National Library of Energy BETA

Sample records for tc tc tc

  1. High Tc Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by C. Kim (SSRL), D. H. Lu (Stanford), K. M. Shen (Stanford) and Z.-X. Shen (Stanford/SSRL) Extensive research efforts to study the novel electronic properties of high-Tc superconductors and their related materials by angle-resolved photoemission spectroscopy at a recently commissioned Beam Line 5-4 (led by Z.-X. Shen) continue to be successful, producing many important results. These results, which are highlighted by five articles recently published in Physical Review Letters and one in

  2. Tc-99 Ion Exchange Resin Testing

    SciTech Connect (OSTI)

    Valenta, Michelle M.; Parker, Kent E.; Pierce, Eric M.

    2010-08-01

    Pacific Northwest National Laboratory was contracted by CHPRC to evaluate the release of 99Tc from spent resin used to treat water from well 299-W15-765 and stored for several years. The key questions to be answered are: 1) does 99Tc readily release from the spent ion exchange resin after being in storage for several years; 2) if hot water stripping is used to remove the co-contaminant carbon tetrachloride, will 99Tc that has been sequestered by the resin be released; and 3) can spent resin be encapsulated into a cementitious waste form; if so, how much 99Tc would be released from the weathering of the monolith waste form? The results from the long term stability leach test results confirm that the resin is not releasing a significant amount of the sequestered 99Tc, evident by the less than 0.02% of the total 99Tc loaded being identified in the solution. Furthermore, it is possible that the measured 99Tc concentration is the result of 99Tc contained in the pore spaces of the resin. In addition to these results, analyses conducted to examine the impact of hot water on the release of 99Tc suggest that only a small percentage of the total is being released. This suggest that hot water stripping to remove carbon tetrachloride will not have a significant affect on the resins ability to hold-on to sequestered 99Tc. Finally, encapsulation of spent resin in a cementitious material may be a viable disposal option, but additional tests are needed to examine the extent of physical degradation caused by moisture loss and the effect this degradation process can have on the release of 99Tc.

  3. Tc-99m Labeled carrier for imaging

    DOE Patents [OSTI]

    Henze, Eberhard

    1984-01-01

    Novel radionuclide imaging agents, having particular application for lymphangiography are provided by non-covalently binding Tc-99m to a pharmaceutically acceptable cross-linked polysaccharide. Upon injection of the Tc-99m labeled polysaccharide into the blood stream, optimum contrast can be obtained within one hour.

  4. Scintillating 99Tc Selective Ion Exchange Resins

    SciTech Connect (OSTI)

    Mitchell Greenhalgh; Richard D. Tillotson

    2012-07-01

    Scintillating technetium (99Tc) selective ion exchange resins have been developed and evaluated for equilibrium capacities and detection efficiencies. These resins can be utilized for the in-situ concentration and detection of low levels of pertechnetate anions (99TcO4-) in natural waters. Three different polystyrene type resin support materials were impregnated with varying amounts of tricaprylmethylammonium chloride (Aliquat 336) extractant, several different scintillating fluors and wavelength shifters. The prepared resins were contacted batch-wise to equilibrium over a wide range of 99TcO4- concentrations in natural water. The measured capacities were used to develop Langmuir adsorption isotherms for each resin. 99Tc detection efficiencies were determined and up to 71.4 ± 2.6% was achieved with some resins. The results demonstrate that a low level detection limit for 99TcO4- in natural waters can be realized.

  5. Trexler Climate Energy Services TC ES | Open Energy Information

    Open Energy Info (EERE)

    Trexler Climate Energy Services TC ES Jump to: navigation, search Name: Trexler Climate + Energy Services (TC + ES) Place: Portland, Oregon Zip: 97214 Sector: Services Product:...

  6. Technetium Removal Using Tc-Goethite Coprecipitation

    SciTech Connect (OSTI)

    Um, Wooyong; Wang, Guohui; Jung, Hun Bok; Peterson, Reid A.

    2013-11-18

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory for the U.S. Department of Energy (DOE) EM-31 Support Program (EMSP) subtask, “Low temperature waste forms coupled with technetium removal using an alternative immobilization process such as Fe(II) treated-goethite precipitation” to increase our understanding of 99Tc long-term stability in goethite mineral form and the process that controls the 99Tc(VII) reduction and removal by the final Fe (oxy)hydroxide forms. The overall objectives of this task were to 1) evaluate the transformation process of Fe (oxy)hydroxide solids to the more crystalline goethite (α-FeOOH) mineral for 99Tc removal and 2) determine the mechanism that limits 99Tc(IV) reoxidation in Fe(II)-treated 99Tc-goethite mineral and 3) evaluate whether there is a long-term 99Tcoxidation state change for Tc sequestered in the iron solids.

  7. Insights into Stabilization of the 99TcVO Core for Synthesis of 99TcVO Compounds

    SciTech Connect (OSTI)

    McGregor, Donna; Burton-Pye, Benjamin P.; Lukens, Wayne W.; Howell, Robertha C.; Francesconi, Lynn C.

    2014-01-01

    Synthesis of technetium-99 (99Tc; t1/2: 2.1 105 years, max: 253 keV) materials is of importance in studies of the nuclear fuel cycle where Tc is a major fission product (6percent thermal yield from 235U and 239Pu), in understanding radioactive tank waste composition, and in identifying 99mTc compounds for nuclear medicine imaging. One of the most useful synthetic starting materials, (NBu4)TcOCl4, is susceptible to disproportionation in water to form TcO4 and TcIV species, especially TcO2 2H2O. This unwanted reaction is especially problematic when working with ligands bearing hard donor atoms, such as oxygen, where the stability with the soft TcV=O3+ core may be low. Polyoxometalates (POMs) are such ligands. They possess defect sites with four hard oxygen atoms and show low (ca. 108) stability constants with transition metals. Tc complexes of POMs are molecular-level models for Tc metal oxide solid-state materials and can provide information on coordination and redox environments of metal oxides that stabilize low-valent Tc. In order to synthesize pure Tc POM complexes [TcVO(1-P2W17O61)]7 (TcVO-1) and [TcVO(2-P2W17O61)]7 (TcVO-2) from (NBu4)TcOCl4, we have identified strategies that minimize formation of TcIV species and optimize the formation of pure TcV species. The parameters that we consider are the amount of ethylene glycol, which is employed as a transfer ligand to prevent hydrolysis of (NBu4)TcOCl4, and the precipitating agent. The TcIV species that contaminates the non-optimized syntheses is likely a TcIV -oxido-bridged dimer [TcIV-(-O)2-TcIV]. We also employ a novel procedure where the 2 ligand is photoactivated and reduced (in the presence of a sacrificial electron donor) to subsequently reduce TcVIIO4 to an isolatable TcVO-2 product that is remarkably free of TcIV.

  8. Development of Tc(IV)-Incorporated Fe Minerals to Enhance 99Tc Retention in Glass Waste Form

    SciTech Connect (OSTI)

    Um, Wooyong; Luksic, Steven A.; Wang, Guohui; Kim, Dong-Sang; Schweiger, Michael J.; Hrma, Pavel R.; Kruger, Albert A.

    2015-03-17

    Iron minerals have been considered to be good hosts for Tc immobilization because the Tc(IV) ion substitutes for Fe(III) in the crystal structure of the Fe oxide due to similarities in (1) cation size [Tc(IV) = 78.5 pm ; Fe(III) = 69 or 78.5 pm], (2) metal-oxygen interatomic distance (Tc—O = 0.199 nm, Fe—O = 0.203 nm), (3) number of coordinating oxygen atoms (both 6-fold coordinated), and (4) the redox potential (Eh=ca. +20 mV at pH = 7) for a redox couple between Tc(VII)/Tc(IV) and Fe(III)/Fe(II). Magnetite, maghemite, and trevorite are iron oxide minerals and all belong to spinel mineral group. Laboratory testing shows that Tc can be removed from aqueous waste solutions by a process of Tc reduction from Tc(VII) to Tc(IV) followed by co-precipitation with iron oxide minerals during recrystallization of Fe(OH)2(s) used as an initial solid precursor. X-ray absorption near edge structure (XANES) spectroscopy confirmed that Tc was in the +4 oxidation state in final Tc-Fe minerals. The Tc-incorporated Fe minerals were also tested for Tc retention in glass melts at different temperatures between 600 – 1,000 oC in a furnace. After being cooled in air, the solid glass specimens collected at different temperatures were analyzed for Tc oxidation state using XANES and Tc retention using liquid scintillation counting (LSC). Even though Tc(IV) started to reoxidize at 600 oC, Tc retention in the final glass specimen prepared with Tc-incorporated Fe mineral even at high temperatures was at least two times higher than glass prepared with KTcO4 salt. Higher Tc retention in glass is considered to result from limited and delayed Tc volatilization process due to Fe mineral encapsulation for Tc. Therefore, the results showing the presence of Tc(IV) in the Fe mineral structure indicate strong possibility to enhance Tc retention in borosilicate glass as well as to reduce the remediation costs at the Hanford Site.

  9. ARM - Campaign Instrument - tc-bc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentstc-bc Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Total Carbon and Black Carbon Concentrations on Filter Samples (TC-BC) Instrument Categories Aerosols, Atmospheric Carbon Campaigns Aerosol IOP [ Download Data ] Southern Great Plains, 2003.05.01 - 2003.05.31 Primary Measurements Taken The following measurements are those considered scientifically relevant. Refer to the datastream (netcdf) file headers for

  10. Pretreatment of Tc-Containing Waste and Its Effect on Tc-99 Leaching From Grouts

    SciTech Connect (OSTI)

    Aloy, Albert; Kovarskaya, Elena N.; Harbour, John R.; Langton, Christine A.; Holtzscheiter, E. William

    2007-07-01

    A salt solution (doped with Tc-99), that simulates the salt waste stream to be processed at the Saltstone Production Facility, was immobilized in grout waste forms with and without (1) ground granulated blast furnace slag and (2) pretreatment with iron salts. The degree of immobilization of Tc-99 was measured through monolithic and crushed grout leaching tests. Although Fe (+2) was shown to be effective in reducing Tc-99 to the +4 state, the strong reducing nature of the blast furnace slag present in the grout formulation dominated the reduction of Tc-99 in the cured grouts. An effective diffusion coefficient of 4.75 x 10{sup -12} (Leach Index of 11.4) was measured using the ANSI/ANS-16.1 protocol. The leaching results show that, even in the presence of a concentrated salt solution, blast furnace slag can effectively reduce pertechnetate to the immobile +4 oxidation state. The measured diffusivity was introduced into a flow and transport model (PORFLOW) to calculate the release of Tc-99 from a Saltstone Vault as a function of hydraulic conductivity of the matrix. (authors)

  11. Electromagnetics in high-{Tc} superconductors

    SciTech Connect (OSTI)

    Ma, J.G.; Wolff, I.

    1996-04-01

    The behavior of electromagnetic fields in high-{Tc} superconductors (HTS`s) is studied in order to examine their effects in classical electromagnetic boundary value problems. It is shown that an HTS can not be simply treated as a low loss conductor and boundary conditions of HTS`s can not be considered as perfect conducting boundaries like conventional treatments. The electromagnetics of HTS are investigated in terms of complex conductivity, surface impedance with applied magnetic fields, and computational electrodynamics using the new proposed model in Ref. 1.

  12. Microsoft Word - HAB Adv #146 Tc-99.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Performance Assessments identify Tc-99 as the primary long-term contributor to ground water contamination. What are the increased impacts to groundwater caused by elimination...

  13. 99Tc Process Monitoring System In-Lab Performance Characterization

    SciTech Connect (OSTI)

    O'Hara, Matthew J.; Niver, Cynthia M.

    2014-01-01

    Executive Summary A 99Tc Process Monitoring (Tc-Mon) System has been designed and built for deployment at the recently constructed 200 West Pump & Treat (200W P&T) Plant in the 200 West Area ZP-1 Operable Unit of the Hanford Site. The plant is operated by CH2M Hill Plateau Remediation Company (CHPRC). The Tc-Mon system was created through collaboration between Pacific Northwest National Laboratory (PNNL) and Burge Environmental, Inc. The new systems design has been optimized based on experience from an earlier field test (2011) of a prototype system at the 200W-ZP-1 Interim Pump & Treat Plant. A portion of the new 200W P&T Plant is dedicated to removal of 99Tc from contaminated groundwater in the 200 West Area. 99Tc, as the pertechnetate anion (99TcO4-), is remediated through delivery of water into two trains (Trains A and B) of three tandem extraction columns filled with Purolite A530E resin. The resin columns cannot be regenerated; therefore, once they have reached their maximum useful capacity, the columns must be disposed of as radioactive waste. The Tc-Mon systems primary duty will be to periodically sample and analyze the effluents from each of the two primary extraction columns to determine 99Tc breakthrough. The Tc-Mon system will enable the CH2M Hill Plateau Remediation Company (CHPRC) to measure primary extraction column breakthrough on demand. In this manner, CHPRC will be able to utilize each extraction column to its maximum capacity. This will significantly reduce column disposal and replacement costs over the life of the plant. The Tc-Mon system was constructed by Burge Environmental, Inc. and was delivered to PNNL in June 2013 for setup and initial hardware and software performance testing in the 325 Building. By early July, PNNL had initiated an in-laboratory performance characterization study on the system. The objective was to fully calibrate the system and then evaluate the quality of the analytical outputs 1) against a series of clean

  14. RILEM TC ISR Summer 2015 Activity Report

    SciTech Connect (OSTI)

    Le Pape, Yann

    2015-08-01

    With aging infrastructures, instances of Alkali Silica Reaction (ASR) and Delayed Ettringite Formation (DEF), broadly covered under the term Internal Swelling Reaction (ISR), are increasingly being detected. They have been observed in bridges, dams, and most recently in nuclear power plants. Concrete swelling may result in bridge partial failure, dams with structural cracks and misaligned turbine shafts, and locked slice gates. For nuclear reactors micro-cracks may cause increased gas permeability which will jeopardize the containment integrity and may decrease the residual structural resistance under accidental loading. This TC, which limits its activity to structures with known expansive concrete, seeks to address two complementary but fundamental questions: a) What is the kinetics of the reaction and b) How would it affect the integrity of the structure (serviceability and strength) and thus establish a science based prognostic to the structure owner.

  15. DOE Tour of Zero: Bellingham Power House by TC Legend Homes ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bellingham Power House by TC Legend Homes DOE Tour of Zero: Bellingham Power House by TC Legend Homes Addthis 1 of 19 TC Legend Homes built this 2,781-square-foot home in ...

  16. DOE Tour of Zero Floorplans: Bellingham Power House by TC Legend...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bellingham Power House by TC Legend Homes DOE Tour of Zero Floorplans: Bellingham Power House by TC Legend Homes DOE Tour of Zero Floorplans: Bellingham Power House by TC Legend

  17. DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TC Legend Homes, Bellingham, WA DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham, WA DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham, WA Case ...

  18. DOE Tour of Zero: The Cedarwood by TC Legend Homes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cedarwood by TC Legend Homes DOE Tour of Zero: The Cedarwood by TC Legend Homes Addthis 1 of 13 Custom builder TC Legend Homes packed energy-efficiency features into this tidy...

  19. DOE Tour of Zero: The Net Zero in Seattle by TC Legend Homes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Net Zero in Seattle by TC Legend Homes DOE Tour of Zero: The Net Zero in Seattle by TC Legend Homes Addthis 1 of 15 Northwest builder TC Legend Homes has built a certified U.S. DOE...

  20. DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham Power House, ... DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham Power House, ...

  1. Bounding the Pseudogap in Cuprate High-TC Superconductors (Technical...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Bounding the Pseudogap in Cuprate High-TC Superconductors Authors: McDonald, Ross David 1 ; Shehter, Arkady 1 ; Balakirev, Fedor F. ...

  2. Introduction to Tc/I in Hanford Flowsheet

    Office of Environmental Management (EM)

    Introduction to TcI in Hanford Flowsheet Gary Smith Office of Waste Processing (EM-31) November 18, 2010 2 Rough Flowsheet Diagram Tank Farm Evaporator Pretreatment Evaporator IDF ...

  3. Solvent Extraction of Tc and Cs from Alkaline Nitrate Wastes

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bonnesen, Peter V.; Delmau, Laetitia H.; Haverlock, T J.; Sachleben, R A.; Leonard, R A.; Conner, C; Lumetta, Gregg J. ); M. Cox, M. Hidalgo, and M. Valiente

    2001-01-01

    This paper summarizes progress at three collaborating U.S. national laboratories on the extraction of the fission products 99Tc and 137Cs from alkaline high-level wastes. Efficient economical processes for Tc and Cs extraction (SRTALK and alkaline-side CSEX, respectively) have been developed, and testing has progressed through batch tests on actual wastes and continuous counter-current centrifugal-contactor tests on simulants.

  4. Solvent Extraction of Tc and Cs from Alkaline Nitrate Wastes

    SciTech Connect (OSTI)

    Bonnesen, P.V.; Conner, C.; Delmau, L.H.; Haverlock, T.J.; Leonard, R.A.; Lumetta, G.J.; Moyer, B.A.; Sachleben, R.A.

    1999-07-11

    This paper summarizes progress at three collaborating US national laboratories on the extraction of the fission products {sup 99}Tc and {sup 137}Cs from alkaline high-level wastes (HLW). Efficient, economical processes for Tc and Cs extraction (SRTALK and alkaline-side CSEX, respectively) have been developed, and testing has progressed through batch tests on actual wastes and continuous countercurrent centrifugal-contactor tests on simulants.

  5. Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity Print Wednesday, 26 April 2006 00:00 Working at the ALS, a multi-institutional collaboration led by researchers at ALS and Stanford University has identified a pseudogap phase with a nodal-antinodal dichotomy in ferromagnetic manganese oxide materials (manganites). Even though ferromagnetism and superconductivity do not exist together, the pseudogap state found in

  6. Power Systems Development Facility Gasification Test Campaign TC25

    SciTech Connect (OSTI)

    Southern Company Services

    2008-12-01

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC25, the second test campaign using a high moisture lignite coal from the Red Hills mine in Mississippi as the feedstock in the modified Transport Gasifier configuration. TC25 was conducted from July 4, 2008, through August 12, 2008. During TC25, the PSDF gasification process operated for 742 hours in air-blown gasification mode. Operation with the Mississippi lignite was significantly improved in TC25 compared to the previous test (TC22) with this fuel due to the addition of a fluid bed coal dryer. The new dryer was installed to dry coals with very high moisture contents for reliable coal feeding. The TC25 test campaign demonstrated steady operation with high carbon conversion and optimized performance of the coal handling and gasifier systems. Operation during TC25 provided the opportunity for further testing of instrumentation enhancements, hot gas filter materials, and advanced syngas cleanup technologies. The PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane with syngas from the Transport Gasifier.

  7. Tc Reductant Chemistry and Crucible Melting Studies with Simulated Hanford Low-Activity Waste

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Soderquist, Chuck Z.; Icenhower, Jonathan P.; McGrail, B PETER.; Scheele, Randall D.; McNamara, Bruce K.; Bagaasen, Larry M.; Schweiger, Michael J.; Crum, Jarrod V.; Yeager, John D.; Matyas, Josef; Darnell, Lori P.; Schaef, Herbert T.; Owen, Antionette T.; Kozelisky, Anne E.; Snow, Lanee A.; Steele, Marilyn J.

    2005-03-30

    The FY 2003 risk assessment (RA) of bulk vitrification (BV) waste packages used 0.3 wt% of the technetium (Tc) inventory as a leachable salt and found it sufficient to create a significant peak in the groundwater concentration in a 100-meter down-gradient well. Although this peak met regulatory limits, considering uncertainty in the actual Tc salt fraction, peak concentrations could exceed the maximum concentration limit (MCL) under some scenarios so reducing the leachable salt inventory is desirable. The main objective of this study was to reduce the mobile Tc species available within a BV disposal package by reducing the oxidation state of the Tc in the waste feed and/or during melting because Tc in its reduced form of Tc(IV) has a much lower volatility than Tc(VII). Reduced Tc volatility has a secondary benefit of increasing the Tc retention in glass.

  8. Tc-99 Adsorption on Selected Activated Carbons - Batch Testing Results

    SciTech Connect (OSTI)

    Mattigod, Shas V.; Wellman, Dawn M.; Golovich, Elizabeth C.; Cordova, Elsa A.; Smith, Ronald M.

    2010-12-01

    CH2M HILL Plateau Remediation Company (CHPRC) is currently developing a 200-West Area groundwater pump-and-treat system as the remedial action selected under the Comprehensive Environmental Response, Compensation, and Liability Act Record of Decision for Operable Unit (OU) 200-ZP-1. This report documents the results of treatability tests Pacific Northwest National Laboratory researchers conducted to quantify the ability of selected activated carbon products (or carbons) to adsorb technetium-99 (Tc-99) from 200-West Area groundwater. The Tc-99 adsorption performance of seven activated carbons (J177601 Calgon Fitrasorb 400, J177606 Siemens AC1230AWC, J177609 Carbon Resources CR-1240-AW, J177611 General Carbon GC20X50, J177612 Norit GAC830, J177613 Norit GAC830, and J177617 Nucon LW1230) were evaluated using water from well 299-W19-36. Four of the best performing carbons (J177606 Siemens AC1230AWC, J177609 Carbon Resources CR-1240-AW, J177611 General Carbon GC20X50, and J177613 Norit GAC830) were selected for batch isotherm testing. The batch isotherm tests on four of the selected carbons indicated that under lower nitrate concentration conditions (382 mg/L), Kd values ranged from 6,000 to 20,000 mL/g. In comparison. Under higher nitrate (750 mg/L) conditions, there was a measureable decrease in Tc-99 adsorption with Kd values ranging from 3,000 to 7,000 mL/g. The adsorption data fit both the Langmuir and the Freundlich equations. Supplemental tests were conducted using the two carbons that demonstrated the highest adsorption capacity to resolve the issue of the best fit isotherm. These tests indicated that Langmuir isotherms provided the best fit for Tc-99 adsorption under low nitrate concentration conditions. At the design basis concentration of Tc 0.865 g/L(14,700 pCi/L), the predicted Kd values from using Langmuir isotherm constants were 5,980 mL/g and 6,870 mL/g for for the two carbons. These Kd values did not meet the target Kd value of 9,000 mL/g. Tests

  9. Funda o Parque Tecnol gico da Paraiba PaqTc Incubator | Open...

    Open Energy Info (EERE)

    Funda o Parque Tecnol gico da Paraiba PaqTc Incubator Jump to: navigation, search Name: Fundao Parque Tecnolgico da Paraiba (PaqTc Incubator) Place: Brazil Sector: Services...

  10. T-692: VMware vFabric tc Server Lets Remote Users Login Using Obfuscated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Passwords | Department of Energy 92: VMware vFabric tc Server Lets Remote Users Login Using Obfuscated Passwords T-692: VMware vFabric tc Server Lets Remote Users Login Using Obfuscated Passwords August 12, 2011 - 3:47pm Addthis PROBLEM: A vulnerability was reported in VMware vFabric tc Server. A remote user can login using an obfuscated version of their password. PLATFORM: Version(s): vFabric tc Server 2.0.0.RELEASE to 2.0.5.SR01, 2.1.0.RELEASE to 2.1.1.SR01 ABSTRACT: VMware vFabric tc

  11. Spin-polaron theory of high-{Tc} superconductivity: I, spin polarons and

    Office of Scientific and Technical Information (OSTI)

    high-{Tc} pairing (Conference) | SciTech Connect Spin-polaron theory of high-{Tc} superconductivity: I, spin polarons and high-{Tc} pairing Citation Details In-Document Search Title: Spin-polaron theory of high-{Tc} superconductivity: I, spin polarons and high-{Tc} pairing The concept of a spin polaron is introduced and contrasted with the more familiar ionic polaron picture. A brief review of aspects of ionic bipolaronic superconductivity is given with particular emphasis on the real-space

  12. NMR/MRI with hyperpolarized gas and high Tc SQUID

    DOE Patents [OSTI]

    Schlenga, Klaus; de Souza, Ricardo E.; Wong-Foy, Annjoe; Clarke, John; Pines, Alexander

    2000-01-01

    A method and apparatus for the detection of nuclear magnetic resonance (NMR) signals and production of magnetic resonance imaging (MRI) from samples combines the use of hyperpolarized inert gases to enhance the NMR signals from target nuclei in a sample and a high critical temperature (Tc) superconducting quantum interference device (SQUID) to detect the NMR signals. The system operates in static magnetic fields of 3 mT or less (down to 0.1 mT), and at temperatures from liquid nitrogen (77K) to room temperature. Sample size is limited only by the size of the magnetic field coils and not by the detector. The detector is a high Tc SQUID magnetometer designed so that the SQUID detector can be very close to the sample, which can be at room temperature.

  13. Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity Print Working at the ALS, a multi-institutional collaboration led by researchers at ALS and Stanford University has identified a pseudogap phase with a nodal-antinodal dichotomy in ferromagnetic manganese oxide materials (manganites). Even though ferromagnetism and superconductivity do not exist together, the pseudogap state found in these manganites is remarkably similar to that found in high-temperature superconducting copper

  14. Bridging the Gaps of High-Tc Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bridging the Gaps of High-Tc Superconductor Since the discovery of high-temperature superconductor by Bednorz and Müller in 1986, this field has become one of the most important research topics in solid state physics. In the past 20 years many unconventional properties have been discovered in this new class of materials. These have challenged our conventional wisdom and driven the development of many novel theories. Among these discoveries, the most mysterious is probably the pseudogap

  15. Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity Print Working at the ALS, a multi-institutional collaboration led by researchers at ALS and Stanford University has identified a pseudogap phase with a nodal-antinodal dichotomy in ferromagnetic manganese oxide materials (manganites). Even though ferromagnetism and superconductivity do not exist together, the pseudogap state found in these manganites is remarkably similar to that found in high-temperature superconducting copper

  16. Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity Print Working at the ALS, a multi-institutional collaboration led by researchers at ALS and Stanford University has identified a pseudogap phase with a nodal-antinodal dichotomy in ferromagnetic manganese oxide materials (manganites). Even though ferromagnetism and superconductivity do not exist together, the pseudogap state found in these manganites is remarkably similar to that found in high-temperature superconducting copper

  17. Power Systems Development Facility Gasification Test Campaign TC24

    SciTech Connect (OSTI)

    Southern Company Services

    2008-03-30

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC24, the first test campaign using a bituminous coal as the feedstock in the modified Transport Gasifier configuration. TC24 was conducted from February 16, 2008, through March 19, 2008. The PSDF gasification process operated for about 230 hours in air-blown gasification mode with about 225 tons of Utah bituminous coal feed. Operational challenges in gasifier operation were related to particle agglomeration, a large percentage of oversize coal particles, low overall gasifier solids collection efficiency, and refractory degradation in the gasifier solids collection unit. The carbon conversion and syngas heating values varied widely, with low values obtained during periods of low gasifier operating temperature. Despite the operating difficulties, several periods of steady state operation were achieved, which provided useful data for future testing. TC24 operation afforded the opportunity for testing of various types of technologies, including dry coal feeding with a developmental feeder, the Pressure Decoupled Advanced Coal (PDAC) feeder; evaluating a new hot gas filter element media configuration; and enhancing syngas cleanup with water-gas shift catalysts. During TC24, the PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane.

  18. Power Systems Development Facility Gasification Test Campaing TC18

    SciTech Connect (OSTI)

    Southern Company Services

    2005-08-31

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details Test Campaign TC18 of the PSDF gasification process. Test campaign TC18 began on June 23, 2005, and ended on August 22, 2005, with the gasifier train accumulating 1,342 hours of operation using Powder River Basin (PRB) subbituminous coal. Some of the testing conducted included commissioning of a new recycle syngas compressor for gasifier aeration, evaluation of PCD filter elements and failsafes, testing of gas cleanup technologies, and further evaluation of solids handling equipment. At the conclusion of TC18, the PSDF gasification process had been operated for more than 7,750 hours.

  19. Tc and Re Behavior in Borosilicate Waste Glass Vapor Hydration Tests

    SciTech Connect (OSTI)

    McKeown, David A.; Buechele, Andrew C.; Pegg, Ian L.; Lukens, Wayne W.; Shuh, David K.

    2007-07-01

    Technetium (Tc), found in some nuclear wastes, is of particular concern with regard to long-term storage, because of its long-lived radioactivity and high mobility in the environment. Tc and rhenium (Re), commonly used as a non-radioactive surrogate for Tc, were studied to assess their behavior in borosilicate glass under hydrothermal conditions in the Vapor Hydration Test (VHT). X-ray absorption spectroscopy (XAS) and scanning electron microscopy (SEM) measurements were made on the original Tc- and Re-containing glasses and their corresponding VHT samples, and show different behavior for Tc and Re under VHT conditions. XAS indicates that, despite starting with different Tc(IV) and Tc(VII) distributions in each glass, the VHT samples have 100% Tc(IV)O{sub 6} environments. SEM shows complete alteration of the original glass, Tc enrichment near the sample surface, and Tc depletion in the center. Perrhenate (Re(VII)O{sub 4}{sup -}) is dominant in both Re-containing samples before and after the VHT, where Re is depleted near the VHT sample surface and more concentrated toward the center. (authors)

  20. Universal Charge Order in the High-Tc Superconductors | Stanford

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotron Radiation Lightsource Universal Charge Order in the High-Tc Superconductors Wednesday, May 4, 2016 - 3:00pm SLAC, Redtail Hawk Conference Room 108A Speaker: Eduardo H. da Silva Neto - UBC Eduardo H. da Silva Neto was born in Recife, Brazil. He obtained his B.A. in Physics and Mathematics (2008) from Amherst College, and his Ph. D. (2013) in Physics from Princeton University. Since 2013 he has been a Max-Planck-UBC postdoctoral research fellow at the Quantum Matter Institute at

  1. Spin-polaron theory of high-{Tc} superconductivity: I, spin polarons...

    Office of Scientific and Technical Information (OSTI)

    Subject: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; HIGH-TC SUPERCONDUCTORS; PAIRING ENERGY; POLARONS; SPIN; SPIN FLIP; COPPER OXIDES 665411; BASIC ...

  2. Recap and Conclusions to Tc/I in Hanford Flowsheet Presentations

    Office of Environmental Management (EM)

    Recap & Conclusions to TcI in Hanford Flowsheet Presentations Gary Smith Office of Waste Processing (EM-31) November 18, 2010 2 Rough Flowsheet Diagram Tank Farm Evaporator ...

  3. 99Tc(VII) Retardation, Reduction, and Redox Rate Scaling in Naturally...

    Office of Scientific and Technical Information (OSTI)

    Reduction, and Redox Rate Scaling in Naturally Reduced Sediments Citation Details In-Document Search Title: 99Tc(VII) Retardation, Reduction, and Redox Rate Scaling in ...

  4. Power Systems Development Facility Gasification Test Campaign TC22

    SciTech Connect (OSTI)

    Southern Company Services

    2008-11-01

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC22, the first test campaign using a high moisture lignite from Mississippi as the feedstock in the modified Transport Gasifier configuration. TC22 was conducted from March 24 to April 17, 2007. The gasification process was operated for 543 hours, increasing the total gasification operation at the PSDF to over 10,000 hours. The PSDF gasification process was operated in air-blown mode with a total of about 1,080 tons of coal. Coal feeder operation was challenging due to the high as-received moisture content of the lignite, but adjustments to the feeder operating parameters reduced the frequency of coal feeder trips. Gasifier operation was stable, and carbon conversions as high as 98.9 percent were demonstrated. Operation of the PCD and other support equipment such as the recycle gas compressor and ash removal systems operated reliably.

  5. Synthesis, structure elucidation and redox properties of 99Tc complexes of lacunary Wells Dawson polyoxometalates: insights into molecular 99Tc - metal oxide interactions

    SciTech Connect (OSTI)

    McGregor, Donna; Burton-Pye, Benjamin P.; Howell, Robertha C.; Mbomekalle, Israel M.; Lukens Jr, Wayne W.; Bian, Fang; Mausolf, Edward; Poineau, Frederic; Czerwinski, Kenneth R; Francesconi, Lynn C.

    2011-01-10

    The isotope 99Tc (beta max: 250 keV, half-life: 2 x 105 year) is an abundant product of uranium-235 fission in nuclear reactors and is present throughout the radioactive waste stored in underground tanks at Hanford and Savannah River. Understanding and controlling the extensive redox chemistry of 99Tc is important to identify tunable strategies to separate 99Tc from spent fuel and from waste tanks and once separated, to identify and develop an appropriately stable waste-form for 99Tc. Polyoxometalates (POMs), nanometer sized models for metal oxide solid-state materials, are used in this study to provide a molecular level understanding of the speciation and redox chemistry of incorporated 99Tc. In this study, 99Tc complexes of the (alpha 2-P2W17O61)10- and (alpha 1-P2W17O61)10- isomers were prepared. Ethylene glycol was used as a"transfer ligand" to minimize the formation of TcO2 cdot xH2O. The solution structures, formulations, and purity of TcVO(alpha 1/alpha 2-P2W17O61)7- were determined by multinuclear NMR. X-ray Absorption Spectroscopy of the complexes are in agreement with the formulation and structures determined from 31P and 183W NMR. Preliminary electrochemistry results are consistent with the EXAFS results, showing a facile reduction of the TcVO(alpha 1-P2W17O61)7- species compared to the TcVO(alpha 2-P2W17O61)7- analog. The alpha1- defect is unique in that a basic oxygen atom is positioned toward the alpha1- site and the TcVO center appears to form a dative metal-metal bond with a framework W site. These attributes may lead to the assistance of protonation events that facilitate reduction. Electrochemistry comparison shows that the ReV analogs are about 200 mV more difficult to reduce in accordance with periodic trends.

  6. In-Situ Data for Microphysical Retrievals: TC4, 2007

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    2016-04-01

    This data set is derived from measurements collected in situ by the NASA DC8 during the Tropical Cloud Climate Composition Coupling Experiment (TC4) that was conducted during July and August, 2007 (Toon et al., 2010). During this experiment the DC8 was based in San Jose, Costa Rica and sampled clouds in the maritime region of the Eastern Pacific and adjoining continental areas. The primary objective of the DC8 during this deployment was to sample ice clouds associated with convective activity. While the vast majority of the data are from ice-phase clouds that have recent association with convection, other types of clouds such as boundary layer clouds and active convection were also sampled and are represented in this data set. The derived data set, as compiled in this delivery, includes approximately 15,000 5-second averaged measurements collected by the NASA DC8.

  7. Oxidative Dissolution Potential of Biogenic and Abiogenic TcO2 in Subsurface Sediments

    SciTech Connect (OSTI)

    Fredrickson, Jim K.; Zachara, John M.; Plymale, Andrew E.; Heald, Steve M.; McKinley, James P.; Kennedy, David W.; Liu, Chongxuan; Nachimuthu, Ponnusamy

    2009-04-15

    Technetium-99 (Tc) is an important fission product contaminant associated with sites of nuclear fuels reprocessing and geologic nuclear waste disposal. Exhibiting an intermediate redox potential, Tc is highly mobile in its anionic, oxidized state [Tc(VII)O4-]; and less mobile as a poorly soluble oxyhydroxide precipitate [Tc(IV)O2•nH2O] in its reduced state. Here we investigate the potential for oxidation of Tc(IV) that was heterogeneously reduced by reaction with biogenic Fe(II) in two sediments differing in mineralogy and aggregation state (FRC, RG). Both sediments contained Fe(III) and Mn(III/IV) as redox active phases, but FRC also contained mass-dominant Fe-phyllosilicates of different types. Biogenic Tc(IV)O2•nH2O was oxidized in anoxic, but unreduced RG and FRC sediments through redox interaction with Mn(III/IV) oxides. Bioreduction by Shewanella putrefaciens CN32 dissolved Mn(III/IV) oxides and generated biogenic Fe(II) that was reactive with Tc(VII) in heat-killed, bioreduced sediment. Biogenic Fe(II) in the FRC exceeded that in RG by a factor of two. More rapid reduction rates were observed in the RG that had lower biogenic Fe(II), and less particle aggregation. EXAFS measurements indicated that the primary reduction product was a TcO2-like phase in both sediments. Redox product Tc(IV) oxidized rapidly and completely in RG when contacted with air. Oxidation, in contrast, was slow and incomplete in the FRC, in spite of similar molecular speciation to RG. X-ray microprobe, electron microprobe, x-ray absorption spectroscopy, and micro x-ray diffraction were applied to the whole sediment and isolated Tc-contained particles. These analyses revealed that non-oxidizable Tc(IV) in the FRC existed as complexes with octahedral Fe(III) within intra-grain domains of 50-100 µm-sized, Fe-containing micas presumptively identified as celadonite. The markedly slower oxidation rates in FRC as compared to RG were attributed to mass-transfer-limited migration of O2 into

  8. Oxidative dissolution potential of biogenic and abiogenic TcO{sub 2} in subsurface sediments.

    SciTech Connect (OSTI)

    Fredrickson, J. K.; Zachara, J. M.; Plymale, A. E.; Heald, S. M.; McKinley, J. P.; Kennedy, D. W.; Liu, C.; Nachimuthu, P.

    2009-04-01

    Technetium-99 (Tc) is an important fission product contaminant associated with sites of nuclear fuels reprocessing and geologic nuclear waste disposal. Tc is highly mobile in its most oxidized state [Tc(VII)O{sub 4}{sup -}] and less mobile in the reduced form [Tc(IV)O{sub 2} {center_dot} nH{sub 2}O]. Here we investigate the potential for oxidation of Tc(IV) that was heterogeneously reduced by reaction with biogenic Fe(II) in two sediments differing in mineralogy and aggregation state; unconsolidated Pliocene-age fluvial sediment from the upper Ringold (RG) Formation at the Hanford Site and a clay-rich saprolite from the Field Research Center (FRC) background site on the Oak Ridge Site. Both sediments contained Fe(III) and Mn(III/IV) as redox active phases, but FRC also contained mass-dominant Fe-phyllosilicates of different types. Shewanella putrefaciens CN32 reduced Mn(III/IV) oxides and generated Fe(II) that was reactive with Tc(VII) in heat-killed, bioreduced sediment. After bioreduction and heat-killing, biogenic Fe(II) in the FRC exceeded that in RG by a factor of two. More rapid reduction rates were observed in the RG that had lower biogenic Fe(II), and less particle aggregation. EXAFS measurements indicated that the primary reduction product was a TcO{sub 2}-like phase in both sediments. The biogenic redox product Tc(IV) oxidized rapidly and completely in RG when contacted with air. Oxidation, in contrast, was slow and incomplete in the FRC, in spite of similar molecular scale speciation of Tc compared to RG. X-ray microprobe, electron microprobe, X-ray absorption spectroscopy, and micro X-ray diffraction were applied to the whole sediment and isolated Tc-containing particles. These analyses revealed that non-oxidizable Tc(IV) in the FRC existed as complexes with octahedral Fe(III) within intra-grain domains of 50-100 {micro}m-sized, Fe-containing micas presumptively identified as celadonite. The markedly slower oxidation rates in FRC as compared to RG were

  9. INFLUENCE OF NATURAL AND SYNTHETIC ORGANIC LIGANDS ON THE STABILITY AND MOBILITY OF REDUCED TC(IV)

    SciTech Connect (OSTI)

    Nathalie A. Wall; Baohua Gu

    2012-12-20

    The primary objectives were (1) to quantify the interactions of organic ligands with Tc(IV) through the generation of thermodynamic (complexation) and kinetic parameters needed to assess and predict the mobility of reduced Tc(IV) at DOE contaminated sites; and (2) to determine the impact of organic ligands on the mobility and fate of reduced Tc(IV) under field geochemical conditions.

  10. ARM - PI Product - In-Situ Data for Microphysical Retrievals: TC4, 2007

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsIn-Situ Data for Microphysical Retrievals: TC4, 2007 Citation DOI: 10.5439/1244832 [ What is this? ] ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : In-Situ Data for Microphysical Retrievals: TC4, 2007 [ ARM research ] This data set is derived from measurements collected in situ by the NASA DC8 during the Tropical Cloud Climate Composition Coupling Experiment (TC4) that was conducted during July

  11. DOE Tour of Zero: Bellingham Power House by TC Legend Homes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Bellingham Power House by TC Legend Homes DOE Tour of Zero: Bellingham Power House by TC Legend Homes 1 of 19 TC Legend Homes built this 2,781-square-foot home in Bellingham, Washington, to the performance criteria of the U.S. Department of Energy Zero Energy Ready Home (ZERH) program. 2 of 19 A greenhouse off the kitchen provides a thermal transition zone into the home, minimizing heat losses during the winter. The solar hot water heating panels are visible on the porch roof. 3 of 19

  12. In-Situ Data for Microphysical Retrievals: TC4, 2007 (Dataset...

    Office of Scientific and Technical Information (OSTI)

    This data set is derived from measurements collected in situ by the NASA DC8 during the Tropical Cloud Climate Composition Coupling Experiment (TC4) that was conducted during July ...

  13. DOE Zero Energy Ready Home Case Study: TC Legend, Seattle, WA...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Legend, Seattle, WA, Custom Home DOE Zero Energy Ready Home Case Study: TC Legend, Seattle, WA, Custom Home Case study of a DOE Zero Energy Ready Home in Seattle, WA, that scored ...

  14. V-183: Cisco TelePresence TC and TE Bugs Let Remote Users Deny...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Remote Users Deny Service and Remote Adjacent Authenticated Users Gain Root Shell Access V-183: Cisco TelePresence TC and TE Bugs Let Remote Users Deny Service and Remote Adjacent...

  15. PV Standards: What IEC TC82 is Doing for You | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Standards: What IEC TC82 is Doing for You PV Standards: What IEC TC82 is Doing for You Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado pvmrw13_ps3_sunset_kelly.pdf (74.81 KB) More Documents & Publications QA TG5 UV, temperature and humidity Test Procedure for UV Weathering Resistance of Backsheet Literature Review of the Effects of UV Exposure on PV Modules

  16. Response of High-Tc Superconductor Metamaterials to High Intensity THz

    Office of Scientific and Technical Information (OSTI)

    Radiation (Conference) | SciTech Connect Response of High-Tc Superconductor Metamaterials to High Intensity THz Radiation Citation Details In-Document Search Title: Response of High-Tc Superconductor Metamaterials to High Intensity THz Radiation Authors: Grady, Nathaniel [1] ; Perkins Jr., Bradford G. [2] ; Hwang, Harold Y. [2] ; Brandt, Nate [2] ; Torchinsky, Darius [2] ; Singh, Ranjan [1] ; Yan, Li [3] ; Jia, Quanxi [1] ; Trugman, Stuart A. [1] ; Taylor, Antoinette J. [1] ; Nelson, Keith

  17. Investigation of Tc Migration Mechanism During Bulk Vitrification Process Using Re Surrogate

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Bagaasen, Larry M.; Crum, Jarrod V.; Fluegel, Alex; Gallegos, Autumn B.; Martinez, Baudelio; Matyas, Josef; Meyer, Perry A.; Paulsen, Dan; Riley, Brian J.; Schweiger, Michael J.; Stewart, Charles W.; Swoboda, Robert G.; Yeager, John D.

    2006-12-04

    As a part of Bulk vitrification (BV) performance enhancement tasks, Laboratory scoping tests were performed in FY 2004-2005 to explore possible ways to reduce the amount of soluble Tc in the BV waste package. Theses scoping tests helped identify which mechanisms play an important role in the migration of Tc in the BV process (Hrma et al. 2005 and Kim et al. 2005). Based on the results from these scoping tests, additional tests were identified that will improve the understanding of Tc migration and to clearly identify the dominant mechanisms. The additional activities identified from previous studies were evaluated and prioritized for planning for Tasks 29 and 30 conducted in FY2006. Task 29 focused on the improved understanding of Tc migration mechanisms, and Task 30 focused on identifying the potential process changes that might reduce Tc/Re migration into the castable refractory block (CRB). This report summarizes the results from the laboratory- and crucible-scale tests in the lab for improved Tc migration mechanism understanding utilizing Re as a surrogate performed in Task 29.

  18. Near-yrast, medium-spin structure of the {sup 109}Tc nucleus

    SciTech Connect (OSTI)

    Urban, W.; Pinston, J. A.; Smith, A. G.; Ahmad, I.

    2010-12-15

    Excited levels in the {sup 109}Tc nucleus, populated in the spontaneous fission of {sup 248}Cm, have been studied using the EUROGAM2 array. In {sup 109}Tc we have found a new band corresponding to the {pi}5/2{sup -}[303] configuration and a three-quasiparticle band with I{sup {pi}}=(15/2{sup -}) band-head level at 1749.5 keV. The structure of the 1749.5-keV level probably involves the {l_brace}{pi}5/2{sup +}[422]{nu}(5/2{sup -}[532],5/2{sup +}[413]){r_brace}{sub 15/2}{sup -} prolate configuration. The quasiparticle-rotor model calculations performed in this work show that the odd-proton configurations observed in {sup 107}Tc and {sup 109}Tc are consistent with the scheme of proton excitations in a prolate triaxial potential. Significant differences between the degree of triaxiality observed for positive- and negative-parity excitations may be due to blocking of the triaxial shape by the odd proton populating negative-parity orbitals. The properties of the new 494.5-, 1440.7-, and 1748.8-keV levels found in {sup 109}Tc may indicate a change toward an oblate shape in this nucleus.

  19. DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham, WA |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Bellingham, WA DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham, WA DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham, WA Case study of a DOE Zero Energy Ready home in Bellingham, WA, that achieves HERS 43 without PV or HERS 13 with 3.2 kW of PV. The 1,055-ft2 two-story production home has 6-in. SIP walls, a 10-in. SIP roof, and ICF foundation walls with R-20 high-density rigid EPS foam under the slab. A single ductless heat pump heats

  20. Migrating data from TcSE to DOORS : an evaluation of the T-Plan Integrator software application.

    SciTech Connect (OSTI)

    Post, Debra S.; Manzanares, David A.; Taylor, Jeffrey L.

    2011-02-01

    This report describes our evaluation of the T-Plan Integrator software application as it was used to transfer a real data set from the Teamcenter for Systems Engineering (TcSE) software application to the DOORS software application. The T-Plan Integrator was evaluated to determine if it would meet the needs of Sandia National Laboratories to migrate our existing data sets from TcSE to DOORS. This report presents the struggles of migrating data and focuses on how the Integrator can be used to map a data set and its data architecture from TcSE to DOORS. Finally, this report describes how the bulk of the migration can take place using the Integrator; however, about 20-30% of the data would need to be transferred from TcSE to DOORS manually. This report does not evaluate the transfer of data from DOORS to TcSE.

