National Library of Energy BETA

Sample records for telemetry systems geochemical

  1. Downhole telemetry system

    DOE Patents [OSTI]

    Normann, R.A.; Kadlec, E.R.

    1994-11-08

    A downhole telemetry system is described for optically communicating to the surface operating parameters of a drill bit during ongoing drilling operations. The downhole telemetry system includes sensors mounted with a drill bit for monitoring at least one operating parameter of the drill bit and generating a signal representative thereof. The downhole telemetry system includes means for transforming and optically communicating the signal to the surface as well as means at the surface for producing a visual display of the optically communicated operating parameters of the drill bit. 7 figs.

  2. Downhole telemetry system

    DOE Patents [OSTI]

    Normann, Randy A.; Kadlec, Emil R.

    1994-01-01

    A downhole telemetry system is described for optically communicating to the surface operating parameters of a drill bit during ongoing drilling operations. The downhole telemetry system includes sensors mounted with a drill bit for monitoring at least one operating parameter of the drill bit and generating a signal representative thereof. The downhole telemetry system includes means for transforming and optically communicating the signal to the surface as well as means at the surface for producing a visual display of the optically communicated operating parameters of the drill bit.

  3. Disposable telemetry cable deployment system

    DOE Patents [OSTI]

    Holcomb, David Joseph

    2000-01-01

    A disposable telemetry cable deployment system for facilitating information retrieval while drilling a well includes a cable spool adapted for insertion into a drill string and an unarmored fiber optic cable spooled onto the spool cable and having a downhole end and a stinger end. Connected to the cable spool is a rigid stinger which extends through a kelly of the drilling apparatus. A data transmission device for transmitting data to a data acquisition system is disposed either within or on the upper end of the rigid stinger.

  4. Impedance-matched drilling telemetry system

    DOE Patents [OSTI]

    Normann, Randy A.; Mansure, Arthur J.

    2008-04-22

    A downhole telemetry system that uses inductance or capacitance as a mode through which signal is communicated across joints between assembled lengths of pipe wherein efficiency of signal propagation through a drill string, for example, over multiple successive pipe segments is enhanced through matching impedances associated with the various telemetry system components.

  5. Ultrasonic ranging and data telemetry system

    DOE Patents [OSTI]

    Brashear, Hugh R.; Blair, Michael S.; Phelps, James E.; Bauer, Martin L.; Nowlin, Charles H.

    1990-01-01

    An ultrasonic ranging and data telemetry system determines a surveyor's position and automatically links it with other simultaneously taken survey data. An ultrasonic and radio frequency (rf) transmitter are carried by the surveyor in a backpack. The surveyor's position is determined by calculations that use the measured transmission times of an airborne ultrasonic pulse transmitted from the backpack to two or more prepositioned ultrasonic transceivers. Once a second, rf communications are used both to synchronize the ultrasonic pulse transmission-time measurements and to transmit other simultaneously taken survey data. The rf communications are interpreted by a portable receiver and microcomputer which are brought to the property site. A video display attached to the computer provides real-time visual monitoring of the survey progress and site coverage.

  6. Electromechanical transducer for acoustic telemetry system

    DOE Patents [OSTI]

    Drumheller, Douglas S.

    1993-01-01

    An improved electromechanical transducer is provided for use in an acoustic telemetry system. The transducer of this invention comprises a stack of ferroelectric ceramic disks interleaved with a plurality of spaced electrodes which are used to electrically pole the ceramic disks. The ceramic stack is housed in a metal tubular drill collar segment. The electrodes are preferably alternatively connected to ground potential and driving potential. This alternating connection of electrodes to ground and driving potential subjects each disk to an equal electric field; and the direction of the field alternates to match the alternating direction of polarization of the ceramic disks. Preferably, a thin metal foil is sandwiched between electrodes to facilitate the electrical connection. Alternatively, a thicker metal spacer plate is selectively used in place of the metal foil in order to promote thermal cooling of the ceramic stack.

  7. Electromechanical transducer for acoustic telemetry system

    DOE Patents [OSTI]

    Drumheller, D.S.

    1993-06-22

    An improved electromechanical transducer is provided for use in an acoustic telemetry system. The transducer of this invention comprises a stack of ferroelectric ceramic disks interleaved with a plurality of spaced electrodes which are used to electrically pole the ceramic disks. The ceramic stack is housed in a metal tubular drill collar segment. The electrodes are preferably alternatively connected to ground potential and driving potential. This alternating connection of electrodes to ground and driving potential subjects each disk to an equal electric field; and the direction of the field alternates to match the alternating direction of polarization of the ceramic disks. Preferably, a thin metal foil is sandwiched between electrodes to facilitate the electrical connection. Alternatively, a thicker metal spacer plate is selectively used in place of the metal foil in order to promote thermal cooling of the ceramic stack.

  8. Geochemical Modeling Of Aqueous Systems

    Energy Science and Technology Software Center (OSTI)

    1995-09-07

    EQ3/6 is a software package for geochemical modeling of aqueous systems. This description pertains to version 7.2b. It addresses aqueous speciation, thermodynamic equilibrium, disequilibrium, and chemical kinetics. The major components of the package are EQ3NR, a speciation-solubility code, and EQ6 a reaction path code. EQ3NR is useful for analyzing groundwater chemistry data, calculating solubility limits, and determining whether certain reactions are in states of equilibrium or disequilibrium. It also initializes EQ6 calculations. EQ6 models themore » consequences of reacting an aqueous solution with a specified set of reactants (e.g., minerals or waste forms). It can also model fluid mixing and the effects of changes in temperature. Each of five supporting data files contain both standard state and activity coefficient-related data. Three support the use of the Davies or B-dot equations for the activity coefficients; the other two support the use of Pitzer''s equations. The temperature range of the thermodynamic data on the data files varies from 25 degrees C only to 0-300 degrees C.« less

  9. Juvenile Salmon Acoustic Telemetry System Transmitter Downsize Assessment

    SciTech Connect (OSTI)

    Carlson, Thomas J.; Myjak, Mitchell J.

    2010-04-30

    At the request of the U.S. Army Corps of Engineers, Portland District, researchers from Pacific Northwest National Laboratory investigated the use of an application-specific integrated circuit (ASIC) to reduce the weight and volume of Juvenile Salmon Acoustic Telemetry System (JSATS) transmitters while retaining current functionality. Review of the design of current JSATS transmitters identified components that could be replaced by an ASIC while retaining the function of the current transmitter and offering opportunities to extend function if desired. ASIC design alternatives were identified that could meet transmitter weight and volume targets of 200 mg and 100 mm3. If alternatives to the cylindrical batteries used in current JSATS transmitters can be identified, it could be possible to implant ASIC-based JSATS transmitters by injection rather than surgery. Using criteria for the size of fish suitable for surgical implantation of current JSATS transmitters, it was concluded that fish as small as 70 mm in length could be implanted with an ASIC-based transmitter, particularly if implantation by injection became feasible.

  10. Rotary acting shear valve for drilling fluid telemetry systems

    SciTech Connect (OSTI)

    Larronde, M.L.

    1986-12-16

    This patent describes a valve apparatus useful in a borehole drilling fluid telemetry system for transmitting data pulses from one end of a pipe string to another by imparting pressure pulses to a drilling fluid circulating down the pipe string, through a drilling member and up the annulus between the pipe string and borehole wall. The valve is operated in the drilling fluid flow path to modulate the flow of the drilling fluid and thereby impart detectable pressure pulses to the drilling fluid. The apparatus comprises a housing disposable within the drill string, adapted for the flow of drilling fluid therearound and formed with a passage therethrough for selectable flow communication between the drill string and the borehole annulus; a shear valve mounted within the housing across the passage and comprising a valve seat and rotational gate member having alignable seat and gate openings formed therethrough, the gate opening being movable in an arc into and out of axial alignment with the seat opening; and valve actuation means for coupling to the gate for rotationally moving the gate opening through an arc relative to the seat opening to open the passage and generate a pressure pulse. The valve actuation means comprises a first solenoid and cam means coupled thereto for translating the non-linear, axial forces of the solenoid into generally linear, rotational forces for rotating the valve gate.

  11. Innovative Telemetry System Will Help Tap Hard-to-Reach Natural Gas Resources

    Office of Energy Efficiency and Renewable Energy (EERE)

    The commercialization of an innovative telemetry communications system developed through a U.S. Department of Energy research program will help U.S. producers tap previously hard-to-reach natural gas resources deep underground, resulting in access to additional supplies that will help enhance national energy security.

  12. Development of a High-Temperature Smart Transducer Interface Node and Telemetry System (HSTINTS)

    SciTech Connect (OSTI)

    Buckner, M.A. et al.

    2006-11-03

    Halliburton Energy Services and Oak Ridge National Laboratory established a CRADA to conduct applied research to develop a general purpose, High-Temperature, Smart Transducer Interface Node and Telemetry System (HSTINTS) capable of temporally-coherent multiple-channel, high speed, high-resolution data transuction and acquisition while operating in a hostile thermal, chemical, and pressure environment for extended periods of time over a single coaxial cable. This ambitious, high-risk effort required development of custom dielectric isolated integrated circuits, amplified hybrid couplers for telemetry and an audio-frequency based power supply and distribution system using an engineered application of standing waves to compensate voltage drop along a 2 mile long cable. Several goals were achieved but underestimated challenges and a couple of mistakes hampered progress. When it was determined that an additional year of concerted effort would be required to complete the system demonstration, the sponsor withdrew funding and terminated the effort.

  13. Code System to Model Aqueous Geochemical Equilibria.

    Energy Science and Technology Software Center (OSTI)

    2001-08-23

    Version: 00 MINTEQ is a geochemical program to model aqueous solutions and the interactions of aqueous solutions with hypothesized assemblages of solid phases. It was developed for the Environmental Protection Agency to perform the calculations necessary to simulate the contact of waste solutions with heterogeneous sediments or the interaction of ground water with solidified wastes. MINTEQ can calculate ion speciation/solubility, adsorption, oxidation-reduction, gas phase equilibria, and precipitation/dissolution ofsolid phases. MINTEQ can accept a finite massmore » for any solid considered for dissolution and will dissolve the specified solid phase only until its initial mass is exhausted. This ability enables MINTEQ to model flow-through systems. In these systems the masses of solid phases that precipitate at earlier pore volumes can be dissolved at later pore volumes according to thermodynamic constraints imposed by the solution composition and solid phases present. The ability to model these systems permits evaluation of the geochemistry of dissolved traced metals, such as low-level waste in shallow land burial sites. MINTEQ was designed to solve geochemical equilibria for systems composed of one kilogram of water, various amounts of material dissolved in solution, and any solid materials that are present. Systems modeled using MINTEQ can exchange energy and material (open systems) or just energy (closed systems) with the surrounding environment. Each system is composed of a number of phases. Every phase is a region with distinct composition and physically definable boundaries. All of the material in the aqueous solution forms one phase. The gas phase is composed of any gaseous material present, and each compositionally and structurally distinct solid forms a separate phase.« less

  14. A high speed multi-tasking, multi-processor telemetry system

    SciTech Connect (OSTI)

    Wu, Kung Chris

    1996-12-31

    This paper describes a small size, light weight, multitasking, multiprocessor telemetry system capable of collecting 32 channels of differential signals at a sampling rate of 6.25 kHz per channel. The system is designed to collect data from remote wind turbine research sites and transfer the data via wireless communication. A description of operational theory, hardware components, and itemized cost is provided. Synchronization with other data acquisition systems and test data on data transmission rates is also given. 11 refs., 7 figs., 4 tabs.

  15. Acoustic telemetry.

    SciTech Connect (OSTI)

    Drumheller, Douglas Schaeffer; Kuszmaul, Scott S.

    2003-08-01

    Broadcasting messages through the earth is a daunting task. Indeed, broadcasting a normal telephone conversion through the earth by wireless means is impossible with todays technology. Most of us don't care, but some do. Industries that drill into the earth need wireless communication to broadcast navigation parameters. This allows them to steer their drill bits. They also need information about the natural formation that they are drilling. Measurements of parameters such as pressure, temperature, and gamma radiation levels can tell them if they have found a valuable resource such as a geothermal reservoir or a stratum bearing natural gas. Wireless communication methods are available to the drilling industry. Information is broadcast via either pressure waves in the drilling fluid or electromagnetic waves in the earth and well tubing. Data transmission can only travel one way at rates around a few baud. Given that normal Internet telephone modems operate near 20,000 baud, these data rates are truly very slow. Moreover, communication is often interrupted or permanently blocked by drilling conditions or natural formation properties. Here we describe a tool that communicates with stress waves traveling through the steel drill pipe and production tubing in the well. It's based on an old idea called Acoustic Telemetry. But what we present here is more than an idea. This tool exists, it's drilled several wells, and it works. Currently, it's the first and only acoustic telemetry tool that can withstand the drilling environment. It broadcasts one way over a limited range at much faster rates than existing methods, but we also know how build a system that can communicate both up and down wells of indefinite length.

  16. Design and Instrumentation of a Measurement and Calibration System for an Acoustic Telemetry System

    SciTech Connect (OSTI)

    Deng, Zhiqun; Weiland, Mark A.; Carlson, Thomas J.; Eppard, M. B.

    2010-03-31

    The Juvenile Salmon Acoustic Telemetry System (JSATS) is an active sensing technology developed by Portland District, the U.S. Army Corps of Engineers for detecting and tracking small fish. It is used at hydroelectric projects and in the laboratory for evaluating behavior and survival of juvenile salmonids migrating through the Federal Columbia River Power System to the Pacific Ocean. It provides critical data for salmon protection and development of more “fish-friendly” hydroelectric facilities. The objective of this study was to design and build a measurement and calibration system for evaluating the JSATS component, because the JSATS requires comprehensive acceptance and performance testing in a controlled environment before it is deployed in the field. The system consists of a reference transducer, a water test tank lined with anechoic material, a motion control unit, a reference receiver, a signal conditioner and amplifier unit, a data acquisition board, MATLAB control and analysis interface, and a computer. The fully integrated system has been evaluated successfully at various simulated distances and using different encoded signals at frequencies within the bandwidth of the JSATS transmitter. It provides accurate acoustic mapping capability in a controlled environment and automates the process that allows real-time measurements and evaluation of the piezoelectric transducers, sensors, or the acoustic fields. The measurement and calibration system has been in use since 2009 for acceptance and performance testing of, and further improvements to, the JSATS.

  17. Micro-battery Development for Juvenile Salmon Acoustic Telemetry System Applications

    SciTech Connect (OSTI)

    Chen, Honghao; Cartmell, Samuel S.; Wang, Qiang; Lozano, Terence J.; Deng, Zhiqun; Li, Huidong; Chen, Xilin; Yuan, Yong; Gross, Mark E.; Carlson, Thomas J.; Xiao, Jie

    2014-01-21

    The Juvenile Salmon Acoustic Telemetry System (JSATS) project supported by the U.S. Army Corps of Engineers, Portland District, has yielded the smallest acoustic fish tag transmitter commercially available to date. In order to study even smaller fish populations and make the transmitter injectable by needles, the JSATS acoustic micro transmitter needs to be further downsized. This study focuses on the optimization of microbattery design based on Li/CFx chemistry. Through appropriate modifications, a steady high-rate pulse current with desirable life time has been achieved while the weight and volume of the battery is largely reduced. The impedance variation in as-designed microbatteries is systematically compared with that of currently used watch batteries in JSATS with an attempt to understand the intrinsic factors that control the performances of microbatteries under the real testing environments.

  18. Real-time data acquisition and telemetry based irrigation control system

    DOE Patents [OSTI]

    Slater, John M.; Svoboda, John M.

    2005-12-13

    A data acquisition and telemetry based control system for use in facilitating substantially real time management of an agricultural irrigation system. The soil moisture sensor includes a reader and a plurality of probes. The probes each include an electronic circuit having a moisture sensing capacitor in operative communication with the soil whose moisture is to be measured. Each probe also includes a receive/transmit antenna and the reader includes a transmit/receive antenna, so that as the reader passes near the probe, the reader transmits a digital excitation signal to the electronic circuit of the biodegradable probe via an inductive couple formed between the transmit/receive antenna of the reader and the receive/transmit coil of the probe. The electronic circuit uses an energy component of the excitation signal to generate a digital data signal which indicates the moisture content of the soil adjacent to the moisture sensing capacitor. The probe sends the data signal to the reader which then uses the data signal to develop a corresponding set of watering instructions which are then transmitted to a control module in communication with the irrigation system. The control module sends corresponding control signals to nozzles of the irrigation system causing the irrigation system to disperse water in a manner consistent with the moisture content data transmitted by the probes to the reader. Because the irrigation system moves continuously through the field to be irrigated, the moisture content data acquisition and resultant water dispersal by the irrigation system occur substantially in real time.

  19. Geochemical Enhancement Of Enhanced Geothermal System Reservoirs: An Integrated Field And Geochemical Approach

    SciTech Connect (OSTI)

    Joseph N. Moore

    2007-12-31

    . In contrast, fluid inclusions trapped prior to injection are relatively gas rich. These results suggest that the rocks undergo extensive microfracturing during injection and that the composition of the fluid inclusions will be biased toward the youngest event. Interactions between the reservoir rocks and injectate were modeled using the non-isothermal reactive geochemical transport code TOUGHREACT. Changes in fluid pH, fracture porosity, fracture permeability, fluid temperature, and mineral abundances were monitored. The simulations predict that amorphous silica will precipitate primarily within a few meters of the injection well and that mineral deposition will lead to rapid declines in fracture porosity and permeability, consistent with field observations. In support of Enhanced Geothermal System development, petrologic studies of Coso well 46A-19RD were conducted to determine the regions that are most likely to fail when stimulated. These studies indicate that the most intensely brecciated and altered rocks in the zone targeted for stimulation (below 10,000 ft (3048 m)) occur between 11,200 and 11,350 ft (3414 and 3459 m). This zone is interpreted as a shear zone that initially juxtaposed quartz diorite against granodiorite. Strong pervasive alteration and veining within the brecciated quartz diorite and granodiorite suggest this shear zone was permeable in the past. This zone of weakness was subsequently exploited by a granophyre dike whose top occurs at 11,350 ft (3459 m). The dike is unaltered. We anticipate, based on analysis of the well samples that failure during stimulation will most likely occur on this shear zone.

  20. Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems

    Broader source: Energy.gov [DOE]

    Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems presentation at the April 2013 peer review meeting held in Denver, Colorado.

  1. Optimization of Concurrent Deployments of the Juvenile Salmon Acoustic Telemetry System and Other Hydroacoustic Equipment at John Day Dam

    SciTech Connect (OSTI)

    Ploskey, Gene R.; Hughes, James S.; Khan, Fenton; Kim, Jina; Lamarche, Brian L.; Johnson, Gary E.; Choi, Eric Y.; Faber, Derrek M.; Wilberding, Matthew C.; Deng, Zhiqun; Weiland, Mark A.; Zimmerman, Shon A.; Fischer, Eric S.; Cushing, Aaron W.

    2008-09-01

    The purpose of this report is to document the results of the acoustic optimization study conducted at John Day Dam during January and February 2008. The goal of the study was to optimize performance of the Juvenile Salmon Acoustic Telemetry System (JSATS) by determining deployment and data acquisition methods to minimize electrical and acoustic interference from various other acoustic sampling devices. Thereby, this would allow concurrent sampling by active and passive acoustic methods during the formal evaluations of the prototype surface flow outlets at the dam during spring and summer outmigration seasons for juvenile salmonids. The objectives for the optimization study at John Day Dam were to: 1. Design and test prototypes and provide a total needs list of pipes and trolleys to deploy JSATS hydrophones on the forebay face of the powerhouse and spillway. 2. Assess the effect on mean percentage decoded of JSATS transmissions from tags arrayed in the forebay and detected on the hydrophones by comparing: turbine unit OFF vs. ON; spill bay OPEN vs. CLOSED; dual frequency identification sonar (DIDSON) and acoustic Doppler current profiler (ADCP) both OFF vs. ON at a spill bay; and, fixed-aspect hydroacoustic system OFF vs. ON at a turbine unit and a spill bay. 3. Determine the relationship between fixed-aspect hydroacoustic transmit level and mean percentage of JSATS transmissions decoded. The general approach was to use hydrophones to listen for transmissions from JSATS tags deployed in vertical arrays in a series perpendicular to the face of the dam. We used acoustic telemetry equipment manufactured by Technologic and Sonic Concepts. In addition, we assessed old and new JSATS signal detectors and decoders and two different types of hydrophone baffling. The optimization study consisted of a suite of off/on tests. The primary response variable was mean percentage of tag transmissions decoded. We found that there was no appreciable adverse effect on mean percentage

  2. Pressure sensor and Telemetry methods for measurement while drilling in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    geothermal wells | Department of Energy Pressure sensor and Telemetry methods for measurement while drilling in geothermal wells Pressure sensor and Telemetry methods for measurement while drilling in geothermal wells Project objective: Develop telemetry electronics and pressure sensor system for operation at 300ºC and demonstrate the operation of multiple pressure sensor systems at 300ºC. high_tilak_telemetry_methods.pdf (1000.13 KB) More Documents & Publications 300°C Capable

  3. Geochemical Modeling of the Near-Surface Hydrothermal System...

    Open Energy Info (EERE)

    with non-thermal groundwater. Our conceptual model is based on hypotheses in the literature and published geochemical and petrologic data. Mixing of thermal and non-thermal...

  4. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    SciTech Connect (OSTI)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  5. A Cabled Acoustic Telemetry System for Detecting and Tracking Juvenile Salmon: Part 2. Three-Dimensional Tracking and Passage Outcomes

    SciTech Connect (OSTI)

    Deng, Zhiqun; Weiland, Mark A.; Fu, Tao; Seim, Thomas A.; Lamarche, Brian L.; Choi, Eric Y.; Carlson, Thomas J.; Eppard, Matthew B.

    2011-05-26

    In Part 1 of this paper [1], we presented the engineering design and instrumentation of the Juvenile Salmon Acoustic Telemetry System (JSATS) cabled system, a nonproprietary technology developed by the U.S. Army Corps of Engineers, Portland District, to meet the needs for monitoring the survival of juvenile salmonids through the 31 dams in the Federal Columbia River Power System. Here in Part 2, we describe how the JSATS cabled system was employed as a reference sensor network for detecting and tracking juvenile salmon. Time-of-arrival data for valid detections on four hydrophones were used to solve for the three-dimensional (3D) position of fish surgically implanted with JSATS acoustic transmitters. Validation tests demonstrated high accuracy of 3D tracking up to 100 m from the John Day Dam spillway. The along-dam component, used for assigning the route of fish passage, had the highest accuracy; the median errors ranged from 0.06 to 0.22 m, and root mean square errors ranged from 0.05 to 0.56 m at distances up to 100 m. For the case study at John Day Dam during 2008, the range for 3D tracking was more than 100 m upstream of the dam face where hydrophones were deployed, and detection and tracking probabilities of fish tagged with JSATS acoustic transmitters were higher than 98%. JSATS cabled systems have been successfully deployed on several major dams to acquire information for salmon protection and for development of more “fish-friendly” hydroelectric facilities.

  6. Group telemetry analysis using the World Wide Web

    SciTech Connect (OSTI)

    Kalibjian, J.

    1996-12-31

    Today it is not uncommon to have large contractor teams involved in the design and deployment of even small satellite systems. The larger (and more geographically remote) the team members, the more difficult it becomes to efficiently manage the disbursement of telemetry data for evaluation and analysis. Further complications are introduced if some of the telemetry data is sensitive. An application is described which can facilitate telemetry data sharing utilizing the National Information Infrastructure (Internet).

  7. Advanced Telemetry | Open Energy Information

    Open Energy Info (EERE)

    search Name: Advanced Telemetry Place: San Diego, California Zip: 92131-2435 Sector: Buildings Product: San Diego-based provider of energy management software, communication and...

  8. Geochemical characterization of geothermal systems in the Great...

    Open Energy Info (EERE)

    Basin. Development of this database is one of the first steps in understanding the nature of geothermal systems in the Great Basin. Of particular importance in the Great Basin...

  9. Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems Alexandra Hakala (National Energy Technology Laboratory) Track 1 Project Officer: Lauren Boyd Total Project Funding: $995,718 April 25, 2013 This presentation does not contain any proprietary confidential, or otherwise restricted information. 2 | US DOE Geothermal Office eere.energy.gov Relevance/Impact of Research * Fractures - primary pathway for geothermal heat

  10. EM Telemetry Tool for Deep Well Drilling Applications

    SciTech Connect (OSTI)

    Jeffrey M. Gabelmann

    2005-11-15

    This final report discusses the successful development and testing of a deep operational electromagnetic (EM) telemetry system, produced under a cooperative agreement with the United States Department of Energy's National Energy Technology Laboratory. This new electromagnetic telemetry system provides a wireless communication link between sensors deployed deep within oil and gas wells and data acquisition equipment located on the earth's surface. EM based wireless telemetry is a highly appropriate technology for oil and gas exploration in that it avoids the need for thousands of feet of wired connections. In order to achieve the project performance objectives, significant improvements over existing EM telemetry systems were made. These improvements included the development of new technologies that have improved the reliability of the communications link while extending operational depth. A key element of the new design is the incorporation of a data-fusion methodology which enhances the communication receiver's ability to extract very weak signals from large amounts of ambient environmental noise. This innovative data-fusion receiver based system adapts advanced technologies, not normally associated with low-frequency communications, and makes them work within the harsh drilling environments associated with the energy exploration market. Every element of a traditional EM telemetry system design, from power efficiency to reliability, has been addressed. The data fusion based EM telemetry system developed during this project is anticipated to provide an EM tool capability that will impact both onshore and offshore oil and gas exploration operations, for conventional and underbalanced drilling applications.

