 hours of continuous power operation at temperature. Two 25-kW SOFC customer tests units were delivered in 1992; a 20-kW SOFC system is bein manufactured and will be operated by Southern California Edison in 1995. Megawatt class generators are being developed.

  15. High temperature solid lubricant materials for heavy duty and advanced heat engines

    SciTech Connect (OSTI)

    DellaCorte, C.; Wood, J.C.

    1994-10-01

    Advanced engine designs incorporate higher mechanical and thermal loading to achieve efficiency improvements. This approach often leads to higher operating temperatures of critical sliding elements (e.g. piston ring/cylinder wall contacts and valve guides) which compromise the use of conventional and even advanced synthetic liquid lubricants. For these applications solid lubricants must be considered. Several novel solid lubricant composites and coatings designated PS/PM200 have been employed to dry and marginally oil lubricated contacts in advanced heat engines. These applications include cylinder kits of heavy duty diesels, and high temperature sterling engines, sidewall seals of rotary engines and various exhaust valve and exhaust component applications. The following paper describes the tribological and thermophysical properties of these tribomaterials and reviews the results of applying them to engine applications. Other potential tribological materials and applications are also discussed with particular emphasis to heavy duty and advanced heat engines.

  16. SEACAS Theory Manuals: Part III. Finite Element Analysis in Nonlinear Solid Mechanics

    SciTech Connect (OSTI)

    Laursen, T.A.; Attaway, S.W.; Zadoks, R.I.

    1999-03-01

    This report outlines the application of finite element methodology to large deformation solid mechanics problems, detailing also some of the key technological issues that effective finite element formulations must address. The presentation is organized into three major portions: first, a discussion of finite element discretization from the global point of view, emphasizing the relationship between a virtual work principle and the associated fully discrete system, second, a discussion of finite element technology, emphasizing the important theoretical and practical features associated with an individual finite element; and third, detailed description of specific elements that enjoy widespread use, providing some examples of the theoretical ideas already described. Descriptions of problem formulation in nonlinear solid mechanics, nonlinear continuum mechanics, and constitutive modeling are given in three companion reports.

  17. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Singh, P.; Vasilow, T.R.; Richards, V.L.

    1996-05-14

    The invention is comprised of an electrically conducting doped or admixed cerium oxide composition with niobium oxide and/or tantalum oxide for electrochemical devices, characterized by the general formula: Nb{sub x}Ta{sub y}Ce{sub 1{minus}x{minus}y}O{sub 2} where x is about 0.0 to 0.05, y is about 0.0 to 0.05, and x+y is about 0.02 to 0.05, and where x is preferably about 0.02 to 0.05 and y is 0, and a method of making the same is also described. This novel composition is particularly applicable in forming a protective interlayer of a high temperature, solid electrolyte electrochemical cell, characterized by a first electrode; an electrically conductive interlayer of niobium and/or tantalum doped cerium oxide deposited over at least a first portion of the first electrode; an interconnect deposited over the interlayer; a solid electrolyte deposited over a second portion of the first electrode, the first portion being discontinuous from the second portion; and, a second electrode deposited over the solid electrolyte. The interlayer is characterized as being porous and selected from the group consisting of niobium doped cerium oxide, tantalum doped cerium oxide, and niobium and tantalum doped cerium oxide or admixtures of the same. The first electrode, an air electrode, is a porous layer of doped lanthanum manganite, the solid electrolyte layer is a dense yttria stabilized zirconium oxide, the interconnect layer is a dense, doped lanthanum chromite, and the second electrode, a fuel electrode, is a porous layer of nickel-zirconium oxide cermet. The electrochemical cell can take on a plurality of shapes such as annular, planar, etc. and can be connected to a plurality of electrochemical cells in series and/or in parallel to generate electrical energy. 5 figs.

  18. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Singh, Prabhakar; Vasilow, Theodore R.; Richards, Von L.

    1996-01-01

    The invention comprises of an electrically conducting doped or admixed cerium oxide composition with niobium oxide and/or tantalum oxide for electrochemical devices, characterized by the general formula: Nb.sub.x Ta.sub.y Ce.sub.1-x-y O.sub.2 where x is about 0.0 to 0.05, y is about 0.0 to 0.05, and x+y is about 0.02 to 0.05, and where x is preferably about 0.02 to 0.05 and y is 0, and a method of making the same. This novel composition is particularly applicable in forming a protective interlayer of a high temperature, solid electrolyte electrochemical cell (10), characterized by a first electrode (12); an electrically conductive interlayer (14) of niobium and/or tantalum doped cerium oxide deposited over at least a first portion (R) of the first electrode; an interconnect (16) deposited over the interlayer; a solid electrolyte (18) deposited over a second portion of the first electrode, the first portion being discontinuous from the second portion; and, a second electrode (20) deposited over the solid electrolyte. The interlayer (14) is characterized as being porous and selected from the group consisting of niobium doped cerium oxide, tantalum doped cerium oxide, and niobium and tantalum doped cerium oxide or admixtures of the same. The first electrode (12), an air electrode, is a porous layer of doped lanthanum manganite, the solid electrolyte layer (18) is a dense yttria stabilized zirconium oxide, the interconnect layer (16) is a dense, doped lanthanum chromite, and the second electrode (20), a fuel electrode, is a porous layer of nickel-zirconium oxide cermet. The electrochemical cell (10) can take on a plurality of shapes such as annular, planar, etc. and can be connected to a plurality of electrochemical cells in series and/or in parallel to generate electrical energy.

  19. Temperature Dependence of the Mechanical Properties of Equiatomic Solid Solution Alloys with FCC Crystal Structures

    SciTech Connect (OSTI)

    Wu, Zhenggang; Bei, Hongbin; Pharr, George M.; George, Easo P.

    2014-10-03

    We found that compared to decades-old theories of strengthening in dilute solid solutions, the mechanical behavior of concentrated solid solutions is relatively poorly understood. A special subset of these materials includes alloys in which the constituent elements are present in equal atomic proportions, including the high-entropy alloys of recent interest. A unique characteristic of equiatomic alloys is the absence of “solvent” and “solute” atoms, resulting in a breakdown of the textbook picture of dislocations moving through a solvent lattice and encountering discrete solute obstacles. Likewise, to clarify the mechanical behavior of this interesting new class of materials, we investigate here a family of equiatomic binary, ternary and quaternary alloys based on the elements Fe, Ni, Co, Cr and Mn that were previously shown to be single-phase face-centered cubic (fcc) solid solutions. The alloys were arc-melted, drop-cast, homogenized, cold-rolled and recrystallized to produce equiaxed microstructures with comparable grain sizes. Tensile tests were performed at an engineering strain rate of 10-3 s-1 at temperatures in the range 77–673 K. Unalloyed fcc Ni was processed similarly and tested for comparison. The flow stresses depend to varying degrees on temperature, with some (e.g. NiCoCr, NiCoCrMn and FeNiCoCr) exhibiting yield and ultimate strengths that increase strongly with decreasing temperature, while others (e.g. NiCo and Ni) exhibit very weak temperature dependencies. Moreover, to better understand this behavior, the temperature dependencies of the yield strength and strain hardening were analyzed separately. Lattice friction appears to be the predominant component of the temperature-dependent yield stress, possibly because the Peierls barrier height decreases with increasing temperature due to a thermally induced increase of dislocation width. In the early stages of plastic flow (5–13% strain, depending on material), the temperature dependence of strain hardening is due mainly to the temperature dependence of the shear modulus. In all the equiatomic alloys, ductility and strength increase with decreasing temperature down to 77 K. Keywords

  20. Temperature Dependence of the Mechanical Properties of Equiatomic Solid Solution Alloys with FCC Crystal Structures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Zhenggang; Bei, Hongbin; Pharr, George M.; George, Easo P.

    2014-10-03

    We found that compared to decades-old theories of strengthening in dilute solid solutions, the mechanical behavior of concentrated solid solutions is relatively poorly understood. A special subset of these materials includes alloys in which the constituent elements are present in equal atomic proportions, including the high-entropy alloys of recent interest. A unique characteristic of equiatomic alloys is the absence of “solvent” and “solute” atoms, resulting in a breakdown of the textbook picture of dislocations moving through a solvent lattice and encountering discrete solute obstacles. Likewise, to clarify the mechanical behavior of this interesting new class of materials, we investigate heremore » a family of equiatomic binary, ternary and quaternary alloys based on the elements Fe, Ni, Co, Cr and Mn that were previously shown to be single-phase face-centered cubic (fcc) solid solutions. The alloys were arc-melted, drop-cast, homogenized, cold-rolled and recrystallized to produce equiaxed microstructures with comparable grain sizes. Tensile tests were performed at an engineering strain rate of 10-3 s-1 at temperatures in the range 77–673 K. Unalloyed fcc Ni was processed similarly and tested for comparison. The flow stresses depend to varying degrees on temperature, with some (e.g. NiCoCr, NiCoCrMn and FeNiCoCr) exhibiting yield and ultimate strengths that increase strongly with decreasing temperature, while others (e.g. NiCo and Ni) exhibit very weak temperature dependencies. Moreover, to better understand this behavior, the temperature dependencies of the yield strength and strain hardening were analyzed separately. Lattice friction appears to be the predominant component of the temperature-dependent yield stress, possibly because the Peierls barrier height decreases with increasing temperature due to a thermally induced increase of dislocation width. In the early stages of plastic flow (5–13% strain, depending on material), the temperature dependence of strain hardening is due mainly to the temperature dependence of the shear modulus. In all the equiatomic alloys, ductility and strength increase with decreasing temperature down to 77 K. Keywords« less

  1. DEGRADATION ISSUES IN SOLID OXIDE CELLS DURING HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    J. E. O'Brien; C. M. Stoots; V. I. Sharma; B. Yildiz; A. V. Virkar

    2010-06-01

    Idaho National Laboratory (INL) is performing high-temperature electrolysis research to generate hydrogen using solid oxide electrolysis cells (SOECs). The project goals are to address the technical and degradation issues associated with the SOECs. This paper provides a summary of various ongoing INL and INL sponsored activities aimed at addressing SOEC degradation. These activities include stack testing, post-test examination, degradation modeling, and a list of issues that need to be addressed in future. Major degradation issues relating to solid oxide fuel cells (SOFC) are relatively better understood than those for SOECs. Some of the degradation mechanisms in SOFCs include contact problems between adjacent cell components, microstructural deterioration (coarsening) of the porous electrodes, and blocking of the reaction sites within the electrodes. Contact problems include delamination of an electrode from the electrolyte, growth of a poorly (electronically) conducting oxide layer between the metallic interconnect plates and the electrodes, and lack of contact between the interconnect and the electrode. INLs test results on high temperature electrolysis (HTE) using solid oxide cells do not provide a clear evidence whether different events lead to similar or drastically different electrochemical degradation mechanisms. Post-test examination of the solid oxide electrolysis cells showed that the hydrogen electrode and interconnect get partially oxidized and become non-conductive. This is most likely caused by the hydrogen stream composition and flow rate during cool down. The oxygen electrode side of the stacks seemed to be responsible for the observed degradation due to large areas of electrode delamination. Based on the oxygen electrode appearance, the degradation of these stacks was largely controlled by the oxygen electrode delamination rate. University of Utah (Virkar) has developed a SOEC model based on concepts in local thermodynamic equilibrium in systems otherwise in global thermodynamic non-equilibrium. This model is under continued development. It shows that electronic conduction through the electrolyte, however small, must be taken into account for determining local oxygen chemical potential, within the electrolyte. The chemical potential within the electrolyte may lie out of bounds in relation to values at the electrodes in the electrolyzer mode. Under certain conditions, high pressures can develop in the electrolyte just under the oxygen electrode (anode)/electrolyte interface, leading to electrode delamination. This theory is being further refined and tested by introducing some electronic conduction in the electrolyte.

  2. Degradation in Solid Oxide Cells During High Temperature Electrolysis

    SciTech Connect (OSTI)

    Manohar Sohal

    2009-05-01

    Idaho National Laboratory has an ongoing project to generate hydrogen from steam using solid oxide electrolysis cells. One goal of that project is to address the technical and degradation issues associated with solid oxide electrolysis cells. This report covers a variety of these degradation issues, which were discussed during a workshop on Degradation in Solid Oxide Electrolysis Cells and Strategies for its Mitigation, held in Phoenix, AZ on October 27, 2008. Three major degradation issues related to solid oxide electrolysis cells discussed at the workshop are: Delamination of O2-electrode and bond layer on steam/O2-electrode side Contaminants (Ni, Cr, Si, etc.) on reaction sites (triple-phase boundary) Loss of electrical/ionic conductivity of electrolyte. This list is not all inclusive, but the workshop summary can be useful in providing a direction for future research related to the degradation of solid oxide electrolysis cells.

  3. Solid state thin film battery having a high temperature lithium alloy anode

    DOE Patents [OSTI]

    Hobson, David O.

    1998-01-01

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

  4. Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells

    SciTech Connect (OSTI)

    Chen, Fanglin; Zhao, Fei; Liu, Qiang

    2015-10-06

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  5. Density functional and theoretical study of the temperature and pressure dependency of the plasmon energy of solids

    SciTech Connect (OSTI)

    Attarian Shandiz, M. Gauvin, R.

    2014-10-28

    The temperature and pressure dependency of the volume plasmon energy of solids was investigated by density functional theory calculations. The volume change of crystal is the major factor responsible for the variation of valence electron density and plasmon energy in the free electron model. Hence, to introduce the effect of temperature and pressure for the density functional theory calculations of plasmon energy, the temperature and pressure dependency of lattice parameter was used. Also, by combination of the free electron model and the equation of state based on the pseudo-spinodal approach, the temperature and pressure dependency of the plasmon energy was modeled. The suggested model is in good agreement with the results of density functional theory calculations and available experimental data for elements with the free electron behavior.

  6. High strength porous support tubes for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Rossing, Barry R.; Zymboly, Gregory E.

    1986-01-01

    A high temperature, solid electrolyte electrochemical cell is made, having an electrode and a solid electrolyte disposed on a porous, sintered support material containing thermally stabilized zirconia powder particles and from about 3 wt. % to about 45 wt. % of thermally stable oxide fibers.

  7. EA-0510: High-Temperature Solid Oxide Fuel Cell (Sofc) Generator Development Project (METC), Churchill, Pennsylvania

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to enter into a 5-year cooperative agreement with the Westinghouse Electric Corporation for the development of high-temperature solid oxide...

  8. High temperature solid electrolyte fuel cell with ceramic electrodes

    DOE Patents [OSTI]

    Bates, J.L.; Marchant, D.D.

    A solid oxide electrolyte fuel cell is described having a central electrolyte comprised of a HfO/sub 2/ or ZrO/sub 2/ ceramic stabilized and rendered ionically conductive by the addition of Ca, Mg, Y, La, Nd, Sm, Gd, Dy Er, or Yb. The electrolyte is sandwiched between porous electrodes of a HfO/sub 2/ or ZrO/sub 2/ ceramic stabilized by the addition of a rare earth and rendered electronically conductive by the addition of In/sub 2/O/sub 3/. Alternatively, the anode electrode may be made of a metal such as Co, Ni, Ir Pt, or Pd.

  9. High temperature solid electrolyte fuel cell with ceramic electrodes

    DOE Patents [OSTI]

    Marchant, David D.; Bates, J. Lambert

    1984-01-01

    A solid oxide electrolyte fuel cell is described having a central electrolyte comprised of a HfO.sub.2 or ZrO.sub.2 ceramic stabilized and rendered ionically conductive by the addition of Ca, Mg, Y, La, Nd, Sm, Gd, Dy Er, or Yb. The electrolyte is sandwiched between porous electrodes of a HfO.sub.2 or ZrO.sub.2 ceramic stabilized by the addition of a rare earth and rendered electronically conductive by the addition of In.sub.2 O.sub.3. Alternatively, the anode electrode may be made of a metal such as Co, Ni, Ir Pt, or Pd.

  10. Rapid low-temperature epitaxial growth using a hot-element assisted chemical vapor deposition process

    DOE Patents [OSTI]

    Iwancizko, Eugene; Jones, Kim M.; Crandall, Richard S.; Nelson, Brent P.; Mahan, Archie Harvin

    2001-01-01

    The invention provides a process for depositing an epitaxial layer on a crystalline substrate, comprising the steps of providing a chamber having an element capable of heating, introducing the substrate into the chamber, heating the element at a temperature sufficient to decompose a source gas, passing the source gas in contact with the element; and forming an epitaxial layer on the substrate.

  11. HIGH-TEMPERATURE TUBULAR SOLID OXIDE FUEL CELL GENERATOR DEVELOPMENT

    SciTech Connect (OSTI)

    S.E. Veyo

    1998-09-01

    During the Westinghouse/USDOE Cooperative Agreement period of November 1, 1990 through November 30, 1997, the Westinghouse solid oxide fuel cell has evolved from a 16 mm diameter, 50 cm length cell with a peak power of 1.27 watts/cm to the 22 mm diameter, 150 cm length dimensions of today's commercial prototype cell with a peak power of 1.40 watts/cm. Accompanying the increase in size and power density was the elimination of an expensive EVD step in the manufacturing process. Demonstrated performance of Westinghouse's tubular SOFC includes a lifetime cell test which ran for a period in excess of 69,000 hours, and a fully integrated 25 kWe-class system field test which operated for over 13,000 hours at 90% availability with less than 2% performance degradation over the entire period. Concluding the agreement period, a 100 kW SOFC system successfully passed its factory acceptance test in October 1997 and was delivered in November to its demonstration site in Westervoort, The Netherlands.

  12. Solid state thin film battery having a high temperature lithium alloy anode

    DOE Patents [OSTI]

    Hobson, D.O.

    1998-01-06

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

  13. Characterization of high-current, high-temperature superconductor current lead elements

    SciTech Connect (OSTI)

    Niemann, R.C.; Evans, D.J.; Fisher, B.L.; Brockenborough, W.E.; Roberts, P.R.; Rodenbush, A.J.

    1996-08-01

    The refrigeration loads of current leads for superconducting magnets can be significantly reduced by using high-temperature superconductor (HTS) leads. An HTS conductor type that is well suited for this application is a laminated sintered stack of HTS powder-in-tube (PIT) tapes. The superconducting elements are normally characterized by their manufacturer by measuring critical currents at 77 K in self field. Additional characterization, which correlates electrical performance at 77 K and at lower temperatures with applied magnetic fields, provides the current lead designer and conductor element manufacturer with critical information. For HTS conductor elements comprising a laminated and sintered stack of Bi-2223 PIT tapes having an alloyed Ag sheath, this characterization uses variable applied fields and operating temperatures.

  14. Improved Laser Induced Breakdown Spectroscopy (LIBS) Elemental Composition Detection System: A device to measure subsurface gases, liquids, and solids at subsurface conditions

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2016-02-23

    This device can measure subsurface gases, liquids, and solids at subsurface conditions. Atomic identification and concentration measurements can be made on solids, liquids, and gases at down hole pressure and temperature conditions....

  15. Development of high temperature solid lubricant coatings. Final report, 15 August 1997--14 August 1998

    SciTech Connect (OSTI)

    Bhattacharya, R.S.; Keller, S.

    1999-01-29

    The primary research objective of this work was to develop a solid lubricant coating that can function over a broad temperature range. The approach investigated consisted of developing adaptive lubricant coating from materials that undergo chemical change with increasing temperature by reacting together and with the environment. To test this approach, UES and Cleveland State University have conducted experiments to form cesium oxythiotungstate, a high temperature lubricant, on Inconel 718 surface from composite coatings of cesium tungstate and tungsten sulfide. The coatings were deposited by RF sputtering and characterized by X-ray Photoelectron Spectroscopy (XPS). The results indicate that sulfur escapes from the composite coating upon exposure to temperature above 5000C in air. Thus, the desired adaptive lubricant phase, cesium oxythiotungstate could not be formed. However, cesium oxythiotungstate phase has been found to form upon annealing at high temperature in vacuum. The friction coefficients of sputtered cesium oxythiotungstate and cesium tungstate coatings have been measured.

  16. Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures

    SciTech Connect (OSTI)

    Sirwardane, Ranjani V.

    2005-06-21

    New low-cost CO2 sorbents are provided that can be used in large-scale gas-solid processes. A new method is provided for making these sorbents that involves treating substrates with an amine and/or an ether so that the amine and/or ether comprise at least 50 wt. percent of the sorbent. The sorbent acts by capturing compounds contained in gaseous fluids via chemisorption and/or physisorption between the unit layers of the substrate's lattice where the polar amine liquids and solids and/or polar ether liquids and solids are located. The method eliminates the need for high surface area supports and polymeric materials for the preparation of CO2 capture systems, and provides sorbents with absorption capabilities that are independent of the sorbents' surface areas. The sorbents can be regenerated by heating at temperatures in excess of 35 degrees C.

  17. Solid sorbents for removal of carbon dioxide from gas streams at low temperatures

    DOE Patents [OSTI]

    Sirwardane, Ranjani V.

    2005-06-21

    New low-cost CO.sub.2 sorbents are provided that can be used in large-scale gas-solid processes. A new method is provided for making these sorbents that involves treating substrates with an amine and/or an ether so that the amine and/or ether comprise at least 50 wt. percent of the sorbent. The sorbent acts by capturing compounds contained in gaseous fluids via chemisorption and/or physisorption between the unit layers of the substrate's lattice where the polar amine liquids and solids and/or polar ether liquids and solids are located. The method eliminates the need for high surface area supports and polymeric materials for the preparation of CO.sub.2 capture systems, and provides sorbents with absorption capabilities that are independent of the sorbents' surface areas. The sorbents can be regenerated by heating at temperatures in excess of 35.degree. C.

  18. Thermal element for maintaining minimum lamp wall temperature in fluorescent fixtures

    DOE Patents [OSTI]

    Siminovitch, Michael J.

    1992-01-01

    In a lighting fixture including a lamp and a housing, an improvement is disclosed for maintaining a lamp envelope area at a cooler, reduced temperature relative to the enclosed housing ambient. The improvement comprises a thermal element in thermal communication with the housing extending to and springably urging thermal communication with a predetermined area of the lamp envelope surface.

  19. Thermal element for maintaining minimum lamp wall temperature in fluorescent fixtures

    DOE Patents [OSTI]

    Siminovitch, M.J.

    1992-11-10

    In a lighting fixture including a lamp and a housing, an improvement is disclosed for maintaining a lamp envelope area at a cooler, reduced temperature relative to the enclosed housing ambient. The improvement comprises a thermal element in thermal communication with the housing extending to and springably urging thermal communication with a predetermined area of the lamp envelope surface. 12 figs.

  20. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus

    DOE Patents [OSTI]

    Zaromb, S.

    1994-06-21

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity [>=]10[sup [minus]4] (ohm-cm)[sup [minus]1], and preferably [>=]0.01 (ohm-cm)[sup [minus]1]. The conductivity may be due predominantly to Ag[sup +] ions, as in Ag[sub 2]WO[sub 4], or to F[sup [minus

  1. Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells

    DOE Patents [OSTI]

    Kuo, Lewis J. H.; Singh, Prabhakar; Ruka, Roswell J.; Vasilow, Theodore R.; Bratton, Raymond J.

    1997-01-01

    A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators.

  2. Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells

    DOE Patents [OSTI]

    Kuo, L.J.H.; Singh, P.; Ruka, R.J.; Vasilow, T.R.; Bratton, R.J.

    1997-11-11

    A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators. 4 figs.

  3. DYNA3D: A nonlinear, explicit, three-dimensional finite element code for solid and structural mechanics

    SciTech Connect (OSTI)

    Whirley, R.G.

    1991-05-01

    This report is the User Manual for the 1991 version of DYNA3D, and also serves as an interim User Guide. DYNA3D is a nonlinear, explicit, finite element code for analyzing the transient dynamic response of three-dimensional solids and structures. The code is fully vectorized and is available on several computer platforms. DYNA3D includes solid, shell, beam, and truss elements to allow maximum flexibility in modeling physical problems. Many material models are available to represent a wide range of material behavior, including elasticity, plasticity, composites, thermal effects, and rate dependence. In addition, DYNA3D has a sophisticated contact interface capability, including frictional sliding and single surface contact. Rigid materials provide added modeling flexibility. A material model driver with interactive graphics display is incorporated into DYNA3D to permit accurate modeling of complex material response based on experimental data. Along with the DYNA3D Example Problem Manual, this document provides the information necessary to apply DYNA3D to solve a wide range of engineering analysis problems. 73 refs., 49 figs.

  4. Microwave plasma monitoring system for the elemental composition analysis of high temperature process streams

    DOE Patents [OSTI]

    Woskov, Paul P.; Cohn, Daniel R.; Titus, Charles H.; Surma, Jeffrey E.

    1997-01-01

    Microwave-induced plasma for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, high temperature capability refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury. The invention may be incorporated into a high temperature process device and implemented in situ for example, such as with a DC graphite electrode plasma arc furnace. The invention further provides a system for the elemental analysis of process streams by removing particulate and/or droplet samples therefrom and entraining such samples in the gas flow which passes through the plasma flame. Introduction of and entraining samples in the gas flow may be facilitated by a suction pump, regulating gas flow, gravity or combinations thereof.

  5. Paradyn a parallel nonlinear, explicit, three-dimensional finite-element code for solid and structural mechanics user manual

    SciTech Connect (OSTI)

    Hoover, C G; DeGroot, A J; Sherwood, R J

    2000-06-01

    ParaDyn is a parallel version of the DYNA3D computer program, a three-dimensional explicit finite-element program for analyzing the dynamic response of solids and structures. The ParaDyn program has been used as a production tool for over three years for analyzing problems which range in size from a few tens of thousands of elements to between one-million and ten-million elements. ParaDyn runs on parallel computers provided by the Department of Energy Accelerated Strategic Computing Initiative (ASCI) and the Department of Defense High Performance Computing and Modernization Program. Preprocessing and post-processing software utilities and tools are designed to facilitate the generation of partitioned domains for processors on a massively parallel computer and the visualization of both resultant data and boundary data generated in a parallel simulation. This manual provides a brief overview of the parallel implementation; describes techniques for running the ParaDyn program, tools and utilities; and provides examples of parallel simulations.

  6. Element

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Departmental Element 2. System Name/ Major Application Name 3. Location 4. Name of System Owner/ Information or Data Owner 5. Contact Information 6. Does the system collect or maintain Social Security numbers? 7. Source of Legal Requirement/Authority to Collect or Maintain Social Security Numbers? 8. Does the system have a Privacy Impact Assessment (PIA)? 9. Does the system have a System of Records Notice (SORN)? If yes, provide the name of the System of Records Notice. 10. Does the system

  7. Low-temperature synthesis of actinide tetraborides by solid-state metathesis reactions

    DOE Patents [OSTI]

    Lupinetti, Anthony J.; Garcia, Eduardo; Abney, Kent D.

    2004-12-14

    The synthesis of actinide tetraborides including uranium tetraboride (UB.sub.4), plutonium tetraboride (PuB.sub.4) and thorium tetraboride (ThB.sub.4) by a solid-state metathesis reaction are demonstrated. The present method significantly lowers the temperature required to .ltoreq.850.degree. C. As an example, when UCl.sub.4 is reacted with an excess of MgB.sub.2, at 850.degree. C., crystalline UB.sub.4 is formed. Powder X-ray diffraction and ICP-AES data support the reduction of UCl.sub.3 as the initial step in the reaction. The UB.sub.4 product is purified by washing water and drying.

  8. Porous nuclear fuel element for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2011-03-01

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  9. Methods for manufacturing porous nuclear fuel elements for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2010-02-23

    Methods for manufacturing porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's). Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, a thin coating of nuclear fuel may be deposited inside of a highly porous skeletal structure made, for example, of reticulated vitreous carbon foam.

  10. Porous nuclear fuel element with internal skeleton for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2013-09-03

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  11. A reduced temperature solid oxide fuel cell with three-dimensionally ordered macroporous cathode

    SciTech Connect (OSTI)

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-01-01

    Three-dimensionally ordered macroporous cathode was fabricated for a zirconia based micro-tubular solid oxide fuel cells (SOFCs). Three different cathodes (cathode A, no pore former; cathode B, with pore former (1.5 {micro}m in diameter); cathode C, with pore former (0.8 {micro}m in diameter)) were compared to investigate how the microstructure of it affected the cell performance at various operating temperatures. Micro-sized pores were well distributed within cathode B and C. The total porosity of cathode A is 35%, while it respectively reached 42 and 50% for cathodes B and C. At the same time, the specific surface area of them was 28.8 and 52.0% larger than that of the cathode A. As a result, the peak power density of the zirconia based cell, with cathode C, was 0.25 and 0.56 W cm{sup -2} at 550 and 600 C, while the respective value was just 0.11 and 0.30 W cm{sup -2} for the cell with cathode A. Thus, optimizing microstructure of cathode should be one of the best approaches for lowering the operating temperature for SOFCs.

  12. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus

    DOE Patents [OSTI]

    Zaromb, Solomon

    1994-01-01

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

  13. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus and methods

    DOE Patents [OSTI]

    Zaromb, Solomon

    2001-01-01

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

  14. High temperature fuel/emitter system for advanced thermionic fuel elements

    SciTech Connect (OSTI)

    Moeller, Helen H.; Bremser, Albert H.; Gontar, Alexander; Fiviesky, Evgeny

    1997-01-10

    Specialists in space applications are currently focusing on bimodal power systems designed to provide both electric power and thermal propulsion (Kennedy, 1994 and Houts, 1995). Our work showed that thermionics is a viable technology for nuclear bimodal power systems. We demonstrated that materials for a thermionic fuel-emitter combination capable of performing at operating temperatures of 2473 K are not only possible but available. The objective of this work, funded by the US Department of Energy, Office of Space and Defense Power Systems, was to evaluate the compatibility of fuel material consisting of an uranium carbide/tantalum carbide solid solution with an emitter material consisting of a monocrystalline tungsten-niobium alloy. The uranium loading of the fuel material was 70 mole% uranium carbide. The program was successfully accomplished by a B and W/SIA LUTCH team. Its workscope was integrated with tasks being performed at both Babcock and Wilcox, Lynchburg Research Center, Lynchburg, Virginia, and SIA LUTCH, Podolsk, Russia. Samples were fabricated by LUTCH and seven thermal tests were performed in a hydrogen atmosphere. The first preliminary test was performed at 2273 K by LUTCH, and the remaining six tests were performed At B and W. Three tests were performed at 2273 K, two at 2373 K, and the final test at 2473 K. The results showed that the fuel and emitter materials were compatible in the presence of hydrogen. No evidence of liquid formation, dissolution of the uranium carbide from the uranium carbide/tantalum carbide solid solution, or diffusion of the uranium into the monocrystalline tungsten alloy was observed. Among the highlights of the program was the successful export of the fuel samples from Russia and their import into the US by commercial transport. This paper will discuss the technical aspects of this work.

  15. Novel Electrode Materials for Low-Temperature Solid-Oxide Fuel Cells

    SciTech Connect (OSTI)

    Shaowu Zha; Meilin Liu

    2005-03-23

    Composites electrodes consisting of silver and bismuth vanadates exhibit remarkable catalytic activity for oxygen reduction at 500-550 C and greatly reduce the cathode-electrolyte (doped ceria) resistances of low temperature SOFCs, down to about 0.53 {omega}cm{sup 2} at 500 C and 0.21 {omega}cm{sup 2} at 550 C. The observed power densities of 231, 332, and 443 mWcm-2 at 500, 525 and 550 C, respectively, make it possible to operate SOFCs at temperatures about 500 C. Fuel cell performance depends strongly on the anode microstructure, which is determined by the anode compositions and fabrication conditions. Four types of anodes with two kinds of NiO and GDC powders were investigated. By carefully adjusting the anode microstructure, the GDC electrolyte/anode interfacial polarization resistances reduced dramatically. The interfacial resistance at 600 C decreased from 1.61 {omega} cm{sup 2} for the anodes prepared using commercially available powders to 0.06 {omega} cm{sup 2} for those prepared using powders derived from a glycine-nitrate process. Although steam reforming or partial oxidation is effective in avoiding carbon deposition of hydrocarbon fuels, it increases the operating cost and reduces the energy efficiency. Anode-supported SOFCs with an electrolyte of 20 {micro}m-thick Gd-doped ceria (GDC) were fabricated by co-pressing. A catalyst (1 %wt Pt dispersed on porous Gd-doped ceria) for pre-reforming of propane was developed with relatively low steam to carbon (S/C) ratio ({approx}0.5), coupled with direct utilization of the reformate in low-temperature SOFCs. Propane was converted to smaller molecules during pre-reforming, including H{sub 2}, CH{sub 4}, CO, and CO{sub 2}. A peak power density of 247 mW/cm{sup 2} was observed when pre-reformed propane was directly fed to an SOFC operated at 600 C. No carbon deposition was observed in the fuel cell for a continuous operation of 10 hours at 600 C. The ability of producing vastly different microstructures and morphologies of the very same material is critical to the fabrication of functionally graded electrodes for solid-state electrochemical devices such as SOFCs and lithium batteries. By carefully adjusting deposition parameters, we have successfully produced oxide nano-powders with the size of 30 {approx} 200 nm. Porous films with various microstructures and morphologies are also deposited on several substrates by systematic adjustment of the deposition parameters. Highly porous, excellently bonded and nano-structured electrodes fabricated by combustion CVD exhibit extremely high surface area and remarkable catalytic activities. Using in situ potential dependent FTIR emission spectroscopy, we have found evidence for two, possibly three distinct di-oxygen species present on the electrode surface. We have successfully identified which surface oxygen species is present under a particular electrical or chemical condition and have been able to deduce the reaction mechanisms. This technique will be used to probe the gas-solid interactions at or near the TPB and on the surfaces of mixed-conducting electrodes in an effort to understand the molecular processes relevant to the intrinsic catalytic activity. Broad spectral features are assigned to the electrochemical-polarization-induced changes in the optical properties of the electrode surface layer.

  16. A green synthesis of a layered titanate, potassium lithium titanate; lower temperature solid-state reaction and improved materials performance

    SciTech Connect (OSTI)

    Ogawa, Makoto; Morita, Masashi; Igarashi, Shota; Sato, Soh

    2013-10-15

    A layered titanate, potassium lithium titanate, with the size range from 0.1 to 30 m was prepared to show the effects of the particle size on the materials performance. The potassium lithium titanate was prepared by solid-state reaction as reported previously, where the reaction temperature was varied. The reported temperature for the titanate preparation was higher than 800 C, though 600 C is good enough to obtain single-phase potassium lithium titanate. The lower temperature synthesis is cost effective and the product exhibit better performance as photocatalysts due to surface reactivity. - Graphical abstract: Finite particle of a layered titanate, potassium lithium titanate, was prepared by solid-state reaction at lower temperature to show modified materials performance. Display Omitted - Highlights: Potassium lithium titanate was prepared by solid-state reaction. Lower temperature reaction resulted in smaller sized particles of titanate. 600 C was good enough to obtain single phased potassium lithium titanate. The product exhibited better performance as photocatalyst.

  17. A High Temperature Electrochemical Energy Storage System Based on Sodium Beta-Alumina Solid Electrolyte (Base)

    SciTech Connect (OSTI)

    Anil Virkar

    2008-03-31

    This report summarizes the work done during the period September 1, 2005 and March 31, 2008. Work was conducted in the following areas: (1) Fabrication of sodium beta{double_prime} alumina solid electrolyte (BASE) using a vapor phase process. (2) Mechanistic studies on the conversion of {alpha}-alumina + zirconia into beta{double_prime}-alumina + zirconia by the vapor phase process. (3) Characterization of BASE by X-ray diffraction, SEM, and conductivity measurements. (4) Design, construction and electrochemical testing of a symmetric cell containing BASE as the electrolyte and NaCl + ZnCl{sub 2} as the electrodes. (5) Design, construction, and electrochemical evaluation of Na/BASE/ZnCl{sub 2} electrochemical cells. (6) Stability studies in ZnCl{sub 2}, SnCl{sub 2}, and SnI{sub 4} (7) Design, assembly and testing of planar stacks. (8) Investigation of the effect of porous surface layers on BASE on cell resistance. The conventional process for the fabrication of sodium ion conducting beta{double_prime}-alumina involves calcination of {alpha}-alumina + Na{sub 2}CO{sub 3} + LiNO{sub 3} at 1250 C, followed by sintering powder compacts in sealed containers (platinum or MgO) at {approx}1600 C. The novel vapor phase process involves first sintering a mixture of {alpha}-alumina + yttria-stabilized zirconia (YSZ) into a dense ceramic followed by exposure to soda vapor at {approx}1450 C to convert {alpha}-alumina into beta{double_prime}-alumina. The vapor phase process leads to a high strength BASE, which is also resistant to moisture attack, unlike BASE made by the conventional process. The PI is the lead inventor of the process. Discs and tubes of BASE were fabricated in the present work. In the conventional process, sintering of BASE is accomplished by a transient liquid phase mechanism wherein the liquid phase contains NaAlO{sub 2}. Some NaAlO{sub 2} continues to remain at grain boundaries; and is the root cause of its water sensitivity. In the vapor phase process, NaAlO{sub 2} is never formed. Conversion occurs by a coupled transport of Na{sup +} through BASE formed and of O{sup 2-} through YSZ to the reaction front. Transport to the reaction front is described in terms of a chemical diffusion coefficient of Na{sub 2}O. The conversion kinetics as a function of microstructure is under investigation. The mechanism of conversion is described in this report. A number of discs and tubes of BASE have been fabricated by the vapor phase process. The material was investigated by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM), before and after conversion. Conductivity (which is almost exclusively due to sodium ion transport at the temperatures of interest) was measured. Conductivity was measured using sodium-sodium tests as well as by impedance spectroscopy. Various types of both planar and tubular electrochemical cells were assembled and tested. In some cases the objective was to determine if there was any interaction between the salt and BASE. The interaction of interest was mainly ion exchange (possible replacement of sodium ion by the salt cation). It was noted that Zn{sup 2+} did not replace Na+ over the conditions of interest. For this reason much of the work was conducted with ZnCl{sub 2} as the cathode salt. In the case of Sn-based, Sn{sup 2+} did ion exchange, but Sn{sup 4+} did not. This suggests that Sn{sup 4+} salts are viable candidates. These results and implications are discussed in the report. Cells made with Na as the anode and ZnCl{sub 2} as the cathode were successfully charged/discharged numerous times. The key advantages of the batteries under investigation here over the Na-S batteries are: (1) Steel wool can be used in the cathode compartment unlike Na-S batteries which require expensive graphite. (2) Planar cells can be constructed in addition to tubular, allowing for greater design flexibility and integration with other devices such as planar SOFC. (3) Comparable or higher open circuit voltage (OCV) than the Na-S battery. (4) Wider operating temperature range and higher temper

  18. Performance evaluation of ZnO–CuO hetero junction solid state room temperature ethanol sensor

    SciTech Connect (OSTI)

    Yu, Ming-Ru; Suyambrakasam, Gobalakrishnan; Wu, Ren-Jang; Department of Nanotechnology, School of Interdisciplinary Courses, Noorul Islam Centre for Higher Education, Noorul Islam University, Kumaracoil 629180, Tamil Nadu ; Chavali, Murthy; Department of Applied Chemistry, Providence University, 200 Chungchi Road, Shalu, Taichung Hsien 433, Taiwan, R.O.C

    2012-07-15

    Graphical abstract: Sensor response (resistance) curves of time were changed from 150 ppm to 250 ppm alcohol concentration of ZnO–CuO 1:1. The response and recovery times were measured to be 62 and 83 s, respectively. The sensing material ZnO–CuO is a high potential alcohol sensor which provides a simple, rapid and highly sensitive alcohol gas sensor operating at room temperature. Highlights: ► The main advantages of the ethanol sensor are as followings. ► Novel materials ZnO–CuO ethanol sensor. ► The optimized ZnO–CuO hetero contact system. ► A good sensor response and room working temperature (save energy). -- Abstract: A semiconductor ethanol sensor was developed using ZnO–CuO and its performance was evaluated at room temperature. Hetero-junction sensor was made of ZnO–CuO nanoparticles for sensing alcohol at room temperature. Nanoparticles were prepared by hydrothermal method and optimized with different weight ratios. Sensor characteristics were linear for the concentration range of 150–250 ppm. Composite materials of ZnO–CuO were characterized using X-ray diffraction (XRD), temperature-programmed reduction (TPR) and high-resolution transmission electron microscopy (HR-TEM). ZnO–CuO (1:1) material showed maximum sensor response (S = R{sub air}/R{sub alcohol}) of 3.32 ± 0.1 toward 200 ppm of alcohol vapor at room temperature. The response and recovery times were measured to be 62 and 83 s, respectively. The linearity R{sup 2} of the sensor response was 0.9026. The sensing materials ZnO–CuO (1:1) provide a simple, rapid and highly sensitive alcohol gas sensor operating at room temperature.

  19. Low Temperature Solid-State NMR Spectroscopy. A Strategy for the Direct Observation of Quadrupolar Nuclides of Biological Interest.

    SciTech Connect (OSTI)

    Ellis, Paul D.; Lipton, Andrew S.

    2007-01-01

    This review presents a self-contained summary of the experimental methods necessary to perform a low temperature solid-state NMR experiment. Specific references are made for Zn? and Mg?. However, this is not a comprehensive review of the NMR literature of these nuclides. As the review is concerned with solid-state NMR spectroscopy of quadrupolar nuclides, we limit the discussions to odd-half-integral spin systems, i.e. 3/2, 5/2, 7/2, and 9/2 spins. The reason for the limitation is due to the relative ease of observing the central transition, which is common to all of these nuclides. The review is divided into two major sections; the first dealing with experimental methods, e.g. use of low temperature, magnetization transfer, spin echo methods, and questions dealing with nonspecific binding. Following those discussions we turn to the introduction of structure into the experiment, i.e. the use triple resonance experiments to selectively introduce dipolar interactions and the use of molecular theory.

  20. Laser generated proton beam focusing and high temperature isochoric heating of solid matter

    SciTech Connect (OSTI)

    Snavely, R. A.; Hatchett, S. P.; Key, M. H.; Langdon, A. B.; Lasinski, B. F.; MacKinnon, A. J.; Patel, P.; Town, R.; Wilks, S. C.; Zhang, B.; Akli, K.; Hey, D.; King, J.; Chen, Z.; Izawa, Y.; Kitagawa, Y.; Kodama, R.; Lei, A.; Tampo, M.; Tanaka, K. A.

