National Library of Energy BETA

Sample records for tars absorption oils

  1. Secure Fuels from Domestic Resources - Oil Shale and Tar Sands...

    Office of Environmental Management (EM)

    Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Profiles of Companies Engaged in Domestic Oil Shale ...

  2. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  3. Heavy oil and tar sands recovery and upgrading. International technology

    SciTech Connect (OSTI)

    Schumacher, M.M.

    1982-01-01

    This work provides an in-depth assessment of international technology for the recovery and upgrading of heavy crude oil and tar sands. The technologies included are currently in use, under development, or planned; emphasis is placed on post-1978 activities. The heavy oil technologies and processes considered include methods relating to the exploitation of heavy oil reservoirs, such as production from underground workings, all types of improved or enhanced recovery, subsurface extraction, and well rate stimulation. The tar sands section includes sizing the resource base and reviewing and evaluating past, present, and planned research and field developments on processes for mining, producing, extracting, and upgrading very heavy oils recovered from tar sands, e.g., bitumen recovery from tar sands where primary production was impossible because of the oil's high viscosity. 616 references.

  4. Heavy oil and tar sands recovery and upgrading: international technology

    SciTech Connect (OSTI)

    Schumacher, M.M.

    1982-01-01

    This book provides an in-depth assessment of international technology for the recovery and upgrading of heavy crude oil and tar sands. The technologies included are currently in use, under development, or planned; emphasis is placed on post-1978 activities. The heavy oil technologies and processes considered in Part I include methods relating to the exploitation of heavy oil reservoirs, such as production from undergorun workings, all types of improved or enhanced recovery, subsurface extraction, and well rate stimulation. Furthermore, even though heavy crudes are understood to include only those liquid or semiliquid hydrocarbons with a gravity of 20/sup 0/API or less, technology applied to lighter crude oils with in situ viscosities of the same order of magnitude as some US heavy oils is also included. The scope of the tar sands section (Part II) includes sizing the resource base and reviewing and evaluatin past, present, and planned research and field developments on processes for mining, producing, extracting, and upgrading very heavy oils recovered from tar sands, e.g., bitumen recovery from tar sands where primary production was impossible because of the oil's high viscosity. On the production side, very heavy oil is defined as having a gravity less than 10/sup 0/ to 12/sup 0/API and greater than 100,000-centipoise viscosity at 50/sup 0/F. On the upgrading side, hydrocarbons whose characteristics dictated additional processing prior to conventional refining into salable products (1050+/sup 0/ material) were included, regardless of origin, in order to encompass all pertinent upgrading technologies.

  5. In situ recovery of oil from Utah tar sand: a summary of tar sand research at the Laramie Energy Technology Center

    SciTech Connect (OSTI)

    Marchant, L.C.; Westhoff, J.D.

    1985-10-01

    This report describes work done by the United States Department of Energy's Laramie Energy Technology Center from 1971 through 1982 to develop technology for future recovery of oil from US tar sands. Work was concentrated on major US tar sand deposits that are found in Utah. Major objectives of the program were as follows: determine the feasibility of in situ recovery methods applied to tar sand deposits; and establish a system for classifying tar sand deposits relative to those characteristics that would affect the design and operation of various in situ recovery processes. Contents of this report include: (1) characterization of Utah tar sand; (2) laboratory extraction studies relative to Utah tar sand in situ methods; (3) geological site evaluation; (4) environmental assessments and water availability; (5) reverse combustion field experiment, TS-1C; (6) a reverse combustion followed by forward combustion field experiment, TS-2C; (7) tar sand permeability enhancement studies; (8) two-well steam injection experiment; (9) in situ steam-flood experiment, TS-1S; (10) design of a tar sand field experiment for air-stream co-injection, TS-4; (11) wastewater treatment and oil analyses; (12) economic evaluation of an in situ tar sand recovery process; and (13) appendix I (extraction studies involving Utah tar sands, surface methods). 70 figs., 68 tabs.

  6. Paleontological overview of oil shale and tar sands areas in Colorado, Utah, and Wyoming.

    SciTech Connect (OSTI)

    Murphey, P. C.; Daitch, D.; Environmental Science Division

    2009-02-11

    In August 2005, the U.S. Congress enacted the Energy Policy Act of 2005, Public Law 109-58. In Section 369 of this Act, also known as the ''Oil Shale, Tar Sands, and Other Strategic Unconventional Fuels Act of 2005,'' Congress declared that oil shale and tar sands (and other unconventional fuels) are strategically important domestic energy resources that should be developed to reduce the nation's growing dependence on oil from politically and economically unstable foreign sources. In addition, Congress declared that both research- and commercial-scale development of oil shale and tar sands should (1) be conducted in an environmentally sound manner using management practices that will minimize potential impacts, (2) occur with an emphasis on sustainability, and (3) benefit the United States while taking into account concerns of the affected states and communities. To support this declaration of policy, Congress directed the Secretary of the Interior to undertake a series of steps, several of which are directly related to the development of a commercial leasing program for oil shale and tar sands. One of these steps was the completion of a programmatic environmental impact statement (PEIS) to analyze the impacts of a commercial leasing program for oil shale and tar sands resources on public lands, with an emphasis on the most geologically prospective lands in Colorado, Utah, and Wyoming. For oil shale, the scope of the PEIS analysis includes public lands within the Green River, Washakie, Uinta, and Piceance Creek Basins. For tar sands, the scope includes Special Tar Sand Areas (STSAs) located in Utah. This paleontological resources overview report was prepared in support of the Oil Shale and Tar Sands Resource Management Plan Amendments to Address Land Use Allocations in Colorado, Utah, and Wyoming and PEIS, and it is intended to be used by Bureau of Land Management (BLM) regional paleontologists and field office staff to support future projectspecific analyses

  7. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research

    SciTech Connect (OSTI)

    Speight, J.G.

    1992-01-01

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  8. Class I cultural resource overview for oil shale and tar sands areas in Colorado, Utah and Wyoming.

    SciTech Connect (OSTI)

    O'Rourke, D.; Kullen, D.; Gierek, L.; Wescott, K.; Greby, M.; Anast, G.; Nesta, M.; Walston, L.; Tate, R.; Azzarello, A.; Vinikour, B.; Van Lonkhuyzen, B.; Quinn, J.; Yuen, R.; Environmental Science Division

    2007-11-01

    In August 2005, the U.S. Congress enacted the Energy Policy Act of 2005, Public Law 109-58. In Section 369 of this Act, also known as the 'Oil Shale, Tar Sands, and Other Strategic Unconventional Fuels Act of 2005', Congress declared that oil shale and tar sands (and other unconventional fuels) are strategically important domestic energy resources that should be developed to reduce the nation's growing dependence on oil from politically and economically unstable foreign sources. The Bureau of Land Management (BLM) is developing a Programmatic Environmental Impact Statement (PEIS) to evaluate alternatives for establishing commercial oil shale and tar sands leasing programs in Colorado, Wyoming, and Utah. This PEIS evaluates the potential impacts of alternatives identifying BLM-administered lands as available for application for commercial leasing of oil shale resources within the three states and of tar sands resources within Utah. The scope of the analysis of the PEIS also includes an assessment of the potential effects of future commercial leasing. This Class I cultural resources study is in support of the Draft Oil Shale and Tar Sands Resource Management Plan Amendments to Address Land Use Allocations in Colorado, Utah, and Wyoming and Programmatic Environmental Impact Statement and is an attempt to synthesize archaeological data covering the most geologically prospective lands for oil shale and tar sands in Colorado, Utah, and Wyoming. This report is based solely on geographic information system (GIS) data held by the Colorado, Utah, and Wyoming State Historic Preservation Offices (SHPOs). The GIS data include the information that the BLM has provided to the SHPOs. The primary purpose of the Class I cultural resources overview is to provide information on the affected environment for the PEIS. Furthermore, this report provides recommendations to support planning decisions and the management of cultural resources that could be impacted by future oil shale and tar

  9. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  10. Future directions in advanced exploratory research related to oil, gas, shale and tar sand resources

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The Office of Technical Coordination (OTC) is responsible for long-range, high-risk research that could provide major advances in technologies for the use of fossil fuels. In late 1986, OTC was given responsibility for an existing program of research in Advanced Process Technology (APT) for oil, gas, shale, and tar sands. To meet these challenges and opportunities, the OTC approached the National Research Council with a request to organize an advisory panel to examine future directions in fundamental research appropriate for sponsorship by the Advanced Process Technology program. An advisory group was formed with broad representation from the geosciences, physical sciences, and engineering disciplines to accomplish this task. The charge to the panel was to prepare a report for the director of the Office of Technical Coordination, identifying critical research areas. This report contains the findings and recommendations of the panel. It is written both to advise the research management of the Department of Energy on research opportunities and needs, and to stimulate interest and involvement in the research community in fundamental research related to fossil energy, and in particular, oil and gas resources. 1 tab.

  11. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, October--December 1992

    SciTech Connect (OSTI)

    Speight, J.G.

    1992-12-31

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  12. U. S. Department of Energy (DOE) research and development programs for heavy oil and tar sand recovery

    SciTech Connect (OSTI)

    Anderson, H.R.

    1981-01-01

    The main emphasis of the DOE tar sand program described is to develop in situ techniques capable of recovering bitumen from domestic tar sand deposits. This program primarily involves field experiments of in situ techniques (in situ combustion and steam drive). Supporting activities include resource assessment, upgrading and surface processing research, and environmental permitting and control. 5 refs.

  13. Oil shales and tar sands: a bibliography. Supplement 2, Parts 1 and 2

    SciTech Connect (OSTI)

    Grissom, M.C.

    1984-07-01

    This bibliography includes 4715 citations arranged in the broad subject categories: reserves and exploration; site geology and hydrology; drilling, fracturing, and mining; oil production, recovery, and refining; properties and composition; direct uses and by-products; health and safety; marketing and economics; waste research and management; environmental aspects; regulations; and general. There are corporate, author, subject, contract number, and report number indexes.

  14. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, July--September 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  15. Tar loads on Omani beaches

    SciTech Connect (OSTI)

    Badawy, M.I.; Al-Harthy, F.T. )

    1991-11-01

    Owing to Oman's geographic position and long coastal line, the coastal areas of Oman are particularly vulnerable to oil pollution from normal tanker operations, illegal discharges, and accidental spills as well as local sources of oil input. UNEP carried out a survey on the coasts of Oman to determine the major sources of oil pollution and concluded that the major shoreline pollution problems in Oman arose from operational discharges of oil from passing vessels traffic. The oil, because of the high sea and air temperatures in the area, was subjected to relatively high rates of evaporation and photo-oxidation and tended to arrive at the coast as heavy petroleum particulate residues (tar balls). The aim of the present study was to measure the loads of tar balls in Omani coastal areas and to identify the source of oil pollutants on beaches.

  16. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  17. The extraction of bitumen from western tar sands. Annual report

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  18. The extraction of bitumen from western tar sands

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  19. Future of heavy crude and tar sands

    SciTech Connect (OSTI)

    Meyer, R.F.; Steele, C.T.

    1981-01-01

    The 106 papers which were presented at the First International Conference on the Future of Heavy Crude and Tar Sands, held in Edmonton, Alberta are incorporated in this volume. They are grouped under the following sections: (1) role of heavy crude oils and tar sands in world energy; (2) major known occurrences; (3) chemistry and geochemistry; (4) geology; (5) resource evaluation techniques; (6) production research and pilot projects; (7) current production; (8) upgrading and refining; (9) transportation; (10) environmental research; (11) economics; (12) technological problems; (13) institutional factors; and (14) bibliography. All papers have been abstracted and indexed. (ATT)

  20. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, J.D.; Harak, A.E.

    1988-05-04

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

  1. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, James D.; Harak, Arnold E.

    1989-01-01

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

  2. Assessment of tar pollution on the United Arab emirates beaches

    SciTech Connect (OSTI)

    Abu-Hilal, A.H.; Khordagui, H.K. )

    1993-01-01

    In light of the inadequate information concerning stranded tar on the southwest beaches of the Arabian Gulf and the Gulf of Oman, particularly following the massive oil releases during the Gulf War, the present investigation was designed to provide reference-integrated information on the nature, location, and levels of stranded tar balls on the beaches of the United Arab Emirates (UAE). The recorded levels appeared to be higher than expected or previously reported. The tar distribution pattern, in addition to the degree of weathering, indicates that the massive oil release during the Gulf War did not reach the UAE shorelines. The highest reported levels of stranded tar ever recorded in the Arabian Gulf at Jabal Dhannah apparently originated from oil spills and tankers' ballast water at the main oil terminal at the Al-Ruwaiss oil refinery some 10 km to the east. The surprising, relatively high levels of stranded tar on the beaches of the Gulf of Oman were solely attributed to the heavy navigation traffic close to the shorelines. 19 refs., 2 figs., 3 tabs.

  3. The extraction of bitumen from western tar sands. Annual report, July 1990--July 1991

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-04-01

    Contents of this report include the following: executive summary; characterization of the native bitumen from the Whiterocks oil sand deposit; influence of carboxylic acid content on bitumen viscosity; water based oil sand separation technology; extraction of bitumen from western oil sands by an energy-efficient thermal method; large- diameter fluidized bed reactor studies; rotary kiln pyrolysis of oil sand; catalytic upgrading of bitumen and bitumen derived liquids; ebullieted bed hydrotreating and hydrocracking; super critical fluid extraction; bitumen upgrading; 232 references; Appendix A--Whiterocks tar sand deposit bibliography; Appendix B--Asphalt Ridge tar sand deposit bibliography; and Appendix C--University of Utah tar sands bibliography.

  4. Centrifuge treatment of coal tar

    SciTech Connect (OSTI)

    L.A. Kazak; V.Z. Kaidalov; L.F. Syrova; O.S. Miroshnichenko; A.S. Minakov

    2009-07-15

    New technology is required for the removal of water and heavy fractions from regular coal tar. Centrifuges offer the best option. Purification of coal tar by means of centrifuges at OAO NLMK permits the production of pitch coke or electrode pitch that complies with current standards.

  5. Solvent extraction of Southern US tar sands

    SciTech Connect (OSTI)

    Penney, W.R.

    1990-01-01

    The Department of Chemical Engineering at the University of Arkansas, in association with Diversified Petroleum Recovery, Inc. (DPR) of Little Rock, Arkansas, has been developing a solvent extraction process for the recovery of bitumen from tar sands for the past five years. The unique feature of the process is that the bitumen is recovered from the solvent by contacting with a co-solvent, which causes the bitumen to precipitate. The overall purpose of this project is to study both the technical and economic feasibility of applying this technology for recovery of bitumen from tar sands by (1) investigating the socioeconmic factors which affect (a) plant siting and (b) the market value of recovered bitumen; (2) operating a process demonstration unit at the rate of 1 lb/hr recovered bitumen while producing clean sand and recyclable solvents; and (3) determine the economic conditions which will make a bitumen recovery project economical. DPR has analyzed the historical trends of domestic production, consumption, discoveries and reserves of crude oil. They have started an investigation of the volatility in the price of crude oil and of gasoline prices and of the differential between gasoline and crude oil. DPR continues to analyze the geographical movement and demand for asphalt products. Utah does not appear economically attractive as a site for a bitumen from tar sands asphalt plant. Oklahoma sites are now being studied. This report also contains the quarterly progress report from a University of Nevada study to determine bitumen composition, oxygen uptake rates, and viscosities of Alabama and Utah bitumens. Both reports have been indexed separately for inclusion on the data base.

  6. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  7. Turbine fuels from tar sands bitumen and heavy oil. Phase I. Preliminary process analysis. Interim report, 8 July 1983-9 April 1984

    SciTech Connect (OSTI)

    Talbot, A.F.; Elanchenny, V.; Macris, A.; Schwedock, J.P.

    1985-04-09

    The strategic potential of domestic bitumens and heavy crude oils as substitutes for imported crude rests with their efficient conversion into aviation turbine fuels. In this Phase I study, preliminary analyses of several processing schemes were performed. The comparison included both hydrogen-addition and carbon-rejection upgrading processes. Projected JP-4 yields, costs, and thermal efficiencies suggest further exploration of the hydrovisbreaking process. For Phase II, laboratory-scale demonstration of the recommended process is proposed.

  8. Heavy liquid beneficiation developed for Alabama tar sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    The tar sand deposits in the State of Alabama contain about 1.8 billion barrels of measured and more than 4 billion barrels of speculative in-place bitumen. A comprehensive research program is in progress for the separation of bitumen from these deposits. In general, Alabama tar sands are oil wetted, low grade and highly viscous in nature. In view of these facts, a beneficiation strategy has been developed to recover bitumen enriched concentrate which can be used as a feed material for further processing. Heavy liquid separation tests and results are discussed. A 77% zinc bromide solution, specific gravity of 2.4, was used for the tests. 2 figures.