  11. Real Time Telemetry Data Capture and Storage

    Energy Science and Technology Software Center (OSTI)

    1997-05-14

    This program is used to capture telemetry data from remote instrumentation systems. The data can be captured at the rate of 1M bit per second. The data can come in one of several formats, NRZ, RZ, and Bi-Phase. The DECOM software takes the serial data stream and locks on to a unique code word. By tracking the code word the software can strip out the information. Thus the program can display the incoming data realmore » time while saving the data to disk.« less

  12. The low temperature hydrothermal system of Campiglia, Tuscany (Italy); A geochemical approach

    SciTech Connect (OSTI)

    Celati, R.; Grassi, S.; D'Amore, F.; Marcolini, L. )

    1991-01-01

    This paper reports on the Campiglia hydrothermal system which is a low temperature hydrothermal system located in southwestern Tuscany, a region of Italy characterized by intense geothermal activity and by the presence of high temperature exploited geothermal reservoirs. Six water-points, with temperatures ranging between 20 and 47{degrees} C and different chemical and isotopic compositions, are found close to the margins of outcrops of the main regional aquifer formation. Systematic hydrogeological, geochemical and isotopic observations and temperature measurements were carried out on the different springs and wells for a period of three years (1984-1986). Constant water characteristics with time were observed in four water-points; two wells had variable trends depending on mixing processes. A groundwater circulation model characterized by flowpaths of different length and depth is suggested by the variety of chemical and isotopic characteristics and is consistent with geothermometry, which indicates temperatures up to 25{degrees} C higher than those measured at the spring emergencies. An important water supply to the system comes from local recharge, although regional circulation may also be present, particularly in the eastern part of the investigated area.

  13. Pressure sensor and Telemetry methods for measurement while drilling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pressure sensor and Telemetry methods for measurement while drilling in geothermal wells Pressure sensor and Telemetry methods for measurement while drilling in geothermal wells ...

  14. Downhole tool adapted for telemetry

    DOE Patents [OSTI]

    Hall, David R.; Fox, Joe

    2010-12-14

    A cycleable downhole tool such as a Jar, a hydraulic hammer, and a shock absorber adapted for telemetry. This invention applies to other tools where the active components of the tool are displaced when the tool is rotationally or translationally cycled. The invention consists of inductive or contact transmission rings that are connected by an extensible conductor. The extensible conductor permits the transmission of the signal before, after, and during the cycling of the tool. The signal may be continuous or intermittent during cycling. The invention also applies to downhole tools that do not cycle, but in operation are under such stress that an extensible conductor is beneficial. The extensible conductor may also consist of an extensible portion and a fixed portion. The extensible conductor also features clamps that maintain the conductor under stresses greater than that seen by the tool, and seals that are capable of protecting against downhole pressure and contamination.

  15. HBH-GEOCHEM-GEOPHY

    Energy Science and Technology Software Center (OSTI)

    003015WKSTN00 Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

  16. Optimizing parameters for predicting the geochemical behavior...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of discrete fracture networks in geothermal systems Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal ...

  17. Hydrology of the Greater Tongonan geothermal system, Philippines, as deduced from geochemical and isotopic data

    SciTech Connect (OSTI)

    Alvis-Isidro, R.R.; Solana, R.R.; D`amore, F.; Nuti, S.; Gonfiantini, R.

    1993-10-01

    Fluids in the Greater Tongonan geothermal system exhibit a large positive {sup 18}O shift from the Leyte meteoric water line. However, there is also a significant shift in {sup 2}H. The {delta}{sup 2}H-{delta}{sup 18}O plot shows that the geothermal fluids may be derived by the mixing of meteoric water with local magmatic water. The most enriched water in the Greater Tongonan system, in terms of {delta}{sup 18}O, {delta}{sup 2}H and Cl, is comprised of approximately 40% magmatic water. Baseline isotope results support a hydrogeochemical model in which there is increasing meteoric water dilution to the southeast, from Mahiao to Sambaloran and towards Malitbog. The Cl-{delta}{sup 18}O plot confirms that the geothermal fluid in Mahanagdong, further southeast, is distinct from that of the Mahiao-Sambaloran-Malitbog system.

  18. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt & Subtle Volcanic Systems, Hawaii & Maui

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review 2010 - Presentation. Project Objective: To use a combination of traditional geophysical and geochemical tools with exploration suites not typically used in geothermal exploration.

  19. Remote down-hole well telemetry

    DOE Patents [OSTI]

    Briles, Scott D.; Neagley, Daniel L.; Coates, Don M.; Freund, Samuel M.

    2004-07-20

    The present invention includes an apparatus and method for telemetry communication with oil-well monitoring and recording instruments located in the vicinity of the bottom of gas or oil recovery pipes. Such instruments are currently monitored using electrical cabling that is inserted into the pipes; cabling has a short life in this environment, and requires periodic replacement with the concomitant, costly shutdown of the well. Modulated reflectance, a wireless communication method that does not require signal transmission power from the telemetry package will provide a long-lived and reliable way to monitor down-hole conditions. Normal wireless technology is not practical since batteries and capacitors have to frequently be replaced or recharged, again with the well being removed from service. RF energy generated above ground can also be received, converted and stored down-hole without the use of wires, for actuating down-hole valves, as one example. Although modulated reflectance reduces or eliminates the loss of energy at the sensor package because energy is not consumed, during the transmission process, additional stored extra energy down-hole is needed.

  20. Flexible network wireless transceiver and flexible network telemetry transceiver

    DOE Patents [OSTI]

    Brown, Kenneth D.

    2008-08-05

    A transceiver for facilitating two-way wireless communication between a baseband application and other nodes in a wireless network, wherein the transceiver provides baseband communication networking and necessary configuration and control functions along with transmitter, receiver, and antenna functions to enable the wireless communication. More specifically, the transceiver provides a long-range wireless duplex communication node or channel between the baseband application, which is associated with a mobile or fixed space, air, water, or ground vehicle or other platform, and other nodes in the wireless network or grid. The transceiver broadly comprises a communication processor; a flexible telemetry transceiver including a receiver and a transmitter; a power conversion and regulation mechanism; a diplexer; and a phased array antenna system, wherein these various components and certain subcomponents thereof may be separately enclosed and distributable relative to the other components and subcomponents.

  1. Electromagnetic anti-jam telemetry tool

    DOE Patents [OSTI]

    Ganesan, Harini; Mayzenberg, Nataliya

    2008-02-12

    A mud-pulse telemetry tool includes a tool housing, a motor disposed in the tool housing, and a magnetic coupling coupled to the motor and having an inner shaft and an outer shaft. The tool may also include a stator coupled to the tool housing, a restrictor disposed proximate the stator and coupled to the magnetic coupling, so that the restrictor and the stator adapted to generate selected pulses in a drilling fluid when the restrictor is selectively rotated. The tool may also include a first anti-jam magnet coupled to the too housing, and an second anti-jam magnet disposed proximate the first anti-jam magnet and coupled to the inner shaft and/or the outer shaft, wherein at least one of the first anti-jam magnet and the second anti-jam magnet is an electromagnet, and wherein the first anti-jam magnet and the second anti-jam magnet are positioned with adjacent like poles.

  2. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt and Subtle Volcanic Systems, Hawai’i and Maui

    SciTech Connect (OSTI)

    Fercho, Steven; Owens, Lara; Walsh, Patrick; Drakos, Peter; Martini, Brigette; Lewicki, Jennifer L.; Kennedy, Burton M.

    2015-08-01

    Suites of new geophysical and geochemical exploration surveys were conducted to provide evidence for geothermal resource at the Haleakala Southwest Rift Zone (HSWRZ) on Maui Island, Hawai’i. Ground-based gravity (~400 stations) coupled with heli-bourne magnetics (~1500 line kilometers) define both deep and shallow fractures/faults, while also delineating potentially widespread subsurface hydrothermal alteration on the lower flanks (below approximately 1800 feet a.s.l.). Multi-level, upward continuation calculations and 2-D gravity and magnetic modeling provide information on source depths, but lack of lithologic information leaves ambiguity in the estimates. Additionally, several well-defined gravity lows (possibly vent zones) lie coincident with magnetic highs suggesting the presence of dike intrusions at depth which may represent a potentially young source of heat. Soil CO2 fluxes were measured along transects across geophysically-defined faults and fractures as well as young cinder cones along the HSWRZ. This survey generally did not detect CO2 levels above background, with the exception of a weak anomalous flux signal over one young cinder cone. The general lack of observed CO2 flux signals on the HSWRZ is likely due to a combination of lower magmatic CO2 fluxes and relatively high biogenic surface CO2 fluxes which mix with the magmatic signal. Similar surveys at the Puna geothermal field on the Kilauea Lower East Rift Zone (KLERZ) also showed a lack of surface CO2 flux signals, however aqueous geochemistry indicated contribution of magmatic CO2 and He to shallow groundwater here. As magma has been intercepted in geothermal drilling at the Puna field, the lack of measured surface CO2 flux indicative of upflow of magmatic fluids here is likely due to effective “scrubbing” by high groundwater and a mature hydrothermal system. Dissolved inorganic carbon (DIC) concentrations, δ13C compositions and 3He/4He values were sampled at Maui from several shallow

  3. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This report describes and assesses the aging process and related environmental aspects that may provide useful insights toward postponing some of the inevitable effects of aging. Although the Panel on Aging and the Geochemical Environment is convinced that the geochemical environment is associated with aging, it of course recognizes that other factors may also be significant or, perhaps, more important. Accordingly, the report is intended to enhance the awareness of biomedical and geochemical research scientists, decision makers in related areas, and the lay public interested in an understanding of the relation of the geochemical environment to senescence.

  4. User's Guide of TOUGH2-EGS. A Coupled Geomechanical and Reactive Geochemical Simulator for Fluid and Heat Flow in Enhanced Geothermal Systems Version 1.0

    SciTech Connect (OSTI)

    Fakcharoenphol, Perapon; Xiong, Yi; Hu, Litang; Winterfeld, Philip H.; Xu, Tianfu; Wu, Yu-Shu

    2013-05-01

    TOUGH2-EGS is a numerical simulation program coupling geomechanics and chemical reactions for fluid and heat flows in porous media and fractured reservoirs of enhanced geothermal systems. The simulator includes the fully-coupled geomechanical (THM) module, the fully-coupled geochemical (THC) module, and the sequentially coupled reactive geochemistry (THMC) module. The fully-coupled flow-geomechanics model is developed from the linear elastic theory for the thermo-poro-elastic system and is formulated with the mean normal stress as well as pore pressure and temperature. The chemical reaction is sequentially coupled after solution of flow equations, which provides the flow velocity and phase saturation for the solute transport calculation at each time step. In addition, reservoir rock properties, such as porosity and permeability, are subjected to change due to rock deformation and chemical reactions. The relationships between rock properties and geomechanical and chemical effects from poro-elasticity theories and empirical correlations are incorporated into the simulator. This report provides the user with detailed information on both mathematical models and instructions for using TOUGH2-EGS for THM, THC or THMC simulations. The mathematical models include the fluid and heat flow equations, geomechanical equation, reactive geochemistry equations, and discretization methods. Although TOUGH2-EGS has the capability for simulating fluid and heat flows coupled with both geomechanical and chemical effects, it is up to the users to select the specific coupling process, such as THM, THC, or THMC in a simulation. There are several example problems illustrating the applications of this program. These example problems are described in details and their input data are presented. The results demonstrate that this program can be used for field-scale geothermal reservoir simulation with fluid and heat flow, geomechanical effect, and chemical reaction in porous and fractured media.

  5. Geochemical Speciation Mass Transfer

    Energy Science and Technology Software Center (OSTI)

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less

  6. Category:Geochemical Techniques | Open Energy Information

    Open Energy Info (EERE)

    Techniques Technique Subcategories This category has only the following subcategory. G + Geochemical Data Analysis (2 categories) 4 pages Pages in category "Geochemical...

  7. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical ...

  8. Downhole pipe selection for acoustic telemetry

    DOE Patents [OSTI]

    Drumheller, Douglas S.

    1995-01-01

    A system for transmitting signals along a downhole string including a plurality of serially connected tubular pipes such as drill or production pipes, a transmitter for transmitting a signal along the string and a receiver for receiving the signal placed along the string at a location spaced from said transmitting means, wherein the pipes between the transmitter and the receiver are ordered according to length of tube to minimize loss of signal from said transmitter to said receiver.

  9. Downhole pipe selection for acoustic telemetry

    DOE Patents [OSTI]

    Drumheller, D.S.

    1995-12-19

    A system is described for transmitting signals along a downhole string including a plurality of serially connected tubular pipes such as drill or production pipes, a transmitter for transmitting a signal along the string and a receiver for receiving the signal placed along the string at a location spaced from said transmitting means, wherein the pipes between the transmitter and the receiver are ordered according to length of tube to minimize loss of signal from said transmitter to said receiver. 7 figs.

  10. OIT Wireless Telemetry for Industrial Applications

    SciTech Connect (OSTI)

    Manges, WW

    2002-09-03

    The need for advanced wireless technology has been identified in the National Research Council publication (1) ''Manufacturing Process Controls for the Industries of the Future as a Critical Technology for the Future''. The deployment challenges to be overcome in order for wireless to be a viable option include: (1) eliminating interference (assuring reliable communications); (2) easing the deployment of intelligent, wireless sensors; (3) developing reliable networks (robust architectures); (4) developing remote power (long-lasting and reliable); and (5) developing standardized communication protocols. This project demonstrated the feasibility of robust wireless sensor networks that could meet these requirements for the harsh environments common to the DOE/OIT Industries of the Future. It resulted in a wireless test bed that was demonstrated in a paper mill and a steel plant. The test bed illustrated key protocols and components that would be required in a real-life, wireless network. The technologies for low power connectivity developed and demonstrated at the plant eased fears that the radios would interfere with existing control equipment. The same direct sequence, spread spectrum (DSSS) technology that helped assure the reliability of the connection also demonstrated that wireless communication was feasible in these plants without boosting the transmitted power to dangerous levels. Our experience and research have indicated that two key parameters are of ultimate importance: (1) reliability and (2) inter-system compatibility. Reliability is the key to immediate acceptance among industrial users. The importance cannot be overstated, because users will not tolerate an unreliable information network. A longer term issue that is at least as important as the reliability of a single system is the inter-system compatibility between these wireless sensor networks and other wireless systems that are part of our industries. In the long run, the ability of wireless sensor

  11. Equatorial hydrology studies by satellite telemetry

    SciTech Connect (OSTI)

    Clegg, B.; Koranda, J.; Robison, W.; Holladay, G.

    1980-12-30

    We are using a geostationary satellite functioning as a transponder to collect surface environmental data to describe the fate of soil-borne radionuclides. The remote, former atomic testing grounds at the Enewetak and Bikini Atolls present a difficult environment in which to collect continuous field data. Our land-based, solar-powered microprocessor and environmental data systems remotely measure net and total solar radiation, rain, humidity, temperature, and soil-water potentials. For the past year, our water-flux model predicted wet season plant-transpiration rates nearly equal to the 6- to 7-mm/d evaporation-pan rate, which decreases to 2 to 3 mm/d for the dry season. From the microclimate data we estimated a 1:3 and 1:20 /sup 137/Cs dry-matter concentration ratio, which was later confirmed by radioisotopic analysis. This ratio exacerbates the dose to man from intake of food plants. Nephelometer measurements of airborne particulates presently indicate a minimum respiratory radiological dose.

  12. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    The report describes and assesses the aging process and related environmental aspects. Specific geographic areas of increased and decreased longevity were identified and geochemically characterized in terms of surface rocks, drinking water quality, soils, and abnormal absorption of trace elements by plants. Environmental factors that may be related to increased longevity are discussed. 11 references, 32 figures, 8 tables. (ACR)

  13. Acoustic Telemetry Evaluation of Juvenile Salmonid Passage and Survival at John Day Dam with Emphasis on the Prototype Surface Flow Outlet, 2008

    SciTech Connect (OSTI)

    Weiland, Mark A.; Ploskey, Gene R.; Hughes, James S.; Deng, Zhiqun; Fu, Tao; Monter, Tyrell J.; Johnson, Gary E.; Khan, Fenton; Wilberding, Matthew C.; Cushing, Aaron W.; Zimmerman, Shon A.; Faber, Derrek M.; Durham, Robin E.; Townsend, Richard L.; Skalski, John R.; Kim, Jina; Fischer, Eric S.; Meyer, Matthew M.

    2009-12-01

    The main purpose of the study was to evaluate the performance of Top Spill Weirs installed at two spillbays at John Day Dam and evaluate the effectiveness of these surface flow outlets at attracting juvenile salmon away from the powerhouse and reducing turbine passage. The Juvenile Salmonid Acoustic Telemetry System (JSATS) was used to estimate survival of juvenile salmonids passing the dam and also for calculating performance metrics used to evaluate the efficiency and effectiveness of the dam at passing juvenile salmonids.

  14. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  15. Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    Information Provided by Technique Lithology: StratigraphicStructural: Hydrological: Thermal: Dictionary.png Geochemical Data Analysis: No definition has been provided for...

  16. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... in a well-characterized structural context (permeability and alteration) in order to ... and geochemical data integration and model Innovative approach combining structural ...

  17. Book Review - Geochemical Exploration 1982 | Open Energy Information

    Open Energy Info (EERE)

    Book Review - Geochemical Exploration 1982 Jump to: navigation, search OpenEI Reference LibraryAdd to library Book Review: Book Review - Geochemical Exploration 1982 Author R. A....

  18. Computer Modeling of Chemical and Geochemical Processes in High...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer modeling of chemical and geochemical processes in high ionic strength solutions ... in brine Computer modeling of chemical and geochemical processes in high ionic ...

  19. Application Of Geochemical Methods In The Search For Geothermal...

    Open Energy Info (EERE)

    Geochemical Methods In The Search For Geothermal Fields Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Application Of Geochemical Methods In...

  20. Validation of the WATEQ4 geochemical model for uranium

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.; Deutsch, W.J.

    1983-09-01

    As part of the Geochemical Modeling and Nuclide/Rock/Groundwater Interactions Studies Program, a study was conducted to partially validate the WATEQ4 aqueous speciation-solubility geochemical model for uranium. The solubility controls determined with the WATEQ4 geochemical model were in excellent agreement with those laboratory studies in which the solids schoepite (UO/sub 2/(OH)/sub 2/ . H/sub 2/O), UO/sub 2/(OH)/sub 2/, and rutherfordine ((UO/sub 2/CO/sub 3/) were identified as actual solubility controls for uranium. The results of modeling solution analyses from laboratory studies of uranyl phosphate solids, however, identified possible errors in the characterization of solids in the original solubility experiments. As part of this study, significant deficiencies in the WATEQ4 thermodynamic data base for uranium solutes and solids were corrected. Revisions included recalculation of selected uranium reactions. Additionally, thermodynamic data for the hydroxyl complexes of U(VI), including anionic (VI) species, were evaluated (to the extent permitted by the available data). Vanadium reactions were also added to the thermodynamic data base because uranium-vanadium solids can exist in natural ground-water systems. This study is only a partial validation of the WATEQ4 geochemical model because the available laboratory solubility studies do not cover the range of solid phases, alkaline pH values, and concentrations of inorganic complexing ligands needed to evaluate the potential solubility of uranium in ground waters associated with various proposed nuclear waste repositories. Further validation of this or other geochemical models for uranium will require careful determinations of uraninite solubility over the pH range of 7 to 10 under highly reducing conditions and of uranyl hydroxide and phosphate solubilities over the pH range of 7 to 10 under oxygenated conditions.

  1. Geothermal/Geochemical Database | Open Energy Information

    Open Energy Info (EERE)

    to library Chart: GeothermalGeochemical DatabaseInfo GraphicMapChart Author Nevada Bureau of Mines and Geology Published Nevada Bureau of Mines and Geology, 2012 DOI Not...

  2. Nanogeochemistry: Geochemical reactions and mass transfers in...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores ... OSTI Identifier: 913493 Report Number(s): SAND2003-0369J Journal ID: ISSN 0091-7613; TRN: ...

  3. Integrated model for the natural flow regime in the Cerro Prieto hydrothermal system, B. C. , Mexico, based upon petrological and isotope geochemical criteria

    SciTech Connect (OSTI)

    Elders, W.A.; Williams, A.E.; Hoagland, J.R.

    1981-01-01

    Studies of cuttings and core at Cerro Prieto have now been extended to more than 50 boreholes. The aims of this petrological and isotopic work are to determine the shape of the reservoir, its physical properties, and its temperature distribution and flow regime before the steam field was produced. A map showing the first occurrence of hydrothermal epidote shows a dome-shaped top to the steam-producing zone. The hottest of the mapped mineral zones - the biotite vermiculite zone - shows a dome displaced to the northeast relative to the epidote zone. Patterns of mineral zones observed in wells are consistent with patterns of oxygen isotopic ratios in calcite and quartz. Using both criteria all of the boreholes so far studied were classified as belonging to one of four different regimes. These are: (a) the thermal plume of upward flowing water close to boiling, marked by a regular sequence of prograde mineral zones and large isotopic shifts; (b) the discharge system where fluid leaks to the surface, as indicated by the occurrence of only a few low temperature mineral zones, which extend over large depth intervals with little isotope exchange; (c) the horizontal flow zone, in which boreholes penetrate reversals of both mineral zones and isotope shifts with increasing depth; and (d) the recharge zone where cold water is descending. Plotting these four types of boreholes on a map reveals a simple, consistent, pattern. This is interpreted to have been produced by a thermal plume dipping at 45/sup 0/ to the northeast.

  4. Geochemical Mud Logging of geothermal drilling

    SciTech Connect (OSTI)

    Tonani, F.B.; Guidi, M.; Johnson, S.D.

    1988-01-01

    The experience and results described in the present paper were developed over nearly two decades, with a major R&D project around 1980. The expression Geochemical Mud Logging (GML) has ill defined meaning in the geothermal industry, and ought to be specified. We refer here to GML as featuring mud and formation fluid tracer(s) and temperature as the bare essentials and with specified accuracies. Air and water logging are expected to be less demanding with regard to analysis accuracy, but are not discussed in this report. During application of GML to several drill holes with low formation permeabilities and under conditions of high temperature and high mud weight, GML as specified, revealed unexpected influx of formation brine. Such influx was a recurring feature that has been referenced to individual fractures and reflects both fracture size and permeability. As a consequence, continuous or subcontinuous sampling of mud systems appears more cost effective than trying to keep up with cumulative changes of bulk mud composition; although, the latter approach is more sensitive to extremely low rate, steady, inflow of formation fluid into the mud system. It appears, that based on this influx of formation fluid, permeability can be estimated well before mud losses are detected and/or drill strings are stuck. The main advantages of GML are: (1) the capability to assess formation temperature and permeability in nearly real time, resulting in (a) assessments of undisturbed formation and (b) having data in hand for holes lost during drilling operations and (2) being effective under conditions of very high temperatures where electrical logs are very costly and less reliable. Estimated cost for GML is $1500 per day (1982) based on assessments of R&D operations. However, extrapolating to larger scale services and to different operating conditions is indeed difficult. GML cost is probably the only significant point of controversy with regard to GML being a viable evaluation tool.

  5. Monitoring and Analysis of In-Pile Phenomena in Advanced Test Reactor using Acoustic Telemetry

    SciTech Connect (OSTI)

    Agarwal, Vivek; Smith, James A.; Jewell, James Keith

    2015-02-01

    The interior of a nuclear reactor presents a particularly harsh and challenging environment for both sensors and telemetry due to high temperatures and high fluxes of energetic and ionizing particles among the radioactive decay products. A number of research programs are developing acoustic-based sensing approach to take advantage of the acoustic transmission properties of reactor cores. Idaho National Laboratory has installed vibroacoustic receivers on and around the Advanced Test Reactor (ATR) containment vessel to take advantage of acoustically telemetered sensors such as thermoacoustic (TAC) transducers. The installation represents the first step in developing an acoustic telemetry infrastructure. This paper presents the theory of TAC, application of installed vibroacoustic receivers in monitoring the in-pile phenomena inside the ATR, and preliminary data processing results.

  6. Geochemical Reaction Mechanism Discovery from Molecular Simulation

    SciTech Connect (OSTI)

    Stack, Andrew G.; Kent, Paul R. C.

    2014-11-10

    Methods to explore reactions using computer simulation are becoming increasingly quantitative, versatile, and robust. In this review, a rationale for how molecular simulation can help build better geochemical kinetics models is first given. We summarize some common methods that geochemists use to simulate reaction mechanisms, specifically classical molecular dynamics and quantum chemical methods and discuss their strengths and weaknesses. Useful tools such as umbrella sampling and metadynamics that enable one to explore reactions are discussed. Several case studies wherein geochemists have used these tools to understand reaction mechanisms are presented, including water exchange and sorption on aqueous species and mineral surfaces, surface charging, crystal growth and dissolution, and electron transfer. The impact that molecular simulation has had on our understanding of geochemical reactivity are highlighted in each case. In the future, it is anticipated that molecular simulation of geochemical reaction mechanisms will become more commonplace as a tool to validate and interpret experimental data, and provide a check on the plausibility of geochemical kinetic models.