    2007-09-15

    The results of laser-driven proton beam focusing and heating with a high energy (170 J) short pulse are reported. Thin hemispherical aluminum shells are illuminated with the Gekko petawatt laser using 1 {mu}m light at intensities of {approx}3x10{sup 18} W/cm{sup 2} and measured heating of thin Al slabs. The heating pattern is inferred by imaging visible and extreme-ultraviolet light Planckian emission from the rear surface. When Al slabs 100 {mu}m thick were placed at distances spanning the proton focus beam waist, the highest temperatures were produced at 0.94x the hemisphere radius beyond the equatorial plane. Isochoric heating temperatures reached 81 eV in 15 {mu}m thick foils. The heating with a three-dimensional Monte Carlo model of proton transport with self-consistent heating and proton stopping in hot plasma was modeled.

  1. DYNA3D: A nonlinear, explicit, three-dimensional finite element code for solid and structural mechanics, User manual. Revision 1

    SciTech Connect (OSTI)

    Whirley, R.G.; Engelmann, B.E.

    1993-11-01

    This report is the User Manual for the 1993 version of DYNA3D, and also serves as a User Guide. DYNA3D is a nonlinear, explicit, finite element code for analyzing the transient dynamic response of three-dimensional solids and structures. The code is fully vectorized and is available on several computer platforms. DYNA3D includes solid, shell, beam, and truss elements to allow maximum flexibility in modeling physical problems. Many material models are available to represent a wide range of material behavior, including elasticity, plasticity, composites, thermal effects, and rate dependence. In addition, DYNA3D has a sophisticated contact interface capability, including frictional sliding and single surface contact. Rigid materials provide added modeling flexibility. A material model driver with interactive graphics display is incorporated into DYNA3D to permit accurate modeling of complex material response based on experimental data. Along with the DYNA3D Example Problem Manual, this document provides the information necessary to apply DYNA3D to solve a wide range of engineering analysis problems.

  2. Apparatus for measuring tensile and compressive properties of solid materials at cryogenic temperatures

    DOE Patents [OSTI]

    Gonczy, John D.; Markley, Finley W.; McCaw, William R.; Niemann, Ralph C.

    1992-01-01

    An apparatus for evaluating the tensile and compressive properties of material samples at very low or cryogenic temperatures employs a stationary frame and a dewar mounted below the frame. A pair of coaxial cylindrical tubes extend downward towards the bottom of the dewar. A compressive or tensile load is generated hydraulically and is transmitted by the inner tube to the material sample. The material sample is located near the bottom of the dewar in a liquid refrigerant bath. The apparatus employs a displacement measuring device, such as a linear variable differential transformer, to measure the deformation of the material sample relative to the amount of compressive or tensile force applied to the sample.

  3. Solids mass flow determination

    DOE Patents [OSTI]

    Macko, Joseph E.

    1981-01-01

    Method and apparatus for determining the mass flow rate of solids mixed with a transport fluid to form a flowing mixture. A temperature differential is established between the solids and fluid. The temperature of the transport fluid prior to mixing, the temperature of the solids prior to mixing, and the equilibrium temperature of the mixture are monitored and correlated in a heat balance with the heat capacities of the solids and fluid to determine the solids mass flow rate.

  4. High temperature phase stabilities and electrochemical properties of InBaCo4-xZnxO7 cathodes for intermediate temperature solid oxide fuel cells

    SciTech Connect (OSTI)

    Kim, Jung-Hyun; Young Nam, Kim; Bi, Zhonghe; Manthiram, Arumugam; Paranthaman, Mariappan Parans; Huq, Ashfia

    2011-01-01

    InBaCo4-xZnxO7 oxides have been synthesized and characterized as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC). The effect of Zn substitution for Co on the structure, phase stability, thermal expansion, and electrochemical properties of the InBaCo4-xZnxO7 has been investigated. The increase in the Zn content from x = 1 to 1.5 improves the high temperature phase stability at 600 oC and 700 oC for 100 h, and chemical stability against a Gd0.2Ce0.8O1.9 (GDC) electrolyte. Thermal expansion coefficient (TEC) values of the InBaCo4-xZnxO7 (x = 1, 1.5, 2) specimens were determined to be 8.6 10-6 9.6 10-6 /oC in the range of 80 900 oC, which provides good thermal expansion compatibility with the standard SOFC electrolyte materials. The InBaCo4-xZnxO7 + GDC (50:50 wt. %) composite cathodes exhibit improved cathode performances compared to those obtained from the simple InBaCo4-xZnxO7 cathodes due to the extended triple-phase boundary (TPB) and enhanced oxide-ion conductivity through the GDC portion in the composites.

  5. Apparatus for measuring tensile and compressive properties of solid materials at cryogenic temperatures

    DOE Patents [OSTI]

    Gonczy, J.D.; Markley, F.W.; McCaw, W.R.; Niemann, R.C.

    1992-04-21

    An apparatus for evaluating the tensile and compressive properties of material samples at very low or cryogenic temperatures employs a stationary frame and a dewar mounted below the frame. A pair of coaxial cylindrical tubes extend downward towards the bottom of the dewar. A compressive or tensile load is generated hydraulically and is transmitted by the inner tube to the material sample. The material sample is located near the bottom of the dewar in a liquid refrigerant bath. The apparatus employs a displacement measuring device, such as a linear variable differential transformer, to measure the deformation of the material sample relative to the amount of compressive or tensile force applied to the sample. 7 figs.

  6. Temperature activated absorption during laser-induced damage: The evolution of laser-supported solid-state absorption fronts

    SciTech Connect (OSTI)

    Carr, C W; Bude, J D; Shen, N; Demange, P

    2010-10-26

    Previously we have shown that the size of laser induced damage sites in both KDP and SiO{sub 2} is largely governed by the duration of the laser pulse which creates them. Here we present a model based on experiment and simulation that accounts for this behavior. Specifically, we show that solid-state laser-supported absorption fronts are generated during a damage event and that these fronts propagate at constant velocities for laser intensities up to 4 GW/cm{sup 2}. It is the constant absorption front velocity that leads to the dependence of laser damage site size on pulse duration. We show that these absorption fronts are driven principally by the temperature-activated deep sub band-gap optical absorptivity, free electron transport, and thermal diffusion in defect-free silica for temperatures up to 15,000K and pressures < 15GPa. In addition to the practical application of selecting an optimal laser for pre-initiation of large aperture optics, this work serves as a platform for understanding general laser-matter interactions in dielectrics under a variety of conditions.

  7. Electrical connection structure for a superconductor element

    DOE Patents [OSTI]

    Lallouet, Nicolas; Maguire, James

    2010-05-04

    The invention relates to an electrical connection structure for a superconductor element cooled by a cryogenic fluid and connected to an electrical bushing, which bushing passes successively through an enclosure at an intermediate temperature between ambient temperature and the temperature of the cryogenic fluid, and an enclosure at ambient temperature, said bushing projecting outside the ambient temperature enclosure. According to the invention, said intermediate enclosure is filled at least in part with a solid material of low thermal conductivity, such as a polyurethane foam or a cellular glass foam. The invention is applicable to connecting a superconductor cable at cryogenic temperature to a device for equipment at ambient temperature.

  8. Multilayered YSZ/GZO films with greatly enhanced ionic conduction for low temperature solid oxide fuel cells

    SciTech Connect (OSTI)

    Li, Bin; Zhang, Jiaming; Kaspar, Tiffany C.; Shutthanandan, V.; Ewing, Rodney C.; Lian, Jie

    2013-01-01

    Strain confinement in heterostructured films significantly affects ionic conductivity of the electrolytes for solid oxide fuel cells based on a multi-layered design strategy. Nearly ideal tensile strain can be achieved by a dedicated manipulation of the lattice mismatch between adjacent layers and fine control of the layer thicknesses to minimize the formation of dislocations and thus to achieve optimized ionic conduction. This strategy was demonstrated by a model system of multilayered 8 mol%Y2O3 stabilized ZrO2 (YSZ) with Gd2Zr2O7 (GZO) films, which were epitaxially grown on Al2O3 (0001) substrates by pulsed laser deposition (PLD) with the {111} planes of YSZ/GZO along the Al2O3 [0 1 ?1 0] direction. The tensile strain (3%) resulting from the lattice mismatch can be confined in individual YSZ layers with the formation of a coherent, dislocation-free interface upon the manipulation of the layer thickness below a critical value, e.g., down to 5 nm. The strained heterostructure displays a two order-of-magnitude increase in oxide-ion conductivity as compared with bulk YSZ, and a high ionic conductivity of 0.01 S cm?1 at 475 C can be achieved, five times greater than that of Gd-doped ceria/zirconia. The approach of strain confinement by fine control of lattice mismatch and layer thickness represents a promising strategy in developing advanced electrolytes enabling the miniaturization of solid-state ionic devices that can be operated at low temperatures below 500 C.

  9. Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature

    SciTech Connect (OSTI)

    Li, Jiawei; Huo, Juntao; Chang, Chuntao E-mail: dujun@nimte.ac.cn; Du, Juan E-mail: dujun@nimte.ac.cn; Man, Qikui; Wang, Xinmin; Li, Run-Wei; Law, Jiayan

    2014-08-14

    The effects of heavy rare earth (RE) additions on the Curie temperature (T{sub C}) and magnetocaloric effect of the Fe-RE-B-Nb (RE = Gd, Dy and Ho) bulk metallic glasses were studied. The type of dopping RE element and its concentration can easily tune T{sub C} in a large temperature range of 120 K without significantly decreasing the magnetic entropy change (ΔS{sub M}) and refrigerant capacity (RC) of the alloys. The observed values of ΔS{sub M} and RC of these alloys compare favorably with those of recently reported Fe-based metallic glasses with enhanced RC compared to Gd{sub 5}Ge{sub 1.9}Si{sub 2}Fe{sub 0.1}. The tunable T{sub C} and large glass-forming ability of these RE doped Fe-based bulk metallic glasses can be used in a wide temperature range with the final required shapes.

  10. Thermodynamic estimation of minor element distribution between immiscible liquids in Fe-Cu-based metal phase generated in melting treatment of municipal solid wastes

    SciTech Connect (OSTI)

    Lu, X.; Nakajima, K.; Sakanakura, H.; Matsubae, K.; Bai, H.; Nagasaka, T.

    2012-06-15

    Graphical abstract: Display Omitted Highlights: Black-Right-Pointing-Pointer Two liquids separation of metal occurs in the melting of municipal solid waste. Black-Right-Pointing-Pointer The distribution of PGMs etc. between two liquid metal phases is studied. Black-Right-Pointing-Pointer Quite simple thermodynamic model is applied to predict the distribution ratio. Black-Right-Pointing-Pointer Au and Ag originated from WEEE are found to be concentrated into Cu-rich phase. - Abstract: Waste electrical and electronic equipment (WEEE) has become an important target in managing material cycles from the viewpoint of not only waste management and control of environmental pollution but also resource conservation. This study investigated the distribution tendency of trace elements in municipal solid waste (MSW) or incinerator ash, including valuable non-ferrous metals (Ni, Co, Cr, Mn, Mo, Ti, V, W, Zr), precious group metals (PGMs) originated from WEEE (Ag, Au, Pd, Pt), and others (Al, B, Pb, Si), between Fe-rich and Cu-rich metal phases by means of simple thermodynamic calculations. Most of the typical alloying elements for steel (Co, Cr, Mo, Nb, Ni, Si, Ti, V, and W) and Rh were preferentially distributed into the Fe-rich phase. PGMs, such as Au, Ag, and Pd, were enriched in the Cu-rich phase, whereas Pt was almost equally distributed into both phases. Since the primary metallurgical processing of Cu is followed by an electrolysis for refining, and since PGMs in crude copper have been industrially recovered from the resulting anode slime, our results indicated that Ag, Au, and Pd could be effectively recovered from MSW if the Cu-rich phase could be selectively collected.

  11. Calculations of atomic sputtering and displacement cross-sections in solid elements by electrons with energies from threshold to 1. 5 MV

    SciTech Connect (OSTI)

    Bradley, C.R.

    1988-12-01

    The kinetics of knock-on collisions of relativistic electrons with nuclei and details of the numerical evaluation of differential, recoil, and total Mott cross-sections are reviewed and discussed. The effects of electron beam induced displacement and sputtering, in the transmission electron microscope (TEM) environment, on microanalysis are analyzed with particular emphasis placed on the removal of material by knock-on sputtering. The mass loss predicted due to transmission knock-on sputtering is significant for many elements under conditions frequently encountered in microanalysis. Total Mott cross-sections are tabulated for all naturally occurring solid elements up to Z = 92 at displacement energies of one, two, four, and five times the sublimation energy and for accelerating voltages accessible in the transmission electron microscope. Fortran source code listings for the calculation of the differential Mott cross-section as a function of electron scattering angle (dMottCS), as a function of nuclear recoil angle (RECOIL), and the total Mott cross-section (TOTCS) are included. 48 refs., 21 figs., 12 tabs.

  12. Order-parameter-aided temperature-accelerated sampling for the exploration of crystal polymorphism and solid-liquid phase transitions

    SciTech Connect (OSTI)

    Yu, Tang-Qing Vanden-Eijnden, Eric; Chen, Pei-Yang; Chen, Ming; Samanta, Amit; Tuckerman, Mark

    2014-06-07

    The problem of predicting polymorphism in atomic and molecular crystals constitutes a significant challenge both experimentally and theoretically. From the theoretical viewpoint, polymorphism prediction falls into the general class of problems characterized by an underlying rough energy landscape, and consequently, free energy based enhanced sampling approaches can be brought to bear on the problem. In this paper, we build on a scheme previously introduced by two of the authors in which the lengths and angles of the supercell are targeted for enhanced sampling via temperature accelerated adiabatic free energy dynamics [T. Q. Yu and M. E. Tuckerman, Phys. Rev. Lett. 107, 015701 (2011)]. Here, that framework is expanded to include general order parameters that distinguish different crystalline arrangements as target collective variables for enhanced sampling. The resulting free energy surface, being of quite high dimension, is nontrivial to reconstruct, and we discuss one particular strategy for performing the free energy analysis. The method is applied to the study of polymorphism in xenon crystals at high pressure and temperature using the Steinhardt order parameters without and with the supercell included in the set of collective variables. The expected fcc and bcc structures are obtained, and when the supercell parameters are included as collective variables, we also find several new structures, including fcc states with hcp stacking faults. We also apply the new method to the solid-liquid phase transition in copper at 1300 K using the same Steinhardt order parameters. Our method is able to melt and refreeze the system repeatedly, and the free energy profile can be obtained with high efficiency.

  13. Upward shift of the vortex solid phase in high-temperature-superconducting wires through high density nanoparticle addition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miura, Masashi; Maiorov, Boris; Balakirev, Fedor F.; Kato, Takeharu; Sato, Michio; Takagi, Yuji; Izumi, Teruo; Civale, Leonardo

    2016-02-08

    Here, we show a simple and effective way to improve the vortex irreversibility line up to very high magnetic fields (60T) by increasing the density of second phase BaZrO3 nanoparticles. (Y0.77,Gd0.23)Ba2Cu3Oy films were grown on metal substrates with different concentration of BaZrO3 nanoparticles by the metal organic deposition method. We find that upon increase of the BaZrO3 concentration, the nanoparticle size remains constant but the twin-boundary density increases. Up to the highest nanoparticle concentration (n ~ 1.3 × 1022/m3), the irreversibility field (Hirr) continues to increase with no sign of saturation up to 60 T, although the vortices vastly outnumbermore » pinning centers. We find extremely high Hirr, namely Hirr = 30 T (H||45°) and 24 T (H||c) at 65 K and 58 T (H||45°) and 45 T (H||c) at 50K. The difference in pinning landscape shifts the vortex solid-liquid transition upwards, increasing the vortex region useful for power applications, while keeping the upper critical field, critical temperature and electronic mass anisotropy unchanged.« less

  14. Manipulation of Zeeman coherence in solids at room temperature: Ramsey interference in the coherent-population-trapping spectrum of ruby

    SciTech Connect (OSTI)

    Kolesov, Roman; Scully, Marlan O.; Kocharovskaya, Olga [Department of Physics, Texas A and M University, College Station, Texas 77843-4242 (United States)

    2006-11-15

    Coherent population trapping (CPT) in a three-level atomic medium pumped by two subsequent short optical pulses is considered under the condition of negligible population decay from the excited optical state. It is shown that the amount of atomic population transferred to the excited state by the combined action of the pulses strongly depends on the phase of the ground-state coherence excited by the first pulse at the arrival time of the second pulse. Oscillatory behavior of optical excitation efficiency on the time delay between the pulses is predicted. It is also shown that saturating optical pulses can produce population inversion in a resonantly pumped quasi-two-level system. A class of solid materials in which the predicted phenomena can be observed at room temperature is found. It includes some rare-earth and transition-metal doped dielectric crystals where Orbach relaxation between ground-state Zeeman states is suppressed: ruby, alexandrite, and several others. On the basis of the theoretical predictions, experimental observation of Ramsey fringes in CPT spectrum of ruby is reported.

  15. Neutronic fuel element fabrication

    DOE Patents [OSTI]

    Korton, George

    2004-02-24

    This disclosure describes a method for metallurgically bonding a complete leak-tight enclosure to a matrix-type fuel element penetrated longitudinally by a multiplicity of coolant channels. Coolant tubes containing solid filler pins are disposed in the coolant channels. A leak-tight metal enclosure is then formed about the entire assembly of fuel matrix, coolant tubes and pins. The completely enclosed and sealed assembly is exposed to a high temperature and pressure gas environment to effect a metallurgical bond between all contacting surfaces therein. The ends of the assembly are then machined away to expose the pin ends which are chemically leached from the coolant tubes to leave the coolant tubes with internal coolant passageways. The invention described herein was made in the course of, or under, a contract with the U.S. Atomic Energy Commission. It relates generally to fuel elements for neutronic reactors and more particularly to a method for providing a leak-tight metal enclosure for a high-performance matrix-type fuel element penetrated longitudinally by a multiplicity of coolant tubes. The planned utilization of nuclear energy in high-performance, compact-propulsion and mobile power-generation systems has necessitated the development of fuel elements capable of operating at high power densities. High power densities in turn require fuel elements having high thermal conductivities and good fuel retention capabilities at high temperatures. A metal clad fuel element containing a ceramic phase of fuel intimately mixed with and bonded to a continuous refractory metal matrix has been found to satisfy the above requirements. Metal coolant tubes penetrate the matrix to afford internal cooling to the fuel element while providing positive fuel retention and containment of fission products generated within the fuel matrix. Metal header plates are bonded to the coolant tubes at each end of the fuel element and a metal cladding or can completes the fuel-matrix enclosure by encompassing the sides of the fuel element between the header plates.

  16. Anaerobic digestion of organic fraction of municipal solid waste combining two pretreatment modalities, high temperature microwave and hydrogen peroxide

    SciTech Connect (OSTI)

    Shahriari, Haleh; Warith, Mostafa; Hamoda, Mohamed; Kennedy, Kevin J.

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer Microwave and H{sub 2}O{sub 2} pretreatment were studied to enhance anaerobic digestion of organic waste. Black-Right-Pointing-Pointer The whole waste pretreated at 115 Degree-Sign C or 145 Degree-Sign C had the highest biogas production. Black-Right-Pointing-Pointer Biogas production of the whole waste decreased at 175 Degree-Sign C due to formation of refractory compounds. Black-Right-Pointing-Pointer Pretreatment to 145 Degree-Sign C and 175 Degree-Sign C were the best when considering only the free liquid fraction. Black-Right-Pointing-Pointer H{sub 2}O{sub 2} pretreatment had a lag phase and the biogas production was not higher than MW pretreated samples. - Abstract: In order to enhance anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW), pretreatment combining two modalities, microwave (MW) heating in presence or absence of hydrogen peroxide (H{sub 2}O{sub 2}) were investigated. The main pretreatment variables affecting the characteristics of the OFMSW were temperature (T) via MW irradiation and supplemental water additions of 20% and 30% (SWA20 and SW30). Subsequently, the focus of this study was to evaluate mesophilic batch AD performance in terms of biogas production, as well as changes in the characteristics of the OFMSW post digestion. A high MW induced temperature range (115-175 Degree-Sign C) was applied, using sealed vessels and a bench scale MW unit equipped with temperature and pressure controls. Biochemical methane potential (BMP) tests were conducted on the whole OFMSW as well as the liquid fractions. The whole OFMSW pretreated at 115 Degree-Sign C and 145 Degree-Sign C showed 4-7% improvement in biogas production over untreated OFMSW (control). When pretreated at 175 Degree-Sign C, biogas production decreased due to formation of refractory compounds, inhibiting the digestion. For the liquid fraction of OFMSW, the effect of pretreatment on the cumulative biogas production (CBP) was more pronounced for SWA20 at 145 Degree-Sign C, with a 26% increase in biogas production after 8 days of digestion, compared to the control. When considering the increased substrate availability in the liquid fraction after MW pretreatment, a 78% improvement in biogas production vs. the control was achieved. Combining MW and H{sub 2}O{sub 2} modalities did not have a positive impact on OFMSW stabilization and enhanced biogas production. In general, all samples pretreated with H{sub 2}O{sub 2} displayed a long lag phase and the CBP was usually lower than MW irradiated only samples. First order rate constant was calculated.

  17. GOMA 6.0 : a full-Newton finite element program for free and moving boundary problems with coupled fluid/solid momentum, energy, mass, and chemical species transport : user%3CU%2B2019%3Es guide.

    SciTech Connect (OSTI)

    Schunk, Peter Randall; Rao, Rekha Ranjana; Chen, Ken Shuang; Labreche, Duane A.; Sun, Amy Cha-Tien; Hopkins, Matthew Morgan; Moffat, Harry K.; Roach, Robert Allen; Hopkins, Polly L.; Notz, Patrick K.; Roberts, Scott Alan; Sackinger, Philip A.; Subia, Samuel Ramirez; Wilkes, Edward Dean; Baer, Thomas A.; Noble, David R.; Secor, Robert B.

    2013-07-01

    Goma 6.0 is a finite element program which excels in analyses of multiphysical processes, particularly those involving the major branches of mechanics (viz. fluid/solid mechanics, energy transport and chemical species transport). Goma is based on a full-Newton-coupled algorithm which allows for simultaneous solution of the governing principles, making the code ideally suited for problems involving closely coupled bulk mechanics and interfacial phenomena. Example applications include, but are not limited to, coating and polymer processing flows, super-alloy processing, welding/soldering, electrochemical processes, and solid-network or solution film drying. This document serves as a user's guide and reference.

  18. Solid Cold - C

    Office of Scientific and Technical Information (OSTI)

    How rarely depends on what the temperature is. Suppose our small object is one atom in a solid, and the larger object is all the rest of the solid. Under ordinary conditions, our ...

  19. Effect of pre-oxidation and environmental aging on the seal strength of a novel high-temperature solid oxide fuel cell (SOFC) sealing glass with metallic interconnect

    SciTech Connect (OSTI)

    Chou, Y. S.; Stevenson, Jeffry W.; Singh, Prabhakar

    2008-09-15

    A novel high-temperature alkaline-earth silicate sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was used to join two ferritic stainless steel coupons for strength evaluation. The steel coupons were pre-oxidized at elevated temperatures to promote thick oxide layers to simulate long-term exposure conditions. In addition, seals to as-received metal coupons were also tested after aging in oxidizing or reducing environments to simulate the actual SOFC environment. Room temperature tensile testing showed strength degradation when using pre-oxidized coupons, and more extensive degradation after aging in air. Fracture surface and microstructural analysis confirmed that the cause of degradation was formation of SrCrO4 at the outer sealing edges exposed to air.

  20. REE Sorption Study for Media #1 and Media #2 in Brine #1 and #2 at different Liquid to Solid Ratio's at Ambient Temperature

    SciTech Connect (OSTI)

    Gary Garland

    2015-03-27

    This data set shows the different loading capacities of Media #1 and Media #2 in a high and low salt content brine matrix at different liquid to solid ratio's. These data sets are shaker bath tests on media #1 and media #2 in brine's #1 and #2 at 500mL-.5g(1000-1 ratio), 150mL-.75g(200-1 ratio), and 150mL-2.5g(60-1 ratio) at ambient temperature.

  1. Discrete Element Modeling

    SciTech Connect (OSTI)

    Morris, J; Johnson, S

    2007-12-03

    The Distinct Element Method (also frequently referred to as the Discrete Element Method) (DEM) is a Lagrangian numerical technique where the computational domain consists of discrete solid elements which interact via compliant contacts. This can be contrasted with Finite Element Methods where the computational domain is assumed to represent a continuum (although many modern implementations of the FEM can accommodate some Distinct Element capabilities). Often the terms Discrete Element Method and Distinct Element Method are used interchangeably in the literature, although Cundall and Hart (1992) suggested that Discrete Element Methods should be a more inclusive term covering Distinct Element Methods, Displacement Discontinuity Analysis and Modal Methods. In this work, DEM specifically refers to the Distinct Element Method, where the discrete elements interact via compliant contacts, in contrast with Displacement Discontinuity Analysis where the contacts are rigid and all compliance is taken up by the adjacent intact material.

  2. GOMA - A full-Newton finite element program for free and moving boundary problems with coupled fluid/solid momentum, energy, mass, and chemical species transport: User`s guide

    SciTech Connect (OSTI)

    Schunk, P.R.; Sackinger, P.A.; Rao, R.R.

    1996-01-01

    GOMA is a two- and three-dimensional finite element program which excels in analyses of manufacturing processes, particularly those involving free or moving interfaces. Specifically, the full-Newton-coupled heat, mass, momentum, and pseudo-solid mesh motion algorithm makes GOMA ideally suited for simulating processes in which the bulk fluid transport is closely coupled to the interfacial physics. Examples include, but are not limited to, coating and polymer processing flows, soldering, crystal growth, and solid-network or solution film drying. The code is based on the premise that any boundary can be (1) moving or free, with an apriori unknown position dictated by the distinguishing physics, (2) fixed, according to a global analytical representation, or (3) moving in time and space under user-prescribed kinematics. The goal is to enable the user to predict boundary position or motion simultaneously with the physics of the problem being analyzed and to pursue geometrical design studies and fluid-structure interaction problems. The moving mesh algorithm treats the entire domain as a computational Lagrangian solid that deforms subject to the physical principles which dictate boundary position. As an added benefit, the same Lagrangian solid mechanics can be exploited to solve multi-field problems for which the solid motion and stresses interact with other transport phenomena, either within the same material phase (e.g. shrinking coating) or in neighboring material phases (e.g. flexible blade coating). Thus, analyses of many fluid-structure interaction problems and deformable porous media problems are accessible. This document serves as a user`s guide and reference for GOMA and provides a brief overview of GOMA`s capabilities, theoretical background, and classes of problems for which it is targeted.

  3. High temperature thermoelectric properties of the solid-solution zintl phase Eu₁₁Cd6-xZnxSb₁₂

    SciTech Connect (OSTI)

    Kazem, Nasrin; Hurtado, Antonio; Sui, Fan; Ohno, Saneyuki; Zevalkink, Alexandra; Snyder, Jeffrey G.; Kauzlarich, Susan M.

    2015-08-24

    Solid-solution Zintl compounds with the formulaEu₁₁Cd6-xZnxSb₁₂ have been synthesized from the elements as single crystals using a tin flux according to the stoichiometry Eu:Cd:Zn:Sb:Sn of 11:6–xp:xp:12:30 with xp = 0, 1, 2, 3, 4, 5, and 6, where xp is the preparative amount of Zn employed in the reaction. The crystal structures and the compositions were established by single-crystal as well as powder X-ray diffraction and wavelength-dispersive X-ray analysis measurements. The title solid-solution Zintl compounds crystallize isostructurally in the centrosymmetric monoclinic space group C 2/m (No. 12, Z = 2) as the Sr₁₁Cd₆Sb₁₂ structure type (Pearson symbol mC58). There is a miscibility gap at 3 ≤ xp ≤ 4 where the major product crystallizes in a disordered structure related to the Ca₉Mn₄Bi₉ structure type; otherwise, for all other compositions, the Sr₁₁Cd₆Sb₁₂ structure is the majority phase. Eu₁₁Cd₆Sb₁₂ shows lower lattice thermal conductivity relative to Eu₁₁Zn₆Sb₁₂ consistent with its higher mean atomic weight, and as anticipated, the solid-solution samples of Eu₁₁Cd6–xZnxSb₁₂ have effectively reduced lattice thermal conductivities relative to the end member compounds. Eu₁₁̣̣₀(1)Cd₄̣̣₅(2)Zn₁̣̣₅(2)Sb₁₂̣̣₀(1) exhibits the highest zT value of >0.5 at around 800 K which is twice as large as the end member compounds.

  4. DYNA3D: A nonlinear, explicit, three-dimensional finite element...

    Office of Scientific and Technical Information (OSTI)

    three-dimensional finite element code for solid and structural mechanics, User manual. ... three-dimensional finite element code for solid and structural mechanics, User manual. ...

  5. Multi-element microelectropolishing method

    DOE Patents [OSTI]

    Lee, Peter J.

    1994-01-01

    A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle.

  6. Multi-element microelectropolishing method

    DOE Patents [OSTI]

    Lee, P.J.

    1994-10-11

    A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle. 10 figs.

  7. High Temperature Oxidation Behavior of gamma-Ni+gamma'-Ni3Al Alloys and Coatings Modified with Pt and Reactive Elements

    SciTech Connect (OSTI)

    Nan Mu

    2007-12-01

    Materials for high-pressure turbine blades must be able to operate in the high-temperature gases (above 1000 C) emerging from the combustion chamber. Accordingly, the development of nickel-based superalloys has been constantly motivated by the need to have improved engine efficiency, reliability and service lifetime under the harsh conditions imposed by the turbine environment. However, the melting point of nickel (1455 C) provides a natural ceiling for the temperature capability of nickel-based superalloys. Thus, surface-engineered turbine components with modified diffusion coatings and overlay coatings are used. Theses coatings are capable of forming a compact and adherent oxide scale, which greatly impedes the further transport of reactants between the high-temperature gases and the underlying metal and thus reducing attack by the atmosphere. Typically, these coatings contain {beta}-NiAl as a principal constituent phase in order to have sufficient aluminum content to form an Al{sub 2}O{sub 3} scale at elevated temperatures. The drawbacks to the currently-used {beta}-based coatings, such as phase instabilities, associated stresses induced by such phase instabilities, and extensive coating/substrate interdiffusion, are major motivations in this study to seek next-generation coatings. The high-temperature oxidation resistance of novel Pt + Hf-modified {gamma}-Ni + {gamma}-Ni{sub 3}Al-based alloys and coatings were investigated in this study. Both early-stage and 4-days isothermal oxidation behavior of single-phase {gamma}-Ni and {gamma}{prime}-Ni{sub 3}Al alloys were assessed by examining the weight changes, oxide-scale structures, and elemental concentration profiles through the scales and subsurface alloy regions. It was found that Pt promotes Al{sub 2}O{sub 3} formation by suppressing the NiO growth on both {gamma}-Ni and {gamma}{prime}Ni{sub 3}Al single-phase alloys. This effect increases with increasing Pt content. Moreover, Pt exhibits this effect even at lower temperatures ({approx}970 C) in the very early stage of oxidation. It was also inferred that Pt enhances the diffusive flux of aluminum from the substrate to the scale/alloy interface. Relatively low levels of hafnium addition to Pt-free {gamma}{prime}-Ni{sub 3}Al increased the extent of external NiO formation due to non-protective HfO{sub 2} formation. Accordingly, this effect intensified with increasing Hf content from 0.2 to 0.5 at.%.

  8. (Y0.5In0.5)Ba(Co,Zn)4O7 cathodes with superior high-temperature phase stability for solid oxide fuel cells

    SciTech Connect (OSTI)

    Young Nam, Kim; Kim, Jung-Hyun; Paranthaman, Mariappan Parans; Manthiram, Arumugam; Huq, Ashfia

    2012-01-01

    (Y0.5In0.5)BaCo4-xZnxO7 (1.0 x 2.0) oxides crystallizing in a trigonal P31c structure have been synthesized and explored as cathode materials for solid oxide fuel cells (SOFC). At a given Zn content, the (Y0.5In0.5)BaCo4-xZnxO7 sample with 50 % Y and 50 % In exhibits much improved phase stability at intermediate temperatures (600 - 800 oC) compared to the samples with 100 % Y or In. However, the substitution of Zn for Co in (Y0.5In0.5)Ba(Co4-xZnx)O7 (1.0 x 2.0) decreases the amount of oxygen loss on heating, total electrical conductivity, and cathode performance in SOFC while providing good long-term phase stability at high temperatures. Among the various chemical compositions investigated in the (Y0.5In0.5)Ba(Co4-xZnx)O7 system, the (Y0.5In0.5)BaCo3ZnO7 sample offers a combination of good electrochemical performance and low thermal expansion coefficient (TEC) while maintaining superior phase stability at 600 800 oC for 100 h. Fuel cell performances of the (Y0.5In0.5)Ba(Co3Zn)O7 + Ce0.8Gd0.2O1.9 (GDC) (50 : 50 wt. %) composite cathodes collected with anode-supported single cell reveal a maximum power density value of 521 mW cm-2 at 700 oC.

  9. Solids irradiator

    DOE Patents [OSTI]

    Morris, Marvin E.; Pierce, Jim D.; Whitfield, Willis J.

    1979-01-01

    A novel facility for irradiation of solids embodying pathogens wherein solids are conveyed through an irradiation chamber in individual containers of an endless conveyor.

  10. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott; Wang, Ruiping; Derouane, Eric

    2003-01-01

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  11. ELECTRON IRRADIATION OF SOLIDS

    DOE Patents [OSTI]

    Damask, A.C.

    1959-11-01

    A method is presented for altering physical properties of certain solids, such as enhancing the usefulness of solids, in which atomic interchange occurs through a vacancy mechanism, electron irradiation, and temperature control. In a centain class of metals, alloys, and semiconductors, diffusion or displacement of atoms occurs through a vacancy mechanism, i.e., an atom can only move when there exists a vacant atomic or lattice site in an adjacent position. In the process of the invention highenergy electron irradiation produces additional vacancies in a solid over those normally occurring at a given temperature and allows diffusion of the component atoms of the solid to proceed at temperatures at which it would not occur under thermal means alone in any reasonable length of time. The invention offers a precise way to increase the number of vacancies and thereby, to a controlled degree, change the physical properties of some materials, such as resistivity or hardness.

  12. SAMPLE RESULTS FROM MCU SOLIDS OUTAGE

    SciTech Connect (OSTI)

    Peters, T.; Washington, A.; Oji, L.; Coleman, C.; Poirier, M.

    2014-09-22

    Savannah River National Laboratory (SRNL) has received several solid and liquid samples from MCU in an effort to understand and recover from the system outage starting on April 6, 2014. SRNL concludes that the presence of solids in the Salt Solution Feed Tank (SSFT) is the likely root cause for the outage, based upon the following discoveries ? A solids sample from the extraction contactor #1 proved to be mostly sodium oxalate ? A solids sample from the scrub contactor#1 proved to be mostly sodium oxalate ? A solids sample from the Salt Solution Feed Tank (SSFT) proved to be mostly sodium oxalate ? An archived sample from Tank 49H taken last year was shown to contain a fine precipitate of sodium oxalate ? A solids sample from the extraction contactor #1 drain pipe from extraction contactor#1 proved to be mostly sodium aluminosilicate ? A liquid sample from the SSFT was shown to have elevated levels of oxalate anion compared to the expected concentration in the feed Visual inspection of the SSFT indicated the presence of precipitated or transferred solids, which were likely also in the Salt Solution Receipt Tank (SSRT). The presence of the solids coupled with agitation performed to maintain feed temperature resulted in oxalate solids migration through the MCU system and caused hydraulic issues that resulted in unplanned phase carryover from the extraction into the scrub, and ultimately the strip contactors. Not only did this carryover result in the Strip Effluent (SE) being pushed out of waste acceptance specification, but it resulted in the deposition of solids into several of the contactors. At the same time, extensive deposits of aluminosilicates were found in the drain tube in the extraction contactor #1. However it is not known at this time how the aluminosilicate solids are related to the oxalate solids. The solids were successfully cleaned out of the MCU system. However, future consideration must be given to the exclusion of oxalate solids into the MCU system. There were 53 recommendations for improving operations recently identified. Some additional considerations or additional details are provided below as recommendations. ? From this point on, IC-Anions analyses of the DSSHT should be part of the monthly routine analysis in order to spot negative trends in the oxalate leaving the MCU system. Care must be taken to monitor the oxalate content to watch for sudden precipitation of oxalate salts in the system. ? Conduct a study to optimize the cleaning strategy at ARP-MCU through decreasing the concentration or entirely eliminating the oxalic acid. ? The contents of the SSFT should remain unagitated. Routine visual observation should be maintained to ensure there is not a large buildup of solids. As water with agitation provided sufficient removal of the solids in the feed tank, it should be considered as a good means for dissolving oxalate solids if they are found in the future. ? Conduct a study to improve prediction of oxalate solubility in salt batch feed materials. As titanium and mercury have been found in various solids in this report, evaluate if either element plays a role in oxalate solubility during processing. ? Salt batch characterization focuses primarily on characterization and testing of unaltered Tank 21H material; however, non-typical feeds are developed through cleaning, washing, and/or sump transfers. As these solutions are processed through MCU, they may precipitate solids or reduce performance. Salt batch characterization and testing should be expanded to encompass a broader range of feeds that may be processed through ARPMCU.

  13. Solid state rapid thermocycling

    DOE Patents [OSTI]

    Beer, Neil Reginald; Spadaccini, Christopher

    2014-05-13

    The rapid thermal cycling of a material is targeted. A solid state heat exchanger with a first well and second well is coupled to a power module. A thermoelectric element is coupled to the first well, the second well, and the power module, is configured to transfer thermal energy from the first well to the second well when current from the power module flows through the thermoelectric element in a first direction, and is configured to transfer thermal energy from the second well to the first well when current from the power module flows through the thermoelectric element in a second direction. A controller may be coupled to the thermoelectric elements, and may switch the direction of current flowing through the thermoelectric element in response to a determination by sensors coupled to the wells that the amount of thermal energy in the wells falls below or exceeds a pre-determined threshold.

  14. Solid Cold - A

    Office of Scientific and Technical Information (OSTI)

    Celebrating Einstein "Solid Cold" By the early 20th century, the way in which temperatures of solid objects changed as they absorbed heat was considered strong evidence that matter was not made of atoms. Einstein used some recent discoveries about light to turn this assessment around. A B C D E F A. A puzzle, and a surprising solution Take equal masses of lead and aluminum. Heat them until their temperatures are both 10 degrees higher. Will it take the same amount of heat for each?

  15. Cast heat-resistant austenitic steel with improved temperature creep properties and balanced alloying element additions and methodology for development of the same

    DOE Patents [OSTI]

    Pankiw, Roman I; Muralidharan, Govindrarajan; Sikka, Vinod Kumar; Maziasz, Philip J

    2012-11-27

    The present invention addresses the need for new austenitic steel compositions with higher creep strength and higher upper temperatures. The new austenitic steel compositions retain desirable phases, such as austenite, M.sub.23C.sub.6, and MC in its microstructure to higher temperatures. The present invention also discloses a methodology for the development of new austenitic steel compositions with higher creep strength and higher upper temperatures.

  16. NUCLEAR REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Anderson, W.F.; Tellefson, D.R.; Shimazaki, T.T.

    1962-04-10

    A plate type fuel element which is particularly useful for organic cooled reactors is described. Generally, the fuel element comprises a plurality of fissionable fuel bearing plates held in spaced relationship by a frame in which the plates are slidably mounted in grooves. Clearance is provided in the grooves to allow the plates to expand laterally. The plates may be rigidly interconnected but are floatingly supported at their ends within the frame to allow for longi-tudinal expansion. Thus, this fuel element is able to withstand large temperature differentials without great structural stresses. (AEC)

  17. Solid electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M.; Alamgir, Mohamed

    1993-06-15

    This invention pertains to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized (encapsulated) in a solid organic polymer matrix. In particular, this invention relates to solid polymer electrolytes derived by immobilizing complexes (solvates) formed between a Li salt such as LiAsF.sub.6, LiCF.sub.3 SO.sub.3 or LiClO.sub.4 and a mixture of aprotic organic solvents having high dielectric constants such as ethylene carbonate (EC) (dielectric constant=89.6) and propylene carbonate (PC) (dielectric constant=64.4) in a polymer matrix such as polyacrylonitrile, poly(tetraethylene glycol diacrylate), or poly(vinyl pyrrolidinone).

  18. Edge remap for solids

    SciTech Connect (OSTI)

    Kamm, James R.; Love, Edward; Robinson, Allen C.; Young, Joseph G.; Ridzal, Denis

    2013-12-01

    We review the edge element formulation for describing the kinematics of hyperelastic solids. This approach is used to frame the problem of remapping the inverse deformation gradient for Arbitrary Lagrangian-Eulerian (ALE) simulations of solid dynamics. For hyperelastic materials, the stress state is completely determined by the deformation gradient, so remapping this quantity effectively updates the stress state of the material. A method, inspired by the constrained transport remap in electromagnetics, is reviewed, according to which the zero-curl constraint on the inverse deformation gradient is implicitly satisfied. Open issues related to the accuracy of this approach are identified. An optimization-based approach is implemented to enforce positivity of the determinant of the deformation gradient. The efficacy of this approach is illustrated with numerical examples.

  19. Enzymatic temperature change indicator

    DOE Patents [OSTI]

    Klibanov, Alexander M.; Dordick, Jonathan S.

    1989-01-21

    A temperature change indicator is described which is composed of an enzyme and a substrate for that enzyme suspended in a solid organic solvent or mixture of solvents as a support medium. The organic solvent or solvents are chosen so as to melt at a specific temperature or in a specific temperature range. When the temperature of the indicator is elevated above the chosen, or critical temperature, the solid organic solvent support will melt, and the enzymatic reaction will occur, producing a visually detectable product which is stable to further temperature variation.

  20. SolidEnergy Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SolidEnergy Systems National Clean Energy Business Plan Competition SolidEnergy Systems Massachusetts Institute of Technology The Polymer Ionic Liquid (PIL) lithium battery combines the safety and energy density of a solid polymer lithium battery and the high performance of a lithium-ion battery. The battery developed by SolidEnergy achieves high energy density that works safely over a wide temperature range, which makes it ideal for electric vehicles and consumer electronics where both energy

  1. FUEL ELEMENT CONSTRUCTION

    DOE Patents [OSTI]

    Zumwalt, L.R.

    1961-08-01

    Fuel elements having a solid core of fissionable material encased in a cladding material are described. A conversion material is provided within the cladding to react with the fission products to form stable, relatively non- volatile compounds thereby minimizing the migration of the fission products into the coolant. The conversion material is preferably a metallic fluoride, such as lead difluoride, and may be in the form of a coating on the fuel core or interior of the cladding, or dispersed within the fuel core. (AEC)

  2. DYNA3D: a finite element program for supercomputers

    SciTech Connect (OSTI)

    Benson, D.J.; Hallquist, J.O.