  9. GJO-2001-208-TAR

    Office of Legacy Management (LM)

    GJO-2001-208-TAR MAC-GWSHP 11.7-1 UMTRA Ground Water Project Biological Assessment for Ground Water Remediation at the Shiprock Site Final April 2001 Prepared by U.S. Department of ...

  10. Treating tar sands formations with karsted zones

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-03-09

    Methods for treating a tar sands formation are described herein. The tar sands formation may have one or more karsted zones. Methods may include providing heat from one or more heaters to one or more karsted zones of the tar sands formation to mobilize fluids in the formation. At least some of the mobilized fluids may be produced from the formation.

  11. EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 02 PETROLEUM; 04 OIL SHALES AND TAR SANDS; API GRAVITY; BOILING POINTS; MOLECULAR WEIGHT; OIL SANDS; PETROLEUM; PHYSICAL PROPERTIES; STEAM; TESTING; ...

  12. Process for hydrogenation of hydrocarbon tars

    DOE Patents [OSTI]

    Dolbear, Geoffrey E.

    1978-07-18

    Hydrocarbon tars of high asphaltene content such as tars obtained from pyrolysis of coal are dissolved in a solvent formed from the hydrogenation of the coal tars, and the resultant mixture hydrogenated in the presence of a catalyst at a pressure from about 1500 to 5000 psig at a temperature from about 500.degree. F to about the critical temperature of the solvent to form a light hydrocarbon as a solvent for the tars. Hydrogen content is at least three times the amount of hydrogen consumed.

  13. Catalyst specificities in high pressure hydroprocessing of pyrolysis and gasification tars

    SciTech Connect (OSTI)

    Soltes, E.J.; Lin, S.C.K.; Sheu, Y.H.E.

    1987-04-01

    Over a period of several years, the Department of Forest Science at Texas A and M University has been conducting studies in the hydroprocessing (catalytic high pressure hydrotreating or hydrodeoxygenation accompanied by hydrocracking) of pyrolytic tars produced in biomass pyrolysis and gasification. Upgrading through hydroprocessing results in good yields of volatile hydrocarbon and phenolic products. This paper compares the performance of twenty different catalysts selected for hydroprocessing of a pine pyrolysis oil, describes the use of noble metal catalysts with tars produced from nine different biomass feedstocks (oil from pine pyrolysis and the tars from pine wood chip, pine plywood trim, pecan shell, peanut shell, sugarcane bagasse, corncob, rice hull, and cottonseed hull gasification), and compares the use of several catalysts in a trickle bed reactor for kinetic studies of the hyroprocessing reaction.

  14. G JO-2001-283-TAR

    Office of Legacy Management (LM)

    JO-2001-283-TAR MAGLREP 6.3.1-4 Long-Term Surveillance and Maintenance Program 2001 Annual ... MAC-LREP 6 . 3 . 1 4 Long-Term Surveillance and Maintenance Program 2001 Annual Site ...

  15. Treating tar sands formations with dolomite

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-06-08

    Methods for treating a tar sands formation are described herein. The tar sands formation may include dolomite and hydrocarbons. Methods may include providing heat at less than the decomposition temperature of dolomite from one or more heaters to at least a portion of the formation. At least some of the hydrocarbon fluids are mobilized in the formation. At least some of the hydrocarbon fluids may be produced from the formation.

  16. Strategic Significance of Americas Oil Shale Resource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... When the petroleum production peak occurs, the consequences will be severe if import-depen... unconventional fossil energy sources, namely liquids from oil shale, coal, and tar sand. ...

  17. Tar Sands | Open Energy Information

    Open Energy Info (EERE)

    jobs are considered, an even larger job growth number is found. The net value of oil sands rose from 1.3 billion to 22.8 billion over that same period. This resulted in a...

  18. II international conference on heavy crude and tar sands. Summary report

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The Second International Conference on Heavy Crude and Tar Sands clearly demonstrated that the world has abundant heavy and extra heavy crudes that will sustain the petroleum age for decades. Perhaps even more important for many developed and developing countries is that these resources are widely distributed throughout the world, for deposits are known to exist in at least forty-nine countries. Moreover, the rapid expansion over the last two and a half years of knowledge of the magnitude of these resources suggests there is much more to be added to the world's list of useful energy assets. The current ample supply of crude oil does not appear to have lessened the resolve to develop heavy crude and tar sands. Major industrial countries are eager to develop their heavy oil resources to free themselves from dependence on OPEC and the developing nations hope to reduce their cash outflows for imported oil which they can ill afford. Venezuela and Canada, which both have massive heavy crude reserves, are intent on developing their resources to supplement declining supplies of light oil. Despite the weakening international price of oil, the economics for many heavy crude ventures seem favorable. Statistics quoted at the conference suggest considerable heavy crude production can be brought on stream at costs approaching the finding costs of light conventional crude. At the same time, it has to be acknowledged that those large tar sands projects, like Alberta's multi-billion dollar ventures, are sufficiently marginal that they may be held back by current soft oil demand. This summary report covers the following areas: resources; international cooperation; production; environment; technological developments; upgrading and refining; marketing; and future of heavy crude oil and tar sands.

  19. Ultralight carbon aerogel from nanocellulose as a highly selective oil absorption material

    SciTech Connect (OSTI)

    Meng, Yujie; Yang, Timothy M; Peizhi, Liu; Contescu, Cristian I; Biao, Huang; Siqun, Wang

    2015-01-01

    The synthesis of a sponge-like carbon aerogel from microfibril cellulose (MFC), with high porosity (99%), ultra-low density (0.01 g/cm3), hydrophobic properties (149 static contact angle) and reusability is reported in this paper. The physical properties, internal morphology, thermal properties, and chemical properties of carbon aerogels heat-treated at 700 and 900 oC (Samples C-700 and C-900) were examined. Stabilization and carbonization parameters were optimized in terms of residual carbon yield. The BET surface area of Sample C-700 (521 m2 /g) was significantly higher than of Sample C-950 (149 m2 /g). Graphitic-like domains were observed in C-950. The highest normalized sorption capacity (86 g/g) for paraffin oil was observed in sample C-700. The removal of hydrophilic function groups during carbonization causes carbon aerogel to present highly hydrophobic properties. Carbon aerogel s ability to absorb oil is enhanced by its highly porous 3D network structure with interconnected cellulose nanofibrils.

  20. Ultralight carbon aerogel from nanocellulose as a highly selective oil absorption material

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Yujie; Yang, Timothy M.; Liu, Peizhi; Contescu, Cristian I.; Huang, Biao; Wang, Siqun

    2014-12-04

    The synthesis of a sponge-like carbon aerogel from microfibril cellulose (MFC), with high porosity (99%), ultra-low density (0.01 g/cm3), hydrophobic properties (149° static contact angle) and reusability is reported in this paper. The physical properties, internal morphology, thermal properties, and chemical properties of carbon aerogels heat-treated at 700 and 900 °C (Samples C-700 and C-900) were examined. Stabilization and carbonization parameters were optimized in terms of residual carbon yield. The BET surface area of Sample C-700 (521 m2 /g) was significantly higher than of Sample C-950 (149 m2 /g). Graphitic-like domains were observed in C-950. The highest normalized sorption capacitymore » (86 g/g) for paraffin oil was observed in sample C-700. The removal of hydrophilic function groups during carbonization causes carbon aerogel to present highly hydrophobic properties. Lastly, carbon aerogel's ability to absorb oil is enhanced by its highly porous 3D network structure with interconnected cellulose nanofibrils.« less

  1. Ultralight carbon aerogel from nanocellulose as a highly selective oil absorption material

    SciTech Connect (OSTI)

    Meng, Yujie; Yang, Timothy M.; Liu, Peizhi; Contescu, Cristian I.; Huang, Biao; Wang, Siqun

    2014-12-04

    The synthesis of a sponge-like carbon aerogel from microfibril cellulose (MFC), with high porosity (99%), ultra-low density (0.01 g/cm3), hydrophobic properties (149° static contact angle) and reusability is reported in this paper. The physical properties, internal morphology, thermal properties, and chemical properties of carbon aerogels heat-treated at 700 and 900 °C (Samples C-700 and C-900) were examined. Stabilization and carbonization parameters were optimized in terms of residual carbon yield. The BET surface area of Sample C-700 (521 m2 /g) was significantly higher than of Sample C-950 (149 m2 /g). Graphitic-like domains were observed in C-950. The highest normalized sorption capacity (86 g/g) for paraffin oil was observed in sample C-700. The removal of hydrophilic function groups during carbonization causes carbon aerogel to present highly hydrophobic properties. Lastly, carbon aerogel's ability to absorb oil is enhanced by its highly porous 3D network structure with interconnected cellulose nanofibrils.

  2. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2012-06-05

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons including mobilized hydrocarbons are produced from the portion.

  3. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  4. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS Citation Details In-Document Search Title: VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS You are ...

  5. Oil

    Broader source: Energy.gov [DOE]

    The Energy Department works to ensure domestic and global oil supplies are environmentally sustainable and invests in research and technology to make oil drilling cleaner and more efficient.

  6. An Industrial Membrane System Suitable for Distributed Used Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    such as thermal and chemical stability, including waste oil re-refining, coal tar oil clean-up, and FCC slurry upgrading. * In parallel, use these applications and know-how ...

  7. Investigation of coal tar mobility at a former MGP site

    SciTech Connect (OSTI)

    Moo-Young, H.K.; Mo, X.H.; Waterman, R.; Coleman, A.; Saroff, S.

    2009-11-15

    The presence of coal tar in the subsurface of former manufactured gas plant sites poses an environmental hazard and a potential threat to public health. Coal tar can release various chemical compounds that are transported into the groundwater. Before any efforts can be made to remove coal tar from contaminated subsurface soils, it is recommended to characterize coal tar properties and composition and to delineate the residual saturation point between mobile and immobile coal tar. This paper presents a new innovative field device, the Res-SAT field tool, and laboratory procedures that can be used to determine the saturation-capillary pressure relationship for a soil-water coal-tar system and the critical pressure for coal tar mobility.

  8. Turbine fuels from tar sands bitumen and heavy oil. Volume 1. Phase 3. Pilot plant testing, final design, and economics. Final report, 1 June 1985-31 March 1987

    SciTech Connect (OSTI)

    Talbot, A.F.; Carson, T.C.; Magill, L.G.; Swesey, J.R.

    1987-08-01

    Pilot-plant-scale demonstration of an upgrading/refining scheme to convert bitumen or heavy crude oil into high yields of specification-quality aviation turbine fuel was performed. An atmospheric residue from San Ardo (California) crude was converted under hydrovisbreaking conditions to synthetic crude for further refining. Naphtha cuts from the straight run and synthetic crude were combined, catalytically hydrotreated, then hydrocracked. Products from these operations were combined to produce two prototype specification fuels (JP-4 and JP-8) as well as two heavier, variable-quality fuels. An engineering design (Volume II) was developed for a 50,000 BPSD grass-roots refinery, from the pilot-plant operations. Capital investment and operating costs were estimated, and fuel manufacturing costs projected. Conclusions and recommendations for further work are included.

  9. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  10. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS Citation Details In-Document Search Title: VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY ...

  11. Heating tar sands formations while controlling pressure

    DOE Patents [OSTI]

    Stegemeier, George Leo [Houston, TX; Beer, Gary Lee [Houston, TX; Zhang, Etuan [Houston, TX

    2010-01-12

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. A pressure in the majority of the section may be maintained below a fracture pressure of the formation. The pressure in the majority of the section may be reduced to a selected pressure after the average temperature reaches a temperature that is above 240.degree. C. and is at or below pyrolysis temperatures of hydrocarbons in the section. At least some hydrocarbon fluids may be produced from the formation.

  12. Heating tar sands formations to visbreaking temperatures

    DOE Patents [OSTI]

    Karanikas, John Michael; Colmenares, Tulio Rafael; Zhang, Etuan; Marino, Marian; Roes, Augustinus Wilhelmus Maria; Ryan, Robert Charles; Beer, Gary Lee; Dombrowski, Robert James; Jaiswal, Namit

    2009-12-22

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat may be controlled so that at least a majority of the section reaches an average temperature of between 200.degree. C. and 240.degree. C., which results in visbreaking of at least some hydrocarbons in the section. At least some visbroken hydrocarbon fluids may be produced from the formation.

  13. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  14. Creating and maintaining a gas cap in tar sands formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX); Dinkoruk, Deniz Sumnu (Houston, TX); Wellington, Scott Lee (Bellaire, TX)

    2010-03-16

    Methods for treating a tar sands formation are disclosed herein. Methods for treating a tar sands formation may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. Pressure may be allowed to increase in an upper portion of the formation to provide a gas cap in the upper portion. At least some hydrocarbons are produced from a lower portion of the formation.

  15. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-05-07

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through September 2000, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood projects. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone so the project team could use the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. The project team spent the fourth quarter 2000 performing well work and reservoir surveillance on the Tar II-A post-steamflood project and the Tar V horizontal well steamflood pilot. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being evaluated.

  16. Biodegradation of naphthalene from coal tar. Research progress report

    SciTech Connect (OSTI)

    Ghoshal, S.; Ramaswami, A.; Luthy, R.G.

    1994-02-07

    Biodegradation experiments were conducted to evaluate the mineralization of naphthalene released from coal tar entrapped in microporous silica media. Tests were performed with two coal tars recovered from former manufactured gas plant sites. Results from these tests showed that the degradation end point for naphthalene was significantly lower than the total amount of naphthalene present in coal tar. The role of physico-chemical and biological processes on the rate of biotransformation of naphthalene was evaluated. Mass transfer rates for dissolution of naphthalene from entrapped coal tar were measured in batch, flow-through systems. The rate of naphthalene mass transfer from the coal tar was found to be significantly greater than the rate of naphthalene biomineralization in batch slurry reactors. This implied that the rate acting factor for the biodegradation process was related to biokinetic phenomena rather than mass transfer processes. Further tests indicated that conditions inhibitory to bacteria limited the biodegradation of naphthalene, and in some cases the inhibition was reversible upon dilution of the reactor contents.

  17. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F.

    2007-05-15

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  18. Coal tar technology. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The bibliography contains citations concerning coal tar production and applications. Topics examine production from coal gasification, synthesis of chemicals from coal tar, and chemical analyses of coal tar products. Toxicology pollution studies, and commercial uses of the product are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  19. Coal tar technology. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning coal tar production and applications. Topics examine production from coal gasification, synthesis of chemicals from coal tar, and chemical analyses of coal tar products. Toxicology pollution studies, and commercial uses of the product are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  20. Coal tar technology. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The bibliography contains citations concerning coal tar production and applications. Topics examine production from coal gasification, synthesis of chemicals from coal tar, and chemical analyses of coal tar products. Toxicology pollution studies, and commercial uses of the product are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  1. Method for creating high carbon content products from biomass oil

    DOE Patents [OSTI]

    Parker, Reginald; Seames, Wayne

    2012-12-18

    In a method for producing high carbon content products from biomass, a biomass oil is added to a cracking reactor vessel. The biomass oil is heated to a temperature ranging from about 100.degree. C. to about 800.degree. C. at a pressure ranging from about vacuum conditions to about 20,700 kPa for a time sufficient to crack the biomass oil. Tar is separated from the cracked biomass oil. The tar is heated to a temperature ranging from about 200.degree. C. to about 1500.degree. C. at a pressure ranging from about vacuum conditions to about 20,700 kPa for a time sufficient to reduce the tar to a high carbon content product containing at least about 50% carbon by weight.

  2. Oil Shale Research in the United States | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research in the United States Oil Shale Research in the United States Profiles of Oil Shale Research and Development Activities In Universities, National Laboratories, and Public Agencies Oil Shale Research in the United States (7.2 MB) More Documents & Publications Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Applicability of a Hybrid Retorting Technology in the Green River Formation National Strategic Unconventional Resource Model

  3. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-11-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through June 2002, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V post-steamflood pilot and Tar II-A post-steamflood projects. During the Third Quarter 2002, the project team essentially completed implementing the accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project developed in March 2002 and is proceeding with additional related work. The project team has completed developing laboratory research procedures to analyze the sand consolidation well completion technique and will initiate work in the fourth quarter. The Tar V pilot steamflood project terminated hot water injection and converted to post-steamflood cold water injection on April 19, 2002. Proposals have been approved to repair two sand consolidated horizontal wells that sanded up, Tar II-A well UP-955 and Tar V well J-205, with gravel-packed inner liner jobs to be performed next quarter. Other well work to be performed next quarter is to convert well L-337 to a Tar V water injector and to recomplete vertical well A-194 as a Tar V interior steamflood pattern producer. Plans have been approved to drill and

  4. Production from multiple zones of a tar sands formation

    DOE Patents [OSTI]

    Karanikas, John Michael; Vinegar, Harold J

    2013-02-26

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat is allowed to transfer from the heaters to at least a portion of the formation. Fluids are produced from the formation through at least one production well that is located in at least two zones in the formation. The first zone has an initial permeability of at least 1 darcy. The second zone has an initial of at most 0.1 darcy. The two zones are separated by a substantially impermeable barrier.