  7. Geochemical Reaction Mechanism Discovery from Molecular Simulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stack, Andrew G.; Kent, Paul R. C.

    2014-11-10

    Methods to explore reactions using computer simulation are becoming increasingly quantitative, versatile, and robust. In this review, a rationale for how molecular simulation can help build better geochemical kinetics models is first given. We summarize some common methods that geochemists use to simulate reaction mechanisms, specifically classical molecular dynamics and quantum chemical methods and discuss their strengths and weaknesses. Useful tools such as umbrella sampling and metadynamics that enable one to explore reactions are discussed. Several case studies wherein geochemists have used these tools to understand reaction mechanisms are presented, including water exchange and sorption on aqueous species and mineralmore » surfaces, surface charging, crystal growth and dissolution, and electron transfer. The impact that molecular simulation has had on our understanding of geochemical reactivity are highlighted in each case. In the future, it is anticipated that molecular simulation of geochemical reaction mechanisms will become more commonplace as a tool to validate and interpret experimental data, and provide a check on the plausibility of geochemical kinetic models.« less

  8. Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Rifle Processing Site, Colorado | Department of Energy and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado

  9. Novel Coupled Thermochronometric and Geochemical Investigation of Blind

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Resources in Fault-Controlled Dilational Corners | Department of Energy Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners presentation at the

  10. Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

    Energy Science and Technology Software Center (OSTI)

    2013-05-01

    Development of a hierarchical Bayesian model to estimate the spatiotemporal distribution of aqueous geochemical parameters associated with in-situ bioremediation using surface spectral induced polarization (SIP) data and borehole geochemical measurements collected during a bioremediation experiment at a uranium-contaminated site near Rifle, Colorado. The SIP data are first inverted for Cole-Cole parameters including chargeability, time constant, resistivity at the DC frequency and dependence factor, at each pixel of two-dimensional grids using a previously developed stochastic method.more » Correlations between the inverted Cole-Cole parameters and the wellbore-based groundwater chemistry measurements indicative of key metabolic processes within the aquifer (e.g. ferrous iron, sulfate, uranium) were established and used as a basis for petrophysical model development. The developed Bayesian model consists of three levels of statistical sub-models: 1) data model, providing links between geochemical and geophysical attributes, 2) process model, describing the spatial and temporal variability of geochemical properties in the subsurface system, and 3) parameter model, describing prior distributions of various parameters and initial conditions. The unknown parameters are estimated using Markov chain Monte Carlo methods. By combining the temporally distributed geochemical data with the spatially distributed geophysical data, we obtain the spatio-temporal distribution of ferrous iron, sulfate and sulfide, and their associated uncertainity information. The obtained results can be used to assess the efficacy of the bioremediation treatment over space and time and to constrain reactive transport models.« less

  11. Acoustic Telemetry Evaluation of Juvenile Salmonid Passage and Survival Proportions at John Day Dam, 2009

    SciTech Connect (OSTI)

    Weiland, Mark A.; Ploskey, Gene R.; Hughes, James S.; Deng, Zhiqun; Fu, Tao; Kim, Jin A.; Johnson, Gary E.; Fischer, Eric S.; Khan, Fenton; Zimmerman, Shon A.; Faber, Derrek M.; Carter, Kathleen M.; Boyd, James W.; Townsend, Richard L.; Skalski, J. R.; Monter, Tyrell J.; Cushing, Aaron W.; Wilberding, Matthew C.; Meyer, Matthew M.

    2011-09-28

    The overall purpose of the acoustic telemetry study at JDA during 2009 was to determine the best configuration and operation for JDA prior to conducting BiOp performance standard tests. The primary objective was to determine the best operation between 30% and 40% spill treatments. Route-specific and JDA to TDA forebay survival estimates, passage distribution, and timing/behavior metrics were used for comparison of 30% to a 40% spill treatments. A secondary objective was to evaluate the performance of TSWs installed in spill bays 15 and 16 and to estimate fish survival rates and passage efficiencies under 30% and 40% spill-discharge treatments each season.

  12. Laser telemetry

    SciTech Connect (OSTI)

    Clark, L.K.; Peron, M.C.

    1982-10-12

    A projectile carries a laser transmitter which directs its output beam to the rear through an aperture in the projectile. The beam is coded (Modulated) in accordance with the start or stop of events or flight conditions being monitored by one or more transducers in the projectile. The beam is initially pulsed at a known reference rate from a thermal battery automatically activated by the launching acceleration of the projectile. Thus, occurrence of an event or condition will change the laser frequency to a new predetermined rate. The beam can be decoded at a receiving station in the vicinity of the launching site.

  13. Acoustic Telemetry Studies of Juvenile Chinook Salmon Survival at the Lower Columbia Projects in 2006

    SciTech Connect (OSTI)

    Ploskey, Gene R.; Weiland, Mark A.; Hughes, James S.; Zimmerman, Shon A.; Durham, Robin E.; Fischer, Eric S.; Kim, Jina; Townsend, Richard L.; Skalski, John R.; McComas, Roy L.

    2008-02-01

    The Portland District of the U.S. Army Corps of Engineers contracted with the Pacific Northwest National Laboratory (PNNL) to conduct three studies using acoustic telemetry to estimate detection probabilities and survival of juvenile Chinook salmon at three hydropower projects on the lower Columbia River. The primary goals were to estimate detection and survival probabilities based on sampling with JSATS equipment, assess the feasibility of using JSATS for survival studies, and estimate sample sizes needed to obtain a desired level of precision in future studies. The 2006 JSATS arrays usually performed as well or better than radio telemetry arrays in the JDA and TDA tailwaters, and underperformed radio arrays in the BON tailwater, particularly in spring. Most of the probabilities of detection on at least one of all arrays in a tailwater exceeded 80% for each method, which was sufficient to provide confidence in survival estimates. The probability of detection on one of three arrays includes survival and detection probabilities because fish may die or pass all three arrays undetected but alive.

  14. A Geochemical Speciation Program Based on PHREEQE

    Energy Science and Technology Software Center (OSTI)

    1992-02-18

    HARPHRQ is a program based on the code PHREEQE and is designed to model geochemical reactions. Like PHREEQE, it can calculate the pH, redox potential and mass transfer as a function of reaction progress and the composition of solution in equilibrium with multiple phases. In addition, HARPHRQ includes options to allow the composition of a solution at a fixed pH to be calculated and to automatically add or remove mineral phases as they become saturatedmore » or exhausted. A separate module can also be interfaced to give a choice of sorption models including the triple-layer model.« less

  15. DNA-based methods of geochemical prospecting

    DOE Patents [OSTI]

    Ashby, Matthew

    2011-12-06

    The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

  16. Category:Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    category, out of 4 total. G Geochemical Data Analysis Geothermometry T Thermal Ion Dispersion Thermochronometry Retrieved from "http:en.openei.orgwindex.php?titleCategory:Ge...

  17. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon ...

  18. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Monitoring CO2 intrusion and associated geochemical transformations in a shallow ... Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated ...

  19. Merging high resolution geophysical and geochemical surveys to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships. ...

  20. The hydrogeologic-geochemical model of Cerro Prieto revisited

    SciTech Connect (OSTI)

    Lippmann, M.J.; Halfman, S.E.; Truesdell, A.H.; Manon M., A.

    1989-01-01

    As the exploitation of the Cerro Prieto, Mexico, geothermal field continues, there is increasing evidence that the hydrogeologic model developed by Halfman et al. (1984, 1986) presents the basic features controlling the movement of geothermal fluids in the system. At the present time the total installed capacity at Cerro Prieto is 620 MWe requiring the production of more than 10,500 tonnes/hr of a brine-steam mixture. This significant rate of fluid production has resulted in changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. After reviewing the hydrogeologic-geochemical model of Cerro Prieto, some of the changes observed in the field due to its exploitation are discussed and interpreted on the basis of the model. 21 refs., 11 figs., 1 tab.

  1. RF transmission line and drill/pipe string switching technology for down-hole telemetry

    DOE Patents [OSTI]

    Clark, David D.; Coates, Don M.

    2007-08-14

    A modulated reflectance well telemetry apparatus having an electrically conductive pipe extending from above a surface to a point below the surface inside a casing. An electrical conductor is located at a position a distance from the electrically conductive pipe and extending from above the surface to a point below the surface. Modulated reflectance apparatus is located below the surface for modulating well data into a RF carrier transmitted from the surface and reflecting the modulated carrier back to the surface. A RF transceiver is located at the surface and is connected between the electrically conductive pipe and the electrical conductor for transmitting a RF signal that is confined between the electrically conductive well pipe and the electrical conductor to the modulated reflectance apparatus, and for receiving reflected data on the well from the modulated reflectance apparatus.

  2. A Mineralogical Petrographic And Geochemical Study Of Samples...

    Open Energy Info (EERE)

    Mineralogical Petrographic And Geochemical Study Of Samples From Wells In The Geothermal Field Of Milos Island (Greece) Jump to: navigation, search OpenEI Reference LibraryAdd to...

  3. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  4. Geochemical and isotopic water results, Barrow, Alaska, 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Heikoop, Jeff; Wilson, Cathy; Newman, Brent

    2012-07-18

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  5. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Signals in the Subsurface | Department of Energy SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface Grand Challenge Workshop -Imaging Subsurface.pdf (434.52 KB) More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Presentation at Town Hall - American Geophysical Union Controlling Subsurface Fractures and Fluid Flow: A Basic

  6. Modeling Background Radiation in our Environment Using Geochemical Data

    SciTech Connect (OSTI)

    Malchow, Russell L.; Marsac, Kara; Burnley, Pamela; Hausrath, Elisabeth; Haber, Daniel; Adcock, Christopher

    2015-02-01

    Radiation occurs naturally in bedrock and soil. Gamma rays are released from the decay of the radioactive isotopes K, U, and Th. Gamma rays observed at the surface come from the first 30 cm of rock and soil. The energy of gamma rays is specific to each isotope, allowing identification. For this research, data was collected from national databases, private companies, scientific literature, and field work. Data points were then evaluated for self-consistency. A model was created by converting concentrations of U, K, and Th for each rock and soil unit into a ground exposure rate using the following equation: D=1.32 K+ 0.548 U+ 0.272 Th. The first objective of this research was to compare the original Aerial Measurement System gamma ray survey to results produced by the model. The second objective was to improve the method and learn the constraints of the model. Future work will include sample data analysis from field work with a goal of improving the geochemical model.

  7. Geochemical Modeling of ILAW Lysimeter Water Extracts

    SciTech Connect (OSTI)

    Cantrell, Kirk J.

    2014-12-22

    Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90°C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90°C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90°C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90°C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90°C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network than gibbsite under field conditions. This may be due to the

  8. How 12 geochemical methods fared in GERT project in Permian basin

    SciTech Connect (OSTI)

    Calhoun, G.G.

    1991-05-13

    This paper reports on Geochemical Evaluation Research Team (GERT) which is an experiment conceived to identify surface geochemical exploration methods that are effective in finding oil. Many of the methods use technology developed in the last 5 years. In fact, one of the challenging jobs for the geochemical explorationist is keeping up with new techniques and improvements. The way to minimize dry holes is to screen prospects with carefully selected geochemical techniques prior to acreage acquisition and seismic surveys.

  9. A Geochemical Model Of The Platanares Geothermal System, Honduras...

    Open Energy Info (EERE)

    concentrations reflect mixed cooling paths. Authors C. J. Janik, A. H. Truesdell, F. Goff, L. Shevenell, M. L. Stallard, P. E. Trujillo Jr and D. Counce Published Journal...

  10. Spatial And Temporal Geochemical Trends In The Hydrothermal System...

    Open Energy Info (EERE)

    tracking changes in river solute flux. Authors Shaul Hurwitz, Jacob B. Lowenstern and Henry Heasler Published Journal Journal of Volcanology and Geothermal Research, 2007 DOI Not...

  11. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-05-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  12. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-01-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  13. Self-Organized Pattern Formation in Sedimentary Geochemical Systems...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Word Cloud More Like This Full Text Books Please see Document Availability for additional information on obtaining the ...

  14. Blind Geothermal System Exploration in Active Volcanic Environments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt & Subtle Volcanic Systems, Hawaii & Maui Blind...

  15. Geochemical Triggers of Arsenic Mobilization during Managed Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recharge | Stanford Synchrotron Radiation Lightsource Geochemical Triggers of Arsenic Mobilization during Managed Aquifer Recharge Monday, February 29, 2016 Managed aquifer recharge (MAR) is an increasingly used water enhancement strategy, which involves subsurface storage of water supplies in groundwater aquifers. While MAR projects have the potential to alleviate water deficits, they can also adversely impact groundwater quality by altering the native geochemistry of the aquifer and

  16. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    2013-05-22

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  17. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  18. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  19. INEEL Subregional Conceptual Model Report Volume 2: Summary of Existing Knowledge of Geochemical Influences on the Fate and Transport of Contaminants in the Subsurface at the INEEL

    SciTech Connect (OSTI)

    Paul L. Wichlacz; Robert C. Starr; Brennon Orr

    2003-09-01

    This document summarizes previous descriptions of geochemical system conceptual models for the vadose zone and groundwater zone (aquifer) beneath the Idaho National Engineering and Environmental Laboratory (INEEL). The primary focus is on groundwater because contaminants derived from wastes disposed at INEEL are present in groundwater, groundwater provides a pathway for potential migration to receptors, and because geochemical characteristics in and processes in the aquifer can substantially affect the movement, attenuation, and toxicity of contaminants. The secondary emphasis is perched water bodies in the vadose zone. Perched water eventually reaches the regional groundwater system, and thus processes that affect contaminants in the perched water bodies are important relative to the migration of contaminants into groundwater. Similarly, processes that affect solutes during transport from nearsurface disposal facilities downward through the vadose zone to the aquifer are relevant. Sediments in the vadose zone can affect both water and solute transport by restricting the downward migration of water sufficiently that a perched water body forms, and by retarding solute migration via ion exchange. Geochemical conceptual models have been prepared by a variety of researchers for different purposes. They have been published in documents prepared by INEEL contractors, the United States Geological Survey (USGS), academic researchers, and others. The documents themselves are INEEL and USGS reports, and articles in technical journals. The documents reviewed were selected from citation lists generated by searching the INEEL Technical Library, the INEEL Environmental Restoration Optical Imaging System, and the ISI Web of Science databases. The citation lists were generated using the keywords ground water, groundwater, chemistry, geochemistry, contaminant, INEL, INEEL, and Idaho. In addition, a list of USGS documents that pertain to the INEEL was obtained and manually searched

  20. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  1. Precipitation in Pores: A Geochemical Frontier

    SciTech Connect (OSTI)

    Stack, Andrew G.

    2015-01-01

    This article's purpose is to review some of the recent research in which geochemists have examined precipitation of solid phases in porous media, particularly in pores a few nanometers in diameter (nanopores). While this is a “review,” it is actually more forward-looking in that the list of things about this phenomenon that we do not know or cannot control at this time is likely longer than what we do know and can control. For example, there are three directly contradictory theories on how to predict how precipitation proceeds in a medium of varying pore size, as will be discussed below. The confusion on this subject likely stems from the complexity of the phenomenon itself: One can easily clog a porous medium by inducing a rapid, homogeneous precipitation directly from solution, or have limited precipitation occur that does not affect permeability or even porosity substantially. It is more difficult to engineer mineral precipitation in order to obtain a specific outcome, such as filling all available pore space over a targeted area for the purposes of contaminant sequestration. However, breakthrough discoveries could occur in the next five to ten years that enhance our ability to predict robustly and finely control precipitation in porous media by understanding how porosity and permeability evolve in response to system perturbations. These discoveries will likely stem (at least in part) from advances in our ability to 1) perform and interpret X-ray/neutron scattering experiments that reveal the extent of precipitation and its locales within porous media (Anovitz and Cole 2015, this volume), and 2) utilize increasingly powerful simulations to test concepts and models about the evolution of porosity and permeability as precipitation occurs (Steefel et al. 2015, this volume). A further important technique to isolate specific phenomena and understand reactivity is also microfluidics cell experiments that allow specific control of flow paths and fluid velocities

  2. Precipitation in pores: A geochemical frontier

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stack, Andrew G.

    2015-07-29

    This article's purpose is to review some of the recent research in which geochemists have examined precipitation of solid phases in porous media, particularly in pores a few nanometers in diameter (nanopores). While this is a “review,” it is actually more forward-looking in that the list of things about this phenomenon that we do not know or cannot control at this time is likely longer than what we do know and can control. For example, there are three directly contradictory theories on how to predict how precipitation proceeds in a medium of varying pore size, as will be discussed below.more » The confusion on this subject likely stems from the complexity of the phenomenon itself: One can easily clog a porous medium by inducing a rapid, homogeneous precipitation directly from solution, or have limited precipitation occur that does not affect permeability or even porosity substantially. It is more difficult to engineer mineral precipitation in order to obtain a specific outcome, such as filling all available pore space over a targeted area for the purposes of contaminant sequestration. However, breakthrough discoveries could occur in the next five to ten years that enhance our ability to predict robustly and finely control precipitation in porous media by understanding how porosity and permeability evolve in response to system perturbations. These discoveries will likely stem (at least in part) from advances in our ability to 1) perform and interpret X-ray/neutron scattering experiments that reveal the extent of precipitation and its locales within porous media (Anovitz and Cole 2015, this volume), and 2) utilize increasingly powerful simulations to test concepts and models about the evolution of porosity and permeability as precipitation occurs (Steefel et al. 2015, this volume). A further important technique to isolate specific phenomena and understand reactivity is also microfluidics cell experiments that allow specific control of flow paths and fluid

  3. Workshop on hydrologic and geochemical monitoring in the Long Valley Caldera: proceedings

    SciTech Connect (OSTI)

    Sorey, M.L.; Farrar, C.D.; Wollenberg, H.A.

    1984-10-01

    A workshop reviewed the results of hydrologic and geochemical monitoring in the Long Valley caldera. Such monitoring is being done to detect changes in the hydrothermal system induced by ongoing magmatic and tectonic processes. Workshop participants discussed the need to instrument sites for continuous measurements of several parameters and to obtain additional hydrologic and chemical information from intermediate and deep drill holes. In addition to seismic and deformation monitoring, programs are currently in progress to monitor changes in the discharge characteristics of hot springs, fumaroles, and soil gases, as well as pressures and temperatures in wells. Some hydrochemical parameters are measured continuously, others are measured monthly or at longer intervals. This report summarizes the information presented at the hydrologic monitoring workshop, following the workshop agenda which was divided into four sessions: (1) overview of the hydrothermal system; (2) monitoring springs, fumaroles, and wells; (3) monitoring gas emissions; and (4) conclusions and recommendations.

  4. Assessment of Barotrauma Resulting from Rapid Decompression of Depth Acclimated Juvenile Chinook Salmon Bearing Radio Telemetry Transmitters

    SciTech Connect (OSTI)

    Brown, Richard S.; Carlson, Thomas J.; Welch, Abigail E.; Stephenson, John R.; Abernethy, Cary S.; McKinstry, Craig A.; Theriault, Marie-Helene

    2007-09-06

    A multifactor study was conducted by Battelle for the US Army Corps of Engineers to assess the significance of the presence of a radio telemetry transmitter on the effects of rapid decompression from simulated hydro turbine passage on depth acclimated juvenile run-of-the-river Chinook salmon. Study factors were: (1) juvenile chinook salmon age;, subyearling or yearling, (2) radio transmitter present or absent, (3) three transmitter implantation factors: gastric, surgical, and no transmitter, and (4) four acclimation depth factors: 1, 10, 20, and 40 foot submergence equivalent absolute pressure, for a total of 48 unique treatments. Exposed fish were examined for changes in behavior, presence or absence of barotrauma injuries, and immediate or delayed mortality. Logistic models were used to test hypotheses that addressed study objectives. The presence of a radio transmitter was found to significantly increase the risk of barotrauma injury and mortality at exposure to rapid decompression. Gastric implantation was found to present a higher risk than surgical implantation. Fish were exposed within 48 hours of transmitter implantation so surgical incisions were not completely healed. The difference in results obtained for gastric and surgical implantation methods may be the result of study design and the results may have been different if tested fish had completely healed surgical wounds. However, the test did simulate the typical surgical-release time frame for in-river telemetry studies of fish survival so the results are probably representative for fish passing through a turbine shortly following release into the river. The finding of a significant difference in response to rapid decompression between fish bearing radio transmitters and those not implies a bias may exist in estimates of turbine passage survival obtained using radio telemetry. However, the rapid decompression (simulated turbine passage) conditions used for the study represented near worst case exposure

  5. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns ofmore » dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.« less

  6. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    SciTech Connect (OSTI)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns of dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.

  7. EQ3/6 A Software Package for Geochemical Modeling

    Energy Science and Technology Software Center (OSTI)

    2010-12-13

    EQ3/6 is a software package for modeling geochemical interactions between aqueous solution, solids, and gases, following principles of chemical thermodynamics and chemical kinetics. It is useful for interpreting aqueiou solution chemical compositions and for calculating the consequences of reaction of such solutions with minerals, other solids, and gases. It is designed to run in a command line environment. EQPT is a thermodynamic data file preprocessor. EQ3NR is a speciation-solubility code. EQ6 is a reaction pathmore » code.« less

  8. New Mexico Play Fairway Analysis: New Mexico available wells for geochemical sampling

    SciTech Connect (OSTI)

    Jeff Pepin

    2015-11-15

    This is a map package that is used to show the wells in New Mexico that may be available for geochemical sampling.

  9. Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators

    Broader source: Energy.gov [DOE]

    Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators presentation at the April 2013 peer review meeting held in Denver, Colorado.

  10. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Citation Details...

  11. Inferences On The Hydrothermal System Beneath The Resurgent Dome...

    Open Energy Info (EERE)

    Inferences On The Hydrothermal System Beneath The Resurgent Dome In Long Valley Caldera, East-Central California, USA, From Recent Pumping Tests And Geochemical Sampling Jump to:...

  12. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnectionmore » of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is

  13. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnection of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much

  14. REAL-TIME TRACER MONITORING OF RESERVOIR STIMULATION PROCEDURES VIA ELECTRONIC WIRELINE AND TELEMETRY DATA TRANSMISSION

    SciTech Connect (OSTI)

    George Scott III

    2003-08-01

    Ongoing Phase 2-3 work comprises the final development and field-testing of two complementary real-time reservoir technologies; a stimulation process and a tracer fracturing diagnostic system. Initial DE-FC26-99FT40129 project work included research, development, and testing of the patented gamma tracer fracturing diagnostic system. This process was field-proven to be technically useful in providing tracer measurement of fracture height while fracturing; however, technical licensing restrictions blocked Realtimezone from fully field-testing this real-time gamma diagnostic system, as originally planned. Said restrictions were encountered during Phase 2 field test work as result of licensing limitations and potential conflicts between service companies participating in project work, as related to their gamma tracer logging tool technology. Phase 3 work principally demonstrated field-testing of Realtimezone (RTZ) and NETL's Downhole-mixed Reservoir Stimulation process. Early on, the simplicity of and success of downhole-mixing was evident from well tests, which were made commercially productive. A downhole-mixed acid stimulation process was tested successfully and is currently commercially used in Canada. The fourth well test was aborted due to well bore conditions, and an alternate test project is scheduled April, 2004. Realtimezone continues to effectuate ongoing patent protection in the United States and foreign markets. In 2002, Realtimezone and the NETL licensed their United States patent to Halliburton Energy Services (HES). Additional licensing arrangements with other industry companies are anticipated in 2004-2005. Ongoing Phase 2 and Phase 3 field-testing continues to confirm applications of both real-time technologies. Technical data transfer to industry is ongoing via Internet tech-transfer and various industry presentations and publications including Society of Petroleum Engineers. These real-time enhanced stimulation procedures should significantly

  15. Acoustic Telemetry Evaluation of Juvenile Salmonid Passage and Survival at John Day Dam, 2010

    SciTech Connect (OSTI)

    Weiland, Mark A.; Woodley, Christa M.; Ploskey, Gene R.; Hughes, James S.; Kim, Jin A.; Deng, Zhiqun; Fu, Tao; Fischer, Eric S.; Skalski, J. R.; Townsend, Richard L.; Duncan, Joanne P.; Hennen, Matthew J.; Wagner, Katie A.; Arntzen, Evan V.; Miller, Benjamin L.; Miracle, Ann L.; Zimmerman, Shon A.; Royer, Ida M.; Khan, Fenton; Cushing, Aaron W.; Etherington, D. J.; Mitchell, T. D.; Elder, T.; Batton, George; Johnson, Gary E.; Carlson, Thomas J.

    2013-05-01

    This report presents survival, behavioral, and fish passage results for yearling and subyearling Chinook salmon smolts and juvenile steelhead tagged with JSATS acoustic micro-transmitters as part of a survival study conducted at John Day Dam during 2010. This study was designed to evaluate the passage and survival of yearling and subyearling Chinook salmon and juvenile steelhead to assist managers in identifying dam operations for compliance testing as stipulated by the 2008 Federal Columbia River Power System Biological Opinion and the 2008 Columbia Basin Fish Accords. Survival estimates were based on a single-release survival estimate model.