    1986-01-01

    DYNA3D is an explicit three-dimensional finite element code for analyzing the large deformation dynamic response of inelastic solids and structures. A contact-impact algorithm permits gaps and sliding along material interfaces with friction. By a specialization of this algorithm, such interfaces can be rigidly tied to admit variable zoning without the need of transition regions. Spatial discretization is achieved by the use of 8-node solid elements, 2-node beam elements, 4-node shell elements, 8-node solid shell elements, and rigid bodies. The equations-of-motion are integrated in time by the central difference method. 8 refs., 15 figs.

  3. High temperature lubricating process

    DOE Patents [OSTI]

    Taylor, R.W.; Shell, T.E.

    1979-10-04

    It has been difficult to provide adequate lubrication for load bearing, engine components when such engines are operating in excess of about 475/sup 0/C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface, such as in an engine being operated at temperatures in excess of about 475/sup 0/C. The process comprises contacting and maintaining the following steps: a gas phase is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant; the gas phase is contacted with the load bearing surface; the load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant; and the solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

  4. High temperature lubricating process

    DOE Patents [OSTI]

    Taylor, Robert W.; Shell, Thomas E.

    1982-01-01

    It has been difficult to provide adaquate lubrication for load bearing, engine components when such engines are operating in excess of about 475.degree. C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface (14), such as in an engine (10) being operated at temperatures in excess of about 475.degree. C. The process comprises contacting and maintaining steps. A gas phase (42) is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant. The gas phase is contacted with the load bearing surface. The load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant. The solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

  5. FUEL ELEMENT

    DOE Patents [OSTI]

    Bean, R.W.

    1963-11-19

    A ceramic fuel element for a nuclear reactor that has improved structural stability as well as improved cooling and fission product retention characteristics is presented. The fuel element includes a plurality of stacked hollow ceramic moderator blocks arranged along a tubular raetallic shroud that encloses a series of axially apertured moderator cylinders spaced inwardly of the shroud. A plurality of ceramic nuclear fuel rods are arranged in the annular space between the shroud and cylinders of moderator and appropriate support means and means for directing gas coolant through the annular space are also provided. (AEC)

  6. 3-D Finite Element Code Postprocessor

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    TAURUS is an interactive post-processing application supporting visualization of finite element analysis results on unstructured grids. TAURUS provides the ability to display deformed geometries and contours or fringes of a large number of derived results on meshes consisting of beam, plate, shell, and solid type finite elements. Time history plotting is also available.

  7. JAC3D -- A three-dimensional finite element computer program for the nonlinear quasi-static response of solids with the conjugate gradient method; Yucca Mountain Site Characterization Project

    SciTech Connect (OSTI)

    Biffle, J.H.

    1993-02-01

    JAC3D is a three-dimensional finite element program designed to solve quasi-static nonlinear mechanics problems. A set of continuum equations describes the nonlinear mechanics involving large rotation and strain. A nonlinear conjugate gradient method is used to solve the equation. The method is implemented in a three-dimensional setting with various methods for accelerating convergence. Sliding interface logic is also implemented. An eight-node Lagrangian uniform strain element is used with hourglass stiffness to control the zero-energy modes. This report documents the elastic and isothermal elastic-plastic material model. Other material models, documented elsewhere, are also available. The program is vectorized for efficient performance on Cray computers. Sample problems described are the bending of a thin beam, the rotation of a unit cube, and the pressurization and thermal loading of a hollow sphere.

  8. Nuclear fuel element

    DOE Patents [OSTI]

    Zocher, Roy W.

    1991-01-01

    A nuclear fuel element and a method of manufacturing the element. The fuel element is comprised of a metal primary container and a fuel pellet which is located inside it and which is often fragmented. The primary container is subjected to elevated pressure and temperature to deform the container such that the container conforms to the fuel pellet, that is, such that the container is in substantial contact with the surface of the pellet. This conformance eliminates clearances which permit rubbing together of fuel pellet fragments and rubbing of fuel pellet fragments against the container, thus reducing the amount of dust inside the fuel container and the amount of dust which may escape in the event of container breach. Also, as a result of the inventive method, fuel pellet fragments tend to adhere to one another to form a coherent non-fragmented mass; this reduces the tendency of a fragment to pierce the container in the event of impact.

  9. Low exchange element for nuclear reactor

    DOE Patents [OSTI]

    Brogli, Rudolf H. (Aarau, CH); Shamasunder, Bangalore I. (Encinitas, CA); Seth, Shivaji S. (Encinitas, CA)

    1985-01-01

    A flow exchange element is presented which lowers temperature gradients in fuel elements and reduces maximum local temperature within high temperature gas-cooled reactors. The flow exchange element is inserted within a column of fuel elements where it serves to redirect coolant flow. Coolant which has been flowing in a hotter region of the column is redirected to a cooler region, and coolant which has been flowing in the cooler region of the column is redirected to the hotter region. The safety, efficiency, and longevity of the high temperature gas-cooled reactor is thereby enhanced.

  10. OXIDATION OF TRANSURANIC ELEMENTS

    DOE Patents [OSTI]

    Moore, R.L.

    1959-02-17

    A method is reported for oxidizing neptunium or plutonium in the presence of cerous values without also oxidizing the cerous values. The method consists in treating an aqueous 1N nitric acid solution, containing such cerous values together with the trivalent transuranic elements, with a quantity of hydrogen peroxide stoichiometrically sufficient to oxidize the transuranic values to the hexavalent state, and digesting the solution at room temperature.

  11. NEUTRONIC REACTOR AND FUEL ELEMENT THEREFOR

    DOE Patents [OSTI]

    Szilard, L.; Young, G.J.

    1958-03-01

    This patent relates to a reactor design of the type which employs solid fuel elements disposed in channels within the moderator through which channels and around the fuel elements is conveyed a coolant fiuid. The coolant channels are comprised of aluminum tubes extending through a solid moderator such as graphite and the fuel elements are comprised of an elongated solid body of natural uranium jacketed in an aluminum jacket with the ends thereof closed by aluminum caps of substantially greater thickness than the jacket was and in good thermal contact with the fuel material to facilitate the conduction of heat from the central portion of said ends to the coolant surrounding the fuel element to prevent overheating of said central portion.

  12. Programmatic Elements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2007-07-11

    The Guide provides acceptable methods of meeting the requirements of DOE O 151.1C for programmatic elements that sustain the emergency management program and maintain the readiness of the program to respond to an emergency. Supersedes DOE G 151.1-1, Volume 5-1, DOE G 151.1-1, Volume 5-2, DOE G 151.1-1, Volume 5-3, DOE G 151.1-1, Volume 5-4, DOE G 151.1-1, Volume 7-1, and DOE G 151.1-1, Volume 7-3.

  13. FUEL ELEMENT FOR NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Evans, T.C.; Beasley, E.G.

    1961-01-17

    A fuel element for neutronic reactors, particularly the gas-cooled type of reactor, is described. The element comprises a fuel-bearing plate rolled to form a cylinder having a spiral passageway passing from its periphery to its center. In operation a coolant is admitted to the passageway at the periphery of the element, is passed through the spiral passageway, and emerges into a central channel defined by the inner turn of the rolled plate. The advantage of the element is that the fully heated coolant (i.e., coolant emerging into the central channel) is separated and thus insulated from the periphery of the element, which may be in contact with a low-temperature moderator, by the intermediate turns of the spiral fuel element.

  14. Biochemical transformation of solid carbonaceous material

    DOE Patents [OSTI]

    Lin, Mow S. (Rocky Point, NY); Premuzic, Eugene T. (East Moriches, NY)

    2001-09-25

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed.

  15. Element partitioning in combustion- and gasification-based waste-to-energy units

    SciTech Connect (OSTI)

    Arena, Umberto; Di Gregorio, Fabrizio

    2013-05-15

    Highlights: ? Element partitioning of waste-to-energy units by means of a substance flow analysis. ? A comparison between moving grate combustors and high temperature gasifiers. ? Classification of key elements according to their behavior during WtE processes. ? Slags and metals from waste gasifiers are completely and immediately recyclable. ? Potential reduction of amounts of solid residue to be sent to landfill disposal. - Abstract: A critical comparison between combustion- and gasification-based waste-to-energy systems needs a deep knowledge of the mass flows of materials and elements inside and throughout the units. The study collected and processed data from several moving grate conventional incinerators and high-temperature shaft gasifiers with direct melting, which are in operation worldwide. A material and substance flow analysis was then developed to systematically assess the flows and stocks of materials and elements within each waste-to-energy unit, by connecting the sources, pathways, and intermediate and final sinks of each species. The patterns of key elements, such as carbon, chloride and heavy metals, in the different solid and gaseous output streams of the two compared processes have been then defined. The combination of partitioning coefficients with the mass balances on atomic species and results of mineralogical characterization from recent literatures was used to estimate a composition of bottom ashes and slags from the two types of waste-to-energy technologies. The results also allow to quantify some of the performance parameters of the units and, in particular, the potential reduction of the amount of solid residues to be sent to final disposal.

  16. Response Elements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2007-07-11

    The Guide provides acceptable methods for meeting the requirement of DOE O 151.1C for response elements that respond or contribute to response as needed in an emergency. Supersedes DOE G 151.1-1, Volume 3-1, DOE G 151.1-1, Volume 3-2, DOE G 151.1-1, Volume 3-3, DOE G 151.1-1, Volume 3-4, DOE G 151.1-1, Volume 4-1, DOE G 151.1-1, Volume 4-2, DOE G 151.1-1, Volume 4-3, DOE G 151.1-1, Volume 4-4, DOE G 151.1-1, Volume 4-5, and DOE G 151.1-1, Volume 4-6.

  17. Solid-state lithium battery

    DOE Patents [OSTI]

    Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

    2014-11-04

    The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

  18. Solid oxide fuel cell with single material for electrodes and interconnect

    DOE Patents [OSTI]

    McPheeters, Charles C.; Nelson, Paul A.; Dees, Dennis W.

    1994-01-01

    A solid oxide fuel cell having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed therebetween, and the anode, cathode and interconnect elements are comprised of substantially one material.

  19. Interfacial material for solid oxide fuel cell

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  20. SolidShperal

    Energy Science and Technology Software Center (OSTI)

    2013-12-22

    SolidSpheral is an extension of the Spheral open source meshless hydrodynamics method. SolidSpheral adds the capability to model solid materials using analytic equations of state, and a simple damage model to allow for the modeled materials to undergo dynamic damage evolution. SolidSpheral is a distributed parallel code employing MPI for the parallel framework.

  1. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, Tytus R. (Hickory Hills, IL)

    1990-01-01

    An apparatus and process for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine.

  2. Solid oxide electrochemical reactor science.

    SciTech Connect (OSTI)

    Sullivan, Neal P.; Stechel, Ellen Beth; Moyer, Connor J.; Ambrosini, Andrea; Key, Robert J.

    2010-09-01

    Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

  3. Verification of Advective Bar Elements Implemented in the Aria Thermal Response Code.

    SciTech Connect (OSTI)

    Mills, Brantley

    2016-01-01

    A verification effort was undertaken to evaluate the implementation of the new advective bar capability in the Aria thermal response code. Several approaches to the verification process were taken : a mesh refinement study to demonstrate solution convergence in the fluid and the solid, visually examining the mapping of the advective bar element nodes to the surrounding surfaces, and a comparison of solutions produced using the advective bars for simple geometries with solutions from commercial CFD software . The mesh refinement study has shown solution convergence for simple pipe flow in both temperature and velocity . Guidelines were provided to achieve appropriate meshes between the advective bar elements and the surrounding volume. Simulations of pipe flow using advective bars elements in Aria have been compared to simulations using the commercial CFD software ANSYS Fluent (r) and provided comparable solutions in temperature and velocity supporting proper implementation of the new capability. Verification of Advective Bar Elements iv Acknowledgements A special thanks goes to Dean Dobranich for his guidance and expertise through all stages of this effort . His advice and feedback was instrumental to its completion. Thanks also goes to Sam Subia and Tolu Okusanya for helping to plan many of the verification activities performed in this document. Thank you to Sam, Justin Lamb and Victor Brunini for their assistance in resolving issues encountered with running the advective bar element model. Finally, thanks goes to Dean, Sam, and Adam Hetzler for reviewing the document and providing very valuable comments.

  4. High-Temperature Thermoelectric Properties of the Solid-Solution Zintl Phase Eu11Cd6Sb12-xAsx (x < 3)

    SciTech Connect (OSTI)

    Kazem, Nasrin; Xie, Weiwei; Ohno, Saneyuki; Zevalkink, Alexandra; Miller, Gordon J.; Snyder, G. Jeffrey; Kauzlarich, Susan M.

    2014-02-20

    Zintl phases are compounds that have shown promise for thermoelectric applications. The title solid–solution Zintl compounds were prepared from the elements as single crystals using a tin flux for compositions x = 0, 1, 2, and 3. Eu11Cd6Sb12–xAsx (x < 3) crystallize isostructurally in the centrosymmetric monoclinic space group C2/m (no. 12, Z = 2) as the Sr11Cd6Sb12 structure type (Pearson symbol mC58). Efforts to make the As compositions for x exceeding ~3 resulted in structures other than the Sr11Cd6Sb12 structure type. Single-crystal X-ray diffraction indicates that As does not randomly substitute for Sb in the structure but is site specific for each composition. The amount of As determined by structural refinement was verified by electron microprobe analysis. Electronic structures and energies calculated for various model structures of Eu11Cd6Sb10As2 (x = 2) indicated that the preferred As substitution pattern involves a mixture of three of the six pnicogen sites in the asymmetric unit. In addition, As substitution at the Pn4 site opens an energy gap at the Fermi level, whereas substitution at the other five pnicogen sites remains semimetallic with a pseudo gap. Thermoelectric properties of these compounds were measured on hot-pressed, fully densified pellets. Samples show exceptionally low lattice thermal conductivities from room temperature to 775 K: 0.78–0.49 W/mK for x = 0; 0.72–0.53 W/mK for x = 1; and 0.70–0.56 W/mK for x = 2. Eu11Cd6Sb12 shows a high p-type Seebeck coefficient (from +118 to 153 μ V/K) but also high electrical resistivity (6.8 to 12.8 mΩ·cm). The value of zT reaches 0.23 at 774 K. The properties of Eu11Cd6Sb12–xAsx are interpreted in discussion with the As site substitution.

  5. Process and material that encapsulates solid hazardous waste

    DOE Patents [OSTI]

    O'Brien, Michael H.; Erickson, Arnold W.

    1999-01-01

    A method of encapsulating mixed waste in which a thermoplastic polymer having a melting temperature less than about 150.degree. C. and sulfur and mixed waste are mixed at an elevated temperature not greater than about 200.degree. C. and mixed for a time sufficient to intimately mix the constituents, and then cooled to a solid. The resulting solid is also disclosed.

  6. Sorption of redox-sensitive elements: critical analysis

    SciTech Connect (OSTI)

    Strickert, R.G.

    1980-12-01

    The redox-sensitive elements (Tc, U, Np, Pu) discussed in this report are of interest to nuclear waste management due to their long-lived isotopes which have a potential radiotoxic effect on man. In their lower oxidation states these elements have been shown to be highly adsorbed by geologic materials occurring under reducing conditions. Experimental research conducted in recent years, especially through the Waste Isolation Safety Assessment Program (WISAP) and Waste/Rock Interaction Technology (WRIT) program, has provided extensive information on the mechanisms of retardation. In general, ion-exchange probably plays a minor role in the sorption behavior of cations of the above three actinide elements. Formation of anionic complexes of the oxidized states with common ligands (OH/sup -/, CO/sup - -//sub 3/) is expected to reduce adsorption by ion exchange further. Pertechnetate also exhibits little ion-exchange sorption by geologic media. In the reduced (IV) state, all of the elements are highly charged and it appears that they form a very insoluble compound (oxide, hydroxide, etc.) or undergo coprecipitation or are incorporated into minerals. The exact nature of the insoluble compounds and the effect of temperature, pH, pe, other chemical species, and other parameters are currently being investigated. Oxidation states other than Tc (IV,VII), U(IV,VI), Np(IV,V), and Pu(IV,V) are probably not important for the geologic repository environment expected, but should be considered especially when extreme conditions exist (radiation, temperature, etc.). Various experimental techniques such as oxidation-state analysis of tracer-level isotopes, redox potential measurement and control, pH measurement, and solid phase identification have been used to categorize the behavior of the various valence states.

  7. A Process and Environment Aware Sierra/SolidMechanics Cohesive Zone Modeling Capability for Polymer/Solid Interfaces

    SciTech Connect (OSTI)

    Reedy, E. D.; Chambers, Robert S.; Hughes, Lindsey Gloe; Kropka, Jamie Michael; Stavig, Mark E.; Stevens, Mark J.

    2015-09-01

    The performance and reliability of many mechanical and electrical components depend on the integrity of po lymer - to - solid interfaces . Such interfaces are found in adhesively bonded joints, encapsulated or underfilled electronic modules, protective coatings, and laminates. The work described herein was aimed at improving Sandia's finite element - based capability to predict interfacial crack growth by 1) using a high fidelity nonlinear viscoelastic material model for the adhesive in fracture simulations, and 2) developing and implementing a novel cohesive zone fracture model that generates a mode - mixity dependent toughness as a natural consequence of its formulation (i.e., generates the observed increase in interfacial toughness wi th increasing crack - tip interfacial shear). Furthermore, molecular dynamics simulations were used to study fundamental material/interfa cial physics so as to develop a fuller understanding of the connection between molecular structure and failure . Also reported are test results that quantify how joint strength and interfacial toughness vary with temperature.

  8. Laser cooling of solids

    SciTech Connect (OSTI)

    Epstein, Richard I; Sheik-bahae, Mansoor

    2008-01-01

    We present an overview of solid-state optical refrigeration also known as laser cooling in solids by fluorescence upconversion. The idea of cooling a solid-state optical material by simply shining a laser beam onto it may sound counter intuitive but is rapidly becoming a promising technology for future cryocooler. We chart the evolution of this science in rare-earth doped solids and semiconductors.

  9. Rotary bulk solids divider

    DOE Patents [OSTI]

    Maronde, Carl P. (McMurray, PA); Killmeyer, Jr., Richard P. (Pittsburgh, PA)

    1992-01-01

    An apparatus for the disbursement of a bulk solid sample comprising, a gravity hopper having a top open end and a bottom discharge end, a feeder positioned beneath the gravity hopper so as to receive a bulk solid sample flowing from the bottom discharge end, and a conveyor receiving the bulk solid sample from the feeder and rotating on an axis that allows the bulk solid sample to disperse the sample to a collection station.

  10. Solid State Division

    SciTech Connect (OSTI)

    Green, P.H.; Watson, D.M.

    1989-08-01

    This report contains brief discussions on work done in the Solid State Division of Oak Ridge National Laboratory. The topics covered are: Theoretical Solid State Physics; Neutron scattering; Physical properties of materials; The synthesis and characterization of materials; Ion beam and laser processing; and Structure of solids and surfaces. (LSP)

  11. Solid aerosol generator

    DOE Patents [OSTI]

    Prescott, Donald S.; Schober, Robert K.; Beller, John

    1992-01-01

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates.

  12. Improved solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1988-07-19

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  13. Solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1992-03-17

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration is disclosed. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  14. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, T.R.

    1990-04-17

    An apparatus and process are described for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine. 3 figs.

  15. Temperature differential detection device

    DOE Patents [OSTI]

    Girling, Peter M.

    1986-01-01

    A temperature differential detection device for detecting the temperature differential between predetermined portions of a container wall is disclosed as comprising a Wheatstone bridge circuit for detecting resistance imbalance with a first circuit branch having a first elongated wire element mounted in thermal contact with a predetermined portion of the container wall, a second circuit branch having a second elongated wire element mounted in thermal contact with a second predetermined portion of a container wall with the wire elements having a predetermined temperature-resistant coefficient, an indicator interconnected between the first and second branches remote from the container wall for detecting and indicating resistance imbalance between the first and second wire elements, and connector leads for electrically connecting the wire elements to the remote indicator in order to maintain the respective resistance value relationship between the first and second wire elements. The indicator is calibrated to indicate the detected resistance imbalance in terms of a temperature differential between the first and second wall portions.

  16. Temperature differential detection device

    DOE Patents [OSTI]

    Girling, P.M.

    1986-04-22

    A temperature differential detection device for detecting the temperature differential between predetermined portions of a container wall is disclosed as comprising a Wheatstone bridge circuit for detecting resistance imbalance with a first circuit branch having a first elongated wire element mounted in thermal contact with a predetermined portion of the container wall, a second circuit branch having a second elongated wire element mounted in thermal contact with a second predetermined portion of a container wall with the wire elements having a predetermined temperature-resistant coefficient, an indicator interconnected between the first and second branches remote from the container wall for detecting and indicating resistance imbalance between the first and second wire elements, and connector leads for electrically connecting the wire elements to the remote indicator in order to maintain the respective resistance value relationship between the first and second wire elements. The indicator is calibrated to indicate the detected resistance imbalance in terms of a temperature differential between the first and second wall portions. 2 figs.

  17. Trace element emissions. Semi-annual report, October 1994--February 1995

    SciTech Connect (OSTI)

    Pigeaud, A.; Maru, H.; Wilemski, G.; Helble, J.

    1995-02-01

    Many trace elements can exist in raw coal gas either in the form of metallic vapors or gaseous compounds which, besides their action on potentially ``very clean`` advanced power generating systems such as fuel cells and gas turbines, can also be detrimental to plant and animal life when released into the atmosphere. Therefore, volatile trace contaminants from coal which can also be toxic must be removed before they become detrimental to both power plant performance/endurance and the environment. Five trace elements were selected in this project based on: abundance in solid coal, volatility during gasification, effects on downstream systems and toxicity to plant and animal life. An understanding was sought in this investigation of the interactions of these five trace elements (and their high temperature species) with the different components in integrated cleanup and power generating systems, as well as the ultimate effects with respect to atmospheric emissions. Utilizing thermodynamic calculations and various experimental techniques, it was determined that a number of trace contaminants that exist in coal may be substantially removed by flyash, and after that by different sorbent systems. High temperature cleanup of contaminants by sorbents such as zinc titanate, primarily to remove sulfur, can also absorb some metallic contaminants such as cadmium and antimony. Further polishing will be required, however, to eliminate trace contaminant species incorporating the elements arsenic, selemium, lead, and mercury.

  18. Gasification of carbonaceous solids

    DOE Patents [OSTI]

    Coates, Ralph L.

    1976-10-26

    A process and apparatus for converting coal and other carbonaceous solids to an intermediate heating value fuel gas or to a synthesis gas. A stream of entrained pulverized coal is fed into the combustion stage of a three-stage gasifier along with a mixture of oxygen and steam at selected pressure and temperature. The products of the combustion stage pass into the second or quench stage where they are partially cooled and further reacted with water and/or steam. Ash is solidified into small particles and the formation of soot is suppressed by water/steam injections in the quench stage. The design of the quench stage prevents slag from solidifying on the walls. The products from the quench stage pass directly into a heat recovery stage where the products pass through the tube, or tubes, of a single-pass, shell and tube heat exchanger and steam is generated on the shell side and utilized for steam feed requirements of the process.

  19. COMPARTMENTED REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Cain, F.M. Jr.

    1962-09-11

    A method of making a nuclear reactor fuel element of the elongated red type is given wherein the fissionable fuel material is enclosed within a tubular metal cladding. The method comprises coating the metal cladding tube on its inside wall with a brazing alloy, inserting groups of cylindrical pellets of fissionable fuel material into the tube with spacing members between adjacent groups of pellets, sealing the ends of the tubes to leave a void space therewithin, heating the tube and its contents to an elevated temperature to melt the brazing alloy and to expand the pellets to their maximum dimensions under predetermined operating conditions thereby automatically positioning the spacing members along the tube, and finally cooling the tube to room temperature whereby the spacing disks become permanently fixed at their edges in the brazing alloy and define a hermetically sealed compartment for each fl group of fuel pellets. Upon cooling, the pellets contract thus leaving a space to accommodate thermal expansion of the pellets when in use in a reactor. The spacing members also provide lateral support for the tubular cladding to prevent collapse thereof when subjected to a reactor environment. (AEC)

  20. Temperature-sensitive optrode

    DOE Patents [OSTI]

    Hirschfeld, Tomas B.

    1985-01-01

    Method and apparatus are provided for measuring temperature and for generating optical signals related to temperature. Light from a fiber optic is directed to a material whose fluorescent response varies with ambient temperature. The same fiber optic delivering the excitation beam also collects a portion of the fluorescent emission for analysis. Signal collection efficiency of the fiber optic is enhanced by requiring that the fluorescent probe material be in the shape of an oblong parabolically tapered solid. Reproducibility is enhanced by using Raman backscatter to monitor excitation beam fluctuations, and by using measurements of fluorescence lifetime.

  1. Temperature-sensitive optrode

    DOE Patents [OSTI]

    Hirschfeld, T.B.

    1985-09-24

    Method and apparatus are provided for measuring temperature and for generating optical signals related to temperature. Light from a fiber optic is directed to a material whose fluorescent response varies with ambient temperature. The same fiber optic delivering the excitation beam also collects a portion of the fluorescent emission for analysis. Signal collection efficiency of the fiber optic is enhanced by requiring that the fluorescent probe material be in the shape of an oblong parabolically tapered solid. Reproducibility is enhanced by using Raman backscatter to monitor excitation beam fluctuations, and by using measurements of fluorescence lifetime. 10 figs.

  2. Solid-State Lighting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... HomeSolid-State Lighting Permalink ECIS-Veeco: Research Driving Down the Costs of Efficient LED Lighting Energy, Energy Efficiency, Materials Science, Partnership, Research & ...

  3. 3 MW Solid Rotating Target Design

    SciTech Connect (OSTI)

    McManamy, Thomas J; Gallmeier, Franz X; Rennich, Mark J; Ferguson, Phillip D; Janney, Jim G

    2010-01-01

    A rotating solid target design concept is being developed for potential use at the second SNS target station (STS). A long pulse beam (~ 1 msec) at 1.3 GeV and 20 Hz is planned with power levels at or above 1 MW. Since the long pulse may give future opportunities for higher power, this study is looking at 3 MW to compare the performance of a solid rotating target to a mercury target. Unlike the case for stationary solid targets at such powers this study indicates that a rotating solid target, when used with large coupled hydrogen moderators, has neutronic performance equal to or better than that with a mercury target, and the solid target has a greatly increased lifetime. Design studies have investigated water cooled tungsten targets with tantalum cladding approximately 1.2 m in diameter, and 70mm thick. Operating temperatures are low ( < 150 C) with mid-plane, top and bottom surface cooling. In case of cooling system failure, the diameter gives enough surface area to remove the decay heat by radiation to the surrounding reflector assemblies while keeping the peak temperatures below approximately 700 C. This temperature should mitigate potential loss of coolant accidents and subsequent steam, tungsten interaction which has a threshold of approximately 800 C. Design layouts for the sealing systems and potential target station concepts have been developed.

  4. Solid-state-laser-rod holder

    DOE Patents [OSTI]

    Gettemy, D.J.; Barnes, N.P.; Griggs, J.E.

    1981-08-11

    The disclosure relates to a solid state laser rod holder comprising Invar, copper tubing, and epoxy joints. Materials and coefficients of expansion of the components of the holder combine with the rod to produce a joint which will give before the rod itself will. The rod may be lased at about 70 to 80/sup 0/K and returned from such a temperature to room temperature repeatedly without its or the holder's destruction.

  5. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E.; Grohmann, Karel; Himmel, Michael E.; Richard, Christopher J.

    1993-03-02

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  6. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E.; Grohmann, Karel; Himmel, Michael E.; Richard, Christopher J.

    1993-01-01

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  7. Solid composite electrolytes for lithium batteries

    DOE Patents [OSTI]

    Kumar, Binod; Scanlon, Jr., Lawrence G.

    2000-01-01

    Solid composite electrolytes are provided for use in lithium batteries which exhibit moderate to high ionic conductivity at ambient temperatures and low activation energies. In one embodiment, a ceramic-ceramic composite electrolyte is provided containing lithium nitride and lithium phosphate. The ceramic-ceramic composite is also preferably annealed and exhibits an activation energy of about 0.1 eV.

  8. Solid tags for identifying failed reactor components

    DOE Patents [OSTI]

    Bunch, Wilbur L.; Schenter, Robert E.

    1987-01-01

    A solid tag material which generates stable detectable, identifiable, and measurable isotopic gases on exposure to a neutron flux to be placed in a nuclear reactor component, particularly a fuel element, in order to identify the reactor component in event of its failure. Several tag materials consisting of salts which generate a multiplicity of gaseous isotopes in predetermined ratios are used to identify different reactor components.

  9. Electrical bushing for a superconductor element

    DOE Patents [OSTI]

    Mirebeau, Pierre; Lallouet, Nicolas; Delplace, Sebastien; Lapierre, Regis

    2010-05-04

    The invention relates to an electrical bushing serving to make a connection at ambient temperature to a superconductor element situated in an enclosure at cryogenic temperature. The electrical bushing passes successively through an enclosure at intermediate temperature between ambient temperature and cryogenic temperature, and an enclosure at ambient temperature, and it comprises a central electrical conductor surrounded by an electrically insulating sheath. According to the invention, an electrically conductive screen connected to ground potential surrounds the insulating sheath over a section that extends from the end of the bushing that is in contact with the enclosure at cryogenic temperature at least as far as the junction between the enclosure at intermediate temperature and the enclosure at ambient temperature. The invention is more particularly applicable to making a connection to a superconductor cable.

  10. TAURUS. 3-d Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1991-05-01

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D (ESTSC 139), DYNA3D (ESTSC 138), TACO3D (ESTSC 287), TOPAZ3D (ESTSC 231), and GEMINI (ESTSC 455) and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  11. TAURUS. 3-d Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1992-03-03

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D (ESTSC 139), DYNA3D (ESTSC 138), TACO3D (ESTSC 287), TOPAZ3D (ESTSC 231), and GEMINI (ESTSC 455) and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  12. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1984-05-01

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  13. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1993-11-30

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  14. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1992-03-03

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  15. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Kennedy, T.

    1992-03-03

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories, and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  16. Thermal and hydrometallurgical recovery methods of heavy metals from municipal solid waste fly ash

    SciTech Connect (OSTI)

    Kubo?ov, L.

    2013-11-15

    Highlights: MSW fly ash was thermally and hydrometallurgically treated to remove heavy metals. More than 90% of easy volatile heavy metals (Cd and Pb) were removed thermally. More than 90% of Cd, Cr, Cu an Zn were removed by alkaline acid leaching. The best results were obtained for the solution of 3 M NaOH and 2 M H{sub 2}SO{sub 4}. - Abstract: Heavy metals in fly ash from municipal solid waste incinerators are present in high concentrations. Therefore fly ash must be treated as a hazardous material. On the other hand, it may be a potential source of heavy metals. Zinc, lead, cadmium, and copper can be relatively easily removed during the thermal treatment of fly ash, e.g. in the form of chlorides. In return, wet extraction methods could provide promising results for these elements including chromium and nickel. The aim of this study was to investigate and compare thermal and hydrometallurgical treatment of municipal solid waste fly ash. Thermal treatment of fly ash was performed in a rotary reactor at temperatures between 950 and 1050 C and in a muffle oven at temperatures from 500 to 1200 C. The removal more than 90% was reached by easy volatile heavy metals such as cadmium and lead and also by copper, however at higher temperature in the muffle oven. The alkaline (sodium hydroxide) and acid (sulphuric acid) leaching of the fly ash was carried out while the influence of temperature, time, concentration, and liquid/solid ratio were investigated. The combination of alkaline-acidic leaching enhanced the removal of, namely, zinc, chromium and nickel.

  17. Solid Phase Characterization of Solids Recovered from Failed Sluicer Arm

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Solid Phase Characterization of Solids Recovered from Failed Sluicer Arm Citation Details In-Document Search Title: Solid Phase Characterization of Solids Recovered from Failed Sluicer Arm The Enclosure to this memo discusses the solid phase characterization of a solid sample that was retrieved from the single-shell Tank 241-C-111 extended reach sluicer #2. This sluicer, removed from riser #3 on September 25, 2014, was found to have approximately 0.4

  18. NEUTRONIC REACTOR CONTROL ELEMENT

    DOE Patents [OSTI]

    Beaver, R.J.; Leitten, C.F. Jr.

    1962-04-17

    A boron-10 containing reactor control element wherein the boron-10 is dispersed in a matrix material is describeri. The concentration of boron-10 in the matrix varies transversely across the element from a minimum at the surface to a maximum at the center of the element, prior to exposure to neutrons. (AEC)

  19. Delivery system for molten salt oxidation of solid waste

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

    2002-01-01

    The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

  20. Simple and low-temperature preparation of Co{sub 3}O{sub 4} sphere-like nanoparticles via solid-state thermolysis of the [Co(NH{sub 3}){sub 6}](NO{sub 3}){sub 3} complex

    SciTech Connect (OSTI)

    Farhadi, Saeid; Pourzare, Kolsoum

    2012-06-15

    Highlights: ? [Co(NH{sub 3}){sub 6}](NO{sub 3}){sub 3} precursor was used for synthesizing pure Co{sub 3}O{sub 4} nanocrystals. ? Co{sub 3}O{sub 4} nanocrystals were synthesized at low temperature of 200 C. ? Co{sub 3}O{sub 4} nanocrystals show a weak ferromagnetic behavior at room temperature. ? This simple method is low-cost and suitable for high-scale production of Co{sub 3}O{sub 4}. -- Abstract: In this work, spinel-type Co{sub 3}O{sub 4} spherical nanoparticles were easily prepared via decomposition of the hexamminecobalt(III) nitrate complex, [Co(NH{sub 3}){sub 6}](NO{sub 3}){sub 3}, at low temperature (200 C). The product was characterized by thermal analysis (TGA/DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, UVvis spectroscopy, transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), BrunauerEmmettTeller (BET) specific surface area measurement and magnetic measurements. The results confirmed that pure single-phase Co{sub 3}O{sub 4} nanoparticles with weak ferromagnetic behavior were obtained by this method. TEM images showed that the Co{sub 3}O{sub 4} nanoparticles are sphere-like with an average diameter size of around 15 nm. The optical spectrum indicated two direct band gaps at 2.15 and 3.56 eV which are blue-shifted relative to reported values for the bulk sample. Using this fast and simple method, Co{sub 3}O{sub 4} nanoparticles can be produced without expensive and toxic solvents or complicated equipment.

  1. Solid Cold - D

    Office of Scientific and Technical Information (OSTI)

    D. Einstein's solution illustrated The problem with 19th-century atomic theory was the ... to the absolute temperature, as earlier theory implied, though if the temperature were ...

  2. Solids Accumulation Scouting Studies

    SciTech Connect (OSTI)

    Duignan, M. R.; Steeper, T. J.; Steimke, J. L.

    2012-09-26

    The objective of Solids Accumulation activities was to perform scaled testing to understand the behavior of remaining solids in a Double Shell Tank (DST), specifically AW-105, at Hanford during multiple fill, mix, and transfer operations. It is important to know if fissionable materials can concentrate when waste is transferred from staging tanks prior to feeding waste treatment plants. Specifically, there is a concern that large, dense particles containing plutonium could accumulate in poorly mixed regions of a blend tank heel for tanks that employ mixing jet pumps. At the request of the DOE Hanford Tank Operations Contractor, Washington River Protection Solutions, the Engineering Development Laboratory of the Savannah River National Laboratory performed a scouting study in a 1/22-scale model of a waste staging tank to investigate this concern and to develop measurement techniques that could be applied in a more extensive study at a larger scale. Simulated waste tank solids: Gibbsite, Zirconia, Sand, and Stainless Steel, with stainless steel particles representing the heavier particles, e.g., plutonium, and supernatant were charged to the test tank and rotating liquid jets were used to mix most of the solids while the simulant was pumped out. Subsequently, the volume and shape of the mounds of residual solids and the spatial concentration profiles for the surrogate for heavier particles were measured. Several techniques were developed and equipment designed to accomplish the measurements needed and they included: 1. Magnetic particle separator to remove simulant stainless steel solids. A device was designed and built to capture these solids, which represent the heavier solids during a waste transfer from a staging tank. 2. Photographic equipment to determine the volume of the solids mounds. The mounds were photographed as they were exposed at different tank waste levels to develop a composite of topographical areas. 3. Laser rangefinders to determine the volume of the solids mounds. The mounds were scanned after tank supernatant was removed. 4. Core sampler to determine the stainless steel solids distribution within the solids mounds. This sampler was designed and built to remove small sections of the mounds to evaluate concentrations of the stainless steel solids at different special locations. 5. Computer driven positioner that placed the laser rangefinders and the core sampler in appropriate locations over solids mounds that accumulated on the bottom of a scaled staging tank where mixing is poor. These devices and techniques were effective to estimate the movement, location, and concentrations of the solids representing heavier particles and could perform well at a larger scale The experiment contained two campaigns with each comprised of ten cycles to fill and empty the scaled staging tank. The tank was filled without mixing, but emptied, while mixing, in seven batches; the first six were of equal volumes of 13.1 gallons each to represent the planned fullscale batches of 145,000 gallons, and the last, partial, batch of 6.9 gallons represented a full-scale partial batch of 76,000 gallons that will leave a 72-inch heel in the staging tank for the next cycle. The sole difference between the two campaigns was the energy to mix the scaled staging tank, i.e., the nozzle velocity and jet rotational speed of the two jet pumps. Campaign 1 used 22.9 ft/s, at 1.54 rpm based on past testing and Campaign 2 used 23.9 ft/s at 1.75 rpm, based on visual observation of minimum velocity that allowed fast settling solids, i.e., sand and stainless steel, to accumulate on the scaled tank bottom.

  3. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, K.M.; Alamgir, M.; Choe, H.S.

    1995-12-12

    This invention relates to Li ion (Li{sup +}) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF{sub 3}SO{sub 2}){sub 2}, LiAsF{sub 6}, and LiClO{sub 4}. 2 figs.

  4. Solid state switch

    DOE Patents [OSTI]

    Merritt, Bernard T.; Dreifuerst, Gary R.

    1994-01-01

    A solid state switch, with reverse conducting thyristors, is designed to operate at 20 kV hold-off voltage, 1500 A peak, 1.0 .mu.s pulsewidth, and 4500 pps, to replace thyratrons. The solid state switch is more reliable, more economical, and more easily repaired. The switch includes a stack of circuit card assemblies, a magnetic assist and a trigger chassis. Each circuit card assembly contains a reverse conducting thyristor, a resistor capacitor network, and triggering circuitry.

  5. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M.; Alamgir, Mohamed; Choe, Hyoun S.

    1995-01-01

    This invention relates to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF.sub.3 SO.sub.2).sub.2, LiAsF.sub.6, and LiClO.sub.4.

  6. Pressurization of whole element canister during staging

    SciTech Connect (OSTI)

    Huang, F.F.

    1998-01-27

    An analytical model was developed to estimate the buildup of gas pressure for a single outer element in a hot cell test container for a post cold vacuum drying staging/storage test. This model considers various sources of gas generation and gas consumption as a function of time. In a canister containing spent nuclear fuel, hydrogen is generated from the reactions of uranium with free water or hydrated water, hydride decomposition, and radiolysis. The canister pressurization model predicts a stable pressure and a peak temperature during staging, with an assumption that a fuel element contains 40 gm of corrosion products and a decay heat of 2.07 or 1.06 Watts. Calculations were also performed on constant temperature tests for fuel elements containing varied amounts of sludge tested at 150, 125, 105, and 85 C. The pressurization model will be used to evaluate test results obtained from post-drying testing on whole fuel elements.

  7. Thermoelectric refrigerator having improved temperature stabilization means

    DOE Patents [OSTI]

    Falco, Charles M.

    1982-01-01

    A control system for thermoelectric refrigerators is disclosed. The thermoelectric refrigerator includes at least one thermoelectric element that undergoes a first order change at a predetermined critical temperature. The element functions as a thermoelectric refrigerator element above the critical temperature, but discontinuously ceases to function as a thermoelectric refrigerator element below the critical temperature. One example of such an arrangement includes thermoelectric refrigerator elements which are superconductors. The transition temperature of one of the superconductor elements is selected as the temperature control point of the refrigerator. When the refrigerator attempts to cool below the point, the metals become superconductors losing their ability to perform as a thermoelectric refrigerator. An extremely accurate, first-order control is realized.

  8. Self supporting heat transfer element

    DOE Patents [OSTI]

    Story, Grosvenor Cook (Livermore, CA); Baldonado, Ray Orico (Livermore, CA)

    2002-01-01

    The present invention provides an improved internal heat exchange element arranged so as to traverse the inside diameter of a container vessel such that it makes good mechanical contact with the interior wall of that vessel. The mechanical element is fabricated from a material having a coefficient of thermal conductivity above about 0.8 W cm.sup.-1.degree. K.sup.-1 and is designed to function as a simple spring member when that member has been cooled to reduce its diameter to just below that of a cylindrical container or vessel into which it is placed and then allowed to warm to room temperature. A particularly important application of this invention is directed to a providing a simple compartmented storage container for accommodating a hydrogen absorbing alloy.

  9. Solid State Division progress report, September 30, 1981

    SciTech Connect (OSTI)

    Not Available

    1982-04-01

    Progress made during the 19 months from March 1, 1980, through September 30, 1981, is reported in the following areas: theoretical solid state physics (surfaces, electronic and magnetic properties, particle-solid interactions, and laser annealing); surface and near-surface properties of solids (plasma materials interactions, ion-solid interactions, pulsed laser annealing, and semiconductor physics and photovoltaic conversion); defects in solids (radiation effects, fracture, and defects and impurities in insulating crystals); transport properties of solids (fast-ion conductors, superconductivity, and physical properties of insulating materials); neutron scattering (small-angle scattering, lattice dynamics, and magnetic properties); crystal growth and characterization (nuclear waste forms, ferroelectric mateirals, high-temperature materials, and special materials); and isotope research materials. Publications and papers are listed. (WHK)

  10. The synthetic elements

    SciTech Connect (OSTI)

    Hoffman, D.C.

    1990-05-01

    Prior to 1940, the heaviest element known was uranium, discovered in 1789. Since that time the elements 93 through 109 have been synthesized and identified and the elements 43, 61, 85, and 87 which were missing form the periodic tables of the 1930's have been discovered. The techniques and problems involved in these discoveries and the placement of the transuranium elements in the periodic table will be discussed. The production and positive identification of elements heavier than Md (Z=101), which have very short half-lives and can only be produced an atom-at-a-time, are very difficult and there have been controversies concerning their discovery. Some of the new methods which have been developed and used in these studies will be described. The prospects for production of still heavier elements will be considered.