  5. Systems and methods for producing hydrocarbons from tar sands formations

    DOE Patents [OSTI]

    Li, Ruijian; Karanikas, John Michael

    2009-07-21

    A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

  6. Geology and resources of the Tar Sand Triangle, southeastern Utah

    SciTech Connect (OSTI)

    Dana, G.F.; Oliver, R.L.; Elliott, J.R.

    1984-05-01

    The Tar Sand Triangle is located in southeastern Utah between the Dirty Devil and Colorado Rivers and covers an area of about 200 square miles. The geology of the area consists of gently northwest dipping strata exposed in the box canyons and slopes of the canyonlands morphology. Strata in the area range in age from Jurassic to Permian. The majority of tar sand saturation is found in the Permian White Rim Sandstone Member of the Cutler Formation. The White Rim Sandstone Member consists of a clean, well-sorted sandstone which was deposited in a shallow marine environment. Resources were calculated from analytical data from the three coreholes drilled by the Laramie Energy Technology Center and other available data. The total in-place resources, determined from this study, are 6.3 billion barels. Previous estimates ranged from 2.9 to 16 million barrels. More coring and analyses will be necessary before a more accurate determination of resources can be attempted. 8 references, 11 figures, 7 tables.

  7. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-01-31

    to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The steamflood operation in the Tar V pilot project is mature and profitable. Recent production performance is below projections because of wellbore mechanical limitations that were being addressed in 2001. As the fluid production is hot, the pilot steamflood was converted to a hot waterflood project in June 2001.

  8. Water issues associated with heavy oil production.

    SciTech Connect (OSTI)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  9. NREL Patents a Catalyst that Removes Syngas Tar, Boosting the Economics of Biofuels (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-08-01

    NREL has patented a catalyst that reforms tar into syngas, a breakthrough that can accelerate the process of getting biomass ready for fuel synthesis and use as a drop-in fuel.

  10. Integrated Biomass Gasification with Catalytic Partial Oxidation for Selective Tar Conversion

    SciTech Connect (OSTI)

    Zhang, Lingzhi; Wei, Wei; Manke, Jeff; Vazquez, Arturo; Thompson, Jeff; Thompson, Mark

    2011-05-28

    Biomass gasification is a flexible and efficient way of utilizing widely available domestic renewable resources. Syngas from biomass has the potential for biofuels production, which will enhance energy security and environmental benefits. Additionally, with the successful development of low Btu fuel engines (e.g. GE Jenbacher engines), syngas from biomass can be efficiently used for power/heat co-generation. However, biomass gasification has not been widely commercialized because of a number of technical/economic issues related to gasifier design and syngas cleanup. Biomass gasification, due to its scale limitation, cannot afford to use pure oxygen as the gasification agent that used in coal gasification. Because, it uses air instead of oxygen, the biomass gasification temperature is much lower than well-understood coal gasification. The low temperature leads to a lot of tar formation and the tar can gum up the downstream equipment. Thus, the biomass gasification tar removal is a critical technology challenge for all types of biomass gasifiers. This USDA/DOE funded program (award number: DE-FG36-O8GO18085) aims to develop an advanced catalytic tar conversion system that can economically and efficiently convert tar into useful light gases (such as syngas) for downstream fuel synthesis or power generation. This program has been executed by GE Global Research in Irvine, CA, in collaboration with Professor Lanny Schmidt's group at the University of Minnesota (UoMn). Biomass gasification produces a raw syngas stream containing H2, CO, CO2, H2O, CH4 and other hydrocarbons, tars, char, and ash. Tars are defined as organic compounds that are condensable at room temperature and are assumed to be largely aromatic. Downstream units in biomass gasification such as gas engine, turbine or fuel synthesis reactors require stringent control in syngas quality, especially tar content to avoid plugging (gum) of downstream equipment. Tar- and ash-free syngas streams are a critical

  11. First experimental results on the IShTAR testbed

    SciTech Connect (OSTI)

    D’Inca, R.; Jacquot, J.; Ochoukov, R.; Morgal, I.; Fünfgelder, H.; Faugel, H.; Crombe, K.; Louche, F.; Van Eester, D.; Heuraux, S.; Devaux, S.; Moritz, J.; Faudot, E.; Noterdaeme, J.-M.

    2015-12-10

    IShTAR (Ion cyclotron Sheath Test ARrangement) is a linear magnetized plasma test facility dedicated to the investigation of RF wave/plasma interaction [1] in the Ion Cyclotron Range of Frequencies (ICRF). It provides a better accessibility for the instrumentation than tokamaks while being representative of the neighboring region of the wave emitter. It is equipped with a magnetized plasma source (1 m long, 0.4 m diameter) powered by a helical antenna up to 3 kW at 11 MHz. We present the results of the first analysis of the plasma characteristics (plasma density, electron temperature) in function of the operating parameters (injected power, neutral pressure and magnetic field) as measured with fixed and movable Langmuir probes, spectrometer and cameras. The plasma is presently produced only by the helical antenna (no ICRF). We show that the plasma exists in three regime depending on the power level: the first two ones are stable and separated by a jump in density; a first spatial profile of the plasma density has been established for these modes; The third mode is unstable, characterized by strong oscillations of the plasma tube position.

  12. Studies of RF sheaths and diagnostics on IShTAR

    SciTech Connect (OSTI)

    Crombé, K.; D’Inca, R.; Faugel, H.; Fünfgelder, H.; Jacquot, J.; Ochoukov, R.; Louche, F.; Tripsky, M.; Van Eester, D.; Wauters, T.

    2015-12-10

    IShTAR (Ion cyclotron Sheath Test ARrangement) is a linear magnetised plasma test facility for RF sheaths studies at the Max-Planck-Institut für Plasmaphysik in Garching. In contrast to a tokamak, a test stand provides more liberty to impose the parameters and gives better access for the instrumentation and antennas. The project will support the development of diagnostic methods for characterising RF sheaths and validate and improve theoretical predictions. The cylindrical vacuum vessel has a diameter of 1 m and is 1.1 m long. The plasma is created by an external cylindrical plasma source equipped with a helical antenna that has been designed to excite the m=1 helicon mode. In inductive mode, plasma densities and electron temperatures have been characterised with a planar Langmuir probe as a function of gas pressure and input RF power. A 2D array of RF compensated Langmuir probes and a spectrometer are planned. A single strap RF antenna has been designed; the plasma-facing surface is aligned to the cylindrical plasma to ease the modelling. The probes will allow direct measurements of plasma density profiles in front of the RF antenna, and thus a detailed study of the density modifications induced by RF sheaths, which influences the coupling. The RF antenna frequency has been chosen to study different plasma wave interactions: the accessible plasma density range includes an evanescent and propagative behaviour of slow or fast waves, and allows the study of the effect of the lower hybrid resonance layer.

  13. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-05-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through March 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Second Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A steamflood reservoirs have been operated over fifteen months at relatively stable pressures, due in large part to the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase in January 1999. Starting in the Fourth Quarter 2000, the project team has ramped up activity to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical

  14. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-11-01

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through June 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Third Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. The project team ramped up well work activity from October 2000 to September 2001 to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for

  15. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-04-30

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through December 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. During the First Quarter 2002, the project team developed an accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project and began implementing the associated well work in March. The Tar V pilot steamflood project will be converted to post-steamflood cold water injection in April 2002. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. Most of the 2001 well work resulted in maintaining oil and gross fluid production and water injection rates. Reservoir pressures in the ''T'' and ''D'' sands are at 88% and 91% hydrostatic levels, respectively. Well work during the first quarter and plans for 2002 are

  16. A photographic method for estimating wear of coal tar sealcoat from parking lots

    SciTech Connect (OSTI)

    Mateo Scoggins; Tom Ennis; Nathan Parker; Chris Herrington

    2009-07-01

    Coal-tar-based sealcoat has been recognized as an important source of PAHs to the environment through wear and transport via stormwater runoff. Sealcoat removal rates have not been measured or even estimated in the literature due to the complex array of physical and chemical process involved. A photographic study was conducted that incorporates all sources of wear using 10 coal tar-sealed parking lots in Austin, Texas, with sealcoat age ranging from 0 to 5 years. Randomly located photographs from each parking lot were analyzed digitally to quantify black sealed areas versus lighter colored unsealed areas at the pixel level. The results indicate that coal tar sealcoat wears off of the driving areas of parking lots at a rate of approximately 4.7% per year, and from the parking areas of the lots at a rate of approximately 1.4% per year. The overall annual loss of sealcoat was calculated at 2.4%. This results in an annual delivery to the environment of 0.51 g of PAHs per m{sup 2} of coal tar-sealed parking lot. These values provide a more robust and much higher estimate of loading of PAHs from coal tar sealcoated parking lots when compared to other available measures. 20 refs., 6 figs.

  17. Thermodynamic analysis of tar reforming through auto-thermal reforming process

    SciTech Connect (OSTI)

    Nurhadi, N. Diniyati, Dahlia; Efendi, M. Ade Andriansyah; Istadi, I.

    2015-12-29

    Fixed bed gasification is a simple and suitable technology for small scale power generation. One of the disadvantages of this technology is producing tar. So far, tar is not utilized yet and being waste that should be treated into a more useful product. This paper presents a thermodynamic analysis of tar conversion into gas producer through non-catalytic auto-thermal reforming technology. Tar was converted into components, C, H, O, N and S, and then reacted with oxidant such as mixture of air or pure oxygen. Thus, this reaction occurred auto-thermally and reached chemical equilibrium. The sensitivity analysis resulted that the most promising process performance occurred at flow rate of air was reached 43% of stoichiometry while temperature of process is 1100°C, the addition of pure oxygen is 40% and preheating of oxidant flow is 250°C. The yield of the most promising process performance between 11.15-11.17 kmol/h and cold gas efficiency was between 73.8-73.9%.The results of this study indicated that thermodynamically the conversion of tar into producer gas through non-catalytic auto-thermal reformingis more promising.

  18. NREL Patents a Catalyst that Removes Syngas Tar, Boosting the Economics of Biofuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Patents a Catalyst that Removes Syngas Tar, Boosting the Economics of Biofuels NREL has patented a catalyst that reforms tar into syngas, a breakthrough that can accelerate the process of getting biomass ready for fuel synthesis and use as a drop-in fuel. The process also can help reduce greenhouse gases because the biomass that is used in fuel gets combusted into carbon dioxide, which is food for future biomass. The result is that 90% of carbon emissions get recycled into new biomass. Syngas is

  19. In situ heat treatment of a tar sands formation after drive process treatment

    DOE Patents [OSTI]

    Vinegar, Harold J.; Stanecki, John

    2010-09-21

    A method for treating a tar sands formation includes providing a drive fluid to a hydrocarbon containing layer of the tar sands formation to mobilize at least some hydrocarbons in the layer. At least some first hydrocarbons from the layer are produced. Heat is provided to the layer from one or more heaters located in the formation. At least some second hydrocarbons are produced from the layer of the formation. The second hydrocarbons include at least some hydrocarbons that are upgraded compared to the first hydrocarbons produced by using the drive fluid.

  20. ABSORPTION ANALYZER

    DOE Patents [OSTI]

    Brooksbank, W.A. Jr.; Leddicotte, G.W.; Strain, J.E.; Hendon, H.H. Jr.

    1961-11-14

    A means was developed for continuously computing and indicating the isotopic assay of a process solution and for automatically controlling the process output of isotope separation equipment to provide a continuous output of the desired isotopic ratio. A counter tube is surrounded with a sample to be analyzed so that the tube is exactly in the center of the sample. A source of fast neutrons is provided and is spaced from the sample. The neutrons from the source are thermalized by causing them to pass through a neutron moderator, and the neutrons are allowed to diffuse radially through the sample to actuate the counter. A reference counter in a known sample of pure solvent is also actuated by the thermal neutrons from the neutron source. The number of neutrons which actuate the detectors is a function of a concentration of the elements in solution and their neutron absorption cross sections. The pulses produced by the detectors responsive to each neu tron passing therethrough are amplified and counted. The respective times required to accumulate a selected number of counts are measured by associated timing devices. The concentration of a particular element in solution may be determined by utilizing the following relation: T2/Ti = BCR, where B is a constant proportional to the absorption cross sections, T2 is the time of count collection for the unknown solution, Ti is the time of count collection for the pure solvent, R is the isotopic ratlo, and C is the molar concentration of the element to be determined. Knowing the slope constant B for any element and when the chemical concentration is known, the isotopic concentration may be readily determined, and conversely when the isotopic ratio is known, the chemical concentrations may be determined. (AEC)

  1. Impact and future of heavy oil produciton

    SciTech Connect (OSTI)

    Olsen, D.K, )

    1996-01-01

    Heavy oil resources are becoming increaingly important in meeting world oil demand. Heavy oil accounts for 10% of the worlds current oil production and is anticipated to grow significantly. Recent narrowing of the price margins between light and heavy oil and the development of regional heavy oil markets (production, refining and marketing) have prompted renewed investment in heavy oil. Production of well known heavy oil resources of Canada, Venezuela, United States, and elsewhere throughout the world will be expanded on a project-by-project basis. Custom refineries designed to process these heavy crudes are being expanded. Refined products from these crudes will be cleaner than ever before because of the huge investment. However, heavy oil still remains at a competitive disadvantage due to higher production, transportation and refining have to compete with other investment opportunities available in the industry. Expansion of the U.S. heavy oil industry is no exception. Relaxation of export restrictions on Alaskan North Slope crude has prompted renewed development of California's heavy oil resources. The location, resource volume, and oil properties of the more than 80-billion barrel U.S. heavy oil resource are well known. Our recent studies summarize the constraints on production, define the anticipated impact (volume, location and time frame) of development of U.S. heavy oil resources, and examines the $7-billion investment in refining units (bottoms conversion capacity) required to accommodate increased U.S. heavy oil production. Expansion of Canadian and Venezuelan heavy oil and tar sands production are anticipated to dramatically impact the U.S. petroleum market while displacing some imported Mideast crude.

  2. Impact and future of heavy oil produciton

    SciTech Connect (OSTI)

    Olsen, D.K,

    1996-12-31

    Heavy oil resources are becoming increaingly important in meeting world oil demand. Heavy oil accounts for 10% of the worlds current oil production and is anticipated to grow significantly. Recent narrowing of the price margins between light and heavy oil and the development of regional heavy oil markets (production, refining and marketing) have prompted renewed investment in heavy oil. Production of well known heavy oil resources of Canada, Venezuela, United States, and elsewhere throughout the world will be expanded on a project-by-project basis. Custom refineries designed to process these heavy crudes are being expanded. Refined products from these crudes will be cleaner than ever before because of the huge investment. However, heavy oil still remains at a competitive disadvantage due to higher production, transportation and refining have to compete with other investment opportunities available in the industry. Expansion of the U.S. heavy oil industry is no exception. Relaxation of export restrictions on Alaskan North Slope crude has prompted renewed development of California`s heavy oil resources. The location, resource volume, and oil properties of the more than 80-billion barrel U.S. heavy oil resource are well known. Our recent studies summarize the constraints on production, define the anticipated impact (volume, location and time frame) of development of U.S. heavy oil resources, and examines the $7-billion investment in refining units (bottoms conversion capacity) required to accommodate increased U.S. heavy oil production. Expansion of Canadian and Venezuelan heavy oil and tar sands production are anticipated to dramatically impact the U.S. petroleum market while displacing some imported Mideast crude.

  3. Gas-chromatographic determination of the main components of hard-coal tar and its fractions

    SciTech Connect (OSTI)

    Nabivach, V.M.

    1983-01-01

    An investigation was carried out into the composition of bituminous coal tars from several coking plants in the Ukraine using gas-liquid chromatography. It was shown that analytical data can be used for operational quality control of the fractions produced.

  4. Class III Mid-Term Project, "Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies"

    SciTech Connect (OSTI)

    Scott Hara

    2007-03-31

    The overall objective of this project was to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involved improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective has been to transfer technology that can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The first budget period addressed several producibility problems in the Tar II-A and Tar V thermal recovery operations that are common in SBC reservoirs. A few of the advanced technologies developed include a three-dimensional (3-D) deterministic geologic model, a 3-D deterministic thermal reservoir simulation model to aid in reservoir management and subsequent post-steamflood development work, and a detailed study on the geochemical interactions between the steam and the formation rocks and fluids. State of the art operational work included drilling and performing a pilot steam injection and production project via four new horizontal wells (2 producers and 2 injectors), implementing a hot water alternating steam (WAS) drive pilot in the existing steamflood area to improve thermal efficiency, installing a 2400-foot insulated, subsurface harbor channel crossing to supply steam to an island location, testing a novel alkaline steam completion technique to control well sanding problems, and starting on an advanced reservoir management system through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation. The second budget period phase (BP2) continued to implement state-of-the-art operational work to optimize thermal recovery processes, improve well drilling and completion practices, and evaluate the

  5. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in themore » mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.« less

  6. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    SciTech Connect (OSTI)

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in the mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.