  16. Acoustic Telemetry Evaluation of Juvenile Salmonid Passage and Survival at John Day Dam, 2011

    SciTech Connect (OSTI)

    Weiland, Mark A.; Woodley, Christa M.; Ploskey, Gene R.; Hughes, James S.; Hennen, Matthew J.; Kim, Jin A.; Deng, Zhiqun; Fu, Tao; Skalski, J. R.; Townsend, Richard L.; Wagner, Katie A.; Fischer, Eric S.; Duncan, Joanne P.; Batten, G.; Carlson, Thomas J.; Carpenter, Scott M.; Cushing, Aaron W.; Elder, T.; Etherington, D. J.; Johnson, Gary E.; Khan, Fenton; Miracle, Ann L.; Mitchell, T. D.; Prather, K.; Rayamajhi, Bishes; Royer, Ida; Seaburg, Adam; Zimmerman, Shon A.

    2013-06-21

    This report presents survival, behavioral, and fish passage results for tagged yearling Chinook salmon and juvenile steelhead as part of a survival study conducted at John Day Dam during spring 2011. This study was designed to evaluate the passage and survival of yearling Chinook salmon and juvenile steelhead to assist managers in identifying dam operations for compliance testing as stipulated by the 2008 Federal Columbia River Power System Biological Opinion and the 2008 Columbia Basin Fish Accords. Survival estimates were based on a paired-release survival model.

  17. REAL-TIME TRACER MONITORING OF RESERVOIR STIMULATION PROCEDURES VIA ELECTRONIC WIRELINE AND TELEMETRY DATA TRANSMISSION

    SciTech Connect (OSTI)

    George L. Scott III

    2005-01-01

    Finalized Phase 2-3 project work has field-proven two separate real-time reservoir processes that were co-developed via funding by the National Energy Technology Laboratory (NETL). Both technologies are presently patented in the United States and select foreign markets; a downhole-commingled reservoir stimulation procedure and a real-time tracer-logged fracturing diagnostic system. Phase 2 and early Phase 3 project work included the research, development and well testing of a U.S. patented gamma tracer fracturing diagnostic system. This stimulation logging process was successfully field-demonstrated; real-time tracer measurement of fracture height while fracturing was accomplished and proven technically possible. However, after the initial well tests, there were several licensing issues that developed between service providers that restricted and minimized Realtimezone's (RTZ) ability to field-test the real-time gamma diagnostic system as was originally outlined for this project. Said restrictions were encountered after when one major provider agreed to license their gamma logging tools to another. Both of these companies previously promised contributory support toward Realtimezone's DE-FC26-99FT40129 project work, however, actual support was less than desired when newly-licensed wireline gamma logging tools from one company were converted by the other from electric wireline into slickline, batter-powered ''memory'' tools for post-stimulation logging purposes. Unfortunately, the converted post-fracture measurement memory tools have no applications in experimentally monitoring real-time movement of tracers in the reservoir concurrent with the fracturing treatment. RTZ subsequently worked with other tracer gamma-logging tool companies for basic gamma logging services, but with lessened results due to lack of multiple-isotope detection capability. In addition to real-time logging system development and well testing, final Phase 2 and Phase 3 project work included the

  18. GIS Regional Spatial Data from the Great Basin Center for Geothermal Energy: Geochemical, Geodesic, Geologic, Geophysical, Geothermal, and Groundwater Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Great Basin Center for Geothermal Energy, part of the University of Nevada, Reno, conducts research towards the establishment of geothermal energy as an economically viable energy source within the Great Basin. The Center specializes in collecting and synthesizing geologic, geochemical, geodetic, geophysical, and tectonic data, and using Geographic Information System (GIS) technology to view and analyze this data and to produce favorability maps of geothermal potential. The center also makes its collections of spatial data available for direct download to the public. Data are in Lambert Conformable Conic Projection.

  19. WATEQ3 geochemical model: thermodynamic data for several additional solids

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

  20. Sampling designs for geochemical baseline studies in the Colorado oil shale region: a manual for practical application

    SciTech Connect (OSTI)

    Klusman, R. W.; Ringrose, C. D.; Candito, R. J.; Zuccaro, B.; Rutherford, D. W.; Dean, W. E.

    1980-06-01

    This manual presents a rationale for sampling designs, and results of geochemical baseline studies in the Colorado portion of the oil-shale region. The program consists of a systematic trace element study of soils, stream sediments, and plants carried out in a way to be conservative of human and financial resources and yield maximum information. Extension of this approach to other parameters, other locations, and to environmental baseline studies in general is a primary objective. A baseline for any geochemical parameter can be defined as the concentration of that parameter in a given medium such as soil, the range of its concentration, and the geographic scale of variability. In air quality studies, and to a lesser extent for plants, the temporal scale of variability must also be considered. In studies of soil, the temporal variablility does not become a factor until such time that a study is deemed necessary to evaluate whether or not there have been changes in baseline levels as a result of development. The manual is divided into five major parts. The first is a suggested sampling protocol which is presented in an outline form for guiding baseline studies in this area. The second section is background information on the physical features of the area of study, trace elements of significance occurring in oil shale, and the sample media used in these studies. The third section is concerned primarily with sampling design and its application to the geochemical studies of the oil shale region. The last sections, in the form of appendices, provide actual data and illustrate in a systematic manner, the calculations performed to obtain the various summary data. The last segment of the appendices is a more academic discussion of the geochemistry of trace elements and the parameters of importance influencing their behavior in natural systems.

  1. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  2. A Geological and Hydro-Geochemical Study of the Animas Geothermal...

    Open Energy Info (EERE)

    Hydro-Geochemical Study of the Animas Geothermal Area, Hidalgo County, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Geological...

  3. 31 TAC, part 1, chapter 9, rule 9.11 Geophysical and Geochemical...

    Open Energy Info (EERE)

    9, rule 9.11 Geophysical and Geochemical Exploration Permits Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 31 TAC, part...

  4. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Bacon, Diana H. carbon...

  5. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review - 2010. The primary objective of this project is to combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships.

  6. A geochemical model of the Kilauea east rift zone | Open Energy...

    Open Energy Info (EERE)

    rift zone Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A geochemical model of the Kilauea east rift zone Abstract NA Author Donald Thomas...

  7. Geochemical Monitoring Considerations for the FutureGen 2.0 Project

    SciTech Connect (OSTI)

    Amonette, James E.; Johnson, Timothy A.; Spencer, Clayton F.; Zhong, Lirong; Szecsody, James E.; Vermeul, Vince R.

    2014-12-31

    Geochemical monitoring is an essential component of a suite of monitoring technologies designed to evaluate CO2 mass balance and detect possible loss of containment at the FutureGen 2.0 geologic sequestration site near Jacksonville, IL. This presentation gives an overview of the potential geochemical approaches and tracer technologies that were considered, and describes the evaluation process by which the most cost-effective and robust of these were selected for implementation

  8. Natural bacterial communities serve as quantitative geochemical biosensors

    SciTech Connect (OSTI)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; Earles, Jennifer E.; Phillips, Jana; Techtmann, Steve M.; Joyner, Dominique C.; Elias, Dwayne A.; Bailey, Kathryn L.; Hurt, Richard A.; Preheim, Sarah P.; Sanders, Matthew C.; Yang, Joy; Mueller, Marcella A.; Brooks, Scott; Watson, David B.; Zhang, Ping; He, Zhili; Dubinsky, Eric A.; Adams, Paul D.; Arkin, Adam P.; Fields, Matthew W.; Zhou, Jizhong; Alm, Eric J.; Hazen, Terry C.

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination, even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.

  9. Geochemical characteristics of bitumens and seeps from Tanzania

    SciTech Connect (OSTI)

    Mpanju, F. ); Philp, P. )

    1991-03-01

    A number of bitumen extracts from prospective source rocks and oil seeps of potential oil-producing areas in Tanzania have been characterized by a variety of geochemical techniques. The data obtained from this study have provided additional insight into the source rock potential of these areas. However, in this paper it is proposed to discuss in detail the results from two of the more unusual samples in this region, namely Wingayongo and Pemba. The Wingayongo bitumens isolated from an exposed Neocomian-aged sandstone, possibly a paleoreservoir, are almost totally devoid of n-alkanes and steranes and dominated by hopane-type biomarkers with the so-called immature {beta}{beta}-stereochemistry at the C{sub 17} and C{sub 21} positions. There is no typical evidence of biodegradation having occurred leading to the proposal of an unusual source material or maturity history for this sample. The Pemba seep samples were also characterized by relatively high concentrations of hopanes with the immature stereochemistry at the C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21}. On the basis of these data, it is proposed that the seeps in the Pemba region are not true oil seeps. Rather they are formed as a result of extremely high levels of bacterial activity with the bacteria utilizing natural gas in the region as the substrate. The net result is a material referred to in other areas of the world as paraffin dirt whose occurrence results from extensive microbial activity in the region and not directly from seepage of products having a thermal origin.

  10. Natural bacterial communities serve as quantitative geochemical biosensors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; et al

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination,more » even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.« less

  11. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at glass buttes, Oregon

    SciTech Connect (OSTI)

    Walsh, Patrick; Fercho, Steven; Perkin, Doug; Martini, Brigette; Boshmann, Darrick

    2015-06-01

    The engineering and studies phase of the Glass Buttes project was aimed at reducing risk during the early stages of geothermal project development. The project’s inclusion of high resolution geophysical and geochemical surveys allowed Ormat to evaluate the value of these surveys both independently and in combination to quantify the most valuable course of action for exploration in an area where structure, permeability, and temperature are the most pressing questions. The sizes of the thermal anomalies at Glass Buttes are unusually large. Over the course of Phase I Ormat acquired high resolution LIDAR data to accurately map fault manifestations at the surface and collected detailed gravity and aeromagnetic surveys to map subsurface structural features. In addition, Ormat collected airborne hyperspectral data to assist with mapping the rock petrology and mineral alteration assemblages along Glass Buttes faults and magnetotelluric (MT) survey to try to better constrain the structures at depth. Direct and indirect identification of alteration assemblages reveal not only the geochemical character and temperature of the causative hydrothermal fluids but can also constrain areas of upflow along specific fault segments. All five datasets were merged along with subsurface lithologies and temperatures to predict the most likely locations for high permeability and hot fluids. The Glass Buttes temperature anomalies include 2 areas, totaling 60 km2 (23 mi2) of measured temperature gradients over 165° C/km (10° F/100ft). The Midnight Point temperature anomaly includes the Strat-1 well with 90°C (194 °F) at 603 m (1981 ft) with a 164 °C/km (10°F/100ft) temperature gradient at bottom hole and the GB-18 well with 71°C (160 °F) at 396 m (1300 ft) with a 182°C/km (11°F/100ft) gradient. The primary area of alteration and elevated temperature occurs near major fault intersections associated with Brothers Fault Zone and Basin and Range systems. Evidence for faulting is

  12. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Peters, Catherine A

    2013-02-28

    Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of

  13. Geochemical information for sites contaminated with low-level radioactive wastes: I. Niagara Falls Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1984-11-01

    The Niagara Falls Storage Site (NFSS) became radioactively contaminated as a result of wastes that were being stored from operations carried out to recover uranium from pitchblende ore in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the NFSS. This report describes the results of geochemical investigations performed to help provide a quantitative evaluation of the effects of various options. NFSS soil and groundwater samples were characterized; and uranium and radium sorption ratios, as well as apparent concentration limit values, were measured in site soil/groundwater systems by employing batch contact methodology. The results suggest that any uranium which is in solution in the groundwater at the NFSS may be poorly retarded due to the low uranium sorption ratio values and high solubility measured. Further, appreciable concentrations of uranium in groundwater could be attained from soluble wastes. Release of uranium via groundwater migration could be a significant release pathway. Solubilized radium would be expected to be effectively retarded by soil at the NFSS as a result of the very high radium sorption ratios observed. The addition of iron oxyhydroxide to NFSS soils resulted in much higher uranium sorption ratios. Additional field testing of this potential remedial action additive could be desirable. 10 references.

  14. Unearthing the Antibacterial Mechanism of Medicinal Clay: A Geochemical Approach to Combating Antibiotic Resistance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Morrison, Keith D.; Misra, Rajeev; Williams, Lynda B.

    2016-01-08

    Natural antibacterial clays, when hydrated and applied topically, kill human pathogens including antibiotic resistant strains proliferating worldwide. Only certain clays are bactericidal; those containing soluble reduced metals and expandable clay minerals that absorb cations, providing a capacity for extended metal release and production of toxic hydroxyl radicals. Here we show the critical antibacterial components are soluble Fe2+ and Al3+ that synergistically attack multiple cellular systems in pathogens normally growth-limited by Fe supply. This geochemical process is more effective than metal solutions alone and provides an alternative antibacterial strategy to traditional antibiotics. Advanced bioimaging methods and genetic show that Al3+ misfoldsmore » cell membrane proteins, while Fe2+ evokes membrane oxidation and enters the cytoplasm inflicting hydroxyl radical attack on intracellular proteins and DNA. The lethal reaction precipitates Fe3+-oxides as biomolecular damage proceeds. In conclusion, discovery of this bactericidal mechanism demonstrated by natural clays should guide designs of new mineral-based antibacterial agents.« less

  15. Characterizing Microbial Community and Geochemical Dynamics at Hydrothermal Vents Using Osmotically Driven Continuous Fluid Samplers

    SciTech Connect (OSTI)

    Robidart, Julie C.; Callister, Stephen J.; Song, Peng F.; Nicora, Carrie D.; Wheat, Charles G.; Girguis, Peter R.

    2013-05-07

    Microbes play a key role in mediating all aquatic biogeochemical cycles, and ongoing efforts are aimed at better understanding the relationships between microbial phylogenetic and physiological diversity, and habitat physical and chemical characteristics. Establishing such relationships is facilitated by sampling and studying microbiology and geochemistry at the appropriate spatial and temporal scales, to access information on the past and current environmental state that contributes to observed microbial abundances and activities. A modest number of sampling systems exist to date, few of which can be used in remote, harsh environments such as hydrothermal vents, where the ephemeral nature of venting underscores the necessity for higher resolution sampling. We have developed a robust, continuous fluid sampling system for co-registered microbial and biogeochemical analyses. The osmosis-powered bio-osmosampling system (BOSS) use no electricity, collects fluids with daily resolution or better, can be deployed in harsh, inaccessible environments and can sample fluids continuously for up to five years. Here we present a series of tests to examine DNA, RNA and protein stability over time, as well as material compatability, via lab experiments. We also conducted two field deployments at deep-sea hydrothermal vents to assess changes in microbial diversity and protein expression as a function of the physico-chemical environment. Our data reveal significant changes in microbial community composition co-occurring with relatively modest changes in the geochemistry. These data additionally provide new insights into the distribution of an enigmatic sulfur oxidizing symbiont in its free-living state. Data from the second deployment reveal differences in the representation of peptides over time, underscoring the utility of the BOSS in meta-proteomic studies. In concert, these data demonstrate the efficacy of this approach, and illustrate the value of using this method to study

  16. Actualistic and Geochemical Modeling of Reservoir Rock, CO2 and Formation Fluid Interaction, Citronelle Oil Field, Alabama

    SciTech Connect (OSTI)

    Weislogel, Amy

    2014-01-31

    This report includes description of the Citronelle field study area and the work carried out in the project to characterize the geology and composition of reservoir rock material and to collect an analyze the geochemical composition of produced fluid waters from the Citronelle field. Reservoir rock samples collected from well bore core were made into thin-sections and assessed for textural properties, including pore types and porosity distribution. Compositional framework grain modal data were collected via point-counting, and grain and cement mineralogy was assessed using SEM-EDS. Geochemistry of fluid samples is described and modeled using PHREEQC. Composition of rock and produced fluids were used as inputs for TOUGHREACT reactive transport modeling, which determined the rock-fluid system was in disequilibrium.

  17. Scaling Effects of Cr(VI) Reduction Kinetics. The Role of Geochemical Heterogeneity

    SciTech Connect (OSTI)

    Wang, Li; Li, Li

    2015-10-22

    The natural subsurface is highly heterogeneous with minerals distributed in different spatial patterns. Fundamental understanding of how mineral spatial distribution patterns regulate sorption process is important for predicting the transport and fate of chemicals. Existing studies about the sorption was carried out in well-mixed batch reactors or uniformly packed columns, with few data available on the effects of spatial heterogeneities. As a result, there is a lack of data and understanding on how spatial heterogeneities control sorption processes. In this project, we aim to understand and develop modeling capabilities to predict the sorption of Cr(VI), an omnipresent contaminant in natural systems due to its natural occurrence and industrial utilization. We systematically examine the role of spatial patterns of illite, a common clay, in determining the extent of transport limitation and scaling effects associated with Cr(VI) sorption capacity and kinetics using column experiments and reactive transport modeling. Our results showed that the sorbed mass and rates can differ by an order of magnitude due to of the illite spatial heterogeneities and transport limitation. With constraints from data, we also developed the capabilities of modeling Cr(VI) in heterogeneous media. The developed model is then utilized to understand the general principles that govern the relationship between sorption and connectivity, a key measure of the spatial pattern characteristics. This correlation can be used to estimate Cr(VI) sorption characteristics in heterogeneous porous media. Insights gained here bridge gaps between laboratory and field application in hydrogeology and geochemical field, and advance predictive understanding of reactive transport processes in the natural heterogeneous subsurface. We believe that these findings will be of interest to a large number of environmental geochemists and engineers, hydrogeologists, and those interested in contaminant fate and transport

  18. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-03-15

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  19. Geothermal prospecting by geochemical methods on natural gas and water discharges in the Vulsini Mts Volcanic District (Central Italy)

    SciTech Connect (OSTI)

    Duchi, V.; Minissale, A.A.; Ortino, S.; Romani, L.

    1987-01-01

    The Latera and Torre Alfina geothermal fields were discovered in the Vulsini Mts district (central Italy) in the 70s. The fluid produced by the two geothermal systems is a high rhoCO/sub 2/(around 7 MPa) sodium chloride solution (T.D.S. is 9200 ppm at Latera and 7800 at Torre Alfina), with high SiO/sub 2/ and H/sub 3/BO/sub 3/ contents. The fluid temperature taken at well bottom is about 155/sup 0/C at Torre Alfina, whereas at Latera it ranges from 200 to over 350/sup 0/C. In spite of these temperatures, recorded in producing wells, previous geochemical prospectings using geothermometers in natural thermal manifestations had predicted temperatures no higher than 140/sup 0/C in all the Vulsini district. This contrasting feature between real temperatures and those evaluated during prospecting is caused by the fast circulation of large amounts of meteoric waters in the aquifer located in the shallow parts of the carbonate reservoir formations, and by the short interaction between the latter and the deep geothermal fluids. In the present study a new geochemical survey on thermal and cold springs, stream samples, as well as natural gas emissions has been carried out. A critical review of the main geothermometers, some considerations about the hydraulic behavior of the reservoir formations, and the cross comparison between NH/sub 4//sup +//B ratio, rhoCO/sub 2/ and SiO/sub 2/ content in both cold and thermal waters, have led to the conclusion that in the Vulsini Mts there are no shallow anomalous areas apart from those already discovered at Latera and Torre Alfina. The present method could be successfully applied in other geothermal systems, where the potential reservoir is represented by carbonate formations.

  20. Geochemical Data Package for the 2005 Hanford Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Serne, R JEFFREY.; Kaplan, D I.

    2004-09-30

    CH2M HILL Hanford Group, Inc. (CH2M HILL) is designing and assessing the performance of an integrated disposal facility (IDF) to receive low-level waste (LLW), mixed low-level waste (MLLW), immobilized low-activity waste (ILAW), and failed or decommissioned melters. The CH2M HILL project to assess the performance of this disposal facility is the Hanford IDF Performance Assessment (PA) activity. The goal of the Hanford IDF PA activity is to provide a reasonable expectation that the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require prediction of contaminant migration from the facilities. This migration is expected to occur primarily via the movement of water through the facilities, and the consequent transport of dissolved contaminants in the vadose zone to groundwater where contaminants may be re-introduced to receptors via drinking water wells or mixing in the Columbia River. Pacific Northwest National Laboratory (PNNL) assists CH2M HILL in their performance assessment activities. One of the PNNL tasks is to provide estimates of the geochemical properties of the materials comprising the IDF, the disturbed region around the facility, and the physically undisturbed sediments below the facility (including the vadose zone sediments and the aquifer sediments in the upper unconfined aquifer). The geochemical properties are expressed as parameters that quantify the adsorption of contaminants and the solubility constraints that might apply for those contaminants that may exceed solubility constraints. The common parameters used to quantify adsorption and solubility are the distribution coefficient (Kd) and the thermodynamic solubility product (Ksp), respectively. In this data package, we approximate the solubility of contaminants using a more simplified construct, called the solution concentration limit, a constant value. The Kd values and

  1. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from Subsurface Storage Reservoirs on Groundwater Quality

    SciTech Connect (OSTI)

    Shao, Hongbo; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Brown, Christopher F.

    2015-07-07

    The leakage of CO2 and the concomitant saline solutions from deep storage reservoirs to overlying groundwater aquifers is considered one of the major potential risks associated with geologic CO2 sequestration (GCS). Batch and column experiments were conducted to determine the fate of trace metals in groundwater in the scenarios of CO2 and metal contaminated brine leakage. The sediments used in this work were collected from an unconsolidated sand and gravel aquifer in Kansas, and contained 0-4 wt% carbonates. Cd and As were spiked into the reaction system to represent potential contaminants from the reservoir brine that could intrude into groundwater aquifers with leaking CO2 at initial concentrations of 114 and 40 ppb, respectively. Through this research we demonstrated that Cd and As were adsorbed on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. Cd concentrations were well below its MCL in both batch and column studies, even for sediment samples without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent were also significantly lower than influent concentration, suggesting that the sediments tested have the capacity to mitigate the coupled adverse effects of CO2 leakage and brine intrusion. However, the mitigation capacity of sediment is a function of its geochemical properties [e.g., the calcite content; the presence of adsorbed As(III); and the presence of P in the natural sediment]. The competitive adsorption between phosphate and arsenate may result in higher concentrations of As in the aqueous phase.

  2. Model-Based Analysis of the Role of Biological, Hydrological and Geochemical Factors Affecting Uranium Bioremediation

    SciTech Connect (OSTI)

    Zhao, Jiao; Scheibe, Timothy D.; Mahadevan, Radhakrishnan

    2011-01-24

    Uranium contamination is a serious concern at several sites motivating the development of novel treatment strategies such as the Geobacter-mediated reductive immobilization of uranium. However, this bioremediation strategy has not yet been optimized for the sustained uranium removal. While several reactive-transport models have been developed to represent Geobacter-mediated bioremediation of uranium, these models often lack the detailed quantitative description of the microbial process (e.g., biomass build-up in both groundwater and sediments, electron transport system, etc.) and the interaction between biogeochemical and hydrological process. In this study, a novel multi-scale model was developed by integrating our recent model on electron capacitance of Geobacter (Zhao et al., 2010) with a comprehensive simulator of coupled fluid flow, hydrologic transport, heat transfer, and biogeochemical reactions. This mechanistic reactive-transport model accurately reproduces the experimental data for the bioremediation of uranium with acetate amendment. We subsequently performed global sensitivity analysis with the reactive-transport model in order to identify the main sources of prediction uncertainty caused by synergistic effects of biological, geochemical, and hydrological processes. The proposed approach successfully captured significant contributing factors across time and space, thereby improving the structure and parameterization of the comprehensive reactive-transport model. The global sensitivity analysis also provides a potentially useful tool to evaluate uranium bioremediation strategy. The simulations suggest that under difficult environments (e.g., highly contaminated with U(VI) at a high migration rate of solutes), the efficiency of uranium removal can be improved by adding Geobacter species to the contaminated site (bioaugmentation) in conjunction with the addition of electron donor (biostimulation). The simulations also highlight the interactive effect of

  3. Geochemical information for sites contaminated with low-level radioactive wastes. III. Weldon Spring Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-02-01

    The Weldon Spring Storage Site (WSSS), which includes both the chemical site and the quarry, became radioactively contaminated as the result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the WSSS. This report describes the results of geochemical investigations carried out at Oak Ridge National Laboratory (ORNL) to support these activities and to help quantify various remedial action options. Soil and groundwater samples were characterized, and uranium and radium sorption ratios were measured in site soil/groundwater systems by batch contact methodology. Soil samples from various locations around the raffinate pits were found to contain major amounts of silica, along with illite as the primary clay constituent. Particle sizes of the five soil samples were variable (50% distribution point ranging from 12 to 81 ..mu..m); the surface areas varied from 13 to 62 m/sup 2//g. Elemental analysis of the samples showed them to be typical of sandy clay and silty clay soils. Groundwater samples included solution from Pit 3 and well water from Well D. Anion analyses showed significant concentrations of sulfate and nitrate (>350 and >7000 mg/L, respectively) in the solution from Pit 3. These anions were also present in the well water, but in lower concentrations. Uranium sorption ratios for four of the soil samples contacted with the solution from Pit 3 were moderate to high (approx. 300 to approx. 1000 mL/g). The fifth sample had a ratio of only 12 mL/g. Radium sorption ratios for the five samples were moderate to high (approx. 600 to approx. 1000 mL/g). These values indicate that soil at the WSSS may show favorable retardation of uranium and radium in the groundwater. 13 references, 13 figures, 10 tables.