  11. Nuclear fuel elements made from nanophase materials

    DOE Patents [OSTI]

    Heubeck, N.B.

    1998-09-08

    A nuclear reactor core fuel element is composed of nanophase high temperature materials. An array of the fuel elements in rod form are joined in an open geometry fuel cell that preferably also uses such nanophase materials for the cell structures. The particular high temperature nanophase fuel element material must have the appropriate mechanical characteristics to avoid strain related failure even at high temperatures, in the order of about 3000 F. Preferably, the reactor type is a pressurized or boiling water reactor and the nanophase material is a high temperature ceramic or ceramic composite. Nanophase metals, or nanophase metals with nanophase ceramics in a composite mixture, also have desirable characteristics, although their temperature capability is not as great as with all-ceramic nanophase material. Combinations of conventional or nanophase metals and conventional or nanophase ceramics can be employed as long as there is at least one nanophase material in the composite. The nuclear reactor so constructed has a number of high strength fuel particles, a nanophase structural material for supporting a fuel rod at high temperature, a configuration to allow passive cooling in the event of a primary cooling system failure, an ability to retain a coolable geometry even at high temperatures, an ability to resist generation of hydrogen gas, and a configuration having good nuclear, corrosion, and mechanical characteristics. 5 figs.

  12. Nuclear fuel elements made from nanophase materials

    DOE Patents [OSTI]

    Heubeck, Norman B.

    1998-01-01

    A nuclear reactor core fuel element is composed of nanophase high temperature materials. An array of the fuel elements in rod form are joined in an open geometry fuel cell that preferably also uses such nanophase materials for the cell structures. The particular high temperature nanophase fuel element material must have the appropriate mechanical characteristics to avoid strain related failure even at high temperatures, in the order of about 3000.degree. F. Preferably, the reactor type is a pressurized or boiling water reactor and the nanophase material is a high temperature ceramic or ceramic composite. Nanophase metals, or nanophase metals with nanophase ceramics in a composite mixture, also have desirable characteristics, although their temperature capability is not as great as with all-ceramic nanophase material. Combinations of conventional or nanophase metals and conventional or nanophase ceramics can be employed as long as there is at least one nanophase material in the composite. The nuclear reactor so constructed has a number of high strength fuel particles, a nanophase structural material for supporting a fuel rod at high temperature, a configuration to allow passive cooling in the event of a primary cooling system failure, an ability to retain a coolable geometry even at high temperatures, an ability to resist generation of hydrogen gas, and a configuration having good nuclear, corrosion, and mechanical characteristics.

  13. Creep Behavior of Glass/Ceramic Sealant and its Effect on Long-term Performance of Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Liu, Wenning N.; Sun, Xin; Koeppel, Brian J.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2009-10-14

    The creep behavior of glass or glass-ceramic sealant materials used in solid oxide fuel cells (SOFCs) becomes relevant under SOFC operating temperatures. In this paper, the creep of glass-ceramic sealants was experimentally examined, and a standard linear solid model was applied to capture the creep behavior of glass ceramic sealant materials developed for planar SOFCs at high temperatures. The parameters of this model were determined based on the creep test results. Furthermore, the creep model was incorporated into finite-element software programs SOFC-MP and Mentat-FC developed at Pacific Northwest National Laboratory for multi-physics simulation of SOFCs. The effect of creep of glass ceramic sealant materials on the long-term performance of SOFC stacks was investigated by studying the stability of the flow channels and the stress redistribution in the glass seal and on the various interfaces of the glass seal with other layers. Finite element analyses were performed to quantify the stresses in various parts. The stresses in glass seals were released because of creep behavior during operations.

  14. Rate Case Elements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proceeding Rate Information Residential Exchange Program Surplus Power Sales Reports Rate Case Elements BPA's rate cases are decided "on the record." That is, in making a decision...

  15. Summary compilation of shell element performance versus formulation.

    SciTech Connect (OSTI)

    Heinstein, Martin Wilhelm; Hales, Jason Dean; Breivik, Nicole L.; Key, Samuel W.

    2011-07-01

    This document compares the finite element shell formulations in the Sierra Solid Mechanics code. These are finite elements either currently in the Sierra simulation codes Presto and Adagio, or expected to be added to them in time. The list of elements are divided into traditional two-dimensional, plane stress shell finite elements, and three-dimensional solid finite elements that contain either modifications or additional terms designed to represent the bending stiffness expected to be found in shell formulations. These particular finite elements are formulated for finite deformation and inelastic material response, and, as such, are not based on some of the elegant formulations that can be found in an elastic, infinitesimal finite element setting. Each shell element is subjected to a series of 12 verification and validation test problems. The underlying purpose of the tests here is to identify the quality of both the spatially discrete finite element gradient operator and the spatially discrete finite element divergence operator. If the derivation of the finite element is proper, the discrete divergence operator is the transpose of the discrete gradient operator. An overall summary is provided from which one can rank, at least in an average sense, how well the individual formulations can be expected to perform in applications encountered year in and year out. A letter grade has been assigned albeit sometimes subjectively for each shell element and each test problem result. The number of A's, B's, C's, et cetera assigned have been totaled, and a grade point average (GPA) has been computed, based on a 4.0-system. These grades, combined with a comparison between the test problems and the application problem, can be used to guide an analyst to select the element with the best shell formulation.

  16. Solid state switch

    DOE Patents [OSTI]

    Merritt, B.T.; Dreifuerst, G.R.

    1994-07-19

    A solid state switch, with reverse conducting thyristors, is designed to operate at 20 kV hold-off voltage, 1,500 A peak, 1.0 [mu]s pulsewidth, and 4,500 pps, to replace thyratrons. The solid state switch is more reliable, more economical, and more easily repaired. The switch includes a stack of circuit card assemblies, a magnetic assist and a trigger chassis. Each circuit card assembly contains a reverse conducting thyristor, a resistor capacitor network, and triggering circuitry. 6 figs.

  17. Solid handling valve

    DOE Patents [OSTI]

    Williams, William R.

    1979-01-01

    The present invention is directed to a solids handling valve for use in combination with lock hoppers utilized for conveying pulverized coal to a coal gasifier. The valve comprises a fluid-actuated flow control piston disposed within a housing and provided with a tapered primary seal having a recessed seat on the housing and a radially expandable fluid-actuated secondary seal. The valve seals are highly resistive to corrosion, erosion and abrasion by the solids, liquids, and gases associated with the gasification process so as to minimize valve failure.

  18. Generator configuration for solid oxide fuel cells

    DOE Patents [OSTI]

    Reichner, Philip

    1989-01-01

    Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

  19. MOLDED SEALING ELEMENT

    DOE Patents [OSTI]

    Bradford, B.W.; Skinner, W.J.

    1959-03-24

    Molded sealing elements suitable for use under conditions involving exposure to uranium hexafluoride vapor are described. Such sealing elements are made by subjecting graphitic carbons to a preliminary treatment with uranium hexafluoride vapor, and then incorporating polytetrafluorethylene in them. The resulting composition has good wear resistant and frictional properties and is resistant to disintegration by uranium hexafluoride over long periods of exposure.

  20. Static & Dynamic Response of 3D Solids

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    NIKE3D is a large deformations 3D finite element code used to obtain the resulting displacements and stresses from multi-body static and dynamic structural thermo-mechanics problems with sliding interfaces. Many nonlinear and temperature dependent constitutive models are available.

  1. Solid state engine using nitinol memory alloy

    DOE Patents [OSTI]

    Golestaneh, Ahmad A.

    1981-01-01

    A device for converting heat energy to mechanical energy includes a reservoir of a hot fluid and a rotor assembly mounted thereabove so a portion of it dips into the hot fluid. The rotor assembly may include a shaft having four spokes extending radially outwardly therefrom at right angles to each other, a floating ring and four flexible elements composed of a thermal memory material having a critical temperature between the temperature of the hot fluid and that of the ambient atmosphere extending between the ends of the spokes and the floating ring. Preferably, the flexible elements are attached to the floating ring through curved leaf springs. Energetic shape recovery of the flexible elements in the hot fluid causes the rotor assembly to rotate.

  2. Solid state engine using nitinol memory alloy

    DOE Patents [OSTI]

    Golestaneh, A.A.

    1980-01-21

    A device for converting heat energy to mechanical energy includes a reservoir of a hot fluid and a rotor assembly mounted thereabove so a portion of it dips into the hot fluid. The rotor assembly may include a shaft having four spokes extending radially outwardly therefrom at right angles to each other, a floating ring and four flexible elements composed of a thermal memory material having a critical temperature between the temperature of the hot fluid and that of the ambient atmosphere extending between the ends of the spokes and the floating ring. Preferably, the flexible elements are attached to the floating ring through curved leaf springs. Energetic shape recovery of the flexible elements in the hot fluid causes the rotor assembly to rotate.

  3. Solid polymer electrolyte compositions

    DOE Patents [OSTI]

    Garbe, James E.; Atanasoski, Radoslav; Hamrock, Steven J.; Le, Dinh Ba

    2001-01-01

    An electrolyte composition is featured that includes a solid, ionically conductive polymer, organically modified oxide particles that include organic groups covalently bonded to the oxide particles, and an alkali metal salt. The electrolyte composition is free of lithiated zeolite. The invention also features cells that incorporate the electrolyte composition.

  4. Method of altering the effective bulk density of solid material and the resulting product

    DOE Patents [OSTI]

    Kool, Lawrence B.; Nolen, Robert L.; Solomon, David E.

    1983-01-01

    A method of adjustably tailoring the effective bulk density of a solid material in which a mixture comprising the solid material, a film-forming polymer and a volatile solvent are sprayed into a drying chamber such that the solvent evaporates and the polymer dries into hollow shells having the solid material captured within the shell walls. Shell density may be varied as a function of solid/polymer concentration, droplet size and drying temperature.

  5. Solid composite electrolytes for lithium batteries

    DOE Patents [OSTI]

    Kumar, Binod; Scanlon, Jr., Lawrence G.

    2001-01-01

    Solid composite electrolytes are provided for use in lithium batteries which exhibit moderate to high ionic conductivity at ambient temperatures and low activation energies. In one embodiment, a polymer-ceramic composite electrolyte containing poly(ethylene oxide), lithium tetrafluoroborate and titanium dioxide is provided in the form of an annealed film having a room temperature conductivity of from 10.sup.-5 S cm.sup.-1 to 10.sup.-3 S cm.sup.-1 and an activation energy of about 0.5 eV.

  6. Harsh-Environment Solid-State Gamma Detector for Down-hole Gas and Oil Exploration

    SciTech Connect (OSTI)

    Peter Sandvik; Stanislav Soloviev; Emad Andarawis; Ho-Young Cha; Jim Rose; Kevin Durocher; Robert Lyons; Bob Pieciuk; Jim Williams; David O'Connor

    2007-08-10

    The goal of this program was to develop a revolutionary solid-state gamma-ray detector suitable for use in down-hole gas and oil exploration. This advanced detector would employ wide-bandgap semiconductor technology to extend the gamma sensor's temperature capability up to 200 C as well as extended reliability, which significantly exceeds current designs based on photomultiplier tubes. In Phase II, project tasks were focused on optimization of the final APD design, growing and characterizing the full scintillator crystals of the selected composition, arranging the APD device packaging, developing the needed optical coupling between scintillator and APD, and characterizing the combined elements as a full detector system preparing for commercialization. What follows is a summary report from the second 18-month phase of this program.

  7. Simulation of uranium transport with variable temperature and oxidation potential: The computer program THCC (Thermo-Hydro-Chemical Coupling)

    SciTech Connect (OSTI)

    Carnahan, C.L.

    1986-12-01

    A simulator of reactive chemical transport has been constructed with the capabilities of treating variable temperatures and variable oxidation potentials within a single simulation. Homogeneous and heterogeneous chemical reactions are simulated at temperature-dependent equilibrium, and changes of oxidation states of multivalent elements can be simulated during transport. Chemical mass action relations for formation of complexes in the fluid phase are included explicitly within the partial differential equations of transport, and a special algorithm greatly simplifies treatment of reversible precipitation of solid phases. This approach allows direct solution of the complete set of governing equations for concentrations of all aqueous species and solids affected simultaneously by chemical and physical processes. Results of example simulations of transport, along a temperature gradient, of uranium solution species under conditions of varying pH and oxidation potential and with reversible precipitation of uraninite and coffinite are presented. The examples illustrate how inclusion of variable temperature and oxidation potential in numerical simulators can enhance understanding of the chemical mechanisms affecting migration of multivalent waste elements.

  8. Temperature controlled high voltage regulator

    DOE Patents [OSTI]

    Chiaro, Jr., Peter J. (Clinton, TN); Schulze, Gerald K. (Knoxville, TN)

    2004-04-20

    A temperature controlled high voltage regulator for automatically adjusting the high voltage applied to a radiation detector is described. The regulator is a solid state device that is independent of the attached radiation detector, enabling the regulator to be used by various models of radiation detectors, such as gas flow proportional radiation detectors.

  9. Elements in biological AMS

    SciTech Connect (OSTI)

    Vogel, J.S.; McAninch, J.; Freeman, S.

    1996-08-01

    AMS (Accelerator Mass Spectrometry) provides high detection sensitivity for isotopes whose half-lives are between 10 years and 100 million years. {sup 14}C is the most developed of such isotopes and is used in tracing natural and anthropogenic organic compounds in the Earth`s biosphere. Thirty-three elements in the main periodic table and 17 lanthanides or actinides have long lived isotopes, providing potential tracers for research in elemental biochemistry. Overlap of biologically interesting heavy elements and possible AMS tracers is discussed.

  10. Probabilistic Based Design Methodology for Solid Oxide Fuel Cell Stacks

    SciTech Connect (OSTI)

    Sun, Xin; Tartakovsky, Alexandre M.; Khaleel, Mohammad A.

    2009-05-01

    A probabilistic-based component design methodology is developed for solid oxide fuel cell (SOFC) stack. This method takes into account the randomness in SOFC material properties as well as the stresses arising from different manufacturing and operating conditions. The purpose of this work is to provide the SOFC designers a design methodology such that desired level of component reliability can be achieved with deterministic design functions using an equivalent safety factor to account for the uncertainties in material properties and structural stresses. Multi-physics-based finite element analyses were used to predict the electrochemical and thermal mechanical responses of SOFC stacks with different geometric variations and under different operating conditions. Failures in the anode and the seal were used as design examples. The predicted maximum principal stresses in the anode and the seal were compared with the experimentally determined strength characteristics for the anode and the seal respectively. Component failure probabilities for the current design were then calculated under different operating conditions. It was found that anode failure probability is very low under all conditions examined. The seal failure probability is relatively high, particularly for high fuel utilization rate under low average cell temperature. Next, the procedures for calculating the equivalent safety factors for anode and seal were demonstrated such that uniform failure probability of the anode and seal can be achieved. Analysis procedures were also included for non-normal distributed random variables such that more realistic distributions of strength and stress can be analyzed using the proposed design methodology.

  11. Solid electrolytes strengthened by metal dispersions

    DOE Patents [OSTI]

    Lauf, Robert J.; Morgan, Chester S.

    1983-01-01

    An improvement in solid electrolytes of advanced secondary batteries of the sodium-sulfur, sodium-halogen, and like combinations is achieved by providing said battery with a cermet electrolyte containing a metal dispersion ranging from 0.1 to 10.0 vol. % of a substantially nonreactive metal selected from the group consisting essentially of Pt, Cr, Fe, Co, Ni, Nb, their alloys, and their physical mixtures in the elemental or uncombined state, the remainder of said cermet being an ion-conductive ceramic material.

  12. Solid electrolytes strengthened by metal dispersions

    DOE Patents [OSTI]

    Lauf, R.J.; Morgan, C.S.

    1981-10-05

    An improvement in solid electrolytes of advanced secondary batteries of the sodium-sulfur, sodium-halogen, and like combinations is achieved by providing said battery with a cermet electrolyte containing a metal dispersion ranging from 0.1 to 10.0 vol. % of a substantially nonreactive metal selected from the group consisting essentially of Pt, Cr, Fe, Co, Ni, Nb, their alloys, and their physical mixtures in the elemental or uncombined state, the remainder of said cermet being an ion-conductive ceramic material.

  13. Solid oxide fuel cell with single material for electrodes and interconnect

    DOE Patents [OSTI]

    McPheeters, C.C.; Nelson, P.A.; Dees, D.W.

    1994-07-19

    A solid oxide fuel cell is described having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed there between, and the anode, cathode and interconnect elements are comprised of substantially one material. 9 figs.

  14. COMPOSITE FUEL ELEMENT

    DOE Patents [OSTI]

    Hurford, W.J.; Gordon, R.B.; Johnson, W.A.

    1962-12-25

    A sandwich-type fuel element for a reactor is described. This fuel element has the shape of an elongated flat plate and includes a filler plate having a plurality of compartments therein in which the fuel material is located. The filler plate is clad on both sides with a thin cladding material which is secured to the filler plate only to completely enclose the fuel material in each compartment. (AEC)

  15. Solid Fuels Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Software Computations Uncertainty Quantification Stochastic About CRF Transportation Energy Consortiums Engine Combustion Heavy Duty Heavy Duty Low-Temperature & Diesel Combustion ...

  16. PURPA and solid fuels

    SciTech Connect (OSTI)

    Not Available

    1987-09-01

    Speaking before the FERC during the Spring, 1987 PURPA Hearings, Dr. Thomas A.V. Cassel, president of the Philadelphia, Pennsylvania-based Reading Energy Group, testified on the role PURPA has played in the development of the nation's solid fuel resource. Reading's Energy Group has in excess of $150 million of cogeneration assets under construction. These projects represent more than 65 MW and are fired by solid fuels which, prior to PURPA's enactment, were considered to be valueless waste and were overlooked by the electric utility industry. These plants will burn lignite and culm. Because of PURPA, culm will soon be eliminated as an eyesore and source of river pollution, and, at the same time, will help revitalize depressed mining areas.

  17. Solid waste handling

    SciTech Connect (OSTI)

    Parazin, R.J.

    1995-05-31

    This study presents estimates of the solid radioactive waste quantities that will be generated in the Separations, Low-Level Waste Vitrification and High-Level Waste Vitrification facilities, collectively called the Tank Waste Remediation System Treatment Complex, over the life of these facilities. This study then considers previous estimates from other 200 Area generators and compares alternative methods of handling (segregation, packaging, assaying, shipping, etc.).

  18. Solid phase extraction membrane

    DOE Patents [OSTI]

    Carlson, Kurt C [Nashville, TN; Langer, Roger L [Hudson, WI

    2002-11-05

    A wet-laid, porous solid phase extraction sheet material that contains both active particles and binder and that possesses excellent wet strength is described. The binder is present in a relatively small amount while the particles are present in a relatively large amount. The sheet material is sufficiently strong and flexible so as to be pleatable so that, for example, it can be used in a cartridge device.

  19. solid rocket propellant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    solid rocket propellant - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  20. Solar solids reactor

    DOE Patents [OSTI]

    Yudow, Bernard D.

    1987-01-01

    A solar powered kiln is provided, that is of relatively simple design and which efficiently uses solar energy. The kiln or solids reactor includes a stationary chamber with a rearward end which receives solid material to be reacted and a forward end through which reacted material is disposed of, and a screw conveyor extending along the bottom of the chamber for slowly advancing the material between the chamber ends. Concentrated solar energy is directed to an aperture at the forward end of the chamber to heat the solid material moving along the bottom of the chamber. The solar energy can be reflected from a mirror facing at an upward incline, through the aperture and against a heat-absorbing material near the top of the chamber, which moves towards the rear of the chamber to distribute heat throughout the chamber. Pumps at the forward and rearward ends of the chamber pump heated sweep gas through the length of the chamber, while minimizing the flow of gas through an open aperture through which concentrated sunlight is received.

  1. Solar solids reactor

    DOE Patents [OSTI]

    Yudow, B.D.

    1986-02-24

    A solar powered kiln is provided, that is of relatively simple design and which efficiently uses solar energy. The kiln or solids reactor includes a stationary chamber with a rearward end which receives solid material to be reacted and a forward end through which reacted material is disposed of, and a screw conveyor extending along the bottom of the chamber for slowly advancing the material between the chamber ends. Concentrated solar energy is directed to an aperture at the forward end of the chamber to heat the solid material moving along the bottom of the chamber. The solar energy can be reflected from a mirror facing at an upward incline, through the aperture and against a heat-absorbing material near the top of the chamber, which moves towards the rear of the chamber to distribute heat throughout the chamber. Pumps at the forward and rearward ends of the chamber pump heated sweep gas through the length of the chamber, while minimizing the flow of gas through an open aperture through which concentrated sunlight is received.

  2. Solid state electrochemical current source

    DOE Patents [OSTI]

    Potanin, Alexander Arkadyevich; Vedeneev, Nikolai Ivanovich

    2002-04-30

    A cathode and a solid state electrochemical cell comprising said cathode, a solid anode and solid fluoride ion conducting electrolyte. The cathode comprises a metal oxide and a compound fluoride containing at least two metals with different valences. Representative compound fluorides include solid solutions of bismuth fluoride and potassium fluoride; and lead fluoride and potassium fluoride. Representative metal oxides include copper oxide, lead oxide, manganese oxide, vanadium oxide and silver oxide.

  3. Chemical digestion of low level nuclear solid waste material

    DOE Patents [OSTI]

    Cooley, Carl R.; Lerch, Ronald E.

    1976-01-01

    A chemical digestion for treatment of low level combustible nuclear solid waste material is provided and comprises reacting the solid waste material with concentrated sulfuric acid at a temperature within the range of 230.degree.-300.degree.C and simultaneously and/or thereafter contacting the reacting mixture with concentrated nitric acid or nitrogen dioxide. In a special embodiment spent ion exchange resins are converted by this chemical digestion to noncombustible gases and a low volume noncombustible residue.

  4. Solid oxide fuel cell steam reforming power system

    DOE Patents [OSTI]

    Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

    2013-03-12

    The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

  5. Thermionic converter temperature controller

    DOE Patents [OSTI]

    Shaner, Benjamin J. (McMurray, PA); Wolf, Joseph H. (Pittsburgh, PA); Johnson, Robert G. R. (Trafford, PA)

    2001-04-24

    A method and apparatus for controlling the temperature of a thermionic reactor over a wide range of operating power, including a thermionic reactor having a plurality of integral cesium reservoirs, a honeycomb material disposed about the reactor which has a plurality of separated cavities, a solid sheath disposed about the honeycomb material and having an opening therein communicating with the honeycomb material and cavities thereof, and a shell disposed about the sheath for creating a coolant annulus therewith so that the coolant in the annulus may fill the cavities and permit nucleate boiling during the operation of the reactor.

  6. Ferroelectric tunneling element and memory applications which utilize the tunneling element

    DOE Patents [OSTI]

    Kalinin, Sergei V. [Knoxville, TN; Christen, Hans M. [Knoxville, TN; Baddorf, Arthur P. [Knoxville, TN; Meunier, Vincent [Knoxville, TN; Lee, Ho Nyung [Oak Ridge, TN

    2010-07-20

    A tunneling element includes a thin film layer of ferroelectric material and a pair of dissimilar electrically-conductive layers disposed on opposite sides of the ferroelectric layer. Because of the dissimilarity in composition or construction between the electrically-conductive layers, the electron transport behavior of the electrically-conductive layers is polarization dependent when the tunneling element is below the Curie temperature of the layer of ferroelectric material. The element can be used as a basis of compact 1R type non-volatile random access memory (RAM). The advantages include extremely simple architecture, ultimate scalability and fast access times generic for all ferroelectric memories.

  7. Compliant high temperature seals for dissimilar materials

    DOE Patents [OSTI]

    Rynders, Steven Walton; Minford, Eric; Tressler, Richard Ernest; Taylor, Dale M.

    2001-01-01

    A high temperature, gas-tight seal is formed by utilizing one or more compliant metallic toroidal ring sealing elements, where the applied pressure serves to activate the seal, thus improving the quality of the seal. The compliant nature of the sealing element compensates for differences in thermal expansion between the materials to be sealed, and is particularly useful in sealing a metallic member and a ceramic tube art elevated temperatures. The performance of the seal may be improved by coating the sealing element with a soft or flowable coating such as silver or gold and/or by backing the sealing element with a bed of fine powder. The material of the sealing element is chosen such that the element responds to stress elastically, even at elevated temperatures, permitting the seal to operate through multiple thermal cycles.

  8. 2-d Finite Element Code Postprocessor

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    ORION is an interactive program that serves as a postprocessor for the analysis programs NIKE2D, DYNA2D, TOPAZ2D, and CHEMICAL TOPAZ2D. ORION reads binary plot files generated by the two-dimensional finite element codes currently used by the Methods Development Group at LLNL. Contour and color fringe plots of a large number of quantities may be displayed on meshes consisting of triangular and quadrilateral elements. ORION can compute strain measures, interface pressures along slide lines, reaction forcesmore » along constrained boundaries, and momentum. ORION has been applied to study the response of two-dimensional solids and structures undergoing finite deformations under a wide variety of large deformation transient dynamic and static problems and heat transfer analyses.« less

  9. Solid oxide MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  10. Solid polymer MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.

    2008-04-22

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  11. High temperature solid oxide fuel cell: Customer test units

    SciTech Connect (OSTI)

    Ray, E.R.; Veyo, S.E.

    1993-11-01

    There are three 25-kW class SOFC customer test unit programs; two are in Japan (utility joint ventures), one for Southern California Edison Co. The two in Japan are described: Startup, testing, modifications, and operational performance are discussed.

  12. High Temperature Solid Oxide Fuel Cell Generator Development

    SciTech Connect (OSTI)

    Joseph Pierre

    2007-09-30

    This report describes the results of the tubular SOFC development program from August 22, 1997 to September 30, 2007 under the Siemens/U.S. Department of Energy Cooperative Agreement. The technical areas discussed include cell manufacturing development, cell power enhancement, SOFC module and system cost reduction and technology advancement, and our field unit test program. Whereas significant progress has been made toward commercialization, significant effort remains to achieve our cost, performance and reliability targets for successful commercialization.

  13. Packaging of solid state devices

    DOE Patents [OSTI]

    Glidden, Steven C.; Sanders, Howard D.

    2006-01-03

    A package for one or more solid state devices in a single module that allows for operation at high voltage, high current, or both high voltage and high current. Low thermal resistance between the solid state devices and an exterior of the package and matched coefficient of thermal expansion between the solid state devices and the materials used in packaging enables high power operation. The solid state devices are soldered between two layers of ceramic with metal traces that interconnect the devices and external contacts. This approach provides a simple method for assembling and encapsulating high power solid state devices.

  14. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Hu, Zhicheng

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  15. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  16. Temperature profile detector

    DOE Patents [OSTI]

    Tokarz, R.D.

    1983-10-11

    Disclosed is a temperature profile detector shown as a tubular enclosure surrounding an elongated electrical conductor having a plurality of meltable conductive segments surrounding it. Duplicative meltable segments are spaced apart from one another along the length of the enclosure. Electrical insulators surround these elements to confine molten material from the segments in bridging contact between the conductor and a second electrical conductor, which might be the confining tube. The location and rate of growth of the resulting short circuits between the two conductors can be monitored by measuring changes in electrical resistance between terminals at both ends of the two conductors. Additional conductors and separate sets of meltable segments operational at differing temperatures can be monitored simultaneously for measuring different temperature profiles. 8 figs.

  17. Temperature System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Soil Water and Temperature System  SWATS In the realm of global climate modeling, numerous variables affect the state of the atmosphere and climate. One important area is soil moisture and temperature. The ARM Program uses several types of instruments to gather soil moisture information. An example is the soil water and temperature system (SWATS) (Figure 1). A SWATS is located at each of 21 extended facility sites within the CART site boundary. Each system is configured to measure soil

  18. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  19. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  20. Solid state optical microscope

    DOE Patents [OSTI]

    Young, Ian T.

    1983-01-01

    A solid state optical microscope wherein wide-field and high-resolution images of an object are produced at a rapid rate by utilizing conventional optics with a charge-coupled photodiode array. A galvanometer scanning mirror, for scanning in one of two orthogonal directions is provided, while the charge-coupled photodiode array scans in the other orthogonal direction. Illumination light from the object is incident upon the photodiodes, creating packets of electrons (signals) which are representative of the illuminated object. The signals are then processed, stored in a memory, and finally displayed as a video signal.

  1. Solid state optical microscope

    DOE Patents [OSTI]

    Young, I.T.

    1983-08-09

    A solid state optical microscope wherein wide-field and high-resolution images of an object are produced at a rapid rate by utilizing conventional optics with a charge-coupled photodiode array. A galvanometer scanning mirror, for scanning in one of two orthogonal directions is provided, while the charge-coupled photodiode array scans in the other orthogonal direction. Illumination light from the object is incident upon the photodiodes, creating packets of electrons (signals) which are representative of the illuminated object. The signals are then processed, stored in a memory, and finally displayed as a video signal. 2 figs.

  2. Super-Heavy Element Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Targets for Super-Heavy Element Research Presented at International Workshop on Super-Heavy Element Research SHE-15 J. B. Roberto Oak Ridge National Laboratory Oak Ridge,...

  3. Element Partners | Open Energy Information

    Open Energy Info (EERE)

    Product: DFJ Element, a partnership between Element Venture Partners and Draper Fisher Jurvetson, manages a venture capital fund focusing on investments in high growth,...

  4. American Elements | Open Energy Information

    Open Energy Info (EERE)

    Elements Jump to: navigation, search Name: American Elements Place: Los Angeles, California Zip: 90024 Product: US-based manufacturer and supplier of PV feedstocks such as silicon,...

  5. Elemental Energy | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Logo: Elemental Energy Name: Elemental Energy Address: 14500 SW 92nd Ave Place: Portland, Oregon Country: United States Zip: 97224 Region: Pacific...

  6. Thermodynamic analysis of interactions between Ni-based solid oxide fuel cells (SOFC) anodes and trace species in a survey of coal syngas

    SciTech Connect (OSTI)

    Andrew Martinez; Kirk Gerdes; Randall Gemmen; James Postona

    2010-03-20

    A thermodynamic analysis was conducted to characterize the effects of trace contaminants in syngas derived from coal gasification on solid oxide fuel cell (SOFC) anode material. The effluents from 15 different gasification facilities were considered to assess the impact of fuel composition on anode susceptibility to contamination. For each syngas case, the study considers the magnitude of contaminant exposure resulting from operation of a warm gas cleanup unit at two different temperatures and operation of a nickel-based SOFC at three different temperatures. Contaminant elements arsenic (As), phosphorous (P), and antimony (Sb) are predicted to be present in warm gas cleanup effluent and will interact with the nickel (Ni) components of a SOFC anode. Phosphorous is the trace element found in the largest concentration of the three contaminants and is potentially the most detrimental. Poisoning was found to depend on the composition of the syngas as well as system operating conditions. Results for all trace elements tended to show invariance with cleanup operating temperature, but results were sensitive to syngas bulk composition. Synthesis gas with high steam content tended to resist poisoning.

  7. Solid state radiative heat pump

    DOE Patents [OSTI]

    Berdahl, Paul H.

    1986-01-01

    A solid state radiative heat pump (10, 50, 70) operable at room temperature (300.degree. K.) utilizes a semiconductor having a gap energy in the range of 0.03-0.25 eV and operated reversibly to produce an excess or deficit of charge carriers as compared to thermal equilibrium. In one form of the invention (10, 70) an infrared semiconductor photodiode (21, 71) is used, with forward or reverse bias, to emit an excess or deficit of infrared radiation. In another form of the invention (50), a homogeneous semiconductor (51) is subjected to orthogonal magnetic and electric fields to emit an excess or deficit of infrared radiation. Three methods of enhancing transmission of radiation through the active surface of the semiconductor are disclosed. In one method, an anti-reflection layer (19) is coated into the active surface (13) of the semiconductor (11), the anti-reflection layer (19) having an index of refraction equal to the square root of that of the semiconductor (11). In the second method, a passive layer (75) is spaced from the active surface (73) of the semiconductor (71) by a submicron vacuum gap, the passive layer having an index of refractive equal to that of the semiconductor. In the third method, a coupler (91) with a paraboloid reflecting surface (92) is in contact with the active surface (13, 53) of the semiconductor (11, 51), the coupler having an index of refraction about the same as that of the semiconductor.

  8. Solid state radiative heat pump

    DOE Patents [OSTI]

    Berdahl, P.H.

    1984-09-28

    A solid state radiative heat pump operable at room temperature (300 K) utilizes a semiconductor having a gap energy in the range of 0.03-0.25 eV and operated reversibly to produce an excess or deficit of change carriers as compared equilibrium. In one form of the invention an infrared semiconductor photodiode is used, with forward or reverse bias, to emit an excess or deficit of infrared radiation. In another form of the invention, a homogenous semiconductor is subjected to orthogonal magnetic and electric fields to emit an excess or deficit of infrared radiation. Three methods of enhancing transmission of radiation the active surface of the semiconductor are disclosed. In one method, an anti-refection layer is coated into the active surface of the semiconductor, the anti-reflection layer having an index of refraction equal to the square root of that of the semiconductor. In the second method, a passive layer is speaced trom the active surface of the semiconductor by a submicron vacuum gap, the passive layer having an index of refractive equal to that of the semiconductor. In the third method, a coupler with a paraboloid reflecting surface surface is in contact with the active surface of the semiconductor, the coupler having an index of refraction about the same as that of the semiconductor.

  9. JACKETED REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Smith, K.F.; Van Thyne, R.J.

    1958-12-01

    A fuel element is described for fast reactors comprised of a core of uranium metal containing material and a jacket around the core, the jacket consisting of from 2.5 to 15 percent of titanium, from 1 to 5 percent of niobium, and from 80 to 96.5 percent of vanadium.

  10. Senescence responsive transcriptional element

    DOE Patents [OSTI]

    Campisi, Judith; Testori, Alessandro

    1999-01-01

    Recombinant polynucleotides have expression control sequences that have a senescence responsive element and a minimal promoter, and which are operatively linked to a heterologous nucleotide sequence. The molecules are useful for achieving high levels of expression of genes in senescent cells. Methods of inhibiting expression of genes in senescent cells also are provided.

  11. Photovoltaic radiation detector element

    DOE Patents [OSTI]

    Agouridis, Dimitrios C.

    1983-01-01

    A radiation detector element is formed of a body of semiconductor material, a coating on the body which forms a photovoltaic junction therewith, and a current collector consisting of narrow metallic strips, the aforesaid coating having an opening therein the edge of which closely approaches but is spaced from the current collector strips.

  12. Heating element support clip

    DOE Patents [OSTI]

    Sawyer, William C.

    1995-01-01

    An apparatus for supporting a heating element in a channel formed in a heater base is disclosed. A preferred embodiment includes a substantially U-shaped tantalum member. The U-shape is characterized by two substantially parallel portions of tantalum that each have an end connected to opposite ends of a base portion of tantalum. The parallel portions are each substantially perpendicular to the base portion and spaced apart a distance not larger than a width of the channel and not smaller than a width of a graphite heating element. The parallel portions each have a hole therein, and the centers of the holes define an axis that is substantially parallel to the base portion. An aluminum oxide ceramic retaining pin extends through the holes in the parallel portions and into a hole in a wall of the channel to retain the U-shaped member in the channel and to support the graphite heating element. The graphite heating element is confined by the parallel portions of tantalum, the base portion of tantalum, and the retaining pin. A tantalum tube surrounds the retaining pin between the parallel portions of tantalum.

  13. Heating element support clip

    DOE Patents [OSTI]

    Sawyer, W.C.

    1995-08-15

    An apparatus for supporting a heating element in a channel formed in a heater base is disclosed. A preferred embodiment includes a substantially U-shaped tantalum member. The U-shape is characterized by two substantially parallel portions of tantalum that each have an end connected to opposite ends of a base portion of tantalum. The parallel portions are each substantially perpendicular to the base portion and spaced apart a distance not larger than a width of the channel and not smaller than a width of a graphite heating element. The parallel portions each have a hole therein, and the centers of the holes define an axis that is substantially parallel to the base portion. An aluminum oxide ceramic retaining pin extends through the holes in the parallel portions and into a hole in a wall of the channel to retain the U-shaped member in the channel and to support the graphite heating element. The graphite heating element is confined by the parallel portions of tantalum, the base portion of tantalum, and the retaining pin. A tantalum tube surrounds the retaining pin between the parallel portions of tantalum. 6 figs.

  14. NEUTRONIC REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Gurinsky, D.H.; Powell, R.W.; Fox, M.

    1959-11-24

    A nuclear fuel element comprising a plurality of nuclear fuel bearing strips is presented. The strips are folded along their longitudinal axes to an angle of about 60 deg and are secured at each end by ferrule to form an elongated assembly suitable for occupying a cylindrical coolant channel.

  15. Photovoltaic radiation detector element

    DOE Patents [OSTI]

    Agouridis, D.C.

    1980-12-17

    A radiation detector element is formed of a body of semiconductor material, a coating on the body which forms a photovoltaic junction therewith, and a current collector consisting of narrow metallic strips, the aforesaid coating having an opening therein in the edge of which closely approaches but is spaced from the current collector strips.

  16. NEUTRONIC REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Stacy, J.T.

    1958-12-01

    A reactor fuel element having a core of molybdenum-uranium alloy jacketed in stainless steel is described. A barrier layer of tungsten, tantalum, molybdenum, columbium, or silver is interposed between the core and jacket to prevent formation of a low melting eutectic between uranium and the varlous alloy constituents of the stainless steel.

  17. Low Energy Electrodynamics in Solids (LEES) 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low Energy Electrodynamics in Solids (LEES) 2012 Low Energy Electrodynamics in Solids (LEES) 2012 July 22-27, 2012; Napa...

  18. Low Energy Electrodynamics in Solids (LEES) 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low Energy Electrodynamics in Solids (LEES) 2012 Low Energy Electrodynamics in Solids (LEES) 2012 July 22-27, 2012; Napa

  19. 3-D Finite Element Heat Transfer

    Energy Science and Technology Software Center (OSTI)

    1992-02-01

    TOPAZ3D is a three-dimensional implicit finite element computer code for heat transfer analysis. TOPAZ3D can be used to solve for the steady-state or transient temperature field on three-dimensional geometries. Material properties may be temperature-dependent and either isotropic or orthotropic. A variety of time-dependent and temperature-dependent boundary conditions can be specified including temperature, flux, convection, and radiation. By implementing the user subroutine feature, users can model chemical reaction kinetics and allow for any type of functionalmore » representation of boundary conditions and internal heat generation. TOPAZ3D can solve problems of diffuse and specular band radiation in an enclosure coupled with conduction in the material surrounding the enclosure. Additional features include thermal contact resistance across an interface, bulk fluids, phase change, and energy balances.« less

  20. Method and apparatus for acoustic plate mode liquid-solid phase transition detection

    DOE Patents [OSTI]

    Blair, Dianna S.; Freye, Gregory C.; Hughes, Robert C.; Martin, Stephen J.; Ricco, Antonio J.

    1993-01-01

    A method and apparatus for sensing a liquid-solid phase transition event is provided which comprises an acoustic plate mode detecting element placed in contact with a liquid or solid material which generates a high-frequency acoustic wave that is attenuated to an extent based on the physical state of the material is contact with the detecting element. The attenuation caused by the material in contact with the acoustic plate mode detecting element is used to determine the physical state of the material being detected. The method and device are particularly suited for detecting conditions such as the icing and deicing of wings of an aircraft. In another aspect of the present invention, a method is provided wherein the adhesion of a solid material to the detecting element can be measured using the apparatus of the invention.

  1. Rare Earth Elements Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Elements Rare Earth Elements from Coal and Coal By-Products logo. Download the 2016 Rare Earth Elements from Coal and Coal By-Products Project Portfolio Rare Earth Elements from Coal and Coal By-Products program overview slide. The REE Program is focused on developing technologies for the recovery of REEs from Coal and Coal By-Products. Rare Earth Elements from Coal and Coal By-Products background slide The 17-element group known as rare earth elements (REEs) provides significant

  2. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, M.; Abraham, K.M.

    1993-10-12

    This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

  3. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, Mohamed; Abraham, Kuzhikalail M.

    1993-01-01

    This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

  4. Solids feeder apparatus

    DOE Patents [OSTI]

    Bell, Jr., Harold S.

    1979-01-01

    This invention sets forth a double-acting piston, which carries a floating piston, and which is reciprocated in a housing, for feeding coal to a high pressure gasifier system. The housing has a plurality of solids (for instance: coal) in-feeding ports and a single discharge port, the latter port being in communication with a high pressure gasifier system. The double-acting piston sequentially and individually communicates each of the in-feeding ports with the discharge port. The floating piston both seals off the discharge port while each in-feeding port is receiving coal or the like, to prevent undue escape of gas from the gasifier system, and translates in the housing, following a discharge of coal or the like into the discharge port, to return gas which has been admitted into the housing back into the gasifier system.

  5. Tubular solid oxide fuel cell development program

    SciTech Connect (OSTI)

    Ray, E.R.; Cracraft, C.

    1995-12-31

    This paper presents an overview of the Westinghouse Solid Oxide Fuel Cell (SOFC) development activities and current program status. The Westinghouse goal is to develop a cost effective cell that can operate for 50,000 to 100,000 hours. Progress toward this goal will be discussed and test results presented for multiple single cell tests which have now successfully exceeded 56,000 hours of continuous power operation at temperature. Results of development efforts to reduce cost and increase power output of tubular SOFCs are described.

  6. Fast-neutron solid-state dosimeter

    DOE Patents [OSTI]

    Kecker, K.H.; Haywood, F.F.; Perdue, P.T.; Thorngate, J.H.

    1975-07-22

    This patent relates to an improved fast-neutron solid-state dosimeter that does not require separation of materials before it can be read out, that utilizes materials that do not melt or otherwise degrade at about 300$sup 0$C readout temperature, that provides a more efficient dosimeter, and that can be reused. The dosimeters are fabricated by intimately mixing a TL material, such as CaSO$sub 4$:Dy, with a powdered polyphenyl, such as p-sexiphenyl, and hot- pressing the mixture to form pellets, followed by out-gassing in a vacuum furnace at 150$sup 0$C prior to first use dosimeters. (auth)

  7. Solid fuel volatilization to produce synthesis gas

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Degenstein, Nick J.; Dreyer, Brandon J.; Colby, Joshua L.

    2014-07-29

    A method comprising contacting a carbon and hydrogen-containing solid fuel and a metal-based catalyst in the presence of oxygen to produce hydrogen gas and carbon monoxide gas, wherein the contacting occurs at a temperature sufficiently high to prevent char formation in an amount capable of stopping production of the hydrogen gas and the carbon monoxide gas is provided. In one embodiment, the metal-based catalyst comprises a rhodium-cerium catalyst. Embodiments further include a system for producing syngas. The systems and methods described herein provide shorter residence time and high selectivity for hydrogen and carbon monoxide.