  7. A new hydrocracking catalyst for heavy oil upgrading

    SciTech Connect (OSTI)

    Itoh, T. )

    1987-04-01

    In comparison with ordinary oil, tar sands bitumen and vacuum residue contain large quantities of impurities such as asphaltene, heavy metal compounds, sulfur, and nitrogen, which are obstacles to upgrading the refining process. Therefore, these types of materials are extremely difficult to treat with existing refining technologies. In order to upgrade oil feedstocks that are of poor quality, such as tar sands bitumen, new upgrading technologies must be established. In this paper, the author discusses first, the results of catalyst screening, second, the factors of the active catalyst, and finally, the performance of a semi-industrially produced catalyst. The catalyst has high middle-distillate yield, coke plus gum (coke precursors) suppressing ability, low hydrogen consumption and mechanical strength and high temperature stability in slurry reactors.

  8. Filamentous carbon catalytic deposition of coal-tar pitch fraction on corundum

    SciTech Connect (OSTI)

    Martynkova, G.S.; Supova, M.

    2007-01-15

    Our work was focused on deposition of volatile hydrocarbons of carbonaceous precursor on corundum wafer, taking advantage of a metallic catalyst incorporated in precursor. Coal tar-pitch, namely a fraction soluble in toluene, served as precursor material for deposition of filamentous material. The toluene-soluble fraction of tar-pitch originally contained metallic particles of iron and nickel. During heat treatment up to 1000{sup o}C, metallic particles accompanied the volatile hydrocarbons conducive to forming a filamentous deposit. The deposit obtained demonstrates a semicrystalline material that has an irregular filamentous structure with an average filament diameter of 30 {mu}m. The presence of catalysts after the deposition process was proved in the deposit but catalysts were not found in the residuum.

  9. Method of producing drive fluid in situ in tar sands formations

    DOE Patents [OSTI]

    Mudunuri, Ramesh Raju (Houston, TX); Jaiswal, Namit (Houston, TX); Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX)

    2010-03-23

    Methods of treating a tar sands formation are described herein. Methods for treating a tar sands may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. The heat may be allowed to transfer from the heaters to at least a portion of the formation such that a drive fluid is produced in situ in the formation. The drive fluid may move at least some mobilized, visbroken, and/or pyrolyzed hydrocarbons from a first portion of the formation to a second portion of the formation. At least some of the mobilized, visbroken, and/or pyrolyzed hydrocarbons may be produced from the formation.

  10. Controlling and assessing pressure conditions during treatment of tar sands formations

    SciTech Connect (OSTI)

    Zhang, Etuan; Beer, Gary Lee

    2015-11-10

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the tar sands formation from a plurality of heaters located in the formation. Heat is allowed to transfer from the heaters to at least a portion of the formation. A pressure in the portion of the formation is controlled such that the pressure remains below a fracture pressure of the formation overburden while allowing the portion of the formation to heat to a selected average temperature of at least about 280.degree. C. and at most about 300.degree. C. The pressure in the portion of the formation is reduced to a selected pressure after the portion of the formation reaches the selected average temperature.

  11. Effect of cavitation on the properties of coal-tar pitch as studied by gas-liquid chromatography

    SciTech Connect (OSTI)

    M.I. Baikenov; T.B. Omarbekov; S.K. Amerkhanova

    2008-02-15

    The applicability of the cavitation-wave effect to coal-tar pitch processing is considered. The results of the GLC analysis of the test material before and after rotor-pulsation cavitation treatment are given. The organic matter of coal-tar pitch was found to degrade upon cavitation; as a result of this, the yields of light and medium fractions considerably increased. 5 refs., 2 figs., 4 tabs.

  12. Plant Encroachment on the Burrell, Pennsylvania, Disposal Cell--GJO-99-96-TAR, June 1999

    Office of Legacy Management (LM)

    Performed Under DOE Contract No. DE-AC13-96GJ87335 for the U.S. Department of Energy Approved for public release; distribution is unlimited. U.S. Department of Energy GJO-99-96-TAR Plant Encroachment on the Burrell, Pennsylvania, Disposal Cell: Evaluation of Long-Term Performance and Risk June 1999 DOE Grand Junction Office June 1999 Plant Encroachment on the Burrell, Pennsylvania, Disposal Cell Page iii Contents Page Executive Summary

  13. Relationship of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide yield of cigarettes

    SciTech Connect (OSTI)

    Krzyzanowski, M.; Sherrill, D.L.; Paoletti, P.; Lebowitz, M.D. )

    1991-02-01

    The data from consecutive surveys of the Tucson Epidemiologic Study (1981-1988) were used to evaluate the relationship in cigarette smokers of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide (CO) yields of the cigarette. There were 690 subjects who reported smoking regularly in at least one survey, over age 15. After adjustment for intensity and duration of smoking and for depth of inhalation, the risk of chronic phlegm, cough, and dyspnea were not related to the tar and nicotine yields. In 414 subjects with pulmonary function tested in at least one of the three surveys the spirometric indices used were significantly related to the daily dose of tar, nicotine, and CO (product of the cigarette yield and daily number of cigarettes smoked). The effects were more pronounced for past than for current doses. However, the differentiation of pulmonary function due to various yields of cigarettes was small in comparison to the difference in pulmonary function between smokers and nonsmokers.

  14. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-06-27

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies will result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs.

  15. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2004-03-05

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  16. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2003-09-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  17. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2003-06-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  18. Carcinogenic effects in A/J mice of particulate of a coal-tar paint used in potable water systems

    SciTech Connect (OSTI)

    Robinson, M.; Laurie, R.D.; Bull, R.J.; Stober, J.A.

    1987-01-01

    Coal-tar paints are among the products used as inside coatings for water pipes and storage tanks to retard corrosion in potable water-supply systems. Four different formulations of these paints were tested in earlier work by this laboratory in the Ames mutagenesis and the mouse skin carcinogenesis bioassays(6). The paint most active in these assays was then tested in a particulate form in the lung adenoma assay with A/J mice. The paint was applied to clean glass plates, cured, collected and homogenized in 2% Emulphor. Doses of this coal-tar suspension were administered by gavage at 1.0, 10.0, and 55.0 mg in 0.2 ml per mouse 3 x weekly for 8 weeks. The total doses of coal-tar paint were 24, 240, and 1320 mg/mouse. Benzo(a)pyrene, administered in a parallel schedule to a total dose of 6 mg/mouse, served as positive control. A negative control group received an equivalent volume of 2% Emulphor. Animals were sacrificed at 9 months of age (8 months after first dose) and lung adenomas counted. A dose-related response, in the average number of lung tumors per mouse, was observed with the coal-tar particulate. There were also squamous-cell tumors of the forestomach in 42% of the mice receiving 55.0 mg coal tar paint per application.

  19. Absorption Cooling Basics

    Office of Energy Efficiency and Renewable Energy (EERE)

    Absorption coolers use heat rather than electricity as their energy source. Because natural gas is the most common heat source for absorption cooling, it is also referred to as gas-fired cooling.

  20. In situ heat treatment from multiple layers of a tar sands formation

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX)

    2010-11-30

    A method for treating a tar sands formation is disclosed. The method includes providing a drive fluid to a first hydrocarbon containing layer of the formation to mobilize at least some hydrocarbons in the first layer. At least some of the mobilized hydrocarbons are allowed to flow into a second hydrocarbon containing layer of the formation. Heat is provided to the second layer from one or more heaters located in the second layer. At least some hydrocarbons are produced from the second layer of the formation.

  1. Biomass waste gasification - Can be the two stage process suitable for tar reduction and power generation?

    SciTech Connect (OSTI)

    Sulc, Jindrich; Stojdl, Jiri; Richter, Miroslav; Popelka, Jan; Svoboda, Karel; Smetana, Jiri; Vacek, Jiri; Skoblja, Siarhei; Buryan, Petr

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Comparison of one stage (co-current) and two stage gasification of wood pellets. Black-Right-Pointing-Pointer Original arrangement with grate-less reactor and upward moving bed of the pellets. Black-Right-Pointing-Pointer Two stage gasification leads to drastic reduction of tar content in gas. Black-Right-Pointing-Pointer One stage gasification produces gas with higher LHV at lower overall ER. Black-Right-Pointing-Pointer Content of ammonia in gas is lower in two stage moving bed gasification. - Abstract: A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter-current downdraft in the second stage was developed and exploited for studying effects of two stage gasification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass particles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW{sub th}. The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950 Degree-Sign C) and for gasification reaction of the fuel gas with char. The second stage used additional combustion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar

  2. Method of condensing vaporized water in situ to treat tar sands formations

    DOE Patents [OSTI]

    Hsu, Chia-Fu

    2010-03-16

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  3. Epoxy-borax-coal tar composition for a radiation protective, burn resistant drum liner and centrifugal casting method

    DOE Patents [OSTI]

    Taylor, Robert S.; Boyer, Norman W.

    1980-01-01

    A boron containing burn resistant, low level radiation protection material useful, for example, as a liner for radioactive waste disposal and storage, a component for neutron absorber, and a shield for a neutron source. The material is basically composed of Borax in the range of 25-50%, coal tar in the range of 25-37.5%, with the remainder being an epoxy resin mix. A preferred composition is 50% Borax, 25% coal tar and 25% epoxy resin. The material is not susceptible to burning and is about 1/5 the cost of existing radiation protection material utilized in similar applications.

  4. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  5. Residential Absorption Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Absorption Water Heater 2014 Building Technologies Office Peer Review Kyle ... Target MarketAudience: Residential gas water heating Key Partners: GE CRADA partner SRA ...

  6. Mass transfer and biodegradation of PAH compounds from coal tar. Quarterly technical report, January--March 1993

    SciTech Connect (OSTI)

    Ramaswami, A.; Ghoshal, S.; Luthy, R.G.

    1994-09-01

    This study examines the role of physico-chemical mass transfer processes on the rate of biotransformation of polycyclic aromatic hydrocarbon (PAH) compounds released from non-aqueous phase liquid (NAPL) coal tar present at residual saturation within a microporous medium. A simplified coupled dissolution-degradation model is developed that describes the concurrent mass transfer and biokinetic processes occurring in the system. Model results indicate that a dimensionless Damkohler number can be utilized to distinguish between systems that are mass transfer limited, and those that are limited by biological phenomena. The Damkohler number is estimated from independent laboratory experiments that measure the rates of aqueous phase dissolution and biodegradation of naphthalene from coal tar. Experimental data for Stroudsburg coal tar imbibed within 236 {mu}m diameter silica particles yield Damkohler numbers smaller than unity, indicating, for the particular system under study, that the overall rate of biotransformation of naphthalene is not limited by the mass transfer of naphthalene from coal tar to the bulk aqueous phase. There is a need for investigation of mass transfer for larger particles and/or other PAH compounds, and study of microbial rate-limiting phenomena including toxicity, inhibition and competitive substrate utilization.

  7. Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification

    SciTech Connect (OSTI)

    Pradeep Agrawal

    2004-09-07

    The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

  8. World oil trends

    SciTech Connect (OSTI)

    Anderson, A. )

    1991-01-01

    This book provides data on many facets of the world oil industry topics include; oil consumption; oils share of energy consumption; crude oil production; natural gas production; oil reserves; prices of oil; world refining capacity; and oil tankers.

  9. Moving hydrocarbons through portions of tar sands formations with a fluid

    DOE Patents [OSTI]

    Stegemeier, George Leo; Mudunuri, Ramesh Raju; Vinegar, Harold J.; Karanikas, John Michael; Jaiswal, Namit; Mo, Weijian

    2010-05-18

    A method for treating a tar sands formation is disclosed. The method includes heating a first portion of a hydrocarbon layer in the formation from one or more heaters located in the first portion. The heat is controlled to increase a fluid injectivity of the first portion. A drive fluid and/or an oxidizing fluid is injected and/or created in the first portion to cause at least some hydrocarbons to move from a second portion of the hydrocarbon layer to a third portion of the hydrocarbon layer. The second portion is between the first portion and the third portion. The first, second, and third portions are horizontally displaced from each other. The third portion is heated from one or more heaters located in the third portion. Hydrocarbons are produced from the third portion of the formation. The hydrocarbons include at least some hydrocarbons from the second portion of the formation.

  10. Varying properties of in situ heat treatment of a tar sands formation based on assessed viscosities

    DOE Patents [OSTI]

    Karanikas, John Michael; Vinegar, Harold J

    2014-03-04

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat is allowed to transfer from the heaters to at least a portion of the formation. A viscosity of one or more zones of the hydrocarbon layer is assessed. The heating rates in the zones are varied based on the assessed viscosities. The heating rate in a first zone of the formation is greater than the heating rate in a second zone of the formation if the viscosity in the first zone is greater than the viscosity in the second zone. Fluids are produced from the formation through the production wells.

  11. Solar absorption surface panel

    DOE Patents [OSTI]

    Santala, Teuvo J.

    1978-01-01

    A composite metal of aluminum and nickel is used to form an economical solar absorption surface for a collector plate wherein an intermetallic compound of the aluminum and nickel provides a surface morphology with high absorptance and relatively low infrared emittance along with good durability.

  12. Hydroprocessing catalysts for heavy oil and coal

    SciTech Connect (OSTI)

    Satriana, M.J.

    1982-01-01

    Hydroprocessing catalysts, as described in over 230 processes covered in this book, are hydrogenation catalysts used in the upgrading of heavy crudes and coal to products expected to be in great demand as the world's primary oil supplies gradually dwindle. The techniques employed in hydroprocessing result in the removal of contaminants, the transformation of lower grade materials such as heavy crudes to valuable fuels, or the conversion of hydrocarbonaceous solids into gaseous or liquid fuel products. All of these techniques are, of course, carried out in the presence of hydrogen. Some of the brightest energy prospects for the future lie in heavy oil reservoirs and coal reserves. Heavy oils, defined in this book as having gravities of < 20/sup 0/API, are crudes so thick that they are not readily extracted from their reservoirs. However, processing of these crudes is of great importance, because the US resource alone is enormous. The main types of processing catalysts covered in the book are hydrorefining catalysts plus some combinations of the two. Catalysts for the conversion of hydrocarbonaceous materials to gaseous or liquid fuels are also covered. The primary starting material for these conversions is coal, but wood, lignin, oil shale, tar sands, and peat are other possibilities. The final chapter describes the preparation of various catalyst support systems.

  13. Upgrading heavy oils by non-catalytic treatment with hydrogen and hydrogen transfer solvent

    SciTech Connect (OSTI)

    Derbyshire, F.J.; Mitchell, T.O.; Whitehurst, D.D.

    1981-09-29

    Heavy liquid hydrocarbon oil, such as petroleum derived tars, predominantly boiling over 425/sup 0/C, are upgraded to products boiling below 425/sup 0/C, without substantial formation of insoluble char, by heating the heavy oil with hydrogen and a hydrogen transfer solvent in the absence of hydrogenation catalyst at temperatures of about 320/sup 0/C to 500/sup 0/C, and a pressure of 20 to 180 bar for 3 to 30 minutes. The hydrogen transfer solvents polycyclic compounds free of carbonyl groups, e.g., pyrene, and have a polarographic reduction potential which is less negative than phenanthrene and equal to or more negative than azapyrene.

  14. Soliton absorption spectroscopy

    SciTech Connect (OSTI)

    Kalashnikov, V. L.; Sorokin, E.

    2010-03-15

    We analyze optical soliton propagation in the presence of weak absorption lines with much narrower linewidths as compared to the soliton spectrum width by using a perturbation analysis technique based on an integral representation in the spectral domain. The stable soliton acquires a spectral modulation that follows the associated index of refraction of the absorber. The model can be applied to ordinary soliton propagation and to an absorber inside a passively mode-locked laser. In the latter case, a comparison with water vapor absorption in a femtosecond Cr:ZnSe laser yields a very good agreement with experiment. Compared to the conventional absorption measurements in a cell of the same length, the signal is increased by an order of magnitude. The obtained analytical expressions allow further improvement in the sensitivity and spectroscopic accuracy, which makes soliton absorption spectroscopy a promising measurement technique.

  15. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, G.

    1982-06-16

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  16. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, Gershon

    1984-01-01

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  17. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R.; Reed, Scott T.; Ashley, Carol S.; Martinez, F. Edward

    2004-08-31

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  18. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R.; Reed, Scott T.; Ashley, Carol S.; Martinez, F. Edward

    2003-10-14

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  19. Optical absorption measurement system

    DOE Patents [OSTI]

    Draggoo, Vaughn G.; Morton, Richard G.; Sawicki, Richard H.; Bissinger, Horst D.

    1989-01-01

    The system of the present invention contemplates a non-intrusive method for measuring the temperature rise of optical elements under high laser power optical loading to determine the absorption coefficient. The method comprises irradiating the optical element with a high average power laser beam, viewing the optical element with an infrared camera to determine the temperature across the optical element and calculating the absorption of the optical element from the temperature.