  4. Rotor component displacement measurement system

    DOE Patents [OSTI]

    Mercer, Gary D.; Li, Ming C.; Baum, Charles R.

    2003-05-27

    A measuring system for measuring axial displacement of a tube relative to an axially stationary component in a rotating rotor assembly includes at least one displacement sensor adapted to be located normal to a longitudinal axis of the tube; an insulated cable system adapted for passage through the rotor assembly; a rotatable proximitor module located axially beyond the rotor assembly to which the cables are connected; and a telemetry system operatively connected to the proximitor module for sampling signals from the proximitor module and forwarding data to a ground station.

  5. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    transformations in a shallow groundwater system using complex electrical methods Citation ... Country of Publication: United States Language: English Subject: 54 ENVIRONMENTAL ...

  6. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    Increased output of greenhouse gases, particularly carbon dioxide (CO₂), into the atmosphere from anthropogenic sources is of great concern. A potential technology to reduce CO₂ emissions is geologic carbon sequestration. This technology is currently being evaluated in the United States and throughout the world. The geology of the Illinois Basin exhibits outstanding potential as a carbon sequestration target, as demonstrated by the ongoing Illinois Basin – Decatur Project that is using the Mt. Simon Sandstone reservoir and Eau Claire Shale seal system to store and contain 1 million tonnes of CO₂. The Knox Group-Maquoketa Shale reservoir and seal system, located stratigraphically above the Mt. Simon Sandstone-Eau Claire Shale reservoir and seal system, has little economic value as a resource for fossil fuels or as a potable water source, making it ideal as a potential carbon sequestration target. In order for a reservoir-seal system to be effective, it must be able to contain the injected CO₂ without the potential for the release of harmful contaminants liberated by the reaction between CO₂-formation fluids and reservoir and seal rocks. This study examines portions of the Knox Group (Potosi Dolomite, Gunter Sandstone, New Richmond Sandstone) and St. Peter Sandstone, and Maquoketa Shale from various locations around the Illinois Basin. A total of 14 rock and fluid samples were exposed to simulated sequestration conditions (9101–9860 kPa [1320–1430 psi] and 32°–42°C [90°– 108°F]) for varying amounts of time (6 hours to 4 months). Knox Group reservoir rocks exhibited dissolution of dolomite in the presence of CO₂ as indicated by petrographic examination, X-ray diffraction analysis, and fluid chemistry analysis. These reactions equilibrated rapidly, and geochemical modeling confirmed that these reactions reached equilibrium within the time frames of the experiments. Pre-reaction sample mineralogy and postreaction fluid geochemistry from this

  7. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    SciTech Connect (OSTI)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthite component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.

  8. Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators Project Officer: Eric Hass Total Project Funding: $999,000 April 24, 2013 Craig Cooper Larry Hull Idaho National Laboratory This presentation does not contain any proprietary confidential, or otherwise restricted information. 2 | US DOE Geothermal Program eere.energy.gov Relevance/Impact of Research Geothermometry enables estimation of

  9. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    2012-07-18

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  10. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  11. Kinetics of Uranium(VI) Desorption from Contaminated Sediments: Effect of Geochemical Conditions and Model Evaluation

    SciTech Connect (OSTI)

    Liu, Chongxuan; Shi, Zhenqing; Zachara, John M.

    2009-09-01

    Stirred-flow cell experiments were performed to investigate the kinetics of uranyl [U(VI)] desorption from a contaminated sediment collected from the Hanford 300 Area at the US Department of Energy (DOE) Hanford Site, Washington. Three influent solutions of variable pH, Ca and carbonate concentrations that affected U(VI) aqueous and surface speciation were used under dynamic flow conditions to evaluate the effect of geochemical conditions on the rate of U(VI) desorption. The measured rate of U(VI) desorption varied with solution chemical composition that evolved as a result of thermodynamic and kinetic interactions between the influent solutions and sediment. The solution chemical composition that led to a lower equilibrium U(VI) sorption to the solid phase yielded a faster desorption rate. The experimental results were used to evaluate a multi-rate, surface complexation model (SCM) that has been proposed to describe U(VI) desorption kinetics in the Hanford sediment that contained complex sorbed U(VI) species in mass transfer limited domains. The model was modified and supplemented by including multi-rate, ion exchange reactions to describe the geochemical interactions between the solutions and sediment. With the same set of model parameters, the modified model reasonably well described the evolution of major ions and the rates of U(VI) desorption under variable geochemical and flow conditions, implying that the multi-rate SCM is an effective way to describe U(VI) desorption kinetics in subsurface sediments.

  12. Geochemical factors affecting radionuclide transport through near and far fields at a Low-Level Waste Disposal Site

    SciTech Connect (OSTI)

    Kaplan, D.I.; Seme, R.J.; Piepkho, M.G.

    1995-03-01

    The concentration of low-level waste (LLW) contaminants in groundwater is determined by the amount of contaminant present in the solid waste, rate of release from the waste and surrounding barriers, and a number of geochemical processes including adsorption, desorption, diffusion, precipitation, and dissolution. To accurately predict radionuclide transport through the subsurface, it is essential that the important geochemical processes affecting radionuclide transport be identified and, perhaps more importantly, accurately quantified and described in a mathematically defensible manner.

  13. Thermodynamic Data for Geochemical Modeling of Carbonate Reactions Associated with CO2 Sequestration – Literature Review

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Cantrell, Kirk J.; McGrail, B. Peter

    2010-09-28

    Permanent storage of anthropogenic CO2 in deep geologic formations is being considered as a means to reduce the concentration of atmospheric CO2 and thus its contribution to global climate change. To ensure safe and effective geologic sequestration, numerous studies have been completed of the extent to which the CO2 migrates within geologic formations and what physical and geochemical changes occur in these formations when CO2 is injected. Sophisticated, computerized reservoir simulations are used as part of field site and laboratory CO2 sequestration studies. These simulations use coupled multiphase flow-reactive chemical transport models and/or standalone (i.e., no coupled fluid transport) geochemical models to calculate gas solubility, aqueous complexation, reduction/oxidation (redox), and/or mineral solubility reactions related to CO2 injection and sequestration. Thermodynamic data are critical inputs to modeling geochemical processes. The adequacy of thermodynamic data for carbonate compounds has been identified as an important data requirement for the successful application of these geochemical reaction models to CO2 sequestration. A review of thermodynamic data for CO2 gas and carbonate aqueous species and minerals present in published data compilations and databases used in geochemical reaction models was therefore completed. Published studies that describe mineralogical analyses from CO2 sequestration field and natural analogue sites and laboratory studies were also reviewed to identify specific carbonate minerals that are important to CO2 sequestration reactions and therefore require thermodynamic data. The results of the literature review indicated that an extensive thermodynamic database exists for CO2 and CH4 gases, carbonate aqueous species, and carbonate minerals. Values of ∆fG298° and/or log Kr,298° are available for essentially all of these compounds. However, log Kr,T° or heat capacity values at temperatures above 298 K exist for less than

  14. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Magmas | Stanford Synchrotron Radiation Lightsource Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating Natural Magmas Monday, March 26, 2012 - 11:00am SSRL Conference Room 137-322 G. Giuli, R. Alonso-Mori, E. Paris, P. Glatzel, S. Eeckhout, M. Carroll, School of Science and Technology, Geology Division, University of Camerino, Via G. III da Varano, 62032 Camerino; e-mail: The solubility behaviour of S and Cl in silicate magmas is a key to understand the

  15. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  16. Remote Raman - laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions

    SciTech Connect (OSTI)

    Clegg, Sanuel M; Barefield, James E; Humphries, Seth D; Wiens, Roger C; Vaniman, D. T.; Sharma, S. K.; Misra, A. K.; Dyar, M. D.; Smrekar, S. E.

    2010-12-13

    The extreme Venus surface temperatures ({approx}740 K) and atmospheric pressures ({approx}93 atm) create a challenging environment for surface missions. Scientific investigations capable of Venus geochemical observations must be completed within hours of landing before the lander will be overcome by the harsh atmosphere. A combined remote Raman - LIBS (Laser Induced Breakdown Spectroscopy) instrument is capable of accomplishing the geochemical science goals without the risks associated with collecting samples and bringing them into the lander. Wiens et al. and Sharma et al. demonstrated that both analytical techniques can be integrated into a single instrument capable of planetary missions. The focus of this paper is to explore the capability to probe geologic samples with Raman - LIBS and demonstrate quantitative analysis under Venus surface conditions. Raman and LIBS are highly complementary analytical techniques capable of detecting both the mineralogical and geochemical composition of Venus surface materials. These techniques have the potential to profoundly increase our knowledge of the Venus surface composition, which is currently limited to geochemical data from Soviet Venera and VEGA landers that collectively suggest a surface composition that is primarily tholeiitic basaltic with some potentially more evolved compositions and, in some locations, K-rich trachyandesite. These landers were not equipped to probe the surface mineralogy as can be accomplished with Raman spectroscopy. Based on the observed compositional differences and recognizing the imprecise nature of the existing data, 15 samples were chosen to constitute a Venus-analog suite for this study, including five basalts, two each of andesites, dacites, and sulfates, and single samples of a foidite, trachyandesite, rhyolite, and basaltic trachyandesite under Venus conditions. LIBS data reduction involved generating a partial least squares (PLS) model with a subset of the rock powder standards to

  17. Geochemical Data Package for Performance Assessment Calculations Related to the Savannah River Site

    SciTech Connect (OSTI)

    Kaplan, Daniel I.

    2010-03-15

    The Savannah River Site disposes of low-activity radioactive waste within subsurface-engineered facilities. One of the tools used to establish the capacity of a given site to safely store radioactive waste (i.e., that a site does not exceed its Waste Acceptance Criteria) is the Performance Assessment (PA). The objective of this document is to provide the geochemical values for the PA calculations. This work is being conducted as part of the on-going maintenance program that permits the PA to periodically update existing calculations when new data becomes available.

  18. Geochemical information for sites contaminated with low-level radioactive wastes: II. St. Louis Airport Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-01-01

    The St. Louis Airport Storage Site (SLASS) became radioactively contaminated as a result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy is considering various remedial action options for the SLASS under the Formerly Utilized Site Remedial Action Program (FUSRAP). This report describes the results of geochemical investigations, carried out to support the FUSRAP activities and to aid in quantifying various remedial action options. Soil and groundwater samples from the site were characterized, and sorption ratios for uranium and radium and apparent concentration limit values for uranium were measured in soil/groundwater systems by batch contact methodology. The uranium and radium concentrations in soil samples were significantly above background near the old contaminated surface horizon (now at the 0.3/sup -/ to 0.9/sup -/m depth); the maximum values were 1566 ..mu..g/g and 101 pCi/g, respectively. Below about the 6/sup -/m depth, the concentrations appeared to be typical of those naturally present in soils of this area (3.8 +- 1.2 ..mu..g/g and 3.1 +- 0.6 pCi/g). Uranium sorption ratios showed stratigraphic trends but were generally moderate to high (100 to 1000 L/kg). The sorption isotherm suggested an apparent uranium concentration limit of about 200 mg/L. This relatively high solubility can probably be correlated with the carbonate content of the soil/groundwater systems. The lower sorption ratio values obtained from the sorption isotherm may have resulted from changes in the experimental procedure or the groundwater used. The SLASS appears to exhibit generally favorable behavior for the retardation of uranium solubilized from waste in the site. Parametric tests were conducted to estimate the sensitivity of uranium sorption and solubility to the pH and carbonate content of the system.

  19. Geochemical and geologic factors effecting the formulation of gas hydrate: Task No. 5, Final report

    SciTech Connect (OSTI)

    Kvenvolden, K.A.; Claypool, G.E.

    1988-01-01

    The main objective of our work has been to determine the primary geochemical and geological factors controlling gas hydrate information and occurrence and particularly in the factors responsible for the generation and accumulation of methane in oceanic gas hydrates. In order to understand the interrelation of geochemical/geological factors controlling gas hydrate occurrence, we have undertaken a multicomponent program which has included (1) comparison of available information at sites where gas hydrates have been observed through drilling by the Deep Sea Drilling Project (DSDP) on the Blake Outer Ridge and Middle America Trench; (2) regional synthesis of information related to gas hydrate occurrences of the Middle America Trench; (3) development of a model for the occurrence of a massive gas hydrate as DSDP Site 570; (4) a global synthesis of gas hydrate occurrences; and (5) development of a predictive model for gas hydrate occurrence in oceanic sediment. The first three components of this program were treated as part of a 1985 Department of Energy Peer Review. The present report considers the last two components and presents information on the worldwide occurrence of gas hydrates with particular emphasis on the Circum-Pacific and Arctic basins. A model is developed to account for the occurrence of oceanic gas hydrates in which the source of the methane is from microbial processes. 101 refs., 17 figs., 6 tabs.

  20. Evapotranspiration And Geochemical Controls On Groundwater Plumes At Arid Sites: Toward Innovative Alternate End-States For Uranium Processing And Tailings Facilities

    SciTech Connect (OSTI)

    Looney, Brian B.; Denham, Miles E.; Eddy-Dilek, Carol A.; Millings, Margaret R.; Kautsky, Mark

    2014-01-08

    Management of legacy tailings/waste and groundwater contamination are ongoing at the former uranium milling site in Tuba City AZ. The tailings have been consolidated and effectively isolated using an engineered cover system. For the existing groundwater plume, a system of recovery wells extracts contaminated groundwater for treatment using an advanced distillation process. The ten years of pump and treat (P&T) operations have had minimal impact on the contaminant plume – primarily due to geochemical and hydrological limits. A flow net analysis demonstrates that groundwater contamination beneath the former processing site flows in the uppermost portion of the aquifer and exits the groundwater as the plume transits into and beneath a lower terrace in the landscape. The evaluation indicates that contaminated water will not reach Moenkopi Wash, a locally important stream. Instead, shallow groundwater in arid settings such as Tuba City is transferred into the vadose zone and atmosphere via evaporation, transpiration and diffuse seepage. The dissolved constituents are projected to precipitate and accumulate as minerals such as calcite and gypsum in the deep vadose zone (near the capillary fringe), around the roots of phreatophyte plants, and near seeps. The natural hydrologic and geochemical controls common in arid environments such as Tuba City work together to limit the size of the groundwater plume, to naturally attenuate and detoxify groundwater contaminants, and to reduce risks to humans, livestock and the environment. The technical evaluation supports an alternative beneficial reuse (“brownfield”) scenario for Tuba City. This alternative approach would have low risks, similar to the current P&T scenario, but would eliminate the energy and expense associated with the active treatment and convert the former uranium processing site into a resource for future employment of local citizens and ongoing benefit to the Native American Nations.

  1. Rock-Water Interactions In Hot Dry Rock Geothermal Systems- Field...

    Open Energy Info (EERE)

    Rock-Water Interactions In Hot Dry Rock Geothermal Systems- Field Investigations Of In Situ Geochemical Behavior Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  2. Groundwater geochemical modeling and simulation of a breached high-level radioactive waste repository in the northern Tularosa Basin, New Mexico

    SciTech Connect (OSTI)

    Chappell, R.W.

    1989-01-01

    The northern Tularosa Basin in south-central New Mexico was ranked favorably as a potential location for a high-level radioactive waste repository by a US Geological Survey pilot screening study of the Basin and Range Province. The favorable ranking was based chiefly on hydrogeologic and descriptive geochemical evidence. A goal of this study was to develop a methodology for predicting the performance of this or any other basin as a potential repository site using geochemical methods. The approach involves first characterizing the groundwater geochemistry, both chemically and isotopically, and reconstructing the probable evolutionary history of, and controls on the ground water chemistry through modeling. In the second phase of the approach, a hypothetically breached repository is introduced into the system, and the mobility of the parent radionuclide, uranium, in the groundwater is predicted. Possible retardation of uranium transport in the downgradient flow direction from the repository by adsorption and mineral precipitation is then considered. The Permian Yeso Formation, the primary aquifer in the northern Tularosa Basin, was selected for study, development and testing of the methodology outlined above. The Yeso Formation contains abundant gypsum and related evaporite minerals, which impart a distinctive chemical signature to the ground water. Ground water data and solubility calculations indicate a conceptual model of irreversible gypsum and dolomite dissolution with concomitant calcite precipitation. Recharge areas are apparent from temperature, {delta}{sup 18}O and {delta}{sup 2} H, and {sup 3}H trends in the aquifer. Corrected {sup 14}C ages range between modern and 31,200 years, and suggest an average ground water velocity of 0.83 m/yr.

  3. Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration

    SciTech Connect (OSTI)

    Teng, H. Henry; Xu, Huifang

    2013-07-17

    We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at ambient conditions from a new perspective by exploring the formation of MgCO{sub 3} and Mg{sub x}Ca{sub (1-x)}CO{sub 3} in non-aqueous solutions. Data collected from our experiments in this funding period suggest that a fundamental barrier, other than cation hydration, exists that prevents Mg{sup 2+} and CO{sub 3}{sup 2-} ions from forming long-range ordered structures. We propose that this barrier mainly stems from the lattice limitation on the spatial configuration of CO{sub 3} groups in magnesite crystals. On the other hand, the measured higher distribution coefficients of Mg between magnesian calcites formed in the absence and presence of water give us a first direct proof to support and quantify the cation hydration effect.

  4. Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

    SciTech Connect (OSTI)

    Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

    1985-01-01

    An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

  5. Evaluating oil quality and monitoring production from heavy oil reservoirs using geochemical methods: Application to the Boscan Field, Venezuela

    SciTech Connect (OSTI)

    Kaufman, R.L.; Noguera, V.H.; Bantz, D.M.; Rodriguez, R.

    1996-08-01

    Many oil fields worldwide contain heavy oil in one or more reservoir units. The low gravity of these oils is most frequently due to biodegradation and/or low maturity. The challenge is to find ways to economically recover this oil. Methods which reduce the operating costs of producing heavy oil add significant value to such projects. Geochemical techniques which use the composition of the reservoir fluids as natural tracers offer cost effective methods to assist with reservoir management. The low viscosity and gravity of heavy oil, combined with frequent high water cuts, low flow rates, and the presence of downhole artificial lift equipment, make many conventional production logging methods difficult to apply. Therefore, monitoring production, especially if the produced oil is commingled from multiple reservoirs, can be difficult. Geochemical methods can be used to identify oil/water contacts, tubing string leaks and to allocate production to individual zones from commingled production. An example of a giant heavy oil field where geochemical methods may be applicable is the Boscan Field in Venezuela. Low maturity oil, averaging 10{degrees} API gravity, is produced from the Eocene Upper and Lower Boscan (Miosa) Sands. Geochemical, stratigraphic and engineering data have helped to better define the controls on oil quality within the field, identified new reservoir compartments and defined unique characteristics of the Upper and Lower Boscan oils. This information can be used to identify existing wells in need of workovers due to mechanical problems and to monitor production from new infill wells.

  6. Geochemical and physical properties of wetland soils at the Savannah River site

    SciTech Connect (OSTI)

    Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

    1996-05-01

    The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

  7. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and

  8. Basic devices and techniques for supervisory control and telemetery systems

    SciTech Connect (OSTI)

    Knox, R.M.

    1984-04-01

    The microprocessor is creating extraordinary changes in the basic devices used for supervisory control and telemetry systems. Devices which incorporate microprocessors are providing new capabilities to monitor, to control, and to transmit data. These new capabilities provide the opportunity to utilize new techniques in achieving more efficient operation and control of gas transmission and distribution systems. This paper describes several devices being installed at Transcocontinental Gas Pipe Line Corporation and their impact on the planned techniques to be used to collect gas flow data and to implement supervisory control.

  9. Novel Imaging Techniques, Integrated with Mineralogical, Geochemical and Microbiological Characterization to Determine the Biogeochemical Controls....

    SciTech Connect (OSTI)

    Lloyd, Jonathan R.

    2005-06-01

    conditions on the stability/solubility of Fe(II) and Tc(IV), found 80 % resolubilization of the Tc. Column experiments exploring this behavior are being planned. HYPOTHESIS 4 The mobility of 99mTc in the sediment columns can be modeled using a coupled speciation and transport code. Microbiological and geochemical characterization of the column experiments is ongoing and transport and geochemical modeling experiments are being planned.

  10. Improved Geothermometry Through Multivariate Reaction-path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators: Final Report

    SciTech Connect (OSTI)

    Mattson, Earl; Smith, Robert; Fujita, Yoshiko; McLing, Travis; Neupane, Ghanashyam; Palmer, Carl; Reed, David; Thompson, Vicki

    2015-03-01

    The project was aimed at demonstrating that the geothermometric predictions can be improved through the application of multi-element reaction path modeling that accounts for lithologic and tectonic settings, while also accounting for biological influences on geochemical temperature indicators. The limited utilization of chemical signatures by individual traditional geothermometer in the development of reservoir temperature estimates may have been constraining their reliability for evaluation of potential geothermal resources. This project, however, was intended to build a geothermometry tool which can integrate multi-component reaction path modeling with process-optimization capability that can be applied to dilute, low-temperature water samples to consistently predict reservoir temperature within ±30 °C. The project was also intended to evaluate the extent to which microbiological processes can modulate the geochemical signals in some thermal waters and influence the geothermometric predictions.

  11. Comparison of microbial and sorbed soil gas surgace geochemical techniques with seismic surveys from the Southern Altiplano, Bolivia

    SciTech Connect (OSTI)

    Aranibar, O.R.; Tucker, J.D.; Hiltzman, D.C.

    1995-12-31

    Yacimientos Petroliferos Fiscales Bolivianos (YPFB) undertook a large seismic evaluation in the southern Altiplano, Bolivia in 1994. As an additional layer of information, sorbed soil gas and Microbial Oil Survey Technique (MOST) geochemical surveys were conducted to evaluate the hydrocarbon microseepage potential. The Wara Sara Prospect had 387 sorbed soil gas samples, collected from one meter depth, and 539 shallow soil microbial samples, collected from 15 to 20 centimeter depth. The sorbed soil gas samples were collected every 500 meters and microbial samples every 250 meters along geochemical traverses spaced 1 km apart. The presence of anmalous hydrocarbon microseepage is indicated by (1) a single hydrocarbon source identified by gas crossplots, (2) the high gas values with a broad range, (3) the high overall gas average, (4) the clusters of elevated samples, and (5) the right hand skewed data distributions.

  12. Preburn versus postburn mineralogical and geochemical characteristics of overburden and coal at the Hanna, Wyoming underground coal gasification site

    SciTech Connect (OSTI)

    Oliver, R.L.; Youngberg, A.D.

    1983-12-01

    Hundreds of mineralogic and geochemical tests were done under US Department of Energy contracts on core samples taken from the Hanna underground coal gasification site. These tests included x-ray diffraction studies of minerals in coal ash, overburden rocks, and heat-altered rocks; x-ray fluorescence analyses of oxides in coal ash and heat-altered rocks; semi-quantitative spectrographic analyses of elements in coal, overburden, and heat-altered rocks; chemical analyses of elements and compounds in coal, overburden, and heat-altered rocks and ASTM proximate and ultimate analyses of coal and heat-altered coal. These data sets were grouped, averaged, and analyzed to provide preburn and postburn mineralogic and geochemical characteristics of rock units at the site. Where possible, the changes in characteristics from the preburn to the postburn state are related to underground coal gasification processes. 11 references, 13 figures, 8 tables.

  13. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    SciTech Connect (OSTI)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; Griffith, C.; Hedges, S.; Dilmore, R.; Goodman, A.; Black, J.; Haese, R.; Deusner, C.; Bigalke, N.; Haeckel, M.; Fischer, S.; Liebscher, A.; Icenhower, J. P.; Daval, D.; Saldi, G. D.; Knauss, K. G.; Schmidt, M.; Mito, S.; Sorai, M.; Truche, L.

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in composition of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.

  14. Geochemical and physical properties of soils and shallow sediments at the Savannah River Site

    SciTech Connect (OSTI)

    Looney, B.B.; Eddy, C.A.; Ramdeen, M.; Pickett, J. ); Rogers, V. . Savannah River Site Savannah River Lab., Aiken, SC ); Scott, M.T.; Shirley, P.A. )

    1990-08-31

    A program to characterize the geochemical and physical properties of the unimpacted soils and shallow sediments at the Savannah River Site (SRS) has been completed. The maximum, minimum, median, standard deviation, and mean values for metals, radionuclides, inorganic anions, organic compounds, and agricultural indicator parameters are summarized for six soil series that were identified as representative of the 29 soil series at SRS. The soils from unimpacted areas of SRS are typical of soils found in moderately aggressive weathering environments, including the southeastern United States. Appendix 8 organic compounds were detected in all samples. Since these constituents are not generally present in soil, this portion of the investigation was intended to assess possible laboratory artifacts. An additional objective of the SRS Soil Study was to determine if the composition of the split spoon sampler biased chemical analysis of the soils. Twenty-five duplicate samples were analyzed for a number of metals, radiological and agricultural parameters, and organics by two laboratories currently contracted with to analyze samples during waste site characterization. In all cases, the absolute values of the average differences are relatively small compared to the overall variability in the population. 31 refs., 14 figs., 48 tabs.