  8. Solid-State Lighting Webcasts

    SciTech Connect (OSTI)

    2011-12-16

    Links to past webcast presentations related to solid-state lighting, including presentation slides and question-and-answer sessions, where available.

  9. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2006-03-08

    MAPVAR-KD is designed to transfer solution results from one finite element mesh to another. MAPVAR-KD draws heavily from the structure and coding of MERLIN II, but it employs a new finite element data base, EXODUS II, and offers enhanced speed and new capabilities not available in MERLIN II. In keeping with the MERLIN II documentation, the computational algorithms used in MAPVAR-KD are described. User instructions are presented. Example problems are included to demonstrate the operationmore » of the code and the effects of various input options. MAPVAR-KD is a modification of MAPVAR in which the search algorithm was replaced by a kd-tree-based search for better performance on large problems.« less

  10. Nuclear fuel element

    DOE Patents [OSTI]

    Meadowcroft, Ronald Ross; Bain, Alastair Stewart

    1977-01-01

    A nuclear fuel element wherein a tubular cladding of zirconium or a zirconium alloy has a fission gas plenum chamber which is held against collapse by the loops of a spacer in the form of a tube which has been deformed inwardly at three equally spaced, circumferential positions to provide three loops. A heat resistant disc of, say, graphite separates nuclear fuel pellets within the cladding from the plenum chamber. The spacer is of zirconium or a zirconium alloy.

  11. Deep Burn: Development of Transuranic Fuel for High-Temperature...

    Office of Scientific and Technical Information (OSTI)

    discusses: (1) Core and Fuel Analysis; (2) Spent Fuel Management; (3) Fuel Cycle Integration of the HTR (high temperature helium-cooled reactor); (4) TRU (transuranic elements) ...

  12. Effect of Creep of Ferritic Interconnect on Long-Term Performance of Solid Oxide Fuel Cell Stacks

    SciTech Connect (OSTI)

    Liu, Wenning N.; Sun, Xin; Khaleel, Mohammad A.

    2010-08-01

    High-temperature ferritic alloys are potential candidates as interconnect (IC) materials and spacers due to their low cost and coefficient of thermal expansion (CTE) compatibility with other components for most of the solid oxide fuel cells (SOFCs) . However, creep deformation becomes relevant for a material when the operating temperature exceeds or even is less than half of its melting temperature (in degrees of Kelvin). The operating temperatures for most of the SOFCs under development are around 1,073 K. With around 1,800 K of the melting temperature for most stainless steel, possible creep deformation of ferritic IC under the typical cell operating temperature should not be neglected. In this paper, the effects of IC creep behavior on stack geometry change and the stress redistribution of different cell components are predicted and summarized. The goal of the study is to investigate the performance of the fuel cell stack by obtaining the changes in fuel- and air-channel geometry due to creep of the ferritic stainless steel IC, therefore indicating possible changes in SOFC performance under long-term operations. The ferritic IC creep model was incorporated into software SOFC-MP and Mentat-FC, and finite element analyses were performed to quantify the deformed configuration of the SOFC stack under the long-term steady-state operating temperature. It was found that the creep behavior of the ferritic stainless steel IC contributes to narrowing of both the fuel- and the air-flow channels. In addition, stress re-distribution of the cell components suggests the need for a compliant sealing material that also relaxes at operating temperature.

  13. Finite-element analysis of an epoxy-curing process

    SciTech Connect (OSTI)

    Gartling, D K; Hickox, C E; Nunziato, J W

    1983-01-01

    A finite element numerical procedure is used to study the curing of an epoxy compound. The problem involves the gelation of an incompressible liquid due to an exothermic chemical reaction. Nonuniform temperature fields produce buoyancy-driven fluid motions that interact with the solidifying material. The numerical simulations provide temperature histories and the progression of the gel front that are compared with experimental data.

  14. The transuranium elements: From neptunium and plutonium to element 112

    SciTech Connect (OSTI)

    Hoffman, D.C. |

    1996-07-26

    Beginning in the 1930`s, both chemists and physicists became interested in synthesizing new artificial elements. The first transuranium element, Np, was synthesized in 1940. Over the past six decades, 20 transuranium elements have been produced. A review of the synthesis is given. The procedure of naming the heavy elements is also discussed. It appears feasible to produce elements 113 and 114. With the Berkeley Gas-filled Separator, it should be possible to reach the superheavy elements in the region of the spherical Z=114 shell, but with fewer neutrons than the N=184 spherical shell. 57 refs, 6 figs.

  15. Carbon nanotube temperature and pressure sensors

    DOE Patents [OSTI]

    Ivanov, Ilia N; Geohegan, David Bruce

    2013-10-29

    The present invention, in one embodiment, provides a method of measuring pressure or temperature using a sensor including a sensor element composed of a plurality of carbon nanotubes. In one example, the resistance of the plurality of carbon nanotubes is measured in response to the application of temperature or pressure. The changes in resistance are then recorded and correlated to temperature or pressure. In one embodiment, the present invention provides for independent measurement of pressure or temperature using the sensors disclosed herein.

  16. High temperature detonator

    DOE Patents [OSTI]

    Johnson, James O. (Los Alamos, NM); Dinegar, Robert H. (Los Alamos, NM)

    1988-01-01

    A detonator assembly is provided which is usable at high temperatures about 300.degree. C. A detonator body is provided with an internal volume defining an anvil surface. A first acceptor explosive is disposed on the anvil surface. A donor assembly having an ignition element, an explosive material, and a flying plate, are placed in the body effective to accelerate the flying plate to impact the first acceptor explosive on the anvil for detonating the first acceptor explosive. A second acceptor explosive is eccentrically located in detonation relationship with the first acceptor explosive to thereafter effect detonation of a main charge.

  17. Compacting Plastic-Bonded Explosive Molding Powders to Dense Solids

    SciTech Connect (OSTI)

    B. Olinger

    2005-04-15

    Dense solid high explosives are made by compacting plastic-bonded explosive molding powders with high pressures and temperatures for extended periods of time. The density is influenced by manufacturing processes of the powders, compaction temperature, the magnitude of compaction pressure, pressure duration, and number of repeated applications of pressure. The internal density variation of compacted explosives depends on method of compaction and the material being compacted.

  18. High temperature ceramic composition for hydrogen retention

    DOE Patents [OSTI]

    Webb, R.W.

    1974-01-01

    A ceramic coating for H retention in fuel elements is described. The coating has relatively low thermal neutron cross section, is not readily reduced by H at 1500 deg F, is adherent to the fuel element base metal, and is stable at reactor operating temperatures. (JRD)

  19. Computational Investigations of Solid-Liquid Interfaces

    SciTech Connect (OSTI)

    Mark Asta

    2011-08-31

    In a variety of materials synthesis and processing contexts, atomistic processes at heterophase interfaces play a critical role governing defect formation, growth morphologies, and microstructure evolution. Accurate knowledge of interfacial structure, free energies, mobilities and segregation coefficients are critical for predictive modeling of microstructure evolution, yet direct experimental measurement of these fundamental interfacial properties remains elusive in many cases. In this project first-principles calculations were combined with molecular-dynamics (MD) and Monte-Carlo (MC) simulations, to investigate the atomic-scale structural and dynamical properties of heterophase interfaces, and the relationship between these properties and the calculated thermodynamic and kinetic parameters that influence the evolution of phase transformation structures at nanometer to micron length scales. The topics investigated in this project were motivated primarily by phenomena associated with solidification processing of metals and alloys, and the main focus of the work was thus on solid-liquid interfaces and high-temperature grain boundaries. Additional efforts involved first-principles calculations of coherent solid-solid heterophase interfaces, where a close collaboration with researchers at the National Center for Electron Microscopy was undertaken to understand the evolution of novel core-shell precipitate microstructures in aluminum alloys.

  20. Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects

    SciTech Connect (OSTI)

    Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

    2011-01-10

    Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

  1. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H.; Brosha, Eric L.

    1997-01-01

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures.

  2. Valve for controlling solids flow

    DOE Patents [OSTI]

    Staiger, M. Daniel (Idaho Falls, ID)

    1985-01-01

    A valve for controlling the flow of solids comprises a vessel having an overflow point, an inlet line for discharging solids into the vessel positioned within the vessel such that the inlet line's discharge point is lower than the vessel's overflow point, and apparatus for introducing a fluidizing fluid into the vessel. The fluidizing fluid fluidizes the solids within the vessel so that they overflow at the vessel's overflow point. For the removal of nuclear waste product the vessel may be placed within a sealed container having a bottom connected transport line for transporting the solids to storage or other sites. The rate of solids flow is controlled by the flow rate of the fluidizing fluid and by V-notch weirs of different sizes spaced about the top of the vessel.

  3. Valve for controlling solids flow

    DOE Patents [OSTI]

    Staiger, M.D.

    1982-09-29

    A valve for controlling the flow of solids comprises a vessel having an overflow point, an inlet line for discharging solids into the vessel positioned within the vessel such that the inlet line's discharge point is lower than the vessel's overflow point, and means for introducing a fluidizing fluid into the vessel. The fluidizing fluid fluidizes the solids within the vessel so that they overflow at the vessel's overflow point. For the removal of nuclear waste product the vessel may be placed within a sealed container having a bottom connected transport line for transporting the solids to storage or other sites. The rate of solids flow is controlled by the flow rate of the fluidizing fluid and by V-notch weirs of different sizes spaced about the top of the vessel.

  4. Nuclear reactor fuel element

    DOE Patents [OSTI]

    Johnson, Carl E. (Elk Grove, IL); Crouthamel, Carl E. (Richland, WA)

    1980-01-01

    A nuclear reactor fuel element is described which has an outer cladding, a central core of fissionable or mixed fissionable and fertile fuel material and a layer of oxygen gettering material on the inner surface of the cladding. The gettering material reacts with oxygen released by the fissionable material during irradiation of the core thereby preventing the oxygen from reacting with and corroding the cladding. Also described is an improved method for coating the inner surface of the cladding with a layer of gettering material.

  5. TWISTED RIBBON FUEL ELEMENT

    DOE Patents [OSTI]

    Breden, C.R.; Schultz, A.B.

    1961-06-01

    A reactor core formed of bundles of parallel fuel elements in the form of ribbons is patented. The fuel ribbons are twisted about their axes so as to have contact with one another at regions spaced lengthwise of the ribbons and to be out of contact with one another at locations between these spaced regions. The contact between the ribbons is sufficient to allow them to be held together in a stable bundle in a containing tube without intermediate support, while permitting enough space between the ribbon for coolant flowing.

  6. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2005-06-26

    Exotxt is an analysis code that reads finite element results data stored in an exodusII file and generates a file in a structured text format. The text file can be edited or modified via a number of text formatting tools. Exotxt is used by analysis to translate data from the binary exodusII format into a structured text format which can then be edited or modified and then either translated back to exodusII format or tomore » another format.« less

  7. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2005-05-07

    CONEX is a code for joining sequentially in time multiple exodusll database files which all represent the same base mesh topology and geometry. It is used to create a single results or restart file from multiple results or restart files which typically arise as the result of multiple restarted analyses. CONEX is used to postprocess the results from a series of finite element analyses. It can join sequentially the data from multiple results databases intomore » a single database which makes it easier to postprocess the results data.« less

  8. Solid Xenon Project

    SciTech Connect (OSTI)

    Balakishiyeva, Durdana N.; Saab, Tarek [University of Florida (United States); Mahapatra, Rupak [Texas A and M University (United States); Yoo, Jonghee [FNAL (United States)

    2010-08-30

    Crystals like Germanium and Silicon need to be grown in specialized facilities which is time and money costly. It takes many runs to test the detector once it's manufactured and mishaps are very probable. It is of a great challenge to grow big germanium crystals and that's why stacking them up in a tower is the only way at the moment to increase testing mass. Liquid Noble gas experiments experiencing contamination problems, their predicted energy resolution at 10 keV and lower energy range is not as good as predicted. Every experiment is targeting one specific purpose, looking for one thing. Why not to design an experiment that is diverse and build a detector that can search for Dark Matter, Solar Axions, Neutrinoless Double Beta decay, etc. Solid Xenon detector is such detector. We designed a simple Xenon crystal growing chamber that was put together at Fermi National Accelerator Laboratory. The first phase of this experiment was to demonstrate that a good, crack free Xenon crystal can be grown (regardless of many failed attempts by various groups) and our first goal, 1 kg crystal, was successful.

  9. 2016 CROSSCUTTING RESEARCH & RARE EARTH ELEMENTS PORTFOLIOS REVIEW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2016 CROSSCUTTING RESEARCH & RARE EARTH ELEMENTS PORTFOLIOS REVIEW GRAND STATION 3-5 POSTER PRESENTATIONS TUESDAY, APRIL 19 - 5:00-6:45 P.M. ADVANCED SENSORS 1 2 3 4 5 * Passive Wireless Sensors Fabricated by Direct-Writing for Temperature and Health Monitoring of Energy Systems in Harsh-Environments - Ioannis Kortidis and Michael Comparetto, West Virginia University * High Temperature Integrated Gas and Temperature Wireless Microwave Acoustic Sensor System for Fossil Energy Applications -

  10. Nondestructive examination of 54 fuel and reflector elements from Fort St. Vrain core segment 2

    SciTech Connect (OSTI)

    Saurwein, J.J.

    1982-10-01

    Fifty-four fuel and reflector elements irradiated in core segment 2 of the Fort St. Vrain high-temperature gas-cooled reactor (HTGR) were nondestructively examined. The time- and volume-averaged graphite irradiation temperatures for the elements ranged from approx. 350/sup 0/ to 750/sup 0/C. The element-averaged fast neutron fluences ranged from approx. 0.2 to 1.6 x 10/sup 25/ n/m/sup 2/ (E > 29 fJ)/sub HTGR/. The elements, except for two fuel elements in which single localizeed cracks developed during irradiation, were in excellent condition. No evidence was observed of significant graphite oxidation or mechanical interaction beween elements. The cracks in the two elements did not affect their performance or handling. These elements were, otherwise, in excellent condition. Nearly all elements shrank in both the axial and radial directions, but the dimensional changes were relatively small.

  11. Static & Dynamic Response of 2D Solids

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    NIKE2D is an implicit finite-element code for analyzing the finite deformation, static and dynamic response of two-dimensional, axisymmetric, plane strain, and plane stress solids. The code is fully vectorized and available on several computing platforms. A number of material models are incorporated to simulate a wide range of material behavior including elasto-placicity, anisotropy, creep, thermal effects, and rate dependence. Slideline algorithms model gaps and sliding along material interfaces, including interface friction, penetration and single surfacemore » contact. Interactive-graphics and rezoning is included for analyses with large mesh distortions. In addition to quasi-Newton and arc-length procedures, adaptive algorithms can be defined to solve the implicit equations using the solution language ISLAND. Each of these capabilities and more make NIKE2D a robust analysis tool.« less

  12. Static & Dynamic Response of 2D Solids

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    NIKE2D is an implicit finite-element code for analyzing the finite deformation, static and dynamic response of two-dimensional, axisymmetric, plane strain, and plane stress solids. The code is fully vectorized and available on several computing platforms. A number of material models are incorporated to simulate a wide range of material behavior including elasto-placicity, anisotropy, creep, thermal effects, and rate dependence. Slideline algorithms model gaps and sliding along material interfaces, including interface friction, penetration and single surfacemorecontact. Interactive-graphics and rezoning is included for analyses with large mesh distortions. In addition to quasi-Newton and arc-length procedures, adaptive algorithms can be defined to solve the implicit equations using the solution language ISLAND. Each of these capabilities and more make NIKE2D a robust analysis tool.less

  13. A Finite Element Model Of Self-Resonating Bimorph Microcantilever For Fast

    Office of Scientific and Technical Information (OSTI)

    Temperature Cycling In A Pyroelectric Energy Harvester (Conference) | SciTech Connect A Finite Element Model Of Self-Resonating Bimorph Microcantilever For Fast Temperature Cycling In A Pyroelectric Energy Harvester Citation Details In-Document Search Title: A Finite Element Model Of Self-Resonating Bimorph Microcantilever For Fast Temperature Cycling In A Pyroelectric Energy Harvester A self resonating bimorph cantilever structure for fast temperature cycling in a pyroelectric energy

  14. A comparison of observables for solid-solid phase transitions

    SciTech Connect (OSTI)

    Smilowitz, Laura B [Los Alamos National Laboratory; Henson, Bryan F [Los Alamos National Laboratory; Romero, Jerry J [Los Alamos National Laboratory

    2009-01-01

    The study of solid-solid phase transformations is hindered by the difficulty of finding a volumetric probe to use as a progress variable. Solids are typically optically opaque and heterogeneous. Over the past several years, second harmonic generation (SHG) has been used as a kinetic probe for a solid-solid phase transition in which the initial and final phases have different symmetries. Bulk generation of SHG is allowed by symmetry only in noncentrosymmetric crystallographic space groups. For the organic energetic nitramine octahydro-1,3 ,5,7 -tetranitro-1,3 ,5,7 -tatrazocine (HMX), the beta phase is centro symmetric (space group P2{sub 1}/c) and the delta phase iS noncentrosymmetric (space group P6{sub 1}22) making SHG an extremely sensitive, essentially zero background probe of the phase change progress. We have used SHG as a tool to follow the progress of the transformation from beta to delta phase during the solid-solid transformation. However, kinetic models of the transformation derived using different observables from several other groups have differed, showing later onset for the phase change and faster progression to completion. In this work, we have intercompared several techniques to understand these differences. The three techniques discussed are second harmonic generation, Raman spectroscopy, and differential scanning calorimetry (DSC). The progress of the beta to delta phase transition in HMX observed with each of these different probes will be discussed and advantages and disadvantages of each technique described. This paper compares several different observables for use in measuring the kinetics of solid-solid phase transitions. Relative advantages and disadvantages for each technique are described and a direct comparison of results is made for the beta to delta polymorphic phase transition of the energetic nitramine, octahydro-1,3,5,7-tetranitro-1,3,5,7-tatrazocine.

  15. Partitioning planning studies: Preliminary evaluation of metal and radionuclide partitioning the high-temperature thermal treatment systems

    SciTech Connect (OSTI)

    Liekhus, K.; Grandy, J.; Chambers, A.

    1997-03-01

    A preliminary study of toxic metals and radionuclide partitioning during high-temperature processing of mixed waste has been conducted during Fiscal Year 1996 within the Environmental Management Technology Evaluation Project. The study included: (a) identification of relevant partitioning mechanisms that cause feed material to be distributed between the solid, molten, and gas phases within a thermal treatment system; (b) evaluations of existing test data from applicable demonstration test programs as a means to identify and understand elemental and species partitioning; and, (c) evaluation of theoretical or empirical partitioning models for use in predicting elemental or species partitioning in a thermal treatment system. This preliminary study was conducted to identify the need for and the viability of developing the tools capable of describing and predicting toxic metals and radionuclide partitioning in the most applicable mixed waste thermal treatment processes. This document presents the results and recommendations resulting from this study that may serve as an impetus for developing and implementing these predictive tools.

  16. Sandia Energy - High-Pressure and High-Temperature Neutron Reflectomet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Pressure and High-Temperature Neutron Reflectometry Cell for Solid-Fluid Interface Studies Home Carbon Capture & Storage Climate News News & Events Carbon Capture Carbon...

  17. International team discovers element 117

    Broader source: Energy.gov [DOE]

    An international team of scientists from Russia and the United States, including two Department of Energy national laboratories and two universities, has discovered the newest superheavy element, element 117.

  18. Nuclear fuel elements and method of making same

    DOE Patents [OSTI]

    Schweitzer, Donald G.

    1992-01-01

    A nuclear fuel element for a high temperature gas nuclear reactor that has an average operating temperature in excess of 2000.degree. C., and a method of making such a fuel element. The fuel element is characterized by having fissionable fuel material localized and stabilized within pores of a carbon or graphite member by melting the fissionable material to cause it to chemically react with the carbon walls of the pores. The fissionable fuel material is further stabilized and localized within the pores of the graphite member by providing one or more coatings of pyrolytic carbon or diamond surrounding the porous graphite member so that each layer defines a successive barrier against migration of the fissionable fuel from the pores, and so that the outermost layer of pyrolytic carbon or diamond forms a barrier between the fissionable material and the moderating gases used in an associated high temperature gas reactor. The method of the invention provides for making such new elements either as generally spherically elements, or as flexible filaments, or as other relatively small-sized fuel elements that are particularly suited for use in high temperature gas reactors.

  19. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Brosha, E.L.

    1997-12-09

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures. 6 figs.

  20. Regenerable solid imine sorbents

    DOE Patents [OSTI]

    Gray, McMahan; Champagne, Kenneth J.; Fauth, Daniel; Beckman, Eric

    2013-09-10

    Two new classes of amine-based sorbents are disclosed. The first class comprises new polymer-immobilized tertiary amine sorbents; the second class new polymer-bound amine sorbents. Both classes are tailored to facilitate removal of acid anhydrides, especially carbon dioxide (CO.sub.2), from effluent gases. The amines adsorb acid anhydrides in a 1:1 molar ratio. Both classes of amine sorbents adsorb in the temperature range from about 20.degree. C. upwards to 90.degree. C. and can be regenerated by heating upwards to 100.degree. C.

  1. Cohesive Zone Model User Element

    Energy Science and Technology Software Center (OSTI)

    2007-04-17

    Cohesive Zone Model User Element (CZM UEL) is an implementation of a Cohesive Zone Model as an element for use in finite element simulations. CZM UEL computes a nodal force vector and stiffness matrix from a vector of nodal displacements. It is designed for structural analysts using finite element software to predict crack initiation, crack propagation, and the effect of a crack on the rest of a structure.

  2. REACTOR FUEL ELEMENTS TESTING CONTAINER

    DOE Patents [OSTI]

    Whitham, G.K.; Smith, R.R.

    1963-01-15

    This patent shows a method for detecting leaks in jacketed fuel elements. The element is placed in a sealed tank within a nuclear reactor, and, while the reactor operates, the element is sparged with gas. The gas is then led outside the reactor and monitored for radioactive Xe or Kr. (AEC)

  3. Process for the retorting of hydrocarbon-containing solids

    SciTech Connect (OSTI)

    Silva, J.C.; Gaiao, U.; Novicki, R.E.

    1987-11-17

    This patent describes a process for the retorting of hydrocarbon-containing solids, characterized in that it comprises the following steps: (a) contacting the solid particles with superheated steam; (b) transporting, in an upward direction, the mixture obtained in the previous step, at a gas velocity close to the critical impact velocity, through a vertical multi-tube reactor, immersed in a vertical furnace, held at a temperature in the range from 800/sup 0/ to 1000/sup 0/C; (c) heating the obtained mixture to the solids' pyrolysis temperature, by means of the heat generated by the burning of fuel inside the vertical furnace and supplied to the mixture through the walls of the reactor; (d) removing the products from the reactor, separating the solid phase from the retorting products, by forcing the products to pass through primary and secondary separators; (e) removing the gaseous phase from the retorting products exiting the secondary separator thus effecting a second separation stage, for the obtaining of fuel gas and oil the process further characterized in that spaced static devices are provided within the multi-tube reactor tube, so as to cause the solid particles to come close to the walls of the reactor, as a consequence of the superheated steam flow redistribution in order to increase heat transfer between the vertical furnace and the reactor walls.

  4. RECONDITIONING FUEL ELEMENTS

    DOE Patents [OSTI]

    Brandt, H.L.

    1962-02-20

    A process is given for decanning fuel elements that consist of a uranium core, an intermediate section either of bronze, silicon, Al-Si, and uranium silicide layers or of lead, Al-Si, and uranium silicide layers around said core, and an aluminum can bonded to said intermediate section. The aluminum can is dissolved in a solution of sodium hydroxide (9 to 20 wt%) and sodium nitrate (35 to 12 wt %), and the layers of the intermediate section are dissolved in a boiling sodium hydroxide solution of a minimum concentration of 50 wt%. (AEC) A method of selectively reducing plutonium oxides and the rare earth oxides but not uranium oxides is described which comprises placing the oxides in a molten solvent of zinc or cadmium and then adding metallic uranium as a reducing agent. (AEC)

  5. Nuclear fuel element

    DOE Patents [OSTI]

    Armijo, Joseph S.; Coffin, Jr., Louis F.

    1983-01-01

    A nuclear fuel element for use in the core of a nuclear reactor is disclosed and has a composite cladding having a substrate and a metal barrier metallurgically bonded on the inside surface of the substrate so that the metal barrier forms a shield between the substrate and the nuclear fuel material held within the cladding. The metal barrier forms about 1 to about 30 percent of the thickness of the cladding and is comprised of a low neutron absorption metal of substantially pure zirconium. The metal barrier serves as a preferential reaction site for gaseous impurities and fission products and protects the substrate from contact and reaction with such impurities and fission products. The substrate of the composite cladding is selected from conventional cladding materials and preferably is a zirconium alloy. Methods of manufacturing the composite cladding are also disclosed.

  6. Nuclear fuel element

    DOE Patents [OSTI]

    Armijo, Joseph S.; Coffin, Jr., Louis F.

    1980-04-29

    A nuclear fuel element for use in the core of a nuclear reactor is disclosed and has an improved composite cladding comprised of a moderate purity metal barrier of zirconium metallurgically bonded on the inside surface of a zirconium alloy tube. The metal barrier forms a shield between the alloy tube and a core of nuclear fuel material enclosed in the composite cladding. There is a gap between the cladding and the core. The metal barrier forms about 1 to about 30 percent of the thickness of the composite cladding and has low neutron absorption characteristics. The metal barrier serves as a preferential reaction site for gaseous impurities and fission products and protects the alloy tube from contact and reaction with such impurities and fission products. Methods of manufacturing the composite cladding are also disclosed.

  7. Photoconductive circuit element reflectometer

    DOE Patents [OSTI]

    Rauscher, Christen (Alexandria, VA)

    1990-01-01

    A photoconductive reflectometer for characterizing semiconductor devices at millimeter wavelength frequencies where a first photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short first laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test. Second PCEs are connected along the transmission line to sample the signals on the transmission line when excited into conductance by short second laser light pulses, spaced apart in time a variable period from the first laser light pulses. Electronic filters connected to each of the second PCEs act as low-pass filters and remove parasitic interference from the sampled signals and output the sampled signals in the form of slowed-motion images of the signals on the transmission line.

  8. Photoconductive circuit element reflectometer

    DOE Patents [OSTI]

    Rauscher, C.

    1987-12-07

    A photoconductive reflectometer for characterizing semiconductor devices at millimeter wavelength frequencies where a first photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short first laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test. Second PCEs are connected along the transmission line to sample the signals on the transmission line when excited into conductance by short second laser light pulses, spaced apart in time a determinable period from the first laser light pulses. Electronic filters connected to each of the second PCEs act as low-pass filters and remove parasitic interference from the sampled signals and output the sampled signals in the form of slowed-motion images of the signals on the transmission line. 4 figs.

  9. Solid-State NMR | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solid-State NMR Solid-State NMR Our team is well-known for its work in the following areas: - Using multi-dimensional solid-state NMR of quadrupolar nuclei to study spin-12 nuclei...

  10. Trace elements in coal by glow discharge mass spectrometry

    SciTech Connect (OSTI)

    Jacobs, M.L.; Wilson, C.R.; Pestovich, J. Jr.

    1995-08-01

    A need and a demand exist for determining trace elements in coal and coal related by-products, especially those elements which may potentially be a health hazard. The provisions of the 1990 clean air act require that the EPA evaluate the emissions of electric utilities for trace elements and other potentially hazardous organic compounds. The coal fired electric utility industry supplies roughly 60% of the total generating capacity of 2,882,525 million kilowatt hours (nearly 3 trillion kilowatt hours) generated in the U.S. This is accomplished by 414 power plants scattered across the country that burned 813,508,000 short tons of coal in 1993. The relative volatility of some inorganic constituents in coal makes them more prone to be emitted to the atmosphere following combustion. The production of analytical data for trace elements is known to be a difficult task in coal and by-products of coal combustion (fly ash, bottom ash, gas streams, etc.), in terms of both sample collection and analytical determinations. There are several common analytical methods available to the analyst to determine trace elements in coal and coal by-products. In general analytical germs, the material to be analyzed can be totally solubilized (or extracted), or the elements analytes can be determined in the material as a solid. A relatively new elemental technique, Glow Discharge Mass Spectrometry (GDMS) can be used with solids as well. This new analytical technique had never before been applied directly to coal. The radio frequency-glow discharge quadropole mass spectrometer was used to analyze coal directly for the first time ever by rf-GDMS. The rf-GDMS technique is described.

  11. Municipal solid waste management in Rasht City, Iran

    SciTech Connect (OSTI)

    Alavi Moghadam, M.R. Mokhtarani, N. Mokhtarani, B.

    2009-01-15

    Pollution and health risks generated by improper solid waste management are important issues concerning environmental management in developing countries. In most cities, the use of open dumps is common for the disposal of wastes, resulting in soil and water resource contamination by leachate in addition to odors and fires. Solid waste management infrastructure and services in developing countries are far from achieving basic standards in terms of hygiene and efficient collection and disposal. This paper presents an overview of current municipal solid waste management in Rasht city, Gilan Province, Iran, and provides recommendations for system improvement. The collected data of different MSW functional elements were based on data from questionnaires, visual observations of the authors, available reports and several interviews and meetings with responsible persons. Due to an increase in population and changes in lifestyle, the quantity and quality of MSW in Rasht city has changed. Lack of resources, infrastructure, suitable planning, leadership, and public awareness are the main challenges of MSW management of Rasht city. However, the present situation of solid waste management in this city, which generates more than 400 tons/d, has been improved since the establishment of an organization responsible only for solid waste management. Source separation of wastes and construction of a composting plant are the two main activities of the Rasht Municipality in recent years.

  12. Dynamic Modeling in Solid-Oxide Fuel Cells Controller Design

    SciTech Connect (OSTI)

    Lu, Ning; Li, Qinghe; Sun, Xin; Khaleel, Mohammad A.

    2007-06-28

    In this paper, a dynamic model of the solid-oxide fuel cell (SOFC) power unit is developed for the purpose of designing a controller to regulate fuel flow rate, fuel temperature, air flow rate, and air temperature to maintain the SOFC stack temperature, fuel utilization rate, and voltage within operation limits. A lumped model is used to consider the thermal dynamics and the electro-chemial dynamics inside an SOFC power unit. The fluid dynamics at the fuel and air inlets are considered by using the in-flow ramp-rates.

  13. WATEQ3 geochemical model: thermodynamic data for several additional solids

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

  14. Composite solid polymer electrolyte membranes

    DOE Patents [OSTI]

    Formato, Richard M.; Kovar, Robert F.; Osenar, Paul; Landrau, Nelson; Rubin, Leslie S.

    2001-06-19

    The present invention relates to composite solid polymer electrolyte membranes (SPEMs) which include a porous polymer substrate interpenetrated with an ion-conducting material. SPEMs of the present invention are useful in electrochemical applications, including fuel cells and electrodialysis.

  15. Is solid helium a supersolid?

    SciTech Connect (OSTI)

    Hallock, Robert

    2015-05-15

    Recent experiments suggest that helium-4 atoms can flow through an experimental cell filled with solid helium. But that incompletely understood flow is quite different from the reported superfluid-like motion that so excited physicists a decade ago.

  16. Solid Waste Management Program Plan

    SciTech Connect (OSTI)

    Duncan, D.R.

    1990-08-01

    The objective of the Solid Waste Management Program Plan (SWMPP) is to provide a summary level comprehensive approach for the storage, treatment, and disposal of current and future solid waste received at the Hanford Site (from onsite and offsite generators) in a manner compliant with current and evolving regulations and orders (federal, state, and Westinghouse Hanford Company (Westinghouse Hanford)). The Plan also presents activities required for disposal of selected wastes currently in retrievable storage. The SWMPP provides a central focus for the description and control of cost, scope, and schedule of Hanford Site solid waste activities, and provides a vehicle for ready communication of the scope of those activities to onsite and offsite organizations. This Plan represents the most complete description available of Hanford Site Solid Waste Management (SWM) activities and the interfaces between those activities. It will be updated annually to reflect changes in plans due to evolving regulatory requirements and/or the SWM mission. 8 refs., 9 figs., 4 tabs.

  17. Composite solid polymer electrolyte membranes

    DOE Patents [OSTI]

    Formato, Richard M.; Kovar, Robert F.; Osenar, Paul; Landrau, Nelson; Rubin, Leslie S.

    2006-05-30

    The present invention relates to composite solid polymer electrolyte membranes (SPEMs) which include a porous polymer substrate interpenetrated with an ion-conducting material. SPEMs of the present invention are useful in electrochemical applications, including fuel cells and electrodialysis.

  18. Incorporating Technetium in Minerals and Other Solids: A Review

    SciTech Connect (OSTI)

    Luksic, Steven A.; Riley, Brian J.; Schweiger, Michael J.; Hrma, Pavel R.

    2015-08-29

    Technetium (Tc) can be incorporated into a number of different solids including spinel, sodalite, rutile, tin dioxide, pyrochlore, perovskite, goethite, layered double hydroxides, cements, and alloys. Synthetic routes are possible for each of these phases, ranging from high temperature ceramic sintering to ball-milling of constituent oxides. However, in practice, Tc has only been incorporated into solid materials by a limited number of the possible syntheses. Reviewing the diverse ways in which Tc-immobilizing materials can be made shows the range of options available.

  19. NETL: Solid Oxide Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solid Oxide Fuel Cells Solid oxide fuel cells (SOFC) are electrochemical devices that convert chemical energy of a fuel and oxidant directly into electrical energy. Since SOFCs produce electricity through an electrochemical reaction and not through a combustion process, they are much more efficient and environmentally benign than conventional electric power generation processes. Their inherent characteristics make them uniquely suitable to address the environmental, climate change, and water

  20. Solid State Photovoltaic Research Branch

    SciTech Connect (OSTI)

    Not Available

    1990-09-01

    This report summarizes the progress of the Solid State Photovoltaic Research Branch of the Solar Energy Research Institute (SERI) from October 1, 1988, through September 30,l 1989. Six technical sections of the report cover these main areas of SERIs in-house research: Semiconductor Crystal Growth, Amorphous Silicon Research, Polycrystalline Thin Films, III-V High-Efficiency Photovoltaic Cells, Solid-State Theory, and Laser Raman and Luminescence Spectroscopy. Sections have been indexed separately for inclusion on the data base.

  1. 2015 Solid Oxide Fuel Cells Project Portfolio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015 Solid Oxide Fuel Cells Project Portfolio Solid Oxide Fuel Cells are energy conversion devices that produce electric power through an electrochemical reaction rather than by...

  2. Wastes Hazardous or Solid | Open Energy Information

    Open Energy Info (EERE)

    or Solid Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleWastesHazardousorSolid&oldid612186" Feedback Contact needs updating Image...

  3. NETL: Solid Oxide Fuel Cells Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solid Oxide Fuel Cells Publications This page provides links to SOFC Program related documents and reference materials. Solid Oxide Fuel Cells Program 2015 Project Portfolio The ...

  4. Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About This Technology Technology Marketing Summary INL has developed a solid catalyst process for the alkylation reaction of isoparaffins with olefins over solid catalysts. The...

  5. Microsoft Word - Solid Waste at Hanford

    Office of Environmental Management (EM)

    Use of American Recovery and Reinvestment Act of 2009 Funds on Solid Waste Project ... Reinvestment Act of 2009 Funds on Solid Waste Project Activities at the Department of ...

  6. Municipal Solid Waste | Open Energy Information

    Open Energy Info (EERE)

    Municipal Solid Waste Jump to: navigation, search TODO: Add description List of Municipal Solid Waste Incentives Retrieved from "http:en.openei.orgwindex.php?titleMunicipalSo...

  7. Two-fluid Hydrodynamic Model for Fluid-Flow Simulation in Fluid-Solids Systems

    Energy Science and Technology Software Center (OSTI)

    1994-06-20

    FLUFIX is a two-dimensional , transient, Eulerian, and finite-difference program, based on a two-fluid hydrodynamic model, for fluid flow simulation in fluid-solids systems. The software is written in a modular form using the Implicit Multi-Field (IMF) numerical technique. Quantities computed are the spatial distribution of solids loading, gas and solids velocities, pressure, and temperatures. Predicted are bubble formation, bed frequencies, and solids recirculation. Applications include bubbling and circulating atmospheric and pressurized fluidized bed reactors, combustors,more » gasifiers, and FCC (Fluid Catalytic Cracker) reactors.« less

  8. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D.; Sulchek, Todd A.; Feigin, Stuart C.

    2010-04-06

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  9. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D.; Sulchek, Todd A.; Feigin, Stuart C.

    2012-07-10

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  10. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

    2014-04-29

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  11. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

    2013-04-30

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  12. Resistive hydrogen sensing element

    DOE Patents [OSTI]

    Lauf, Robert J.

    2000-01-01

    Systems and methods are described for providing a hydrogen sensing element with a more robust exposed metallization by application of a discontinuous or porous overlay to hold the metallization firmly on the substrate. An apparatus includes: a substantially inert, electrically-insulating substrate; a first Pd containing metallization deposited upon the substrate and completely covered by a substantially hydrogen-impermeable layer so as to form a reference resistor on the substrate; a second Pd containing metallization deposited upon the substrate and at least a partially accessible to a gas to be tested, so as to form a hydrogen-sensing resistor; a protective structure disposed upon at least a portion of the second Pd containing metallization and at least a portion of the substrate to improve the attachment of the second Pd containing metallization to the substrate while allowing the gas to contact said the second Pd containing metallization; and a resistance bridge circuit coupled to both the first and second Pd containing metallizations. The circuit determines the difference in electrical resistance between the first and second Pd containing metallizations. The hydrogen concentration in the gas may be determined. The systems and methods provide advantages because adhesion is improved without adversely effecting measurement speed or sensitivity.

  13. Solid feeder and method

    DOE Patents [OSTI]

    Hathaway, Thomas J.

    1979-01-01

    This invention provides a housing containing a rotatable coal bucket that is sealed at its ends in the housing with a reciprocal plunger that is sealed in the bucket at one end and has an opposite cone-shaped end that wedges up against a closed end of the bucket, and a method for feeding dry, variable size coal from an ambient atmosphere at low pressure into a high temperature, high pressure reactor between the seals for producing fuel gas substantially without losing any high pressure gas from the reactor or excessively wearing the seals. To this end, the piston biases the plunger back and forth for loading and unloading the bucket with coal along an axis that is separated from the seals, the bucket is rotated to unload the coal into the reactor so as to fill the bucket with trapped high pressure gas from the reactor while preventing the gas from escaping therefrom, and then the cone-shaped plunger end is wedged into mating engagement with the closed end of the bucket to displace this high pressure bucket gas by expelling it back into the reactor whereby the bucket can be re-rotated for filling it with coal again substantially without losing any of the high pressure gas or excessively wearing the seals.

  14. DYNA3D user's manual (nonlinear dynamic analysis of solids in three-dimensions)

    SciTech Connect (OSTI)

    Hallquist, J.O.

    1982-11-01

    This report provides an updated user's manual for DYNA3D, an explicit three-dimensional finite-element code for analyzing the large-deformation dynamic response of inelastic solids. A contact-impact algorithm permits gaps and sliding along material interfaces. By a specialization of this algorithm, such interfaces can be rigidly tied to admit variable zoning without the need of transition regions. Spatial discretization is achieved by the use of 8-node solid elements, and the equations-of-motion are integrated by the central difference method. DYNA3D contains fifteen material models and nine equations of state to cover a wide range of material behavior.

  15. DYNA3D user's manual (nonlinear dynamic analysis of solids in three dimensions)

    SciTech Connect (OSTI)

    Hallquist, J.O.

    1984-04-01

    This report provides an updated user's manual for DYNA3D, an explicit three-dimensional finite element code for analyzing the large deformation dynamic response of inelastic solids. A contact-impact algorithm permits gaps and sliding along material interfaces. By a specialization of this algorithm, such interfaces can be rigidly tied to admit variable zoning without the need of transition regions. Spatial discretization is achieved by the use of 8-node solid elements, and the equations-of-motion are integrated by the central difference method. DYNA3D contains fifteen material models and nine equations of state to cover a wide range of material behavior.

  16. Recoverable immobilization of transuranic elements in sulfate ash

    DOE Patents [OSTI]

    Greenhalgh, Wilbur O.

    1985-01-01

    Disclosed is a method of reversibly immobilizing sulfate ash at least about 20% of which is sulfates of transuranic elements. The ash is mixed with a metal which can be aluminum, cerium, samarium, europium, or a mixture thereof, in amounts sufficient to form an alloy with the transuranic elements, plus an additional amount to reduce the transuranic element sulfates to elemental form. Also added to the ash is a fluxing agent in an amount sufficient to lower the percentage of the transuranic element sulfates to about 1% to about 10%. The mixture of the ash, metal, and fluxing agent is heated to a temperature sufficient to melt the fluxing agent and the metal. The mixture is then cooled and the alloy is separated from the remainder of the mixture.

  17. Carbon or graphite foam as a heating element and system thereof

    DOE Patents [OSTI]

    Ott, Ronald D. (Knoxville, TN) [Knoxville, TN; McMillan, April D. (Knoxville, TN) [Knoxville, TN; Choudhury, Ashok (Oak Ridge, TN) [Oak Ridge, TN

    2004-05-04

    A temperature regulator includes at least one electrically conductive carbon foam element. The foam element includes at least two locations adapted for receiving electrical connectors thereto for heating a fluid, such as engine oil. A combustion engine includes an engine block and at least one carbon foam element, the foam element extending into the engine block or disposed in thermal contact with at least one engine fluid.

  18. Beamline Temperatures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Temperatures Energy: 3.0000 GeV Current: 497.0950 mA Date: 16-May-2016 02:53:04 Beamline Temperatures Energy 3.0000 GeV Current 497.1 mA 16-May-2016 02:53:04 LN:MainTankLevel 168.9 in LN:MainTankPress 60.0 psi SPEAR-BL:B120HeFlow 13.4 l/min SPEAR-BL:B131HeFlow 22.7 l/min BL 2 BL02:M0_LCW 31.5 ℃ BL 4-1 BL04-1:BasePlate -13.0 ℃ BL04-1:Bottom1 54.0 ℃ BL04-1:Bottom2 55.0 ℃ BL04-1:Lower 32.0 ℃ BL04-1:Moly 64.0 ℃ BL04-1:ChinGuard1 31.0 ℃ BL04-1:ChinGuard2 31.0 ℃ BL04-1:FirstXtalA

  19. Heat Pump Water Heater using Solid-State Energy Converters | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Water Heater using Solid-State Energy Converters Heat Pump Water Heater using Solid-State Energy Converters Sheetak will work on developing a full scale prototype of its low cost heat pump water heater. These solid state heat pumping elements can be implemented in low cost manner which have the potential to dramatically change the way in which he heat water.<BR />Image: Sheetak Sheetak will work on developing a full scale prototype of its low cost heat pump water heater. These

  20. NUCLEAR REACTOR FUEL ELEMENT ASSEMBLY

    DOE Patents [OSTI]

    Stengel, F.G.