  20. Combating oil spill problem using plastic waste

    SciTech Connect (OSTI)

    Saleem, Junaid; Ning, Chao; Barford, John; McKay, Gordon

    2015-10-15

    Highlights: • Up-cycling one type of pollution i.e. plastic waste and successfully using it to combat the other type of pollution i.e. oil spill. • Synthesized oil sorbent that has extremely high oil uptake of 90 g/g after prolonged dripping of 1 h. • Synthesized porous oil sorbent film which not only facilitates in oil sorption but also increases the affinity between sorbent and oil by means of adhesion. - Abstract: Thermoplastic polymers (such as polypropylene, polyethylene, polyethylene terephthalate (PET) and high density polyethylene (HDPE)) constitute 5–15% of municipal solid waste produced across the world. A huge quantity of plastic waste is disposed of each year and is mostly either discarded in landfills or incinerated. On the other hand, the usage of synthetic polymers as oil sorbents, in particular, polyolefins, including polypropylene (PP), and polyethylene (PE) are the most commonly used oil sorbent materials mainly due to their low cost. However, they possess relatively low oil absorption capacities. In this work, we provide an innovative way to produce a value-added product such as oil-sorbent film with high practical oil uptake values in terms of g/g from waste HDPE bottles for rapid oil spill remedy.

  1. Seven-effect absorption refrigeration

    DOE Patents [OSTI]

    DeVault, R.C.; Biermann, W.J.

    1989-05-09

    A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit. 1 fig.

  2. Seven-effect absorption refrigeration

    DOE Patents [OSTI]

    DeVault, Robert C.; Biermann, Wendell J.

    1989-01-01

    A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit.

  3. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Energy Savers [EERE]

    Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil)...

  4. Venezuelan oil

    SciTech Connect (OSTI)

    Martinez, A.R. )

    1989-01-01

    Oil reserves have been known to exist in Venezuela since early historical records, however, it was not until the 20th century that the extensive search for new reserves began. The 1950's marked the height of oil exploration when 200 new oil fields were discovered, as well as over 60{percent} of proven reserves. Venezuela now produces one tone in seven of crude oil consumption and the country's abundant reserves such as the Bolivar Coastal field in the West of the country and the Orinoco Belt field in the East, will ensure it's continuing importance as an oil producer well into the 21st century. This book charts the historical development of Venezuela oil and provides a chronology of all the significant events which have shaped the oil industry of today. It covers all the technical, legal, economic and political factors which have contributed to the evolution of the industry and also gives information on current oil resources and production. Those events significant to the development of the industry, those which were influential in shaping future policy and those which precipitated further action are included. The book provides a source of reference to oil companies, oil economists and petroleum geologists.

  5. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot...

  6. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Fuel Oil Consumption and Expenditure Intensities, 1999" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot (gallons)","per Worker...

  7. Crude Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Barrels) Product: Crude Oil Liquefied Petroleum Gases Distillate Fuel Oil Residual Fuel Oil Still Gas Petroleum Coke Marketable Petroleum Coke Catalyst Petroleum Coke Other Petroleum Products Natural Gas Coal Purchased Electricity Purchased Steam Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History U.S. 0 0 0 0 0 0 1986-2015 East Coast (PADD 1) 0 0 0 0

  8. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, Gershon; Perez-Blanco, Horacio

    1984-01-01

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  9. Increasing Heavy Oil Reserves in the Wilmington Oil Field through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect (OSTI)

    City of Long Beach; David K.Davies and Associates; Tidelands Oil Production Company; University of Southern California

    1999-06-25

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California. This is realized through the testing and application of advanced reservoir characterization and thermal production technologies. It is hoped that the successful application of these technologies will result in their implementation throughout the Wilmington Field and through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively insufficient because of several producability problems which are common in SBC reservoir; inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves.

  10. 9000 wells planned for heavy oil field. [Canada

    SciTech Connect (OSTI)

    Not Available

    1981-05-01

    Beginning in 1983, Esso Resources Canada Ltd. will begin drilling the first of an estimated 9000 directional crude bitumen wells in the tar sands at Cold Lake, Alberta, Canada, the final wells being drilled in the year 2008. The area, covering 50 sq miles of extreme E. Alberta along the Saskatchewan border, contains one of the richest deposits of heavy oil sands in Canada. The company and future partners will drill the bitumen wells directionally into the shallow clearwater formation, which can be reached at approx. 100 m (330 ft). The formation contains an estimated 80 billion bbl of crude bitumen at a rate of 60,000 bpd for 25 yr. This volume of crude will be refined in an upgrading plant to 140,000 bpd of synthetic crude oil. When completed, the Cold Lake project will be one of the largest facilities for producing crude bitumen from wells in the world.

  11. Statistical planning and analysis for treatments of tar sand wastewater. Final report

    SciTech Connect (OSTI)

    Pirie, W.R.

    1984-03-01

    The first part of this report discusses the overall statistical planning, coordination and design for several tar sand wastewater treatment projects contracted by the Laramie Energy Technology Center (LETC) of the Department of Energy. A general discussion of the benefits of consistent statistical design and analysis for data-oriented projects is included, with recommendations for implementation. A detailed outline of the principles of general linear models design is followed by an introduction to recent developments in general linear models by ranks (GLMR) analysis and a comparison to standard analysis using Gaussian or normal theory (GLMN). A listing of routines contained in the VPI Nonparametric Statistics Package (NPSP), installed on the Cyber computer system at the University of Wyoming is included. Part 2 describes in detail the design and analysis for treatments by Gas Flotation, Foam Separation, Coagulation, and Ozonation, with comparisons among the first three methods. Rank methods are used for most analyses, and several detailed examples are included. For optimization studies, the powerful tools of response surface analysis (RSA) are employed, and several sections contain discussion on the benefits of RSA. All four treatment methods proved to be effective for removal of TOC and suspended solids from the wastewater. Because the processes and equipment designs were new, optimum removals were not achieved by these initial studies and reasons for that are discussed. Pollutant levels were nevertheless reduced to levels appropriate for recycling within the process, and for such reuses as steam generation, according to the DOE/LETC project officer. 12 refs., 8 figs., 21 tabs.

  12. Oils and source rocks from the Anadarko Basin: Final report, March 1, 1985-March 15, 1995

    SciTech Connect (OSTI)

    Philp, R. P. [School of Geology and Geophysics, Univ. of Oklahoma, Norman, OK (United States)

    1996-11-01

    The research project investigated various geochemical aspects of oils, suspected source rocks, and tar sands collected from the Anadarko Basin, Oklahoma. The information has been used, in general, to investigate possible sources for the oils in the basin, to study mechanisms of oil generation and migration, and characterization of depositional environments. The major thrust of the recent work involved characterization of potential source formations in the Basin in addition to the Woodford shale. The formations evaluated included the Morrow, Springer, Viola, Arbuckle, Oil Creek, and Sylvan shales. A good distribution of these samples was obtained from throughout the basin and were evaluated in terms of source potential and thermal maturity based on geochemical characteristics. The data were incorporated into a basin modelling program aimed at predicting the quantities of oil that could, potentially, have been generated from each formation. The study of crude oils was extended from our earlier work to cover a much wider area of the basin to determine the distribution of genetically-related oils, and whether or not they were derived from single or multiple sources, as well as attempting to correlate them with their suspected source formations. Recent studies in our laboratory also demonstrated the presence of high molecular weight components(C{sub 4}-C{sub 80}) in oils and waxes from drill pipes of various wells in the region. Results from such a study will have possible ramifications for enhanced oil recovery and reservoir engineering studies.

  13. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Unknown

    2001-08-08

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a

  14. Canadian incentives for oil and gas exploration. [Applicability to USA

    SciTech Connect (OSTI)

    Not Available

    1980-04-01

    During the 1970s a number of different exploration and production incentive programs were put in place in Canada, in particular in the Province of Alberta, Canada's principal oil- and gas-producing province. The DOE/RA is evaluating Canadian incentives for oil and gas exploration, and this study is intended to provide information that will help guide DOE/RA in determining the applicability of Canadian incentive programs in US energy policy. The study describes and documents the fiscal structure in which the Canadian oil industry operates. The incentive features of pricing policy, taxation policy, and provincial royalty systems are discussed. A principal focus of the study is on one of the most important of Canada's specific incentive programs, the Alberta Exploratory Drilling Incentive Credit Program (EDICP). The study describes and evaluates the effect of the EDICP on increased oil and gas exploration activity. Similarly, the study also reviews and evaluates other specific incentive programs such as the Alberta Geophysical Incentive Program, Frontier Exploration Allowances, and various tar sand and heavy oil development incentives. Finally the study evaluates the applicability of Canadian incentives to US energy policy.

  15. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  16. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  17. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  18. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  19. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  20. Ultraviolet absorption hygrometer

    DOE Patents [OSTI]

    Gersh, Michael E.; Bien, Fritz; Bernstein, Lawrence S.

    1986-01-01

    An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined.

  1. Ultraviolet absorption hygrometer

    DOE Patents [OSTI]

    Gersh, M.E.; Bien, F.; Bernstein, L.S.

    1986-12-09

    An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined. 5 figs.

  2. Production and gasification tests of coal fines/coal tar extrudate. Final report June 1982-December 1983

    SciTech Connect (OSTI)

    Furman, A.; Rib, D.; Smith, D.; Waslo, D.

    1984-01-01

    Gasification is a fuels conversion technology that permits the production of clean synthetic gas from coal and other carbonaceous fuels. Of the various gasifier types, however, the fixed bed is the only system currently being offered on a commercial basis. While this reactor type offers proven performance in terms of reliability and thermal efficiency, it requires a sized feedstock. This means that up to 30% of the incoming run-of-mine coal could be rejected as fines. Direct extrusion of this - 1/8-inch coal fines fraction with a tar binder offers a potentially attractive solution to this problem by consolidating the fines and, at the same time, providing a feed mechanism to the pressurized reactor. Work is described on a recently completed extrudate evaluation program conducted at the General Electric Research and Development Center in Schenectady under GRI and NYSERDA sponsorship. A 6-inch, single screw extruder was used to produce 88 tons of Illinois No. 6 coal extrudate with tar binder, which was then successfully gasified in General Electric's 1-ton/hr, Process Evaluation Facility (PEF) scale, fixed-bed reactor. Performance data on the extrusion process and on gasification testing are presented. The test results indicate that the extrudate makes a satisfactory gasifier feedstock in terms of both thermal and mechanical performance.

  3. Heavy oil reservoirs recoverable by thermal technology. Annual report

    SciTech Connect (OSTI)

    Kujawa, P.

    1981-02-01

    The purpose of this study was to compile data on reservoirs that contain heavy oil in the 8 to 25/sup 0/ API gravity range, contain at least ten million barrels of oil currently in place, and are non-carbonate in lithology. The reservoirs within these constraints were then analyzed in light of applicable recovery technology, either steam-drive or in situ combustion, and then ranked hierarchically as candidate reservoirs. The study is presented in three volumes. Volume I presents the project background and approach, the screening analysis, ranking criteria, and listing of candidate reservoirs. The economic and environmental aspects of heavy oil recovery are included in appendices to this volume. This study provides an extensive basis for heavy oil development, but should be extended to include carbonate reservoirs and tar sands. It is imperative to look at heavy oil reservoirs and projects on an individual basis; it was discovered that operators, and industrial and government analysts will lump heavy oil reservoirs as poor producers, however, it was found that upon detailed analysis, a large number, so categorized, were producing very well. A study also should be conducted on abandoned reservoirs. To utilize heavy oil, refiners will have to add various unit operations to their processes, such as hydrotreaters and hydrodesulfurizers and will require, in most cases, a lighter blending stock. A big problem in producing heavy oil is that of regulation; specifically, it was found that the regulatory constraints are so fluid and changing that one cannot settle on a favorable recovery and production plan with enough confidence in the regulatory requirements to commit capital to the project.

  4. SMB, X-ray Absorption Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Absorption Spectroscopy X-ray Absorption Spectroscopy X-ray absorption spectroscopy (XAS) is a well-established technique for simultaneous local geometric and electronic structure...

  5. Characterization of Venezuelan heavy oil vacuum residua

    SciTech Connect (OSTI)

    Izquierdo, A.; Carbognani, L.; Leon, V.; Parisi, A. )

    1988-06-01

    Characterization of abundant ''heavy'' feedstocks such as tar sands, heavy oils and vacuum residua will play a fundamental role in the use of these energy sources. Their physical and chemical properties vary from one feed to another, and this can have some consequences in their necessary upgrading processes. In this paper results on the characterization of 510/sup 0/C-vacuum residua (VR) obtained from Venezuelan Heavy and Medium Oils are presented. These are Morichal (Mo), Merey (Me), Guafita (Gu) and Barinas (Ba). The VR have all an API gravity between 3 and 6, more than 15% asphaltenes, metals above 200 ppm, as well as high contents of nitrogen, more than 6000 ppm, and sulphur, over 1%. It has been found that when these feeds are hydrotreated under similar conditions the processability improves in the order Ba

  6. Post Retort, Pre Hydro-treat Upgrading of Shale Oil

    SciTech Connect (OSTI)

    Gordon, John

    2012-09-30

    Various oil feedstocks, including oil from oil shale, bitumen from tar sands, heavy oil, and refin- ery streams were reacted with the alkali metals lithium or sodium in the presence of hydrogen or methane at elevated temperature and pressure in a reactor. The products were liquids with sub- stantially reduced metals, sulfur and nitrogen content. The API gravity typically increased. Sodi- um was found to be more effective than lithium in effectiveness. The solids formed when sodium was utilized contained sodium sulfide which could be regenerated electrochemically back to so- dium and a sulfur product using a "Nasicon", sodium ion conducting membrane. In addition, the process was found to be effective reducing total acid number (TAN) to zero, dramatically reduc- ing the asphaltene content and vacuum residual fraction in the product liquid. The process has promise as a means of eliminating sulfur oxide and carbon monoxide emissions. The process al- so opens the possibility of eliminating the coking process from upgrading schemes and upgrad- ing without using hydrogen.

  7. An NMR (Nuclear Magnetic Resonance) Investigation of the Chemical Association and Molecular Dynamics in Asphalt Ridge Tar Sand Ore and Bitumen

    DOE R&D Accomplishments [OSTI]

    Netzel, D. A.; Coover, P. T.

    1987-09-01

    Preliminary studies on tar sand bitumen given in this report have shown that the reassociation of tar sand bitumen to its original molecular configuration after thermal stressing is a first-order process requiring nearly a week to establish equilibrium. Studies were also conducted on the dissolution of tar sand bitumen in solvents of varying polarity. At a high-weight fraction of solute to solvent the apparent molecular weight of the bitumen molecules was greater than that of the original bitumen when dissolved in chloroform-d{sub 1} and benzene-d{sub 6}. This increase in the apparent molecular weight may be due to micellar formation or a weak solute-solvent molecular complex. Upon further dilution with any of the solvents studied, the apparent molecular weight of the tar sand bitumen decreased because of reduced van der Waals forces of interaction and/or hydrogen bonding. To define the exact nature of the interactions, it will be necessary to have viscosity measurements of the solutions.

  8. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2000-12-06

    to accurately project reservoir steam chest fill-up by October 1999. A geomechanics study and a separate reservoir simulation study have been performed to determine the possible indicators of formation compaction, the temperatures at which specific indicators are affected and the projected temperature profiles in the over and underburden shales over a ten year period following steam injection. It was believed that once steam chest fill-up occurred, the reservoir would act more like a waterflood and production and cold water injection could be operated at lower Injection to production ratios (I/P) and net injection rates. In mid-September 1999, net water injection was reduced substantially in the ''D'' sands following steam chest fill-up. This caused reservoir pressures to plummet about 100 psi within six weeks. Starting in late-October 1999, net ''D'' sand injection was increased and reservoir pressures have slowly increased back to steam chest fill-up pressures as of the end of March 2000. When the ''T'' sands reached fill-up, net ''T'' sand injection was lowered only slightly and reservoir pressures stabilized. A more detailed discussion of the operational changes is in the Reservoir Management section of this report. A reservoir pressure monitoring program was developed as part of the poststeamflood reservoir management plan. This bi-monthly sonic fluid level program measures the static fluid levels in all idle wells an average of once a month. The fluid levels have been calibrated for liquid and gas density gradients by comparing a number of them with Amerada bomb pressures taken within a few days. This data allows engineering to respond quickly to rises or declines in reservoir pressure by either increasing injection or production or idling production. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil

  9. The extraction of bitumen from western oil sands. Annual report, July 1991--July 1992

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-08-01

    The University of Utah tar sand research and development program is concerned with research and development on Utah is extensive oil sands deposits. The program has been intended to develop a scientific and technological base required for eventual commercial recovery of the heavy oils from oil sands and processing these oils to produce synthetic crude oil and other products such as asphalt. The overall program is based on mining the oil sand, processing the mined sand to recover the heavy oils and upgrading them to products. Multiple deposits are being investigated since it is believed that a large scale (approximately 20,000 bbl/day) plant would require the use of resources from more than one deposit. The tasks or projects in the program are organized according to the following classification: Recovery technologies which includes thermal recovery methods, water extraction methods, and solvent extraction methods; upgrading and processing technologies which covers hydrotreating, hydrocracking, and hydropyrolysis; solvent extraction; production of specialty products; and environmental aspects of the production and processing technologies. These tasks are covered in this report.