  15. Geochemical characteristics of oils from New Zealand, Papua New Guinea and Taiwan

    SciTech Connect (OSTI)

    Jung-Nan, Oung; Philp, P.R. )

    1990-05-01

    Oils from a number of convergent margin settings of the Pacific and Philippine plates have been characterized by geochemical techniques including gas chromatography-mass spectrometry and carbon isotopic analysis. The oils, collected from New Zealand, New Guinea, and Taiwan, are described in terms of their biomarker compositions, and these distributions are used to evaluate the nature of the source material responsible for the oils. For the most part these oils are of Tertiary age and the source materials were derived predominantly from higher plants. The authors describe the effects of a convergent margin on the relative maturity of the oils as reflected by their biomarker distributions. In other words, do any of the oils from these regions have anomalous maturity values that can be attributed to additional heating resulting from plate movement in the area. The results will also be compared with oils from similar source materials but not in convergent margin settings (for example, the Gippsland basin, Australia) to further evaluate the effects of the convergent margin setting on the biomarker distributions.

  16. Microbial distributions detected by an oligonucleotide microarray across geochemical zones associated with methane in marine sediments from the Ulleung Basin

    SciTech Connect (OSTI)

    Briggs, Brandon R.; Graw, Michael; Brodie, Eoin L.; Bahk, Jang-Jun; Kim, Sung-Han; Hyun, Jung-Ho; Kim, Ji-Hoon; Torres, Marta; Colwell, Frederick S.

    2013-11-01

    The biogeochemical processes that occur in marine sediments on continental margins are complex; however, from one perspective they can be considered with respect to three geochemical zones based on the presence and form of methane: sulfatemethane transition (SMTZ), gas hydrate stability zone (GHSZ), and free gas zone (FGZ). These geochemical zones may harbor distinct microbial communities that are important in biogeochemical carbon cycles. The objective of this study was to describe the microbial communities in sediments from the SMTZ, GHSZ, and FGZ using molecular ecology methods (i.e. PhyloChip microarray analysis and terminal restriction fragment length polymorphism (T-RFLP)) and examining the results in the context of non-biological parameters in the sediments. Non-metric multidimensional scaling and multi-response permutation procedures were used to determine whether microbial community compositions were significantly different in the three geochemical zones and to correlate samples with abiotic characteristics of the sediments. This analysis indicated that microbial communities from all three zones were distinct from one another and that variables such as sulfate concentration, hydrate saturation of the nearest gas hydrate layer, and depth (or unmeasured variables associated with depth e.g. temperature, pressure) were correlated to differences between the three zones. The archaeal anaerobic methanotrophs typically attributed to performing anaerobic oxidation of methane were not detected in the SMTZ; however, the marine benthic group-B, which is often found in SMTZ, was detected. Within the GHSZ, samples that were typically closer to layers that contained higher hydrate saturation had indicator sequences related to Vibrio-type taxa. These results suggest that the biogeographic patterns of microbial communities in marine sediments are distinct based on geochemical zones defined by methane.

  17. Geologic, geophysical, and geochemical aspects of site-specific studies of the geopressured-geothermal energy resource of southern Louisiana. Final report

    SciTech Connect (OSTI)

    Pilger, R.H. Jr.

    1985-01-01

    The report consists of four sections dealing with progress in evaluating geologic, geochemical, and geophysical aspects of geopressured-geothermal energy resources in Louisiana. Separate abstracts have been prepared for the individual sections. (ACR)

  18. Using 3D Acoustic Telemetry to Assess the Response of Resident Salmonids to Strobe Lights in Lake Roosevelt, Washington; Chief Joseph Kokanee Enhancement Feasibility Study, Annual Report 2001-2002.

    SciTech Connect (OSTI)

    Perry, Russlee; Farley, M.; Hansen, Gabriel

    2003-01-01

    In 1995, the Chief Joseph Kokanee Enhancement Project was established to mitigate the loss of anadromous fish due to the construction of Chief Joseph and Grand Coulee dams. The objectives of the Chief Joseph Enhancement Project are to determine the status of resident kokanee (Oncorhynchus nerka) populations above Chief Joseph and Grand Coulee dams and to enhance kokanee and rainbow trout (Oncorhynchus mykiss) populations. Studies conducted at Grand Coulee Dam documented substantial entrainment of kokanee through turbines at the third powerhouse. In response to finding high entrainment at Grand Coulee Dam, the Independent Scientific Review Panel (ISRP) recommended investigating the use of strobe lights to repel fish from the forebay of the third powerhouse. Therefore, our study focused on the third powerhouse and how strobe lights affected fish behavior in this area. The primary objective of our study was to assess the behavioral response of kokanee and rainbow trout to strobe lights using 3D acoustic telemetry, which yields explicit spatial locations of fish in three dimensions. Our secondary objectives were to (1) use a 3D acoustic system to mobile track tagged fish in the forebay and upriver of Grand Coulee Dam and (2) determine the feasibility of detecting fish using a hydrophone mounted in the tailrace of the third powerhouse. Within the fixed hydrophone array located in the third powerhouse cul-de-sac, we detected 50 kokanee and 30 rainbow trout, accounting for 47% and 45% respectively, of the fish released. Kokanee had a median residence time of 0.20 h and rainbow trout had a median residence time of 1.07 h. We detected more kokanee in the array at night compared to the day, and we detected more rainbow trout during the day compared to the night. In general, kokanee and rainbow trout approached along the eastern shore and the relative frequency of kokanee and rainbow trout detections was highest along the eastern shoreline of the 3D array. However, because we

  19. Geochemical and Isotopic Evaluation of Groundwater Movement in Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada Test Site, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-02-01

    This report describes the results of a comprehensive geochemical evaluation of the groundwater flow system in the Yucca Flat/Climax Mine Corrective Action Unit (CAU). The main objectives of this study are to identify probable pathways for groundwater flow within the study area and to develop constraints on groundwater transit times between selected data collection sites. This work provides an independent means of testing and verifying predictive flow models being developed for this CAU using finite element methods. The Yucca Flat/Climax Mine CAU constitutes the largest of six underground test areas on the Nevada Test Site (NTS) specified for remedial action in the ''Federal Facility Agreement and Consent Order''. A total of 747 underground nuclear detonations were conducted in this CAU. Approximately 23 percent of these detonations were conducted below or near the water table, resulting in groundwater contamination in the vicinity and possibly downgradient of these underground test locations. Therefore, a rigorous evaluation of the groundwater flow system in this CAU is necessary to assess potential long-term risks to the public water supply at downgradient locations.

  20. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We presentmore » new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a reliable classification method for

  1. Geochemical engineering design tools for uranium in situ recovery : the HYDROGEOCHEM codes.

    SciTech Connect (OSTI)

    Siegel, Malcolm Dean; Li, Ming-Hsu; Yeh, Gour-Tsyh

    2010-11-01

    Geochemical Engineering Design (GED) is based on applications of the principles and various computer models that describe the biogeochemistry and physics of removal of contaminants from water by adsorption, precipitation and filtration. It can be used to optimize or evaluate the efficiency of all phases of in situ recovery (ISR). The primary tools of GED are reactive transport models; this talk describes the potential application of the HYDROGEOCHEM family of codes to ISR. The codes can describe a complete suite of equilibrium or kinetic aqueous complexation, adsorption-desorption, precipitation-dissolution, redox, and acid-base reactions in variably saturated media with density-dependent fluid flow. Applications to ISR are illustrated with simulations of (1) the effectiveness of a reactive barrier to prevent off-site uranium migration and (2) evaluation of the effect of sorption hysteresis on natural attenuation. In the first example, it can be seen that the apparent effectiveness of the barrier depends on monitoring location and that it changes over time. This is due to changes in pH, saturation of sorption sites, as well as the geometry of the flow field. The second simulation shows how sorption hysteresis leads to observable attenuation of a uranium contamination plume. Different sorption mechanisms including fast (or reversible), slow, and irreversible sorption were simulated. The migration of the dissolved and total uranium plumes for the different cases are compared and the simulations show that when 50-100% of the sites have slow desorption rates, the center of mass of the dissolved uranium plume begins to move upstream. This would correspond to the case in which the plume boundaries begin to shrink as required for demonstration of natural attenuation.

  2. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    SciTech Connect (OSTI)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We present new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a

  3. Structural Analysis for Gold Mineralization Using Remote Sensing and Geochemical Techniques in a GIS Environment: Island of Lesvos, Hellas

    SciTech Connect (OSTI)

    Rokos, D. Argialas, D. Mavrantza, R. St Seymour, K.; Vamvoukakis, C.; Kouli, M.; Lamera, S.; Paraskevas, H.; Karfakis, I.; Denes, G

    2000-12-15

    Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field data (dip and strike measurements of faults, joints, and veins), respectively. The derived lineament map and the band ratio images were manipulated in a GIS environment, in order to study the relation of the tectonic pattern to both the alteration zoning and the geomorphology of the volcanic field of the study area. Target areas of high interest for possible mineralization also were specified using geochemical techniques, such as X-Ray Diffraction (XRD) analysis, trace-element, and fluid-inclusion analysis. Finally, preliminary conclusions were derived about possible mineralization, the type (high or low sulfidation), and the extent of mineralization, by combining the structural information with geochemical information.

  4. Final Report: Molecular Basis for Microbial Adhesion and Geochemical Surface Reactions: A Study Across Scales

    SciTech Connect (OSTI)

    Dixon, David Adams

    2013-06-27

    Computational chemistry was used to help provide a molecular level description of the interactions of Gram-negative microbial membranes with subsurface materials. The goal is to develop a better understanding of the molecular processes involved in microbial metal binding, microbial attachment to mineral surfaces, and, eventually, oxidation/reduction reactions (electron transfer) that can occur at these surfaces and are mediated by the bacterial exterior surface. The project focused on the interaction of the outer microbial membrane, which is dominated by an exterior lipopolysaccharide (LPS) portion, of Pseudomonas aeruginosa with the mineral goethite and with solvated ions in the environment. This was originally a collaborative project with T.P. Straatsma and B. Lowery of the Pacific Northwest National Laboratory. The University of Alabama effort used electronic structure calculations to predict the molecular behavior of ions in solution and the behavior of the sugars which form a critical part of the LPS. The interactions of the sugars with metal ions are expected to dominate much of the microscopic structure and transport phenomena in the LPS. This work, in combination with the molecular dynamics simulations of Straatsma and the experimental electrochemistry and microscopy measurements of Lowry, both at PNNL, is providing new insights into the detailed molecular behavior of these membranes in geochemical environments. The effort at The University of Alabama has three components: solvation energies and structures of ions in solution, prediction of the acidity of the critical groups in the sugars in the LPS, and binding of metal ions to the sugar anions. An important aspect of the structure of the LPS membrane as well as ion transport in the LPS is the ability of the sugar side groups such as the carboxylic acids and the phosphates to bind positively charged ions. We are studying the acidity of the acidic side groups in order to better understand the ability of

  5. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption) in the aquifer sediments and will support site selection, risk assessment, policy-making, and public education efforts associated with geologic carbon sequestration.

  6. Effect of curing conditions on the geotechnical and geochemical properties of CFBC ashes

    SciTech Connect (OSTI)

    Bland, A.E.

    1999-07-01

    Western Research Institute, in cooperation with the US Department of Energy Federal Energy Technology Center, initiated a multi-year program to examine the relationship between CFBC ash chemistry and geotechnical properties as they relate to ash disposal and utilization. Four CFBC facilities supplied ash from their units for the study representing high-sulfur (4%) and medium-sulfur (1.8%) bituminous coal. Sub-bituminous coal (0.9% sulfur) and petroleum coke (5--6% sulfur) fired ashes were also included in the study. The ashes were composed principally of large quantities of anhydrite (CaSO{sub 4}) and lime (CaO) and minor amounts of calcite (CaCO{sub 3}). The ash curing study addressed the impact of curing conditions (sealed and saturated curing and 23 C and 5 C curing temperature) on the geochemical and geotechnical properties of the ash. The strength development and expansion varied with the type and characteristics of the ashes. The expansion appeared to be inversely related to strength development. As the strength decreased under saturated curing, the expansion increased significantly. The application of 5 C saturated curing resulted in further strength loss and increased expansion. The hydration reaction products appeared to be principally the hydration of lime (CaO) to portlandite (Ca[OH]{sub 2}), the hydration of anhydrite (CaSO{sub 4}) to gypsum (CaSO{sub 4} {center{underscore}dot} 2H{sub 2}O), and the precipitation of ettringite (Ca{sub 6}Al{sub 2}[SO{sub 4}]{sub 3}[OH]{sub 12} {center{underscore}dot} 26H{sub 2}O) from the soluble calcium, sulfates and alumina. No thaumasite was noted in the specimens. The ashes appeared to follow one of several hydration reaction trends: (1) ettringite-only development, (2) ettringite and/or gypsum early followed by later gypsum formation, or (3) gypsum-only formation. Testing confirmed that the hydration reaction chemistry was related to geotechnical properties of the ashes. Strength development and expansion appeared to

  7. Control Systems Cyber Security:Defense in Depth Strategies

    SciTech Connect (OSTI)

    David Kuipers; Mark Fabro

    2006-05-01

    Information infrastructures across many public and private domains share several common attributes regarding IT deployments and data communications. This is particularly true in the control systems domain. A majority of the systems use robust architectures to enhance business and reduce costs by increasing the integration of external, business, and control system networks. However, multi-network integration strategies often lead to vulnerabilities that greatly reduce the security of an organization, and can expose mission-critical control systems to cyber threats. This document provides guidance and direction for developing ‘defense-in-depth’ strategies for organizations that use control system networks while maintaining a multi-tier information architecture that requires: Maintenance of various field devices, telemetry collection, and/or industrial-level process systems Access to facilities via remote data link or modem Public facing services for customer or corporate operations A robust business environment that requires connections among the control system domain, the external Internet, and other peer organizations.

  8. Permeability, geochemical, and water quality tests in support of an aquifer thermal energy storage site in Minnesota

    SciTech Connect (OSTI)

    Blair, S.C.; Deutsch, W.J.; Mitchell, P.J.

    1985-04-01

    This report describes the Underground Energy Storage Program's efforts to characterize physicochemical processes at DOE's ATES Field Test Facility (FTF) located on the University of Minnesota campus at St. Paul, Minnesota. Experimental efforts include: field tests at the St. Paul FTF to characterize fluid injectability and to evaluate the effectiveness of fluid-conditioning equipment, geochemical studies to investigate chemical reactions resulting from alterations to the aquifer's thermal regime, and laboratory tests on sandstone core from the site. Each experimental area is discussed and results obtained thus far are reported. 23 refs., 39 figs., 12 tabs.

  9. Geologic, geochemical, and geographic controls on NORM in produced water from Texas oil, gas, and geothermal reservoirs. Final report

    SciTech Connect (OSTI)

    Fisher, R.

    1995-08-01

    Water from Texas oil, gas, and geothermal wells contains natural radioactivity that ranges from several hundred to several thousand Picocuries per liter (pCi/L). This natural radioactivity in produced fluids and the scale that forms in producing and processing equipment can lead to increased concerns for worker safety and additional costs for handling and disposing of water and scale. Naturally occurring radioactive materials (NORM) in oil and gas operations are mainly caused by concentrations of radium-226 ({sup 226}Ra) and radium-228 ({sup 228}Ra), daughter products of uranium-238 ({sup 238}U) and thorium-232 ({sup 232}Th), respectively, in barite scale. We examined (1) the geographic distribution of high NORM levels in oil-producing and gas-processing equipment, (2) geologic controls on uranium (U), thorium (Th), and radium (Ra) in sedimentary basins and reservoirs, (3) mineralogy of NORM scale, (4) chemical variability and potential to form barite scale in Texas formation waters, (5) Ra activity in Texas formation waters, and (6) geochemical controls on Ra isotopes in formation water and barite scale to explore natural controls on radioactivity. Our approach combined extensive compilations of published data, collection and analyses of new water samples and scale material, and geochemical modeling of scale Precipitation and Ra incorporation in barite.

  10. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; et al

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in compositionmore » of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.« less

  11. Application of geochemical techniques to deduce the reservoir performance of the Palinpinon Geothermal Field, Philippines - an update

    SciTech Connect (OSTI)

    Ramos-Candelaria, M.N.; Garcia, S.E.; Hermoso, D.Z.

    1997-12-31

    Regular monitoring of various geochemical parameters in the water and vapor phases of the production wells at the Palinpinon I and II sectors of the Southern Negros Geothermal Field have been useful in the identification of the dominant reservoir processes occurring related to the present exploitation strategy. Observed geochemical and physical changes in the output of production wells have dictated production and injection strategies adopted to maximize production to meet the steam requirements of the power plant. Correlation of both physical and chemical data have identified the following reservoir processes: (1) Injection breakthrough via the Ticala Fault of the highly mineralized (Cl {approximately}8,000-10,500 mg/kg), isotopically enriched ({delta}{sup 18}O = -3.00{per_thousand}, {delta}{sup 2} H = -39{per_thousand}), and gas depleted brine for wells in the SW and central Puhagan. Injection breakthrough is also occurring in Palinpinon II and has resulted in temperature drops of 5-10{degrees}C.2. Pressure drawdown enhanced boiling in the liquid reservoir with steam separation of 220-240{degrees}C, feeding wells tapping the natural steam zone. However, enhanced drawdown has induced the entry of shallow acid steam condensate fluids in some wells (e.g. OK-7, PN-29D, PN-18D), which if not arrested could reduce production.

  12. Geophex Airborne Unmanned Survey System

    SciTech Connect (OSTI)

    Won, I.L.; Keiswetter, D.

    1995-12-31

    Ground-based surveys place personnel at risk due to the proximity of buried unexploded ordnance (UXO) items or by exposure to radioactive materials and hazardous chemicals. The purpose of this effort is to design, construct, and evaluate a portable, remotely-piloted, airborne, geophysical survey system. This non-intrusive system will provide stand-off capability to conduct surveys and detect buried objects, structures, and conditions of interest at hazardous locations. During a survey, the operators remain remote from, but within visual distance of, the site. The sensor system never contacts the Earth, but can be positioned near the ground so that weak geophysical anomalies can be detected. The Geophex Airborne Unmanned Survey System (GAUSS) is designed to detect and locate small-scale anomalies at hazardous sites using magnetic and electromagnetic survey techniques. The system consists of a remotely-piloted, radio-controlled, model helicopter (RCH) with flight computer, light-weight geophysical sensors, an electronic positioning system, a data telemetry system, and a computer base-station. The report describes GAUSS and its test results.

  13. Data Package of Samples Collected for Hydrogeologic and Geochemical Characterization: 300 Area RI/FS Sediment Cores

    SciTech Connect (OSTI)

    Lindberg, Michael J.; Bjornstad, Bruce N.; Lanigan, David C.; Williams, Benjamin D.

    2011-05-01

    This is a data package for sediment samples received from the 300 FF 5 OU. This report was prepared for CHPRC. Between August 16, 2010 and April 25, 2011 sediment samples were received from 300-FF-5 for geochemical studies. The analyses for this project were performed at the 331 building located in the 300 Area of the Hanford Site. The analyses were performed according to Pacific Northwest National Laboratory (PNNL) approved procedures and/or nationally recognized test procedures. The data sets include the sample identification numbers, analytical results, estimated quantification limits (EQL), and quality control data. The preparatory and analytical quality control requirements, calibration requirements, acceptance criteria, and failure actions are defined in the on-line QA plan 'Conducting Analytical Work in Support of Regulatory Programs' (CAW). This QA plan implements the Hanford Analytical Services Quality Assurance Requirements Documents (HASQARD) for PNNL.

  14. The integration of geochemical, geological and engineering data to determine reservoir continuity in the Iagifu-Hedinia field, Papua New Guinea

    SciTech Connect (OSTI)

    Kaufman, R.L.; Eisenberg, L.I.; Fitzmorris, R.E.

    1995-08-01

    A series of oil and gas fields, including Iagifu-Hedinia, occur along the leading edge of the Papuan fold and thrust belt. Formed during Pliocene to Recent compression, they are structurally complex, and typically broken into multiple reservoir compartments. The presence of the karstic Darai Limestone at the surface over most of the fold belt prevents acquisition of useful seismic data. Reservoir mapping, and establishment of reservoir continuity, is therefore based soley on (1) surface geologic data, (2) drilling data; initially dipmeter and RFT pressure data, and subsequently well production histories, and (3) geochemical correlation of reservoir fluids. During appraisal of the Iagifu-Hedinia discovery, these complimentary data sets demonstrated that (1) a single hydrocarbon column existed above a flowing aquifer in the main block of Iagifu-Hedinia field, (2) a separate acuumulation existed in the Usano area. Geochemical data have suggested the presence of reservoir compartments where other data were missing or inconclusive. Subsequently-acquired production history data have confirmed the geochemically-based interpretations. Geochemical data suggest that oils at Iagifu-Hedinia have a common source. The slight differences in oil composition between reservoirs are likely due to multiple phases of expulsion from the same source rock and/or migration-fractionation.

  15. Development of a Drillrod/Telemetry Radar

    SciTech Connect (OSTI)

    Raton Technology Research, Inc.

    1999-11-12

    Efficient extraction of deeply buried natural resources is dependent upon accurate geologic models. The model becomes the basis for developing plans for extraction of the resource. Geoscientists working in geothermal and hydrocarbon recovery have a great deal in common with fellow geoscientists working in the mining industry. They appreciate the intractable problem of increasing the depth of investigation to tens of meters from the wellbore. The goal of this project was to develop a borehole radar tool to acquire data within tens of meters from the wellbore. For geothermal and hydrocarbon applications, the tool was to acquire data for mapping fractures surrounding the wellbore. In mining of coal, the radar acquires data for determining coal seam thickness and detecting geologic anomalies ahead of mining.

  16. A unified site evaluation system for wind energy conversion

    SciTech Connect (OSTI)

    Biro, G.G.

    1980-12-01

    The described evaluation system includes all field and office engineering work needed for proper site selections and for writing the environmental impact statement. Meteorological measurements with collapsible towers trucked to the site, the needed instrumentation, and data transmission with satellite telemetry for storing the meteorological data on a magnetic tape for direct input into the computer are described. A computer program WESES was developed to calculate the energy output of WECSs using the meteorological data on the magnetic tapes. A test site analysis using 7 years of wind velocity measurements is performed, and two 500-kW power wind energy conversion systems have been evaluated. The calculational results give the hourly fluctuations of energy output for any day of the measurements, which also can be used for comparing with load demands. It also calculates and shows in graphs the daily and monthly cumulative energy outputs and compares the energy outputs of different wind energy conversion systems for any desired time period.

  17. Mercury Geochemical, Groundwater Geochemical, And Radiometric...

    Open Energy Info (EERE)

    at right angles to known and suspected faults. Scintillometer readings (gamma radiation - total counts second) were also recorded at each soil sample station. At the...

  18. Solid phase evolution in the Biosphere 2 hillslope experiment as predicted by modeling of hydrologic and geochemical fluxes

    SciTech Connect (OSTI)

    Dontsova, K.; Steefel, C.I.; Desilets, S.; Thompson, A.; Chorover, J.

    2009-07-15

    A reactive transport geochemical modeling study was conducted to help predict the mineral transformations occurring over a ten year time-scale that are expected to impact soil hydraulic properties in the Biosphere 2 (B2) synthetic hillslope experiment. The modeling sought to predict the rate and extent of weathering of a granular basalt (selected for hillslope construction) as a function of climatic drivers, and to assess the feedback effects of such weathering processes on the hydraulic properties of the hillslope. Flow vectors were imported from HYDRUS into a reactive transport code, CrunchFlow2007, which was then used to model mineral weathering coupled to reactive solute transport. Associated particle size evolution was translated into changes in saturated hydraulic conductivity using Rosetta software. We found that flow characteristics, including velocity and saturation, strongly influenced the predicted extent of incongruent mineral weathering and neo-phase precipitation on the hillslope. Results were also highly sensitive to specific surface areas of the soil media, consistent with surface reaction controls on dissolution. Effects of fluid flow on weathering resulted in significant differences in the prediction of soil particle size distributions, which should feedback to alter hillslope hydraulic conductivities.

  19. Geochemical and Mineralogical Investigation of Uranium in Multielement Contaminated, Organicrich Subsurface Sediment

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Gartman, Brandy N.; Kukkadapu, Ravi K.; Arey, Bruce W.; Williams, Kenneth H.; Mouser, Paula J.; Heald, Steve M.; Bargar, John R.; Janot, Noemie; Yabusaki, Steven B.; Long, Philip E.

    2014-03-02

    Alluvial sediments characterized by an abundance of refractory or lignitic organic carbon compounds and reduced Fe and S bearing mineral phases have been identified through drilling activities at the U.S. Department of Energys (DOE) Integrated Field Research Challenge (IFRC) site at Rifle, CO. Regions of the subsurface from which such sediments are derived are referred to as Naturally Reduced Zones (NRZ). We conducted a study with NRZ sediments with the objective to: i.) Characterize solid phase contamination of U and other co-contaminants; ii.) Document the occurrence of potential U host minerals; iii.) Determine U valence state and micron scale spatial association with co-contaminants. Macroscopic (wet chemical batch extractions and a column experiment), microscopic (SEM-EDS), and spectroscopic (Mssbauer, -XRF and XANES) techniques were employed. Results showed that sediments solid phase had significant concentrations of U, S, As, Zn, V, Cr, Cu and Se, and a remarkable assortment of potential U hosts (sorbents and/or electron donors), such as Fe oxides (hematite, magnetite, Al-substituted goethite), siderite, reduced Fe(II) bearing clays, sulfides of different types, Zn sulfide framboids and multi element sulfides. Multi-contaminants, micron size (ca. 5 to 30 m) areas of mainly U(IV) and some U(VI), and/or other electron scavengers or donors such as Se, As, Cr, and V were discovered in the sediments, suggesting complex micron-scale system responses to transient redox conditions, and different extent and rates of competing U redox reactions than those of single contaminant systems. Collectively, the results improve our understanding and ability to predict U and NRZs complex behavior and will delineate future research directions to further study both the natural attenuation and persistence of contaminant plumes and their contribution to groundwater contamination.