    1963-12-24

    A method of fabricating nuclear reactor fuel element assemblies having a plurality of longitudinally extending flat fuel elements in spaced parallel relation to each other to form channels is presented. One side of a flat side plate is held contiguous to the ends of the elements and a welding means is passed along the other side of the platertransverse to the direction of the longitudinal extension of the elements. The setting and speed of travel of the welding means is set to cause penetration of the side plate with welds at bridge the gap in each channel between adjacent fuel elements with a weld-through bubble of predetermined size. The fabrication of a high strength, dependable fuel element is provided, and the reduction of distortion and high production costs are facilitated by this method. (AEC)

  1. MFT homogeneity study at TNX: Final report on the low weight percent solids concentration

    SciTech Connect (OSTI)

    Jenkins, W.J.

    1993-09-21

    A statistical design and analysis of both elemental analyses and weight percent solids analyses data was utilized to evaluate the MFT homogeneity at low heel levels and low agitator speed at both high and low solids feed concentrations. The homogeneity was also evaluated at both low and high agitator speed at the 6000+ gallons static level. The dynamic level portion of the test simulated feeding the Melter from the MFT to evaluate the uniformity of the solids slurry composition (Frit-PHA-Sludge) entering the melter from the MFT. This final report provides the results and conclusions from the second half of the study, the low weight percent solids concentration portion, as well as a comparison with the results from the first half of the study, the high weight percent solids portion.

  2. 2-D Finite Element Heat Conduction

    Energy Science and Technology Software Center (OSTI)

    1989-10-30

    AYER is a finite element program which implicitly solves the general two-dimensional equation of thermal conduction for plane or axisymmetric bodies. AYER takes into account the effects of time (transient problems), in-plane anisotropic thermal conductivity, a three-dimensional velocity distribution, and interface thermal contact resistance. Geometry and material distributions are arbitrary, and input is via subroutines provided by the user. As a result, boundary conditions, material properties, velocity distributions, and internal power generation may be mademore » functions of, e.g., time, temperature, location, and heat flux.« less

  3. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-05-16

    A fuel element particularly adapted for use in nuclear reactors of high power density is offered. It has fissionable fuel pellet segments mounted in a tubular housing and defining a central passage in the fuel element. A burnable poison element extends through the central passage, which is designed to contain more poison material at the median portion than at the end portions thereby providing a more uniform hurnup and longer reactivity life.

  4. Finite element modeling of lightning

    SciTech Connect (OSTI)

    Hwang, C.C.; Huang, S.R.; Bor, S.S.

    1995-12-31

    In this paper the transmission line equation which describes the transient voltage and current distributions of a lightning stroke is employed. Finite element method is used to derive the element equations and one-dimensional linear elements are used to discretize the field region. The implicit Newmark time integration technique is used to convert the resulting second-order ordinary differential equations into a set of recurrence equations which are then solved at each time step. Numerical example is included and discussed.

  5. Element Labs | Open Energy Information

    Open Energy Info (EERE)

    Labs Jump to: navigation, search Name: Element Labs Address: 3350 Scott Blvd Place: Santa Clara, California Zip: 95054 Region: Bay Area Sector: Efficiency Product: LED Producer...

  6. Solids flow rate measurement in dense slurries

    SciTech Connect (OSTI)

    Porges, K.G.; Doss, E.D.

    1993-09-01

    Accurate and rapid flow rate measurement of solids in dense slurries remains an unsolved technical problem, with important industrial applications in chemical processing plants and long-distance solids conveyance. In a hostile two-phase medium, such a measurement calls for two independent parameter determinations, both by non-intrusive means. Typically, dense slurries tend to flow in laminar, non-Newtonian mode, eliminating most conventional means that usually rely on calibration (which becomes more difficult and costly for high pressure and temperature media). These issues are reviewed, and specific solutions are recommended in this report. Detailed calculations that lead to improved measuring device designs are presented for both bulk density and average velocity measurements. Cross-correlation, chosen here for the latter task, has long been too inaccurate for practical applications. The cause and the cure of this deficiency are discussed using theory-supported modeling. Fluid Mechanics are used to develop the velocity profiles of laminar non-Newtonian flow in a rectangular duct. This geometry uniquely allows the design of highly accurate `capacitive` devices and also lends itself to gamma transmission densitometry on an absolute basis. An absolute readout, though of less accuracy, is also available from a capacitive densitometer and a pair of capacitive sensors yields signals suitable for cross-correlation velocity measurement.

  7. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, Elias

    1995-01-01

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

  8. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, E.

    1995-05-23

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

  9. Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solution

    SciTech Connect (OSTI)

    DePaolo, D.

    2010-10-15

    A surface reaction kinetic model is developed for predicting Ca isotope fractionation and metal/Ca ratios of calcite as a function of rate of precipitation from aqueous solution. The model is based on the requirements for dynamic equilibrium; i.e. proximity to equilibrium conditions is determined by the ratio of the net precipitation rate (R{sub p}) to the gross forward precipitation rate (R{sub f}), for conditions where ionic transport to the growing crystal surface is not rate-limiting. The value of R{sub p} has been experimentally measured under varying conditions, but the magnitude of R{sub f} is not generally known, and may depend on several factors. It is posited that, for systems with no trace constituents that alter the surface chemistry, R{sub f} can be estimated from the bulk far-from-equilibrium dissolution rate of calcite (R{sub b} or k{sub b}), since at equilibrium R{sub f} = R{sub b}, and R{sub p} = 0. Hence it can be inferred that R{sub f} {approx} R{sub p} + R{sub b}. The dissolution rate of pure calcite is measureable and is known to be a function of temperature and pH. At given temperature and pH, equilibrium precipitation is approached when R{sub p} (= R{sub f} - R{sub b}) << R{sub b}. For precipitation rates high enough that R{sub p} >> R{sub b}, both isotopic and trace element partitioning are controlled by the kinetics of ion attachment to the mineral surface, which tend to favor more rapid incorporation of the light isotopes of Ca and discriminate weakly between trace metals and Ca. With varying precipitation rate, a transition region between equilibrium and kinetic control occurs near R{sub p} {approx} R{sub b} for Ca isotopic fractionation. According to this model, Ca isotopic data can be used to estimate R{sub f} for calcite precipitation. Mechanistic models for calcite precipitation indicate that the molecular exchange rate is not constant at constant T and pH, but rather is dependent also on solution saturation state and hence R{sub p}. Allowing R{sub b} to vary as R{sub p}{sup 1/2}, consistent with available precipitation rate studies, produces a better fit to some trace element and isotopic data than a model where R{sub b} is constant. This model can account for most of the experimental data in the literature on the dependence of {sup 44}Ca/{sup 40}Ca and metal/Ca fractionation in calcite as a function of precipitation rate and temperature, and also accounts for {sup 18}O/{sup 16}O variations with some assumptions. The apparent temperature dependence of Ca isotope fractionation in calcite may stem from the dependence of R{sub b} on temperature; there should be analogous pH dependence at pH < 6. The proposed model may be valuable for predicting the behavior of isotopic and trace element fractionation for a range of elements of interest in low-temperature aqueous geochemistry. The theory presented is based on measureable thermo-kinetic parameters in contrast to models that equire hyper-fast diffusivity in near-surface layers of the solid.

  10. Temperature sensors for OTEC applications

    SciTech Connect (OSTI)

    Seren, L.; Panchal, C.B.; Rote, D.M.

    1984-05-01

    Ocean thermal energy conversion (OTEC) applications require accurate measurement of temperatures in the 0 to 30/sup 0/C range. This report documents an experimental examination of commercially available quartz-crystal thermometers and thermistors. Three fixed-point baths were used for temperature measurements: the distilled-water/distilled-ice-water slurry, the triple-point-of-water cell, and the gallium melting-point cell. The temperature of carefully prepared ice-water slurries was verified routinely as 0.001 +- 0.003/sup 0/C. Quartz-crystal probes proved accurate to about 1 to 2 mK, with drift errors of the same order over a few days. Bead- and disk-type thermistor probes were found to be about equally stable with time in the 0 to 30/sup 0/C range. The overall probable error of using thermistors was found to be +-4 mK. A solid-block temperature bath suitable for on-site calibrations in OTEC work was used in the temperature-sweeping mode. Various polynomial fits were examined for the purpose of thermistor calibration; fits of order two and higher yielded about equally accurate calculated temperatures.

  11. Method for processing pulverized solid fuel

    SciTech Connect (OSTI)

    Chukhanov, Z.F.; Chukhanov, Z.Z.; Karasev, V.A.; Samsonov, V.I.; Tsuprov, S.A.

    1982-01-05

    A method is disclosed for processing a pulverized solid fuel by heat, which comprises the steps of drying said fuel and subjecting the latter to two-stage pyrolysis with the resulting formation of vapor, gaseous products and small coke. According to the invention, at least a part of the small coke is additionally heated to a temperature of 800 to 1500/sup 0/C by combustion gas and/or by partial burning of the small coke, whereafter the heated small coke is separated from the combustion gas, fed to the first stage of pyrolysis and for drying the fuel. The heated small coke is gasified by steam. The resultant gasification products are separated from the small coke which is then fed as the heat carrier to the first stage of pyrolysis.

  12. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

    2001-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  13. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, V.K.; Deevi, S.C.; Fleischhauer, G.S.; Hajaligol, M.R.; Lilly, A.C. Jr.

    1997-04-15

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, {<=}1% Cr and either {>=}0.05% Zr or ZrO{sub 2} stringers extending perpendicular to an exposed surface of the heating element or {>=}0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, {<=}2% Ti, {<=}2% Mo, {<=}1% Zr, {<=}1% C, {<=}0.1% B, {<=}30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, {<=}1% rare earth metal, {<=}1% oxygen, {<=}3% Cu, balance Fe. 64 figs.

  14. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

    1999-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  15. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

    1997-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  16. Solid evacuated microspheres of hydrogen

    DOE Patents [OSTI]

    Turnbull, Robert J.; Foster, Christopher A.; Hendricks, Charles D.

    1982-01-01

    A method is provided for producing solid, evacuated microspheres comprised of hydrogen. The spheres are produced by forming a jet of liquid hydrogen and exciting mechanical waves on the jet of appropriate frequency so that the jet breaks up into drops with a bubble formed in each drop by cavitation. The drops are exposed to a pressure less than the vapor pressure of the liquid hydrogen so that the bubble which is formed within each drop expands. The drops which contain bubbles are exposed to an environment having a pressure just below the triple point of liquid hydrogen and they thereby freeze giving solid, evacuated spheres of hydrogen.

  17. The Search for Heavy Elements

    SciTech Connect (OSTI)

    2008-04-17

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  18. The Search for Heavy Elements

    ScienceCinema (OSTI)

    None

    2010-01-08

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  19. Solid fuel combustion system for gas turbine engine

    DOE Patents [OSTI]

    Wilkes, Colin; Mongia, Hukam C.

    1993-01-01

    A solid fuel, pressurized fluidized bed combustion system for a gas turbine engine includes a carbonizer outside of the engine for gasifying coal to a low Btu fuel gas in a first fraction of compressor discharge, a pressurized fluidized bed outside of the engine for combusting the char residue from the carbonizer in a second fraction of compressor discharge to produce low temperature vitiated air, and a fuel-rich, fuel-lean staged topping combustor inside the engine in a compressed air plenum thereof. Diversion of less than 100% of compressor discharge outside the engine minimizes the expense of fabricating and maintaining conduits for transferring high pressure and high temperature gas and incorporation of the topping combustor in the compressed air plenum of the engine minimizes the expense of modifying otherwise conventional gas turbine engines for solid fuel, pressurized fluidized bed combustion.

  20. Thermal battery. [solid metal halide electrolytes with enhanced electrical conductance after a phase transition

    DOE Patents [OSTI]

    Carlsten, R.W.; Nissen, D.A.

    1973-03-06

    The patent describes an improved thermal battery whose novel design eliminates various disadvantages of previous such devices. Its major features include a halide cathode, a solid metal halide electrolyte which has a substantially greater electrical conductance after a phase transition at some temperature, and a means for heating its electrochemical cells to activation temperature.

  1. Method of encapsulating solid radioactive waste material for storage

    DOE Patents [OSTI]

    Bunnell, Lee Roy; Bates, J. Lambert

    1976-01-01

    High-level radioactive wastes are encapsulated in vitreous carbon for long-term storage by mixing the wastes as finely divided solids with a suitable resin, formed into an appropriate shape and cured. The cured resin is carbonized by heating under a vacuum to form vitreous carbon. The vitreous carbon shapes may be further protected for storage by encasement in a canister containing a low melting temperature matrix material such as aluminum to increase impact resistance and improve heat dissipation.

  2. Sierra/solid mechanics 4.22 user's guide.

    SciTech Connect (OSTI)

    Thomas, Jesse David

    2011-10-01

    Sierra/SolidMechanics (Sierra/SM) is a Lagrangian, three-dimensional code for the analysis of solids and structures. It provides capabilities for explicit dynamic and implicit quasistatic and dynamic analyses. The explicit dynamics capabilities allow for the efficient and robust solution of models subjected to large, suddenly applied loads. For implicit problems, Sierra/SM uses a multi-level iterative solver, which enables it to effectively solve problems with large deformations, nonlinear material behavior, and contact. Sierra/SM has a versatile library of continuum and structural elements, and an extensive library of material models. The code is written for parallel computing environments, and it allows for scalable solutions of very large problems for both implicit and explicit analyses. It is built on the SIERRA Framework, which allows for coupling with other SIERRA mechanics codes. This document describes the functionality and input structure for Sierra/SM.

  3. Ultrasonic transducer for extreme temperature environments

    DOE Patents [OSTI]

    Light, Glenn M.; Cervantes, Richard A.; Alcazar, David G.

    1993-03-23

    An ultrasonic piezoelectric transducer that is operable in very high and very low temperatures. The transducer has a dual housing structure that isolates the expansion and contraction of the piezoelectric element from the expansion and contraction of the housing. Also, the internal components are made from materials having similar coefficients of expansion so that they do not interfere with the motion of the piezoelectric element.

  4. Solid lithium-ion electrolyte

    DOE Patents [OSTI]

    Zhang, Ji-Guang; Benson, David K.; Tracy, C. Edwin

    1998-01-01

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

  5. Solid-State Lighting Consortia

    Broader source: Energy.gov [DOE]

    Most potential users of light-emitting diode (LED) lighting do not have large training budgets to independently educate themselves; participation in the Solid-State Lighting (SSL) Consortia is a low-cost–low-risk way to benefit from the knowledge and experience of others.

  6. Solid-state radioluminescent compositions

    DOE Patents [OSTI]

    Clough, Roger L.; Gill, John T.; Hawkins, Daniel B.; Renschler, Clifford L.; Shepodd, Timothy J.; Smith, Henry M.

    1991-01-01

    A solid state radioluminescent composition for light source comprises an optically clear polymer organic matrix containing tritiated organic materials and dyes capable of "red" shifting primary scintillation emissions from the polymer matrix. The tritiated organic materials are made by reducing, with tritium, an unsaturated organic compound that prior to reduction contains olefinic or alkynylic bonds.

  7. Solid lithium-ion electrolyte

    DOE Patents [OSTI]

    Zhang, J.G.; Benson, D.K.; Tracy, C.E.

    1998-02-10

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O--CeO{sub 2}--SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

  8. Solid colloidal optical wavelength filter

    DOE Patents [OSTI]

    Alvarez, Joseph L.

    1992-01-01

    A solid colloidal optical wavelength filter includes a suspension of spheal particles dispersed in a coagulable medium such as a setting plastic. The filter is formed by suspending spherical particles in a coagulable medium; agitating the particles and coagulable medium to produce an emulsion of particles suspended in the coagulable medium; and allowing the coagulable medium and suspended emulsion of particles to cool.

  9. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  10. Regional solid waste management study

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    In 1990, the Lower Savannah Council of Governments (LSCOG) began dialogue with the United States Department of Energy (DOE) regarding possibilities for cooperation and coordination of solid waste management practices among the local governments and the Savannah River Site. The Department of Energy eventually awarded a grant to the Lower Savannah Council of Governments for the development of a study, which was initiated on March 5, 1992. After careful analysis of the region`s solid waste needs, this study indicates a network approach to solid waste management to be the most viable. The network involves the following major components: (1) Rural Collection Centers, designed to provide convenience to rural citizens, while allowing some degree of participation in recycling; (2) Rural Drop-Off Centers, designed to give a greater level of education and recycling activity; (3) Inert landfills and composting centers, designed to reduce volumes going into municipal (Subtitle D) landfills and produce useable products from yard waste; (4) Transfer Stations, ultimate landfill disposal; (5) Materials Recovery Facilities, designed to separate recyclables into useable and sellable units, and (6) Subtitle D landfill for burial of all solid waste not treated through previous means.

  11. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael; Draper, Robert

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  12. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    P. Bernot

    2005-07-13

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this activity is to predict dissolved concentrations or solubility limits for elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) relevant to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are provided in the form of tabulated functions with pH and log fCO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. Even though selection of an appropriate set of radionuclides documented in Radionuclide Screening (BSC 2002 [DIRS 160059]) includes actinium, transport of Ac is not modeled in the total system performance assessment for the license application (TSPA-LA) model because of its extremely short half-life. Actinium dose is calculated in the TSPA-LA by assuming secular equilibrium with {sup 231}Pa (Section 6.10); therefore, Ac is not analyzed in this report. The output data from this report are fundamental inputs for TSPA-LA used to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for the actinides discussed in this report. These models cover broad ranges of environmental conditions so they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

  13. Status of Segmented Element Thermoelectric Generator for Vehicle Waste Heat

    Broader source: Energy.gov (indexed) [DOE]

    Recovery | Department of Energy Discusses progress of thermoelectric generator development at BSST and assessment of potential to enter commercial operation in vehicles PDF icon crane.pdf More Documents & Publications Status of Segmented Element Thermoelectric Generator for Vehicle Waste Heat Recovery Development of a 100-Watt High Temperature Thermoelectric Generator Development of a Scalable 10% Efficient Thermoelectric Generator

  14. Simulating Solid-Solid Phase Transition in Shape-Memory Alloy Microstructure by Face-Offsetting Method

    SciTech Connect (OSTI)

    Bellur Ramaswamy, Ravi S.; Tortorelli, Daniel A.; Fried, Eliot; Jiao Xiangmin

    2008-02-15

    Advances in the understanding of martensitic transformations (diffusionless, solid-solid phase transformations) have been instrumental to the recent discovery of new low hysteresis alloys. However, some key fundamental issues must be better understood to design still better alloys. Restricting attention to antiplane shear, we use finite element analysis to model the shape-memory alloy microstructure within the Abeyaratne-Knowles continuum thermomechanical framework and use an interface kinetic relation of the kind proposed by Rosakis and Tsai. Geometric singularities and topological changes associated with microstructural evolution pose significant numerical challenges. We address such challenges with a recently developed front-tracking scheme called the face-offsetting method (FOM) to explicitly model phase interfaces. Initial results demonstrate the effectiveness of FOM in resolving needle-like twinned microstructures.

  15. Method for detecting an element

    DOE Patents [OSTI]

    Blackwood, Larry G.; Reber, Edward L.; Rohde, Kenneth W.

    2007-02-06

    A method for detecting an element is disclosed and which includes the steps of providing a gamma-ray spectrum which depicts, at least in part, a test region having boundaries, and which has a small amount of the element to be detected; providing a calculation which detects the small amount of the element to be detected; and providing a moving window and performing the calculation within the moving window, and over a range of possible window boundaries within the test region to determine the location of the optimal test region within the gamma-ray spectrum.

  16. Electrical contact structures for solid oxide electrolyte fuel cell

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills, PA)

    1984-01-01

    An improved electrical output connection means is provided for a high temperature solid oxide electrolyte type fuel cell generator. The electrical connection of the fuel cell electrodes to the electrical output bus, which is brought through the generator housing to be connected to an electrical load line maintains a highly uniform temperature distribution. The electrical connection means includes an electrode bus which is spaced parallel to the output bus with a plurality of symmetrically spaced transversely extending conductors extending between the electrode bus and the output bus, with thermal insulation means provided about the transverse conductors between the spaced apart buses. Single or plural stages of the insulated transversely extending conductors can be provided within the high temperatures regions of the fuel cell generator to provide highly homogeneous temperature distribution over the contacting surfaces.

  17. Nanostructured Solid Oxide Fuel Cell Electrodes

    SciTech Connect (OSTI)

    Sholklapper, Tal Zvi

    2007-12-15

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  18. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, C.C.; Mrazek, F.C.

    1988-08-02

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

  19. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, Charles C.; Mrazek, Franklin C.

    1988-01-01

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

  20. FUEL ELEMENTS FOR NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Foote, F.G.; Jette, E.R.

    1963-05-01

    A fuel element for a nuclear reactor is described that consists of a jacket containing a unitary core of fissionable material and a filling of a metal of the group consisting of sodium and sodium-potassium alloys. (AEC)

  1. Environmental research on actinide elements

    SciTech Connect (OSTI)

    Pinder, J.E. III; Alberts, J.J.; McLeod, K.W.; Schreckhise, R.G.

    1987-08-01

    The papers synthesize the results of research sponsored by DOE's Office of Health and Environmental Research on the behavior of transuranic and actinide elements in the environment. Separate abstracts have been prepared for the 21 individual papers. (ACR)

  2. Low exhaust temperature electrically heated particulate matter filter system

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2012-02-14

    A system includes a particulate matter (PM) filter, a sensor, a heating element, and a control module. The PM filter includes with an upstream end that receives exhaust gas, a downstream end and multiple zones. The sensor detects a temperature of the exhaust gas. The control module controls current to the heating element to convection heat one of the zones and initiate a regeneration process. The control module selectively increases current to the heating element relative to a reference regeneration current level when the temperature is less than a predetermined temperature.

  3. Efficient large-scale finite-element computations in a CRAY environment

    SciTech Connect (OSTI)

    Goudreau, G.L.; Bailey, R.A.; Hallquist, J.O.; Murray, R.C.; Sackett, S.J.

    1983-06-01

    The Lawrence Livermore National Laboratory engineering computational experience on the CRAY-1 is highlighted in the context of our large general purpose solid and structural mechanics codes. DYNA2D and DYNA3D are explicit large deformation inelastic Lagrangian codes with one point elements and hourglass control. NIKE2D and NIKE3D are implicit codes of comparable continuum formulation but use two point constant pressure elements and an optimized linear equation solver. NIKE3D has a finite rotation plastic resultant shell element. The new general purpose linear elastic structures code GEMINI is also illustrated for large static and eigenvalue analysis. 19 references.

  4. Results of Characterization and Retrieval Testing on Tank 241-C-109 Heel Solids

    SciTech Connect (OSTI)

    Callaway, William S.

    2013-09-26

    Eight samples of heel solids from tank 241-C-109 were delivered to the 222-S Laboratory for characterization and dissolution testing. After being drained thoroughly, one-half to two-thirds of the solids were off-white to tan solids that, visually, were fairly evenly graded in size from coarse silt (30-60 μm) to medium pebbles (8-16 mm). The remaining solids were mostly strongly cemented aggregates ranging from coarse pebbles (16-32 mm) to fine cobbles (6-15 cm) in size. Solid phase characterization and chemical analysis indicated that the air-dry heel solids contained ≈58 wt% gibbsite [Al(OH){sub 3}] and ≈37 wt% natrophosphate [Na{sub 7}F(PO{sub 4}){sub 2}�19H{sub 2}O]. The strongly cemented aggregates were mostly fine-grained gibbsite cemented with additional gibbsite. Dissolution testing was performed on two test samples. One set of tests was performed on large pieces of aggregate solids removed from the heel solids samples. The other set of dissolution tests was performed on a composite sample prepared from well-drained, air-dry heel solids that were crushed to pass a �-in. sieve. The bulk density of the composite sample was 2.04 g/mL. The dissolution tests included water dissolution followed by caustic dissolution testing. In each step of the three-step water dissolution tests, a volume of water approximately equal to 3 times the initial volume of the test solids was added. In each step, the test samples were gently but thoroughly mixed for approximately 2 days at an average ambient temperature of 25 �C. The caustic dissolution tests began with the addition of sufficient 49.6 wt% NaOH to the water dissolution residues to provide ≈3.1 moles of OH for each mole of Al estimated to have been present in the starting composite sample and ≈2.6 moles of OH for each mole of Al potentially present in the starting aggregate sample. Metathesis of gibbsite to sodium aluminate was then allowed to proceed over 10 days of gentle mixing of the test samples at temperatures ranging from 26-30 �C. The metathesized sodium aluminate was then dissolved by addition of volumes of water approximately equal to 1.3 times the volumes of caustic added to the test slurries. Aluminate dissolution was allowed to proceed for 2 days at ambient temperatures of ≈29 �C. Overall, the sequential water and caustic dissolution tests dissolved and removed 80.0 wt% of the tank 241-C-109 crushed heel solids composite test sample. The 20 wt% of solids remaining after the dissolution tests were 85-88 wt% gibbsite. If the density of the residual solids was approximately equal to that of gibbsite, they represented ≈17 vol% of the initial crushed solids composite test sample. In the water dissolution tests, addition of a volume of water ≈6.9 times the initial volume of the crushed solids composite was sufficient to dissolve and recover essentially all of the natrophosphate present. The ratio of the weight of water required to dissolve the natrophosphate solids to the estimated weight of natrophosphate present was 8.51. The Environmental Simulation Program (OLI Systems, Inc., Morris Plains, New Jersey) predicts that an 8.36 w/w ratio would be required to dissolve the estimated weight of natrophosphate present in the absence of other components of the heel solids. Only minor amounts of Al-bearing solids were removed from the composite solids in the water dissolution tests. The caustic metathesis/aluminate dissolution test sequence, executed at temperatures ranging from 27-30 �C, dissolved and recovered ≈69 wt% of the gibbsite estimated to have been present in the initial crushed heel solids composite. This level of gibbsite recovery is consistent with that measured in previous scoping tests on the dissolution of gibbsite in strong caustic solutions. Overall, the sequential water and caustic dissolution tests dissolved and removed 80.3 wt% of the tank 241-C-109 aggregate solids test sample. The residual solids were 92-95 wt% gibbsite. Only a minor portion (≈4.5 wt%) of the aggregate solids was dissolved and recovered in the water dissolution test. Other than some smoothing caused by continuous mixing, the aggregates were essentially unaffected by the water dissolution tests. During the caustic metathesis/aluminate dissolution test sequence, ≈81 wt% of the gibbsite estimated to have been present in the aggregate solids was dissolved and recovered. The pieces of aggregate were significantly reduced in size but persisted as distinct pieces of solids. The increased level of gibbsite recovery, as compared to that for the crushed heel solids composite, suggests that the way the gibbsite solids and caustic solution are mixed is a key determinant of the overall efficiency of gibbsite dissolution and recovery. The liquids recovered after the caustic dissolution tests on the crushed solids composite and the aggregate solids were observed for 170 days. No precipitation of gibbsite was observed. The distribution of particle sizes in the residual solids recovered following the dissolution tests on the crushed heel solids composite was characterized. Wet sieving indicated that 21.4 wt% of the residual solids were >710 μm in size, and laser light scattering indicated that the median equivalent spherical diameter in the <710-μm solids was 35 μm. The settling behavior of the residual solids following the large-scale dissolution tests was also studied. When dispersed at a concentration of ≈1 vol% in water, ≈24 wt% of the residual solids settled at a rate >0.43 in./s; ≈68 wt% settled at rates between 0.02 and 0.43 in./s; and ≈7 wt% settled slower than 0.02 in./s.

  5. Solid-state membrane module

    DOE Patents [OSTI]

    Gordon, John Howard; Taylor, Dale M.

    2011-06-07

    Solid-state membrane modules comprising at least one membrane unit, where the membrane unit has a dense mixed conducting oxide layer, and at least one conduit or manifold wherein the conduit or manifold comprises a dense layer and at least one of a porous layer and a slotted layer contiguous with the dense layer. The solid-state membrane modules may be used to carry out a variety of processes including the separating of any ionizable component from a feedstream wherein such ionizable component is capable of being transported through a dense mixed conducting oxide layer of the membrane units making up the membrane modules. For ease of construction, the membrane units may be planar.

  6. Solid-State Lighting | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Princeton's approach to solid-state lighting. Read more A Comprehensive Program Solid-state lighting (SSL) technology has the potential to reduce U.S. lighting energy usage by...

  7. Idaho Solid Waste Webpage | Open Energy Information

    Open Energy Info (EERE)

    Solid Waste Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Idaho Solid Waste Webpage Abstract This webpage provides an overview of regulation...

  8. Supercritical/Solid Catalyst (SSC)

    ScienceCinema (OSTI)

    None

    2013-05-28

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  9. Supercritical/Solid Catalyst (SSC)

    SciTech Connect (OSTI)

    2010-01-01

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  10. Solid-state membrane module

    DOE Patents [OSTI]

    Hinklin, Thomas Ray; Lewinsohn, Charles Arthur

    2015-06-30

    A module for separating oxygen from an oxygen-containing gaseous mixture comprising planar solid-state membrane units, each membrane unit comprising planar dense mixed conducting oxides layers, planar channel-free porous support layers, and one or more planar intermediate support layers comprising at least one channeled porous support layer. The porosity of the planar channeled porous support layers is less than the porosity of the planar channel-free porous support layers.

  11. Solid Oxide Fuel Cells FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FAQs faq-header-big.jpg SOLID OXIDE FUEL CELLS - BASICS Q: What is a fuel cell? A: A fuel cell is a power generation device that converts the chemical energy of a fuel and oxidant directly into electrical energy, with heat and water as byproducts. Since fuel cells produce electricity through an electrochemical reaction and not through a combustion process, they are inherently more efficient and environmentally friendly than conventional electric power generation processes. Q: What are the

  12. Fluid Dynamics and Solid Mechanics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Fluid Dynamics and Solid Mechanics Basic and applied research in theoretical continuum dynamics, modern hydrodynamic theory, materials modeling, global climate modeling, numerical algorithm development, and large-scale computational simulations. Global climate modeling simulation The Art of Climate Modeling Global climate change ParaView visualization READ MORE Multiscale modeling Multiscale Modeling Strain contours illustrate the process of shear localization in metallic materials Projectile

  13. SEACAS Theory Manuals: Part 1. Problem Formulation in Nonlinear Solid Mechancis

    SciTech Connect (OSTI)

    Attaway, S.W.; Laursen, T.A.; Zadoks, R.I.

    1998-08-01

    This report gives an introduction to the basic concepts and principles involved in the formulation of nonlinear problems in solid mechanics. By way of motivation, the discussion begins with a survey of some of the important sources of nonlinearity in solid mechanics applications, using wherever possible simple one dimensional idealizations to demonstrate the physical concepts. This discussion is then generalized by presenting generic statements of initial/boundary value problems in solid mechanics, using linear elasticity as a template and encompassing such ideas as strong and weak forms of boundary value problems, boundary and initial conditions, and dynamic and quasistatic idealizations. The notational framework used for the linearized problem is then extended to account for finite deformation of possibly inelastic solids, providing the context for the descriptions of nonlinear continuum mechanics, constitutive modeling, and finite element technology given in three companion reports.

  14. Refining of solid ferrous scrap intermingled with copper by using molten aluminum

    SciTech Connect (OSTI)

    Iwase, M.

    1996-12-31

    A new approach for the removal of copper from solid ferrous scrap has been proposed by the present authors. With this process, solid ferrous scrap intermingled with pure copper is brought into contact with molten aluminum, which dissolved copper preferentially, and is recovered as {l_brace}Al + Cu{r_brace} alloys. After a duration of 30 minutes at temperatures between 963 K and 1,223 K, steel scrap is removed from the bath, resulting in being free of copper contamination.

  15. Temperature programmable microfabricated gas chromatography column

    DOE Patents [OSTI]

    Manginell, Ronald P.; Frye-Mason, Gregory C.

    2003-12-23

    A temperature programmable microfabricated gas chromatography column enables more efficient chemical separation of chemical analytes in a gas mixture by the integration of a resistive heating element and temperature sensing on the microfabricated column. Additionally, means are provided to thermally isolate the heated column from their surroundings. The small heat capacity and thermal isolation of the microfabricated column improves the thermal time response and power consumption, both important factors for portable microanalytical systems.

  16. Processing and properties of a solid energy fuel from municipal solid waste (MSW) and recycled plastics

    SciTech Connect (OSTI)

    Gug, JeongIn Cacciola, David Sobkowicz, Margaret J.

    2015-01-15

    Highlights: • Briquetting was used to produce solid fuels from municipal solid waste and recycled plastics. • Optimal drying, processing temperature and pressure were found to produce stable briquettes. • Addition of waste plastics yielded heating values comparable with typical coal feedstocks. • This processing method improves utilization of paper and plastic diverted from landfills. - Abstract: Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW) is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in higher heating value. Analysis of the post-processing water uptake and compressive strength showed a correlation between density and stability to both mechanical stress and humid environment. Proximate analysis indicated heating values comparable to coal. The results showed that mechanical and moisture uptake stability were improved when the moisture and air contents were optimized. Moreover, the briquette sample composition was similar to biomass fuels but had significant advantages due to addition of waste plastics that have high energy content compared to other waste types. Addition of PP and HDPE presented better benefits than addition of PET due to lower softening temperature and lower oxygen content. It should be noted that while harmful emissions such as dioxins, furans and mercury can result from burning plastics, WTE facilities have been able to control these emissions to meet US EPA standards. This research provides a drop-in coal replacement that reduces demand on landfill space and replaces a significant fraction of fossil-derived fuel with a renewable alternative.

  17. Energy and solid/hazardous waste

    SciTech Connect (OSTI)

    1981-12-01

    This report addresses the past and potential future solid and hazardous waste impacts from energy development, and summarizes the major environmental, legislation applicable to solid and hazardous waste generation and disposal. A glossary of terms and acronyms used to describe and measure solid waste impacts of energy development is included. (PSB)

  18. Rechargeable solid polymer electrolyte battery cell

    DOE Patents [OSTI]

    Skotheim, Terji

    1985-01-01

    A rechargeable battery cell comprising first and second electrodes sandwiching a solid polymer electrolyte comprising a layer of a polymer blend of a highly conductive polymer and a solid polymer electrolyte adjacent said polymer blend and a layer of dry solid polymer electrolyte adjacent said layer of polymer blend and said second electrode.

  19. Solid Waste Management Plan. Revision 4

    SciTech Connect (OSTI)

    1995-04-26

    The waste types discussed in this Solid Waste Management Plan are Municipal Solid Waste, Hazardous Waste, Low-Level Mixed Waste, Low-Level Radioactive Waste, and Transuranic Waste. The plan describes for each type of solid waste, the existing waste management facilities, the issues, and the assumptions used to develop the current management plan.

  20. Suspended Solids Profiler Shop Test Report

    SciTech Connect (OSTI)

    STAEHR, T.W.

    2000-01-19

    The Suspended Solids Profiler (SSP) Instrument is planned to be installed in the AZ-101 tank to measure suspended solids concentrations during mixer pump testing. The SSP sensor uses a reflectance measurement principle to determine the suspended solids concentrations. The purpose of this test is to provide a documented means of verifying that the functional components of the SSP operate properly.

  1. High temperature two component explosive

    DOE Patents [OSTI]

    Mars, James E.; Poole, Donald R.; Schmidt, Eckart W.; Wang, Charles

    1981-01-01

    A two component, high temperature, thermally stable explosive composition comprises a liquid or low melting oxidizer and a liquid or low melting organic fuel. The oxidizer and fuel in admixture are incapable of substantial spontaneous exothermic reaction at temperatures on the order of 475.degree. K. At temperatures on the order of 475.degree. K., the oxidizer and fuel in admixture have an activation energy of at least about 40 kcal/mol. As a result of the high activation energy, the preferred explosive compositions are nondetonable as solids at ambient temperature, and become detonable only when heated beyond the melting point. Preferable oxidizers are selected from alkali or alkaline earth metal nitrates, nitrites, perchlorates, and/or mixtures thereof. Preferred fuels are organic compounds having polar hydrophilic groups. The most preferred fuels are guanidinium nitrate, acetamide and mixtures of the two. Most preferred oxidizers are eutectic mixtures of lithium nitrate, potassium nitrate and sodium nitrate, of sodium nitrite, sodium nitrate and potassium nitrate, and of potassium nitrate, calcium nitrate and sodium nitrate.

  2. Extractability of heavy metals in wastewater solids undergoing anaerobic digestion

    SciTech Connect (OSTI)

    Chen, D.D.

    1983-01-01

    The extractability of heavy metals in wastewater sludge undergoing anaerobic digestion was investigated. Using batch laboratory digesters, raw wastewater sludge was anaerobically digested at different raw sludge solids loadings and two temperatures. From each of the laboratory digesters, wastewater sludge was sampled at three day intervals and sequentially separated into seven extraction fractions and analyzed for the metals Cu, Cr, Cd, Fe, Ni, and Pb. The seven step sequential extraction was for metal species: (a) soluble, (b) displaced-exchangeable, (c) adsorbed, (d) organic, (e) carbonate, (f) sulfide-acid soluble, and (g) residual. At the 35/sup 0/C digestion temperature the distribution of metals in the extractant fractions between the raw and anaerobically digested sludges were significantly different. For the 45/sup 0/C digestion temperature the distribution of metals in the raw and digested sludge extractant fractions were different and different compared to the 35/sup 0/C system. The 45/sup 0/C raw sludge showed greater percent metal in the organic and sulfide-acid soluble fraction than the digested sludge. At the 45/sup 0/C anaerobic digestion temperature the percent of raw sludge solids loading in the digester had a greater effect on changes in metal extractability and proposed metal species than the 35/sup 0/C.

  3. Molecular Solid EOS based on Quasi-Harmonic Oscillator approximation for phonons

    SciTech Connect (OSTI)

    Menikoff, Ralph

    2014-09-02

    A complete equation of state (EOS) for a molecular solid is derived utilizing a Helmholtz free energy. Assuming that the solid is nonconducting, phonon excitations dominate the specific heat. Phonons are approximated as independent quasi-harmonic oscillators with vibrational frequencies depending on the specific volume. The model is suitable for calibrating an EOS based on isothermal compression data and infrared/Raman spectroscopy data from high pressure measurements utilizing a diamond anvil cell. In contrast to a Mie-Gr ̈uneisen EOS developed for an atomic solid, the specific heat and Gr ̈uneisen coefficient depend on both density and temperature.

  4. Process for producing high purity silicon nitride by the direct reaction between elemental silicon and nitrogen-hydrogen liquid reactants

    DOE Patents [OSTI]

    Pugar, Eloise A.; Morgan, Peter E. D.

    1990-01-01

    A process is disclosed for producing, at a low temperature, a high purity reaction product consisting essentially of silicon, nitrogen, and hydrogen which can then be heated to produce a high purity alpha silicon nitride. The process comprises: reacting together a particulate elemental high purity silicon with a high purity nitrogen-hydrogen reactant in its liquid state (such as ammonia or hydrazine) having the formula: N.sub.n H.sub.(n+m) wherein: n=1-4 and m=2 when the nitrogen-hydrogen reactant is straight chain, and 0 when the nitrogen-hydrogen reactant is cyclic. High purity silicon nitride can be formed from this intermediate product by heating the intermediate product at a temperature of from about 1200.degree.-1700.degree. C. for a period from about 15 minutes up to about 2 hours to form a high purity alpha silicon nitride product. The discovery of the existence of a soluble Si-N-H intermediate enables chemical pathways to be explored previously unavailable in conventional solid state approaches to silicon-nitrogen ceramics.

  5. Process for producing high purity silicon nitride by the direct reaction between elemental silicon and nitrogen-hydrogen liquid reactants

    DOE Patents [OSTI]

    Pugar, E.A.; Morgan, P.E.D.

    1987-09-15

    A process is disclosed for producing, at a low temperature, a high purity reaction product consisting essentially of silicon, nitrogen, and hydrogen which can then be heated to produce a high purity alpha silicon nitride. The process comprises: reacting together a particulate elemental high purity silicon with a high purity nitrogen-hydrogen reactant in its liquid state (such as ammonia or hydrazine) having the formula: N/sub n/H/sub (n+m)/ wherein: n = 1--4 and m = 2 when the nitrogen-hydrogen reactant is straight chain, and 0 when the nitrogen-hydrogen reactant is cyclic. High purity silicon nitride can be formed from this intermediate product by heating the intermediate product at a temperature of from about 1200--1700/degree/C for a period from about 15 minutes up to about 2 hours to form a high purity alpha silicon nitride product. The discovery of the existence of a soluble Si/endash/N/endash/H intermediate enables chemical pathways to be explored previously unavailable in conventional solid-state approaches to silicon-nitrogen ceramics

  6. Solid State Lighting FAQ Tip Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solid State Lighting FAQ Tip Sheet Solid State Lighting FAQ Tip Sheet Contains information on solid state lighting applications for energy efficiency in buildings. PDF icon ...

  7. Solid-State Lighting Program Overview Brochure | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Overview Brochure Solid-State Lighting Program Overview Brochure PDF icon Solid-State Lighting Program Overview Brochure.pdf More Documents & Publications Solid-State ...

  8. International Solid Waste Association (ISWA) | Open Energy Information

    Open Energy Info (EERE)

    Solid Waste Association (ISWA) Jump to: navigation, search Name: International Solid Waste Association (ISWA) Address: ISWA - International Solid Waste Association General...

  9. Methods and apparatuses for making cathodes for high-temperature, rechargeable batteries

    DOE Patents [OSTI]

    Meinhardt, Kerry D; Sprenkle, Vincent L; Coffey, Gregory W

    2014-05-20

    The approaches for fabricating cathodes can be adapted to improve control over cathode composition and to better accommodate batteries of any shape and their assembly. For example, a first solid having an alkali metal halide, a second solid having a transition metal, and a third solid having an alkali metal aluminum halide are combined into a mixture. The mixture can be heated in a vacuum to a temperature that is greater than or equal to the melting point of the third solid. When the third solid is substantially molten liquid, the mixture is compressed into a desired cathode shape and then cooled to solidify the mixture in the desired cathode shape.

  10. Process for oxidation of hydrogen halides to elemental halogens

    DOE Patents [OSTI]

    Lyke, Stephen E.