  10. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Broader source: Energy.gov (indexed) [DOE]

    Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) (3.31 MB) More Documents & Publications PIA - WEB Physical ...

  11. FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds Breakout Session 2: Frontiers and Horizons ...

  12. Subgap Absorption in Conjugated Polymers

    DOE R&D Accomplishments [OSTI]

    Sinclair, M.; Seager, C. H.; McBranch, D.; Heeger, A. J; Baker, G. L.

    1991-01-01

    Along with X{sup (3)}, the magnitude of the optical absorption in the transparent window below the principal absorption edge is an important parameter which will ultimately determine the utility of conjugated polymers in active integrated optical devices. With an absorptance sensitivity of < 10{sup {minus}5}, Photothermal Deflection Spectroscopy (PDS) is ideal for determining the absorption coefficients of thin films of transparent'' materials. We have used PDS to measure the optical absorption spectra of the conjugated polymers poly(1,4-phenylene-vinylene) (and derivitives) and polydiacetylene-4BCMU in the spectral region from 0.55 eV to 3 eV. Our spectra show that the shape of the absorption edge varies considerably from polymer to polymer, with polydiacetylene-4BCMU having the steepest absorption edge. The minimum absorption coefficients measured varied somewhat with sample age and quality, but were typically in the range 1 cm{sup {minus}1} to 10 cm{sup {minus}1}. In the region below 1 eV, overtones of C-H stretching modes were observed, indicating that further improvements in transparency in this spectral region might be achieved via deuteration of fluorination.

  13. Gas-absorption process

    DOE Patents [OSTI]

    Stephenson, Michael J.; Eby, Robert S.

    1978-01-01

    This invention is an improved gas-absorption process for the recovery of a desired component from a feed-gas mixture containing the same. In the preferred form of the invention, the process operations are conducted in a closed-loop system including a gas-liquid contacting column having upper, intermediate, and lower contacting zones. A liquid absorbent for the desired component is circulated through the loop, being passed downwardly through the column, regenerated, withdrawn from a reboiler, and then recycled to the column. A novel technique is employed to concentrate the desired component in a narrow section of the intermediate zone. This technique comprises maintaining the temperature of the liquid-phase input to the intermediate zone at a sufficiently lower value than that of the gas-phase input to the zone to effect condensation of a major part of the absorbent-vapor upflow to the section. This establishes a steep temperature gradient in the section. The stripping factors below this section are selected to ensure that virtually all of the gases in the downflowing absorbent from the section are desorbed. The stripping factors above the section are selected to ensure re-dissolution of the desired component but not the less-soluble diluent gases. As a result, a peak concentration of the desired component is established in the section, and gas rich in that component can be withdrawn therefrom. The new process provides important advantages. The chief advantage is that the process operations can be conducted in a single column in which the contacting zones operate at essentially the same pressure.

  14. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Total Fuel Oil Consumption and Expenditures for All Buildings, 2003" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  15. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    . Total Fuel Oil Consumption and Expenditures for Non-Mall Buildings, 2003" ,"All Buildings* Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  16. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    SciTech Connect (OSTI)

    Carbognani, L.; Hazos, M.; Sanchez, V. ); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  17. Evaluation of solvent-based in situ processes for upgrading and recovery of heavy oil bitumen

    SciTech Connect (OSTI)

    Duerksen, J.H.; Eloyan, A.

    1995-12-31

    Solvent-based in situ recovery processes have been proposed as lower cost alternatives to thermal processes for recovery of heavy oil and bitumen. Advantages of solvent based processes are: reduced steam requirements, reduced water treating, and in situ upgrading of the produced oil. Lab results and process calculations show that low-pressure, low-energy solvent-based in situ processes have considerable technical and economic potential for upgrading and recovery of bitumen and heavy oil. In a lab flow test using Athabasca tar sand and propane as solvent, 50 percent of the bitumen was recovered as upgraded oil. Relative to the raw bitumen, API gravity increased by about 10{degrees}API, viscosity was reduced 30-fold, sulfur content was reduced about 50 percent, and metals content was also substantially reduced. Process uncertainties that will have a major impact on economics are: (1) oil production rate, (2) oil recovery, (3) extent of in situ upgrading, and (4) solvent losses. Additional lab development and field testing are required to reduce these process uncertainties and to predict commercial-scale economics.

  18. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, L.

    1995-07-11

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350 and 375 C to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan. 2 figs.

  19. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, Luc

    1995-01-01

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.

  20. Heavy crude and tar sands: Hydrocarbons for the 21st century. Volume 4, Upgrading, government and environment

    SciTech Connect (OSTI)

    Meyer, R.F.

    1991-12-31

    The 46 reports in Volume 4 begin with a section in the all-important subject of upgrading. Seventeen papers deals with upgrading of heavy oil and bitumen involving either of two basic processes, hydrogen addition or carbon rejection. Another five reports deal with the treatment of the oil in upgrading process through demetallization and by coprocessing with coal or lignite. The two papers on the Imulsion process present both the technology and the field experiences developed to transport and produce ORIMULSION{trademark}, the fuel developed with the bitumen from the Orinoco Belt. Seven papers in the section on environmental impacts are directed specifically to heavy oil. These deal mostly with the upgrading process, although one addresses the vexing problems of the refusal of extraction fines to settle out of tailings ponds in oil sand processing. A principal objective of the Centre is the fostering of technical cooperation between countries and the transfer of technological expertise in the area of heavy oil and natural bitumens from countries with advanced technology to those with undeveloped resources. The five reports in the section on Marketing and Economics carefully consider the demand in the context of world oil supply. Economic incentives is the stage for the final section of the volume, Government Policies and Legal Considerations. One of these reports presents an excellent review of the Venezuelan oil industry and its major efforts to promote the exploitation and utilization of heavy crude oil. Another of the reports describes ways in which the leasing procedures in Alberta may be modified to make the development of oil sands more effective. A third paper outlines procedures a company may usefully follow in order to most efficiently undertake the entire process of obtaining and developing oil sands leases. Individual papers have been processed separately for the database.

  1. The rediscovery of absorption chillers

    SciTech Connect (OSTI)

    Katzel, J.

    1992-04-23

    Absorption chillers are back - and for two very good reasons: they are environmentally sound and, in many cases, economically attractive. One factor fueling this resurgence is the outlook for natural gas, the energy source of most absorption systems. Deregulation has spurred exploration, and forecasts indicate an abundant supply and relatively low prices through 2050. Threats of global warming and depletion of the ozone layer also are forces driving the absorption chiller market. Being a good corporate citizen today means minimizing or eliminating the use of chlorofluorocarbons (CFCs), the basis of many refrigerants used in mechanical chillers. Even as chemical and chiller manufacturers alike work to develop substitute refrigerants, the perfect alternative has yet to be found. Absorption units are free of these problems, a benefit that appeals to many people.

  2. Absorption Heat Pumps | Department of Energy

    Energy Savers [EERE]

    Heat Pump Systems Absorption Heat Pumps Absorption Heat Pumps Absorption heat pumps are ... As in a standard heat pump, the refrigerant (in this case, ammonia) is condensed in one ...

  3. Oil & Gas Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil & Gas Research Unconventional Resources NETL's onsite research in unconventional ... quantify potential risks associated with oil and gas resources in shale reservoirs that ...

  4. Oil and Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil and Gas Oil and Gas R&D focus on the use of conventional and unconventional fossil fuels, including associated environmental challenges Contact thumbnail of Business ...

  5. Oil Security Metrics Model

    SciTech Connect (OSTI)

    Greene, David L.; Leiby, Paul N.

    2005-03-06

    A presentation to the IWG GPRA USDOE, March 6, 2005, Washington, DC. OSMM estimates oil security benefits of changes in the U.S. oil market.

  6. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1994-03-29

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  7. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow

    1994-01-01

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  8. Mechanical properties and energy absorption characteristics of...

    Office of Scientific and Technical Information (OSTI)

    Mechanical properties and energy absorption characteristics of a polyurethane foam Citation Details In-Document Search Title: Mechanical properties and energy absorption ...

  9. Heavy crude and tar sands: Hydrocarbons for the 21st century. Volume 2, Reservoir behavior, drilling and production

    SciTech Connect (OSTI)

    Meyer, R.F.

    1991-12-31

    Volume 2 is devoted to heavy oil reservoir behavior, production, and the drilling and completion of wells to meet the special needs of these fascinating but difficult oils and bitumens. The volume begins with four papers describing approaches to the recovery of heavy oil and to two fields subject to different recovery mechanisms. Although most heavy oil fields are produced with the assistance of steam stimulation, which commenced in Venezuela, or steam flood, many other methods for the improvement of recovery are potentially applicable. The seven reports on pilot projects examine mostly the results of studies on the dominant thermal recovery methods - steam stimulation, steam flood, and in situ combustion. The behavior of reservoirs under development through use of horizontal wells is the subject of three reports, of vertical wells, nine papers. Much is still to be teamed concerning the relative advantages of these two distinctive methods of reservoir development. The 18 reports on drilling and production are of great importance to the science and engineering of heavy oil because of the problems heavy oil causes after it is induced to flow to the well bore. Artificial lifting of the oil has traditionally centered on the use of sucker rods, but other methods, such as chamber or cavity-pump lift may prove to be efficacious. Horizontal well drilling is a logical approach to maximizing the amount of reservoir exposed to the well bore but this entails special problems in bore-hole clean-up. Heavy oils, too, pose special, frequently very difficult gravel packing problems. Sand production with heavy oil has always posed both economic and technological difficulties and major effort is devoted to overcoming them, as evidenced by the reports in this section. Individual papers have been processed separately for inclusion in the Energy Science and Technology Database.

  10. Rates and Mechanisms of Oil Shale Pyrolysis: A Chemical Structure Approach

    SciTech Connect (OSTI)

    Fletcher, Thomas; Pugmire, Ronald

    2015-01-01

    Three pristine Utah Green River oil shale samples were obtained and used for analysis by the combined research groups at the University of Utah and Brigham Young University. Oil shale samples were first demineralized and the separated kerogen and extracted bitumen samples were then studied by a host of techniques including high resolution liquid-state carbon-13 NMR, solid-state magic angle sample spinning 13C NMR, GC/MS, FTIR, and pyrolysis. Bitumen was extracted from the shale using methanol/dichloromethane and analyzed using high resolution 13C NMR liquid state spectroscopy, showing carbon aromaticities of 7 to 11%. The three parent shales and the demineralized kerogens were each analyzed with solid-state 13C NMR spectroscopy. Carbon aromaticity of the kerogen was 23-24%, with 10-12 aromatic carbons per cluster. Crushed samples of Green River oil shale and its kerogen extract were pyrolyzed at heating rates from 1 to 10 K/min at pressures of 1 and 40 bar and temperatures up to 1000°C. The transient pyrolysis data were fit with a first-order model and a Distributed Activation Energy Model (DAEM). The demineralized kerogen was pyrolyzed at 10 K/min in nitrogen at atmospheric pressure at temperatures up to 525°C, and the pyrolysis products (light gas, tar, and char) were analyzed using 13C NMR, GC/MS, and FTIR. Details of the kerogen pyrolysis have been modeled by a modified version of the chemical percolation devolatilization (CPD) model that has been widely used to model coal combustion/pyrolysis. This refined CPD model has been successful in predicting the char, tar, and gas yields of the three shale samples during pyrolysis. This set of experiments and associated modeling represents the most sophisticated and complete analysis available for a given set of oil shale samples.

  11. Fluvial-deltaic heavy oil reservoir, San Joaquin basin

    SciTech Connect (OSTI)

    Miller, D.D.; McPherson, J.G.; Covington, T.E.

    1989-03-01

    Unconsolidated arkosic sands deposited in a fluvial-deltaic geologic setting comprise the heavy oil (13/degree/ API gravity) reservoir at South Belridge field. The field is located along the western side of the San Joaquin basin in Kern County, California. More than 6000 closely spaced and shallow wells are the key to producing the estimated 1 billion bbl of ultimate recoverable oil production. Thousands of layered and laterally discontinuous reservoir sands produce from the Pleistocene Tulare Formation. The small scale of reservoir geometries is exploited by a high well density, required for optimal heavy oil production. Wells are typically spaced 200-500 ft (66-164 m) apart and drilled to 1000 ft (328 m) deep in the 14-mi/sup 2/ (36-km/sup 2/) producing area. Successful in-situ combustion, cyclic steaming, and steamflood projects have benefited from the shallow-depth, thick, layered sands, which exhibit excellent reservoir quality. The fundamental criterion for finding another South Belridge field is to realize the extraordinary development potential of shallow, heavy oil reservoirs, even when an unspectacular discovery well is drilled. The trap is a combination of structural and stratigraphic mechanisms plus influence from unconventional fluid-level and tar-seal traps. The depositional model is interpreted as a braid delta sequence that prograded from the nearby basin-margin highlands. A detailed fluvial-deltaic sedimentologic model establishes close correlation between depositional lithofacies, reservoir geometries, reservoir quality, and heavy oil producibility. Typical porosity is 35% and permeability is 3000 md.

  12. Oil Production

    Energy Science and Technology Software Center (OSTI)

    1989-07-01

    A horizontal and slanted well model was developed and incorporated into BOAST, a black oil simulator, to predict the potential production rates for such wells. The HORIZONTAL/SLANTED WELL MODEL can be used to calculate the productivity index, based on the length and location of the wellbore within the block, for each reservoir grid block penetrated by the horizontal/slanted wellbore. The well model can be run under either pressure or rate constraints in which wellbore pressuresmore » can be calculated as an option of infinite-conductivity. The model can simulate the performance of multiple horizontal/slanted wells in any geometric combination within reservoirs.« less

  13. Effect of dietary fat on plasma glutathione peroxidase levels and intestinal absorption of /sup 75/Se-labeled sodium selenite in chicks

    SciTech Connect (OSTI)

    Mutanen, M.L.; Mykkaenen, H.M.

    1984-05-01

    The effect of dietary fat on the availability of selenium was investigated in chicks fed either 4 or 20% butter, olive oil, rape oil, corn oil or sunflower oil in the diet for 3 weeks after hatching. Plasma glutathione peroxidase (GSH-Px) activity was used as an indicator of the body selenium status. In addition, the intestinal absorption of sodium selenite (/sup 75/Se-labeled) was determined by using both the in vivo ligated loop procedure and oral administration of the isotope. The plasma GSH-Px levels increased with increasing proportion of the polyunsaturated fatty acids in the diet. Increasing the amount of fat from 4 to 20% significantly enhanced the GSH-Px activity in the groups receiving butter or olive oil, but had no effect in animals fed the unsaturated fats. The absorption of (/sup 75/Se)selenite from the ligated duodenal loops tended to be reduced in chicks fed corn oil or sunflower oil as compared to the animals receiving butter in their diet. On the other hand, the type of dietary fat did not appear to affect the absorption of the orally administered selenite. The present study demonstrates that the type of dietary fat can affect the plasma GSH-Px levels in chicks without altering the intestinal absorption of selenite. However, the results on the absorption of the intraduodenally injected sodium selenite suggest that dietary fat plays some role in the intestinal transport of selenium.

  14. Eco Oil 4

    SciTech Connect (OSTI)

    Brett Earl; Brenda Clark

    2009-10-26

    This article describes the processes, challenges, and achievements of researching and developing a biobased motor oil.

  15. World Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    World Crude Oil Prices (Dollars per Barrel) The data on this page are no longer available.

  16. Absorption-heat-pump system

    DOE Patents [OSTI]

    Grossman, G.; Perez-Blanco, H.

    1983-06-16

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  17. Transient absorption spectroscopy of laser shocked explosives

    SciTech Connect (OSTI)

    Mcgrane, Shawn D; Dang, Nhan C; Whitley, Von H; Bolome, Cindy A; Moore, D S

    2010-01-01

    Transient absorption spectra from 390-890 nm of laser shocked RDX, PETN, sapphire, and polyvinylnitrate (PVN) at sub-nanosecond time scales are reported. RDX shows a nearly linear increase in absorption with time after shock at {approx}23 GPa. PETN is similar, but with smaller total absorption. A broad visible absorption in sapphire begins nearly immediately upon shock loading but does not build over time. PVN exhibits thin film interference in the absorption spectra along with increased absorption with time. The absorptions in RDX and PETN are suggested to originate in chemical reactions happening on picosecond time scales at these shock stresses, although further diagnostics are required to prove this interpretation.