  20. Salt effects on isotope partitioning and their geochemical implications: An overview

    SciTech Connect (OSTI)

    Horita, J.; Cole, D.R.; Fortier, S.M.

    1996-01-01

    Essential to the use of stable isotopes as natural tracers and geothermometers is the knowledge of equilibrium isotope partitioning between different phases and species, which is usually a function of temperature only. The one exception known to date is oxygen and hydrogen isotope fractionation between liquid water and other phases (steam, gases, minerals), which changes upon the addition of salts to water, i.e., the isotope salt salt effect. Our knowledge of this effect, the difference between activity and composition (a-X) of isotopic water molecules in salt solutions, is very limited and controversial, especially at elevated temperatures. For the last several years, we have been conducting a detailed, systematic experimental study at Oak Ridge National Laboratory to determine the isotope salt effects from room temperature to elevated temperatures (currently to 500{degree}C). From this effort, a simple, coherent picture of the isotope salt effect is emerging, that differs markedly from the complex results reported in the literature. In this communication, we present an overview on the isotope salt effect, obtained chiefly from our study. Observed isotope salt effects in salt solutions are significant even at elevated temperatures. The importance and implications of the isotope salt effect for isotopic studies of brine-dominated systems are also discussed in general terms.

  1. Petroleum potential of the Upper Ordovician Maquoketa Group in Illinois: A coordinated geological and geochemical study

    SciTech Connect (OSTI)

    Crockett, J.E.; Oltz, D.F. ); Kruge, M.A. )

    1990-05-01

    The Ordovician Maquoketa Group in Illinois, predominantly composed of shale, calcareous shale, and carbonates, has long been considered a potential source for Illinois basin hydrocarbons. Methods used to better define the petroleum potential of the Maquoketa in the Illinois basin were lithostratigraphic study, Rock-Eval (pyrolysis) analyses, comparison of molecular markers from whole-rock extracts and produced oil, and construction of burial history models. Organic-rich submature Maquoketa potential source rocks are present in western Illinois at shallow depths on the basin flank. Deeper in the basin in southern Illinois, Rock-Eval analyses indicate that the Maquoketa shale is within the oil window. Solvent extracts of the Maquoketa from western Illinois closely resemble the Devonian New Albany Shale, suggesting that past studies may have erroneously attributed Maquoketa-generated petroleum to a New Albany source or failed to identify mixed source oils. Subtle differences between Maquoketa and New Albany solvent extracts include differences in pristane/phytane ratios, proportions of steroids, and distribution of dimethyldibenzothiophene isomers. Maquoketa solvent extracts show little resemblance to Middle Ordovician oils from the Illinois or Michigan basins. Lithostratigraphic studies identified localized thick carbonate facies in the Maquoketa, suggesting depositional response to upper Ordovician paleostructures. Sandstone facies in the Maquoketa in southwestern Illinois offer a potential source/trap play, as well as serving as potential carrier beds for hydrocarbon migration. Maquoketa source and carrier beds may feed older Ordovician rocks in faulted areas along and south of the Cottage Grove fault system in southern Illinois.

  2. CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    Lauren P. Birgenheier; Michael D. Vanden Berg,

    2011-04-11

    An integrated detailed sedimentologic, stratigraphic, and geochemical study of Utah's Green River Formation has found that Lake Uinta evolved in three phases (1) a freshwater rising lake phase below the Mahogany zone, (2) an anoxic deep lake phase above the base of the Mahogany zone and (3) a hypersaline lake phase within the middle and upper R-8. This long term lake evolution was driven by tectonic basin development and the balance of sediment and water fill with the neighboring basins, as postulated by models developed from the Greater Green River Basin by Carroll and Bohacs (1999). Early Eocene abrupt global-warming events may have had significant control on deposition through the amount of sediment production and deposition rates, such that lean zones below the Mahogany zone record hyperthermal events and rich zones record periods between hyperthermals. This type of climatic control on short-term and long-term lake evolution and deposition has been previously overlooked. This geologic history contains key points relevant to oil shale development and engineering design including: (1) Stratigraphic changes in oil shale quality and composition are systematic and can be related to spatial and temporal changes in the depositional environment and basin dynamics. (2) The inorganic mineral matrix of oil shale units changes significantly from clay mineral/dolomite dominated to calcite above the base of the Mahogany zone. This variation may result in significant differences in pyrolysis products and geomechanical properties relevant to development and should be incorporated into engineering experiments. (3) This study includes a region in the Uinta Basin that would be highly prospective for application of in-situ production techniques. Stratigraphic targets for in-situ recovery techniques should extend above and below the Mahogany zone and include the upper R-6 and lower R-8.

  3. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; et al

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility atmore » an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.« less

  4. Large-Scale Information Systems

    SciTech Connect (OSTI)

    D. M. Nicol; H. R. Ammerlahn; M. E. Goldsby; M. M. Johnson; D. E. Rhodes; A. S. Yoshimura

    2000-12-01

    Large enterprises are ever more dependent on their Large-Scale Information Systems (LSLS), computer systems that are distinguished architecturally by distributed components--data sources, networks, computing engines, simulations, human-in-the-loop control and remote access stations. These systems provide such capabilities as workflow, data fusion and distributed database access. The Nuclear Weapons Complex (NWC) contains many examples of LSIS components, a fact that motivates this research. However, most LSIS in use grew up from collections of separate subsystems that were not designed to be components of an integrated system. For this reason, they are often difficult to analyze and control. The problem is made more difficult by the size of a typical system, its diversity of information sources, and the institutional complexities associated with its geographic distribution across the enterprise. Moreover, there is no integrated approach for analyzing or managing such systems. Indeed, integrated development of LSIS is an active area of academic research. This work developed such an approach by simulating the various components of the LSIS and allowing the simulated components to interact with real LSIS subsystems. This research demonstrated two benefits. First, applying it to a particular LSIS provided a thorough understanding of the interfaces between the system's components. Second, it demonstrated how more rapid and detailed answers could be obtained to questions significant to the enterprise by interacting with the relevant LSIS subsystems through simulated components designed with those questions in mind. In a final, added phase of the project, investigations were made on extending this research to wireless communication networks in support of telemetry applications.

  5. Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico

    SciTech Connect (OSTI)

    Viswanathan, Hari; Dai, Zhenxue; Lopano, Christina; Keating, Elizabeth; Hakala, J. Alexandra; Scheckel, Kirk G.; Zheng, Liange; Gutherie, George D.; Pawar, Rajesh

    2012-10-24

    Migration of carbon dioxide (CO{sub 2}) from deep storage formations into shallow drinking water aquifers is a possible system failure related to geologic CO{sub 2} sequestration. A CO{sub 2} leak may cause mineral precipitation/dissolution reactions, changes in aqueous speciation, and alteration of pH and redox conditions leading to potential increases of trace metal concentrations above EPA National Primary Drinking Water Standards. In this study, the Chimayo site (NM) was examined for site-specific impacts of shallow groundwater interacting with CO{sub 2} from deep storage formations. Major ion and trace element chemistry for the site have been previously studied. This work focuses on arsenic (As), which is regulated by the EPA under the Safe Drinking Water Act and for which some wells in the Chimayo area have concentrations higher than the maximum contaminant level (MCL). Statistical analysis of the existing Chimayo groundwater data indicates that As is strongly correlated with trace metals U and Pb indicating that their source may be from the same deep subsurface water. Batch experiments and materials characterization, such as: X-ray diffraction (XRD), scanning electron microscopy (SEM), and synchrotron micro X-ray fluorescence ({mu}-XRF), were used to identify As association with Fe-rich phases, such as clays or oxides, in the Chimayo sediments as the major factor controlling As fate in the subsurface. Batch laboratory experiments with Chimayo sediments and groundwater show that pH decreases as CO{sub 2} is introduced into the system and buffered by calcite. The introduction of CO{sub 2} causes an immediate increase in As solution concentration, which then decreases over time. A geochemical model was developed to simulate these batch experiments and successfully predicted the pH drop once CO{sub 2} was introduced into the experiment. In the model, sorption of As to illite, kaolinite and smectite through surface complexation proved to be the key reactions in

  6. Geochemical engineering reference manual

    SciTech Connect (OSTI)

    Owen, L.B.; Michels, D.E.

    1984-01-01

    The following topics are included in this manual: physical and chemical properties of geothermal brine and steam, scale and solids control, processing spent brine for reinjection, control of noncondensable gas emissions, and goethermal mineral recovery. (MHR)

  7. Geochemical indicators of depositional environment and soruce-rock potential for the Upper Ordovician Maquoketa Group, Illinois basin

    SciTech Connect (OSTI)

    Guthrie, J.M.; Pratt, L.M. )

    1994-05-01

    Two depositional cycles are recognized within the Upper Ordovician Maquoketa Group of the Illinois basin in a core from the New Jersey Zinc 1 Parrish well of Fulton County, Illinois. Organic carbon (C[sub org]), total sulfur, [sup 13]C content of the organic carbon ([delta][sup 13]C[sub org]), hydrogen and oxygen indices (HI and OI) from Rock-Eval pyrolysis and yields of extractable organic matter (EOM) vary through the cycles. Dark-brown to black, laminated shales are present in the lower portion of each cycle and have high values of C[sub org] (1.0-3.0%), HI (500-1000 mg hydrocarbon [HC]/g total organic carbon[TOC]), and EOM (500-2500 ppm), and more negative [delta][sup 13]C[sub org] values ([delta][sup 13]C[sub org] = -30 to -30.5%). Gray to greenish-gray, bioturbated shales are present in the upper portion of each cycle and have low values of C[sub org] (<1.0%), HI (<500 mg HC/g TOC), and EOM (<500 ppm), and more positive [delta][sup 13]C[sub org] values (-28.5 to 29.5%) compared to the laminated shales. Although thermally immature or marginally mature in this core, the laminated shales represent potential source rock s for petroleum because they contain good to excellent quantities of oil-prone organic matter and are more deeply buried in other areas of the basin. Kerogen elemental data and Rock-Eval data suggest that the source of organic matter in the Maquoketa was uniform, with the notable exception of graptolite-rich layers. Distributions of saturated hydrocarbons for Maquoketa samples resemble those derived from amorphous organic matter. Variations in bulk geochemical data and carbon isotopic compositions within the Maquoketa Group indicate substantial reworking and degradation of organic matter associated with bioturbation and oxygenated depositional conditions. 64 refs., 10 figs., 1 tab.

  8. Geochemical Processes Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Zachara, John M.; Dresel, P. Evan; Krupka, Kenneth M.; Serne, R. Jeffrey

    2007-09-28

    This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical process information available for the vadose zone beneath the single-shell tank farms and the Integrated Disposal Facility. Two companion reports to this one were recently published which discuss the geology of the farms (Reidel and Chamness 2007) and groundwater flow and contamination beneath the farms (Horton 2007).

  9. Novel imaging techniques, integrated with mineralogical, geochemical and microbiological characterizations to determine the biogeochemical controls on technetium mobility in FRC sediments

    SciTech Connect (OSTI)

    Jonathan R. Lloyd

    2009-02-03

    The objective of this research program was to take a highly multidisciplinary approach to define the biogeochemical factors that control technetium (Tc) mobility in FRC sediments. The aim was to use batch and column studies to probe the biogeochemical conditions that control the mobility of Tc at the FRC. Background sediment samples from Area 2 (pH 6.5, low nitrate, low {sup 99}Tc) and Area 3 (pH 3.5, high nitrate, relatively high {sup 99}Tc) of the FRC were selected (http://www.esd.ornl.gov/nabirfrc). For the batch experiments, sediments were mixed with simulated groundwater, modeled on chemical constituents of FRC waters and supplemented with {sup 99}Tc(VII), both with and without added electron donor (acetate). The solubility of the Tc was monitored, alongside other biogeochemical markers (nitrate, nitrite, Fe(II), sulfate, acetate, pH, Eh) as the 'microcosms' aged. At key points, the microbial communities were also profiled using both cultivation-dependent and molecular techniques, and results correlated with the geochemical conditions in the sediments. The mineral phases present in the sediments were also characterized, and the solid phase associations of the Tc determined using sequential extraction and synchrotron techniques. In addition to the batch sediment experiments, where discrete microbial communities with the potential to reduce and precipitate {sup 99}Tc will be separated in time, we also developed column experiments where biogeochemical processes were spatially separated. Experiments were conducted both with and without amendments proposed to stimulate radionuclide immobilization (e.g. the addition of acetate as an electron donor for metal reduction), and were also planned with and without competing anions at high concentration (e.g. nitrate, with columns containing Area 3 sediments). When the columns had stabilized, as determined by chemical analysis of the effluents, we used a spike of the short-lived gamma emitter {sup 99m}Tc (50-200 MBq; half

  10. DOWNHOLE VIBRATION MONITORING & CONTROL SYSTEM

    SciTech Connect (OSTI)

    Martin E. Cobern

    2004-08-31

    The deep hard rock drilling environment induces severe vibrations into the drillstring, which can cause reduced rates of penetration (ROP) and premature failure of the equipment. The only current means of controlling vibration under varying conditions is to change either the rotary speed or the weight-on-bit (WOB). These changes often reduce drilling efficiency. Conventional shock subs are useful in some situations, but often exacerbate the problems. The objective of this project is development of a unique system to monitor and control drilling vibrations in a ''smart'' drilling system. This system has two primary elements: (1) The first is an active vibration damper (AVD) to minimize harmful axial, lateral and torsional vibrations. The hardness of this damper will be continuously adjusted using a robust, fast-acting and reliable unique technology. (2) The second is a real-time system to monitor drillstring vibration, and related parameters. This monitor adjusts the damper according to local conditions. In some configurations, it may also send diagnostic information to the surface via real-time telemetry. The AVD is implemented in a configuration using magnetorheological (MR) fluid. By applying a current to the magnetic coils in the damper, the viscosity of the fluid can be changed rapidly, thereby altering the damping coefficient in response to the measured motion of the tool. Phase I of this program entailed modeling and design of the necessary subsystems and design, manufacture and test of a full laboratory prototype. Phase I of the project was completed by the revised end date of May 31, 2004. The objectives of this phase were met, and all prerequisites for Phase II have been completed.

  11. A Reactive Transport Simulator for Biogeochemical Processes in Subsurface System

    Energy Science and Technology Software Center (OSTI)

    2003-04-01

    BIOGEOCHEM is a Fortran code that mumerically simulates the coupled processes of solute transport, microbial population dynamics, microbial metabolism, and geochemical reactions. The potential applications of the code include, but not limited to, (a) sensitivity and uncertainty analyses for assessing the impact of microbial activity on subsurface geochemical systems; (b) extraction of biogeochemical parameter values from field observations or laboratory measurements, (c) helping to design and optimize laboratory biogeochemical experiments, and (d) data integration. Methodmore » of Solution: A finite difference method and a Newton-Raphson technique are used to solve a set of coupled nonlinear partial differential equations and algebraic equations. Practical Application: Environmental analysis, bioremediation performance assessments of radioactive or non-radioactive wase disposal, and academic research.« less

  12. Field testing of a high-temperature aquifer thermal energy storage system

    SciTech Connect (OSTI)

    Sterling, R.L.; Hoyer, M.C.

    1989-03-01

    The University of Minnesota Aquifer Thermal Energy Storage (ATES) System has been operated as a field test facility for the past six years. Four short-term and two long-term cycles have been completed to data providing a greatly increased understanding of the efficiency and geochemical effects of high-temperature aquifer thermal energy storage. A third long-term cycle is currently being planned to operate the ATES system in conjunction with a real heating load and to further study the geochemical impact on the aquifer from heated waste storage cycles. The most critical activities in the preparation for the next cycle have proved to be the applications for the various permits and variances necessary to conduct the third cycle and the matching of the characteristics of the ATES system during heat recovery with a suitable adjacent building thermal load.

  13. Control Systems Cyber Security: Defense-in-Depth Strategies

    SciTech Connect (OSTI)

    Mark Fabro

    2007-10-01

    Information infrastructures across many public and private domains share several common attributes regarding IT deployments and data communications. This is particularly true in the control systems domain. A majority of the systems use robust architectures to enhance business and reduce costs by increasing the integration of external, business, and control system networks. However, multi-network integration strategies often lead to vulnerabilities that greatly reduce the security of an organization, and can expose mission-critical control systems to cyber threats. This document provides guidance and direction for developing ‘defense-in-depth’ strategies for organizations that use control system networks while maintaining a multi-tier information architecture that requires: • Maintenance of various field devices, telemetry collection, and/or industrial-level process systems • Access to facilities via remote data link or modem • Public facing services for customer or corporate operations • A robust business environment that requires connections among the control system domain, the external Internet, and other peer organizations.

  14. Pre-test geological and geochemical evaluation of the Caprock, St. Peter Sandstone and formation fluids, Yakley Field, Pike County, Illinois

    SciTech Connect (OSTI)

    Not Available

    1983-03-01

    The goal of these studies is to ensure long-term stable containment of air in the underground reservoirs used in conjunction with compressed air energy storage (CAES) plants. The specific objective is to develop stability criteria and engineering guidelines for designing CAES reservoirs in each of the three major reservoir types, including aquifers, salt cavities, and mined hard rock caverns. This document characterizes the geologic nature of porous media constituents native to the aquifer field test site near Pittsfield, Illinois. The geologic samples were subjected to geochemical evaluations to determine anticipated responses to cyclic air injection, heating and moisture - conditions typical of an operating CAES reservoir. This report documents the procedures used and results obtained from these analyses.

  15. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  16. Renewable Energy, Photovoltaic Systems Near Airfields. Electromagnetic Interference

    SciTech Connect (OSTI)

    Deline, Chris; Dann, Geoff

    2015-04-01

    Recent increases in photovoltaic (PV) systems on Department of the Navy (DON) land and potential siting near airfields prompted Commander, Naval Installations Command to fund the Naval Facilities Engineering Command to evaluate the impact of electromagnetic interference (EMI) from PV systems on airfield electronic equipment. Naval Facilities Engineering and Expeditionary Warfare Center tasked Department of Energy National Renewable Energy laboratory (NREL) to conduct the assessment. PV systems often include high-speed switching semiconductor circuits to convert the voltage produced by the PV arrays to the voltage needed by the end user. Switching circuits inherently produce electromagnetic radiation at harmonics of the switching frequency. In this report, existing literature is summarized and tests to measure emissions and mitigation methods are discussed. The literature shows that the emissions from typical PV systems are low strength and unlikely to cause interference to most airfield electronic systems. With diligent procurement and siting of PV systems, including specifications for FCC Part 15 Class A compliant equipment and a 250-foot setback from communication equipment, NREL anticipates little to no EMI impact on nearby communications or telemetry equipment.

  17. Creation of an Engineered Geothermal System through Hydraulic and Thermal Stimulation

    Broader source: Energy.gov [DOE]

    Project objectives: To create an Enhanced Geothermal System on the margin of the Cosofield through the hydraulic, thermal, and/or chemical stimulation of one or more tight injection wells; To increase the productivity of the Cosofield by 10 MWe; To develop and calibrate geomechanical, geochemical, and fluid flow models in order to extend the Coso/EGS concepts to wherever appropriate tectonic and thermal conditions apply.

  18. Drill-hole data, drill-site geology, and geochemical data from the study of Precambrian uraniferous conglomerates of the Medicine Bow Mountains and Sierra Madre of southeastern Wyoming

    SciTech Connect (OSTI)

    Karlstrom, K.E.; Houston, R.S.; Schmidt, T.G.; Inlow, D.; Flurkey, A.J.; Kratochvil, A.L.; Coolidge, C.M.; Sever, C.K.; Quimby, W.F.

    1981-02-01

    This volume is presented as a companion to Volume 1: The Geology and Uranium Potential of Precambrian Conglomerates in the Medicine Bow Mountains and Sierra Madre of Southeastern Wyoming; and to Volume 3: Uranium Assessment for Precambrian Pebble Conglomerates in Southeastern Wyoming. Volume 1 summarized the geologic setting and geologic and geochemical characteristics of uranium-bearing conglomerates in Precambrian metasedimentary rocks of southeastern Wyoming. Volume 3 is a geostatistical resource estimate of U and Th in quartz-pebble conglomerates. This volume contains supporting geochemical data, lithologic logs from 48 drill holes in Precambrian rocks of the Medicine Bow Mountains and Sierra Madre, and drill site geologic maps and cross-sections from most of the holes.

  19. EQ3NR, a computer program for geochemical aqueous speciation-solubility calculations: Theoretical manual, user`s guide, and related documentation (Version 7.0); Part 3

    SciTech Connect (OSTI)

    Wolery, T.J.

    1992-09-14

    EQ3NR is an aqueous solution speciation-solubility modeling code. It is part of the EQ3/6 software package for geochemical modeling. It computes the thermodynamic state of an aqueous solution by determining the distribution of chemical species, including simple ions, ion pairs, and complexes, using standard state thermodynamic data and various equations which describe the thermodynamic activity coefficients of these species. The input to the code describes the aqueous solution in terms of analytical data, including total (analytical) concentrations of dissolved components and such other parameters as the pH, pHCl, Eh, pe, and oxygen fugacity. The input may also include a desired electrical balancing adjustment and various constraints which impose equilibrium with special pure minerals, solid solution end-member components (of specified mole fractions), and gases (of specified fugacities). The code evaluates the degree of disequilibrium in terms of the saturation index (SI = 1og Q/K) and the thermodynamic affinity (A = {minus}2.303 RT log Q/K) for various reactions, such as mineral dissolution or oxidation-reduction in the aqueous solution itself. Individual values of Eh, pe, oxygen fugacity, and Ah (redox affinity) are computed for aqueous redox couples. Equilibrium fugacities are computed for gas species. The code is highly flexible in dealing with various parameters as either model inputs or outputs. The user can specify modification or substitution of equilibrium constants at run time by using options on the input file.

  20. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    SciTech Connect (OSTI)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; Maher, Kate

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ?U/?U (??U), ?U/?U activity ratio, and ?S/S (??S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility at an ISR mining site at Rosita, TX, USA. The ??U in Rosita groundwater varies from 0.61 to -2.49, with a trend toward lower ??U in downgradient wells. The concurrent decrease in U(VI) concentration and ??U with an ? of 0.48 0.08 is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ?U/?U activity ratio and ??S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.

  1. Sedimentological, mineralogical and geochemical definition of oil-shale facies in the lower Parachute Creek Member of Green River Formation, Colorado

    SciTech Connect (OSTI)

    Cole, R.D.

    1984-04-01

    Sedimentological, mineralogical and geochemical studies of two drill cores penetrating the lower Saline zone of the Parachute Creek Member (middle L-4 oil-shale zone through upper R-2 zone) of the Green River Formation in north-central Piceance Creek basin, Colorado, indicate the presence of two distinct oil-shale facies. The most abundant facies has laminated stratification and frequently occurs in the L-4, L-3 and L-2 oil-shale zones. The second, and subordinate facies, has ''streaked and blebby'' stratification and is most abundant in the R-4, R-3 and R-2 zones. Laminated oil shale originated by slow, regular sedimentation during meromictic phases of ancient Lake Uinta, whereas streaked and blebby oil shale was deposited by episodic, non-channelized turbidity currents. Laminated oil shale has higher contents of nahcolite, dawsonite, quartz, K-feldspar and calcite, but less dolomite/ankerite and albite than streaked and blebby oil shale. Ca-Mg-Fe carbonate minerals in laminated oil shale have more variable compositions than those in streaked and blebby shales. Streaked and blebby oil shale has more kerogen and a greater diversity of kerogen particles than laminated oil shale. Such variations may produce different pyrolysis reactions when each shale type is retorted.

  2. Development of an Advanced Hydraulic Fracture Mapping System

    SciTech Connect (OSTI)

    Norm Warpinski; Steve Wolhart; Larry Griffin; Eric Davis

    2007-01-31

    The project to develop an advanced hydraulic fracture mapping system consisted of both hardware and analysis components in an effort to build, field, and analyze combined data from tiltmeter and microseismic arrays. The hardware sections of the project included: (1) the building of new tiltmeter housings with feedthroughs for use in conjunction with a microseismic array, (2) the development of a means to use separate telemetry systems for the tilt and microseismic arrays, and (3) the selection and fabrication of an accelerometer sensor system to improve signal-to-noise ratios. The analysis sections of the project included a joint inversion for analysis and interpretation of combined tiltmeter and microseismic data and improved methods for extracting slippage planes and other reservoir information from the microseisms. In addition, testing was performed at various steps in the process to assess the data quality and problems/issues that arose during various parts of the project. A prototype array was successfully tested and a full array is now being fabricated for industrial use.