    1992-01-01

    An improved process for generating an elemental halogen selected from chlorine, bromine or iodine, from a corresponding hydrogen halide by absorbing a molten salt mixture, which includes sulfur, alkali metals and oxygen with a sulfur to metal molar ratio between 0.9 and 1.1 and includes a dissolved oxygen compound capable of reacting with hydrogen halide to produce elemental halogen, into a porous, relatively inert substrate to produce a substrate-supported salt mixture. Thereafter, the substrate-supported salt mixture is contacted (stage 1) with a hydrogen halide while maintaining the substrate-supported salt mixture during the contacting at an elevated temperature sufficient to sustain a reaction between the oxygen compound and the hydrogen halide to produce a gaseous elemental halogen product. This is followed by purging the substrate-supported salt mixture with steam (stage 2) thereby recovering any unreacted hydrogen halide and additional elemental halogen for recycle to stage 1. The dissolved oxygen compound is regenerated in a high temperature (stage 3) and an optical intermediate temperature stage (stage 4) by contacting the substrate-supported salt mixture with a gas containing oxygen whereby the dissolved oxygen compound in the substrate-supported salt mixture is regenerated by being oxidized to a higher valence state.

  11. Solid Deuterium-Tritium Surface Roughness In A Beryllium Inertial Confinement Fusion Shell

    SciTech Connect (OSTI)

    Kozioziemski, B J; Sater, J D; Moody, J D; Montgomery, D S; Gautier, C

    2006-04-19

    Solid deuterium-tritium (D-T) fuel layers for inertial confinement fusion experiments were formed inside of a 2 mm diameter beryllium shell and were characterized using phase-contrast enhanced x-ray imaging. The solid D-T surface roughness is found to be 0.4 {micro}m for modes 7-128 at 1.5 K below the melting temperature. The layer roughness is found to increase with decreasing temperature, in agreement with previous visible light characterization studies. However, phase-contrast enhanced x-ray imaging provides a more robust surface roughness measurement than visible light methods. The new x-ray imaging results demonstrate clearly that the surface roughness decreases with time for solid D-T layers held at 1.5 K below the melting temperature.

  12. INTEC SBW Solid Sludge Surrogate Recipe and Validation

    SciTech Connect (OSTI)

    Maio, Vince; Janikowski, Stuart; Johnson, Jim; Maio, Vince; Pao, Jenn-Hai

    2004-06-01

    A nonhazardous INTEC tank farm sludge surrogate that incorporated metathesis reactions to generate solids from solutions of known elements present in the radioactive INTEC tank farm sodium-bearing waste sludges was formulated. Elemental analyses, physical property analyses, and filtration testing were performed on waste surrogate and tank farm waste samples, and the results were compared. For testing physical systems associated with moving the tank farm solids, the surrogate described in this report is the best currently available choice. No other available surrogate exhibits the noted similarities in behavior to the sludges. The chemical morphology, particle size distribution, and settling and flow characteristics of the surrogate were similar to those exhibited by the waste sludges. Nonetheless, there is a difference in chemical makeup of the surrogate and the tank farm waste. If a chemical treatment process were to be evaluated for final treatment and disposition of the waste sludges, the surrogate synthesis process would likely require modification to yield a surrogate with a closer matching chemical composition.

  13. Measured and predicted temperature profiles along MEMS bridges at pressures from 0.05 to 625 torr.

    SciTech Connect (OSTI)

    Gallis, Michail A.; Torczynski, John Robert; Piekos, Edward Stanley; Serrano, Justin Raymond; Gorby, Allen D.; Phinney, Leslie Mary

    2010-10-01

    We will present experimental and computational investigations of the thermal performance of microelectromechanical systems (MEMS) as a function of the surrounding gas pressure. Lowering the pressure in MEMS packages reduces gas damping, providing increased sensitivity for certain MEMS sensors; however, such packaging also dramatically affects their thermal performance since energy transfer to the environment is substantially reduced. High-spatial-resolution Raman thermometry was used to measure the temperature profiles on electrically heated, polycrystalline silicon bridges that are nominally 10 microns wide, 2.25 microns thick, 12 microns above the substrate, and either 200 or 400 microns long in nitrogen atmospheres with pressures ranging from 0.05 to 625 Torr. Finite element modeling of the thermal behavior of the MEMS bridges is performed and compared to the experimental results. Noncontinuum gas effects are incorporated into the continuum finite element model by imposing temperature discontinuities at gas-solid interfaces that are determined from noncontinuum simulations. The experimental and simulation results indicate that at pressures below 0.5 Torr the gas-phase heat transfer is negligible compared to heat conduction through the thermal actuator legs. As the pressure increases above 0.5 Torr, the gas-phase heat transfer becomes more significant. At ambient pressures, gas-phase heat transfer drastically impacts the thermal performance. The measured and simulated temperature profiles are in qualitative agreement in the present study. Quantitative agreement between experimental and simulated temperature profiles requires accurate knowledge of temperature-dependent thermophysical properties, the device geometry, and the thermal accommodation coefficient.

  14. FABRICATION OF TUBE TYPE FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Loeb, E.; Nicklas, J.H.

    1959-02-01

    A method of fabricating a nuclear reactor fuel element is given. It consists essentially of fixing two tubes in concentric relationship with respect to one another to provide an annulus therebetween, filling the annulus with a fissionablematerial-containing powder, compacting the powder material within the annulus and closing the ends thereof. The powder material is further compacted by swaging the inner surface of the inner tube to increase its diameter while maintaining the original size of the outer tube. This process results in reduced fabrication costs of powdered fissionable material type fuel elements and a substantial reduction in the peak core temperatures while materially enhancing the heat removal characteristics.

  15. Cryogenic Thermal Expansion of Y-12 Graphite Fuel Elements

    SciTech Connect (OSTI)

    Eash, D. T.

    2013-07-08

    Thermal expansion measurements betwccn 20°K and 300°K were made on segments of three uranium-loaded Y-12 uncoated graphite fuel elements. The thermal expansion of these fuel elements over this temperature range is represented by the equation: {Delta}L/L = -39.42 x 10{sup -5} + 1.10 x 10{sup -7} T + 6.47 x 10{sup -9} T{sup 2} - 8.30 x 10{sup -12} T{sup 3}.

  16. Experimentally validated finite element model of electrocaloric multilayer ceramic structures

    SciTech Connect (OSTI)

    Smith, N. A. S. E-mail: maciej.rokosz@npl.co.uk Correia, T. M. E-mail: maciej.rokosz@npl.co.uk; Rokosz, M. K. E-mail: maciej.rokosz@npl.co.uk

    2014-07-28

    A novel finite element model to simulate the electrocaloric response of a multilayer ceramic capacitor (MLCC) under real environment and operational conditions has been developed. The two-dimensional transient conductive heat transfer model presented includes the electrocaloric effect as a source term, as well as accounting for radiative and convective effects. The model has been validated with experimental data obtained from the direct imaging of MLCC transient temperature variation under application of an electric field. The good agreement between simulated and experimental data, suggests that the novel experimental direct measurement methodology and the finite element model could be used to support the design of optimised electrocaloric units and operating conditions.

  17. SOLID STATE ENERGY CONVERSION ALLIANCE DELPHI SOLID OXIDE FUEL CELL

    SciTech Connect (OSTI)

    Steven Shaffer; Sean Kelly; Subhasish Mukerjee; David Schumann; Gail Geiger; Kevin Keegan; John Noetzel; Larry Chick

    2003-12-08

    The objective of Phase I under this project is to develop a 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. During Phase I, the following will be accomplished: Develop and demonstrate technology transfer efforts on a 5 kW stationary distributed power generation system that incorporates steam reforming of natural gas with the option of piped-in water (Demonstration System A). Initiate development of a 5 kW system for later mass-market automotive auxiliary power unit application, which will incorporate Catalytic Partial Oxidation (CPO) reforming of gasoline, with anode exhaust gas injected into an ultra-lean burn internal combustion engine. This technical progress report covers work performed by Delphi from January 1, 2003 to June 30, 2003, under Department of Energy Cooperative Agreement DE-FC-02NT41246. This report highlights technical results of the work performed under the following tasks: Task 1 System Design and Integration; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant (BOP) Components; Task 5 Manufacturing Development (Privately Funded); Task 6 System Fabrication; Task 7 System Testing; Task 8 Program Management; and Task 9 Stack Testing with Coal-Based Reformate.

  18. Solid waste management in Kolkata, India: Practices and challenges

    SciTech Connect (OSTI)

    Hazra, Tumpa; Goel, Sudha

    2009-01-15

    This paper presents an overview of current solid waste management (SWM) practices in Kolkata, India and suggests solutions to some of the major problems. More than 2920 ton/d of solid waste are generated in the Kolkata Municipal Corporation (KMC) area and the budget allocation for 2007-2008 was Rs. 1590 million (US$40 million), which amounts to Rs. 265/cap-y (US$6.7/cap-d) on SWM. This expenditure is insufficient to provide adequate SWM services. Major deficiencies were found in all elements of SWM. Despite 70% of the SWM budget being allocated for collection, collection efficiency is around 60-70% for the registered residents and less than 20% for unregistered residents (slum dwellers). The collection process is deficient in terms of manpower and vehicle availability. Bin capacity provided is adequate but locations were found to be inappropriate, thus contributing to the inefficiency of the system. At this time, no treatment is provided to the waste and waste is dumped on open land at Dhapa after collection. Lack of suitable facilities (equipment and infrastructure) and underestimates of waste generation rates, inadequate management and technical skills, improper bin collection, and route planning are responsible for poor collection and transportation of municipal solid wastes.

  19. Flowmeter for gas-entrained solids flow

    DOE Patents [OSTI]

    Porges, Karl G.

    1990-01-01

    An apparatus and method for the measurement of solids feedrate in a gas-entrained solids flow conveyance system. The apparatus and method of the present invention include a vertical duct connecting a source of solids to the gas-entrained flow conveyance system, a control valve positioned in the vertical duct, and a capacitive densitometer positioned along the duct at a location a known distance below the control valved so that the solid feedrate, Q, of the gas entrained flow can be determined by Q=S.rho..phi.V.sub.S where S is the cross sectional area of the duct, .rho. is the density of the solid, .phi. is the solid volume fraction determined by the capacitive densitometer, and v.sub.S is the local solid velocity which can be inferred from the konown distance of the capacitive densitometer below the control valve.

  20. Heating of solid earthen material, measuring moisture and resistivity

    DOE Patents [OSTI]

    Heath, W.O.; Richardson, R.L.; Goheen, S.C.

    1994-07-19

    The present invention includes a method of treating solid earthen material having volatile, semi-volatile, and non-volatile contaminants. Six electrodes are inserted into a region of earthen material to be treated in a substantially equilateral hexagonal arrangement. Six phases of voltages are applied to corresponding electrodes. The voltages are adjusted within a first range of voltages to create multiple current paths between pairs of the electrodes. The current paths are evenly distributed throughout the region defined by the electrodes and therefore uniformly heat the region. The region of earthen material is heated to a temperature sufficient to substantially remove volatile and semi-volatile contaminants by promoting microbial action. This temperature is less than a melting temperature of the earthen material. 13 figs.

  1. Heating of solid earthen material, measuring moisture and resistivity

    DOE Patents [OSTI]

    Heath, William O.; Richardson, Richard L.; Goheen, Steven C.

    1994-01-01

    The present invention includes a method of treating solid earthen material having volatile, semi-volatile, and non-volatile contaminants. Six electrodes are inserted into a region of earthen material to be treated in a substantially equilateral hexagonal arrangement. Six phases of voltages are applied to corresponding electrodes. The voltages are adjusted within a first range of voltages to create multiple current paths between pairs of the electrodes. The current paths are evenly distributed throughout the region defined by the electrodes and therefore uniformly heat the region. The region of earthen material is heated to a temperature sufficient to substantially remove volatile and semi-volatile contaminants by promoting microbial action. This temperature is less than a melting temperature of the earthen material.

  2. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  3. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley; Szreders, Bernard E.

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  4. Method For Reactivating Solid Catalysts Used For Alklation Reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Coates, Kyle; Zalewski, David J.; Fox, Robert V.

    2005-05-03

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  5. Method for reactivating solid catalysts used in alkylation reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Coates, Kyle; Zalewski, David J.; Fox, Robert V.

    2003-06-17

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  6. Element Labs Inc | Open Energy Information

    Open Energy Info (EERE)

    Labs Inc Jump to: navigation, search Name: Element Labs, Inc. Place: Santa Clara, California Zip: 95054 Product: Element Labs is a developer of LED video technology for...

  7. William Fowler and Elements in the Stars

    Office of Scientific and Technical Information (OSTI)

    in physics for his research into the creation of chemical elements inside stars ... . ... reactions--how the nuclei of lighter chemical elements fuse to create the heavier ones ...

  8. Element Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    Element Energy Ltd Jump to: navigation, search Name: Element Energy Ltd. Place: Cambridge, England, United Kingdom Zip: CB1 2JD Product: Cambridge-based strategic energy...

  9. Solid phase microextraction field kit

    DOE Patents [OSTI]

    Nunes, Peter J.; Andresen, Brian D.

    2005-08-16

    A field kit for the collection, isolation and concentration of trace amounts of high explosives (HE), biological weapons (BW) and chemical weapons (CW) residues in air, soil, vegetation, swipe, and liquid samples. The field kit includes a number of Solid Phase Microextraction (SPME) fiber and syringe assemblies in a hermetically sealed transportation container or tubes which includes a sampling port, a number of extra SPME fiber and syringe assemblies, the fiber and syringe assemblies including a protective cap for the fiber, and an extractor for the protective cap, along with other items including spare parts, protective glove, and an instruction manual, all located in an airtight container.

  10. Solid state electrochromic light modulator

    DOE Patents [OSTI]

    Cogan, Stuart F.; Rauh, R. David

    1993-01-01

    An all solid-state variable transmission electrochromic device has a source of charge compensating ions. An inorganic oxide counterelectrode film which on reduction with the accompanying insertion of the charge compensating ions increases its transmission of light of predetermined wavelength is separated from a primary electrochromic film which on reduction with the accompanying insertion of the charge compensating ions decreases its transmission of light of predetermined wavelength by an insulating electrolyte film that transports the charge compensating ions. First and second electrodes are contiguous with the inorganic oxide counter electrode film and the primary electrochromic film, respectively, and separated by the three films.

  11. Solid state electrochromic light modulator

    DOE Patents [OSTI]

    Cogan, Stuart F.; Rauh, R. David

    1993-12-07

    An all solid-state variable transmission electrochromic device has a source of charge compensating ions. An inorganic oxide counterelectrode film which on reduction with the accompanying insertion of the charge compensating ions increases its transmission of light of predetermined wavelength is separated from a primary electrochromic film which on reduction with the accompanying insertion of the charge compensating ions decreases its transmission of light of predetermined wavelength by an insulating electrolyte film that transports the charge compensating ions. First and second electrodes are contiguous with the inorganic oxide counter electrode film and the primary electrochromic film, respectively, and separated by the three films.

  12. Solid-state optical microscope

    DOE Patents [OSTI]

    Young, I.T.

    1981-01-07

    A solid state optical microscope is described wherein wide-field and high-resolution images of an object are produced at a rapid rate by utilizing conventional optics with a charge-coupled photodiode array. Means for scanning in one of two orthogonal directions are provided, while the charge-coupled photodiode array scans in the other orthogonal direction. Illumination light from the object is incident upon the photodiodes, creating packets of electrons (signals) which are representative of the illuminated object. The signals are then processed, stored in a memory, and finally displayed as a video signal.

  13. Solid state electrochromic light modulator

    DOE Patents [OSTI]

    Cogan, Stuart F.; Rauh, R. David

    1990-01-01

    An all solid-state variable transmission electrochromic device has a source of charge compensating ions. An inorganic oxide counterelectrode film which on reduction with the accompanying insertion of the charge compensating ions increases its transmission of light of predetermined wavelength is separated from a primary electrochromic film which on reduction with the accompanying insertion of the charge compensating ions decreases its transmission of light of predetermined wavelength by an insulating electrolyte film that transports the charge compensating ions. First and second electrodes are contiguous with the inorganic oxide counter electrode film and the primary electrochromic film, respectively, and separated by the three films.

  14. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert; George, Raymond A.; Shockling, Larry A.

    1993-01-01

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  15. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  16. Solid state electrochromic light modulator

    DOE Patents [OSTI]

    Cogan, S.F.; Rauh, R.D.

    1990-07-03

    An all solid-state variable transmission electrochromic device has a source of charge compensating ions. An inorganic oxide counter electrode film which on reduction with the accompanying insertion of the charge compensating ions increases its transmission of light of predetermined wavelength is separated from a primary electrochromic film which on reduction with the accompanying insertion of the charge compensating ions decreases its transmission of light of predetermined wavelength by an insulating electrolyte film that transports the charge compensating ions. First and second electrodes are contiguous with the inorganic oxide counter electrode film and the primary electrochromic film, respectively, and separated by the three films. 4 figs.

  17. Solid Oxide Fuel Cell Systems PVL Line

    SciTech Connect (OSTI)

    Susan Shearer - Stark State College; Gregory Rush - Rolls-Royce Fuel Cell Systems

    2012-05-01

    In July 2010, Stark State College (SSC), received Grant DE-EE0003229 from the U.S. Department of Energy (DOE), Golden Field Office, for the development of the electrical and control systems, and mechanical commissioning of a unique 20kW scale high-pressure, high temperature, natural gas fueled Stack Block Test System (SBTS). SSC worked closely with subcontractor, Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) over a 13 month period to successfully complete the project activities. This system will be utilized by RRFCS for pre-commercial technology development and training of SSC student interns. In the longer term, when RRFCS is producing commercial products, SSC will utilize the equipment for workforce training. In addition to DOE Hydrogen, Fuel Cells, and Infrastructure Technologies program funding, RRFCS internal funds, funds from the state of Ohio, and funding from the DOE Solid State Energy Conversion Alliance (SECA) program have been utilized to design, develop and commission this equipment. Construction of the SBTS (mechanical components) was performed under a Grant from the State of Ohio through Ohio's Third Frontier program (Grant TECH 08-053). This Ohio program supported development of a system that uses natural gas as a fuel. Funding was provided under the Department of Energy (DOE) Solid-state Energy Conversion Alliance (SECA) program for modifications required to test on coal synthesis gas. The subject DOE program provided funding for the electrical build, control system development and mechanical commissioning. Performance testing, which includes electrical commissioning, was subsequently performed under the DOE SECA program. Rolls-Royce Fuel Cell Systems is developing a megawatt-scale solid oxide fuel cell (SOFC) stationary power generation system. This system, based on RRFCS proprietary technology, is fueled with natural gas, and operates at elevated pressure. A critical success factor for development of the full scale system is the capability to test fuel cell components at a scale and under conditions that can be accurately extrapolated to full system performance. This requires specially designed equipment that replicates the pressure (up to 6.5 bara), temperature (about 910 C), anode and cathode gas compositions, flows and power generation density of the full scale design. The SBTS fuel cell anode gas is produced through the reaction of pipeline natural gas with a mixture of steam, CO2, and O2 in a catalytic partial oxidation (CPOX) reactor. Production of the fuel cell anode gas in this manner provides the capability to test a fuel cell with varying anode gas compositions ranging from traditional reformed natural gas to a coal-syngas surrogate fuel. Stark State College and RRFCS have a history of collaboration. This is based upon SSCAs commitment to provide students with skills for advanced energy industries, and RRFCS need for a workforce that is skilled in high temperature fuel cell development and testing. A key to this approach is the access of students to unique SOFC test and evaluation equipment. This equipment is designed and developed by RRFCS, with the participation of SSC interns. In the near-term, the equipment will be used by RRFCS for technology development. When this stage is completed, and RRFCS has moved to commercial products, SSC will utilize this equipment for workforce training. The RRFCS fuel cell design is based upon a unique ceramic substrate architecture in which a porous, flat substrate (tube) provides the support structure for a network of solid oxide fuel cells that are electrically connected in series. These tubes are grouped into a {approx}350-tube repeat configuration, called a stack/block. Stack/block testing, performed at system conditions, provides data that can be confidently scaled to full scale performance. This is the basis for the specially designed and developed test equipment that is required for advancing and accelerating the RRFCS SOFC power system development program. All contract DE-EE0003229 objectives were achieved and deliverables completed during the period from March 1, 2010 through March 31, 2011. As a result of program completion, the Stack Block Test System was ready to support installation and electrical operation of a RRFCS solid oxide fuel cell (SOFC) stack block in the second quarter of 2011.

  18. Development of a 100-Watt High Temperature Thermoelectric Generator |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Test results for low and high temperature thermoelectric generators (TEG) those for a 530-watt BiTe TEG; design and construction of a 100-watt high temperature TEG currently in fabrication. PDF icon deer08_lagrandeur.pdf More Documents & Publications Status of Segmented Element Thermoelectric Generator for Vehicle Waste Heat Recovery Status of Segmented Element Thermoelectric Generator for Vehicle Waste Heat Recovery Development of a Scalable 10% Efficient

  19. LOW ACTIVITY WASTE FEED SOLIDS CARACTERIZATION AND FILTERABILITY TESTS

    SciTech Connect (OSTI)

    McCabe, D.; Crawford, C.; Duignan, M.; Williams, M.; Burket, P.

    2014-04-03

    The primary treatment of the tank waste at the DOE Hanford site will be done in the Waste Treatment and Immobilization Plant (WTP) that is currently under construction. The baseline plan for the WTP Pretreatment facility is to treat the waste, splitting it into High Level Waste (HLW) feed and Low Activity Waste (LAW) feed. Both waste streams are then separately vitrified as glass and sealed in canisters. The LAW glass will be disposed onsite in the Integrated Disposal Facility (IDF). There are currently no plans to treat the waste to remove technetium in the WTP Pretreatment facility, so its disposition path is the LAW glass. Options are being explored to immobilize the LAW portion of the tank waste, i.e., the LAW feed from the WTP Pretreatment facility. Removal of {sup 99}Tc from the LAW Feed, followed by off-site disposal of the {sup 99}Tc, would eliminate a key risk contributor for the IDF Performance Assessment (PA) for supplemental waste forms, and has potential to reduce treatment and disposal costs. Washington River Protection Solutions (WRPS) is developing some conceptual flow sheets for LAW treatment and disposal that could benefit from technetium removal. One of these flowsheets will specifically examine removing {sup 99}Tc from the LAW feed stream to supplemental immobilization. The conceptual flow sheet of the {sup 99}Tc removal process includes a filter to remove insoluble solids prior to processing the stream in an ion exchange column, but the characteristics and behavior of the liquid and solid phases has not previously been investigated. This report contains results of testing of a simulant that represents the projected composition of the feed to the Supplemental LAW process. This feed composition is not identical to the aqueous tank waste fed to the Waste Treatment Plant because it has been processed through WTP Pretreatment facility and therefore contains internal changes and recycle streams that will be generated within the WTP process. Although a Supplemental LAW feed simulant has previously been prepared, this feed composition differs from that simulant because those tests examined only the fully soluble aqueous solution at room temperature, not the composition formed after evaporation, including the insoluble solids that precipitate after it cools. The conceptual flow sheet for Supplemental LAW immobilization has an option for removal of {sup 99}Tc from the feed stream, if needed. Elutable ion exchange has been selected for that process. If implemented, the stream would need filtration to remove the insoluble solids prior to processing in an ion exchange column. The characteristics, chemical speciation, physical properties, and filterability of the solids are important to judge the feasibility of the concept, and to estimate the size and cost of a facility. The insoluble solids formed during these tests were primarily natrophosphate, natroxalate, and a sodium aluminosilicate compound. At the elevated temperature and 8 M [Na+], appreciable insoluble solids (1.39 wt%) were present. Cooling to room temperature and dilution of the slurry from 8 M to 5 M [Na+] resulted in a slurry containing 0.8 wt% insoluble solids. The solids (natrophosphate, natroxalate, sodium aluminum silicate, and a hydrated sodium phosphate) were relatively stable and settled quickly. Filtration rates were in the range of those observed with iron-based simulated Hanford tank sludge simulants, e.g., 6 M [Na+] Hanford tank 241-AN-102, even though their chemical speciation is considerably different. Chemical cleaning of the crossflow filter was readily accomplished with acid. As this simulant formulation was based on an average composition of a wide range of feeds using an integrated computer model, this exact composition may never be observed. But the test conditions were selected to enable comparison to the model to enable improving its chemical prediction capability.

  20. Filter unit for use at high temperatures

    DOE Patents [OSTI]

    Ciliberti, David F.; Lippert, Thomas E.

    1988-01-01

    A filtering unit for filtering particulates from high temperature gases uses a spiral ceramic spring to bias a ceramic, tubular filter element into sealing contact with a flange about an aperture of a metallic tube sheet. The ceramic spiral spring may contact the upper edge of the filter element and be restrained by a stop member spaced from one end of the tube sheet, or the spring may contact the bottom of the filter element and be restrained by a support member spaced from the opposite end of the tube sheet. The stop member and support member are adjustably secured to the tube sheet. A filtering system uses the ceramic spiral spring to bias a plurality of ceramic, tubular filter elements in a respective plurality of apertures in a tube sheet which divides a vessel into upper and lower enclosed sections.

  1. Solid state division progress report, period ending February 29, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-09-01

    Research is reported concerning theoretical solid state physics; surface and near-surface properties of solids; defects in solids; transport properties of solids; neutron scattering; crystal growth and characterization; and isotope research materials.

  2. Quadrilateral finite element mesh coarsening

    DOE Patents [OSTI]

    Staten, Matthew L; Dewey, Mark W; Benzley, Steven E

    2012-10-16

    Techniques for coarsening a quadrilateral mesh are described. These techniques include identifying a coarsening region within the quadrilateral mesh to be coarsened. Quadrilateral elements along a path through the coarsening region are removed. Node pairs along opposite sides of the path are identified. The node pairs along the path are then merged to collapse the path.

  3. FOIL ELEMENT FOR NUCLEAR REACTOR

    DOE Patents [OSTI]

    Noland, R.A.; Walker, D.E.; Spinrad, B.I.

    1963-07-16

    A method of making a foil-type fuel element is described. A foil of fuel metal is perforated in; regular design and sheets of cladding metal are placed on both sides. The cladding metal sheets are then spot-welded to each other through the perforations, and the edges sealed. (AEC)

  4. Superheavy Elements - Achievements and Challenges

    SciTech Connect (OSTI)

    Ackermann, Dieter

    2009-03-04

    The search for superheavy elements (SHE) has yielded exciting results for both the 'cold fusion' approach with reactions employing Pb and Bi targets and the ''hot fusion'' reactions with {sup 48}Ca beams on actinide targets. The most recent activities at GSI were the successful production of a more neutron rich isotope of element 112 in the reaction {sup 48}Ca+{sup 238}U confirming earlier result from FLNR, and the attempt to synthesize an isotope with Z 120 in the reaction {sup 64}Ni+{sup 238}U. Apart from the synthesis of new elements, advanced nuclear structure studies for heavy and super heavy elements promise a detailed insight in the properties of nuclear matter under the extreme conditions of high Z and A. The means are evaporation residue(ER)-{alpha}-{alpha} and -{alpha}-{gamma} coincidence techniques applied after separation of the reaction products from the beam. Recent examples of interesting physics to be discovered in this region of the chart of nuclides are the investigation of K-isomers observed for {sup 252,254}No and indicated for {sup 270}Ds. Fast chemistry and precision mass measurements deliver in addition valuable information on the fundamental properties of the SHE.

  5. Single element laser beam shaper

    DOE Patents [OSTI]

    Zhang, Shukui (Yorktown, VA); Michelle D. Shinn (Newport News, VA)

    2005-09-13

    A single lens laser beam shaper for converting laser beams from any spatial profile to a flat-top or uniform spatial profile. The laser beam shaper includes a lens having two aspheric surfaces. The beam shaper significantly simplifies the overall structure in comparison with conventional 2-element systems and therefore provides great ease in alignment and reduction of cost.

  6. Infrared trace element detection system

    DOE Patents [OSTI]

    Bien, F.; Bernstein, L.S.; Matthew, M.W.

    1988-11-15

    An infrared trace element detection system includes an optical cell into which the sample fluid to be examined is introduced and removed. Also introduced into the optical cell is a sample beam of infrared radiation in a first wavelength band which is significantly absorbed by the trace element and a second wavelength band which is not significantly absorbed by the trace element for passage through the optical cell through the sample fluid. The output intensities of the sample beam of radiation are selectively detected in the first and second wavelength bands. The intensities of a reference beam of the radiation are similarly detected in the first and second wavelength bands. The sensed output intensity of the sample beam in one of the first and second wavelength bands is normalized with respect to the other and similarly, the intensity of the reference beam of radiation in one of the first and second wavelength bands is normalized with respect to the other. The normalized sample beam intensity and normalized reference beam intensity are then compared to provide a signal from which the amount of trace element in the sample fluid can be determined. 11 figs.

  7. Fast acting multiple element valve

    DOE Patents [OSTI]

    Yang, Jefferson Y. S.; Wada, James M.

    1991-01-01

    A plurality of slide valve elements having plural axial-spaced annular parts and an internal slide are inserted into a bulkhead in a fluid conduit from a downstream side of the bulkhead, locked in place by a bayonet coupling and set screw, and project through the bulkhead into the upstream conduit. Pneumatic lines connecting the slide valve element actuator to pilot valves are brought out the throat of the valve element to the downstream side. Pilot valves are radially spaced around the exterior of the valve to permit the pneumatic lines to be made identical, thereby to minimize adverse timing tolerances in operation due to pressure variations. Ring manifolds surround the valve adjacent respective pilot valve arrangements to further reduce adverse timing tolerances due to pressure variations, the manifolds being directly connected to the respective pilot valves. Position sensors are provided the valve element slides to signal the precise time at which a slide reaches or passes through a particular point in its stroke to initiate a calibrated timing function.

  8. Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized by sputter deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    An, Zhinan; Jia, Haoling; Wu, Yueying; Rack, Philip D.; Patchen, Allan D.; Liu, Yuzi; Ren, Yang; Li, Nan; Liaw, Peter K.

    2015-05-04

    The concept of high configurational entropy requires that the high-entropy alloys (HEAs) yield single-phase solid solutions. However, phase separations are quite common in bulk HEAs. A five-element alloy, CrCoCuFeNi, was deposited via radio frequency magnetron sputtering and confirmed to be a single-phase solid solution through the high-energy synchrotron X-ray diffraction, energy-dispersive spectroscopy, wavelength-dispersive spectroscopy, and transmission electron microscopy. The formation of the solid-solution phase is presumed to be due to the high cooling rate of the sputter-deposition process.

  9. Final Hanford Site Solid (Radioactive and Hazardous) Waste Program...

    Office of Environmental Management (EM)

    Site Solid (Radioactive and Hazardous) Waste Program Environmental Impact Statement, ... Site Solid (Radioactive and Hazardous) Waste Program Environmental Impact Statement ...

  10. SOLID STATE ENERGY CONVERSION ALLIANCE DELPHI SOLID OXIDE FUEL CELL

    SciTech Connect (OSTI)

    Steven Shaffer; Sean Kelly; Subhasish Mukerjee; David Schumann; Gail Geiger; Kevin Keegan; Larry Chick

    2004-05-07

    The objective of this project is to develop a 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. During Phase I, the following will be accomplished: Develop and demonstrate technology transfer efforts on a 5 kW stationary distributed power generation system that incorporates steam reforming of natural gas with the option of piped-in water (Demonstration System A). Initiate development of a 5 kW system for later mass-market automotive auxiliary power unit application, which will incorporate Catalytic Partial Oxidation (CPO) reforming of gasoline, with anode exhaust gas injected into an ultra-lean burn internal combustion engine. This technical progress report covers work performed by Delphi from July 1, 2003 to December 31, 2003, under Department of Energy Cooperative Agreement DE-FC-02NT41246. This report highlights technical results of the work performed under the following tasks: Task 1 System Design and Integration; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant (BOP) Components; Task 5 Manufacturing Development (Privately Funded); Task 6 System Fabrication; Task 7 System Testing; Task 8 Program Management; Task 9 Stack Testing with Coal-Based Reformate; and Task 10 Technology Transfer from SECA CORE Technology Program. In this reporting period, unless otherwise noted Task 6--System Fabrication and Task 7--System Testing will be reported within Task 1 System Design and Integration. Task 8--Program Management, Task 9--Stack Testing with Coal Based Reformate, and Task 10--Technology Transfer from SECA CORE Technology Program will be reported on in the Executive Summary section of this report.

  11. The Transuranium Elements - Present Status: Nobel Lecture

    DOE R&D Accomplishments [OSTI]

    Seaborg, G. T.

    1951-12-12

    The discovery of the transuranium elements and the work done on them up to the present time are reviewed. The properties of these elements, their relationship to other elements, their place in the periodic table, and the possibility of production and identification of other transuranium elements are discussed briefly.

  12. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, Michael P.; Overmyer, Donald L.; Dominguez, Frank

    1998-01-01

    A system for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source.

  13. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, M.P.; Overmyer, D.L.; Dominguez, F.

    1998-12-22

    A system is disclosed for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source. 3 figs.

  14. Process for removing copper in a recoverable form from solid scrap metal

    DOE Patents [OSTI]

    Hartman, Alan D.; Oden, Laurance L.; White, Jack C.

    1995-01-01

    A process for removing copper in a recoverable form from a copper/solid ferrous scrap metal mix is disclosed. The process begins by placing a copper/solid ferrous scrap metal mix into a reactor vessel. The atmosphere within the reactor vessel is purged with an inert gas or oxidizing while the reactor vessel is heated in the area of the copper/solid ferrous scrap metal mix to raise the temperature within the reactor vessel to a selected elevated temperature. Air is introduced into the reactor vessel and thereafter hydrogen chloride is introduced into the reactor vessel to obtain a desired air-hydrogen chloride mix. The air-hydrogen chloride mix is operable to form an oxidizing and chloridizing atmosphere which provides a protective oxide coating on the surface of the solid ferrous scrap metal in the mix and simultaneously oxidizes/chloridizes the copper in the mix to convert the copper to a copper monochloride gas for transport away from the solid ferrous scrap metal. After the copper is completely removed from the copper/solid ferrous scrap metal mix, the flows of air and hydrogen chloride are stopped and the copper monochloride gas is collected for conversion to a recoverable copper species.

  15. Solid-oxide fuel cell electrolyte

    DOE Patents [OSTI]

    Bloom, Ira D.; Hash, Mark C.; Krumpelt, Michael

    1993-01-01

    A solid-oxide electrolyte operable at between 600.degree. C. and 800.degree. C. and a method of producing the solid-oxide electrolyte are provided. The solid-oxide electrolyte comprises a combination of a compound having weak metal-oxygen interactions with a compound having stronger metal-oxygen interactions whereby the resulting combination has both strong and weak metal-oxygen interaction properties.

  16. Method of manufacturing a high temperature superconductor with improved transport properties

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Siegel, Richard W.; Askew, Thomas R.

    2001-01-01

    A method of preparing a high temperature superconductor. A method of preparing a superconductor includes providing a powdered high temperature superconductor and a nanophase paramagnetic material. These components are combined to form a solid compacted mass with the paramagnetic material disposed on the grain boundaries of the polycrystaline high temperature superconductor.

  17. Permeability computation on a REV with an immersed finite element method

    SciTech Connect (OSTI)

    Laure, P. [Laboratoire J.-A. Dieudonne, CNRS UMR 6621, Universite de Nice-Sophia Antipolis, Parc Valrose, 06108 Nice, Cedex 02 (France); Puaux, G.; Silva, L.; Vincent, M. [MINES ParisTech, CEMEF-Centre de Mise en Forme des Materiaux, CNRS UMR 7635, BP 207 1 rue Claude, Daunesse 06904 Sophia Antipolis cedex (France)

    2011-05-04

    An efficient method to compute permeability of fibrous media is presented. An immersed domain approach is used to represent the porous material at its microscopic scale and the flow motion is computed with a stabilized mixed finite element method. Therefore the Stokes equation is solved on the whole domain (including solid part) using a penalty method. The accuracy is controlled by refining the mesh around the solid-fluid interface defined by a level set function. Using homogenisation techniques, the permeability of a representative elementary volume (REV) is computed. The computed permeabilities of regular fibre packings are compared to classical analytical relations found in the bibliography.

  18. The Origin of the Elements

    ScienceCinema (OSTI)

    Murphy, Edward

    2014-08-06

    The world around us is made of atoms. Did you ever wonder where these atoms came from? How was the gold in our jewelry, the carbon in our bodies, and the iron in our cars made? In this lecture, we will trace the origin of a gold atom from the Big Bang to the present day, and beyond. You will learn how the elements were forged in the nuclear furnaces inside stars, and how, when they die, these massive stars spread the elements into space. You will learn about the origin of the building blocks of matter in the Big Bang, and we will speculate on the future of the atoms around us today.

  19. Element of an inductive coupler

    DOE Patents [OSTI]

    Hall, David R.; Fox, Joe

    2006-08-15

    An element for an inductive coupler in a downhole component comprises magnetically conductive material, which is disposed in a recess in annular housing. The magnetically conductive material forms a generally circular trough. The circular trough comprises an outer generally U-shaped surface, an inner generally U-shaped surface, and two generally planar surfaces joining the inner and outer surfaces. The element further comprises pressure relief grooves in at least one of the surfaces of the circular trough. The pressure relief grooves may be scored lines. Preferably the pressure relief grooves are parallel to the magnetic field generated by the magnetically conductive material. The magnetically conductive material is selected from the group consisting of soft iron, ferrite, a nickel iron alloy, a silicon iron alloy, a cobalt iron alloy, and a mu-metal. Preferably, the annular housing is a metal ring.

  20. The Origin of the Elements

    SciTech Connect (OSTI)

    Murphy, Edward

    2012-11-20

    The world around us is made of atoms. Did you ever wonder where these atoms came from? How was the gold in our jewelry, the carbon in our bodies, and the iron in our cars made? In this lecture, we will trace the origin of a gold atom from the Big Bang to the present day, and beyond. You will learn how the elements were forged in the nuclear furnaces inside stars, and how, when they die, these massive stars spread the elements into space. You will learn about the origin of the building blocks of matter in the Big Bang, and we will speculate on the future of the atoms around us today.

  1. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C.; Besecker, Charles J.; Chen, Hancun; Robinson, Earil T.

    2007-06-12

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  2. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-11-21

    A fuel element is designed which is particularly adapted for reactors of high power density used to generate steam for the production of electricity. The fuel element consists of inner and outer concentric tubes forming an annular chamber within which is contained fissionable fuel pellet segments, wedge members interposed between the fuel segments, and a spring which, acting with wedge members, urges said fuel pellets radially into contact against the inner surface of the outer tube. The wedge members may be a fertile material convertible into fissionable fuel material by absorbing neutrons emitted from the fissionable fuel pellet segments. The costly grinding of cylindrical fuel pellets to close tolerances for snug engagement is reduced because the need to finish the exact size is eliminated. (AEC)

  3. Solid phase sequencing of biopolymers

    DOE Patents [OSTI]

    Cantor, Charles; Koster, Hubert

    2010-09-28

    This invention relates to methods for detecting and sequencing target nucleic acid sequences, to mass modified nucleic acid probes and arrays of probes useful in these methods, and to kits and systems which contain these probes. Useful methods involve hybridizing the nucleic acids or nucleic acids which represent complementary or homologous sequences of the target to an array of nucleic acid probes. These probes comprise a single-stranded portion, an optional double-stranded portion and a variable sequence within the single-stranded portion. The molecular weights of the hybridized nucleic acids of the set can be determined by mass spectroscopy, and the sequence of the target determined from the molecular weights of the fragments. Nucleic acids whose sequences can be determined include DNA or RNA in biological samples such as patient biopsies and environmental samples. Probes may be fixed to a solid support such as a hybridization chip to facilitate automated molecular weight analysis and identification of the target sequence.

  4. Solid phase sequencing of biopolymers

    DOE Patents [OSTI]

    Cantor, Charles R.; Hubert, Koster

    2014-06-24

    This invention relates to methods for detecting and sequencing target nucleic acid sequences, to mass modified nucleic acid probes and arrays of probes useful in these methods, and to kits and systems which contain these probes. Useful methods involve hybridizing the nucleic acids or nucleic acids which represent complementary or homologous sequences of the target to an array of nucleic acid probes. These probes comprise a single-stranded portion, an optional double-stranded portion and a variable sequence within the single-stranded portion. The molecular weights of the hybridized nucleic acids of the set can be determined by mass spectroscopy, and the sequence of the target determined from the molecular weights of the fragments. Probes may be affixed to a solid support such as a hybridization chip to facilitate automated molecular weight analysis and identification of the target sequence.

  5. Trace-element zoning in garnets from sheared mantle xenoliths

    SciTech Connect (OSTI)

    Griffin, W.L.; Cousens, D.R.; Ryan, C.G.; Sie, S.H.; Suter, G.F. ); Smith, D. ); Boyd, F.R. )

    1989-02-01

    Proton-microprobe analyses of garnets from sheared high-temperature ultramafic xenoliths reveal marked zonation of trace elements, paralleling trends in major and minor elements. Garnet rims (600-1,000 {mu}m wide) are enriched in Fe, Ti, Zr, Y and Ga, and either enriched or depleted in Cr, relative to cores. Zoning profiles for Ti and Zr are S-shaped and extend further into the grains than the Cr and Ga gradients. The profiles are consistent with the formation of Ti, Zr, Y-enriched garnet overgrowths, followed by diffusive equilibration between rim and core over years to hundreds of years. This enrichment in Fe, Ca, Al and incompatible elements is ascribed to melt infiltration and consequent melt-crystal exchange and garnet growth, shortly before eruption. Zr/Y is 1 to 2 in garnet cores but 4 to 5 in rims, and so the infiltrating melt may have been relatively alkalic. Major and trace element concentrations in such high-temperature sheared xenoliths are not likely to resemble those of primitive mantle or of residual mantle depleted by melt extraction.

  6. 2.10 Heavy Element Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 6/1/2011 2.10 Heavy Element Chemistry For more than 50 years, the Office of Science and predecessor agencies have supported the discovery and study of the actinide elements, in particular the transuranium elements-atoms that are heavier than uranium. Glenn Seaborg and Ed McMillan of the Lawrence Berkeley National Laboratory, 1951 Nobel Laureates in Chemistry for the discovery of plutonium and other actinide elements, began this quest. Today, the Heavy Element Chemistry program continues the

  7. Photoconductive circuit element pulse generator

    DOE Patents [OSTI]

    Rauscher, Christen

    1989-01-01

    A pulse generator for characterizing semiconductor devices at millimeter wavelength frequencies where a photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test.