  18. New short contact time processes upgrade residual oils and heavy crudes

    SciTech Connect (OSTI)

    Not Available

    1991-08-12

    This paper reports on new short contact time carbon rejection technology developed for upgrading residual oils and converting heavier crudes into high-quality synthetic crudes. The process, called discriminatory destructive distillation, or 3D, has been demonstrated in a Kansas refinery on feedstocks ranging from 13.5 to 30.6{degrees} API. For the past year, Coastal Derby Refining Co. has been operating a revolutionary, according to Bartholic, circulating fluid solids processing apparatus that can be run as either a 3D process unit, to virtually eliminate the residual oil component of crude, or as an MSCC process unit, to upgrade VGO residual oils. Because both of these processes circulate a fluid solid in a manner similar to the well known and commercially accepted fluid catalytic cracking (FCC) process, existing FCC-type units can be easily and economically converted to either 3D or MSCC operation. The 3D process is a low-pressure, carbon-rejection residual oil treating process for preparation of gas oils for fluid catalytic cracking (or MSCC), hydrotreating, mild hydrocracking, or full hydrocracking, says Bartholic. The process is also applicable, he says to upgrading heavy crudes or tar sands bitumen to high-quality reconstituted crudes for world markets.

  19. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (Btu) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy Intensity (thousand Btu...

  20. Going Global: Tight Oil Production

    Gasoline and Diesel Fuel Update (EIA)

    GOING GLOBAL: TIGHT OIL PRODUCTION Leaping out of North America and onto the World Stage JULY 2014 GOING GLOBAL: TIGHT OIL PRODUCTION Jamie Webster, Senior Director Global Oil ...

  1. Pacific Northwest Laboratory Annual Report for 1979 to the DOE...

    Office of Scientific and Technical Information (OSTI)

    resource development, oil shale and tar sand research, and multitechnology development. ... AND DOSIMETRY; 15 GEOTHERMAL ENERGY; 04 OIL SHALES AND TAR SANDS Word Cloud More Like ...

  2. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  3. Crude Oil Characteristics Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SAE Plan June 29, 2015 Page 1 Crude Oil Characteristics Research Sampling, Analysis and Experiment (SAE) Plan The U.S. is experiencing a renaissance in oil and gas production. The Energy Information Administration projects that U.S. oil production will reach 9.3 million barrels per day in 2015 - the highest annual average level of oil production since 1972. This domestic energy boom is due primarily to new unconventional production of light sweet crude oil from tight-oil formations like the

  4. United States Department of Energy large commercial absorption chiller development program

    SciTech Connect (OSTI)

    Garland, P.W.; DeVault, R.C.; Zaltash, A.

    1998-11-01

    The US Department of Energy (DOE) is working with partners from the gas cooling industry to improve energy efficiency and US competitiveness by using advanced absorption technologies that eliminate the use of chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs), refrigerants that contribute to ozone depletion and global warming. Absorption cooling uses natural gas as the heat source, which produces much lower NO{sub x} emissions than oil- or coal-generated electricity. Gas-fired chillers also have the advantage of helping reduce peak electrical usage during summer months. To assist industry in developing advanced absorption cooling technologies, DOE sponsors the Large Commercial Chiller Development Program. The goal of the program is to improve chiller cooling efficiency by 30--50% compared with the best currently available absorption systems.

  5. Absorption Heat Pumps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat Pump Systems » Absorption Heat Pumps Absorption Heat Pumps Absorption heat pumps are essentially air-source heat pumps driven not by electricity, but by a heat source such as natural gas, propane, solar-heated water, or geothermal-heated water. Because natural gas is the most common heat source for absorption heat pumps, they are also referred to as gas-fired heat pumps. There are also absorption (or gas-fired) coolers available that work on the same principle. Unlike some absorption heat

  6. Fuel Oil Use in Manufacturing

    U.S. Energy Information Administration (EIA) Indexed Site

    logo Return to: Manufacturing Home Page Fuel Oil Facts Oil Price Effect Fuel Switching Actual Fuel Switching Storage Capacity Fuel Oil Use in Manufacturing Why Look at Fuel Oil?...

  7. Photodetector with enhanced light absorption

    DOE Patents [OSTI]

    Kane, James

    1985-01-01

    A photodetector including a light transmissive electrically conducting layer having a textured surface with a semiconductor body thereon. This layer traps incident light thereby enhancing the absorption of light by the semiconductor body. A photodetector comprising a textured light transmissive electrically conducting layer of SnO.sub.2 and a body of hydrogenated amorphous silicon has a conversion efficiency about fifty percent greater than that of comparative cells. The invention also includes a method of fabricating the photodetector of the invention.

  8. Sound Oil Company

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Ward Oil Co., 24 DOE 81,002 (1994); see also Belcher Oil Co., 15 DOE 81,018 (1987) ... months relief because of flood); Utilities Bd. of Citronelle-Gas, 4 DOE 81,205 (1979) ...

  9. South American oil

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    GAO reviewed the petroleum industries of the following eight South American Countries that produce petroleum but are not major exporters: Argentina, Bolivia, Brazil, Chile, Colombia, Ecuador, Peru, and Trinidad and Tobago. This report discusses the amount of crude oil the United States imports from the eight countries, expected crude oil production for these countries through the year 2010, and investment reforms that these countries have recently made in their petroleum industries. In general, although the United States imports some oil from these countries, as a group, the eight countries are currently net oil importers because combined domestic oil consumption exceeds oil production. Furthermore, the net oil imports are expected to continue to increase through the year 2010, making it unlikely that the United States will obtain increased oil shipments from these countries.

  10. Enhanced Oil Recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Oil Recovery As much as two-thirds of conventional crude oil discovered in U.S. fields remains unproduced, left behind due to the physics of fluid flow. In addition, ...

  11. US Crude oil exports

    Gasoline and Diesel Fuel Update (EIA)

    2014 EIA Energy Conference U.S. Crude Oil Exports July 14, 2014 By Lynn D. Westfall U.S. Energy Information Administration U.S. crude oil production has grown by almost 50% since ...

  12. Crude Oil Characteristics Research

    Broader source: Energy.gov (indexed) [DOE]

    SAE Plan June 29, 2015 Page 1 Crude Oil Characteristics Research Sampling, Analysis and Experiment (SAE) Plan The U.S. is experiencing a renaissance in oil and gas production. The ...

  13. GAX absorption cycle design process

    SciTech Connect (OSTI)

    Priedeman, D.K.; Christensen, R.N.

    1999-07-01

    This paper presents an absorption system design process that relies on computer simulations that are validated by experimental findings. An ammonia-water absorption heat pump cycle at 3 refrigeration tons (RT) and chillers at 3.3 RT and 5 RT (10.5 kW, 11.6 kW, and 17.6 kW) were initially modeled and then built and tested. The experimental results were used to calibrate both the cycle simulation and the component simulations, yielding computer design routines that could accurately predict component and cycle performance. Each system was a generator-absorber heat exchange (GAX) cycle, and all were sized for residential and light commercial use, where very little absorption equipment is currently used. The specific findings of the 5 RT (17.6 kW) chiller are presented. Modeling incorporated a heat loss from the gas-fired generator and pressure drops in both the evaporator and absorber. Simulation results and experimental findings agreed closely and validated the modeling method and simulation software.

  14. Purge needs in absorption chillers

    SciTech Connect (OSTI)

    Murray, J.G. )

    1993-10-01

    Absorption chillers are regaining a significant share of large tonnage chiller sales, such as they had 20 years ago. Gas-fired chillers are now available that have a base energy (ultimate fuel usage) consumption rate per ton comparable to that in electric units. Effective purging in an absorption chiller is an absolute necessity to achieve the low chilled water temperature needed for dehumidification and to fully benefit from the energy savings offered by double-effect cycles. Although the purge system is usually not shown on the typical cycle schematic, its proper functioning is a key requirement for satisfactory machine operation. This article discusses the effect of noncondensible (N/C) gases on the absorption cooling process and the basics of purge systems. In addition, the article discusses the rationale for the important design step of selecting the location of the N/C probe, and discusses purge systems applicable to the direct-fired, double-effect machines now entering the marketplace.

  15. Report. Results of a Piezocone Investigation - Shiprock, New Mexico - February 2002. GJO-2001-276-TAR. MAC-GWSHP 13.3-1.

    Office of Legacy Management (LM)

    GJO-2001-276-TAR MAC-GWSHP13.3-1 UMTRA Ground Water Project Results of A Piezocone Investigation Shiprock, New Mexico February 2002 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado Project Number UGW-511-0020-28-003 Document Number U0145400 Work Performed Under DOE Contract Number DE-AC13-96GJ87335 Document Number U0145400 DOE/Grand Junction Office Results of A Piezocone InvestigationShiprock, New Mexico February 2002 Page 2 Executive Summary A piezocone

  16. Dandruff, seborrheic dermatitis, and psoriasis drug products containing coal tar and menthol for over-the-counter human use; amendment to the monograph. Final rule

    SciTech Connect (OSTI)

    2006-03-15

    The Food and Drug Administration (FDA) is issuing a final rule amending the final monograph (FM) for over-the-counter (OTC) dandruff, seborrheic dermatitis, and psoriasis drug products to include the combination of 1.8 percent coal tar solution and 1.5 percent menthol in a shampoo drug product to control dandruff. FDA did not receive any comments or data in response to its previously proposed rule to include this combination. This final rule is part of FDA's ongoing review of OTC drug products.

  17. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  18. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C.; Foster, Edward P.

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  19. Vegetable oils for tractors

    SciTech Connect (OSTI)

    Moroney, M.

    1981-11-14

    Preliminary tests by the Agricultural Institute, show that tractors can be run on a 50:50 rape oil-diesel mixture or on pure rape oil. In fact, engine power actually increased slightly with the 50:50 blend but decreased fractionally with pure rape oil. Research at the North Dakota State University on using sunflower oil as an alternative to diesel fuel is also noted.

  20. Oil-futures markets

    SciTech Connect (OSTI)

    Prast, W.G.; Lax, H.L.

    1983-01-01

    This book on oil futures trading takes a look at a market and its various hedging strategies. Growing interest in trading of commodity futures has spread to petroleum, including crude oil, and key refined products such as gasoline and heating oil. This book describes how the international petroleum trade is structured, examines the working of oil futures markets in the United States and the United Kingdom, and assesses the possible courses of further developments.

  1. Development prospects of the capital-surplus oil-exporting countries. [Monograph

    SciTech Connect (OSTI)

    Habluetzel, R.

    1981-01-01

    The purpose of this paper is to assess the political and economic factors that are likely to determine, in the next five years, the absorptive capacity for investment and consumption in the capital-surplus oil-exporting countries; this permits an evaluation of the prospective size of their oil surplus under specific assumptions of oil export volume and oil prices. Starting with an analysis of the notion that the volume of oil production, beyond a specific point for each country, is of a discretionary nature, the paper proceeds to review the experience of the oil-surplus countries during the last seven years in absorbing oil income and creating a domestic income base for the post-oil era. The results of this experience and its side effects (in the form of inflation and immigrant labor) and their political and economic implications are reviewed in the context of different resource endowments and societal structures with a view to understanding the likely development and expenditures the governments will take. The paper concludes with a prognosis of likely levels of total oil income, domestic absorptions, and oil surpluses for the six countries. 4 references, 26 tables.

  2. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  3. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing in organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed.

  4. Absorption Cooling Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Absorption coolers use heat rather than electricity as their energy source. Because natural gas is the most common heat source for absorption cooling, it is also referred to as...

  5. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  6. Advanced regenerative absorption refrigeration cycles

    DOE Patents [OSTI]

    Dao, Kim

    1990-01-01

    Multi-effect regenerative absorption cycles which provide a high coefficient of performance (COP) at relatively high input temperatures. An absorber-coupled double-effect regenerative cycle (ADR cycle) (10) is provided having a single-effect absorption cycle (SEA cycle) (11) as a topping subcycle and a single-effect regenerative absorption cycle (1R cycle) (12) as a bottoming subcycle. The SEA cycle (11) includes a boiler (13), a condenser (21), an expansion device (28), an evaporator (31), and an absorber (40), all operatively connected together. The 1R cycle (12) includes a multistage boiler (48), a multi-stage resorber (51), a multisection regenerator (49) and also uses the condenser (21), expansion device (28) and evaporator (31) of the SEA topping subcycle (11), all operatively connected together. External heat is applied to the SEA boiler (13) for operation up to about 500 degrees F., with most of the high pressure vapor going to the condenser (21) and evaporator (31) being generated by the regenerator (49). The substantially adiabatic and isothermal functioning of the SER subcycle (12) provides a high COP. For higher input temperatures of up to 700 degrees F., another SEA cycle (111) is used as a topping subcycle, with the absorber (140) of the topping subcycle being heat coupled to the boiler (13) of an ADR cycle (10). The 1R cycle (12) itself is an improvement in that all resorber stages (50b-f) have a portion of their output pumped to boiling conduits (71a-f) through the regenerator (49), which conduits are connected to and at the same pressure as the highest pressure stage (48a) of the 1R multistage boiler (48).

  7. NEUTRON ABSORPTION AND SHIELDING DEVICE

    DOE Patents [OSTI]

    Axelrad, I.R.

    1960-06-21

    A neutron absorption and shielding device is described which is adapted for mounting in a radiation shielding wall surrounding a radioactive area through which instrumentation leads and the like may safely pass without permitting gamma or neutron radiation to pass to the exterior. The shielding device comprises a container having at least one nonrectilinear tube or passageway means extending therethrough, which is adapted to contain instrumentation leads or the like, a layer of a substance capable of absorbing gamma rays, and a solid resinous composition adapted to attenuate fast-moving neutrons and capture slow- moving or thermal neutrons.

  8. New constraints in absorptive capacity and the optimum rate of petroleum output

    SciTech Connect (OSTI)

    El Mallakh, R

    1980-01-01

    Economic policy in four oil-producing countries is analyzed within a framework that combines a qualitative assessment of the policy-making process with an empirical formulation based on historical and current trends in these countries. The concept of absorptive capacity is used to analyze the optimum rates of petroleum production in Iran, Iraq, Saudi Arabia, and Kuwait. A control solution with an econometric model is developed which is then modified for alternative development strategies based on analysis of factors influencing production decisions. The study shows the consistencies and inconsistencies between the goals of economic growth, oil production, and exports, and the constraints on economic development. Simulation experiments incorporated a number of the constraints on absorptive capacity. Impact of other constraints such as income distribution and political stability is considered qualitatively. (DLC)

  9. Crude Oil Analysis Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shay, Johanna Y.

    The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

  10. The extraction of bitumen from western oil sands. Final report, July 1989--September 1993

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1994-03-01

    Research and development of surface extraction and upgrading processes of western tar sands are described. Research areas included modified hot water, fluidized bed, and rotary kiln pyrolysis of tar sands for extraction of bitumen. Bitumen upgrading included solvent extraction of bitumen, and catalytic hydrotreating of bitumen. Characterization of Utah tar sand deposits is also included.

  11. Shale oil dearsenation process

    SciTech Connect (OSTI)

    Brickman, F.E.; Degnan, T.F.; Weiss, C.S.

    1984-10-29

    This invention relates to processing shale oil and in particular to processing shale oil to reduce the arsenic content. Specifically, the invention relates to treating shale oil by a combination of processes - coking and water washing. Many shale oils produced by conventional retorting processes contain inorganic materials, such as arsenic, which interfere with subsequent refining or catalytic hydroprocessing operations. Examples of these hydroprocessing operations are hydrogenation, denitrogenation, and desulfurization. From an environmental standpoint, removal of such contaminants may be desirable even if the shale oil is to be used directly as a fuel. Hence, it is desirable that contaminants such as arsenic be removed, or reduced to low levels, prior to further processing of the shale oil or prior to its use as a fuel.

  12. Olefin recovery via chemical absorption

    SciTech Connect (OSTI)

    Barchas, R.

    1998-06-01

    The recovery of fight olefins in petrochemical plants has generally been accomplished through cryogenic distillation, a process which is very capital and energy intensive. In an effort to simplify the recovery process and reduce its cost, BP Chemicals has developed a chemical absorption technology based on an aqueous silver nitrate solution. Stone & Webster is now marketing, licensing, and engineering the technology. The process is commercially ready for recovering olefins from olefin derivative plant vent gases, such as vents from polyethylene, polypropylene, ethylene oxide, and synthetic ethanol units. The process can also be used to debottleneck C{sub 2} or C{sub 3} splinters, or to improve olefin product purity. This paper presents the olefin recovery imp technology, discusses its applications, and presents economics for the recovery of ethylene and propylene.

  13. Backscatter absorption gas imaging system

    DOE Patents [OSTI]

    McRae, T.G. Jr.

    A video imaging system for detecting hazardous gas leaks. Visual displays of invisible gas clouds are produced by radiation augmentation of the field of view of an imaging device by radiation corresponding to an absorption line of the gas to be detected. The field of view of an imager is irradiated by a laser. The imager receives both backscattered laser light and background radiation. When a detectable gas is present, the backscattered laser light is highly attenuated, producing a region of contrast or shadow on the image. A flying spot imaging system is utilized to synchronously irradiate and scan the area to lower laser power requirements. The imager signal is processed to produce a video display.