  1. Liquid scintillation counting methodology for 99Tc analysis. A remedy for radiopharmaceutical waste

    SciTech Connect (OSTI)

    Khan, Mumtaz; Um, Wooyong

    2015-08-13

    This paper presents a new approach for liquid scintillation counting (LSC) analysis of single-radionuclide samples containing appreciable organic or inorganic quench. This work offers better analytical results than existing LSC methods for technetium-99 (99gTc) analysis with significant savings in analysis cost and time. The method was developed to quantify 99gTc in environmental liquid and urine samples using LSC. Method efficiency was measured in the presence of 1.9 to 11,900 ppm total dissolved solids. The quench curve was proved to be effective in the case of spiked 99gTc activity calculation for deionized water, tap water, groundwater, seawater, and urine samples. Counting efficiency was found to be 91.66% for Ultima Gold LLT (ULG-LLT) and Ultima Gold (ULG). Relative error in spiked 99gTc samples was ±3.98% in ULG and ULG-LLT cocktails. Minimum detectable activity was determined to be 25.3 mBq and 22.7 mBq for ULG-LLT and ULG cocktails, respectively. A pre-concentration factor of 1000 was achieved at 100°C for 100% chemical recovery.

  2. Kit for the selective labeling of red blood cells in whole blood with [sup 99]Tc

    DOE Patents [OSTI]

    Srivastava, S.C.; Babich, J.W.; Straub, R.; Richards, P.

    1992-05-26

    Disclosed herein are a method and kit for the preparation of [sup 99m]Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available therein for reduction of technetium. No Drawings

  3. Kit for the selective labeling of red blood cells in whole blood with .sup.9 TC

    DOE Patents [OSTI]

    Srivastava, Suresh C.; Babich, John W.; Straub, Rita; Richards, Powell

    1992-01-01

    Disclosed herein are a method and kit for the preparation of .sup.99m Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available therein for reduction of technetium.

  4. New method for the selective labeling of erythrocytes in whole blood with Tc-99m

    DOE Patents [OSTI]

    Srivastava, S.C.; Babich, J.W.; Straub, R.; Richards, P.

    1984-01-27

    Method and kit are described for the preparation of /sup 99m/Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available therein for the reduction of technetium.

  5. Luminescence-Based Spectroelectrochemical Sensor for [Tc(dmpe)3]2+/+ (dmpe = 1,2-bis(dimethylphosphino)ethane) within a Charge-Selective Polymer Film

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Edwards, Matthew K.; Bryan, Samuel A.; Kaval, Necati; Pantelic, Nebojsa; Morris, Laura K.; Heineman, W. R.; Seliskar, Carl J.

    2011-03-01

    A spectroelectrochemical sensor consisting of an indium tin oxide (ITO) optically transparent electrode (OTE) coated with a thin film of sulfonated polystyrene-blockpoly(ethylene-ran-butylene)-block-polystyrene (SSEBS) was developed for [Tc(dmpe)3]+.. [Tc(dmpe)3]+ preconcentrated by ion-exchange into the SSEBS film after 20 min exposure to aqueous [Tc(dmpe)3]+ solution, resulting in a 14-fold increase in cathodic peak current compared to a bare OTE. Colorless [Tc(dmpe)3]+ was reversibly oxidized to colored [Tc(dmpe)3]2+ by cyclic voltammetry. Detection of [Tc(dmpe)3]2+ was accomplished by electrochemically cycling the complex between non-emissive [Tc(dmpe)3]+ and emissive [Tc(dmpe)3]2+ and monitoring the modulated emission (?exc = 532 nm; ?em = 660 nm). The sensor gave a linear response over the range of 0.16 to 340.0 M.

  6. DOE Zero Energy Ready Home Case Study 2013: TC Legend, Seattle, WA

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TC Legend Homes Seattle, WA BUILDING TECHNOLOGIES OFFICE The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of excellence and quality specifi ed in DOE's Zero Energy Ready Home program (formerly known as Challenge Home). Every DOE Zero Energy Ready Home starts with ENERGY STAR for Homes Version 3 for an energy-effi cient home built on a solid foundation of building science research. Advanced technologies are designed in to give you superior

  7. Novel Approach to Prepare {sup 99m}Tc-Based Multivalent RGD Peptides

    SciTech Connect (OSTI)

    Shuang Liu

    2012-10-24

    This project presents a novel approach to prepare the {sup 99m}Tc-bridged multivalent RGD (arginine-glycine-aspartate) peptides. This project will focus on fundamentals of {sup 99m}Tc radiochemistry. The main objective of this project is to demonstrate the proof-of-principle for the proposed radiotracers. Once a kit formulation is developed for preparation of the {sup 99m}Tc-bridged multivalent RGD peptides, various tumor-bearing animal models will be used to evaluate their potential for SPECT (single photon-emission computed tomography) imaging of cancer. We have demonstrated that (1) multimerization of cyclic RGD peptides enhances the integrin {alpha}{sub v}{beta}{sub 3} bonding affinity and radiotracer tumor uptake; (2) addition of G{sub 3} or PEG{sub 4} linkers makes it possible for two RGD motifs in 3P-RGD{sub 2} and 3G-RGD{sub 2} to achieve simultaneous integrin {alpha}{sub v}{beta}{sub 3} binding; and (3) multimers are actually bivalent (not multivalent), the presence of extra RGD motifs can enhance the tumor retention time of the radiotracer.

  8. Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

    DOE Patents [OSTI]

    Bennett, Ralph G.; Christian, Jerry D.; Grover, S. Blaine; Petti, David A.; Terry, William K.; Yoon, Woo Y.

    1998-01-01

    An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

  9. Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

    1998-09-01

    An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

  10. Optimizing Cr(VI) and Tc(VII) remediation through nano-scale biomineral engineering

    SciTech Connect (OSTI)

    Cutting, R. S.; Coker, V. S.; Telling, N. D.; Kimber, R. L.; Pearce, C. I.; Ellis, B.; Lawson, R; van der Laan, G.; Pattrick, R.A.D.; Vaughan, D.J.; Arenholz, E.; Lloyd, J. R.

    2009-09-09

    To optimize the production of biomagnetite for the bioremediation of metal oxyanion contaminated waters, the reduction of aqueous Cr(VI) to Cr(III) by two biogenic magnetites and a synthetic magnetite was evaluated under batch and continuous flow conditions. Results indicate that nano-scale biogenic magnetite produced by incubating synthetic schwertmannite powder in cell suspensions of Geobacter sulfurreducens is more efficient at reducing Cr(VI) than either biogenic nano-magnetite produced from a suspension of ferrihydrite 'gel' or synthetic nano-scale Fe{sub 3}O{sub 4} powder. Although X-ray Photoelectron Spectroscopy (XPS) measurements obtained from post-exposure magnetite samples reveal that both Cr(III) and Cr(VI) are associated with nanoparticle surfaces, X-ray Magnetic Circular Dichroism (XMCD) studies indicate that some Cr(III) has replaced octahedrally coordinated Fe in the lattice of the magnetite. Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) measurements of total aqueous Cr in the associated solution phase indicated that, although the majority of Cr(III) was incorporated within or adsorbed to the magnetite samples, a proportion ({approx}10-15 %) was released back into solution. Studies of Tc(VII) uptake by magnetites produced via the different synthesis routes also revealed significant differences between them as regards effectiveness for remediation. In addition, column studies using a {gamma}-camera to obtain real time images of a {sup 99m}Tc(VII) radiotracer were performed to visualize directly the relative performances of the magnetite sorbents against ultra-trace concentrations of metal oxyanion contaminants. Again, the magnetite produced from schwertmannite proved capable of retaining more ({approx}20%) {sup 99m}Tc(VII) than the magnetite produced from ferrihydrite, confirming that biomagnetite production for efficient environmental remediation can be fine-tuned through careful selection of the initial Fe(III) mineral substrate

  11. Soy-Based, Water-Cooled, TC W-III Two Cycle Engine Oil

    SciTech Connect (OSTI)

    Scharf, Curtis R.; Miller, Mark E.

    2003-08-30

    The objective of this project was to achieve technical approval and commercial launch for a biodegradable soy oil-based, environmentally safe, TC W-III performance, water-cooled, two cycle engine oil. To do so would: (1) develop a new use for RBD soybean oil; (2) increase soybean utilization in North America in the range of 500 K-3.0 MM bushels; and (3) open up supply opportunities of 1.5-5.0 MM bushels worldwide. These goals have been successfully obtained.

  12. {sup 97}Tc produced by the ({sup 3}He,{ital pn}{gamma}) reaction

    SciTech Connect (OSTI)

    Aslan, H.; Crowe, B.; Dague, T.; Savage, D.G.; Zeghib, S.; Rickey, F.A.; Simms, P.C.

    1996-08-01

    The nuclear structure of {sup 97}Tc was studied using the {sup 96}Mo({sup 3}He,{ital pn}{gamma}) reaction, which has populated most states in the nucleus below 2 MeV excitation energy. The proton exit channel was isolated from competing reaction channels by operating {gamma}-ray detectors in coincidence with a large-solid-angle proton detector. The experiments included {gamma}-ray excitation functions, {gamma}-ray angular distributions, and {gamma}-{gamma} coincidences. The results were interpreted using a particle-rotor model. {copyright} {ital 1996 The American Physical Society.}

  13. {sup 101}Tc produced by the ({sup 3}He,pn{gamma}) reaction

    SciTech Connect (OSTI)

    Savage, D.G.; Aslan, H.; Crowe, B.; Dague, T.; Zeghib, S.; Rickey, F.A.; Simms, P.C.

    1997-01-01

    The nuclear structure of {sup 101}Tc was studied using the {sup 100}Mo({sup 3}He,pn{gamma}) reaction, which has populated most states in the nucleus below 2 MeV excitation energy. The proton exit channel was isolated from competing reaction channels by operating {gamma}-ray detectors in coincidence with a large-solid-angle proton detector. The experiments included {gamma}-ray excitation functions, {gamma}-ray angular distributions, and {gamma}-{gamma} coincidences. The results were interpreted using a particle-rotor model. {copyright} {ital 1997} {ital The American Physical Society}

  14. Kit for the rapid preparation of .sup.99m Tc red blood cells

    DOE Patents [OSTI]

    Richards, Powell; Smith, Terry D.

    1976-01-01

    A method and sample kit for the preparation of .sup.99m Tc-labeled red blood cells in a closed, sterile system. A partially evacuated tube, containing a freeze-dried stannous citrate formulation with heparin as an anticoagulant, allows whole blood to be automatically drawn from the patient. The radioisotope is added at the end of the labeling sequence to minimize operator exposure. Consistent 97% yields in 20 minutes are obtained with small blood samples. Freeze-dried kits have remained stable after five months.

  15. Interfacial Electron-Phonon Coupling as the Cause of Enhanced Tc in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Single-layer FeSe Films on SrTiO3 | Stanford Synchrotron Radiation Lightsource Interfacial Electron-Phonon Coupling as the Cause of Enhanced Tc in Single-layer FeSe Films on SrTiO3 Friday, February 27, 2015 In the past several years, multiple studies have confirmed superconductivity in single-unit-cell-thick films of iron selenide (1UC FeSe) grown on strontium titanate (STO), with gap opening temperatures approaching the boiling point of liquid nitrogen, which is nearly a decade higher than

  16. Spatially resolved assessment of hepatic function using 99mTc-IDA SPECT

    SciTech Connect (OSTI)

    Wang, Hesheng; Cao, Yue

    2013-09-15

    Purpose: 99mTc-iminodiacetic acid (IDA) hepatobiliary imaging is usually quantified for hepatic function on the entire liver or regions of interest (ROIs) in the liver. The authors presented a method to estimate the hepatic extraction fraction (HEF) voxel-by-voxel from single-photon emission computed tomography (SPECT)/CT with a 99mTc-labeled IDA agent of mebrofenin and evaluated the spatially resolved HEF measurements with an independent physiological measurement.Methods: Fourteen patients with intrahepatic cancers were treated with radiation therapy (RT) and imaged by 99mTc-mebrofenin SPECT before and 1 month after RT. The dynamic SPECT volumes were with a resolution of 3.9 × 3.9 × 2.5 mm{sup 3}. Throughout the whole liver with approximate 50 000 voxels, voxelwise HEF quantifications were estimated and compared between using arterial input function (AIF) from the heart and using vascular input function (VIF) from the spleen. The correlation between mean of the HEFs over the nontumor liver tissue and the overall liver function measured by Indocyanine green clearance half-time (T1/2) was assessed. Variation of the voxelwise estimation was evaluated in ROIs drawn in relatively homogeneous regions of the livers. The authors also examined effects of the time range parameter on the voxelwise HEF quantification.Results: Mean of the HEFs over the liver estimated using AIF significantly correlated with the physiological measurement T1/2 (r= 0.52, p= 0.0004), and the correlation was greatly improved by using VIF (r= 0.79, p < 0.0001). The parameter of time range for the retention phase did not lead to a significant difference in the means of the HEFs in the ROIs. Using VIF and a retention phase time range of 7–30 min, the relative variation of the voxelwise HEF in the ROIs was 10%± 6% of respective mean HEF.Conclusions: The voxelwise HEF derived from 99mTc-IDA SPECT by the deconvolution analysis is feasible to assess the spatial distribution of hepatic function in the

  17. Conceptual design of a new homogeneous reactor for medical radioisotope Mo-99/Tc-99m production

    SciTech Connect (OSTI)

    Liem, Peng Hong; Tran, Hoai Nam; Sembiring, Tagor Malem; Arbie, Bakri

    2014-09-30

    To partly solve the global and regional shortages of Mo-99 supply, a conceptual design of a nitrate-fuel-solution based homogeneous reactor dedicated for Mo-99/Tc-99m medical radioisotope production is proposed. The modified LEU Cintichem process for Mo-99 extraction which has been licensed and demonstrated commercially for decades by BATAN is taken into account as a key design consideration. The design characteristics and main parameters are identified and the advantageous aspects are shown by comparing with the BATAN's existing Mo-99 supply chain which uses a heterogeneous reactor (RSG GAS multipurpose reactor)

  18. Thrombus detection using a Tc-99m labeled antifibrin monoclonal antibody (MoAb). Experiments in vitro and in animals

    SciTech Connect (OSTI)

    Wasser, M.N.; Pauwels, E.K.; Nieuwenhuizen, W. )

    1990-01-01

    This paper describes the production and characterization of an antifibrin monoclonal antibody, produced by immunizing mice with fibrinogen degradation fragment Y. The antibody (designated Y22) is directed against a conformation dependent epitope in the D-domain of fibrin Y22 was labeled with the radionuclide Tc-99m. Experiments in vitro and in rats are presented which show the potential of scintigraphic detection of thrombi with Tc-99m-Y22. Preliminary results show that immunoscintigraphy of thrombi may also have potential for the monitoring of thrombolytic therapy (eg with t-PA).

  19. trans-K3[TcO2(CN)4

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S; Edwards, Matthew K; Twamley, Brendan; Krause, Jeanette A; Bryan, Samuel A

    2010-07-14

    The dioxotetracyanotechnetate anion, [TcO2(CN)4]3-, of the title complex has octahedral symmetry. The technetium is located on a center of inversion and is bound by two oxygen atoms and four cyano ligands. The Tc=O bond distance of 1.7721 (12) Å is consistent with double bond character. The potassium cations [located on special (1/2,0,1) and general positions] reside in octahedral or tetrahedral environments; interionic K···O and K···N interactions occur in the 2.7877 (19)-2.8598 (15) Å range.

  20. New Synthesis Route and Characterization of Siderite (FeCO{sub 3} ) and Coprecipitation of {sup 99}Tc

    SciTech Connect (OSTI)

    Llorens, Isabelle; Fattahi, Massoud; Grambow, Bernd

    2007-07-01

    Technetium-99 is a long-lived product of nuclear fission. In the ground-waters of European disposal sites Tc is expected to be in the tetravalent state since the geochemical conditions are reducing due to the presence of redox couples such as Fe(II)/Fe(III), and the presence of reducing minerals such as pyrite and siderite (FeCO{sub 3}). Siderite is expected to be formed as well as container corrosion product. Experiments of coprecipitation of Fe{sup 2+} and Tc(IV) were conducted in the laboratory under an inert atmosphere at room temperature. High resolution transmission electron microscopy shows that the co-precipitate is around 3 nm sized particles. Analytical electron microscopy indicates that the precipitate contains 30 atom % of Tc and 70 atom % Fe. The Tc was homogeneously distributed. Selected Area Electron Diffraction does not reveal the formation of siderite, which suggests that the presence of technetium in high concentration inhibit the formation of this phase. (authors)

  1. A field trial of novel bifunctional resins for removing pertechnetate (TcO{sub 4}{sup {minus}}) from contaminated groundwater

    SciTech Connect (OSTI)

    Gu, B.; Liang, L.; Brown, G.M.; Bonnesen, P.V.; Moyer, B.A.; Alexandratos, S.D.; Ober, R.

    1998-03-01

    A field trial using a custom-designed bifunctional synthetic resin prepared at the University of Tennessee and designed to selectively remove pertechnetate (TcO{sub 4}{sup {minus}}) from groundwater was conducted in summer 1997 at the Northwest Plume Pump-and-Treat Facility at the US Department of Energy`s Paducah Gaseous Diffusion Plant (PGDP) site. The bifunctional resin, RO-02-119, was a copolymer of vinylbenzylchloride and divinylbenzene that had been functionalized with trihexylamine and triethylamine. The experiment was a parallel test of the synthetic resin and a commercial resin, Purolite A-520E, to directly compare the performance of the two resins. Purolite resin is currently used by the treatment facility to remove Tc-99 from the contaminated groundwater containing {approximately}1,000 pCi/L TcO{sub 4}{sup {minus}}. A total of {approximately}692,000 bed volumes of groundwater was passed through the column containing the synthetic resin (RO-02-119) whereas only {approximately}205,000 bed volumes of groundwater were passed through the Purolite resin column because of reduced hydraulic conductivity and clogging within the latter column. Despite less groundwater passing through the Purolite resin column, however, the breakthrough of TcO{sub 4}{sup {minus}} occurred earlier in the Purolite column than in the RO-02-119 column.

  2. Method and kit for the selective labeling of red blood cells in whole blood with TC-99M

    DOE Patents [OSTI]

    Srivastava, Suresh C.; Babich, John W.; Straub, Rita; Richards, Powell

    1988-01-01

    Disclosed herein are a method and kit for the preparation of .sup.99m Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available therein for the reduction of technetium.

  3. Method and kit for the selective labeling of red blood cells in whole blood with Tc-99m

    DOE Patents [OSTI]

    Srivastava, S.C.; Babich, J.W.; Straub, R.; Richards, P.

    1988-07-05

    Disclosed herein are a method and kit for the preparation of [sup 99m]Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available for the reduction of technetium. No Drawings

  4. Photophysics and Luminescence Spectroelectrochemistry of [Tc(dmpe)3]+/2+ (dmpe = 1,2-bis(dimethylphosphino)ethane)

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Smith, Frances N.; Wang, Zheming; Hightower, Sean E.; Sullivan, Brian P.; Heineman, William R.; Seliskar, Carl J.; Bryan, Samuel A.

    2013-12-05

    The ligand-to-metal charge transfer (LMCT) excited state luminescence of [Tc(dmpe)3]2+ (dmpe is 1,2-bis-(dimethylphosphino)ethane) has been measured in solution at room temperature, and is compared to its Re analogue. Surprisingly, both [M(dmpe)3]2+* (M = Re, Tc) species have extremely large excited-state potentials (ESPs) as oxidants - the highest for any simple coordination complex of a transition metal. Furthermore, this potential is available using a photon of visible light (calculated for M = Re(Tc); E1/2* = +2.61(2.48) V versus SCE; ?max = 526(585) nm). Open shell TDDFT calculations support the assignment of the lowest energy transition in both the technetium and rhenium complexes to be a doublet-doublet process that involve predominantly LMCT (dmpe-to-metal) character and is in agreement with past assignments for the Re system. As expected for highly oxidizing excited state potentials, quenching is observed for the excited states by both the rhenium and technetium complexes. Stern-Volmer analysis resulted in quenching parameters for both the rhenium and technetium complexes under identical conditions, and are compared using Rehm-Weller analysis. Of particular interest is the fact that both benzene and toluene are oxidized by both the Re and Tc systems.

  5. A technique using {sup 99m}Tc-mebrofenin SPECT for radiotherapy treatment planning for liver cancers or metastases

    SciTech Connect (OSTI)

    Shen, Sui; Jacob, Rojymon; Bender, Luvenia W.; Duan, Jun; Spencer, Sharon A.

    2014-04-01

    Radiotherapy or stereotactic body radiosurgery (SBRT) requires a sufficient functional liver volume to tolerate the treatment. The current study extended the work of de Graaf et al. (2010) [3] on the use of {sup 99m}Tc-mebrofenin imaging for presurgery planning to radiotherapy planning for liver cancer or metastases. Patient was immobilized and imaged in an identical position on a single-photon emission computed tomography/computed tomography (SPECT-CT) system and a radiotherapy simulation CT system. {sup 99m}Tc-mebrofenin SPECT was registered to the planning CT through image registration of noncontrast CT from SPECT-CT system to the radiotherapy planning CT. The voxels with higher uptake of {sup 99m}Tc-mebrofenin were transferred to the planning CT as an avoidance structure in optimizing a 2-arc RapidArc plan for SBRT delivery. Excellent dose coverage to the target and sparing of the healthy remnant liver volume was achieved. This report illustrated a procedure for the use of {sup 99m}Tc-mebrofenin SPECT for optimizing radiotherapy for liver cancers and metastases.

  6. Method for generating a crystalline {sup 99}MoO{sub 3} product and the isolation {sup 99m}Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Kirkham, R.J.; Tranter, T.J.

    1998-09-01

    An improved method is described for producing {sup 99m}Tc compositions. {sup 100}Mo metal is irradiated with photons in a particle (electron) accelerator to produce {sup 99}Mo metal which is dissolved in a solvent. A solvated {sup 99}Mo product is then dried to generate a supply of {sup 99}MoO{sub 3} crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized {sup 99m}TcO{sub 3} and vaporized {sup 99m}TcO{sub 2} but will not cause the production of vaporized {sup 99}MoO{sub 3}. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7}. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline {sup 99}MoO{sub 3} starting materials with segregated {sup 99m}Tc compositions therein which avoid the production of vaporized {sup 99}MoO{sub 3} contaminants. 1 fig.

  7. Method for generating a crystalline .sup.99 MoO.sub.3 product and the isolation .sup.99m Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, Ralph G.; Christian, Jerry D.; Kirkham, Robert J.; Tranter, Troy J.

    1998-01-01

    An improved method for producing .sup.99m Tc compositions. .sup.100 Mo metal is irradiated with photons in a particle (electron) accelerator to produce .sup.99 Mo metal which is dissolved in a solvent. A solvated .sup.99 Mo product is then dried to generate a supply of .sup.99 MoO.sub.3 crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized .sup.99m TcO.sub.3 and vaporized .sup.99m TcO.sub.2 but will not cause the production of vaporized .sup.99 MoO.sub.3. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline .sup.99 MoO.sub.3 starting materials with segregated .sup.99m Tc compositions therein which avoid the production of vaporized .sup.99 MoO.sub.3 contaminants.

  8. Nodal bilayer-splitting controlled by spin-orbit interactions in underdoped high-Tc cuprates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harrison, N.; Ramshaw, B. J.; Shekhter, A.

    2015-06-03

    The highest superconducting transition temperatures in the cuprates are achieved in bilayer and trilayer systems, highlighting the importance of interlayer interactions for high Tc. It has been argued that interlayer hybridization vanishes along the nodal directions by way of a specific pattern of orbital overlap. Recent quantum oscillation measurements in bilayer cuprates have provided evidence for a residual bilayer-splitting at the nodes that is sufficiently small to enable magnetic breakdown tunneling at the nodes. Here we show that several key features of the experimental data can be understood in terms of weak spin-orbit interactions naturally present in bilayer systems, whosemore » primary effect is to cause the magnetic breakdown to be accompanied by a spin flip. These features can now be understood to include the equidistant set of three quantum oscillation frequencies, the asymmetry of the quantum oscillation amplitudes in c-axis transport compared to ab-plane transport, and the anomalous magnetic field angle dependence of the amplitude of the side frequencies suggestive of small effective g-factors. We suggest that spin-orbit interactions in bilayer systems can further affect the structure of the nodal quasiparticle spectrum in the superconducting phase. PACS numbers: 71.45.Lr, 71.20.Ps, 71.18.+y« less

  9. Mass Measurements of Very Neutron-Deficient Mo and Tc Isotopes and Their Impact on rp Process Nucleosynthesis

    SciTech Connect (OSTI)

    Haettner, E.; Plass, W. R.; Scheidenberger, C.; Ackermann, D.; Block, M.; Eliseev, S.; Herfurth, F.; Hessberger, F. P.; Hofmann, S.; Kluge, H.-J.; Audi, G.; Blaum, K.; Ketter, J.; Fleckenstein, T.; Ketelaer, J.; Marx, G.; Schweikhard, L.; Mazzocco, M.; Novikov, Yu. N.; Vorobjev, G.

    2011-03-25

    The masses of ten proton-rich nuclides, including the N=Z+1 nuclides {sup 85}Mo and {sup 87}Tc, were measured with the Penning trap mass spectrometer SHIPTRAP. Compared to the Atomic Mass Evaluation 2003 a systematic shift of the mass surface by up to 1.6 MeV is observed causing significant abundance changes of the ashes of astrophysical x-ray bursts. Surprisingly low {alpha} separation energies for neutron-deficient Mo and Tc are found, making the formation of a ZrNb cycle in the rp process possible. Such a cycle would impose an upper temperature limit for the synthesis of elements beyond Nb in the rp process.

  10. V-183: Cisco TelePresence TC and TE Bugs Let Remote Users Deny Service and Remote Adjacent Authenticated Users Gain Root Shell Access

    Broader source: Energy.gov [DOE]

    Cisco TelePresence TC and TE Software contain two vulnerabilities in the implementation of the Session Initiation Protocol (SIP) that could allow an unauthenticated remote attacker to cause a denial of service (DoS) condition. Additionally, Cisco TelePresence TC Software contain an adjacent root access vulnerability that could allow an attacker on the same physical or logical Layer-2 network as the affected system to gain an unauthenticated root shell.

  11. Fiscal Year 2010 Summary Report on the Epsilon-Metal Phase as a Waste Form for 99 Tc

    SciTech Connect (OSTI)

    Strachan, Denis M.; Crum, Jarrod V.; Buck, Edgar C.; Riley, Brian J.; Zumhoff, Mac R.

    2010-09-30

    Epsilon metal (ε-metal) is generated in nuclear fuel during irradiation. This metal consists of Pd, Ru, Rh, Mo, and some Te. These accumulate at the UO2 grain boundaries as small (ca 5 µm) particles. These metals have limited solubility in the acid used to dissolve fuel during reprocessing and in typical borosilicate glass. These must be treated separately to improve overall waste loading in glass. This low solubility and their survival in 2 Gy-old natural reactors led us to investigate them as a waste form for the immobilization of 99Tc and 107Pd, two very long-lived isotopes.

  12. Anisotropic Hc2 , thermodynamic and transport measurements, and pressure dependence of Tc in K2Cr3As3 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kong, Tai; Bud'ko, Sergey L.; Canfield, Paul C.

    2015-01-30

    We present a detailed study of single crystalline K2Cr3As3 and analyze its thermodynamic and transport properties, anisotropic Hc2(T), and initial pressure dependence of Tc. In zero field, the temperature-dependent resistivity is metallic. Deviation from a linear temperature dependence is evident below 100 K and a T3 dependence is roughly followed from just above Tc (~10K) to ~40K. Anisotropic Hc2(T) data were measured up to 140 kOe with field applied along and perpendicular to the rodlike crystals. For the applied field perpendicular to the rod, Hc2(T) is linear with a slope ~–70 kOe/K. For field applied along the rod, the slopemore » is about –120 kOe/K below 70 kOe. Above 70 kOe, the magnitude of the slope decreases to ~–70 kOe/K. The electronic specific heat coefficient γ, just above Tc, is 73 mJ/mol K2; the Debye temperature ΘD is 220 K. As a result, the specific heat jump at the superconducting transition ΔC~2.2γTc. Finally, for hydrostatic pressures up to ~7 kbar, Tc decreases under pressure linearly at a rate of –0.034K/kbar.« less

  13. Assessment of RELAP/MOD3 using BETHSY 6.2TC 6-inch cold leg side break comparative test

    SciTech Connect (OSTI)

    Chung, Young-Jong; Jeong, Jae-Jun; Chang, Won-Pyo; Kim, Dong-Su

    1996-10-01

    This report presents the results of the RELAP5/MOD3 Version 7j assessment on BETHSY 6.2TC. BETHSY 6.2TC test corresponding to a six inch cold leg break LOCA of the Pressurizer Water Reactor(PWR). The primary objective of the test was to provide reference data of two facilities of different scales (BETHSY and LSTF facility). On the other hand, the present calculation aims at analysis of RELAP5/N4OD3 capability on the small break LOCA simulation, The results of calculation have shown that the RELAP5/MOD3 reasonably predicts occurrences as well as trends of the major phenomena such as primary pressure, timing of loop seal clearing, liquid hold up, etc. However, some disagreements also have been found in the predictions of loop seal clearing, collapsed core water level after loop seal clearing, and accumulator injection behaviors. For better understanding of discrepancies in same predictions, several sensitivity calculations have been performed as well. These include the changes of two-phase discharge coefficient at the break junction and some corrections of the interphase drag term. As result, change of a single parameter has not improved the overall predictions and it has been found that the interphase drag model has still large uncertainties.

  14. NMR characterization of sulphur substitution effects in the KxFe2-ySe2-zSz high-Tc superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Torchetti, D. A.; Imai, T.; Lei, H. C.; Petrovic, C.

    2012-04-17

    We present a⁷⁷ Se NMR study of the effect of S substitution in the high-Tc superconductor KxFe2-ySe2-zSz in a temperature range up to 250 K. We examine two S concentrations, with z=0.8 (Tc~ 26 K) and z=1.6 (nonsuperconducting). The samples containing sulphur exhibit broader NMR line shapes than the KxFe₂Se₂ sample due to local disorder in the Se environment. Our Knight shift ⁷⁷K data indicate that in all samples, uniform spin susceptibility decreases with temperature, and that the magnitude of the Knight shift itself decreases with increased S concentration. In addition, S substitution progressively suppresses low-frequency spin fluctuations. None ofmore » the samples exhibit an enhancement of low-frequency antiferromagnetic spin fluctuations near Tc in 1/T₁T, as seen in FeSe.« less

  15. Evidence for a new excitation at the interface between a high-Tc superconductor and a topological insulator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zareapour, Parisa; Hayat, Alex; Zhao, Shu Yang F.; Kreshchuk, Michael; Lee, Yong Kiat; Reijnders, Anjan A.; Jain, Achint; Xu, Zhijun; Liu, T. S.; Gu, G. D.; et al

    2014-12-09

    In this research, high-temperature superconductors exhibit a wide variety of novel excitations. If contacted with a topological insulator, the lifting of spin rotation symmetry in the surface states can lead to the emergence of unconventional superconductivity and novel particles. In pursuit of this possibility, we fabricated high critical-temperature (Tc ~ 85 K) superconductor/topological insulator (Bi₂Sr₂CaCu₂O₈₊δ/Bi₂Te₂Se) junctions. Below 75 K, a zero-bias conductance peak (ZBCP) emerges in the differential conductance spectra of this junction. The magnitude of the ZBCP is suppressed at the same rate for magnetic fields applied parallel or perpendicular to the junction. Furthermore, it can still be observedmore » and does not split up to at least 8.5 T. The temperature and magnetic field dependence of the excitation we observe appears to fall outside the known paradigms for a ZBCP.« less

  16. Attenuation compensation in TC-99M SPECT brain imaging: Use of attenuation maps derived from tranmission versus emission data

    SciTech Connect (OSTI)

    Pan, T.S.; Licho, R.; Penney, B.C. [Univ. of Massachusetts Mecical Center, Worcester, MA (United States)] [and others

    1994-05-01

    This study compares reconstructions of Tc-99m brain SPECT studies made using two methods of estimating the attenuation map: (1) transmission scanning, and (2) segmenting reconstructions of emission data and assigning attenuation coefficient values. A three-head SPECT system with fan beam collimators was used. Transmission scanning was performed using a line source at the focal line of a fan beam collimator right after the regular emission scan. The higher attenuation of the skull and the lower attenuation in the sinus cavities were identifiable despite the noise in the reconstructed transmission data due to: (1) the contamination of the transmission data by emission photons, (2) the maximum acquisition count rate imposed by the SPECT system, and (3) the clinical scanning time. Emission data were recorded using both photopeak and Compton scatter energy windows. Outlines of the head and the maxillary sinus could be obtained using only the Compton scatter reconstructions, whereas identifying the skull regions and the frontal sinus required the photopeak data as well. We placed appropriate linear attenuation coefficients in the soft tissue, bone, sinus and air regions (0.15,. 0.22, 0, and 0 cm{sup -1}) and blurred this attenuation map with a Gaussian kernel of about 0.2 cm standard deviation to obtain the attenuation map based on the emission data. Reconstructions were computed using the maximum likelihood expectation maximization algorithm with Siddon`s ray-tracing algorithm. Reconstructions based on the two attenuation maps were compared quantitatively on the patient data. The differences noted were quite small. These results imply that attenuation correction based on emission data alone may be adequate for Tc-99m SPECT brain imaging.

  17. High-Tc superconductivity at the interface between the CaCuO2 and SrTiO3 insulating oxides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Di Castro, D.; Cantoni, C.; Ridolfi, F.; Aruta, C.; Tebano, A.; Yang, N.; Balestrino, G.

    2015-09-28

    At interfaces between complex oxides it is possible to generate electronic systems with unusual electronic properties, which are not present in the isolated oxides. One important example is the appearance of superconductivity at the interface between insulating oxides, although, until now, with very low Tc. We report the occurrence of high Tc superconductivity in the bilayer CaCuO2/SrTiO3, where both the constituent oxides are insulating. In order to obtain a superconducting state, the CaCuO2/SrTiO3 interface must be realized between the Ca plane of CaCuO2 and the TiO2 plane of SrTiO3. Only in this case can oxygen ions be incorporated in themore » interface Ca plane, acting as apical oxygen for Cu and providing holes to the CuO2 planes. In addition, a detailed hole doping spatial profile can be obtained by scanning transmission electron microscopy and electron-energy-loss spectroscopy at the O K edge, clearly showing that the (super)conductivity is confined to about 1–2 CaCuO2 unit cells close to the interface with SrTiO3. The results obtained for the CaCuO2/SrTiO3 interface can be extended to multilayered high Tc cuprates, contributing to explaining the dependence of Tc on the number of CuO2 planes in these systems.« less

  18. Highly Selective Colorimetric and Luminescence Response of a Square-Planar Platinum(II) Terpyridyl Complex to Aqueous TcO4-

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Norton, Amie E.; Edwards, Matthew K.; Peterson, James M.; Taylor, Stephen D.; Bryan, Samuel A.; Andersen, Amity; Govind, Niranjan; Albrecht-Schmitt, Thomas E.; Connick, William; Levitskaia, Tatiana G.

    2015-10-08

    In an effort to address the need for a rapid, selective and economical detection technique for aqueous pertechnetate (TcO4-) anion based on recognition at the molecular level, simple salts of transition metal complexes that undergo a distinct spectroscopic change upon exposure to aqueous anions were explored. The Pt(II) complex [Pt(tpy)Br]SbF6 (tpy=2,2';6',2"-terpyridine) undergoes a dramatic color change and intense luminescence response upon TcO4- uptake due to concomitant enhancement of Pt•••Pt interactions. The spectroscopic response was highly selective and quantitative for aqueous TcO4- among other competing anions. Complimentary Raman spectroscopy and microscopy techniques, structural determination and theoretical methods were employed to achieve molecular-level understanding of the mechanism of the response to aqueous TcO4-.

  19. Implications of CT noise and artifacts for quantitative {sup 99m}Tc SPECT/CT imaging

    SciTech Connect (OSTI)

    Hulme, K. W.; Kappadath, S. C.

    2014-04-15

    Purpose: This paper evaluates the effects of computed tomography (CT) image noise and artifacts on quantitative single-photon emission computed-tomography (SPECT) imaging, with the aim of establishing an appropriate range of CT acquisition parameters for low-dose protocols with respect to accurate SPECT attenuation correction (AC). Methods: SPECT images of two geometric and one anthropomorphic phantom were reconstructed iteratively using CT scans acquired at a range of dose levels (CTDI{sub vol} = 0.4 to 46 mGy). Resultant SPECT image quality was evaluated by comparing mean signal, background noise, and artifacts to SPECT images reconstructed using the highest dose CT for AC. Noise injection was performed on linear-attenuation (μ) maps to determine the CT noise threshold for accurate AC. Results: High levels of CT noise (σ ∼ 200–400 HU) resulted in low μ-maps noise (σ ∼ 1%–3%). Noise levels greater than ∼10% in 140 keV μ-maps were required to produce visibly perceptible increases of ∼15% in {sup 99m}Tc SPECT images. These noise levels would be achieved at low CT dose levels (CTDI{sub vol} = 4 μGy) that are over 2 orders of magnitude lower than the minimum dose for diagnostic CT scanners. CT noise could also lower (bias) the expected μ values. The relative error in reconstructed SPECT signal trended linearly with the relative shift in μ. SPECT signal was, on average, underestimated in regions corresponding with beam-hardening artifacts in CT images. Any process that has the potential to change the CT number of a region by ∼100 HU (e.g., misregistration between CT images and SPECT images due to motion, the presence of contrast in CT images) could introduce errors in μ{sub 140} {sub keV} on the order of 10%, that in turn, could introduce errors on the order of ∼10% into the reconstructed {sup 99m}Tc SPECT image. Conclusions: The impact of CT noise on SPECT noise was demonstrated to be negligible for clinically achievable CT parameters. Because

  20. Prototype Development of Remote Operated Hot Uniaxial Press (ROHUP) to Fabricate Advanced Tc-99 Bearing Ceramic Waste Forms - 13381

    SciTech Connect (OSTI)

    Alaniz, Ariana J.; Delgado, Luc R.; Werbick, Brett M.; Hartmann, Thomas

    2013-07-01

    The objective of this senior student project is to design and build a prototype construction of a machine that simultaneously provides the proper pressure and temperature parameters to sinter ceramic powders in-situ to create pellets of rather high densities of above 90% (theoretical). This ROHUP (Remote Operated Hot Uniaxial Press) device is designed specifically to fabricate advanced ceramic Tc-99 bearing waste forms and therefore radiological barriers have been included in the system. The HUP features electronic control and feedback systems to set and monitor pressure, load, and temperature parameters. This device operates wirelessly via portable computer using Bluetooth{sup R} technology. The HUP device is designed to fit in a standard atmosphere controlled glove box to further allow sintering under inert conditions (e.g. under Ar, He, N{sub 2}). This will further allow utilizing this HUP for other potential applications, including radioactive samples, novel ceramic waste forms, advanced oxide fuels, air-sensitive samples, metallic systems, advanced powder metallurgy, diffusion experiments and more. (authors)

  1. Sci—Thur PM: Imaging — 04: An iterative triple energy window (TEW) approach to cross talk correction in quantitative small animal Tc99m and In111 SPECT

    SciTech Connect (OSTI)

    Prior, P; Timmins, R; Wells, R G

    2014-08-15

    Dual isotope SPECT allows simultaneous measurement of two different tracers in vivo. With In111 (emission energies of 171keV and 245keV) and Tc99m (140keV), quantification of Tc99m is degraded by cross talk from the In111 photons that scatter and are detected at an energy corresponding to Tc99m. TEW uses counts recorded in two narrow windows surrounding the Tc99m primary window to estimate scatter. Iterative TEW corrects for the bias introduced into the TEW estimate resulting from un-scattered counts detected in the scatter windows. The contamination in the scatter windows is iteratively estimated and subtracted as a fraction of the scatter-corrected primary window counts. The iterative TEW approach was validated with a small-animal SPECT/CT camera using a 2.5mL plastic container holding thoroughly mixed Tc99m/In111 activity fractions of 0.15, 0.28, 0.52, 0.99, 2.47 and 6.90. Dose calibrator measurements were the gold standard. Uncorrected for scatter, the Tc99m activity was over-estimated by as much as 80%. Unmodified TEW underestimated the Tc99m activity by 13%. With iterative TEW corrections applied in projection space, the Tc99m activity was estimated within 5% of truth across all activity fractions above 0.15. This is an improvement over the non-iterative TEW, which could not sufficiently correct for scatter in the 0.15 and 0.28 phantoms.

  2. High-Tc Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Donghui Lu, Kyle Shen, and Zhi-Xun Shen Departments of Applied Physics, Physics, and Stanford Synchrotron Radiation Laboratory, Stanford University, Stanford, CA 94305 High-temperature superconductors (HTSC's), following their remarkable discovery in 1986, continue to be at the center stage of modern condensed matter physics. Despite great efforts from both theoretical and experimental sides, the mechanism of HTSC still remains elusive. One of the most peculiar aspects of HTSC's is that their

  3. Predictive Models for Regional Hepatic Function Based on 99mTc-IDA SPECT and Local Radiation Dose for Physiologic Adaptive Radiation Therapy

    SciTech Connect (OSTI)

    Wang, Hesheng; Feng, Mary; Frey, Kirk A.; Ten Haken, Randall K.; Lawrence, Theodore S.; Cao, Yue

    2013-08-01

    Purpose: High-dose radiation therapy (RT) for intrahepatic cancer is limited by the development of liver injury. This study investigated whether regional hepatic function assessed before and during the course of RT using 99mTc-labeled iminodiacetic acid (IDA) single photon emission computed tomography (SPECT) could predict regional liver function reserve after RT. Methods and Materials: Fourteen patients treated with RT for intrahepatic cancers underwent dynamic 99mTc-IDA SPECT scans before RT, during, and 1 month after completion of RT. Indocyanine green (ICG) tests, a measure of overall liver function, were performed within 1 day of each scan. Three-dimensional volumetric hepatic extraction fraction (HEF) images of the liver were estimated by deconvolution analysis. After coregistration of the CT/SPECT and the treatment planning CT, HEF dose–response functions during and after RT were generated. The volumetric mean of the HEFs in the whole liver was correlated with ICG clearance time. Three models, dose, priori, and adaptive models, were developed using multivariate linear regression to assess whether the regional HEFs measured before and during RT helped predict regional hepatic function after RT. Results: The mean of the volumetric liver HEFs was significantly correlated with ICG clearance half-life time (r=−0.80, P<.0001), for all time points. Linear correlations between local doses and regional HEFs 1 month after RT were significant in 12 patients. In the priori model, regional HEF after RT was predicted by the planned dose and regional HEF assessed before RT (R=0.71, P<.0001). In the adaptive model, regional HEF after RT was predicted by regional HEF reassessed during RT and the remaining planned local dose (R=0.83, P<.0001). Conclusions: 99mTc-IDA SPECT obtained during RT could be used to assess regional hepatic function and helped predict post-RT regional liver function reserve. This could support individualized adaptive radiation treatment strategies

  4. Application of Surface Analysis Methods to Nanomaterials: Summaryof ISO/TC 201 Technical Report: ISO 14187:2011 -Surface Chemical Analysis- Characterization of Nanomaterials

    SciTech Connect (OSTI)

    Baer, Donald R.

    2012-09-01

    ISO Technical Report (TR) 14187 provides an introduction to (and examples of) the information that can be obtained about nanostructured materials using surface-analysis tools. In addition, both general issues and challenges associated with characterising nanostructured materials and the specific opportunities and challenges associated with individual analytical methods are identified. As the size of objects or components of materials approaches a few nanometres, the distinctions among 'bulk', 'surface' and 'particle' analysis blur. This Technical Report focuses on issues specifically relevant to surface chemical analysis of nanostructured materials. The report considers a variety of analysis methods but focuses on techniques that are in the domain of ISO/TC 201 including Auger electron spectroscopy, X-ray photoelectron spectroscopy, secondary ion mass spectrometry, and scanning probe microscopy. Measurements of nanoparticle surface properties such as surface potential that are often made in a solution are not discussed.

  5. Adaptation of methodology to select structural alternatives of one-way slab in residential building to the guidelines of the European Committee for Standardization (CEN/TC 350)

    SciTech Connect (OSTI)

    Fraile-Garcia, Esteban; Ferreiro-Cabello, Javier; Martinez-Camara, Eduardo; Jimenez-Macias, Emilio

    2015-11-15

    The European Committee for Standardization (CEN) through its Technical Committee CEN/TC-350 is developing a series of standards for assessing the building sustainability, at both product and building levels. The practical application of the selection (decision making) of structural alternatives made by one-way slabs leads to an intermediate level between the product and the building. Thus the present study addresses this problem of decision making, following the CEN guidelines and incorporating relevant aspects of architectural design into residential construction. A life cycle assessment (LCA) is developed in order to obtain valid information for the decision making process (the LCA was developed applying CML methodology although Ecoindicator99 was used in order to facilitate the comparison of the values); this information (the carbon footprint values) is contrasted with other databases and with the information from the Environmental Product Declaration (EPD) of one of the lightening materials (expanded polystyrene), in order to validate the results. Solutions of different column disposition and geometries are evaluated in the three pillars of sustainable construction on residential construction: social, economic and environmental. The quantitative analysis of the variables used in this study enables and facilitates an objective comparison in the design stage by a responsible technician; the application of the proposed methodology reduces the possible solutions to be evaluated by the expert to 12.22% of the options in the case of low values of the column index and to 26.67% for the highest values. - Highlights: • Methodology for selection of structural alternatives in buildings with one-way slabs • Adapted to CEN guidelines (CEN/TC-350) for assessing the building sustainability • LCA is developed in order to obtain valid information for the decision making process. • Results validated comparing carbon footprint, databases and Env. Product Declarations

  6. Sci—Thur PM: Imaging — 05: Calibration of a SPECT/CT camera for quantitative SPECT with {sup 99m}Tc

    SciTech Connect (OSTI)

    Gaudin, Émilie; Montégiani, Jean-François; Després, Philippe; Beauregard, Jean-Mathieu

    2014-08-15

    While quantitation is the norm in PET, it is not widely available yet in SPECT. This work's aim was to calibrate a commercially available SPECT/CT system to perform quantitative SPECT. Counting sensitivity, dead-time (DT) constant and partial volume effect (PVE) of the system were assessed. A dual-head Siemens SymbiaT6 SPECT/CT camera equipped with low energy high-resolution collimators was studied. {sup 99m}Tc was the radioisotope of interest because of its wide usage in nuclear medicine. First, point source acquisitions were performed (activity: 30–990MBq). Further acquisitions were then performed with a uniform Jaszczak phantom filled with water at high activity (25–5000MBq). PVE was studied using 6 hot spheres (diameters: 9.9–31.2 mm) filled with {sup 99m}Tc (2.8MBq/cc) in the Jaszczak phantom, which was: (1) empty, (2) water-filled and (3) water-filled with low activity (0.1MBq/cc). The data was reconstructed with the Siemens's Flash3D iterative algorithm with 4 subsets and 8 iterations, attenuation-correction (AC) and scatter-correction (SC). DT modelling was based on the total spectrum counting rate. Sensitivity was assessed using AC-SC reconstructed SPECT data. Sensitivity and DT for the sources were 99.51±1.46cps/MBq and 0.60±0.04µs. For the phantom, sensitivity and DT were 109.9±2.3cps/MBq and 0.62±0.13µs. The recovery-coefficient varied from 5% for the 9.9mm, to 80% for the 31.2mm spheres. With our calibration methods, both sensitivity and DT constant of the SPECT camera had little dependence on the object geometry and attenuation. For small objects of known size, recovery-coefficient can be applied to correct PVE. Clinical quantitative SPECT appears to be possible and has many potential applications.