  8. Thermal Expansion in the Garnet-Type Solid Electrolyte

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Li7-xAlx/3)La3Zr2O12 as a Function of Al Content - Joint Center for Energy Storage Research September 25, 2015, Research Highlights Thermal Expansion in the Garnet-Type Solid Electrolyte (Li7-xAlx/3)La3Zr2O12 as a Function of Al Content Evolution of the lattice constant as a function of temperature with the evolution of the (211) peak of cubic (Li6.1Al0.3)La3Zr2O12 during heating (inset). Scientific Achievement The study identified the lattice expansion lithium lanthanum zirconium oxide

  9. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect (OSTI)

    Kojda, Danny [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universitt Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  10. Method for joining metal by solid-state bonding

    DOE Patents [OSTI]

    Burkhart, L. Elkin; Fultz, Chester R.; Maulden, Kerry A.

    1979-01-01

    The present development is directed to a method for joining metal at relatively low temperatures by solid-state bonding. Planar surfaces of the metal workpieces are placed in a parallel abutting relationship with one another. A load is applied to at least one of the workpieces for forcing the workpieces together while one of the workpieces is relatively slowly oscillated in a rotary motion over a distance of about 1.degree.. After a preselected number of oscillations, the rotary motion is terminated and the bond between the abutting surfaces is effected. An additional load may be applied to facilitate the bond after terminating the rotary motion.

  11. Solid electrolyte material manufacturable by polymer processing...

    Office of Scientific and Technical Information (OSTI)

    An exemplary material can include material components made of diblock polymers or triblock polymers. Many uses are contemplated for the solid polymer electrolyte materials. For ...

  12. Solid State Gas Sensors - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Solid State Gas Sensors Los Alamos National Laboratory Contact LANL About This Technology LANLs...

  13. Solid-State Lighting Technical Reports

    SciTech Connect (OSTI)

    2011-12-16

    A page that contains links to technical reports of studies estimating the energy savings potential of solid-state lighting in numerous applications.

  14. Solid flexible electrochemical supercapacitor using Tobacco mosaic...

    Office of Scientific and Technical Information (OSTI)

    mosaic virus nanostructures and ALD ruthenium oxide Citation Details In-Document Search Title: Solid flexible electrochemical supercapacitor using Tobacco mosaic virus ...

  15. MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; SOLID STATE...

    Office of Scientific and Technical Information (OSTI)

    Open problems in condensed matter physics, 1987 Falicov, L.M. 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; SOLID STATE PHYSICS; RESEARCH PROGRAMS;...

  16. Design of Nanocrystal Solids for Photoelectrochemical Synthesis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Design of Nanocrystal Solids for Photoelectrochemical Synthesis of Liquid Fuels The proposed research project seeks to exploit the unique size-, composition-, and surface-tunable...

  17. NREL: Energy Sciences - Solid-State Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Printable Version Solid-State Theory Image showing a roughly spherical red shape that looks like an apple that is floating within a yellow hemispherical shell....

  18. Solid Waste Program Website | Open Energy Information

    Open Energy Info (EERE)

    Waste Program Website Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Solid Waste Program Website Author Alaska Division of Environmental Health...

  19. Dissolution of Danazol Amorphous Solid Dispersions: Supersaturation...

    Office of Scientific and Technical Information (OSTI)

    Dissolution of Danazol Amorphous Solid Dispersions: Supersaturation and Phase Behavior as a Function of Drug Loading and Polymer Type Citation Details In-Document Search Title: ...

  20. High temperature thermoelectrics

    DOE Patents [OSTI]

    Moczygemba, Joshua E.; Biershcenk, James L.; Sharp, Jeffrey W.

    2014-09-23

    In accordance with one embodiment of the present disclosure, a thermoelectric device includes a plurality of thermoelectric elements that each include a diffusion barrier. The diffusion barrier includes a refractory metal. The thermoelectric device also includes a plurality of conductors coupled to the plurality of thermoelectric elements. The plurality of conductors include aluminum. In addition, the thermoelectric device includes at least one plate coupled to the plurality of thermoelectric elements using a braze. The braze includes aluminum.

  1. Peridynamic Multiscale Finite Element Methods

    SciTech Connect (OSTI)

    Costa, Timothy; Bond, Stephen D.; Littlewood, David John; Moore, Stan Gerald

    2015-12-01

    The problem of computing quantum-accurate design-scale solutions to mechanics problems is rich with applications and serves as the background to modern multiscale science research. The prob- lem can be broken into component problems comprised of communicating across adjacent scales, which when strung together create a pipeline for information to travel from quantum scales to design scales. Traditionally, this involves connections between a) quantum electronic structure calculations and molecular dynamics and between b) molecular dynamics and local partial differ- ential equation models at the design scale. The second step, b), is particularly challenging since the appropriate scales of molecular dynamic and local partial differential equation models do not overlap. The peridynamic model for continuum mechanics provides an advantage in this endeavor, as the basic equations of peridynamics are valid at a wide range of scales limiting from the classical partial differential equation models valid at the design scale to the scale of molecular dynamics. In this work we focus on the development of multiscale finite element methods for the peridynamic model, in an effort to create a mathematically consistent channel for microscale information to travel from the upper limits of the molecular dynamics scale to the design scale. In particular, we first develop a Nonlocal Multiscale Finite Element Method which solves the peridynamic model at multiple scales to include microscale information at the coarse-scale. We then consider a method that solves a fine-scale peridynamic model to build element-support basis functions for a coarse- scale local partial differential equation model, called the Mixed Locality Multiscale Finite Element Method. Given decades of research and development into finite element codes for the local partial differential equation models of continuum mechanics there is a strong desire to couple local and nonlocal models to leverage the speed and state of the art of local models with the flexibility and accuracy of the nonlocal peridynamic model. In the mixed locality method this coupling occurs across scales, so that the nonlocal model can be used to communicate material heterogeneity at scales inappropriate to local partial differential equation models. Additionally, the computational burden of the weak form of the peridynamic model is reduced dramatically by only requiring that the model be solved on local patches of the simulation domain which may be computed in parallel, taking advantage of the heterogeneous nature of next generation computing platforms. Addition- ally, we present a novel Galerkin framework, the 'Ambulant Galerkin Method', which represents a first step towards a unified mathematical analysis of local and nonlocal multiscale finite element methods, and whose future extension will allow the analysis of multiscale finite element methods that mix models across scales under certain assumptions of the consistency of those models.

  2. Method of monitoring stored nuclear fuel elements

    SciTech Connect (OSTI)

    Borloo, E.; Buergers, W.; Crutzen, S.; Vinche, C.

    1983-05-24

    To monitor a nuclear fuel element or fuel elements located in a store, e.g. a pond in a swimming pool reactor, the store is illuminated ultrasonically using one or more transducers transmitting ultrasonic signals in one or more predetermined directions to obtain an output which, because it depends on the number and relative location of the fuel elements in the store, and the structure of the store itself is distinctive to the fuel elements or elements stored therein. From this distinctive output is derived an identity unique to the stored fuel element or elements and a reference signal indicative of the whole structure when intact, the reference signal and identity being recorded. Subsequent ultrasonic testing of the store and its contents under identical operating conditions produces a signal which is compared to the recorded reference signal and if different therefrom reveals the occurrence of tampering with the store and/or the fuel element or elements.

  3. Nonisothermal particle modeling of municipal solid waste combustion with heavy metal vaporization

    SciTech Connect (OSTI)

    Mazza, G.; Falcoz, Q.; Gauthier, D.; Flamant, G.; Soria, J.

    2010-12-15

    A particulate model was developed for municipal solid-waste incineration in a fluidized bed combining solid-waste-particle combustion and heavy metal vaporization from the burning particles. Based on a simpler, isothermal version presented previously, this model combines an asymptotic-combustion model for carbonaceous-solid combustion and a shrinking-core model to describe the heavy metal vaporization phenomenon, in which the particle is now considered nonisothermal. A parametric study is presented that shows the influence of temperature on the global metal-vaporization process. The simulation results are compared to experimental data obtained with a lab-scale fluid bed incinerator and to the results of the simpler isothermal model. It is shown that conduction in the particle strongly affects the variation of the vaporization rate with time and that the present version of the model well fits both the shape of the plots and the maximum heavy metal vaporization rates for all bed temperatures. (author)

  4. Co-firing coal and municipal solid waste

    SciTech Connect (OSTI)

    Demirbas, A.

    2008-07-01

    The aim of this study was to experimentally investigate how different the organic fraction of municipal solid waste (OFMSW) or municipal solid waste (MSW) utilizing strategies affects the gas emission in simple fluidized bed combustion (FBC) of biomass. In this study, ground OFMSW and pulverized coal (PC) were used for co-firing tests. The tests were carried out in a bench-scale bubbling FBC. Coal and bio-waste fuels are quite different in composition. Ash composition of the bio-waste fuels is fundamentally different from ash composition of the coal. Chlorine (Cl) in the MSW may affect operation by corrosion. Ash deposits reduce heat transfer and also may result in severe corrosion at high temperatures. Nitrogen (N) and carbon ) assessments can play an important role in a strategy to control carbon dioxide (CO{sub 2}) and nitrogen oxide (NOx) emissions while raising revenue. Regulations such as subsidies for oil, liquid petroleum gas (LPG) for natural gas powered vehicles, and renewables, especially biomass lines, to reduce emissions may be more cost-effective than assessments. Research and development (RD) resources are driven by energy policy goals and can change the competitiveness of renewables, especially solid waste. The future supply of co-firing depends on energy prices and technical progress, both of which are driven by energy policy priorities.

  5. Method and apparatus for assembling solid oxide fuel cells

    DOE Patents [OSTI]

    Szreders, B.E.; Campanella, N.

    1988-05-11

    This invention relates generally to solid oxide fuel power generators and is particularly directed to improvements in the assembly and coupling of solid oxide fuel cell modules. A plurality of jet air tubes are supported and maintained in a spaced matrix array by a positioning/insertion assembly for insertion in respective tubes of a solid oxide fuel cell (SOFC) in the assembly of an SOFC module. The positioning/insertion assembly includes a plurality of generally planar, elongated, linear vanes which are pivotally mounted at each end thereof to a support frame. A rectangular compression assembly of adjustable size is adapted to receive and squeeze a matrix of SOFC tubes so as to compress the inter-tube nickel felt conductive pads which provide series/parallel electrical connection between adjacent SOFCs, with a series of increasingly larger retainer frames used to maintain larger matrices of SOFC tubes in position. Expansion of the SOFC module housing at the high operating temperatures of the SOFC is accommodated by conductive, flexible, resilient expansion, connector bars which provide support and electrical coupling at the top and bottom of the SOFC module housing. 17 figs.

  6. Calculation of binary phase diagrams between the actinide elements, rare earth elements, and transition metal elements

    SciTech Connect (OSTI)

    Selle, J E

    1992-06-26

    Attempts were made to apply the Kaufman method of calculating binary phase diagrams to the calculation of binary phase diagrams between the rare earths, actinides, and the refractory transition metals. Difficulties were encountered in applying the method to the rare earths and actinides, and modifications were necessary to provide accurate representation of known diagrams. To calculate the interaction parameters for rare earth-rare earth diagrams, it was necessary to use the atomic volumes for each of the phases: liquid, body-centered cubic, hexagonal close-packed, and face-centered cubic. Determination of the atomic volumes of each of these phases for each element is discussed in detail. In some cases, empirical means were necessary. Results are presented on the calculation of rare earth-rare earth, rare earth-actinide, and actinide-actinide diagrams. For rare earth-refractory transition metal diagrams and actinide-refractory transition metal diagrams, empirical means were required to develop values for the enthalpy of vaporization for rare earth elements and values for the constant (C) required when intermediate phases are present. Results of using the values determined for each element are presented.

  7. Influence of chemical disorder on energy dissipation and defect evolution in concentrated solid solution alloys

    SciTech Connect (OSTI)

    Zhang, Yanwen; Stocks, George Malcolm; Jin, Ke; Lu, Chenyang; Bei, Hongbin; Sales, Brian C.; Wang, Lumin; Béland, Laurent K.; Stoller, Roger E.; Samolyuk, German D.; Caro, Magdalena; Caro, Alfredo; Weber, William J.

    2015-10-28

    A long-standing objective in materials research is to understand how energy is dissipated in both the electronic and atomic subsystems in irradiated materials, and how related non-equilibrium processes may affect defect dynamics and microstructure evolution. Here we show that alloy complexity in concentrated solid solution alloys having both an increasing number of principal elements and altered concentrations of specific elements can lead to substantial reduction in the electron mean free path and thermal conductivity, which has a significant impact on energy dissipation and consequentially on defect evolution during ion irradiation. Enhanced radiation resistance with increasing complexity from pure nickel to binary and to more complex quaternary solid solutions is observed under ion irradiation up to an average damage level of 1 displacement per atom. Understanding how materials properties can be tailored by alloy complexity and their influence on defect dynamics may pave the way for new principles for the design of radiation tolerant structural alloys.

  8. User's manuals for DYNA3D and DYNAP: nonlinear dynamic analysis of solids in three dimensions

    SciTech Connect (OSTI)

    Hallquist, J.O.

    1981-07-01

    This report provides a user's manual for DYNA3D, an explicit three-dimensional finite element code for analyzing the large deformation dynamic response of inelastic solids. A contact-impact algorithm permits gaps and sliding along material interfaces. By a specialization of this algorithm, such interfaces can be rigidly tied to admit variable zoning without the need of transition regions. Spatial discretization is achieved by the use of 8-node solid elements, and the equations-of-motion are integrated by the central difference method. Post-processors for DYNA3D include GRAPE for plotting deformed shapes and stress contours and DYNAP for plotting time histories. A user's manual for DYNAP is also provided in this report.

  9. Vacuum encapsulated, high temperature diamond amplified cathode capsule and method for making same

    SciTech Connect (OSTI)

    Rao, Triveni; Walsh, Josh; Gangone, Elizabeth

    2015-12-29

    A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first high-temperature solder weld disposed between the diamond window element and the annular insulating spacer and a second high-temperature solder weld disposed between the annular insulating spacer and the cathode element. The cathode capsule is formed by a high temperature weld process under vacuum such that the first solder weld forms a hermetical seal between the diamond window element and the annular insulating spacer and the second solder weld forms a hermetical seal between the annular spacer and the cathode element whereby a vacuum encapsulated chamber is formed within the capsule.

  10. System for conversion between the boundary representation model and a constructive solid geometry model of an object

    DOE Patents [OSTI]

    Christensen, Noel C.; Emery, James D.; Smith, Maurice L.

    1988-04-05

    A system converts from the boundary representation of an object to the constructive solid geometry representation thereof. The system converts the boundary representation of the object into elemental atomic geometrical units or I-bodies which are in the shape of stock primitives or regularized intersections of stock primitives. These elemental atomic geometrical units are then represented in symbolic form. The symbolic representations of the elemental atomic geometrical units are then assembled heuristically to form a constructive solid geometry representation of the object usable for manufacturing thereof. Artificial intelligence is used to determine the best constructive solid geometry representation from the boundary representation of the object. Heuristic criteria are adapted to the manufacturing environment for which the device is to be utilized. The surface finish, tolerance, and other information associated with each surface of the boundary representation of the object are mapped onto the constructive solid geometry representation of the object to produce an enhanced solid geometry representation, particularly useful for computer-aided manufacture of the object.

  11. System for conversion between the boundary representation model and a constructive solid geometry model of an object

    DOE Patents [OSTI]

    Christensen, N.C.; Emery, J.D.; Smith, M.L.

    1985-04-29

    A system converts from the boundary representation of an object to the constructive solid geometry representation thereof. The system converts the boundary representation of the object into elemental atomic geometrical units or I-bodies which are in the shape of stock primitives or regularized intersections of stock primitives. These elemental atomic geometrical units are then represented in symbolic form. The symbolic representations of the elemental atomic geometrical units are then assembled heuristically to form a constructive solid geometry representation of the object usable for manufacturing thereof. Artificial intelligence is used to determine the best constructive solid geometry representation from the boundary representation of the object. Heuristic criteria are adapted to the manufacturing environment for which the device is to be utilized. The surface finish, tolerance, and other information associated with each surface of the boundary representation of the object are mapped onto the constructive solid geometry representation of the object to produce an enhanced solid geometry representation, particularly useful for computer-aided manufacture of the object. 19 figs.

  12. Heat exchanger with ceramic elements

    DOE Patents [OSTI]

    Corey, John A.

    1986-01-01

    An annular heat exchanger assembly includes a plurality of low thermal growth ceramic heat exchange members with inlet and exit flow ports on distinct faces. A mounting member locates each ceramic member in a near-annular array and seals the flow ports on the distinct faces into the separate flow paths of the heat exchanger. The mounting member adjusts for the temperature gradient in the assembly and the different coefficients of thermal expansion of the members of the assembly during all operating temperatures.

  13. High Temperature ESP Monitoring

    Broader source: Energy.gov [DOE]

    The purpose of the High Temperature ESP Monitoring project is to develop a down-hole monitoring system to be used in wells with bottom hole temperature up to 300 °C for measuring motor temperature; pump discharge pressure; and formation temperature and pressure.

  14. Cooled, temperature controlled electrometer

    DOE Patents [OSTI]

    Morgan, John P.

    1992-08-04

    A cooled, temperature controlled electrometer for the measurement of small currents. The device employs a thermal transfer system to remove heat from the electrometer circuit and its environment and dissipate it to the external environment by means of a heat sink. The operation of the thermal transfer system is governed by a temperature regulation circuit which activates the thermal transfer system when the temperature of the electrometer circuit and its environment exceeds a level previously inputted to the external variable temperature control circuit. The variable temperature control circuit functions as subpart of the temperature control circuit. To provide temperature stability and uniformity, the electrometer circuit is enclosed by an insulated housing.

  15. Cooled, temperature controlled electrometer

    DOE Patents [OSTI]

    Morgan, John P.

    1992-01-01

    A cooled, temperature controlled electrometer for the measurement of small currents. The device employs a thermal transfer system to remove heat from the electrometer circuit and its environment and dissipate it to the external environment by means of a heat sink. The operation of the thermal transfer system is governed by a temperature regulation circuit which activates the thermal transfer system when the temperature of the electrometer circuit and its environment exceeds a level previously inputted to the external variable temperature control circuit. The variable temperature control circuit functions as subpart of the temperature control circuit. To provide temperature stability and uniformity, the electrometer circuit is enclosed by an insulated housing.

  16. Managing America`s solid waste

    SciTech Connect (OSTI)

    Not Available

    1998-03-02

    This report presents an historical overview of the federal role in municipal solid waste management from 1965 to approximately 1995. Attention is focuses on the federal role in safeguarding public health, protecting the environment, and wisely using material and energy resources. It is hoped that this report will provide important background for future municipal solid waste research and development initiatives.

  17. Solid fuel applications to transportation engines

    SciTech Connect (OSTI)

    Rentz, Richard L.; Renner, Roy A.

    1980-06-01

    The utilization of solid fuels as alternatives to liquid fuels for future transportation engines is reviewed. Alternative liquid fuels will not be addressed nor will petroleum/solid fuel blends except for the case of diesel engines. With respect to diesel engines, coal/oil mixtures will be addressed because of the high interest in this specific application as a result of the large number of diesel engines currently in transportation use. Final assessments refer to solid fuels only for diesel engines. The technical assessments of solid fuels utilization for transportation engines is summarized: solid fuel combustion in transportation engines is in a non-developed state; highway transportation is not amenable to solid fuels utilization due to severe environmental, packaging, control, and disposal problems; diesel and open-cycle gas turbines do not appear worthy of further development, although coal/oil mixtures for slow speed diesels may offer some promise as a transition technology; closed-cycle gas turbines show some promise for solid fuels utilization for limited applications as does the Stirling engine for use of cleaner solid fuels; Rankine cycle engines show good potential for limited applications, such as for locomotives and ships; and any development program will require large resources and sophisticated equipment in order to advance the state-of-the-art.

  18. Ab initio thermodynamic approach to identify mixed solid sorbents for CO2 capture technology

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duan, Yuhua

    2015-10-15

    Because the current technologies for capturing CO2 are still too energy intensive, new materials must be developed that can capture CO2 reversibly with acceptable energy costs. At a given CO2 pressure, the turnover temperature (Tt) of the reaction of an individual solid that can capture CO2 is fixed. Such Tt may be outside the operating temperature range (ΔTo) for a practical capture technology. To adjust Tt to fit the practical ΔTo, in this study, three scenarios of mixing schemes are explored by combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations. Our calculated resultsmore » demonstrate that by mixing different types of solids, it’s possible to shift Tt to the range of practical operating temperature conditions. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO2 capture reactions by the mixed solids of interest, we were able to identify the mixing ratios of two or more solids to form new sorbent materials for which lower capture energy costs are expected at the desired pressure and temperature conditions.« less

  19. Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    DOE Patents [OSTI]

    Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

    2014-01-28

    Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  20. Methods of conveying fluids and methods of sublimating solid particles

    DOE Patents [OSTI]

    Turner, Terry D; Wilding, Bruce M

    2013-10-01

    A heat exchanger and associated methods for sublimating solid particles therein, for conveying fluids therethrough, or both. The heat exchanger includes a chamber and a porous member having a porous wall having pores in communication with the chamber and with an interior of the porous member. A first fluid is conveyed into the porous member while a second fluid is conveyed into the porous member through the porous wall. The second fluid may form a positive flow boundary layer along the porous wall to reduce or eliminate substantial contact between the first fluid and the interior of the porous wall. The combined first and second fluids are conveyed out of the porous member. Additionally, the first fluid and the second fluid may each be conveyed into the porous member at different temperatures and may exit the porous member at substantially the same temperature.

  1. Materials issues in solid oxide fuel cell systems

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.

    2007-03-02

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). The presence of carbon oxides in the fuel can cause significant performance problems resulting in decreasing the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC below ~800 C may allow less expensive metallic materials to be used for interconnects. This presentation provides insight on the material performance of ferritic steels in fuels containing carbon oxides and seeks to quantify the extent of possible degradation due to carbon species in the gas stream.

  2. Monitoring arrangement for vented nuclear fuel elements

    DOE Patents [OSTI]

    Campana, Robert J.

    1981-01-01

    In a nuclear fuel reactor core, fuel elements are arranged in a closely packed hexagonal configuration, each fuel element having diametrically opposed vents permitting 180.degree. rotation of the fuel elements to counteract bowing. A grid plate engages the fuel elements and forms passages for communicating sets of three, four or six individual vents with respective monitor lines in order to communicate vented radioactive gases from the fuel elements to suitable monitor means in a manner readily permitting detection of leakage in individual fuel elements.

  3. The New Element Americium (Atomic Number 95)

    DOE R&D Accomplishments [OSTI]

    Seaborg, G.T.; James, R.A.; Morgan, L.O.

    1948-01-00

    Several isotopes of the new element 95 have been produced and their radiations characterized. The chemical properties of this tripositive element are similar to those of the typical tripositive lanthanide rare-earth elements. Element 95 is different from the latter in the degree and rate of formation of certain compounds of the complex ion type, which makes possible the separation of element 95 from the lanthanide rare-earths. The name americium (after the Americas) and the symbol Am are suggested for the element on the basis of its position as the sixth member of the actinide rare-earth series, analogous to europium, Eu, of the lanthanide series.

  4. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-05-01

    A nuclear reactor fuel element comprising high density ceramic fissionable material enclosed in a tubular cladding of corrosion-resistant material is described. The fissionable material is in the form of segments of a tube which have cooperating tapered interfaces which produce outward radial displacement when the segments are urged axially together. A resilient means is provided within the tubular housing to constantly urge the fuel segments axially. This design maintains the fuel material in tight contacting engagement against the inner surface of the outer cladding tube to eliminate any gap therebetween which may be caused by differential thermal expansion between the fuel material and the material of the tube.

  5. METHOD OF MAKING FUEL ELEMENTS

    DOE Patents [OSTI]

    Bean, C.H.; Macherey, R.E.

    1959-12-01

    A method is described for fabricating fuel elements, particularly for enclosing a plate of metal with a second metal by inserting the plate into an aperture of a frame of a second plate, placing a sheet of the second metal on each of opposite faces of the assembled plate and frame, purging with an inert gas the air from the space within the frame and the sheets while sealing the seams between the frame and the sheets, exhausting the space, purging the space with air, re-exhausting the spaces, sealing the second aperture, and applying heat and pressure to bond the sheets, the plate, and the frame to one another.

  6. Fundamental Studies of the Durability of Materials for Interconnects in Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Frederick S. Pettit; Gerald H. Meier

    2006-06-30

    Ferritic stainless steels are a leading candidate material for use as an SOFC interconnect, but have the problem of forming volatile chromia species that lead to cathode poisoning. This project has focused both on optimization of ferritic alloys for SOFC applications and evaluating the possibility of using alternative materials. The initial efforts involved studying the oxidation behavior of a variety of chromia-forming ferritic stainless steels in the temperature range 700-900 C in atmospheres relevant to solid oxide fuel cell operation. The alloys exhibited a wide variety of oxidation behavior based on composition. A method for reducing the vaporization is to add alloying elements that lead to the formation of a thermally grown oxide layer over the protective chromia. Several commercial steels form manganese chromate on the surface. This same approach, combined with observations of TiO{sub 2} overlayer formation on the chromia forming, Ni-based superalloy IN 738, has resulted in the development of a series of Fe-22 Cr-X Ti alloys (X=0-4 wt%). Oxidation testing has indicated that this approach results in significant reduction in chromia evaporation. Unfortunately, the Ti also results in accelerated chromia scale growth. Fundamental thermo-mechanical aspects of the durability of solid oxide fuel cell (SOFC) interconnect alloys have also been investigated. A key failure mechanism for interconnects is the spallation of the chromia scale that forms on the alloy, as it is exposed to fuel cell environments. Indentation testing methods to measure the critical energy release rate (Gc) associated with the spallation of chromia scale/alloy systems have been evaluated. This approach has been used to evaluate the thermomechanical stability of chromia films as a function of oxidation exposure. The oxidation of pure nickel in SOFC environments was evaluated using thermogravimetric analysis (TGA) to determine the NiO scaling kinetics and a four-point probe was used to measure the area-specific resistance (ASR) to estimate the electrical degradation of the interconnect. In addition to the baseline study of pure nickel, steps were taken to decrease the ASR through alloying and surface modifications. Finally, high conductivity composite systems, consisting of nickel and silver, were studied. These systems utilize high conductivity silver pathways through nickel while maintaining the mechanical stability that a nickel matrix provides.

  7. Flow-Solution-Liquid-Solid Growth of Semiconductor Nanowires: A Novel Approach for Controlled Synthesis

    SciTech Connect (OSTI)

    Hollingsworth, Jennifer A.; Palaniappan, Kumaranand; Laocharoensuk, Rawiwan; Smith, Nickolaus A.; Dickerson, Robert M.; Casson, Joanna L.; Baldwin, Jon K.

    2012-06-07

    Semiconductor nanowires (SC-NWs) have potential applications in diverse technologies from nanoelectronics and photonics to energy harvesting and storage due to their quantum-confined opto-electronic properties coupled with their highly anisotropic shape. Here, we explore new approaches to an important solution-based growth method known as solution-liquid-solid (SLS) growth. In SLS, molecular precursors are reacted in the presence of low-melting metal nanoparticles that serve as molten fluxes to catalyze the growth of the SC-NWs. The mechanism of growth is assumed to be similar to that of vapor-liquid-solid (VLS) growth, with the clear distinctions of being conducted in solution in the presence of coordinating ligands and at relatively lower temperatures (<300 C). The resultant SC-NWs are soluble in common organic solvents and solution processable, offering advantages such as simplified processing, scale-up, ultra-small diameters for quantum-confinement effects, and flexible choice of materials from group III-V to groups II-VI, IV-VI, as well as truly ternary I-III-VI semiconductors as we recently demonstrates. Despite these advantages of SLS growth, VLS offers several clear opportunities not allowed by conventional SLS. Namely, VLS allows sequential addition of precursors for facile synthesis of complex axial heterostructures. In addition, growth proceeds relatively slowly compared to SLS, allowing clear assessments of growth kinetics. In order to retain the materials and processing flexibility afforded by SLS, but add the elements of controlled growth afforded by VLS, we transformed SLS into a flow based method by adapting it to synthesis in a microfluidic system. By this new method - so-called 'flow-SLS' (FSLS) - we have now demonstrated unprecedented fabrication of multi-segmented SC-NWs, e.g., 8-segmented CdSe/ZnSe defined by either compositionally abrupt or alloyed interfaces as a function of growth conditions. In addition, we have studied growth rates as a function of catalyst size/SC-NW diameter and shown for the first time that SLS is governed by Gibbs-Thomson effects. Lastly, from an applications standpoint, we report growth of SC-NWs from a range of substrates, including ITO-coated glass for fabrication of hybrid photovoltaic devices, comparing these to their quasi zero-dimensional quantum-dot counterparts.

  8. High temperature furnace

    DOE Patents [OSTI]

    Borkowski, Casimer J.

    1976-08-03

    A high temperature furnace for use above 2000.degree.C is provided that features fast initial heating and low power consumption at the operating temperature. The cathode is initially heated by joule heating followed by electron emission heating at the operating temperature. The cathode is designed for routine large temperature excursions without being subjected to high thermal stresses. A further characteristic of the device is the elimination of any ceramic components from the high temperature zone of the furnace.

  9. Solid waste burial grounds interim safety analysis

    SciTech Connect (OSTI)

    Saito, G.H.

    1994-10-01

    This Interim Safety Analysis document supports the authorization basis for the interim operation and restrictions on interim operations for the near-surface land disposal of solid waste in the Solid Waste Burial Grounds. The Solid Waste Burial Grounds Interim Safety Basis supports the upgrade progress for the safety analysis report and the technical safety requirements for the operations in the Solid Waste Burial Grounds. Accident safety analysis scenarios have been analyzed based on the significant events identified in the preliminary hazards analysis. The interim safety analysis provides an evaluation of the operations in the Solid Waste Burial Grounds to determine if the radiological and hazardous material exposures will be acceptable from an overall health and safety standpoint to the worker, the onsite personnel, the public, and the environment.

  10. Ionization By Impact Electrons in Solids: Electron Mean Free Path Fitted Over A Wide Energy Range

    SciTech Connect (OSTI)

    Ziaja, B; London, R A; Hajdu, J

    2005-06-09

    We propose a simple formula for fitting the electron mean free paths in solids both at high and at low electron energies. The free-electron-gas approximation used for predicting electron mean free paths is no longer valid at low energies (E < 50 eV), as the band structure effects become significant at those energies. Therefore we include the results of the band structure calculations in our fit. Finally, we apply the fit to 9 elements and 2 compounds.

  11. Determinants of sustainability in solid waste management - The Gianyar Waste Recovery Project in Indonesia

    SciTech Connect (OSTI)

    Zurbruegg, Christian; Gfrerer, Margareth; Ashadi, Henki; Brenner, Werner; Kueper, David

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer Our assessment tool helps evaluate success factors in solid waste projects. Black-Right-Pointing-Pointer Success of the composting plant in Indonesia is linked to its community integration. Black-Right-Pointing-Pointer Appropriate technology is not a main determining success factor for sustainability. Black-Right-Pointing-Pointer Structured assessment of 'best practices' can enhance replication in other cities. - Abstract: According to most experts, integrated and sustainable solid waste management should not only be given top priority, but must go beyond technical aspects to include various key elements of sustainability to ensure success of any solid waste project. Aside from project sustainable impacts, the overall enabling environment is the key feature determining performance and success of an integrated and affordable solid waste system. This paper describes a project-specific approach to assess typical success or failure factors. A questionnaire-based assessment method covers issues of: (i) social mobilisation and acceptance (social element), (ii) stakeholder, legal and institutional arrangements comprising roles, responsibilities and management functions (institutional element); (iii) financial and operational requirements, as well as cost recovery mechanisms (economic element). The Gianyar Waste Recovery Project in Bali, Indonesia was analysed using this integrated assessment method. The results clearly identified chief characteristics, key factors to consider when planning country wide replication but also major barriers and obstacles which must be overcome to ensure project sustainability. The Gianyar project consists of a composting unit processing 60 tons of municipal waste per day from 500,000 inhabitants, including manual waste segregation and subsequent composting of the biodegradable organic fraction.

  12. Inorganic-organic composite solid polymer electrolytes

    SciTech Connect (OSTI)

    Abraham, K.M.; Koch, V.R.; Blakley, T.J.

    2000-04-01

    Inorganic-organic composite solid polymer electrolytes (CSPEs) have been prepared from the poly(ethylene oxide) (PEO)-like electrolytes of the general formula polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP)-PEO{sub n}-LiX and Li{sup +}-conducting ceramic powders. In the PEO-like electrolytes, PVdF-HFP is the copolymer of PVdF and HFP, PEO{sub n} is a nonvolatile oligomeric polyethylene oxide of {approximately}400 g/mol molecular weight, and LiX is lithium bis(trifluoroethylsulfonyl)imide. Two types of inorganic oxide ceramic powders were used: a highly Li{sup +}-conducting material of the composition 14 mol % Li{sub 2}O-9Al{sub 2}O{sub 3}-38TiO{sub 2}-39P{sub 2}O{sub 5}, and the poorly Li{sup +}-conducting Li-silicates Li{sub 4{minus}x}M{sub x}SiO{sub 4} where M is Ca or Mg and x is 0 or 0.05. The composite electrolytes can be prepared as thin membranes in which the Li{sup +} conductivity and good mechanical strength of the Li{sup +}-conducting inorganic ceramics are complemented by the structural flexibility and high conductivity of organic polymer electrolytes. Excellent electrochemical and thermal stabilities have been demonstrated for the electrolyte films. Li//composite electrolyte//LiCoO{sub 2} rechargeable cells have been fabricated and cycled at room temperature and 50 C.

  13. Solid state safety jumper cables

    DOE Patents [OSTI]

    Kronberg, James W.

    1993-01-01

    Solid state jumper cables for connecting two batteries in parallel, having two bridge rectifiers for developing a reference voltage, a four-input decoder for determining which terminals are to be connected based on a comparison of the voltage at each of the four terminals to the reference voltage, and a pair of relays for effecting the correct connection depending on the determination of the decoder. No connection will be made unless only one terminal of each battery has a higher voltage than the reference voltage, indicating "positive" terminals, and one has a lower voltage than the reference voltage, indicating "negative" terminals, and that, therefore, the two high voltage terminals may be connected and the two lower voltage terminals may be connected. Current flows once the appropriate relay device is closed. The relay device is preferably a MOSFET (metal oxide semiconductor field effect transistor) combined with a series array of photodiodes that develop MOSFET gate-closing potential when the decoder output causes an LED to light.

  14. Solid state safety jumper cables

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-02-23

    Solid state jumper cables for connecting two batteries in parallel, having two bridge rectifiers for developing a reference voltage, a four-input decoder for determining which terminals are to be connected based on a comparison of the voltage at each of the four terminals to the reference voltage, and a pair of relays for effecting the correct connection depending on the determination of the decoder. No connection will be made unless only one terminal of each battery has a higher voltage than the reference voltage, indicating positive'' terminals, and one has a lower voltage than the reference voltage, indicating negative'' terminals, and that, therefore, the two high voltage terminals may be connected and the two lower voltage terminals may be connected. Current flows once the appropriate relay device is closed. The relay device is preferably a MOSFET (metal oxide semiconductor field effect transistor) combined with a series array of photodiodes that develop MOSFET gate-closing potential when the decoder output causes an LED to light.

  15. Valve for controlling solids flow

    DOE Patents [OSTI]

    Feldman, David K.

    1980-01-01

    A fluidized solids control valve is disclosed that is particularly well adapted for use with a flow of coal or char that includes both large particles and fines. The particles may or may not be fluidized at various times during the operation. The valve includes a tubular body that terminates in a valve seat covered by a normally closed closure plate. The valve body at the seat and the closure plate is provided with aligned longitudinal slots that receive a pivotally supported key plate. The key plate is positionable by an operator in inserted, intermediate and retracted positions respecting the longitudinal slot in the valve body. The key plate normally closes the slot within the closure plate but is shaped and aligned obliquely to the longitudinal slot within the valve body to provide progressively increasing slot openings between the inserted and retracted positions. Transfer members are provided between the operator, key plate and closure plate to move the closure plate into an open position only when the key plate is retracted from the longitudinal slot within the valve body.

  16. LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES

    SciTech Connect (OSTI)

    Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

    2003-03-31

    This report represents a summary of the work carried out on this project which started October 1999 and ended March 2003. A list of the publications resulting from the work are contained in Appendix A. The most significant achievements are: (1) Dense nanocrystalline zirconia and ceria films were obtained at temperatures < 400 C. (2) Nanocrystalline films of both ceria and zirconia were characterized. (3) We showed that under anodic conditions 0.5 to 1 micron thick nanocrystalline films of Sc doped zirconia have sufficient electronic conductivity to prevent them from being useful as an electrolyte. (4) We have developed a process by which dense 0.5 to 5 micron thick dense films of either YSZ or ceria can be deposited on sintered porous substrates which serve as either the cathode or anode at temperatures as low as 400 C. (5) The program has provided the research to produce two PhD thesis for students, one is now working in the solid oxide fuel cell field. (6) The results of the research have resulted in 69 papers published, 3 papers submitted or being prepared for publication, 50 oral presentations and 3 patent disclosures.

  17. Effect of La{sub 2}O{sub 3}-treatment on textural and solid-solid interactions in ferric/cobaltic oxides system

    SciTech Connect (OSTI)

    Fagal, Gehan A.; Badawy, Abdelrahman A.; Hassan, Neven A.; El-Shobaky, Gamil A.

    2012-10-15

    Pure and La{sub 2}O{sub 3}-containing (0.75-3.0 mol%) Fe{sub 2}O{sub 3}/Co{sub 3}O{sub 4} solids were prepared by thermal treatment of their carbonates at 500-700 Degree-Sign C. The produced solids were characterized using XRD, HRTEM, EDX and nitrogen adsorption at -196 Degree-Sign C. The results revealed that pure solids calcined at 600 and 700 Degree-Sign C consisted of nanosized CoFe{sub 2}O{sub 4} phase, while pure mixed solids calcined at 500 Degree-Sign C consisted of trace amount of CoFe{sub 2}O{sub 4} and unreacted Fe{sub 2}O{sub 3}, Co{sub 3}O{sub 4} phases. The presence of 0.75 mol% La{sub 2}O{sub 3} enhanced solid-solid interaction between Fe{sub 2}O{sub 3} and Co{sub 3}O{sub 4} at 500 Degree-Sign C yielding CoFe{sub 2}O{sub 4}. The ferrite phase existed also in all mixed oxides upon treated with La{sub 2}O{sub 3} besides LaCoO{sub 3} phase. LaCoO{sub 3} existed as a major phase in all mixed oxides treated with 3 mol% La{sub 2}O{sub 3}. La{sub 2}O{sub 3}-treatment modified the crystallite size of all phases present to an extent dependent on calcination temperature and amount of La{sub 2}O{sub 3} content. This treatment decreased effectively the S{sub BET} of all mixed solids. - Graphical Abstract: TEM photographs of pure mixed oxides calcined at 500 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Cobalt ferrite exhibit chemical stability, low electric loss and high coercivity. Black-Right-Pointing-Pointer Cobalt ferrite is used in microwave devices, computer memories and magnetic storage. Black-Right-Pointing-Pointer Solid-solid interactions in ferric/cobaltic oxides system were investigated. Black-Right-Pointing-Pointer La{sub 2}O{sub 3}-treatment modified surface compositions of the system investigated. Black-Right-Pointing-Pointer All phases present in various solids existed as nanosized solids.

  18. Theoretical and computer models of detonation in solid explosives

    SciTech Connect (OSTI)

    Tarver, C.M.; Urtiew, P.A.

    1997-10-01

    Recent experimental and theoretical advances in understanding energy transfer and chemical kinetics have led to improved models of detonation waves in solid explosives. The Nonequilibrium Zeldovich - von Neumann - Doring (NEZND) model is supported by picosecond laser experiments and molecular dynamics simulations of the multiphonon up-pumping and internal vibrational energy redistribution (IVR) processes by which the unreacted explosive molecules are excited to the transition state(s) preceding reaction behind the leading shock front(s). High temperature, high density transition state theory calculates the induction times measured by laser interferometric techniques. Exothermic chain reactions form product gases in highly excited vibrational states, which have been demonstrated to rapidly equilibrate via supercollisions. Embedded gauge and Fabry-Perot techniques measure the rates of reaction product expansion as thermal and chemical equilibrium is approached. Detonation reaction zone lengths in carbon-rich condensed phase explosives depend on the relatively slow formation of solid graphite or diamond. The Ignition and Growth reactive flow model based on pressure dependent reaction rates and Jones-Wilkins-Lee (JWL) equations of state has reproduced this nanosecond time resolved experimental data and thus has yielded accurate average reaction zone descriptions in one-, two- and three- dimensional hydrodynamic code calculations. The next generation reactive flow model requires improved equations of state and temperature dependent chemical kinetics. Such a model is being developed for the ALE3D hydrodynamic code, in which heat transfer and Arrhenius kinetics are intimately linked to the hydrodynamics.

  19. Irradiation-induced composition patterns in binary solid solutions

    SciTech Connect (OSTI)

    Dubey, Santosh; El-Azab, Anter

    2013-09-28

    A theoretical/computational model for the irradiation-driven compositional instabilities in binary solid solutions has been developed. The model is suitable for investigating the behavior of structural alloys and metallic nuclear fuels in a reactor environment as well as the response of alloy thin films to ion beam irradiation. The model is based on a set of reaction-diffusion equations for the dynamics of vacancies, interstitials, and lattice atoms under irradiation. The dynamics of these species includes the stochastic generation of defects by collision cascades as well as the defect reactions and diffusion. The atomic fluxes in this model are derived based on the transitions of lattice defects. The set of reaction-diffusion equations are stiff, hence a stiffly stable method, also known as the Gear method, has been used to numerically approximate the equations. For the Cu-Au alloy in the solid solution regime, the model results demonstrate the formation of compositional patterns under high-temperature particle irradiation, with Fourier space properties (Fourier spectrum, average wavelength, and wavevector) depending on the cascade damage characteristics, average composition, and irradiation temperature.

  20. The Thermodynamic Properties of the f-Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides

    SciTech Connect (OSTI)

    Konings, Rudy J. M. Bene, Ondrej; Kovcs, Attila; Manara, Dario; Sedmidubsk, David; Gorokhov, Lev; Iorish, Vladimir S.; Yungman, Vladimir; Shenyavskaya, E.; Osina, E.

    2014-03-15

    A comprehensive review of the thermodynamic properties of the oxide compounds of the lanthanide and actinide elements is presented. The available literature data for the solid, liquid, and gaseous state have been analysed and recommended values are presented. In case experimental data are missing, estimates have been made based on the trends in the two series, which are extensively discussed.