  14. Backscatter absorption gas imaging system

    DOE Patents [OSTI]

    McRae, Jr., Thomas G.

    1985-01-01

    A video imaging system for detecting hazardous gas leaks. Visual displays of invisible gas clouds are produced by radiation augmentation of the field of view of an imaging device by radiation corresponding to an absorption line of the gas to be detected. The field of view of an imager is irradiated by a laser. The imager receives both backscattered laser light and background radiation. When a detectable gas is present, the backscattered laser light is highly attenuated, producing a region of contrast or shadow on the image. A flying spot imaging system is utilized to synchronously irradiate and scan the area to lower laser power requirements. The imager signal is processed to produce a video display.

  15. Neutron scattering and absorption properties

    SciTech Connect (OSTI)

    Holden, N.E.

    1993-12-01

    The Table in this report presents an evaluated set of values for the experimental quantities, which characterize the properties for scattering and absorption of neutrons. The neutron cross section is given for room temperature neutrons, 20.43{degree}C, corresponds to a thermal neutron energy of 0.0253 electron volts (eV) or a neutron velocity of 2200 meters/second. The neutron resonance integral is defined over the energy range from 0.5 eV to 0.1 {times} 10{sup 6} eV, or 0.1 MeV. A list of the major references used is given below. The literature cutoff data is October 1993. Uncertainties are given in parentheses. Parentheses with two or more numbers indicate values to the excited states(s) and to the ground state of the product nucleus.

  16. Hot Oiling Spreadsheet

    Energy Science and Technology Software Center (OSTI)

    1993-10-22

    One of the most common oil-field treatments is hot oiling to remove paraffin from wells. Even though the practice is common, the thermal effectiveness of the process is not commonly understood. In order for producers to easily understand the thermodynamics of hot oiling, a simple tool is needed for estimating downhole temperatures. Such a tool has been developed that can be distributed as a compiled spreadsheet.

  17. Vegetable oil fuel

    SciTech Connect (OSTI)

    Bartholomew, D.

    1981-04-01

    In this article, the future role of renewable agricultural resources in providing fuel is discussed. it was only during this century that U.S. farmers began to use petroleum as a fuel for tractors as opposed to forage crop as fuel for work animals. Now farmers may again turn to crops as fuel for agricultural production - the possible use of sunflower oil, soybean oil and rapeseed oil as substitutes for diesel fuel is discussed.

  18. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 7.6 cents from a week ago to $2.97 per gallon. That's down $1.05 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.94 per gallon, down 6.7 cents from last week, and down $1.07

  19. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 6.3 cents from a week ago to $2.91 per gallon. That's down $1.10 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.88 per gallon, down 6.8 cents from last week, and down $1.13

  20. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 7.5 cents from a week ago to $2.84 per gallon. That's down $1.22 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.80 per gallon, down 7.4 cents from last week, and down $1.23

  1. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 4.1 cents from a week ago to $2.89 per gallon, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.84 per gallon, down 5.4 cents from last week

  2. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 3.6 cents from a week ago to $3.04 per gallon. That's down 99.4 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.01 per gallon, down 3.6 cents from last week, and down $1.01

  3. Lower oil prices also cutting winter heating oil and propane...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    see even lower natural gas and heating oil bills this winter than previously expected ... said the average household heating with oil will experience a 41% drop in heating oil ...

  4. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 2001 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  5. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1998 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  6. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1999 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  7. Upgrading heavy gas oils

    SciTech Connect (OSTI)

    Ferguson, S.; Reese, D.D.

    1986-05-20

    A method is described of neutralizing the organic acidity in heavy gas oils to produce a neutralization number less than 1.0 whereby they are rendered suitable as lube oil feed stocks which consists essentially of treating the heavy gas oils with a neutralizing amount of monoethanolamine to form an amine salt with the organic acids and then heating the thus-neutralized heavy gas oil at a temperature at least about 25/sup 0/F greater than the boiling point of water and for a time sufficient to convert the amine salts to amides.

  8. Pressure dependence of Hexanitrostilbene Raman/ electronic absorption...

    Office of Scientific and Technical Information (OSTI)

    in hydrodynamic simulations of the performance of HNS, we have measured the Raman and electronic absorption spectra of this material under static pressure in a diamond anvil cell. ...

  9. Cavity-Enhanced Transient Absorption Spectroscopy: Ultrafast...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cavity-Enhanced Transient Absorption Spectroscopy: Ultrafast Spectroscopy goes Ultra-Sensitive Wednesday, November 11, 2015 - 3:00pm SLAC, Redtail Hawk Conference Room 108A...

  10. Compact Absorption Chiller - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Efficiency Building Energy Efficiency Find More Like This Return to Search Compact Absorption Chiller Pacific Northwest National Laboratory Contact PNNL About This...

  11. Direct and quantitative broadband absorptance spectroscopy with...

    Office of Scientific and Technical Information (OSTI)

    Patent: Direct and quantitative broadband absorptance spectroscopy with multilayer ... DOE Contract Number: FG02-02ER45977 Resource Type: Patent Research Org: Massachusetts ...

  12. Advanced Low Temperature Absorption Chiller Module Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Data Center - Presentation by Exergy Partners Corp., June 2011 Advanced Low Temperature Absorption Chiller Module Integrated with a CHP System at a Distributed Data Center - ...

  13. Absorption Heat Pump Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat Pump Basics Absorption Heat Pump Basics August 19, 2013 - 11:11am Addthis Absorption heat pumps are essentially air-source heat pumps driven not by electricity, but by a heat source such as natural gas, propane, solar-heated water, or geothermal-heated water. Because natural gas is the most common heat source for absorption heat pumps, they are also referred to as gas-fired heat pumps. There are also absorption coolers available that work on the same principal, but are not reversible and

  14. Combining Feedback Absorption Spectroscopy, Amplified Resonance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Emissions Combining Feedback Absorption Spectroscopy, Amplified Resonance and Low Pressure Sampling for the Measurement of Nitrogen-Containing Compounds in Automotive ...

  15. Pressure dependence of Hexanitrostilbene Raman/ electronic absorption...

    Office of Scientific and Technical Information (OSTI)

    Hexanitrostilbene Raman electronic absorption spectra to validate DFT EOS. Citation Details In-Document Search Title: Pressure dependence of Hexanitrostilbene Raman electronic ...

  16. Commercial Absorption Heat Pump Water Heater

    Broader source: Energy.gov (indexed) [DOE]

    Absorption Heat Pump Water Heater 2016 Building Technologies Office Peer Review Patrick ... The target market is the hospital, hotel and full service restaurant gas hot water heating ...

  17. Oil Shale and Oil Sands Development Robert Keiter; John Ruple...

    Office of Scientific and Technical Information (OSTI)

    Conjunctive Surface and Groundwater Management in Utah: Implications for Oil Shale and Oil Sands Development Robert Keiter; John Ruple; Heather Tanana; Rebecca Holt 29 ENERGY...

  18. STEO September 2012 - oil production

    U.S. Energy Information Administration (EIA) Indexed Site

    EIA analyst Sam Gorgen explains: "Higher oil supplies, especially from North Dakota and Texas, boosted U.S. oil production. The number of on-shore drilling rigs targeting oil ...

  19. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  20. Solvent extraction of bituminous coals using light cycle oil: characterization of diaromatic products in liquids

    SciTech Connect (OSTI)

    Josefa M. Griffith; Caroline E. Burgess Clifford; Leslie R. Rudnick; Harold H. Schobert

    2009-09-15

    Many studies of the pyrolytic degradation of coal-derived and petroleum-derived aviation fuels have demonstrated that the coal-derived fuels show better thermal stability, both with respect to deposition of carbonaceous solids and cracking to gases. Much previous work at our institute has focused on the use of refined chemical oil (RCO), a distillate from the refining of coal tar, blended with light cycle oil (LCO) from catalytic cracking of vacuum gas oil. Hydroprocessing of this blend forms high concentrations of tetralin and decalin derivatives that confer particularly good thermal stability on the fuel. However, possible supply constraints for RCO make it important to consider alternative ways to produce an 'RCO-like' product from coal in an inexpensive process. This study shows the results of coal extraction using LCO as a solvent. At 350{sup o}C at a solvent-to-coal ratio of 10:1, the conversions were 30-50 wt % and extract yields 28-40 wt % when testing five different coals. When using lower LCO/coal ratios, conversions and extract yields were much smaller; lower LCO/coal ratios also caused mechanical issues. LCO is thought to behave similarly to a nonpolar, non-hydrogen donor solvent, which would facilitate heat-induced structural relaxation of the coal followed by solubilization. The main components contributed from the coal to the extract when using Pittsburgh coal are di- and triaromatic compounds. 41 refs., 3 figs., 12 tabs.

  1. Vegetable oil as fuel

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    A review is presented of various experiments undertaken over the past few years in the U.S. to test the performance of vegetable oils in diesel engines, mainly with a view to on-farm energy self-sufficiency. The USDA Northern Regional Research Center in Peoria, Illinois, is screening native U.S. plant species as potential fuel oil sources.

  2. Balancing oil and environment... responsibly.

    SciTech Connect (OSTI)

    Weimer, Walter C.; Teske, Lisa

    2007-01-25

    Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

  3. Transient simulation of absorption machines

    SciTech Connect (OSTI)

    Anand, D.K.; Allen, R.W.; Kumar, B.

    1982-08-01

    This paper presents a model for a water-cooled Lithium-Bromide/water absorption chiller and predicts its transient response both during the start-up phase and during the shutoff period. The simulation model incorporates such influencing factors as the thermodynamic properties of the working fluid, the absorbent, the heat-transfer configuration of different components of the chiller and related physical data. The time constants of different components are controlled by a set of key parameters that have been identified in this study. The results show a variable but at times significant amount of time delay before the chiller capacity gets close to its steady-state value. The model is intended to provide an insight into the mechanism of build-up to steady-state performance. By recognizing the significant factors contributing to transient degradation, steps can be taken to reduce such degradation. The evaluation of the residual capacity in the shut-off period will yield more realistic estimates of chiller COP for a chiller satisfying dynamic space cooling load.

  4. Transient simulation of absorption machines

    SciTech Connect (OSTI)

    Anand, D.K.; Allen, R.W.; Kumar, B.

    1982-08-01

    This paper presents a model for a water-cooled Lithium-Bromide/water absorption chiller and predicts its transient response both during the start-up phase and during the shutoff period. The simulation model incorporates such influencing factors as the thermodynamic properties of the working fluid, the absorbent, the heat-transfer configuration of different components of the chiller and related physical data. The time constants of different components are controlled by a set of key parameters that have been identified in this study. The results show a variable but at times significant amount of time delay before the chiller capacity gets close to its steadystate value. The model is intended to provide an insight into the mechanism of build-up to steady-state performance. By recognizing the significant factors contributing to transient degradation, steps can be taken to reduce such degradation. The evaluation of the residual capacity in the shut-off period will yield more realistic estimates of chiller COP for a chiller satisfying dynamic space cooling load.

  5. Corrosivity Of Pyrolysis Oils

    SciTech Connect (OSTI)

    Keiser, James R; Bestor, Michael A; Lewis Sr, Samuel Arthur; Storey, John Morse

    2011-01-01

    Pyrolysis oils from several sources have been analyzed and used in corrosion studies which have consisted of exposing corrosion coupons and stress corrosion cracking U-bend samples. The chemical analyses have identified the carboxylic acid compounds as well as the other organic components which are primarily aromatic hydrocarbons. The corrosion studies have shown that raw pyrolysis oil is very corrosive to carbon steel and other alloys with relatively low chromium content. Stress corrosion cracking samples of carbon steel and several low alloy steels developed through-wall cracks after a few hundred hours of exposure at 50 C. Thermochemical processing of biomass can produce solid, liquid and/or gaseous products depending on the temperature and exposure time used for processing. The liquid product, known as pyrolysis oil or bio-oil, as produced contains a significant amount of oxygen, primarily as components of water, carboxylic acids, phenols, ketones and aldehydes. As a result of these constituents, these oils are generally quite acidic with a Total Acid Number (TAN) that can be around 100. Because of this acidity, bio-oil is reported to be corrosive to many common structural materials. Despite this corrosive nature, these oils have the potential to replace some imported petroleum. If the more acidic components can be removed from this bio-oil, it is expected that the oil could be blended with crude oil and then processed in existing petroleum refineries. The refinery products could be transported using customary routes - pipelines, barges, tanker trucks and rail cars - without a need for modification of existing hardware or construction of new infrastructure components - a feature not shared by ethanol.

  6. Gas-fueled absorption heat pump

    SciTech Connect (OSTI)

    Florette, M.; Peuportier, B.

    1982-01-01

    To determine the feasibility of using an absorption heat pump for residential space heating, French investigators are studying both theoretically and experimentally, the performance of the absorption cycle in terms of its efficiency and suitability to space-heating conditions. A 10-kW pilot unit is supplying data on design criteria, heat-exchange fluid selection, and heat and mass balances.

  7. Novel absorption detection techniques for capillary electrophoresis

    SciTech Connect (OSTI)

    Xue, Y.

    1994-07-27

    Capillary electrophoresis (CE) has emerged as one of the most versatile separation methods. However, efficient separation is not sufficient unless coupled to adequate detection. The narrow inner diameter (I.D.) of the capillary column raises a big challenge to detection methods. For UV-vis absorption detection, the concentration sensitivity is only at the {mu}M level. Most commercial CE instruments are equipped with incoherent UV-vis lamps. Low-brightness, instability and inefficient coupling of the light source with the capillary limit the further improvement of UV-vis absorption detection in CE. The goals of this research have been to show the utility of laser-based absorption detection. The approaches involve: on-column double-beam laser absorption detection and its application to the detection of small ions and proteins, and absorption detection with the bubble-shaped flow cell.

  8. Absorption of carbonyl sulfide in aqueous methyldiethanolamine

    SciTech Connect (OSTI)

    Al-Ghawas, H.A.; Ruiz-Ibanez, G.; Sandall, O.C. (Dept. of Chemical and Nuclear Engineering, Univ. of California, Santa Barbara, CA (US))

    1988-01-01

    The absorption of carbonyl sulfide in aqueous methyldiethanolamine (MDEA) was studied over a range of temperatures and MDEA concentrations. MDEA is commonly used for selective absorption of hydrogen sulfide in the presence of carbon dioxide. However, sulfur in the form of COS may also be present and it is necessary that estimates of absorption rates of this compound be made. The objective of this study is to determine the physiochemical properties needed to predict COS absorption rates in aqueous MDEA. Free gas solubility and the diffusivity of COS in MDEA solutions were measured over the temperature range 15 to 40{sup 0}C for MDEA concentrations up to 30 weight per cent using the nitrous oxide analogy method. Solubilities were measured volumetrically in an equilibrium cell and diffusivities were measured using a laminar liquid jet absorber. The kinetics of the reaction between COS and MDEA were studied by measuring absorption rates in a single wetted-sphere absorber.

  9. INCREASING WATERFLOOD RESERVES IN THE WILMINGTON OIL FIELD THROUGH IMPROVED RESERVOIR CHARACTERIZATION AND RESERVOIR MANAGEMENT

    SciTech Connect (OSTI)

    Scott Walker; Chris Phillips; Roy Koerner; Don Clarke; Dan Moos; Kwasi Tagbor

    2002-02-28

    This project increased recoverable waterflood reserves in slope and basin reservoirs through improved reservoir characterization and reservoir management. The particular application of this project is in portions of Fault Blocks IV and V of the Wilmington Oil Field, in Long Beach, California, but the approach is widely applicable in slope and basin reservoirs. Transferring technology so that it can be applied in other sections of the Wilmington Field and by operators in other slope and basin reservoirs is a primary component of the project. This project used advanced reservoir characterization tools, including the pulsed acoustic cased-hole logging tool, geologic three-dimensional (3-D) modeling software, and commercially available reservoir management software to identify sands with remaining high oil saturation following waterflood. Production from the identified high oil saturated sands was stimulated by recompleting existing production and injection wells in these sands using conventional means as well as a short radius redrill candidate. Although these reservoirs have been waterflooded over 40 years, researchers have found areas of remaining oil saturation. Areas such as the top sand in the Upper Terminal Zone Fault Block V, the western fault slivers of Upper Terminal Zone Fault Block V, the bottom sands of the Tar Zone Fault Block V, and the eastern edge of Fault Block IV in both the Upper Terminal and Lower Terminal Zones all show significant remaining oil saturation. Each area of interest was uncovered emphasizing a different type of reservoir characterization technique or practice. This was not the original strategy but was necessitated by the different levels of progress in each of the project activities.

  10. China shows increasing interest in heavy oil and oil sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    China and Canadian and US groups are cooperating in several areas to develop the heavy oil, asphalt, and oil sand deposits of China. The agreements dealing with exploration and upgrading are briefly described. The majority of the paper describes the occurrences of heavy oil, asphalt, and oil sands in China. 1 figure.