  7. Travel to France as Chief US Delegate at a meeting of International Standards Organization ISO/TC-85, ``Nuclear Technology``. Foreign trip report, March 17--March 26, 1994

    SciTech Connect (OSTI)

    Westfall, R.M.

    1994-04-11

    As overall US Advisor for ISO/TC-85, SC-5, Dr. Westfall met with (1) Work Group 1, ``Measurement Techniques for the Chemical and Physical Characterization of UF{sub 6}, UO{sub 2}, and Mixed Oxide,`` on Monday, March 21, (2) Work Group 5, ``Standardization of Measurement Methods for the Characterization of Solid and Solidified Waste Forms, and for the Corrosion of their Primary Containers,`` on Tuesday, March 22; and (3) the full Subcommittee-5 on Wednesday, March 23. The status of work by all seven work groups in SC-5 was reported. Those having to do with nuclear fuel transportation (WG-4: UF, Containers, WG-9: Cask Trunnions, and WG-10: Cask Confinement) either have approved standards or drafts at an advanced stage of development. These work group convenors were asked to maintain their membership and establish new work areas in the field of nuclear fuel packaging. Definition of scope for new work is to be done in coordination with the interested staff members of the International Atomic Energy Agency, Vienna, Austria. On Thursday, March 24, the Cogema-Marcoule Plant staff hosted the SC-5 members to technical tours of their nuclear fuel reprocessing and waste vitrification and storage facilities.

  8. Wang-Landau density of states based study of the folding-unfolding transition in the mini-protein Trp-cage (TC5b)

    SciTech Connect (OSTI)

    Singh, Priya; Sarkar, Subir K.; Bandyopadhyay, Pradipta

    2014-07-07

    We present the results of a high-statistics equilibrium study of the folding/unfolding transition for the 20-residue mini-protein Trp-cage (TC5b) in water. The ECEPP/3 force field is used and the interaction with water is treated by a solvent-accessible surface area method. A Wang-Landau type simulation is used to calculate the density of states and the conditional probabilities for the various values of the radius of gyration and the number of native contacts at fixed values of energyalong with a systematic check on their convergence. All thermodynamic quantities of interest are calculated from this information. The folding-unfolding transition corresponds to a peak in the temperature dependence of the computed specific heat. This is corroborated further by the structural signatures of folding in the distributions for radius of gyration and the number of native contacts as a function of temperature. The potentials of mean force are also calculated for these variables, both separately and jointly. A local free energy minimum, in addition to the global minimum, is found in a temperature range substantially below the folding temperature. The free energy at this second minimum is approximately 5?k{sub B}T higher than the value at the global minimum.

  9. TC_CLOUD_REGIME.cdr

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    intensity (e.g. May and Ballinger, 2007) Resulting Cloud Properties Examine rain DSD using polarimetric radar Examine ice cloud properties using MMCR and MPL Expect...

  10. TU-F-12A-04: Differential Radiation Avoidance of Functional Liver Regions Defined by 99mTc-Sulfur Colloid SPECT/CT with Proton Therapy

    SciTech Connect (OSTI)

    Bowen, S; Miyaoka, R; Kinahan, P; Sandison, G; Vesselle, H; Nyflot, M; Apisarnthanarax, S; Saini, J; Wong, T

    2014-06-15

    Purpose: Radiotherapy for hepatocellular carcinoma patients is conventionally planned without consideration of spatial heterogeneity in hepatic function, which may increase risk of radiation-induced liver disease. Pencil beam scanning (PBS) proton radiotherapy (pRT) plans were generated to differentially decrease dose to functional liver volumes (FLV) defined on [{sup 99m}Tc]sulfur colloid (SC) SPECT/CT images (functional avoidance plans) and compared against conventional pRT plans. Methods: Three HCC patients underwent SC SPECT/CT scans for pRT planning acquired 15 min post injection over 24 min. Images were reconstructed with OSEM following scatter, collimator, and exhale CT attenuation correction. Functional liver volumes (FLV) were defined by liver:spleen uptake ratio thresholds (43% to 90% maximum). Planning objectives to FLV were based on mean SC SPECT uptake ratio relative to GTV-subtracted liver and inversely scaled to mean liver dose of 20 Gy. PTV target coverage (V{sub 95}) was matched between conventional and functional avoidance plans. PBS pRT plans were optimized in RayStation for single field uniform dose (SFUD) and systematically perturbed to verify robustness to uncertainty in range, setup, and motion. Relative differences in FLV DVH and target dose heterogeneity (D{sub 2}-D{sub 98})/D50 were assessed. Results: For similar liver dose between functional avoidance and conventional PBS pRT plans (D{sub mean}?5% difference, V{sub 18Gy}?1% difference), dose to functional liver volumes were lower in avoidance plans but varied in magnitude across patients (FLV{sub 70%max} D{sub mean}?26% difference, V{sub 18Gy}?8% difference). Higher PTV dose heterogeneity in avoidance plans was associated with lower functional liver dose, particularly for the largest lesion [(D{sub 2}-D{sub 98})/D{sub 50}=13%, FLV{sub 90%max}=50% difference]. Conclusion: Differential avoidance of functional liver regions defined on sulfur colloid SPECT/CT is feasible with proton therapy

  11. {sup 99m}Tc generators for clinical use based on zirconium molybdate gel and (n, gamma) produced {sup 99}Mo: Indian experience in the development and deployment of indigenous technology and processing facilities

    SciTech Connect (OSTI)

    Saraswathy, P.; Dey, A.C.; Sarkar, S.K.; Kothalkar, C.; Naskar, P.; Arjun, G.; Arora, S.S.; Kohli, A.K.; Meera, V.; Venugopal, V.; Ramamoorthy, N.

    2008-07-15

    The Indian pursuit of gel generator technology for {sup 99m}Tc was driven mainly by three considerations, namely, (i) well-established and ease of reliable production of (n, gamma)-based {sup 99}Mo in several tens of GBq quantities in the research reactors in Trombay/Mumbai, India, (ii) need for relatively low-cost alternate technology to replace the solvent (MEK) extraction generator system in use in India since 1970s and (iii) minimize dependency on weekly import of fission-produced {sup 99}Mo raw material required for alumina column generator. Extensive investigations on process standardisation for zirconium molybdate gel (ZMG) led to a steady progress, achieved both in terms of process technology and final performance of {sup 99m}Tc gel generators. The {sup 99m}Tc final product purity from the Indian gel system was comparable to that obtained from the gold-standard alumina column generators. Based on the feasibility established for reliable small-scale production, as well as satisfactory clinical experience with a number of gel generators used in collaborating hospital radiopharmacies, full-fledged mechanised processing facilities for handling up to 150 g of ZMG were set up. The indigenous design and development included setting up of shielded plant facilities with pneumatic-driven as well as manual controls and special gadgets such as, microwave heating of the zirconium molybdate cake, dispenser for gel granules, loading of gel columns into pre-assembled generator housing etc. Formal review of the safety features was carried out by the regulatory body and stage-wise clearance for processing low and medium level {sup 99}Mo activity was granted. Starting from around 70 GBq {sup 99}Mo handling, the processing facilities have since been successfully operated at a level of 740 GBq {sup 99}Mo, twice a month. In all 18 batches of gel have been processed and 156 generators produced. The individual generator capacity was 15 to 30 GBq with an elution yield of nearly 75

  12. Systematic investigation of electronic structure in BEDT-TTF based organic superconductors with Tc above 10 K; [kappa]-(BEDT-TTF)[sub 2]X (X = Cu(NCS)[sub 2], Cu[N(CN)[sub 2

    SciTech Connect (OSTI)

    Nakamura, Toshikazu; Nobutoki, Tomoko; Miyamoto, Masao; Tsubokura, Yuichi; Tsuchiya, Ryota; Takahashi, Toshihiro ); Kanoda, Kazushi ); Saito, Gunzi )

    1994-06-01

    The electronic structure of the title superconductors has been investigated by electrical resistivity, complex susceptibility, and electron paramagnetic resonance (EPR) measurements. The superconducting properties (pressure dependence of Tc, magnetic penetration depth, upper critical field, and so on) of these three salts are similar to each other, while transport properties in the normal state have shown a large variety in the temperature dependence. In order to clarify the electronic structure in the normal state, the EPR parameters, the spin susceptibility ([Chi][sub spin]), and the linewidth ([Delta]H[sub pp]), are compared. An anomalous temperature dependence of the g-value has been observed below 150 K in the Cu(NCS)[sub 2] and Cu(CN)[N(CN)[sub 2

  13. Electromagnetic behavior of high-{Tc} superconductors

    SciTech Connect (OSTI)

    Ma, J.G.; Wolff, I.

    1996-05-01

    Using a new proposed model, the electromagnetic behavior of high-temperature superconductors (HTSs) is discussed. It indicates that the real part of the complex conductivity of HTSs is dependent on the driving frequency, and the simulated results agree well with measured data in literature. Nonlinear surface resistances dependence on an external magnetic field are also simulated and compared with experimental results.

  14. TC&WM EIS Scoping

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    information, please call the Tank Closure & Waste Management EIS Info Line at 888-829-6347 A Citizen's Guide Background A January 9, 2006, legal settlement requires USDOE to prepare the Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington. USDOE intends for the EIS to provide a comprehensive and integrated look at near-term waste management and tank waste cleanup actions at Hanford. What are the key points of the settlement? * Expand the

  15. Rapid formation of the Bi{sub 2{minus}x}Pb{sub x}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub y} high {Tc}-phase, using spray-dried nitrate precursor powders

    SciTech Connect (OSTI)

    Van Driessche, I.; Mouton, R.; Hoste, S.

    1996-08-01

    This study describes the use of spray-dried nitrate precursor powders in the synthesis of Bi-2223 high {Tc}-superconductors. The decomposition of the precursor powder is studied using TGA/DTA, XRD, IR, and nitrogen analyses. The particle size is determined using SEM. The low decomposition temperature of the nitrates ({approximately}600 C) and the small particle size of the spray dried powder ({approximately}3{center_dot}10{sup {minus}6} m), resulting in a lowering of the calcination temperature and a shortening of the sinter time, enabled the authors to synthesize a > 96% pure Bi-2223 phase (from XRD peak intensities) after a thermal process of 5h at 650 C and 60 h at 855 C.

  16. Response of High-Tc Superconductor Metamaterials to High Intensity...

    Office of Scientific and Technical Information (OSTI)

    2 ; Singh, Ranjan 1 ; Yan, Li 3 ; Jia, Quanxi 1 ; Trugman, Stuart A. 1 ; Taylor, Antoinette J. 1 ; Nelson, Keith A. 2 ; Chen, Hou-Tong 1 + Show Author ...

  17. Response of High-Tc Superconductor Metamaterials to High Intensity...

    Office of Scientific and Technical Information (OSTI)

    Hao 3 ; Xiong, Jie 3 ; Yan, Li 3 ; Jia, Quanxi 1 ; Trugman, Stuart A. 1 ; Taylor, Antoinette J. 1 ; Nelson, Keith A. 2 ; Chen, Houtong 1 + Show Author ...

  18. High Temperature Irradiation Resistant Thermocouple (HTIR-TC)

    ScienceCinema (OSTI)

    None

    2013-05-28

    INL researchers have created a new thermocouple that can resist high temperature and radiation. This device will improve safety and reduce costs associated with unit failures. Learn more about INL research at http://www.facebook.com/idahonationallaboratory

  19. High Tc YBCO superconductor deposited on biaxially textured Ni substrate

    DOE Patents [OSTI]

    Budai, John D.; Christen, David K.; Goyal, Amit; He, Qing; Kroeger, Donald M.; Lee, Dominic F.; List, III, Frederick A.; Norton, David P.; Paranthaman, Mariappan; Sales, Brian C.; Specht, Eliot D.

    1999-01-01

    A superconducting article includes a biaxially-textured Ni substrate, and epitaxial buffer layers of Pd (optional), CeO.sub.2 and YSZ, and a top layer of in-plane aligned, c-axis oriented YBCO having a critical current density (J.sub.c) in the range of at least 100,000 A/cm.sup.2 at 77 K.

  20. Melt-spin processing of high {Tc} oxide superconductors

    SciTech Connect (OSTI)

    Folkerts, T.J.; Wu, Hengning; Yoo, S.I.; Merkle, B.D.; Arrasmith, S.R.; Dennis, K.W.; Kramer, M.J.; McCallum, R.W.

    1993-10-01

    Containerless techniques offer distinct advantages for the melt processing of oxide superconductors. The majority of these materials form liquids which are highly reactive with standard crucible materials such as Al{sub 2}O{sub 3} and Pt, resulting in non-negligible contamination. We have developed a containerless melt-spin processing technique where in 50--400 {mu}m particles of REBa{sub 2}Cu{sub 3}O{sub 7-x} high temperature oxide superconductors are melted in free fall through a vertical tube furnace and quenched onto a copper wheel. Previously this method has been successful in producing glasses of NdBa{sub 2}Cu{sub 3}O{sub 7-x} and GdBa{sub 2}Cu{sub 3}O{sub 7-x}. In this report we discuss the results for both stoichiometric and non-stoichiometric YBa{sub 2}Cu{sub 3}O{sub 7-x} (Y123). Thermal, microstructural, and superconducting characterization of both the as-quenched and the annealed materials will be presented.

  1. High Temperature Irradiation Resistant Thermocouple (HTIR-TC)

    SciTech Connect (OSTI)

    2011-01-01

    INL researchers have created a new thermocouple that can resist high temperature and radiation. This device will improve safety and reduce costs associated with unit failures. Learn more about INL research at http://www.facebook.com/idahonationallaboratory

  2. Response of High-Tc Superconductor Metamaterials to High Intensity...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Conference: PECS-X: 10th International Symposium on Photonic and Electromagnetic Crystal Structures ; 2012-06-03 - 2012-06-08 ; Santa Fe, New Mexico, United ...

  3. LD Vehicles AFDC 11 25 13 TC.xlsx

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Model Year 2014: Alternative Fuel and Advanced Technology Vehicles 1 (Updated 11252013) MY FuelPowertrain Type Make Model Vehicle Type Engine SizeCylinders Transmission...

  4. Tc with AsqTad and p4rhmc

    SciTech Connect (OSTI)

    Soltz, R; Vranas, P; Gupta, R

    2007-06-20

    We present the ongoing analysis of Lattice Quantum Chromodynamics runs on the LLNL BG/L supercomputer. This installment includes the analysis of 12,000 trajectories from the MILC AsqTad code on a 32{sup 3} x 8 lattice and the time histories from the plaquette and {psi} - bar{psi} trajectories from the p4rhmc code.

  5. Universal Charge Order in the High-Tc Superconductors | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such as heavy-fermion materials and copper-oxide based superconductors, by the use ... (BCS) theory of superconductivity are obtained in some copper-oxide (cuprate) materials. ...

  6. Pseudogaps, Polarons, and the Mystery of High-Tc Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such an explanation would not only answer a foundational question in modern solid-state physics, but it could provide more precise hints on where to search for the elusive...

  7. Bounding the Pseudogap in Cuprate High-TC Superconductors (Technical...

    Office of Scientific and Technical Information (OSTI)

    A paper copy of this document is also available for sale to the public from the National Technical Information Service, Springfield, VA at www.ntis.gov. Authors: McDonald, Ross ...

  8. Strength and flexibility of bulk high-{Tc} superconductors

    SciTech Connect (OSTI)

    Goretta, K.C.; Jiang, M.; Kupperman, D.S.; Lanagan, M.T.; Singh, J.P.; Vasanthamohan, N.; Hinks, D.G.; Mitchell, J.F.; Richardson, J.W. Jr.

    1996-08-01

    Strength, fracture toughness, and elastic modulus data have been gathered for bulk high-temperature superconductors, commercial 99.9% Ag, and a 1.2 at.% Mg/Ag alloy. These data have been used to calculate fracture strains for bulk conductors. The calculations indicate that the superconducting cores of clad tapes should begin to fracture at strains below 0.2%. In addition, residual strains in Ag-clad (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} tapes have been measured by neutron diffraction. An explanation is offered for why many tapes appear to be able to tolerate large strains before exhibiting a reduction in current transport.

  9. Response of High-Tc Superconductor Metamaterials to High Intensity...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: AC52-06NA25396 Resource Type: Conference Resource Relation: Conference: SPIE Optics+Photonics ; 2012-08-12 - 2012-08-16 ; San Diego, California, United States ...

  10. TC&WM EIS doc.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  11. Response of High-Tc Superconductor Metamaterials to High Intensity...

    Office of Scientific and Technical Information (OSTI)

    Laboratory (LANL) LDRD United States 2012-08-13 English Conference Conference: SPIE Optics+Photonics ; 2012-08-12 - 2012-08-16 ; San Diego, California, United States Medium: ED...

  12. EPRI-TC-80-907-23 DISCLAIMER

    Office of Scientific and Technical Information (OSTI)

    ... water almost six times as much heat would have to be disposed of as would be required in a coal or oil fired plant of the same size operating at high temperature and pressure. ...

  13. DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An exhaust fan provides ventilation by drawing in tempered outside air through a 100-foot "earth tube" buried 2-feet underground. DOEZEHTCLegendCedarwood09-20-14.pdf (1.41 MB) ...

  14. DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham, WA

    Broader source: Energy.gov [DOE]

    Case study of a DOE Zero Energy Ready home in Bellingham, WA, that achieves HERS 43 without PV or HERS 13 with 3.2 kW of PV.

  15. DOE Zero Energy Ready Home Case Study: TC Legend, Seattle, WA, Custom Home

    Broader source: Energy.gov [DOE]

    Case study of a DOE Zero Energy Ready Home in Seattle, WA, that scored HERS 37 without PV, HERS -1 with PV. This 1,915-square-foot custom home has SIP walls and roof, R-20 XPS under the slab, triple-pane windows, an air to water heat pump for radiant heat, and balanced ventilation with timer-controlled fans to bring in and exhaust air.

  16. DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham Power House, Bellingham, WA

    Broader source: Energy.gov [DOE]

    Case study of a DOE 2015 Housing Innovation Award winning custom home in the marine climate that got HERS 34 without PV or HERS -12 with PV, with 6” SIP walls and 10” SIP roof; R-28 ICF around slab, R-20 rigid foam under slab; radiant floor heat and passive design; air-to-water heat pump COP 4.4; HRV; earth tube ventilation; triple-pane windows, 100% LED.

  17. HAB_Ecology_Letter_on_Draft_TC-WM-EIS043010.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  18. WP-96/TR-96 & TC-96 Power and Transmission Rate Case (rates/ratecases...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Decision (WP-96 ROD) Final Studies And Documentation (WP-96-FS) Loads and Resources Revenue Requirement Segmentation Marginal Cost Analysis Wholesale Power Rate Development...

  19. Phonon characteristics of high {Tc} superconductors from neutron Doppler broadening measurements

    SciTech Connect (OSTI)

    Trela, W.J.; Kwei, G.H.; Lynn, J.E.; Meggers, K.

    1994-12-01

    Statistical information on the phonon frequency spectrum of materials can be measured by neutron transmission techniques if they contain nuclei with low energy resonances, narrow enough to be Doppler-broadened, in their neutron cross sections. The authors have carried out some measurements using this technique for materials of the lanthanum barium cuprate class, La{sub 2{minus}x}Ba{sub x}CuO{sub 4}. Two samples with slightly different concentrations of oxygen, one being superconductive, the other not, were examined. Pure lanthanum cuprate was also measured. Lanthanum, barium and copper all have relatively low energy narrow resonances. Thus it should be possible to detect differences in the phonons carried by different kinds of atom in the lattice. Neutron cross section measurements have been made with high energy resolution and statistical precision on the 59m flight path of LANSCE, the pulsed spallation neutron source at Los Alamos National Laboratory. Measurements on all three materials were made over a range of temperatures from 15K to 300K, with small steps through the critical temperature region near 27K. No significant changes in the mean phonon energy of the lanthanum atoms were observed near the critical temperature of the super-conducting material. It appears however that the mean phonon energy of lanthanum in the superconductor is considerably higher than that in the non-superconductors. The samples used in this series of experiments were too thin in barium and copper to determine anything significant about their phonon spectra.

  20. Materials Data on Tc2O7 (SG:61) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. Compensated electron and hole pickets in an underdoped high Tc superconductor

    SciTech Connect (OSTI)

    Harrison, Neil; Altarawneh, Moaz M; Mielke, Charles H; Sebastian, Suchitra E; Goddard, P A; Liang, Ruixing; Bonn, D A; Hardy, W N; Andersen, O K; Lonzarich, G G

    2010-01-01

    Important to the question of high temperature superconductivity is whether bound fermionic pairs with zero or finite momentum - exhibiting bosonic physics - are involved. Here we use angle-dependent magnetic quantum oscillation measurements in underdoped YBa{sub 2}Cu{sub 3}O{sub 6+x} to reveal two significantly differently corrugated small sections of Fermi surface, identifying them as comprising opposite carriers located at different locations of the Brillouin zone. The surprising finding that these disproportionately heavy small pockets are equal in size indicates they are prone to a finite momentum excitonic insulator instability. We discuss the possibility that reducing the doping drives YBa{sub 2}Cu{sub 3}O{sub 6+x} closer to an instability of this nature, its ultimate realization occuring at the metal-insulator quantum critical point, accompanied by a potential enhancement of superconducting transition temperatures.

  2. Shielded high-TC BSCCO tapes or wires for high field applications

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Lelovic, Milan; Eror, Nicholas G.

    2001-01-01

    A composite superconductor having an interior component of multiple filaments of superconducting Bi-2223 sheathed in a Ag or Ag alloy material, and a RE, TI or Hg based superconductor surrounding the interior component.

  3. Shielded high-Tc bscco tapes or wires for high field applications

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Lelovic, Milan; Eror, Nicholas G.

    2002-01-01

    A composite superconductor having an interior component of multiple filaments of superconducting Bi-2223 sheathed in a Ag or Ag alloy material, and a RE, TI or Hg based superconductor surrounding the interior component.

  4. DOE Tour of Zero: The Montlake Modern by TC Legend Homes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 of 17 The home is equipped with a high-capture filtered fresh-air intake for passive makeup air; the air intake has a fan that is electronically controlled to operate when the...

  5. Irradiation response of commercial, high-Tc superconducting tapes: Electromagnetic transport properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gapud, A. A.; Greenwood, N. T.; Alexander, J. A.; Khan, A.; Leonard, K. J.; Aytug, T.; List III, F. A.; Rupich, M. W.; Zhang, Y.

    2015-07-01

    Effects of low dose irradiation on the electrical transport current properties of commercially available high-temperature superconducting, coated-conductor tapes were investigated, in view of potential applications in the irradiative environment of fusion reactors. Three different tapes, each with unique as-grown flux-pinning structures, were irradiated with Au and Ni ions at energies that provide a range of damage effects, with accumulated damage levels near that expected for conductors in a fusion reactor environment. Measurements using transport current determined the pre- and post-irradiation resistivity, critical current density, and pinning force density, yielding critical temperatures, irreversibility lines, and inferred vortex creep rates. Results showmore » that at the irradiation damage levels tested, any detriment to as-grown pre-irradiation properties is modest; indeed in one case already-superior pinning forces are enhanced, leading to higher critical currents.« less

  6. Intra-unit-cell Electronic Nematicity of the High-Tc Copper-oxide Pseudogap States

    SciTech Connect (OSTI)

    Davis, J.C.; Lawler, M.J.; Fujita, K.; Lee, J.; Schmidt, A.R.; Kohsaka, Y.; Kim, C.K.; Eisaki, H.; Uchida, S.; Sethna, J.P.; Kim, E.-A.

    2010-07-15

    In the high-transition-temperature (high-T{sub c}) superconductors the pseudogap phase becomes predominant when the density of doped holes is reduced. Within this phase it has been unclear which electronic symmetries (if any) are broken, what the identity of any associated order parameter might be, and which microscopic electronic degrees of freedom are active. Here we report the determination of a quantitative order parameter representing intra-unit-cell nematicity: the breaking of rotational symmetry by the electronic structure within each CuO{sub 2} unit cell. We analyse spectroscopic-imaging scanning tunnelling microscope images of the intra-unit-cell states in underdoped Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}} and, using two independent evaluation techniques, find evidence for electronic nematicity of the states close to the pseudogap energy. Moreover, we demonstrate directly that these phenomena arise from electronic differences at the two oxygen sites within each unit cell. If the characteristics of the pseudogap seen here and by other techniques all have the same microscopic origin, this phase involves weak magnetic states at the O sites that break 90{sup o}-rotational symmetry within every CuO{sub 2} unit cell.

  7. Materials Data on U2Si5Tc3 (SG:128) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-03-07

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. DOE Zero Energy Ready Home Case Study: TC Legend Homes — Cedarwood, Bellingham, WA

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This house was the Grand Winner in the Affordable Builder category of the 2014 Housing Innovation Awards, and has 6-inch SIP walls, a 10-inch structural insulated panel roof, and insulating concrete forms foundation walls with R-20 high-density rigid EPS foam under the slab.A single ductless heat pump heats and cools the home, which also gets passive solar heating from south-facing triple-pane windows that heat a concrete slab floor plus a connected greenhouse.

  9. DOE Zero Energy Ready Home Case Study: TC Legend Homes, Seattle, Washington

    SciTech Connect (OSTI)

    none,

    2013-09-01

    This house incorporates slab-on-grade, EPS roof, and radiant heating with an air-to-water heat pump that also preheats domestic hot water. Without counting in the solar panels, the home earns a home energy rating system (HERS) score of 37, with projected utility bills of about $740 a year. With the 6.4-kW photovoltaic power system installed on the roof, the home’s HERS scores drops to -1 and utility bills for the all-electric home drop to zero. This home was awarded a 2013 Housing Innovation Award in the affordable builder category.

  10. Reactive nanophase oxide additions to melt-processed high-{Tc} superconductors

    SciTech Connect (OSTI)

    Goretta, K.C.; Brandel, B.P.; Lanagan, M.T.; Hu, J.; Miller, D.J.; Sengupta, S.; Parker, J.C.; Ali, M.N.; Chen, Nan

    1994-10-01

    Nanophase TiO{sub 2} and Al{sub 2}O{sub 3} powders were synthesized by a vapor-phase process and mechanically mixed with stoichiometric YBa{sub 2}Cu{sub 3}O{sub x} and TlBa{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} powders in 20 mole % concentrations. Pellets produced from powders with and without nanophase oxides were heated in air or O{sub 2} above the peritectic melt temperature and slow-cooled. At 4.2 K, the intragranular critical current density (J{sub c}) increased dramatically with the oxide additions. At 35--50 K, effects of the oxide additions were positive, but less pronounced. At 77 K, the additions decreased J{sub c}, probably because of inducing a depresion of the transition temperature.

  11. Giant flux creep through the surface barriers and the irreversibility line in high-{Tc} superconductors

    SciTech Connect (OSTI)

    Burlachkov, L.; Geshkenbein, V.B. ||; Koshelev, A.E. |; Larkin, A.I. |; Vinokur, V.M.

    1994-05-01

    Magnetic flux relaxation over the surface barrier in high temperature superconductors are investigated Vortex dynamics controlled by the penetration both of pancake vortices and vortex lines are discussed. The penetration field H{sub p} for pancakes decay is exponentially with temperature. The size of the magnetization loop is determined by the decay of H{sub p} during the process of relaxation, but its shape remains unchanged. The irreversibility line associated with the pancake penetration is given by H{sub irr} {proportional_to} exp(- 2T/T{sub o}), and may lie both above and below the melting line.

  12. Irradiation of commercial, high-Tc superconducting tape for potential fusion applications: electromagnetic transport properties

    SciTech Connect (OSTI)

    Aytug, Tolga [ORNL; Gapud, Albert A. [University of South Alabama, Mobile; List III, Frederick Alyious [ORNL; Leonard, Keith J [ORNL; Rupich, Marty [American Superconductor Corporation, Westborough, MA; Zhang, Yanwen [ORNL; Greenwood, N T [University of South Alabama, Mobile; Alexander, J A [University of South Alabama, Mobile; Khan, A [University of South Alabama, Mobile

    2015-01-01

    Effects of low dose irradiation on the electrical transport current properties of commercially available high-temperature superconducting, coated-conductor tapes were investigated, in view of potential applications in the irradiative environment of fusion reactors. Three different tapes, each with unique as-grown flux-pinning structures, were irradiated with Au and Ni ions at energies that provide a range of damage effects, with accumulated damage levels near that expected for conductors in a fusion reactor environment. Measurements using transport current determined the pre- and post-irradiation resistivity, critical current density, and pinning force density, yielding critical temperatures, irreversibility lines, and inferred vortex creep rates. Results show that at the irradiation damage levels tested, any detriment to as-grown pre-irradiation properties is modest; indeed in one case already-superior pinning forces are enhanced, leading to higher critical currents.

  13. High-Risk Components Removed from K-25’s Tc-99 Area

    Broader source: Energy.gov [DOE]

    Oak Ridge's EM program removes one of the highest risk components remaining in K-25 building with the successful crane removal of five components known as NaF traps.

  14. Bearing design for flywheel energy storage using high-TC superconductors

    DOE Patents [OSTI]

    Hull, John R.; Mulcahy, Thomas M.

    2000-01-01

    A high temperature superconductor material bearing system (38) This system (38) includes a rotor (50) having a ring permanent magnet (60), a plurality of permanent magnets (16, 20 and 70) for interacting to generate levitation forces for the system (38). This group of magnets are a push/pull bearing (75). A high temperature superconductor structure (30) interacts with the ting permanent magnet (60) to provide stabilizing forces for the system (38).

  15. Fate of Tc99 at WTP and Current Work on Capture

    Office of Environmental Management (EM)

    as seen at the DOE EM Construction Project Review November 2010 Bechtel National, Inc. Albert A. Kruger, DOE-WED Glass Scientist John Olson, BNI Manager, Process Engineering Design...

  16. Reductive Sequestration Of Pertechnetate (99TcO4-) By Nano Zerovalent...

    Office of Scientific and Technical Information (OSTI)

    Authors: Fan, Dimin ; Anitori, Roberto ; Tebo, Bradley M. ; Tratnyek, Paul G. ; Lezama Pacheco, Juan S. ; Kukkadapu, Ravi K. ; Engelhard, Mark H. ; Bowden, Mark E. ; Kovarik, Libor ...

  17. T-692: VMware vFabric tc Server Lets Remote Users Login Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A remote user can login using an obfuscated version of their password. PLATFORM: ... user can use the password in obfuscated form (or in plain text form) to authenticate. ...

  18. Low-loss, high-speed, high-{Tc} superconducting bearings

    DOE Patents [OSTI]

    Hull, J.R.; Mulcahy, T.M.; Uherka, K.L.

    1997-06-24

    A flywheel energy storage device is disclosed including an iron structure disposed for rotation adjacent a stationary superconductor material structure and a stationary permanent magnet. The stationary permanent magnet levitates the iron structure while the superconductor structure can stabilize the rotating iron structure. 15 figs.

  19. Low-loss, high-speed, high-{Tc} superconducting bearings

    DOE Patents [OSTI]

    Hull, J.R.; Mulcahy, T.M.; Uherka, K.L.

    1996-07-30

    A flywheel energy storage device is disclosed including an iron structure disposed for rotation adjacent a stationary superconductor material structure and a stationary permanent magnet. The stationary permanent magnet levitates the iron structure while the superconductor structure can stabilize and levitate the rotating iron structure. 15 figs.

  20. Materials Data on Co2TcO4 (SG:74) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-05-16

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. DOE Zero Energy Ready Home Case Study 2014: TC Legend Homes, Montlake Modern, Seattle, WA

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Montlake Modern Seattle, WA DOE ZERO ENERGY READY HOME(tm) CASE STUDY The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of excellence and quality specified in DOE's Zero Energy Ready Home program (formerly known as Challenge Home). Every DOE Zero Energy Ready Home starts with ENERGY STAR Certified Homes Version 3.0 for an energy-efficient home built on a solid foundation of building science research. Advanced technologies are designed in to

  2. DOE Zero Ready Home Case Study: TC Legend Homes, Cedarwood, Bellingham, WA

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cedarwood Bellingham, WA DOE ZERO ENERGY READY HOME(tm) The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of excellence and quality specified in DOE's Zero Energy Ready Home program (formerly known as Challenge Home). Every DOE Zero Energy Ready Home starts with ENERGY STAR Certified Homes Version 3.0 for an energy-efficient home built on a solid foundation of building science research. Advanced technologies are designed in to give you

  3. Lessons learned from substation predictive maintenance project, TC project {number_sign}7014. Final report

    SciTech Connect (OSTI)

    Geisecke, J.; Spencer, G.; Richardson, F.

    1998-12-01

    The EPRI Maintenance and Diagnostics Center, through a tailored collaboration effort with 10 utilities, developed a Substation Predictive Maintenance Program (SPDM). The objective of the program was to reduce Operation and Maintenance (O and M) costs by applying predictive/condition based maintenance practices to energized substation equipment. This report presents a summary of the project including: how new and existing diagnostic technologies and equipment were evaluated and utilized; how information was gathered in program cost justification and savings and specific work procedures and program administrative aids for a SPDM process. The program was effective in implementing a preventive or condition based maintenance process for participating utilities--enhancing the prioritization or work, redirecting maintenance activity and reducing costs. This document can serve as an implementation guide with lessons learned for substation predictive maintenance processes or to compare and contrast programs currently in place.

  4. Materials Data on Co2TcO4 (SG:74) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. DOE ZERH Case Study: TC Legend Homes, Bellingham Power House, Bellingham, WA

    SciTech Connect (OSTI)

    none,

    2015-09-01

    Case study of a DOE 2015 Housing Innovation Award winning custom home in the marine climate that got HERS 34 without PV or HERS -12 with PV, with 6” SIP walls and 10” SIP roof; R-28 ICF around slab, R-20 rigid foam under slab; radiant floor heat and passive design; air-to-water heat pump COP 4.4; HRV; earth tube ventilation; triple-pane windows, 100% LED.

  6. Analytical description of the Jc(B) dependence of high Tc superconducting thin films in small perpendicular fields

    SciTech Connect (OSTI)

    Hanisch, Jens; Grilli, Francesco; Holzapfel, Bernhard

    2008-01-01

    The field dependencies of J{sub c} of YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} based high-temperature superconducting thin films are measured in fine steps for B||c in a wide temperature range. It is found that J{sub c}(B) of all samples can be described by a generalization of Kim's critical state model with two additional variables. At very low fields, a plateau of constant J{sub c} is observed, for which two possible reasons are discussed - self-field effects and a strong single-vortex pinning mechanism. Around 1 T we identified a small 'peak' which may be responsible for ultralow experimental {alpha} values in high-quality samples.

  7. Thallium 2223 high Tc superconductor in a silver matrix and its magnetic shielding, hermal cycle and time aging properties

    SciTech Connect (OSTI)

    Fei, X.; He, W.S.; Havenhill, A.

    1994-12-31

    Superconducting Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} (Tl2223) was ground to powder. Mixture with silver powder (0--80% weight) and press to desired shape. After proper annealing, one can get good silver-content Tl2223 bulk superconductor. It is time-stable and has good superconducting property as same as pure Tl2223. It also has better mechanical property and far better thermal cycle property than pure Tl2223.

  8. HIA 2015 DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham Power House, Bellingham, WA

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bellingham Power House Bellingham, WA DOE ZERO ENERGY READY HOME(tm) The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of excellence and quality specified in DOE's Zero Energy Ready Home program (formerly known as Challenge Home). Every DOE Zero Energy Ready Home starts with ENERGY STAR Certified Homes Version 3.0 for an energy-efficient home built on a solid foundation of building science research. Advanced technologies are designed in to

  9. Improvement of magnetic shielding effects: The superposition of a double-magnetic cylinder over a high-Tc superconducting cylinder

    SciTech Connect (OSTI)

    Ohyama, Takashi; Minemoto, Takumi ); Itoh, Mineo ); Hoshino, Kazutomo )

    1993-11-01

    Improvement of magnetic shielding was achieved by superimposing a double-magnetic cylinder over a YBCO (Y-Ba-Cu-0) cylinder. The value of the magnetic shielded field for the superimposed cylinder was 47 times larger than that of the YBCO cylinder. The magnetic shielded field obtained when superimposing a soft iron single-cylinder over a YBCO cylinder was analyzed using the Bean, Wills, and Mager models, with an important criterion being derived for designing an effective shield of the chamber.

  10. Thermodynamic and nonstoichiometric behavior of promising Hi-Tc cuprate systems via EMF measurements : a short review.

    SciTech Connect (OSTI)

    Tetenbaum, M.

    1999-02-24

    Electromotive force (EMF) measurements of oxygen fugacities as a function of stoichiometry have been made on the YBa{sub 2}Cu{sub 3}O{sub x}, GdBa{sub 2}Cu{sub 3}O{sub x}, NdBa{sub 2}Cu{sub 3}O{sub x} and bismuth cuprate systems in the temperature range {approximately}400-750 C by means of an oxygen titration technique with an yttria-stabilized zirconia electrolyte. The shapes of the 400 C isotherms as a function of oxygen stoichiometry for the Gd and Nd cuprate systems suggest the presence of miscibility gaps at values of x that are higher than those in the YBa{sub 2}Cu{sub 3}O{sub x} system. For a given oxygen stoichiometry, oxygen partial pressures above GdBa{sub 2}Cu{sub 3}O{sub x} and NdBa{sub 2}Cu{sub 3}O{sub x} are higher (above x=6.5) than that for the promising YBa{sub 2}Cu{sub 3}O{sub x} system. A thermodynamic assessment and intercomparison of our partial pressure measurements with the results of related measurements will be presented.

  11. “Nodal Gap” induced by the incommensurate diagonal spin density modulation in underdoped high- Tc superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Tao; Gao, Yi; Zhu, Jian -Xin

    2015-03-07

    Recenmore » tly it was revealed that the whole Fermi surface is fully gapped for several families of underdoped cuprates. The existence of the finite energy gap along the d-wave nodal lines (nodal gap) contrasts the common understanding of the d-wave pairing symmetry, which challenges the present theories for the high-Tcsuperconductors. Here we propose that the incommensurate diagonal spin-density-wave order can account for the above experimental observation. The Fermi surface and the local density of states are also studied. Our results are in good agreement with many important experiments in high-Tcsuperconductors.« less

  12. Synthesis of high {Tc} superconducting coatings and patterns by melt writing and oxidation of metallic precursor alloys

    DOE Patents [OSTI]

    Gao, W.; Vander Sande, J.B.

    1998-07-28

    A method is provided for fabrication of superconducting oxides and superconducting oxide composites and for joining superconductors to other materials. A coating of a molten alloy containing the metallic elements of the oxide is applied to a substrate surface and oxidized to form the superconducting oxide. A material can be contacted to the molten alloy which is subsequently oxidized joining the material to the resulting superconducting oxide coating. Substrates of varied composition and shape can be coated or joined by this method. 5 figs.

  13. HYBRID SULFUR ELECTROLYZER DEVELOPMENT, NHI WORK PACKAGE N-SR07TC0301, FY07 FIRST QUARTER REPORT

    SciTech Connect (OSTI)

    Summers, W

    2006-12-20

    The proof of concept of SO2 electrolysis for the hybrid sulfur (HyS) process is the second priority research target of the DOE Nuclear Hydrogen Initiative's thermochemical program for FY07. The proof of concept of the liquid-phase option must be demonstrated at the single cell level for an extended run times (>100 hours). The rate of development of HyS will depend on the identification of a promising membrane or an alternative means for controlling sulfur formation. Once successful long-duration operation has been demonstrated, SRNL will develop a multi-cell stack that can be connected to the H2SO4 decomposer being developed by SNL for the S-I ILS for a Hybrid Sulfur Integrated Laboratory-Scale Experiment during FY 2008. During the first quarter of FY07, SRNL continued the component development and membrane development activities with the goal of identifying and characterizing improved electrodes, electrocatalysts, membranes and MEA configurations which could then be tested at larger scale in the SDE test facility. A modified glass cell was fabricated to allow measurements of sulfur dioxide (SO2) transport across membrane samples at elevated temperatures (up to 70 C). This testing also includes evaluating SO2 transport in different sulfuric acid concentrations (30-70 wt%). A new potentiostat/frequency analyzer was installed for determining ionic conductivity of membranes. This instrument enhances our capabilities to characterize membrane, electrocatalyst and MEA properties and performance. Continuing work from FY06, evaluations were preformed on various commercial and experimental membranes and electrocatalyst materials for the SDE. Several different types of commercially-available membranes were analyzed for sulfur dioxide transport as a function of acid strength including perfluorinated sulfonic acid (PFSA), sulfonated polyetherketone-ketone, and poly-benzimidazole (PBI) membranes. Experimental membranes from the sulfonated diels-alder polyphenylenes (SDAPP) and modified Nafion{reg_sign} 117 were evaluated for SO{sub 2} transport as well. These membranes exhibited reduced transport coefficient for SO{sub 2} transport without the loss in ionic conductivity.

  14. HYBRID SULFUR ELECROLYZER DEVELOPMENT, NHI WORK PACKAGE N-SR07TC0301, FY08 FIRST QUARTER REPORT

    SciTech Connect (OSTI)

    Summers, W

    2007-12-20

    Hydrogen has been identified as a leading candidate to replace petroleum as part of the transition to a sustainable energy system, and major efforts are being conducted worldwide to develop the technologies and supporting activities required for this transition. In the United States, the federal research efforts are led by the U.S. Department of Energy (DOE). The U.S. DOE Hydrogen Program is an integrated inter-office program being conducted by the Office of Energy Efficiency and Renewable Energy, Office of Nuclear Energy (DOE-NE), Office of Fossil Energy and Office of Science. The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. The HyS Process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency and small footprint, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test, and designed and built a larger, multi-cell stack electrolyzer. The proof of concept of SO2 electrolysis for the HyS Process is a priority research target for the FY 2008 NHI Program. Technical options must be better defined and the challenges better understood. The current status of electrolyzer performance must be established by operation at elevated temperature (>90C) and pressure (>10 atmospheres) and during a long duration run (>100 hours). SRNL is pursuing the liquid-phase sulfur dioxide decoupled electrolyzer (SDE) option, which is the main focus of the NHI work. The rate of development of HyS will depend on the identification of a promising membrane or an alternative means for controlling sulfur formation at the cathode of the cell. SRNL will work with Sandia National Laboratory (SNL), universities, and industry to address this issue. Electrolyzers of larger size will be required as the process development proceeds, and SRNL will test a multi-cell stack that was built in FY 2007. Work will be initiated for a Hybrid Sulfur Integrated Laboratory-Scale (ILS) Experiment that will combine a SRNL electrolyzer with the sulfuric acid decomposer developed by SNL for the S-I ILS. A review will be held at mid-year, and if progress warrants, work will progress to the ILS level including ILS system design, electrolyzer fabrication and infrastructure development. Benchmarks to be considered include electrochemical efficiency, membrane durability, and minimization of SO2 crossover.

  15. Spectroscopic Evidence for a High-Spin Br-Fe(IV)-Oxo Intermediate in the -Ketoglutarate-Dependent Halogenase CyTc3 From Streptomyces

    SciTech Connect (OSTI)

    Fujimori, D.Galonic; Barr, E.W.; Matthews, M.L.; Koch, G.M.; Yonce, J.R.; Walsh, C.T.; Bollinger, J.M., Jr.; Krebs, C.; Riggs-Gelasco, P.J.

    2009-06-01

    The complex of the mononuclear non-heme halogenase CytC3 from Streptomyces, Fe(II), {alpha}-ketoglutarate, bromide, and the substrate l-2-aminobutyryl-S-CytC2 reacts with O{sub 2} to form a reaction intermediate. Variable-field, freeze-quench Moessbauer spectroscopy reveals this intermediate to be a mixture of two high-spin Fe(IV) complexes in an approximate 3.7/1 ratio. Freeze-quench Fe K-edge X-ray absorption spectroscopy provides further insight into the structure of this intermediate. A short 1.62-{angstrom} interaction between the Fe and one of its ligands is attributed to the Fe(IV)-oxo group, and a 2.43-{angstrom} interaction is assigned to the Fe-Br interaction. A significantly longer Fe-Br separation (2.53 {angstrom}) is observed in the reactant complex, consistent with lower valency of the Fe in the reactant complex. This intermediate is the first example for a Br-Fe(IV)-oxo complex in a protein and provides evidence for a unifying mechanism for Fe(II) and {alpha}-ketoglutarate-dependent dioxygenases and halogenases.

  16. Preliminary results of Tc-99m Sulfur Colloid (SC) and glucoheptonate (GHP) surveillance of renal allografts (AG) on cyclosporin a (CSA) maintenance

    SciTech Connect (OSTI)

    George, F.A.; Brown, W.W.; Malone, J.D.; Naidu, R.; Carney, K.; Garvin, P.J.

    1985-05-01

    The potential nephro-toxicity of CSA complicates the therapeutic management of AG with unexplained reduced function. Seven living related donor (LRD) and 23 cadaver (C) AG maintained, at least initially, on CSA and low dose prednisone and functioning for at least 2 months were studied during a 10 month period; mean serum creatinine (Scr) was 1.5 mg/dl for LRD and 2.35 mg/dl for C AG recipients. A total of 12 biopsies were performed in 10 recipients (2 LRD, 10 C AG) for unexplained SCr levels above 3.0 mg/dl. SC-GHP surveillance was carried out in each recipient between 4 and 15 times. SC exam was analyzed by temporal quantitation (as previously reported) and GHP exam was evaluated visually for AG perfusion, uptake and excretion of GHP. Biopsies were examined with H and E and immunofluorescent staining. Results were compared to therapeutic outcome, subsequent biopsy or AG nephrectomy. In summary, the comparison of SC-GHP exam and biopsy diagnosis in 12 instances for the differential diagnosis of CSA toxicity versus AR demonstrated correct assessment by the SC-GHP exam 12/12. AG biopsy diagnosis was correct in 8/12 instances.

  17. Stability of U(VI)- and Tc(VII) reducing microbial communities to environmental perturbation: a thermodynamic network model and intermediate-scale experiments

    SciTech Connect (OSTI)

    McKinley, James P.; Liu, Chongxuan; Istok, Jack; Krumholz, Lee

    2006-06-01

    The project is a collaborative task with a larger project headed by Jack Istok at Oregon State University, which is conducted under the same title. The project was conceptualized as follows. A ''geochemical'' model of microbial communities was hypothesized, in which microbes were characterized as mineral species according to the chemical transformations they used for metabolic function. The iron-reducing bacteria, for example, would be represented by the iron reducing chemical reaction, including a specific electron donor, the fraction of the consumed donor used for biomass maintenance or growth, and a free energy for the reaction. The pseudomineral species would then be included in a standard geochemical model, and community succession could be calculated according to the thermodynamically favored microbially mediated reactions under progressive consumption of electron donors and receptors, and evolving geochemical conditions. The project includes relatively minor participation by the University of Oklahoma and Pacific Northwest National Laboratory, with the major component at OSU. The PNNL project was funded to provide assistance to Dr. Istok in formulating the appropriate modeling approach and geochemical constraints on the modeling effort.

  18. Matching field effects at tesla-level magnetic fields in critical current density in high-Tc superconductors containing self-assembled columnar defects

    SciTech Connect (OSTI)

    Sinclair, J.; Zuev, Yuri L; Cantoni, Claudia; Wee, Sung Hun; Varanasi, C. V.; Thompson, James R; Christen, David K

    2012-01-01

    We have investigated the superconductive transport properties of YBa2Cu3O7 films containing self-assembled columnar arrays of second phase SrZrO3 or BaSnO3 precipitates. A matching condition between columnar pinning sites (aligned at or near the c axis) and external magnetic flux, tilted with respect to them, is identified in the critical current JC.H/ data. The results for the material containing SrZrO3-based pins are analyzed within a simple intuitive model. At matching, the critical current is enhanced above the model prediction. In complementary contact-free investigations of BaSnO3-doped material, matching effects are observed over a wide range of temperatures in the field dependence of JC.H/. The deduced matching fields agree reasonably well with the densities of columnar pins directly observed by scanning electron microscopy.

  19. Atomic scale studies of doped-hole distributions, self-organized electronic nano-domains, and electron-boson coupling in high Tc-cuprates

    SciTech Connect (OSTI)

    Davis, James C.

    2014-05-14

    Progress is reported in these areas (titles and abstracts of journal articles produced for the contract): Exotic Density Wave in Underdoped Cuprates; Varying the inter-atomic distances within individual crystal unit-­cells of cuprates; Truncated Momentum Space Electronic Structure of Underdoped Bi2Sr2CaCu2O8+δ; and, Visualizing Phase Fluctuating d-Wave Superconductivity in the Cuprate Pseudogap State.

  20. From Ions to Wires to the Grid: The Transformational Science of LANL Research in High-Tc Superconducting Tapes and Electric Power Applications

    ScienceCinema (OSTI)

    Marken, Ken [Superconductivity Technology Center, Los Alamos, New Mexico, United States

    2010-01-08

    The Department of Energy (DOE) Office of Electricity Delivery and Energy Reliability (OE) has been tasked to lead national efforts to modernize the electric grid, enhance security and reliability of the energy infrastructure, and facilitate recovery from disruptions to energy supplies. LANL has pioneered the development of coated conductors ? high-temperature superconducting (HTS) tapes ? which permit dramatically greater current densities than conventional copper cable, and enable new technologies to secure the national electric grid. Sustained world-class research from concept, demonstration, transfer, and ongoing industrial support has moved this idea from the laboratory to the commercial marketplace.

  1. Commensurate antiferromagnetic excitations as a signature of the pseudogap in the tetragonal high-Tc cuprate HgBa2CuO4+δ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chan, M. K.; Dorow, C. J.; Mangin-Thro, L.; Tang, Y.; Ge, Y.; Veit, M. J.; Yu, G.; Zhao, X.; Christianson, A. D.; Park, J. T.; et al

    2016-03-04

    We report that antiferromagnetic correlations have been argued to be the cause of the d-wave superconductivity and the pseudogap phenomena exhibited by the cuprates. Although the antiferromagnetic response in the pseudogap state has been reported for a number of compounds, there exists no information for structurally simple HgBa2CuO4+δ. We report neutron-scattering results for HgBa2CuO4+δ (superconducting transition temperature Tc≈71 K, pseudogap temperature T*≈305 K) that demonstrate the absence of the two most prominent features of the magnetic excitation spectrum of the cuprates: the X-shaped ‘hourglass’ response and the resonance mode in the superconducting state. Instead, the response is Y-shaped, gapped andmore » significantly enhanced below T*, and hence a prominent signature of the pseudogap state.« less

  2. Notices Disabled, 1401 S. Clark Street, Suite

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... in the Final TC&WM EIS, for FFTF Decommissioning, DOE's preference is for Alternative ... Public Comments on the Final TC&WM EIS DOE received six letters regarding the Final TC&WM ...

  3. Oak Ridge Site Specific Advisory Board Monthly Meeting W W W

    Office of Environmental Management (EM)

    Ecology Corp. SEP - supplemental environmental project STP - site treatment plan SW - surface water SWSA - solid waste storage area Tc - technetium TC - time critical TDEC -...

  4. Browse by Discipline -- E-print Network Subject Pathways: Biotechnolog...

    Office of Scientific and Technical Information (OSTI)

    Yang) - Department of Geological Sciences, University of Texas at Austin Yeh, T.-C. Jim (T.-C. Jim Yeh) - Department of Hydrology and Water Resources, University ...

  5. Memorandum of Understanding Between the United States Department of Energy and the Washington State Department of Ecology for Development of the Hanford Site Tank Closure and Waste Management EIS ("TC&WM EIS")

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) and Washington State Department of Ecology (Ecology) have mutual responsibilities for accomplishing cleanup of the Hanford Site as well as continuing ongoing...

  6. Assessment of the influences of groundwater colloids on the migration of technetium-99 at the Paducah Gaseous Diffusion Plant Site in Paducah, Kentucky

    SciTech Connect (OSTI)

    Gu, B.; McDonald, J.A.; McCarthy, J.F.; Clausen, J.L.

    1994-07-01

    This short report summarizes the influences of groundwater colloids on the migration/transport of {sup 99}Tc at the Paducah Gaseous Diffusion Plant (PGDP) site in Paducah, Kentucky. Limited data suggest that inorganic colloidal materials (e.g., aluminosilicate clay minerals) may not play a significant role in the retention and transport of Tc. Studies by size fractionation reveal that both Tc and natural organic matter (NOM) are largely present in the <3K fraction. The role of NOM on Tc retention and transport is not conclusive on the basis of this study. However, a literature review suggests that Tc is very likely associated with the groundwater organics. The presence of the organic matter could have increased the solubility and cotransport of Tc at the PGDP site. Further studies, applying such techniques as gel chromatography, size exclusion, and spectroscopy, may be useful to determine the association of organic matter with Tc. If Tc is associated with groundwater organics, appropriate protocols for removal of organic matter associated with Tc may be developed. Time and resources were limited so this study is not comprehensive with respect to the role of mobile organic and inorganic colloidal materials on Tc transport in subsurface soils. The redox conditions (DO) of groundwaters reported may not represent the true groundwater conditions, which could have influenced the association and dissociation of Tc with groundwater colloidal materials. Because Tc concentrations in the groundwater (on the order of nCi/L) at the PGDP site is much lower than the solubility of reduced Tc (IV) (on the order of {approximately}10{sup {minus}8} mol/L or parts per billion), regardless of the redox conditions, Tc will stay in solution phase as TC(IV) or Tc(VII). The mechanisms of adsorption/association vs precipitation must be understood under reduced and low Tc conditions so that strategic plans for remediation of Tc contaminated soils and groundwaters can be developed.

  7. Preparation of high specific activity technetium-96

    DOE Patents [OSTI]

    Mausner, Leonard F.; Srivastava, Suresh C.; Prach, Thomas

    1992-01-01

    The present invention relates to a method of producing Tc-96 from the proton irradiation of a rhodium target and a technique for isolating under remote hot cell conditions the Tc-96 from the proton irradiated target.

  8. U.S. DEPARTMENT OF ENERGY BIOENERGY TECHNOLOGIES OFFICE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TC Bio-oil Pathways R&D May 20-24, 2013 Melissa Klembara Technology Manager 2 | Bioenergy ... cases are being developed for TC Bio-oil Pathways to gasoline, diesel, and jet fuel ...

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    CreatorsAuthors contains: "Department of Physics and TcSUH, University of Houston, ... NbCoSb Huang, Lihong ; Department of Physics and TcSUH, University of Houston, ...

  10. Technetium Retention During LAW Vitrification

    Office of Environmental Management (EM)

    (1% I) for LAWE7H (AN-102, high organics) * 18% Tc (22% I) for LAWE3 (AP-101, high K) * Sugar most effective organic reductant for Tc and I retention * 15-20% absolute increase...

  11. HIPed Tailored Ceramic Waste Forms for the Immobilization of...

    Office of Scientific and Technical Information (OSTI)

    Experimental data on the immobilization of Tc in titanate ceramics containing up to 40wt% TcO2 are also be presented. Authors: Melody L. Carter ; Martin W. A. Stewart ; Eric R. ...

  12. DOE Zero Energy Ready Home: Montlake Modern - Seattle, Washington...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Zero Energy Ready Home Case Study: TC Legend Homes, Bellingham Power House, ... Port Hadlock WA DOE Zero Energy Ready Home Case Study: TC Legend, Seattle, WA, Custom Home

  13. Technetium Reduction and Permanent Sequestration by Abiotic and...

    Office of Scientific and Technical Information (OSTI)

    This project aims to provide a fundamental understanding of the feasibility of immobilization of TcO4- as TcSx in the vadose zone or groundwater by application nano zero-valent ...

  14. Technetium Reduction and Permanent Sequestration by Abiotic and...

    Office of Scientific and Technical Information (OSTI)

    The sulfidebacteria-containing system consistently reduced aqueous pertechnetate rapidly ... Preliminary XAS analysis pointed to a mixture of Tc-O and Tc-S binding in the abiotic ...

  15. RAP Meeting Transcribed Flipcharts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on TC & WM EIS Page 1 January * DST AY-102 update (Dirk) o Assumptions communication, lessons learned (PIC) * TC & WM EIS o Were previous HAB comments addressed? Do we need new...

  16. Spinning Chen Zhou1, a), Kewei Sun3, Frederick E. Pinkerton2...

    Office of Scientific and Technical Information (OSTI)

    ... Fig. 3 (a) and (b) show the hard magnetic properties and Tc as a function of Co substitution y. For Co substitution range discussed in this study, Tc has a near linear dependence on Co ...

  17. Tank Closure and Waste Management Environmental Impact Statement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Post Office Box 1178 Richland, WA 99352 Attention: TC & WM EIS Email: TC&WMEIS@saic.com Fax: 1-888-785-2865 Telephone and voicemail: 1-888-829-6347 For general information ...

  18. Notices

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Mary Beth Burandt, NEPA Document Manager, Office of River Protection, U.S. Department of Energy, P.O. Box 1178, Richland, Washington 99352, Email: TC&WMEIS@saic.com. The Final TC & ...

  19. The Geochemistry of Technetium: A Summary of the Behavior of an Artificial Element in the Natural Environment

    SciTech Connect (OSTI)

    Icenhower, Jonathan P.; Qafoku, Nikolla; Martin, Wayne J.; Zachara, John M.

    2008-12-01

    Interest in the chemistry of technetium has only increased since its discovery in 1937, mainly because of the large and growing inventory of 99Tc generated during fission of 235U, its environmental mobility in oxidizing conditions, and its potential radiotoxicity. For every ton of enriched uranium fuel (3% 235U) that is consumed at a typical burn-up rate, nearly 1 kg of 99Tc is generated. Thus, the mass of 99Tc produced since 1993 has nearly quadrupled, and will likely to continue to increase if more emphasis is placed on nuclear power to slow the accumulation of atmospheric greenhouse gases. In order to gain a comprehensive understanding of the interaction of 99Tc and the natural environment, we review the sources of 99Tc in the nuclear fuel cycle, its chemical properties, radiochemistry, and biogeochemical behavior. We include an evaluation of the use of Re as a chemical analog of Tc, as well as a summary of the redox potential, thermodynamics, sorption, colloidal behavior, and interaction of humic substances with Tc, and the potential for re-oxidation and remobilization of Tc(IV). What emerges is a more complicated picture of Tc behavior than that of an easily tractable transition of Tc(VII) to Tc(IV) with consequent immobilization. Reducing conditions (+200 to +100 mV Eh) are generally thought necessary to cause reduction of Tc(VII) to Tc(IV), but far more important are the presence of reducing agents, such as Fe(II) sorbed onto mineral grains. Catalysis of Tc(VII) by surface-mediated Fe(II) will bring the mobile Tc(VII) species to a lower oxidation state and will form the relatively insoluble Tc(IV)O2∙nH2O, but even as a solid, equilibrium concentrations of aqueous Tc are nearly a factor of 20× above the EPA set drinking water standards. However, sequestration of Tc(IV) into Fe(III)-bearing phases, such as goethite or other hydrous oxyhydroxides of iron, may ameliorate concerns over the mobility of Tc. Further, the outcome of many studies on terrestrial and

  20. Model for Energy Supply System Alternatives and their General...

    Open Energy Info (EERE)

    Resource Type: Softwaremodeling tools Website: www-tc.iaea.orgtcwebabouttcstrategyThematicpdfpresentationsener References: Overview of IAEA PESS Models 1 "MESSAGE...

  1. Financial Analysis of Electric Sector Expansion Plans (FINPLAN...

    Open Energy Info (EERE)

    Resource Type: Softwaremodeling tools Website: www-tc.iaea.orgtcwebabouttcstrategyThematicpdfpresentationsener References: Overview of IAEA PESS Models 1 "In...

  2. Magnetic coherence in cuprate superconductors (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Subject: 36 MATERIALS SCIENCE; HIGH-TC SUPERCONDUCTORS; LANTHANUM OXIDES; STRONTIUM OXIDES; COPPER OXIDES; COHERENCE LENGTH; NEUTRON DIFFRACTION; MAGNETIZATION; MAGNETIC ...

  3. Equipment | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Analyzer Hot Vacuum Extraction System Leco CS-444 Carbon/Sulfur Determinator Leco TC-436 Nitrogen/Oxygen Determinator

  4. Spectroscopic Evidence for the Phase Competition between the Pseudogap and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Tc Superconductivity | Stanford Synchrotron Radiation Lightsource Spectroscopic Evidence for the Phase Competition between the Pseudogap and High-Tc Superconductivity Friday, January 30, 2015 Figure 1 Figure 1 (a) Temperature dependence of the ARPES spectra at the antinode of optimally-doped Bi2212. (b) - (d) Singularities at Tc in the spectral weight as a spectroscopic evidence of phase competition. High-transition-temperature (Tc) superconductivity is one of the most intriguing

  5. Estimating Radiation Risk from Total Effective Dose Equivalent...

    National Nuclear Security Administration (NNSA)

    0 Tc 0.37 No. 1Tj 5.25 0 TD 0.098 Tc 0 Tw (No.) Tj 15.755 -13.5 TD 0.3to Tw ( ) Tj 5.25 0 TD F1 10.5 Tf -0.1925 Tc 0 5 Report 0 1Tj 5.25 0 TD 0.098 Tc 0 Tw 8No. 7 0 TD -0.IRRPC,

  6. Tornado Climatology of the Contiguous United States (NURG/CR...

    National Nuclear Security Administration (NNSA)

    0 >76 Tc765 Tf0 Ts0.000 Tc(0) TjETBT3 Tr0.000 0.000 0.000 rg376.800 540.960 Td0.000 Tw100.756 TzF Tc765 Tf0 0 0 0 0 0 0 1...

  7. An investigation of groundwater organics, soil minerals, and activated carbon on the complexation, adsorption, and separation of technetium-99

    SciTech Connect (OSTI)

    Gu, B.; Dowlen, K.E.

    1996-01-01

    This report summarizes studies on the interactions of technetium-99 (Tc) with different organic compounds and soil minerals under both oxidizing and reducing conditions. The report is divided into four parts and includes (1) effect of natural organic matter (NOM) on the complexation and solubility of Tc, (2) complexation between Tc and trichloroethylene (TCE) in aqueous solutions, (3) adsorption of Tc on soil samples from Paducah Gaseous Diffusion Plant (PGDP), and (4) adsorption and separation of Tc on activated carbon. Various experimental techniques were applied to characterize and identify Tc complexation with organic compounds and TCE, including liquid-liquid extraction, membrane filtration, size exclusion, and gel chromatography. Results indicate, within the experimental error, Tc (as pertechnetate, TcO{sub 4}) did not appear to form complexes with groundwater or natural organic matter under both atmospheric and reducing conditions. However, Tc can form complexes with certain organic compounds or specific functional groups such as salicylate. Tc did not appear to form complexes with TCE in aqueous solution.Both liquid-liquid extraction and high performance liquid chromatography (HPLC) gave no indication Tc was complexed with TCE. The correlations between Tc and TCE concentrations in monitoring wells at PGDP may be a coincidence because TCE was commonly used as a decontamination reagent. Once TCE and Tc entered the groundwater, they behaved similarly because both TcO{sub 4}{sup {minus}} and TCE are poorly adsorbed by soils. An effective remediation technique to remove TcO{sub 4}{sup {minus}} from PGDP contaminated groundwater is needed. One possibility is the use of an activated carbon adsorption technique developed in this study.

  8. Evolution of technetium speciation in reducing grout

    SciTech Connect (OSTI)

    Lukens, Wayne W.; Bucher, Jerome J.; Shuh, David K.; Edelstein,Norman M.

    2003-11-24

    Cementitious waste forms (CWFs) are an important component of the strategy to immobilize high-level nuclear waste resulting from plutonium production by the U.S. Department of Energy (DOE). Technetium (99Tc) is an abundant fission product of particular concern in CWFs due to the high solubility and mobility of pertechnetate, TcO4-, the stable form of technetium in aerobic environments. CWFs can more effectively immobilize 99Tc if they contain additives that reduce mobile TcO4- to immobile Tc(IV) species. Leaching of 99Tc from reducing CWFs that contain Tc(IV) is much slower than for CWFs containing TcO4-. Previous X-ray absorption fine structure (XAFS) studies showed that the Tc(IV) species were oxidized to TcO4- in reducing grout samples prepared on a laboratory scale. Whether the oxidizer was atmospheric O2 or NO3- in the waste simulant was not determined. In actual CWFs, rapid oxidation of Tc(IV) by NO3- would be a concern, whereas oxidation by atmospheric O2 would be of less concern due to the slow diffusion and reaction of O2 with the reducing CWF. To address this uncertainty, two series of reducing grouts were prepared using TcO4- containing waste simulants with and without NO3-. In the first series of samples, the TcO4- was completely reduced using Na2S, and the samples were placed in containers that permitted O2 diffusion. In these samples, all of the technetium was initially present as aTc(IV) sulfide compound, TcSx, which was characterized using extended X-ray absorption fine structure (EXAFS) spectroscopy, and is likely Tc2S7. The TcSx initially present in the grout samples was steadily oxidized over 4 years. In the second series of samples, all of the TcO4- was not initially reduced, and the grout samples were placed in airtight containers. In these samples, the remaining TcO4- continued to be reduced as the samples aged, presumably due to the presence of reducing blast furnace slag. When samples in the second series were exposed to atmosphere, the

  9. Investigation of Technetium Redox Cycling in FRC Background Sediments using EXAFS and Gamma Camera Imaging

    SciTech Connect (OSTI)

    Lloyd, J.R.; McBeth, J.M.; Lear, G.; Morris, K.; Burke, I.T.; Livens, F.R.; Ellis, B.; Lawson, R.

    2006-04-05

    Technetium-99 is a priority pollutant at numerous DOE sites, due to its long half-life (2.1 x 105 years), high mobility as Tc(VII) in oxic waters, and bioavailability as a sulfate analogue. {sup 99}Tc is far less mobile under anaerobic conditions, forming insoluble Tc(IV) precipitates. As anaerobic microorganisms can reduce soluble Tc(VII) to insoluble Tc(IV), microbial metabolism may have the potential to treat sediments and waters contaminated with Tc. Baseline studies of fundamental mechanisms of Tc(VII) bioreduction and precipitation (reviewed by Lloyd et al., 2005, in press) have generally used pure cultures of metal-reducing bacteria, in order to develop conceptual models for the biogeochemical cycling of {sup 99}Tc. There is, however, comparatively little known about interactions of metal-reducing bacteria with environmentally relevant trace concentrations of {sup 99}Tc, against a more complex biogeochemical background provided by mixed microbial communities in aquifer sediments. The objective of this project is to probe the site specific biogeochemical conditions that control the mobility of {sup 99}Tc at the US DOE Field Research Center Site (FRC; Oak Ridge, Tennessee). This information is required for the rational design of in situ bioremediation strategies for technetium-contaminated subsurface environments. We are using a combination of geochemical, mineralogical, microbiological and spectroscopic techniques to determine the solubility and phase associations of {sup 99}Tc in FRC sediments, and characterize the underpinning biogeochemical controls.

  10. Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron

    SciTech Connect (OSTI)

    Fan, Dimin; Anitori, Roberto; Tebo, Bradley M.; Tratnyek, P. G.; Lezama Pacheco, Juan S.; Kukkadapu, Ravi K.; Kovarik, Libor; Engelhard, Mark H.; Bowden, Mark E.

    2014-06-02

    The dissolution of Tc(IV) sulfide and concurrent transformation of sulfidated ZVI during 2 oxidation were examined. Kinetic data obtained with 10 mL batch reactors showed that Tc(VII) 3 reduced by sulfidated nZVI has significantly slower reoxidation rates than Tc(VII) reduced by 4 nZVI only. In a 50 mL batch reactor, initial inhibition of Tc(IV) dissolution was apparent and 5 lasted until 120 hours at S/Fe = 0.112, presumably due to the redox buffer capacity of FeS. This 6 is evidenced by the parallel trends in oxidation-reduction potentials (ORP) and Tc dissolution 7 kinetics. M?ssbauer spectra and micro X-ray diffraction of S/Fe = 0.112 suggested the 8 persistence of FeS after 24-h oxidation although X-ray photoelectron spectroscopy indicated 9 substantial surface oxidation. After 120-h oxidation, all characterizations showed complete 10 oxidation of FeS, which further indicates that FeS inhibits Tc oxidation. X-ray absorption 11 spectroscopy for S/Fe = 0.011 showed significantly increasing percentage of TcS2 in the solid 12 phase after 24-h oxidation, indicating TcS2 is more resistant to oxidation than TcO2. At S/Fe = 13 0.112, the XAS results revealed significant transformation of Tc speciation from TcS2 to TcO2 14 after 120-h oxidation at S/Fe = 0.112. Given that no apparent Tc dissolution occurred during this 15 period, the speciation transformation might play a secondary role in hindering Tc oxidation, 16 especially as redox buffer capacity approached depletion.

  11. Comment on "Radiocarbon Calibration Curve Spanning 0 to 50,000 Years B.P. Based on Paired 230Th/234U/238U and 14C Dates on Pristine Corals" by R.G. Fairbanks, R. A. Mortlock, T.-C. Chiu, L. Cao, A. Kaplan, T. P. Guilderson, T. W. Fairbanks, A. L. Bloom, P

    SciTech Connect (OSTI)

    Reimer, P J; Baillie, M L; Bard, E; Beck, J W; Blackwell, P G; Buck, C E; Burr, G S; Edwards, R L; Friedrich, M; Guilderson, T P; Hogg, A G; Hughen, K A; Kromer, B; McCormac, G; Manning, S; Reimer, R W; Southon, J R; Stuiver, M; der Plicht, J v; Weyhenmeyer, C E

    2005-10-02

    Radiocarbon calibration curves are essential for converting radiocarbon dated chronologies to the calendar timescale. Prior to the 1980's numerous differently derived calibration curves based on radiocarbon ages of known age material were in use, resulting in ''apples and oranges'' comparisons between various records (Klein et al., 1982), further complicated by until then unappreciated inter-laboratory variations (International Study Group, 1982). The solution was to produce an internationally-agreed calibration curve based on carefully screened data with updates at 4-6 year intervals (Klein et al., 1982; Stuiver and Reimer, 1986; Stuiver and Reimer, 1993; Stuiver et al., 1998). The IntCal working group has continued this tradition with the active participation of researchers who produced the records that were considered for incorporation into the current, internationally-ratified calibration curves, IntCal04, SHCal04, and Marine04, for Northern Hemisphere terrestrial, Southern Hemisphere terrestrial, and marine samples, respectively (Reimer et al., 2004; Hughen et al., 2004; McCormac et al., 2004). Fairbanks et al. (2005), accompanied by a more technical paper, Chiu et al. (2005), and an introductory comment, Adkins (2005), recently published a ''calibration curve spanning 0-50,000 years''. Fairbanks et al. (2005) and Chiu et al. (2005) have made a significant contribution to the database on which the IntCal04 and Marine04 calibration curves are based. These authors have now taken the further step to derive their own radiocarbon calibration extending to 50,000 cal BP, which they claim is superior to that generated by the IntCal working group. In their papers, these authors are strongly critical of the IntCal calibration efforts for what they claim to be inadequate screening and sample pretreatment methods. While these criticisms may ultimately be helpful in identifying a better set of protocols, we feel that there are also several erroneous and misleading statements made by these authors which require a response by the IntCal working group. Furthermore, we would like to comment on the sample selection criteria, pretreatment methods, and statistical methods utilized by Fairbanks et al. in derivation of their own radiocarbon calibration.

  12. Effects of aqueous-soluble organic compounds on the removal of selected radionuclides from high-level waste part I: Distribution of Sr, Cs, and Tc onto 18 absorbers from an irradiated, organic-containing leachate simulant for Hanford Tank 101-SY

    SciTech Connect (OSTI)

    Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.

    1995-01-01

    Many of the radioactive waste storage tanks at U.S. Department of Energy facilities contain organic compounds that have been degraded by radiolysis and chemical reactions. In this investigation, we measured the effect of some aqueous-soluble organic compounds on the sorption of strontium, cesium, and technetium onto 18 absorbers that offer high sorption of strontium from organic-free solutions. For our test solution we used a leachate from a simulated slurry for Hanford Tank 101-SY that initially contained ethylenediaminetetraacetic acid (EDTA) and then was gamma-irradiated to 34 Mrads. We measured distribution coefficients (Kds) for each element/absorber combination for dynamic contact periods of 30 min, 2 h, and 6 h to obtain information about sorption kinetics. To facilitate comparisons, we include Kd values for these same element/absorber combinations from three organic-free simulant solutions. The Kd values for strontium sorption from the simulant that contained the degraded organics usually decreased by large factors, whereas the Kd values for cesium and technetium sorption were relatively unaffected.

  13. Gas-Phase Treatment of Technetium in the Vadose Zone at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Zhong, Lirong; Qafoku, Nikolla

    2014-09-01

    Technetium-99 (Tc-99) is present in the vadose zone of the Hanford Central Plateau and is a concern with respect to the protection of groundwater. The persistence, limited natural attenuation mechanisms, and geochemical behavior of Tc-99 in oxic vadose zone environments must be considered in developing effective alternatives for remediation. This report describes a new in situ geochemical manipulation technique for decreasing Tc-99 mobility using a combination of geochemical Tc-99 reduction with hydrogen sulfide gas and induced sediment mineral dissolution with ammonia vapor, which create conditions for deposition of stable precipitates that decrease the mobility of Tc-99. Laboratory experiments were conducted to examine changes in Tc-99 mobility in vadose zone sediment samples to evaluate the effectiveness of the treatment under a variety of operational and sediment conditions.

  14. Technetium-99m generator system

    DOE Patents [OSTI]

    Mirzadeh, Saed (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN); Collins, Emory D. (Knoxville, TN)

    1998-01-01

    A .sup.99 Mo/.sup.99m Tc generator system includes a sorbent column loaded with a composition containing .sup.99 Mo. The sorbent column has an effluent end in fluid communication with an anion-exchange column for concentrating .sup.99m Tc eluted from the sorbent column. A method of preparing a concentrated solution of .sup.99m Tc includes the general steps of: a. providing a sorbent column loaded with a composition containing .sup.99 Mo, the sorbent column having an effluent end in fluid communication with an anion-exchange column; b. eluting the sorbent column with a salt solution to elute .sup.99m Tc from the sorbent and to trap and concentrate the eluted .sup.99m Tc on the ion-exchange column; and c. eluting the concentrated .sup.99m Tc from the ion-exchange column with a solution comprising a reductive complexing agent.

  15. Technetium-99m generator system

    DOE Patents [OSTI]

    Mirzadeh, S.; Knapp, F.F. Jr.; Collins, E.D.

    1998-06-30

    A {sup 99}Mo/{sup 99m}Tc generator system includes a sorbent column loaded with a composition containing {sup 99}Mo. The sorbent column has an effluent end in fluid communication with an anion-exchange column for concentrating {sup 99m}Tc eluted from the sorbent column. A method of preparing a concentrated solution of {sup 99m}Tc includes the general steps of: (a) providing a sorbent column loaded with a composition containing {sup 99}Mo, the sorbent column having an effluent end in fluid communication with an anion-exchange column; (b) eluting the sorbent column with a salt solution to elute {sup 99m}Tc from the sorbent and to trap and concentrate the eluted {sup 99m}Tc on the ion-exchange column; and (c) eluting the concentrated {sup 99m}Tc from the ion-exchange column with a solution comprising a reductive complexing agent. 1 fig.

  16. Nuclear Waste Program Quarterly Report July 1, 2003 - September...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ecology's Perspective on the Draft TC & WM EIS Suzanne Dahl Nuclear Waste Program Washington State Department of Ecology Topics Decisions the Draft EIS supports Cooperating ...

  17. Ultrafast charge localization in a stripe-phase nickelate (Journal...

    Office of Scientific and Technical Information (OSTI)

    e.g. fluctuating charge stripes whose role in high-Tc superconductivity is under debate. ... Subject: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS ...

  18. Tank Closure and Waste Management Environmental Impact Statement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 APPENDIX V RECHARGE SENSITIVITY ANALYSIS In the Draft Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (Draft TC & WM...

  19. Microsoft Word - Settlement Agreement - FINAL - 01-06-061.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (DOE) and the Washington State Department of Ecology's ... involving the Hanford Solid Waste EIS. The overarching ... participate in the preparation of the TC&WM EIS as ...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Full Text Available April 2008 Compensated electron and hole pickets in an underdoped high Tc superconductor Harrison, Neil ; Altarawneh, Moaz M ; Mielke, Charles H ; Sebastian, ...

  1. Two-Phase Westward Encroachment of Basin and Range Extension...

    Open Energy Info (EERE)

    Authors Benjamin E. Surpless, Daniel F. Stockli, Trevor A. Dumitru and Elizabeth L. Miller Published Journal Tectonics, 012002 DOI 10.10292000TC001257 Online Internet link for...

  2. Search for: All records | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    ... Evidence for a new excitation at the interface between a high- T c superconductor and a ... high critical-temperature (Tc 85 K) superconductortopological insulator ...

  3. Burkina Faso-IAEA Cooperation | Open Energy Information

    Open Energy Info (EERE)

    Agency Sector Energy Topics Background analysis Website http:www-tc.iaea.orgtcwebt Program Start 2009 Country Burkina Faso Western Africa References IAEA Project...

  4. Mauritania-IAEA Cooperation | Open Energy Information

    Open Energy Info (EERE)

    Agency Sector Energy Topics Background analysis Website http:www-tc.iaea.orgtcwebt Country Mauritania Western Africa References IAEA project database1 IAEA is working...

  5. Sudan-IAEA Cooperation | Open Energy Information

    Open Energy Info (EERE)

    Agency Sector Energy Topics Background analysis Website http:www-tc.iaea.orgtcwebt Program Start 2007 Country Sudan Northern Africa References IAEA project database1...

  6. Nigeria-IAEA Energy Planning | Open Energy Information

    Open Energy Info (EERE)

    Agency Sector Energy Topics Background analysis Website http:www-tc.iaea.orgtcwebt Program Start 2005 Country Nigeria Western Africa References IAEA project database1...

  7. South Africa-IAEA Energy Planning | Open Energy Information

    Open Energy Info (EERE)

    Agency Sector Energy Topics Background analysis Website http:www-tc.iaea.orgtcwebt Country South Africa Southern Africa References IAEA Project Database1 IAEA is working...

  8. Malawi-IAEA Cooperation | Open Energy Information

    Open Energy Info (EERE)

    Agency Sector Energy Topics Background analysis Website http:www-tc.iaea.orgtcwebt Country Malawi Eastern Africa References IAEA project database1 IAEA is working with...

  9. Niger-IAEA Cooperation | Open Energy Information

    Open Energy Info (EERE)

    Agency Sector Energy Topics Background analysis Website http:www-tc.iaea.orgtcwebt Program Start 2007 Country Niger Western Africa References IAEA Project Database1 IAEA...

  10. Double-sided reel-to-reel metal-organic chemical vapor deposition...

    Office of Scientific and Technical Information (OSTI)

    Subject: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; BARIUM OXIDES; CHEMICAL VAPOR DEPOSITION; COPPER OXIDES; CRITICAL CURRENT; HIGH-TC SUPERCONDUCTORS; ...

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (United States) Naval Petroleum and Oil Shale Reserves ... Office of Groundwater and Soil Remediation Office of ... for remediation of Tc-contaminated groundwater whereby ...

  12. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Temperature dependence of the helical half-pitch scattering profile. Top: Heating from room temperature (RT) to the B4-phase critical temperature (TC 142 C). The peak...

  13. Department

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BUSINESS (WOSB) CONCERNS 4. HISTORICALLY BLACK COLLEGES AND UNIVERSITIES (HBCU) AND ... LARGE BUSINESS CONCERNS tc. TOTAL Name: Scott Harrison Whole Dollars Percent 98,430,119 ...

  14. News Archive | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Impact Statement for the Hanford Site, Richland, Washington (Final TC & WM EIS, DOEEIS-0391, December 2012). With regard to those wastes that, in the future,...

  15. EIS-0391: Notice to Extend Scoping Period | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Management Environmental Impact Statement for the Hanford Site, Richland, Washington (TC & WM EIS) and rescheduling the public scoping meetings. PDF icon EIS-0391-NOI-scop-2006....

  16. Highly Selective Colorimetric and Luminescence Response of a...

    Office of Scientific and Technical Information (OSTI)

    The spectroscopic response was highly selective and quantitative for aqueous TcO4- among other competing anions. Complimentary Raman spectroscopy and microscopy techniques, ...

  17. Microsoft Word - finalMOU-4-signature1.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in place for the Tank Closure Environmental Impact Statement (TC-EIS) effective March 25, 2003. ... V. PROCEDURES ECOLOGY Ecology will notify the DOE document manager of any ...

  18. Using magnetic fields to understand high-temperature superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (high-Tc) superconductivity has been the issue as to whether a quantum critical point-a special doping value where quantum fluctuations lead to strong...

  19. Technetium Sorption by Cementitious Materials Under Reducing Conditions

    SciTech Connect (OSTI)

    Kaplan, Daniel I.; Estes, Shanna L.; Powell, Brian A.

    2012-09-28

    The objective of this study was to measure technetium ({sup 99}Tc) sorption to cementitious materials under reducing conditions to simulate Saltstone Disposal Facility conditions. {sup 99}Tc(VII) batch sorption experiments were conducted for 319 days in an inert glovebag with a variety of cementitious materials (aged cement, Vault 2, TR545, and TR547) containing varying amounts of blast furnace slag. Between 154 and 319 days, the {sup 99}Tc aqueous concentrations tended to remain constant and samples amended with different initial {sup 99}Tc concentrations, tended to merge at about 10{sup -9} M for Vault 2 (17% slag) and TR545 (90% slag) and 10{sup -8} M for TR547 (45% slag). This data provided strong evidence that solubility, and not adsorption (K{sub d} values), was controlling aqueous {sup 99}Tc concentrations. Laboratory data superimposed over thermodynamic speciation diagrams further supported the conclusion that solubility, and not adsorption controlled {sup 99}Tc aqueous concentrations. The oxidation state of the aqueous {sup 99}Tc at the end of the sorption experiment was determined by solvent extraction to be almost entirely {sup 99}Tc(VII). The pH of the present system was ~11.8. Previously proposed solubility controlling phases including Tc-sulfides may be present, but do not appear to control solubility. After the 319 day sorption period, the suspensions were removed from the glovebag and a desorption step under oxic conditions was conducted for 20 days by adding oxic, pH-buffered solutions to the suspensions. {sup 99}Tc aqueous concentrations increased by more than an order of magnitude and Eh increased by several hundred millivolts within 24 hours after the introduction of the oxic solutions. These desorption results are consistent with re-oxidation and dissolution/desorption of {sup 99}Tc(IV) phases possibly present in the cementitious materials after the anoxic sorption step of the experiment. Aqueous {sup 99}Tc concentrations continued to increase

  20. DOE/ORO-2467 Cleanup Progress Annual Report

    Broader source: Energy.gov (indexed) [DOE]

    ... to remove flush and fuel salt at MSRE ... could theoretically cause a nuclear criticality to occur. ... the Tc-99 area would have spent weeks cutting out ...

  1. Tank Closure and Waste Management Environmental Impact Statement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford Site, Richland, Washington (Final TC & WM EIS) U.S. Department of Energy (DOE) Foreword DOE appreciates the efforts of the Washington State Department of Ecology (Ecology)...

  2. ALSNews Vol. 326

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Two Phase Transitions Make a High-Temperature Superconductor Three research groups joined forces to show that high- temperature (high-Tc) cuprate superconductors undergo two phase...

  3. Frederic Laquai Seminar: Photocurrent Generation in Low-Bandgap...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... In: G. Gurzadyan, G. Lanzani, C. Soci, T.C. Sum (Ed.): Ultrafast Dynamics in Molecules, Nanostructures and Interfaces, World Scientific - Series in Optics and Photonics - Vol. 8 ...

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (77) copper oxides (73) high-tc superconductors (62) strontium oxides (55) chalcogenides (51) oxides (49) superconductors (48) oxygen compounds (47) alkaline earth ...

  5. Rhenium Solubility in Borosilicate Nuclear Waste Glass: Implications...

    Office of Scientific and Technical Information (OSTI)

    In this context, the present article reports on the solubilityretention of rhenium, a nonradioactive surrogate for 99Tc, in a LAW borosilicate glass. Due to the radioactive nature ...

  6. PowerPoint Presentation

    Office of Environmental Management (EM)

    "moly") * "Molybdenum-99 is the parent isotope of technetium-99m ( 99m Tc) - 99 Mo is ... development and commercialization of the medical radioisotope molybdenum-99 (Mo-99) ...

  7. IAEA-Botswana Cooperation | Open Energy Information

    Open Energy Info (EERE)

    Website http:www-tc.iaea.orgtcwebt Program Start 2009 Country Botswana Southern Africa References IAEA Project Database1 IAEA is working with Botswana on Supporting...

  8. Anomalous Fermi-Surface Dependent Pairing in a Self-DopedHigh...

    Office of Scientific and Technical Information (OSTI)

    mechanism:the van Hove singularity and the antiferromagnetic (pia, pia)scattering. ... Subject: 75; FERMI LEVEL; HIGH-TC SUPERCONDUCTORS; SCATTERING; SHAPE; SINGULARITY; ...

  9. Anomalous Fermi-Surface Dependent Pairing in a Self-Doped High...

    Office of Scientific and Technical Information (OSTI)

    Subject: 36 MATERIALS SCIENCE; FERMI LEVEL; HIGH-TC SUPERCONDUCTORS; VALENCE; BARIUM OXIDES; CALCIUM OXIDES; COPPER OXIDES; BARIUM FLUORIDES; CALCIUM FLUORIDES; COPPER FLUORIDES; ...

  10. Novel Imaging Techniques, Integrated with Mineralogical, Geochemical and Microbiological Characterization to Determine the Biogeochemical Controls....

    SciTech Connect (OSTI)

    Lloyd, Jonathan R.

    2005-06-01

    Tc(VII) will be reduced and precipitated in FRC sediments under anaerobic conditions in batch experiments (progressive microcosms). The complementary microcosm experiments using low pH/nigh nitrate sediments from 3 (near FW 009) are imminent, with the sediment cores already shipped to Manchester. HYPOTHESIS 2. Tc(VII) reduction and precipitation can be visualized in discrete biogeochemical zones in sediment columns using 99mTc and a gamma-camera. Preliminary experiments testing the use of 99mTc as a radiotracer to address hypotheses 2 and 3 have suggested that the 99mTc associates with Fe(II)-bearing sediments in microcosms and stratified columns containing FRC sediments. Initial proof of concept microcosms containing Fe(II)-bearing, microbially-reduced FRC sediments were spiked with 99mTc and imaged using a gamma-camera. In comparison with oxic controls, 99mTc was significantly partitioned in the solid phase in Fe(III)-reducing sediments in batch experiments. Column experiments using FRC background area soil with stratified biogeochemical zones after stimulation of anaerobic processes through nutrient supplementation, suggested that 99mTc transport was retarded through areas of Fe(III) reduction. HYPOTHESIS 3. Sediment-bound reduced 99mTc can be solubilized by perturbations including oxidation coupled to biological nitrate reduction, and mobilization visualized in real-time using a gamma-camera. Significant progress has been made focusing on the impact of nitrate on the biogeochemical behavior of technetium. Additions of 100 mM nitrate to FRC sediment microcosms, which could potentially compete for electrons during metal reduction, inhibited the reduction of both Fe(III) and Tc(VII) completely. Experiments have also addressed the impact of high nitrate concentrations on Fe(II) and Tc(IV) in pre-reduced sediments, showing no significant resolubilization of Tc with the addition of 25 mM nitrate. A parallel set of experiments addressing the impact of aerobic

  11. Technetium radiodiagnostic fatty acids derived from bisamide bisthiol ligands

    DOE Patents [OSTI]

    Jones, Alun G.; Lister-James, John; Davison, Alan

    1988-05-24

    A bisamide-bisthiol ligand containing fatty acid substituted thiol useful for producing Tc-labelled radiodiagnostic imaging agents is described. The ligand forms a complex with the radionuclide .sup.99m Tc suitable for administration as a radiopharmaceutical to obtain images of the heart for diagnosis of myocardial disfunction.

  12. Bisamide bisthiol compounds useful for making technetium radiodiagnostic renal agents

    DOE Patents [OSTI]

    Davison, Alan; Brenner, David; Lister-James, John; Jones, Alun G.

    1987-06-16

    A radiodiagnostic bisamido-bisthio ligand useful for producing Tc-labelled radiodiagnostic renal agents is described. The ligand forms a complex with the radionuclide .sup.99m Tc suitable for administration as a radiopharmaceutical to obtain images of the kidney for diagnosis of kidney disfunction.

  13. Process for the extraction of technetium from uranium

    DOE Patents [OSTI]

    Gong, Cynthia-May S.; Poineau, Frederic; Czerwinski, Kenneth R.

    2010-12-21

    A spent fuel reprocessing method contacts an aqueous solution containing Technetium(V) and uranyl with an acidic solution comprising hydroxylamine hydrochloride or acetohydroxamic acid to reduce Tc(V) to Tc(II, and then extracts the uranyl with an organic phase, leaving technetium(II) in aqueous solution.

  14. Polaron Coherence Condensation in Layered Colossal Resistive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    when the temperature is close to the Curie point, TC 120 K, for LSMO and the critical point, Tc 83 K, for BiSCCO2212. BiSCCO2212 data from D.L. Feng et al., Science 289, 277...

  15. Polymorphism influences singlet fission rates in tetracene thin films

    SciTech Connect (OSTI)

    Arias, Dylan H.; Ryerson, Joseph L.; Cook, Jasper D.; Damrauer, Niels H.; Johnson, Justin C.

    2015-11-06

    Here, we report the effect of crystal structure and crystallite grain size on singlet fission (SF) in polycrystalline tetracene, one of the most widely studied SF and organic semiconductor materials. SF has been comprehensively studied in one polymoprh (Tc I), but not in the other, less stable polymorph (Tc II). Using carefully controlled thermal evaporation deposition conditions and high sensitivity ultrafast transient absorption spectroscopy, we found that for large crystallite size samples, SF in nearly pure Tc II films is significantly faster than SF in Tc I films. We also discovered that crystallite size has a minimal impact on the SF rate in Tc II films, but a significant influence in Tc I films. Large crystallites exhibit SF times of 125 ps and 22 ps in Tc I and Tc II, respectively, whereas small crystallites have SF times of 31 ps and 33 ps. Our results demonstrate first, that attention must be paid to polymorphism in obtaining a self-consistent rate picture for SF in tetracene and second, that control of polymorphism can play a significant role towards achieving a mechanistic understanding of SF in polycrystalline systems. In this latter context we show that conventional theory based on non-covalent tetracene couplings is insufficient, thus highlighting the need for models that capture the delocalized and highly mobile nature of excited states in elucidating the full photophysical picture.

  16. Cobalt Fischer-Tropsch catalysts having improved selectivity

    DOE Patents [OSTI]

    Miller, James G.; Rabo, Jule A.

    1989-01-01

    The promoter(s) Mn oxide or Mn oxide and Zr oxide are added to a cobalt Fischer-Tropsch catalyst combined with the molecular sieve TC-103 or TC-123 such that the resultant catalyst demonstrates improved product selectivity, stability and catalyst life. The improved selectivity is evidenced by lower methane production, higher C5+ yield and increased olefin production.

  17. Polymorphism influences singlet fission rates in tetracene thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Arias, Dylan H.; Ryerson, Joseph L.; Cook, Jasper D.; Damrauer, Niels H.; Johnson, Justin C.

    2015-11-06

    Here, we report the effect of crystal structure and crystallite grain size on singlet fission (SF) in polycrystalline tetracene, one of the most widely studied SF and organic semiconductor materials. SF has been comprehensively studied in one polymoprh (Tc I), but not in the other, less stable polymorph (Tc II). Using carefully controlled thermal evaporation deposition conditions and high sensitivity ultrafast transient absorption spectroscopy, we found that for large crystallite size samples, SF in nearly pure Tc II films is significantly faster than SF in Tc I films. We also discovered that crystallite size has a minimal impact on themore » SF rate in Tc II films, but a significant influence in Tc I films. Large crystallites exhibit SF times of 125 ps and 22 ps in Tc I and Tc II, respectively, whereas small crystallites have SF times of 31 ps and 33 ps. Our results demonstrate first, that attention must be paid to polymorphism in obtaining a self-consistent rate picture for SF in tetracene and second, that control of polymorphism can play a significant role towards achieving a mechanistic understanding of SF in polycrystalline systems. In this latter context we show that conventional theory based on non-covalent tetracene couplings is insufficient, thus highlighting the need for models that capture the delocalized and highly mobile nature of excited states in elucidating the full photophysical picture.« less

  18. Corrosion of Metal Inclusions In Bulk Vitrification Waste Packages

    SciTech Connect (OSTI)

    Bacon, Diana H.; Pierce, Eric M.; Wellman, Dawn M.; Strachan, Denis M.; Josephson, Gary B.

    2006-07-31

    The primary purpose of the work reported here is to analyze the potential effect of the release of technetium (Tc) from metal inclusions in bulk vitrification waste packages once they are placed in the Integrated Disposal Facility (IDF). As part of the strategy for immobilizing waste from the underground tanks at Hanford, selected wastes will be immobilized using bulk vitrification. During analyses of the glass produced in engineering-scale tests, metal inclusions were found in the glass product. This report contains the results from experiments designed to quantify the corrosion rates of metal inclusions found in the glass product from AMEC Test ES-32B and simulations designed to compare the rate of Tc release from the metal inclusions to the release of Tc from glass produced with the bulk vitrification process. In the simulations, the Tc in the metal inclusions was assumed to be released congruently during metal corrosion as soluble TcO4-. The experimental results and modeling calculations show that the metal corrosion rate will, under all conceivable conditions at the IDF, be dominated by the presence of the passivating layer and corrosion products on the metal particles. As a result, the release of Tc from the metal particles at the surfaces of fractures in the glass releases at a rate similar to the Tc present as a soluble salt. The release of the remaining Tc in the metal is controlled by the dissolution of the glass matrix. To summarize, the release of 99Tc from the BV glass within precipitated Fe is directly proportional to the diameter of the Fe particles and to the amount of precipitated Fe. However, the main contribution to the Tc release from the iron particles is over the same time period as the release of the soluble Tc salt. For the base case used in this study (0.48 mass% of 0.5 mm diameter metal particles homogeneously distributed in the BV glass), the release of 99Tc from the metal is approximately the same as the release from 0.3 mass% soluble Tc

  19. Separation of technetium from ruthenium after the accelerator transmutation of technetium

    SciTech Connect (OSTI)

    Abney, K.D.; Schroeder, N.C.; Kinkead, S.A.; Attrep, M. Jr.

    1992-10-01

    Both civilian and defense related waste must be processed with a strategy for dealing with Tc. One solution is to remove the Tc from the waste steam and transmute the Tc to stable Ru in either a reactor or an accelerator. Before any processing of waste streams can be performed (even if transmutation is not performed) the separations chemistry from the spent fuels or the stored wastes containing Tc must be developed. This report details some of the separation schemes possible for the separation of Tc and Ru, which include the baseline ion exchange process of Roberts, Smith and Wheelwright, ozonolysis, filtration, magnetic separation, solvent extraction, electrodeposition, fluorination, and pyrolysis. 5 figs, 4 refs. (DLC)

  20. Speciation of technetium peroxo complexes in sulfuric acid revisited

    SciTech Connect (OSTI)

    Poineau, Frederic; German, Konstantin E.; Burton-Pye, Benjamin P.; Weck, Philippe F.; Kim, Eunja; Kriyzhovets, Olga; Safonov, Aleksey; Ilin, Viktor; Francesconi, Lynn C.; Sattelberger, Alfred P.; Czerwinski, Kenneth R.

    2014-08-24

    We found that the reaction of Tc(+7) with H2O2 has been studied in H2SO4 and the speciation of technetium performed by UV–visible and 99-Tc NMR spectroscopy. UV–visible measurements show that for H2SO4 ≥ 9 M and H2O2 = 0.17 M, TcO3(OH)(H2O)2 reacts immediately and blue solutions are obtained, while no reaction occurs for H2SO4Tc(+7) peroxo species. Furthermore, our studies in 6 M H2SO4TcO4 - begins to react for H2O2 = 2.12 M and red solutions are obtained. The UV–visible spectra of the red species are identical to the one obtained from the reaction of TcO4 - with H2O2 in HNO3 and consistent with the presence of TcO(O2)2(H2O)(OH). The 99-Tc NMR spectrum of the red solution exhibits a broad signal centered at +5.5 ppm vs TcO4 - and is consistent with the presence of a low symmetry Tc(+7) molecule.

  1. Technitium Management at the Hanford Site

    SciTech Connect (OSTI)

    Robbins, Rebecca A.

    2013-08-15

    Long Abstract. Full Text. The Hanford tank waste contains approx 26,000 Ci of technetium-99 (Tc-99), the majority of which is in the supernate fraction. Tc-99 is a long-lived radionuclide with a half-life of approx 212,000 years and, in its predominant pertechnetate (TcO{sub 4}) form, is highly soluble and very mobile in the vadose zone and ultimately the groundwater. Tc-99 is identified as the major dose contributor (in groundwater) by past Hanford site performance assessments and therefore considered a key radionuclide of concern at Hanford. The United States Department of Energy (DOE) River Protection Project's (RPP) long-term Tc-99 management strategy is to immobilize the Tc-99 in a waste form that will retain the Tc-99 for many thousands of years. To achieve this, the RPP flowsheet will immobilize the majority of the Tc-99 as a vitrified low-activity waste product that will be ultimately disposed on site in the Integrated Disposal Facility. The Tc-99 will be released gradually from the glass at very low rates such that the groundwater concentrations at any point in time would be substantially below regulatory limits.The liquid secondary waste will be immobilized in a low-temperature matrix (cast stone) and the solid secondary waste will be stabilized using grout. Although the Tc-99 that is immobilized in glass will meet the release rate for disposal in IDF, a proportion is driven into the secondary waste stream that will not be vitrified and therefore presents a disposal risk. If a portion of the Tc-99 were to be removed from the Hanford waste inventory and disposed off-site, (e.g., as HLW), it could lessen a major constraint on LAW waste form performance, i.e., the requirement to retain Tc-99 over thousands of years and have a positive impact on the IDF Performance Assessment. There are several technologies available at various stages of technical maturity that can be employed for Tc-99 removal. The choice of technology and the associated efficacy of the

  2. Superconductivity in the presence of disorder in skutterudite-related La3Co4Sn13 and La3Ru4Sn13 compounds: Electrical transport and magnetic studies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Slebarski, A.; Maska, M. M.; Fijalkowski, M.; McElroy, C. A.; Maple, M. B.

    2015-06-25

    La3Co4Sn13 and La3Ru4Sn13 were categorized as BCS superconductors. In a plot of the critical field Hc2 vs T, La3Ru4Sn13 displays a second superconducting phase at the higher critical temperature Tc*, characteristic of inhomogeneous superconductors, while La3Co4Sn13 shows bulk superconductivity below Tc. We observe a decrease in critical temperatures with external pressure and magnetic field for both compounds. Additionally, for La3Ru4Sn13 we find that Tc*/dP>dTc/dP. The pressure dependences of Tc are interpreted according to the McMillan theory and understood to be a consequence of lattice stiffening. The investigation of the superconducting state of La3CoxRu4–xSn13 shows a Tc* that is larger thenmore » Tc for x < 4. Furthermore, this unique and unexpected observation is discussed as a result of the local disorder and/or the effect of chemical pressure when Ru atoms are partially replaced by smaller Co atoms.« less

  3. Pressure-induced phase transition in La1–xSmxO0.5F0.5BiS2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, Y.; Yazici, D.; White, B. D.; Maple, M. B.

    2015-09-15

    Electrical resistivity measurements on La1–xSmxO0.5F0.5BiS2 (x = 0.1, 0.3, 0.6, 0.8) have been performed under applied pressures up to 2.6 GPa from 2 K to room temperature. The superconducting transition temperature Tc of each sample significantly increases at a Sm-concentration dependent pressure Pt, indicating a pressure-induced phase transition from a low-Tc to a high-Tc phase. At ambient pressure, Tc increases dramatically from 2.8 K at x = 0.1 to 5.4 K at x = 0.8; however, the Tc values at P > Pt decrease slightly with x and Pt shifts to higher pressures with Sm substitution. In the normal state,more » semiconducting-like behavior is suppressed and metallic conduction is induced with increasing pressure in all of the samples. Furthermore, these results suggest that the pressure dependence of Tc for the BiS2-based superconductors is related to the lattice parameters at ambient pressure and enable us to estimate the evolution of Tc for SmO0.5F0.5BiS2 under pressure.« less

  4. Development of Alternative Technetium Waste Forms

    SciTech Connect (OSTI)

    Czerwinski, Kenneth

    2013-09-13

    The UREX+1 process is under consideration for the separation of transuranic elements from spent nuclear fuel. The first steps of this process extract the fission product technicium-99 ({sup 99}Tc) into an organic phase containing tributylphosphate together with uranium. Treatment of this stream requires the separation of Tc from U and placement into a suitable waste storage form. A potential candidate waste form involves immobilizing the Tc as an alloy with either excess metallic zirconium or stainless steel. Although Tc-Zr alloys seem to be promising waste forms, alternative materials must be investigated. Innovative studies related to the synthesis and behavior of a different class of Tc materials will increase the scientific knowledge related to development of Tc waste forms. These studies will also provide a better understanding of the behavior of {sup 99}Tc in repository conditions. A literature survey has selected promising alternative waste forms for further study: technetium metallic alloys, nitrides, oxides, sulfides, and pertechnetate salts. The goals of this project are to 1) synthesize and structurally characterize relevant technetium materials that may be considered as waste forms, 2) investigate material behavior in solution under different conditions of temperature, electrochemical potential, and radiation, and 3) predict the long-term behavior of these materials.

  5. Speciation of technetium peroxo complexes in sulfuric acid revisited

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Poineau, Frederic; German, Konstantin E.; Burton-Pye, Benjamin P.; Weck, Philippe F.; Kim, Eunja; Kriyzhovets, Olga; Safonov, Aleksey; Ilin, Viktor; Francesconi, Lynn C.; Sattelberger, Alfred P.; et al

    2014-08-24

    We found that the reaction of Tc(+7) with H2O2 has been studied in H2SO4 and the speciation of technetium performed by UV–visible and 99-Tc NMR spectroscopy. UV–visible measurements show that for H2SO4 ≥ 9 M and H2O2 = 0.17 M, TcO3(OH)(H2O)2 reacts immediately and blue solutions are obtained, while no reaction occurs for H2SO42SO44 - begins to react for H2O2 = 2.12 M and red solutions are obtained. The UV–visible spectra of the red species are identical to the one obtained from the reaction of TcO4 - with H2O2 in HNO3 and consistent with the presence of TcO(O2)2(H2O)(OH). The 99-Tcmore » NMR spectrum of the red solution exhibits a broad signal centered at +5.5 ppm vs TcO4 - and is consistent with the presence of a low symmetry Tc(+7) molecule.« less

  6. Production of radionuclide molybdenum 99 in a distributed and in situ fashion

    DOE Patents [OSTI]

    Gentile, Charles A.; Cohen, Adam B.; Ascione, George

    2016-04-19

    A method and apparatus for producing Mo-99 from Mo-100 for the use of the produced Mo-99 in a Tc-99m generator without the use of uranium is presented. Both the method and apparatus employ high energy gamma rays for the transformation of Mo-100 to Mo-99. The high energy gamma rays are produced by exposing a metal target to a moderated neutron output of between 6 MeV and 14 MeV. The resulting Mo-99 spontaneously decays into Tc-99m and can therefore be used in a Tc-99m generator.

  7. PowerPoint Presentation

    Office of Environmental Management (EM)

    SRNL Mo-99 Technical Support for SHINE TM Discussion on Tritiated Waste Disposition Pathways for Commercial Entities Nancy Halverson SRNL Presentation for Tritium Focus Group Meeting Los Alamos, NM November 3, 2015 SRNL-L2100-2015-00098 Background - Molybdenum-99 ( 99 Mo or "moly") * "Molybdenum-99 is the parent isotope of technetium-99m ( 99m Tc) - 99 Mo is loaded into 99m Tc generator and is produced by 99 Mo decay - 99m Tc is extracted (by radiopharmacy staff) for use in

  8. Microsoft PowerPoint - Last MTRG Sheet May 10.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tribal, Stakeholder, and Public - Information Opportunities The U.S. Department of Energy wants to keep you informed on the continued progress with the TC&WM EIS. As the Public Involvement and agency coordination work evolves, it is important to inform you about opportunities to get information on the TC&WM EIS. The Model Technical Review Group (MTRG) is made up of independent experts whom will provide guidance to the TC&WM EIS contractor on the development of the groundwater model.

  9. Microsoft Word - FAQs _English_ 01-22-10 WITH NEW PARAGRAPHS AND EDITS ADDED mk 01-26-10.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Draft Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (Draft TC & WM EIS) (DOE/EIS-0391-D) Frequently Asked Questions What are the U.S. Department of Energy (DOE) proposed actions in the Draft TC & WM EIS? The Draft TC & WM EIS (DOE/EIS-0391-D) evaluates three sets of proposed actions, as follows: * Retrieve and treat the waste remaining in 177 underground storage tanks; store the high-level radioactive waste (HLW); dispose

  10. Current Projects | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Projects In Situ Production of Radionuclide Technetium-99m Researchers at Princeton Plasma Physics Laboratory have developed a new process for the production of Molybdenum 99 (Mo-99), a man made radionuclide which decays (T 1/2 = 66 hours) to Technetium-99m (Tc-99m). Tc-99 m is a radioactive tracer isotope, used in the nuclear medical field for diagnostic imaging, for 2/3 of all diagnostic medical isotope procedures In the United States. Tc-99m has a relatively short half life of 6

  11. Incorporating Technetium in Minerals and Other Solids: A Review

    SciTech Connect (OSTI)

    Luksic, Steven A.; Riley, Brian J.; Schweiger, Michael J.; Hrma, Pavel R.

    2015-08-29

    Technetium (Tc) can be incorporated into a number of different solids including spinel, sodalite, rutile, tin dioxide, pyrochlore, perovskite, goethite, layered double hydroxides, cements, and alloys. Synthetic routes are possible for each of these phases, ranging from high temperature ceramic sintering to ball-milling of constituent oxides. However, in practice, Tc has only been incorporated into solid materials by a limited number of the possible syntheses. Reviewing the diverse ways in which Tc-immobilizing materials can be made shows the range of options available.

  12. Evaluation of Technetium Getters to Improve the Performance of Cast Stone

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla P.; Serne, R. Jeffrey; Lawter, Amanda R.; Stephenson, John R.; Lukens, Wayne W.; Westsik, Joseph H.

    2015-11-01

    Cast Stone has been selected as the preferred waste form for solidification of aqueous secondary liquid effluents from the Hanford Tank Waste Treatment and Immobilization Plant (WTP) process condensates and low-activity waste (LAW) melter off-gas caustic scrubber effluents. Cast Stone is also being evaluated as a supplemental immobilization technology to provide the necessary LAW treatment capacity to complete the Hanford tank waste cleanup mission in a timely and cost effective manner. One of the major radionuclides that Cast Stone has the potential to immobilize is technetium (Tc). The mechanism for immobilization is through the reduction of the highly mobile Tc(VII) species to the less mobile Tc(IV) species by the blast furnace slag (BFS) used in the Cast Stone formulation. Technetium immobilization through this method would be beneficial because Tc is one of the most difficult contaminants to address at the U.S. Department of Energy (DOE) Hanford Site due to its complex chemical behavior in tank waste, limited incorporation in mid- to high-temperature immobilization processes (vitrification, steam reformation, etc.), and high mobility in subsurface environments. In fact, the Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (TC&WM EIS) identifies technetium-99 (99Tc) as one of the radioactive tank waste components contributing the most to the environmental impact associated with the cleanup of the Hanford Site. The TC&WM EIS, along with an earlier supplemental waste-form risk assessment, used a diffusion-limited release model to estimate the release of different contaminants from the WTP process waste forms. In both of these predictive modeling exercises, where effective diffusivities based on grout performance data available at the time, groundwater at the 100-m down-gradient well exceeded the allowable maximum permissible concentrations for 99Tc. (900 pCi/L). Recent relatively

  13. Cast Stone Oxidation Front Evaluation: Preliminary Results For Samples Exposed To Moist Air

    SciTech Connect (OSTI)

    Langton, C. A.; Almond, P. M.

    2013-11-26

    The rate of oxidation is important to the long-term performance of reducing salt waste forms because the solubility of some contaminants, e.g., technetium, is a function of oxidation state. TcO{sub 4}{sup −} in the salt solution is reduced to Tc(IV) and has been shown to react with ingredients in the waste form to precipitate low solubility sulfide and/or oxide phases. Upon exposure to oxygen, the compounds containing Tc(IV) oxidize to the pertechnetate ion, Tc(VII)O{sub 4}{sup −}, which is very soluble. Consequently the rate of technetium oxidation front advancement into a monolith and the technetium leaching profile as a function of depth from an exposed surface are important to waste form performance and ground water concentration predictions. An approach for measuring contaminant oxidation rate (effective contaminant specific oxidation rate) based on leaching of select contaminants of concern is described in this report. In addition, the relationship between reduction capacity and contaminant oxidation is addressed. Chromate (Cr(VI) was used as a non-radioactive surrogate for pertechnetate, Tc(VII), in Cast Stone samples prepared with 5 M Simulant. Cast Stone spiked with pertechnetate was also prepared and tested. Depth discrete subsamples spiked with Cr were cut from Cast Stone exposed to Savannah River Site (SRS) outdoor ambient temperature fluctuations and moist air. Depth discrete subsamples spiked with Tc-99 were cut from Cast Stone exposed to laboratory ambient temperature fluctuations and moist air. Similar conditions are expected to be encountered in the Cast Stone curing container. The leachability of Cr and Tc-99 and the reduction capacities, measured by the Angus-Glasser method, were determined for each subsample as a function of depth from the exposed surface. The results obtained to date were focused on continued method development and are preliminary and apply to the sample composition and curing / exposure conditions described in this report

  14. Technetium Reduction and Permanent Sequestration by Abiotic and Biotic Formation of Low-Solubility Sulfide Mineral Phases

    SciTech Connect (OSTI)

    Tratnyek, Paul G.; Tebo, Bradley M.; Fan, Dimin; Anitori, Roberto; Szecsody, Jim; Jansik, Danielle

    2015-11-14

    One way to minimize the mobility of the TcVII oxyanion pertechnetate (TcO4-) is to effect reduction under sulfidogenic conditions (generated abiotically by Fe0 or biotically) to form TcSx, which is significantly slower to oxidize than TcIVO2. In sediment systems, TcSx and other precipitates may oxidize more slowly due to oxygen diffusion limitations to these low permeability precipitate zones. In addition, the TcO4- reduction rate may be more rapid in the presence of sediment because of additional reductive surface phases. This project aims to provide a fundamental understanding of the feasibility of immobilization of TcO4- as TcSx in the vadose zone or groundwater by application nano zero-valent iron (nZVI), and sulfide or sulfate. Biotic batch experiments have used the sulfate-reducing bacterium (SRB) Desulfotomaculum reducens. The iron sulfide mineral mackinawite was generated under these conditions, while vivianite was formed in nZVI only controls. The sulfide/bacteria-containing system consistently reduced aqueous pertechnetate rapidly (> 95% in the first hour), a rate similar to that for the sulfide-free, nZVI only system. Reduced Tc (aged for 3 months) generated in both SRB/nZVI systems was highly resistant to reoxidation. In reduced samples, Tc was found associated with solid phases containing Fe and S (D. reducens/nZVI) or Fe (nZVI only). Experiments using D. reducens without nZVI provided some additional insights. Firstly, stationary phase cultures were able to slowly reduce pertechnetate. Secondly, addition of pertechnetate at the beginning of cell growth (lag phase) resulted in a faster rate of Tc reduction, possibly indicating a direct (e.g. enzymatic) role for D. reducens in Tc reduction. Abiotic batch experiments were conducted with Na2S as the sulfide source. Pertechnetate reduction was

  15. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Chiang, T.-C. (12) Lin, Hsin (12) Neupane, Madhab (12) Miller, T. (11) Chang, Tay-Rong (10) Jeng, Horng-Tay (10) Zheng, Hao (10) Chang, Guoqing (8) Liu, Chang (8) Sanchez, Daniel ...

  16. From the Woods to the Refinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Woods to the Refinery CORRIM Life Cycle Analyses of Woody Feedstocks Dr. Steve Kelley ... composition, sugar types, residue fuel value * TC models are sensitive to MC, much less ...

  17. Ralph T. Muehleisen | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Meetings on Acoustics, a voting member of several ASTM and ASHRAE Technical Committees, chair to the ASHRAE TC 4.7 Data Driven Modeling subcommittee and the vice-chair of ...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Climate Models: Results from TC4 and ISDAC Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Mishra, S., DOE - SunShot Initiative, AAAS S&T...

  19. Advances in Glass Chemistry - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Structural and Chemical Incorporation of ReO4- and TcO4- in Borosilicate Glasses Submitted for publication the Journal of Raman Spectroscopy Iron phosphate glass for immobilization ...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... HANFORD DOUBLE SHELL TANK THERMAL AND SEISMIC PROJECT SEISMIC ANALYSIS OF HANFORD DOUBLE SHELL TANKS MACKEY TC ; RINKER MW ; CARPENTER BG ; HENDRIX C ; ABATT FG M&D Professional ...

  1. Elliot Mainzer - A

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - TC Aircraft Services Tina Ko, ACTING - TG Transmission Internal Operations E N E R G Y E F F I C I E N C Y Richard Gnec - PE Vice President Allison Mace, ACTING - PEH...

  2. TO: FILE

    Office of Legacy Management (LM)

    v%CEED INVOLVEMENT AT SITE --- ----T----C---... Control VA c Health Physics Protection 0 AECMeD managed operations c Little or None 0 AECMED responsible for c ...

  3. Interfacial Electron-Phonon Coupling as the Cause of Enhanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interfacial Electron-Phonon Coupling as the Cause of Enhanced Tc in Single-layer FeSe Films on SrTiO3 Friday, February 27, 2015 In the past several years, multiple studies have...

  4. Microsoft Word - Agenda for Information Exchange Webinar 6Mar14...

    Broader source: Energy.gov (indexed) [DOE]

    Exchange Webinar Thursday, March 6, 2014 11:00 AM - 1:00 PM EST Call in number: 1-888-677-0837 Passcode: 10542 http:www.mymeetings.comncjoin.php?i742128065&p10312008&tc ...

  5. A. A. Abrikosov Publications at Argonne National Laboratory ...

    Office of Scientific and Technical Information (OSTI)

    "The Dependance of Delta and Tc on Hopping and the Temperature Variation of delta in a Layered Model of HTSC"; Abrikosov, A. A.; Klemm, R. A.; Physica C, 191: 224-36; 1992 "Raman ...

  6. Molecular Foundry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Senior Scientific Engineering Associate, NCEM csong@lbl.gov 510.486.6751 Biography Education B.S. in Materials Science, Zhejiang University, China M.S. in high Tc superconductor ...

  7. T~p~ U.S. Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    we are cognizant of the number of cross-cutting public involvement activities. We look forward to working with the Board to have a meaningful public dialogue on the Draft TC &...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Matching field effects at tesla-level magnetic fields in critical current density in high-Tc superconductors containing self-assembled columnar defects Sinclair, J. ; Zuev, Yuri L ...

  9. Volatility literature of chlorine, iodine, cesium, strontium, technetium, and rhenium; technetium and rhenium volatility testing

    SciTech Connect (OSTI)

    Langowski, M.H.; Darab, J.G.; Smith, P.A.

    1996-03-01

    A literature review pertaining to the volatilization of Sr, Cs, Tc (and its surrogate Re), Cl, I and other related species during the vitrification of Hanford Low Level Waste (LLW) streams has been performed and the relevant information summarized. For many of these species, the chemistry which occurs in solution prior to the waste stream entering the melter is important in dictating their loss at higher temperatures. In addition, the interactive effects between the species being lost was found to be important. A review of the chemistries of Tc and Re was also performed. It was suggested that Re would indeed act as an excellent surrogate for Tc in non-radioactive materials testing. Experimental results on Tc and Re loss from sodium aluminoborosilicate melts of temperatures ranging from 900--1350{degrees}C performed at PNL are reported and confirm that Re behaves in a nearly identical manner to that of technetium.

  10. Washington. DC.20585'

    Office of Legacy Management (LM)

    Alexander Williams at 301-427-1719 of my'staff. . . Enclosures' tc: Ames W: Wagoner II" : Director ' Off-SiteSavannah River Program Division Office of,Eastern Area Programs ...

  11. Final Meeting Summary Page 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... EA (non-TPA event) * Natural Gas Pipeline EIS (early 2014) (non-TPA event) * 2014 ... come up at the SOS meetings. * Statewide Permit (non-TPA event) * NEPA ROD for TC&WM EIS ...

  12. Mr. John E. Kieling, Chief Hazardous Waste Bureau

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Act NMSW New Mexico Special Waste MSW - Municipal Solid Wa:.tc C&D - Construction and ... operating costs devoted to source reduction and recycling of hazardous and mixed wastes. ...

  13. Superconductivity with Stripes | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structure in high-Tc superconductors was manipulated in high-pressure experiments at the APS. The physics of low-temperature superconductivity is fairly well understood, but the...

  14. ATLAS APPROVED EXPERIMENTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8MAY98 Exp Spokesperson Experiment Title Days 433-9 Miller Ion Irradiations of Anisotropic High-Tc Superconductors: Probing Dynamics of Magnetic Vortices 2 651-2 Paul...

  15. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect (OSTI)

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  16. Pressure-enhanced superconductivity in Eu 3 Bi 2 S 4 F 4 (Journal...

    Office of Scientific and Technical Information (OSTI)

    The pressure effect on the newly discovered charge-transferred BiS2-based superconductor, Eu3Bi2S4F4, with a Tc of 1.5 K at ambient pressure, is investigated by transport and ...

  17. Search for: microbes OR Microbiomes | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (358) waste management (349) coal, lignite, and peat (343) chemical reactions (340) chemistry (327) Filter by Author Hazen, T.C. (57) Woyke, Tanja (45) Lapidus, Alla (39) Hazen, ...

  18. STEAB January 2015 Meeting Minutes

    Energy Savers [EERE]

    Oklahoma Department of Commerce X Marion Gold, Commissioner of Energy, Rhode Island ... TC offered to be the Chair of a HUD Task Force and Marion Gold (MG) indicated she would ...

  19. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Betts, Jonathan B. (2) Liang, Ruixing (2) McDonald, Ross David (2) Migliori, Albert (2) ... Bounding the Pseudogap in Cuprate High-TC Superconductors McDonald, Ross David ; Shehter, ...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Balakirev, Fedor F. (2) Liang, Ruixing (2) McDonald, Ross David (2) Ramshaw, Brad (2) ... Bounding the Pseudogap in Cuprate High-TC Superconductors McDonald, Ross David ; Shehter, ...

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (2) symmetry (2) arsenic oxides (1) copper oxides (1) crystals (1) cuprates (1) ... of high-transition temperature (high-Tc) copper oxides,1,2 there have been tremendous ...

  2. Temperature, thermal-conductivity, and heat-flux data,Raft River...

    Open Energy Info (EERE)

    conductivity; United States; USGS Authors Urban, T.C.; Diment, W.H.; Nathenson, M.; Smith, E.P.; Ziagos, J.P.; Shaeffer and M.H. Published Open-File Report - U. S. Geological...

  3. Geothermometry At Raft River Geothermal Area (1980) | Open Energy...

    Open Energy Info (EERE)

    River geothermal system, Cassia County, Idaho Urban, T.C.; Diment, W.H.; Nathenson, M.; Smith, E.P.; Ziagos, J.P.; Shaeffer, M.H. (1 January 1986) Temperature,...

  4. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

    1995-12-26

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

  5. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, Kattesh V.; Volkert, Wynn A.; Singh, Prahlad; Ketring, Alan R.

    1995-01-01

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

  6. Development of a Chemistry-Based, Predictive Method for Determining the Amount of Non-Pertechnetate Technetium in the Hanford Tanks: FY 2012 Progress Report

    SciTech Connect (OSTI)

    Rapko, Brian M.; Bryan, Samuel A.; Bryant, Janet L.; Chatterjee, Sayandev; Edwards, Matthew K.; Houchin, Joy Y.; Janik, Tadeusz J.; Levitskaia, Tatiana G.; Peterson, James M.; Peterson, Reid A.; Sinkov, Sergey I.; Smith, Frances N.; Wittman, Richard S.

    2013-01-30

    This report describes investigations directed toward understanding the extent of the presence of highly alkaline soluble, non-pertechnetate technetium (n-Tc) in the Hanford Tank supernatants. The goals of this report are to: a) present a review of the available literature relevant to the speciation of technetium in the Hanford tank supernatants, b) attempt to establish a chemically logical correlation between available Hanford tank measurements and the presence of supernatant soluble n-Tc, c) use existing measurement data to estimate the amount of n-Tc in the Hanford tank supernatants, and d) report on any likely, process-friendly methods to eventually sequester soluble n-Tc from Hanford tank supernatants.

  7. BPA-2015-01782-FOIA Response

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    751-782 1 or by email at jcrnurray@bpa.gov. Sillccrel:. ), H.-.:. ' .ranit L. Murray ) I c:;td Rca lt ySpda l i st bee: Aircraft Services - TC-SP-Hanger M. Stolfus -...

  8. Cell Data Sheet Specification (Presentation)

    SciTech Connect (OSTI)

    Kurtz, S.

    2012-03-01

    The presentation shows a brief status report on the development of a specification being considered by IEC TC82 WG7 for a concentrator cell data sheet and solicits suggestions from the community.

  9. Integrated Manhattan Project for Excellence in Radiochemistry (IMPER)

    SciTech Connect (OSTI)

    Lewis, Jason

    2014-03-27

    Accomplishments are reported in these areas: single step radiolabeling of peptides with fluorine-18; photoreduction of 99Tc pertechnetate by nanometer-sized metal oxides for environmental remediation; synthesis and characterization of multi-modal CNT imaging constructs.

  10. PowerPoint Presentation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... T * QCP where Tc of order 1 vanishes * No entropy, order-to-order transition driven by ... D.M. Broun, Nature Physics, 4, 170 * QCP seen in * Resistivity * NMR * C * Kerr effect * ...

  11. DOE, NEPA, and YOU | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the United States Department of Energy and the Washington State Department of Ecology for Development of the Hanford Site Tank Closure and Waste Management EIS ("TC&WM EIS")...

  12. Search for: All records | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    wasmore obtained at 8K agrees with the Slater-Pauling rule and the Curie temperature (TC) is found to exceed 400K. Carrier concentration (up to 250K) and electrical conductivity...

  13. HBCU College Festival sponsored by Alfred Street Baptist Church

    Broader source: Energy.gov [DOE]

    Location: T.C. Williams High School, 3330 King St, Alexandria, VA 22302Attendees: Rauland Sharp (HC) and Dameone Ferguson (NNSA)POC: Chester Scott Website: http://bit.ly/1BARRqp

  14. Magneto-optical characterizations of FeTe₀̣₅Se₀̣₅ thin...

    Office of Scientific and Technical Information (OSTI)

    Compared with bulk crystals, FeTeSe thin film demonstrates not only higher Tc, but also much larger Jc, which is attractive for applications. Authors: Sun, Yue 1 ...

  15. Photos placed in horizontal position

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    File s ystem Lustre Panasas TradiAonal Network F ile S ystem ( NFS), E xtended F ile s ystem ( EXT), e tc. 4 Tri---Lab t ools Parallel F ile T...

  16. STANDING ORDER 1. Standing Order Number: EP-DIV-S0-20222, R.O

    Office of Environmental Management (EM)

    , ;, . USQ Qualified E1 luator (QEV) JLl. p M r .L .. r- c. 'i:> i" L v....ur- 1 rA .?4-- L1 I 2.t::.c'-- 0- 0 Print name Signa Date ERID-257356 Verified...

  17. Microsoft Word - Technetium.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the 99 Tc in the waste tanks. 1 The high activity waste stream will be vitrified and the resulting glass will be sent to the high-level waste repository (currently Yucca Mountain). ...

  18. SPEC CPI Demonstration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Crystals Shattering on the Inlets of Cloud Particle Probes Paul Lawson and Brad Baker Ice Particle Shattering on the CAS in Cirrus Anvils During the TC4 Field Campaign SPEC ...

  19. Untitled

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Disnguished(Lecture(Series Dr.(Kevin(Bedell Rourke(Professor(of(Physics(?(Boston(College Vice(Provost(for(Research,(Boston(College Superfluid(Fluctuaons(Above(TC:(An(alternave(p...

  20. Linkages of Remote Sea Surface Temperatures and Atlantic Tropical Cyclone Activity Mediated by the African Monsoon

    SciTech Connect (OSTI)

    Taraphdar, Sourav; Leung, Lai-Yung R.; Hagos, Samson M.

    2015-01-28

    Warm sea surface temperatures (SSTs) in North Atlantic and Mediterranean (NAMED) can influence tropical cyclone (TC) activity in the tropical East Atlantic by modulating summer convection over western Africa. Analysis of 30 years of observations show that the NAMED SST is linked to a strengthening of the Saharan heat low and enhancement of moisture and moist static energy in the lower atmosphere over West Africa, which favors a northward displacement of the monsoonal front. These processes also lead to a northward shift of the African easterly jet that introduces an anomalous positive vorticity from western Africa to the main development region (50W20E; 10N20N) of Atlantic TC. By modulating multiple processes associated with the African monsoon, this study demonstrates that warm NAMED SST explains 8% of interannual variability of Atlantic TC frequency. Thus NAME SST may provide useful predictability for Atlantic TC activity on seasonal-to-interannual time scale.

  1. V-1 PAPERS PUBLISHED

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Rev. C 88, 015805 (2013). Total absorption study of the decay of 102,104,105 Tc, D. Jordan, A. Algora, J.L. Ta, B. Rubio, J. Agramunt, A.B. Perez-Cerdan, F. Molina, L. ...

  2. DOE-STD-1090-2004; Hoisting and Rigging (Formerly Hoisting and...

    Office of Environmental Management (EM)

    ASME B56.6, Rough Terrain Fork Lift Trucks. ASME B56.7, Industrial Crane Trucks. Special ... ASNT-TC-1A. American Welding Society ANSIAWS D1.1 Structural Welding Code - Steel. Crane ...

  3. DOE-STD-1090-2007; Hoisting and Rigging Standard (Formerly Hoisting...

    Energy Savers [EERE]

    ANSIITSDF B56.6, Rough Terrain Fork Lift Trucks. ASME B56.7, Industrial Crane Trucks. ... ASNT-TC-1A. American Welding Society ANSIAWS D1.1 Structural Welding Code - Steel. Crane ...

  4. Microsoft PowerPoint - Update on IEC Inverter Standards Activity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    work of the IEC TC 82 Working Groups WG 1 Glossary WG 2 Modules, non-concentrating WG 3 Systems WG 6 Balance-of-system components WG 7 Concentrator modules Joint Working Groups...

  5. ANRCP-1998-3 LITERATURE REVIEW: PHYTOACCUMULATION OF CHROMIUM...

    Office of Scientific and Technical Information (OSTI)

    ... T.C. Huthchinson (et al.) eds. Symposium proceedings vol. 1. Toronto, Canada Oct. 27-3 1. pp. 35-47. Andrew, J., C. Smith, U. Kramer and J.M. Baker. 1995. Role of metal transport ...

  6. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... a standards-based solution through committees such as the IEC TC 57 WG 15, the IEEE Substation Committee, and the IEEE P1547-related activity on communications and controls. ...

  7. LANL: AOT & LANSCE The Pulse July 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Mo-99 is the parent isotope for technetium-99m (Tc-99m), a medical isotope used in approximately 50,000 medical imaging procedures a day in the United States, accounting for around ...

  8. Photo Galleries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inc. DOE Tour of Zero: The Net Zero in Seattle by TC Legend Homes DOE Tour of Zero: The School Street Homes by StreetScape Development, LLC DOE Tour of Zero: The Performance...

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... of superconductivity in boron-doped diamond with a critical temperature (TC) near 4 ... -NbN is below 11.6 K, which is significantly higher than that for boron-doped diamond. ...

  10. Interlayer Coherence and Superconducting Condensate in the c...

    Office of Scientific and Technical Information (OSTI)

    Interlayer Coherence and Superconducting Condensate in the c-Axis Response of Optimally Doped Ba(Fe1-xCox)2As2 High-Tc Superconductor Using Infrared Spectroscopy Citation Details ...

  11. Hydrothermal Regime of the Southwest Moat of the Long Valley...

    Open Energy Info (EERE)

    as well as some preliminary speculations as to the meaning of the results. Authors T.C. Urban, W.H. Diment and Michael L. Sorey Conference GRC Annual Meeting; Sparks, NV; 1987...

  12. HIPed Tailored Ceramic Waste Forms for the Immobilization of...

    Office of Scientific and Technical Information (OSTI)

    An important element of this initiative is the separation of key radionuclides . One of the systems being developed to separate key radionuclides is the UREX+1 process. The Tc and ...

  13. Special Notice: 2016 U.S. Department of Energy Collegiate Wind...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Toll-free : 888-461-9425 Participant passcode: 3869930 Web Access URL: https:www.mymeetings.comncjoin.php?iRW3109386&p3869930&tc Addthis Related Articles Collegiate Wind ...

  14. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stop H6-60 Richland, WA 99352 TC&WMEIS@saic.com Fax: 509-376-7701 - Phone: ... & Waste Management EIS Workshop Where: SAIC Building, 3250 Port of Benton Blvd ...

  15. Notices

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dial-In Information: Phone: 1-800- FON-SAIC (1-800-366-7242). Code: 4511074. FOR FURTHER ... information can be submitted at TC&WMEIS@saic.com, or by faxing to 888-785-2865. The ...

  16. Document

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... ADDRESSES: The Draft EIS is available electronically through, and written comments can be submitted at, TC&WMEIS@saic.com, or by faxing to (1-888) 785-2865. Paper copies may be ...

  17. Document

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Beth Burandt, Document Manager, Office of River Protection, U.S. Department of Energy, Post Office Box 450, Mail Stop H6-60, Richland, WA 99352, Electronic mail: TC&WMEIS@saic.com. ...

  18. Document

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... ADDRESSES: The Draft EIS is available electronically through, and written comments can be submitted at, TC&WMEIS@saic.com, or by faxing to (888) 785-2865. Paper copies may be ...

  19. Final Tank Closure and Waste Management Environmental Impact...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Mary Beth Burandt, Document Manager U.S. Department of Energy, Office of River Protection P.O. Box 450, Mail Stop H6-60 Richland, WA 99352 TC&WMEIS@saic.com Fax: 1-888-785-2865 - ...

  20. Translation--Final Tank Closure and Waste Management Environmental...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... de Proteccin de Ro P.O. Box 450, Mail Stop H6-60 Richland, WA 99352 TC&WMEIS@saic.com Fax: 509-376-7701 - Telfono: 888-829-6347 Para ver documentos relacionados con el ...

  1. Microsoft Word - MODFLOW TRG Meeting Summary September 2006.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, 2006, an open house was hosted by SAIC. Representatives of the American Indian ... Department of Energy's Office of River Protection at TC&WMEIS@saic.com or 509-372-7772

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... In this setting a variety of constituents were found to retard TcOsub 4: imogolite, boehmite, hydrotalcite, goethite, copper sulfide and oxide and coal. Near leaking tanks of ...

  3. Turks and Caicos Islands: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Country Profile Name Turks and Caicos Islands Population 31,458 GDP Unavailable Energy Consumption 0.00 Quadrillion Btu 2-letter ISO code TC 3-letter ISO code TCA Numeric ISO...

  4. DOE, NEPA, and YOU (DOE, 2011) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Between the United States Department of Energy and the Washington State Department of Ecology for Development of the Hanford Site Tank Closure and Waste Management EIS ("TC&WM EIS"

  5. Particle-hole symmetry broken pseudogap in high temperature superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Particle-hole symmetry broken pseudogap in high temperature superconductors High-temperature (Tc) superconductivity is one of the most important topics in condensed matter physics. Despite extensive studies over more than two decades, the microscopic mechanism of high temperature superconductivity still remains elusive due to many unconventional properties that are not well understood. Among them, the most mysterious behavior of high-Tc superconductor is the nature of so called

  6. Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -1 CHAPTER 1 PROPOSED ACTIONS: BACKGROUND, PURPOSE AND NEED Chapter 1 describes the background, purpose and need for the agency action presented in this Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (TC & WM EIS). Section 1.1 provides summary information on the size and distribution of the waste inventory at the Hanford Site (Hanford), the specific objectives of this TC & WM EIS, and the regulatory basis for the proposed

  7. Final Technical Report for project "Factors Controlling In Situ Uranium and Technetium Bio-Reduction and Reoxidation at the NABIR Field Research Center"

    SciTech Connect (OSTI)

    Dr. Jonathan D. Istok , Oregon State University; Dr. Lee Krumholz, University of Oklahoma; Dr. James McKinley, Pacific Northwest National Laboratory; Dr. Baohua Gu, Oak Ridge National Laboratory

    2006-10-31

    The overall goal of this project was to better understand factors and processes controlling microbially-mediated reduction and reoxidation of U and Tc in the unconsolidated residuum overlying the Nolichucky shale at the Field Research Center (FRC) at Oak Ridge National Laboratory. Project activities were designed to test the following hypotheses: 1. The small rates of denitrification and U bio-reduction observed in laboratory incubations of sediments from FRC Area 1 at low pH (< 5) are due to the presence of high concentrations of toxic metals (especially Al and Ni). Rates of Tc reduction will also be small at low pH in the presence of high concentrations of toxic metals. 2. In situ rates of U and perhaps Tc bio-reduction can be increased by increasing system pH and thus precipitating toxic metals from solution. 3. In situ rates of U and Tc bio-reduction can be increased by the addition of humic substances, which complex toxic metals such as Al and Ni, buffer pH, and serve as electron shuttles to facilitate U and Tc reduction. 4. Microbially-reduced U and Tc are rapidly oxidized in the presence of high concentrations of NO3- and the denitrification intermediates NO2-, N2O, and NO. 5. An electron-donor-addition strategy (type and form of donor, with or without pH adjustment and with or without the co-addition of humic substances) can be devised to reduce U and Tc concentrations for an extended period of time in low pH groundwater in the presence of high concentrations of NO3-, Al, and Ni. This strategy operates by removing or complexing these components of FRC groundwater to allow the subsequent reduction of U(VI) and Tc(VII).

  8. UNCLASSIFIED

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stephen R. Guimond, Ph.D. University of Maryland and Goddard Space Flight Center The Impacts of Numerical Schemes on Asymmetric Hurricane Intensification Thursday, June 9, 2016 1:00 PM - 2:00 PM Research Park, 203A Conference Room (TA-03, Bldg. 4200) Abstract: The fundamental pathways for tropical cyclone (TC) intensification are explored by considering axisymmetric and asymmetric impulsive thermal perturbations to balanced, TC-like vortices using the dynamic cores of three different nonlinear

  9. Final Technical report-4-30-13

    Office of Scientific and Technical Information (OSTI)

    FINAL TECHNICAL REPORT DE-FG02-05ER64124 Microbial Tc(VII) reduction is an attractive alternative strategy for bioremediation of technetium-contaminated subsurface environments. Traditional ex situ remediation processes (e.g., adsorption or ion exchange) are often limited by poor extraction efficiency, inhibition by competing ions and production of large volumes of produced waste. Microbial Tc(VII) reduction provides an attractive alternative in situ remediation strategy since the reduced

  10. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one year of operating experience with a transcritical carbon dioxide (TC CO2) booster refrigeration system at Delhaize America's Hannaford supermarket location in Turner, Maine. This supermarket, which began operation in June 2013, is the first supermarket installation in the U.S. of a TC CO2 booster

  11. Hydrogen Vehicles and Fueling Infrastructure in China

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Vehicles and Fueling Infrastructure in China Prof. Jinyang Zheng Director of IPE, Zhejiang University Director of Engineering Research Center for High Pressure Process Equipment and Safety, Ministry of Education Vice Director of China National Safety Committee of Pressure Vessels Vice President of CMES-P.R. China China Representative of ISO/TC197 and ISO/TC58 U.S. Department of Transportation and U. S. Department of Energy Workshop: Compressed Natural Gas and Hydrogen Fuels: Lessons

  12. Spectroelectrochemical Sensor for Pertechnetate Applicable to Hanford and Other DOE Sites

    SciTech Connect (OSTI)

    Heineman, William R; Seliskar, Carl J; Bryan, Samuel A

    2012-09-18

    The general aim of our work funded by DOE is the design and implementation of a new sensor technology that offers unprecedented levels of specificity needed for analysis of the complex chemical mixtures found at DOE sites nationwide. The specific goal of this project was the development of a sensor for technetium (Tc) that is applicable to characterizing and monitoring the vadose zone and associated subsurface water at the Hanford Site and other DOE sites. The concept for the spectroelectrochemical sensor is innovative and represents a breakthrough in sensor technology. The sensor combines three modes of selectivity (electrochemistry, spectroscopy, and selective partitioning) into a single sensor to substantially improve selectivity. The sensor consists of a basic spectroelectrochemical configuration that we have developed under our previous DOE grants: a waveguide with an optically transparent electrode (OTE) that is coated with a thin chemically-selective film that preconcnetrates the analyte. The key to adapting this generic sensor to detect TcO4- and Tc complexes lies in the development of chemically-selective films that preconcentrate the analyte and, when necessary, chemically convert it into a complex with electrochemical and spectroscopic properties appropriate for sensing. Significant accomplishments were made in the general areas of synthesis and characterization of polymer films that efficiently preconcentrate the analyte, development and characterization of sensors and associated instrumentation, and synthesis and characterization of relevant Re and Tc complexes. Two new polymer films for the preconcentration step in the sensor were developed: partially sulfonated polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene (SSEBS) and phosphine containing polymer films. The latter was a directed polymer film synthesis that combined the proper electrostatic properties to attract TcO4- and also incorporated a suitable ligand for covalently trapping a

  13. Electrode Induced Removal and Recovery of Uranium (VI) from Acidic Subsurfaces

    SciTech Connect (OSTI)

    Gregory, Kelvin

    2013-08-12

    The overarching objective of this research is to provide an improved understanding of how aqueous geochemical conditions impact the removal of U and Tc from groundwater and how engineering design may be utilized to optimize removal of these radionuclides. Experiments were designed to address the unique conditions in Area 3 of ORNL while also providing broader insight into the geochemical effectors of the removal rates and extent for U and Tc. The specific tasks of this work were to: 1) quantify the impact of common aqueous geochemical and operational conditions on the rate and extent of U removal and recovery from water, 2) investigate the removal of Tc with polarized graphite electrode, and determine the influence of geochemical and operational conditions on Tc removal and recovery, 3) determine whether U and Tc may be treated simultaneous from Area 3 groundwater, and examine the bench-scale performance of electrode-based treatment, and 4) determine the capacity of graphite electrodes for U(VI) removal and develop a mathematical, kinetic model for the removal of U(VI) from aqueous solution. Overall the body of work suggests that an electrode-based approach for the remediation of acidic subsurface environments, such as those observed in Area 3 of ORNL may be successful for the removal for both U(VI) and Tc. Carbonaceous (graphite) electrode materials are likely to be the least costly means to maximize removal rates and efficiency by maximizing the electrode surface area.

  14. Technetium Immobilization Forms Literature Survey

    SciTech Connect (OSTI)

    Westsik, Joseph H.; Cantrell, Kirk J.; Serne, R. Jeffrey; Qafoku, Nikolla

    2014-05-01

    Of the many radionuclides and contaminants in the tank wastes stored at the Hanford site, technetium-99 (99Tc) is one of the most challenging to effectively immobilize in a waste form for ultimate disposal. Within the Hanford Tank Waste Treatment and Immobilization Plant (WTP), the Tc will partition between both the high-level waste (HLW) and low-activity waste (LAW) fractions of the tank waste. The HLW fraction will be converted to a glass waste form in the HLW vitrification facility and the LAW fraction will be converted to another glass waste form in the LAW vitrification facility. In both vitrification facilities, the Tc is incorporated into the glass waste form but a significant fraction of the Tc volatilizes at the high glass-melting temperatures and is captured in the off-gas treatment systems at both facilities. The aqueous off-gas condensate solution containing the volatilized Tc is recycled and is added to the LAW glass melter feed. This recycle process is effective in increasing the loading of Tc in the LAW glass but it also disproportionally increases the sulfur and halides in the LAW melter feed which increases both the amount of LAW glass and either the duration of the LAW vitrification mission or the required supplemental LAW treatment capacity.

  15. Investigations Into the Nature of Alkaline Soluble, Non-Pertechnetate Technetium

    SciTech Connect (OSTI)

    Rapko, Brian M.; Bryan, Samuel A.; Chatterjee, Sayandev; Edwards, Matthew K.; Levitskaia, Tatiana G.; Peterson, James M.; Peterson, Reid A.; Sinkov, Sergey I.

    2013-11-14

    This report summarizes work accomplished in fiscal year (FY) 2013, exploring the chemistry of a low-valence technetium(I) species, [Tc(CO)3(H2O)3]+, a compound of interest due to its implication in the speciation of alkaline-soluble technetium in several Hanford tank waste supernatants. Various aspects of FY 2013s work were sponsored both by Washington River Protection Solutions and the U.S. Department of Energys Office of River Protection; because of this commonality, both sponsors work is summarized in this report. There were three tasks in this FY 2013 study. The first task involved examining the speciation of [(CO)3Tc(H2O)3]+ in alkaline solution by 99Tc nuclear magnetic resonance spectroscopy. The second task involved the purchase and installation of a microcalorimeter suitable to study the binding affinity of [(CO)3Tc(H2O)3]+ with various inorganic and organic compounds relevant to Hanford tank wastes, although the actual measure of such binding affinities is scheduled to occur in future FYs. The third task involved examining the chemical reactivity of [(CO)3Tc(H2O)3]+ as relevant to the development of a [(CO)3Tc(H2O)3]+ spectroelectrochemical sensor based on fluorescence spectroscopy.

  16. Characterization of Technetium Speciation in Cast Stone

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Wang, Guohui; Westsik, Joseph H.; Peterson, Reid A.

    2013-11-11

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE) EM-31 Support Program (EMSP) subtask, “Production and Long-Term Performance of Low Temperature Waste Forms” to provide additional information on technetium (Tc) speciation characterization in the Cast Stone waste form. To support the use of Cast Stone as an alternative to vitrification for solidifying low-activity waste (LAW) and as the current baseline waste form for secondary waste streams at the Hanford Site, additional understanding of Tc speciation in Cast Stone is needed to predict the long-term Tc leachability from Cast Stone and to meet the regulatory disposal-facility performance requirements for the Integrated Disposal Facility (IDF). Characterizations of the Tc speciation within the Cast Stone after leaching under various conditions provide insights into how the Tc is retained and released. The data generated by the laboratory tests described in this report provide both empirical and more scientific information to increase our understanding of Tc speciation in Cast Stone and its release mechanism under relevant leaching processes for the purpose of filling data gaps and to support the long-term risk and performance assessments of Cast Stone in the IDF at the Hanford Site.

  17. High-Resolution Modeling to Assess Tropical Cyclone Activity in Future Climate Regimes

    SciTech Connect (OSTI)

    Lackmann, Gary

    2013-06-10

    Applied research is proposed with the following objectives: (i) to determine the most likely level of tropical cyclone intensity and frequency in future climate regimes, (ii) to provide a quantitative measure of uncertainty in these predictions, and (iii) to improve understanding of the linkage between tropical cyclones and the planetary-scale circulation. Current mesoscale weather forecasting models, such as the Weather Research and Forecasting (WRF) model, are capable of simulating the full intensity of tropical cyclones (TC) with realistic structures. However, in order to accurately represent both the primary and secondary circulations in these systems, model simulations must be configured with sufficient resolution to explicitly represent convection (omitting the convective parameterization scheme). Most previous numerical studies of TC activity at seasonal and longer time scales have not utilized such explicit convection (EC) model runs. Here, we propose to employ the moving nest capability of WRF to optimally represent TC activity on a seasonal scale using a downscaling approach. The statistical results of a suite of these high-resolution TC simulations will yield a realistic representation of TC intensity on a seasonal basis, while at the same time allowing analysis of the feedback that TCs exert on the larger-scale climate system. Experiments will be driven with analyzed lateral boundary conditions for several recent Atlantic seasons, spanning a range of activity levels and TC track patterns. Results of the ensemble of WRF simulations will then be compared to analyzed TC data in order to determine the extent to which this modeling setup can reproduce recent levels of TC activity. Next, the boundary conditions (sea-surface temperature, tropopause height, and thermal/moisture profiles) from the recent seasons will be altered in a manner consistent with various future GCM/RCM scenarios, but that preserves the large-scale shear and incipient disturbance

  18. Novel imaging techniques, integrated with mineralogical, geochemical and microbiological characterizations to determine the biogeochemical controls on technetium mobility in FRC sediments

    SciTech Connect (OSTI)

    Jonathan R. Lloyd

    2009-02-03

    The objective of this research program was to take a highly multidisciplinary approach to define the biogeochemical factors that control technetium (Tc) mobility in FRC sediments. The aim was to use batch and column studies to probe the biogeochemical conditions that control the mobility of Tc at the FRC. Background sediment samples from Area 2 (pH 6.5, low nitrate, low {sup 99}Tc) and Area 3 (pH 3.5, high nitrate, relatively high {sup 99}Tc) of the FRC were selected (http://www.esd.ornl.gov/nabirfrc). For the batch experiments, sediments were mixed with simulated groundwater, modeled on chemical constituents of FRC waters and supplemented with {sup 99}Tc(VII), both with and without added electron donor (acetate). The solubility of the Tc was monitored, alongside other biogeochemical markers (nitrate, nitrite, Fe(II), sulfate, acetate, pH, Eh) as the 'microcosms' aged. At key points, the microbial communities were also profiled using both cultivation-dependent and molecular techniques, and results correlated with the geochemical conditions in the sediments. The mineral phases present in the sediments were also characterized, and the solid phase associations of the Tc determined using sequential extraction and synchrotron techniques. In addition to the batch sediment experiments, where discrete microbial communities with the potential to reduce and precipitate {sup 99}Tc will be separated in time, we also developed column experiments where biogeochemical processes were spatially separated. Experiments were conducted both with and without amendments proposed to stimulate radionuclide immobilization (e.g. the addition of acetate as an electron donor for metal reduction), and were also planned with and without competing anions at high concentration (e.g. nitrate, with columns containing Area 3 sediments). When the columns had stabilized, as determined by chemical analysis of the effluents, we used a spike of the short-lived gamma emitter {sup 99m}Tc (50-200 MBq; half

  19. Technetium Incorporation in Glass for the Hanford Tank Waste Treatment and Immobilization Plant

    SciTech Connect (OSTI)

    Kruger, Albert A.; Kim, Dong Sang

    2015-01-14

    A priority of the United States Department of Energy (U.S. DOE) is to dispose of nuclear wastes accumulated in 177 underground tanks at the Hanford Nuclear Reservation in eastern Washington State. These nuclear wastes date from the Manhattan Project of World War II and from plutonium production during the Cold War. The DOE plans to separate high-level radioactive wastes from low activity wastes and to treat each of the waste streams by vitrification (immobilization of the nuclides in glass) for disposal. The immobilized low-activity waste will be disposed of here at Hanford and the immobilized high-level waste at the national geologic repository. Included in the inventory of highly radioactive wastes is large volumes of 99Tc (~9 × 10E2 TBq or ~2.5 × 104 Ci or ~1500 kg). A problem facing safe disposal of Tc-bearing wastes is the processing of waste feed into in a chemically durable waste form. Technetium incorporates poorly into silicate glass in traditional glass melting. It readily evaporates during melting of glass feeds and out of the molten glass, leading to a spectrum of high-to-low retention (ca. 20 to 80%) in the cooled glass product. DOE-ORP currently has a program at Pacific Northwest National Laboratory (PNNL), in the Department of Materials Science and Engineering at Rutgers University and in the School of Mechanical and Materials Engineering at Washington State University that seeks to understand aspects of Tc retention by means of studying Tc partitioning, molten salt formation, volatilization pathways, and cold cap chemistry. Another problem involves the stability of Tc in glass in both the national geologic repository and on-site disposal after it has been immobilized. The major environmental concern with 99Tc is its high mobility in addition to a long half-life (2.1×105 yrs). The pertechnetate ion (TcO4-) is highly soluble in water and does not adsorb well onto the surface of minerals and so migrates nearly at the same velocity as groundwater

  20. Technetium Inventory, Distribution, and Speciation in Hanford Tanks

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Rapko, Brian M.

    2014-05-02

    The purpose of this report is three fold: 1) assemble the available information regarding technetium (Tc) inventory, distribution between phases, and speciation in Hanford’s 177 storage tanks into a single, detailed, comprehensive assessment; 2) discuss the fate (distribution/speciation) of Tc once retrieved from the storage tanks and processed into a final waste form; and 3) discuss/document in less detail the available data on the inventory of Tc in other "pools" such as the vadose zone below inactive cribs and trenches, below single-shell tanks (SSTs) that have leaked, and in the groundwater below the Hanford Site. A thorough understanding of the inventory for mobile contaminants is key to any performance or risk assessment for Hanford Site facilities because potential groundwater and river contamination levels are proportional to the amount of contaminants disposed at the Hanford Site. Because the majority of the total 99Tc produced at Hanford (~32,600 Ci) is currently stored in Hanford’s 177 tanks (~26,500 Ci), there is a critical need for knowledge of the fate of this 99Tc as it is removed from the tanks and processed into a final solid waste form. Current flow sheets for the Hanford Waste Treatment and Immobilization Plant process show most of the 99Tc will be immobilized as low-activity waste glass that will remain on the Hanford Site and disposed at the Integrated Disposal Facility (IDF); only a small fraction will be shipped to a geologic repository with the immobilized high-level waste. Past performance assessment studies, which focused on groundwater protection, have shown that 99Tc would be the primary dose contributor to the IDF performance.

  1. T-O, OII-OIII and OIII-OI phase boundary in oxygen-chain-equalized and order-stabilized polycrystalline pair samples of YBa{sub 2}Cu{sub 3}O{sub 6+x}

    SciTech Connect (OSTI)

    Calestani, G.; Manca, P.; Sanna, S.; Migliori, A.

    1999-04-20

    A comparative investigation, performed on Oxygen-Chain-equalized(k) Deintercalated [OCD]{sub k} and Intercalated [OCI]{sub k} pair-samples (k-pairs) of YBa{sub 2}Cu{sub 3}O{sub 6+x} by resistive {Tc} and electron diffraction (ED) at steps {Delta}k = 0.02--0.03, revealed that equivalent or non-equivalent microscopic oxygen-chain arrangements are produced, at the same oxygen content k, by intercalation and deintercalation of oxygen in the Cu(1)O{sub x} chains. These arrangements manifest in {Tc}-singularities or {Tc}-splittings of the k-pairs, whose occurrence can be straightforwardly explained by taking into account the non equivalence of the structural phase diagrams of YBCO, pointed out by electron diffraction, when produced by intercalation of oxygen in the tetragonal T structure or by deintercalation from the orthorhombic OI structure. {Tc}-singularities are produced in the k ranges for which a superimposition of the phase diagrams occurs, whereas {Tc}-splittings are pointed out in correspondence of split structural regions. The maximum {Tc}-splitting is observed in proximity of the semiconductor-metal transition with the appearing of superconductivity related to an anti-OIII (OIII{sup *}) superstructure in intercalated samples at k = 0.30, where the corresponding deintercalated samples are tetragonal and semiconductor. This result confirms that the vanishing of the antiferromagnetic ordering, the emergence of hole doped superconductivity and the symmetry breaking at the T-O transition are nearly coincident phenomena in YBCO. However, the related critical oxygen stoichiometry is strictly dependent on the ordering parameter in the Cu(1) plane, i.e., on the formation of extended chains. The OIII{sup *} structure, for the first time observed in a systematic way at the T-O transition in intercalated samples, seems to exhibit in analogy with OII and OIII a characteristic {Tc}.

  2. Significant enhancement of compositional and superconducting homogeneity in Ti rather than Ta-doped Nb3Sn

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tarantini, C.; Sung, Z. -H.; Lee, P. J.; Ghosh, A. K.; Larbalestier, D. C.

    2016-01-25

    Nb3Sn wires are now very close to their final optimization but despite its classical nature, detailed understanding of the role of Ta and Ti doping in the A15 is not fully understood. Long thought to be essentially equivalent in their influence on Hc2, they were interchangeably applied. Here we show that Ti produces significantly more homogeneous chemical and superconducting properties. Despite Ta-doped samples having a slightly higher Tc onset in zero-field, they always have a wider Tc-distribution. In particular, whereas the Ta-doped A15 has a Tc-distribution extending from 18 down to 5-6 K (the lowest expected Tc for the binarymore » A15 phase), the Ti-doped samples have no A15 phase with Tc below ~12 K. The much narrower Tc distribution in the Ti-doped samples has a positive effect on their in-field Tc-distribution too, leading to an extrapolated μ0Hc2(0) 2 Tesla larger than the Ta-doped one. Ti-doping also appears to be very homogeneous even when the Sn content is reduced in order to inhibit breakdown of the diffusion barriers in very high Jc conductors. As a result, the enhanced homogeneity of the Ti-doped samples appears to result from its assistance of rapid diffusion of Sn into the filaments and by its incorporation into the A15 phase interchangeably with Sn on the Sn sites of the A15 phase.« less

  3. RHENIUM SOLUBILITY IN BOROSILICATE NUCLEAR WASTE GLASS IMPLICATIONS FOR THE PROCESSING AND IMMOBILIZATION OF TECHNETIUM-99 (AND SUPPORTING INFORMATION WITH GRAPHICAL ABSTRACT)

    SciTech Connect (OSTI)

    AA KRUGER; A GOEL; CP RODRIGUEZ; JS MCCLOY; MJ SCHWEIGER; WW LUKENS; JR, BJ RILEY; D KIM; M LIEZERS; P HRMA

    2012-08-13

    The immobilization of 99Tc in a suitable host matrix has proved a challenging task for researchers in the nuclear waste community around the world. At the Hanford site in Washington State in the U.S., the total amount of 99Tc in low-activity waste (LAW) is {approx} 1,300 kg and the current strategy is to immobilize the 99Tc in borosilicate glass with vitrification. In this context, the present article reports on the solubility and retention of rhenium, a nonradioactive surrogate for 99Tc, in a LAW sodium borosilicate glass. Due to the radioactive nature of technetium, rhenium was chosen as a simulant because of previously established similarities in ionic radii and other chemical aspects. The glasses containing target Re concentrations varying from 0 to10,000 ppm by mass were synthesized in vacuum-sealed quartz ampoules to minimize the loss of Re by volatilization during melting at 1000 DC. The rhenium was found to be present predominantly as Re7 + in all the glasses as observed by X-ray absorption near-edge structure (XANES). The solubility of Re in borosilicate glasses was determined to be {approx}3,000 ppm (by mass) using inductively coupled plasma-optical emission spectroscopy (ICP-OES). At higher rhenium concentrations, some additional material was retained in the glasses in the form of alkali perrhenate crystalline inclusions detected by X-ray diffraction (XRD) and laser ablation-ICP mass spectrometry (LA-ICP-MS). Assuming justifiably substantial similarities between Re7 + and Tc 7+ behavior in this glass system, these results implied that the processing and immobilization of 99Tc from radioactive wastes should not be limited by the solubility of 99Tc in borosilicate LAW glasses.

  4. Radiolabeled technetium chelates for use in renal function determinations

    DOE Patents [OSTI]

    Fritzberg, Alan; Kasina, Sudhaker; Johnson, Dennis L.

    1994-01-01

    The present invention is directed to novel radiopharmaceutical imaging agents incorporating Tc-99m as a radiolabel. In particular, the novel imaging agents disclosed herein have relatively high renal extraction efficiencies, and hence are useful for conducting renal function imaging procedures. The novel Tc-99m compounds of a present invention have the following general formula: ##STR1## wherein X is S or N; and wherein Y is --H or wherein Y is ##STR2## and where R.sub.1 is --H, --CH.sub.3, or --CH.sub.2 CH.sub.3 ; R.sub.2 is --H, --CH.sub.2 CO.sub.2 H, --CH.sub.2 CONH.sub.2, --CH.sub.2 CH.sub.2 CO.sub.2 H, --CH.sub.2 CH.sub.2 CONH.sub.2, --CH.sub.3, --CH.sub.2 CH.sub.3, CH.sub.2 C.sub.6 H.sub.5, or --CH.sub.2 OH; and Z is --H, --CO.sub.2 H, --CONH.sub.2, --SO.sub.3 H, --SO.sub.2 NH.sub.2, or --CONHCH.sub.2 CO.sub.2 H; and the Tc is Tc-99m; and water-soluble salts thereof. Of the foregoing, the presently preferred Tc-99m compound of the present invention is Tc-99m-mercaptoacetylglycylglycylglycine (Tc-99m-MAGGG). The present invention is also directed to novel chelating agents that may be reacted with Tc-99m to form the foregoing compounds. Such novel chelating agents have the following general formula. ##STR3## where X and Y have the same definitions as above, and wherein Y' is --H.sub.2 when X is N, or wherein Y' is --H, or a suitable protective group such as --COCH.sub.3, --COC.sub.6 H.sub.5, --CH.sub.2 NHCOCH.sub.3, --COCF.sub.3, or --COCH.sub.2 OH when X is S. The present invention also provides methods for preparing and using the novel Tc-99m compounds.

  5. Radiolabeled technetium chelates for use in renal function determinations

    DOE Patents [OSTI]

    Fritzberg, Alan; Kasina, Sudhakar; Johnson, Dennis L.

    1990-01-01

    The present invention is directed to novel radiopharmaceutical imaging agents incorporating Tc-99m as a radiolabel. In particular, the novel imaging agents disclosed herein have relatively high renal extraction efficiencies, and hence are useful for conducting renal function imaging procedures. The novel Tc-99m compounds of a present invention have the following general formula: ##STR1## wherein X is S or N; and wherein Y is--H or wherein Y is ##STR2## and where R.sub.1 is --H, --CH.sub.3, or --CH.sub.2 CH.sub.3 ; R.sub.2 is --H, --CH.sub.2 CO.sub.2 H, --CH.sub.2 CONH.sub.2, --CH.sub.2 CH.sub.2 CO.sub.2 H, --CH.sub.2 CH.sub.2 CONH.sub.2, --CH.sub.3, --CH.sub.2 CH.sub.3, CH.sub.2 C.sub.6 H.sub.5, or --CH.sub.2 OH; and Z is --H, --CO.sub.2 H, --CONH.sub.2, --SO.sub.3 H, --SO.sub.2 NH.sub.2, or --CONHCH.sub.2 CO.sub.2 H; and the Tc is Tc-99m; and water-soluble salts thereof. Of the foregoing, the presently preferred Tc-99m compound of the present invention is Tc-99m-mercaptoacetylglycylglycylglycine (Tc-99m-MAGGG). The present invention is also directed to novel chelating agents that may be reacted with Tc-99m to form the foregoing compounds. Such novel chelating agents have the following general formula. ##STR3## where X and Y have the same definitions as above, and wherein Y' is --H.sub.2 when X is N, or wherein Y' is --H, or a suitable protective group such as --COCH.sub.3, --COC.sub.6 H.sub.5, --CH.sub.2 NHCOCH.sub.3, --COCF.sub.3, or --COCH.sub.2 OH when X is S. The present invention also provides methods for preparing and using the novel Tc-99m compounds.

  6. TECHNETIUM SORPTION BY CEMENTITIOUS MATERIALS UNDER REDUCING CONDITIONS

    SciTech Connect (OSTI)

    Kaplan, D.; Estes, S.; Arai, Y.; Powell, B.

    2012-01-31

    The objective of this study was to measure Tc sorption to cementitious materials under reducing conditions to simulate Saltstone Disposal Facility conditions. Earlier studies were conducted and the experimental conditions were found not to simulate those of the facility. Through a five month subcontract with Clemson University, sorption of {sup 99}Tc to four cementitious materials was examined within an anaerobic glovebag targeting a 0.1% H2(g)/ 99.9% N{sub 2}(g) atmosphere. Early experiments based on Tc sorption and Eh indicated that 0.1% H{sub 2}(g) (a reductant) was necessary to preclude experimental impacts from O{sub 2}(g) diffusion into the glovebag. Preliminary data to date (up to 56 days) indicates that sorption of {sup 99}Tc to cementitious materials increased with increasing slag content for simulated saltstone samples. This is consistent with the conceptual model that redox active sulfide groups within the reducing slag facilitate reduction of Tc(VII) to Tc(IV). These experiments differ from previous experiments where a 2% H{sub 2}(g) atmosphere was maintained (Kaplan et al., 2011 (SRNL-STI-2010-00668)). The impact of the 2% H{sub 2}(g) reducing atmosphere on this data was examined and determined to cause the reduction of Tc in experimental samples without slag. In the present ongoing study, after 56 days, Tc sorption by the 50-year old cement samples (no slag) was undetectable, whereas Tc sorption in the cementitious materials containing slag continues to increase with contact time (measured after 1, 4, 8, 19 and 56 days). Sorption was not consistent with spike concentrations and steady state has not been demonstrated after 56 days. The average conditional K{sub d} value for the Vault 2 cementitious material was 6,362 mL/g (17% slag), for the TR547 Saltstone (45% slag) the conditional K{sub d} was 1258 mL/g, and for TR545 (90% slag) the conditional K{sub d} was 12,112 mL/g. It is anticipated that additional samples will be collected until steady state

  7. GLASSES CONTAINING IRON (II III) OXIDES FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM

    SciTech Connect (OSTI)

    KRUGER AA; HEO J; XU K; CHOI JK; HRMA PR; UM W

    2011-11-07

    Technetium-99 (Tc-99) has posed serious environmental threats as US Department of Energy's high-level waste. This work reports the vitrification of Re, as surrogate for Tc-99, by iron-borosilicate and iron-phosphate glasses, respectively. Iron-phosphate glasses can dissolve Re as high as {approx} 1.2 wt. %, which can become candidate waste forms for Tc-99 disposal, while borosilicate glasses can retain less than 0.1 wt. % of Re due to high melting temperature and long melting duration. Vitrification of Re as Tc-99's mimic was investigated using iron-borosilicate and iron-phosphate glasses. The retention of Re in borosilicate glasses was less than 0.1 wt. % and more than 99 wt. % of Re were volatilized due to high melting temperature and long melting duration. Because the retention of Re in iron-phosphate glasses is as high as 1.2 wt. % and the volatilization is reduced down to {approx}50 wt. %, iron-phosphate glasses can be one of the glass waste form candidates for Tc (or Re) disposal. The investigations of chemical durability and leaching test of iron-phosphate glasses containing Re are now underway to test the performance of the waste form.

  8. Non-Pertechnetate Technetium Sensor Research and Development

    SciTech Connect (OSTI)

    Bryan, Samuel A.; Crawford, Amanda D.; Heineman, William R.; Rapko, Brian M.; Branch, Shirmir D.

    2014-10-01

    There remain several significant uncertainties in the understanding and modeling of the fate and speciation of 99Tc in Hanford waste tanks, glass, and low-temperature waste forms. A significant (2% to 25%) fraction of the 99Tc in the water-soluble portion of the tank waste may be present as a non-pertechnetate species that has not been identified and, based on experimentation to date, cannot be effectively separated from the wastes. This task will provide a sensor specifically tuned to detect the Tc(I)-carbonyl species believed to constitute the main fraction of the non-pertechnetate form of technetium. By direct measurement of the non-pertechnetate species, such a sensor will help reduce the uncertainties in the modeling of the fate and speciation of 99Tc in Hanford tanks and waste forms. This report summarizes work done in FY 2014 exploring the chemistry of a low-valence technetium species, [Tc(CO)3(H2O)3]+, a compound of interest due to its implication in the speciation of alkaline-soluble technetium in several Hanford tank waste supernatants. Progress made in FY 2014 was sponsored by the Department of Energys Office of Environmental Management and is summarized in this report.

  9. Oceanic Control of Northeast Pacific Hurricane Activity at Interannual Timescales

    SciTech Connect (OSTI)

    Balaguru, Karthik; Leung, Lai-Yung R.; Yoon, Jin-Ho

    2013-10-16

    Despite the strong dependence of the Power Dissipation Index (PDI), which is a measure of the intensity of Tropical Cyclone (TC) activity, on tropical sea-surface temperatures (SSTs), the variations in PDI are not completely explained by SST. Here we show, using an analysis of a string of observational data sets, that the variability of the thermocline depth (TD) in the east Pacific exerts a significant degree of control on the variability of PDI in that region. On average, a deep thermocline with a larger reservoir of heat favors TC intensification by reducing SST cooling while a shallow thermocline with a smaller heat reservoir promotes enhanced SST cooling that contributes to TC decay. At interannual time scales, the variability of basin-mean TD accounts for nearly 30% of the variability in the PDI during the TC season. Also, about 20% of the interannual variability in the east Pacific basin-mean TD is due to the El Nio and the Southern Oscillation (ENSO), a dominant climate signal in this region. This study suggests that a better understanding of the factors governing the interannual variability of the TD conditions in the east Pacific and how they may change over time, may lead to an improved projection of future east Pacific TC activity.

  10. Pressure-enhanced superconductivity in Eu3Bi2S4F4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Yongkang; Zhai, Hui -Fei; Zhang, Pan; Xu, Zhu -An; Cao, Guang -Han; Thompson, J. D.

    2014-12-17

    The pressure effect on the newly discovered charge-transferred BiS2-based superconductor, Eu3Bi2S4F4, with a Tc of 1.5 K at ambient pressure, is investigated by transport and magnetic measurements. Accompanied with the enhancement of metallicity under pressures, the onset superconducting transition temperature increases abruptly around 1.0 GPa, reaching ~10.0 K at 2.26 GPa. Alternating current magnetic susceptibility measurements indicate that a new superconducting phase with a higher Tc emerges and dominates at high pressures. In the broad pressure window of 0.68GPa≤p≤2.00 GPa, the high-Tc phase coexists with the low-Tc phase. Hall effect measurements reveal a significant difference in electronic structures between themore » two superconducting phases. As a result, our work devotes the effort to establish the commonality of pressure effect on the BiS2-based superconductors, and also uncovers the importance of electron carrier density in the high-Tc phase.« less

  11. LONG-TERM TECHNETIUM INTERACTIONS WITH REDUCING CEMENTITIOUS MATERIALS

    SciTech Connect (OSTI)

    Kaplan, D.; Lilley, M.; Almond, P.; Powell, B.

    2011-03-15

    Technetium is among the key risk drivers at the Saltstone Facility. The way that it is immobilized in this cementitious waste form is by converting its highly mobile Tc(VII) form to a much less mobile Tc(IV) form through reduction by the cement's blast furnace slag. This report includes a review of published data and experimental results dealing with Tc leaching from Portland cement waste forms. The objectives for the literature study were to document previous reports of Tc interactions with slag-containing cementitious materials. The objectives for the laboratory study were to measure Tc-saltstone Kd values under reducing conditions. From the literature it was concluded: (1) Spectroscopic evidence showed that when Tc(IV) in a slag-cement was exposed to an oxidizing environment, it will convert to the more mobile Tc(VII) species within a short time frame, 2.5 years. (2) SRS saltstone will reduce Tc(VII) in the absence of NaS or sodium dithionite in a reducing atmosphere. (3) Only trace concentrations of atmospheric oxygen (30 to 60 ppm O{sub 2}; Eh 120 mV) at the high pH levels of cementitious systems is required to maintain Tc as Tc(VII). (4) Experimental conditions must be responsible for wide variability of measured K{sub d} values, such that they are either very low, {approx}1 mL/g, or they are very high {approx}1000 mL/g, suggesting that Tc(VII) or Tc(IV) dominate the systems. Much of this variability appears to be the result of experimental conditions, especially direct controls of oxygen contact with the sample. (5) A field study conducted at SRS in the 1980s indicated that a slag-saltstone immobilized Tc for 2.5 years. Below background concentrations of Tc leached out of the slag-containing saltstone, whereas Tc leached out of the slag-free saltstone at the rate of nitrate loss. One possible explanation for the immobilization of Tc in this study was that the slag-saltstone maintained reducing conditions within the core of the 55-gallon sample, whereas in

  12. Process for recovering pertechnetate ions from an aqueous solution also containing other ions

    DOE Patents [OSTI]

    Rogers, Robin; Horwitz, E. Philip; Bond, Andrew H.

    1997-01-01

    A solid/liquid process for the separation and recovery of TcO.sub.4.sup.-1 ions from an aqueous solution is disclosed. The solid support comprises separation particles having surface-bonded poly(ethylene glycol) groups; whereas the aqueous solution from which the TcO.sub.4.sup.-1 ions are separated contains a poly(ethylene glycol) liquid/liquid biphase-forming amount of a dissolved salt. A solid/liquid phase admixture of separation particles containing bound TcO.sub.4.sup.-1 ions in such an aqueous solution that is free from MoO.sub.4.sup.-2 ions is also contemplated, as is a chromatography apparatus containing that solid/liquid phase admixture.

  13. Wavelength-dependent optical enhancement of superconducting interlayer coupling in La1.885Ba0.115CuO4

    SciTech Connect (OSTI)

    Casandruc, E.; Nicoletti, D.; Rajasekaran, S.; Laplace, Y.; Khanna, V.; Gu, G.; Hill, J. P.; Cavalleri, A.

    2015-05-05

    We analyze the pump wavelength dependence for the photo-induced enhancement of interlayer coupling in La1.885Ba0.115CuO4, which is promoted by optical melting of the stripe order. In the equilibrium superconducting state (T < TC = 13 K), in which stripes and superconductivity coexist, time-domain THz spectroscopy reveals a photo-induced blue-shift of the Josephson Plasma Resonance after excitation with optical pulses polarized perpendicular to the CuO2 planes. In the striped, non-superconducting state (TC < T < TSO ? 40 K) a transient plasma resonance similar to that seen below TC appears from a featureless equilibrium reflectivity. Most strikingly, both these effects become stronger upon tuning of the pump wavelength from the mid-infrared to the visible, underscoring an unconventional competition between stripe order and superconductivity, which occurs on energy scales far above the ordering temperature.

  14. Process for recovering pertechnetate ions from an aqueous solution also containing other ions

    DOE Patents [OSTI]

    Rogers, R.; Horwitz, E.P.; Bond, A.H.

    1997-02-18

    A solid/liquid process for the separation and recovery of TcO{sub 4}{sup {minus}1} ions from an aqueous solution is disclosed. The solid support comprises separation particles having surface-bonded poly(ethylene glycol) groups; whereas the aqueous solution from which the TcO{sub 4}{sup {minus}1} ions are separated contains a poly(ethylene glycol) liquid/liquid biphase-forming amount of a dissolved salt. A solid/liquid phase admixture of separation particles containing bound TcO{sub 4}{sup {minus}1} ions in such an aqueous solution that is free from MoO{sub 4}{sup {minus}2} ions is also contemplated, as is a chromatography apparatus containing that solid/liquid phase admixture. 15 figs.

  15. Study of technetium uptake in vegetation in the vicinity of the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Acox, T.A.

    1982-01-01

    Technetium-99 was measured in vegetation and soil collected on and near the Portsmouth Gaseous Diffusion Plant to obtain an estimate of the soil-to-vegetation concentration factors. The concentration factors appear to be lognormally distributed with a geometric mean of 3.4 (Bq/kg dry wt. tissue per Bq/kg dry wt. soil) and a geometric standard deviation of 4.7. A dose commitment was calculated using a hypothetical 3.7 x 10/sup 10/ Bq Tc-99/year release and the actual CY-1981 concentration release of Tc-99. The radiological significance of Tc-99 in the terrestial food chain is substantially less than previously believed.

  16. Wavelength-dependent optical enhancement of superconducting interlayer coupling in La1.885Ba0.115CuO4

    SciTech Connect (OSTI)

    Casandruc, E.; Nicoletti, D.; Rajasekaran, S.; Laplace, Y.; Khanna, V.; Gu, G.; Hill, J. P.; Cavalleri, A.

    2015-05-05

    We analyze the pump wavelength dependence for the photo-induced enhancement of interlayer coupling in La1.885Ba0.115CuO4, which is promoted by optical melting of the stripe order. In the equilibrium superconducting state (T < TC = 13 K), in which stripes and superconductivity coexist, time-domain THz spectroscopy reveals a photo-induced blue-shift of the Josephson Plasma Resonance after excitation with optical pulses polarized perpendicular to the CuO2 planes. In the striped, non-superconducting state (TC < T < TSO ≃ 40 K) a transient plasma resonance similar to that seen below TC appears from a featureless equilibrium reflectivity. Most strikingly, both these effects become stronger upon tuning of the pump wavelength from the mid-infrared to the visible, underscoring an unconventional competition between stripe order and superconductivity, which occurs on energy scales far above the ordering temperature.

  17. Wavelength-dependent optical enhancement of superconducting interlayer coupling in La1.885Ba0.115CuO4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Casandruc, E.; Nicoletti, D.; Rajasekaran, S.; Laplace, Y.; Khanna, V.; Gu, G.; Hill, J. P.; Cavalleri, A.

    2015-05-05

    We analyze the pump wavelength dependence for the photo-induced enhancement of interlayer coupling in La1.885Ba0.115CuO4, which is promoted by optical melting of the stripe order. In the equilibrium superconducting state (T < TC = 13 K), in which stripes and superconductivity coexist, time-domain THz spectroscopy reveals a photo-induced blue-shift of the Josephson Plasma Resonance after excitation with optical pulses polarized perpendicular to the CuO2 planes. In the striped, non-superconducting state (TC < T < TSO ≃ 40 K) a transient plasma resonance similar to that seen below TC appears from a featureless equilibrium reflectivity. Most strikingly, both these effects becomemore » stronger upon tuning of the pump wavelength from the mid-infrared to the visible, underscoring an unconventional competition between stripe order and superconductivity, which occurs on energy scales far above the ordering temperature.« less

  18. Separation of Nickel from Technetium-Contaminated Scrap

    SciTech Connect (OSTI)

    El-Azzami, Louei; Zhai, Tony; Grulke, Eric W

    2004-10-01

    The recovery of nickel (Ni) from Department of Energy (DOE) gaseous diffusion plant barriers contaminated with radionuclides and specifically the separation of from Ni from technetium-99, has proven to be difficult. Manufacturing Science Corporation (MSC) could not remove Tc99 from volumetrically contaminated Ni utilizing electro-refining approaches to levels that would allow the free release of Ni for commercial and industrial uses. The various methods applied by Manufacturing Sciences Corporation (MSC) are reported in the attached appendices. The electro-refining methods employed by MSC resulted in Ni containing residual Tc99. Residual Tc99 in Ni purified by MSC's electro-refining methods resulted in a moratorium being issued by the Secretary of the DOE and congressional opposition to the release of Ni from the K-25 plant at Oak Ridge.

  19. Characteristics of tropical cyclones in high-resolution models in the present climate

    SciTech Connect (OSTI)

    Shaevitz, Daniel A.; Camargo, Suzana J.; Sobel, Adam H.; Jonas, Jeffrey A.; Kim, Daehyun; Kumar, Arun; Lim, Young -Kwon; Reed, Kevin A.; Roberts, Malcolm J.; Scoccimarro, Enrico; Vidale, Pier Luigi; Wang, Hui; Zhao, Ming; Henderson, Naomi

    2014-12-05

    The global characteristics of tropical cyclones (TCs) simulated by several climate models are analyzed and compared with observations. The global climate models were forced by the same sea surface temperature (SST) fields in two types of experiments, using climatological SST and interannually varying SST. TC tracks and intensities are derived from each model's output fields by the group who ran that model, using their own preferred tracking scheme; the study considers the combination of model and tracking scheme as a single modeling system, and compares the properties derived from the different systems. Overall, the observed geographic distribution of global TC frequency was reasonably well reproduced. As expected, with the exception of one model, intensities of the simulated TC were lower than in observations, to a degree that varies considerably across models.

  20. Down-regulation of transcobalamin receptor TCblR/CD320 by siRNA inhibits cobalamin uptake and proliferation of cells in culture

    SciTech Connect (OSTI)

    Lai, Shao-Chiang; Nakayama, Yasumi; Sequeira, Jeffrey M.; Quadros, Edward V.

    2011-07-01

    The clinical phenotype of cobalamin (Cbl) deficiency is dictated by the essential role of this vitamin in two key enzymatic reactions. Multiple proteins and receptors participate in the absorption, transport and delivery of this vitamin to tissue cells. Cellular uptake of Cbl is mediated by transcobalamin (TC), a plasma protein and a transmembrane receptor (TCblR) with high affinity for TC saturated with Cbl. Knockdown of TCblR with siRNA results in decreased TC-Cbl uptake. The ensuing Cbl deficiency leads to an increase in doubling time and decreased proliferation of these cells. The study confirms the seminal role of this receptor in the cellular uptake of Cbl and its down-regulation as a potential strategy to inhibit proliferation of cancer cells.

  1. Charm degrees of freedom in the quark gluon plasma

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mukherjee, Swagato; Petreczky, Peter; Sharma, Sayantan

    2016-01-11

    The lattice QCD studies on fluctuations and correlations of charm quantum number have established that deconfinement of charm degrees of freedom sets in around the chiral crossover temperature, Tc; i.e., charm degrees of freedom carrying fractional baryonic charge start to appear. When we reexamine those same lattice QCD data we show that, in addition to the contributions from quarklike excitations, the partial pressure of charm degrees of freedom may still contain significant contributions from open-charm-meson- and baryonlike excitations associated with integral baryonic charges for temperatures up to 1.2Tc. Finally, charm-quark quasiparticles become the dominant degrees of freedom for temperatures T>1.2Tc.

  2. Reactive amendment saltstone (RAS). A novel approach for improved sorption/retention of radionuclides such as technetium and iodine

    SciTech Connect (OSTI)

    Dixon, K. L.; Knox, A. S.; Cozzi, A. D.; Flach, G. P.; Hill, K. A.

    2015-09-30

    This study examined the use of reactive amendments (hydroxyapatite, activated carbon, and two types of organoclays) that prior research suggests may improve retention of 99Tc and 129I. Tests were conducted using surrogates for 99Tc (NaReO4) and 129I (NaI). Results showed that adding up to 10% of organoclay improved the retention of Re without adversely impacting hydraulic properties. To a lesser extent, iodine retention was also improved by adding up to 10% organoclay. Numerical modeling showed that using organoclay as a reactive barrier may significantly retard 99Tc release from saltstone disposal units.

  3. Biogeochemical Mechanisms Controlling Reduced Radionuclide Particle Properties and Stability

    SciTech Connect (OSTI)

    Jim K. Fredrickson; John M. Zachara; Matthew J. Marshall; Alex S. Beliaev

    2006-06-01

    Uranium and Technetium are the major risk-driving contaminants at Hanford and other DOE sites. These radionuclides have been shown to be reduced by dissimilatory metal reducing bacteria (DMRB) under anoxic conditions. Laboratory studies have demonstrated that reduction results in the formation of poorly soluble hydrous oxides, UO2(s) and TcO2n?H2O(s), that are believed to limit mobility in the environment. The mechanisms of microbial reduction of U and Tc have been the focus of considerable research in the Environmental Remediation Sciences Program (ERSP). In spite of equal or greater importance in terms of controlling the environmental fate of the contaminants relatively little is known regarding the precipitation mechanism(s), reactivity, persistence, and transport of biogenic UO2(s) and TcO2(s).

  4. Resonant tunneling of fluctuation Cooper pairs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Galda, Alexey; Mel'nikov, A. S.; Vinokur, V. M.

    2015-02-09

    Superconducting fluctuations have proved to be an irreplaceable source of information about microscopic and macroscopic material parameters that could be inferred from the experiment. According to common wisdom, the effect of thermodynamic fluctuations in the vicinity of the superconducting transition temperature, Tc, is to round off all of the sharp corners and discontinuities, which otherwise would have been expected to occur at Tc. Here we report the current spikes due to radiation-induced resonant tunneling of fluctuation Cooper pairs between two superconductors which grow even sharper and more pronounced upon approach to Tc. This striking effect offers an unprecedented tool formore » direct measurements of fluctuation Cooper pair lifetime, which is key to our understanding of the fluctuation regime, most notably to nature of the pseudogap state in high-temperature superconductors. Our finding marks a radical departure from the conventional view of superconducting fluctuations as a blurring and rounding phenomenon.« less

  5. Activation of type 2 cannabinoid receptors (CB2R) promotes fatty acid oxidation through the SIRT1/PGC-1? pathway

    SciTech Connect (OSTI)

    Zheng, Xuqin; Sun, Tao; Wang, Xiaodong

    2013-07-05

    Highlights: TC, a CB2R specific agonist, stimulates SIRT1 activity by PKA/CREB pathway. TC promotes PGC-1? transcriptional activity by increasing its deacetylation. TC increases the expression of genes linked to FAO and promotes the rate of FAO. The effects of TC in FAO are dependent on CB2R. Suggesting CB2R as a target to treat diseases with lipid dysregulation. -- Abstract: Abnormal fatty acid oxidation has been associated with obesity and type 2 diabetes. At the transcriptional level, peroxisome proliferator-activated receptor-gamma coactivator 1? (PGC-1?) has been reported to strongly increase the ability of hormone nuclear receptors PPAR? and ERR? to drive transcription of fatty acid oxidation enzymes. In this study, we report that a specific agonist of the type 2 cannabinoid receptor (CB2R) can lead to fatty acid oxidation through the PGC-1? pathway. We have found that CB2R is expressed in differentiated C2C12 myotubes, and that use of the specific agonist trans-caryophyllene (TC) stimulates sirtuin 1 (SIRT1) deacetylase activity by increasing the phosphorylation of cAMP response element-binding protein (CREB), thus leading to increased levels of PGC-1? deacetylation. This use of TC treatment increases the expression of genes linked to the fatty acid oxidation pathway in a SIRT1/PGC-1?-dependent mechanism and also drastically accelerates the rate of complete fatty acid oxidation in C2C12 myotubes, neither of which occur when CB2R mRNA is knocked down using siRNA. These results reveal that activation of CB2R by a selective agonist promotes lipid oxidation through a signaling/transcriptional pathway. Our findings imply that pharmacological manipulation of CB2R may provide therapeutic possibilities to treat metabolic diseases associated with lipid dysregulation.

  6. Giant increase in critical current density of KxFe2-ySe₂ single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lei, Hechang; Petrovic, C.

    2011-12-28

    The critical current density Jabc of KxFe2-ySe₂ single crystals can be enhanced by more than one order of magnitude, up to ~2.1×10⁴ A/cm² by the post annealing and quenching technique. A scaling analysis reveals the universal behavior of the normalized pinning force as a function of the reduced field for all temperatures, indicating the presence of a single vortex pinning mechanism. The main pinning sources are three-dimensional (3D) point-like normal cores. The dominant vortex interaction with pinning centers is via spatial variations in critical temperature Tc (“δTc pinning”).

  7. Nuclear Data Sheets for A = 91

    SciTech Connect (OSTI)

    Baglin, Coral M.

    2013-10-15

    Experimental nuclear structure and decay data for all known A=91 nuclides (As, Se, Br, Kr, Rb, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd) have been evaluated. This evaluation, covering data received by 1 September 2013, supersedes the 1998 evaluation by C. M. Baglin published in Nuclear Data Sheets86, 1 (1999) (15 December 1998 literature cutoff), and subsequent evaluations by C. M. Baglin added to the ENSDF database for Kr, Sr and Zr (29 December 2000 literature cutoff) and by B. Singh for {sup 91}Tc (6 November 2000 literature cutoff)

  8. SU-E-T-224: Is Monte Carlo Dose Calculation Method Necessary for Cyberknife Brain Treatment Planning?

    SciTech Connect (OSTI)

    Wang, L; Fourkal, E; Hayes, S; Jin, L; Ma, C

    2014-06-01

    Purpose: To study the dosimetric difference resulted in using the pencil beam algorithm instead of Monte Carlo (MC) methods for tumors adjacent to the skull. Methods: We retrospectively calculated the dosimetric differences between RT and MC algorithms for brain tumors treated with CyberKnife located adjacent to the skull for 18 patients (total of 27 tumors). The median tumor sizes was 0.53-cc (range 0.018-cc to 26.2-cc). The absolute mean distance from the tumor to the skull was 2.11 mm (range - 17.0 mm to 9.2 mm). The dosimetric variables examined include the mean, maximum, and minimum doses to the target, the target coverage (TC) and conformality index. The MC calculation used the same MUs as the RT dose calculation without further normalization and 1% statistical uncertainty. The differences were analyzed by tumor size and distance from the skull. Results: The TC was generally reduced with the MC calculation (24 out of 27 cases). The average difference in TC between RT and MC was 3.3% (range 0.0% to 23.5%). When the TC was deemed unacceptable, the plans were re-normalized in order to increase the TC to 99%. This resulted in a 6.9% maximum change in the prescription isodose line. The maximum changes in the mean, maximum, and minimum doses were 5.4 %, 7.7%, and 8.4%, respectively, before re-normalization. When the TC was analyzed with regards to target size, it was found that the worst coverage occurred with the smaller targets (0.018-cc). When the TC was analyzed with regards to the distance to the skull, there was no correlation between proximity to the skull and TC between the RT and MC plans. Conclusions: For smaller targets (< 4.0-cc), MC should be used to re-evaluate the dose coverage after RT is used for the initial dose calculation in order to ensure target coverage.

  9. Draft HAB Advice on Delaying Decisions Associated with the Final Tank Closure and Waste

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Committee Draft Advice - TC&WM EIS Delayed Decisions v1 - Mattson, et.al. Page 1/1 Draft HAB Advice on Delaying Decisions Associated with the Final Tank Closure and Waste Management EIS Background: The Hanford Advisory Board (HAB or Board) spent a considerable amount of time developing advice on the Draft Tank Closure and Waste Management Environmental Impact Statement (TC&WM EIS, EIS). The U.S. Department of Energy (DOE) has spent over $80 million on the EIS, and thousands of people

  10. 119Sn-NMR investigations on superconducting Ca3Ir4Sn13: Evidence for multigap superconductivity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarkar, R.; Petrovic, C.; Bruckner, F.; Gunther, M.; Wang, Kefeng; Biswas, P. K.; Luetkens, H.; Morenzoni, E.; Amato, A.; Klauss, H. -H.

    2015-09-25

    In this study, we report bulk superconductivity (SC) in Ca3Ir4Sn13 by means of 119Sn nuclear magnetic resonance (NMR) experiments. Two classical signatures of BCS superconductivity in spin-lattice relaxation rate (1/T1), namely the Hebel–Slichter coherence peak just below the Tc, and the exponential decay in the superconducting phase, are evident. The noticeable decrease of 119Sn Knight shift below Tc indicates spin-singlet superconductivity. The temperature dependence of the spin-lattice relaxation rate 119(1/T1) is convincingly described by the multigap isotropic superconducting gap. NMR experiments do not witness any sign of enhanced spin fluctuations.

  11. Infrared response of YBa sub 2 Cu sub 3 O sub 7-. delta. films to pulsed, broadband synchrotron radiation

    SciTech Connect (OSTI)

    Carr, G.L.; Quijada, M.; Tanner, D.B. . Dept. of Physics); Hirschmugl, C.J.; Williams, G.P. ); Etemad, S.; DeRosa, F.; Venkatesan, T. ); Dutta, B.; Hemmick, D.; Xi, X. . Dept. of Physics)

    1990-01-01

    We report studies of a thin high {Tc} film operating as a fast bolometric detector of infrared radiation. The film has a response of infrared radiation. The film has a response of several mV when exposed to a 1 W, 1 ns duration broadband infrared pulse. The decay after the pulse was about 4 ns. The temperature dependence of the response accurately tracked dR/dT. A thermal model, in which the film's temperature varies relative to the substrate, provides a good description of the response. We find no evidence for other (non-bolometric) response mechanisms for temperatures near or well below {Tc}. 13 refs., 4 figs.

  12. Treatability Test for Removing Technetium-99 from 200-ZP-1 Groundwater, Hanford Site

    SciTech Connect (OSTI)

    Byrnes, M.E.; Petersen, S.W. [Fluor Hanford, Inc., Soil and Groundwater Remediation Project, Richland, WA (United States); Tortoso, A. [U.S. Department of Energy, Richland Operations Office, Richland, WA (United States); Elliott, W.S. [Environmental Quality Management, Inc., Richland, WA (United States)

    2008-07-01

    The 200-ZP-1 Groundwater Operable Unit (OU) is one of two groundwater OUs located within the 200 West groundwater aggregate area of the Hanford Site. The primary risk-driving contaminants within the 200-ZP-1 OU include carbon tetrachloride and technetium-99 (Tc-99). A pump-and-treat system for this OU was initially installed in 1995 to control the 0.002 kg /m{sup 3} (2000 {mu}g/L) contour of the carbon tetrachloride plume. Carbon tetrachloride is removed from groundwater with the assistance of an air-stripping tower. Ten extraction wells and three injection wells operate at a combined rate of approximately 0.017m{sup 3}/s (17.03 L/s). In 2005, groundwater from two of the extraction wells (299-W15-765 and 299-W15-44) began to show concentrations greater than twice the maximum contaminant level (MCL) of Tc-99 (33,309 beq/m{sup 3} or 900 pCi/L). The Tc-99 groundwater concentrations from all ten of the extraction wells when mixed were more than one-half of the MCL and were slowly increasing. If concentrations continued to rise and the water remained untreated for Tc-99, there was concern that the water re-injected into the aquifer could exceed the MCL standard. Multiple treatment technologies were reviewed for selectively removing Tc-99 from the groundwater. Of the treatment technologies, only ion exchange was determined to be highly selective, commercially available, and relatively low in cost. Through research funded by the U.S. Department of Energy, the ion-exchange resin Purolite{sup R} A-530E1 was found to successfully remove Tc-99 from groundwater, even in the presence of competing anions. For this and other reasons, Purolite{sup R} A-530E ion exchange resin was selected for treatability testing. The treatability test required installing resin columns on the discharge lines from extraction wells 299-W15-765 and 299-W15-44. Preliminary test results have concluded that the Purolite{sup R} A-530E1 resin is effective at removing Tc-99 from groundwater to below

  13. Distributed Production of Radionuclide Mo-99 Charles A. Gentile, Adam B.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cohen and George Ascione | Princeton Plasma Physics Lab Distributed Production of Radionuclide Mo-99 Charles A. Gentile, Adam B. Cohen and George Ascione This invention is for the production of Technetium-99m (Tc-99m), a widely used medical isotope in a distributed and in-situ fashion. Tc-99m results when Molybdenum 99 (Mo-99) decays. Mo-99 is typically produced in a nuclear reactor, but it can be produced from naturally occurring Molybdenum 100 or from Molybdenum 98 using either neutrons or

  14. Microsoft PowerPoint - Briefings_Galan

    Office of Environmental Management (EM)

    1 1 GTRI Mission & Program Goals Defense Nuclear Nonproliferation U.S. DEPARTMENT OF ENERGY 2 GTRI World Wide Scope Defense Nuclear Nonproliferation U.S. DEPARTMENT OF ENERGY 3 Mo-99 Production and Usage * Mo-99 Production Background Foreign research reactors produce 100% of the U.S. supply of Mo-99. Canada currently supplies approximately 60% of this important radiopharmaceutical. Mo-99 is used to generate Tc-99m. * Medical Usage - Tc-99m is used in approximately 80 percent of all

  15. Technetium (VII) Co-precipitation with Framework Aluminosilicates

    SciTech Connect (OSTI)

    Harsh, James B.; Dickson, Johnbull Otah; Pierce, Eric M.; Bargar, John

    2015-07-13

    Technetium-99 (99Tc), a long-lived radionuclide, is one of the most widespread contaminants within the Hanford subsurface. At some depths, it is only extractable with strong acids, suggesting incorporation into a solid phase. We hypothesized that Tc may have coprecipitated with feldspathoid aluminosilicates under waste tanks that had leaked caustic solutions into the vadose zone. Our objectives were to determine if Tc could be incorporated into the feldspathoids cancrinite and sodalite and under what conditions coprecipitation could occur. Our hypothesis was that sodalite was more likely to incorporate and retain Tc. Our approach was to use known methods of feldspathoid formation in solutions resembling those in Hanford waste tanks contacting sediments in terms of major ion (Na, NO3, OH, Al(OH)4, and Si(OH)4 concentrations. In some cases, Al and Si were supplied from zeolite. We used perrhenate (ReO4) as a surrogate for pertechnetate (TcO4) to avoid the radioactivity. The major findings of this study were 1) ReO4 could be incorporated into either sodalite or cancrinite but the concentration in the solid was < 1% of the competing ion Cl, NO3, or NO2. 2) The small amount of ReO4 incorporated was not exchangeable with NO3 or NO2. 3) In sodalite, NO3 was highly preferred over ReO4 but significant Re-sodalite was formed when the mole fraction in solution (Re/Re+N) exceeded 0.8. 4) A nonlinear relation between the unit cell parameter and amount of Re incorporated suggested that a separate Re-sodalite phase was formed rather than a solid solution. 5) We determined that sodalite preference for sodalite in the presence of different anions increased with the ionic size of the competing anion: Cl < CO3 < NO3 < SO4 < MnO4 < WO4 and significant incorporation did not occur unless the difference in anion radii was less than 12%. 6) Re(VII) was not significantly reduced to Re(IV) under the conditions of this experiment and Re appeared to be a good surrogate for Tc under oxidizing

  16. CX-014694: Categorical Exclusion Determination | Department of Energy

    Office of Environmental Management (EM)

    694: Categorical Exclusion Determination CX-014694: Categorical Exclusion Determination Attenuation-based Sampling for I129 and Tc99 Along Fourmile Branch at the F-Area Seepage Basins CX(s) Applied: B3.1 Date: 12/21/2015 Location(s): South Carolina Offices(s): Savannah River Operations Office Savannah River National Laboratory is conducting an attenuation-based sampling for I129 and Tc99 along Fourmile Branch down-gradient from the F-Area Seepage Basins as part of the Department of Energy EM-12

  17. Investigations to Identify the Soluble, Non-pertechnetate Species in the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-level Nuclear Waste at the Hanford Site Wayne W. Lukens1, David K. Shuh1, Norman C. Schroeder2, and Kenneth R. Ashley3 1Lawrence Berkeley National Laboratory, Berkeley, CA 2Los Alamos National Laboratory, Los Alamos, NM 3Texas A&M University-Commerce, Commerce, TX Technetium (99Tc) is an abundant fission product that presents a number of challenges for the safe, long-term disposal of high-level nuclear waste due to the 213,000 year half-life of 99Tc and the high environmental

  18. U.S. Department of Energy Categorical Exclusion Determination Form

    Office of Environmental Management (EM)

    Attenuation-based Sampling for I129 and Tc99 Along Fourmile Branch at the F-Area Seepage Basins Savannah River Site Aiken/Aiken/South Carolina SRNL is conducting an attenuation-based sampling for I129 and Tc99 along Fourmile Branch down-gradient from the F-Area Seepage Basins as part of the Department of Energy EM-12 Office of Soil and Groundwater Remediation "Attenuation-Based Remedies for the Subsurface Applied Field Research Initiative (ABRS AFRI)". Groundwater sampling will be

  19. Separation of uranium from technetium in recovery of spent nuclear fuel

    DOE Patents [OSTI]

    Friedman, Horace A.

    1985-01-01

    A method for decontaminating uranium product from the Purex process comprises addition of hydrazine to the product uranyl nitrate stream from the Purex process, which contains hexavalent (UO.sub.2.sup.2+) uranium and heptavalent technetium (TcO.sub.4 -). Technetium in the product stream is reduced and then complexed by the addition of oxalic acid (H.sub.2 C.sub.2 O.sub.4), and the Tc-oxalate complex is readily separated from the uranium by solvent extraction with 30 vol. % tributyl phosphate in n-dodecane.

  20. Separation of uranium from technetium in recovery of spent nuclear fuel

    DOE Patents [OSTI]

    Friedman, H.A.

    1984-06-13

    A method for decontaminating uranium product from the Purex 5 process comprises addition of hydrazine to the product uranyl nitrate stream from the Purex process, which contains hexavalent (UO/sub 2//sup 2 +/) uranium and heptavalent technetium (TcO/sub 4/-). Technetium in the product stream is reduced and then complexed by the addition of oxalic acid (H/sub 2/C/sub 2/O/sub 4/), and the Tc-oxalate complex is readily separated from the 10 uranium by solvent extraction with 30 vol % tributyl phosphate in n-dodecane.

  1. RAP Meeting Transcribed Flipcharts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 8, 2013 COTW [TC&WM FEIS] * IM framing of prior HAB advice & agency response - Dale * History/Overview component, Board's involvement with draft advice * Technical research by IMs with DOE about what changed from draft to final - Jean Page 1 TC & WM EIS * New potential proposal - Sounding Board instead of COTW advice? o Will discuss @ TWC 1/9/2013 Page 2 100 - D/H Draft A Proposed Plan * ECY Comments back to DOE in mid-February - Dale & Jean * Rev. 0 next Fiscal Year? End

  2. Bulk Vitrification Castable Refractory Block Protection Study

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Beck, Andrew E.; Brouns, Thomas M.; Caldwell, Dustin D.; Elliott, Michael L.; Matyas, Josef; Minister, Kevin BC; Schweiger, Michael J.; Strachan, Denis M.; Tinsley, Bronnie P.; Hollenberg, Glenn W.

    2005-05-01

    Bulk vitrification (BV) was selected for a pilot-scale test and demonstration facility for supplemental treatment to accelerate the cleanup of low-activity waste (LAW) at the Hanford U.S. DOE Site. During engineering-scale (ES) tests, a small fraction of radioactive Tc (and Re, its nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass, and deposited on the surface and within the pores of the castable refractory block (CRB). Laboratory experiments were undertaken to understand the mechanisms of the transport Tc/Re into the CRB during vitrification and to evaluate various means of CRB protection against the deposition of leachable Tc/Re. The tests used Re as a chemical surrogate for Tc. The tests with the baseline CRB showed that the molten LAW penetrates into CRB pores before it converts to glass, leaving deposits of sulfates and chlorides when the nitrate components decompose. Na2O from the LAW reacts with the CRB to create a durable glass phase that may contain Tc/Re. Limited data from a single CRB sample taken from an ES experiment indicate that, while a fraction of Tc/Re is present in the CRB in a readily leachable form, most of the Tc/Re deposited in the refractory is retained in the form of a durable glass phase. In addition, the molten salts from the LAW, mainly sulfates, chlorides, and nitrates, begin to evaporate from BV feeds at temperatures below 800 C and condense on solid surfaces at temperatures below 530 C. Three approaches aimed at reducing or preventing the deposition of soluble Tc/Re within the CRB were proposed: metal lining, sealing the CRB surface with a glaze, and lining the CRB with ceramic tiles. Metal liners were deemed unsuitable because evaluations showed that they can cause unacceptable distortions of the electric field in the BV system. Sodium silicate and a low-alkali borosilicate glaze were selected for testing. The glazes slowed down molten salt condensate penetration, but did little to reduce the

  3. Technetium and Iodine Getters to Improve Cast Stone Performance

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Neeway, James J.; Lawter, Amanda R.; Levitskaia, Tatiana G.; Serne, R. Jeffrey; Westsik, Joseph H.; Snyder, Michelle MV

    2015-02-19

    To determine the effectiveness of the various getter materials prior to their solidification in Cast Stone, a series of batch sorption experiments was performed at Pacific Northwest National Laboratory. To quantify the effectiveness of the removal of Tc(VII) and I(I) from solution by getters, the distribution coefficient, Kd (mL/g), was calculated. Testing involved placing getter material in contact with spiked waste solutions at a 1:100 solid-to-solution ratio for periods up to 45 days with periodic solution sampling. One Tc getter was also tested at a 1:10 solid-to-solution ratio. Two different solution media, 18.2 MΩ deionized water (DI H2O) and a 7.8 M Na LAW simulant, were used in the batch sorption tests. Each test was conducted at room temperature in an anoxic chamber containing N2 with a small amount of H2 (0.7%) to maintain anoxic conditions. Each getter-solution combination was run in duplicate. Three Tc- and I-doping concentrations were used separately in aliquots of both the 18.2 MΩ DI H2O and a 7.8 M Na LAW waste simulant. The 1× concentration was developed based on Hanford Tank Waste Operations Simulator (HTWOS) model runs to support the River Protection Project System Plan Revision 6. The other two concentrations were 5× and 10× of the HTWOS values. The Tc and I tests were run separately (i.e., the solutions did not contain both solutes). Sampling of the solid-solution mixtures occurred nominally after 0.2, 1, 3, 6, 9, 12, 15 days and ~35 to 45 days. Seven getter materials were tested for Tc and five materials were tested for I. The seven Tc getters were blast furnace slag 1 (BFS1) (northwest source), BFS2 (southeast source), Sn(II)-treated apatite, Sn(II) chloride, nano tin phosphate, KMS (a potassium-metal-sulfide), and tin hydroxapatite. The five iodine getters were layered bismuth hydroxide (LBH), argentite mineral, synthetic argentite, silver-treated carbon, and silver-treated zeolite. The Tc Kd values measured from experiments conducted

  4. Technetium and Iodine Getters to Improve Cast Stone Performance

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Neeway, James J.; Lawter, Amanda R.; Levitskaia, Tatiana G.; Serne, R. Jeffrey; Westsik, Joseph H.; Snyder, Michelle MV

    2014-07-01

    To determine the effectiveness of the various getter materials prior to their solidification in Cast Stone, a series of batch sorption experiments was performed at Pacific Northwest National Laboratory. To quantify the effectiveness of the removal of Tc(VII) and I(I) from solution by getters, the distribution coefficient, Kd (mL/g), was calculated. Testing involved placing getter material in contact with spiked waste solutions at a 1:100 solid-to-solution ratio for periods up to 45 days with periodic solution sampling. One Tc getter was also tested at a 1:10 solid-to-solution ratio. Two different solution media, 18.2 MΩ deionized water (DI H2O) and a 7.8 M Na LAW simulant, were used in the batch sorption tests. Each test was conducted at room temperature in an anoxic chamber containing N2 with a small amount of H2 (0.7%) to maintain anoxic conditions. Each getter-solution combination was run in duplicate. Three Tc- and I-doping concentrations were used separately in aliquots of both the 18.2 MΩ DI H2O and a 7.8 M Na LAW waste simulant. The 1× concentration was developed based on Hanford Tank Waste Operations Simulator (HTWOS) model runs to support the River Protection Project System Plan Revision 6. The other two concentrations were 5× and 10× of the HTWOS values. The Tc and I tests were run separately (i.e., the solutions did not contain both solutes). Sampling of the solid-solution mixtures occurred nominally after 0.2, 1, 3, 6, 9, 12, 15 days and ~35 to 45 days. Seven getter materials were tested for Tc and five materials were tested for I. The seven Tc getters were blast furnace slag 1 (BFS1) (northwest source), BFS2 (southeast source), Sn(II)-treated apatite, Sn(II) chloride, nano tin phosphate, KMS (a potassium-metal-sulfide), and tin hydroxapatite. The five iodine getters were layered bismuth hydroxide (LBH), argentite mineral, synthetic argentite, silver-treated carbon, and silver-treated zeolite. The Tc Kd values measured from experiments conducted

  5. Report on the Behavior of Fission Products in the Co-decontamination Process

    SciTech Connect (OSTI)

    Martin, Leigh Robert; Riddle, Catherine Lynn

    2015-09-30

    This document was prepared to meet FCT level 3 milestone M3FT-15IN0302042, “Generate Zr, Ru, Mo and Tc data for the Co-decontamination Process.” This work was carried out under the auspices of the Lab-Scale Testing of Reference Processes FCT work package. This document reports preliminary work in identifying the behavior of important fission products in a Co-decontamination flowsheet. Current results show that Tc, in the presence of Zr alone, does not behave as the Argonne Model for Universal Solvent Extraction (AMUSE) code would predict. The Tc distribution is reproducibly lower than predicted, with Zr distributions remaining close to the AMUSE code prediction. In addition, it appears there may be an intricate relationship between multiple fission product metals, in different combinations, that will have a direct impact on U, Tc and other important fission products such as Zr, Mo, and Rh. More extensive testing is required to adequately predict flowsheet behavior for these variances within the fission products.

  6. HANFORD ADVISORY BOARD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Committee of the Whole Page 1 Final Meeting Summary February 16-17, 2010 FINAL MEETING SUMMARY HANFORD ADVISORY BOARD COMMITTEE OF THE WHOLE MEETING February 16-17, 2010 Richland, WA Topics in This Meeting Summary Welcome, introductions and announcements ................................................................................................. 1 Background and framing: DOE-ORP overview on the draft TC&WM EIS .................................................. 1 Background and framing:

  7. First-principles prediction of magnetic superatoms in 4d-transition-metal-doped magnesium clusters

    SciTech Connect (OSTI)

    Ge, Gui-Xian [National Laboratory of Solid State Microstructures, and Department of Physics, Nanjing University, Nanjing 210093 (China) [National Laboratory of Solid State Microstructures, and Department of Physics, Nanjing University, Nanjing 210093 (China); Key Laboratory of Ecophysics and Department of Physics, College of Science, Shihezi University, Xinjiang 832003 (China); Han, Yan; Wan, Jian-Guo, E-mail: wanjg@nju.edu.cn; Wang, Guang-Hou [National Laboratory of Solid State Microstructures, and Department of Physics, Nanjing University, Nanjing 210093 (China)] [National Laboratory of Solid State Microstructures, and Department of Physics, Nanjing University, Nanjing 210093 (China); Zhao, Ji-Jun [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Dalian University of Technology, Ministry of Education, Dalian 116024 (China)] [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Dalian University of Technology, Ministry of Education, Dalian 116024 (China)

    2013-11-07

    We theoretically predict magnetic superatoms in the 4d-transition-metal-doped Mg{sub 8} clusters using a spin-polarized density functional theory method. We demonstrate that TcMg{sub 8} is highly energetically stable in both structure and magnetic states, and identify it as a magnetic superatom with a magnetic moment as large as 5 ?{sub B}. The magnetic TcMg{sub 8} with 23 valence electrons has a configuration of 1S{sup 2}1P{sup 6}1D{sup 10} closed shell and 2S{sup 1}2D{sup 4} open shell, complying with Hund's rule similar to the single atom. We elucidate the formation mechanism of the magnetic TcMg{sub 8} superatom based on the detailed analysis of molecular orbitals, and attribute it to the large exchange interaction and moderate crystal field effect. Finally, we predict that the magnetic TcMg{sub 8} may exhibit semiconductor-like property with spin polarization characteristics.

  8. Solvent extraction of radionuclides from aqueous tank waste

    SciTech Connect (OSTI)

    Moyer, B.A.; Bonnesen, P.V.; Sachleben, R.A.; Leonard, R.A.; Lumetta, G.J.

    1997-01-01

    This task aims toward the development of efficient solvent-extraction processes for the removal of the fission products {sup 99}Tc, {sup 90}Sr, and {sup 137}Cs from alkaline tank wastes. Processes already developed or proposed entail direct treatment of the waste solution with the solvent and subsequent stripping of the extracted contaminants from the solvent into a dilute aqueous solution. Working processes to remove Tc(and SR) separately and Cs separately have been developed; the feasibility of a combined process is under investigation. Since Tc, Sr, and Cs will be vitrified together in the high-level fraction, however, a process that could separate Tc, Sr, and Cs simultaneously, as opposed to sequentially, potentially offers the greatest impact. A figure presents a simplified diagram of a proposed solvent-extraction cycle followed by three possible treatments for the stripping solution. Some degree of recycle of the stripping solution (option a) is expected. Simple evaporation (option c) is possible prior to vitrification; this offers the greatest possible volume reduction with simple operation and no consumption of chemicals, but it is energy intensive. However, if the contaminants are concentrated (option b) by fixed-bed technology, the energy penalty of evaporation can be avoided and vitrification facilitated without any additional secondary waste being produced.

  9. 100 T science at the NHMFL

    SciTech Connect (OSTI)

    Harrison, Neil

    2012-06-29

    100 T science is a vibrant area of research: (1) Collapse of magnetic length crucial tool for understanding high Tc superconductors; (2) Field can also behave as 'negative pressure' in condensed matter; and (3) Field-tuned emergent phenomena involving commensurability effects.

  10. Raman Analysis of Perrhenate and Pertechnetate in Alkali Salts and Borosilicate Glasses

    SciTech Connect (OSTI)

    Gassman, Paul L.; McCloy, John S.; Soderquist, Chuck Z.; Schweiger, Michael J.

    2014-01-03

    Sodium borosilicate glasses containing various concentrations of rhenium or technetium were fabricated, and their vibrational spectra studied using a Raman microscope. Spectra were interpreted with reference to new high resolution measurements of alkali pertechnetates and perrhenates NaReO4, KReO4, NaTcO4, and KTcO4. At low concentrations of ReO4- or TcO4-, glass spectra show weak peaks superimposed on a dominant spectrum of glass characteristic of silicate and borate network vibrations. At high concentrations, sharp peaks characteristic of crystal field splitting and C4h symmetry dominate the spectra of glasses, indicating alkali nearby tetrahedral Re or Tc. Often peaks indicative of both the K and Na pertechnetates/ perrhenates are evident in the Raman spectrum, with the latter being favored at high additions of the source chemical, since Na is more prevalent in the glass and ion exchange takes place. These results have significance to immobilization of nuclear waste containing radioactive 99Tc in glass for ultimate disposal.

  11. Isonitrile radionuclide complexes for labelling and imaging agents

    DOE Patents [OSTI]

    Jones, Alun G.; Davison, Alan; Abrams, Michael J.

    1984-06-04

    A coordination complex of an isonitrile ligand and radionuclide such as Tc, Ru, Co, Pt, Fe, Os, Ir, W, Re, Cr, Mo, Mn, Ni, Rh, Pd, Nb and Ta, is useful as a diagnostic agent for labelling liposomes or vesicles, and selected living cells containing lipid membranes, such as blood clots, myocardial tissue, gall bladder tissue, etc.

  12. Partial growth plate closure: apex view on bone scan

    SciTech Connect (OSTI)

    Howman-Giles, R.; Trochei, M.; Yeates, K.; Middleton, R.; Barrett, I.; Scougall, J.; Whiteway, D.

    1985-01-01

    A new technique of using /sup 99m/Tc bone scan to assess partial closure of the growth plate is described. The site and degree of osseous fusion can be obtained by using the apex view. The technique has the potential of assessing serially the growth of a plate before and after surgery.

  13. Structural and superconducting features of Tl-1223 prepared at ambient pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shipra, Fnu; Idrobo Tapia, Juan Carlos; Sefat, Athena Safa

    2015-09-25

    This study provides an account of the bulk preparation of TlBa2Ca2Cu3O9-δ (Tl-1223) superconductor at ambient pressure, and the Tc features under thermal-annealing conditions. The ‘as-prepared’ Tl-1223 (Tc =106 K) presents a significantly higher Tc = 125 K after annealing the polycrystalline material in either flowing Ar+4% H2, or N2 gases. In order to understand the fundamental reasons for a particular Tc, we refined the average bulk structures using powder X-ray diffraction data. Although Ar+4%H2 annealed Tl- 1223 shows an increased ‘c’ lattice parameter, it shrinks by 0.03% (approximately unchanged) upon N2 anneal. Due to such indeterminate conclusions on the averagemore » structural changes, local structures were investigated at using aberration-corrected scanning-transmission electron microscopy technique. Similar compositional changes in the atomic arrangements of both annealed-samples of Tl-1223 were detected in which the plane containing Ca atomic layer gives a non-uniform contrast, due to substitution of some heavier Tl. In this report, extensive bulk properties are summarized through temperature-dependent resistivity, and shielding and Meissner fractions of magnetic susceptibility results; the bulk and local structures are investigated to correlate to properties.« less

  14. Cuprate-titanate superconductor and method for making

    DOE Patents [OSTI]

    Toreki, R.; Poeppelmeier, K.; Dabrowski, B.

    1995-05-23

    A new copper oxide superconductor of the formula Ln{sub 1{minus}x}M{sub x}Sr{sub 2}Cu{sub 3{minus}y}Ti{sub y}O{sub 7+{delta}} is disclosed, and exhibits a {Tc} of 60 K with deviations from linear metallic behavior as high as 130 K. 2 Figs.

  15. Insensitivity of the pressure dependences of characteristic energy scales in Ce1–xRxCoIn₅ (R=Yb,Y,Gd) to the electronic configuration of the rare-earth ion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    White, B. D.; Hamlin, J. J.; Huang, K.; Shu, L.; Lum, I. K.; Baumbach, R. E.; Janoschek, M.; Maple, M. B.

    2012-09-11

    Cooperative Ce and Yb valence fluctuations have recently been proposed as the mechanism responsible for stabilizing correlated electron phenomena in Ce₁₋xYbxCoIn₅ over an unexpectedly large range of concentrations. In order to better understand the origins and character of this stability, we have measured the effect of applied pressure on relevant energy scales such as the superconducting critical (Tc) and Kondo-lattice coherence (T*) temperatures of Ce₁₋xRxCoIn₅ with R=Yb, Y, and Gd. Electrical resistivity measurements were performed under applied pressure on samples doped with intermediate-valent Yb and stable-valent Gd and Y, and the responses of Tc and T* to increased pressure inmore » these systems are compared. The character of Tc(P) and T*(P) in Ce₁₋xRxCoIn₅ depends only on their respective ambient-pressure values Tc(0) and T*(0), independent of the electronic configuration of R or concentration x. The consequences of this result are discussed within the context of possible cooperative valence fluctuations in Ce₁₋xYbxCoIn₅.« less

  16. Current methods to handle wall conduction and room internal heat transfer

    SciTech Connect (OSTI)

    Davies, M.G.

    1999-07-01

    This paper reviews methods of handling wall conduction and room internal heat exchange adopted by ASHRAE (1993 Handbook of Fundamentals and later developments), CIBSE (1986 Guide and current proposals), and the CEN/TC89/WG6 proposals to calculate heating and cooling loads and related topics.

  17. Dependence of the critical temperature in overdoped copper oxides on superfluid density

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Božović, I.; He, X.; Wu, J.; Bollinger, A. T.

    2016-08-17

    The physics of underdoped copper-oxide superconductors, including the pseudogap, spin and charge ordering, and their relation to superconductivity1-3, is intensely debated. The overdoped side is perceived as simpler, with strongly-correlated fermion physics evolving smoothly into the conventional Bardeen-Cooper-Schrieffer (BCS) behavior. Pioneering studies on a few overdoped samples4-11 indicated that the superfluid density was much smaller than expected, but this was attributed to pair-breaking, disorder, and phase separation. Here, we test this conjecture by studying how the magnetic penetration depth λ and the phase stiffness ρs depend on temperature and doping, scanning densely the entire overdoped side of the La2-xSrxCuO4 (LSCO)more » phase diagram. We have measured the absolute values of λ and ρs to the accuracy of ±1% in thousands of cuprate samples; the large statistics reveals clear trends and intrinsic properties. The films are quite homogeneous; variations in the critical temperature (Tc) within a film are very small (< 1 K). At every doping, ρs(T) decreases linearly with temperature. The Tc(ρ s0) dependence is linear but with an offset, (Tc - T0) ∝ ρs0 where T0 ≈ 7 K, except very close to the origin where Tc ∝ √ρ s0. This scaling law defies the standard BCS description, posing a challenge to theory.« less

  18. Technetium Inventory, Distribution, and Speciation in Hanford Tanks

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Rapko, Brian M.; Pegg, Ian L.

    2014-11-13

    The purpose of this report is three fold: 1) assemble the available information regarding Tc inventory, distribution between phases, and speciation in Hanford’s 177 storage tanks into a single, detailed, comprehensive assessment; 2) discuss the fate (distribution/speciation) of Tc once retrieved from the storage tanks and processed into final waste forms; and 3) discuss/document in less detail the available data on the inventory of Tc in other “pools” such as the vadose zone below inactive cribs and trenches, below single-shell tanks (SSTs) that have leaked, and in the groundwater below the Hanford Site. This report was revised in September 2014 to add detail and correct inaccuracies in Section 5.0 on the fate of technetium (Tc) recycle from the off-gas systems downstream of the low-activity waste (LAW) melters back to the melters, based on several reports that were not found in the original literature search on the topic. The newly provided reports, from experts active in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) glass studies, the Vitreous State Laboratory at The Catholic University of America (VSL) melter and off-gas system demonstrations and overall WTP systems analysis, were not originally found on electronic databases commonly searched. The major revisions to Section 5.0 also required changes to Section 7.0 (Summary and Conclusions) and this executive summary.

  19. Pressure-enhanced superconductivity in Eu 3 Bi 2 S 4 F 4 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: Pressure-enhanced superconductivity in Eu 3 Bi 2 S 4 F 4 The pressure effect on the newly discovered charge-transferred BiS2-based superconductor, Eu3Bi2S4F4, with a Tc of ...

  20. Nonmonotonic pressure evolution of the upper critical field in superconducting FeSe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Taufour, Valentin; Böhmer, Anna E.; Tanatar, Makariy A.; Bud'ko, Sergey L.; Kogan, Vladimir G.; Prozorov, Ruslan; Canfield, Paul C.

    2016-02-01

    The pressure dependence of the upper critical field, Hc2,c, of single crystalline FeSe was studied using measurements of the interplane resistivity, ρc, in magnetic fields parallel to tetragonal c axis. Hc2,c(T) curves obtained under hydrostatic pressures up to 1.56 GPa, the range over which the superconducting transition temperature, Tc, of FeSe exhibits a nonmonotonic dependence with local maximum at p1 ≈ 0.8 GPa and local minimum at p2 ≈ 1.2 GPa. The slope of the upper critical field at Tc,(dHc2,c/dT)Tc, also exhibits a nonmonotonic pressure dependence with distinct changes at p1 and p2. For p < p1 the slope canmore » be described within a multiband orbital model. For both p1 < p < p2 and p > p2 the slope is in good semiquantitative agreement with a single band, orbital Helfand-Werthamer theory with Fermi velocities determined from Shubnikov–de Haas measurements. Lastly, this finding indicates that Fermi surface changes are responsible for the local minimum of Tc(p) at p2 ≈ 1.2 GPa.« less

  1. Task Group 9 Update (Presentation)

    SciTech Connect (OSTI)

    Bosco, N.

    2014-04-01

    This presentation is a brief update of IEC TC82 QA Task Force, Group 9. Presented is an outline of the recently submitted New Work Item Proposal (NWIP) for a Comparative Thermal Cycling Test for CPV Modules to Differentiate Thermal Fatigue Durability.

  2. Materials Sciences Division 1990 annual report

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    This report is the Materials Sciences Division`s annual report. It contains abstracts describing materials research at the National Center for Electron Microscopy, and for research groups in metallurgy, solid-state physics, materials chemistry, electrochemical energy storage, electronic materials, surface science and catalysis, ceramic science, high tc superconductivity, polymers, composites, and high performance metals.

  3. Materials Sciences Division 1990 annual report

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This report is the Materials Sciences Division's annual report. It contains abstracts describing materials research at the National Center for Electron Microscopy, and for research groups in metallurgy, solid-state physics, materials chemistry, electrochemical energy storage, electronic materials, surface science and catalysis, ceramic science, high tc superconductivity, polymers, composites, and high performance metals.

  4. High-temperature superconducting detectors: Bolometric and nonbolometric. Proceedings SPIE Volume 2159

    SciTech Connect (OSTI)

    Nahum, M.; Villegier, J.C.

    1994-12-31

    This conference was divided into the following sessions: high-{Tc} bolometers and applications; high-speed detectors based on bolometric and nonbolometric effects; nonequilibrium and kinetic inductance detectors; SNS and grain boundary junctions; and poster presentations. Separate abstracts were prepared for 22 papers in this book.

  5. Thermal Cycling Combined with Dynamic Mechanical Load: Preliminary...

    Office of Environmental Management (EM)

    o f C ell C rack) Modules: T ype A B ( MulM---c---Si) ( Module t ypes a re s ame w ith t hose i n T C600 T esMng) D ML---TC: E ach 2 M odules o f 2 T ypes R eference: E...

  6. Science at 100 T

    SciTech Connect (OSTI)

    Harrison, Neil

    2012-06-01

    100 tesla fields are essential for answering many key questions in condensed matter: (1) Collapse of magnetic length crucial tool for understanding high Tc superconductors; (2) Field can also behave as 'negative pressure' in condensed matter; and (3) Field-tuned emergent phenomena involving commensurability effects.

  7. Email Template

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 14, 2010 FINAL MEETING SUMMARY HANFORD ADVISORY BOARD PUBLIC INVOLVEMENT COMMITTEE MEETING January 14, 2009 Richland, WA Topics in this Meeting Summary Welcome and introductions ................................................................................................ 1 Strategic Planning Process - Part 1 .................................................................................... 2 Public Involvement -- Tank Closure and Waste Management EIS (TC&WM EIS) .......... 9

  8. Email Template

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 FINAL MEETING SUMMARY HANFORD ADVISORY BOARD TANK WASTE COMMITTEE MEETING March 11, 2010 Richland, WA Topics in this Meeting Summary Welcome and Introductions ................................................................................................ 1 Single-Shell Tank Integrity Expert Panel Workshop.......................................................... 1 Draft Tank Closure & Waste Management Environmental Impact Statement (TC&WM EIS)

  9. Email Template

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 18, 2009 FINAL MEETING SUMMARY HANFORD ADVISORY BOARD TANK WASTE COMMITTEE MEETING November 18, 2009 Richland, WA Topics in this Meeting Summary Welcome and Introductions ................................................................................................ 1 Tank Closure and Waste Management Environmental Impact Statement (TC&WM EIS) 1 River Protection System Plan, Rev. 4 ................................................................................. 5 Waste Treatment

  10. Optional Partnering Form for Potential Applicants to DE-FOA-0001412...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    escription o f y our o rganization's r elevant o r u nique c apabilities, e quipment, e tc. t hat would b e a pplicable t o D E---FOA---0001412, A OI 3 : If y ou a re i nterested...

  11. Microsoft Word - 03-PTD-0089 Deactivation EA.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Environmental Assessment Deactivation of the Plutonium Finishing Plant, Hanford Site, Richland, Washington U.S. Department of Energy Richland Operations Office Richland, Washington 99352 May 2003 PREDECISIONAL DRAFT This page intentionally left blank. DOE/EA-1469 U.S. Department of Energy Contents Environmental Assessment TC-1 May 2003 Predecisional Draft CONTENTS GLOSSARY

  12. Magnetic nanohole superlattices

    DOE Patents [OSTI]

    Liu, Feng

    2013-05-14

    A magnetic material is disclosed including a two-dimensional array of carbon atoms and a two-dimensional array of nanoholes patterned in the two-dimensional array of carbon atoms. The magnetic material has long-range magnetic ordering at a temperature below a critical temperature Tc.

  13. HC-21C off-gas test report

    SciTech Connect (OSTI)

    Cunningham, L.T.

    1995-09-12

    Test procedure WHC-SD-CP-TC-032, HC-21C Off-Gas Test Procedure, was performed to determine the cause and establish a method of the elimination of liquid formation in the HC-21C Furnace off-gas system. This report discusses the findings of the test procedure and the changes implemented.

  14. SSRL HEADLINES Jul 2001

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Jul, 2001 _____________________________________________________________________________ Contents of This Issue: Science Highlight - Complex Materials Research by Angle-Resolved Photoemission Spectroscopy: Challenging the Mystery of the High Tc Superconductivity 2000-2001 Experimental Run Highlights Stanford-Berkeley 2001 SR Summer School: A Successful Start to the First in a Series SSRL Well Represented at the American Crystallographic Association Meeting The Shutdown Clock is Ticking BL10

  15. Thin Film Electronic Devices with Conductive and Transparent Gas and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Moisture Permeation Barriers - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Thin Film Electronic Devices with Conductive and Transparent Gas and Moisture Permeation Barriers National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Transparent conducting (TC) materials are extensively used in electronics and

  16. "Solar Probe Plus Spacecraft", Dr. Justin C. Kasper, Harvard University |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab January 17, 2012, 4:15pm "Solar Probe Plus Spacecraft", Dr. Justin C. Kasper, Harvard University Presentation: File TC17JAN2012_JKasper.pptx http://mediacentral.princeton.edu/id/0_9mt5rumh

  17. Superconductivity and Physical Properties of CaPd2Ge2 Single Crystals

    SciTech Connect (OSTI)

    Anand, V K; Kim, Hyunsoo; Tanatar, Makariy A; Prozorov, Ruslan; Johnston, David C

    2014-10-08

    We present the superconducting and normal state properties of CaPd2Ge2 single crystals investigated by magnetic susceptibility ?, isothermal magnetization M, heat capacity Cp, in-plane electrical resistivity ? and London penetration depth ? versus temperature T and magnetic field H measurements. Bulk superconductivity is inferred from the ?(T) and Cp(T) data. The ?(T) data exhibit metallic behavior and a superconducting transition with Tc onset = 1.98 K and zero resistivity at Tc 0 = 1.67 K. The ?(T) reveals the onset of superconductivity at 2.0 K. For T > 2.0 K, the ?(T) and M(H) are weakly anisotropic paramagnetic with ?ab > ?c. The Cp(T) data confirm the bulk superconductivity below Tc = 1.69(3) K. The superconducting state electronic heat capacity is analyzed within the framework of a single-band ?-model of BCS superconductivity and various normal and superconducting state parameters are estimated. Within the ?-model, the Cp(T) data and the ab plane ?(T) data consistently indicate a moderately anisotropic s-wave gap with ?(0)/kBTc ? 1.6, somewhat smaller than the BCS value of 1.764. The relationship of the heat capacity jump at Tc and the penetration depth measurement to the anisotropy in the s-wave gap is discussed.

  18. Cuprate-titanate superconductor and method for making

    DOE Patents [OSTI]

    Toreki, Robert; Poeppelmeier, Kenneth; Dabrowski, Bogdan

    1995-01-01

    A new copper oxide superconductor of the formula Ln.sub.1-x M.sub.x Sr.sub.2 Cu.sub.3-y Ti.sub.y O.sub.7+.delta. is disclosed, and exhibits a Tc of 60.degree. K. with deviations from linear metallic behavior as high as 130.degree. K.

  19. W. T. Shmayda

    Office of Environmental Management (EM)

    ... Stream activity (nCim 3 ) 1 0 120 160 80 40 0 2 3 Air Target Bay Argon Scrubber To stack ... The TC-TRS is based on classical "burn-and-dry" technology T2515c * All tritiated air ...

  20. Radiation Stability of Benzyl Tributyl Ammonium Chloride towards Technetium-99 Extraction - 13016

    SciTech Connect (OSTI)

    Paviet-Hartmann, Patricia; Horkley, Jared; Campbell, Keri; Roman, Audrey; Nunez, Ana; Espartero, Amparo

    2013-07-01

    A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning processes, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, the UREX process has been developed in the United States to co-extract hexavalent uranium (U) and hepta-valent technetium (Tc) by tri-n-butyl phosphate (TBP). Tc-99 is recognized to be one of the most abundant, long-lived radio-toxic isotopes in UNF (half-life, t{sub 1/2} = 2.13 x 10{sup 5} years), and as such, is targeted in UNF separation strategies for isolation and encapsulation in solid waste-forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste-form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flowsheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste-forms for ultimate disposal. In addition, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste-forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been

  1. Radiation Stability of Benzyl Tributyl Ammonium Chloride Towards Technetium-99 Extraction

    SciTech Connect (OSTI)

    Jared Horkley; Audrey Roman; Keri Campbell; Ana Nunez; Amparo Espartero

    2013-02-01

    A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning process, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, low nitric acid concentration in the aqueous phase of a UREX based process will co-extract U(VI) and Tc(VII) by tri-n-butyl phosphate (TBP). Technetium (Tc-99) is recognized to be one of the most abundant, long-lived radiotoxic isotopes in UNF (half-life, t1/2 = 2.13 × 105 years), and as such, it is targeted in UNF separation strategies for isolation and encapsulation in solid waste forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flow sheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste forms for ultimate disposal. Furthermore, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to

  2. Corrosion mechanisms for metal alloy waste forms: experiment and theory Level 4 Milestone M4FT-14LA0804024 Fuel Cycle Research & Development

    SciTech Connect (OSTI)

    Liu, Xiang-Yang; Taylor, Christopher D.; Kim, Eunja; Goff, George Scott; Kolman, David Gary

    2014-07-31

    This document meets Level 4 Milestone: Corrosion mechanisms for metal alloy waste forms - experiment and theory. A multiphysics model is introduces that will provide the framework for the quantitative prediction of corrosion rates of metallic waste forms incorporating the fission product Tc. The model requires a knowledge of the properties of not only the metallic waste form, but also the passive oxide films that will be generated on the waste form, and the chemistry of the metal/oxide and oxide/environment interfaces. in collaboration with experimental work, the focus of this work is on obtaining these properties from fundamental atomistic models. herein we describe the overall multiphysics model, which is based on MacDonald's point-defect model for passivity. We then present the results of detailed electronic-structure calculations for the determination of the compatibility and properties of Tc when incorporated into intermetallic oxide phases. This work is relevant to the formation of multi-component oxides on metal surfaces that will incorporate Tc, and provide a kinetic barrier to corrosion (i.e. the release of Tc to the environment). Atomistic models that build upon the electronic structure calculations are then described using the modified embedded atom method to simulate metallic dissolution, and Buckingham potentials to perform classical molecular dynamics and statics simulations of the technetium (and, later, iron-technetium) oxide phases. Electrochemical methods were then applied to provide some benchmark information of the corrosion and electrochemical properties of Technetium metal. The results indicate that published information on Tc passivity is not complete and that further investigation is warranted.

  3. Deconfinement as an entropic self-destruction: A solution for the quarkonium suppression puzzle?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kharzeev, Dmitri E.

    2014-10-02

    The entropic approach to dissociation of bound states immersed in strongly coupled systems is developed. In such systems, the excitations of the bound state are often delocalized and characterized by a large entropy, so that the bound state is strongly entangled with the rest of the statistical system. If this entropy S increases with the separation r between the constituents of the bound state, S=S(r), then the resulting entropic force F=T ∂S/∂r (T is temperature) can drive the dissociation process. As a specific example, we consider the case of heavy quarkonium in strongly coupled quark-gluon plasma, where lattice QCD indicatesmore » a large amount of entropy associated with the heavy quark pair at temperatures 0.9Tc ≤ T ≤ 1.5Tc (Tc is the deconfinement temperature); this entropy S(r) grows with the interquark distance r. We argue that the entropic mechanism results in an anomalously strong quarkonium suppression in the temperature range near Tc. This entropic self-destruction may thus explain why the experimentally measured quarkonium nuclear modification factor at RHIC (lower energy density) is smaller than at LHC (higher energy density), possibly resolving the “quarkonium suppression puzzle”—all of the previously known mechanisms of quarkonium dissociation operate more effectively at higher energy densities, and this contradicts the data. As a result, we find that near Tc the entropic force leads to delocalization of the bound hadron states; we argue that this delocalization may be the mechanism underlying deconfinement.« less

  4. Effects of CT-based attenuation correction of rat microSPECT images on relative myocardial perfusion and quantitative tracer uptake

    SciTech Connect (OSTI)

    Strydhorst, Jared H. Ruddy, Terrence D.; Wells, R. Glenn

    2015-04-15

    Purpose: Our goal in this work was to investigate the impact of CT-based attenuation correction on measurements of rat myocardial perfusion with {sup 99m}Tc and {sup 201}Tl single photon emission computed tomography (SPECT). Methods: Eight male Sprague-Dawley rats were injected with {sup 99m}Tc-tetrofosmin and scanned in a small animal pinhole SPECT/CT scanner. Scans were repeated weekly over a period of 5 weeks. Eight additional rats were injected with {sup 201}Tl and also scanned following a similar protocol. The images were reconstructed with and without attenuation correction, and the relative perfusion was analyzed with the commercial cardiac analysis software. The absolute uptake of {sup 99m}Tc in the heart was also quantified with and without attenuation correction. Results: For {sup 99m}Tc imaging, relative segmental perfusion changed by up to +2.1%/−1.8% as a result of attenuation correction. Relative changes of +3.6%/−1.0% were observed for the {sup 201}Tl images. Interscan and inter-rat reproducibilities of relative segmental perfusion were 2.7% and 3.9%, respectively, for the uncorrected {sup 99m}Tc scans, and 3.6% and 4.3%, respectively, for the {sup 201}Tl scans, and were not significantly affected by attenuation correction for either tracer. Attenuation correction also significantly increased the measured absolute uptake of tetrofosmin and significantly altered the relationship between the rat weight and tracer uptake. Conclusions: Our results show that attenuation correction has a small but statistically significant impact on the relative perfusion measurements in some segments of the heart and does not adversely affect reproducibility. Attenuation correction had a small but statistically significant impact on measured absolute tracer uptake.

  5. Technetium Sorption By Cementitious Materials Under Reducing Conditions

    SciTech Connect (OSTI)

    Kaplan, Daniel I.; Estes, Shanna L.; Arai, Yuji; Powell, Brian A.

    2013-07-18

    The objective of this study was to measure Tc sorption to cementitious materials under reducing conditions to simulate Saltstone Disposal Facility conditions. Earlier studies were conducted and the experimental conditions were found not to simulate those of the facility. Through a five month subcontract with Clemson University, sorption of {sup 99}Tc to four cementitious materials was examined within an anaerobic glovebag targeting a 0.1% H{sub 2}(g)/ 99.9% N{sub 2}(g) atmosphere. Early experiments based on Tc sorption and Eh indicated that 0.1% H{sub 2}(g) (a reductant) was necessary to preclude experimental impacts from O{sub 2}(g) diffusion into the glovebag. Preliminary data to date (up to 56 days) indicates that sorption of {sup 99}Tc to cementitious materials increased with increasing slag content for simulated saltstone samples. This is consistent with the conceptual model that redox active sulfide groups within the reducing slag facilitate reduction of Tc(VII) to Tc(IV). These experiments differ from previous experiments where a 2% H{sub 2}(g) atmosphere was maintained (Kaplan et al., 2011 (SRNL-STI-2010-00668)). The impact of the 2% H{sub 2}(g) reducing atmosphere on this data was examined and determined to cause the reduction of Tc in experimental samples without slag. In the present ongoing study, after 56 days, Tc sorption by the 50-year old cement samples (no slag) was undetectable, whereas Tc sorption in the cementitious materials containing slag continues to increase with contact time (measured after 1, 4, 8, 19 and 56 days). Sorption was not consistent with spike concentrations and steady state has not been demonstrated after 56 days. The average conditional K{sub d} value for the Vault 2 cementitious material was 873 mL/g (17% slag), for the TR547 Saltstone (45% slag) the conditional K{sub d} was 168 mL/g, and for TR545 (90% slag) the conditional K{sub d} was 1,619 mL/g. It is anticipated that additional samples will be collected until steady state

  6. Removal of pertechnetate from simulated nuclear waste streams using supported zerovalent iron

    SciTech Connect (OSTI)

    Darab, John; Amonette, Alexandra; Burke, Deborah; Orr, Robert; Ponder, Sherman; Schrick, Bettina; Mallouk, Thomas; Lukens, Wayne; Caulder, Dana; Shuh, David

    2007-07-11

    The application of nanoparticles of predominantly zerovalent iron (nanoiron), either unsupported or supported, to the separation and reduction of pertechnetate anions (TcO4-) from complex waste mixtures was investigated as an alternative approach to current waste-processing schemes. Although applicable to pertechnetate-containing waste streams in general, the research discussed here was directed at two specific potential applications at the U.S. Department of Energy's Hanford Site: (1) the direct removal of pertechnetate from highly alkaline solutions, typical of those found in Hanford tank waste, and (2) the removal of dilute pertechnetate from near-neutral solutions, typical of the eluate streams from commercial organic ion-exchange resins that may be used to remediate Hanford tank wastes. It was envisioned that both applications would involve the subsequent encapsulation of the loaded sorbent material into a separate waste form. A high surface area (>200 M2/g) base-stable, nanocrystalline zirconia was used as a support for nanoiron for tests with highly alkaline solutions, while a silica gel support was used for tests with near-neutral solutions. It was shown that after 24 h of contact time, the high surface area zirconia supported nanoiron sorbent removed about 50percent (K-d = 370 L/kg) of the pertechnetate from a pH 14 tank waste simulant containing 0.51 mM TCO4- and large concentrations of Na+, OH-, NO3-, and CO32- for a phase ratio of 360 L simulant per kg of sorbent. It was also shown that after 18 h of contact time, the silica-supported nanoiron removed>95percent pertechnetate from a neutral pH eluate simulant containing 0.076 mM TcO4_ for a phase ratio of 290 L/kg. It was determined that in all cases, nanoiron reduced the Tc(VII) to Tc(IV), or possibly to Tc(V), through a redox reaction. Finally, it was demonstrated that a mixture of 20 mass percent of the solid reaction products obtained from contacting zirconia- supported nanoiron with an alkaline

  7. WORKSHOP ON DEVELOPMENT OF RADIONUCLIDE GETTERS FOR THE YUCCA MOUNTAIN WASTE REPOSITORY

    SciTech Connect (OSTI)

    K.C. Holt

    2006-03-13

    One of the important that the U.S. Department of Energy (DOE) is currently undertaking is the development of a high-level nuclear waste repository to be located at Yucca Mountain, Nevada. Concern is generated by the Yucca Mountain Project (YMP) is due to potential releases as groundwater contamination, as described in the Total System Performance Assessment (TSPA). The dose to an off-site individual using this groundwater for drinking and irrigation is dominated by four radionuclides: Tc-99, I-127, Np-237, and U-238. Ideally, this dose would be limited to a single radionuclide, U-238; in other words, YMP would resemble a uranium ore body, a common geologic feature in the Western U.S. For this reason and because of uncertainties in the behavior of Tc-99, I-127, and Np-237, it would be helpful to limit the amount of Tc, I, and Np leaving the repository, which would greatly increase the confidence in the long-term performance of YMP. An approach to limiting the migration of Tc, I, and Np that is complementary to the existing YMP repository design plans is to employ sequestering agents or ''getters'' for these radionuclides such that their migration is greatly hindered, thus decreasing the amount of radionuclide leaving the repository. Development of such getters presents a number of significant challenges. The getter must have a high affinity and high selectivity for the radionuclide in question since there is approximately a 20- to 50-fold excess of other fission products and a 1000-fold excess of uranium in addition to the ions present in the groundwater. An even greater challenge is that the getters must function over a period greater than the half-life of the radionuclide (greater than 5 half-lives would be ideal). Typically, materials with a high affinity for Tc, I, or Np are not sufficiently durable. For example, strong-base ion exchange resins have a very high affinity for TcO{sub 4}{sup -} but are not expected to be durable. On the other hand, durable

  8. LABORATORY REPORT ON THE REMOVAL OF PERTECHNETATE FROM TANK 241-AN-105 SIMULANT USING PUROLITE A530E

    SciTech Connect (OSTI)

    DUNCAN JB; HAGERTY KJ, MOORE WP; JOHNSON JM

    2012-04-17

    This report documents the laboratory testing and analyses as directed under the test plan, LAB-PLN-11-00010, Evaluation of Technetium Ion Exchange Material against Hanford Double Shell Tank Supernate Simulate with Pertechnetate. Technetium (Tc-99) is a major fission product from nuclear reactors, and because it has few applications outside of scientific research, most of the technetium will ultimately be disposed of as nuclear waste. The radioactive decay of Tc-99 to ruthenium 99 (Ru-99) produces a low energy {beta}{sup -} particle (0.1 MeV max). However, due to its fairly long half-life (t{sub 1/2} = 2.13E05 years), Tc-99 is a major source of radiation in low-level waste (UCRL-JRNL-212334, Current Status of the Thermodynamic Data for Technetium and its Compounds and Aqueous Species). Technetium forms the soluble oxy anion, TcO{sub 4}{sup -} under aerobic conditions. This anion is very mobile in groundwater and poses a health risk (ANL, Radiological and Chemical Fact Sheets to Support Health Risk Analyses for Contaminated Areas). It has been demonstrated that Purolite{reg_sign} A530E is highly effective in removing TcO{sub 4}{sup -} from a water matrix (RPP-RPT-23199, The Removal of Technetium-99 from the Effluent Treatment Facility Basin 44 Waste Using Purolite A-530E, Reillex HPQ, and Sybron IONAC SR-7 Ion Exchange Resins). Purolite{reg_sign} A530E is the commercial product of the Oak Ridge National Laboratory's Biquat{trademark} resin (Gu, B. et. ai, Development of Novel Bifunctional Anion-Exchange Resins with Improved Selectivity for Pertechnetate Sorption from Contaminated Groundwater). Further work has demonstrated that technetium-loaded A530E achieves a leachability index in Cast Stone of 12.5 (ANSI/ASN-16.1-2003, Measurement of the Leachability of Solidified Low-Level Radioactive Wastes by a Short-term Test Procedure) as reported in RPP-RPT-39195, Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine. This effort falls under

  9. Office of River Protection Advanced Low-Activity Waste Glass Research and Development Plan

    SciTech Connect (OSTI)

    Peeler, David K.; Kim, Dong-Sang; Vienna, John D.; Schweiger, Michael J.; Piepel, Gregory F.

    2015-11-01

    The U.S. Department of Energy Office of River Protection (ORP) has initiated and leads an integrated Advanced Waste Glass (AWG) program to increase the loading of Hanford tank wastes in glass while meeting melter lifetime expectancies and process, regulatory, and product performance requirements. The integrated ORP program is focused on providing a technical, science-based foundation for making key decisions regarding the successful operation of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) facilities in the context of an optimized River Protection Project (RPP) flowsheet. The fundamental data stemming from this program will support development of advanced glass formulations, key product performance and process control models, and tactical processing strategies to ensure safe and successful operations for both the low-activity waste (LAW) and high-level waste vitrification facilities. These activities will be conducted with the objective of improving the overall RPP mission by enhancing flexibility and reducing cost and schedule. The purpose of this advanced LAW glass research and development plan is to identify the near-term, mid-term, and longer-term research and development activities required to develop and validate advanced LAW glasses, property-composition models and their uncertainties, and an advanced glass algorithm to support WTP facility operations, including both Direct Feed LAW and full pretreatment flowsheets. Data are needed to develop, validate, and implement 1) new glass property-composition models and 2) a new glass formulation algorithm. Hence, this plan integrates specific studies associated with increasing the Na2O and SO3/halide concentrations in glass, because these components will ultimately dictate waste loadings for LAW vitrification. Of equal importance is the development of an efficient and economic strategy for 99Tc management. Specific and detailed studies are being implemented to understand the fate of Tc throughout

  10. Nodal to nodeless superconducting energy gap structure change concomitant with Fermi surface reconstruction in the heavy-fermion CeCoIn?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Hyunsoo; Petrovic, C.; Tanatar, M. A.; Flint, R.; Hu, Rongwei; White, B. D.; Lum, I. K.; Maple, M. B.; Prozorov, R.

    2015-01-15

    The London penetration depth ?(T) was measured in single crystals of Ce1xRxCoIn?, R=La, Nd, and Yb down to Tmin ? 50 mK (Tc/Tmin ~50) using a tunnel-diode resonator. In the cleanest samples ??(T) is best described by the power law, ??(T) ? Tn, with n ~ 1, consistent with line nodes. Substitutions of Ce with La, Nd, and Yb lead to similar monotonic suppressions of Tc, however, the effects on ??(T) differ. While La and Nd dopings lead to increase of the exponent n and saturation at n ~ 2, as expected for a dirty nodal superconductor, Yb doping leadsmoreto n > 3, suggesting a change from nodal to nodeless superconductivity. This superconducting gap structure change happens in the same doping range where changes of the Fermi surface topology were reported, implying that the nodal structure and Fermi surface topology are closely linked.less

  11. Radionuclide transport in sandstones with WIPP brine

    SciTech Connect (OSTI)

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01

    Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

  12. Magnetism and superconductivity in U?PtxRh(1x)C?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x.moreThe reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.less

  13. High temperature interface superconductivity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gozar, A.; Bozovic, I.

    2016-01-20

    High-Tc superconductivity at interfaces has a history of more than a couple of decades. In this review we focus our attention on copper-oxide based heterostructures and multi-layers. We first discuss the technique, atomic layer-by-layer molecular beam epitaxy (ALL-MBE) engineering, that enabled High-Tc Interface Superconductivity (HT-IS), and the challenges associated with the realization of high quality interfaces. Then we turn our attention to the experiments which shed light on the structure and properties of interfacial layers, allowing comparison to those of single-phase films and bulk crystals. Both ‘passive’ hetero-structures as well as surface-induced effects by external gating are discussed. Here, wemore » conclude by comparing HT-IS in cuprates and in other classes of materials, especially Fe-based superconductors, and by examining the grand challenges currently laying ahead for the field.« less

  14. Magneto-optical characterizations of FeTe₀̣₅Se₀̣₅ thin films with critical current density over 1 MA/cm²

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Yue; Li, Qiang; Tsuchiya, Yuji; Pyon, Sunseng; Tamegai, Tsuyoshi; Zhang, Cheng; Ozaki, Toshinori

    2014-12-03

    We performed magneto-optical (MO) measurements on FeTe₀̣₅Se₀̣₅ thin films grown on LaAlO₃ (LAO) and Yttria-stabilized zirconia (YSZ) single-crystalline substrates. These thin films show superconducting transition temperature Tc ~19 K, 4 K higher than the bulk sample. Typical roof-top patterns can be observed in the MO images of thin films grown on LAO and YSZ, from which a large and homogeneous critical current density Jc ~ 3 - 4 x 10⁶ A/cm² at 5 K was obtained. In this study, magnetic flux penetration measurement reveals that the current is almost isotropically distributed in the two thin films. Compared with bulk crystals,more » FeTe₀̣₅Se₀̣₅ thin film demonstrates not only higher Tc, but also much larger Jc, which is attractive for applications.« less

  15. Superconducting properties of Rh9In4S4 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Lin, Qisheng; Xie, Weiwei; Taufour, Valentin; Bud'ko, Sergey L.; Miller, Gordon J.; Canfield, Paul C.

    2016-03-28

    The synthesis and crystallographic, thermodynamic, and transport properties of single crystalline Rh9In4S4 were studied. The resistivity, magnetization, and specific heat measurements all clearly indicate bulk superconductivity with a critical temperature, Tc~2.25 K. The Sommerfeld coefficient γ and the Debye temperature (ΘD) were found to be 34 mJ mol–1 K–2 and 217 K, respectively. The observed specific heat jump, ΔC/γTc=1.66, is larger than the expected BCS weak coupling value of 1.43. Ginzburg-Landau (GL) ratio of the low-temperature GL-penetration depth, λGL≈5750 Å, to the GL-coherence length, ξGL≈94 Å, is large: κ ~60. However, we observed a peak effect in the resistivity measurementmore » as a function of both temperature and magnetic field.« less

  16. Characteristics of tropical cyclones in high-resolution models in the present climate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shaevitz, Daniel A.; Camargo, Suzana J.; Sobel, Adam H.; Jonas, Jeffrey A.; Kim, Daehyun; Kumar, Arun; LaRow, Timothy E.; Lim, Young -Kwon; Murakami, Hiroyuki; Reed, Kevin A.; et al

    2014-12-05

    The global characteristics of tropical cyclones (TCs) simulated by several climate models are analyzed and compared with observations. The global climate models were forced by the same sea surface temperature (SST) fields in two types of experiments, using climatological SST and interannually varying SST. TC tracks and intensities are derived from each model's output fields by the group who ran that model, using their own preferred tracking scheme; the study considers the combination of model and tracking scheme as a single modeling system, and compares the properties derived from the different systems. Overall, the observed geographic distribution of global TCmore » frequency was reasonably well reproduced. As expected, with the exception of one model, intensities of the simulated TC were lower than in observations, to a degree that varies considerably across models.« less

  17. Temperature compensated photovoltaic array

    DOE Patents [OSTI]

    Mosher, Dan Michael

    1997-11-18

    A temperature compensated photovoltaic module (20) comprised of a series of solar cells (22) having a thermally activated switch (24) connected in parallel with several of the cells (22). The photovoltaic module (20) is adapted to charge conventional batteries having a temperature coefficient (TC) differing from the temperature coefficient (TC) of the module (20). The calibration temperatures of the switches (24) are chosen whereby the colder the ambient temperature for the module (20), the more switches that are on and form a closed circuit to short the associated solar cells (22). By shorting some of the solar cells (22) as the ambient temperature decreases, the battery being charged by the module (20) is not excessively overcharged at lower temperatures. PV module (20) is an integrated solution that is reliable and inexpensive.

  18. Magnetism and superconductivity in U2PtxRh1?xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. Themorereduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.less

  19. TECHNETIUM SORPTION MEDIA REVIEW

    SciTech Connect (OSTI)

    DUNCAN JB; KELLY SE; ROBBINS RA; ADAMS RD; THORSON MA; HAASS CC

    2011-08-25

    This report presents information and references to aid in the selection of 99Tc sorption media for feasibility studies regarding the removal of 99Tc from Hanford's low activity waste. The report contains literature search material for sorption media (including ion exchange media) for the most tested media to date, including SuperLig 639, Reillex HPQ, TAM (Kruion), Purolite A520E and A530E, and Dowex 1X8. The U.S. Department of Energy (DOE), Office of River Protection (ORP) is responsible for management and completion of the River Protection Project (RPP) mission, which comprises both the Hanford Site tank farms and the Waste Treatment and Immobilization Plant (WTP). The RPP mission is to store, retrieve and treat Hanford's tank waste; store and dispose of treated wastes; and close the tank farm waste management areas and treatment facilities in a safe, environmentally compliant, cost-effective and energy-effective manner.

  20. Effect of proton irradiation on superconductivity in optimally doped BaFe2(As1-xPx)2 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smylie, M. P.; Leroux, M.; Fang, L.; Chmaissem, Omar H.; Claus, H.; Kayani, A.; Snezhko, A.; Welp, U.; Kwok, W. -K.; Mishra, V.; et al

    2016-03-10

    Irradiation with 4 MeV protons was used to systematically introduce defects in single crystals of the iron-arsenide superconductor BaFe2(As1-xPx)2, x = 0.33. The effect of disorder on the low-temperature behavior of the London penetration depth λ(T) and transition temperature Tc was investigated. In nearly optimally doped samples with Tc ~ 29 K, signatures of a superconducting gap with nodes were observed. Contrary to previous reports on electron-irradiated crystals, we do not see a disorder-driven lifting of accidental nodes, and we observe that proton-induced defects are weaker pair breakers than electron-induced defects. Lastly, we attribute our findings to anisotropic electron scatteringmore » caused by proton irradiation defects.« less

  1. Strong interaction between electrons and collective excitations in the multiband superconductor MgB2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mou, Daixiang; Jiang, Rui; Taufour, Valentin; Flint, Rebecca; Bud'ko, S. L.; Canfield, P. C.; Wen, J. S.; Xu, Z. J.; Gu, Genda; Kaminski, Adam

    2015-04-08

    We use a tunable laser angle-resolved photoemission spectroscopy to study the electronic properties of the prototypical multiband BCS superconductor MgB2. Our data reveal a strong renormalization of the dispersion (kink) at ~65meV, which is caused by the coupling of electrons to the E2g phonon mode. In contrast to cuprates, the 65 meV kink in MgB2 does not change significantly across Tc. More interestingly, we observe strong coupling to a second, lower energy collective mode at a binding energy of 10 meV. As a result, this excitation vanishes above Tc and is likely a signature of the elusive Leggett mode.

  2. Goethite Bench-scale and Large-scale Preparation Tests

    SciTech Connect (OSTI)

    Josephson, Gary B.; Westsik, Joseph H.

    2011-10-23

    The Hanford Waste Treatment and Immobilization Plant (WTP) is the keystone for cleanup of high-level radioactive waste from our nation's nuclear defense program. The WTP will process high-level waste from the Hanford tanks and produce immobilized high-level waste glass for disposal at a national repository, low activity waste (LAW) glass, and liquid effluent from the vitrification off-gas scrubbers. The liquid effluent will be stabilized into a secondary waste form (e.g. grout-like material) and disposed on the Hanford site in the Integrated Disposal Facility (IDF) along with the low-activity waste glass. The major long-term environmental impact at Hanford results from technetium that volatilizes from the WTP melters and finally resides in the secondary waste. Laboratory studies have indicated that pertechnetate ({sup 99}TcO{sub 4}{sup -}) can be reduced and captured into a solid solution of {alpha}-FeOOH, goethite (Um 2010). Goethite is a stable mineral and can significantly retard the release of technetium to the environment from the IDF. The laboratory studies were conducted using reaction times of many days, which is typical of environmental subsurface reactions that were the genesis of this new process. This study was the first step in considering adaptation of the slow laboratory steps to a larger-scale and faster process that could be conducted either within the WTP or within the effluent treatment facility (ETF). Two levels of scale-up tests were conducted (25x and 400x). The largest scale-up produced slurries of Fe-rich precipitates that contained rhenium as a nonradioactive surrogate for {sup 99}Tc. The slurries were used in melter tests at Vitreous State Laboratory (VSL) to determine whether captured rhenium was less volatile in the vitrification process than rhenium in an unmodified feed. A critical step in the technetium immobilization process is to chemically reduce Tc(VII) in the pertechnetate (TcO{sub 4}{sup -}) to Tc(Iv)by reaction with the ferrous

  3. Itinerant ferromagnetism in the As 4p conduction band of Ba0.6K0.4Mn2As2 identified by x-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ueland, B. G.; Pandey, Abhishek; Lee, Y.; Sapkota, A.; Choi, Y.; Haskel, D.; Rosenberg, R. A.; Lang, J. C.; Harmon, B. N.; Johnston, D. C.; et al

    2015-05-27

    In this study, x-ray magnetic circular dichroism (XMCD) measurements on single-crystal and powder samples of Ba0.6K0.4Mn2As2 show that the ferromagnetism below TC ≈ 100 K arises in the As 4p conduction band. No XMCD signal is observed at the Mn x-ray absorption edges. Below TC, however, a clear XMCD signal is found at the As K edge which increases with decreasing temperature. The XMCD signal is absent in data taken with the beam directed parallel to the crystallographic c axis indicating that the orbital magnetic moment lies in the basal plane of the tetragonal lattice. These results show that themore » previously reported itinerant ferromagnetism is associated with the As 4p conduction band and that distinct local-moment antiferromagnetism and itinerant ferromagnetism with perpendicular easy axes coexist in this compound at low temperature.« less

  4. Hydrogen Fuel Quality

    SciTech Connect (OSTI)

    Rockward, Tommy

    2012-07-16

    For the past 6 years, open discussions and/or meetings have been held and are still on-going with OEM, Hydrogen Suppliers, other test facilities from the North America Team and International collaborators regarding experimental results, fuel clean-up cost, modeling, and analytical techniques to help determine levels of constituents for the development of an international standard for hydrogen fuel quality (ISO TC197 WG-12). Significant progress has been made. The process for the fuel standard is entering final stages as a result of the technical accomplishments. The objectives are to: (1) Determine the allowable levels of hydrogen fuel contaminants in support of the development of science-based international standards for hydrogen fuel quality (ISO TC197 WG-12); and (2) Validate the ASTM test method for determining low levels of non-hydrogen constituents.

  5. Separation of technetium and rare earth metals for co-decontamination process

    SciTech Connect (OSTI)

    Riddle, Catherine; Martin, Leigh

    2015-05-01

    Poster. In the US there are several technologies under consideration for the separation of the useful components in used nuclear fuel. One such process is the co-decontamination process to separate U, Np and Pu in a single step and produce a Np/ Pu and a U product stream. Although the behavior of the actinide elements is reasonably well defined in this system, the same is not true for the fission products, mainly Zr, Mo, Ru and Tc. As these elements are cationic and anionic they may interact with each other to extract in a manner not predicted by empirical models such as AMUSE. This poster presentation will discuss the initial results of batch contact testing under flowsheet conditions and as a function of varying acidity and flowsheet conditions to optimize recovery of Tc and minimize extraction of Mo, Zr and Ru with the goal of developing a better understanding of the behavior of these elements in the co-decontamination process.

  6. Neutronics parameter variation studies for the Los Alamos ATW concept

    SciTech Connect (OSTI)

    Krohn, B.J.; Perry, R.T.; Sapir, J.L.

    1991-01-01

    The purpose of the Los Alamos ATW (Accelerator Transmutation of nuclear Waste) project is to utilize a high-energy (800--1600 MeV), high current (25--60mA) proton beam to generate a large neutron flux for the transmutation of nuclear wastes. Our theoretical modeling efforts have been directed toward designing a device that will transmute the 2000 kg of Tc and I in the Hanford waste depository along with significant quantities of actinides. Previous system studies have indicated the feasibility of such a device. However, it required thirty years to transmute 2000 kg of Tc and 400 kg of Np. In the present work, we have expanded on the previous study and focused on a device which will significantly reduce the time required for the transmutation of the fission products. 3 refs., 1 tab.

  7. Microbial methods of reducing technetium

    DOE Patents [OSTI]

    Wildung, Raymond E. [Richland, WA; Garland, Thomas R. [Greybull, WY; Gorby, Yuri A. [Richland, WA; Hess, Nancy J. [Benton City, WA; Li, Shu-Mei W. [Richland, WA; Plymale, Andrew E. [Richland, WA

    2001-01-01

    The present invention is directed toward a method for microbial reduction of a technetium compound to form other compounds of value in medical imaging. The technetium compound is combined in a mixture with non-growing microbial cells which contain a technetium-reducing enzyme system, a stabilizing agent and an electron donor in a saline solution under anaerobic conditions. The mixture is substantially free of an inorganic technetium reducing agent and its reduction products. The resulting product is Tc of lower oxidation states, the form of which can be partially controlled by the stabilizing agent. It has been discovered that the microorganisms Shewanella alga, strain Bry and Shewanelia putrifacians, strain CN-32 contain the necessary enzyme systems for technetium reduction and can form both mono nuclear and polynuclear reduced Tc species depending on the stabilizing agent.

  8. Kit for providing a technetium medical radioimaging agent

    DOE Patents [OSTI]

    Wildung, Raymond E.; Garland, Thomas R.; Li, Shu-Mei W.

    2000-01-01

    The present invention is directed toward a kit for microbial reduction of a technetium compound to form other compounds of value in medical imaging. The technetium compound is combined in a mixture with non-growing microbial cells which contain a technetium-reducing enzyme system, a stabilizing agent and an electron donor in a saline solution under anaerobic conditions. The mixture is substantially free of an inorganic technetium reducing agent and its reduction products. The resulting product is Tc of lower oxidation states, the form of which can be partially controlled by the stabilizing agent. It has been discovered that the microorganisms Shewanella alga, strain Bry and Shewanella putrifacians, strain CN-32 contain the necessary enzyme systems for technetium reduction and can form both mono nuclear and polynuclear reduced Tc species depending on the stabilizing agent.

  9. New multifunctional ligands for potential use in the design therapeutic or diagnostic radiopharmaceutical imaging agents

    DOE Patents [OSTI]

    Katti, Kattesh V.; Volkert, Wynn A.; Ketring, Alan R.; Singh, Prahlad R.

    1997-01-01

    A class of diagnostic and therapeutic compounds derived from phosphinimines that include ligands containing either a single phosphinimine functionality or both a phosphinimine group and a phosphine or arsine group, or an aminato group, or a second phosphinimine moiety. These phosphinimine ligands are complexed to early transition metal radionuclides (e.g. .sup.99m Tc or .sup.186 Re/.sup.188 Re) or late transition metals (e.g., .sup.105 Rh or .sup.109 Pd). The complexes with these metals .sup.186 Re/.sup.188 Re, .sup.99m Tc and .sup.109 Pd exhibit a high in vitro and high in vivo stability. The complexes are formed in high yields and can be neutral or charged. These ligands can also be used to form stable compounds with paramagnetic transition metals (e.g. Fe and Mn) for potential use as MRI contrast agents. Applications for the use of ligands and making the ligands are also disclosed.

  10. Model for assessing bronchial mucus transport

    SciTech Connect (OSTI)

    Agnew, J.E.; Bateman, J.R.M.; Pavia, D.; Clarke, S.W.

    1984-02-01

    The authors propose a scheme for the assessment of regional mucus transport using inhaled Tc-99m aerosol particles and quantitative analysis of serial gamma-camera images. The model treats input to inner and intermediate lung regions as the total of initial deposition there plus subsequent transport into these regions from more peripheral airways. It allows for interregional differences in the proportion of particles deposited on the mucus-bearing conducting airways, and does not require a gamma image 24 hr after particle inhalation. Instead, distribution of particles reaching the respiratory bronchioles or alveoli is determined from a Kr-81m ventilation image, while the total amount of such deposition is obtained from 24-hr Tc-99m retention measured with a sensitive counter system. The model is applicable to transport by mucociliary action or by cough, and has been tested in ten normal and ten asthmatic subjects.

  11. Corrosion Tests of LWR Fuels - Nuclide Release

    SciTech Connect (OSTI)

    P.A. Finn; Y. Tsai; J.C. Cunnane

    2001-12-14

    Two BWR fuels [64 and 71 (MWd)/kgU], one of which contained 2% Gd, and two PWR fuels [30 and 45 (MWd)/kgU], are tested by dripping groundwater on the fuels under oxidizing and hydrologically unsaturated conditions for times ranging from 2.4 to 8.2 yr at 90 C. The {sup 99}Tc, {sup 129}I, {sup 137}Cs, {sup 97}Mo, and {sup 90}Sr releases are presented to show the effects of long reaction times and of gadolinium on nuclide release. This investigation showed that the five nuclides at long reaction times have similar fractional release rates and that the presence of 2% Gd reduced the {sup 99}Tc cumulative release fraction by about an order of magnitude over that of a fuel with a similar burnup.

  12. Magnetism and superconductivity in U2PtxRh1-xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U₂PtxRh(1–x)C₂, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U₂Rh₂C₂ of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ≥ 0.9, with Tc increasing with increasing x. Themore » reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  13. Progress Report on the Laboratory Testing of the Bulk Vitrification Cast Refractory

    SciTech Connect (OSTI)

    Pierce, Eric M.; McGrail, B PETER.; Bagaasen, Larry M.; Wellman, Dawn M.; Crum, J V.; Geiszler, Keith N.; Baum, Steven R.

    2004-11-15

    The Hanford Site in southeastern Washington State has been used extensively to produce nuclear materials for the U. S. strategic defense arsenal by the U. S. Department of Energy (DOE). A large inventory of radioactive and mixed waste has accumulated in 177 single- and double-shell tanks. Liquid waste recovered from the tanks will be pre-treated to separate the low-activity fraction from the high-level and transuranic wastes. Currently, the DOE Office of River Protection (ORP) is evaluating several options for immobilization of low-activity tank wastes for eventual disposal in a shallow subsurface facility at the Hanford Site. A significant portion of the waste will be converted into immobilized low-activity waste (ILAW) glass with a conventional Joule-heated ceramic melter. In addition to ILAW glass, supplemental treatment technologies are under consideration by the DOE to treat a portion of the low activity waste. The reason for using this alternative treatment technology is to accelerate the overall cleanup mission at the Hanford site. The ORP selected Bulk Vitrification (BV) for further development and testing. Work in FY03 on engineered and large scale tests of the BV process suggested that approximately 0.3 to as much as 3 wt% of the waste stream 99Tc inventory would end up in a soluble form deposited in a vesicular layer located at the top of the BV melt and in the sand used as an insulator after vitrification. In the FY03 risk assessment (RA) (Mann et al., 2003), the soluble Tc salt in the BV waste packages creates a 99Tc concentration peak at early times in the groundwater extracted from a 100-meter down-gradient well. This peak differs from the presently predicted baseline WTP glass performance, which shows an asymptotic rise to a constant release rate. Because of the desire by regulatory agencies to achieve essentially equivalent performance to WTP glass with supplemental treatment technologies, the BV process was modified in FY04 in an attempt to

  14. New coal technology to flourish at Kentucky plant

    SciTech Connect (OSTI)

    Blankinship, S.

    2007-08-15

    Within four years a 76 MW (net) advanced supercritical coal unit, TC2, will go into service at the Trimble County power plant on the Ohio River near Louiseville, KY, USA. The unit is designed to burn a blend of eastern bituminous and western sub-bituminous Powder River Basin coals. TC2 is one of four US power plants to receive a $125 m tax credit under the 2005 EPACT Qualifying Advanced Coal Program for high efficiency and low emission generating units. Trimble County is owned and operated by E.ON US subsidiaries Kentucky Utilities and Louiseville Gas & Electric. It was originally designed to accommodate four 500 MW coal-fired units fired by bituminous coal from the Illinois Basin. 1 photo.

  15. Protocol for Identifying the Presence of and Understanding the Nature of Soluble, Non-pertechnetate Technetium in Hanford Tank Supernatants

    SciTech Connect (OSTI)

    Rapko, Brian M.

    2014-02-27

    The objective of this report is to propose a method to evaluate the presence and extent of soluble, non-pertechnetate Tc in Hanford tank supernatants as well as methods that might be used to gain insight as to the nature of the specie(s) that make up this fraction. This study will then provide a recommendation as to the preferred approach for identifying and quantifying the presence of Hanford tank supernatant-soluble, non-pertechnetate, technetium. The recommendation will also describe an approach to address the issue of whether inductively coupled plasma mass spectrometry (ICP-MS) analysis, which is useful as a monitoring tool for Tc, may be confounded by the presence of other mass 99 species.

  16. Two-dimensional resonant magnetic excitation in BaFe1.84Co0.16As2

    SciTech Connect (OSTI)

    Lumsden, Mark D; Christianson, Andrew D; Parshall, Daniel; Stone, Matthew B; Nagler, Stephen E; Mook Jr, Herbert A; Lokshin, Konstantin A; Egami, Takeshi; Abernathy, Douglas L; Goremychkin, E. A.; Osborn, R.; McGuire, Michael A; Safa-Sefat, Athena; Jin, Rongying; Sales, Brian C; Mandrus, David

    2009-01-01

    Inelastic neutron scattering measurements on single crystals of superconducting BaFe1.84Co0.16As2 clearly reveal a magnetic excitation located at wavevectors (1/2 1/2 L) in tetragonal notation. The scattering is much broader in L than are spin waves observed in the parent compound BaFe2As2 indicating that the excitations in the superconducting material are more two-dimensional in nature. The excitation appears gapless for T > TC and becomes gapped on cooling below TC. The observed gap energy is approximately 9.6 meV corresponding to 5 kBTC which is remarkably similar to the canonical value for the resonance energy in the cuprates.

  17. Orbital glass state of the nearly metallic spinel cobalt vanadate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Koborinai, R.; Dissanayake, Sachith E.; Reehuis, M.; Matsuda, Masaaki; Kajita, T.; Kuwahara, H.; Lee, Seung -Hun; Katsufuji, T.

    2016-01-19

    Strain, magnetization, dielectric relaxation, and unpolarized and polarized neutron diffraction measurements were performed to study the magnetic and structural properties of spinel Co1–xV2+xO4. The strain measurement indicates that, upon cooling, ΔL/L in the order of ~10–4 starts increasing below TC, becomes maximum at Tmax, and then decreases and changes its sign at T*. Neutron measurements indicate that a collinear ferrimagnetic order develops below TC and upon further cooling noncollinear ferrimagnetic ordering occurs below Tmax. At low temperatures, the dielectric constant exhibits a frequency dependence, indicating slow dynamics. Lastly, these results indicate the existence of an orbital glassy state at lowmore » temperatures in this nearly metallic frustrated magnet.« less

  18. Analysis of molybdenum-99 production capability in the materials test station

    SciTech Connect (OSTI)

    Pitcher, Eric J

    2009-01-01

    The United States of America currently relies on foreign suppliers to meet all of it needs for molybdenum-99 (Mo-99) used in medical diagnostic procedures. The current US demand is at least 5000 six-day curies per week. Neutronics calculations have been performed to assess whether the proposed Materials Test Station (MTS) could potentially generate Mo-99. Two target material options have been explored for Mo-99 production in the MTS: low enriched uranium (LEU) and Tc-99. For LEU, scoping calculations indicate that MTS can supply nearly half of the current US demand with only minor neutronic impact on the MTS primary mission. For the Tc-99 option, the MTS could produce about one-tenth of the US demand.

  19. 57Fe Mössbauer study of Lu2Fe3Si5 iron silicide superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ma, Xiaoming; Ran, Sheng; Pang, Hua; Li, Fashen; Canfield, Paul C.; Bud'ko, Sergey L.

    2015-08-01

    With the advent of Fe–As based superconductivity it has become important to study how superconductivity manifests itself in details of 57Fe Mössbauer spectroscopy of conventional, Fe-bearing superconductors. The iron-based superconductor Lu2Fe3Si5 has been studied by 57Fe Mössbauer spectroscopy over the temperature range from 4.4 K to room temperature with particular attention to the region close to the superconducting transition temperature (Tc=6.1 K). Consistent with the two crystallographic sites for Fe in this structure, the observed spectra appear to have a pattern consisting of two doublets over the whole temperature range. Furthermore, the value of Debye temperature was estimated from temperaturemore » dependence of the isomer shift and the total spectral area and compared with the specific heat capacity data. Neither abnormal behavior of the hyperfine parameters at or near Tc, nor phonon softening were observed.« less

  20. A Linked-Cell Domain Decomposition Method for Molecular Dynamics Simulation on a Scalable Multiprocessor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, L. H.; Brooks III, E. D.; Belak, J.

    1992-01-01

    A molecular dynamics algorithm for performing large-scale simulations using the Parallel C Preprocessor (PCP) programming paradigm on the BBN TC2000, a massively parallel computer, is discussed. The algorithm uses a linked-cell data structure to obtain the near neighbors of each atom as time evoles. Each processor is assigned to a geometric domain containing many subcells and the storage for that domain is private to the processor. Within this scheme, the interdomain (i.e., interprocessor) communication is minimized.

  1. Interagency Advanced Power Group meeting minutes

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This document contains the minutes and viewgraphs from a meeting of military personnel on the subject of power generation and distribution systems for military applications. Topics include heating and cooling systems for standard shelters, SDIO power programs, solar dynamic space power systems, hybrid solar dynamic/ photovoltaic systems, pulsed power technology, high-{Tc} superconductors, and actuators and other electronic equipment for aerospace vehicles. Attendees represented the US Air Force, Army, Navy, and NASA. (GHH)

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectro-microscopic Measurements of Carbonaceous Aerosol Aging in Central California Download a printable PDF Submitter: Gilles, M., Lawrence Berkeley National Laboratory Moffet, R., University of the Pacific Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Moffet RC, TC Rödel, ST Kelly, XY Yu, GT Carroll, J Fast, RA Zaveri, A Laskin, and MK Gilles. 2013. "Spectro-microscopic measurements of carbonaceous aerosol aging in Central California."

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Light Absorption of Primary Organic Aerosol Paper Named ACS Editors' Choice Download a printable PDF Submitter: Lu, Z., Argonne National Laboratory Streets, D. ., Argonne National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Lu Z, DG Streets, E Winijkul, F Yan, Y Chen, TC Bond, Y Feng, MK Dubey, S Liu, JP Pinto, and GR Carmichael. 2015. "Light absorption properties and radiative effects of primary organic aerosol emissions."

  4. Gensheng Wang | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gensheng Wang Assistant Physicist Summary of Research Gensheng Wang is an Assistant Physicist at High Energy Physics division. His scientific interests are precision measurements of the Cosmic Microwave Background (CMB), Dark Matter (DM) particle searches, and Neutrino-Less Double Beta Decay (NLDBD) searches. He worked on CDMS and SPTpol before. Most recently, he is working on SPT-3G TES bolometric detector array for CMB and low-Tc TES detector for NLDBD. Wang has expertise on cryogenic

  5. Interagency Advanced Power Group meeting minutes

    SciTech Connect (OSTI)

    Not Available

    1991-12-31

    This document contains the minutes and viewgraphs from a meeting of military personnel on the subject of power generation and distribution systems for military applications. Topics include heating and cooling systems for standard shelters, SDIO power programs, solar dynamic space power systems, hybrid solar dynamic/ photovoltaic systems, pulsed power technology, high-{Tc} superconductors, and actuators and other electronic equipment for aerospace vehicles. Attendees represented the US Air Force, Army, Navy, and NASA. (GHH)

  6. Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    L-1 APPENDIX L GROUNDWATER FLOW FIELD DEVELOPMENT This appendix describes the development of the regional-scale groundwater flow field used for the groundwater modeling that supports assessment of the groundwater quality impacts discussed in the Draft and Final Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (TC & WM EIS), Chapters 5 and 6 and Appendices O and V. Included are an overview of groundwater flow at the site; the purpose

  7. Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Volume 3, Book 1 Section 1: Overview Section 2: Topics of Interest Section 3: Individual Commentors U.S. Department of Energy November 2012 1 Cover Sheet Responsible Agency: U.S. Department of Energy (DOE) Cooperating Agencies: Washington State Department of Ecology (Ecology) U.S. Environmental Protection Agency (EPA) Title: Final Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (TC & WM EIS) (DOE/EIS-0391) Location: Benton County,

  8. Separation of uranium from technetium in recovery of spent nuclear fuel

    DOE Patents [OSTI]

    Pruett, David J. (Knoxville, TN); McTaggart, Donald R. (Knoxville, TN)

    1984-01-01

    Uranium and technetium in the product stream of the Purex process for recovery of uranium in spent nuclear fuel are separated by (1) contacting the aqueous Purex product stream with hydrazine to reduce Tc.sup.+7 therein to a reduced species, and (2) contacting said aqueous stream with an organic phase containing tributyl phosphate and an organic diluent to extract uranium from said aqueous stream into said organic phase.

  9. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity Print Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless electrical transmission or magnetically levitated trains become. Scientists thought

  10. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity Print Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless electrical transmission or magnetically levitated trains become. Scientists thought

  11. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity A New Universal Parameter for Superconductivity Print Thursday, 14 April 2016 00:00 Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless

  12. Superconducting submillimeter and millimeter wave detectors

    SciTech Connect (OSTI)

    Nahum, M.

    1992-10-20

    The series of projects described in this dissertation was stimulated by the discovery of high temperature superconductivity. Our goal was to develop useful applications which would be competitive with the current state of technology. The high-[Tc] microbolometer was developed into the most sensitive direct detector of millimeter waves, when operated at liquid nitrogen temperatures. The thermal boundary resistance of thin YBa[sub 2]Cu[sub 3]0[sub 7-[delta

  13. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity Print Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless electrical transmission or magnetically levitated trains become. Scientists thought

  14. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity Print Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless electrical transmission or magnetically levitated trains become. Scientists thought

  15. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity Print Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless electrical transmission or magnetically levitated trains become. Scientists thought

  16. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity Print Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless electrical transmission or magnetically levitated trains become. Scientists thought

  17. A New Universal Parameter for Superconductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Universal Parameter for Superconductivity Print Scientists have been researching high-temperature (high-Tc) superconductors for decades with the goal of finding materials that express superconducting capabilities at room temperature, which would be a requirement for practical and cost-effective applications. The higher the operating temperature, the more realistic energy-saving applications such as lossless electrical transmission or magnetically levitated trains become. Scientists thought

  18. Radiochemical analysis using Empore{trademark} Rad Disks.

    SciTech Connect (OSTI)

    Smith, L. L.

    1999-06-07

    A solid-phase extraction technique that isolates specific radionuclides (i.e., {sup 89/90}Sr, {sup 226/228}Ra, {sup 99}Tc) from surface, ground, and drinking waters is described. The analyte is isolated by pulling a sample through an appropriate Empore{trademark} Rad Disk with a vacuum, and the disk is subsequently assayed by a suitable counting technique. The method has both laboratory and field applications. Interferences are discussed.

  19. HEU Minimization and the Reliable Supply of Medical Isotopes Nuclear

    National Nuclear Security Administration (NNSA)

    Security Summit: Fact Sheet | National Nuclear Security Administration | (NNSA) HEU Minimization and the Reliable Supply of Medical Isotopes Nuclear Security Summit: Fact Sheet March 26, 2012 Molybdenum-99 (Mo-99) is used to produce technetium-99m (Tc-99m), a medical isotope that is used in about 100,000 diagnostic medical procedures globally every day. Today, Mo-99 is produced at aging facilities in Europe, Canada and South Africa primarily using highly-enriched uranium (HEU) - a

  20. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first