  3. High Temperature 300°C Directional Drilling System

    SciTech Connect (OSTI)

    Chatterjee, Kamalesh; Aaron, Dick; Macpherson, John

    2015-07-31

    Many countries around the world, including the USA, have untapped geothermal energy potential. Enhanced Geothermal Systems (EGS) technology is needed to economically utilize this resource. Temperatures in some EGS reservoirs can exceed 300°C. To effectively utilize EGS resources, an array of injector and production wells must be accurately placed in the formation fracture network. This requires a high temperature directional drilling system. Most commercial services for directional drilling systems are rated for 175°C while geothermal wells require operation at much higher temperatures. Two U.S. Department of Energy (DOE) Geothermal Technologies Program (GTP) projects have been initiated to develop a 300°C capable directional drilling system, the first developing a drill bit, directional motor, and drilling fluid, and the second adding navigation and telemetry systems. This report is for the first project, “High Temperature 300°C Directional Drilling System, including drill bit, directional motor and drilling fluid, for enhanced geothermal systems,” award number DE-EE0002782. The drilling system consists of a drill bit, a directional motor, and drilling fluid. The DOE deliverables are three prototype drilling systems. We have developed three drilling motors; we have developed four roller-cone and five Kymera® bits; and finally, we have developed a 300°C stable drilling fluid, along with a lubricant additive for the metal-to-metal motor. Metal-to-metal directional motors require coatings to the rotor and stator for wear and corrosion resistance, and this coating research has been a significant part of the project. The drill bits performed well in the drill bit simulator test, and the complete drilling system has been tested drilling granite at Baker Hughes’ Experimental Test Facility in Oklahoma. The metal-to-metal motor was additionally subjected to a flow loop test in Baker Hughes’ Celle Technology Center in Germany, where it ran for more than 100

  4. Assessment of Geochemical Environment for the Proposed INL Remote-Handled Low-Level Waste Disposal Facility

    SciTech Connect (OSTI)

    D. Craig Cooper

    2011-11-01

    Conservative sorption parameters have been estimated for the proposed Idaho National Laboratory Remote-Handled Low-Level Waste Disposal Facility. This analysis considers the influence of soils, concrete, and steel components on water chemistry and the influence of water chemistry on the relative partitioning of radionuclides over the life of the facility. A set of estimated conservative distribution coefficients for the primary media encountered by transported radionuclides has been recommended. These media include the vault system, concrete-sand-gravel mix, alluvium, and sedimentary interbeds. This analysis was prepared to support the performance assessment required by U.S. Department of Energy Order 435.1, 'Radioactive Waste Management.' The estimated distribution coefficients are provided to support release and transport calculations of radionuclides from the waste form through the vadose zone. A range of sorption parameters are provided for each key transport media, with recommended values being conservative. The range of uncertainty has been bounded through an assessment of most-likely-minimum and most-likely-maximum distribution coefficient values. The range allows for adequate assessment of mean facility performance while providing the basis for uncertainty analysis.

  5. Description of Fracture Systems for External Criticality Reports

    SciTech Connect (OSTI)

    Jean-Philippe Nicot

    2001-09-21

    The purpose of this Analysis/Model Report (AMR) is to describe probabilistically the main features of the geometry of the fracture system in the vicinity of the repository. They will be used to determine the quantity of fissile material that could accumulate in the fractured rock underneath a waste package as it degrades. This AMR is to feed the geochemical calculations for external criticality reports. This AMR is done in accordance with the technical work plan (BSC (Bechtel SAIC Company) 2001 b). The scope of this AMR is restricted to the relevant parameters of the fracture system. The main parameters of interest are fracture aperture and fracture spacing distribution parameters. The relative orientation of the different fracture sets is also important because of its impact on criticality, but they will be set deterministically. The maximum accumulation of material depends primarily on the fracture porosity, combination of the fracture aperture, and fracture intensity. However, the fracture porosity itself is not sufficient to characterize the potential for accumulation of a fracture system. The fracture aperture is also important because it controls both the flow through the fracture and the potential plugging of the system. Other features contributing to the void space such as lithophysae are also investigated. On the other hand, no analysis of the matrix porosity is done. The parameters will be used in sensitivity analyses of geochemical calculations providing actinide accumulations and in the subsequent Monte Carlo criticality analyses.

  6. Predictive modeling of CO{sub 2} sequestration in deep saline sandstone reservoirs: Impacts of geochemical kinetics

    SciTech Connect (OSTI)

    Balashov, Victor N.; Guthrie, George D.; Hakala, J. Alexandra; Lopano, Christina L. J.; Rimstidt, Donald; Brantley, Susan L.

    2013-03-01

    One idea for mitigating the increase in fossil-fuel generated CO{sub 2} in the atmosphere is to inject CO{sub 2} into subsurface saline sandstone reservoirs. To decide whether to try such sequestration at a globally significant scale will require the ability to predict the fate of injected CO{sub 2}. Thus, models are needed to predict the rates and extents of subsurface rock-water-gas interactions. Several reactive transport models for CO{sub 2} sequestration created in the last decade predicted sequestration in sandstone reservoirs of ~17 to ~90 kg CO{sub 2} m{sup -3|. To build confidence in such models, a baseline problem including rock + water chemistry is proposed as the basis for future modeling so that both the models and the parameterizations can be compared systematically. In addition, a reactive diffusion model is used to investigate the fate of injected supercritical CO{sub 2} fluid in the proposed baseline reservoir + brine system. In the baseline problem, injected CO{sub 2} is redistributed from the supercritical (SC) free phase by dissolution into pore brine and by formation of carbonates in the sandstone. The numerical transport model incorporates a full kinetic description of mineral-water reactions under the assumption that transport is by diffusion only. Sensitivity tests were also run to understand which mineral kinetics reactions are important for CO{sub 2} trapping. The diffusion transport model shows that for the first ~20 years after CO{sub 2} diffusion initiates, CO{sub 2} is mostly consumed by dissolution into the brine to form CO{sub 2,aq} (solubility trapping). From 20-200 years, both solubility and mineral trapping are important as calcite precipitation is driven by dissolution of oligoclase. From 200 to 1000 years, mineral trapping is the most important sequestration mechanism, as smectite dissolves and calcite precipitates. Beyond 2000 years, most trapping is due to formation of aqueous HCO{sub 3}{sup -}. Ninety-seven percent of the

  7. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    SciTech Connect (OSTI)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; Maher, Kate

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility at an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.

  8. DOE ER63951-3 Final Report: An Integrated Assessment of Geochemical and Community Structure Determinants of Metal Reduction Rates in Subsurface Sediments

    SciTech Connect (OSTI)

    Susan Pfiffner

    2010-06-28

    The objective of this research was to examine the importance of microbial community structure in influencing uranium reduction rates in subsurface sediments. If the redox state alone is the key to metal reduction, then any organisms that can utilize the oxygen and nitrate in the subsurface can change the geochemical conditions so metal reduction becomes an energetically favored reaction. Thus, community structure would not be critical in determining rates or extent of metal reduction unless community structure influenced the rate of change in redox. Alternatively, some microbes may directly catalyze metal reduction (e.g., specifically reduce U). In this case the composition of the community may be more important and specific types of electron donors may promote the production of communities that are more adept at U reduction. Our results helped determine if the type of electron donor or the preexisting community is important in the bioremediation of metal-contaminated environments subjected to biostimulation. In a series of experiments at the DOE FRC site in Oak Ridge we have consistently shown that all substrates promoted nitrate reduction, while glucose, ethanol, and acetate always promoted U reduction. Methanol only occasionally promoted extensive U reduction which is possibly due to community heterogeneity. There appeared to be limitations imposed on the community related to some substrates (e.g. methanol and pyruvate). Membrane lipid analyses (phospholipids and respiratory quinones) indicated different communities depending on electron donor used. Terminal restriction fragment length polymorphism and clone libraries indicated distinct differences among communities even in treatments that promoted U reduction. Thus, there was enough metabolic diversity to accommodate many different electron donors resulting in the U bioimmobilization.

  9. Computed solid phases limiting the concentration of dissolved constituents in basalt aquifers of the Columbia Plateau in eastern Washington. Geochemical modeling and nuclide/rock/groundwater interaction studies

    SciTech Connect (OSTI)

    Deutsch, W.J.; Jenne, E.A.; Krupka, K.M.

    1982-08-01

    A speciation-solubility geochemical model, WATEQ2, was used to analyze geographically-diverse, ground-water samples from the aquifers of the Columbia Plateau basalts in eastern Washington. The ground-water samples compute to be at equilibrium with calcite, which provides both a solubility control for dissolved calcium and a pH buffer. Amorphic ferric hydroxide, Fe(OH)/sub 3/(A), is at saturation or modestly oversaturated in the few water samples with measured redox potentials. Most of the ground-water samples compute to be at equilibrium with amorphic silica (glass) and wairakite, a zeolite, and are saturated to oversaturated with respect to allophane, an amorphic aluminosilicate. The water samples are saturated to undersaturated with halloysite, a clay, and are variably oversaturated with regard to other secondary clay minerals. Equilibrium between the ground water and amorphic silica presumably results from the dissolution of the glassy matrix of the basalt. The oversaturation of the clay minerals other than halloysite indicates that their rate of formation lags the dissolution rate of the basaltic glass. The modeling results indicate that metastable amorphic solids limit the concentration of dissolved silicon and suggest the same possibility for aluminum and iron, and that the processes of dissolution of basaltic glass and formation of metastable secondary minerals are continuing even though the basalts are of Miocene age. The computed solubility relations are found to agree with the known assemblages of alteration minerals in the basalt fractures and vesicles. Because the chemical reactivity of the bedrock will influence the transport of solutes in ground water, the observed solubility equilibria are important factors with regard to chemical-retention processes associated with the possible migration of nuclear waste stored in the earth's crust.

  10. Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

    SciTech Connect (OSTI)

    Rose, A. W.; Smith, A. T.; Wesolowski, D.

    1982-08-01

    A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program.

  11. The oil and gas potential of southern Bolivia: Contributions from a dual source rock system

    SciTech Connect (OSTI)

    Hartshorn, K.G.

    1996-08-01

    The southern Sub-Andean and Chaco basins of Bolivia produce oil, gas and condensate from reservoirs ranging from Devonian to Tertiary in age. Geochemical evidence points to contributions from two Paleozoic source rocks: the Devonian Los Monos Formation and the Silurian Kirusillas Formation. Rock-Eval pyrolysis, biomarker data, microscopic kerogen analysis, and burial history modeling are used to assess the quality, distribution, and maturity of both source rock systems. The geochemical results are then integrated with the structural model for the area in order to determine the most likely pathways for migration of oil and gas in the thrust belt and its foreland. Geochemical analysis and modeling show that the primary source rock, shales of the Devonian Los Monos Formation, entered the oil window during the initial phase of thrusting in the sub-Andean belt. This provides ideal timing for oil accumulation in younger reservoirs of the thrust belt. The secondary source rock, although richer, consumed most of its oil generating capacity prior to the development of the thrust related structures. Depending on burial depth and location, however, the Silurian source still contributes gas, and some oil, to traps in the region.

  12. Wideband precision analog telemetry link using digital techniques

    SciTech Connect (OSTI)

    Hearn, W.E.

    1982-10-01

    A highly linear Wideband Analog Fiber Optic Link is described which samples at a 1 MHz rate with 10-bit accuracy and transmits and receives by means of a high speed PDM code. Aliasing and sampling effects are fully suppressed and a nearly Gaussian pulse response is attained with a 2 ..mu..sec risetime. Analog signals are recovered with very low distortion and d.c. drift and a S/N ratio of better than 52 db.

  13. Geochemical Techniques | Open Energy Information

    Open Energy Info (EERE)

    Geothermometers Multicomponent Geothermometers Silica Geothermometers Thermal Ion Dispersion Thermochronometry References General References Technical References No exploration...

  14. ENZYME ACTIVITY PROBE AND GEOCHEMICAL ASSESSMENT FOR POTENTIAL AEROBIC COMETABOLISM OF TRICHLOROETHENE IN GROUNDWATER OF THE NORTHWEST PLUME, PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY

    SciTech Connect (OSTI)

    Looney, B; M. Hope Lee, M; S. K. Hampson, S

    2008-06-27

    The overarching objective of the Paducah Gaseous Diffusion Plant (PGDP) enzyme activity probe (EAP) effort is to determine if aerobic cometabolism is contributing to the attenuation of trichloroethene (TCE) and other chlorinated solvents in the contaminated groundwater beneath PGDP. The site-specific objective for the EAP assessment is to identify if key metabolic pathways are present and expressed in the microbial community--namely the pathways that are responsible for degradation of methane and aromatic (e.g. toluene, benzene, phenol) substrates. The enzymes produced to degrade methane and aromatic compounds also break down TCE through a process known as cometabolism. EAPs directly measure if methane and/or aromatic enzyme production pathways are operating and, for the aromatic pathways, provide an estimate of the number of active organisms in the sampled groundwater. This study in the groundwater plumes at PGDP is a major part of a larger scientific effort being conducted by Interstate Technology and Regulatory Council (ITRC), U.S. Department of Energy (DOE) Office of Environmental Management (EM), Savannah River National Laboratory (SRNL), and North Wind Inc. in which EAPs are being applied to contaminated groundwater from diverse hydrogeologic and plume settings throughout the U.S. to help standardize their application as well as their interpretation. While EAP data provide key information to support the site specific objective for PGDP, several additional lines of evidence are being evaluated to increase confidence in the determination of the occurrence of biodegradation and the rate and sustainability of aerobic cometabolism. These complementary efforts include: (1) Examination of plume flowpaths and comparison of TCE behavior to 'conservative' tracers in the plume (e.g., {sup 99}Tc); (2) Evaluation of geochemical conditions throughout the plume; and (3) Evaluation of stable isotopes in the contaminants and their daughter products throughout the plume. If

  15. Generic Natural Systems Evaluation - Thermodynamic Database Development and Data Management

    SciTech Connect (OSTI)

    Wolery, T W; Sutton, M

    2011-09-19

    Thermodynamic data are essential for understanding and evaluating geochemical processes, as by speciation-solubility calculations, reaction-path modeling, or reactive transport simulation. These data are required to evaluate both equilibrium states and the kinetic approach to such states (via the affinity term or its equivalent in commonly used rate laws). These types of calculations and the data needed to carry them out are a central feature of geochemistry in many applications, including water-rock interactions in natural systems at low and high temperatures. Such calculations are also made in engineering studies, for example studies of interactions involving man-made materials such as metal alloys and concrete. They are used in a fairly broad spectrum of repository studies where interactions take place among water, rock, and man-made materials (e.g., usage on YMP and WIPP). Waste form degradation, engineered barrier system performance, and near-field and far-field transport typically incorporate some level of thermodynamic modeling, requiring the relevant supporting data. Typical applications of thermodynamic modeling involve calculations of aqueous speciation (which is of great importance in the case of most radionuclides), solubilities of minerals and related solids, solubilities of gases, and stability relations among the various possible phases that might be present in a chemical system at a given temperature and pressure. If a phase can have a variable chemical composition, then a common calculational task is to determine that composition. Thermodynamic modeling also encompasses ion exchange and surface complexation processes. Any and all of these processes may be important in a geochemical process or reactive transport calculation. Such calculations are generally carried out using computer codes. For geochemical modeling calculations, codes such as EQ3/6 and PHREEQC, are commonly used. These codes typically provide 'full service' geochemistry, meaning that

  16. ITC/USA/'90; Proceedings of the International Telemetering Conference, Las Vegas, NV, Oct. 29-Nov. 2, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This conference presents papers in the fields of airborne telemetry, measurement technology, video instrumentation and monitoring, tracking and receiving systems, and real-time processing in telemetry. Topics presented include packet telemetry ground station simulation, a predictable performance wideband noise generator, an improved drone tracking control system transponder, the application of neural networks to drone control, and an integrated real-time turbine engine flight test system.

  17. Statistical Characterization of School Bus Drive Cycles Collected via Onboard Logging Systems

    SciTech Connect (OSTI)

    Duran, A.; Walkowicz, K.

    2013-10-01

    In an effort to characterize the dynamics typical of school bus operation, National Renewable Energy Laboratory (NREL) researchers set out to gather in-use duty cycle data from school bus fleets operating across the country. Employing a combination of Isaac Instruments GPS/CAN data loggers in conjunction with existing onboard telemetric systems resulted in the capture of operating information for more than 200 individual vehicles in three geographically unique domestic locations. In total, over 1,500 individual operational route shifts from Washington, New York, and Colorado were collected. Upon completing the collection of in-use field data using either NREL-installed data acquisition devices or existing onboard telemetry systems, large-scale duty-cycle statistical analyses were performed to examine underlying vehicle dynamics trends within the data and to explore vehicle operation variations between fleet locations. Based on the results of these analyses, high, low, and average vehicle dynamics requirements were determined, resulting in the selection of representative standard chassis dynamometer test cycles for each condition. In this paper, the methodology and accompanying results of the large-scale duty-cycle statistical analysis are presented, including graphical and tabular representations of a number of relationships between key duty-cycle metrics observed within the larger data set. In addition to presenting the results of this analysis, conclusions are drawn and presented regarding potential applications of advanced vehicle technology as it relates specifically to school buses.

  18. South Atlantic sag basins: new petroleum system components

    SciTech Connect (OSTI)

    Henry, S.G. Mohriak, W.U.; Mello, M.R.

    1996-08-01

    Newly discovered pre-salt source rocks, reservoirs and seals need to be included as components to the petroleum systems of both sides of the South Atlantic. These new components lie between the pre-salt rift strata and the Aptian salt layers, forming large, post-rift, thermal subsidence sag basins. These are differentiated from the older rift basins by the lack of syn-rift faulting and a reflector geometry that is parallel to the base salt regional unconformity rather than to the Precambrian basement. These basins are observed in deep water regions overlying areas where both the mantle and the crust have been involved in the extension. This mantle involvement creates post-rift subsiding depocenters in which deposition is continuous while proximal rift-phase troughs with little or no mantle involvement are bypassed and failed to accumulate potential source rocks during anoxic times. These features have been recognized in both West African Kwanza Basin and in the East Brasil Rift systems. The pre-salt source rocks that are in the West African sag basins were deposited in lacustrine brackish to saline water environment and are geochemically distinct from the older, syn-rift fresh to brackish water lakes, as well as from younger, post-salt marine anoxic environments of the drift phase. Geochemical analyses of the source rocks and their oils have shown a developing source rock system evolving from isolated deep rift lakes to shallow saline lakes, and culminating with the infill of the sag basin by large saline lakes to a marginally marine restricted gulf. Sag basin source rocks may be important in the South Atlantic petroleum system by charging deep-water prospects where syn-rift source rocks are overmature and the post-salt sequences are immature.

  19. Determination of the response function for the Portsmouth Gaseous Diffusion Plant criticality accident alarm system neutron detectors

    SciTech Connect (OSTI)

    Tayloe, R.W. Jr.; Brown, A.S.; Dobelbower, M.C.; Woollard, J.E.

    1997-03-01

    Neutron-sensitive radiation detectors are used in the Portsmouth Gaseous Diffusion Plant`s (PORTS) criticality accident alarm system (CAAS). The CAAS is composed of numerous detectors, electronics, and logic units. It uses a telemetry system to sound building evacuation horns and to provide remote alarm status in a central control facility. The ANSI Standard for a CAAS uses a free-in-air dose rate to define the detection criteria for a minimum accident-of-concern. Previously, the free-in-air absorbed dose rate from neutrons was used for determining the areal coverge of criticality detection within PORTS buildings handling fissile materials. However, the free-in-air dose rate does not accurately reflect the response of the neutron detectors in use at PORTS. Because the cost of placing additional CAAS detectors in areas of questionable coverage (based on a free-in-air absorbed dose rate) is high, the actual response function for the CAAS neutron detectors was determined. This report, which is organized into three major sections, discusses how the actual response function for the PORTS CAAS neutron detectors was determined. The CAAS neutron detectors are described in Section 2. The model of the detector system developed to facilitate calculation of the response function is discussed in Section 3. The results of the calculations, including confirmatory measurements with neutron sources, are given in Section 4.

  20. Geophex Airborne Unmanned Survey System (GAUSS). Topical report, October 1993--September 1996

    SciTech Connect (OSTI)

    1998-12-31

    This document is a Final Technical Report that describes the results of the Geophex Airborne Unmanned Survey System (GAUSS) research project. The objectives were to construct a geophysical data acquisition system that uses a remotely operated unmanned aerial vehicle (UAV) and to evaluate its effectiveness for characterization of hazardous environmental sites. The GAUSS is a data acquisition system that mitigates the potential risk to personnel during geophysical characterization of hazardous or radioactive sites. The fundamental basis of the GAUSS is as follows: (1) an unmanned survey vehicle carries geophysical sensors into a hazardous location, (2) the pilot remains outside the hazardous site and operates the vehicle using radio control, (3) geophysical measurements and their spatial locations are processed by an automated data-acquisition system which displays data on an off-site monitor in real-time, and (4) the pilot uses the display to direct the survey vehicle for complete site coverage. The objective of our Phase I research was to develop a data acquisition and processing (DAP) subsystem and geophysical sensors suitable for UAV deployment. We integrated these two subsystems to produce an automated, hand-held geophysical surveying system. The objective of the Phase II effort was to modify the subsystems and integrate them into an airborne prototype. The completed GAUSS DAP system consists of a UAV platform, a laser tracking and ranging subsystem, a telemetry subsystem, light-weight geophysical sensors, a base-station computer (BC), and custom-written survey control software (SCS). We have utilized off-the-shelf commercial products, where possible, to reduce cost and design time.

  1. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

  2. Geochemical simulation of dissolution of West Valley and DWPF [Defense Waste Product Facility] glasses in J-13 water at 90{sup 0}C.

    SciTech Connect (OSTI)

    Bruton, C.J.

    1987-11-01

    Dissolution of West Valley and Defense Waste Product Facility (DWPF) glasses in J-13 water at 90{sup 0}C at the candidate Yucca Mountain, Nevada repository was simulated using the EQ3/6 computer code package. The objectives of the study were to attempt to predict the concentrations of radionuclides and other glass components in solution resulting from glass dissolution, and to identify potential precipitates that sequester glass components. Modified projected inventories of 10,000 year-old West Valley and DWPF SRL-165 frit glasses were used as starting glass compositions. J-13 water was considered to be representative of groundwater at Yucca Mountain. A total of 10 grams of each glass was assumed to dissolve congruently into a kilogram of J-13 water in a closed system. No inhibitions to precipitation, except for crystalline SiO{sub 2} polymorphs, were assumed to exist. Radiolysis and materials interactions were not considered. Simulation results predict that radionuclides and other glass components precipitate predominantly in the form of oxides and hydroxides, together with carbonates, silicates and phosphates. Precipitates appear to be effective in limiting the concentrations of radionuclides and other elements in solution. The general compositional trends in precipitates and solution chemistry are the same in the West Valley and DWPF simulations, except for variations arising from differences in glass chemistry. 20 refs., 7 figs., 3 tabs.

  3. System Diagram

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    System Diagram System Diagram Diagram of I/O architecture on Hopper Diagram of external I/O services on the Hopper system Last edited: 2016-04-29 11:35:23

  4. System Diagram

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    System Diagram System Diagram Diagram of IO architecture on Hopper Diagram of external IO services on the Hopper system Last edited: 2011-04-14 15:11:1...

  5. File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    File Systems File Systems For a general description of the different file systems available on PDSF please see Eliza File Systems and Other File Systems. Below is a summary of how ATLAS uses the various systems: /common In the past ATLAS used /common primarily for their software installations but with cvmfs (see below) this is no longer necessary. ATLAS users also have made personal directories under /common/atlas. However, this is not the intended use of /common, as described on Other File

  6. Pressure Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering > Pressure Systems Privacy and Security Notice Skip over navigation Search the JLab Site Pressure Systems Please upgrade your browser. This site's design is only ...

  7. Computer System,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    undergraduate summer institute http:isti.lanl.gov (Educational Prog) 2016 Computer System, Cluster, and Networking Summer Institute Purpose The Computer System,...

  8. Natural bacterial communities serve as quantitative geochemical...

    Office of Scientific and Technical Information (OSTI)

    that respond to and capture perturbations caused by human impacts. less Authors: Smith, Mark B. 1 ; Rocha, Andrea M. 2 ; Smillie, Chris S. 1 ; Olesen, Scott W. 1 ;...

  9. Geochemical, Genetic, and Community Controls on Mercury

    SciTech Connect (OSTI)

    Wall, Judy D.

    2014-11-10

    The sulfate-reducing bacteria (SRB) are soil bacteria that share two common characteristics, strict anaerobiosis and the ability to respire sulfate. The metabolic activities of these bacteria play significant roles in the global sulfur cycle, anaerobic degradation of biomass, biological metal corrosion in the environment and, recently, degradation of toxic compounds. The accumulation of evidence suggests these bacteria are also key to the production of the neurotoxin methylmercury in environmental settings. We propose to use our experience with the development of genetics in sulfate-reducing bacteria of the genus Desulfovibrio to create mutations that will eliminate the methylation of mercury, thereby identifying the genes essential for this process. This information may allow the environmental monitoring of the mercury methylation potential to learn the location and quantity of the production this toxin. From these data, more accurate predictive models of mercury cycling can be generated.

  10. Natural bacterial communities serve as quantitative geochemical...

    Office of Scientific and Technical Information (OSTI)

    approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior...